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Safety Data Sheets Forestry Main Office / Shop Solon Forestry Department 11/16/2015 ---PAGE BREAK--- Safety Data Sheet Index Binder: Forestry Department - Forestry Main Office / Shop Solon 121-45 CUTTER INSECT REPELLENT-TICK REPELLENT Miles Inc. - Consumer Household Products 09/27/1993 7 235605 Stainless Steel Cleaner (A-209) Wood Wyant Inc. 03/05/2008 10 28201 - HEET Gas Line Antifreeze 67-56-1 GOLD EAGLE COMPANY 03/11/2010 16 3BT Humidifier Bacteriostatic Water Treatment RPS Products Inc 05/13/2008 23 3BT Humidifier Bacteriostatic Water Treatment 8030-78-2 RPS Products Inc 05/20/2015 26 3M BRAND DESK AND OFFICE CLEANER 573 3M - Office Supplies Division 02/12/2013 30 3M BRAND DESK AND OFFICE CLEANER 573 3M - Stationery & office Supplies 02/10/2015 39 A-100 Exterior Flat Latex Paint, White Sherwin-Williams Company 03/18/2008 49 AERO SPOT CO2 ALL COLORS Nelson Paint Company 05/30/2002 55 AEROBLUE Foam hand and Body Shampoo AEROBLUE 12/14/2012 60 AIR WICK Air Freshener (Aerosols All Scents) Reckitt Benckiser 09/26/2012 62 Ajax Bleach Alternative OXI Regular and HE Heavy Duty Liquid Detergent; All Sizes Phoenix Brands LLC 06/04/2012 70 ALL WEATHER OUTDOOR CARPET ADHESIVE DAP, INC. 05/15/2003 75 Antiseptic Spray ZEE MEDICAL, INC. 02/01/1999 82 AQUA hand soap AQUA 12/14/2012 84 BLAST BLEACH ZECOL PRODUCTS COMPANY 05/01/2007 88 Blood Clotting Spray ZEE MEDICAL, INC. 02/01/2012 90 Blue Chalk - Standard Irwin Industrial Tools 03/15/2007 92 Burn Relief Spray, Non-Aerosol ZEE MEDICAL, INC. 02/01/2012 96 CLEAR GUARD AEROSOL CHEMSEARCH DIV. OF NCH CORP. 08/19/2013 98 CLEAR GUARD AEROSOL CHEMSEARCH DIV. OF NCH CORP. 12/16/2014 104 CLOROX REGULAR-BLEACH The Clorox Company 07/01/2012 110 Comet With Bleach (All Variations) Procter & Gamble 11/01/1999 111 Product Name CAS Number Manufacturer Version Date Page Page 2 of 553 Page 2 of 553 Page 2 of 553 Page 2 of 553 ---PAGE BREAK--- COMPLETE floor finish COMPLETE 12/14/2012 115 DAP 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR DAP, INC. 01/29/2002 119 DAWN (All Variations) Procter & Gamble 09/08/2005 127 DAWN (All Variations), IVORY (All Variations), JOY (All Variations), SALVO Procter & Gamble - Fabric and Home Care 09/25/2003 131 De-Solv-it ORANGE-SOL Household Products, Inc. 08/11/2009 135 DERMA FLEUR Lotion ZEE MEDICAL, INC. 02/01/2012 139 Distilled White Vinegar 8028-52-2 H.J. HEINZ CO. 08/22/2011 141 DRANO MAX GEL S. C. Johnson & Son, Inc. 10/07/2005 143 DUST MOP / DUST CLOTH TREATMENT (BULK) Spartan Chemical Company, Inc. 06/08/2012 147 DUTCH BOY* Professional Ext. Acrylic Latex Traffic Zone Marking Paint, Yellow Dutch Boy Group 10/28/2004 149 Elements low ordor stripper Elements 12/14/2012 154 Expo Dry Erase Cleaner Sanford Corporation 10/20/2003 158 Expunge Lawson Products, Inc. 07/29/2014 160 Expunge Lawson Products, Inc. 02/03/2014 164 Eye Wash ZEE MEDICAL, INC. 02/01/2012 168 Eye/Skin Buffered Flushing Solution ZEE MEDICAL, INC. 02/01/2012 170 Eye/Skin Buffered Flushing Solution ZEE MEDICAL, INC. 06/01/2008 172 Febreeze 64-17-5 Procter & Gamble 11/01/1999 174 FIRST MARK ALL PURPOSE PINE CLEANER Performance Food Group 02/05/2010 178 FLASH AEROSOL CHEMSEARCH DIV. OF NCH CORP. 04/01/2011 182 FORMULA 409 ALL PURPOSE CLEANER The Clorox Company 03/01/2010 186 FSCA6, FSRM6, FSFV6, FSOB6 SPLASH SCENTS RPS Products Inc 10/01/2005 187 Garden Safe Houseplant & Garden Insect Spray, Garden Safe Rose & Flo0wer Insect Spray, Garden Safe Fruit & Vegetable Insect Spray Schultz Company 01/01/2001 191 Glade Neutralizer Aerosol S.C. Johnson & Son, Inc. 01/16/2007 194 GREM X wipes GERM X wipes 12/14/2012 198 Hydrogen Peroxide ZEE MEDICAL, INC. 10/01/2009 204 Product Name CAS Number Manufacturer Version Date Page Page 3 of 553 Page 3 of 553 Page 3 of 553 Page 3 of 553 ---PAGE BREAK--- Hydrogen Peroxide 7722-84-1 ZEE MEDICAL, INC. 02/01/2012 206 Instant Cold Spray ZEE MEDICAL, INC. 02/01/2012 208 InstantFOAM ALCOHOL HAND SANITIZER Deb USA, Inc. 03/07/2011 210 INT EXT LTX FLAT WHITE The Valspar Corporation - Architectural Coatings Division 02/09/2011 213 ISOPROPYL ALCOHOL (IPA) 70% Cumberland Swan 03/01/2000 219 Joint Cement Powder BONDEX INTERNATIONAL INC 10/14/1985 223 Kleen All Kleen All 12/14/2012 226 LAV Clean LAV Clean 12/14/2012 228 LIQUID PAPER CORRECTION FLUID (COLORS, LPCF-17) Gillette Medical evaluation Labs 12/10/1998 230 LUSTER COTE (AEROSOL) TRI-CHEM CORPORATION 06/11/2007 234 Lysol Disinfectant Spray Reckitt Benckiser, Inc. 12/21/2004 236 MAGIC SHOCK FREE (aerosol product) MAGIC AMERICAN PRODUCTS, INC. 12/17/2002 240 Miracle-Gro Liquid African Violet Plant Food, 7- 7-7 Scotts Company 07/29/2005 241 Miracle-Gro Potting Mix Scotts Miracle - Gro Products Inc. 06/21/2001 245 Miracle-Gro Pro Select All Purpose Plant Food 20-20-20 Scotts Company 09/21/2004 250 Muskol Aerosol Insect Repellent (40%) Schering-Plough HealthCare Products, Inc. 05/08/1997 254 OfficeMax Compressed Gas Duster Falcon Safety Products, Inc 10/28/2009 257 OfficeMax Compressed Gas Duster Falcon Safety Products, Inc 10/28/2009 263 ORANGE TOUGH 15 Spartan Chemical Company, Inc. 01/09/2012 269 ORTHO ROSE & FLOWER INSECT KILLER READY-TO-USE The ORTHO Group 10/10/2011 271 ORTHO ROSE & FLOWER INSECT KILLER READY-TO-USE The ORTHO Group 11/24/2013 276 OUST AIR SANITIZER - CITRUS SCENT S. C. Johnson & Son, Inc. 01/31/2002 283 OUST AIR SANITIZER - CITRUS SCENT S. C. Johnson & Son, Inc. 03/08/2007 287 OUST AIR SANITIZER - CITRUS SCENT S. C. Johnson & Son, Inc. 04/28/2005 291 OUST AIR SANITIZER - CITRUS SCENT S. C. Johnson & Son, Inc. 05/08/2007 295 Patching Plaster BONDEX INTERNATIONAL INC 10/28/1997 299 Perma Glaze, elastic, face glazing compound 8052-41-3 Schnee-Morehead, Inc. 03/08/1999 304 Product Name CAS Number Manufacturer Version Date Page Page 4 of 553 Page 4 of 553 Page 4 of 553 Page 4 of 553 ---PAGE BREAK--- PINESOL YELLOW The Clorox Company 07/25/2000 307 POWER X WINDOW CLEANER Custom Solutions Inc 12/20/2002 315 Propane 74-98-6 SpecAir Specialty Gases 11/28/2006 318 Raid Flying Insect Killer JohnsonDiversey 01/15/2003 321 RAID WASP & HORNET KILLER 33 S.C. Johnson & Son, Inc. 03/26/2009 324 RAID WASP & HORNET KILLER 33 S.C. Johnson & Son, Inc. 02/23/2015 332 RAID WASP & HORNET KILLER 33 S.C. Johnson & Son, Inc. 05/17/2011 346 Rain X Rain X 12/14/2012 356 Resilience Exterior Latex Satin Paint, Extra White Sherwin-Williams Company 05/14/2008 360 Resolve Carpet Stain Remover (Trigger Spray) Reckitt Benckiser, Inc. 10/28/2003 365 RESOLVE DUAL POWER CARPET STAIN REMOVER (LIQUID) Reckitt Benckiser North America, Inc. 07/24/2009 369 Rust Stain Remover Whink Products Company 02/01/2008 374 Rust Stain Remover Whink Products Company 10/06/2008 381 Rust Stain Remover Whink Products Company 07/20/2014 389 Rust Stain Remover Whink Products Company 04/03/2012 395 Scotchguard Fabric Protector 3M - Protective Materials & Consumer Specialties Division 09/14/2005 403 Sheila Shine (Aerosol) SHEILA SHINE, INC. 07/26/2007 411 Sheila Shine (Aerosol) SHEILA SHINE, INC. 08/01/2014 415 Sheila Shine (Aerosol) SHEILA SHINE, INC. 01/08/2014 431 Sheila Shine (Aerosol) SHEILA SHINE, INC. 05/20/2010 447 Sheila Shine (Aerosol) SHEILA SHINE, INC. 05/01/2013 451 Sheila Shine (Liquid) SHEILA SHINE, INC. 07/26/2007 455 Shine Shine 12/14/2012 459 SHINE PLUS Spartan Chemical Company, Inc. 03/07/2011 460 SHINE PLUS Spartan Chemical Company, Inc. 03/20/2014 462 Sikkens wood siding maintenance Sikkens 12/14/2012 464 Sil-Glyde Grease AGS COMPANY 10/20/2014 470 SOFT CARE LOTIONIZED HAND SOAP Johnson Wax Professional 02/25/2003 477 SUPER SPOT TREE MARK ALL COLOR Nelson Paint Company 05/09/2002 480 Product Name CAS Number Manufacturer Version Date Page Page 5 of 553 Page 5 of 553 Page 5 of 553 Page 5 of 553 ---PAGE BREAK--- The Works Glass And Surface Cleaner HomeCare Labs Inc 02/11/2004 483 TnT TUB AND TILE CLEANER Spartan Chemical Company 09/24/1999 487 transparent glass cleaner tri chem 12/14/2012 490 Transparent glass cleaner tri chem 12/14/2012 492 Tree & Log Marking Paint Nelson Paint Company 01/05/2010 494 Tri Black tri chem 12/14/2012 498 Tri Clean tri chem 12/14/2012 500 TURTLE WAX BUG & TAR AND TREE SAP REMOVER Turtle Wax, Inc. 09/11/2007 502 TURTLE WAX PREMIUM POLISHING COMPOUND, T-417(C) Turtle Wax, Inc. 07/25/2006 507 UNITED 195 SMELL JEL United Laboratories Inc. 12/22/2009 509 UNITED 195 SMELL JEL United Laboratories Inc. 06/29/2015 511 UNITED 195 SMELL JEL United Laboratories Inc. 12/22/2012 512 UNITED 50 PINK MARVEL United Laboratories Inc. 02/16/2012 514 VAL INT EXT GLS BLACK The Valspar Corporation - Architectural Coatings Division 10/17/2009 516 Vinyl Cement Patch AKONA CORPORATION 06/21/2002 522 WD-40 WD-40 Company 03/13/2010 524 Whink Rust Flush Whink Products Company 01/01/2007 528 WHITE MARKING SPRAY PAINT Rust-Oleum Corporation - Industrial Coatings 02/14/2001 534 WHITE MARKING SPRAY PAINT Rust-Oleum Corporation - Industrial Coatings 09/19/2001 543 Zinc floor finish Zinc Floor finish 12/14/2012 552 Product Name CAS Number Manufacturer Version Date Page Page 6 of 553 Page 6 of 553 Page 6 of 553 Page 6 of 553 ---PAGE BREAK--- MILES HOUSEHOLD PRODUCTS DIV 121-45 CUTTER INSECT REPELLENT-TICK REPELLENT MATERIAL SAFETY DATA SHEET NSN: 684000F030344 Manufacturer's CAGE: 62801 Part No. Indicator: A Part Number/Trade Name: 121-45 CUTTER INSECT REPELLENT-TICK REPELLENT FORMULA MMII General Information Company's Name: MILES INC HOUSEHOLD PRODUCTS DIV Company's Street: 7123 W 65TH ST Company's City: CHICAGO Company's State: IL Company's Country: US Company's Zip Code: 60638-4605 Company's Emerg Ph [PHONE REDACTED]/[PHONE REDACTED] Company's Info Ph [PHONE REDACTED] Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SE Date MSDS Prepared: 27MAR91 Safety Data Review Date: 27SEP93 Preparer's Company: MILES INC HOUSEHOLD PRODUCTS DIV Preparer's St Or P. O. Box: 7123 W 65TH ST Preparer's City: CHICAGO Preparer's State: IL Preparer's Zip Code: 60638-4605 MSDS Serial Number: Ingredients/Identity Information Proprietary: NO Ingredient: ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL Ingredient Sequence Number: 01 NIOSH (RTECS) Number: KQ6300000 CAS Number: 64-17-5 OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM Other Recommended Limit: 1900 MG/CUM Proprietary: NO Ingredient: HYDROCARBON PROPELLANT, PETROLEUM GASES LIQUEFIED SWEETENED, C3-7 *93-3* Ingredient Sequence Number: 02 NIOSH (RTECS) Number: 1004627HP CAS Number: 68476-86-8 Proprietary: NO Ingredient: N,N-DIETHYL-META-TOLUAMIDE, DEET, FLYPEL Ingredient Sequence Number: 03 Percent: 28.5 NIOSH (RTECS) Number: XS3675000 CAS Number: 134-62-3 Proprietary: NO Ingredient: N,N-DIMETHYL-P-TOLUIMIDE *93-3* Page 7 of 553 Page 7 of 553 Page 7 of 553 Page 7 of 553 ---PAGE BREAK--- Ingredient Sequence Number: 04 Percent: 1.5 NIOSH (RTECS) Number: 1004013TO CAS Number: 272-85-4 Proprietary: NO Ingredient: N/N-DIETHYL-0-TOLUIMIDE *93-3* Ingredient Sequence Number: 05 NIOSH (RTECS) Number: 1004013TO CAS Number: 272-84-3 Physical/Chemical Characteristics Appearance And Odor: CLEAR, COLORLESS OR PALE YELLOW LIQUID W/ETHANOLIC ODOR. Boiling Point: 75C Vapor Pressure (MM Hg/70 43 Vapor Density (Air=1): 1.6 Specific Gravity: 0.862 Evaporation Rate And Ref: (BU AC = 1 Percent Volatiles By Volume: 70 Fire and Explosion Hazard Data Flash Point: 50F Flash Point Method: CC Lower Explosive Limit: 3.3% Upper Explosive Limit: 19% COPIOUS AMOUNTS OF WATER. Unusual Fire And Expl Hazrds: AUTOIGNITION TEMPERATURE: 793F. FLAMMABLE. Reactivity Data Stability: YES Cond To Avoid (Stability): HEAT, SPARKS, OPEN FLAME, & OTHER SOURCES OF IGNITION Materials To Avoid: (E.G. RAYON), LEATHER Hazardous Poly Occur: NO Health Hazard Data LD50-LC50 Mixture: ORAL LD50 (RAT): >500 MG/KG Route Of Entry - Inhalation: NO Route Of Entry - Skin: NO Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: EYES: IRRITATION. SKIN: REACTIONS IN RARE CASES. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NONE Of Overexp: EYES: IRRITATION. Emergency/First Aid Proc: EYES: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. INGESTION: IF CONSCIOUS, GIVE 1-2 GLASSES OF WATER & INDUCE VOMITING. IF UNCONSCIOUS, DON'T INDUCE VOMITING OR GIVE ANYTHING BY MOUTH. SKIN: WASH W/ SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. Page 8 of 553 Page 8 of 553 Page 8 of 553 Page 8 of 553 ---PAGE BREAK--- Precautions for Safe Handling and Use Steps If Matl Released/Spill: REMOVE ALL POSSIBLE IGNITION SOURCES. WIPE UP W/ABSORBENT MATERIAL. WASH SMALL QUANTITIES AWAY W/SOAPY WATER. PREVENT BULK QUANTITIES FROM ENTERING OPEN SEWERS/WATERWAYS. Waste Disposal Method: FLAMMABLE. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. DON'T PUNCTURE OR INCINERATE EMPTY CONTAINER, DISPOSE OF PROPERLY. Precautions-Handling/Storing: MAY SOFTEN OR DAMAGE SOME SUCH AS RAYON. MAY DAMAGE LEATHER. DON'T INGEST. KEEP OUT OF EYES. APPLY ONLY TO SKIN OR CLOTHING. Other Precautions: FREQUENT REAPPLICATION OR SATURATION IS UNNECESSARY. AVOID BREATHING MIST. FOR PERSONAL USE. DON'T EXPOSE TREATED SKIN TO FIRE, SPARKS, OR FLAME UNTIL LIQUID HAS DRIED. Control Measures Ventilation: ADEQUATE Transportation Data Disposal Data Label Data Label Required: NO Label Status: X Common Name: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED Page 9 of 553 Page 9 of 553 Page 9 of 553 Page 9 of 553 ---PAGE BREAK--- Page 10 of 553 Page 10 of 553 Page 10 of 553 Page 10 of 553 ---PAGE BREAK--- Page 11 of 553 Page 11 of 553 Page 11 of 553 Page 11 of 553 ---PAGE BREAK--- Page 12 of 553 Page 12 of 553 Page 12 of 553 Page 12 of 553 ---PAGE BREAK--- Page 13 of 553 Page 13 of 553 Page 13 of 553 Page 13 of 553 ---PAGE BREAK--- Page 14 of 553 Page 14 of 553 Page 14 of 553 Page 14 of 553 ---PAGE BREAK--- Page 15 of 553 Page 15 of 553 Page 15 of 553 Page 15 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 28201 - HEET Gas Line Antifreeze SEC 1 - PRODUCT AND MANUFACTURER INFO SEC 9 - PHYS, CHEM PROPERTIES SEC 2 - COMPOSITION INFORMATION SEC 10 - STABILITY, REACTIVITY SEC 3 - HAZARDS IDENTIFICATION SEC 11 - TOXICOLOGY INFORMATION SEC 4 - FIRST AID MEASURES SEC 12 - ECOLOGICAL INFORMATION SEC 5 - FIRE FIGHTING MEASURES SEC 13 - DISPOSAL CONSIDERATIONS SEC 6 - ACCIDENTAL RELEASE MEASURES SEC 14 - TRANSPORT INFORMATION SEC 7 - HANDLING AND STORAGE SEC 15 - REGULATORY INFORMATION SEC 8 - EXPOSURE, PERS. PROTECTION SEC 16 - ADDITIONAL INFORMATION SECTION 1 - CHEMICAL PRODUCT AND MANUFACTURER IDENTIFICATION Product Name: 28201 - HEET Gas Line Antifreeze Part Number: 28201 Product CAS: (None) Product Code: 28201 Synonyms: 28201 - HEET Gas Line Antifreeze MANUFACTURER IDENTIFICATION Name: Gold Eagle Company Address: 4400 S. Kildare Blvd. City: Chicago State: IL Zip: 60632-4372 For information call: [PHONE REDACTED] Emergency Number: N/A Emergency Agency: INFOTRAC Agency Number: 1-[PHONE REDACTED] MSDS Effective Date: 1/1/1980 MSDS Supersedes Date: 3/11/2010 Miscellaneous: Product CAS: Mixture Brief Description: Gas line dryer and antifreeze for automobiles. Return to top SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS 1 of 7 2/15/2011 11:30 AM Page 16 of 553 Page 16 of 553 Page 16 of 553 Page 16 of 553 ---PAGE BREAK--- Chemical Name CAS MIN MAX Methanol 67-56-1 99 99 Proprietary Additive (none) 1 1 Miscellaneous: CHEMICAL NAME LIMIT VALUES Methanol PEL 200 ppm PEL 260 mg/m3 Proprietary Additive (CAS#:Mixture) N/A Return to top SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: NFPA: Health: 1 Fire: 3 Reactivity: 0 Specific Hazard: None HMIS: Health: 1 Flammability: 3 Reactivity: 0 PPE: B Miscellaneous: This product does not contain any components above de minimus concentrations that are considered carcinogenic by OSHA, IARC or NTP. POTENTIAL HEALTH EFFECTS Target Organs/Primary Route(s) of Entry: Eye: Mild irritant. Skin: Prolonged or repeated skin contact may cause dermatitis, scaling and possible systemic effects. Ingestion: POISON-Oral human lowest lethal dose = 6.4 g/kg Inhalation: Poisonous, narcotic chemical affecting central nervous system resulting in: dizziness, nausea, visual impairment, narcosis and muscular impairment. Miscellaneous: Return to top SECTION 4 - FIRST AID MEASURES Eye: If the product contacts the eyes, immediately wash the eyes with large quantities of room temperature water for at least 15 minutes, occasionally lifting the lower and upper lids. Get medical attention immediately. A follow up visit to an ophthalmologist should be made. Contact lenses should not be worn when working with this chemical. Skin: If the product contacts the skin, wash the contaminated skin with soap and water for at least 15 minutes. If this product penetrates the clothing, remove the clothing and wash the skin with soap and water. Systemic effects may be delayed 18 to 72 hours, therefore keep individual under observation. Ingestion: If this product is ingested and the person is conscious, induce vomiting, then give 2 teaspoons of baking soda in a glass of water. DO NOT INDUCE AN UNCONSCIOUS PERSON TO VOMIT. Get medical attention immediately. 2 of 7 2/15/2011 11:30 AM Page 17 of 553 Page 17 of 553 Page 17 of 553 Page 17 of 553 ---PAGE BREAK--- Inhalation: Move the exposed person to fresh air at once and call emergency medical care. If breathing has stopped, give artificial respiration. If breathing is difficult, give humidified oxygen. Notes to Physician: No data available. Return to top SECTION 5 - FIRE FIGHTING MEASURES Flash Point: 52 F. (11 TOC AutoIgnition Temperature: N/A Flammable Limits Lower Limit: Explosive Limit (LEL): 6.0 Upper Limit: Explosive Limit (UEL): 36.5 Extinguishing Media: Use halon replacement or carbon dioxide extinguishers or alcohol foam for small fires. Water spray or fog can cool fire but may not be effective in extinguishing fire. Large fires should be extinguished with alcohol foam. Use water spray to cool containers exposed to fire. Containers may explode in heat or fire. Unusual Fire and Explosion Hazards: Dangerous fire and explosion hazard when exposed to heat or flame. Methanol is extremely flammable and forms explosive mixtures with air. Methanol vapors may travel considerable distance to a source of ignition and flash back. Special Fire Fighting Procedures: Wear NIOSH approved SCBA respirator in the positive pressure mode and chemical protective clothing. General Information: Flammable Limits: 6.0 to 36.5 Return to top SECTION 6 - ACCIDENTAL RELEASE MEASURES Small Spill: Remove sources of heat or ignition, provide adequate ventilation, contain leak using absorbent, inert, non-combustible material. Large Spill: Contain spill, transfer to secure containers. In the event of an uncontrolled material release, the user should determine if release is reportable under applicable laws and regulations. Return to top SECTION 7 - HANDLING AND STORAGE Handling: See other sections of MSDS. Storage: See other sections of MSDS. 3 of 7 2/15/2011 11:30 AM Page 18 of 553 Page 18 of 553 Page 18 of 553 Page 18 of 553 ---PAGE BREAK--- Return to top SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION GENERAL HYGIENE CONSIDERATIONS: Use normal hygiene practices. OTHER PRECAUTIONS: Methanol waste and material contaminated with methanol would be regulated as a hazardous waste material under the hazardous waste number U154. ENGINEERING CONTROLS: Local Exhaust: Provide local ventilation to maintain exposure levels below recommended exposure limits. Mechanical (General): In confined spaces, mechanical ventilation may be required. Special Ventilation: N/A Other Ventilation: N/A PERSONAL PROTECTIVE EQUIPMENT Eyes/face: Use splash proof chemical, safety goggles or appropriate full-face respirator. Contact lenses should not be worn when working with this chemical. Skin: Use natural rubber or neoprene gloves as required. Respirators: Do not use air purifying respirator. Use NIOSH approved respirator approved supplied or self contained respirator. Respirators must be selected based on the airborne levels found in the workplace and must not exceed the working limits of the respirator. Other Protective Clothing/Equipment: If there is a possibility of exposure of an individual's body to methanol, wear body covering work clothes to avoid prolonged or repeated exposure. Return to top SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance/Odor: Yellow liquid, solvent odor pH: N/A Vapor Pressure: (MM HG): 97.0 Vapor Density(Air=1): 1.1 Evaporation Rate: N/A Viscosity: N/A Boiling Point: 148 F. (65 N/A 4 of 7 2/15/2011 11:30 AM Page 19 of 553 Page 19 of 553 Page 19 of 553 Page 19 of 553 ---PAGE BREAK--- Freezing/Melting Point: N/A Decomposition Temperature: N/A Solubility in Water: Soluble Specific Gravity: 0.795 Molecular Formula: N/A Molecular Weight: N/A VOC Coating (minus water): 0 Lbs/Gallon Coating Density : 0 Lbs/Gallon Solvent Density : 0 Lbs/Gallon Percent Solvent (volume): 0 Percent Solids (volume): 0 Percent Water (volume): 0 Percent Volatile by Weight: 0 Miscellaneous: % Volatile/Volume: 100.0 Specific Gravity (H2O = N/A Percent Solvent (Volume): N/A Percent Solids (Volume): N/A Percent Water (Volume): N/A Product is flammable, keep away from sources of ignition, combustibles, oxidizing material and acid. Store in an area equipped with automatic sprinklers or fire extinguishing system. Empty containers contain product residues, assume empty container to have the same hazards as full containers. Return to top SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable: Yes Conditions to Avoid: Store in a well ventilated place away from sources of ignition, combustibles, oxidizing materials and acid. Incompatibilities with Other Materials: Strong oxidizing agents, aluminum, zinc, or metals that displace hydrogen, rubber and rubber based coatings, chromic lead perchlorate and perchloric acids. Hazardous Decomposition Products: Excessive heating and/or incomplete combustion will produce carbon monoxide. Hazardous Polymerization: 5 of 7 2/15/2011 11:30 AM Page 20 of 553 Page 20 of 553 Page 20 of 553 Page 20 of 553 ---PAGE BREAK--- Hazardous Polymerization May Occur: No Return to top SECTION 11 - TOXICOLOGICAL INFORMATION No data available. Return to top SECTION 12 - ECOLOGICAL INFORMATION No data available. Return to top SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of product in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections of MSDS for hazard warning information. Return to top SECTION 14 - TRANSPORT INFORMATION Transportation Information: Shipping Information (CFR 49 and IMDG): Proper Shipping Name: Gasoline Additive, N.O.I. DOT Hazard Class: Consumer commodity, ORM-D DOT UN Number: None required. IMDG Shipping Name: Dangerous Goods in Limited Quantities of Class 3.2 (Methanol), PGII Label Information: No data available. Return to top SECTION 15 - REGULATORY INFORMATION SARA Title III: Section 302: None Section 304: None Section 311: Hazard categories-Fire Hazard-Yes; Acute=Yes and Chronic=Yes Section 313: Methanol, CAS# 67-56-1, 99.0% CERCLA: Section 311(b)(4): Requires discharges of crude oil and petroleum products in any kind or form to waters must immediately be reported to the National Response Center at (800) 424-8802. Return to top 6 of 7 2/15/2011 11:30 AM Page 21 of 553 Page 21 of 553 Page 21 of 553 Page 21 of 553 ---PAGE BREAK--- SECTION 16 - ADDITIONAL INFORMATION Disclaimer: Information presented herein is believed to be factual, as it has been derived from the works and opinions of persons believed to be qualified experts. However, nothing contained in this information is to be taken as warranty or representation for which the Gold Eagle Co. bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate. Prepared by: Mike Profetto Return to top 7 of 7 2/15/2011 11:30 AM Page 22 of 553 Page 22 of 553 Page 22 of 553 Page 22 of 553 ---PAGE BREAK--- 3BT BACTERIOSTATIC WATER TREATMENT RPS Products, Inc. 281 Keyes Avenue, Hampshire, IL 60140 ([PHONE REDACTED]) MATERIAL SAFETY DATA SHEET A. Identification and Emergency Information Product Identity: 3BT Humidifier Bacteriostatic Water Treatment Emergency Telephone Numbers: R.P.S. Products [PHONE REDACTED] Chemtrec [PHONE REDACTED] B. Components and Hazard Information Hazardous Components (Specific Chemical Identity) (Common name(s)) CAS Number OSHA PEL ACGIH TLV %Percent None C. Emergency and First Aid Procedures Eye Contact Flush eyes with plenty of flowing water for 15 minutes lifting upper and lower lids. Remove contact lenses if applicable. Seek medical attention. Skin Contact Wash with plenty of soap and water. If irritation develops, seek medical attention. Inhalation Remove person to fresh air. If breathing has stopped, resuscitate and seek medical attention. Ingestion If ingested, MAY CAUSE ABDOMINAL IRRITATION, NAUSEA, VOMITING, AND DIARREHEA. Seek medical attention immediately. INDUCE VOMITING. Mouth may be rinsed with water. NEVER give anything by mouth to unconscious person. D. Fire and Explosion Hazard Information Flash Point: N/A Method Used: N/A (NFPA) National Fire Protection Association- Hazard Information Health-0 Flammability-0 Reactivity-0 (THIS PRODUCT MEETS REQUIREMENTS OF L A RULE 66 & SIMILAR REGUALTIONS) Handling Precautions Use only with adequate ventilation. Do not store above 49C/120F. E. Health and Hazard Information Effects of Overexposure: (Signs and of Exposure) Eye Contact Product contacting the eyes may cause redness, tearing, blurred vision. Rinse eyes thoroughly for 15 minutes. Seek medical attention. 1 Page 23 of 553 Page 23 of 553 Page 23 of 553 Page 23 of 553 ---PAGE BREAK--- 3BT BACTERIOSTATIC WATER TREATMENT 2 Skin Contact Contact with skin may cause slight skin irritation or rash if not washed immediately. Inhalation After high vapor exposure, remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped give artificial respiration. Ingestion If swallowed, call physician immediately! Induce vomiting following physician’s instructions. Cancer Hazard This product has no carcinogens listed by IARC, NTP, NIOSH, OSHA, or ACGIH as of this date, greater or equal to 0.1%. F. Physical Data The following data are approximate or typical values and should be used for precise design purposes. Boiling Range 100 101 101*deg. C/212 214 214*deg. F (*=end point) API Gravity 8.8 Specific Gravity (Water=1) 1.008 Pounds/Gallon 8.400 Vapor Pressure (mm of HG)@20 C 17.0 Vapor Density (Air=1) 0.6 Water Absorption Complete Acid Absorption (85% H2SO4) Complete Dry Time (Ether=1) Long % Volatile by VOL 97.8 Appearance Clear, Water-White or Green Odor Mild HKB (Hydrogen Bonding) 88.1 PKB (Polarity) 5.6 DKB (Dispersion) 6.4 Refractive Index 1.333 G. Reactivity Under normal conditions, this product is considered stable. Materials to Avoid: Isolate from strong oxidizers, such as permanganate. Hazardous: Carbon Monoxide, Carbon Dioxide from heating. Decomposition: Nitrogen Oxide vapors from heating. H. Spill or Leak Procedures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Stop spill at source. Dike area and contain. Pump liquid to salvage tank. Remaining residue may be taken up on absorbent material and shoveled into containers. Evaporate Page 24 of 553 Page 24 of 553 Page 24 of 553 Page 24 of 553 ---PAGE BREAK--- 3BT BACTERIOSTATIC WATER TREATMENT 3 until all vapors are gone. Dispose of in accordance with all local, state, and federal regulations I. Protection and Precautions Ventilation: Use local exhaust to capture excessive vapor, mists or fumes. Respiratory Protection: Use supplied-air respiratory protection in confined or enclosed spaces, if needed. Mechanical (General): OSHA acceptable Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact. Eye Protection: Use splash goggles or face shield when eye contact may occur. Work Practices/Engineering Controls: Keep container closed and upright when not in use to prevent leakage. Personal Hygiene: Cleanse skin thoroughly after contact, before breaks and meals, and at end of work period. Remove contaminated clothing and shoes and thoroughly clean before reuse. Maintain good personal hygiene. J. Transportation Information For further information relative to spills resulting from transportation incidents, refer to latest Department of Transportation Emergency Response Guidebook for Hazardous Materials Incidents. DOT IDENTIFICATION NUMBER None (UN0000) Legal responsibility is assumed only for the fact that all studies reported are those of qualified experts. Buyer assumes all risk and liability. He accepts and uses this material on these conditions. He must keep a copy of this MSDS where material is handled N. A. (not applicable) N. D. (not determined) N. K. (not known) Revised date 05-13-2008 RPS Products (herein called RPS) has been asked to supply the attached Material Safety Data Sheet (“MSDS”) despite the fact that some of the data contained therein is based on information supplied to RPS by third parties and the fact that RPS cannot anticipate all of the conditions of use and application with the respect to the product described in the MSDS. Although RPS has made a good faith effort in filling out the MSDS and believes the information, data and suggestions contained therein to be reliable, RPS DOES NOT WARRANT OR GUARANTEE THE COMPLETENESS OR THE ACCURACY OF THE DATA CONTAINED IN THE MSDS. RPS DISCLAIMS ANY AND ALL RESPONSIBILITY FOR ANY USE OF OR RELIANCE ON SUCH DATA. Page 25 of 553 Page 25 of 553 Page 25 of 553 Page 25 of 553 ---PAGE BREAK--- 3BT BACTERIOSTATIC WATER TREATMENT 1 RPS Products, Inc. 281 Keyes Avenue, Hampshire, IL 60140 ([PHONE REDACTED]) Hazard Communication Safety Data Sheet Section 1, Identification Product Identity: 3BT Humidifier Bacteriostatic Water Treatment Manufactured by: RPS Products, Inc. 281 Keyes Avenue, Hampshire, IL 60140, Phone [PHONE REDACTED] Recommend use in all manually filled evaporative humidifiers. Not to be used in Ultrasonic or Vaporizers. Emergency Telephone Numbers: R.P.S. Products [PHONE REDACTED] Chemtrec [PHONE REDACTED] Section 2, Hazard(s) Identification Warning Symbols and Risk Factors Avoid contact with skin and eyes Do not use while eating or drinking In case of contact with eyes, rinse immediately with plenty of water and seek medical attention If swallowed, seek medical attention Irritating to skin Risk of damage to eyes Irritating to respiratory system if inhaled Section 3, Composition/Information on Ingredients Component CAS# H20/Water 7732-18-5 Maquat 8030-78-2 *The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. Section 4, First-Aid Measures Eye Contact o Flush eyes with plenty of flowing water for 15 minutes lifting upper and lower lids. o Remove contact lenses if applicable. Seek medical attention. Skin Contact o Wash with plenty of soap and water. If irritation develops, seek medical attention. Inhalation o Remove person to fresh air. If breathing has stopped, resuscitate and seek medical attention. Ingestion o If ingested, MAY CAUSE ABDOMINAL IRRITATION, NAUSEA, VOMITING, AND DIARREHEA. Seek medical attention immediately. INDUCE VOMITING. Mouth may be rinsed with water. NEVER give anything by mouth to unconscious person. Page 26 of 553 Page 26 of 553 Page 26 of 553 Page 26 of 553 ---PAGE BREAK--- 3BT BACTERIOSTATIC WATER TREATMENT 2 Section 5, Fire-Fighting Measures Flash Point: N/A Method Used: N/A (NFPA) National Fire Protection Association- Hazard Information o Health-0 Flammability-0 Reactivity-0 THIS PRODUCT MEETS REQUIREMENTS OF L A RULE 66 & SIMILAR REGUALTIONS Handling Precautions o Use only with adequate ventilation. Do not store above 49C/120F. Section 6, Accidental Release Measures Use of Personal Precautions: o Ventilation: Use local exhaust to capture excessive vapor, mists or fumes. o Respiratory Protection: Use supplied-air respiratory protection in confined or enclosed spaces, if needed. o Mechanical (General): OSHA acceptable o Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact. o Eye Protection: Use splash goggles or face shield when eye contact may occur. o Work Practices/Engineering Controls: Keep container closed and upright when not in use to prevent leakage. o Personal Hygiene: Cleanse skin thoroughly after contact, before breaks and meals, and at end of work period. Remove contaminated clothing and shoes and thoroughly clean before reuse. Maintain good personal hygiene. Emergency Procedures: o Remove contaminated clothing and wash before reuse. o Rinse skin thoroughly with plenty of soap and water Methods and Materials used for containment: o Replace Cap immediately after use Cleanup Procedures o Wear gloves and clean up spills immediately Section 7, Handling and Storage Precautions for safe handling: o Wash hands after exposure and before eating or drinking Recommendations on safe storage: o Keep container closed and upright when not in use to prevent leakage Ventilation: o Use local exhaust to capture excessive vapor, mists or fumes. Section 8, Exposure Controls/Personal Protection Effects of Overexposure: (Signs and of Exposure) Eye Contact o Product contacting the eyes may cause redness, tearing, and blurred vision. o Rinse eyes thoroughly for 15 minutes. Seek medical attention. Skin Contact o Contact with skin may cause slight skin irritation or rash if not washed immediately. Inhalation o After high vapor exposure, remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped give artificial respiration. Ingestion Page 27 of 553 Page 27 of 553 Page 27 of 553 Page 27 of 553 ---PAGE BREAK--- 3BT BACTERIOSTATIC WATER TREATMENT 3 o If swallowed, call physician immediately! Induce vomiting following physician’s instructions. Cancer Hazard o This product has no carcinogens listed by IARC, NTP, NIOSH, OSHA, or ACGIH as of this date, greater or equal to 0.1%. Section 9, Physical and Chemical Properties The following data are approximate or typical values and should be used for precise design purposes. Appearance Clear, Water-White or Green Auto-ignition Temperature N/A Boiling Range 100 101 101*deg. C/212 214 214*deg. F (*=end point) Decomposition Temperature N/A DKB (Dispersion) 6.4 Dry Time (Ether=1) Long Evaporation Rate >0.8 Explosive Limits N/A Flash Point N/A Flammability 0 Freezing Point Below 20 Degrees F Odor Mild Odor Threshold N/A pH Neutral Melting Point N/A Partition Coefficient: n-octanol/water N/A Relative Density 1.008 Solubility Complete Vapor Density (Air=1) 0.6 Vapor Pressure (mm of HG)@20 C 17 Viscosity N/A Water Absorption Complete Section 10, Stability and Reactivity Reactivity o N/A Chemical Stability o Under normal conditions, this product is considered stable. Other o Material to Avoid: Isolate from strong oxidizers, such as permanganate. o Hazardous: Carbon Monoxide, Carbon Dioxide from heating. o Decomposition: Nitrogen Oxide vapors from heating. Section 11, Toxicological Information Information on likely routes of Exposure o Eye Contact- product contacting the eyes may cause redness, tearing, and blurred vision. Rinse eyes thoroughly for 15 minutes. Seek medical attention. o Skin Contact- contact with skin may cause slight skin irritation or rash if not washed immediately. Page 28 of 553 Page 28 of 553 Page 28 of 553 Page 28 of 553 ---PAGE BREAK--- 3BT BACTERIOSTATIC WATER TREATMENT 4 o Inhalation- after high vapor exposure, remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped give artificial respiration. o Ingestion- if swallowed, call physician immediately! Induce vomiting following physician’s instructions. Delayed, Immediate or Chronic effects not determined Section 12, Ecological Information Not Available Section 13, Disposal Considerations Steps to be taken in case material is released or spilled. o Stop spill at source. Dike area and contain. Pump liquid to salvage tank. Remaining residue may be taken up on absorbent material and shoveled into containers. Evaporate until all vapors are gone. Dispose of in accordance with all local, state, and federal regulations Section 14, Transport Information For further information relative to spills resulting from transportation incidents, refer to latest Department of Transportation Emergency Response Guidebook for Hazardous Materials Incidents. DOT IDENTIFICATION NUMBER o None (UN0000) Section 15, Regulatory Information Non-hazardous Non-regulated material Section 16, Other Information Legal responsibility is assumed only for the fact that all studies reported are those of qualified experts. Buyer assumes all risk and liability. He accepts and uses this material on these conditions. He must keep a copy of this MSDS where material is handled N. A. (not applicable) N. D. (not determined) N. K. (not known) Revised date 05-20-2015 RPS Products (herein called RPS) has been asked to supply the attached Material Safety Data Sheet (“MSDS”) despite the fact that some of the data contained therein is based on information supplied to RPS by third parties and the fact that RPS cannot anticipate all of the conditions of use and application with the respect to the product described in the MSDS. Although RPS has made a good faith effort in filling out the MSDS and believes the information, data and suggestions contained therein to be reliable, RPS DOES NOT WARRANT OR GUARANTEE THE COMPLETENESS OR THE ACCURACY OF THE DATA CONTAINED IN THE MSDS. RPS DISCLAIMS ANY AND ALL RESPONSIBILITY FOR ANY USE OF OR RELIANCE ON SUCH DATA. Page 29 of 553 Page 29 of 553 Page 29 of 553 Page 29 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 1 of 9 Material Safety Data Sheet Copyright, 2013, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M BRAND DESK AND OFFICE CLEANER 573 MANUFACTURER: 3M DIVISION: Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) Issue Date: 02/12/13 Supercedes Date: 10/02/07 Document Group: 10-0157-7 Product Use: Intended Use: Aerosol Cleaner for Office Surfaces Specific Use: AEROSOL FOAM CLEANER FOR OFFICE SURFACES SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt WATER 7732-18-5 86 - 92 ISOBUTANE PROPELLANT 75-28-5 1 - 8 ISOPROPYL ALCOHOL 67-63-0 3 - 5 ETHOXYLATED TALL-OIL FATTY ACIDS 61791-00-2 1 - 3 SODIUM CARBONATE 497-19-8 < 1 ETHANOLAMINE 141-43-5 < 0.5 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Foam Odor, Color, Grade: White foam, Lemon odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Flammable liquefied gas. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects. Page 30 of 553 Page 30 of 553 Page 30 of 553 Page 30 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 2 of 9 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Mild Skin Irritation: may include localized redness, swelling, and itching. Inhalation: Cardiac Sensitization: may include irregular heartbeat faintness, chest pain, and may be fatal. Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Single exposure, above recommended guidelines, may cause: Simple may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If persist, get medical attention. Skin Contact: Wash affected area with soap and water. If develop, get medical attention. Inhalation: Remove person to fresh air. Get immediate medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Page 31 of 553 Page 31 of 553 Page 31 of 553 Page 31 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 3 of 9 Flash Point 30 ºF [Test Method: Open Cup] [Details: specific method: D92] Flammable Limits(LEL) 1.80 % Flammable Limits(UEL) 8.40 % [Details: for isobutane.] 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Flammable liquefied gas. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in an approved metal container. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-[PHONE REDACTED]) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Page 32 of 553 Page 32 of 553 Page 32 of 553 Page 32 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 4 of 9 Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol container contains flammable gas under pressure. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Do not breathe vapors. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container closed. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. 8.2.3 Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of vapors, mists or spray. Do not breathe vapors. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information ETHANOLAMINE ACGIH TWA 3 ppm ETHANOLAMINE ACGIH STEL 6 ppm ETHANOLAMINE OSHA TWA 6 mg/m3 ISOPROPYL ALCOHOL ACGIH TWA 200 ppm ISOPROPYL ALCOHOL ACGIH STEL 400 ppm ISOPROPYL ALCOHOL OSHA TWA 980 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists Page 33 of 553 Page 33 of 553 Page 33 of 553 Page 33 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 5 of 9 CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Foam Odor, Color, Grade: White foam, Lemon odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 30 ºF [Test Method: Open Cup] [Details: specific method: D92] Flammable Limits(LEL) 1.80 % Flammable Limits(UEL) 8.40 % [Details: for isobutane.] Boiling Point Not Applicable Density 1 g/ml Vapor Density No Data Available Vapor Pressure 31 - 43 psi 70 ºF] [Details: (aerosol can pressure)] Specific Gravity Approximately 1 [Ref Std: WATER=1] Melting point Not Applicable Solubility In Water 100.00 % Evaporation rate >=1.00 [Ref Std: WATER=1] [Details: product as applied (without propellant)] Volatile Organic Compounds 55 - 115 g/l Kow - Oct/Water partition coef No Data Available Percent volatile 96 - 98 % weight VOC Less H2O & Exempt Solvents 702 - 831 g/l Viscosity Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat Sparks and/or flames 10.2 Materials to avoid Not determined Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Page 34 of 553 Page 34 of 553 Page 34 of 553 Page 34 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 6 of 9 SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. The facility should be equipped to handle gaseous waste. Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. Do not puncture or burn cans in a household incinerator. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 70-0061-3328-7, 70-0160-6830-9, 70-0701-7945-5, 70-0704-0450-7, 70-0709-0857-2, 70-0711-2910-3 For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Page 35 of 553 Page 35 of 553 Page 35 of 553 Page 35 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 7 of 9 All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Protection: X - See PPE section. Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 1: Product use information was modified. Section 16: Disclaimer (second paragraph) was modified. Section 3: Immediate physical hazard(s) was modified. Section 3: Potential effects from inhalation information was modified. Section 5: Unusual fire and explosion hazard information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Engineering controls information was modified. Section 8: Skin protection phrase was modified. Section 8: Respiratory protection information was modified. Section 8: Prevention of swallowing information was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 14: Transportation legal text was modified. Section 16: HMIS explanation was modified. Section 15: Inventories information was modified. Section 9: Density information was modified. Section 9: Vapor density value was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Page 36 of 553 Page 36 of 553 Page 36 of 553 Page 36 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 8 of 9 Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: Melting point information was modified. Section 9: Solubility in water value was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flash point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Autoignition temperature information was modified. Section 14: ID Number Heading Template 1 was added. Section 14: ID Number(s) Template 1 was added. Section 2: Ingredient table was added. Section 8: Exposure guidelines ingredient information was added. Section 8: Exposure guidelines data source legend was added. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 10.1 Conditions to avoid heading was added. Section 10.2 Materials to avoid heading was added. Section 16: Web address was added. Section 6: Personal precautions information was added. Section 6: Environmental procedures information was added. Section 6: Methods for cleaning up information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 8: Hand protection information was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 6: Release measures information was deleted. Section 6: Release measures heading was deleted. Section 10: Materials and conditions to avoid physical property was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. Section 8: Respiratory protection - recommended respirators punctuation was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M Page 37 of 553 Page 37 of 553 Page 37 of 553 Page 37 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M BRAND DESK AND OFFICE CLEANER 573 02/12/13 Page 9 of 9 3M USA are available at www.3M.com Page 38 of 553 Page 38 of 553 Page 38 of 553 Page 38 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 1 of 10 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-0157-7 Version Number: 27.00 Issue Date: 02/10/15 Supercedes Date: 02/12/13 SECTION 1: Identification 1.1. Product identifier 3M BRAND DESK AND OFFICE CLEANER 573 Product Identification Numbers 70-0061-3328-7, 70-0160-6830-9, 70-0701-7945-5, 70-0704-0450-7, 70-0709-0857-2, 70-0711-2910-3 1.2. Recommended use and restrictions on use Recommended use Aerosol Cleaner for Office Surfaces, AEROSOL FOAM CLEANER FOR OFFICE SURFACES 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Stationery and Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Aerosol: Category 1. Specific Target Organ Toxicity (single exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame I Health Hazard I Pictograms Page 39 of 553 Page 39 of 553 Page 39 of 553 Page 39 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 2 of 10 Hazard Statements Extremely flammable aerosol. Causes damage to organs: cardiovascular system I Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. 2% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt WATER 7732-18-5 86 - 92 ISOBUTANE PROPELLANT 75-28-5 1 - 8 Trade Secret * ISOPROPYL ALCOHOL 67-63-0 3 - 5 Trade Secret * ETHOXYLATED TALL-OIL FATTY ACIDS 61791-00-2 1 - 3 Trade Secret * SODIUM CARBONATE 497-19-8 < 1 ETHANOLAMINE 141-43-5 < 0.5 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. Page 40 of 553 Page 40 of 553 Page 40 of 553 Page 40 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 3 of 10 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If you feel unwell, get medical attention. Eye Contact: No need for first aid is anticipated. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that Page 41 of 553 Page 41 of 553 Page 41 of 553 Page 41 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 4 of 10 can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments ETHANOLAMINE 141-43-5 OSHA TWA:6 mg/m3(3 ppm) ETHANOLAMINE 141-43-5 ACGIH TWA:3 ppm;STEL:6 ppm ISOPROPYL ALCOHOL 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ISOPROPYL ALCOHOL 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin ISOBUTANE PROPELLANT 75-28-5 ACGIH STEL:1000 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Page 42 of 553 Page 42 of 553 Page 42 of 553 Page 42 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 5 of 10 Skin/hand protection No chemical protective gloves are required. Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life. For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Foam Odor, Color, Grade: White foam, Lemon odor Odor threshold No Data Available Melting point Not Applicable Boiling Point Not Applicable Flash Point 30 ºF [Test Method: Open Cup] [Details: specific method: D92] Evaporation rate >=1.00 [Ref Std: WATER=1] [Details: product as applied (without propellant)] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.80 % Flammable Limits(UEL) 8.40 % [Details: for isobutane.] Vapor Pressure 31 - 43 psi 70 ºF] [Details: (aerosol can pressure)] Vapor Density No Data Available Density 1 g/ml Specific Gravity Approximately 1 [Ref Std: WATER=1] Solubility In Water 100.00 % Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Volatile Organic Compounds 55 - 115 g/l Percent volatile 96 - 98 % weight VOC Less H2O & Exempt Solvents 702 - 831 g/l SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. Page 43 of 553 Page 43 of 553 Page 43 of 553 Page 43 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 6 of 10 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Single exposure may cause target organ effects: Cardiac Sensitization: may include irregular heartbeat faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Page 44 of 553 Page 44 of 553 Page 44 of 553 Page 44 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 7 of 10 Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg ISOBUTANE PROPELLANT Inhalation- Gas (4 hours) Rat LC50 276,000 ppm ISOPROPYL ALCOHOL Dermal Rabbit LD50 12,870 mg/kg ISOPROPYL ALCOHOL Inhalation- Vapor (4 hours) Rat LC50 72.6 mg/l ISOPROPYL ALCOHOL Ingestion Rat LD50 4,710 mg/kg SODIUM CARBONATE Dermal Rabbit LD50 > 2,000 mg/kg SODIUM CARBONATE Ingestion Rat LD50 2,800 mg/kg ETHANOLAMINE Inhalation- Vapor official classifica tion LC50 estimated to be 10 - 20 mg/l ETHANOLAMINE Dermal Rabbit LD50 1,000 mg/kg ETHANOLAMINE Ingestion Rat LD50 1,720 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value ISOBUTANE PROPELLANT Professio nal judgeme nt No significant irritation ISOPROPYL ALCOHOL Multiple animal species No significant irritation SODIUM CARBONATE Rabbit No significant irritation ETHANOLAMINE Rabbit Corrosive Serious Eye Damage/Irritation Name Species Value ISOBUTANE PROPELLANT Professio nal judgeme nt No significant irritation ISOPROPYL ALCOHOL Rabbit Severe irritant SODIUM CARBONATE Rabbit Corrosive ETHANOLAMINE Rabbit Corrosive Skin Sensitization Name Species Value ISOPROPYL ALCOHOL Guinea pig Not sensitizing ETHANOLAMINE Guinea pig Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value ISOBUTANE PROPELLANT In Vitro Not mutagenic ISOPROPYL ALCOHOL In Vitro Not mutagenic ISOPROPYL ALCOHOL In vivo Not mutagenic SODIUM CARBONATE In Vitro Not mutagenic ETHANOLAMINE In Vitro Not mutagenic ETHANOLAMINE In vivo Not mutagenic Carcinogenicity Name Route Species Value Page 45 of 553 Page 45 of 553 Page 45 of 553 Page 45 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 8 of 10 ISOPROPYL ALCOHOL Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration ISOPROPYL ALCOHOL Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day during organogenesi s ISOPROPYL ALCOHOL Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat LOAEL 9 mg/l during gestation SODIUM CARBONATE Ingestion Not toxic to development Mouse NOAEL 340 mg/kg/day during organogenesi s ETHANOLAMINE Dermal Not toxic to development Rat NOAEL 225 mg/kg/day during organogenesi s ETHANOLAMINE Ingestion Not toxic to development Rat NOAEL 616 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration ISOBUTANE PROPELLANT Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available ISOBUTANE PROPELLANT Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available ISOBUTANE PROPELLANT Inhalation respiratory irritation All data are negative Mouse NOAEL Not available ISOPROPYL ALCOHOL Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available ISOPROPYL ALCOHOL Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available ISOPROPYL ALCOHOL Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 13.4 mg/l 24 hours ISOPROPYL ALCOHOL Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse ETHANOLAMINE Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration ISOBUTANE PROPELLANT Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4,500 ppm 13 weeks ISOPROPYL ALCOHOL Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 12.3 mg/l 24 months ISOPROPYL ALCOHOL Inhalation nervous system All data are negative Rat NOAEL 12 mg/l 13 weeks ISOPROPYL ALCOHOL Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day 12 weeks SODIUM CARBONATE Inhalation respiratory system Some positive data exist, but the Rat LOAEL 0.07 3 months Page 46 of 553 Page 46 of 553 Page 46 of 553 Page 46 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 9 of 10 data are not sufficient for classification mg/l ETHANOLAMINE Inhalation liver I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.656 mg/l 5 weeks ETHANOLAMINE Ingestion hematopoietic system I liver I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Page 47 of 553 Page 47 of 553 Page 47 of 553 Page 47 of 553 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 10 of 10 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 3 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 1 Flammability: 3 Physical Hazard: 1 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group: 10-0157-7 Version Number: 27.00 Issue Date: 02/10/15 Supercedes Date: 02/12/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 48 of 553 Page 48 of 553 Page 48 of 553 Page 48 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET A6W816 08 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 2* A6W816 18-MAR-08 Flammability 0 Reactivity 0 PRODUCT NAME A-100® Exterior Flat Latex Paint, White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 2 107-21-1 Ethylene Glycol ACGIH TLV 100 mg/m3 CEILI (aerosol) 0.12 mm OSHA PEL 50 ppm CEILING 6 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 1 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 17 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 2 1314-13-2 Zinc Oxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Continued on page 2 Page 49 of 553 Page 49 of 553 Page 49 of 553 Page 49 of 553 ---PAGE BREAK--- A6W816 page 2 EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 Page 50 of 553 Page 50 of 553 Page 50 of 553 Page 50 of 553 ---PAGE BREAK--- A6W816 page 3 Section 7 HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Continued on page 4 Page 51 of 553 Page 51 of 553 Page 51 of 553 Page 51 of 553 ---PAGE BREAK--- A6W816 page 4 Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.96 lb/gal 1313 g/l SPECIFIC GRAVITY 1.32 BOILING POINT 212 - 388 F 100 - 197 C MELTING POINT Not Available VOLATILE VOLUME 68 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.78 lb/gal 94 g/l Less Water and Federally Exempt Solvents 0.27 lb/gal 32 g/l Emitted VOC VOLATILE ORGANIC COMPOUNDS (VOC - As Applied) <0.83 lb/gal <100 g/l Less Water and Federally Exempt Solvents Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans. TOXICOLOGY DATA Continued on page 5 Page 52 of 553 Page 52 of 553 Page 52 of 553 Page 52 of 553 ---PAGE BREAK--- A6W816 page 5 CAS No. Ingredient Name 107-21-1 Ethylene Glycol LC50 RAT 4HR Not Available LD50 RAT 4700 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available 1314-13-2 Zinc Oxide LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element 107-21-1 Ethylene Glycol 2 Zinc Compound 2 1.8 Continued on page 6 Page 53 of 553 Page 53 of 553 Page 53 of 553 Page 53 of 553 ---PAGE BREAK--- A6W816 page 6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 54 of 553 Page 54 of 553 Page 54 of 553 Page 54 of 553 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : AERO-SPOT-CO2-ALL COLORS IDENTIFICATION NUMBER: E&I 30 14 AEC DATE PRINTED: 05/30/02 PRODUCT USE/CLASS : SUPPLIER: MANUFACTURER: The Nelson Paint Co of Michigan Inc The Nelson Paint Co of Michigan Inc PO Box 2040 PO Box 2040 Kingsford, MI 49802-2040 Kingsford, MI 49802-2040 EMERGENCY TELEPHONE:[PHONE REDACTED] EMERGENCY TELEPHONE:[PHONE REDACTED] CHEMTEL: 24 hours CHEMTEL: 24 hours PREPARER: Doyle Yoder, PHONE: [PHONE REDACTED], PREPARE DATE: 05/30/02 I SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS I WT. PERCENT OCCUPATIONAL EXPOSURE LIMITS CHEMICAL NAME CAS NUMBER IS LESS THAN TLV-TWA TLV-STEL PEL-TWA PEL-CEILING SKIN Methyl Alcohol 67-56-1 15.0 % 200ppm 250ppm 200ppm N.E. YES Aliphatic Hydrocarbons 8052-41-3 35.0 % 100ppm N.E 100ppm N.E. NO (See Section XI for abbreviation legend) I SECTION III - PHYSICAL DATA I BOILING RANGE : 147 - 385 F VAPOR DENSITY : Is heavier than air ODOR : Slight solvent SPECIFIC GRAVITY: 0.0000 APPEARANCE : Ccolored liquid EVAPORATION RATE: Is faster than Butyl SOLUBILITY IN H2O : Partial Acetate VOLATILE BY WEIGHT: 74.3% VOLATILE BY VOL.: 84.9% VOCS, lbs/gal : 5.15 VOCS, grams/ltr : 617 (See Section 11 for abbreviation legend) I SECTION IV - FIRE AND EXPLOSION HAZARD DATA I FLASH POINT: 74 F LOWER EXPLOSIVE LIMIT: 1.0 % UPPER EXPLOSIVE LIMIT: 36.0 % EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid breathing dusts and fumes from burning material. Vapors may form explosive mixture with air. Vapors can travel to a source of ignition and flash back. “Empty” containers retain Page 55 of 553 Page 55 of 553 Page 55 of 553 Page 55 of 553 ---PAGE BREAK--- product residue (liquid and/or vapor) and can be dangerous. DO NOT (Continued on Page 2) Product: E&I 30 14 AEC Preparation Date: 05/30/02 Page 2 I SECTION IV - FIRE AND EXPLOSION HAZARD DATA I PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner, or properly disposed of. Keep containers closed . Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Water spray may be used for cooling containers to prevent possible pressure build-up and auto-ignition or explosion when exposed to extreme heat. I SECTION V - HEALTH HAZARD DATA I EFFECTS OF OVEREXPOSURE - EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness, nausea, decreased blood pressure, changes in heart rate and cyanosis (characterized by bluish discoloration of the skin and nails) may result from over-exposure to vapor or skin exposure. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes. Get immediate medical attention. FIRST AID - SKIN CONTACT: Immediately flush skin with plenty of water. Wash with soap and water. Remove soiled clothing. Wash clothing separately before reuse. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Page 56 of 553 Page 56 of 553 Page 56 of 553 Page 56 of 553 ---PAGE BREAK--- (Continued on Page 3) Product: E&I 30 14 AEC Preparation Date: 05/30/02 Page 3 I SECTION V - HEALTH HAZARD DATA I FIRST AID - INGESTION: NOTE TO PHYSICIAN: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at methanol concentrations above 20 UG/DL. Methanol is effectively removed by hemodialysis. Keep person warm, quiet and get immediate medical attention. Do NOT induce vomiting, because aspiration of material into the lungs from vomiting can cause chemical pneumonitis which can be fatal. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION EYE CONTACT I SECTION VI - REACTIVITY DATA I HAZARDOUS DECOMPOSITION PRODUCTS: Hazardous decomposition products: CO, CO2 and Nox. CONDITIONS TO AVOID: Heat, sparks and open flames. INCOMPATABILITY: Avoid contact with: strong oxidizing agents. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. I SECTION VII - SPILL OR LEAK PROCEDURES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate all non-essential personnel. Remove all sources of ignition. Ventilate the area. Equip employees with appropriate protection equipment. Dike around spilled material. Cover spill with absorbent material and shovel with non-sparking tools into container. Remove containers to safe area and seal. Avoid runoff into storm sewers and ditches which lead to waterways. WASTE DISPOSAL METHOD: Dispose of in accordance with State and Federal laws. Do not discharge into waterways without proper authority. I SECTION VIII - SAFE HANDLING AND USE INFORMATION I RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is Page 57 of 553 Page 57 of 553 Page 57 of 553 Page 57 of 553 ---PAGE BREAK--- (Continued on Page 4) Product: E&I 30 14 AEC Preparation Date: 05/30/02 Page 4 I SECTION VIII - SAFE HANDLING AND USE INFORMATION I limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. VENTILATION: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. SKIN PROTECTION: Where contact is likely, wear chemical resistant gloves, a chemical suit and rubber boots. EYE PROTECTION: Do not wear contact lenses. Wear safety glasses with side shields or goggles. OTHER PROTECTIVE EQUIPMENT: Where splashing is possible, full chemically resistant protective clothing and boots are required. HYGENIC PRACTICES: Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor Liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Wash hands before eating or smoking. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid contact with eyes, skin, and clothing. I SECTION IX - SPECIAL PRECAUTIONS I PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store away from incompatible substances. Wash thoroughly after handling. Keep away from heat, sparks and flame. Keep container closed when not in use. OTHER PRECAUTIONS: Do not inhale mist or vapor. Keep out of reach of children. Apply with back to wind during outdoor application. I SECTION X - HMIS RATINGS I HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 1 I SECTION XI - OTHER REGULATIONS I (Continued on Page 5) Product: E&I 30 14 AEC Preparation Date: 05/30/02 Page 5 I SECTION XI - OTHER REGULATIONS I Page 58 of 553 Page 58 of 553 Page 58 of 553 Page 58 of 553 ---PAGE BREAK--- SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN Methyl Alcohol 67-56-1 15.0 % PREVIOUS MSDS REVISION DATE: 01/28/97 LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined **The Nelson Paint Company, Inc. (TNPC) expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein.** All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, TNPC makes no representations as to its accuracy or sufficiency. Conditions of use are beyond TNPC’s control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. Page 59 of 553 Page 59 of 553 Page 59 of 553 Page 59 of 553 ---PAGE BREAK--- Page 60 of 553 Page 60 of 553 Page 60 of 553 Page 60 of 553 ---PAGE BREAK--- Page 61 of 553 Page 61 of 553 Page 61 of 553 Page 61 of 553 ---PAGE BREAK--- #23109 Page 1 of 8 Issue date 26-Sep-2012 Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 MATERIAL SAFETY DATA SHEET . 1. Product and Company Identification space Product Name AIR WICK® Air Freshener (Aerosols All Scents) space CAS # Mixture space This MSDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the U.S. Government's Occupational Safety and Health Administration (OSHA). This MSDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation. Air freshener Product Use space Distributed by Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway P.O. Box 225 Parsippany, NJ 07054-0225 In Case of Emergency: 1-[PHONE REDACTED] Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-[PHONE REDACTED] Outside North America: 1-[PHONE REDACTED] space LEGEND HMIS/NFPA Health / 0 1 Flammability 1 0 0 Physical Hazard 0 Personal Protection B . 2. Hazards Identification space Emergency overview CAUTION EYE IRRITANT. Prolonged or frequent skin contact may cause an allergic reaction. CONTENTS UNDER PRESSURE. DO NOT spray towards face. Avoid contact with eyes and skin. CONTAINER MAY EXPLODE IF HEATED. Do not puncture or incinerate container. DO NOT expose to heat or store at temperatures above 120°F (49°C) as the container may burst. space Potential short term health effects Routes of exposure KEEP OUT OF REACH OF CHILDREN AND PETS. Eye, Skin contact, Inhalation. space space space space space Eyes None expected during normal conditions of use. May cause eye irritation upon direct contact with the eyes. Skin None expected during normal conditions of use. Prolonged or frequent skin contact may cause an allergic reaction. Inhalation None expected during normal conditions of use. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Ingestion Health injuries are not known or expected under normal use. Target organs Eyes. space Chronic effects The finished product is not expected to have chronic health effects. space Signs and of overexposure may be headache, dizziness, tiredness, nausea and vomiting. space OSHA Regulatory Status This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. space Potential environmental effects This product has not been tested. Page 62 of 553 Page 62 of 553 Page 62 of 553 Page 62 of 553 ---PAGE BREAK--- #23109 Page 2 of 8 Issue date 26-Sep-2012 . 3. Composition / Information on Ingredients space Ingredient(s) CAS # Percent Propane Butane Ethane, 1,1-difluoro- 74-98-6 106-97-8 75-37-6 7 - 13 10 - 30 10 - 30 . 4. First Aid Measures space First aid procedures Eye contact space If in eyes, IMMEDIATELY rinse eyes with plenty of water. Remove any contact lenses and continue rinsing eyes for at least 15 minutes. If irritation persists, get medical attention. space space space Skin contact If on skin, wash with soap and water. If Irritation develops, get medical attention. Inhalation Move to fresh air in case of accidental inhalation of vapors. Ingestion Rinse mouth with water and drink afterwards plenty of water. DO NOT INDUCE VOMITING. Notes to physician Treat patient space General advice Do not puncture or incinerate container. Keep away from sources of ignition. No smoking. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. NOTE TO PARENTS: Intentional misuse by deliberately concentrating and inhaling aerosol products may be harmful or fatal. Help stop inhalation abuse; for information visit www.inhalant.org. . 5. Fire Fighting Measures space Flammable properties Non-flammable aerosol by flame projection test. NFPA AEROSOL LEVEL: Flammability Rating 1, per NFPA 30B space Extinguishing media Suitable extinguishing media Dry chemical. Foam. space space Unsuitable extinguishing media Water. Water spray. Protection of firefighters Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. Cool containers with flooding quantities of water until well after fire is out. space space Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. Hazardous combustion products May include and are not limited to: Oxides of carbon. space Explosion data Sensitivity to mechanical impact Not available space Sensitivity to static discharge Not available . 6. Accidental Release Measures space Personal precautions Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Keep unnecessary personnel away. space Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Do not allow material to contaminate ground water system. Advise authorities if product has penetrated drains, sewers or water pipes. space Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Page 63 of 553 Page 63 of 553 Page 63 of 553 Page 63 of 553 ---PAGE BREAK--- #23109 Page 3 of 8 Issue date 26-Sep-2012 space Methods for cleaning up Before attempting clean up, refer to hazard data given above. Remove sources of ignition. Although the chance of a significant spill or leak is unlikely in aerosol containers, in the event of such an occurrence, absorb spilled material with a non-flammable absorbent such as sand or vermiculite. . 7. Handling and Storage space Handling Ensure adequate ventilation. DO NOT spray towards face. Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn after use. Keep away from all sources of ignition. Fires involving aerosols with flammable contents are severe and can spread quickly. Warehouses or stores containing aerosols should therefore be separated from other areas by a fire resistant construction. Stores should be well ventilated. The natural ventilation in a large open warehouse building will normally be suitable. Do not spray on a naked flame or any other incandescent material. Use good industrial hygiene practices in handling this material. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. space Storage DO NOT expose to heat or store at temperatures above 120°F (49°C) as the container may burst. Do not puncture or incinerate container. CONTAINER MAY EXPLODE IF HEATED. Keep away from heat, open flames or other sources of ignition. Store in a cool place. Keep out of reach of children. NOTE TO PARENTS: Intentional misuse by deliberately concentrating and inhaling aerosol products may be harmful or fatal. Help stop inhalation abuse; for information visit www.inhalant.org. . 8. Exposure Controls / Personal Protection space Exposure limits Ingredient(s) Butane Exposure Limits ACGIH-TLV TWA: 1000 ppm OSHA-PEL Not established Ethane, 1,1-difluoro- ACGIH-TLV Not established OSHA-PEL Not established Propane ACGIH-TLV TWA: 1000 ppm OSHA-PEL TWA: 1000 ppm space Engineering controls Provide adequate ventilation. space Personal protective equipment Consult the product label for special protection or precautions that have been identified for using this product under directed consumer use conditions. The following recommendations are given for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure. space space Eye / face protection Not required under normal use conditions. Emergency responders should wear full eye and face protection. Hand protection No special requirements under normal use conditions. Emergency responders should wear impermeable gloves. Skin and body protection No special requirements under normal use conditions. Prolonged or frequent skin contact may produce an allergic reaction in some individuals. Page 64 of 553 Page 64 of 553 Page 64 of 553 Page 64 of 553 ---PAGE BREAK--- #23109 Page 4 of 8 Issue date 26-Sep-2012 space space Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of vapours generated by this product during a spill or other clean-up operations. General hygiene considerations Avoid contact with skin, eyes and clothing. Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact. . 9. Physical and Chemical Properties space Appearance Aerosol. space Color Clear space Form Misty spray space Odor Characteristic space Odor threshold Not available space Physical state Gas space pH Not available space Freezing point Not available space Boiling point Not available space Pour point Not available space Evaporation rate Not available space Flash point Not available space Auto-ignition temperature Not available space Flammability limits in air, lower, % by volume space Flammability limits in air, upper, % by volume space Not available Not available Vapor pressure Not available space Vapor density Not available space Specific gravity Not available space Octanol/water coefficient Not available . 10. Stability and Reactivity space Reactivity This product may react with oxidizing agents. space Possibility of hazardous reactions Hazardous polymerization does not occur. space Chemical stability Stable under recommended storage conditions. space Conditions to avoid Keep away from open flames, hot surfaces and sources of ignition. Protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Extremes of temperatures can occur in cars and near ovens and fireplaces. Do not place in contact with hot surfaces or near naked flames. Do not pierce or burn after use. Do not spray on a naked flame, onto or near a fire, or any incandescent material such as an electric fire. Aerosol containers are unstable at temperatures above 49°C (120.2°F). space Incompatible materials Caustics. Oxidizers. Acids. space Hazardous decomposition products May include and are not limited to: Oxides of carbon. . 11. Toxicological Information space Component analysis - LC50 Ingredient(s) Butane LC50 Not available Ethane, 1,1-difluoro- > 64000 ppm rat Propane Not available Page 65 of 553 Page 65 of 553 Page 65 of 553 Page 65 of 553 ---PAGE BREAK--- #23109 Page 5 of 8 Issue date 26-Sep-2012 space Component analysis - Oral LD50 Ingredient(s) Butane LD50 Not available Ethane, 1,1-difluoro- 1500 mg/kg rat Propane Not available space Effects of acute exposure space Eye None expected during normal conditions of use. May cause eye irritation upon direct contact with the eyes. space space space Skin None expected during normal conditions of use. Prolonged or frequent skin contact may cause an allergic reaction. Inhalation None expected during normal conditions of use. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Ingestion Health injuries are not known or expected under normal use. Sensitization The finished product is not expected to have chronic health effects. space Chronic effects The finished product is not expected to have chronic health effects. space Carcinogenicity The finished product is not expected to have chronic health effects. space Mutagenicity The finished product is not expected to have chronic health effects. space Reproductive effects The finished product is not expected to have chronic health effects. space Teratogenicity The finished product is not expected to have chronic health effects. space Name of Toxicologically Synergistic Products Not available . 12. Ecological Information space Ecotoxicity This product has not been tested. space Persistence / degradability Not available space Bioaccumulation / accumulation Not available space Mobility in environmental media Not available space Environmental effects Not available space Aquatic toxicity Not available space Partition coefficient Not available space Chemical fate information Not available . 13. Disposal Considerations space Disposal instructions Dispose in accordance with all applicable regulations. Container disposal: Empty containers may be included with domestic refuse for disposal to a landfill. This container may also be recycled in communities where aerosol container recycling is available. Before offering for recycling, empty the can or use the product according to the label instructions. space Waste from residues / unused products space Not available Contaminated packaging Not available Page 66 of 553 Page 66 of 553 Page 66 of 553 Page 66 of 553 ---PAGE BREAK--- #23109 Page 6 of 8 Issue date 26-Sep-2012 . 14. Transport Information space U.S. Department of Transportation (DOT) UN 1950, Aerosols, Class 2.1, Limited Quantity space Transportation of Dangerous Goods (TDG - Canada) UN 1950, Aerosols, Class 2.1, Limited Quantity space IMDG (Marine Transport) UN 1950, Aerosols, Class 2.1, Limited Quantity space IATA/ICAO (Air) UN 1950, Aerosols, Flammable, Class 2.1 Page 67 of 553 Page 67 of 553 Page 67 of 553 Page 67 of 553 ---PAGE BREAK--- #23109 Page 7 of 8 Issue date 26-Sep-2012 . 15. Regulatory Information space Occupational Safety and Health Administration (OSHA) space 29 CFR 1910.1200 hazardous chemical Yes US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. space CERCLA (Superfund) reportable quantity None space Superfund Amendments and Reauthorization Act of 1986 (SARA) space space Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No No space Section 311 hazardous chemical No Clean Air Act (CAA) Not available space Clean Water Act (CWA) Not available space State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances Butane 106-97-8 Present U.S. - Massachusetts - Right To Know List Butane Ethane, 1,1-difluoro- Propane 106-97-8 75-37-6 74-98-6 Present Present Present U.S. - Minnesota - Hazardous Substance List Butane Propane 106-97-8 74-98-6 Present Simple U.S. - New Jersey - Right to Know Hazardous Substance List Butane Ethane, 1,1-difluoro- Propane 106-97-8 75-37-6 74-98-6 sn 0273 sn 0715 sn 1594 U.S. - - RTK (Right to Know) List Butane Propane 106-97-8 74-98-6 Present Present U.S. - Rhode Island - Hazardous Substance List Butane Propane 106-97-8 74-98-6 Toxic; Flammable Toxic; Flammable space Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) . 16. Other Information space Disclaimer This product should only be used as directed on the label and for the purpose intended. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 68 of 553 Page 68 of 553 Page 68 of 553 Page 68 of 553 ---PAGE BREAK--- #23109 Page 8 of 8 Issue date 26-Sep-2012 space Further information AIR WICK® 4-In-1 Air Freshener - Apple Cinnamon Medley, 8 oz - 0.188360v2.0 AIR WICK® 4-In-1 Air Freshener - Cool Linen & White Lilac, 8 oz - 0192143v2.0 AIR WICK® 4-In-1 Air Freshener - Fresh Waters, 8 oz - 0192143v2.0 AIR WICK® 4-In-1 Air Freshener - Lavender & Chamomile, 8 oz - 0121604v2.0 AIR WICK® 4-In-1 Air Freshener - Magnolia & Cherry Blossom, 8 oz - 0188398v2.0 AIR WICK® 4-In-1 Air Freshener - Papaya & Mango, 8 oz - 0188364v2.0 AIR WICK® 4-In-1 Air Freshener - Rain Garden, 8 oz - 0188387v2.0 AIR WICK® 4-In-1 Air Freshener - Sparkling Citrus, 8 oz - 0188375v2.0 AIR WICK® 4-In-1 Air Freshener - Vanilla Indulgence, 8 oz - 0188341v2.0 AIR WICK® Air Freshener - Serene Waters (National Parks - Glacier Bay), 8 oz - 0192143v2.0 AIR WICK® Air Freshener - Tropical Sunset (National Parks - Hawaii), 8 oz - 0.188364v2.0 AIR WICK® Air Freshener - Vanilla Sugar Cookies (Festive Moments), 8 oz - 0299270v2.0 AIR WICK Air Freshener - Warm Apple Pie (Festive Moments), 8 oz - 0340663v1.0 space Issue date 26-Sep-2012 space Effective date 15-Sep-2012 space Prepared by Reckitt Benckiser Regulatory Department [PHONE REDACTED] space Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. Page 69 of 553 Page 69 of 553 Page 69 of 553 Page 69 of 553 ---PAGE BREAK--- Page 70 of 553 Page 70 of 553 Page 70 of 553 Page 70 of 553 ---PAGE BREAK--- Page 71 of 553 Page 71 of 553 Page 71 of 553 Page 71 of 553 ---PAGE BREAK--- Page 72 of 553 Page 72 of 553 Page 72 of 553 Page 72 of 553 ---PAGE BREAK--- Page 73 of 553 Page 73 of 553 Page 73 of 553 Page 73 of 553 ---PAGE BREAK--- Page 74 of 553 Page 74 of 553 Page 74 of 553 Page 74 of 553 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : ALL WEATHER OUTDOOR CARPET ADHESIVE UPC NUMBER : 00438, 00442, 00443, 00444 PRODUCT USE/CLASS : Carpet Adhesive MANUFACTURER: 24 HOUR EMERGENCY: DAP INC. TRANSPORTATION: 1-[PHONE REDACTED] ([PHONE REDACTED]) 2400 BOSTON STREET MEDICAL : 1-[PHONE REDACTED] ([PHONE REDACTED]) BALTIMORE, MD 21224 PREPARE DATE : 09/24/1997 GENERAL INFORMATION: REVISION NO. : 13 DAP INC. : 1-888-DAP-TIPS (1-[PHONE REDACTED]) REVISION DATE: 05/15/2003 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER RANGE 01 Aliphatic Petroleum Distillate 64742-89-8 25.0-30.0 % 02 Toluene EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 400 ppm N.E. 400 ppm N.E. N.E. NO 02 50 ppm. N.E. 100 ppm. N.E. N.E. YES (See Section 16 for abbreviation legend) Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW: DANGER! Flammable liquid and vapor. Vapor harmful. Harmful or fatal if swallowed. Vapors may cause flash fire or explosion. (Continued on Page 2) Page 75 of 553 Page 75 of 553 Page 75 of 553 Page 75 of 553 ---PAGE BREAK--- Product Name: ALL WEATHER OUTDOOR CARPET ADHESIVE Revision Date: 05/15/2003 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I Aspiration hazard if swallowed - can enter lungs and cause damage. Harmful if inhaled. POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Irritates skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor may irritate nose and upper respiratory tract. Vapor inhalation may affect the brain or nervous system causing dizziness, headache or nausea. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis which can be fatal. If ingested, this product may cause vomiting, diarrhea, and depressed respiration. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated permanent brain and nervous system damage with prolonged and repeated occupational overexposure to solvents. include: loss of memory, loss of intellectual ability, and loss of coordination. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION I SECTION 4 - FIRST AID MEASURES I EYE CONTACT: Flush with large quantities of water until irritation subsides. SKIN CONTACT: Wash with soap and water. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. INGESTION: DO NOT INDUCE VOMITING. COMMENTS: Call Medical in Section 1 if irritation or complications arise from any of the above routes of exposure. I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: 20 F minimum LOWER EXPLOSIVE LIMIT: N.A. (SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A. (Continued on Page 3) Page 76 of 553 Page 76 of 553 Page 76 of 553 Page 76 of 553 ---PAGE BREAK--- Product Name: ALL WEATHER OUTDOOR CARPET ADHESIVE Revision Date: 05/15/2003 Page 3 I SECTION 5 - FIRE FIGHTING MEASURES I AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid. Material will readily ignite at room temperature. Vapors may form an explosive mixture with air. Vapors can travel through a source of ignition and flashback. Containers may explode if exposed to extreme heat. Eliminate sources of ignition: heat, electrical equipment, sparks, and flames. Do not put in contact with oxidizing or caustic materials. SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including self-contained breathing apparatus, is recommended to protect from combustion products. Cool exposed containers with water. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I SPILL OR LEAK PROCEDURES: Dike spill area. Immediately eliminate sources of ignition. Use absorbent material or scrape up dried material and place into containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye contact. Avoid breathing vapors. Use only in a well ventilated area. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away from heat, spark, and flame. Keep containers closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Do not take internally. Construction and repair activities can adversely affect indoor air quality. Consult with the occupants or a representative(i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize any impact. I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapors before entering. (Continued on Page 4) Page 77 of 553 Page 77 of 553 Page 77 of 553 Page 77 of 553 ---PAGE BREAK--- Product Name: ALL WEATHER OUTDOOR CARPET ADHESIVE Revision Date: 05/15/2003 Page 4 I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I RESPIRATORY PROTECTION: If 8 hour exposure limit or value is exceeded for any component, use an approved NIOSH respirator. Consult your safety equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. EYE PROTECTION: Goggles or safety glasses with side shields. SKIN PROTECTION: Solvent impervious gloves. OTHER PROTECTIVE EQUIPMENT: Provide eyewash and solvent impervious apron if body contact may occur. HYGIENIC PRACTICES: Remove contaminated clothing and wash before reuse. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : 200 - 250 F VAPOR DENSITY : Is heavier than air ODOR : Pungent Solvent APPEARANCE : Beige mastic EVAPORATION RATE: Is faster than Butyl SOLUBILITY IN H2O : Negligible Acetate SPECIFIC GRAVITY : 1.1869 VAPOR PRESSURE : 36 mm Hg @ 68F. PHYSICAL STATE : Mastic (See Section 16 for abbreviation legend) I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Excessive heat and freezing. INCOMPATIBILITY: Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx, NOx HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I No product or component toxicological information is available. (Continued on Page 5) Page 78 of 553 Page 78 of 553 Page 78 of 553 Page 78 of 553 ---PAGE BREAK--- Product Name: ALL WEATHER OUTDOOR CARPET ADHESIVE Revision Date: 05/15/2003 Page 5 I SECTION 11 - TOXICOLOGICAL PROPERTIES I I SECTION 12 - ECOLOGICAL INFORMATION I No Information. I SECTION 13 - DISPOSAL CONSIDERATIONS I WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. Discarded material should be incinerated at a permitted facility. Liquids cannot be disposed of in a landfill. Do not reuse empty container. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): D001-Ignitable I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: Adhesive(Consumer Commodity*) DOT HAZARD CLASS: 3(ORM-D*) DOT UN/NA NUMBER: UN 1133(NONE*) PACKING GROUP: III(NONE*) * For containers of 1 gallon or less. I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER Toluene 108-88-3 (Continued on Page 6) Page 79 of 553 Page 79 of 553 Page 79 of 553 Page 79 of 553 ---PAGE BREAK--- Product Name: ALL WEATHER OUTDOOR CARPET ADHESIVE Revision Date: 05/15/2003 Page 6 I SECTION 15 - REGULATORY INFORMATION I TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER None NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER Aromatic hydrocarbon TSRN-618608-5118P SB Rubber TSRN-618608-5085P Calcium Carbonate 1317-65-3 Hydrous Aluminum Silicate 1332-58-7 RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER Aromatic hydrocarbon proprietary SB Rubber proprietary Calcium Carbonate 1317-65-3 Hydrous Aluminum Silicate 1332-58-7 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER Toluene 108-88-3 INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: Consumer Commodity I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 12/30/1999 (Continued on Page 7) Page 80 of 553 Page 80 of 553 Page 80 of 553 Page 80 of 553 ---PAGE BREAK--- Product Name: ALL WEATHER OUTDOOR CARPET ADHESIVE Revision Date: 05/15/2003 Page 7 I SECTION 16 - OTHER INFORMATION I REASON FOR REVISION: SECTION 2; Update OSHA hazardous materials. SECTION 15: Update regulatory information. VOC less water, less exempt solvent: 330-335 gm/l(28-29%) VOC material: 330-335 gm/l LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS N.A. - NOT APPLICABLE N.E. - NOT ESTABLISHED PEL - PERMISSIBLE EXPOSURE LIMIT NTP - NATIONAL TOXICOLOGY PROGRAM SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 STEL - SHORT TERM EXPOSURE LIMIT TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOC - VOLATILE ORGANIC COMPOUND - NEW JERSEY RIGHT TO KNOW LAW N.D. - NOT DETERMINED MSDS# 30801 This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. < End OF MSDS > Page 81 of 553 Page 81 of 553 Page 81 of 553 Page 81 of 553 ---PAGE BREAK--- MSDS: 304E MATERIAL SAFETY DATA SHEET REV. DATE: 2/99 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Antiseptic Spray 22 Corporate Park #218 Irvine, CA 92606 949/252-9500 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT % NUMBER OSHA (ppm) ACGIH (ppm) Bromide 0.05 57-09-0 N/E N/E Benzocaine 4.5 94-09-7 N/E N/E Butane, propane Propellants 106-97-8 800 800 Section III - PHYSICAL DATA Boiling Point: -30 F Specific Gravity: 1.032 Vapor Pressure: (mm Hg): 50 PSIG @ 70 F Melting Point: N/A Vapor Density: 1.92 Evaporation Rate: N/A Solubility In Water: Soluble Appearance and Odor: Aerosol consumer product; clear to amber liquid, medicinal odor. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: -120 F Flammability Limits in Air by volume): LEL = 1.9%, UEL = 8.6% Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical. Special Fire Fighting Procedures: Confine fire to immediate area, vent room and low lying areas. Containers are pressurized and explosive and should be cooled by spraying with water so temperature does not exceed 130 F. Unusual Fire and Explosion Hazards: Containers may rupture explosively if exposed to heat above 130 F. NFPA Hazard Rating: Health: 1 Flammability: 4 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 1 Flammability: 4 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 82 of 553 Page 82 of 553 Page 82 of 553 Page 82 of 553 ---PAGE BREAK--- MSDS: 304E MATERIAL SAFETY DATA SHEET REV. DATE: 2/99 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Eye or skin contact, inhalation, ingestion. Health Hazards: Eye contact may result in eye irritation. Inhalation may result in irritation to nasal passages and lungs. Inhalation of high concentrations for extended period of time may result in dizziness, headache, drowsiness, loss of appetite and inability to concentrate. Ingestion may cause gastric disturbances. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: Eye or skin contact: Flush immediately with large amounts of water. If redness or irritation persists, contact a physician. Inhalation: Move to fresh air at once. If breathing has stopped, perform artificial respiration and contact a physician immediately. Ingestion: Contact a physician immediately. Section VI - REACTIVITY DATA Stability: Stable Hazardous Polymerization: Will not occur Hazardous Decomposition Products: Toxic gases may be released during fire. Incompatibilities: Heat, oxidizing materials. Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Leaking cans should be placed in open containers outdoors until pressure has been released. Cover spilled liquid with absorbent material, then transfer to suitable container. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: If TLV or PEL is exceeded, use NIOSH approved air purifying respirator with organic vapor cartridge. Ventilation: General mechanical. Local exhaust may be required if TLV or PEL is exceeded. Protective Equipment: Eye protection and protective equipment as necessary to prevent excessive contact. Section IX - SPECIAL PRECAUTIONS Do not incinerate or store near heat sources such as radiators, open flames, stoves, heaters, etc. Keep in cool dry place at temperature below 130 F. Do not puncture containers. Do not spray near flame or while smoking. Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. Use only as directed on label. Keep out of reach of children. Read label for uses and directions. Do not use beyond expiration date. Eyewash station should be available for emergency use. N/A = Not applicable or not available N/E = Not established Page 83 of 553 Page 83 of 553 Page 83 of 553 Page 83 of 553 ---PAGE BREAK--- Page 84 of 553 Page 84 of 553 Page 84 of 553 Page 84 of 553 ---PAGE BREAK--- Page 85 of 553 Page 85 of 553 Page 85 of 553 Page 85 of 553 ---PAGE BREAK--- Page 86 of 553 Page 86 of 553 Page 86 of 553 Page 86 of 553 ---PAGE BREAK--- Page 87 of 553 Page 87 of 553 Page 87 of 553 Page 87 of 553 ---PAGE BREAK--- Page 88 of 553 Page 88 of 553 Page 88 of 553 Page 88 of 553 ---PAGE BREAK--- Page 89 of 553 Page 89 of 553 Page 89 of 553 Page 89 of 553 ---PAGE BREAK--- MSDS: 303 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Blood Clotting Spray 22 Corporate Park #213 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT % NUMBER OSHA (ppm) ACGIH (ppm) Gum tragacanth 40-60 N/A N/E N/E Gum karaya 40-60 N/A N/E N/E Benzethonium chloride 0.2 121-54-0 N/E N/E Butane, isobutane, propane Propellants 106-97-8 800 800 Section III - PHYSICAL DATA Boiling Point: -30 F Specific Gravity: N/A Vapor Pressure: (mm Hg): 31 PSIG @ 70 F Melting Point: N/A Vapor Density: 2.0 Evaporation Rate: 1.5 (Ethyl ether=1) Solubility In Water: 2% Appearance and Odor: Off-white powder, odorless. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: -187 F Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical. Special Fire Fighting Procedures: Confine fire to immediate area, vent room and low lying areas. Containers are pressurized and explosive and should be cooled by spraying with water so temperature does not exceed 130 F. Unusual Fire and Explosion Hazards: Containers may rupture explosively if exposed to heat above 130 F. NFPA Hazard Rating: Health: 1 Flammability: 4 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 1 Flammability: 4 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 90 of 553 Page 90 of 553 Page 90 of 553 Page 90 of 553 ---PAGE BREAK--- MSDS: 303 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Eye or skin contact, inhalation, ingestion. Health Hazards: Eye contact may result in eye irritation. Inhalation may result in irritation to nasal passages and lungs. Inhalation of high concentrations for extended period of time may result in dizziness, headache, drowsiness, loss of appetite and inability to concentrate. Ingestion may cause gastric disturbances. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: Eye or skin contact: Flush immediately with large amounts of water. If redness or irritation persists, contact a physician. Inhalation: Move to fresh air at once. If breathing has stopped, perform artificial respiration and contact a physician immediately. Ingestion: Contact a physician immediately. Section VI - REACTIVITY DATA Stability: Stable Hazardous Polymerization: Will not occur Incompatibilities: Heat, oxidizing materials. Hazardous Decomposition Products: Toxic gases may be released during fire. Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Leaking cans should be placed in open containers outdoors until pressure has been released. Cover spilled liquid with absorbent material, then transfer to suitable container. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: If TLV or PEL is exceeded, use NIOSH approved air purifying respirator with organic vapor cartridge. Ventilation: General mechanical. Local exhaust may be required if TLV or PEL is exceeded. Protective Equipment: Eye protection and protective equipment as necessary to prevent excessive contact. Section IX - SPECIAL PRECAUTIONS Do not incinerate or store near heat sources such as radiators, open flames, stoves, heaters, etc. Keep in cool dry place at temperature below 130 F. Do not puncture containers. Do not spray near flame or while smoking. Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. Use only as directed on label. Keep out of reach of children. Read label for uses and directions. Do not use beyond expiration date. Eyewash station should be available for emergency use. N/A = Not applicable N/E = Not established Page 91 of 553 Page 91 of 553 Page 91 of 553 Page 91 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Telephone (704) 987-4555 8935 NorthPointe Executive Park Dr. Huntersville, NC 28078 www.irwin.com 1 BLUE CHALK - STANDARD SECTION 1 – IDENTIFICATION OF PRODUCT TRADE NAME: BLUE CONSTRUCTION CHALK CI NAME: N/A COMPOSITION: Component CAS No. % Ultramarine Blue – Pigment Blue 29 57455-37-5 10-25 Calcium Carbonate 471-34-1 75-90 Quartz 14808-60-7 0.01-1.5 Calcium carbonate may contain silica at levels between 0.01% - 1.50% and varies naturally. SUPPLIER: DELTA COLOURS INC. MANUFACTURER: DELTA COLOURS INC. 6369 PEACHTREE ST NE NORCROSS, GA 30071 EMERGENCY TELEPHONE NO: [PHONE REDACTED] or [PHONE REDACTED] DATE PREPARED – 03/15/2007 SECTION 2 – HAZARDOUS INGREDIENTS NO KNOWN HAZARDOUS COMPONENTS SECTION 3 – PHYSICAL DATA APPEARANCE: BLUE POWDER ODOR: NONE SOLUBILITY IN WATER: 0.3% BULK DENSITY: N/A SECTION 4 – FIRE AND EXPLOSION HAZARD DATA EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. UNUSUAL FIRE AND EXPLOSION HAZARDS: PRODUCT IS PRODUCED TO MINIMIZE DUSTING, BUT SINCE MOST POWDER PRODUCTS AS DUSTS CAN FORM EXPLOSIVE MIXTURES WITH AIR, HANDLE TO AVOID DUSTING CONDITIONS. PRODUCT NOT CONSIDERED A FIRE HAZARD, BUT MAY BURN OR SMOLDER IF IGNITED. Page 92 of 553 Page 92 of 553 Page 92 of 553 Page 92 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Telephone (704) 987-4555 8935 NorthPointe Executive Park Dr. Huntersville, NC 28078 www.irwin.com 2 SECTION 5 – REACTIVITY HAZARDS AND INFORMATION STABILITY: STABLE HAZARDOUS DECOMPOSITION PRODUCTS: NONE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. THERMAL DECOMPOSITION: 350C SECTION 6 – HEALTH HAZARDS AND INFORMATION EYE CONTACT: DIRECT EYE CONTACT MAY CAUSE IRRITATION BY MECHANICAL ABRASION. SKIN CONTACT: DIRECT EYE CONTACT MAY CAUSE IRRITATION BY MECHANICAL ABRASION. EFFECTS OF CHRONIC OVEREXPOSURE: AS TRUE WITH ANY MINERAL PRODUCT, LONG TERM OVEREXPOSURE TO HIGH CONCENTRATIONS OF DUST WITHOUT THE USE OF A DUST MASK MAY PRODUCE X-RAY EVIDENCE OF RESPIRATORY DYSFUNCTION IN SOME INDIVIDUALS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: INHALING RESPIRABLE DUST MAY AGGRAVATE EXISTING RESPIRATORY SYSTEM DISEASE(S) AND/OR DYSFUNCTION. EXPOSURE TO DUST MAY AGGRAVATE EXISTING SKIN AND OR EYE CONDITIONS. SECTION 7 – PRECAUTIONS FOR SAFE HANDLING, USE/DISPOSAL STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SPILLS SHOULD BE CLEANED UP USING SPECIAL VACUUM CLEANERS OR WET MOPPING. IF THESE METHODS ARE NOT FEASIBLE, THE BULK OF THE SPILL MAY BE SWEPT UP TAKING CARE TO AVOID EXPOSURE TO DUSTS. RESIDUES AND MINOR QUANTITIES OF DYESMAY BE FLUSHED TO A DRAIN IF ACCEPTABLE TO THE WASTEWATER TREATMENT PLANT. FOLLOW ALL PRECAUTIONS FOR HANDLING THIS PRODUCT WHEN DEALING WITH SPILLS. WASTE DISPOSAL METHOD: SPILLED MATERIALS SHOULD BE RETURNED TO USE, IF POSSIBLE. IF NOT, WASTE MATERIAL MAY BE DUMPED OR INCINERATED UNDER CONITIONS WHICH MEET ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. SECTION 8 – CONTROL AND PROTECTIVE MEASURES – SPECIAL USE PRECAUTIONS RESPIRATORY PROTECTION: AN APPROPRIATE NIOSH APPROVED RESPIRATOR OR DUST SHOULD BE WORN WHEN HANDLING THIS PRODUCT. Page 93 of 553 Page 93 of 553 Page 93 of 553 Page 93 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Telephone (704) 987-4555 8935 NorthPointe Executive Park Dr. Huntersville, NC 28078 www.irwin.com 3 VENTILATION: USE OF LOCAL VENTILATION IS SUGGESTED WHEN USING THIS PRODUCT. HOWEVER, USE OF GOOD GENERAL VENTILATION IS ACCEPTABLE. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS. OTHER PROTECTIVE EQUIPMENT: WEAR IMPERMEABLE RUBBER OR PLASTIC GLOVES. WEAR A RUBBER OR PLASTIC APRON. WEAR NORMAL WORK CLOTHES – LONG SLEEVED SHIRT AND PANTS – CLEAN EVERY SHIFT. OTHER PRECAUTIONS TO BE TAKEN IN HADLING AND STORING: STORE WITH CONTAINER CLOSED IN A DRY PLACE AWAY FROM EXCESSIVE HEAT AND OPEN FLAMES. AVOID UNNECESSARY PERSONAL CONTACT. SECTION 9 – EMERGENCY FIRST AID INFORMATION INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE MEDICAL ATTENTION. SKIN: WASH SKIN CONTACT WITH SOAP AND WATER. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH EYE CONTACT WITH LARGE AMOUNTS OF WATER FOR ATLEAST 15 MINUTES AND THE GET MEDICAL ATTENTION. SECTION 10 – TRANSPORTATION INFORMATION DOT HAZARD CLASSIFICATION: NOT REGULATED BY DOT SECTION 11 – LABEL INFORMATION DO NOT GET ON SKIN OR IN EYES. RESPIRATORY PROTECTION: AN APPROPRIATE NIOSH APPROVED RESPIRATOR FOR DUST SHOULD BE WORN. CAS# COMPONETS 57455-37-5 PIGMENT BLUE 29 471-34-1 CALCIUM CARBONATE 14808-60-7 QUARTZ EMERGENCY FIRST AID PROCEDURES: Page 94 of 553 Page 94 of 553 Page 94 of 553 Page 94 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Telephone (704) 987-4555 8935 NorthPointe Executive Park Dr. Huntersville, NC 28078 www.irwin.com 4 INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE MEDICAL ATTENTION. SKIN: WASH SKIN CONTACT WITH SOAP AND WATER. IF IRRITATION DEVELOPS, SEEK MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH EYE CONTACT WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES AND THEN SEEK MEDICAL ATTENTION. GOOD INDUSTRIAL PRACTICE: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICE, AVOID ALL PERSONAL CONTACT. WEAR WORK CLOTHES WITH LONG SLEEVES, CLEAN EVERY SHIFT. WEAR GOGGLES OR SIDE SHIELD SAFETY GLASSES, IMPERMEABLE GLOVES AND APRON. FOR GOOD HYGIENE A SHOWER AT THE END OF EVERY SHIFT IS RECOMMENDED. WASH WELL BEFORE EATING. DISPOSAL: DISPOSE OF SPILLED PRODUCT, EMPTY CONTAINERS AND UNUSED PRODUCT IN COMPLIANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. EMPTY CONTAINERS: RESIDUES OF THIS PRODUCT MAY REMAIN IN EMPTIED CONTAINERS. CONTAINERS SHOULD NOT BE REUSED WITHOUT PROFESSIONAL CLEANING AND RECONDITIONING. EMPTY CONTAINERS SHOULD BE RINSED BEFORE DISPOSAL. FOLLOW ALL PRECAUTIONS ON LABEL WHEN DEALING WITH EMPTY CONTAINERS. ATTENTION: FOR MANUFACTURING USE ONLY. REFER TO OUR MATERIAL SAFETY DATA SHEET (MSDS) FOR COMPLETE DETAILS. SECTION 12 – ENVIRONMENTAL EFFECTS INFORMATION NO SIGNIFICANT HARMFUL ENVIRONMENTAL EFFECTS ARE KNOWN. SECTION 13 – REFERENCES NONE SECTION 14 – FEDERAL AND STATE REGULATORY INFORMATION NOT CLASSIFIED AS HARZARDOUS MATERIAL PER 40 CFR 261.24 OR 261.3 WE BELIEVE ALL THE DATA AND INFORMATION GIVEN IS ACCURATE AS OF THE DAY OF PREPARATION AND IS OFFERED IN GOOD FAITH, BUT WITHOUT WARRANTY OR REPRESENTATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL WE DISCLAIM ALL LIABILITY FOR RELIANCE THEREON. THIS IS OFFERED SOLELY FOR YOU CONSIDERATION, INVESTIGATION AND VERIFICATION. Page 95 of 553 Page 95 of 553 Page 95 of 553 Page 95 of 553 ---PAGE BREAK--- MSDS: 603 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Burn Relief Spray, Non-Aerosol 22 Corporate Park #1804, 1805 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT % NUMBER OSHA (mg/m3) ACGIH (mg/m3) Lidoocaine hydrochloride 2.0 6108-05-0 N/E N/E Benzalkonium chloride 0.13 8001-54-5 N/E N/E Glycerin < 1 56-81-5 10 10 Section III - PHYSICAL DATA Boiling Point: 212 F Specific Gravity: 1.0 Vapor Pressure (at 70 N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: N/A Solubility In Water: Complete Appearance and Odor: Clear, colorless liquid, characteristic odor. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Product does not burn. Extinguishing Media: Product does not burn. Use extinguishing media appropriate for primary cause of fire in instances where product is involved in a fire. Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None NFPA Hazard Rating: Health: 1 Flammability: 0 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 1 Flammability: 0 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 96 of 553 Page 96 of 553 Page 96 of 553 Page 96 of 553 ---PAGE BREAK--- MSDS: 603 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Eye contact, ingestion. Health Hazards: Eye contact may cause eye irritation. Ingestion may cause nausea, vomiting and diarrhea. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: Eye contact: rinse eyes with large amounts of water. Seek medical attention as soon as possible. Ingestion: Seek medical assistance immediately. Section VI - REACTIVITY DATA Stability: Stable Hazardous Polymerization: Will not occur Hazardous Decomposition Products: None Incompatibilities: None Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Cover with absorbent material (e.g. sand or vermiculite). Collect in suitable container. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: Use NIOSH approved air purifying respirator with particulate filter if TLV or PEL is exceeded. Ventilation: General mechanical. Local exhaust may be required if TLV or PEL is exceeded. Protective Equipment: Eye protection and protective clothing as necessary to prevent excessive contact. Section IX - SPECIAL PRECAUTIONS Eyewash station should be available for emergency use. N/A = Not applicable N/E = Not established Page 97 of 553 Page 97 of 553 Page 97 of 553 Page 97 of 553 ---PAGE BREAK--- Safety Data Sheet: CLEAR GUARD AEROSOL Supercedes Date 08/24/2010 Issuing Date 08/19/2013 1. PRODUCT AND COMPANY IDENTIFICATION Product Name CLEAR GUARD AEROSOL Product Code 5687 Recommended use Lubricant Chemical nature Polymer suspension Information on Manufacturer Emergency Telephone Number CHEMSEARCH DIV. OF NCH CORP. CHEMTREC® [PHONE REDACTED] BOX 152170 IRVING, TX 75015 Telephone inquiry [PHONE REDACTED] 2. HAZARD IDENTIFICATION Color Colorless - Light yellow Physical State Liquid Odor Petroleum distillates GHS Classification Physical Hazards Flammable aerosols Gases under pressure Category 1 Health Hazard Aspiration Toxicity Category 1 Acute Dermal Toxicity Category 4 Acute Inhalation Toxicity - Gas Category 3 Acute Inhalation Toxicity - Dusts and Mists Category 4 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2B Reproductive Toxicity Category 2 Specific target organ systemic toxicity (repeated exposure) Category 1 Other hazards None Labeling Signal Word DANGER Hazard Statements H222 - Extremely flammable aerosol H331 - Toxic if inhaled H312 - Harmful in contact with skin H320 - Causes eye irritation H304 - May be fatal if swallowed and enters airways H370 - Causes damage to heart, liver, kidneys, ears and nervous system through prolonged or repeated exposure H361 - Suspected of damaging fertility or the unborn child H280 - Contains gas under pressure; may explode if heated Precautionary Statements P210 - Keep away from heat, sparks, open flames or hot surfaces. P251 - Pressurized container: Do not pierce or burn, even after use P270 - Do not eat, drink or smoke when using this product P260 - Do not breathe vapor, mist or gas P271 - Use in a well-ventilated area. P280 - Wear protective gloves, protective clothing and eye protection. P264 - Wash face, hands and any exposed skin thoroughly after handling. P304 + P340 - IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P342 + P311 - If experiencing respiratory call a physician P302+ P352 - IF ON SKIN: Wash with plenty of soap and water P312 - Call a physician if unwell. P362 - Take off contaminated clothing and wash before reuse P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists, get medical attention. P301+ P330 + P331 - IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Call a physician if unwell. P403 - Store in a well-ventilated place P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F P501 - Dispose of contents and container in accordance with applicable regulations. Page 1 / 6 Page 98 of 553 Page 98 of 553 Page 98 of 553 Page 98 of 553 ---PAGE BREAK--- 17 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No Weight % Xylenes p- isomers) 1330-20-7 15-40 Hexanes 110-54-3 15-40 Cyclohexane 110-82-7 15-40 Styrene-butadiene polymer 9003-55-8 10-30 Propane 74-98-6 10-30 4. FIRST AID MEASURES General advice Avoid breathing vapors, mist, or gas. Avoid contact with skin, eyes and clothing. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists. Skin Contact Wipe up with absorbent material (e.g. cloth, fleece). Wash off with soap and plenty of water. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use. Inhalation Move to fresh air. In case of shortness of breath, give oxygen. If not breathing, give artificial respiration. Get medical attention immediately. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if irritation develops and persists. Notes to physician Aspiration hazard if swallowed - can enter lungs and cause damage. May be fatal if swallowed and enters airways. 5. FIRE-FIGHTING MEASURES Flash Point -10 °F / -23 °C Method Seta closed cup Flammability Limits in Air % Solvent mixture. Upper 6 Lower 1 Suitable Extinguishing Media Foam. Dry chemical. Water spray. Carbon dioxide (CO2). Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards arising from the chemical Solvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Flame extension: >30 inches / >75 cm and Burnback: 6 inch / 15 cm. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Aerosol Level (NFPA 30B) - 3 NFPA Health 3 Flammability 4 Instability 0 HMIS Health 3 Flammability 4 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Wear protective gloves/clothing. Remove all sources of ignition. Ensure adequate ventilation. Prevent further leakage or spillage if safe to do so. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Use clean non-sparking tools to collect absorbed material. Neutralizing Agent Not applicable. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Avoid breathing vapors, mist or gas. Avoid contact with skin, eyes and clothing. Storage Keep away from heat and sources of ignition. Keep out of the reach of children. Storage Temperature Minimum 35 °F / 2 °C Maximum 130 °F / 54 °C Storage Conditions Indoor X Outdoor Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH Xylenes p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 No data available 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Page 2 / 6 Page 99 of 553 Page 99 of 553 Page 99 of 553 Page 99 of 553 ---PAGE BREAK--- Hexanes TWA: 50 ppm Skin TWA: 500 ppm TWA: 1800 mg/m3 IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3 Cyclohexane TWA: 100 ppm TWA: 300 ppm TWA: 1050 mg/m3 IDLH: 1300 ppm TWA: 300 ppm TWA: 1050 mg/m3 Styrene-butadiene polymer 3 mg/m3 PNOS 5 mg/m3 PNOR No data available Propane TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Engineering Measures Ensure adequate ventilation, especially in confined areas. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection Wear suitable protective clothing, Impervious gloves. Respiratory Protection In case of inadequate ventilation wear respiratory protection. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. General Hygiene Considerations Wear protective gloves/clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity Semi-viscous Color Colorless - Light yellow Odor Petroleum distillates Odor Threshold Not applicable Appearance Transparent - Hazy pH Not applicable Specific Gravity 0.77 Evaporation Rate >1 Percent Volatile (Volume) >83 VOC Content 83 VOC Content (g/L) 639 Vapor Pressure No information available Vapor Density >1 (Air = 1.0) Solubility Negligible n-Octanol/Water Partition No data available Melting Point/Range No data available Decomposition Temperature No data available Boiling Point/Range No data available Flammability (solid, gas) No data available Flash Point -10 °F / -23 °C Method Seta closed cup Autoignition Temperature No information available. Flammability Limits in Air % Solvent mixture. Upper 6 Lower 1 10. STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous polymerization does not occur. Conditions to Avoid None known Incompatible Products Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Possibility of Hazardous Reactions None under normal processing 11. TOXICOLOGICAL INFORMATION Product Information The following values are calculated based on chapter 3.1 of the GHS document (Rev. 3, 2009): Oral LD50 No information available Dermal LD50 No information available Inhalation LC50 Gas No information available Mist No information available Vapor No information available Principle Route of Exposure Eye contact, Skin contact, Inhalation. Primary Routes of Entry Inhalation, Skin Absorption. Acute Effects Eyes Causes eye irritation. Skin Causes skin irritation. May be absorbed through the skin in harmful amounts. Inhalation Causes respiratory tract irritation. Inhalation may cause central nervous system effects. May cause central nervous system depression. and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Aspiration hazard if swallowed - can enter lungs and cause damage. May be fatal if swallowed and enters airways. Chronic Toxicity Repeated and prolonged exposure to solvents may cause brain and nervous system damage. May cause irregular heartbeats, especially under conditions of stress. Repeated absorption may cause disorder of central nervous system, liver, kidneys and blood. Suspect reproductive hazard - contains 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Page 3 / 6 Page 100 of 553 Page 100 of 553 Page 100 of 553 Page 100 of 553 ---PAGE BREAK--- material which may injure unborn child. Target Organ Effects Eyes, Skin, Respiratory system, Central nervous system, Peripheral Nervous System (PNS), Ears, Heart, Liver, Kidney, Blood. Aggravated Medical Conditions Skin disorders, Respiratory disorders, Neurological disorders, Blood disorders, Heart disease, Liver disorders, Kidney disorders. Component Information Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other Xylenes p- isomers) = 4300 mg/kg ( Rat ) > 1700 mg/kg ( Rabbit ) = 47635 mg/L ( Rat ) 4 h no data available no data available Hexanes no data available = 3000 mg/kg ( Rabbit ) = 48000 ppm ( Rat ) 4 h no data available no data available Cyclohexane > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 13.9 mg/L ( Rat ) 4 h no data available no data available Styrene-butadiene polymer no data available no data available no data available no data available no data available Propane no data available no data available = 658 mg/L ( Rat ) 4 h no data available no data available Chronic Toxicity Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects Xylenes p- isomers) no data available no data available yes no data available heart, lung, CNS, PNS, respiratory system, ears, liver, kidney Hexanes no data available no data available no data available no data available eyes,CNS,respiratory system,skin,PNS Cyclohexane no data available no data available no data available no data available eyes, CNS, kidneys, respiratory system, skin Styrene-butadiene polymer no data available no data available no data available no data available no data available Propane no data available no data available no data available no data available CNS, heart Carcinogenicity There are no known carcinogenic chemicals in this product. Component ACGIH IARC NTP OSHA Other Xylenes p- isomers) not applicable not applicable not applicable not applicable not applicable Hexanes not applicable not applicable not applicable not applicable not applicable Cyclohexane not applicable not applicable not applicable not applicable not applicable Styrene-butadiene polymer not applicable not applicable not applicable not applicable not applicable Propane not applicable not applicable not applicable not applicable not applicable 12. ECOLOGICAL INFORMATION Product Information No information available. Component Information Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow Xylenes p- isomers) no data available LC50 = 13.4 mg/L Pimephales promelas 96 h LC50 2.661 - 4.093 mg/L mykiss 96 h LC50 13.5 - 17.3 mg/L mykiss 96 h LC50 13.1 - 16.5 mg/L Lepomis macrochirus 96 h LC50 = 19 mg/L Lepomis macrochirus 96 h LC50 7.711 - 9.591 mg/L Lepomis macrochirus 96 h LC50 23.53 - 29.97 mg/L Pimephales promelas 96 h LC50 = 780 mg/L Cyprinus carpio 96 h LC50 > 780 mg/L Cyprinus carpio 96 h LC50 30.26 - 40.75 mg/L Poecilia reticulata 96 h EC50 = 0.0084 mg/L 24 h EC50= 3.82 mg/L 48 h LC50= 0.6 mg/L 48 h 2.77 - 3.15 Hexanes no data available LC50 2.1 - 2.98 mg/L Pimephales promelas 96 h no data available EC50> 1000 mg/L 24 h N/A Cyclohexane EC50 > 500 mg/L Desmodesmus subspicatus 72 h LC50 3.96 - 5.18 mg/L Pimephales promelas 96 h LC50 23.03 - 42.07 mg/L Pimephales promelas 96 h LC50 24.99 - 44.69 mg/L Lepomis macrochirus 96 h LC50 48.87 - 68.76 mg/L Poecilia reticulata 96 h EC50 = 85.5 mg/L 5 min EC50 = 93 mg/L 10 min EC50> 400 mg/L 24 h 3.44 Styrene-butadiene polymer no data available no data available no data available no data available N/A Propane no data available no data available no data available no data available 2.3 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Page 4 / 6 Page 101 of 553 Page 101 of 553 Page 101 of 553 Page 101 of 553 ---PAGE BREAK--- Persistence and Degradability No information available. Bioaccumulation No information available. Mobility No information available. 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations. Container Disposal Contents under pressure. Do not puncture. Empty containers should be taken for local recycling, recovery, or waste disposal. Empty remaining contents. 14. TRANSPORT INFORMATION DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity ,ORM-D, TDG Hazard Class 2.1 UN-No UN1950 ICAO UN-No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 Shipping Description Aerosols,UN1950 LTD. QTY. IATA UN-No UN1950 Proper Shipping Name Aerosols, flammable Hazard Class 2.1 ERG Code 10L Shipping Description UN1950,Aerosols, flammable,2.1 LTD. QTY. IMDG/IMO Proper Shipping Name Aerosols Hazard Class 2.1 UN-No UN1950 EmS No. F-D, S-U Shipping Description UN1950, Aerosols,2.1 LIMITED QUANTITIES 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Component CAS-No Weight % SARA 313 - Threshold Values Xylenes p- isomers) 1330-20-7 15-40 1.0 Hexanes 110-54-3 15-40 1.0 Cyclohexane 110-82-7 15-40 1.0 SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard Yes Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs Xylenes p- isomers) 100 lb Not applicable Hexanes 5000 lb Not applicable Cyclohexane 1000 lb Not applicable Styrene-butadiene polymer Not applicable Not applicable Propane Not applicable Not applicable 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Page 5 / 6 Page 102 of 553 Page 102 of 553 Page 102 of 553 Page 102 of 553 ---PAGE BREAK--- 16. OTHER INFORMATION Prepared By Angela Hutson Supercedes Date 08/24/2010 Issuing Date 08/19/2013 Reason for Revision No information available. Glossary No information available. List of References. No information available. CHEMSEARCH DIV. OF NCH CORP.assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this document is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL 5687 - CLEAR GUARD AEROSOL Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Issuing Date 08/19/2013 Page 6 / 6 Page 103 of 553 Page 103 of 553 Page 103 of 553 Page 103 of 553 ---PAGE BREAK--- Page 104 of 553 Page 104 of 553 Page 104 of 553 Page 104 of 553 ---PAGE BREAK--- Page 105 of 553 Page 105 of 553 Page 105 of 553 Page 105 of 553 ---PAGE BREAK--- Page 106 of 553 Page 106 of 553 Page 106 of 553 Page 106 of 553 ---PAGE BREAK--- Page 107 of 553 Page 107 of 553 Page 107 of 553 Page 107 of 553 ---PAGE BREAK--- Page 108 of 553 Page 108 of 553 Page 108 of 553 Page 108 of 553 ---PAGE BREAK--- Page 109 of 553 Page 109 of 553 Page 109 of 553 Page 109 of 553 ---PAGE BREAK--- The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000 Material Safety Data Sheet I Product: CLOROX REGULAR-BLEACH Description: CLEAR, LIGHT YELLOW LIQUID WITH A CHARACTERISTIC CHLORINE ODOR Other Designations Distributor Emergency Telephone Nos. Clorox Bleach EPA Reg. No. 5813-100 Clorox Sales Company 1221 Broadway Oakland, CA 94612 For Medical Emergencies call: (800) 446-1014 For Transportation Emergencies Chemtrec (800) 424-9300 II Health Hazard Data III Hazardous Ingredients DANGER: CORROSIVE. HARMFUL IF SWALLOWED. May cause severe irritation or damage to eyes, skin and mucous membranes. Wear rubber gloves. Vapors may irritate. Keep out of reach of children. Some clinical reports suggest a low potential for sensitization upon exaggerated exposure to sodium hypochlorite if skin damage irritation) occurs during exposure. Under normal consumer use conditions the likelihood of any adverse health effects are low. Medical conditions that may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, chronic bronchitis or obstructive lung disease. FIRST AID: Eye Contact: Immediately rinse with water for 15 minutes. Remove contact lenses, after first 5 minutes. Call a doctor. Skin Contact: Remove contaminated clothing and wash skin thoroughly with water. If irritation persists, call a doctor. Ingestion: DO NOT induce vomiting. Drink a glassful of water. Call a doctor or poison control center immediately. Do not try to give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If breathing is affected, call a physician. Ingredient Concentration Exposure Limit Sodium hypochlorite 5-15 % Not established CAS# 7681-52-9 Sodium hydroxide 0.1 - 1% 2 mg/m - TLV - C1 CAS# 1310-73-2 2 mg/m - PEL - TWA 2 1ACGIH Threshold Limit Value (TLV) - Ceiling 2OHSA Permissible Exposure Limit (PEL) – Time Weighted Average (TWA) None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists. IV Special Protection and Precautions V Transportation and Regulatory Data No special protection or precautions have been identified for using this product under directed consumer use conditions. The following recommendations are given for production facilities and for other conditions and situations where there is increased potential for accidental, large-scale or prolonged exposure. Hygienic Practices: Avoid contact with eyes, skin and clothing. Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist. Personal Protective Equipment: Wear safety goggles. Use rubber or nitrile gloves if in contact liquid, especially for prolonged periods. KEEP OUT OF REACH OF CHILDREN DOT: Consumer Commodity ORM-D. IATA: UN 1791, Hypochlorite solution, Class 8, PG III. IMDG: UN 1791, Hypochlorite solution, Class 8, PG III. EPA - SARA TITLE III/CERCLA: Bottled product is not reportable under Sections 311/312 and contains no chemicals reportable under Section 313. This product does contain chemicals (sodium hydroxide <0.2% and sodium hypochlorite <7.35%) that are regulated under Section 304/CERCLA. TSCA/DSL STATUS: All components of this product are on the U.S. TSCA Inventory and Canadian DSL. VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Control spill. Containerize liquid and use absorbents on residual liquid; dispose appropriately. Wash area and let dry. For spills of multiple products, responders should evaluate the MSDS’s of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed, and/or poorly ventilated areas until hazard assessment is complete. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations. Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other household chemicals such as toilet bowl cleaners, rust removers, vinegar, acids or ammonia containing products to produce hazardous gases, such as chlorine and other chlorinated species. Prolonged contact with metal may cause pitting or discoloration. VIII Fire and Explosion Data IX Physical Data Flash Point: None Special Firefighting Procedures: None Unusual Fire/Explosion Hazards: None. Not flammable or explosive. Product does not ignite when exposed to open flame. Boiling point approx. 212°F/100°C Specific Gravity (H20=1) ~ 1.1 at 70oF Solubility in Water complete pH ~11.9 1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 07/12 Page 110 of 553 Page 110 of 553 Page 110 of 553 Page 110 of 553 ---PAGE BREAK--- Page 1 of 4 Procter & Gamble Fabric and Home Care Division Sharon Woods Technical Center 11530 Reed Hartman Highway Cincinnati, OH 45241-2422 MATERIAL SAFETY DATA SHEET MSDS H96222M Issue Date: 11/1/99 Supersedes: N/A Issue Date: N/A SECTION I - CHEMICAL PRODUCT Identity: Liquid Cleaner Brands: COMET WITH BLEACH (All Variations) Hazard Rating: 1 Health: 1 4=EXTREME Flammability: 0 3=HIGH Reactivity: 0 2= MODERATE 1=SLIGHT Emergency Telephone Number: 24hr P&G Operator - 1-[PHONE REDACTED] or call Local Poison Control Center SECTION II - COMPOSITION AND INGREDIENTS Ingredients/Chemical Name: Cleaning agents, bleach (sodium hypochlorite), surface safety agent, perfume and water. This mixture, when tested as a whole, is considered an eye irritant within the meaning of the OSHA Hazard Communication Standard. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. Chemical Name Common Name CAS No. Recommended Limits Composition Range LD50/LC50 Sodium Hypochlorite Bleach 7681-52-9 AIHA STEL: 2 mg/m3 0.5-1.5% Sodium hydroxide Caustic soda 1310-73-2 ACGIH STEL: 2 mg/m3 OSHA PEL: 2 mg/m3 0.1-1% Page 111 of 553 Page 111 of 553 Page 111 of 553 Page 111 of 553 ---PAGE BREAK--- 2 COMET WITH BLEACH LIQUID CLEANER MSDS (Continued) Page 2 of 4 SECTION III - HAZARDS IDENTIFICATION Health Hazards (Acute and Chronic): Ingestion: Mild mucous membrane irritant. Eye Contact: Mild eye irritant. Inhalation: Mild mucous membrane irritant. Skin: Mild skin irritant. Signs and of Exposure: Ingestion: Oral ingestion may result in mild gastrointestinal irritation with nausea, vomiting, or diarrhea. Eye Contact: Instillation into the eye may result in transient mild to moderate irritation. Skin: Use on irritated or extremely dry skin may aggravate the existing condition. Inhalation: N/A SECTION IV - FIRST AID INFORMATION Emergency and First Aid Procedures: Ingestion: Immediately drink two large glasses of water and treat If large amounts are ingested, call a physician. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes, lifting upper and lower lids occasionally. Skin: Thoroughly wash exposed area with soap and water and discontinue use. Remove contaminated clothing. Inhalation: N/A Other: Consumer product package has a caution statement: CAUTION: MAY CAUSE EYE IRRITATION. KEEP OUT OF REACH OF CHILDREN. In case of contact with eyes, rinse thoroughly with water. If swallowed, drink a glassful of water. Contains bleach. Use with adequate ventilation. Do not mix with other products, especially toilet bowl cleaners, acidic cleaners, or products that contain ammonia as irritating fumes may result. SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): over 200° F (cc) Explosive Limits: LEL: N/A UEL: N/A Extinguishing Media: CO2, water, dry chemical or "alcohol" foam. Special Fire Fighting Procedures: Use water to keep fire exposed container cool. Unusual Fire Hazards: None known. Stability Unstable: Stable: X Conditions to Avoid: None known Incompatibility (Materials to Avoid): Do not mix with other products, especially toilet bowl cleaners, acidic cleaners or products that contain ammonia. Hazardous Decomposition/By Products: None Hazardous Polymerization: May Occur: Will Not Occur: X Conditions to Avoid: None known Page 112 of 553 Page 112 of 553 Page 112 of 553 Page 112 of 553 ---PAGE BREAK--- 3 COMET WITH BLEACH LIQUID CLEANER MSDS (Continued) Page 3 of 4 SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Do not landfill. Small (household) quantities may be disposed of via sewer. Steps To Be Taken in Case Material is Released or Spilled: Use water spray to dilute and/or wash away spills to avoid exposure and to protect persons working to stop/repair leak. SECTION VII - HANDLING AND STORAGE Precautions To Be Taken in Handling and Storing: Handling and storage must be well ventilated, cool, and dry. Materials must be isolated from potential sources of ignition. Fire fighting equipment must be available at all times. Other Precautions: Keep away from heat/sparks and open flame. SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION Respiratory Protection (Specify Type): None required with normal use. Ventilation Local Exhaust: None required with normal consumer use. Special: None Mechanical (General): Acceptable. Other: None Eye Protection: None required with normal consumer use. Industrial Setting: For splash protection, use chemical goggles. Eye wash fountain is desirable. Protective Gloves: None required with normal use. Other Protective Equipment: None required with normal use. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point N/A Specific Gravity (H2O=1): 1.030-1.045 Vapor Pressure (mm Hg): N/A Percent Volatile by Volume N/A Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): N/A Odor Threshold: N/A Freezing Point: N/A Coefficient of Water/Oil Distribution: N/A pH solution): Unknown Scooped Density: N/A Solubility in Water: Completely Appearance and Odor: Clear liquid. Products is perfumed. Reserve Alkalinity: N/A SECTION X - STABILITY AND REACTIVITY Possible Hazardous Reactions/Conditions: None known Conditions to Avoid: None Materials to Avoid: None Hazardous Decomposition Products: None known Other Recommendations: None Page 113 of 553 Page 113 of 553 Page 113 of 553 Page 113 of 553 ---PAGE BREAK--- 4 COMET WITH BLEACH LIQUID CLEANER MSDS (Continued) Page 4 of 4 SECTION XI - TOXICOLOGICAL INFORMATION LD50 (rats oral): >6.5 g/kg SECTION XII - ECOLOGICAL INFORMATION No concerns at relevant environmental concentrations. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Do not landfill. Small (household) quantities may be disposed of via sewer. DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. SECTION XIV - TRANSPORT INFORMATION DOT Classification: Packaged consumer products are classified as non-hazardous. Bulk product shipments are classified as a Class 9 Hazardous Substance with a shipping name of Environmentally hazardous substance, liquid n.o.s. SECTION XV - ADDITIONAL REGULATORY INFORMATION All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules (SNURs) under TSCA No components of Comet are subject to California Proposition 65. EPA CERCLA TITLE III Chemical Name CERCLA 304 RQ (LBS) 311/312 313 Sodium Hypochlorite 100 no no Sodium Hydroxide 1000 no no All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified with Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information required by the Canadian Products Regulation. SECTION XVI - OTHER INFORMATION *N/A. - Not Applicable *N/K. - Not Known The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use only in connection with occupational safety and health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from misuse of the controlled product. Page 114 of 553 Page 114 of 553 Page 114 of 553 Page 114 of 553 ---PAGE BREAK--- Page 115 of 553 Page 115 of 553 Page 115 of 553 Page 115 of 553 ---PAGE BREAK--- Page 116 of 553 Page 116 of 553 Page 116 of 553 Page 116 of 553 ---PAGE BREAK--- Page 117 of 553 Page 117 of 553 Page 117 of 553 Page 117 of 553 ---PAGE BREAK--- Page 118 of 553 Page 118 of 553 Page 118 of 553 Page 118 of 553 ---PAGE BREAK--- XIAMETER(TM) Material Safety Data Sheet Page: 1 of 8 Version: 1.1 Revision Date: 2002/01/29 DAP(R) 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR 1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY XIAMETER(TM). The measure of value. Dow Corning Corporation South Saginaw Road Midland, Michigan 48686 24 Hour Emergency Telephone: Customer Service: Product Disposal Information: CHEMTREC: (989) 496-5900 (989) 496-6000 (989) 496-6315 (800) 424-9300 MSDS No.: 02830396 Revision Date: 2002/01/29 Generic Description: Silicone elastomer Physical Form: Paste Color: Colorless Odor: Some odor NFPA Profile: Health 2 Flammability 1 Instability/Reactivity 0 Note: NFPA = National Fire Protection Association 2. OSHA HAZARDOUS COMPONENTS CAS Number Wt % Component Name 22984-54-9 3.0 - 7.0 Methyl silane 96-29-7 1.0 - 5.0 83817-72-5 1.0 - 5.0 Di methoxymethyl silane The above components are hazardous as defined in 29 CFR 1910.1200. 3. EFFECTS OF OVEREXPOSURE Acute Effects Eye: Direct contact may cause moderate irritation. Skin: May cause moderate irritation. Inhalation: Irritates respiratory passages very Vapor overexposure may cause drowsiness. Oral: Low ingestion hazard in normal use. Prolonged/Repeated Exposure Effects Skin: Repeated skin contact may cause allergic skin reaction. Overexposure by skin absorption may injure the following organ(s): Blood. Inhalation: Overexposure by inhalation may injure the following organ(s):Blood. Liver. Page 119 of 553 Page 119 of 553 Page 119 of 553 Page 119 of 553 ---PAGE BREAK--- XIAMETER(TM) Material Safety Data Sheet Page: 2 of 8 Version: 1.1 Revision Date: 2002/01/29 DAP(R) 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR Oral: Overexposure by ingestion may injure the following organ(s):Blood. Signs and of Overexposure No known applicable information. Medical Conditions Aggravated by Exposure No known applicable information. The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 4. FIRST AID MEASURES Eye: Immediately flush with water for 15 minutes. Get medical attention. Skin: Remove from skin and immediately flush with water for 15 minutes. Get medical attention if irritation or ill effects develop or persist. Inhalation: Remove to fresh air. Get medical attention if ill effects persist. Oral: Get medical attention. Comments: Treat according to person's condition and specifics of exposure. 5. FIRE FIGHTING MEASURES Flash Point: Not applicable. Autoignition Temperature: Not determined. Flammability Limits in Air: Not determined. Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. Unusual Fire Hazards: None. Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: Nitrogen oxides. Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. Metal oxides. Page 120 of 553 Page 120 of 553 Page 120 of 553 Page 120 of 553 ---PAGE BREAK--- XIAMETER(TM) Material Safety Data Sheet Page: 3 of 8 Version: 1.1 Revision Date: 2002/01/29 DAP(R) 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR 6. ACCIDENTAL RELEASE MEASURES Containment/Clean up: Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since some silicone materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is required. 7. HANDLING AND STORAGE Use with adequate ventilation. Product evolves methyl ethyl ketoxime (MEKO) when exposed to water or humid air. Provide ventilation during use to control methyl ethyl ketoxime (MEKO) within exposure guidelines or use respiratory protection. Product evolves flammable methyl alcohol when exposed to water or humid air. Provide ventilation during use to control exposure within Section 8 guidelines or use air-supplied or self-contained breathing apparatus. Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep container closed. Do not take internally. Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits CAS Number Component Name Exposure Limits 22984-54-9 Methyl silane See ethyl methyl ketoxime comments. 96-29-7 Vendor guide: TWA 3 ppm, STEL 10 ppm. AIHA WEEL: TWA 10 ppm. 83817-72-5 Di methoxymethyl silane See methyl alcohol and ethyl methyl ketoxime comments. Methyl alcohol forms on contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 200 ppm and ACGIH TLV-skin: TWA 200 ppm, STEL 250 ppm. Ethyl methyl ketoxime is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within the following exposure guidelines: Vendor guide TWA: 3 ppm, STEL: 10 ppm; AIHA WEEL TWA: 10 ppm. Engineering Controls Local Ventilation: Recommended. Page 121 of 553 Page 121 of 553 Page 121 of 553 Page 121 of 553 ---PAGE BREAK--- XIAMETER(TM) Material Safety Data Sheet Page: 4 of 8 Version: 1.1 Revision Date: 2002/01/29 DAP(R) 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR General Ventilation: Recommended. Personal Protective Equipment for Routine Handling Eyes: Use proper protection - safety glasses as a minimum. Skin: Wash at mealtime and end of shift. If skin contact occurs, change contaminated clothing as soon as possible and thoroughly flush affected areas with cool water. Chemical protective gloves are recommended. Suitable Gloves: Butyl Rubber. Natural Rubber. Neoprene Rubber(R). Nitrile Rubber. Silver Shield(R). 4H(R). Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or air sampling data show exposures are within recommended exposure guidelines. Industrial Hygiene Personnel can assist in judging the adequacy of existing engineering controls. Suitable Respirator: General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits as determined by air sampling or are unknown, appropriate respiratory protection should be worn. Follow OSHA Respirator Regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Personal Protective Equipment for Spills Eyes: Use full face respirator. Skin: Wash at mealtime and end of shift. If skin contact occurs, change contaminated clothing as soon as possible and thoroughly flush affected areas with cool water. Chemical protective gloves are recommended. Inhalation/Suitable Respirator: Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR 1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Precautionary Measures: Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep container closed. Do not take internally. Use reasonable care. Comments: Product evolves methyl ethyl ketoxime (MEKO) when exposed to water or humid air. Provide ventilation during use to control methyl ethyl ketoxime (MEKO) within exposure guidelines or use respiratory protection. Product evolves flammable methyl alcohol when exposed to water or humid air. Provide ventilation during use to control exposure within Section 8 guidelines or use air-supplied or self-contained breathing apparatus. Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. Page 122 of 553 Page 122 of 553 Page 122 of 553 Page 122 of 553 ---PAGE BREAK--- XIAMETER(TM) Material Safety Data Sheet Page: 5 of 8 Version: 1.1 Revision Date: 2002/01/29 DAP(R) 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Paste Color: Colorless Odor: Some odor Specific Gravity @ 25°C: 1.05 Viscosity: Not determined. Freezing/Melting Point: Not determined. Boiling Point: Not determined. Vapor Pressure @ 25°C: Not determined. Vapor Density: Not determined. Solubility in Water: Not determined. pH: Not determined. Volatile Content: Not determined. Note: The above information is not intended for use in preparing product specifications. 10. STABILITY AND REACTIVITY Chemical Stability: Stable. Hazardous Polymerization: Hazardous polymerization will not occur. Conditions to Avoid: None. Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8. 11. TOXICOLOGICAL INFORMATION Component Toxicology Information Contains Methyl Ethyl Ketoxime (MEKO). Male rodents exposed to MEKO vapor throughout their lifetime developed liver cancer. Additional testing is planned by the MEKO supplier to determine any relevance to humans. Until more data is known, exposure levels should be maintained as low as achievable. Special Hazard Information on Components Sensitizers CAS Number Wt % Component Name 22984-54-9 3.0 - 7.0 Methyl silane Possible skin sensitizer. 96-29-7 1.0 - 5.0 Possible skin sensitizer. 83817-72-5 1.0 - 5.0 Di methoxymethyl silane Possible skin sensitizer. Page 123 of 553 Page 123 of 553 Page 123 of 553 Page 123 of 553 ---PAGE BREAK--- XIAMETER(TM) Material Safety Data Sheet Page: 6 of 8 Version: 1.1 Revision Date: 2002/01/29 DAP(R) 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR 12. ECOLOGICAL INFORMATION Environmental Fate and Distribution Complete information is not yet available. Environmental Effects Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants Complete information is not yet available. Ecotoxicity Classification Criteria Hazard Parameters (LC50 or EC50) High Medium Low Acute Aquatic Toxicity (mg/L) >1 and <=100 >100 Acute Terrestrial Toxicity <=100 >100 and 2000 >2000 This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993. This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material. 13. DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional information is required. 14. TRANSPORT INFORMATION DOT Road Shipment Information (49 CFR 172.101) Not subject to DOT. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (IATA) Not subject to IATA regulations. 15. REGULATORY INFORMATION Page 124 of 553 Page 124 of 553 Page 124 of 553 Page 124 of 553 ---PAGE BREAK--- XIAMETER(TM) Material Safety Data Sheet Page: 7 of 8 Version: 1.1 Revision Date: 2002/01/29 DAP(R) 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. EPA SARA Title III Chemical Listings Section 302 Extremely Hazardous Substances: None. Section 304 CERCLA Hazardous Substances: None. Section 312 Hazard Class: Acute: Yes Chronic: Yes Fire: No Pressure: No Reactive: No Section 313 Toxic Chemicals: None present or none present in regulated quantities. Supplemental State Compliance Information California Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm. None known. Massachusetts CAS Number Wt % Component Name 7631-86-9 7.0 - 13.0 Silica, amorphous New Jersey CAS Number Wt % Component Name 70131-67-8 > 60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 7.0 - 13.0 Silica, amorphous Page 125 of 553 Page 125 of 553 Page 125 of 553 Page 125 of 553 ---PAGE BREAK--- XIAMETER(TM) Material Safety Data Sheet Page: 8 of 8 Version: 1.1 Revision Date: 2002/01/29 DAP(R) 73358 SILICONE II MULTI-PURPOSE SEALANT CLEAR 22984-54-9 3.0 - 7.0 Methyl silane 83817-72-5 1.0 - 5.0 Di methoxymethyl silane 96-29-7 1.0 - 5.0 CAS Number Wt % Component Name 70131-67-8 > 60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 7.0 - 13.0 Silica, amorphous 22984-54-9 3.0 - 7.0 Methyl silane 16. OTHER INFORMATION Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. XIAMETER(TM) is a trademark of Dow Corning Corporation Get access to the new measure of value at: http://www.xiameter.com Page 126 of 553 Page 126 of 553 Page 126 of 553 Page 126 of 553 ---PAGE BREAK--- Page 1 of 4 Procter & Gamble P&G Household Care Ivorydale Technical Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS FH/L/2005/RWRB-6FLJW3 Issue Date: 09/08/05 Supersedes: LDL 0006 Issue Date: 09/25/03 SECTION I - CHEMICAL PRODUCT Identity: Liquid Hand Dishwashing Detergents Brands: DAWN (All Variations) IVORY (All Variations) JOY (All Variations) SALVO Hazard Rating: Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2= MODERATE 1=SLIGHT Emergency Telephone Number: DAWN 1-[PHONE REDACTED] (DAWN) IVORY 1-[PHONE REDACTED] (IVORY) JOY 1-[PHONE REDACTED] (JOY) SALVO 1-[PHONE REDACTED] or call Local Poison Control Center or your physician SECTION II - COMPOSITION AND INGREDIENTS Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. Chemical Name Common Name CAS No. Recommended Limits Composition Range LD50/LC50 Ethyl alcohol Ethanol 64-17-5 ACGIH TLV: 1880 mg/m3 1-6% Page 127 of 553 Page 127 of 553 Page 127 of 553 Page 127 of 553 ---PAGE BREAK--- 2 Liquid Hand Dishwashing Detergents (Continued) Page 2 of 4 SECTION III - HAZARDS IDENTIFICATION Health Hazards (Acute and Chronic): Ingestions: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Signs and of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. SECTION IV - FIRST AID INFORMATION Emergency and First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If persist or recur, seek medical attention. Other: Consumer product package has a voluntary avoid accidents statement. SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): 115-135°F. Pensky- Martens (Closed cup) Explosive Limits: LEL: N/A UEL: N/A Extinguishing Media: CO2, water or dry chemical. Special Fire Fighting Procedures: None. Although this product has a flash point below 200°F (closed cup), it is a >50% aqueous solution that does not sustain combustion. DOT classification is non-hazardous. Unusual Fire Hazards: None Stability Unstable: Stable: X Conditions to Avoid: None known Incompatibility (Materials to Avoid): None known Hazardous Decomposition/By Products: None known Hazardous Polymerization: May Occur: Will Not Occur: X Conditions to Avoid: None known SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information. Page 128 of 553 Page 128 of 553 Page 128 of 553 Page 128 of 553 ---PAGE BREAK--- 3 Liquid Hand Dishwashing Detergents (Continued) Page 3 of 4 SECTION VII - HANDLING AND STORAGE Precautions To Be Taken in Handling and Storing: No unusual precautions necessary. Other Precautions: None known SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION Respiratory Protection (Specify Type): None required with normal use. Ventilation Local Exhaust: None required with normal consumer use. Special: None Mechanical (General): Normal/general dilution ventilation is acceptable. Other: None Eye Protection: None required with normal consumer use. Industrial Setting: For splash protection, use chemical goggles. Eye Wash fountain is desirable. Protective Gloves: None required with normal use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Other Protective Equipment: None required with normal use. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point Not known Specific Gravity (H2O=1): ca. 1 Vapor Pressure (mm Hg): N/A Percent Volatile by Volume ~60-65% Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): Unknown Odor Threshold: N/A Freezing Point: ~ 30 F Coefficient of Water/Oil Distribution: N/A pH: 8-9 Scooped Density: N/A Solubility in Water: Completely Appearance and Odor: Purple, Blue, Green, Yellow, Pink or Orange liquids. All products are perfumed. Reserve Alkalinity: N/A SECTION X - STABILITY AND REACTIVITY Possible Hazardous Reactions/Conditions: None known Conditions to Avoid: None Materials to Avoid: None Hazardous Decomposition Products: None known Other Recommendations: None SECTION XI - TOXICOLOGICAL INFORMATION LD50 (rats oral): approx 12 mL/kg ED50 approx 2.3 mL/kg Liquid hand dishwashing detergents have a relatively low order of toxicity. They may be irritating, but they are not expected to be corrosive. They are expected to be emetic. Page 129 of 553 Page 129 of 553 Page 129 of 553 Page 129 of 553 ---PAGE BREAK--- 4 Liquid Hand Dishwashing Detergents (Continued) Page 4 of 4 SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable. These products are safe for septic tanks. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal is to be performed in compliance with Federal, state and local regulations. Household product is safe for disposal down the drain during use or in the trash. Industrial Setting: Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. SECTION XIV - TRANSPORT INFORMATION Non-hazardous under DOT. SECTION XV - ADDITIONAL REGULATORY INFORMATION All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules (SNURs) under TSCA No components of Dawn, Ivory, Joy or Salvo are subject to California Proposition 65 labeling. All ingredients are CEPA approved for import to Canada by Procter & Gamble only. SECTION XVI - OTHER INFORMATION *N/A. - Not Applicable *N/K. - Not Known The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use only in connection with occupational safety and health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from misuse of the controlled product. Page 130 of 553 Page 130 of 553 Page 130 of 553 Page 130 of 553 ---PAGE BREAK--- Page 1 of 4 Procter & Gamble Fabric and Home Care Division Ivorydale Technical Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS LDL 0006 Issue Date: 09/25/03 Supersedes: LDL 0005 Issue Date: 02/10/03 SECTION I - CHEMICAL PRODUCT Identity: Liquid Hand Dishwashing Detergents Brands: DAWN (All Variations) IVORY (All Variations) JOY (All Variations) SALVO Hazard Rating: Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2= MODERATE 1=SLIGHT Emergency Telephone Number: 24hr P&G Operator: DAWN 1-[PHONE REDACTED] (DAWN) IVORY 1-[PHONE REDACTED] (IVORY) JOY 1-[PHONE REDACTED] (JOY) SALVO 1-[PHONE REDACTED] or call Local Poison Control Center or your physician Chemical Name Common Name CAS No. Recommended Limits Composition Range Ethyl alcohol Ethanol 64-17-5 ACGIH TLV: 1880 mg/m3 1-6% Subtilisin Protease 9014-01-1 NIOSH STEL 0.00006 mg/m3 <0.01% Amylase Amylase 9000-90-2 NIOSH STEL 0.00006 mg/m3 <0.01% Page 131 of 553 Page 131 of 553 Page 131 of 553 Page 131 of 553 ---PAGE BREAK--- LIQUID HAND DISHWASHING DETERGENTS MSDS (Continued) Page 2 of 4 SECTION III - HAZARDS IDENTIFICATION Health Hazards (Acute and Chronic): Ingestions: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Signs and of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. SECTION IV - FIRST AID INFORMATION Emergency and First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If persist or recur, seek medical attention. Other: Consumer product package has a voluntary avoid accidents statement. SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): 115-135°F. Pensky- Martens (Closed cup) Explosive Limits: LEL: N/A UEL: N/A Extinguishing Media: CO2, water or dry chemical. Special Fire Fighting Procedures: None. Although this product has a flash point below 200°F (closed cup), it is a >50% aqueous solution that does not sustain combustion. DOT classification is non-hazardous. Unusual Fire Hazards: None Stability Unstable: Stable: X Conditions to Avoid: None known Incompatibility (Materials to Avoid): None known Hazardous Decomposition/By Products: None known Hazardous Polymerization: May Occur: Will Not Occur: X Conditions to Avoid: None known SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information. 2 Page 132 of 553 Page 132 of 553 Page 132 of 553 Page 132 of 553 ---PAGE BREAK--- LIQUID HAND DISHWASHING DETERGENTS MSDS (Continued) Page 3 of 4 SECTION VII - HANDLING AND STORAGE Precautions To Be Taken in Handling and Storing: No unusual precautions necessary. Other Precautions: None known SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION Respiratory Protection (Specify Type): None required with normal use. Ventilation Local Exhaust: None required with normal consumer use. Special: None Mechanical (General): Normal/general dilution ventilation is acceptable. Other: None Eye Protection: None required with normal consumer use. Industrial Setting: For splash protection, use chemical goggles. Eye Wash fountain is desirable. Protective Gloves: None required with normal use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Other Protective Equipment: None required with normal use. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point Not known Specific Gravity (H2O=1): ca. 1 Vapor Pressure (mm Hg): N/A Percent Volatile by Volume ~60-65% Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): Unknown Odor Threshold: N/A Freezing Point: ~ 30 F Coefficient of Water/Oil Distribution: N/A pH: 8-9 Scooped Density: N/A Solubility in Water: Completely Appearance and Odor: Purple, Blue, Green, Yellow, Pink or Orange liquids. All products are perfumed. Reserve Alkalinity: N/A SECTION X - STABILITY AND REACTIVITY Possible Hazardous Reactions/Conditions: None known Conditions to Avoid: None Materials to Avoid: None Hazardous Decomposition Products: None known Other Recommendations: None SECTION XI - TOXICOLOGICAL INFORMATION LD50 (rats oral): approx 12 mL/kg ED50 approx 2.3 mL/kg Liquid hand dishwashing detergents have a relatively low order of toxicity. They may be irritating, but they are not expected to be corrosive. They are expected to be emetic. 3 Page 133 of 553 Page 133 of 553 Page 133 of 553 Page 133 of 553 ---PAGE BREAK--- 4 LIQUID HAND DISHWASHING DETERGENTS MSDS (Continued) Page 4 of 4 SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable. These products are safe for septic tanks. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal is to be performed in compliance with Federal, state and local regulations. Household product is safe for disposal down the drain during use or in the trash. Industrial Setting: Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. SECTION XIV - TRANSPORT INFORMATION Dawn, Joy, Ivory and Salvo are non-hazardous under DOT. SECTION XV - ADDITIONAL REGULATORY INFORMATION All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules (SNURs) under TSCA No components of Dawn, Ivory, Joy or Salvo are subject to California Proposition 65 labeling. All ingredients are CEPA approved for import to Canada by Procter & Gamble only. SECTION XVI - OTHER INFORMATION *N/A. - Not Applicable *N/K. - Not Known The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use only in connection with occupational safety and health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from misuse of the controlled product. Page 134 of 553 Page 134 of 553 Page 134 of 553 Page 134 of 553 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T A registered trademark of the ORANGE-SOL Group of Companies, Ltd. Section 1 Product & Company Identifications Product Name: De-Solv-it® Product Use: Removal of grease, oil, tar, asphalt, chewing gum, crayon, fresh blood, grass stains, soap scum, waxes, oily cosmetics, adhesives, scuff marks and stickers. Distributor: ORANGE-SOL Household Products, Inc . 1400 N. Fiesta Blvd., Bldg. 100 Gilbert, AZ 85233-1023 For Information & Emergencies: (480) 497-8822 (7 am-5pm, Mon-Fri MST) www.orange-sol.com Preparation Date: 1 Oct 2004 Revision Date: 11 Aug 2009 MSDS 70004-006 Section 2 Information on Ingredients Product Mixture: No hazardous ingredients as per OSHA, 29CFR 1910.1200. Components: This section is proprietary. Section 3 Hazardous Identification Emergency Overview: Avoid inhalation of mist and contact with eyes. Primary Routes of Contact: Ingestion, inhalation, and absorption. Physical Hazard: None established. Evco Plastics Product code 2043328 Document 2043328 Page 4350 Return to Index Page 135 of 553 Page 135 of 553 Page 135 of 553 Page 135 of 553 ---PAGE BREAK--- Health Hazard Eye: May cause irritation. Skin: Repeated or prolonged exposure may cause dermatitis in sensitive individuals. Ingestion: May cause gastric disturbances such as diarrhea. Vapor Inhalation: Avoid mists, which may irritate mucous membranes. Carcinogenicity Listings: NTP: None. IARC: None. OSHA: None. ACGIH: None. Signs and of Overexposure: Red, dry skin at point of contact. Medical Conditions Aggravated by Exposure: Dermatitis may become aggravated by sensitive individuals. Section 4 First Aid Procedures Eye: Remove contact lenses, flush with water for at least 15 minutes while lifting eyelids. If irritation develops and persists, contact a physician. Skin: Remove effected clothing. Wash skin thoroughly with soap and water. If irritation develops and persists, contact a physician. Ingestion: If swallowed, do not induce vomiting. May cause chemical pneumonia if aspirated into lungs. Inhalation: Move to fresh air. If irritation develops and persists, contact a physician. Section 5 Fire & Explosion Hazard Flash Point and Method: 176°F, PMCC. ASTM D-93. Flammability: Non-Combustible per FHSA, 16CFR 1500.3(C)(6)(iii). Explosion Data: Sensitivity to impact: None. Sensitivity to static charge: None. Combustion Products: As with any organic material, combustion will produce carbon dioxide an/or carbon monoxide. Extinguishing Media: Water fog, carbon dioxide, dry chemical, foam. Unusual Fire and Explosion Hazard: None. Special Firefighting Precautions: Do not use streams of water; may spread burning liquid. Firefighting Equipment: Use self-contained breathing apparatus in any enclosed area. Section 6 Accidental Release Measures Small Spills: Absorb with suitable material. Dispose in an appropriate waste container. Large Spills: Dike with soil, and or other suitable materials avoiding the use of sawdust. Recover usable product, rinse area clean. Personal Precautions: No special requirements. Environmental Precautions: No special requirements known. Evco Plastics Product code 2043328 Document 2043328 Page 4351 Return to Index Page 136 of 553 Page 136 of 553 Page 136 of 553 Page 136 of 553 ---PAGE BREAK--- Section 7 Handling & Storage Safe Handling and Hygienic Practices: Avoid prolonged skin contact. Wash after using. Storage Requirements: Store in closed, original container away from flame or other ignition source. Section 8 Exposure Controls Engineering Controls: No special requirements. Personal Protection Ventilation: No Special requirements. Respiratory: Avoid breathing mist. Eye Protection: Eye protection based on splash potential. Clothing: Gloves recommended for sensitive individuals. Exposure Limit Guidelines: None established. Section 9 Physical & Chemical Properties Appearance and Odor: Clear orange color with a citrus odor. Specific Gravity: .786, 6.56 lbs/US gallon. Vapor Density: (Air=1), Vapor Pressure: Not Determined. Evaporation Rate: (BuAc=1) pH of Concentrate: None Solubility in Water: Dispersible. Percent Volatile by Volume: 84%. Section 10 Stability & Reactivity Stability: Stabile. Conditions to Avoid: Avoid contact with oxidizing agents and acids. Hazardous Decomposition: None expected under normal conditions. Hazardous Polymerization: Should not occur. Section 11 Toxicity Information Toxicity: None known. Section 12 Ecological Information Biodegradability: Biodegradable. Other: Liquid is not expected to have acute toxicity to aquatic organisms. Evco Plastics Product code 2043328 Document 2043328 Page 4352 Return to Index Page 137 of 553 Page 137 of 553 Page 137 of 553 Page 137 of 553 ---PAGE BREAK--- Section 13 Disposal Considerations Biodegradability: Biodegradable. RCRA Classification: This product has been evaluated for RCRA characteristics and does not meet the criteria for a hazardous waste, if discarded in its purchased form. Special Instructions: No special requirements. Section 14 Transportation Information DOT Labeling: The combustible liquid n.o.s. label is exempt in container under 110 gallons. Regulation 49CFR 173.118A. Proper Shipping Name: Combustible liquid n.o.s. Hazard Class: Combustible. Class 3 Identification Number: UN 1993. Packing group III Section 15 Regulatory Information CERCLA, State and Local Planning (Reportable Quantities): Not required. OSHA Compliance: This MSDS prepared in accordance with 29CFR 1910.1200 and ANSI Z400.1 standard. SARA Title III Superfund: The product in its purchased form is not regulated under the SARA "Hazard Categories" under Section 311 and 312 of the Superfund Amendment and the Reauthorization Act of 1986 (SARA Title III). State Right-to-Know Compliance: Not required. TSCA: Although components of this product find listing under the Toxic Substances Act (TSCA), this blended product requires no import or export declaration. Volatile Organic Compound (VOC) Content: This product complies with all VOC requirements in all 50 states. Special Instructions: No special requirements. Section 16 Other Information Hazard: (Based on HMIS Standard), Health: 0 Flammability: 2 Reactivity: 0 Hazard Index: Minimal: 0, Slight: 1, Moderate: 2, High: 3, Extreme: 4 We believe the information contained herein is accurate and current as of the date of this Material Safety Data Sheet. Nevertheless, the user must evaluate and determine whether the conditions for use and application of the product, including proper disposal thereof, are appropriate, safe, and legal. Evco Plastics Product code 2043328 Document 2043328 Page 4353 Return to Index Page 138 of 553 Page 138 of 553 Page 138 of 553 Page 138 of 553 ---PAGE BREAK--- MSDS: 501 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: DERMA FLEUR Lotion 22 Corporate Park #2219, 2220 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT NUMBER OSHA (mg/M3) ACGIH (mg/M3) Contains no hazardous ingredients NOTE: This product has been formulated for skin application and is regulated by the FDA as a cosmetic product. Under normal conditions of use, this product is not a hazardous material as defined by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See product label for list of ingredients. Section III - PHYSICAL DATA Boiling Point: N/A Specific Gravity: 1.05 Vapor Pressure: (mm Hg): N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: N/A Solubility In Water: Soluble Appearance and Odor: White lotion, odorless. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None NFPA Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 139 of 553 Page 139 of 553 Page 139 of 553 Page 139 of 553 ---PAGE BREAK--- MSDS: 501 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Eye Contact Health Hazards: Eye contact may cause irritation and redness of the eyes. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: If material gets in eyes, flush thoroughly with water, lifting upper and lower eyelids occasionally. Section VI - REACTIVITY DATA Stability Stability: Stable Incompatibilities: None Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Collect spill with absorbent material and place in sealed container for disposal. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: Not required Ventilation: General mechanical. Protective Equipment: Use eye protection as necessary to prevent excessive contact. Section IX - SPECIAL PRECAUTIONS None N/A = Not applicable N/E = Not established Page 140 of 553 Page 140 of 553 Page 140 of 553 Page 140 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Date Issued: Revised 8/22/2011 Trade Name: Distilled White Vinegar Chemical Name: Dilute Acetic Acid (CH 3COOH) C.A.S. - 8028-52-2 Definition Product made by the acetous fermentation of Ethyl Alcohol to contain 4–10% acetic acid (or 40–100 grain vinegar) Manufacturer’s Name H. J. Heinz Co. And Address: Heinz 57 Center 357 6th Avenue Pittsburgh, Pa 15222-2530 Contact: Customer & Consumer Resource Center Phone Number: 1-[PHONE REDACTED] HEALTH HAZARD DATA INHALATION Threshold Limit Value: 10 ppm Short Term Exposure: 15 ppm for 15 minutes Odor Threshold: 1.0 ppm Prolonged inhalation of vapors can cause irritation to respiration tract. EYES Will cause eye irritation – smarting and reddening of the eye. Page 141 of 553 Page 141 of 553 Page 141 of 553 Page 141 of 553 ---PAGE BREAK--- MSDS: Distilled White Vinegar Page 2. EMERGENCY AND FIRST – AID PROCEDURES In case of eye contact, flush immediately and thoroughly with water for 15–20 minutes (timed by a clock). Call a physician. If swallowed in large amounts, water should be consumed to dilute. Do not induce vomiting. Do not give emetics of baking soda. Call a physician. Stability – GOOD HAZARDOUS POLYMERIZATION WILL NOT OCCUR. SPILL OR LEAK PROCEDURES If vinegar is spilled, water may be used to dilute. PHYSICAL DATA Appearance and Odor Clear liquid, odor of vinegar. Boiling Point: 244 oF Vapor Pressure (MM Hg): 11 MM Vapor Density (Air = 2.1 Solubility in Water: Complete Specific Gravity: 1.01 pH: 2.2 @ 100 Grain Questions? Contact: Ms. Karen White, Senior Manager Government & Regulatory Affairs and Customer & Consumer Resource Center Heinz North America P.O. Box 57 Pittsburgh, PA. 15230 Page 142 of 553 Page 142 of 553 Page 142 of 553 Page 142 of 553 ---PAGE BREAK--- Page 143 of 553 Page 143 of 553 Page 143 of 553 Page 143 of 553 ---PAGE BREAK--- Page 144 of 553 Page 144 of 553 Page 144 of 553 Page 144 of 553 ---PAGE BREAK--- Page 145 of 553 Page 145 of 553 Page 145 of 553 Page 145 of 553 ---PAGE BREAK--- Page 146 of 553 Page 146 of 553 Page 146 of 553 Page 146 of 553 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: DUST MOP / DUST CLOTH TREATMENT (BULK) Product Number: 3013; 3213 Janitorial Spartan Chemical Company , Inc. Product/Technical Information: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spill Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: Non-Hazardous Products NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: 1- Slight Fire: 0 - Minimal Fire: 0 - Minimal Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A Chemical Name(s) %Wt CAS Registry No. TWA mg/m 3 STEL mg/m 3 CEILING mg/m 3 NTP, IARC or OSHA Carcinogen Petroleum distillates *Ethylene glycol Triethanolamine oleate Alcohol ethoxylate 1-5 1-5 1-5 1-5 64742-46-7 107-21-1 2717-15-9 68131-39-5 5 [oil mist] Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established 127 (ACGIH) Not Established Not Established No No No No Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA Boiling Point: 210-212 °F Vapor Pressure: Undetermined Vapor Density (AIR = Unknown Solubility in Water: Forms an emulsion. pH: 8.5-9.5 Specific Gravity (H2O=1): 1.0 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 10-12 Physical State: Liquid Appearance & Odor: Opaque white liquid, fresh fragrance. SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: > 212°F Method Used: ASTM-D56 Flammable Limits: Not Established Flame Extension: N/A Extinguishing Media: Product does not support combustion. Use extinguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. Page 147 of 553 Page 147 of 553 Page 147 of 553 Page 147 of 553 ---PAGE BREAK--- SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- Conditions to Avoid: CAUSES SKIN AND EYE IRRITATION : may include pain, redness and swelling. HARMFUL IF SWALLOWED . may include nausea, vomiting, pain and diarrhea. INHALATION OF SPRAY MIST MAY CAUSE RESPIRATORY IRRITATION. may include nasal discomfort and coughing. Contains ethylene glycol which has been shown to produce birth defects in laboratory animals and may cause kidney and nervous system damage. Avoid contact with eyes, skin or clothing. Do not swallow. Avoid breathing product mist. Avoid contamination of food . Wash thoroughly with soap and water after handling . Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention if irritation persists. Skin: Remove contaminated clothing. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. Inhalation: Move person to fresh air. Get medical attention if irritation persists. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Strong oxidizers Hazardous Decomposition Products: CO, CO2 Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Small spills of one gallon or less may be flushed with plenty of water to sanitary sewer system (If permitted by local sewer regulations). Dike and contain large spills with inert material and transfer liquid to containers for recovery or disposal. Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or other impervious gloves. Eye Protection(Specify Type): Splash goggles are recommended to prevent eye contact. Other Protective Equipment: See 29 CFR 1910.132-138 for further guidance. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Do not contaminate water, food or feed by storage or disposal. Keep from freezing. Other Precautions: Keep out of reach of children. © SCC 06/08/2012 Name: Ronald T. Cook Title: Manager, Regulatory Affairs DUST MOP / DUST CLOTH TREATMENT (BULK) Effective Date: 06/08/2012 Supercedes: 06/08/2009 Ref: 29 CFR 1910.1200 (OSHA) Changes: General Review This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 148 of 553 Page 148 of 553 Page 148 of 553 Page 148 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 31−1013− 11 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER HMIS CODES Health 3 31−1013− Flammability 2 Reactivity 0 PRODUCT NAME DUTCH BOY* Professional Ext. Acrylic Latex Traffic Zone Marking Paint, Yellow MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. DUTCH BOY (216) 566−2917 101 Prospect Avenue N.W. Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 28−OCT−04 (216) 566−2902 Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 3 67−56−1 Methanol ACGIH TLV 200 ppm (Skin) 92 mm ACGIH TLV 250 ppm (Skin) STEL OSHA PEL 200 ppm (Skin) OSHA PEL 250 ppm (Skin) STEL 1 112−34−5 2−(2−Butoxyethoxy)−ethanol ACGIH TLV Not Available 0.06 mm OSHA PEL Not Available 53 471−34−1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 3 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Continued on page 2 Page 149 of 553 Page 149 of 553 Page 149 of 553 Page 149 of 553 ---PAGE BREAK--- 31−1013− page 2 SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL 145 F PMCC 0.9 36.5 FLAMMABILITY CLASSIFICATION Combustible, Flash above 99 and below 200 F EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build−up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 Page 150 of 553 Page 150 of 553 Page 150 of 553 Page 150 of 553 ---PAGE BREAK--- 31−1013− page 3 Section 7 HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IIIA PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are COMBUSTIBLE. Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 Page 151 of 553 Page 151 of 553 Page 151 of 553 Page 151 of 553 ---PAGE BREAK--- 31−1013− page 4 Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 13.35 lb/gal 1599 g/l SPECIFIC GRAVITY 1.61 BOILING POINT 148 − 448 F 64 − 231 C MELTING POINT Not Available VOLATILE VOLUME 40 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) 0.87 lb/gal 104 g/l Less Water and Federally Exempt Solvents 0.59 lb/gal 70 g/l Emitted VOC Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. TOXICOLOGY DATA CAS No. Ingredient Name 67−56−1 Methanol LC50 RAT 4HR 64000 ppm LD50 RAT 5630 mg/kg 112−34−5 2−(2−Butoxyethoxy)−ethanol LC50 RAT 4HR Not Available LD50 RAT 5660 mg/kg 471−34−1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available Continued on page 5 Page 152 of 553 Page 152 of 553 Page 152 of 553 Page 152 of 553 ---PAGE BREAK--- 31−1013− page 5 Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 TRANSPORT INFORMATION No data available. Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element 67−56−1 Methanol 3 Glycol Ethers 1 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 153 of 553 Page 153 of 553 Page 153 of 553 Page 153 of 553 ---PAGE BREAK--- Page 154 of 553 Page 154 of 553 Page 154 of 553 Page 154 of 553 ---PAGE BREAK--- Page 155 of 553 Page 155 of 553 Page 155 of 553 Page 155 of 553 ---PAGE BREAK--- Page 156 of 553 Page 156 of 553 Page 156 of 553 Page 156 of 553 ---PAGE BREAK--- Page 157 of 553 Page 157 of 553 Page 157 of 553 Page 157 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MSDS 81800 Page 1 of 2 Sanford NA Emergency Medical Number: [PHONE REDACTED] 2711 Washington Boulevard Bellwood, IL 60104 Creation Date: October 20, 2003 Phone: [PHONE REDACTED] or [PHONE REDACTED] Section One: Product Information Product Name: Expo Dry Erase Cleaner Colors: Clear Sanford is a member of The Art and Creative Materials Institute, Inc. This product is certified by the Institute to be labeled in accordance with the voluntary chronic hazard labeling standard ASTM D-4236 and is labeled with the CL (Cautionary Label) Seal. Products bearing the CL Seal are certified to be properly labeled in a program of toxicological evaluation by a medical expert for any known health risks and with information on safe and proper use of these materials. Conforms to ASTM D-4236. Section Two: Composition Water, 2-Butoxyethanol (111-76-2), isopropyl alcohol (67-63-0) Section Three: Hazards Identification WARNING: COMBUSTIBLE. VAPOR HARMFUL. MAY BE HARMFUL IF SWALLOWED, OR BY SKIN CONTACT. EYE IRRITANT. CONTAINS: 2-BUTOXYETHANOL, ISOPROPYL ALCOHOL. PRECAUTIONS: Avoid ingestion. Keep away from eyes. Do not store or use near heat or flame. Use only with adequate ventilation. KEEP OUT OF REACH OF CHILDREN. FIRST AID: If eye contact occurs, rinse with tap water for 5-10 minutes. If irritation persists, seek medical care. If skin contact occurs, wash with soap and water for 5 minutes. If swallowed, get prompt medical attention. For further health information, contact a poison control center or call [PHONE REDACTED]. Section Four: First Aid Measures Inhalation: If occur, move to fresh air. Skin Contact: If skin contact occurs, wash with soap and water for 5 minutes. Eye Contact: If eye contact occurs, rinse with tap water for 5-10 minutes. If irritation persists, seek medical care. Ingestion: If swallowed, get prompt medical attention. Section Five: Fire Fighting Measures Flash Point: 105F (TCC) Flammability Limits by volume): Lower: 2.2% (isopropyl alcohol) Upper: Not available Extinguishing Media: As appropriate for surrounding area. Special Fire Fighting Measures: None Unusual Fire and Explosion Hazards: None Section Six: Accidental Release Measures In Case of Spill or Accidental Release: Wipe up with absorbent material. Section Seven: Handling and Storage Handling: Use in a well-ventilated area. Aim nozzle away from eyes. Storage: Do not store or use near heat or flame. Page 158 of 553 Page 158 of 553 Page 158 of 553 Page 158 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MSDS 81800 Page 2 of 2 Section Eight: Exposure Controls and Personal Protection Eye Protection: None under normal use conditions. Avoid prolonged eye contact. Clothing: None under normal use conditions. Respirator: None under normal use conditions. Ventilation: None under normal use conditions. Use in a well ventilated area. Section Nine: Physical and Chemical Properties For product unless otherwise specified: Boiling Point: 180F (isopropyl alcohol) Specific Gravity: 0.96 Vapor Pressure: 33 mg Hg (isopropyl alcohol) Solubility in Water: complete Evaporation Rate: Not available Appearance; Odor: Clear liquid; alcoholic odor Section Ten: Stability and Reactivity Stability: Stable Conditions to Avoid: None known Chemical Incompatibility: Strong oxidizers, acids, isocyanates Hazardous Decomposition: None known Hazardous Polymerization: Will not occur. Section Eleven: Toxicological Information IARC Monographs: No National Toxicology Program: No OSHA Regulated: No Section Twelve: Ecological Information Not available Section Thirteen: Disposal Considerations Dispose in accordance with Federal, State, and Local Regulations. Section Fourteen: Transport Information ORM-D Consumer Commodity Flammable Liquid, n.o.s. (isopropanol), 3, UN1993, PGIII (105F TCC), Ltd. Qtys, EmS#3-07 Consumer Commodity, 9, ID8000, packing instruction 910 Section Fifteen: Regulatory Information TSCA INVENTORY: The product on this Material Safety Data Sheet is not listed on the Toxic Substances Control Act Inventory. All ingredients used to manufacture this product are listed on the TSCA Inventory . Section Sixteen: Other Information HMIS Code Health 2 Flammability 2 Reactivity 0 Personal Protection H Sanford NA has been advised by Counsel that the OSHA Hazard Communication Standard does not apply to the Sanford Product described in this Material Safety Data Sheet. The reason for the exemption is contained in 29 CFR 1910.1200(b)(6)(ix) as amended July 1, 2002 per the Code of Federal Regulations. The information contained in this MSDS is forwarded to you for your information, but is not meant to imply that the product is covered by the Hazard Communication Standard nor is this MSDS meant to comply with all requirements of the Hazard Communication Standard. 0=Minimal / 4 = Severe Page 159 of 553 Page 159 of 553 Page 159 of 553 Page 159 of 553 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 29-Jul-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83570 Product name Expunge Recommended Use Paint Remover Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Inhalation. Eyes. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Reddening. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Exposure to vapors may cause the following effects. Irritating to respiratory system. Headaches. Dizziness. Nausea. Loss of coordination. Extreme overexposure may cause. Central nervous system depression. Cardiac abnormalities. Liver damage. Reproductive system damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Toluene 108-88-3 30-60 Propane 74-98-6 10-30 Diacetone alcohol 123-42-2 5-10 Butane 106-97-8 5-10 Isopropyl alcohol 67-63-0 1-5 Acetone 67-64-1 1-5 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Ingestion Do Not induce vomiting. Immediate medical attention is required. Inhalation Remove to fresh air. Restore breathing. Keep warm and quiet. 5. FIRE FIGHTING MEASURES Flash point °C < -17.78 Flash point °F < 0 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 1.0 Specific Information for Aerosol Products Flame extension 40" without extension tube Flashback Yes Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Flash back possible over considerable distance. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. Page 1 / 4 Emergency Overview Extremely flammable. Contents under pressure. Irritant. Page 160 of 553 Page 160 of 553 Page 160 of 553 Page 160 of 553 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Vapors may accumulate readily and may ignite explosively. Ensure adequate ventilation. Avoid breathing spray mist. Do not smoke. Turn off other sources of ignition prior to use and until all vapors have dissipated. Do not puncture or incinerate. Do not take internally. Keep out of reach of children. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Standard safety precautions should be observed when handling this material. Storage Containers exposed to extreme heat may burst. Keep away from heat and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Keep away from direct sunlight. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Toluene 200 ppm 300 ppm 20 ppm - Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Diacetone alcohol 50 ppm 240 mg/m3 - 50 ppm - Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Consult OSHA standard 1910.94, 1910.107, 1910.108. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Gloves are not required in normal use. The following gloves are recommended for prolonged or repeated contact: . Chemical resistant gloves. Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions Other Protective Equipment An eye wash station should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor No information available Odor Threshold No information available pH 7.0 Specific Gravity 0.80 Vapor pressure No data available Density 6.65 lb/gal; 796 g/l Vapor density >Air Evaporation Rate >1 (Ether Water solubility No data available VOC Content 71.66% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 172 Boiling point/range °F < 0 - 342 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17.78 Flash point °F < 0 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None known. Page 2 / 4 Product name Expunge Product code 83570 Page 161 of 553 Page 161 of 553 Page 161 of 553 Page 161 of 553 ---PAGE BREAK--- Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Diacetone alcohol 123-42-2 4 g/kg - - Acetone 67-64-1 - - 50100 mg/m3 Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity Possible risk of harm to the unborn fetus. Target Organ Effects See Section 2. Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 Not Listed Not Listed Not Listed Not Listed Isopropyl alcohol A4 Not Listed Not Listed Not Listed Not Listed Diacetone alcohol Not Listed Not Listed Not Listed Not Listed Not Listed Acetone A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Ecotoxicity effects No information available 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Consumer commodity, ORM-D. This product meets the "Limited quantity" exemption TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity, ORM-D. This product meets the "limited quantity" exemption 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane Listed Listed Not Listed Butane Listed Listed Not Listed Toluene Listed Listed Development al Female Reproductive Isopropyl alcohol Listed Listed Not Listed Diacetone alcohol Listed Listed Not Listed Page 3 / 4 Product name Expunge Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Acetone Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Toluene Isopropyl alcohol Product code 83570 Page 162 of 553 Page 162 of 553 Page 162 of 553 Page 162 of 553 ---PAGE BREAK--- Chemical Name New Jersey - RTK - RTK California Prop. 65 Acetone Not Listed Listed Not Listed Chemical Name Type Toluene - 108-88-3 Female Reproductive WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane X X - X Butane X X - X Toluene X X - X Isopropyl alcohol X X - X Diacetone alcohol X X - X Acetone X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 * Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name Expunge Product code 83570 Page 163 of 553 Page 163 of 553 Page 163 of 553 Page 163 of 553 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 03-Feb-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83570 Product name Expunge Recommended Use Paint Remover Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Inhalation. Eyes. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Reddening. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Exposure to vapors may cause the following effects. Irritating to respiratory system. Headaches. Dizziness. Nausea. Loss of coordination. Extreme overexposure may cause. Central nervous system depression. Cardiac abnormalities. Liver damage. Reproductive system damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Toluene 108-88-3 30-60 Propane 74-98-6 10-30 Diacetone alcohol 123-42-2 5-10 Butane 106-97-8 5-10 Isopropyl alcohol 67-63-0 1-5 Acetone 67-64-1 1-5 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting. Call a physician or Poison Control Center immediately. Inhalation Remove to fresh air. Restore breathing. Keep warm and quiet. 5. FIRE FIGHTING MEASURES Flash point °C < -17.78 Flash point °F < 0 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 1.0 Specific Information for Aerosol Products Flame extension 40" without extension tube Flashback Yes Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Extremely flammable. Contents under pressure. Irritant. Page 164 of 553 Page 164 of 553 Page 164 of 553 Page 164 of 553 ---PAGE BREAK--- Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Flash back possible over considerable distance. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Vapors may accumulate readily and may ignite explosively. Ensure adequate ventilation. Avoid breathing spray mist. Do not smoke. Turn off other sources of ignition prior to use and until all vapors have dissipated. Do not puncture or incinerate. Do not take internally. Keep out of reach of children. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Standard safety precautions should be observed when handling this material. Storage Containers exposed to extreme heat may burst. Keep away from heat and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Keep away from direct sunlight. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Toluene 200 ppm 300 ppm 20 ppm - Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Diacetone alcohol 50 ppm 240 mg/m3 - 50 ppm - Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Gloves are not required in normal use. The following gloves are recommended for prolonged or repeated contact: . Chemical resistant gloves. Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor No information available Odor Threshold No information available pH No data available Specific Gravity 0.80 Vapor pressure No data available Density 6.65 lb/gal; 796 g/l Vapor density >Air Evaporation Rate >1 (Ether Water solubility No data available VOC Content 71.70% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 172 Boiling point/range °F < 0 - 342 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17.78 Flash point °F < 0 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None known. Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Page 2 / 4 Product code 83570 Product name Expunge Page 165 of 553 Page 165 of 553 Page 165 of 553 Page 165 of 553 ---PAGE BREAK--- Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Diacetone alcohol 123-42-2 4 g/kg - - Acetone 67-64-1 - - 50100 mg/m3 Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity Possible risk of harm to the unborn fetus. Target Organ Effects See Section 2. Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 Not Listed Not Listed Not Listed Not Listed Isopropyl alcohol A4 Not Listed Not Listed Not Listed Not Listed Diacetone alcohol Not Listed Not Listed Not Listed Not Listed Not Listed Acetone A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Do not let product enter drains. Harmful to aquatic organisms 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane Listed Listed Not Listed Butane Listed Listed Not Listed Toluene Listed Listed Development al Female Reproductive Isopropyl alcohol Listed Listed Not Listed Diacetone alcohol Listed Listed Not Listed Acetone Not Listed Listed Not Listed Chemical Name Type Toluene - 108-88-3 Female Reproductive Page 3 / 4 Acetone Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Toluene Isopropyl alcohol Product name Expunge Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Product code 83570 Page 166 of 553 Page 166 of 553 Page 166 of 553 Page 166 of 553 ---PAGE BREAK--- WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane X X - X Butane X X - X Toluene X X - X Isopropyl alcohol X X - X Diacetone alcohol X X - X Acetone X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 83570 Product name Expunge Page 167 of 553 Page 167 of 553 Page 167 of 553 Page 167 of 553 ---PAGE BREAK--- MSDS: 401 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Eye Wash 22 Corporate Park #602, 605, 606, 2629 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT % NUMBER OSHA (mg/M3) ACGIH (mg/M3) Contains no hazardous ingredients NOTE: This product has been formulated for ophthalmic application and is regulated by the FDA as a drug product. Under normal conditions of use, this product is not a hazardous material as defined by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section III - PHYSICAL DATA Boiling Point: 215 F Specific Gravity: 1.02 Vapor Pressure: (mm Hg): N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: N/A Solubility In Water: Soluble Appearance and Odor: Clear, colorless, odorless liquid. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None NFPA Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 168 of 553 Page 168 of 553 Page 168 of 553 Page 168 of 553 ---PAGE BREAK--- MSDS: 401 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Ingestion Health Hazards: Ingestion of large quantities may cause gastric disturbances. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: If a large quantity has been ingested, contact a physician immediately. Ingredients are listed on the product label. Section VI - REACTIVITY DATA Stability: Stable Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Incompatibilities: None Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Cover with absorbent material, collect in suitable container. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: None required under normal conditions. Ventilation: General mechanical. Protective Equipment: Not generally required. Section IX - SPECIAL PRECAUTIONS None N/A = Not applicable N/E = Not established Page 169 of 553 Page 169 of 553 Page 169 of 553 Page 169 of 553 ---PAGE BREAK--- MSDS: 402 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Eye/Skin Buffered Flushing Solution 22 Corporate Park #608, 612 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT % NUMBER OSHA (mg/M3) ACGIH (mg/M3) Contains no hazardous ingredients NOTE: This product has been formulated for direct application to skin and eyes and is regulated by the FDA as a drug product. Under normal conditions of use, this product is not a hazardous material as defined by the OSHA Hazard Communication Standard (29 CFR 1910.1200). List of ingredients may be found on product label. Section III - PHYSICAL DATA Boiling Point: 215 F Specific Gravity: 1.02 Vapor Pressure: (mm Hg): N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: N/A Solubility In Water: Soluble Appearance and Odor: Clear, colorless, odorless liquid. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None NFPA Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 170 of 553 Page 170 of 553 Page 170 of 553 Page 170 of 553 ---PAGE BREAK--- MSDS: 402 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Ingestion Health Hazards: Ingestion of large quantities may cause gastric disturbances. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: If a large quantity has been ingested, contact a physician immediately. Ingredients are listed on the product label. Section VI - REACTIVITY DATA Stability: Stable Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Incompatibilities: None Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Cover with absorbent material, collect in suitable container. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: None required under normal conditions. Ventilation: General mechanical. Protective Equipment: Not generally required. Section IX - SPECIAL PRECAUTIONS None N/A = Not applicable or not available N/E = Not established Page 171 of 553 Page 171 of 553 Page 171 of 553 Page 171 of 553 ---PAGE BREAK--- MSDS: 402 MATERIAL SAFETY DATA SHEET REV. DATE: 6/08 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Eye/Skin Buffered Flushing Solution 22 Corporate Park #608, 612 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT % NUMBER OSHA (mg/M3) ACGIH (mg/M3) Contains no hazardous ingredients NOTE: This product has been formulated for direct application to skin and eyes and is regulated by the FDA as a drug product. Under normal conditions of use, this product is not a hazardous material as defined by the OSHA Hazard Communication Standard (29 CFR 1910.1200). List of ingredients may be found on product label. Section III - PHYSICAL DATA Boiling Point: 215° F Specific Gravity: 1.02 Vapor Pressure: (mm Hg): N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: N/A Solubility In Water: Soluble Appearance and Odor: Clear, colorless, odorless liquid. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None NFPA Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 172 of 553 Page 172 of 553 Page 172 of 553 Page 172 of 553 ---PAGE BREAK--- MSDS: 402 MATERIAL SAFETY DATA SHEET REV. DATE: 6/08 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Ingestion Health Hazards: Ingestion of large quantities may cause gastric disturbances. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: If a large quantity has been ingested, contact a physician immediately. Ingredients are listed on the product label. Section VI - REACTIVITY DATA Stability: Stable Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Incompatibilities: None Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Cover with absorbent material, collect in suitable container. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: None required under normal conditions. Ventilation: General mechanical. Protective Equipment: Not generally required. Section IX - SPECIAL PRECAUTIONS None N/A = Not applicable or not available N/E = Not established Page 173 of 553 Page 173 of 553 Page 173 of 553 Page 173 of 553 ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- FIRST MARK ALL PURPOSE PINE CLEANER 912266-01 EMERGENCY HEALTH INFORMATION: 1-[PHONE REDACTED] 05-February-2010 Material Safety Data Sheet Trade name Supplier Code Date of issue Section 1. Chemical product and company identification FIRST MARK ALL PURPOSE PINE CLEANER : : : Performance Food Group 12500 West Creek Pkwy Richmond, VA 23238 (888) 311-7372 ~ Fax (804) 784-0576 Product use : All Purpose Cleaner Section 2. Hazards identification Physical state Emergency overview Liquid. [Liquid.] WARNING ! CAUSES EYE IRRITATION. Avoid contact with eyes. Wash thoroughly after handling. : : Potential acute health effects No known significant effects or critical hazards. Severely irritating to eyes. No known significant effects or critical hazards. irritating to the skin. Eyes Skin Inhalation Ingestion : : : : See toxicological information (section 11) Section 3. Composition/information on ingredients Name BUTOXYETHANOL 111-76-2 1 CAS number % by weight SODIUM XYLENE SULFONATE 1300-72-7 1 - 5 alcohols, c10-14, ethoxylated 66455-15-0 1 - 5 pine oil 8002-09-3 1 - 5 Do not induce vomiting. Never give anything by mouth to an unconscious person. If irritation persists, get medical attention. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if irritation occurs. In case of contact, immediately flush skin with plenty of water. Get medical attention if irritation persists. If inhaled, remove to fresh air. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : > 100°C Section 5. Fire-fighting measures Flash point : Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides Use an extinguishing agent suitable for the surrounding fire. Hazardous thermal decomposition products Fire-fighting media and instructions : : Page 178 of 553 Page 178 of 553 Page 178 of 553 Page 178 of 553 ---PAGE BREAK--- FIRST MARK ALL PURPOSE PINE CLEANER Page: 2/4 Dike area of fire to prevent runoff. In a fire or if heated, a pressure increase will occur and the container may burst. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : No special measures required. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain it to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Environmental precautions Section 6. Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Personal precautions : Methods for cleaning up : Keep out of reach of children. Keep container in a cool, well-ventilated area. Keep container closed. Avoid contact with eyes. Wash thoroughly after handling. Section 7. Handling and storage Handling Storage : : Store between the following temperatures: 0 and 50°C BUTOXYETHANOL ACGIH TLV (United States, 1/2009). TWA: 20 ppm 8 hour(s). OSHA PEL (United States, 11/2006). Absorbed through skin. TWA: 240 mg/m³ 8 hour(s). TWA: 50 ppm 8 hour(s). Section 8. Exposure controls/personal protection Name Exposure limits Personal protection : A respirator is not needed under normal and intended conditions of product use. No special protection is required. No protective equipment is needed under normal use conditions. Eyes Skin Respiratory : : : Wear protective gloves. Hands : : Engineering measures Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Liquid. [Liquid.] 11 to 13 [Conc. w/w): 100%] 1.02 to 1.04 Fragrance-like. Brown. [Dark] Section 9. Physical and chemical properties Physical state pH Relative density Viscosity Solubility Odor Color : : : : : : : Dynamic: 4 cP Easily soluble in the following materials: cold water and hot water. The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Section 10. Stability and reactivity Stability : Extremely reactive or incompatible with the following materials: organic materials and moisture. reactive or incompatible with the following materials: acids and alkalis. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Hazardous decomposition products Hazardous polymerization : : : Under normal conditions of storage and use, hazardous polymerization will not occur. Reactivity Page 179 of 553 Page 179 of 553 Page 179 of 553 Page 179 of 553 ---PAGE BREAK--- FIRST MARK ALL PURPOSE PINE CLEANER Page: 3/4 Section 11. Toxicological information Potential chronic health effects Contains material which may cause damage to the following organs: blood, kidneys, liver, system, upper respiratory tract, central nervous system (CNS). Target organs : Potential acute health effects No known significant effects or critical hazards. Severely irritating to eyes. No known significant effects or critical hazards. irritating to the skin. Eyes Skin Inhalation Ingestion : : : : Other adverse effects Section 12. Ecological information Ecotoxicity data : Not reported The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste disposal Section 13. Disposal considerations : Consult your local or regional authorities. Section 14. Transport information See shipping documents for specific transportation information. UN Classification Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. Not regulated. Irritating material Target organ effects HCS Classification Section 15. Regulatory information SARA 313 Form R - Reporting requirements BUTOXYETHANOL 111-76-2 1 : : Product name CAS number Concentration U.S. Federal regulations California Prop. 65 : No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 extremely hazardous substances: No products were found. All components are listed or exempted. TSCA 8(b) inventory : Date of issue 05-February-2010. : Responsible name : Regulatory Affairs Hazardous Material Information System 2 0 0 * Flammability Physical hazards : Section 16. Other information Health Page 180 of 553 Page 180 of 553 Page 180 of 553 Page 180 of 553 ---PAGE BREAK--- FIRST MARK ALL PURPOSE PINE CLEANER Page: 4/4 Section 16. Other information Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Date of previous issue 16-July-2009. : Page 181 of 553 Page 181 of 553 Page 181 of 553 Page 181 of 553 ---PAGE BREAK--- Page 182 of 553 Page 182 of 553 Page 182 of 553 Page 182 of 553 ---PAGE BREAK--- Page 183 of 553 Page 183 of 553 Page 183 of 553 Page 183 of 553 ---PAGE BREAK--- Page 184 of 553 Page 184 of 553 Page 184 of 553 Page 184 of 553 ---PAGE BREAK--- Page 185 of 553 Page 185 of 553 Page 185 of 553 Page 185 of 553 ---PAGE BREAK--- The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000 Material Safety Data Sheet I Product: FORMULA 409 ALL PURPOSE CLEANER Description: GREEN LIQUID Other Designations Distributor Emergency Telephone Nos. All Purpose Cleaner Misty Breeze Fragrance Lemon Fresh Fragrance Clorox Sales Company 1221 Broadway Oakland, CA 94612 For Medical Emergencies call: (800) 446-1014 For Transportation Emergencies Chemtrac (800) 424-9300 II Health Hazard Data III Hazardous Ingredients CAUTION: EYE IRRITANT. Avoid eye and prolonged skin contact. Do Not ingest FIRST AID: EYE CONTACT: Immediately flush eyes with plenty of water. If irritation persists, see a doctor. SKIN CONTACT: Wash with water. Seek medical attention if irritation develops or persists. INGESTION: Drink a glass full of water. Call Physician. Do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. INHALATION: If breathing problems develop remove to fresh air. Seek medical attention if respiratory irritation develops or breathing becomes difficult. KEEP OUT OF REACH OF CHILDREN Ingredients Concentration Worker Exposure Limit Alkyl (C1240%; C1450% 0.3% Not Established C1610%) dimethyl benzyl Ammonium chloride CAS# 68424-85-1 Ethylene Glycol 0.5-5% 25 ppm TLV-TWA Monobutyl Ether 25 ppm PEL CAS # 111-76-2 Substance can be absorbed through the skin and may contribute to overall exposure. None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists. TLV - TWA - Threshold Limit Value - Time Weighted Average. Source: ACGIH 1985-86. PEL - Permissible Exposure Limit. Source: OSHA IV Special Protection and Precautions V Transportation and Regulatory Data Hygienic Practices: Wear safety glasses. With repeated or prolonged use, wear gloves. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist. Work Practices: Minimize skin contact and inhalation of vapor or mist. Not recommended for use on soft vinyl, varnishes or aluminum. If sprayed on these surfaces, rinse and wipe dry immediately. U.S. DOT Hazard Class: Not restricted U.S. DOT Proper Shipping Name:.Not restricted. EPA - SARA Title III/CERCLA: Bottled product is not reportable under Sections 311/312; contains chemicals regulated under Section 313 (ethylene oxide = trace, glycol ethers < and contains chemicals (glycol ethers < ethylenediaminetetracetic acid < 1.0%, ethylene oxide = trace, and sodium hydroxide < 0.5%) which are regulated under Section 304/CERCLA. TSCA Status: All components of this product are on the TSCA Inventory VOC Content: 48 g/L (EPA Method 24) VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations. Stable under normal use and storage conditions. VIII Fire and Explosion Data IX Physical Data Flash Point: >200F Fire Extinguishing Agents: Foam, Dry Chemical, Water, CO2 Unusual Fire and Explosion Hazards: Products of combustion are toxic Solubility in complete Specific Gravity 1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 3/01 Page 186 of 553 Page 186 of 553 Page 186 of 553 Page 186 of 553 ---PAGE BREAK--- FSCA6, FSRM6, FSFV6, FSOB6 SPLASH SCENTS 1 RPS Products, Inc. 281 Keyes Avenue Hampshire, IL 60140 ([PHONE REDACTED]) MATERIAL SAFETY DATA SHEET A. Identification and Emergency Information Product Identity: FSCA6, FSRM6, FSFV6, FSOB6 SPLASH SCENTS Emergency Telephone Numbers: R.P.S. Products [PHONE REDACTED] Chemtrec [PHONE REDACTED] B. Components and Hazard Information Hazardous Components (Specific Chemical Identity) (Common name(s)) CAS Number OSHA PEL ACGIH TLV %Percent Sodium EDTA 64-02-8 N.K. N.K. N.A. C. Emergency and First Aid Procedures Eye Contact Flush eyes with plenty of flowing water for 15 minutes lifting upper and lower lids. Remove contact lenses if applicable. Seek medical attention. Skin Contact Wash with plenty of soap and water. If irritation develops, seek medical attention. Inhalation If overcome by vapor, remove person to fresh air. If breathing is irregular or has stopped, start resuscitation, administer oxygen if available. Ingestion If ingested, MAY CAUSE ABDOMINAL IRRITATION, NAUSEA, VOMITING, AND DIARREHEA. Seek medical attention immediately. INDUCE VOMITING. Mouth may be rinsed with water. NEVER give anything by mouth to unconscious person. Page 187 of 553 Page 187 of 553 Page 187 of 553 Page 187 of 553 ---PAGE BREAK--- FSCA6, FSRM6, FSFV6, FSOB6 SPLASH SCENTS 2 D. Fire and Explosion Hazard Information Flash Point: N/A Method Used: N/A (NFPA) National Fire Protection Association- Hazard Information Health-0 Flammability-0 Reactivity-0 Handling Precautions Use only with adequate ventilation. Wear OSHA standard goggles or face shield. Consult Safety Equipment Supplier. Wear gloves, apron and footwear impervious to this material. Empty Container Warning ~Empty~ containers retain residue (liquid and/or vapor). DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. ~Empty~ drums should be completely drained, properly bunged and should be disposed of in an environmentally safe manner and in accordance with governmental regulations. E. Health and Hazard Information Effects of Overexposure: (Signs and of Exposure) Eye Contact Product contacting the eyes may cause redness, tearing, and irritation. Rinse eyes thoroughly for 15 minutes. Seek medical attention. Skin Contact Contact with skin may cause slight skin irritation or rash if not washed immediately. Inhalation After high vapor exposure, remove to fresh air. If breathing if difficult, give oxygen. If breathing has stopped give artificial respiration. Ingestion If swallowed, call physician immediately! Induce vomiting following physician’s instructions. F. Physical Data The following data are approximate or typical values and should be used for precise design purposes. Page 188 of 553 Page 188 of 553 Page 188 of 553 Page 188 of 553 ---PAGE BREAK--- FSCA6, FSRM6, FSFV6, FSOB6 SPLASH SCENTS 3 Boiling Range 100 101 101*deg. C/212 214 214*deg. F (*=end point) API Gravity 8.8 Specific Gravity (Water=1) 1.008 Pounds/Gallon 8.400 Vapor Pressure (mm of HG)@20 C 16.4 Vapor Density (Air=1) 0.6 Water Absorption Appreciable Acid Absorption (85% H2SO4) Complete Dry Time (Ether=1) Long % Volatile by VOL 93.5 Appearance Clear, Red or Blue Odor Mild HKB (Hydrogen Bonding) 88.8 PKB (Polarity) 5.6 DKB (Dispersion) 5.6 Refractive Index 1.333 G. Reactivity This product is considered stable. H. Spill or Leak Procedures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Materials should be swept up for salvage or disposal. Remaining residue may be flushed with water. Dispose of in accordance with all local, state, and federal regulations. I. Protection and Precautions Ventilation: Use local exhaust to capture excessive vapor, mists or fumes. Respiratory Protection: Use supplied-air respiratory protection in confined or enclosed spaces. Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact. Eye Protection: Use splash goggles or face shield when eye contact may occur. Work Practices/Engineering Controls: Keep container closed and upright when not in use to prevent leakage. Page 189 of 553 Page 189 of 553 Page 189 of 553 Page 189 of 553 ---PAGE BREAK--- FSCA6, FSRM6, FSFV6, FSOB6 SPLASH SCENTS 4 Personal Hygiene: Cleanse skin thoroughly after contact, before breaks and meals, and at end of work period. Remove contaminated clothing and shoes and thoroughly clean before reuse. Maintain good personal hygiene. J. Transportation Information For further information relative to spills resulting from transportation incidents, refer to latest Department of Transportation Emergency Response Guidebook for Hazardous Materials Incidents. Description Non hazardous Non regulated material Legal responsibility is assumed only for the fact that all studies reported are those of qualified experts. Buyer assumes all risk and liability. He accepts and uses this material on these conditions. He must keep a copy of this MSDS where material is handled. N. A. (not applicable) N. D. (not determined) DATE 10/1/2005 RPS Products (herein called RPS) has been asked to supply the attached Material Safety Data Sheet (“MSDS”) despite the fact that some of the data contained therein is based on information supplied to RPS by third parties and the fact that RPS cannot anticipate all of the conditions of use and application with the respect to the product described in the MSDS. Although RPS has made a good faith effort in filling out the MSDS and believes the information, data and suggestions contained therein to be reliable, RPS DOES NOT WARRANT OR GUARANTEE THE COMPLETENESS OR THE ACCURACY OF THE DATA CONTAINED IN THE MSDS. RPS DISCLAIMS ANY AND ALL RESPONSIBILITY FOR ANY USE OF OR RELIANCE ON SUCH DATA. Page 190 of 553 Page 190 of 553 Page 190 of 553 Page 190 of 553 ---PAGE BREAK--- Page 191 of 553 Page 191 of 553 Page 191 of 553 Page 191 of 553 ---PAGE BREAK--- Page 192 of 553 Page 192 of 553 Page 192 of 553 Page 192 of 553 ---PAGE BREAK--- Page 193 of 553 Page 193 of 553 Page 193 of 553 Page 193 of 553 ---PAGE BREAK--- Page 194 of 553 Page 194 of 553 Page 194 of 553 Page 194 of 553 ---PAGE BREAK--- Page 195 of 553 Page 195 of 553 Page 195 of 553 Page 195 of 553 ---PAGE BREAK--- Page 196 of 553 Page 196 of 553 Page 196 of 553 Page 196 of 553 ---PAGE BREAK--- Page 197 of 553 Page 197 of 553 Page 197 of 553 Page 197 of 553 ---PAGE BREAK--- Page 198 of 553 Page 198 of 553 Page 198 of 553 Page 198 of 553 ---PAGE BREAK--- Page 199 of 553 Page 199 of 553 Page 199 of 553 Page 199 of 553 ---PAGE BREAK--- Page 200 of 553 Page 200 of 553 Page 200 of 553 Page 200 of 553 ---PAGE BREAK--- Page 201 of 553 Page 201 of 553 Page 201 of 553 Page 201 of 553 ---PAGE BREAK--- Page 202 of 553 Page 202 of 553 Page 202 of 553 Page 202 of 553 ---PAGE BREAK--- Page 203 of 553 Page 203 of 553 Page 203 of 553 Page 203 of 553 ---PAGE BREAK--- MSDS: 204 MATERIAL SAFETY DATA SHEET REV. DATE: 10/09 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Hydrogen Peroxide 22 Corporate Park #206, 209, 211, 212 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT % NUMBER OSHA (ppm) ACGIH (ppm) Hydrogen peroxide 3 7722-84-1 1 1 Section III - PHYSICAL DATA Boiling Point: 212 F Specific Gravity: 1.00 Vapor Pressure: (mm Hg): N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: 1 Solubility In Water: Soluble Appearance and Odor: Clear, colorless, odorless liquid. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None NFPA Hazard Rating: Health: 1 Flammability: 0 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 1 Flammability: 0 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 204 of 553 Page 204 of 553 Page 204 of 553 Page 204 of 553 ---PAGE BREAK--- MSDS: 204 MATERIAL SAFETY DATA SHEET REV. DATE: 10/09 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Eye contact, ingestion Health Hazards: Eye contact may result in redness, irritation, and possible eye damage. Ingestion may cause gastric disturbances, including liberation of oxygen gas. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: Eye contact: Flush immediately with large amounts of water. If redness or irritation persists, contact a physician. Ingestion: Give large amounts of water, induce vomiting and contact a physician immediately. Section VI - REACTIVITY DATA Stability: Stable Incompatibilities: None Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Dilute with water. Flush into sewer. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: Generally not required. If TLV or PEL is exceeded, use NIOSH approved supplied-air respirator. Ventilation: Local exhaust may be required if TLV or PEL is exceeded. Protective Equipment: Eye protection and protective clothing as necessary to prevent excessive contact. Section IX - SPECIAL PRECAUTIONS None N/A = Not applicable N/E = Not established Page 205 of 553 Page 205 of 553 Page 205 of 553 Page 205 of 553 ---PAGE BREAK--- MSDS: 204 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Hydrogen Peroxide 22 Corporate Park #206, 209, 211, 212 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT % NUMBER OSHA (ppm) ACGIH (ppm) Hydrogen peroxide 3 7722-84-1 1 1 Section III - PHYSICAL DATA Boiling Point: 212 F Specific Gravity: 1.00 Vapor Pressure: (mm Hg): N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: 1 Solubility In Water: Soluble Appearance and Odor: Clear, colorless, odorless liquid. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None NFPA Hazard Rating: Health: 1 Flammability: 0 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 1 Flammability: 0 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 206 of 553 Page 206 of 553 Page 206 of 553 Page 206 of 553 ---PAGE BREAK--- MSDS: 204 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Eye contact, ingestion Health Hazards: Eye contact may result in redness, irritation, and possible eye damage. Ingestion may cause gastric disturbances, including liberation of oxygen gas. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: Eye contact: Flush immediately with large amounts of water. If redness or irritation persists, contact a physician. Ingestion: Give large amounts of water, induce vomiting and contact a physician immediately. Section VI - REACTIVITY DATA Stability: Stable Incompatibilities: None Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Dilute with water. Flush into sewer. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: Generally not required. If TLV or PEL is exceeded, use NIOSH approved supplied-air respirator. Ventilation: Local exhaust may be required if TLV or PEL is exceeded. Protective Equipment: Eye protection and protective clothing as necessary to prevent excessive contact. Section IX - SPECIAL PRECAUTIONS None N/A = Not applicable N/E = Not established Page 207 of 553 Page 207 of 553 Page 207 of 553 Page 207 of 553 ---PAGE BREAK--- MSDS: 305 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: Instant Cold Spray 22 Corporate Park #2325 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT NUMBER OSHA (ppm) ACGIH (ppm) n-Butane 106-97-8 800 800 Isopentane 78-78-4 N/E N/E Section III - PHYSICAL DATA Boiling Point: 31 F Specific Gravity: 0.580 Vapor Pressure: (mm Hg): 1639 Melting Point: -138 C Vapor Density: >1 Evaporation Rate: >1 Solubility In Water: Negligible Appearance and Odor: Clear, colorless gas with light hydrocarbon odor. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: -100 F Flammability Limits in Air by Volume): LEL = 1.4%, UEL = 9.5% Extinguishing Media: Carbon dioxide, foam, dry chemical. Special Fire Fighting Procedures: Use water spray to cool containers. Unusual Fire and Explosion Hazards: Containers generate pressure when heated, causing violent bursting and dangerous propelling of containers. NFPA Hazard Rating: Health: 1 Flammability: 4 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 1 Flammability: 4 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 208 of 553 Page 208 of 553 Page 208 of 553 Page 208 of 553 ---PAGE BREAK--- MSDS: 305 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Skin contact, inhalation. Health Hazards: Simple May cause dizziness, disorientation, headache, excitation, central nervous system depression, and anesthesia if exposure limits are exceeded. Skin contact may cause freeze burns. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: Skin contact: For freeze burns, warm the affected area by immersing in warm (not hot) water or by covering with blanket or clothing. Seek medical assistance if necessary. Inhalation: Move to fresh air at once. If breathing has stopped, perform artificial respiration and contact a physician immediately. Section VI - REACTIVITY DATA Stability: Stable Hazardous Polymerization: Will not occur Hazardous Decomposition Products: Toxic gases may be released during fire. Incompatibilities: Oxygen, strong oxidizers. Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Remove all sources of ignition. Ventilate area throughly. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: If TLV or PEL is exceeded, use NIOSH approved supplied air respirator. Ventilation: General mechanical. Local exhaust may be required if TLV or PEL is exceeded. Protective Equipment: Generally not required. Section IX - SPECIAL PRECAUTIONS Do not store near heat sources such as radiators, open flames, stoves, heaters, etc. Keep in cool dry place at temperature below 130 F. Do not incinerate cans. Do not puncture containers. Do not spray near flame or while smoking. Use only as directed on label. N/A = Not applicable N/E = Not established Page 209 of 553 Page 209 of 553 Page 209 of 553 Page 209 of 553 ---PAGE BREAK--- Material Safety Data Sheet Page 1 of 3 (Essentially similar to Form OSHA-174 / 29 CFR 1910.1200) Product name: InstantFOAM Alcohol Hand Sanitizer Revision Date: 03.07.2011 Supersedes Revision: 08.23.2010 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: InstantFOAM ALCOHOL HAND SANITIZER Product code: IFS1L, IFS1TF, IFS400ML, IFS50ML Use of substance / preparation: Foaming hand sanitizer Company name: Deb USA, Inc. 1100 South Highway 27 Stanley, North Carolina 28164 Tel: [PHONE REDACTED] Fax: [PHONE REDACTED] Web: www.debgroup.com 2. HAZARDS INDENTIFICATION Main hazards: Highly flammable. 3. COMPOSITION / INFORMATION ON INGREDIENTS Contains: ACTIVE INGREDIENT CAS NUMBER WEIGHT, % Ethyl Alcohol 64-17-5 72 INACTIVE INGREDIENTS Water 7732-18-5 n-Propanol 71-23-8 Coco-Glucoside 141464-42-8 Glyceryl Oleate 68424-61-3 PEG-7 Glyceryl Cocoate 68201-46-7 PEG-200 Hydrogenated Glyceryl Palmate 67784-88-7 Dihydroxypropyl PEG-5 Linoleammonium Chloride 168677-75-6 Behentrimonium Chloride 17301-53-0 Bis-PEG-12 Dimethicone 102783-01-7 4. FIRST AID MEASURES 4. FIRST AID MEASURES Skin contact: Not Applicable Eye contact: There may be irritation and redness. Ingestion: There may be soreness and redness of the mouth and throat. Inhalation: Fumes or vapor may cause irritation, nausea or drowsiness. FIRST AID MEASURES (ACTIONS) Skin contact: Not applicable Eye contact: Wash immediately with clean water for at least 10 minutes, while lifting eye lids. If any soreness or irritation persists seek medical advice. Ingestion: Wash out mouth with water. Do not induce vomiting. Seek medical attention. Inhalation: Remove to fresh air and seek medical advice if persist. 5. FIRE-FIGHTING MEASURES Extinguishing media: Carbon dioxide, alcohol resistant foam, dry chemical powder. Do not use water. Protection of fire-fighters: Wear self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of MSDS for personal protection details. Environmental precautions: Do not allow to contaminate watercourses or rivers. Clean-up procedures: In the event of spillage mop up bulk and dilute remainder to foul drain with water. Treat Page 210 of 553 Page 210 of 553 Page 210 of 553 Page 210 of 553 ---PAGE BREAK--- Material Safety Data Sheet Page 2 of 3 (Essentially similar to Form OSHA-174 / 29 CFR 1910.1200) Product name: InstantFOAM Alcohol Hand Sanitizer Revision Date: 03.07.2011 Supersedes Revision: 08.23.2010 large spillages as industrial waste. 7. HANDLING AND STORAGE Handling requirements: Do not mix with any material other than water, as directed. Avoid contact with eyes Storage conditions: Protect from extremes of temperature. Use product within 12 months of opening. Suitable packaging: Must only be kept in original packaging. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory protection: Respiratory protection not required. Hand protection: Not applicable. Eye protection: Not applicable. Skin protection: Not applicable. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Liquid Color: Colorless Odor: Alcohol Solubility in water: Highly soluble Viscosity: Non-viscous Flash point: 21°C (70°F) pH: 6.5 – 7.5 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to avoid: Avoid extremes of temperature and sources of ignition. 11. TOXOLOGICAL INFORMATION Routes of exposure: Eye contact may cause irritation. Ingestion may cause mild gastric irritation. 12. ECOLOGICAL INFORMATION Persistence and degradability: This product conforms to current EEC directives on biodegradability. 13. DISPOSAL CONSIDERATION Disposal operations: Dispose of according to local authority regulations. Disposal of packaging: Drain well. Dispose of as normal household waste. Note: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: 1170 ADR Class: 3 Packing group: II Classification code: F1 Shipping name: ALCOHOLS, N.O.S. (ETHANOL, PROPYL ALCOHOL) Labeling: 3 1 Hazard ID no: 33 IMDG / IMO UN no: 1170 Class: 3 Packing group: II EmS: F-E, S-D Marine pollutant: . Page 211 of 553 Page 211 of 553 Page 211 of 553 Page 211 of 553 ---PAGE BREAK--- Material Safety Data Sheet Page 3 of 3 (Essentially similar to Form OSHA-174 / 29 CFR 1910.1200) Product name: InstantFOAM Alcohol Hand Sanitizer Revision Date: 03.07.2011 Supersedes Revision: 08.23.2010 Labeling: 3 Hazard ID no: 33 IATA / ICAO UN no: 1170 Class: 3 Packing group: II Packing instructions: 305(P&CA); 307(CAO) Labeling: 3 15. REGULATORY INFORMATION Safety phrases: S25: Avoid contact with eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S46: If swallowed, seek medical advice immediately and show this container or label. S49: Keep only in the original container. Note: This product is manufactured and labeled in compliance with the Federal Food, Drug, and Cosmetic Act, and is exempt from the labeling requirements of the OSHA Hazard Communication Standard. Note: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION 16. OTHER INFORMATION Formula code: AFS6510 Reason for issue: New format [db 03.07.11]. Legal disclaimer: The purpose of the above information is to describe the products only in terms of health and safety requirements. The information given should not, therefore, be construed as guaranteeing specific properties or as specification. Customers should satisfy them- selves as to the suitability and completeness of such information for their own particular use. Additional shipping: 1 ORM-D when shipped domestically by ground. Refer to 49 CFR 173.150. Page 212 of 553 Page 212 of 553 Page 212 of 553 Page 212 of 553 ---PAGE BREAK--- 1. PRODUCT AND COMPANY IDENTIFICATION Product Identification Product ID: [PHONE REDACTED].008 Product Name: INT EXT LTX FLAT WHITE Product Use: Paint product. Print date: 04/May/2011 Revision Date: 09/Feb/2011 Company Identification The Valspar Corporation - Architectural Coatings Division 1191 Wheeling Road Wheeling, IL 60090 Manufacturer's Phone: 1-[PHONE REDACTED] 24-Hour Medical Emergency Phone: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Eye Contact: • May cause eye irritation. Skin Contact: • Causes mild skin irritation. Ingestion: None known. Inhalation: • May cause irritation of respiratory tract. This product contains ingredients that may contribute to the following potential chronic health effects: • Prolonged exposure over TLV may produce pneumoconiosis. Product ID: [PHONE REDACTED].008 Page 1 / 6 Material Safety Data Sheet Page 213 of 553 Page 213 of 553 Page 213 of 553 Page 213 of 553 ---PAGE BREAK--- Carcinogens: • Possible cancer hazard. Contains material which may cause cancer based on animal data. 3. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Ingredient Name CAS-No. Approx. Weight % Chemical Name CLAY 66402-68-4 20 - 25 Ceramic materials and wares, chemicals TITANIUM DIOXIDE 13463-67-7 1 - 5 Titanium dioxide If this section is blank there are no hazardous components per OSHA guidelines. 4. FIRST AID MEASURES Eye Contact: Get medical attention, if develop or persist. Immediately flush eye(s) with plenty of water. Skin Contact: Wash off with plenty of water. Ingestion: Get medical attention if occur Inhalation: Move to fresh air. Get medical attention, if develop or persist. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): 205 Flash point (Celsius): 96 Lower explosive limit not determined Upper explosive limit not determined Autoignition temperature: not determined Sensitivity to impact: no Sensitivity to static discharge: Sensitivity to static discharge is not expected. Hazardous combustion products: See Section 10. Unusual fire and explosion hazards: None known. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Keep containers and surroundings cool with water spray. 6. ACCIDENTAL RELEASE MEASURES Product ID: [PHONE REDACTED].008 Page 2 / 6 Page 214 of 553 Page 214 of 553 Page 214 of 553 Page 214 of 553 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate the area. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep container closed when not in use. Do not freeze. Since emptied containers may contain product residue, follow all label warnings, even after container is emptied. Do not cut, drill, grind, or weld on or near this container. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Wear safety glasses or goggles to protect against exposure. Skin protection: Appropriate chemical resistant gloves should be worn. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Use only in well-ventilated areas. Ensure adequate ventilation, especially in confined areas. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Ingredient Name CAS-No. Approx. Weight % TWA (final) Ceilings limits (final) Skin designations CLAY 66402-68-4 20 - 25 5 mg/m3 TWA Zr TITANIUM DIOXIDE 13463-67-7 1 - 5 15 mg/m3 TWA dust total ACGIH Threshold Limit Value (TLV's) Ingredient Name CAS-No. Approx. Weight % TWA STEL Ceiling limits Skin designations CLAY 66402-68-4 20 - 25 0.2 mg/m3 TWA Mn 5 mg/m3 TWA Zr 10 mg/m3 STEL Zr TITANIUM DIOXIDE 13463-67-7 1 - 5 10 mg/m3 TWA 9. PHYSICAL PROPERTIES Odor: Normal for this product type. Physical State: liquid pH: not determined Product ID: [PHONE REDACTED].008 Page 3 / 6 Page 215 of 553 Page 215 of 553 Page 215 of 553 Page 215 of 553 ---PAGE BREAK--- 9. PHYSICAL PROPERTIES Vapor pressure: 24 mmHg @ 77ºF (25ºC) Vapor density (air = 1.0): 0.6 Boiling point: not determined Solubility in water: not determined Coefficient of water/oil distribution: not determined Density (lbs per US gallon): 9.97 Specific Gravity: 1.19 Evaporation rate (butyl acetate = 1.0): 0.1 Flash point (Fahrenheit): 205 Flash point (Celsius): 96 Lower explosive limit not determined Upper explosive limit not determined Autoignition temperature: not determined 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: None known. Incompatibility: Avoid water-reactive materials, heat or contact with peroxides or other Hazardous Polymerization: None anticipated. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Metal oxide fumes. Sensitivity to static discharge: Sensitivity to static discharge is not expected. 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS-No. Approx. Weight % NIOSH - Selected LD50s and LC50s TITANIUM DIOXIDE 13463-67-7 1 - 5 > 10000 mg/kg Oral LD50 Rat Mutagens/Teratogens/Carcinogens: Possible cancer hazard. Contains material which may cause cancer based on animal data. Contains TIO2 which is listed by IARC as a possible human carcinogen (Group 2B) based on animal data. Neither long term animal studies, nor human epidemiology studies of workers exposed to TIO2 provide an adequate basis to conclude TIO2 is carcinogenic. TIO2 is not classified as a carcinogen by NTP, U.S. OSHA, or the U.S. EPA. Ingredient Name CAS-No. Approx. Weight % IARC Group 1 - Human Evidence IARC Group 2A - Limited Human Data IARC Group 2B - Sufficient Animal Data CLAY 66402-68-4 20 - 25 Monograph 43 [1988] TITANIUM DIOXIDE 13463-67-7 1 - 5 Monograph 47 [1989] Ingredient Name CAS-No. Approx. Weight % NTP Known Carcinogens NTP Suspect Carcinogens NTP Evidence of Carcinogenicity TITANIUM DIOXIDE 13463-67-7 1 - 5 male rat-negative; female rat-negative; male mice-negative; female mice-negative Product ID: [PHONE REDACTED].008 Page 4 / 6 Page 216 of 553 Page 216 of 553 Page 216 of 553 Page 216 of 553 ---PAGE BREAK--- Ingredient Name CAS-No. Approx. Weight % OSHA - Hazard Communication Carcinogens OSHA - Specifically Regulated Carcinogens ACGIH Carcinogens CLAY 66402-68-4 20 - 25 Present TITANIUM DIOXIDE 13463-67-7 1 - 5 Present 12. ECOLOGICAL DATA No information on ecology is available. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation UN ID Number (msds): NRPAIN Proper Shipping Name: PAINT, NOT REGULATED U.S Hazmat and/or International DG shipment exceptions The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Reportable Quantity Description: International Air Transport Association (IATA): UN ID Number (msds): NRPAIN Proper Shipping Name: PAINT, NOT REGULATED International Maritime Organization (IMO): IMO UN/ID Number (msds): NRPAIN Proper Shipping Name: PAINT, NOT REGULATED 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: SARA 311/312 Hazard Class: Acute: yes Chronic: yes Flammability: no Reactivity: no Sudden Pressure: no U.S. STATE REGULATIONS: Right to Know: The specific chemical identity of a component may be withheld as a trade secret under 34 Code, Chapter 317. Product ID: [PHONE REDACTED].008 Page 5 / 6 Page 217 of 553 Page 217 of 553 Page 217 of 553 Page 217 of 553 ---PAGE BREAK--- Right To Know: TITANIUM DIOXIDE 13463-67-7 CLAY 66402-68-4 Additional Non-Hazardous Materials WATER 7732-18-5 PROPRIETARY RESIN Trade Secret Rule 66 status of product Not photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories US TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. 16. OTHER INFORMATION HMIS Codes Health: 1* Flammability: 1 Reactivity: 1 PPE: X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Preparation Information: Prepared By: Regulatory Affairs Department Print date: 04/May/2011 Revision Date: 09/Feb/2011 Product ID: [PHONE REDACTED].008 Page 6 / 6 Page 218 of 553 Page 218 of 553 Page 218 of 553 Page 218 of 553 ---PAGE BREAK--- Material Safety Data Sheet SECTION I - Material Identity SECTION II - Manufacturer's Information SECTION III - Physical/Chemical Characteristics SECTION IV - Fire and Explosion Hazard Data SECTION V - Reactivity Data SECTION VI - Health Hazard Data SECTION VII - Precautions for Safe Handling and Use SECTION VIII - Control Measures SECTION IX - Label Data SECTION X - Transportation Data SECTION XI - Site Specific/Reporting Information SECTION XII - Ingredients/Identity Information SECTION I - Material Identity SECTION II - Manufacturer's Information MSDS Preparer's Information Alternate Vendors SECTION III - Physical/Chemical Characteristics Item Name Part Number/Trade Name ISOPROPYL ALCOHOL (IPA) 70% National Stock Number 6505006558366 CAGE Code CSWAN Part Number Indicator A MSDS Number 190947 HAZ Code B Manufacturer Name CUMBERLAND SWAN Street ONE SWAN DRIVE City State TN Country US Zip Code 37167 Emergency Phone [PHONE REDACTED] EXT 5270 Information Phone [PHONE REDACTED] Date MSDS Prepared/Revised 01MAR00 Active Indicator Y Page 1 of 4 ISOPROPYL ALCOHOL (IPA) 70% Page 219 of 553 Page 219 of 553 Page 219 of 553 Page 219 of 553 ---PAGE BREAK--- SECTION IV - Fire and Explosion Hazard Data SECTION V - Reactivity Data SECTION VI - Health Hazard Data Appearance/Odor CLEAR LIQUID, ALCOHOL SMELL Boiling Point 176 F Vapor Pressure 23 Vapor Density NR Specific Gravity 0.878 Solubility in Water NR Chemical pH NR Container Type R Container Pressure Code 1 Temperature Code 4 Product State Code L Flash Point 70.5 Flash Point Method TOC Extinguishing Media USE WATER FOG, ALCOHOL FOAM, DRY CHEMICAL, OR CO2 Special Fire Fighting Procedures CLEAR AREA OF UNPROTECTED PERSONNEL. WEAR COMPLETE TURNOUT GEAR. COOL CONTAINERS EXPOSED TO FIRE WITH WATER Unusual Fire/Explosion Hazards CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH LARGE AMOUNTS OF WATER TO PREVENT BUILDUP OF INTERNAL PRESSURE DUE TO VAPOR GENERATION WHICH COULD RESULT IN CONTAINER RUPTURE Stability YES Stability Conditions to Avoid HEAT, SPARKS, OPEN FLAMES Materials to Avoid STRONG OXIDIZERS, ACETALDEHYDE, CHLORINE, ETHYLENE OXIDE, ACIDS, ISOCYANATES Hazardous Decomposition Products CO AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED OF DECOMPOSITION Hazardous Polymerization NO Polymerization Conditions to Avoid WILL NOT OCCUR Route of Entry: Skin YES Route of Entry: Ingestion YES Route of Entry: Inhalation YES Health Hazards - Acute and Chronic [EYE] MAY CAUSE EYE IRRITATION. MAY INCLUDE STINGING, TEARING, AND REDNESS. WILL CAUSE TISSUE DAMAGE IF NOT REMOVED [SKIN] LONG TERM CONTACT MAY IRRITATE AND CAUSE DERMATITIS. LOW ORDER OF TOXICITY. [INGEST] MINIMAL TOXICITY. SMALL AMOUNTS OF THE LIQUID ASPIRATED INTO THE RESPIRATORY SYSTEM DURING INGESTION, OR FROM VOMITING, MAY CAUSE Page 2 of 4 ISOPROPYL ALCOHOL (IPA) 70% Page 220 of 553 Page 220 of 553 Page 220 of 553 Page 220 of 553 ---PAGE BREAK--- SECTION VII - Precautions for Safe Handling and Use SECTION VIII - Control Measures BRONCHOPNEUMONIA OR PULMONARY EDEMA. [INHAL] HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES AND THE RESPIRATORY TRACT. (CONT. BELOW) Carcinogenity: NTP NO Carcinogenity: IARC NO Carcinogenity: OSHA NO Explanation of Carcinogenity NONE OF THE INGREDIENTS IN THIS PRODUCT ARE LISTED of Overexposure SEE ABOVE AND [INHAL] MAY CAUSE HEADACHES AND DIZZINESS. VAPORS ARE ANESTHETIC AND MAY HAVE OTHER CENTRAL NERVOUS SYSTEM EFFECTS. NEGLIGIBLE HAZARD AT AMBIENT TEMPERATURE (-18 TO 38 C; 0 TO 100 F) Medical Cond. Aggrevated by Exposure NR Emergency/First Aid Procedures [EYE] FLUSH WITH LARGE QUANTITIES OF WATER FOR 15 MIN. GET PROMPT MED ATTENTION [SKIN] FLUSH WITH WATER [INGEST] DO NOT INDUCE VOMITING. KEEP AT REST. GET PROMPT MED ATTEN [INHAL REMOVE TO FRESH AIR. IF BREATHING IS STILL DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP AT REST. GET PROMPT MED ATTENTION Steps if Material Released/Spilled [LARGE] ELIMINATE ALL IGNITION SOURCES. EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. EVACUATE THE AREA OF UNPROTECTED PERSONNEL. CONTAIN OSURCE OF SPILL. DIKE OR OTHERWISE CONFINE SPILLED PRODUCT. UNCONTROLLED RELEASES TO AIR, LAND OR WATER MAY BE REPORTABLE TO THE NRC (1-[PHONE REDACTED]) [SMALL] TAKE UP WITH ABSORBENT MATERIAL AND PLACE IN NON-LEAKING CONTAINER; SEAL DISPOSE OF ABSORBENT Waste Disposal Method CONTACT YOUR SUPPLIER OR A LICENSED CONTRACTOR FOR DETAILED RECOMMENDATIONS. FOLLOW APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS. CONSIDER FUELS BLENDING AS AN ALTERNATIVE TO INCINERATION Handling and Storage Precautions STORE IN A CLOSED CONTAINERS IN A COOL, DRY AREA AWAY FROM HEAT AND OTHER POSSIBLE IGNITION SOURCES. USE NON SPARKING TOOLS TO OPEN OCNTAINERS. MAINTAIN APPROPRIATE CLASS OF FIRE EXTINGUISHERS NEARBY IN CASE OF FIRE Other Precautions NR Respiratory Protection NIOSH APPROVED RESPIRATORY PROTECTION REQUIRED WHEN ABOVE PEL/TWA Ventilation USE EXPLOSION PROOF VENTILATION EQUIPMENT AS NECESSARY TO MAINTAIN AIRBORNE CONCENTRATIONS BELOW THE PEL Page 3 of 4 ISOPROPYL ALCOHOL (IPA) 70% Page 221 of 553 Page 221 of 553 Page 221 of 553 Page 221 of 553 ---PAGE BREAK--- SECTION IX - Label Data SECTION X - Transportation Data SECTION XI - Site Specific/Reporting Information SECTION XII - Ingredients/Identity Information Protective Gloves GLOVES Eye Protection GOGGLES Other Protective Equipment GROUND ALL CONTAINERS TO PREVENT STATIC SPARKS DURING FLUID TRANSFERS. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE Work Hygenic Practices WASH THOROUGHLY AFTER WORKING WITH THIS PRODUCT, BEFORE EATING, SMOKING, DRINKING, OR APPLYING COSMETICS Protect Eye YES Protect Skin YES Protect Respiratory YES Chronic Indicator YES Contact Code SLIGHT Fire Code UNKNOWN Health Code UNKNOWN React Code UNKNOWN Specific Hazard and Precaution TARGET ORGANS: SKIN Volatile Organic Compounds (P/G) 5.14 Volatile Organic Compounds (G/L) 615.9716 Ingredient # 01 Ingredient Name ISOPROPYL ALCOHOL CAS Number 67630 Proprietary NO Percent 70 OSHA PEL 400 PPM ACGIH TLV 400 PPM Page 4 of 4 ISOPROPYL ALCOHOL (IPA) 70% Page 222 of 553 Page 222 of 553 Page 222 of 553 Page 222 of 553 ---PAGE BREAK--- Page 223 of 553 Page 223 of 553 Page 223 of 553 Page 223 of 553 ---PAGE BREAK--- Page 224 of 553 Page 224 of 553 Page 224 of 553 Page 224 of 553 ---PAGE BREAK--- Page 225 of 553 Page 225 of 553 Page 225 of 553 Page 225 of 553 ---PAGE BREAK--- Page 226 of 553 Page 226 of 553 Page 226 of 553 Page 226 of 553 ---PAGE BREAK--- Page 227 of 553 Page 227 of 553 Page 227 of 553 Page 227 of 553 ---PAGE BREAK--- Page 228 of 553 Page 228 of 553 Page 228 of 553 Page 228 of 553 ---PAGE BREAK--- Page 229 of 553 Page 229 of 553 Page 229 of 553 Page 229 of 553 ---PAGE BREAK--- Page 230 of 553 Page 230 of 553 Page 230 of 553 Page 230 of 553 ---PAGE BREAK--- Page 231 of 553 Page 231 of 553 Page 231 of 553 Page 231 of 553 ---PAGE BREAK--- Page 232 of 553 Page 232 of 553 Page 232 of 553 Page 232 of 553 ---PAGE BREAK--- Page 233 of 553 Page 233 of 553 Page 233 of 553 Page 233 of 553 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # AERLCO-1223A SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550, MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS LUSTER COTE (AEROSOL) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GAS % TLV (UNITS) 2-Butoxyethanol (CAS# 111-76-2) >1 25 ppm* Isopropanol (CAS# 67-63-0) >1 400 ppm Isobutane (CAS# 75-28-5) >1 800 ppm This product contains 1 ounce of 2-Butoxyethanol per can of product. 2-Butoxyethanol is a regulated chemical under the Emergency Planning and Right-To-Know Act. You are required to file E.P.A. SARA reports once the threshold of 10,000 pounds of 2-Butoxyethanol has been purchased for one location in each calendar year. *Skin All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING RANGE (ºF) -11 to 212 SPECIFIC GRAVITY (H2O = 1) 1.0 VAPOR PRESSURE (in can PSIG) 50 PERCENT VOLATILE BY VOLUME 95 VAPOR DENSITY (AIR = 1) 4.0 EVAPORATION RATE ( Butyl Acetate faster SOLUBILITY IN WATER complete PH N/A APPEARANCE AND ODOR Clear liquid with pleasant floral fragrance. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) -160ºF T.C.C. FLAMMABLE LIMITS 1.9 8.5 EXTINGUISHING MEDIA Water Fog, Dry Chemical, Carbon Dioxide SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120ºF. (Continued on reverse side) Page 234 of 553 Page 234 of 553 Page 234 of 553 Page 234 of 553 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA (AERLCO-1223A) THRESHOLD LIMIT VALUE 400 ppm PRIMARY ROUTES OF ENTRY Inhalation x Skin Contact x Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- irritation, possible corneal injury. Skin- defatting of skin, irritation, 2-butoxyethanol can be absorbed through skin and may cause blood abnormalities, damage to spleen and testes. Inhalation- dizziness, long term overexposure may cause lung, liver, and CNS damage. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- flush with water and then wash with soap and water, launder contaminated clothing before reuse- get medical attention if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- DO NOT INDUCE VOMITING- aspiration of material into lungs can be harmful or fatal- get medical attention immediately. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Persons with pre-existing heart or respiratory disorders. Carcinogen: NTP IARC OTHER x California’s Prop 67 This product contains a chemical known to the State of California to cause cancer. SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE x CONDITIONS TO AVOID Temperatures in excess of 120ºF and sources of ignition. INCOMPATABILITY (Conditions to avoid) Strong Oxides, Acids, Bases, and Reducers HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon and Silicone, Aldehydes MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR x CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Eliminate all sources of ignition and ventilate area. Use absorbent material to soak up spill. Shovel or sweep into container for disposal. WASTE DISPOSAL METHOD Aerosol cans when emptied and depressurized through normal use pose no disposal hazard and should be recycled. Absorbent materials should be disposed of in accordance with all Local, State, and Federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Use NIOSH approved respirator in areas where TLV has been exceeded. LOCAL EXHAUST To control TLV SPECIAL N/A VENTILATION MECHANICAL (General) To control TLV OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical Goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- use only with adequate ventilation. Do not take internally. Do not store in areas where temperatures may exceed 120ºF. Avoid use near sources of OTHER PRECAUTIONS Ignition. Read and follow label directions before using. Keep Out of Reach of Children. HMIS SYMBOL HMIS NFPA NFPA SYMBOL SEVERE 4 EXTREME FIRE REACTIVITY SERIOUS 3 HIGH 4 MODERATE 2 MODERATE 2 0 SLIGHT 1 SLIGHT TOXICITY MINIMAL 0 INSIGNIFICANT SPECIAL NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE June 11, 2007 PHONE NUMBER CHEMTREC [PHONE REDACTED] HEALTH 2 FLAMMABILITY 4 REACTIVITY 0 Page 235 of 553 Page 235 of 553 Page 235 of 553 Page 235 of 553 ---PAGE BREAK--- Page 236 of 553 Page 236 of 553 Page 236 of 553 Page 236 of 553 ---PAGE BREAK--- Page 237 of 553 Page 237 of 553 Page 237 of 553 Page 237 of 553 ---PAGE BREAK--- Page 238 of 553 Page 238 of 553 Page 238 of 553 Page 238 of 553 ---PAGE BREAK--- Page 239 of 553 Page 239 of 553 Page 239 of 553 Page 239 of 553 ---PAGE BREAK--- MSDS-AS16 Date Prepared: 12/17/02 MATERIAL SAFETY DATA SHEET/COMPLIES WITH OSHA’S HAZARD COMMUNICATION STANDARD (29CFR 1910.1200) SECTION I – PRODUCT IDENTIFICATION MAGIC SHOCK FREE (aerosol product) CONTAINER SIZE: 13 oz. Net Weight STOCK NO.: AS16 SUPPLIER’S NAME: MAGIC AMERICAN PRODUCTS, INC. ADDRESS: 23700 MERCANTILE ROAD; CLEVELAND OH 44122 24 Hour Emergency Phone: CHEMTEL 1-[PHONE REDACTED] Information Phone: MAGIC AMERICAN PRODUCTS, INC. M-F, 9-5 EST 1-[PHONE REDACTED] DOT SHIPPING INFORMATION HAZARDS RATING INFORMATION DOT SHIPPING NAME: Consumer Commodity DOT HAZARD CLASS: ORM-D DOT LABEL: None DOT PACKING GROUP: None Health Flammability Reactivity Personal Protection Code 30B Storage Rating NFPA 1 4 0 N/A Level I NPCA(HMIS) 1 1 0 None 0 – Minimal 1 – Slight 2 – Moderate 3 – Serious 4 - Extreme SECTION II - INGREDIENTS CHEMICAL NAME CAS NO. % WT 313/CHEMICAL OSHA PEL ACGIH/TLV Isopropanol Ammonium Hydroxide Dimethicone Silylate Sodium Nitrite Isobutane/Propane Blend 67-63-0 1336-21-6 68037-64-9 7632-00-0 68476-86-8 <13.5 <2.0 <3.5 <2.0 <14.0 No No No No No 400 ppm 50 ppm N/E N/E 1000 ppm 400 ppm 25 ppm N/D N/D N/D All ingredients used in this proprietary mixture are listed on the TSCA Inventory List and none is listed as carcinogenic by OSHA, IARC or NTP. SECTION III – PHYSICAL DATA SECTION IV – FIRE AND EXPLOSION DATA Boiling Point: N/D Vapor Pressure: 35 – 45 PSIG @ 70°F Solubility in water: Complete pH: 10.5 Specific Gravity: 0.980 g/ml Evaporation Rate: Greater than 1 (H2O=1) Appearance/Odor: Pressurized Hazy Liquid with Lavender/Ammonia Fragrance VOC Content: 20.0 – 22.0% VOC Flash Point: <-20°F by Tag Closed Cup Explosive Hazard: Not an explosive Extinguishing Media: Water fog, foam, carbon dioxide, dry chemical Special Fire Fighting Procedures: None known Unusual Fire and Explosion Hazards: Prolonged exposure to temperature above 130°F may cause cans to burst. SECTION V – REACTIVITY DATA SECTION VI – STORAGE AND HANDLING Stability: Stable Hazardous Polymerization: Will not occur Hazardous Decomposition Products: CO, CO2, Ammonia, Nitrogen Oxides. Incompatibility: None known KEEP OUT OF THE REACH OF CHILDREN Store in a cool, dry area away from heat or open flame. Do not store at temperatures above 120°F or below 32°F. SECTION VII – HEALTH EFFECTS AND FIRST AID PRIMARY ROUTES OF ENTRY AND EFFECTS OF OVEREXPOSURE FIRST AID PROCEDURES EYES: May cause mild irritation in some individuals. EYES: If applicable, remove contact lenses. Flush eyes with plenty of water for at least 15 minutes. Contact a physician if irritation persists. SKIN: May cause mild irritation in some individuals. SKIN: Wash with plenty of soap and large quantities of water. Contact a physician if irritation persists. INHALATION: Inhalation of vapor may produce anaesthetic effects and feelings of euphoria. Prolonged overexposure can cause rapid breathing, headache, dizziness, narcosis, unconsciousness and death from depending on concentration and time of exposure. INGESTION: Not likely, aerosol product; may cause nausea, headache and vomiting. INHALATION: Remove person to fresh air. Seek medical attention if effects are persistent. INGESTION: Induce vomiting; contact a physician immediately. SECTION VIII – SPECIAL PROTECTION INFORMATION SECTION IX – SPILL OR LEAK PRECAUTIONS RESPIRATORY PROTECTION: Not normally needed. STEPS TO BE TAKEN IN CASE OF SPILLAGE OR LEAKAGE: Spilled material can be picked up with sorbant material. Use caution where surfaces may become slippery from spilled material. VENTILATION: Mechanical (general) ventilation not required under normal conditions. WASTE DISPOSAL METHOD: Sweep up and place in empty container and close. Dispose of according to local, state and federal regulations. PROTECTIVE GLOVES: Rubber, latex or neoprene recommended. EYE PROTECTION: Safety glasses recommended. WASTE DISPOSAL CAUTION: Hazardous substances cleaned with this product may create hazardous waste that must be properly characterized and disposed of in accordance with RCRA, state and local regulations. N/A = NOT APPLICABLE N/E = NOT ESTABLISHED N/D = NOT DETERMINED < = LESS THAN > = MORE THAN NOTICE: The information contained on this Material Safety Data Sheet is for Industrial and Institutional use only and considered accurate as of the date of publication. It is not necessarily all inclusive or fully adequate in every circumstance. The suggestions should not be confused with or followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, express or implied, of merchantability, fitness, accuracy of data, or the results to be obtained from the use thereof is made. The vendor assumes no responsibility for injury or damages resulting from the inappropriate use of this product. Magic American assumes no responsibility for any product information placed on the Internet by individuals who are not affiliated with Magic American. Page 240 of 553 Page 240 of 553 Page 240 of 553 Page 240 of 553 ---PAGE BREAK--- Revision Number: 10 Date stamp: 29-Jul-2005 MATERIAL SAFETY DATA SHEET MSDS Ref. No.: 100530 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Miracle-Gro Liquid African Violet Plant Food, 7-7-7 Description: Liquid Fertilizer Formula No.: S9508 2. HAZARDS IDENTIFICATION OSHA Regulatory Status: This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS-No Weight % Urea 57-13-6 10-30 Potassium chloride, KCl 7447-40-7 1-5 Ammonium Phosphate 7722-76-1 3-7 Boric acid, H3BO3 10043-35-3 0.1-1.0 Copper-EDTA 14025-15-1 0.1-1 Iron HEDTA 17084-02-5 1-5 Zinc-EDTA 14025-21-9 0.1-1 Manganese-EDTA 15375-84-5 0.1-1 Potassium Phosphate 7778-77-0 10-30 4. FIRST AID MEASURES Eye contact: Hold eye open and rins slowly and gently with water for 15-20 minutes. Remove contact lenses, if present after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so be a poison control center or doctor. Do not give anything by mouth to an unconscious person Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferabley by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice 5. FIRE-FIGHTING MEASURES Flammable properties: Non-flammable. Aggravated Medical Conditions: Inhalation may aggravate asthma. Signal word: Principle routes of exposure: Skin, Inhalation, Eyes, Ingestion No signal word. Precautionary Statement Keep out of reach of children. Potential health effects Eye contact: Contact with eyes may cause irritation. Company The Scotts Company 14111 Scottslawn Road Marysville, OH 43041 Skin contact: Irritation not expected. Ingestion: Considered practically non-toxic. Possible gastrointestinal tract irritation. Labelling Revision date: 23-Jun-2005 Page 1 of 4 Inhalation: May cause irritation of respiratory tract. 24-HOUR EMERGENCY TELEPHONE NUMBERS: CHEMTREC 1-[PHONE REDACTED] CHEMTREC (International): 1-[PHONE REDACTED] Non-Emergency Calls: 1-[PHONE REDACTED] Page 241 of 553 Page 241 of 553 Page 241 of 553 Page 241 of 553 ---PAGE BREAK--- Miracle-Gro Liquid African Violet Plant Food, 7-7-7 MSDS Ref. No.: 100530 Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, chemical foam Explosion potential: Closed containers may rupture violently under fire conditions. Hazardous combustion products: Toxic fumes may be produced. Fire fighting procedures: Flood with water to cool containers. Select appropriate method to surround and extinguish fire. Contain run-off as ingredients may be toxic to aquatic organisms. Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Wear personal protective equipment Environmental precautions: Prevent product from entering drains Methods for containment: Control spill with dykes and absorb with inert absorbant material. Methods for cleaning up: If material is uncontaminated, collect and reuse as recommended for product. 7. HANDLING AND STORAGE Handling: Avoid container breakage Storage: Keep containers closed in a cool, well-ventilated place 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Components ACGIH: OSHA: Urea Not Listed Not Listed Ammonium Phosphate Not Listed Not Listed Potassium chloride, KCl Not Listed Not Listed Potassium Phosphate Not Listed Not Listed Boric acid, H3BO3 2 mg/m³ TWA inhalable fraction, listed under borate compounds, inorganic Not Listed Copper-EDTA 0.2 mg/m³ TWA fume 1 mg/m³ TWA dusts and mists, as Cu 0.1 mg/m³ TWA fume 1 mg/m³ TWA dusts and mists Iron HEDTA 1 mg/m³ TWA as Fe Not Listed Manganese-EDTA 0.2 mg/m³ TWA Not Listed Zinc-EDTA Not Listed Not Listed Engineering controls Use adequate ventilation to keep the airborne concentrations of this material below the recommended exposure standard Personal Protective Equipment Eye/face protection: Eye/face protection is not required, but is recommended in manufacturing situations where contact may occur. Skin and body protection: Wear suitable protective clothing if contact is anticipated during manufacturing. Imervious gloves. Respiratory protection: If airborne levels are high or product does not remain intact, use a combination of engineering controls (e.g. ventilation) and personal protection (e.g. NIOSH/MSHA approved respirator for dusts, mists, and fumes General hygiene considerations: Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Chemically Stable: Yes Conditions to avoid: Extreme heat. Materials to avoid: Strong oxidizing agents (permanganate, dichromate, chlorine, etc.). Reducing agents (sodium nitrite, etc.). Chlorine compounds (sodium hypochlorite, sodium chlorate, pool chemicals, household bleach and other cleaning products). Fuels. Active metals such as aluminum and magnesium. Hazardous decomposition products: Toxic fumes and gases may be generated. Metal oxides possible. Green Physical State: Odor: None Liquid pH: 7.0 - 7.3 Solubility: Water solubility, Completely soluble Appearance: Density: 1.20 g/cc Clear Revision date: 23-Jun-2005 Page 2 of 4 Flash point: Does not flash Color: Page 242 of 553 Page 242 of 553 Page 242 of 553 Page 242 of 553 ---PAGE BREAK--- Miracle-Gro Liquid African Violet Plant Food, 7-7-7 MSDS Ref. No.: 100530 Possibility of hazardous reactions: Poses little or no immediate hazard. 11. TOXICOLOGICAL INFORMATION Acute toxicity Eye effects: Contact with eyes may cause irritation Skin effects: May cause skin irritation and/or dermatitis Chronic toxicity Carcinogenic effects: The table below indicates whether each agency has listed any indgredient as a carcinogen. Components NTP: IARC: OSHA: Urea Not listed Not listed Not listed Ammonium Phosphate Not listed Not listed Not listed Potassium chloride, KCl Not listed Not listed Not listed Potassium Phosphate Not listed Not listed Not listed Boric acid, H3BO3 Not listed Not listed Not listed Copper-EDTA Not listed Not listed Not listed Iron HEDTA Not listed Not listed Not listed Manganese-EDTA Not listed Not listed Not listed Zinc-EDTA Not listed Not listed Not listed General Information Very low toxicity for humans and animals Ingestion: Health injuries are not known or expected under normal use Inhalation: Health injuries are not known or expected under normal use 12. ECOLOGICAL INFORMATION Ecotoxicity effects: No data is available on the product itself. Persistence and degradability: Inherently biodegradable. Non-persistent. Bioaccumulative potential: Does not bioaccumulate. Mobility: Water contaminating. Aquatic toxicity: May be beneficial to plant life. Additional ecological information: Do not apply directly to lakes, streams, or ponds. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Dispose of in accordance with local regulations and national regulations. Contaminated packaging: Do not re-use empty containers. If empty, place in trash or offer for recycling if available. 14. TRANSPORT INFORMATION The description shown may not apply to all situations. Consult 49 CFR, or appropriate dangerous goods regulations for additional description requirements (e.g. technical name) and mode-specific or quantity-specific shipping requirements. DOT Proper shipping name: Not regulated 15. REGULATORY INFORMATION Page 3 of 4 Revision date: 23-Jun-2005 Page 243 of 553 Page 243 of 553 Page 243 of 553 Page 243 of 553 ---PAGE BREAK--- Miracle-Gro Liquid African Violet Plant Food, 7-7-7 MSDS Ref. No.: 100530 Components CAS-No CERCLA/SARA 313 CERCLA/SARA 302 Urea 57-13-6 Not Listed Not Listed Ammonium Phosphate 7722-76-1 Not Listed Not Listed Potassium chloride, KCl 7447-40-7 Not Listed Not Listed Potassium Phosphate 7778-77-0 Not Listed Not Listed Boric acid, H3BO3 10043-35-3 Not Listed Not Listed Copper-EDTA 14025-15-1 2270 kg final RQ 5000 lb final RQ Not Listed Iron HEDTA 17084-02-5 Not Listed Not Listed Manganese-EDTA 15375-84-5 Not Listed Not Listed Zinc-EDTA 14025-21-9 1000 lb final RQ 454 kg final RQ Not Listed General Information Contact local authorities for disposal of large quantities of product 16. OTHER INFORMATION Hazard Rating: 0=Least; 1-Slight; 2=Moderate; 3=High; 4=Severe General comment: This document contains health, safety, and environmental information useful to emergency response agencies, health care providers, manufacturers, and workers/employees. It does not replace the precautionary language, use directions, or the storage and disposal information found on the product label. Revision date: 23-Jun-2005 Additional Information: This information contained herein is, to the best of Scott's knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and Scotts shall not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, Scotts shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. HMIS: Health: 1 Flammability: 0 Health: 1 Reactivity: 0 Flammability: 0 Revision date: 23-Jun-2005 Page 4 of 4 Reactivity: 0 NFPA: Page 244 of 553 Page 244 of 553 Page 244 of 553 Page 244 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION 2. COMPOSITION / INFORMATION ON INGREDIENTS Date-Issued: 06/20/2001 MSDS Ref. No: 70778300 Date-Revised: 06/21/2001 Revision No: New MSDS Miracle-Gro® Potting Mix PRODUCT NAME: Miracle-Gro® Potting Mix MANUFACTURER The Scotts Company - Hyponex - Miracle Gro - Scotts Scotts Sierra - Swiss Farms 14111 Scottslawn Road Marysville, OH 43041 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC (800) 424-9300 International: 1-[PHONE REDACTED] Emergency Phone: 1-[PHONE REDACTED] Chemical Name CAS# OSHA PEL ACGIH TLV Non-hazardous Product Nuisance Dust 15 mg/m3 3 mg/m3 COMMENTS: This product is not considered to be hazardous in accordance with the OSHA Hazard Communication Standard, 29 CFR 1919.1200, Health Hazard. Thus, no Material Safety Data Sheet is required. This document serves as a guide for a range of Scotts/ORTHO product classes: LAWN FERTILIZER/COATED FERTILIZER (POLY-S®, OSMOCOTES®)/WATER SOLUBLE FERTILIZER-LIQUID PLANT FOOD/PLANT FOOD STICKS & PLANTING TABLETS, SOIL, POTTING MIX, LAWN TOPPING, HUMUS, COMPOST, MANURE, MULCH, BARK, PERLITE, LIME, VERMICULITE, STONE/ROCK, SAND, or SEED PATCH, INSECT TRAPS, ATTRACTANTS, REPELLANTS, and other like products. See product label for ingredients and product-specific Consumer Services telephone numbers. The ACGIH Threshold Limit Values (TLV) for nuisance (inert) dusts containing < 1% silica and no asbestos are: 10 mg/m3 inhalable particulates and 3 mg/m3 respirable particulate. The OSHA TLV is 15 mg/m3 total dust, 5 mg/m3 respirable fraction. Page 1 of 5 MSDS Miracle-Gro® Potting Mix 9/12/03 Page 245 of 553 Page 245 of 553 Page 245 of 553 Page 245 of 553 ---PAGE BREAK--- 3. HAZARDS IDENTIFICATION 4. FIRST AID MEASURES 5. FIRE FIGHTING MEASURES 6. ACCIDENTAL RELEASE MEASURES POTENTIAL HEALTH EFFECTS EYES: May cause eye irritation. SKIN: May cause skin irritation. INGESTION: If swallowed, product is considered practically non-toxic. INHALATION: Inhalation of dusts or aerosols may aggravate asthma. ROUTES OF ENTRY: Ingestion, skin, inhalation, and eyes. EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice. SKIN: If on skin or clothing, take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. INGESTION: If swallowed, call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to by the poison control center or doctor. Do not give anything by mouth to an unconscious person. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice. COMMENTS: See product label for specific First Aid Measures. The above measures are the most conservative and would apply in the event a product label is not immediately available. EXTINGUISHING MEDIA: Water fog or spray. EXPLOSION HAZARDS: Explosive conditions may exist when a high airborne concentration of fertilizer or organic material occurs. FIRE FIGHTING EQUIPMENT: Use self-contained air supply. HAZARDOUS DECOMPOSITION PRODUCTS: In a fire, fertilizer products may produce ammonia and toxic oxides of carbon, nitrogen, potassium, phosphorous, and/or sulfur. Page 2 of 5 MSDS Miracle-Gro® Potting Mix 9/12/03 Page 246 of 553 Page 246 of 553 Page 246 of 553 Page 246 of 553 ---PAGE BREAK--- 7. HANDLING AND STORAGE 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 9. PHYSICAL AND CHEMICAL PROPERTIES GENERAL PROCEDURES: Use good housekeeping practices. Sweep up spills. As a general practice, avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling. Remove to approved landfill. See label for specific disposal procedures. HANDLING: See label. Wash hands with soap and water after handling product. Avoid container breakage. Avoid inhalation or contact with skin, eyes, or clothing. Keep out of lakes, streams or ponds, KEEP OUT OF REACH OF CHILDREN. STORAGE: See label. KEEP OUT OF REACH OF CHILDREN. Avoid container breakage. Store in cool, dry area in closed container or package. Keep away from feed or foodstuffs. ENGINEERING CONTROLS: Use adequate ventilation to keep the airborne concentrations of this material below the recommended exposure standard. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: See label. Protective eye wear is typically not required for normal product use. SKIN: See label. No special protective clothing is necessary under normal use conditions. Gardening gloves are suggested for repeated handling of lawn care products. Fertilizer applicators should wear long-sleeved shirt, long pants, shoes and socks. RESPIRATORY: See label. No special respiratory protection is required under normal use conditions. However, if operating conditions create high airborne concentrations of product, a dust mask, or other appropriate respiratory protection is recommended. APPEARANCE: Fetilizers are typically off-white, tan, to light brown in color, or may contain blue/yellow/green dye coloration. Physical characteristics range from powders, granules (may contain prills), to coated beads, pellets, or sticks. Potting soils have an earth-tone, barks and mulches may be red-brown to dark brown, while manures are characteristically deep brown to black. Page 3 of 5 MSDS Miracle-Gro® Potting Mix 9/12/03 Page 247 of 553 Page 247 of 553 Page 247 of 553 Page 247 of 553 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION CONDITIONS TO AVOID: See label. Keep away from heat, sparks, and open flames. STABILITY: Stable POLYMERIZATION: Will not occur INCOMPATIBLE MATERIALS: Nitrates are incompatible with strong alkalies and reducing agents, active metals (such as aluminum and magnesium), ammonia, organic and combustible materials. Urea is incompatible with strong oxidizers, alkalies, sodium nitrite, and chlorine compounds (including bleach and similar household cleaning products). See product label for ingredients and storage precautions. GENERAL COMMENTS: Toxicology information is limited for this product. Inhalation of dust may irritate nose, throat, and lungs. Eye contact with solids may produce irritation, tearing, or blinking as a foreign body in the eye. ECOTOXICOLOGICAL INFORMATION: See label. Keep out of lakes, streams, or ponds. DISPOSAL METHOD: Dispose in normal waste disposal. Do not reuse empty container. See label for specific product disposal recommendations. DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not DOT regulated. SPECIAL SHIPPING NOTES: The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements technical name) and mode-specific or Page 4 of 5 MSDS Miracle-Gro® Potting Mix 9/12/03 Page 248 of 553 Page 248 of 553 Page 248 of 553 Page 248 of 553 ---PAGE BREAK--- 15. REGULATORY INFORMATION 16. OTHER INFORMATION quantity-specific shipping requirements. GENERAL COMMENTS: Contact local authorities for proper disposal of large quantities of unused product. REVISION SUMMARY New MSDS MANUFACTURER DISCLAIMER: The information contained herein is, to the best of the Manufacturer's (see Section 1) knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and the Manufacturer shall not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, the Manufacturer shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. Page 5 of 5 MSDS Miracle-Gro® Potting Mix 9/12/03 Page 249 of 553 Page 249 of 553 Page 249 of 553 Page 249 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Miracle-Gro® Pro Select™ All Purpose Plant Food 20-20-20 PN: S9994 2. COMPOSITION / INFORMATION ON INGREDIENTS COMMENTS: This product is not considered to be hazardous in accordance with the OSHA Hazard Communication Standard, 29 CFR 1919.1200, Health Hazard. See product label for ingredients and product-specific Consumer Services telephone numbers. The ACGIH Threshold Limit Values (TLV) for nuisance (inert) dusts containing < 1% silica and no asbestos are: 10 mg/m3 inhalable particulates and 3 mg/m3 respirable particulate. The OSHA TLV is 15 mg/m3 total dust, 5 mg/m3 respirable fraction. 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IMMEDIATE CONCERNS: Follow precautionary product label information. General Considerations: Avoid breathing dusts or mists by using adequate ventilation. Reduce material contact by wearing gloves when handling material for extended periods or by washing hands after use. Minimize material contact during application of lawn/garden products by wearing long pants, shoes, and socks. Avoid eye contact with any foreign body and do not ingest product. Keep out of reach of children. POTENTIAL HEALTH EFFECTS EYES: Not known to be an eye irritant. SKIN: Not known to be a skin irritant. INGESTION: If swallowed, product is considered practically non-toxic. Miracle-Gro® Pro Select™ All Purpose Plant Food 20-20-20 Date-Issued: 09/21/2004 MSDS Ref. No: 100204 Date-Revised: 09/21/2004 Revision No: New MSDS MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS The Scotts Company Gro Scotts-Scotts Sierra-Swiss Farms 14111 Scottslawn Road Marysville, OH 43041 CHEMTREC International: Emergency Phone: (800) 424-9300 1-[PHONE REDACTED] 1-[PHONE REDACTED] Chemical Name CAS# OSHA PEL ACGIH TLV Urea 57-13-6 None None Ammonium Phosphate 7722-76-1 None None Potassium Nitrate 7757-79-1 None None Boric Acid 10043-35-3 None None Copper Sulfate 7758-98-7 None 1 mg (Cu)/m3 Iron EDTA 15708-41-5 None None Manganese Sulfate 7785-87-7 5 mg (Mn)/m3 5 mg (Mn)/m3 Sodium Molybdate 7631-95-0 5 mg/m3 5 mg/m3 Zinc Sulfate 7733-02-0 None None Nuisance Dust 15 mg/m3 3 mg/m3 Page 1 of 4 Miracle-Gro® Pro Select™ All Purpose Plant Food 20-20-20 9/21/2004 file://K:\100204.htm Page 250 of 553 Page 250 of 553 Page 250 of 553 Page 250 of 553 ---PAGE BREAK--- INHALATION: Inhalation of dusts or aerosols may aggravate asthma. ROUTES OF ENTRY: Ingestion, skin, inhalation, and eyes. 4. FIRST AID MEASURES EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice. SKIN: If on skin or clothing, take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. INGESTION: If swallowed, call a poison control center or doctor immediately for treatment advice. Have person sip glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never give anything by mouth to an unconscious person. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice. COMMENTS: See product label for specific First Aid Measures. The above measures are the most conservative and would apply in the event a product label is not immediately available. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Water fog or spray. EXPLOSION HAZARDS: Explosive conditions may exist when a high airborne concentration of fertilizer or organic material occurs in an enclosed area. FIRE FIGHTING PROCEDURES: Use self-contained air supply. HAZARDOUS DECOMPOSITION PRODUCTS: In a fire, fertilizer products may produce ammonia and toxic oxides of carbon, nitrogen, potassium, phosphorous, and/or sulfur. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Use good housekeeping practices. Sweep up spills. As a general practice, avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling. Remove to approved landfill. See label for specific disposal procedures. 7. HANDLING AND STORAGE HANDLING: See label. Wash hands with soap and water after handling product. Avoid container breakage. Avoid inhalation or contact with skin, eyes, or clothing. Keep out of lakes, streams or ponds, KEEP OUT OF REACH OF CHILDREN. STORAGE: See label. KEEP OUT OF REACH OF CHILDREN. Avoid container breakage. Store in cool, dry area in closed container or package. Keep away from feed or foodstuffs. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Use adequate ventilation to keep the airborne concentrations of this material below the recommended exposure standard. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: See label. Protective eye wear is typically not required for normal product use. SKIN: See label. No special protective clothing is necessary under normal use conditions. Gardening gloves are suggested for repeated handling of lawn care products. Applicators should wear long-sleeved shirt, long pants, shoes, and socks. Page 2 of 4 Miracle-Gro® Pro Select™ All Purpose Plant Food 20-20-20 9/21/2004 file://K:\100204.htm Page 251 of 553 Page 251 of 553 Page 251 of 553 Page 251 of 553 ---PAGE BREAK--- RESPIRATORY: See label. No special respiratory protection is required under normal use conditions. However, if operating conditions create high airborne concentrations of product, a dust mask, or other appropriate respiratory protection is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Solid APPEARANCE: Granular. 10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: Extreme heat, protect from moisture. STABILITY: Stable POLYMERIZATION: Will not occur HAZARDOUS DECOMPOSITION PRODUCTS: Nitrates are incompatible with strong alkalies and reducing agents, active metals (such as aluminum and magnesium), ammonia, organic, and combustible materials. Urea is incompatible with strong oxidizers, alkalies, sodium nitrite, and chlorine compounds (including bleach and similar household cleaning products). See product label for ingredients and storage precautions. 11. TOXICOLOGICAL INFORMATION ACUTE EYES: Not an eye irritant (rabbit) for a similar formulation. DERMAL LD50: >2,000 mg/kg (rabbit) for a similar formulation. ORAL LD50: >5,000 mg/kg (rat) for a similar formulation. SKIN EFFECTS: Primary Dermal Irritation (rabbit): Non-irritating and non-staining for a similar formulation. CARCINOGENICITY: CARCINOGENICITY COMMENTS: IARC: No; NTP: No; OSHA: No GENERAL COMMENTS: Results of acute toxicity studies conducted on a comparable formulaton accorrding to Consumer Product Safety Commission testing methods (Oral; 15003.(i), Dermal (1500.41), Eye Irritation (1500.42), and Primary Skin Irritation (1500.41) indicate this product is "Non-Hazardous" as defined by 29 CFR, Part 1910.1200. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: See label. Keep out of lakes, streams, or ponds. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose in normal waste disposal. Do not reuse empty container. See label for specific product disposal recommendations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not DOT regulated. SPECIAL SHIPPING NOTES: The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements technical name) and mode-specific or quantity-specific Page 3 of 4 Miracle-Gro® Pro Select™ All Purpose Plant Food 20-20-20 9/21/2004 file://K:\100204.htm Page 252 of 553 Page 252 of 553 Page 252 of 553 Page 252 of 553 ---PAGE BREAK--- shipping requirements. 15. REGULATORY INFORMATION GENERAL COMMENTS: Contact local authorities for proper disposal of large quantities of unused product. 16. OTHER INFORMATION REVISION SUMMARY New MSDS NFPA CODES HEALTH: 1 FIRE: 0 REACTIVITY: 0 MANUFACTURER DISCLAIMER: The information contained herein is, to the best of the Manufacturer's (see Section 1) knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and the Manufacturer shall not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, the Manufacturer shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. ADDITIONAL MSDS INFORMATION: NFPA Hazard Rating: 0=Least; 1=Slight; 2=Moderate; 3=High; 4=Severe. GENERAL STATEMENTS: This document contains health, safety, and environmental information useful to emergency response agencies, health care providers, manufacturers, and workers/employees. It does not replace the precautionary language, use directions, or the storage and disposal information found on the product label. Page 4 of 4 Miracle-Gro® Pro Select™ All Purpose Plant Food 20-20-20 9/21/2004 file://K:\100204.htm Page 253 of 553 Page 253 of 553 Page 253 of 553 Page 253 of 553 ---PAGE BREAK--- Return to search screen SCHERING-PLOUGH HEALTHCARE PRODUCTS, INC. MATERIAL SAFETY DATA SHEET INFORMATION-(901)320-2783 SAFETY/ENVIRONMENTAL AFFAIRS PRODUCT NAME: Muskol Aerosol Insect Repellent (40%) PAGE 1 OF 3 ITEM NUMBER: 01500 RB NUMBER: 920-163 This MSDS Compiled By: David McVoy Data Sheet Number: 920163 Manufacturer: Schering-Plough HealthCare Products, Inc. Prepared: 05/08/97 Address: 3030 Jackson Avenue Supersedes: 07/07/89 Memphis, TN 38151 ATTN. PLANT MANAGER/SAFETY DIRECTOR SECTION I HAZARDOUS COMPONENTS If present, IARC, NTP, and OSHA carcinogens, and chemicals subject to the reporting requirements of SARA Title III Sections 311, 312 and 313 are identified in this section. Ingredient CAS # %By Wt. OSHA ACGIH Notes Propellant A-31 (PEL) (TLV) (Isobutane) 75-28-5 8-10 NE NE 1 Ethyl Alcohol 64-17-5 50 1000ppm 1000ppm 2 DEET 134-62-3 40 NE NE 1, 3 SARA Title III Section 311, 312, 313: Not reportable (Consumer Product Exemption) In Bulk - 312/Flammable NOTES: 1. NE = Not established 2. 1900 mg/m3 TWA 3. DEET= N,N'-Diethyl-m-Toluimide. SECTION II PHYSICAL DATA Boiling Pt.: 10.9 o F (propellant) Specific Gravity: <1 Vapor Pressure: (70 o F) 45.1 psi Percent Volatile: Approx. 60% Vapor Density(air=1): ND Evaporation Rate(ether=1): ND Melting/Dropping Pt.: NA Solubility in Water: Page 254 of 553 Page 254 of 553 Page 254 of 553 Page 254 of 553 ---PAGE BREAK--- ND Appearance/Odor: Clear spray with characteristic odor. Abbreviations: ND=Not determined NA=Not applicable SECTION III FIRE AND EXPLOSION INFORMATION Flash Point: -120 o F * Open Cup Flammable Limits-LEL: 1.8 * UEL: 8.4 * Extinguishing Media: WATER x CO2 x FOAM x OTHER: Dry chemical Special Firefighting Procedures: Confine fire to immediate area. Disperse liquid or vapor. Unusual Fire and Explosion Hazards: Fire hazard-Dangerous. Can react with oxidizing materials. Explosive hazard - Severe. * Data is for propellant. PRODUCT NAME: Muskol Aerosol Insect Repellent (40%) PAGE 2 OF 3 SECTION IV REACTIVITY DATA Stability Under Normal Conditions: STABLE Conditions to Avoid: NA Incompatible Materials(Materials to avoid): Strong Oxidizers Others: Acetyl Chloride Hazardous Polymerization: Will Not Occur Conditions to Avoid: None known Hazardous Decomposition or Byproducts: Burning may produce carbon monoxide and carbon dioxide. SECTION V HEALTH HAZARD DATA Primary Route(s) of Entry: Inhalation x Skin x Ingestion x Effects of Overexposure: Acute: Eyes- Spray may cause irritation. Skin- Prolonged contact may irritate some susceptible persons. Inhalation- High concentrations are irritating to the respiratory tract. Ingestion- May cause gastrointestinal disturbances, nausea, and vomiting. Chronic: May cause headaches and dizziness, anesthetic and other central nervous system effects. First Aid Procedures: Eyes: Flush with large amounts of water Skin: Not expected to have any health effect. Flush with water or wash with soap and rinse well. Inhalation: Leave area of high concentration. Get medical attention if respiratory irritation persists. Give artificial respiration if breathing stops. Ingestion: Do not induce vomiting. Get prompt medical attention. SECTION VI PROTECTION CONTROL MEASURES Page 255 of 553 Page 255 of 553 Page 255 of 553 Page 255 of 553 ---PAGE BREAK--- Eye Protection: None for consumer package. Avoid spraying into eyes. Skin Protection: None for consumer package. Respiratory Protection: None for consumer package. Other Protective Clothing or Equipment: In bulk: Eye, skin, and respiratory protection as required. Ventilation: Local exhaust above 0.05 LEL Mechanical exhaust below 0.05 LEL PRODUCT NAME: Muskol Aerosol Insect Repellent (40%) PAGE 3 OF 3 SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Handling and Storage: Store in well ventilated area. Mechanical ventilation recommended when used in confined area or heated above ambient temperature. Spill and Leak Procedures: Remove all ignition sources. Vent room and low lying areas. Prevent bulk liquid from entering sewers or watercourses. Absorb liquid with a non-combustible solid absorbent and dispose of properly. Waste Disposal Method: Dispose of in accordance with all federal, state and local regulations. Hazardous Waste 40 CFR 261: No for consumer Hazardous Waste Number: None for consumer Container Disposal: Do not incinerate. Discharge any remaining propellant at a moderate rate away from any ignition source. SECTION VIII SHIPPING DATA (DOMESTIC GROUND TRANSPORTATION) D.O.T. Proper Shipping Name(49 CFR 172.101-102): Consumer commodity ID None D.O.T. Hazard Classification(49 CFR 172.101-102) Primary: ORM-D D.O.T. Labels Required(49 CFR 172.101-102): None D.O.T. Placards Required(49 CFR 172.504): None Poison Constituent(49 CFR 172.203(k)): N/A Hazardous Substance(49 CFR CERCLA List) No Reportable Quantities(R.Q.): 100 pounds (45.4 kg.) SECTION IX PRECAUTIONS OR OTHER COMMENTS The information accumulated herein is believed to be accurate but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances of exposure and use. Page 256 of 553 Page 256 of 553 Page 256 of 553 Page 256 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET . 1. Product and Company Identification space Product Name OfficeMax® Compressed Gas Duster space Synonym(s) Model # OM96090 Model OM96091 Model OM96092 Model Model # space CAS # Mixture space Product use Dust control space Manufacturer Falcon Safety Products, Inc. 25 Imclone Drive Branchburg, NJ 08876 US Phone: 1-[PHONE REDACTED] space Supplier OfficeMax 263 Shuman Blvd Naperville, IL 60563 US Phone 1-[PHONE REDACTED] space #19638 Page 1 of 6 Issue date 28-Oct-2009 LEGEND HMIS/NFPA Health / 1 4 Flammability 4 Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 1 1 Physical Hazard 1 Personal Protection X . 2. Hazards Identification space Emergency overview DANGER Flammable gas. Contents under pressure. Containers may explode when heated. space Potential short term health effects Routes of exposure Eye, Skin contact, Inhalation. space space space space space Eyes Contact with liquid may cause frostbite. Skin Contact with liquid may cause frostbite. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Vapors may cause dizziness or suffocation. Ingestion Not a normal route of exposure. Target organs Eyes. Skin. Respiratory system. space Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. space Signs and may include redness, edema, drying, defatting and cracking of the skin. . 3. Composition / Information on Ingredients space Ingredient(s) CAS # Percent Ethane, 1,1-difluoro- 75-37-6 60 - 100 . 4. First Aid Measures space First aid procedures Eye contact space Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Skin contact Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. Page 257 of 553 Page 257 of 553 Page 257 of 553 Page 257 of 553 ---PAGE BREAK--- #19638 Page 2 of 6 Issue date 28-Oct-2009 space space space Inhalation If develop, move victim to fresh air. If persist, obtain medical attention. If breathing has stopped, trained personnel should administer CPR immediately. Ingestion Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. General advice Do not puncture or incinerate container. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. . 5. Fire Fighting Measures space Flammable properties Flammable by WHMIS/OSHA criteria. Containers may explode when heated. space Extinguishing media Suitable extinguishing media Do not extinguish burning gas if flow cannot be shut off immediately. Use water spray or fog nozzle to keep cylinder cool space space Small Fires: Dry chemical. Carbon dioxide. Water spray. Fog. Unsuitable extinguishing media Not available Protection of firefighters Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. Cool containers with flooding quantities of water until well after fire is out. space space Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. Hazardous combustion products May include and are not limited to: Oxides of carbon. Fluoride gases. space Explosion data space Sensitivity to mechanical impact Not available Sensitivity to static discharge Not available . 6. Accidental Release Measures space Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. space Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. space Methods for cleaning up Before attempting clean up, refer to hazard data given above. Remove sources of ignition. Although the chance of a significant spill or leak is unlikely in aerosol containers, in the event of such an occurrence, absorb spilled material with a non-flammable absorbent such as sand or vermiculite. . 7. Handling and Storage space Handling Avoid breathing mists or aerosols of this product. Use good industrial hygiene practices in handling this material. space Storage Keep out of reach of children. Do not store at temperatures above 49 °C (120.2°F). Keep away from heat, open flames or other sources of ignition. . 8. Exposure Controls / Personal Protection space Exposure limits Ingredient(s) Ethane, 1,1-difluoro- Exposure Limits ACGIH-TLV Not established OSHA-PEL Not established space Engineering controls Use only under good ventilation conditions or with respiratory protection. space Personal protective equipment Eye / face protection Wear safety glasses with side shields. Page 258 of 553 Page 258 of 553 Page 258 of 553 Page 258 of 553 ---PAGE BREAK--- #19638 Page 3 of 6 Issue date 28-Oct-2009 space space space space Hand protection If there is constant skin contact, rubber gloves are recommended. Skin and body protection As required by employer code. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands and face before breaks and immediately after handling the product. . 9. Physical and Chemical Properties space Appearance Clear. space Color Colorless space Form Liquefied gas space Odor Slight ethereal. space Odor threshold Not available space Physical state Gas space pH Not applicable space Melting point Not available space Freezing point Not available space Boiling point -25 °C (-13.00 space Flash point -50 °C (-58.00 space Pour point Not available space Evaporation rate Not available space Flammability limits in air, lower, % by volume space Flammability limits in air, upper, % by volume space 3.9 16.9 Vapor pressure 599.43 kPa @25°C space Vapor density 2.4 @25°C (air=1) space Specific gravity 0.91 space Relative density 0.9 g/cc @25°C space Octanol/water coefficient Not available space Solubility (H2O) space Auto-ignition temperature 454 °C (849.20 space Percent volatile 100 . 10. Stability and Reactivity space Chemical stability Stable under recommended storage conditions. space Conditions to avoid Aerosol containers are unstable at temperatures above 49°C (120.2°F). space Incompatible materials Alkaline materials. Alkaline earth metals. space Hazardous decomposition products May include and are not limited to: Oxides of carbon. Fluoride gases. space Possibility of hazardous reactions Hazardous polymerization does not occur. . 11. Toxicological Information space Component analysis - LC50 Ingredient(s) Ethane, 1,1-difluoro- space Component analysis - Oral LD50 Ingredient(s) Ethane, 1,1-difluoro- space Effects of acute exposure Eye LC50 > 64000 ppm rat LD50 1500 mg/kg rat Contact with liquid may cause frostbite. space Skin Contact with liquid may cause frostbite. Page 259 of 553 Page 259 of 553 Page 259 of 553 Page 259 of 553 ---PAGE BREAK--- #19638 Page 4 of 6 Issue date 28-Oct-2009 space space space Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Vapors may cause dizziness or suffocation. Ingestion Not a normal route of exposure. Sensitization Non-hazardous by WHMIS/OSHA criteria. space Chronic effects Non-hazardous by WHMIS/OSHA criteria. space Carcinogenicity Non-hazardous by WHMIS/OSHA criteria. space Mutagenicity Non-hazardous by WHMIS/OSHA criteria. space Reproductive effects Non-hazardous by WHMIS/OSHA criteria. space Teratogenicity Non-hazardous by WHMIS/OSHA criteria. space Synergistic Materials Not available . 12. Ecological Information space Ecotoxicity Not available space Environmental effects Not available space Aquatic toxicity Not available space Persistence / degradability Not available space Bioaccumulation / accumulation Not available space Partition coefficient Not available space Mobility in environmental media Not available space Chemical fate information Not available space Other adverse effects Not available . 13. Disposal Considerations space Waste codes Not available space Disposal instructions Review federal, state/provincial, and local government requirements prior to disposal. space Waste from residues / unused products space Not available Contaminated packaging Not available . 14. Transport Information space U.S. Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Packaging exceptions 1,1-Difluoroethane 2.1 1030 ORM-D (applicable to containers up to 1 L) Page 260 of 553 Page 260 of 553 Page 260 of 553 Page 260 of 553 ---PAGE BREAK--- #19638 Page 5 of 6 Issue date 28-Oct-2009 space Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Packaging exceptions space IATA/ICAO (Air) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Maximum net quantity packaging . 1,1-Difluoroethane 2.1 1030 Limited quantity (containers up to 125mL) 1,1-Difluoroethane 2.1 1030 Forbidden 15. Regulatory Information space Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada - CEPA - Schedule I - List of Toxic Substances Ethane, 1,1-difluoro- 75-37-6 Totally halogenated chlorofluorocarbons that have the molecular formula quantities that may be manufactured or imported; Prohibition on manufacture, use, sale, offer for sale, import or export except for authorized uses [SOR/89-351, s. 16; 90-453, s. 5; 94-408, s. 24; 92-507, s. 17; 96-237, s. 5] space US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. space CERCLA/SARA Hazardous Substances - Not applicable. Occupational Safety and Health Administration (OSHA) space 29 CFR 1910.1200 hazardous chemical Yes CERCLA (Superfund) reportable quantity None space Superfund Amendments and Reauthorization Act of 1986 (SARA) space space Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No No space Section 311 hazardous chemical Yes Clean Air Act (CAA) Not available space Clean Water Act (CWA) Not available Page 261 of 553 Page 261 of 553 Page 261 of 553 Page 261 of 553 ---PAGE BREAK--- #19638 Page 6 of 6 Issue date 28-Oct-2009 space WHMIS status Controlled space WHMIS classification Class A - Compressed Gas, Class B - Division 1 - Flammable Gas space WHMIS labeling space State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. U.S. - Louisiana - Reportable Quantity List for Pollutants Ethane, 1,1-difluoro- 75-37-6 5000 Lb final RQ; 2270 kg final RQ U.S. - Massachusetts - Right To Know List Ethane, 1,1-difluoro- 75-37-6 Present U.S. - New Jersey - Right to Know Hazardous Substance List Ethane, 1,1-difluoro- 75-37-6 sn 0715 space Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory No Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) . 16. Other Information space Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. space Issue date 28-Oct-2009 space Effective date 15-Oct-2009 space Expiry date 15-Oct-2012 space Prepared by Dell Tech Laboratories Ltd. (519) 858-5021 space Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. Page 262 of 553 Page 262 of 553 Page 262 of 553 Page 262 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET . 1. Product and Company Identification space Product Name OfficeMax® Compressed Gas Duster space Synonym(s) Model # OM96090 Model OM96091 Model OM96092 Model Model # space CAS # Mixture space Product use Dust control space Manufacturer Falcon Safety Products, Inc. 25 Imclone Drive Branchburg, NJ 08876 US Phone: 1-[PHONE REDACTED] space Supplier OfficeMax 263 Shuman Blvd Naperville, IL 60563 US Phone 1-[PHONE REDACTED] space #19638 Page 1 of 6 Issue date 28-Oct-2009 LEGEND HMIS/NFPA Health / 1 4 Flammability 4 Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 1 1 Physical Hazard 1 Personal Protection X . 2. Hazards Identification space Emergency overview DANGER Flammable gas. Contents under pressure. Containers may explode when heated. space Potential short term health effects Routes of exposure Eye, Skin contact, Inhalation. space space space space space Eyes Contact with liquid may cause frostbite. Skin Contact with liquid may cause frostbite. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Vapors may cause dizziness or suffocation. Ingestion Not a normal route of exposure. Target organs Eyes. Skin. Respiratory system. space Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. space Signs and may include redness, edema, drying, defatting and cracking of the skin. . 3. Composition / Information on Ingredients space Ingredient(s) CAS # Percent Ethane, 1,1-difluoro- 75-37-6 60 - 100 . 4. First Aid Measures space First aid procedures Eye contact space Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Skin contact Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. Page 263 of 553 Page 263 of 553 Page 263 of 553 Page 263 of 553 ---PAGE BREAK--- #19638 Page 2 of 6 Issue date 28-Oct-2009 space space space Inhalation If develop, move victim to fresh air. If persist, obtain medical attention. If breathing has stopped, trained personnel should administer CPR immediately. Ingestion Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. General advice Do not puncture or incinerate container. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. . 5. Fire Fighting Measures space Flammable properties Flammable by WHMIS/OSHA criteria. Containers may explode when heated. space Extinguishing media Suitable extinguishing media Do not extinguish burning gas if flow cannot be shut off immediately. Use water spray or fog nozzle to keep cylinder cool space space Small Fires: Dry chemical. Carbon dioxide. Water spray. Fog. Unsuitable extinguishing media Not available Protection of firefighters Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. Cool containers with flooding quantities of water until well after fire is out. space space Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. Hazardous combustion products May include and are not limited to: Oxides of carbon. Fluoride gases. space Explosion data space Sensitivity to mechanical impact Not available Sensitivity to static discharge Not available . 6. Accidental Release Measures space Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. space Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. space Methods for cleaning up Before attempting clean up, refer to hazard data given above. Remove sources of ignition. Although the chance of a significant spill or leak is unlikely in aerosol containers, in the event of such an occurrence, absorb spilled material with a non-flammable absorbent such as sand or vermiculite. . 7. Handling and Storage space Handling Avoid breathing mists or aerosols of this product. Use good industrial hygiene practices in handling this material. space Storage Keep out of reach of children. Do not store at temperatures above 49 °C (120.2°F). Keep away from heat, open flames or other sources of ignition. . 8. Exposure Controls / Personal Protection space Exposure limits Ingredient(s) Ethane, 1,1-difluoro- Exposure Limits ACGIH-TLV Not established OSHA-PEL Not established space Engineering controls Use only under good ventilation conditions or with respiratory protection. space Personal protective equipment Eye / face protection Wear safety glasses with side shields. Page 264 of 553 Page 264 of 553 Page 264 of 553 Page 264 of 553 ---PAGE BREAK--- #19638 Page 3 of 6 Issue date 28-Oct-2009 space space space space Hand protection If there is constant skin contact, rubber gloves are recommended. Skin and body protection As required by employer code. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands and face before breaks and immediately after handling the product. . 9. Physical and Chemical Properties space Appearance Clear. space Color Colorless space Form Liquefied gas space Odor Slight ethereal. space Odor threshold Not available space Physical state Gas space pH Not applicable space Melting point Not available space Freezing point Not available space Boiling point -25 °C (-13.00 space Flash point -50 °C (-58.00 space Pour point Not available space Evaporation rate Not available space Flammability limits in air, lower, % by volume space Flammability limits in air, upper, % by volume space 3.9 16.9 Vapor pressure 599.43 kPa @25°C space Vapor density 2.4 @25°C (air=1) space Specific gravity 0.91 space Relative density 0.9 g/cc @25°C space Octanol/water coefficient Not available space Solubility (H2O) space Auto-ignition temperature 454 °C (849.20 space Percent volatile 100 . 10. Stability and Reactivity space Chemical stability Stable under recommended storage conditions. space Conditions to avoid Aerosol containers are unstable at temperatures above 49°C (120.2°F). space Incompatible materials Alkaline materials. Alkaline earth metals. space Hazardous decomposition products May include and are not limited to: Oxides of carbon. Fluoride gases. space Possibility of hazardous reactions Hazardous polymerization does not occur. . 11. Toxicological Information space Component analysis - LC50 Ingredient(s) Ethane, 1,1-difluoro- space Component analysis - Oral LD50 Ingredient(s) Ethane, 1,1-difluoro- space Effects of acute exposure Eye LC50 > 64000 ppm rat LD50 1500 mg/kg rat Contact with liquid may cause frostbite. space Skin Contact with liquid may cause frostbite. Page 265 of 553 Page 265 of 553 Page 265 of 553 Page 265 of 553 ---PAGE BREAK--- #19638 Page 4 of 6 Issue date 28-Oct-2009 space space space Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Vapors may cause dizziness or suffocation. Ingestion Not a normal route of exposure. Sensitization Non-hazardous by WHMIS/OSHA criteria. space Chronic effects Non-hazardous by WHMIS/OSHA criteria. space Carcinogenicity Non-hazardous by WHMIS/OSHA criteria. space Mutagenicity Non-hazardous by WHMIS/OSHA criteria. space Reproductive effects Non-hazardous by WHMIS/OSHA criteria. space Teratogenicity Non-hazardous by WHMIS/OSHA criteria. space Synergistic Materials Not available . 12. Ecological Information space Ecotoxicity Not available space Environmental effects Not available space Aquatic toxicity Not available space Persistence / degradability Not available space Bioaccumulation / accumulation Not available space Partition coefficient Not available space Mobility in environmental media Not available space Chemical fate information Not available space Other adverse effects Not available . 13. Disposal Considerations space Waste codes Not available space Disposal instructions Review federal, state/provincial, and local government requirements prior to disposal. space Waste from residues / unused products space Not available Contaminated packaging Not available . 14. Transport Information space U.S. Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Packaging exceptions 1,1-Difluoroethane 2.1 1030 ORM-D (applicable to containers up to 1 L) Page 266 of 553 Page 266 of 553 Page 266 of 553 Page 266 of 553 ---PAGE BREAK--- #19638 Page 5 of 6 Issue date 28-Oct-2009 space Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Packaging exceptions space IATA/ICAO (Air) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Maximum net quantity packaging . 1,1-Difluoroethane 2.1 1030 Limited quantity (containers up to 125mL) 1,1-Difluoroethane 2.1 1030 Forbidden 15. Regulatory Information space Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada - CEPA - Schedule I - List of Toxic Substances Ethane, 1,1-difluoro- 75-37-6 Totally halogenated chlorofluorocarbons that have the molecular formula quantities that may be manufactured or imported; Prohibition on manufacture, use, sale, offer for sale, import or export except for authorized uses [SOR/89-351, s. 16; 90-453, s. 5; 94-408, s. 24; 92-507, s. 17; 96-237, s. 5] space US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. space CERCLA/SARA Hazardous Substances - Not applicable. Occupational Safety and Health Administration (OSHA) space 29 CFR 1910.1200 hazardous chemical Yes CERCLA (Superfund) reportable quantity None space Superfund Amendments and Reauthorization Act of 1986 (SARA) space space Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No No space Section 311 hazardous chemical Yes Clean Air Act (CAA) Not available space Clean Water Act (CWA) Not available Page 267 of 553 Page 267 of 553 Page 267 of 553 Page 267 of 553 ---PAGE BREAK--- #19638 Page 6 of 6 Issue date 28-Oct-2009 space WHMIS status Controlled space WHMIS classification Class A - Compressed Gas, Class B - Division 1 - Flammable Gas space WHMIS labeling space State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. U.S. - Louisiana - Reportable Quantity List for Pollutants Ethane, 1,1-difluoro- 75-37-6 5000 Lb final RQ; 2270 kg final RQ U.S. - Massachusetts - Right To Know List Ethane, 1,1-difluoro- 75-37-6 Present U.S. - New Jersey - Right to Know Hazardous Substance List Ethane, 1,1-difluoro- 75-37-6 sn 0715 space Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory No Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) . 16. Other Information space Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. space Issue date 28-Oct-2009 space Effective date 15-Oct-2009 space Expiry date 15-Oct-2012 space Prepared by Dell Tech Laboratories Ltd. (519) 858-5021 space Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. Page 268 of 553 Page 268 of 553 Page 268 of 553 Page 268 of 553 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: ORANGE TOUGH 15 Product Number: 2215; 2216 Janitorial Spartan Chemical Company , Inc. Product/Technical Information: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spill Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: Non Hazardous Products NFPA Ratings: HMIS Ratings: Health: 2 - Moderate Health: 2 - Moderate Fire: 1- Slight Fire: 1- Slight Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A Chemical Name(s) %Wt CAS Registry No. TWA mg/m 3 STEL mg/m 3 CEILING mg/m 3 NTP, IARC or OSHA Carcinogen Triethanolamine dodecylbenzenesulfonate Dipropropylene glycol monobutyl ether Triethanolamine Soybean oil methyl esters d-Limonene Alcohol ethoxylate 5-10 - 5-10 - 1-5 1-5 1-5 1-5 27323-41-7 - 29911-28-2 - 102-71-6 67784-80-9 5989-27-5 34398-01-1 Not Established - Not Established - 5 (ACGIH) Not Established Not Established Not Established Not Established - Not Established - Not Established Not Established Not Established Not Established Not Established - Not Established - Not Established Not Established Not Established Not Established No - No - No No No No SECTION III: PHYSICAL DATA Boiling Point: 212 °F Vapor Pressure: Unknown Vapor Density (AIR = Unknown Solubility in Water: Complete pH: 8.5-9.0 Specific Gravity (H2O=1): 0.995 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 15-20 Physical State: Liquid Appearance & Odor: Clear orange liquid, Orange fragrance SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: 210°F Method Used: ASTM-D56 Flammable Limits: Not Established Flame Extension: N/A Extinguishing Media: Water, carbon dioxide or dry chemical. Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. Page 269 of 553 Page 269 of 553 Page 269 of 553 Page 269 of 553 ---PAGE BREAK--- SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- Conditions to Avoid: Causes eye irritation: may include pain, redness and swelling of the conjunctiva. Causes skin irritation: may include redness, pain and swelling. Harmful if swallowed: may include pain, nausea, vomiting and diarrhea. Breathing product vapors or mist may cause respiratory irritation: may include nasal discomfort and coughing. Contains d-limonene and triethanolamine which may cause skin sensitization with repeated contact. Repeated overexposure to triethanolamine may cause liver and kidney damage. Avoid contact with eyes, skin and clothing. Avoid breathing product vapors or mists. Do not swallow. Use with adequate ventilation. Wash thoroughly after handling. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin: Remove contaminated clothing. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. Inhalation: Move person to fresh air. Get medical attention if irritation persists. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Strong acids and oxidizing agents Hazardous Decomposition Products: Carbon dioxide, carbon monoxide Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, commercial absorbent, etc.) and transfer to containers for disposal. Keep spill out of storm sewers and waterways. Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However if exposure limits are exceeded (see Section II) or if respiratory irritation occurs, the use of a NIOSH approved respirator suitable for the use-conditions and chemicals listed in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or other impervious gloves. Eye Protection(Specify Type): Splash goggles are recommended to prevent eye contact. Other Protective Equipment: See 29 CFR 1910.132-138 for further guidance. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Keep container closed. Store in a cool, dry area. Do not freeze. Do not store above 120°F. Do not mix with other chemicals. Other Precautions: Keep out of reach of children © SCC 01/09/2012 Name: Ronald T. Cook Title: Manager, Regulatory Affairs ORANGE TOUGH 15 Effective Date: 01/09/2012 Supercedes: 09/22/2008 Ref: 29 CFR 1910.1200 (OSHA) Changes: General review This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 270 of 553 Page 270 of 553 Page 270 of 553 Page 270 of 553 ---PAGE BREAK--- Latest revision date: 10/10/2011 Version: 1.0 PAGE 1 of 5 Material Safety Data Sheet United States The Ortho Group P.O. Box 190 Marysville, Ohio 43040 United States 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC 1‐800‐424‐9300 CHEMTREC (International) 1‐703‐527‐3887 Non‐Emergency Calls 1‐937‐644‐0011 ORTHO ROSE & FLOWER INSECT KILLER READY‐TO‐USE 1. Product and company identification SKU # : 034501005 EPA Registration Number: : 8033‐21‐239 MSDS # : 320000002381 2. Hazards identification Physical state : liquid [Clear liquid] Odor : odorless OSHA/HCS status : This material is/or contains a chemical that is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Emergency overview : CAUTION! Harmful if absorbed through the skin. Avoid breathing vapor or mist. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Potential chronic health effects Chronic effects : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Target organs : None known. Over‐exposure Inhalation : No specific data. Ingestion : No specific data. Skin : No specific data. Eyes : No specific data. Medical conditions aggravated by over‐exposure : Pre‐existing skin disorders may be aggravated by over‐exposure to this product. Interactions with other Chemicals : Not available. See toxicological information (section 11) 3. Composition/information on ingredients Name CAS number % acetamiprid (ISO) 135410‐20‐7 0.001 ‐ 0.01 Page 271 of 553 Page 271 of 553 Page 271 of 553 Page 271 of 553 ---PAGE BREAK--- Latest revision date: 10/10/2011 Version: 1.0 PAGE 2 of 5 4. First aid measures Eye contact : Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin contact : Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for treatment advice. Inhalation : Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth‐to‐mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion : Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Never give anything by mouth to an unconscious person. Protection of first‐aiders : No action shall be taken involving any personal risk or without suitable training. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : No specific treatment. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. 5. Fire‐fighting measures Flammability of the product : In a fire or if heated, a pressure increase will occur and the container may burst. Extinguishing media Suitable : Use an extinguishing agent suitable for the surrounding fire. Not suitable : None known. Special exposure hazards : isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products : No specific data. Special protective equipment for fire‐fighters : Fire‐fighters should wear appropriate protective equipment and self‐ contained breathing apparatus (SCBA) with a full face‐piece operated in positive pressure mode. 6. Accidental release measures Personal precautions : Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Put on appropriate personal protective equipment (see section Environmental precautions : To protect the environment, do not allow pesticide to enter or run‐off into storm drains, drainage ditches gutters or surface waters Methods for cleaning up : Stop leak if without risk. Dike spill area and do not allow product to reach soil, surface water, ground water or sewers. Contain and collect spillage with non‐combustible, absorbent material and place in container for disposal. Page 272 of 553 Page 272 of 553 Page 272 of 553 Page 272 of 553 ---PAGE BREAK--- Latest revision date: 10/10/2011 Version: 1.0 PAGE 3 of 5 7. Handling and storage Handling : Avoid inhalation or contact with skin, eyes or clothing. Avoid container breakage. Do not contaminate water sources when disposing of equipment washwater or rinsate. Keep out of lakes, stream or ponds. Keep out of reach of children. Storage : Keep from freezing. Store in original container in a cool, dry, well‐ ventilated area inaccessible to children and pets. Do not contaminate food or feedstuffs. 8. Exposure controls/personal protection Consult local authorities for acceptable exposure limits. Engineering measures : Use adequate ventilation to keep the airborne concentrations below the recommended exposure standard. Hygiene measures : Wash thoroughly with soap and water after handling. Remove and launder contaminated clothing before reuse. Personal protection Respiratory : No special respiratory protection required. If ventilation is inadequate to keep the airborne concentrations below the recommended exposure standard wear appropriate respiration protection. Hands : Protective gloves are not required, but may be used in situations were significant contact is expected. Eyes : Protective eyewear is not required, but may be used in situations were contact is expected. Skin : Wear long‐sleeved shirt, long pants, shoes with socks. Remove and wash contaminated clothing before reuse. 9. Physical and chemical properties Physical state : liquid [Clear liquid] Color : Colorless. Flash point : Not available. Auto‐ignition temperature : Not available. Odor : odorless Odor threshold : Not available. pH : 4 Boiling/condensation point : Not available. Melting/freezing point : Not available. Critical temperature : Not available. Density : 1.006 g/cm3 Vapor pressure : Not available. Vapor density : Not available. Evaporation rate : Not available. Viscosity : Not available. Solubility : Not available. Partition Coefficient octanol) : Not available. Decomposition temperature : Not available. 10. Stability and reactivity Chemical stability : The product is stable. Conditions to avoid : No specific data. Materials to avoid : No specific data. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Page 273 of 553 Page 273 of 553 Page 273 of 553 Page 273 of 553 ---PAGE BREAK--- Latest revision date: 10/10/2011 Version: 1.0 PAGE 4 of 5 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Product LD50 Oral Rat > 5,000 mg/kg ‐ Product LC50 Inhalation Rat > 2.11 mg/l 4 h Product LD50 Dermal Rat > 5,000 mg/kg ‐ Conclusion/Summary Very low toxicity to humans or animals. Irritation/Corrosion Skin Slight Eyes Minimal Respiratory Not available. Sensitizer Conclusion/Summary Skin Not sensitizing Respiratory Not available. Chronic toxicity Conclusion/Summary No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary No known significant effects or critical hazards. Mutagenicity Conclusion/Summary No known significant effects or critical hazards. Teratogenicity Conclusion/Summary No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary No known significant effects or critical hazards. 12.Ecological information Ecotoxicity No known significant effects or critical hazards. Aquatic ecotoxicity Conclusion/Summary No known significant effects or critical hazards. Persistence/degradability Conclusion/Summary No known significant effects or critical hazards. 13. Disposal considerations Waste disposal Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. Transport information Regulatory information UN no. Proper shipping name Class PG* Note DOT Not Regulated IATA Not Regulated IATA IMDG Not Regulated TDG Not Regulated Page 274 of 553 Page 274 of 553 Page 274 of 553 Page 274 of 553 ---PAGE BREAK--- Latest revision date: 10/10/2011 Version: 1.0 PAGE 5 of 5 PG* : Packing group 15. Regulatory information United States U.S. Federal regulations : California Prop. 65 : Not listed. United States inventory (TSCA 8b) : All components are listed or exempted. Canada inventory : All components are listed or exempted. 16.Other information Hazardous Material Information System : Health 1 Flammability 0 Physical hazards 0 HMIS® ratings are based on a 0‐4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). The customer is responsible for determining the PPE code for this material. National Fire Protection Association Copyright ©2001: Flammability Health Instability/Reactivity Special Latest revision date 10/10/2011 Date of previous issue 00/00/0000 Version 1.0 Notice to reader General Comment: This document contains health, safety, and environmental information useful to emergency response agencies, health care providers, manufacturers, and workers/employees. It does not replace the precautionary language, use directions, or the storage and disposal information found on the product label. Additional Information: This information contained herein is, to the best of Scott's knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and Scotts shall not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, Scotts shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. 0 0 1 Page 275 of 553 Page 275 of 553 Page 275 of 553 Page 275 of 553 ---PAGE BREAK--- Page:1/7 Latest revision date: 11/24/2013 Version: 1.1 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 10/10/2011 United States Material Safety Data Sheet The Ortho Group P.O. Box 190 Marysville, Ohio 43040 United States 24 h. EMERGENCY TELEPHONE NUMBER CHEMTREC 1-[PHONE REDACTED] CHEMTREC (International) 1-[PHONE REDACTED] Non-Emergency Calls 1-[PHONE REDACTED] ORTHO ROSE & FLOWER INSECT KILLER READY-TO-USE 1. Product and company identification MSDS # : 320000002381 EPA Registration Number: : 8033-21-239 2. Hazards identification Physical state : liquid [Clear liquid] Color : Colorless. Odor : odorless Signal word : CAUTION! OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Emergency Overview Harmful if absorbed through the skin. Avoid breathing vapor or mist. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Potential acute health effects Inhalation : Toxic by inhalation. Ingestion : No known significant effects or critical hazards. Skin : No known significant effects or critical hazards. Eyes : No known significant effects or critical hazards. Target organs : None known. Potential chronic health effects : See section 11 for more information. Over-exposure Inhalation : No specific data. Ingestion : No specific data. Skin : No specific data. Eyes : No specific data. Medical conditions aggravated by over-exposure : Pre-existing skin disorders may be aggravated by over-exposure to this product. See toxicological information (Section 11) Page 276 of 553 Page 276 of 553 Page 276 of 553 Page 276 of 553 ---PAGE BREAK--- Page:2/7 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 10/10/2011 3. Composition/information on ingredients Name CAS number % acetamiprid 135410-20-7 0.001 - 0.01 4. First aid measures Eye contact : Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin contact : Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for treatment advice. Inhalation : Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion : Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Never give anything by mouth to an unconscious person. Notes to physician : No specific treatment. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. 5. Fire-fighting measures Flammability of the product : In a fire or if heated, a pressure increase will occur and the container may burst. Extinguishing media Suitable : Use an extinguishing agent suitable for the surrounding fire. Not suitable : None known. Special exposure hazards : isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products : No specific data. Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal precautions : Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Put on appropriate personal protective equipment (see Section Environmental precautions : To protect the environment, do not allow pesticide to enter or run-off into storm drains, drainage ditches gutters or surface waters Methods for cleaning up Page 277 of 553 Page 277 of 553 Page 277 of 553 Page 277 of 553 ---PAGE BREAK--- Page:3/7 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 10/10/2011 Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Dike spill area and do not allow product to reach soil, surface water, ground water or sewers. Contain and collect spillage with non-combustible, absorbent material and place in container for disposal. 7. Handling and storage Handling : Avoid inhalation or contact with skin, eyes or clothing. Avoid container breakage. Do not contaminate water sources when disposing of equipment washwater or rinsate. Keep out of lakes, stream or ponds. Keep out of reach of children. Storage : Keep from freezing. Store in original container in a cool, dry, well- ventilated area inaccessible to children and pets. Do not contaminate food or feedstuffs. 8. Exposure controls/personal protection Occupational exposure limits No exposure standard allocated. Consult local authorities for acceptable exposure limits. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Engineering measures : Use adequate ventilation to keep the airborne concentrations below the recommended exposure standard. Hygiene measures : Wash thoroughly with soap and water after handling. Remove and launder contaminated clothing before reuse. Personal protection Respiratory : No special respiratory protection required. If ventilation is inadequate to keep the airborne concentrations below the recommended exposure standard wear appropriate respiration protection. Hands : Protective gloves are not required, but may be used in situations were significant contact is expected. Eyes : Protective eyewear is not required, but may be used in situations were contact is expected. Skin : Wear long-sleeved shirt, long pants, shoes with socks. Remove and wash contaminated clothing before reuse. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. Physical and chemical properties Page 278 of 553 Page 278 of 553 Page 278 of 553 Page 278 of 553 ---PAGE BREAK--- Page:4/7 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 10/10/2011 Physical state : liquid [Clear liquid] Flash point : Not Applicable Burning time : Not Applicable Auto-ignition temperature : Not Applicable Flammable limits : Not Applicable Density : 1.006 g/cm3 Color : Colorless. Odor : odorless pH : 4 Boiling/condensation point : Not Applicable Melting/freezing point : Not Applicable Relative density : Not Applicable Vapor pressure : Not Applicable Vapor density : Not Applicable Volatility : Not Applicable Odor threshold : Not Applicable Evaporation rate : Not Applicable Viscosity : Not Applicable Solubility : Not Applicable Solubility in water : Not Applicable 10. Stability and reactivity Chemical stability : The product is stable. Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Product LD50 Oral Rat > 5,000 mg/kg - Product LC50 Inhalation Rat > 2.11 mg/l 4 h Product LD50 Dermal Rat > 5,000 mg/kg - Conclusion/Summary Very low toxicity to humans or animals. Irritation/Corrosion Skin Slight Eyes Minimal Respiratory Not available. Sensitizer Conclusion/Summary Skin Not sensitizing Respiratory Not available. Chronic toxicity Conclusion/Summary No known significant effects or critical hazards. Carcinogenicity Page 279 of 553 Page 279 of 553 Page 279 of 553 Page 279 of 553 ---PAGE BREAK--- Page:5/7 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 10/10/2011 Conclusion/Summary No known significant effects or critical hazards. Mutagenicity Conclusion/Summary No known significant effects or critical hazards. Teratogenicity Product/ingredient name Result Species Dose Exposure Conclusion/Summary No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary No known significant effects or critical hazards. 12.Ecological information Ecotoxicity : No known significant effects or critical hazards. Aquatic ecotoxicity Conclusion/Summary : No known significant effects or critical hazards. Persistence/degradability Conclusion/Summary : No known significant effects or critical hazards. Partition coefficient: n- octanol/water : No known significant effects or critical hazards. Other adverse effects : No known significant effects or critical hazards. 13. Disposal considerations Waste disposal Disposal should be in accordance with applicable regional, national and local laws and regulations. 14.Transport information Regulatory information UN no. Proper shipping name Class PG* Note DOT Not Regulated IATA Not Regulated IATA IMDG Not Regulated TDG Not Regulated PG* : Packing group 15.Regulatory information United States U.S. Federal regulations : SARA 302/304/311/312 extremely hazardous substances: No products Page 280 of 553 Page 280 of 553 Page 280 of 553 Page 280 of 553 ---PAGE BREAK--- Page:6/7 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 10/10/2011 were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found. Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 accidental release prevention: No products were found. Clean Air Act (CAA) 112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. United States inventory (TSCA 8b) : All components are listed or exempted. State regulations Massachusetts : None of the components are listed. New York : None of the components are listed. New Jersey : None of the components are listed. : None of the components are listed. California Prop. 65 : Not listed. International regulations Canada inventory : All components are listed or exempted. International lists : Australia inventory (AICS): Not determined. New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Philippines inventory (PICCS): Not determined. 16.Other information Hazardous Material Information System : Health 1 Flammability 0 Physical hazards 0 Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR Page 281 of 553 Page 281 of 553 Page 281 of 553 Page 281 of 553 ---PAGE BREAK--- Page:7/7 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 10/10/2011 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection Association Flammability Health Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of printing : Print date Date of issue : Validity date***. Version : Report version.Report version Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 0 0 1 Page 282 of 553 Page 282 of 553 Page 282 of 553 Page 282 of 553 ---PAGE BREAK--- Page 283 of 553 Page 283 of 553 Page 283 of 553 Page 283 of 553 ---PAGE BREAK--- Page 284 of 553 Page 284 of 553 Page 284 of 553 Page 284 of 553 ---PAGE BREAK--- Page 285 of 553 Page 285 of 553 Page 285 of 553 Page 285 of 553 ---PAGE BREAK--- Page 286 of 553 Page 286 of 553 Page 286 of 553 Page 286 of 553 ---PAGE BREAK--- Page 287 of 553 Page 287 of 553 Page 287 of 553 Page 287 of 553 ---PAGE BREAK--- Page 288 of 553 Page 288 of 553 Page 288 of 553 Page 288 of 553 ---PAGE BREAK--- Page 289 of 553 Page 289 of 553 Page 289 of 553 Page 289 of 553 ---PAGE BREAK--- Page 290 of 553 Page 290 of 553 Page 290 of 553 Page 290 of 553 ---PAGE BREAK--- Page 291 of 553 Page 291 of 553 Page 291 of 553 Page 291 of 553 ---PAGE BREAK--- Page 292 of 553 Page 292 of 553 Page 292 of 553 Page 292 of 553 ---PAGE BREAK--- Page 293 of 553 Page 293 of 553 Page 293 of 553 Page 293 of 553 ---PAGE BREAK--- Page 294 of 553 Page 294 of 553 Page 294 of 553 Page 294 of 553 ---PAGE BREAK--- Page 295 of 553 Page 295 of 553 Page 295 of 553 Page 295 of 553 ---PAGE BREAK--- Page 296 of 553 Page 296 of 553 Page 296 of 553 Page 296 of 553 ---PAGE BREAK--- Page 297 of 553 Page 297 of 553 Page 297 of 553 Page 297 of 553 ---PAGE BREAK--- Page 298 of 553 Page 298 of 553 Page 298 of 553 Page 298 of 553 ---PAGE BREAK--- POL Hazbrdous Mat-erials Information System DoD 6050.5-L AS OF Juiy 1998 FSC: 5610 NIIN: [PHONE REDACTED] Manufacturer's CAGE: 77699 Part llc. Indicator: A Part Numt?er/Trade Name: P?.TCHING PLASTER General Information It em Name : Company's Name: BOMDEX INTERN-qTIONAL INC Company's Street: 3616 SCARLET OAK 3LVD Company's P. 0. Box: Company's City: ST LOUIS Company's State: MO Company's Country: GS rompany's Zip Code: 63122-6605 Company's Emerj E'h b : [PHONE REDACTED]; 31?-225-Ki;8 Company's Info Ph # : [PHONE REDACTED]; [PHONE REDACTED] !?istributor/Vendor # 1: Discrib;t3r/i7en6or # 1 Cage: Gistria~~~or,"'lendor # 2 : Cistri:~ L,L~r;Vindor - r # 2 C & q e : Distrihutor/Vendor # 3: Uistrihutsr/Vendcr # 3 C a q ~ : Disrrib,;cr;Vefids= C 4 : Distr:butor/Vendar k 4 Cage: Safety Lata Eccion Code: Safety Fccal ?oinz: t l Xecord Elc. Far Saiecyi Ezcry: 001 Tot Safety 2n:rie.s Thi: Stk#: 001 Scat-ds: SFI; Date FISDS Prepared: ,5FE345 Safety Data Review Dat?: ?8CCT97 Supply Item Manager: MSDS Preparer's Name: Preparer's Company: Preparer's St Or P. 0. Box: Preparer's City: Preparer's State: Preparer's Zip Code: Other MSDS Number: MSDS Serial Number: Specification Number: Spec Type, Grade, Class: Hazard Characteristic Code: Unit Of Issue: Unit Of Issue Container Qty: Type Of Coctainer: Net Unit Weight: Report for NIIN: 00N079586 NRC/State License Number: Net Explosive Weight: Net Propellant Weight-Ammo: Coast Guard Ammunitirjn Code: Ingredients/Identity Information Page 299 of 553 Page 299 of 553 Page 299 of 553 Page 299 of 553 ---PAGE BREAK--- Proprietary: NO Ingreoiacc. : SijL'URIC ACID, CALCIUL,; S A T (1 : I! ; (CALCIUM SULFATE) Ingredient Sequence Number: Zl Percent: N/K ingredient Act ion Code: Ingredien; Focal Poict: N NiOSH (RTECS) Number: WS69.20000 CAS Number: 7778-18-9 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST Other Recommendfd Limit: N/K Proprietary: NO ingredient: CALCIUM CARSONATE Ingredient Sequence Number: 02 Percen~: N/K Tngredient ActiorL Code: Ingreaient Focai Point: N NIOSH (RTECS! Kurnbar: EV958iiil00 CAS Number: 1317-65-3 OSHA PEL: 15 MG/Pl3 TDUST .z.CGIH TLi': 10 IS,G/M3 T5;IS'I C:?ier 3ecorrmenaed iin~it : :K ~ ~ - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - . - - - - - - - - - - Physical/Chemical Characteristics ~ .:.spcaronze 2nd Odor: WEITE; CCST S3GR. Boiling Point: N/A Melting Point: N/A Vapor Pzessure (f.414 Hg/70 " : N/A T T - :<,par 3easif:y (Air=:) : 1.25 Specific Gra~~icy: N/A Cecomposition Temperatare : PI/K Evaporation Kate And Ref: NOT APPLICABLE Solubility In Water: Percent Volatiles By Volume: N/K Viscosity: pH: N/K Radioactivity: Form (Radioactive Matl) : Magnetism (Milligauss): Corrosion Rate (IPY) : N/K Autoignition Temperature: Report for NIIN: 00N079586 Fire and Explosion Hazard Data Flash Point: N/K Flash Point Method: N/P Lower Explosive Limit: N/K Upper Explosive Limit: N/K Extinguishing Media: ANY MEDIA. Special Fire Fighting Proc: USE NiOSH APPROVED SCEA & FULL PROTECTIVE EQUIPMENT (FP N) . Unusual Fire And Expl Hazrds: NON-FLAMMABLE. Reactivity Data Page 2 Page 300 of 553 Page 300 of 553 Page 300 of 553 Page 300 of 553 ---PAGE BREAK--- Stability: YES Cond 3 AA-oid (Stabiiity; : NONE SPECIFIED EY MANUFACTURER. Materiais To AT,!cid: NOT APPLICABLE Decomp Products: NOT APPLICABLE Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT ~ ~ ~ Health Hazard Data LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE:INHALATION:NUISANCE DUST. INGESTION: MAY BE HARMFUL. SXINjEYE C0NTACT:IRRITANT. CHRON1C:NOT APPLICABLE. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenizity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT Signs Of 0 - ~ e r e x ~ : SEE HEAL" HAZARDS. Med Cond Aggravated By Exp: NOT APPLICABLE Emer~ezcy/First Aid Proc: 1NHAL:P.EMOVE TO FREES AIR. SUPPORT (GTVE O'2iARTF RESP) (FP N) . 1NGESY:DRI:IK PLENTY OF WATER. GET MEDICAL .4TTETJTIOK. SKIN:W.G.S;i C\'/SOA? & WATER. EYES: FLUSH W/WATES FOR AT LEAST 15 I":ISaTE.? 5 GET NE>ICAL ,?iTTEP 5,000 mg/kg Page 328 of 553 Page 328 of 553 Page 328 of 553 Page 328 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.2 Print Date 04/01/2009 Revision Date 03/26/2009 MSDS Number 350000010777 6/8 Acute inhalation toxicity : LC50 rat Dose: > 5.47 mg/l Acute dermal toxicity : LD50 rabbit Dose: > 5,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : Not known to be a sensitizer. 12. ECOLOGICAL INFORMATION Ecotoxicity effects : Harmful to aquatic organisms; may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS Industrial setting : Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Household setting : Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION Land transport U.S. DOT and Canadian TDG Surface Transportation: UN-Number 1950 Proper shipping name Aerosols, flammable Class: 2.1 Packaging group: None. Note: SC Johnson ships this product as Consumer Commodity ORM-D (non-bulk packages) Page 329 of 553 Page 329 of 553 Page 329 of 553 Page 329 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.2 Print Date 04/01/2009 Revision Date 03/26/2009 MSDS Number 350000010777 7/8 Sea transport IMDG: Class: 2.1 Packaging group: None. Proper shipping name Aerosols, flammable UN-Number: 1950 Note: SC Johnson ships this product as "Limited Quantity" when the container quantity value is 1 Liter or less. Air transport ICAO/IATA: Class: 2.1 Packaging group: None. Proper shipping name Aerosols, flammable UN/ID No.: UN 1950 Note: SC Johnson typically does not ship products via air, therefore it has not been determined if the product container meets current IATA/ICAO package criteria. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air. 15. REGULATORY INFORMATION Global Chemical Inventories Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects. EPA Registration Number : 4822-553 16. OTHER INFORMATION HMIS Ratings Page 330 of 553 Page 330 of 553 Page 330 of 553 Page 330 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.2 Print Date 04/01/2009 Revision Date 03/26/2009 MSDS Number 350000010777 8/8 Health 2 Flammability 3 Reactivity 0 NFPA Ratings Health 2 Fire 3 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 331 of 553 Page 331 of 553 Page 331 of 553 Page 331 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 1/14 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : RAID® WASP & HORNET KILLER 33 Recommended use : Insecticide Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Aerosol Category 1 Extremely flammable aerosol. Aspiration hazard Category 1 May be fatal if swallowed and enters airways. Gases under pressure Compressed gas Contains gas under pressure; may explode if heated. Labelling Hazard symbols Flame Gas cylinder Health hazard Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Precautionary statements If medical advice is needed, have product container or label at hand. Page 332 of 553 Page 332 of 553 Page 332 of 553 Page 332 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 2/14 Keep out of reach of children. Read label before use. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 122 Protect from sunlight. Store in a well-ventilated place. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Distillates (petroleum), hydrotreated light 64742-47-8 60.00 - 100.00 Carbon dioxide 124-38-9 1.00 - 5.00 Isopropanol 67-63-0 1.00 - 5.00 Cypermethrin 52315-07-8 0.0001 - 0.10 Prallethrin 23031-36-9 0.0001 - 0.10 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Page 333 of 553 Page 333 of 553 Page 333 of 553 Page 333 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 3/14 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. NFPA Classification : NFPA Level 3 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Page 334 of 553 Page 334 of 553 Page 334 of 553 Page 334 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 4/14 Precautions for safe handling : Avoid contact with skin, eyes and clothing. Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Pressurized container. Do not pierce or burn, even after use. Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Do not spray on an open flame or other ignition source. Storage Requirements for storage areas and containers : Protect from sunlight. Do not expose to temperatures exceeding 50 122 Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. Store locked up. Page 335 of 553 Page 335 of 553 Page 335 of 553 Page 335 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 5/14 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Distillates (petroleum), hydrotreated light 64742-47-8 1,200 mg/m3 152 ppm - SUPPLIER Carbon dioxide 124-38-9 9,000 mg/m3 5,000 ppm - OSHA TWA Carbon dioxide 124-38-9 - 30,000 ppm - ACGIH STEL Carbon dioxide 124-38-9 - 5,000 ppm - ACGIH TWA Isopropanol 67-63-0 980 mg/m3 400 ppm - OSHA TWA Isopropanol 67-63-0 - 400 ppm - ACGIH STEL Isopropanol 67-63-0 - 200 ppm - ACGIH TWA Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Eye protection : No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 336 of 553 Page 336 of 553 Page 336 of 553 Page 336 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 6/14 Form : aerosol Color : clear Odor : characteristic Odour Threshold : No data available pH : Not applicable Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 22 °C 71.6 °F Evaporation rate : No data available Flammability (solid, gas) : Sustains combustion Upper/lower flammability or explosive limits : No data available Vapour pressure : Not applicable Vapour density : No data available Relative density : 0.81 g/cm3 at 21 °CGLP: yes Solubility(ies) : negligible Partition coefficient: n- : No data available Page 337 of 553 Page 337 of 553 Page 337 of 553 Page 337 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 7/14 octanol/water Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 3 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Stable under recommended storage conditions. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Danger Page 338 of 553 Page 338 of 553 Page 338 of 553 Page 338 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 8/14 Acute oral toxicity : NA GHS LD50 estimated > 5,000 mg/kg Acute inhalation toxicity : NA GHS LC50 (dust and mist) estimated > 5.47 mg/l Acute dermal toxicity : NA GHS LD50 estimated > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Acute toxicity No classification proposed - Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard Category 1 - Aggravated Medical : None known. Page 339 of 553 Page 339 of 553 Page 339 of 553 Page 339 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 9/14 Condition 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Distillates (petroleum), hydrotreated light static test LC50 Lepomis macrochirus 2.2 mg/l 96 h Carbon dioxide No data available Isopropanol LC50 Pimephales promelas (fathead minnow) 9,640 mg/l 96 h Cypermethrin LC50 mykiss (rainbow trout) 0.00283 mg/l 96 h NOEC Pimephales promelas (fathead minnow) 0.00001 mg/l 28 d Prallethrin LC50 mykiss (rainbow trout) 0.012 mg/l 96 h Toxicity to aquatic invertebrates Distillates (petroleum), hydrotreated light No data available Components End point Species Value Exposure time Components End point Species Value Exposure time Page 340 of 553 Page 340 of 553 Page 340 of 553 Page 340 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 10/14 Carbon dioxide No data available Isopropanol EC50 Daphnia magna (Water flea) 13,299 mg/l 48 h Cypermethrin EC50 Daphnia magna (Water flea) 0.00471 mg/l 48 h NOEC Daphnia magna (Water flea) 0.00004 mg/l 21 d Prallethrin EC50 Daphnia magna (Water flea) 0.0062 mg/l 48 h Toxicity to aquatic plants Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol EC50 Desmodesmus subspicatus (green algae) > 1,000 mg/l 72 h Cypermethrin ErC50 No data available > 0.0033 mg/l 72 h Prallethrin No data available Pseudokirchneriella subcapitata (green algae) 2 mg/l 96 h Persistence and degradability Component Biodegradation Exposure time Summary Components End point Species Value Exposure time Page 341 of 553 Page 341 of 553 Page 341 of 553 Page 341 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 11/14 Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol 53 % 5 d Readily biodegradable Cypermethrin 0.6 - 1.4 % 33 d Not readily biodegradable. Prallethrin No data available Not readily biodegradable. Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Distillates (petroleum), hydrotreated light 61 - 159 No data available Carbon dioxide No data available No data available Isopropanol 0.96 estimated 0.05 Cypermethrin 373.4 Measured 5.3 - 5.6 Prallethrin No data available 4.49 Mobility Component End point Value Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol No data available Cypermethrin Koc 80653 - 574360 Prallethrin No data available PBT and vPvB assessment Component Results Distillates (petroleum), hydrotreated light Not fulfilling PBT and vPvB criteria Isopropanol Not fulfilling PBT and vPvB criteria Page 342 of 553 Page 342 of 553 Page 342 of 553 Page 342 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 12/14 Cypermethrin Not fulfilling PBT and vPvB criteria Prallethrin Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper shipping name AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 Transport hazard class(es) 2.1 2 2.1 Packing group - - - Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION FIFRA Labeling This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to Page 343 of 553 Page 343 of 553 Page 343 of 553 Page 343 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 13/14 certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: CONTENTS UNDER PRESSURE. Exposure to temperatures above 130° F may cause bursting. Extremely flammable. This product is extremely toxic to fish and aquatic invertebrates. Drift and runoff may be hazardous to fish in water adjacent to treated areas. Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Registration # / Agency 4822-553/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 3 Reactivity 0 Page 344 of 553 Page 344 of 553 Page 344 of 553 Page 344 of 553 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 14/14 NFPA Ratings Health 2 Fire 3 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 345 of 553 Page 345 of 553 Page 345 of 553 Page 345 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 1/10 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : RAID® WASP & HORNET KILLER 33 Use of the Substance/Mixture : Insecticide Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : clear / aerosol / characteristic Immediate Concerns : Caution FLAMMABLE: CAUSES SKIN IRRITATION. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Harmful if absorbed through skin. Contents under pressure. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg as container may burst. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : May cause skin reactions in rare cases. Causes moderate skin irritation. Harmful if absorbed through skin. May cause systemic effects. May cause transient tingling and reddening of the skin. Inhalation : Excessive exposures may affect human health, as follows: Inhalation may cause central nervous system effects. Page 346 of 553 Page 346 of 553 Page 346 of 553 Page 346 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 2/10 Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aspiration hazard if swallowed - can enter lungs and cause damage. Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Distillates (petroleum), hydrotreated light 64742-47-8 60.00 - 100.00 Carbon dioxide 124-38-9 1.00 - 5.00 Isopropanol 67-63-0 1.00 - 5.00 Cis-,Trans-Cypermethrin 52315-07-8 0.00 - 0.10 Prallethrin 23031-36-9 0.00 - 0.10 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Skin contact : Flush immediately with plenty of water for at least 15 to 20 minutes. Remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Wash clothing before reuse. Thoroughly clean shoes before reuse. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Page 347 of 553 Page 347 of 553 Page 347 of 553 Page 347 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 3/10 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Flash point : 22 °C 71.6 °F Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available NFPA Classification : NFPA Level 3 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods for cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. Page 348 of 553 Page 348 of 553 Page 348 of 553 Page 348 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 4/10 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid contact with skin, eyes and clothing. Do not puncture or incinerate. Do not enter places where used or stored until adequately ventilated. Avoid breathing vapors, mist or gas. For personal protection see section 8. Do not spray toward face. Do not use in areas without adequate ventilation. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Smoking, eating and drinking should be prohibited in the application area. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge. Storage Requirements for storage areas and containers : Keep away from food, drink and animal feedingstuffs. Do not store at temperatures above 120 Deg. F (50 Deg as container may burst. Keep in a dry, cool and well-ventilated place. Page 349 of 553 Page 349 of 553 Page 349 of 553 Page 349 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 5/10 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Distillates (petroleum), hydrotreated light 64742-47-8 1,200 mg/m3 152 ppm - SUPPLIER Carbon dioxide 124-38-9 9,000 mg/m3 5,000 ppm - OSHA TWA Carbon dioxide 124-38-9 - 30,000 ppm - ACGIH STEL Carbon dioxide 124-38-9 - 5,000 ppm - ACGIH TWA Isopropanol 67-63-0 980 mg/m3 400 ppm - OSHA TWA Isopropanol 67-63-0 - 400 ppm - ACGIH STEL Isopropanol 67-63-0 - 200 ppm - ACGIH TWA Personal protective equipment Respiratory protection Industrial setting : Do not spray in enclosed areas. Household setting : Use only with adequate ventilation. Hand protection : If prolonged or repeated contact is possible: Wear suitable gloves. Rubber gloves Eye protection Industrial setting : No special requirements. Household setting : Avoid contact with eyes. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety Page 350 of 553 Page 350 of 553 Page 350 of 553 Page 350 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 6/10 practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : aerosol Color : clear Odor : characteristic pH : no data available Melting point : no data available Boiling point : no data available Freezing point : no data available Flash point : 22 °C 71.6 °F Evaporation rate : no data available Flammability (solid, gas) : Sustains combustion Autoignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 0.81 g/cm3 at 21 °CGLP: yes Water solubility : negligible Partition coefficient: n- octanol/water : no data available Viscosity, dynamic : no data available Viscosity, kinematic : no data available Volatile Organic Compounds : 3 % - does not include any applicable regulatory Page 351 of 553 Page 351 of 553 Page 351 of 553 Page 351 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 7/10 (California Air Resource Board – CARB) Total VOC (wt. exemptions 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 > 5,000 mg/kg Acute inhalation toxicity : LC50 > 5.47 mg/l Acute dermal toxicity : LD50 > 5,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : Not known to be a sensitizer. Page 352 of 553 Page 352 of 553 Page 352 of 553 Page 352 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 8/10 12. ECOLOGICAL INFORMATION Ecotoxicity effects : Harmful to aquatic organisms. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. RCRA waste class : D001 (Ignitable Waste) 14. TRANSPORT INFORMATION Land transport U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2.1 UN number 1950 Packaging group: None. Note: Limited quantities derogation may be applicable to this product, please check transport documents. Sea transport IMDG: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2 UN number: 1950 Packaging group: None. EmS: F-D, S-U Note: Limited quantities derogation may be applicable to this product, please check transport documents. Air transport ICAO/IATA: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2.1 UN/ID No.: UN 1950 Packaging group: None. Page 353 of 553 Page 353 of 553 Page 353 of 553 Page 353 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 9/10 Note: SC Johnson typically does not ship products via air, therefore it has not been determined if the product container meets current IATA/ICAO package criteria. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Registration # / Agency 4822-553/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 3 Reactivity 0 NFPA Ratings Health 2 Fire 3 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 354 of 553 Page 354 of 553 Page 354 of 553 Page 354 of 553 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 2.1 Print Date 06/01/2011 Revision Date 05/17/2011 MSDS Number 350000010778 SITE_FORM Number 30000000000000009102.004 10/10 Page 355 of 553 Page 355 of 553 Page 355 of 553 Page 355 of 553 ---PAGE BREAK--- Page 356 of 553 Page 356 of 553 Page 356 of 553 Page 356 of 553 ---PAGE BREAK--- Page 357 of 553 Page 357 of 553 Page 357 of 553 Page 357 of 553 ---PAGE BREAK--- Page 358 of 553 Page 358 of 553 Page 358 of 553 Page 358 of 553 ---PAGE BREAK--- Page 359 of 553 Page 359 of 553 Page 359 of 553 Page 359 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET K43W51 07 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 1* K43W51 14-MAY-08 Flammability 0 Reactivity 0 PRODUCT NAME RESILIENCE™ Exterior Latex Satin Paint, Extra White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 0.1 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 18 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 2 1314-13-2 Zinc Oxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. Continued on page 2 Page 360 of 553 Page 360 of 553 Page 360 of 553 Page 360 of 553 ---PAGE BREAK--- K43W51 page 2 SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 HANDLING AND STORAGE STORAGE CATEGORY Not Applicable Continued on page 3 Page 361 of 553 Page 361 of 553 Page 361 of 553 Page 361 of 553 ---PAGE BREAK--- K43W51 page 3 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.70 lb/gal 1282 g/l SPECIFIC GRAVITY 1.29 BOILING POINT 212 - 213 F 100 - 100 C MELTING POINT Not Available VOLATILE VOLUME 60 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.0 Continued on page 4 Page 362 of 553 Page 362 of 553 Page 362 of 553 Page 362 of 553 ---PAGE BREAK--- K43W51 page 4 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.41 lb/gal 49 g/l Less Water and Federally Exempt Solvents 0.17 lb/gal 20 g/l Emitted VOC Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available 1314-13-2 Zinc Oxide LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Continued on page 5 Page 363 of 553 Page 363 of 553 Page 363 of 553 Page 363 of 553 ---PAGE BREAK--- K43W51 page 5 Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element Zinc Compound 2 1.8 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 364 of 553 Page 364 of 553 Page 364 of 553 Page 364 of 553 ---PAGE BREAK--- Page 365 of 553 Page 365 of 553 Page 365 of 553 Page 365 of 553 ---PAGE BREAK--- Page 366 of 553 Page 366 of 553 Page 366 of 553 Page 366 of 553 ---PAGE BREAK--- Page 367 of 553 Page 367 of 553 Page 367 of 553 Page 367 of 553 ---PAGE BREAK--- Page 368 of 553 Page 368 of 553 Page 368 of 553 Page 368 of 553 ---PAGE BREAK--- RESOLVE® DUAL POWER CARPET STAIN REMOVER (LIQUID) Dual chamber carpet stain remover. When the chemicals in each chamber are mixed they form the active ingredients that perform the cleaning process. Chemtrec: 1-[PHONE REDACTED] (U.S. & Canada) Outside the U.S & Canada (North America), call: [PHONE REDACTED] Reckitt Benckiser North America, Inc. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, N.J. 07054-0225 Material Safety Data Sheet Section 1. Product and Company Identification Product Name MSDS# Validation Date Print Date In case of Emergency: Manufacturer Product Description 6/14/2005 6/14/2005 Product Identifier Not available. Telephone: [PHONE REDACTED] Transportation Emergencies: Item Number Formula Number 0021985 (969-176) Combined product. 0021983 (969-176A) Blue phase, chamber 0021984 (969-176B) Oxy phase, chamber 0021985 UPC Number 19200-77873 (22 oz. dual chamber HDPE plastic bottles) Section 2. Composition and Information on Ingredients 1) CHAMBER 2) ISOPROPYL ALCOHOL 67-63-0 1.98 TWA: 983 STEL: 1230 (mg/m3) from ACGIH (TLV) [United States] TWA: 400 STEL: 500 (ppm) from ACGIH (TLV) [United States] TWA: 980 STEL: 1230 (mg/m3) from OSHA (PEL) [United States] TWA: 400 (ppm) from OSHA (PEL) [United States] 3) SODIUM BICARBONATE 144-55-8 5.0 Not available. 4) 5) CHAMBER 6) HYDROGEN PEROXIDE 7722-84-1 2.42 TWA: 1.4 (mg/m3) from ACGIH (TLV) [United States] TWA: 1 (ppm) from ACGIH (TLV) [United States] TWA: 1.4 (mg/m3) from OSHA (PEL) [United States] TWA: 1 (ppm) from OSHA (PEL) [United States] 7) CITRIC ACID 77-92-9 1.02 Not available. 8) ISOPROPYL ALCOHOL 67-63-0 1.98 See ACGIH and OSHA data shown in Chamber Name CAS # Exposure Limits : TLV/PEL % by Weight Section 3. Hazards Identification Emergency Overview DANGER: CORROSIVE TO EYES. CAUSES BURNS TO EYES. SKIN IRRITANT. HARMFUL IF SWALLOWED. DO NOT get in eyes or on skin. DO NOT INGEST. Wash hands immediately after use. Contains Hydrogen Peroxide and Citric Acid. KEEP OUT OF REACH OF CHILDREN. Continued on Next Page 7/24/2009 7/24/2009 0169348 (1315-176) Phase 0068263 (969-176) Phase 0169348 Page 369 of 553 Page 369 of 553 Page 369 of 553 Page 369 of 553 ---PAGE BREAK--- RESOLVE® DUAL POWER CARPET STAIN REMOVER (LIQUID) Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of water. Remove any contact lenses and continue rinsing for at least 15 minutes. Get immediate medical attention. In case of skin contact, wash skin thoroughly with soap and water. If irritation persists, consult a physician. Remove to fresh air. If swallowed, DO NOT induce vomiting! Immediately rinse mouth, then drink a glass of water. Contact a physician or poison control center immediately. NEVER give an unconscious person anything to ingest. Not flammable. See Section 14 for any Shipping Classifications. Thermal decomposition products may include carbon oxides and nitrogen oxides. Chamber A = None determined, water content too high to ignite the flame. Chamber B = 61º C (142º Combined = >93º C (>200º F) Not available. Use water spray, foam, dry chemical or carbon dioxide, as suitable, for the surrounding fire. None known. Section 5. Fire and Explosion Data Flammability Flash Point Explosive Limits in Air Products of Combustion Fire and Explosion Hazards Fire Fighting Media and Instructions Wear self-contained breathing apparatus and protective clothing appropriate for fighting a chemical fire. Special Fire Fighting Instructions Small spills: Wearing impervious gloves, soak up spill with absorbent material and dispose of in trash. Rinse area well to avoid slippery conditions. Large spills: Wearing appropriate eye protection, impervious gloves and body protection such as a chemical suit and impervious boots, the liquid should be diked, contained and collected for later disposal according to local, state or federal regulations. Section 6. Accidental Release Measures Accidental Spill Section 7. Handling and Storage Handling and Storage DANGER: CORROSIVE TO EYES. CAUSES BURNS TO EYES. SKIN IRRITANT. HARMFUL IF SWALLOWED. DO NOT get in eyes or on skin. DO NOT INGEST. Wash hands immediately after use. Contains hydrogen peroxide and Citric Acid. READ PACKAGE LABEL CAREFULLY. Store in original container in secure area inaccessible to children and pets. KEEP OUT OF REACH OF CHILDREN. Section 8. Exposure Controls/Personal Protection Ventilation Requirements No specific controls are needed. Corrosive to the eyes. Splashproof glasses, chemical goggles or full face shield. Emergency responders should wear full eye and face protection. Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible. Respiratory Protection Other Protection Eye Protection Skin Protection Skin irritant. Gloves (impervious). Avoid contact with skin. If product gets on clothing, remove clothing and wash before wearing again. Emergency responders should wear impermeable gloves. None required Continued on Next Page Page 370 of 553 Page 370 of 553 Page 370 of 553 Page 370 of 553 ---PAGE BREAK--- RESOLVE® DUAL POWER CARPET STAIN REMOVER (LIQUID) Page Number: 3 Wash thoroughly with soap and water after handling. Work/Hygienic Practices Not available. Liquid. (Dual chamber container that will combine ingredients from each chamber upon use at a common nozzle.) Chamber A (blue color) the pH is 8.5; Chamber B (clear color) the pH is 3.9; Final Product, when combined, the pH is approximately 6.5 Chamber A (Basic) = 1.034 / Chamber B (Acid Oxy) = 1.040 Mixed as finished product = 1.036 (Water = 1.000) Not available. Not available Complete. Citrus / herbaceous scent. Chamber A = Blue Chamber B = Colorless, clear liquid. Section 9. Physical and Chemical Properties Description Odor Color pH Boiling/Condensation Point Specific Gravity Vapor Pressure Vapor Density Solubility Not available. Viscosity Not available. Physical Chemical Comments The product is stable. Do not mix with bleach or other household cleaners. Do not spray on metals. Will not occur. Carbon monoxide, carbon dioxide and oxides of nitrogen may be formed during thermal decomposition. None known. Section 10. Stability and Reactivity Data Chemical Stability Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Not listed as carcinogenic by OSHA, NTP or IARC. Section 11. Toxicological Information Exposure effects Carcinogenicity HARMFUL IF SWALLOWED. Inhalation toxicity not determined. Inhalation Ingestion Eye Contact Corrosive to eyes. Skin Contact Skin irritant. Continued on Next Page Page 371 of 553 Page 371 of 553 Page 371 of 553 Page 371 of 553 ---PAGE BREAK--- RESOLVE® DUAL POWER CARPET STAIN REMOVER (LIQUID) Page Number: 4 Not available. Section 12. Ecological Information Ecotoxicity Discharge small amounts of waste liquid to sanitary sewer. Rinse and discard empty container in trash collection or rinse and recycle if appropriate in your area. Large quantities of waste liquid: Contain and collect liquid for evaluation and disposal according to local, state and federal regulations. Section 13. Disposal Considerations Waste Disposal DOT Classification Not regulated by DOT (United States). Not applicable. Not applicable. Section 14. Transport Information DOT Identification Number Special Provisions for Transport Not applicable. Not applicable. Not applicable. Proper Shipping Name Packing Group Hazardous Substances Reportable Quantity IMDG Classification Not regulated by IMDG. Not regulated by IATA. IATA Classification Not regulated by TDG. TDG Classification Maritime Transportation Not applicable. ADR Classification Not applicable. CLASS C: Oxidizing material. CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). Other Classifications WHMIS (Canada) Federal and State Regulations Section 15. Regulatory Information None 1) ISOPROPYL ALCOHOL Not available. 1.98 Not avai California Proposition 65: This product contains the following ingredients which require a warning under the Safe Drinking Water & Toxic Enforcement Act: SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting: Continued on Next Page Page 372 of 553 Page 372 of 553 Page 372 of 553 Page 372 of 553 ---PAGE BREAK--- RESOLVE® DUAL POWER CARPET STAIN REMOVER (LIQUID) Page Number: 5 Notice to Reader Printed 6/14/2005. Validated by Product Safety on 6/14/2005. Section 16. Other Information HMIS 1 0 3 National Fire Protection Association Health Fire Hazard Reactivity Specific hazard 3 0 1 D Health Hazard Fire Hazard Reactivity Personal Protection To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. NFPA Aerosol Level Not applicable. Validated by Regulatory on 7/24/2009. Printed 7/24/2009. Page 373 of 553 Page 373 of 553 Page 373 of 553 Page 373 of 553 ---PAGE BREAK--- Material Safety Data Sheet NFPA HMIS PPE Transport Symbol Issuing Date 02.01.2008 Revision Date 02.01.2008 Revision Number 1 Page 1 / 7 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Rust Stain Remover Recommended Use Rust Remover Supplier Address Whink Products Company PO Box 230 1901 15th Ave., Eldora, IA, 50627 United States of America Phone: [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone: [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] Company Emergency Phone Number [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Emergency Overview Very toxic by inhalation, in contact with skin and if swallowed. Causes severe burn. Inhalation of vapors in high concentration may cause shortness of breath (lung oedema). Ingestion causes burns of the upper digestive and respiratory tracts. Will penetrate skin and attack underlying tissues and bone. Appearance Clear Physical State Liquid Odor Acrid Potential Health Effects Principle Routes of Exposure Eyes, Skin, Inhalation and Ingestion Acute Toxicity Eyes Avoid contact with eyes. Risk of serious damage to eyes. May cause burns. Severely irritating to eyes. Seek Medical Attention. Skin Causes serious injury to skin, which may not be immediately painful or visible. Inhalation Causes respiratory irritation. may be delayed for several hours. Ingestion Ingestion is toxic and can causes severe mouth, throat and stomach burns. Seek medical attention. Environmental Hazard See Section 12 for additional Ecological Information Page 374 of 553 Page 374 of 553 Page 374 of 553 Page 374 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 2 / 7 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Water 7732-18-5 90 - 100 Hydrofluoric Acid (Hydrogen Fluoride) 7664-39-3 1.50 – 3.5 Denatonium Benzoate 3734-33-6 0.01 – 0.10 4. FIRST AID MEASURES General Advice Call [PHONE REDACTED] or emergency medical service. Remove and isolate contaminated clothing and shoes. Eye Contact In case of contact with substance, remove contacts if needed, immediately flush eyes with running water for at least 20 minutes. Get medical attention immediately. Skin Contact Avoid spreading material on unaffected skin. Wash off immediately with plenty of water for 15 minutes. Treat with Calcium gluconate or with a over-the-counter anti-acid containing Calcium or Magnesium. Seek Medical Attention Immediately! Inhalation Move injured party to fresh air. Apply artificial respiration if injured party is not breathing. Administer oxygen if breathing is difficult. Get Medical Attention Immediately! Ingestion Do not induce vomiting. Rinse mouth. Drink large amounts of water. Several glasses of milk or several ounces of milk of magnesia may be given for soothing. Take Injured Partyto a Doctor Immediately! 5. FIRE-FIGHTING MEASURES Flammable Properties Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Produces Hydrogen Fluoride Gas or Hydrogen Gas upon heating. Containers may rupture due to gas build-up when heated. Reaction with certain metals generates flammable and potentially explosive hydrogen gas. Flash Point Not Flammable. Suitable Extinguishing Media Use water or suitable agent for fires. Do not use solid water streams. Acid reacts with water and can splatter acid onto personnel. Care should be exercised when water is used to dilute acid. Will react with water and generate heat and fumes. Hazardous Combustion Products Hydrogen Gas and/or Hydrogen Fluoride Gas Explosion Data Sensitivity to mechanical impact Not sensitive Sensitivity to static discharge Not sensitive Protective Equipment and Precautions for Firefighters In the event of a fire wear full protective clothing and NIOSH-approved self- contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Wear full protective clothing. National Fire Protection Association (NFPA) Ratings: This information is intended solely for the use of individuals trained in the NFPA system. Health Hazard 3 Flammability 0 Stability 1 Physical and Chemical Hazards W Other: Acid/ Toxic Page 375 of 553 Page 375 of 553 Page 375 of 553 Page 375 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 3 / 7 6. ACCIDENTAL RELEASE MEASURES Methods for Containment Always wear Personal Protective Equipment. Use sand, or pigs to dike area. Keep out of sewer Methods for Cleaning Up Carefully neutralize with caustic soda, lime or other alkaline material. Put into approved disposal container. Other Information Do not use metal or glass containers. Do not use metal tools for cleaning spills. 7. HANDLING AND STORAGE Handling Always wear recommended Personal Protective Equipment. Do not breathe vapor or mist. Use only with adequate ventilation. Avoid contact with skin, eyes and clothing. Do not add water to product. Care should be taken when adding to water to prevent splattering and heat buildup. Storage Store only in the original container. Store in cool, well-ventilated area. Do not store in metal containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines This product does contain a hazardous material with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures Showers – quick-drench Eyewash stations Ventilation systems – sufficient to reduce vapor and acid mists below permissible TLV levels. Personal Protective Equipment Eye/Face Protection fitting safety goggles. Face-shield. Skin and Body Protection Wear Chemical Resistant Gloves. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations Hygiene Measures When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless Odor Acrid / Sharp Pungent Odor Threshold No information available Physical State Liquid pH As is < 1 Autoignition Temperature No information available. Flash Point No information available. Boiling Point/Range 212oF Decomposition Temperature No information available. Explosion Limits No information available. Melting Point/Range No information available. Solubility Water Flammability Limits in Air No information available. Vapor Pressure No data available. Water Solubility Complete (Weight%) VOC Content Not applicable. Evaporation Rate < 1 (Compared to: Ether) Partition Coefficient (n-octanol/water) No data available. Vapor Density No data available. Page 376 of 553 Page 376 of 553 Page 376 of 553 Page 376 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 4 / 7 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions Incompatible Products Glass, concrete and other silicone materials. Carbonates, sulfides and cyanides (yields toxic gases). Alkalies and oxides (cause violent exothermic reactions). Common metals (yield Hydrogen Gas, fire and explosive reactive hazard). Corrosive to many materials (includes leather and many organics). Water added to product yields heat and violent reaction. Conditions to Avoid Moisture, humidity, heat, flame, ignition sources and incompatibles. Hazardous Decomposition Products Emits sulfur oxide gases under fire conditions and in contact with water. Hazardous Reactions Reacts violently with water, metals, alkalies, oxides, carbonates, sulfides, cyanides, glass, concrete and other silicones. Hazardous Polymerization Hazardous polymerization will not occur. 11. TOXICOLOGICAL INFORMATION Signs and of Overexposure Eye, Mouth, Nasal and Mucous Membrane irritation. Burning of the skin, mottling of teeth and bones. Acute Effects Eyes May cause severe conjunctiva irritation and corneal damage. May cause burns. Skin 2% solution of hydrofluoric acid was corrosive to rabbit skin with 1 hour exposure, but not with 1 minute. Inhalation May cause irritation of respiratory tract and mucous membranes. Ingestion Harmful or fatal if swallowed. Ingestion may cause burns and irritation to gastrointestinal track. Target Organ Effects Bone and joints Chronic Toxicity Prolonged exposure can cause bone and joint changes in humans (Fluorosis). Carcinogenicity Contains no ingredient listed as a carcinogen. Acute Toxicity Values Oral LD50 (Rat) = Not Determined Dermal LD50 (Rabbit) = Not Determined Inhalation LC50 (Rat) = Not Determined 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated Page 377 of 553 Page 377 of 553 Page 377 of 553 Page 377 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 5 / 7 13. DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements Contaminated Packaging Dispose of in accordance with local regulations California Hazardous Waste Codes 791 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Hydrofluoric Acid (Hydrogen Fluoride) Corrosive 14. TRANSPORT INFORMATION DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity, ORM-D TDG Proper Shipping Name Hydrofluoric Acid, with 60% strength Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II MEX Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II ICAO UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IATA UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II ERG Code 8L Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IMDG/IMO Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Page 378 of 553 Page 378 of 553 Page 378 of 553 Page 378 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 6 / 7 14. TRANSPORT INFORMATION Subsidiary Class Toxic UN-No UN1790 Packing Group II EmS No. 8.03 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II RID Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1,II, RID ADR/RID-Labels 8, 6.1 ADR Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II ADN Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Classification Code Unknown Special Provisions 274 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II Hazard Labels 8 Limited Quantity Unknown 15. REGULATORY INFORMATION International Inventories TSCA Hydrofluoric Acid, Aqueous is listed U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain chemicals (hydrogen fluoride), which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard Yes Page 379 of 553 Page 379 of 553 Page 379 of 553 Page 379 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 7 / 7 15. REGULATORY INFORMATION Cont. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990 CERCLA This material, as supplied, does contain a substance regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). Hydrogen Fluoride (Hydrofluoric Acid) 100 lbs. There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Illinois Rhode Island Hydrofluoric Acid NA NA NA NA NA International Regulations See Specific Country for Regulations required. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class E Corrosive material D1A Toxic materials 16. OTHER INFORMATION Revision Date 02.01.2008 Revision Note First Revision Prepared By: Manufacturer’s Technical Services Department Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 380 of 553 Page 380 of 553 Page 380 of 553 Page 380 of 553 ---PAGE BREAK--- Material Safety Data Sheet NFPA HMIS PPE Transport Symbol Issuing Date 10/06/2008 Revision Date 10/06/2008 Revision Number 2 Page 1 / 8 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Rust Stain Remover Recommended Use Rust Remover Supplier Address Whink Products Company PO Box 230 1901 15th Ave., Eldora, IA, 50627 United States of America Phone: [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone: [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] Company Emergency Phone Number [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Emergency Overview Very toxic by inhalation, in contact with skin and if swallowed. Causes severe burns. Inhalation of vapors in high concentration may cause shortness of breath (lung edema). Ingestion causes burns of the upper digestive and respiratory tracts. Will penetrate skin and attack underlying tissues and bone. Appearance Clear Physical State Liquid Odor Acrid Potential Health Effects Principle Routes of Exposure Eyes, Skin, Inhalation and Ingestion Acute Toxicity Eyes Avoid contact with eyes. Risk of serious damage to eyes. May cause burns. Severely irritating to eyes. Seek Medical Attention. Skin Causes serious injury to skin, which may not be immediately painful or visible. Inhalation Causes respiratory irritation. may be delayed for several hours. Ingestion Ingestion is toxic and can causes severe mouth, throat and stomach burns. Seek medical attention. Environmental Hazard See Section 12 for additional Ecological Information Page 381 of 553 Page 381 of 553 Page 381 of 553 Page 381 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 2 / 8 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Water 7732-18-5 90 - 100 Hydrofluoric Acid (Hydrogen Fluoride) 7664-39-3 1.50 – 3.5 Denatonium Benzoate 3734-33-6 0.01 – 0.10 4. FIRST AID MEASURES General Advice Call [PHONE REDACTED] or emergency medical service. Remove and isolate contaminated clothing and shoes. Eye Contact In case of contact with eyes, remove contacts if needed, immediately flush eyes with running water for at least 20 minutes. Get medical attention immediately. Skin Contact Avoid spreading material on unaffected skin. Wash off immediately with plenty of water for 15 minutes. Treat with Calcium Gluconate or with a over-the-counter anti-acid containing Calcium or Magnesium. Seek Medical Attention Immediately! Inhalation Move injured party to fresh air. Apply artificial respiration if injured party is not breathing. Administer oxygen if breathing is difficult. Get Medical Attention Immediately! Ingestion Do not induce vomiting. Rinse mouth. Drink large amounts of water. Several glasses of milk or several ounces of milk of magnesia may be given for soothing. Take Injured Party to a Doctor Immediately! 5. FIRE-FIGHTING MEASURES Flammable Properties Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Produces Hydrogen Fluoride Gas or Hydrogen Gas upon heating. Containers may rupture due to gas build-up when heated. Reaction with certain metals generates flammable and potentially explosive hydrogen gas. Flash Point Not Flammable. Suitable Extinguishing Media Use water or suitable agent for fires. Do not use solid water streams. Acid reacts with water and can splatter acid onto personnel. Care should be exercised when water is used to dilute acid. Will react with water and generate heat and fumes. Hazardous Combustion Products Hydrogen Gas and/or Hydrogen Fluoride Gas Explosion Data Sensitivity to mechanical impact Not sensitive Sensitivity to static discharge Not sensitive Protective Equipment and Precautions for Firefighters In the event of a fire wear full protective clothing and NIOSH-approved self- contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Wear full protective clothing. National Fire Protection Association (NFPA) Ratings: This information is intended solely for the use of individuals trained in the NFPA system. Health Hazard 3 Flammability 0 Stability 1 Physical and Chemical Hazards W Other: Acid/ Toxic 6. ACCIDENTAL RELEASE MEASURES Methods for Containment Always wear Personal Protective Equipment. Use sand, or pigs to dike area. Keep out of sewer Page 382 of 553 Page 382 of 553 Page 382 of 553 Page 382 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 3 / 8 Methods for Cleaning Up Carefully neutralize with caustic soda, lime or other alkaline material. Put into approved disposal container. Other Information Do not use metal or glass containers. Do not use metal tools for cleaning spills. 7. HANDLING AND STORAGE Handling Always wear recommended Personal Protective Equipment. Do not breathe vapor or mist. Use only with adequate ventilation. Avoid contact with skin, eyes and clothing. Do not add water to product. Care should be taken when adding to water to prevent splattering and heat buildup. Storage Store only in the original container. Store in cool, well-ventilated area. Do not store in metal containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines This product does contain a hazardous material with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures Showers – quick-drench Eyewash stations Ventilation systems – sufficient to reduce vapor and acid mists below permissible TLV levels. Personal Protective Equipment Eye/Face Protection fitting safety goggles. Face-shield. Skin and Body Protection Wear Chemical Resistant Gloves. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations Hygiene Measures When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing. This Space Intentionally Left Blank Page 383 of 553 Page 383 of 553 Page 383 of 553 Page 383 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 4 / 8 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless Odor Acrid / Sharp Pungent Odor Threshold No information available Physical State Liquid pH As is < 1 Autoignition Temperature No information available. Flash Point No information available. Boiling Point/Range 212oF Decomposition Temperature No information available. Explosion Limits No information available. Melting Point/Range No information available. Solubility Water Fl ammability Limits in Air No information available. Vapor Pressure No data available. Water Solubility Complete (Weight%) VOC Content Not applicable. Evaporation Rate < 1 (Compared to: Ether) P artition Coefficient (n-octanol/water) No data available. Vapor Density No data available. 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions Incompatible Products Glass, concrete and other silicone materials. Carbonates, sulfides and cyanides (yields toxic gases). Alkalies and oxides (cause violent exothermic reactions). Common metals (yield Hydrogen Gas, fire and explosive reactive hazard). Corrosive to many materials (includes leather and many organics). Water added to product yields heat and violent reaction. Conditions to Avoid Moisture, humidity, heat, flame, ignition sources and incompatibles. Hazardous Decomposition Products Emits sulfur oxide gases under fire conditions and in contact with water. Hazardous Reactions Reacts violently with water, metals, alkalies, oxides, carbonates, sulfides, cyanides, glass, concrete and other silicones. Hazardous Polymerization Hazardous polymerization will not occur. 11. TOXICOLOGICAL INFORMATION Signs and of Overexposure Eye, Mouth, Nasal and Mucous Membrane irritation. Burning of the skin, mottling of teeth and bones. Acute Effects Eyes May cause severe conjunctiva irritation and corneal damage. May cause burns. Skin 2% solution of hydrofluoric acid was corrosive to rabbit skin with 1 hour exposure, but not with 1 minute. Inhalation May cause irritation of respiratory tract and mucous membranes. Ingestion Harmful or fatal if swallowed. Ingestion may cause burns and irritation to gastrointestinal tract. Target Organ Effects Bone and joints Chronic Toxicity Prolonged exposure can cause bone and joint changes in humans (Fluorosis). Carcinogenicity Contains no ingredient listed as a carcinogen. Acute Toxicity Values Oral LD50 (Rat) = Not Determined Dermal LD50 (Rabbit) = Not Determined Inhalation LC50 (Rat) = Not Determined Page 384 of 553 Page 384 of 553 Page 384 of 553 Page 384 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 5 / 8 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated 13. DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements Contaminated Packaging Dispose of in accordance with local regulations California Hazardous Waste Codes 791 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Hydrofluoric Acid (Hydrogen Fluoride) Corrosive 14. TRANSPORT INFORMATION DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity, ORM-D TDG Proper Shipping Name Hydrofluoric Acid, with 60% strength Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II MEX Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II ICAO UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IATA UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Page 385 of 553 Page 385 of 553 Page 385 of 553 Page 385 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 6 / 8 14. TRANSPORT INFORMATION Hazard Class 8, 6.1 Packing Group II ERG Code 8L Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IMDG/IMO Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Subsidiary Class Toxic UN-No UN1790 Packing Group II EmS No. 8.03 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II RID Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1,II, RID ADR/RID-Labels 8, 6.1 ADR Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II ADN Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Classification Code Unknown Special Provisions 274 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II Hazard Labels 8 Limited Quantity Unknown This Space Intentionally Left Blank Page 386 of 553 Page 386 of 553 Page 386 of 553 Page 386 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 7 / 8 15. REGULATORY INFORMATION International Inventories TSCA Hydrofluoric Acid, Aqueous is listed U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain chemicals (hydrogen fluoride), which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard Yes 15. REGULATORY INFORMATION Cont. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990 CERCLA This material, as supplied, does contain a substance regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). Hydrogen Fluoride (Hydrofluoric Acid) 100 lbs. There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material This Space Intentionally Left Blank Page 387 of 553 Page 387 of 553 Page 387 of 553 Page 387 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 8 / 8 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Illinois Rhode Island Hydrofluoric Acid NA NA NA NA NA International Regulations See Specific Country for Regulations required. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class E Corrosive material F Dangerously reactive material D1A Toxic materials 16. OTHER INFORMATION Revision Date 10/06/2008 Revision Note Second Revision Prepared By: Manufacturer’s Technical Services Department Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS This Space Intentionally Left Blank Page 388 of 553 Page 388 of 553 Page 388 of 553 Page 388 of 553 ---PAGE BREAK--- Page 389 of 553 Page 389 of 553 Page 389 of 553 Page 389 of 553 ---PAGE BREAK--- Page 390 of 553 Page 390 of 553 Page 390 of 553 Page 390 of 553 ---PAGE BREAK--- Page 391 of 553 Page 391 of 553 Page 391 of 553 Page 391 of 553 ---PAGE BREAK--- Page 392 of 553 Page 392 of 553 Page 392 of 553 Page 392 of 553 ---PAGE BREAK--- Page 393 of 553 Page 393 of 553 Page 393 of 553 Page 393 of 553 ---PAGE BREAK--- Page 394 of 553 Page 394 of 553 Page 394 of 553 Page 394 of 553 ---PAGE BREAK--- Material Safety Data Sheet NFPA HMIS PPE Transport Symbol Revision Date 04/03/2012 Revision Number 3 Page 1 / 8 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Rust Stain Remover Recommended Use Rust Remover Supplier Address Whink Products Company PO Box 230 1901 15th Ave., Eldora, IA, 50627 United States of America Phone: [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone: [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] Company Emergency Phone Number [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Emergency Overview Very toxic by inhalation, in contact with skin and if swallowed. Causes severe burns. Inhalation of vapors in high concentration may cause shortness of breath (lung edema). Ingestion causes burns of the upper digestive and respiratory tracts. Will penetrate skin and attack underlying tissues and bone. Appearance Clear Physical State Liquid Odor Acrid Potential Health Effects Principle Routes of Exposure Eyes, Skin, Inhalation and Ingestion Acute Toxicity Eyes Avoid contact with eyes. Risk of serious damage to eyes. May cause burns. Severely irritating to eyes. Seek Medical Attention. Skin Causes serious injury to skin, which may not be immediately painful or visible. Inhalation Causes respiratory irritation. may be delayed for several hours. Ingestion Ingestion is toxic and can causes severe mouth, throat and stomach burns. Seek medical attention. Environmental Hazard See Section 12 for additional Ecological Information Page 395 of 553 Page 395 of 553 Page 395 of 553 Page 395 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 2 / 8 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Water 7732-18-5 90 - 100 Hydrofluoric Acid (Hydrogen Fluoride) 7664-39-3 1.50 – 3.5 Denatonium Benzoate 3734-33-6 0.01 – 0.10 4. FIRST AID MEASURES General Advice Call [PHONE REDACTED] or emergency medical service. Remove and isolate contaminated clothing and shoes. Eye Contact In case of contact with eyes, remove contacts if needed, immediately flush eyes with running water for at least 20 minutes. Get medical attention immediately. Skin Contact Avoid spreading material on unaffected skin. Wash off immediately with plenty of water for 15 minutes. Treat with Calcium Gluconate or with a over-the-counter anti-acid containing Calcium or Magnesium. Seek Medical Attention Immediately! Inhalation Move injured party to fresh air. Apply artificial respiration if injured party is not breathing. Administer oxygen if breathing is difficult. Get Medical Attention Immediately! Ingestion Do not induce vomiting. Rinse mouth. Drink large amounts of water. Several glasses of milk or several ounces of milk of magnesia may be given for soothing. Take Injured Party to a Doctor Immediately! 5. FIRE-FIGHTING MEASURES Flammable Properties Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Produces Hydrogen Fluoride Gas or Hydrogen Gas upon heating. Containers may rupture due to gas build-up when heated. Reaction with certain metals generates flammable and potentially explosive hydrogen gas. Flash Point Not Flammable. Suitable Extinguishing Media Use water or suitable agent for fires. Do not use solid water streams. Acid reacts with water and can splatter acid onto personnel. Care should be exercised when water is used to dilute acid. Will react with water and generate heat and fumes. Hazardous Combustion Products Hydrogen Gas and/or Hydrogen Fluoride Gas Explosion Data Sensitivity to mechanical impact Not sensitive Sensitivity to static discharge Not sensitive Protective Equipment and Precautions for Firefighters In the event of a fire wear full protective clothing and NIOSH-approved self- contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Wear full protective clothing. National Fire Protection Association (NFPA) Ratings: This information is intended solely for the use of individuals trained in the NFPA system. Health Hazard 3 Flammability 0 Stability 1 Physical and Chemical Hazards W Other: Acid/ Toxic Page 396 of 553 Page 396 of 553 Page 396 of 553 Page 396 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 3 / 8 6. ACCIDENTAL RELEASE MEASURES Methods for Containment Always wear Personal Protective Equipment. Use sand, or pigs to dike area. Keep out of sewer Methods for Cleaning Up Carefully neutralize with caustic soda, lime or other alkaline material. Put into approved disposal container. Other Information Do not use metal or glass containers. Do not use metal tools for cleaning spills. 7. HANDLING AND STORAGE Handling Always wear recommended Personal Protective Equipment. Do not breathe vapor or mist. Use only with adequate ventilation. Avoid contact with skin, eyes and clothing. Do not add water to product. Care should be taken when adding to water to prevent splattering and heat buildup. Storage Store only in the original container. Store in cool, well-ventilated area. Do not store in metal containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines This product does contain a hazardous material with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures Showers – quick-drench Eyewash stations Ventilation systems – sufficient to reduce vapor and acid mists below permissible TLV levels. Personal Protective Equipment Eye/Face Protection fitting safety goggles. Face-shield. Skin and Body Protection Wear Chemical Resistant Gloves. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations Hygiene Measures When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing. This Space Intentionally Left Blank Page 397 of 553 Page 397 of 553 Page 397 of 553 Page 397 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 4 / 8 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless Odor Acrid / Sharp Pungent Odor Threshold No information available Physical State Liquid pH As is < 1 Autoignition Temperature No information available. Flash Point No information available. Boiling Point/Range 212 oF Decomposition Temperature No information available. Explosion Limits No information available. Melting Point/Range No information available. Solubility Water Flammability Limits in Air No information available. Vapor Pressure No data available. Water Solubility Complete (Weight%) VOC Content Not applicable. Evaporation Rate < 1 (Compared to: Ether) Partition Coefficient (n-octanol/water) No data available. Vapor Density No data available. 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions Incompatible Products Glass, concrete and other silicone materials. Carbonates, sulfides and cyanides (yields toxic gases). Alkalies and oxides (cause violent exothermic reactions). Common metals (yield Hydrogen Gas, fire and explosive reactive hazard). Corrosive to many materials (includes leather and many organics). Water added to product yields heat and violent reaction. Conditions to Avoid Moisture, humidity, heat, flame, ignition sources and incompatibles. Hazardous Decomposition Products Emits sulfur oxide gases under fire conditions and in contact with water. Hazardous Reactions Reacts violently with water, metals, alkalies, oxides, carbonates, sulfides, cyanides, glass, concrete and other silicones. Hazardous Polymerization Hazardous polymerization will not occur. 11. TOXICOLOGICAL INFORMATION Signs and of Overexposure Eye, Mouth, Nasal and Mucous Membrane irritation. Burning of the skin, mottling of teeth and bones. Acute Effects Eyes May cause severe conjunctiva irritation and corneal damage. May cause burns. Skin 2% solution of hydrofluoric acid was corrosive to rabbit skin with 1 hour exposure, but not with 1 minute. Inhalation May cause irritation of respiratory tract and mucous membranes. Ingestion Harmful or fatal if swallowed. Ingestion may cause burns and irritation to gastrointestinal tract. Target Organ Effects Bone and joints Chronic Toxicity Prolonged exposure can cause bone and joint changes in humans (Fluorosis). Carcinogenicity Contains no ingredient listed as a carcinogen. Page 398 of 553 Page 398 of 553 Page 398 of 553 Page 398 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 5 / 8 Acute Toxicity Values Oral LD50 (Rat) = Not Determined Dermal LD50 (Rabbit) = Not Determined Inhalation LC50 (Rat) = Not Determined 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated 13. DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements Contaminated Packaging Dispose of in accordance with local regulations California Hazardous Waste Codes 791 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Hydrofluoric Acid (Hydrogen Fluoride) Corrosive 14. TRANSPORT INFORMATION DOT Proper Shipping Name Limited Quantity Hazard Class Limited Quantity Description Limited Quantity TDG Proper Shipping Name Hydrofluoric Acid, with 60% strength Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II MEX Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II ICAO UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II Page 399 of 553 Page 399 of 553 Page 399 of 553 Page 399 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 6 / 8 14. TRANSPORT INFORMATION IATA UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II ERG Code 8L Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IMDG/IMO Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Subsidiary Class Toxic UN-No UN1790 Packing Group II EmS No. 8.03 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II RID Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1,II, RID ADR/RID-Labels 8, 6.1 ADR Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II ADN Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Classification Code Unknown Special Provisions 274 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II Hazard Labels 8 Limited Quantity Unknown This Space Intentionally Left Blank Page 400 of 553 Page 400 of 553 Page 400 of 553 Page 400 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 7 / 8 15. REGULATORY INFORMATION International Inventories TSCA Hydrofluoric Acid, Aqueous is listed U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain chemicals (hydrogen fluoride), which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard Yes 15. REGULATORY INFORMATION Cont. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990 CERCLA This material, as supplied, does contain a substance regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). Hydrogen Fluoride (Hydrofluoric Acid) 100 lbs. There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material This Space Intentionally Left Blank Page 401 of 553 Page 401 of 553 Page 401 of 553 Page 401 of 553 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 8 / 8 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Illinois Rhode Island Hydrofluoric Acid NA NA NA NA NA International Regulations See Specific Country for Regulations required. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class E Corrosive material F Dangerously reactive material D1A Toxic materials 16. OTHER INFORMATION Revision Date 04/03/2012 Revision Note Third Revision Prepared By: Manufacturer’s Technical Services Department Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS This Space Intentionally Left Blank Page 402 of 553 Page 402 of 553 Page 402 of 553 Page 402 of 553 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) 09/14/2005 Page 1 of 8 Material Safety Data Sheet Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) MANUFACTURER: 3M DIVISION: Protective Materials & Consumer Specialties Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) Issue Date: 09/14/2005 Supercedes Date: 08/08/2005 Document Group: 18-4808-4 Product Use: Specific Use: OIL, WATER AND STAIN REPELLENT FOR FABRICS IN CONSUMER MARKET SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt LIGHT ALKYLATE PETROLEUM NAPHTHA 64741-66-8 15 - 40 ISOPROPYL ALCOHOL 67-63-0 15 - 40 ACETONE 67-64-1 15 - 40 CARBON DIOXIDE 124-38-9 1 - 5 FLUOROCHEMICAL URETHANE Trade Secret 1 - 5 POLYSILOXANES 68554-67-6 0.5 - 1.5 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Aerosol Odor, Color, Grade: Chemical odor. General Physical Form: Gas Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Aerosol container contains flammable material under pressure. May cause target organ effects. 3.2 POTENTIAL HEALTH EFFECTS Page 403 of 553 Page 403 of 553 Page 403 of 553 Page 403 of 553 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) 09/14/2005 Page 2 of 8 Eye Contact: Mild Eye Irritation: may include redness, pain, and tearing. Skin Contact: Moderate Skin Irritation: may include localized redness, swelling, itching, and dryness. Inhalation: Upper Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Ingestion may cause: Gastrointestinal Irritation: may include abdominal pain, nausea, diarrhea and vomiting. Target Organ Effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: If develop, remove person to fresh air. If persist, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature > 700 ºF [Details: For liquid only] Page 404 of 553 Page 404 of 553 Page 404 of 553 Page 404 of 553 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) 09/14/2005 Page 3 of 8 Flammable Limits - LEL 2.8 % volume [Details: For acetone only] Flammable Limits - UEL 12.7 % volume [Details: For acetone only] OSHA Flammability Classification: Class IB Flammable Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: For leaks or spills which have not ignited, water spray can be used to disperse the flammable vapor and protect personnel attempting to stop the leak. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-[PHONE REDACTED]) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in an approved metal container. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not pierce or burn container, even after use. Do not spray near flames or sources of ignition. Avoid prolonged or repeated skin contact. Avoid vapor contact with open flame, welding arcs or other high temperature sources which may cause vapor decomposition to produce toxic gases. Avoid breathing of airborne material. Wash hands after handling and before eating. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Keep children and pets out of area until treated article has thoroughly dried. 7.2 STORAGE Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Do not heat under confinement to avoid risk of explosion Page 405 of 553 Page 405 of 553 Page 405 of 553 Page 405 of 553 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) 09/14/2005 Page 4 of 8 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in a well-ventilated area. Do not use in a confined area or areas with little or no air movement. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. 8.2.2 Skin Protection Gloves not normally required. Avoid prolonged or repeated skin contact. Keep children and pets out of area until treated article has thoroughly dried. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information ACETONE ACGIH TWA 500 ppm Table A4 ACETONE ACGIH STEL 750 ppm Table A4 ACETONE OSHA TWA, Vacated 750 ppm ACETONE OSHA TWA 1000 ppm Table Z-1 ACETONE OSHA STEL, Vacated 1000 ppm CARBON DIOXIDE ACGIH TWA 5000 ppm CARBON DIOXIDE ACGIH STEL 30000 ppm CARBON DIOXIDE OSHA TWA 10000 ppm Table Z-1A CARBON DIOXIDE OSHA STEL 30000 ppm Table Z-1A ISOPROPYL ALCOHOL ACGIH TWA 200 ppm Table A4 ISOPROPYL ALCOHOL ACGIH STEL 400 ppm Table A4 ISOPROPYL ALCOHOL OSHA TWA 400 ppm Table Z-1A ISOPROPYL ALCOHOL OSHA STEL 500 ppm Table Z-1A VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Aerosol Odor, Color, Grade: Chemical odor. General Physical Form: Gas Page 406 of 553 Page 406 of 553 Page 406 of 553 Page 406 of 553 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) 09/14/2005 Page 5 of 8 Autoignition temperature > 700 ºF [Details: For liquid only] Flammable Limits - LEL 2.8 % volume [Details: For acetone only] Flammable Limits - UEL 12.7 % volume [Details: For acetone only] Boiling point No Data Available Vapor Density No Data Available Vapor Pressure No Data Available Specific Gravity 0.8 [Details: (Liquid fill only)] pH Not Applicable Melting point Not Applicable Solubility in Water Moderate Volatile Organic Compounds Approximately 54 % weight Percent volatile Approximately 92 % weight SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Heat Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. Page 407 of 553 Page 407 of 553 Page 407 of 553 Page 407 of 553 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) 09/14/2005 Page 6 of 8 SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Combustion products will include HF. Facility must be capable of handling halogenated materials. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Facility must be capable of handling aerosol cans. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number UPC ID Number UPC 70-0711-7105-5 000-21200-00213-7 70-0711-7142-8 000-21200-00213-7 70-0711-7221-0 000-21200-00213-7 70-0711-7222-8 000-21200-00213-7 70-0711-7224-4 000-21200-00213-7 70-0712-0359-3 000-21200-00213-7 70-0712-1174-5 000-21200-97920-0 70-0713-0465-6 000-21200-00213-7 70-0713-6187-0 000-21200-47122-3 70-0713-6271-2 000-21200-00213-7 70-0713-7256-2 000-21200-97920-0 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS This material contains one or more substances which are subject to a TSCA Consent Order or Significant New Use Rule. Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status ACETONE 67-64-1 Toxic Substances Control Act (TSCA) 4 Test Rule Chemicals Applicable FLUOROCHEMICAL URETHANE Trade Secret Toxic Substances Control Act (TSCA) 5 SNUR or Consent Order Chemicals Applicable STATE REGULATIONS Contact 3M for more information. Page 408 of 553 Page 408 of 553 Page 408 of 553 Page 408 of 553 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) 09/14/2005 Page 7 of 8 CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 1 Flammability: 3 Reactivity: 0 Protection: X - See PPE section. Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 14: ID Number(s) and/or UPC(s) was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a Page 409 of 553 Page 409 of 553 Page 409 of 553 Page 409 of 553 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD (TM) FABRIC PROTECTOR (CAT. NO. 4101) 09/14/2005 Page 8 of 8 particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M are available at www.3M.com Page 410 of 553 Page 410 of 553 Page 410 of 553 Page 410 of 553 ---PAGE BREAK--- (CITY, STATE AND ZIP CODE) COUNTRY Miami, FL 33136 USA (CITY, STATE AND ZIP CODE) COUNTRY % SARA RQ (by weight) PPM MG/M3 PPM MG/M3 TITLE III LBS Perchloroethylene (a,b,c,d,e,f,g) 127-18-4 10 -30 100 200 25 Yes 100 Severely solvent refined light paraffinic petroleum oil 64741-89-5 30 - 60 5 (oil mist) Xylene (mixed) (a,b,c) 1330-20-7 7 - 13 100 435 100 Yes 1000 Heavy paraffinic petroleum oil 64741-88-4 10 - 30 5 (mist) 5 (mist) (a,c,d) 100-41-4 1 - 5 100 435 125 545 Yes 1000 Methyl salicylate 119-36-8 < 0.1 not established Carbon dioxide (Propellant) 124-38-9 not specified 5000 9000 30000 54000 (a,c) See Section 15 CARCINOGENICITY NTP? Yes Yes No Indicates listing in Table Z - 2, 29 CFR 1910.1000, value shown is 8-hour Time Weighted Average. See table for acceptable ceiling concentration limits and acceptable maximum peak above the acceptable ceiling concentration. MATERIAL SAFETY DATA SHEET SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Sheila Shine (Aerosol) PRODUCT DESCRIPTION: Aerosol container, clear liquid, wintergreen odor. USA and Canada GENERAL USE: Polishing agent, Cleaner. Do not use on Floors and Bathtubs. May pose slipping hazard. DISTRIBUTOR'S NAME Same ADDRESS (NUMBER, STREET, P.O. BOX) SECTION 2 - HAZARDOUS INGREDIENTS INHALATION: Carbon dioxide gas may cause difficulty in breathing, lightheadedness or drowsiness. High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting or even death in confined or poorly ventilated areas. The primary effect of inhalation is narcosis. SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis. This problem may be accentuated by liquid becoming trapped against the skin by contaminated clothing and shoes. Direct spray on skin may cause frostbite. EYES: High vapor concentration or contact may cause irritation, discomfort or pain. May cause slight transient corneal injury. TELEPHONE NUMBER FOR INFORMATION Aerosol container, contents under pressure. Do not store over 130° F (54.4° do not puncture, do not incinerate. Danger! May be fatal if liquid contents are swallowed, inhaled or absorbed through the skin. Affects liver, kidneys, central nervous system and gastrointestinal tract. Causes severe eye irritation. Causes irritation to skin and respiratory tract. Environmental hazard. Flammable, harmful. Hazard Symbols - Xn, N. Risk Phrases - R40, 51/53 OSHA REGULATED? POTENTIAL HEALTH EFFECTS INGESTION: Swallowing of this material may result in irritation of the mouth and GI tract. Vomiting and subsequent aspiration into the lungs may lead to chemical pneumonia and pulmonary edema which is a potentially fatal condition. IARC MONOGRAPHS? California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A person in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical. This is or contains a component (perchloroethylene) that has been reported to be carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA classification. IARC Rating: 2A; NTP Rating: Clear evidence. HAZARDOUS COMPONENTS CAS # OSHA PEL ACGIH TWA Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product. IARC has determined that residual fuels are possibly carcinogenic to humans. Handling procedures and safety precautions in the MSDS should be followed to minimize employee's exposure. SECTION 3 - HAZARDS IDENTIFICATION Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled according to regulations in 40 CFR 260-281. MANUFACTURER'S NAME Sheila Shine, Inc. DATE PREPARED: ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION Page 1 of 4 SUPERSEDES: July 26, 2007 May 22, 2007 1201 NW 1st Ave. (305) 379-1881 EMERGENCY TELEPHONE NUMBER EMERGENCY OVERVIEW EMERGENCY TELEPHONE NUMBER ChemTel Inc. 1- (800) 255-3924 Intl. + 01 (813) 248-0585 Indicates substance appears on National Toxicology Program (NTP) list of carcinogens, International Agency for Research on Cancer (IARC) list of carcinogens or is regulated by the Occupational Safety and Health Administration (OSHA) as a possible carcinogen. Page 411 of 553 Page 411 of 553 Page 411 of 553 Page 411 of 553 ---PAGE BREAK--- July 26, 2007 FLASH POINT (METHOD USED) LEL: UEL: 127.4° F (53° C) TOC (Liquid) IC MATERIAL SAFETY DATA SHEET Page 2 of 4 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Protect containers from abuse; protect from extreme temperatures. CAUTION - FLAMMABLE - keep away from all sources of ignition. "Empty" containers may contain residue which may form explosive vapors. Do not puncture container. Do not attempt to refill container. Maintain well ventilated work areas to minimize exposure when handling this material. Do not use on Floors. May pose slipping hazard. RESPIRATORY PROTECTION: None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete regulations. DO NOT enter low - lying areas without self - contained breathing apparatus where vapors may be present. Inhalation could be fatal. WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general. PERSONAL PROTECTION: SECTION 4 - FIRST AID MEASURES INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR and seek emergency medical attention. SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation persists, seek medical attention. EYES: Check for and remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek medical attention. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION INGESTION: If conscious drink large amounts of water; DO NOT induce vomiting. Take affected person immediately to a hospital; do not give anything by mouth to unconscious person. SECTION 5 - FIRE FIGHTING MEASURES In case of a fire, phosgene, chlorides, oxides of carbon, hydrocarbons, fumes or vapors, and toxic smoke may be produced. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: CAUTION - FLAMMABLE. Evacuate and ventilate area; confine and absorb into absorbent; place material into approved containers for disposal; for spills in excess of allowable quantities (RQ) notify the National Response Center (800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed instructions concerning reporting requirements. Do not discharge into lakes, ponds, streams or public waters. Not determined Not determined NFPA CLASS: AUTOIGNITION TEMPERATURE: EXTINGUISHING MEDIA GENERAL HAZARDS: Product is flammable and vapors concentrated in a confined or poorly ventilated area can be ignited upon contact with a high energy spark, flame or high intensity source of heat such as welding spark. Products of combustion include compounds of carbon, chlorine, hydrogen and oxygen, including carbon monoxide and phosgene. Toxic gases will form upon combustion. Vapors concentrated in a confined or poorly ventilated area can be ignited upon contact with a high energy spark, flame or high intensity source of heat such as welding spark. SECTION 6 - ACCIDENTAL RELEASE MEASURES HAZARDOUS COMBUSTION PRODUCTS PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs. Fire fighters should wear NIOSH / MSHA approved, self - contained breathing apparatus for possible exposure to hydrogen chloride and phosgene. Fine water spray can be used to keep fire - exposed containers cool. ENGINEERING CONTROLS OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station nearby. SECTION 7 - HANDLING AND STORAGE EYE PROTECTION: Chemical splash goggles. Refer to 29 CFR 1910.133 or European Standard EN166. The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation of confined spaces. Use explosion-proof ventilation equipment. FIRE FIGHTING PROCEDURES Carbon dioxide, water fog, dry chemical, chemical foam. Do not use solid stream of water since stream will scatter and spread fire FLAMMABLE LIMITS Not determined PRODUCT NAME: Sheila Shine (Aerosol) UNUSUAL FIRE AND EXPLOSION HAZARDS Page 412 of 553 Page 412 of 553 Page 412 of 553 Page 412 of 553 ---PAGE BREAK--- July 26, 2007 STABILITY UNSTABLE: STABLE: X HAZARDOUS POLYMERIZATION MAY OCCUR: WILL NOT OCCUR: X PROPER SHIPPING NAME: DOT HAZARD CLASS / Pack Group: REFERENCE: UN / NA IDENTIFICATION NUMBER: LABEL: HAZARD SYMBOLS: Methyl salicylate 119-36-8 204-317-7 887 mg / kg Not established Oral - rat 34,200 mg / m3 SECTION 12 - ECOLOGICAL INFORMATION ORM - D / None Heavy paraffinic petroleum oil 127-18-4 Inhalation - rat 204-825-9 4300 mg / kg Not established 215-535-7 Inhalation - rat Severely solvent refined light paraffinic petroleum oil 64741-89-5 5000 ppm / 4H 265-091-3 See Note below Oral - rat 2629 mg / kg See Note below None 49 CFR 173.306 RID/ADR Dangerous Goods Code: Aerosol container, clear liquid, wintergreen odor. MATERIAL SAFETY DATA SHEET Page 3 of 4 (Liquid) 10 mm Hg @ 20° C (Propellant) 838 psig @ 21.1° C SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES CONDITIONS TO AVOID: Extreme temperatures, open flames. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids. CONDITIONS TO AVOID: None CAS # LC50 of Ingredient (Specify Species) EINECS # LD50 of Ingredient (Specify Species and Route) Consumer Commodity (aerosol containers only) SECTION 14 - TRANSPORT INFORMATION WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. This product may produce hazardous vapors in a closed disposal container creating a dangerous environment. Refer to 40 CFR 260 - 299 for complete waste disposal regulations. Consult your local, state, or federal agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway. SECTION 11 - TOXICOLOGICAL INFORMATION 1330-20-7 VAPOR DENSITY (AIR = 1) Not determined < 1 SOLUBILITY IN WATER VAPOR PRESSURE PRODUCT NAME: Sheila Shine (Aerosol) > 1 APPEARANCE AND ODOR FREEZING POINT Negligible SPECIFIC GRAVITY (WATER = 1) EVAPORATION RATE (n-Butyl Acetate = 1) pH 0.960 (Liquid) 100-41-4 202-849-4 3500 mg / kg 204-696-9 IATA HAZARD CLASS / Pack Group: Liquid BOILING POINT PHYSICAL STATE > 5000 mg / kg Xylene (mixed) (a,b,c) 230° F (110° C) (Liquid) Like that of water 8.03 pounds / gallon (957 grams / liter) SECTION 10 - STABILITY AND REACTIVITY Hazardous Ingredients 64741-88-4 124-38-9 Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping. > 3.9 mg / liter Oral - rat Inhalation - rat 265-090-8 VOLATILE ORGANIC COMPOUNDS (Total VOC's) IMDG HAZARD CLASS: CONSUMER COMMODITY None UN TDG Class / Pack Group: See Note below See Note below Oral - rat SECTION 13 - DISPOSAL CONSIDERATIONS Information not found Oral - rat Carbon dioxide (Propellant) (a,c,d) Inhalation - rat Information not found No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be evaluated and approved for each specific biological system. One of the ingredients in this mixture (perchloroethylene) is classified as a Marine Pollutant. 4000 ppm/4H(LCLo) Oral - rat > 5 gm / kg Perchloroethylene (a,b,c,d,e,f,g) HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fumes or vapors, and smoke may be produced. Not applicable VISCOSITY Hazard Identification Number (HIN): None Page 413 of 553 Page 413 of 553 Page 413 of 553 Page 413 of 553 ---PAGE BREAK--- July 26, 2007 EC Risk Phrases R40 Limited evidence of a carcinogenic effect. Hazard HMIS HAZARD RATINGS HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 B REVISION SUMMARY: MSDS Prepared by: Intercession City, FL 33848 USA P.O. Box 395 EINECS (European Inventory of Existing Commercial Chemical Substances) SECTION 16 - OTHER INFORMATION Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances. SYMBOL(S) REQUIRED FOR LABEL Harmful Environment R51/53 Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic environment. S36/37 Wear suitable protective clothing and gloves. S61 Avoid release to the environment. Refer to special instructions / safety data sheets. Components of this product identified by CAS number are listed on the DSL or NDSL, or are otherwise in compliance with the New Substances Notification (NSN) regulations. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated. DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List) Specific toxicity tests have not been conducted on this product. Our hazard evaluation is based on Information from similar products, the ingredients, technical literature, and/or professional experience. (863) 644 - 3298 www.compdatabase.com or www.msds.cc No changes noted This MSDS has been revised in the following sections: Comprehensive Data Base, Inc. 311/312 Hazard Categories TSCA (Toxic Substance Control Act) SARA TITLE III (Superfund Amendments and Reauthorization Act) SECTION 15 - REGULATORY INFORMATION This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Classification: A, B3, D1B, D2A, D2B The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current, applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as described in Section 1. The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or spills to the environment of the Reportable Quantity (RQ for this mixture = 400 lbs) or greater amounts, according to 40 CFR 302. PERSONAL PROTECTIVE EQUIPMENT CPR (Canadian Controlled Products Regulations) MATERIAL SAFETY DATA SHEET PRODUCT NAME: Sheila Shine (Aerosol) Safety Glasses, Gloves CERCLA (Comprehensive Response Compensation and Liability Act) Page 4 of 4 IDL (Canadian Ingredient Disclosure List) All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted from listing because a Low Volume Exemption has been granted in accordance with 40 CFR 723.50. 313 Reportable Ingredients: Indicates a toxic chemical subject to annual reporting requirements of Section 313 of the Emergency Planning and Community Right-To- Know Act of 1986 and of 40 CFR 372. Immediate health, fire hazard, sudden release of pressure. California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986 4 = EXTREME * = Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT There is a reportable chemical present (perchloroethylene) known to the state of California to cause cancer or reproductive toxicity. 2 = MODERATE 3 = HIGH Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in Section 2. S2 Keep out of the reach of children. S23 Do not breathe vapour. EC Safety Phrases Page 414 of 553 Page 414 of 553 Page 414 of 553 Page 414 of 553 ---PAGE BREAK--- Page 1/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 39.0.3 SECTION 1: Identification of the substance/mixture and of the company/ undertaking · 1.1 Product identifier · Trade name: Sheila Shine (Aerosol) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Polishing agent/ Burnishing compound · 1.3 Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: Sheila Shine Inc. 7725 W 2nd Court Hialeah, FL 33014 Phone: (305) 557-1729 · 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The following Hazard Statements are applicable only to the EU regulations and not the US GHS regulation: H412. flame Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated. health hazard Carc. 1B H350 May cause cancer. Skin Irrit. 2 H315 Causes skin irritation. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC T; Toxic R45: May cause cancer. Xi; Irritant R38: Irritating to skin. (Contd. on page 2) Page 415 of 553 Page 415 of 553 Page 415 of 553 Page 415 of 553 ---PAGE BREAK--- Page 2/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 1) 39.0.3 N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Warning! Pressurized container. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS02 GHS07 GHS08 · Signal word Danger · Hazard-determining components of labelling: Distillates (petroleum), solvent-refined light paraffinic Distillates (petroleum), solvent-refined heavy paraffinic tetrachloroethylene · Hazard statements The following Hazard Statements are applicable only to the EU regulations and not the US GHS regulation: H412. H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated. H315 Causes skin irritation. H350 May cause cancer. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P211 Do not spray on an open flame or other ignition source. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: Restricted to professional users. (Contd. on page 3) Page 416 of 553 Page 416 of 553 Page 416 of 553 Page 416 of 553 ---PAGE BREAK--- Page 3/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 2) 39.0.3 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. 16,0 % by mass of the contents are flammable · Hazard description: · WHMIS-symbols: B2 - Flammable liquid D2A - Very toxic material causing other toxic effects · NFPA ratings (scale 0 - 4) 1 3 0 Health = 1 Fire = 3 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *1 3 0 Health = *1 Fire = 3 Reactivity = 0 * - Indicates a long term health hazard from repeated or prolonged exposures. · HMIS Long Term Health Hazard Substances 100-41-4 127-18-4 tetrachloroethylene · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: CAS: 64741-89-5 EINECS: 265-091-3 Index number: 649-455-00-2 Distillates (petroleum), solvent-refined light paraffinic Carc. 1B, H350 30-60% (Contd. on page 4) Page 417 of 553 Page 417 of 553 Page 417 of 553 Page 417 of 553 ---PAGE BREAK--- Page 4/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 3) 39.0.3 CAS: 124-38-9 EINECS: 204-696-9 carbon dioxide Press. Gas, H280 25-50% CAS: 127-18-4 EINECS: 204-825-9 Index number: 602-028-00-4 tetrachloroethylene Xn R40; N R51/53 Carc. Cat. 3 Carc. 2, H351 Aquatic Chronic 2, H411 10-30% CAS: 64741-88-4 EINECS: 265-090-8 Index number: 649-454-00-7 Distillates (petroleum), solvent-refined heavy paraffinic Carc. 1B, H350 10-30% CAS: 1330-20-7 EINECS: 215-535-7 Index number: 601-022-00-9 xylene Xn R20/21; Xi R38 R10 Flam. Liq. 3, H226 Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315 7-13% CAS: 100-41-4 EINECS: 202-849-4 Index number: 601-023-00-4 Xn R20; F R11 Flam. Liq. 2, H225 Carc. 2, H351 Acute Tox. 4, H332 Aquatic Chronic 3, H412 1-5% · Additional information: For the wording of the listed risk phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information: of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Take affected persons out into the fresh air. Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing. In case of irregular breathing or respiratory arrest provide artificial respiration. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If persist, consult a doctor. · After swallowing: Unlikely route of exposure. Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. (Contd. on page 5) Page 418 of 553 Page 418 of 553 Page 418 of 553 Page 418 of 553 ---PAGE BREAK--- Page 5/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 4) 39.0.3 A person vomiting while laying on their back should be turned onto their side. · 4.2 Most important and effects, both acute and delayed Coughing Breathing difficulty Dizziness Irritant to skin and mucous membranes. Nausea Slight irritant effect on eyes. Gastric or intestinal disorders when ingested. Disorientation · Hazards Danger of disturbed cardiac Danger of convulsion. Danger of impaired breathing. Carcinogenic. Danger through skin adsorption. May be harmful if inhaled. · 4.3 Indication of any immediate medical attention and special treatment needed Medical supervision for at least 48 hours. If necessary oxygen respiration treatment. Monitor circulation. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: Water haze or fog Foam Fire-extinguishing powder Carbon dioxide · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Danger of receptacles bursting because of high vapour pressure when heated. During heating or in case of fire poisonous gases are produced. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. · Additional information Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. Cool endangered receptacles with water fog or haze. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. (Contd. on page 6) Page 419 of 553 Page 419 of 553 Page 419 of 553 Page 419 of 553 ---PAGE BREAK--- Page 6/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 5) 39.0.3 Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Keep away from ignition sources. Keep people at a distance and stay on the windward side. Particular danger of slipping on leaked/spilled product. · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with non-combustible liquid-binding material (sand, diatomite, acid binders, universal binders). Remove from the water surface (e.g. skim or suck off). Send for recovery or disposal in suitable receptacles. Dispose contaminated material as waste according to item 13. Used rags or other cleaning materials should be soaked with water and placed in a sealed container. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from heat and direct sunlight. Use only in well ventilated areas. Avoid splashes or spray in enclosed areas. Rags, metal wools / cuttings / shavings and waste papers soaked with product must be placed in a sealed metal container rated for flammable waste. · Information about fire - and explosion protection: Emergency cooling must be available in case of nearby fire. Keep ignition sources away - Do not smoke. Prevent impact and friction. Flammable gas-air mixtures may form in empty receptacles. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 i.e. electric lights. Do not pierce or burn, even after use. Do not spray onto a naked flame or any incandescent material. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. · Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. · Further information about storage conditions: Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting. · 7.3 Specific end use(s) No further relevant information available. (Contd. on page 7) Page 420 of 553 Page 420 of 553 Page 420 of 553 Page 420 of 553 ---PAGE BREAK--- Page 7/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 6) 39.0.3 SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: 127-18-4 tetrachloroethylene PEL (USA) Long-term value: 100 ppm Ceiling limit: 200; 300* ppm *5-min peak in any 3 hrs REL (USA) Minimize workplace exp. concs.;Pocket Guide App. A TLV (USA) Short-term value: 685 mg/m³, 100 ppm Long-term value: 170 mg/m³, 25 ppm BEI EL (Canada) Short-term value: 100 ppm Long-term value: 25 ppm IARC 2A EV (Canada) Short-term value: 100 ppm Long-term value: 25 ppm 1330-20-7 xylene IOELV (EU) Short-term value: 442 mg/m³, 100 ppm Long-term value: 221 mg/m³, 50 ppm Skin PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI EL (Canada) Short-term value: 150 ppm Long-term value: 100 ppm EV (Canada) Short-term value: 650 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm 100-41-4 IOELV (EU) Short-term value: 884 mg/m³, 200 ppm Long-term value: 442 mg/m³, 100 ppm Skin PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 545 mg/m³, 125 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Long-term value: 87 mg/m³, 20 ppm BEI (Contd. on page 8) Page 421 of 553 Page 421 of 553 Page 421 of 553 Page 421 of 553 ---PAGE BREAK--- Page 8/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 7) 39.0.3 EL (Canada) Long-term value: 20 ppm IARC 2B EV (Canada) Short-term value: 540 mg/m³, 125 ppm Long-term value: 435 mg/m³, 100 ppm · DNELs No further relevant information available. · PNECs No further relevant information available. · Ingredients with biological limit values: 127-18-4 tetrachloroethylene BEI (USA) 3 ppm Medium: end-exhaled air Time: prior to shift Parameter: Tetrachloroethylene 0,5 mg/L Medium: blood Time: prior to shift Parameter: Tetrachloroethylene 1330-20-7 xylene BEI (USA) 1,5 g/g creatinine Medium: urine Time: end of shift Parameter: acids 100-41-4 BEI (USA) 0,7 g/g creatinine Medium: urine Time: end of shift at end of workweek Parameter: Sum of mandelic acid and acid (nonspecific, semi-quantitative) - Medium: end-exhaled air Time: not critical Parameter: Ethyl benzene (semi-quantitative) · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Do not inhale gases / fumes / aerosols. Do not carry product impregnated cleaning cloths in trouser pockets. · Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation. For spills, respiratory protection may be advisable. NIOSH or EN approved organic vapor respirator equipped with a dust/mist prefilter should be used. (Contd. on page 9) Page 422 of 553 Page 422 of 553 Page 422 of 553 Page 422 of 553 ---PAGE BREAK--- Page 9/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 8) 39.0.3 · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing · Limitation and supervision of exposure into the environment No further relevant information available. · Risk management measures See Section 7 for additional information. No further relevant information available. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Colour: Clear · Odour: Pleasant · Odour threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Not Determined. Boiling point/Boiling range: 230 °F / 110 °C · Flash point: 127 °F / 53 °C (TOC) · Flammability (solid, gaseous): Not applicable. · Auto/Self-ignition temperature: Not determined. (Contd. on page 10) Page 423 of 553 Page 423 of 553 Page 423 of 553 Page 423 of 553 ---PAGE BREAK--- Page 10/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 9) 39.0.3 · Decomposition temperature: Not determined. · Self-igniting: Product is not self-igniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/ vapour mixtures are possible. · Explosion limits: Lower: 1,1 Vol % (estimated) Upper: 7,0 Vol % (estimated) · Vapour pressure at 20 (Liquid) 10 mmHg ((Propellant) 838 psig) · Density at 20 0,964 g/cm³ · Relative density Not determined. · Vapour density at 20 °C > 1 (air = 1) · Evaporation rate at 20 °C < 1 (butyl acetate = 1) · Solubility in / Miscibility with water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · 9.2 Other information No further relevant information available. SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. · 10.3 Possibility of hazardous reactions Develops readily flammable gases/fumes. Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised. Reacts with strong acids and oxidizing agents. Reacts with certain metals. Toxic fumes may be released if heated above the decomposition point. · 10.4 Conditions to avoid Keep ignition sources away - Do not smoke. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide Hydrocarbons Chlorine compounds (Contd. on page 11) Page 424 of 553 Page 424 of 553 Page 424 of 553 Page 424 of 553 ---PAGE BREAK--- Page 11/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 10) 39.0.3 SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values relevant for classification: 127-18-4 tetrachloroethylene Oral LD50 2629 mg/kg (rat) 1330-20-7 xylene Oral LD50 4300 mg/kg (rat) Dermal LD50 2000 mg/kg (rabbit) · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Slight irritant effect on eyes. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant May cause cancer. May cause acne. Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and headache, dizziness, etc. · Acute effects (acute toxicity, irritation and corrosivity): Vapours have narcotic effect. May be harmful if inhaled. · Repeated dose toxicity: May cause damage to organs through prolonged or repeated exposure. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): Carc. 1B SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: Toxic for aquatic organisms · 12.2 Persistence and degradability The product is partially biodegradable. Significant residuals remain. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish Due to mechanical actions of the product (e.g. agglutinations) damages may occur. · Additional ecological information: · General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. (Contd. on page 12) Page 425 of 553 Page 425 of 553 Page 425 of 553 Page 425 of 553 ---PAGE BREAK--- Page 12/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 11) 39.0.3 Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Due to available data on eliminability/decomposition and bioaccumulation potential prolonged term damage of the environment can not be excluded. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be burned with household garbage after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · DOT, ADR, IMDG, IATA UN1950 · 14.2 UN proper shipping name · DOT Aerosols · ADR 1950 AEROSOLS · IMDG AEROSOLS, FLAMMABLE, MARINE POLLUTANT · IATA AEROSOLS, flammable · 14.3 Transport hazard class(es) · DOT · Class 2.1 · Label 2.1+6.1 · ADR · Class 2 5F Gases. (Contd. on page 13) Page 426 of 553 Page 426 of 553 Page 426 of 553 Page 426 of 553 ---PAGE BREAK--- Page 13/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 12) 39.0.3 · Label 2.1+6.1 · IMDG · Class 2.1 · Label 2.1+6.1 · IATA · Class 2.1 · Label 2.1+6.1 · 14.4 Packing group · DOT, ADR, IMDG, IATA Not Regulated · 14.5 Environmental hazards: Product contains environmentally hazardous substances: tetrachloroethylene · Marine pollutant: Yes Symbol (fish and tree) · Special marking (ADR): Symbol (fish and tree) · 14.6 Special precautions for user Warning: Gases. · Danger code (Kemler): - · EMS Number: F-D,S-U · Segregation groups Liquid halogenated hydrocarbons · 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) 120 ml · Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity · Transport category 1 · Tunnel restriction code D · IMDG · Limited quantities (LQ) 1L · Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity · DOT May be reclassified as Combustible Liquid for transport by highway or rail. · UN "Model Regulation": UN1950, AEROSOLS, 2.1 (6.1) (Contd. on page 14) Page 427 of 553 Page 427 of 553 Page 427 of 553 Page 427 of 553 ---PAGE BREAK--- Page 14/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 13) 39.0.3 SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · United States (USA) · SARA · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): 127-18-4 tetrachloroethylene 1330-20-7 xylene 100-41-4 · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 (California): · Chemicals known to cause cancer: 127-18-4 tetrachloroethylene 100-41-4 · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Carcinogenic Categories · EPA (Environmental Protection Agency) 127-18-4 tetrachloroethylene L 1330-20-7 xylene I 100-41-4 D · IARC (International Agency for Research on Cancer) 127-18-4 tetrachloroethylene 2A 1330-20-7 xylene 3 100-41-4 2B · TLV (Threshold Limit Value established by ACGIH) 127-18-4 tetrachloroethylene A3 1330-20-7 xylene A4 100-41-4 A3 · NIOSH-Ca (National Institute for Occupational Safety and Health) 127-18-4 tetrachloroethylene (Contd. on page 15) Page 428 of 553 Page 428 of 553 Page 428 of 553 Page 428 of 553 ---PAGE BREAK--- Page 15/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 14) 39.0.3 · Canada · Canadian Domestic Substances List (DSL) All ingredients are listed. · Canadian Ingredient Disclosure list (limit 0.1%) 100-41-4 · Canadian Ingredient Disclosure list (limit 127-18-4 tetrachloroethylene · Information about limitation of use: Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases. · Other regulations, limitations and prohibitive regulations This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. · Substances of very high concern (SVHC) according to REACH, Article 57 None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H280 Contains gas under pressure; may explode if heated. H312 Harmful in contact with skin. H315 Causes skin irritation. H332 Harmful if inhaled. H350 May cause cancer. H351 Suspected of causing cancer. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation (Contd. on page 16) Page 429 of 553 Page 429 of 553 Page 429 of 553 Page 429 of 553 ---PAGE BREAK--- Page 16/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 15) 39.0.3 IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Flam. Aerosol 1: Flammable aerosols, Hazard Category 1 Press. Gas: Gases under pressure: Liquefied gas Flam. Liq. 2: Flammable liquids, Hazard Category 2 Flam. Liq. 3: Flammable liquids, Hazard Category 3 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Carc. 1B: Carcinogenicity, Hazard Category 1B Carc. 2: Carcinogenicity, Hazard Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3 · Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-[PHONE REDACTED] Intl. +01 [PHONE REDACTED] Website: www.chemtelinc.com Page 430 of 553 Page 430 of 553 Page 430 of 553 Page 430 of 553 ---PAGE BREAK--- Page 1/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 39.0.3 SECTION 1: Identification of the substance/mixture and of the company/ undertaking · 1.1 Product identifier · Trade name: Sheila Shine (Aerosol) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Polishing agent/ Burnishing compound · 1.3 Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: Sheila Shine Inc. 7725 W 2nd Court Hialeah, FL 33014 Phone: (305) 557-1729 · 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The following Hazard Statements are applicable only to the EU regulations and not the US GHS regulation: H412. flame Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated. health hazard Carc. 1B H350 May cause cancer. Skin Irrit. 2 H315 Causes skin irritation. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC T; Toxic R45: May cause cancer. Xi; Irritant R38: Irritating to skin. (Contd. on page 2) Page 431 of 553 Page 431 of 553 Page 431 of 553 Page 431 of 553 ---PAGE BREAK--- Page 2/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 1) 39.0.3 N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Warning! Pressurized container. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS02 GHS07 GHS08 · Signal word Danger · Hazard-determining components of labelling: Distillates (petroleum), solvent-refined light paraffinic Distillates (petroleum), solvent-refined heavy paraffinic tetrachloroethylene · Hazard statements The following Hazard Statements are applicable only to the EU regulations and not the US GHS regulation: H412. H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated. H315 Causes skin irritation. H350 May cause cancer. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P211 Do not spray on an open flame or other ignition source. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: Restricted to professional users. (Contd. on page 3) Page 432 of 553 Page 432 of 553 Page 432 of 553 Page 432 of 553 ---PAGE BREAK--- Page 3/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 2) 39.0.3 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. 16,0 % by mass of the contents are flammable · Hazard description: · WHMIS-symbols: B2 - Flammable liquid D2A - Very toxic material causing other toxic effects · NFPA ratings (scale 0 - 4) 1 3 0 Health = 1 Fire = 3 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *1 3 0 Health = *1 Fire = 3 Reactivity = 0 * - Indicates a long term health hazard from repeated or prolonged exposures. · HMIS Long Term Health Hazard Substances 100-41-4 127-18-4 tetrachloroethylene · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: CAS: 64741-89-5 EINECS: 265-091-3 Index number: 649-455-00-2 Distillates (petroleum), solvent-refined light paraffinic Carc. 1B, H350 30-60% (Contd. on page 4) Page 433 of 553 Page 433 of 553 Page 433 of 553 Page 433 of 553 ---PAGE BREAK--- Page 4/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 3) 39.0.3 CAS: 124-38-9 EINECS: 204-696-9 carbon dioxide Press. Gas, H280 25-50% CAS: 127-18-4 EINECS: 204-825-9 Index number: 602-028-00-4 tetrachloroethylene Xn R40; N R51/53 Carc. Cat. 3 Carc. 2, H351 Aquatic Chronic 2, H411 10-30% CAS: 64741-88-4 EINECS: 265-090-8 Index number: 649-454-00-7 Distillates (petroleum), solvent-refined heavy paraffinic Carc. 1B, H350 10-30% CAS: 1330-20-7 EINECS: 215-535-7 Index number: 601-022-00-9 xylene Xn R20/21; Xi R38 R10 Flam. Liq. 3, H226 Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315 7-13% CAS: 100-41-4 EINECS: 202-849-4 Index number: 601-023-00-4 Xn R20; F R11 Flam. Liq. 2, H225 Carc. 2, H351 Acute Tox. 4, H332 Aquatic Chronic 3, H412 1-5% · Additional information: For the wording of the listed risk phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information: of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Take affected persons out into the fresh air. Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing. In case of irregular breathing or respiratory arrest provide artificial respiration. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If persist, consult a doctor. · After swallowing: Unlikely route of exposure. Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. (Contd. on page 5) Page 434 of 553 Page 434 of 553 Page 434 of 553 Page 434 of 553 ---PAGE BREAK--- Page 5/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 4) 39.0.3 A person vomiting while laying on their back should be turned onto their side. · 4.2 Most important and effects, both acute and delayed Coughing Breathing difficulty Dizziness Irritant to skin and mucous membranes. Nausea Slight irritant effect on eyes. Gastric or intestinal disorders when ingested. Disorientation · Hazards Danger of disturbed cardiac Danger of convulsion. Danger of impaired breathing. Carcinogenic. Danger through skin adsorption. May be harmful if inhaled. · 4.3 Indication of any immediate medical attention and special treatment needed Medical supervision for at least 48 hours. If necessary oxygen respiration treatment. Monitor circulation. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: Water haze or fog Foam Fire-extinguishing powder Carbon dioxide · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Danger of receptacles bursting because of high vapour pressure when heated. During heating or in case of fire poisonous gases are produced. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. · Additional information Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. Cool endangered receptacles with water fog or haze. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. (Contd. on page 6) Page 435 of 553 Page 435 of 553 Page 435 of 553 Page 435 of 553 ---PAGE BREAK--- Page 6/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 5) 39.0.3 Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Keep away from ignition sources. Keep people at a distance and stay on the windward side. Particular danger of slipping on leaked/spilled product. · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with non-combustible liquid-binding material (sand, diatomite, acid binders, universal binders). Remove from the water surface (e.g. skim or suck off). Send for recovery or disposal in suitable receptacles. Dispose contaminated material as waste according to item 13. Used rags or other cleaning materials should be soaked with water and placed in a sealed container. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from heat and direct sunlight. Use only in well ventilated areas. Avoid splashes or spray in enclosed areas. Rags, metal wools / cuttings / shavings and waste papers soaked with product must be placed in a sealed metal container rated for flammable waste. · Information about fire - and explosion protection: Emergency cooling must be available in case of nearby fire. Keep ignition sources away - Do not smoke. Prevent impact and friction. Flammable gas-air mixtures may form in empty receptacles. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 i.e. electric lights. Do not pierce or burn, even after use. Do not spray onto a naked flame or any incandescent material. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. · Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. · Further information about storage conditions: Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting. · 7.3 Specific end use(s) No further relevant information available. (Contd. on page 7) Page 436 of 553 Page 436 of 553 Page 436 of 553 Page 436 of 553 ---PAGE BREAK--- Page 7/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 6) 39.0.3 SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: 127-18-4 tetrachloroethylene PEL (USA) Long-term value: 100 ppm Ceiling limit: 200; 300* ppm *5-min peak in any 3 hrs REL (USA) Minimize workplace exp. concs.;Pocket Guide App. A TLV (USA) Short-term value: 685 mg/m³, 100 ppm Long-term value: 170 mg/m³, 25 ppm BEI EL (Canada) Short-term value: 100 ppm Long-term value: 25 ppm IARC 2A EV (Canada) Short-term value: 100 ppm Long-term value: 25 ppm 1330-20-7 xylene IOELV (EU) Short-term value: 442 mg/m³, 100 ppm Long-term value: 221 mg/m³, 50 ppm Skin PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI EL (Canada) Short-term value: 150 ppm Long-term value: 100 ppm EV (Canada) Short-term value: 650 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm 100-41-4 IOELV (EU) Short-term value: 884 mg/m³, 200 ppm Long-term value: 442 mg/m³, 100 ppm Skin PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 545 mg/m³, 125 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Long-term value: 87 mg/m³, 20 ppm BEI (Contd. on page 8) Page 437 of 553 Page 437 of 553 Page 437 of 553 Page 437 of 553 ---PAGE BREAK--- Page 8/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 7) 39.0.3 EL (Canada) Long-term value: 20 ppm IARC 2B EV (Canada) Short-term value: 540 mg/m³, 125 ppm Long-term value: 435 mg/m³, 100 ppm · DNELs No further relevant information available. · PNECs No further relevant information available. · Ingredients with biological limit values: 127-18-4 tetrachloroethylene BEI (USA) 3 ppm Medium: end-exhaled air Time: prior to shift Parameter: Tetrachloroethylene 0,5 mg/L Medium: blood Time: prior to shift Parameter: Tetrachloroethylene 1330-20-7 xylene BEI (USA) 1,5 g/g creatinine Medium: urine Time: end of shift Parameter: acids 100-41-4 BEI (USA) 0,7 g/g creatinine Medium: urine Time: end of shift at end of workweek Parameter: Sum of mandelic acid and acid (nonspecific, semi-quantitative) - Medium: end-exhaled air Time: not critical Parameter: Ethyl benzene (semi-quantitative) · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Do not inhale gases / fumes / aerosols. Do not carry product impregnated cleaning cloths in trouser pockets. · Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation. For spills, respiratory protection may be advisable. NIOSH or EN approved organic vapor respirator equipped with a dust/mist prefilter should be used. (Contd. on page 9) Page 438 of 553 Page 438 of 553 Page 438 of 553 Page 438 of 553 ---PAGE BREAK--- Page 9/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 8) 39.0.3 · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing · Limitation and supervision of exposure into the environment No further relevant information available. · Risk management measures See Section 7 for additional information. No further relevant information available. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Colour: Clear · Odour: Pleasant · Odour threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Not Determined. Boiling point/Boiling range: 230 °F / 110 °C · Flash point: 127 °F / 53 °C (TOC) · Flammability (solid, gaseous): Not applicable. · Auto/Self-ignition temperature: Not determined. (Contd. on page 10) Page 439 of 553 Page 439 of 553 Page 439 of 553 Page 439 of 553 ---PAGE BREAK--- Page 10/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 9) 39.0.3 · Decomposition temperature: Not determined. · Self-igniting: Product is not self-igniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/ vapour mixtures are possible. · Explosion limits: Lower: 1,1 Vol % (estimated) Upper: 7,0 Vol % (estimated) · Vapour pressure at 20 (Liquid) 10 mmHg ((Propellant) 838 psig) · Density at 20 0,964 g/cm³ · Relative density Not determined. · Vapour density at 20 °C > 1 (air = 1) · Evaporation rate at 20 °C < 1 (butyl acetate = 1) · Solubility in / Miscibility with water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · 9.2 Other information No further relevant information available. SECTION 10: Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. · 10.3 Possibility of hazardous reactions Develops readily flammable gases/fumes. Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised. Reacts with strong acids and oxidizing agents. Reacts with certain metals. Toxic fumes may be released if heated above the decomposition point. · 10.4 Conditions to avoid Keep ignition sources away - Do not smoke. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide Hydrocarbons Chlorine compounds (Contd. on page 11) Page 440 of 553 Page 440 of 553 Page 440 of 553 Page 440 of 553 ---PAGE BREAK--- Page 11/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 10) 39.0.3 SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values relevant for classification: 127-18-4 tetrachloroethylene Oral LD50 2629 mg/kg (rat) 1330-20-7 xylene Oral LD50 4300 mg/kg (rat) Dermal LD50 2000 mg/kg (rabbit) · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Slight irritant effect on eyes. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant May cause cancer. May cause acne. Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and headache, dizziness, etc. · Acute effects (acute toxicity, irritation and corrosivity): Vapours have narcotic effect. May be harmful if inhaled. · Repeated dose toxicity: May cause damage to organs through prolonged or repeated exposure. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): Carc. 1B SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: Toxic for aquatic organisms · 12.2 Persistence and degradability The product is partially biodegradable. Significant residuals remain. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish Due to mechanical actions of the product (e.g. agglutinations) damages may occur. · Additional ecological information: · General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. (Contd. on page 12) Page 441 of 553 Page 441 of 553 Page 441 of 553 Page 441 of 553 ---PAGE BREAK--- Page 12/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 11) 39.0.3 Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Due to available data on eliminability/decomposition and bioaccumulation potential prolonged term damage of the environment can not be excluded. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be burned with household garbage after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · DOT, ADR, IMDG, IATA UN1950 · 14.2 UN proper shipping name · DOT Aerosols · ADR 1950 AEROSOLS · IMDG AEROSOLS, FLAMMABLE, MARINE POLLUTANT · IATA AEROSOLS, flammable · 14.3 Transport hazard class(es) · DOT · Class 2.1 · Label 2.1+6.1 · ADR · Class 2 5F Gases. (Contd. on page 13) Page 442 of 553 Page 442 of 553 Page 442 of 553 Page 442 of 553 ---PAGE BREAK--- Page 13/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 12) 39.0.3 · Label 2.1+6.1 · IMDG · Class 2.1 · Label 2.1+6.1 · IATA · Class 2.1 · Label 2.1+6.1 · 14.4 Packing group · DOT, ADR, IMDG, IATA Not Regulated · 14.5 Environmental hazards: Product contains environmentally hazardous substances: tetrachloroethylene · Marine pollutant: Yes Symbol (fish and tree) · Special marking (ADR): Symbol (fish and tree) · 14.6 Special precautions for user Warning: Gases. · Danger code (Kemler): - · EMS Number: F-D,S-U · Segregation groups Liquid halogenated hydrocarbons · 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) 120 ml · Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity · Transport category 1 · Tunnel restriction code D · IMDG · Limited quantities (LQ) 1L · Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity · DOT May be reclassified as Combustible Liquid for transport by highway or rail. · UN "Model Regulation": UN1950, AEROSOLS, 2.1 (6.1) (Contd. on page 14) Page 443 of 553 Page 443 of 553 Page 443 of 553 Page 443 of 553 ---PAGE BREAK--- Page 14/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 13) 39.0.3 SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · United States (USA) · SARA · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): 127-18-4 tetrachloroethylene 1330-20-7 xylene 100-41-4 · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 (California): · Chemicals known to cause cancer: 127-18-4 tetrachloroethylene 100-41-4 · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Carcinogenic Categories · EPA (Environmental Protection Agency) 127-18-4 tetrachloroethylene L 1330-20-7 xylene I 100-41-4 D · IARC (International Agency for Research on Cancer) 127-18-4 tetrachloroethylene 2A 1330-20-7 xylene 3 100-41-4 2B · TLV (Threshold Limit Value established by ACGIH) 127-18-4 tetrachloroethylene A3 1330-20-7 xylene A4 100-41-4 A3 · NIOSH-Ca (National Institute for Occupational Safety and Health) 127-18-4 tetrachloroethylene (Contd. on page 15) Page 444 of 553 Page 444 of 553 Page 444 of 553 Page 444 of 553 ---PAGE BREAK--- Page 15/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 14) 39.0.3 · Canada · Canadian Domestic Substances List (DSL) All ingredients are listed. · Canadian Ingredient Disclosure list (limit 0.1%) 100-41-4 · Canadian Ingredient Disclosure list (limit 127-18-4 tetrachloroethylene · Information about limitation of use: Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases. · Other regulations, limitations and prohibitive regulations This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. · Substances of very high concern (SVHC) according to REACH, Article 57 None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H280 Contains gas under pressure; may explode if heated. H312 Harmful in contact with skin. H315 Causes skin irritation. H332 Harmful if inhaled. H350 May cause cancer. H351 Suspected of causing cancer. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation (Contd. on page 16) Page 445 of 553 Page 445 of 553 Page 445 of 553 Page 445 of 553 ---PAGE BREAK--- Page 16/16 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 01.08.2014 Revision: 01.08.2014 Trade name: Sheila Shine (Aerosol) (Contd. of page 15) 39.0.3 IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Flam. Aerosol 1: Flammable aerosols, Hazard Category 1 Press. Gas: Gases under pressure: Liquefied gas Flam. Liq. 2: Flammable liquids, Hazard Category 2 Flam. Liq. 3: Flammable liquids, Hazard Category 3 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Carc. 1B: Carcinogenicity, Hazard Category 1B Carc. 2: Carcinogenicity, Hazard Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3 · Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-[PHONE REDACTED] Intl. +01 [PHONE REDACTED] Website: www.chemtelinc.com Page 446 of 553 Page 446 of 553 Page 446 of 553 Page 446 of 553 ---PAGE BREAK--- Page 447 of 553 Page 447 of 553 Page 447 of 553 Page 447 of 553 ---PAGE BREAK--- Page 448 of 553 Page 448 of 553 Page 448 of 553 Page 448 of 553 ---PAGE BREAK--- Page 449 of 553 Page 449 of 553 Page 449 of 553 Page 449 of 553 ---PAGE BREAK--- Page 450 of 553 Page 450 of 553 Page 450 of 553 Page 450 of 553 ---PAGE BREAK--- (CITY, STATE AND ZIP CODE) COUNTRY Miami, FL 33136 USA (CITY, STATE AND ZIP CODE) COUNTRY % SARA RQ (by weight) PPM MG/M3 PPM MG/M3 TITLE III LBS Perchloroethylene (a,b,c,d,e,f,g) 127-18-4 10 -30 100 200 25 Yes 100 Severely solvent refined light paraffinic petroleum oil 64741-89-5 30 - 60 5 (oil mist) Xylene (mixed) (a,b,c) 1330-20-7 7 - 13 100 435 100 Yes 1000 Heavy paraffinic petroleum oil 64741-88-4 10 - 30 5 (mist) 5 (mist) (a,c,d) 100-41-4 1 - 5 100 435 125 545 Yes 1000 Methyl salicylate 119-36-8 < 0.1 not established Carbon dioxide (Propellant) 124-38-9 not specified 5000 9000 30000 54000 (a,c) See Section 15 CARCINOGENICITY NTP? Yes Yes No Indicates listing in Table Z - 2, 29 CFR 1910.1000, value shown is 8-hour Time Weighted Average. See table for acceptable ceiling concentration limits and acceptable maximum peak above the acceptable ceiling concentration. INHALATION: Carbon dioxide gas may cause difficulty in breathing, lightheadedness or drowsiness. High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting or even death in confined or poorly ventilated areas. The primary effect of inhalation is narcosis. SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis. This problem may be accentuated by liquid becoming trapped against the skin by contaminated clothing and shoes. Direct spray on skin may cause frostbite. EYES: High vapor concentration or contact may cause irritation, discomfort or pain. May cause slight transient corneal injury. POTENTIAL HEALTH EFFECTS INGESTION: Swallowing of this material may result in irritation of the mouth and GI tract. Vomiting and subsequent aspiration into the lungs may lead to chemical pneumonia and pulmonary edema which is a potentially fatal condition. IARC MONOGRAPHS? California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A person in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical. MATERIAL SAFETY DATA SHEET SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Sheila Shine (Aerosol) PRODUCT DESCRIPTION: Aerosol container, clear liquid, wintergreen odor. USA and Canada GENERAL USE: Polishing agent, Cleaner. Do not use on Floors and Bathtubs. May pose slipping hazard. Aerosol container, contents under pressure. Do not store over 130° F (54.4° do not puncture, do not incinerate. Danger! May be fatal if liquid contents are swallowed, inhaled or absorbed through the skin. Affects liver, kidneys, central nervous system and gastrointestinal tract. Causes severe eye irritation. Causes irritation to skin and respiratory tract. Environmental hazard. Flammable, harmful. Hazard Symbols - Xn, N. Risk Phrases - R40, 51/53 OSHA REGULATED? DISTRIBUTOR'S NAME Same ADDRESS (NUMBER, STREET, P.O. BOX) SECTION 2 - HAZARDOUS INGREDIENTS MANUFACTURER'S NAME Sheila Shine, Inc. DATE PREPARED: ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION Page 1 of 4 SUPERSEDES: May 1, 2013 May 20, 2010 1201 NW 1st Ave. (305) 379-1881 This is or contains a component (perchloroethylene) that has been reported to be carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA classification. IARC Rating: 2A; NTP Rating: Clear evidence. HAZARDOUS COMPONENTS CAS # OSHA PEL ACGIH TWA Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product. IARC has determined that residual fuels are possibly carcinogenic to humans. Handling procedures and safety precautions in the MSDS should be followed to minimize employee's exposure. SECTION 3 - HAZARDS IDENTIFICATION Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled according to regulations in 40 CFR 260-281. TELEPHONE NUMBER FOR INFORMATION EMERGENCY TELEPHONE NUMBER ChemTel Inc. 1- (800) 255-3924 Intl. + 01 (813) 248-0585 EMERGENCY TELEPHONE NUMBER EMERGENCY OVERVIEW Indicates substance appears on National Toxicology Program (NTP) list of carcinogens, International Agency for Research on Cancer (IARC) list of carcinogens or is regulated by the Occupational Safety and Health Administration (OSHA) as a possible carcinogen. Page 451 of 553 Page 451 of 553 Page 451 of 553 Page 451 of 553 ---PAGE BREAK--- May 1, 2013 FLASH POINT (METHOD USED) LEL: UEL: 127.4° F (53° C) TOC (Liquid) IC WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general. MATERIAL SAFETY DATA SHEET PERSONAL PROTECTION: RESPIRATORY PROTECTION: None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete regulations. DO NOT enter low - lying areas without self - contained breathing apparatus where vapors may be present. Inhalation could be fatal. SECTION 4 - FIRST AID MEASURES INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR and seek emergency medical attention. SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation persists, seek medical attention. EYES: Check for and remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek medical attention. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION INGESTION: If conscious drink large amounts of water; DO NOT induce vomiting. Take affected person immediately to a hospital; do not give anything by mouth to unconscious person. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Protect containers from abuse; protect from extreme temperatures. CAUTION - FLAMMABLE - keep away from all sources of ignition. "Empty" containers may contain residue which may form explosive vapors. Do not puncture container. Do not attempt to refill container. Maintain well ventilated work areas to minimize exposure when handling this material. Do not use on Floors. May pose slipping hazard. NFPA CLASS: AUTOIGNITION TEMPERATURE: EXTINGUISHING MEDIA GENERAL HAZARDS: Product is flammable and vapors concentrated in a confined or poorly ventilated area can be ignited upon contact with a high energy spark, flame or high intensity source of heat such as welding spark. Products of combustion include compounds of carbon, chlorine, hydrogen and oxygen, including carbon monoxide and phosgene. Toxic gases will form upon combustion. Vapors concentrated in a confined or poorly ventilated area can be ignited upon contact with a high energy spark, flame or high intensity source of heat such as welding spark. SECTION 6 - ACCIDENTAL RELEASE MEASURES HAZARDOUS COMBUSTION PRODUCTS In case of a fire, phosgene, chlorides, oxides of carbon, hydrocarbons, fumes or vapors, and toxic smoke may be produced. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: CAUTION - FLAMMABLE. Evacuate and ventilate area; confine and absorb into absorbent; place material into approved containers for disposal; for spills in excess of allowable quantities (RQ) notify the National Response Center (800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed instructions concerning reporting requirements. Do not discharge into lakes, ponds, streams or public waters. Not determined PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs. Fire fighters should wear NIOSH / MSHA approved, self - contained breathing apparatus for possible exposure to hydrogen chloride and phosgene. Fine water spray can be used to keep fire - exposed containers cool. ENGINEERING CONTROLS OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station nearby. SECTION 7 - HANDLING AND STORAGE EYE PROTECTION: Chemical splash goggles. Refer to 29 CFR 1910.133 or European Standard EN166. The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation of confined spaces. Use explosion-proof ventilation equipment. Carbon dioxide, water fog, dry chemical, chemical foam. Do not use solid stream of water since stream will scatter and spread fire FLAMMABLE LIMITS Not determined PRODUCT NAME: Sheila Shine (Aerosol) SECTION 5 - FIRE FIGHTING MEASURES Not determined Page 2 of 4 FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS Page 452 of 553 Page 452 of 553 Page 452 of 553 Page 452 of 553 ---PAGE BREAK--- May 1, 2013 STABILITY UNSTABLE: STABLE: X HAZARDOUS POLYMERIZATION MAY OCCUR: WILL NOT OCCUR: X PROPER SHIPPING NAME: DOT HAZARD CLASS / Pack Group: REFERENCE: UN / NA IDENTIFICATION NUMBER: LABEL: HAZARD SYMBOLS: Methyl salicylate 119-36-8 204-317-7 887 mg / kg Not established Oral - rat Oral - rat 2629 mg / kg SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 204-825-9 4300 mg / kg Not established 215-535-7 Inhalation - rat Severely solvent refined light paraffinic petroleum oil 64741-89-5 5000 ppm / 4H 265-091-3 34,200 mg / m3 127-18-4 Inhalation - rat SECTION 11 - TOXICOLOGICAL INFORMATION CONDITIONS TO AVOID: Extreme temperatures, open flames. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids. CONDITIONS TO AVOID: None CAS # LC50 of Ingredient (Specify Species) EINECS # LD50 of Ingredient (Specify Species and Route) Hazardous Ingredients Aerosol container, clear liquid, wintergreen odor. MATERIAL SAFETY DATA SHEET Page 3 of 4 (Liquid) 10 mm Hg @ 20° C (Propellant) 838 psig @ 21.1° C See Note below 1330-20-7 VAPOR DENSITY (AIR = 1) Not determined Consumer Commodity (aerosol containers only) SECTION 14 - TRANSPORT INFORMATION WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. This product may produce hazardous vapors in a closed disposal container creating a dangerous environment. Refer to 40 CFR 260 - 299 for complete waste disposal regulations. Consult your local, state, or federal agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway. None 49 CFR 173.306 RID/ADR Dangerous Goods Code: SOLUBILITY IN WATER VAPOR PRESSURE PRODUCT NAME: Sheila Shine (Aerosol) < 1 > 1 Liquid BOILING POINT PHYSICAL STATE > 5000 mg / kg 100-41-4 202-849-4 3500 mg / kg 204-696-9 IATA HAZARD CLASS / Pack Group: See Note below SECTION 12 - ECOLOGICAL INFORMATION Xylene (mixed) (a,b,c) 230° F (110° C) (Liquid) Like that of water 8.03 pounds / gallon (957 grams / liter) SECTION 10 - STABILITY AND REACTIVITY APPEARANCE AND ODOR FREEZING POINT Negligible SPECIFIC GRAVITY (WATER = 1) EVAPORATION RATE (n-Butyl Acetate = 1) pH 0.960 (Liquid) 64741-88-4 124-38-9 Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping. > 3.9 mg / liter Oral - rat Inhalation - rat 265-090-8 ORM - D / None Heavy paraffinic petroleum oil VOLATILE ORGANIC COMPOUNDS (Total VOC's) IMDG HAZARD CLASS: CONSUMER COMMODITY None UN TDG Class / Pack Group: See Note below See Note below 4000 ppm/4H(LCLo) Oral - rat SECTION 13 - DISPOSAL CONSIDERATIONS Information not found Oral - rat Carbon dioxide (Propellant) (a,c,d) Inhalation - rat Information not found No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be evaluated and approved for each specific biological system. One of the ingredients in this mixture (perchloroethylene) is classified as a Marine Pollutant. Oral - rat HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fumes or vapors, and smoke may be produced. Not applicable VISCOSITY Hazard Identification Number (HIN): None > 5 gm / kg Perchloroethylene (a,b,c,d,e,f,g) Page 453 of 553 Page 453 of 553 Page 453 of 553 Page 453 of 553 ---PAGE BREAK--- May 1, 2013 EC Risk Phrases R40 Limited evidence of a carcinogenic effect. Hazard HMIS HAZARD RATINGS HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 B REVISION SUMMARY: MSDS Prepared by: S61 Avoid release to the environment. Refer to special instructions / safety data sheets. S23 Do not breathe vapour. EINECS (European Inventory of Existing Commercial Chemical Substances) (863) 644 - 3298 www.compdatabase.com or www.msds.cc No changes noted This MSDS has been revised in the following sections: Comprehensive Data Base, Inc. Intercession City, FL 33848 USA P.O. Box 395 TSCA (Toxic Substance Control Act) SARA TITLE III (Superfund Amendments and Reauthorization Act) SECTION 15 - REGULATORY INFORMATION This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Classification: A, B3, D1B, D2A, D2B 311/312 Hazard Categories The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current, applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as described in Section 1. The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or spills to the environment of the Reportable Quantity (RQ for this mixture = 400 lbs) or greater amounts, according to 40 CFR 302. PERSONAL PROTECTIVE EQUIPMENT CPR (Canadian Controlled Products Regulations) Specific toxicity tests have not been conducted on this product. Our hazard evaluation is based on Information from similar products, the ingredients, technical literature, and/or professional experience. Components of this product identified by CAS number are listed on the DSL or NDSL, or are otherwise in compliance with the New Substances Notification (NSN) regulations. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated. DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List) Page 4 of 4 IDL (Canadian Ingredient Disclosure List) SECTION 16 - OTHER INFORMATION Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances. SYMBOL(S) REQUIRED FOR LABEL Harmful Environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S36/37 Wear suitable protective clothing and gloves. CERCLA (Comprehensive Response Compensation and Liability Act) MATERIAL SAFETY DATA SHEET PRODUCT NAME: Sheila Shine (Aerosol) Safety Glasses, Gloves All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted from listing because a Low Volume Exemption has been granted in accordance with 40 CFR 723.50. 313 Reportable Ingredients: Indicates a toxic chemical subject to annual reporting requirements of Section 313 of the Emergency Planning and Community Right- To-Know Act of 1986 and of 40 CFR 372. Immediate health, fire hazard, sudden release of pressure. EC Safety Phrases 4 = EXTREME * = Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT There is a reportable chemical present (perchloroethylene) known to the state of California to cause cancer or reproductive toxicity. 2 = MODERATE 3 = HIGH Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in Section 2. S2 Keep out of the reach of children. California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986 Page 454 of 553 Page 454 of 553 Page 454 of 553 Page 454 of 553 ---PAGE BREAK--- PRODUCT DESCRIPTION: Clear liquid, wintergreen odor. USA and Canada (CITY, STATE AND ZIP CODE) COUNTRY Miami, FL 33136 USA (CITY, STATE AND ZIP CODE) COUNTRY % SARA RQ (by weight) PPM MG/M3 PPM MG/M3 TITLE III LBS Perchloroethylene (a,b,c,d,e,f,g) 127-18-4 10 -30 100 200 25 Yes 100 Severely solvent refined light paraffinic petroleum oil 64741-89-5 30 - 60 5 (oil mist) Xylene (mixed) (a,b,c) 1330-20-7 7 - 13 100 435 100 Yes 1000 Heavy paraffinic petroleum oil 64741-88-4 10 - 30 5 (mist) 5 (mist) (a,c,d) 100-41-4 1 - 5 100 435 125 545 Yes 1000 Methyl salicylate 119-36-8 < 0.1 not established (a,c) See Section 15 CARCINOGENICITY NTP? Yes Yes No Indicates listing in Table Z - 2, 29 CFR 1910.1000, value shown is 8-hour Time Weighted Average. See table for acceptable ceiling concentration limits and acceptable maximum peak above the acceptable ceiling concentration. MATERIAL SAFETY DATA SHEET SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Sheila Shine (Liquid) GENERAL USE: Polishing agent, Cleaner. Do not use on Floors and Bathtubs. May pose slipping hazard. DISTRIBUTOR'S NAME Same ADDRESS (NUMBER, STREET, P.O. BOX) SECTION 2 - HAZARDOUS INGREDIENTS INHALATION: High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting or even death in confined or poorly ventilated areas. The primary effect of inhalation is narcosis. SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis. This problem may be accentuated by liquid becoming trapped against the skin by contaminated clothing and shoes. EYES: High vapor concentration or contact may cause irritation, discomfort or pain. May cause slight transient corneal injury. TELEPHONE NUMBER FOR INFORMATION Danger! May be fatal if swallowed, inhaled or absorbed through the skin. Affects liver, kidneys, central nervous system and gastrointestinal tract. Causes severe eye irritation. Causes irritation to skin and respiratory tract. Environmental hazard. Flammable, harmful. Hazard Symbols - Xn, N. Risk Phrases - R40, 51/53 OSHA REGULATED? POTENTIAL HEALTH EFFECTS INGESTION: Swallowing of this material may result in irritation of the mouth and GI tract. Vomiting and subsequent aspiration into the lungs may lead to chemical pneumonia and pulmonary edema which is a potentially fatal condition. IARC MONOGRAPHS? California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A person in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical. This is or contains a component (perchloroethylene) that has been reported to be carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA classification. IARC Rating: 2A; NTP Rating: Clear evidence. HAZARDOUS COMPONENTS CAS # OSHA PEL ACGIH TWA Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product. IARC has determined that residual fuels are possibly carcinogenic to humans. Handling procedures and safety precautions in the MSDS should be followed to minimize employee's exposure. SECTION 3 - HAZARDS IDENTIFICATION Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled according to regulations in 40 CFR 260-281. MANUFACTURER'S NAME Sheila Shine, Inc. DATE PREPARED: ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION Page 1 of 4 SUPERSEDES: July 26, 2007 May 22, 2007 1201 NW 1st Ave. (305) 379-1881 EMERGENCY TELEPHONE NUMBER EMERGENCY TELEPHONE NUMBER ChemTel Inc. 1- (800) 255-3924 Intl. + 01 (813) 248-0585 Indicates substance appears on National Toxicology Program (NTP) list of carcinogens, International Agency for Research on Cancer (IARC) list of carcinogens or is regulated by the Occupational Safety and Health Administration (OSHA) as a possible carcinogen. EMERGENCY OVERVIEW City of Moreno Valley Product code 30663 Document 35102 Page 2004 Return to Index Page 455 of 553 Page 455 of 553 Page 455 of 553 Page 455 of 553 ---PAGE BREAK--- July 26, 2007 FLASH POINT (METHOD USED) LEL: UEL: 132.8° F (56° C) TOC IC MATERIAL SAFETY DATA SHEET Page 2 of 4 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect containers from abuse; protect from extreme temperatures. CAUTION - FLAMMABLE - keep away from all sources of ignition. "Empty" containers may contain residue which may form explosive vapors. Do not weld or cut near empty container that has not been professionally reconditioned. Use non- sparking tools when opening and closing containers. Maintain well ventilated work areas to minimize exposure when handling this material. Do not use on Floors. May pose slipping hazard. RESPIRATORY PROTECTION: None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete regulations. DO NOT enter low - lying areas without self - contained breathing apparatus where vapors may be present. Inhalation could be fatal. WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general. PERSONAL PROTECTION: SECTION 4 - FIRST AID MEASURES INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR and seek emergency medical attention. SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation persists, seek medical attention. EYES: Check for and remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek medical attention. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION INGESTION: If conscious drink large amounts of water; DO NOT induce vomiting. Take affected person immediately to a hospital; do not give anything by mouth to unconscious person. SECTION 5 - FIRE FIGHTING MEASURES In case of a fire, phosgene, chlorides, oxides of carbon, hydrocarbons, fumes or vapors, and toxic smoke may be produced. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: CAUTION - FLAMMABLE. Evacuate and ventilate area; confine and absorb into absorbent; place material into approved containers for disposal; for spills in excess of allowable quantities (RQ) notify the National Response Center (800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed instructions concerning reporting requirements. Do not discharge into lakes, ponds, streams or public waters. Not determined Not determined UNUSUAL FIRE AND EXPLOSION HAZARDS NFPA CLASS: AUTOIGNITION TEMPERATURE: EXTINGUISHING MEDIA GENERAL HAZARDS: Product is flammable and vapors concentrated in a confined or poorly ventilated area can be ignited upon contact with a high energy spark, flame or high intensity source of heat such as welding spark. Products of combustion include compounds of carbon, chlorine, hydrogen and oxygen, including carbon monoxide and phosgene. Toxic gases will form upon combustion. Vapors concentrated in a confined or poorly ventilated area can be ignited upon contact with a high energy spark, flame or high intensity source of heat such as welding spark. SECTION 6 - ACCIDENTAL RELEASE MEASURES HAZARDOUS COMBUSTION PRODUCTS PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs. Fire fighters should wear NIOSH / MSHA approved, self - contained breathing apparatus for possible exposure to hydrogen chloride and phosgene. Fine water spray can be used to keep fire - exposed containers cool. ENGINEERING CONTROLS OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station nearby. SECTION 7 - HANDLING AND STORAGE EYE PROTECTION: Chemical splash goggles. Refer to 29 CFR 1910.133 or European Standard EN166. The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation of confined spaces. Use explosion-proof ventilation equipment. FIRE FIGHTING PROCEDURES Carbon dioxide, water fog, dry chemical, chemical foam. Do not use solid stream of water since stream will scatter and spread fire FLAMMABLE LIMITS Not determined PRODUCT NAME: Sheila Shine (Liquid) City of Moreno Valley Product code 30663 Document 35102 Page 2005 Return to Index Page 456 of 553 Page 456 of 553 Page 456 of 553 Page 456 of 553 ---PAGE BREAK--- July 26, 2007 STABILITY UNSTABLE: STABLE: X HAZARDOUS POLYMERIZATION MAY OCCUR: WILL NOT OCCUR: X PROPER SHIPPING NAME: DOT HAZARD CLASS / Pack Group: REFERENCE: UN / NA IDENTIFICATION NUMBER: LABEL: HAZARD SYMBOLS: 34,200 mg / m3 SECTION 12 - ECOLOGICAL INFORMATION 3 (6.1) / III Heavy paraffinic petroleum oil 127-18-4 Inhalation - rat 204-825-9 4300 mg / kg Not established 215-535-7 Severely solvent refined light paraffinic petroleum oil 64741-89-5 5000 ppm / 4H 265-091-3 Inhalation - rat 3 (6.1) / III Oral - rat Oral - rat 2629 mg / kg 3 (6.1) / III UN 1992 49 CFR 173.150, .203, .242 RID/ADR Dangerous Goods Code: Clear liquid, wintergreen odor MATERIAL SAFETY DATA SHEET Page 3 of 4 10 mm Hg @ 20° C SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES CONDITIONS TO AVOID: Extreme temperatures, open flames. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids. CONDITIONS TO AVOID: None CAS # LC50 of Ingredient (Specify Species) EINECS # LD50 of Ingredient (Specify Species and Route) Flammable liquids, toxic, n.o.s. (Petroleum distillates, Perchloroethylene) SECTION 14 - TRANSPORT INFORMATION WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. This product may produce hazardous vapors in a closed disposal container creating a dangerous environment. Refer to 40 CFR 260 - 299 for complete waste disposal regulations. Consult your local, state, or federal agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway. SECTION 11 - TOXICOLOGICAL INFORMATION 1330-20-7 VAPOR DENSITY (AIR = 1) Not determined < 1 SOLUBILITY IN WATER VAPOR PRESSURE PRODUCT NAME: Sheila Shine (Liquid) > 1 APPEARANCE AND ODOR FREEZING POINT Negligible SPECIFIC GRAVITY (WATER = 1) EVAPORATION RATE (n-Butyl Acetate = 1) pH 0.964 100-41-4 202-849-4 3500 mg / kg 204-317-7 IATA HAZARD CLASS / Pack Group: Liquid BOILING POINT PHYSICAL STATE > 5000 mg / kg Xylene (mixed) (a,b,c) 234° F (112° C) Like that of water 8.03 pounds / gallon (957 grams / liter) SECTION 10 - STABILITY AND REACTIVITY Hazardous Ingredients 64741-88-4 119-36-8 Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping. > 3.9 mg / liter Oral - rat Inhalation - rat 265-090-8 VOLATILE ORGANIC COMPOUNDS (Total VOC's) IMDG HAZARD CLASS: FLAMMABLE, TOXIC F, T UN TDG Class / Pack Group: 3 (6.1) / III 3 (6.1) / III Oral - rat SECTION 13 - DISPOSAL CONSIDERATIONS Not established Oral - rat Methyl salicylate 4000 ppm/4H(LCLo) > 5 gm / kg No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be evaluated and approved for each specific biological system. One of the ingredients in this mixture (perchloroethylene) is classified as a Marine Pollutant. Oral - rat HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fumes or vapors, and smoke may be produced. Not applicable VISCOSITY Hazard Identification Number (HIN): 36 887 mg / kg Perchloroethylene (a,b,c,d,e,f,g) (a,c,d) Inhalation - rat City of Moreno Valley Product code 30663 Document 35102 Page 2006 Return to Index Page 457 of 553 Page 457 of 553 Page 457 of 553 Page 457 of 553 ---PAGE BREAK--- July 26, 2007 EC Risk Phrases R40 Limited evidence of a carcinogenic effect. Hazard HMIS HAZARD RATINGS HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 B REVISION SUMMARY: MSDS Prepared by: Intercession City, FL 33848 USA P.O. Box 395 EINECS (European Inventory of Existing Commercial Chemical Substances) Components of this product identified by CAS number are listed on the DSL or NDSL, or are otherwise in compliance with the New Substances Notification (NSN) regulations. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated. DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List) SECTION 16 - OTHER INFORMATION Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances. SYMBOL(S) REQUIRED FOR LABEL Harmful Environment R51/53 Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic environment. S36/37 Wear suitable protective clothing and gloves. S61 Avoid release to the environment. Refer to special instructions / safety data sheets. S2 Keep out of the reach of children. S23 Do not breathe vapour. Specific toxicity tests have not been conducted on this product. Our hazard evaluation is based on Information from similar products, the ingredients, technical literature, and/or professional experience. MATERIAL SAFETY DATA SHEET PRODUCT NAME: Sheila Shine (Liquid) Safety Glasses, Gloves (863) 644 - 3298 www.compdatabase.com or www.msds.cc No changes noted This MSDS has been revised in the following sections: Comprehensive Data Base, Inc. 311/312 Hazard Categories TSCA (Toxic Substance Control Act) SARA TITLE III (Superfund Amendments and Reauthorization Act) SECTION 15 - REGULATORY INFORMATION This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Classification: B3, D1B, D2A, D2B The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current, applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as described in Section 1. The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or spills to the environment of the Reportable Quantity (RQ for this mixture = 400 lbs) or greater amounts, according to 40 CFR 302. PERSONAL PROTECTIVE EQUIPMENT CPR (Canadian Controlled Products Regulations) CERCLA (Comprehensive Response Compensation and Liability Act) Page 4 of 4 IDL (Canadian Ingredient Disclosure List) Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in Section 2. There is a reportable chemical present (perchloroethylene) known to the state of California to cause cancer or reproductive toxicity. All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted from listing because a Low Volume Exemption has been granted in accordance with 40 CFR 723.50. 313 Reportable Ingredients: Indicates a toxic chemical subject to annual reporting requirements of Section 313 of the Emergency Planning and Community Right-To- Know Act of 1986 and of 40 CFR 372. California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986 Immediate health, fire hazard EC Safety Phrases 4 = EXTREME * = Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH City of Moreno Valley Product code 30663 Document 35102 Page 2007 Return to Index Page 458 of 553 Page 458 of 553 Page 458 of 553 Page 458 of 553 ---PAGE BREAK--- Page 459 of 553 Page 459 of 553 Page 459 of 553 Page 459 of 553 ---PAGE BREAK--- SPARTAN CHEMICAL COMPANY, INC. WHMIS MATERIAL SAFETY DATA SHEET SECTION I: PRODUCT INFORMATION PRODUCT IDENTIFIER SHINE PLUS PRODUCT USE: Multi Surface Protectant MANUFACTURER’S NAME & ADDRESS MEDICAL EMERGENCY TELEPHONE Spartan Chemical Company, Inc. 888/314-6171 (24 Hours) 1110 Spartan Drive, Maumee, OH 43537 USA PRODUCT INFORMATION 800/537-8990 SECTION II: HAZARDOUS INGREDIENTS CAS TLV REGISTRY % W CHEMICAL NAME(S) TWA STEL Ceiling LD50 LC50 NO. mg/m3 mg/m3 mg/m3 70131-67-8 20-25 Dimethyl siloxane, hydroxyl-terminated Not available Not available 68554-54-1 1-5 Amino functional siloxane Not available Not available 9016-45-9 1-5 Nonyl phenol ethoxylate Not available Not available 127087-87-0 1-5 Nonyl phenol ethoxylate Not available Not available SECTION III: PHYSICAL DATA BOILING POINT SPECIFIC GRAVITY (H20 = 1) PERCENT SOLID BY WEIGHT 100 °C (212°F) 0.992 25-35% VAPOUR PRESSURE EVAPORATION RATE (butyl acetate = 1) FREEZING POINT Not established < 1 Not available VAPOUR DENSITY (AIR = 1) SOLUBILITY IN WATER Not established Complete pH APPEARANCE AND ODOUR ODOUR THRESHOLD 4.8-5.3 Milky-white emulsion, floral fragrance Not available COEFFICIENT OF WATER/OIL DISTRIBUTION PHYSICAL STATE Not available GAS LIQUID X SOLID SECTION IV: FIRE & EXPLOSION DATA FLASH POINT METHOD USED FLAMMABLE LIMITS > 100 °C (212°F) ASTM - D56 Not established EXTINGUISHING MEDIA CONDITIONS OF FLAMMABILITY AUTO-IGNITION TEMPERATURE Water, CO2 or dry chemical Not applicable Not applicable HAZARDOUS COMBUSTION PRODUCTS EXPLOSION DATA Not established Not applicable SPECIAL FIRE FIGHTING PROCEDURES Use self-contained breathing apparatus for maximum respiratory protection. Water may be used to cool containers if not ruptured or leaking. UNUSUAL FIRE AND EXPLOSION HAZARDS Product does not support combustion. Use extinguishing media appropriate for surrounding fire. Combustion products are toxic. Page 460 of 553 Page 460 of 553 Page 460 of 553 Page 460 of 553 ---PAGE BREAK--- SECTION V: REACTIVITY DATA STABILITY: STABLE X CONDITIONS OF INSTABILITY CONDITIONS OF REACTIVITY Not established Not established INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Carbon dioxide, carbon monoxide SECTION VI: TOXICOLOGICAL PROPERTIES PRIMARY ROUTES OF ENTRY: Eye Contact, Skin Contact, Ingestion and Inhalation EXPOSURE LIMIT Not established for mixture. EFFECTS OF ACUTE EXPOSURE: EYE CONTACT: May cause mild eye irritation with such as pain, redness and swelling. SKIN CONTACT: May cause mild skin irritation with such as pain, redness and swelling. INGESTION: May be harmful if swallowed. may include nausea, vomiting, pain and diarrhea. INHALATION: Breathing product mist may cause respiratory irritation with such as coughing and difficulty breathing. EFFECTS OF CHRONIC EXPOSURE None expected. IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT CARCINOGENICITY May cause mild eye & skin irritation. Not available No REPRODUCTIVE TOXICITY TERATOGENICITY MUTAGENICITY SYNERGISTIC PRODUCTS Not available Not available Not available Not available SECTION VII: PREVENTIVE MEASURE PERSONAL PROTECTIVE EQUIPMENT / ENGINEERING CONTROLS: Rubber or other impervious gloves are recommended for prolonged or repeated contact. Splash goggles or safety glasses are recommended. Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. LEAK AND SPILL PROCEDURE: Small spills of one gallon or less may be flushed with plenty of water to sanitary sewer system (If permitted by local sewer regulations). Dike and contain large spills with inert material and transfer liquid to containers for recovery or disposal. Keep spill out of storm sewers and waterways. WASTE DISPOSAL METHOD: Dispose of in compliance with all laws and regulations. HANDLING PROCEDURES: Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Do not swallow. Avoid breathing product mist. Wash thoroughly after handling. STORAGE REQUIREMENTS: Do not mix with other chemicals. Keep out of reach of children. SPECIAL SHIPPING INFORMATION: Not regulated. Shipping Description: Cleaning compounds, liquid, n.o.s. SECTION VIII: FIRST AID MEASURES EYES: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention. SKIN: Wash skin thoroughly with soap and water. Get medical attention if irritation persists. INGESTION: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. INHALATION: In case of respiratory irritation or dizziness, move person to fresh air. Get medical attention if irritation persists. SECTION IX: PREPARATION INFORMATION SHINE PLUS DATE OF PREPARATION: March 7, 2011 SUPERCEDES: March 7, 2008 PREPARED BY: Ronald T. Cook / Manager, Regulatory Affairs / Spartan Chemical Company, Inc. TELEPHONE NUMBER: 800/537-8990 Page 461 of 553 Page 461 of 553 Page 461 of 553 Page 461 of 553 ---PAGE BREAK--- SPARTAN CHEMICAL COMPANY, INC. WHMIS MATERIAL SAFETY DATA SHEET SECTION I: PRODUCT INFORMATION PRODUCT IDENTIFIER SHINE PLUS PRODUCT USE: Multi Surface Protectant MANUFACTURER’S NAME & ADDRESS MEDICAL EMERGENCY TELEPHONE Spartan Chemical Company, Inc. 888/314-6171 (24 Hours) 1110 Spartan Drive, Maumee, OH 43537 USA PRODUCT INFORMATION 800/537-8990 SECTION II: HAZARDOUS INGREDIENTS CAS TLV REGISTRY % W CHEMICAL NAME(S) TWA STEL Ceiling LD50 LC50 NO. mg/m3 mg/m3 mg/m3 70131-67-8 20-25 Dimethyl siloxane, hydroxyl-terminated Not available Not available 68554-54-1 1-5 Amino functional siloxane Not available Not available 9016-45-9 1-5 Nonyl phenol ethoxylate Not available Not available 127087-87-0 1-5 Nonyl phenol ethoxylate Not available Not available SECTION III: PHYSICAL DATA BOILING POINT SPECIFIC GRAVITY (H20 = 1) PERCENT SOLID BY WEIGHT 100 °C (212°F) 0.992 25-35% VAPOUR PRESSURE EVAPORATION RATE (butyl acetate = 1) FREEZING POINT Not established < 1 Not available VAPOUR DENSITY (AIR = 1) SOLUBILITY IN WATER Not established Complete pH APPEARANCE AND ODOUR ODOUR THRESHOLD 4.8-5.3 Milky-white emulsion, floral fragrance Not available COEFFICIENT OF WATER/OIL DISTRIBUTION PHYSICAL STATE Not available GAS LIQUID X SOLID SECTION IV: FIRE & EXPLOSION DATA FLASH POINT METHOD USED FLAMMABLE LIMITS > 100 °C (212°F) ASTM - D56 Not established EXTINGUISHING MEDIA CONDITIONS OF FLAMMABILITY AUTO-IGNITION TEMPERATURE Water, CO2 or dry chemical Not applicable Not applicable HAZARDOUS COMBUSTION PRODUCTS EXPLOSION DATA Not established Not applicable SPECIAL FIRE FIGHTING PROCEDURES Use self-contained breathing apparatus for maximum respiratory protection. Water may be used to cool containers if not ruptured or leaking. UNUSUAL FIRE AND EXPLOSION HAZARDS Product does not support combustion. Use extinguishing media appropriate for surrounding fire. Combustion products are toxic. Page 462 of 553 Page 462 of 553 Page 462 of 553 Page 462 of 553 ---PAGE BREAK--- SECTION V: REACTIVITY DATA STABILITY: STABLE X CONDITIONS OF INSTABILITY CONDITIONS OF REACTIVITY Not established Not established INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Carbon dioxide, carbon monoxide SECTION VI: TOXICOLOGICAL PROPERTIES PRIMARY ROUTES OF ENTRY: Eye Contact, Skin Contact, Ingestion and Inhalation EXPOSURE LIMIT Not established for mixture. EFFECTS OF ACUTE EXPOSURE: EYE CONTACT: May cause mild eye irritation with such as pain, redness and swelling. SKIN CONTACT: May cause mild skin irritation with such as pain, redness and swelling. INGESTION: May be harmful if swallowed. may include nausea, vomiting, pain and diarrhea. INHALATION: Breathing product mist may cause respiratory irritation with such as coughing and difficulty breathing. EFFECTS OF CHRONIC EXPOSURE None expected. IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT CARCINOGENICITY May cause mild eye & skin irritation. Not available No REPRODUCTIVE TOXICITY TERATOGENICITY MUTAGENICITY SYNERGISTIC PRODUCTS Not available Not available Not available Not available SECTION VII: PREVENTIVE MEASURE PERSONAL PROTECTIVE EQUIPMENT / ENGINEERING CONTROLS: Rubber or other impervious gloves are recommended for prolonged or repeated contact. Splash goggles or safety glasses are recommended. Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. LEAK AND SPILL PROCEDURE: Small spills of one gallon or less may be flushed with plenty of water to sanitary sewer system (If permitted by local sewer regulations). Dike and contain large spills with inert material and transfer liquid to containers for recovery or disposal. Keep spill out of storm sewers and waterways. WASTE DISPOSAL METHOD: Dispose of in compliance with all laws and regulations. HANDLING PROCEDURES: Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Do not swallow. Avoid breathing product mist. Wash thoroughly after handling. STORAGE REQUIREMENTS: Do not mix with other chemicals. Keep out of reach of children. SPECIAL SHIPPING INFORMATION: Not regulated. Shipping Description: Cleaning compounds, liquid, n.o.s. SECTION VIII: FIRST AID MEASURES EYES: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention. SKIN: Wash skin thoroughly with soap and water. Get medical attention if irritation persists. INGESTION: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. INHALATION: In case of respiratory irritation or dizziness, move person to fresh air. Get medical attention if irritation persists. SECTION IX: PREPARATION INFORMATION SHINE PLUS DATE OF PREPARATION: March 20, 2014 SUPERCEDES: March 7, 2011 PREPARED BY: Ronald T. Cook / Manager, Regulatory Affairs / Spartan Chemical Company, Inc. TELEPHONE NUMBER: 800/537-8990 Page 463 of 553 Page 463 of 553 Page 463 of 553 Page 463 of 553 ---PAGE BREAK--- Page 464 of 553 Page 464 of 553 Page 464 of 553 Page 464 of 553 ---PAGE BREAK--- Page 465 of 553 Page 465 of 553 Page 465 of 553 Page 465 of 553 ---PAGE BREAK--- Page 466 of 553 Page 466 of 553 Page 466 of 553 Page 466 of 553 ---PAGE BREAK--- Page 467 of 553 Page 467 of 553 Page 467 of 553 Page 467 of 553 ---PAGE BREAK--- Page 468 of 553 Page 468 of 553 Page 468 of 553 Page 468 of 553 ---PAGE BREAK--- Page 469 of 553 Page 469 of 553 Page 469 of 553 Page 469 of 553 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date 20-Nov-2013 Revision Date 20-Oct-2014 Revision Number 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING GHS product identifier Product Name Sil-Glyde Grease Other means of identification Product Code(s) BK-4, BK-8, BK-12, BK-1, BK-1A, BK-1ASP, BK-3, BKC-3, BKB-1P, BKBC-1, HB-1, HB-1A, RH-1, RH-1A, RH-1ASP, SG-2, SG-4, SG-4BK, SG-8, SG-8BK, SG-18, SG-20, SG-55, SGO-2, BK-1D, BKC-1, SG-2H, SG-2SW, and SGB-2 Synonyms Sil-Glyde Lubricating Compound/Sil-Glyde Brake Lubricant Recommended use of the chemical and restrictions on use Recommended Use General Home and Auto Lubricant/Brake Lubricant/Radiator Hose Grease/Hitch Ball Lube Uses advised against No information available Supplier's details Emergency telephone number Emergency Telephone Number [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200) Skin Sensitization Category 1 GHS Label elements, including precautionary statements Emergency Overview Supplier Address AGS Company P.O. Box 729 Muskegon, MI 49443 TEL: [PHONE REDACTED] Page 1 / 7 Signal Word Warning Page 470 of 553 Page 470 of 553 Page 470 of 553 Page 470 of 553 ---PAGE BREAK--- WPS-AGS-003 - Sil-Glyde Grease Revision Date 20-Oct-2014 Precautionary Statements Prevention • Avoid breathing dust/fume/gas/mist/vapors/spray. • Contaminated work clothing should not be allowed out of the workplace. • Wear protective gloves. General Advice • None Skin • IF ON SKIN: Wash with plenty of soap and water. • If skin irritation or rash occurs: Get medical advice/attention. • Wash contaminated clothing before reuse. Storage • None Disposal • Dispose of contents/container to an approved waste disposal plant. Hazard Not Otherwise Classified (HNOC) Not applicable Other information Harmful to aquatic life Harmful to aquatic life with long lasting effects ~15% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Sil-Glyde Lubricating Compound/Sil-Glyde Brake Lubricant Chemical Name CAS-No Weight % Trade secret 90-30-2 0.1-1.0 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of necessary first-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention if irritation persists. Skin Contact Wash off immediately with soap and plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Remove and wash contaminated clothing before re-use. Inhalation Move to fresh air. Ingestion Clean mouth with water and afterwards drink plenty of water. Hazard Statements • May cause an allergic skin reaction Appearance Opaque Page 2 / 7 Physical State Semi-Solid. Odor Odorless Page 471 of 553 Page 471 of 553 Page 471 of 553 Page 471 of 553 ---PAGE BREAK--- WPS-AGS-003 - Sil-Glyde Grease Revision Date 20-Oct-2014 Most important acute and delayed Most Important Rashes Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media None Specific Hazards Arising from the Chemical None known Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Environmental Precautions Environmental Precautions Dispose of contents/container to an approved waste disposal plant. See Section 12 for additional Ecological Information. Methods and materials for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Handling Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Keep containers closed in a dry, cool and well-ventilated place. Incompatible Products Strong oxidizing agents. Strong acids. Strong bases. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV Page 3 / 7 OSHA PEL NIOSH IDLH Page 472 of 553 Page 472 of 553 Page 472 of 553 Page 472 of 553 ---PAGE BREAK--- WPS-AGS-003 - Sil-Glyde Grease Revision Date 20-Oct-2014 Diethyl phthalate 84-66-2 TWA: 5 mg/m3 (vacated) TWA: 5 mg/m3 TWA: 5 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Safety glasses with side-shields. Skin and Body Protection Impervious gloves. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Provide regular cleaning of equipment, work area and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Flammable Properties Not flammable Explosive Properties No data available Oxidizing Properties No data available Other information VOC Content No data available 10. STABILITY AND REACTIVITY Physical State Semi-Solid Appearance Opaque Odor Odorless Odor Threshold No information available Property Values Remarks/ - Method pH No data available None known Melting Point/Range No data available None known Boiling Point/Boiling Range No data available None known Flash Point 218 °C / 425 °F None known Evaporation rate Slower than Butyl Acetate None known Flammability (solid, gas) No data available None known Flammability Limits in Air upper flammability limit No data available lower flammability limit No data available Vapor Pressure Negligible None known Vapor Density Heavier than air Air = 1 Specific Gravity 1.0764 None known Water Solubility Negligible None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/waterNo data available None known Autoignition Temperature No data available None known Decomposition Temperature No data available None known Viscosity Page 4 / 7 No data available None known Page 473 of 553 Page 473 of 553 Page 473 of 553 Page 473 of 553 ---PAGE BREAK--- WPS-AGS-003 - Sil-Glyde Grease Revision Date 20-Oct-2014 Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid None known based on information supplied. Incompatible materials Strong oxidizing agents. Strong acids. Strong bases. Hazardous decomposition products Carbon oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation There is no data available for this product. Eye Contact There is no data available for this product. Skin Contact Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion There is no data available for this product. Component Information related to the physical, chemical and toxicological characteristics Allergic skin reactions or irritation. Delayed and immediate effects and also chronic effects from short and long term exposure Sensitization May cause sensitization by skin contact. Mutagenic Effects No information available. Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen. Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration Hazard No information available. Numerical measures of toxicity - Product Acute Toxicity ~15% of the mixture consists of ingredient(s) of unknown toxicity. 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. No data available. Page 5 / 7 Page 474 of 553 Page 474 of 553 Page 474 of 553 Page 474 of 553 ---PAGE BREAK--- WPS-AGS-003 - Sil-Glyde Grease Revision Date 20-Oct-2014 Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Diethyl phthalate 84-66-2 EC50 96 h: 2.11 - 4.29 mg/L static (Pseudokirchneriella subcapitata) EC50 72 h: 42 - 255 mg/L (Pseudokirchneriella subcapitata) EC50 96 h: = 21 mg/L (Desmodesmus subspicatus) EC50 96 h: = 21 mg/L static (Desmodesmus subspicatus) EC50 72 h: = 23 mg/L (Desmodesmus subspicatus) EC50 72 h: = 23 mg/L static (Desmodesmus subspicatus) LC50 96 h: = 12 mg/L flow-through mykiss) LC50 96 h: = 16.7 mg/L static (Lepomis macrochirus) LC50 96 h: = 16.8 mg/L static (Pimephales promelas) LC50 96 h: = 17 mg/L flow-through (Pimephales promelas) LC50 96 h: = 22 mg/L flow-through (Lepomis macrochirus) EC50 = 112 mg/L 30 min EC50 = 114 mg/L 15 min EC50 = 114 mg/L 5 min EC50 48 h: 36 - 74 mg/L (Daphnia magna) EC50 48 h: = 86 mg/L Static (Daphnia magna) Oleic acid 112-80-1 LC50 96 h: = 205 mg/L static (Pimephales promelas) Persistence and Degradability No information available. Bioaccumulation No information available. Other Adverse Effects No information available. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Contaminated Packaging Do not re-use empty containers. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. TRANSPORT INFORMATION DOT Not regulated TDG Not regulated. MEX Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL Complies Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Page 6 / 7 U.S. Federal Regulations Page 475 of 553 Page 475 of 553 Page 475 of 553 Page 475 of 553 ---PAGE BREAK--- WPS-AGS-003 - Sil-Glyde Grease Revision Date 20-Oct-2014 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated by state right-to-know regulations. U.S. EPA Label Information EPA Pesticide Registration Number Not applicable 16. OTHER INFORMATION *Indicates a chronic health hazard. Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Issuing Date 20-Nov-2013 Revision Date 20-Oct-2014 Revision Note Product Code change. General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazard 2 Flammability 1 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 2* Flammability 1 Page 7 / 7 Physical Hazard 0 Personal Protection X Page 476 of 553 Page 476 of 553 Page 476 of 553 Page 476 of 553 ---PAGE BREAK--- SOFT CARE LOTIONIZED HAND SOAP 5454 & 5468 & 5475 & 5487 & 5500 & 5564 & 5593 Industrial/Institutional: Personal care product. 2/25/2003 2/25/2003 Material Safety Data Sheet Product Name Product Use Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Supersedes No Previous Validation Health 1 0 0 Fire Hazard Reactivity Specific Hazard Health Fire Hazard Reactivity Protective Clothing 0 0 1 (800) 851-7145 Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com U.S. Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) Code MSDS# 115500008 3043938 Canadian Headquarters Pink. Liquid. See Section 9. CAUTION: May be mildly irritating to eyes. Emergency Overview None required. PMS# SOFT CARE LOTIONIZED HAND SOAP Cocamide Diethanolamine 61791-31-9 1-5 Not available. Not available. Ammonium Lauryl Sulfate 68081-96-9 1-5 Not available. Not available. Ammonium Laureth Sulfate 67762-19-0 1-5 Not available. Not available. Water 7732-18-5 60-100 Not available. Not available. Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits LC50/LD50 Inhalation. Eye contact. Medical Conditions Aggravated by Overexposure: Persons with pre-existing skin disorders may be more susceptable to irritating effects. Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects None known. May be mildly irritating to eyes. May cause abdominal discomfort, nausea, vomiting and diarrhea. Prolonged or repeated contact may dry skin and cause irritation. Eyes Skin Inhalation Ingestion See Toxicological Information (section 11) Immediately drink plenty of water. If discomfort persists, get medical attention. Flush immediately with plenty of water. Get medical attention if irritation occurs. Rinse with plenty of running water. No specific first aid measures are required. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Continued on Next Page Page: 1/3 Page 477 of 553 Page 477 of 553 Page 477 of 553 Page 477 of 553 ---PAGE BREAK--- Material Safety Data Sheet SOFT CARE LOTIONIZED HAND SOAP None known. None known. Not available. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Put on appropriate personal protective equipment (see Section Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. Avoid contact with eyes. Use appropriate hygiene measures when handling product. FOR INDUSTRIAL USE ONLY. Section 7. Handling and Storage Handling Storage No special ventilation requirements. General room ventilation is adequate. Section 8. Exposure Controls/Personal Protection Engineering Controls No special requirements under normal use conditions. No special requirements under normal use conditions. No special protective clothing is required. No special requirements under normal use conditions. No special requirements under normal use conditions. Personal Protection Eyes Hands Respiratory Feet Body 93°C (199.4°F) Liquid. 6.3 to 7 [Neutral.] 1.01 Fragrance like. Pink. Boiling/Condensation Point 2000-4000 cP (Dynamic). Section 9. Physical and Chemical Properties Physical State and Appearance pH Specific Gravity Viscosity Solubility in water Odor Color Complete. The product is stable. Not available. Will not occur. When exposed to fire: Produces normal products of combustion. None known. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Continued on Next Page Page: 2/3 Page 478 of 553 Page 478 of 553 Page 478 of 553 Page 478 of 553 ---PAGE BREAK--- Material Safety Data Sheet SOFT CARE LOTIONIZED HAND SOAP Section 11. Toxicological Information Effects of Chronic Exposure Other Toxic Effects None known. ORAL (LD50) Greater than 20000 mg/kg (rat). DERMAL (LD50) Estimated to be greater than 2000 mg/kg (rabbit). Acute toxicity Not available. Section 12. Ecological Information Not available. No special precautions. Dispose of according to all federal, state and local regulations. Waste Information Section 13. Disposal Considerations Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 14. Transport Information DOT Classification DOT Proper Shipping Name TDG Classification TDG Proper Shipping Name Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 15. Regulatory Information Chemical Inventory Status Canadian Regulations Not applicable. All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory Registered Product Information Reporting in this section is based on ingredients disclosed in Section 2 WHMIS Classification WHMIS Icon Registered Product Information Not applicable. Not applicable. US Regulations This product is not subject to the reporting requirements under California's Proposition 65. Not available. Section 16. Other Information Other Special Considerations Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Version 1 Page 479 of 553 Page 479 of 553 Page 479 of 553 Page 479 of 553 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T SECTION I - CHEMICAL PRODUCT AND COMPANY INDENTIFICATION PRODUCT NAME : SUPER-SPOT TREE MARK-ALL COLOR IDENTIFICATION NUMBER : E&I 23 20 DATE PRINTED: 05/30/02 PRODUCT USE/CLASS : SUPPLIER: The Nelson Paint Co of Michigan Inc PO Box 2040 Kingsford, MI 49802-2040 EMERGENCY TELEPHONE : [PHONE REDACTED] CHEMTEL : 24 hours MANUFACTURER: The Nelson Paint Co of Michigan Inc PO Box 2040 Kingsford, MI 49802-2040 EMERGENCY TELEPHONE : [PHONE REDACTED] CHEMTEL : 24 hours PREPARER: Doyle Yoder, PHONE: [PHONE REDACTED], PREPARE DATE: 05/09/02 SECTION II - COMPOSITION / INFORMATION ON INGREDIENTS WT. PERCENT IS LESS THAN EXPOSURE CHEMICAL NAME CAS NUMBER TLV-TWA TLV-STEL PEL-TWA PEL-CEILING SKIN Methyl Alcohol 67-56-1 15.0 % 200ppm 250ppm 200ppm N.E. YES Aliphatic Hydrocarbons 8052-41-3 35.0 % 100ppm N.E. 100ppm N.E. NO (See Section XI for abbreviation legend) SECTION III - PHYSICAL DATA BOILING RANGE : 147 - 385 F VAPOR DENSITY : Is heavier than air ODOR : Slight Solvent SPECIFIC GRAVITY : 0.9882 APPEARANCE : Colored Liquid EVAPORATION RATE : Is faster than Butyl Acetate SOLUBILITY IN H2O : Partial VOLATILE BY WEIGHT : 73.4 % VOLATILE BY VOLUME : 84.1 % VOCS, lbs/gal : 5.09 VOCS, grams/ltr : 610 (See Section XI for abbreviation legend) SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT : 73 F LOWER EXPLOSIVE LIMIT : 1.0 % UPPER EXPLOSIVE LIMIT: 36.0 % EXTINGUISHING MEDIA : ALCOHOL FOAM CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid breathing dusts and fumes from burning material. Vapors may form explosive mixture with air. Vapors can travel to a source of ignition and flash back. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner, or properly disposed of. Keep containers closed . Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Water spray may be used for cooling containers to prevent possible pressure build-up and auto-ignition or explosion when exposed to extreme heat. SECTION V - HEALTH HAZARD DATA Page 480 of 553 Page 480 of 553 Page 480 of 553 Page 480 of 553 ---PAGE BREAK--- EFFECTS OF OVEREXPOSURE - EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness, nausea, decreased blood pressure, changes in heart rate and cyanosis (characterized by bluish discoloration of the skin and nails) may result from over-exposure to vapor or skin exposure. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes. Get immediate medical attention. FIRST AID - SKIN CONTACT: Immediately flush skin with plenty of water. Wash with soap and water. Remove soiled clothing. Wash clothing separately before reuse. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: NOTE TO PHYSICIAN: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at methanol concentrations above 20 UG/DL. Methanol is effectively removed by hemodialysis. Keep person warm, quiet and get immediate medical attention. Do NOT induce vomiting, because aspiration of material into the lungs from vomiting can cause chemical pneumonitis which can be fatal. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION EYE CONTACT SECTION VI - REACTIVITY DATA HAZARDOUS DECOMPOSITION PRODUCTS: Hazardous decomposition products: CO, CO2 and Nox. CONDITIONS TO AVOID: Heat, sparks and open flames. INCOMPATABILITY: Avoid contact with: strong oxidizing agents. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate all non-essential personnel. Remove all sources of ignition. Ventilate the area. Equip employees with appropriate protection equipment. Dike around spilled material. Cover spill with absorbent material and shovel with non-sparking tools into container. Remove containers to safe area and seal. Avoid runoff into storm sewers and ditches which lead to waterways. WASTE DISPOSAL METHOD: Dispose of in accordance with all local, state and federal regulations. SECTION VIII - SAFE HANDLING AND USE INFORMATION Page 481 of 553 Page 481 of 553 Page 481 of 553 Page 481 of 553 ---PAGE BREAK--- RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. VENTILATION: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. SKIN PROTECTION: Where contact is likely, wear chemical resistant gloves, a chemical suit and rubber boots. EYE PROTECTION: Do not wear contact lenses. Wear safety glasses with side shields or goggles. OTHER PROTECTIVE EQUIPMENT: Where splashing is possible, full chemically resistant protective clothing and boots are required. HYGENIC PRACTICES: Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor Liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Wash hands before eating or smoking. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid contact with eyes, skin, and clothing. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store away from incompatible substances. Wash thoroughly after handling. Keep away from heat, sparks and flame. Keep container closed when not in use. OTHER PRECAUTIONS: Do not inhale mist or vapor. Keep out of reach of children. Apply with back to wind during outdoor application. SECTION X - HMIS RATINGS HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 1 SECTION XI - OTHER REGULATIONS SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN Methyl Alcohol 67-56-1 15.0 % PREVIOUS MSDS REVISION DATE: 06/28/00 LEGEND : N.A. - Not Applicable, N.E. - Not Established N.D. - Not Determined DISCLAIMER **The Nelson Paint Company, Inc. (TNPC) expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein.** All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, TNPC makes no representations as to its accuracy or sufficiency. Conditions of use are beyond TNPC's control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. (END OF MSDS) Page 482 of 553 Page 482 of 553 Page 482 of 553 Page 482 of 553 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MSDS The Works® Glass And Surface Cleaner Date-Issued: 02/09/2004 MSDS Ref. No: HWKS03365 Date-Revised: 02/11/2004 Revision No: 1 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: The Works® Glass And Surface Cleaner GENERAL USE: Household glass & hard surface cleaner PRODUCT CODE: 03359; 04465 MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS HomeCare Labs, Inc. P.O. Box 491150 Lawrenceville, GA 30049 Customer SERVICE: (800)448-5281 Poison Control Center (Medical) : (877) 800 - 5553 CHEMTREC (US Transportation) : (800) 424 - 9300 2. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS# Wt.% Proprietary Mixture 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Clear, blue liquid with clean, fresh fruit fragrance. IMMEDIATE CONCERNS: CAUTION: Avoid contact with eyes. Keep out of reach of children. POTENTIAL HEALTH EFFECTS EYES: May cause mild eye irritation. Avoid contact with eyes. SKIN: May cause mild skin irritation. Avoid contact with skin. INGESTION: No adverse health effects anticipated from ingestion of incidental amounts of product. INHALATION: This product is not expected to present an inhalation hazard for normal use practices. CHRONIC: There are no known chronic hazards. ROUTES OF ENTRY: Eye Contact and Skin Contact. 4. FIRST AID MEASURES EYES: If contact with eye occurs: Immediately flush with cold water for at least 15 minutes. If irritation persists, get medical attention. SKIN: If on skin: Flush with plenty of water for at least 15 minutes. Get medical attention if irritation persists. INGESTION: Not an expected route of overexposure. INHALATION: Not an expected route of overexposure. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: (112°F) Page 1 of 4 Page 483 of 553 Page 483 of 553 Page 483 of 553 Page 483 of 553 ---PAGE BREAK--- FLAMMABLE CLASS: Class II Flammable Liquid EXTINGUISHING MEDIA: Dry chemical, water, foam or carbon dioxide. Water should be used to cool surrounding containers. EXPLOSION HAZARDS: This product does not pose an immediate explosion hazard. FIRE FIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Small spills may be mopped up or flushed away with water. Otherwise, cover the liquid with an inert absorbent, and scoop up all spilled material & absorbent and place into clean dry plastic containers for disposal. Dispose of according to local, state and federal regulations. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Avoid contact with eyes, skin or clothing. HANDLING: Mix only with water. Do not mix with other chemicals. STORAGE: Keep this product in original closed container when not in use. Store in a cool, dry, well ventilated area. Do not reuse container, but place in trash collection. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: General room ventilation. PERSONAL PROTECTIVE EQUIPMENT: EYES AND FACE: Use of safety glasses with side shields is recommended, if conditions warrant. SKIN: Household gloves are recommended for prolonged contact or for persons with sensitive skin. RESPIRATORY: None required for normal use. PROTECTIVE CLOTHING: If product gets on clothing, remove and wash before reuse. WORK HYGIENIC PRACTICES: In accordance with good industrial hygiene practices, wash hands thoroughly with soap and water after handling this product. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash and safety shower. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Clean, fresh fruit fragrance APPEARANCE: Clear, non-viscous liquid COLOR: Blue pH: 6.0 to 8.0 VAPOR PRESSURE: Not Established VAPOR DENSITY: Not Established BOILING POINT: (212°F) FREEZING POINT: (31°F) SOLUBILITY IN WATER: Soluble EVAPORATION RATE: >1 (n-Butyl Acetate=1) SPECIFIC GRAVITY: 0.99 at (70°F) The Works® Glass And Surface Cleaner Page 2 of 4 Page 484 of 553 Page 484 of 553 Page 484 of 553 Page 484 of 553 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: Avoid high temperatures. STABILITY: This product is stable under normal conditions. POLYMERIZATION: Hazardous polymerization will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, carbon monoxide. INCOMPATIBLE MATERIALS: Strong oxidizing agents. Do Not mix with other products or chemicals. 11. TOXICOLOGICAL INFORMATION EYE EFFECTS: This product may be irritating to eyes. SKIN EFFECTS: This product may be irritating to skin. CARCINOGENICITY: The components of this product are not listed as a carcinogen by IARC. The components of this product are not listed as a carcinogen by NTP. The components of this product are not listed as a carcinogen by OSHA. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: No data available on product. 13. DISPOSAL CONSIDERATIONS PRODUCT DISPOSAL: Disposal of unused, uncontaminated product is regulated according to local, state, and federal regulations. EMPTY CONTAINER: Do not reuse empty container. Discard in trash. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Flammable Liquid, N.O.S. (Contains isopropyl alcohol) PRIMARY HAZARD CLASS/DIVISION: 3 (Flammable Liquid) UN/NA NUMBER: 1993 PACKING GROUP: III OTHER SHIPPING INFORMATION: Limited Quantity 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: FIRE: YES PRESSURE GENERATING: NO REACTIVITY: NO ACUTE: YES CHRONIC: NO 313 REPORTABLE INGREDIENTS: This product does not contain any chemical components with known CAS numbers that exceed the De Minimis reporting levels established by SARA Title II, Section 313 Toxic Chemicals. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA REGULATORY: This product or its components are not subject to export notification. TSCA STATUS: This product or its components are listed on the TSCA Inventory. OSHA HAZARD COMM. RULE: Product is hazardous by definition of the Hazardous Communication Standard. The Works® Glass And Surface Cleaner Page 3 of 4 Page 485 of 553 Page 485 of 553 Page 485 of 553 Page 485 of 553 ---PAGE BREAK--- FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): This product is not a US EPA registered pesticide. 16. OTHER INFORMATION PREPARED BY: Regulatory Affairs Departement REVISION SUMMARY Revision 1 This MSDS replaces the February 11, 2004 MSDS. Any changes in information are as follows: HMIS RATING HEALTH: 1 FLAMMABILITY: 1 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: NFPA RATING HEALTH: 1 FIRE: 1 REACTIVITY: 0 Key 4 = Severe 3 = Serious 2 = Moderate 1 = Slight 0 = Minimal NFPA STORAGE CLASSIFICATION: NFPA Flammable Liquid, Class 2 MANUFACTURER DISCLAIMER: IMPORTANT: This information is given without a warranty or guarantee. No suggestions for use are intended or shall be construed as a recommendation to infringe any existing patents or violate any Federal, State or local laws. Safe handling and use is the responsibility of the customer. Read the label before using this product. This information is true and accurate to the best of our knowledge. The Works® Glass And Surface Cleaner Page 4 of 4 Page 486 of 553 Page 486 of 553 Page 486 of 553 Page 486 of 553 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: TnT TUB AND TILE CLEANER Product Number: 6343 Janitorial Manufacturers Name:Spartan Chemical Company, Inc. Emergency Phone No:(800)537-8990 Address:1110 Spartan Drive City:Maumee State: OH Zip Code:43537 Shipping Description: ORM-D, Consumer commodity, cleaning compounds, aerosol, n.o.s. NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: 1- Slight Fire: 0 - Minimal Fire: 0 - Minimal Reactivity: 1- Slight Reactivity: 1- Slight Pers. Prot. Equip.: B - Safety Glasses; gloves SECTION II: HAZARDOUS INGREDIENTS All component chemicals are listed or exempted from listing on the "TCSA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Chemical Name(s) % W CAS Registry No. Table Z- 1 - A Carcinogen TWA mg/m3 STEL mg/m 3 CELING mg/m3 *2-Butoxyethanol 4 111-76-2 120 Not Established Not Established No Isobutane 01-05 75-28-5 1900 (NIOSH) Not Established Not Established No Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To- Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA Boiling Point: 210-212 °F Vapor Pressure: 18 mm Hg @ 75°F Vapor Density (AIR = Unknown Solubility in Water: Complete (concentrate) pH: 10.5-11.0 Specific Gravity (H2O=1): 1.01 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 1-2 Physical State: Liquid Appearance & Odor: Foam spray, mint fragrance Page 487 of 553 Page 487 of 553 Page 487 of 553 Page 487 of 553 ---PAGE BREAK--- SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: None Method Used: ASTM-D3065 Flammable Limits: Not Established Flame Extension: N/A Extinguishing Media: None Special Fire Fighting Procedures: Use equipment or shielding required to protect personnel against bursting, rupturing or venting containers. Unusual Fire & Explosive Hazards: At elevated temperatures, (over 54°C/130°F) container may vent, rupture or burst. SECTION V: HEALTH HAZARD DATA SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: None known Hazardous Decomposition Products: None Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Dilute with water and flush into sanitary sewer system. Waste Disposal Method: Do not incinerate or puncture aerosol container. Dispose of in accordance with state or local regulations. Page 488 of 553 Page 488 of 553 Page 488 of 553 Page 488 of 553 ---PAGE BREAK--- SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: None required Ventilation: Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or water-resistant gloves Eye Protection(Specify Type): Goggles or safety glasses Other Protective Equipment: None SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Contents under pressure. Do not use near fire, sparks, or flame. Do not store where temperatures could exceed 120°F. Other Precautions: None © SCC 09/24/99 Name:Ronald T. Cook TnT TUB AND TILE CLEANER Title:Manager, Regulatory Affairs Ref: 29 CRF 1910.1200 (OSHA) Effective Date:09/24/99 Changes:Address and Format Supercedes:02/12/98 This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 489 of 553 Page 489 of 553 Page 489 of 553 Page 489 of 553 ---PAGE BREAK--- Page 490 of 553 Page 490 of 553 Page 490 of 553 Page 490 of 553 ---PAGE BREAK--- Page 491 of 553 Page 491 of 553 Page 491 of 553 Page 491 of 553 ---PAGE BREAK--- Page 492 of 553 Page 492 of 553 Page 492 of 553 Page 492 of 553 ---PAGE BREAK--- Page 493 of 553 Page 493 of 553 Page 493 of 553 Page 493 of 553 ---PAGE BREAK--- Tree & Log Marking Paint Page 1 of 4 MATERIAL SAFETY DATA SHEET SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION Product identifier: Tree & Log Marking Paint Product Numbers: 3242 Blue, 3244A Red, 3145 Green, 3246 Black, 3247 White, 3141LF Yellow, 3143LF Orange, 6242 Dark Blue, 6245 Dark Green, 6249 Gray, 3142FL Blue-Glo, 3144FL Orange-Glo, 3145FL Green-Glo, 3148FL Pink-Glo, 3149FL Red-Glo. Product use: Nelson Aerosol: Industrial forestry marking in pressurized spray containers. Supplier name and address: Manufacturer's name and address: Nelson Paint Company of Canada Refer to supplier 48 Industrial Park Crescent Sault Ste. Marie, ON, Canada P6B 5P2 Emergency Telephone [PHONE REDACTED] (Canutec) SECTION 2 —COMPOSITION / INFORMATION ON INGREDIENTS LC50 (rat, inh) LD50 (mg/kg) Ingredients CAS # % (weight) (4hr) rat, oral dermal, rabbit Petroleum solvent 64742-88-7 15 – 40 > 5500 mg/m3 > 5000 > 2000 Methanol 67-56-1 7 – 10 64,000 ppm 5628 15,800 Propane (propellant) 74-98-6 10 – 20 N/Av N/Ap N/Ap 3246 Black and 6249 Gray also contain: Carbon black 1333-86-4 0.1 – 1.0 6750 mg/m3 > 15,400 > 3000 SECTION 3 — HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Liquid aerosol, various colours. Solvent odour. Danger! Flammable aerosol. Contents under pressure. May be harmful if inhaled, swallowed or absorbed through the skin in large amounts. May cause blindness if swallowed. Causes eye irritation. ***POTENTIAL HEALTH EFFECTS*** Target organs: Eyes, skin, respiratory system, digestive system, central nervous system (CNS) Signs and of short-term (acute) exposure: Inhalation: Inhalation of mists or vapours may cause irritation to the nose, throat and upper respiratory tract. Additional may include headache, nausea, vomiting, dizziness, loss of co-ordination and other central nervous system (CNS) effects. In high concentrations, affected person may experience a latent period, which could then be followed by visual effects including sensitivity to light and blurred vision. Product could potentially act as an and cause increased breathing and pulse rates, fatigue, nausea and vomiting. Skin contact: Liquid concentrate may be irritating to the skin. Product may be absorbed if left on the skin, causing similar to those listed for inhalation. Spraying product directly onto skin could cause of frostbite including numbness, prickling and itching. Eye contact: Liquid concentrate causes moderate irritation to the eyes. Spraying product directly into eyes could cause freezing of the eye. Ingestion: Liquid concentrate is poisonous if swallowed. Causes severe irritation to mouth, throat, and stomach. Severe stomach pains, vomiting and diarrhea may follow. Ingestion of extremely large amounts could cause the product to be absorbed. Absorption could cause additional similar to those listed for inhalation. Blindness or death may occur. Effects of long-term (chronic) exposure: Prolonged skin contact may cause drying and cracking of the skin (dermatitis). Other important hazards: Continual and prolonged overexposure to solvents has been shown to cause CNS effects. For further information on other important hazards, see TOXICOLOGICAL INFORMATION, Section 11. Page 494 of 553 Page 494 of 553 Page 494 of 553 Page 494 of 553 ---PAGE BREAK--- Tree & Log Marking Paint Page 2 of 4 SECTION 4 — FIRST AID MEASURES Inhalation: Immediately remove to fresh air. Obtain medical attention. Skin contact: Remove contaminated clothing and wash skin with plenty of soap and water. Obtain medical attention if irritation persists. Eye contact: Flush immediately with water for at least 15 minutes. Obtain medical attention. Ingestion: Contact a physician immediately. Inducing vomiting should only be performed under the direct supervision of medical personnel. If the person is conscious, have victim rinse mouth with water. Give one to two glasses of water to drink to dilute material in the stomach. Never give anything by mouth to an unconscious person. SECTION 5 — FIRE FIGHTING MEASURES Fire hazards/conditions of flammability: Extremely flammable aerosol. Cans are pressurized to 60 - 80 psi (414 – 552 kPa) at 21oC and can explode if heated above 49oC. Vapours are heavier than air and may collect in confined and low-lying areas. The vapours can travel considerable distances and flashback to a source of ignition. Flash point (Method): 24oC (TCC) (estimated) Auto-ignition temperature: N/Av Lower flammable limit by volume): 1.9 Upper flammable limit by volume): 9.5 Explosion data: Sensitivity to mechanical impact / static discharge: N/Av Oxidizing properties: No Suitable extinguishing media: Carbon dioxide, dry chemical, water fog. Special fire-fighting procedures/equipment: Self Contained Breathing Apparatus (SCBA) & protective clothing must be worn by fire fighting personnel. Move containers from fire area if it can be done without risk. Use water spray to cool fire exposed equipment and containers. Avoid spreading burning liquid with water spray used for cooling purposes. Hazardous combustion products: Carbon oxides, formaldehyde gas and other irritating fumes. Nitrogen oxides and sulfur oxides may also be released during a fire. SECTION 6 — ACCIDENTAL RELEASE MEASURES Personal precautions: Restrict access to area until completion of clean-up. Ensure clean-up is conducted by trained personnel only. All persons dealing with clean-up should wear the appropriate protective equipment including self-contained breathing apparatus. Keep all other personnel upwind and away from the spill/release. Environmental precautions: Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. For large spills, dike far ahead of the spill for later recovery or disposal. Spill response/Cleanup: Avoid breathing vapours or mists. Increase ventilation in area of release to prevent the build-up of a flammable / explosive atmosphere. Eliminate all sources of ignition and heat. Stop leak if you can do so without risk. Contain any spilled liquid concentrate and absorb with inert, non-combustible absorbent material, then place absorbent material into a container for later disposal (see Section 13). Contaminated absorbent material may pose the same hazards as the spilled product. Notify the appropriate authorities as required. Prohibited materials: None known. SECTION 7 — HANDLING AND STORAGE Safe handling procedures: Wear appropriate protective equipment. Use in a well ventilated area. Avoid inhalation of vapours or mists. Avoid prolonged or repeated contact with skin and clothing. Avoid contact with eyes. Do not use near sparks, heat or open flame. Keep cans out of direct sunlight. Turn cans upside down, empty the tube, and replace cap when through using. Do not puncture or incinerate. Wash thoroughly after handling. Storage requirements: Store indoors at temperatures of 4 to 32oC, and away from incompatibles. Do not store near furnaces or other sources of heat. Cans are hazardous when emptied; all labelled precautions must be observed. Inspect periodically for damage or leaks. No smoking in the area. Incompatible materials: Oxidizing agents (e.g. Chlorine, Peroxides, etc.), strong acids (e.g. Sulfuric acid), strong bases (e.g. Sodium hydroxide). Page 495 of 553 Page 495 of 553 Page 495 of 553 Page 495 of 553 ---PAGE BREAK--- Tree & Log Marking Paint Page 3 of 4 SECTION 8 — EXPOSURE CONTROLS / PERSONAL PROTECTION Permissible exposure levels: Ingredient name: OSHA PEL ACGIH TLV Petroleum solvent *500 ppm *100 ppm Methanol 200 ppm 200 ppm (skin) Propane (propellant) 1000 ppm *1000 ppm 3246 Black and 6249 Gray also contain: Carbon black 3.5 mg/m3 3.5 mg/m3 *Note: The OSHA PEL and ACGIH TLV listed above for Petroleum solvent is for “Stoddard Solvent”. The ACGIH TLV listed above for Propane is for “Aliphatic hydrocarbon gases”. Ventilation and engineering controls: Must be adequate to control vapours and mists below TLV levels. Product normally used outdoors. Respiratory protection: Use of NIOSH-approved respirators or face masks advisable in windy conditions. Advice should be sought from respiratory protection specialists. Protective gloves: Gloves impervious to the material are recommended. Confirmation of what type of material is most suitable for the intended application, should be obtained from glove suppliers. Eye protection: Use safety splash goggles when transferring paint or solvent, or during spraying applications. Other protective equipment: Eyewash bottles should be readily available at all times. Other protective equipment may be required as prescribed by workplace standards. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES Odour and appearance: Solvent odour. Colour is dependant on the product number being used. Physical State: Liquid aerosol. Odour threshold: N/Av pH: N/Av Boiling point: 150 – 205oC Vapour pressure: 60 – 70 psig (414 – 483 kPa) @ 20oC Freezing point: N/Av Solubility in water: Insoluble Coefficient of oil/water distribution: N/Av Specific gravity: 0.98 – 1.10 @25oC Vapour density (Air = >1 Evaporation rate (Ether = Slower than ether Volatiles 50.3 – 64.0 SECTION 10 — STABILITY AND REACTIVITY Stability and reactivity: Stable under the recommended storage and handling conditions prescribed. Hazardous polymerization will not occur. Conditions to avoid: Avoid heat, sparks, open flame and direct sunlight. Stable under ambient pressure and temperature. Materials to avoid: Incompatible materials (see Section Hazardous decomposition products: None known. Refer to ‘Hazardous combustion products’, Section 5. SECTION 11 — TOXICOLOGICAL INFORMATION Routes of exposure: Eye contact, skin contact, skin absorption, inhalation and ingestion. Toxicological data: There is no available data for the product itself. See Section 2 for ingredient LD50 and LC50 data. Carcinogenicity: Product numbers 3246 and 6249 contain Carbon black. Carbon black is classified by IARC as possibly carcinogenic to humans, based on animal evidence (Group 2B). Teratogenicity, mutagenicity, other reproductive effects: These products contain Methanol. Methanol may cause fetotoxic and teratogenic effects, based on animal data. Sensitization to material: No skin or respiratory sensitization effects are known. Synergistic materials: Not available. SECTION 12 — ECOLOGICAL INFORMATION Environmental effects: The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. Important environmental characteristics: N/Av Aquatic toxicity: There is no data available on the product itself. Page 496 of 553 Page 496 of 553 Page 496 of 553 Page 496 of 553 ---PAGE BREAK--- Tree & Log Marking Paint Page 4 of 4 SECTION 13 —DISPOSAL CONSIDERATIONS Handling for disposal: Handle waste according to recommendations in Section 7. Methods of disposal: Containers should be disposed of in accordance with all applicable local, provincial and federal regulations. SECTION 14 — TRANSPORT INFORMATION Transportation of Dangerous Goods Regulations (TDGR) information: The product, as supplied, can be shipped under the Limited Quantity Exemption within Canada. Refer to Section 1.17 for additional Limited Quantity requirements, if shipping under this exemption. SECTION 15 — REGULATORY INFORMATION WHMIS information: Class A (Compressed Gas), Class B5 (Flammable Aerosol), Class D2A (Materials Causing Other Toxic Effects, Very Toxic Material), Class D2B (Materials Causing Other Toxic Effects, Toxic Material). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and this MSDS contains all the information required by the CPR. CEPA information: All ingredients are listed on the DSL. TSCA information: All ingredients are listed on the TSCA inventory. SECTION 16 — OTHER INFORMATION Prepared by: Nelson Paint Company of Canada Telephone number: [PHONE REDACTED] Preparation date: January 5, 2010 Legend: ACGIH – American Conference of Governmental Industrial Hygienists NIOSH – National Institute for Occupational Safety and Health RTECS: Registry of Toxic Effects of Chemical Substances WHMIS – Workplace Hazardous Material Information System TSCA – Toxic Substances Control Act CEPA – Canadian Environmental Protection Act CAS: Chemical Abstract Services HSDB: Hazardous Substances Data Bank DSL – Domestic Substances List IARC – International Agency for Research on Cancer Inh – Inhalation N/Ap – Not Applicable N/Av – Not Available OSHA – Occupational Safety and Health Act PEL: Permissible Exposure Limit TCC: Tagliabue Closed Cup TLV – Threshold Limit Value References: 1. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2007 (Chempendium, HSDB and RTECs). 2. Material Safety Data Sheet from manufacturer. 3. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices for 2006. 4. International Agency for Research on Cancer Monographs, searched 2007. DISCLAIMER OF LIABILITY **The Nelson Paint Company Of Canada (TNPC) expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein.** All information appearing herein is based upon the data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, TNPC makes no representations as to its accuracy or sufficiency. Conditions of use are beyond TNPC’s control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable from their particular purposes and they assume all risks, of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. END OF DOCUMENT Page 497 of 553 Page 497 of 553 Page 497 of 553 Page 497 of 553 ---PAGE BREAK--- Page 498 of 553 Page 498 of 553 Page 498 of 553 Page 498 of 553 ---PAGE BREAK--- Page 499 of 553 Page 499 of 553 Page 499 of 553 Page 499 of 553 ---PAGE BREAK--- Page 500 of 553 Page 500 of 553 Page 500 of 553 Page 500 of 553 ---PAGE BREAK--- Page 501 of 553 Page 501 of 553 Page 501 of 553 Page 501 of 553 ---PAGE BREAK--- turtle wax, inc 625 Willowbrook Ctr Pkwy Willowbrook, Illinois 60527 Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME TURTLE WAX BUG & TAR AND TREE SAP REMOVER PRODUCT CODE T-525(C) CHEMICAL FAMILY Bug & Tar Remover CHEMICAL NAME Mixture: waxes, solvent, additives FORMULA Mixture MANUFACTURER EMERGENCY TELEPHONE NUMBERS Turtle Wax, Inc. Transportation: 625 Willowbrook Centre Parkway CHEMTREC: [PHONE REDACTED] Willowbrook, IL 60527 Medical: Phone: [PHONE REDACTED] Contact your local Poison Control Center Fax: [PHONE REDACTED] 2. POSITION/INFORMATION ON INGREDIENTS COMPONENT CAS NUMBER CONCENTRATION (wt Petroleum Disillates 8052-41-3 20-25% (Stoddard Solvent) Petroleum Distillates 64742-47-8 7-10% (Hydrotreated Light Distillate Solvent) Methyl Alcohol 67-56-1 1-3% (Methanol) Ethylene Glycol Mono Butyl Ether 111-76-2 1-3% (2 Butoxyethanol) EXPOSURE LIMITS 8 hrs. TWA(ppm) CARCINOGEN OSHA PEL ACGIH TLV (OSHA, NPT, IARC) Petroleum Distillates 100 ppm 100 ppm No (Staddard Solvent) Petroleum Distillates 100 ppm 100 ppm No (Hydrotreated Light Distillate Solvent) Methyl Alcohol 200 ppm 200 ppm No (Methanol) Ethylene Glycol Mono Butyl Ether 25 ppm 25 ppm No (2 Butoxyethanol) 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS INHALATION: Repeated or excessive inhalation of vapor can cause irritation, dizziness, and nausea. No chronic effects known. INGESTION: Causes digestive system upsets, dizziness, nausea, and may cause chemical pneumonia, which may be fatal, if sucked into lungs. No chronic effects known. SKIN CONTACT: Repeated or excessive contact can cause moderate irritation, de-fatting or dermatitis. No chronic effects known. EYE CONTACT: Causes irritation. No chronic effects known. PDF created with pdfFactory trial version www.pdffactory.com Page 502 of 553 Page 502 of 553 Page 502 of 553 Page 502 of 553 ---PAGE BREAK--- - 2 - 4. FIRST AID MEASURES EYE: Flush with water for 15 minutes. Get medical attention if effects persist. SKIN: Remove contaminated clothing. Wash effected areas thoroughly with soap and water. Launder clothing before re-use. INHALATION: Remove to fresh air. Use artificial respiration and oxygen if needed. INGESTION: Rinse mouth. Do not induce vomiting. Get prompt medical attention. Aspiration into lungs can cause chemical pneumonitis which may be fatal. 5. FIRE FIGHTING MEASURES FLASH POINT: (Seta Cl. Cup): 110oF (43oC) Explosive Limits: Lower: n/av Upper: n/av EXTINGUISHING MEDIA: Water Spray, Alcohol Foam, Carbon Dioxide, Dry Chemical SPECIAL FIRE FIGHTING PROCEDURES: Treat as flammable liquid / vapor fire. Keep un-ignited containers cool with water. Vapors are heavier than air, may collect in low areas, and may travel to distant source of ignition and flash back. Avoid flow of molten liquid into sewers. See section 8 for personal protection. 6. ACCIDENTIAL RELEASE MEASURES SPILL OR LEAK PROCEDURES: Remove all ignition sources and use spark proof equipment. Provide good ventilation. Take up spills and put in closed containers. Avoid flow of molten material so sewers. Floors may be slippery. See section 8 for personal protection. 7. HANDLING AND STORAGE STORAGE TEMPERATURE (MIN./MAX.): 32 º F (0 º C)/120º F (49º C) SHELF LIFE: 7 years minimum when the original container is kept closed and properly stored. SPECIAL SENSITIVITY: None. HANDLING AND STORAGE PRECAUTIONS: Store in cool and ventilated places, but avoid freezing. Do not store above 120ºF (49ºC). 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION REQUIREMENTS: Wear goggles. Have convenient eye wash stations. SKIN PROTECTION REQUIREMENTS: Wear solvent resistant gloves and other clothing as needed to prevent exposure. RESPIRATOR/VENTILATION PROTECTION REQUIREMENTS: Provide sufficient ventilation to avoid exposure levels above the established TLV. INGESTION PROTECTION REQUIREMENTS: Avoid swallowing or sucking into lungs. EXPOSURE LIMITS: Not established for product as whole. PDF created with pdfFactory trial version www.pdffactory.com Page 503 of 553 Page 503 of 553 Page 503 of 553 Page 503 of 553 ---PAGE BREAK--- - 3 - 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM: creamy viscous liquid COLOR: Light Beige to off white ODOR: typical solvent BOILING POINT: n/av MELT / FREEZE POINT n/av PH: n/ap SOLUBILITY IN WATER: Insoluable % NON-VOLATILE BY WEIGHT: 5.5% SPECIFIC GRAVITY: 0.930 VAPOR PRESSURE: n/av VAPOR DENSITY: n/av 10. REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Does not occur. INCOMPATIBILITIES: Strong oxidizers such as peroxides. DECOMPOSITION PRODUCTS: When burned: CO2, CO, Hydrocarbons. 11. TOXICOLOGICAL INFORMATION ACUTE INHALATION: Can cause irritation, dizziness, and nausea. CHRONIC INHALATION: None known. ACUTE SKIN CONTACT: Can cause irritation, de-fatting, or dermatitis. CHRONIC SKIN CONTACT: None known ACUTE EYE CONTACT: Causes irritation 12. ECOLOGICAL INFORMATION No data available. 13. DISPOSAL CONSIDERATIONS RCRA HAZARDOUS WASTE: Is classified as a RCRA Hazardous Waste – D001 Ignitable WASTE DISPOSAL METHOD: Dispose of product in accordance with all local, state and federal laws and regulations. PDF created with pdfFactory trial version www.pdffactory.com Page 504 of 553 Page 504 of 553 Page 504 of 553 Page 504 of 553 ---PAGE BREAK--- - 4 - 14. TRANSPORT INFORMATION DOT INFORMATION: ORM-D PROPER SHIPPING NAME: Consumer Commodity TECHNICAL SHIPPING NAME: Automotive specialty cleaner HAZARD CLASS: 3 Flammable Liquid UN NUMBER: None (Canada) 1993 PRODUCT RQ (lbs): n/ap LABEL: Non Bulk ORM-D Bulk 3 Flammable Liquid Organic n.o.s. PLACARD: Non Bulk None Bulk 3 Flammable Liquid Organic n.o.s. FREIGHT CLASS BULK: PG-III FREIGHT CLASS PACKAGE: PG-III PRODUCT LABEL None 15. REGULATORY INFORMATION TSCA STATUS: All ingredients are commercially available and listed by manufacturer. All ingredients are listed under TSCA. CERCLA REPORTABLE QUANTITY: None SARA TITLE III: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES None SECTION 311/312 HAZARD CATEGORIES Acute Health Yes Chronic Health No Fire Yes Reactive No Sudden Release of Pressure No SECTION 313 CHEMICAL NAME CAS NUMBER CONCENTRATION Ethylene Glycon Mono Butyl Ether 111-76-2 1-3% Methanol 67-56-1 1-3% PDF created with pdfFactory trial version www.pdffactory.com Page 505 of 553 Page 505 of 553 Page 505 of 553 Page 505 of 553 ---PAGE BREAK--- - 5 - CANADIAN STATUS: All materials contained in this product are listed on the Canadian Domestic Substances List. Consult Turtle Wax, Inc. regarding status of ingredients. EUROPEAN UNION: All materials contained in this product are listed on EINECS. STATE REGULATORY INFORMATION: The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. COMPONENT/ CAS NUMBER CONCENTRATION STATE CODE None 16. OTHER INFORMATION HMIS CLASSIFICATION Health 1 Flammability 2 Reactivity 0 PPI B NFPA RATING Health 1 Fire 2 Reactivity 0 Special None REASON FOR ISSUE Revised to ANSI format PREPARED BY James P. Heidel TITLE Technical Director, R&D APPROVAL DATE September 11, 2007 SUPERCEDES DATE March 12, 2007 REVISION NUMBER A - 1 This information is to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy oneself as to the suitableness and completeness of such information for their own particular use. PDF created with pdfFactory trial version www.pdffactory.com Page 506 of 553 Page 506 of 553 Page 506 of 553 Page 506 of 553 ---PAGE BREAK--- turtle wax, inc 625 Willowbrook Ctr Pkwy Willowbrook, Illinois 60527 Material Safety Data Sheet EMERGENCY SPILL PHONE: 1 (800) 424-9300 (CHEMTREC) MSDS No: T-417(C) EMERGENCY MEDICAL PHONE: (Contact you local poison control center) PRODUCT INFORMATION PHONE: 1 (630) 455-3700 NFPA Hazard Ratings: Health 1, Flammability 2, Reactivity 0 HMIS Hazard Ratings: Health 1, Flammability 2, Reactivity 0, Protection B Prepared By: Research and Development, Phone: 1 (630) 455-3700 Date Issued: July 25, 2006 1 - MATERIAL IDENTIFICATION PRODUCT NAME: TURTLE WAX PREMIUM POLISHING COMPOUND, T-417(C) Chemical Family: Mixture: Waxes, Solvent, Water, Additives. Material Use or Occurrence: Wax Coating Product Identification No.: None 2 - IMPORTANT INGREDIENTS CHEMICAL NAME CAS No. PERCENT PEL/TLV/TWA CARCINOGEN (Synonyms) OSHA ACGIH (OSHA,NPT,IARC) Petroleum Distillates 64742-47-8 5-8% 100ppm 100ppm No (Kerosene) 3 - CHEMICAL AND PHYSICAL PROPERTIES Boiling Point: n/av Melting Point: n/av Specific Gravity: 1.127 Vapor Pressure: n/av Solubility In Water: Dispersable Vapor Density (Air=1): n/av Evaporation Rate: n/av % Non-volatile: 30.0% Coefficient of Oil/Water Distribution: n/av pH: 8.00 Appearance and Odor: Off White Creamy Liquid: Solvent Odor 4 - FIRE AND EXPLOSION DATA Flash Point (Pensky/Marten Cl. Cup): >200 oF (93 oC) Explosive Limits: Lower: n/av Upper: n/av Extinguishing Media: Water Spray, Alcohol Foam, Carbon Dioxide, Dry Chemical Special Fire Fighting Procedures and Hazards: Avoid flow of material into sewers. See Sec. 6 for personal protection. 5 - REACTIVITY INFORMATION Stable: X Unstable: Precautions: None Hazardous Polymerization Occurs: Does Not Occur: X Incompatibility: Strong oxidizers such as peroxides. Hazardous Decomposition Product: When burned: CO2, CO, Hydrocarbons. PDF created with pdfFactory trial version www.pdffactory.com Page 507 of 553 Page 507 of 553 Page 507 of 553 Page 507 of 553 ---PAGE BREAK--- Turtle Wax, Inc. MSDS No. T-417(C) – July 25, 2006 6 - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: • Repeated or excessive inhalation of vapor, mist or spray can cause irritation, chemical pneumonia, dizziness, and nausea. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. No chronic effects known. • Use NIOSH approved respirator appropriate for concentration of vapor or mist. Provide good ventilation. • Remove to fresh air. Use artificial respiration and oxygen if needed. Skin: • Repeated or excessive contact can cause blisters or rash due to defatting action. No chronic effects known. • Wear solvent resistant gloves and other clothing as needed to prevent exposure. • Remove contaminated clothing, and avoid ignition sources. Wash effected areas thoroughly with soap and water. Eyes: • Causes irritation. No chronic effects known. • Wear goggles. Have convenient eye wash stations. • Flush with water for 15 minutes. Get medical attention if effects persist. Ingestion: • Causes digestive system upsets, dizziness, nausea, and may be fatal. If sucked into lungs, effects are same as for inhalation above. No chronic effects known. • Avoid swallowing or sucking into lungs. Wear face shield if face contact is likely. • Rinse mouth. Do not induce vomiting. Get prompt medical attention, especially if liquid is sucked into lungs. IN ALL CASES: GET PROMPT MEDICAL ATTENTION IF EFFECTS PERSIST. KEEP OUT OF REACH OF CHILDREN. Most likely routes of entry: Skin, Eyes 7 - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Remove all ignition sources, and use spark proof equipment. Provide good ventilation. Take up spills with absorbent or by pumping and put into closed containers. Avoid flow to sewers. Floors may be slippery. See Section 6 for other protective measures. Storage and Handling: Keep away from ignition or heat source. Store in cool and ventilated places, but avoid freezing. Keep containers closed. Waste Disposal: In accordance with applicable local, state, and federal regulations. Is not a RCRA hazardous waste. Empty Containers: Do not cut or weld on empty containers before thoroughly cleaning. Rinse thoroughly before handling, reuse, or disposal. 8 - REGULATORY INFORMATION DOT(HM-181) USA & Int'l: Not regulated as a hazardous material. SARA,Title III: Reportable for Section 313(Form None TSCA INVENTORY: All ingredients are commercially available and presumed to be listed by manufacturer. CALIFORNIA PROP. 65: No listed substances are known to be present. NEW JERSEY LABEL INGREDIENTS: Water (CAS# 7732-18-5), Aluminum Oxide (CAS# 1344-28-1), Petroleum Distillates (CAS# 64742-47-8), Tall Oil Fatty Acid (CAS# 61790-12-3), White Mineral Oil (CAS# 8042-47-5). CANADA EPA DSL INVENTORY: Consult Turtle Wax, Inc. regarding status of ingredients. EEC SIXTH AMENDMENT INVENTORY: Consult Turtle Wax, Inc. regarding status of ingredients. _ The information contained here in has been compiled from sources believed to be reliable and is accurate to the best of our knowledge at this date. It is provided without warranty, expressed or implied, as to the results of use of this information or to the product to which it relates. Recipient assumes all responsibility for the use of this information and the use, storage, or disposal of the product, including any resultant personal injury or property damage. PDF created with pdfFactory trial version www.pdffactory.com Page 508 of 553 Page 508 of 553 Page 508 of 553 Page 508 of 553 ---PAGE BREAK--- UNITED 195 320 37th Avenue, St. Charles, Illinois 60174 • 214 Dolomite Drive, Downsview, Ontario M3J 2N2 To Reorder Call: www.unitedlabsinc.com [PHONE REDACTED] MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 195 SMELL JEL Jellied Deodorant Spray December 22, 2009 HMIS III HEALTH (0 = Maximum Safety) 0 PHYSICAL HAZARD (0 = Maximum Safety) 0 Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. - 1 - Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: A 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Isopropyl alcohol 67-63-0 5-10 400 ppm 983 mg/m3 400 ppm 980 mg/m3 5045 mg/kg (Rat/oral) 16000 ppm/8 hr (Rat) Propane Isobutane 68476-85-7 10-30 1000 ppm 1800 mg/m3 1000 ppm 1800 mg/m3 NE NE 3. HAZARDS IDENTIFICATION Eyes: May cause slight irritation. Skin: May cause irritation. Inhalation: Intentional overexposure to mist or vapors may result in dizziness and headache. Ingestion: May cause nausea. 4. FIRST AID MEASURES Eyes: Flush with plenty of water for 15 minutes and call a physician immediately. Skin: Wash with soap and water. If irritation persists, call a physician. If Inhaled: Remove patient to fresh air immediately. Apply artificial respiration if needed and call a physician. If Swallowed: Drink several glasses of water. Call a physician immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): 180°F/82.2°C Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): Nonflammable per 16 CFR 1500.45 Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Fire and Explosion Hazards: Do not expose aerosols to temperatures above 120°F/49°C or the container may burst, rupture or vent. Extinguishing Media: Carbon dioxide, Dry chemical, Foam. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. Prevent runoff from entering sewers and public waterways. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Pick up small spills with rag or towel. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Prevent material from entering sewers or drains. Wash area thoroughly. Page 509 of 553 Page 509 of 553 Page 509 of 553 Page 509 of 553 ---PAGE BREAK--- - 1 - 7. HANDLING AND STORAGE Keep this product properly labeled and store in a cool, well-ventilated area, away from heat or other sources of ignition. Do not expose to direct sunlight or store at temperatures above 120°F/49°C. may cause bursting. Wash hands and face with soap and water after using this product. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses recommended if direct contact is possible. Skin: Chemical resistant gloves recommended only for prolonged or repeated exposure. Respiratory: Not normally needed. If TLV is exceeded, use a NIOSH/MSHA approved self-contained breathing apparatus respirator. Engineering Controls: Ventilation not normally required and local exhaust generally adequate. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212°F/100°C (Initial-Concentrate) Specific Gravity: 0.98 (Concentrate@70°F) Vapor Pressure: 17.5 70° Melting Point: ND Vapor Density: >1 Evaporation Rate: >1 Solubility in Water: Soluble pH: 8.5-9.5 Appearance and Odor: White aerosol foam in orange or mulberry scent. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Chemical Stability: Stable Incompatibility: Avoid contact with strong oxidizers, alkalies, and acids. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): 25% TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: ND SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 195 SMELL JEL PREPARED BY: Sandy Kopacz Page 510 of 553 Page 510 of 553 Page 510 of 553 Page 510 of 553 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: UNITED 195 SMELL JEL CAS Number: Manufacturer: United Laboratories Inc. SDS Date: 6/29/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=61R4LeyItgs%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 511 of 553 Page 511 of 553 Page 511 of 553 Page 511 of 553 ---PAGE BREAK--- - 1 - UNITED 195 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 195 SMELL JEL Jellied Deodorant Spray December 22, 2012 HMIS III HEALTH (0 = Maximum Safety) 0 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Isopropyl alcohol 67-63-0 5-10 200 ppm 400 ppm 980 mg/m3 >5045 mg/kg (Rat/oral) 16000 ppm 8 hr (Rat) 1.2-propanediol 57-55-6 5-10 N/A N/A 22000-31000 Mg/kg(Rat/oral) N/A Propane/N-Butane 68476-85-7 10-30 1000 ppm 1800 mg/m3 1000 ppm 1800 mg/m3 N/A N/A 3. HAZARDS IDENTIFICATION Emergency Overview: Aerosol under pressure do not expose to high temperatures 120°F/49°C or store in direct sunlight. Routes of Entry: Eyes, Skin, Ingestion, Inhalation Eyes: May cause irritation. Skin: May cause slight irritation, possible dryness with prolonged contact. Inhalation: Intentional overexposure to mist or vapors may result in dizziness and headache. Ingestion: May cause nausea or gastric discomfort. Chronic Health Hazards: None known. Medical Conditions Generally Aggravated by Exposure: None known. Carcinogenicity (NTP/IARC/OSHA): None 4. FIRST AID MEASURES Eyes: Flush with plenty of water for 15 minutes and call a physician immediately. Skin: Wash with soap and water. If irritation persists, call a physician. If Inhaled: Remove patient to fresh air immediately. Apply artificial respiration if needed and call a physician. If Swallowed: Drink several glasses of water. Call a physician immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): 180°F/82.2°C Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): Nonflammable per 16 CFR 1500.45 Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Fire and Explosion Hazards: Do not expose aerosols to temperatures above 120°F/49°C or the container may burst, rupture or vent. Extinguishing Media: Water, foam, Carbon dioxide, Dry chemical, Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. Prevent runoff from entering sewers and public waterways. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Pick up small spills with rag or towel. Clean surface thoroughly to remove residual contamination. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Prevent material from entering sewers or drains. Wash area thoroughly to remove residual contamination. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: A Page 512 of 553 Page 512 of 553 Page 512 of 553 Page 512 of 553 ---PAGE BREAK--- - 2 - 7. HANDLING AND STORAGE Keep this product properly labeled and store in a cool, well-ventilated area, away from heat or other sources of ignition. Do not expose to direct sunlight or store at temperatures above 120°F/49°C. may cause bursting. Wash hands and face with soap and water after using this product. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses recommended if direct contact is possible. Skin: Chemical resistant gloves recommended only for prolonged or repeated exposure. Respiratory: Not normally needed. If TLV is exceeded, an organic vapor cartridge respirator or SCBA may be needed. Engineering Controls: Ventilation not normally required and local exhaust generally adequate. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212°F/100°C (Initial-Concentrate) Specific Gravity: 0.99 (Concentrate@77°F) Vapor Pressure: 17.5 77°F Melting Point: ND Vapor Density: >1 Evaporation Rate: <1 Solubility in Water: Soluble pH: 7.6—7.7 VOC (Volatile Organic Compounds): 24.9% Appearance and Odor: White aerosol foam in orange or mulberry scent 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Chemical Stability: Stable Conditions to Avoid (Polymerization): None Incompatibility: Avoid contact with strong oxidizers, alkalies, and acids. 11. TOXICOLOGICAL INFORMATION See section 2 12. ECOLOGICAL INFORMATION N/A 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Wrap container and place in trash collection. Disposal regulations may be different for each state and/or locality. Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. RCRA Hazard Class: Considered non-hazardous under RCA, however product should be fully characterized prior to disposal (40 CFR 261) 14. TRANSPORT INFORMATION US DOT: Consumer Commodity, ORM-D IMDG-Water/Ocean: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2, PG None IATA-Air: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2 PG None 15. REGULATORY INFORMATION U.S. Federal Regulations: TSCA (Toxic Substances Control Act): All Chemicals are listed or exempt CERCLA (Comprehensive Response Compensation, and Liability Act): None SARA Title III Section 302 EHS: None SARA Title III Section 311/312: None SARA Title III Section 313 Toxic Chemicals: Isopropyl Alcohol – CAS#67-63-0 State Regulations: California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No Right-to-know acts for Rhode Island, Florida, Minnesota, Massachusetts, New Jersey, Tennessee, Connecticut hazardous material survey. Illinois toxic substances disclosure to employee act. 195WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 195 SMELL JEL PREPARED BY: Sandy Kopacz Page 513 of 553 Page 513 of 553 Page 513 of 553 Page 513 of 553 ---PAGE BREAK--- - 1 - UNITED 50 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 50 PINK MARVEL Cleaner Descaler February 16, 2012 HMIS III HEALTH (0 = Maximum Safety) 2 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 0 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Phosphoric acid 7664-38-2 15-40 1mg/m3 1 mg/m3 1530 mg/kg (Rat/oral) NE Ethanol, 2,2’-imiaobis n-tallow Alkyl derivs 61791-44-4 5-10 NE NE 1200-1500 Mg/kg (Rat/oral) 220 ppm @ 1 hr (Rat) 3. HAZARDS IDENTIFICATION Eyes: May cause irritation or burns. Can cause destructive burns and permanent damage. Skin: Prolonged or repeated contact with the liquid may cause irritation or burns. Inhalation: Mists of this product are irritating to the respiratory tract and may cause breathing difficulty and pulmonary edema. Ingestion: Corrosive. Causes destructive burns to mouth, throat, and stomach. 4. FIRST AID MEASURES Eyes: Flush with cool water for at least 15 minutes. Hold eyelids apart to ensure thorough rinsing of the entire surface of the eye and lids with water. Call a physician or poison center. Skin: Wash with soap and water and remove contaminated clothing. If irritation persists, call a physician or poison center. Inhalation: Remove to fresh air. Apply artificial respiration if needed. Call a physician or poison center immediately. Ingestion: DO NOT induce vomiting. Call a physician or poison center immediately. Drink large amounts of water. If vomiting occurs give fluids. Never give anything by mouth to an unconscious person. 5. FIRE FIGHTING MEASURES Flash Point (TCC): None Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): NA Hazardous Products of Combustion: When strongly heated, as in a fire, may decompose to phosphoric oxide fumes and acid mist. Fire and Explosion Hazards: Thermal decomposition products may be hazardous. These include phosphorous oxide fumes. Extinguishing Media: Water, Dry chemical, Carbon dioxide, Alcohol foam. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing in chemical fires. Vapors are irritating to the respiratory tract and may cause difficulty breathing and pulmonary edema. Provide protection of employees and residents. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Absorb small spills with an inert material and then place in chemical waste container for disposal. Neutralize washing with base such as soda ash or lime. Flush residual spill area with large amounts of water. Exercise caution during neutralization as considerable heat may be generated. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: p & n Page 514 of 553 Page 514 of 553 Page 514 of 553 Page 514 of 553 ---PAGE BREAK--- - 2 - Large Spills: Contain large spills with dikes and absorb with an inert material and then place in a chemical waste container. Neutralize washing with a base such as soda ash or lime. Flush residual spill area with large amounts of water. Exercise caution during neutralization as considerable heat may be generated. 7. HANDLING AND STORAGE When diluting, always add acid slowly to water and stir well to avoid spattering. NEVER ADD WATER TO ACID! Containers should be stored in a cool, dry, well-ventilated area away from incompatible materials. Exercise caution to prevent damage to or leakage from the container. Wash hands and face with soap and water after using this product. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Chemical splash goggles are recommended. Skin: Chemical resistant gloves, rubber or neoprene are recommended. Respiratory: None needed for proper use in accordance with label directions. Use a NIOSH/MSHA approved respirators where mist or spray may be generated. Engineering Controls: Provide adequate ventilation and provide local exhaust. Do not use in closed or confined spaces. Avoid creating dust or mist. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 275°F/135°C Specific Gravity: 1.185 (H2O=1) Vapor Pressure: 5.65 Melting Point: -0.5°F/-17.5°C Vapor Density: ND Evaporation Rate: ~ 1 Solubility in Water: Complete pH: 1-2 Appearance and Odor: Bright pink liquid, with mint scent. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: Under fire conditions, product may decompose to phosphoric oxide fumes and acid mist. Chemical Stability: Stable Incompatibility: This product reacts violently with bases, liberating heat and spattering. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? None 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): None TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: None SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 50 PINK MARVEL PREPARED BY: Sandy Kopacz Page 515 of 553 Page 515 of 553 Page 515 of 553 Page 515 of 553 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Identification Product ID: [PHONE REDACTED] Product Name: VAL INT EXT GLS BLACK Product Use: Paint product. Print date: 20/Oct/2009 Revision Date: 17/Oct/2009 Company Identification The Valspar Corporation - Architectural Coatings Division 1191 Wheeling Road Wheeling, IL 60090 Manufacturer's Phone: 1-[PHONE REDACTED] 24-Hour Medical Emergency Phone: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Eye Contact: • May cause eye irritation. Skin Contact: • Causes mild skin irritation. Ingestion: • Irritation of the mouth, throat, and stomach. • Harmful if swallowed. Inhalation: • Causes respiratory tract irritation. Target Organ and Other Health Effects: • Causes headache, drowsiness or other effects to the central nervous system. • Kidney injury may occur. • Cardiac irregularities This product contains ingredients that may contribute to the following potential chronic health effects: • Overexposure may cause nervous system damage. Product ID: [PHONE REDACTED] Page 1 / 6 Page 516 of 553 Page 516 of 553 Page 516 of 553 Page 516 of 553 ---PAGE BREAK--- Teratogens: • May cause birth defects. Carcinogens: • Possible cancer hazard. Contains material which may cause cancer based on animal data. 3. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Ingredient Name CAS-No. Approx. Weight % Chemical Name C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 Carbon black ETHYLENE GLYCOL 107-21-1 1 - 5 1,2-Ethanediol If this section is blank there are no hazardous components per OSHA guidelines. 4. FIRST AID MEASURES Eye Contact: Get medical attention, if develop or persist. Immediately flush eye(s) with plenty of water. Skin Contact: Wash off with plenty of water. Ingestion: Rinse mouth with water. Give one or two glasses of water. Only induce vomiting at the instruction of medical personnel. Get medical attention. Never give anything by mouth to an unconscious person. Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention, if develop or persist. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): 205ºF (96ºC) Lower explosive limit: 1 % Upper explosive limit: 15 % Autoignition temperature: not determined -ºF (ºC) Sensitivity to impact: no Sensitivity to static discharge: Sensitivity to static discharge is not expected. Hazardous combustion products: See Section 10. Unusual fire and explosion hazards: None known. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Keep containers and surroundings cool with water spray. 6. ACCIDENTAL RELEASE MEASURES Product ID: [PHONE REDACTED] Page 2 / 6 Page 517 of 553 Page 517 of 553 Page 517 of 553 Page 517 of 553 ---PAGE BREAK--- Action to be taken if material is released or spilled: Ventilate the area. Avoid breathing dust or vapor. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 7, "Handling and Storage", for proper container and storage procedures. Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep container closed when not in use. Do not freeze. Since emptied containers may contain product residue, follow all label warnings, even after container is emptied. Do not cut, drill, grind, or weld on or near this container. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Chemical goggles, also wear a face shield if splashing hazard exists. Skin protection: Appropriate chemical resistant gloves should be worn. Other Personel Protection Data: Usual industrial work clothes. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Use only in well-ventilated areas. Ovens used for curing should contain a fresh air purge to prevent vapours from accumulating and creating a possible explosive mixture. Ensure adequate ventilation, especially in confined areas. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Ingredient Name CAS-No. Approx. Weight % TWA (final) Ceilings limits (final) Skin designations C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 3.5 mg/m3 TWA ACGIH Threshold Limit Value (TLV's) Ingredient Name CAS-No. Approx. Weight % TWA STEL Ceiling limits Skin designations C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 3.5 mg/m3 TWA ETHYLENE GLYCOL 107-21-1 1 - 5 100 mg/m3 Ceiling aerosol only 9. PHYSICAL PROPERTIES Odor: Normal for this product type. Physical State: liquid Product ID: [PHONE REDACTED] Page 3 / 6 Page 518 of 553 Page 518 of 553 Page 518 of 553 Page 518 of 553 ---PAGE BREAK--- 9. PHYSICAL PROPERTIES pH: not determined Vapor pressure: 24 mmHg @ 77ºF (25ºC) Vapor density (air = 1.0): 7.4 Boiling point: not determined Solubility in water: not determined Coefficient of water/oil distribution: not determined Density (lbs per US gallon): 8.74 Specific Gravity: 1.05 Evaporation rate (butyl acetate = 1.0): 0.1 Flash point (Fahrenheit): 205ºF (96ºC) Lower explosive limit: 1 % Upper explosive limit: 15 % Autoignition temperature: not determined -ºF (ºC) 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: None known. Incompatibility: Avoid water-reactive materials, heat or contact with peroxides or other Hazardous Polymerization: None anticipated. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Sensitivity to static discharge: Sensitivity to static discharge is not expected. 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS-No. Approx. Weight % NIOSH - Selected LD50s and LC50s C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 > 15400 mg/kg Oral LD50 Rat > 3 g/kg Dermal LD50 Rabbit ETHYLENE GLYCOL 107-21-1 1 - 5 = 4000 mg/kg Oral LD50 Rat = 9530 µL/kg Dermal LD50 Rabbit Mutagens/Teratogens/Carcinogens: May cause birth defects. Possible cancer hazard. Contains material which may cause cancer based on animal data. IARC has classified carbon black as possibly carcinogenic to humans (Group 2B). Ingredient Name CAS-No. Approx. Weight % IARC Group 1 - Human Evidence IARC Group 2A - Limited Human Data IARC Group 2B - Sufficient Animal Data C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 Monograph 65 [1996] Ingredient Name CAS-No. Approx. Weight % NTP Known Carcinogens NTP Suspect Carcinogens NTP Evidence of Carcinogenicity ETHYLENE GLYCOL 107-21-1 1 - 5 male mice-no evidence; female mice-no evidence Ingredient Name CAS-No. Approx. Weight % OSHA - Hazard Communication Carcinogens OSHA - Specifically Regulated Carcinogens ACGIH Carcinogens Product ID: [PHONE REDACTED] Page 4 / 6 Page 519 of 553 Page 519 of 553 Page 519 of 553 Page 519 of 553 ---PAGE BREAK--- C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 Present 12. ECOLOGICAL DATA No information on ecology is available. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation Proper Shipping Name: PAINT, NOT REGULATED UN ID Number (msds): NRPAIN U.S. Highway & Rail Shipments The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Reportable Quantity Description: International Air Transport Association (IATA): Proper Shipping Name: PAINT, NOT REGULATED UN ID Number (msds): NRPAIN International Maritime Organization (IMO): Proper Shipping Name: PAINT, NOT REGULATED IMO UN/ID Number (msds): NRPAIN 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: Ingredient Name CAS-No. Approx. Weight % SARA 302 SARA 313 CERCLA RQ in lbs. ETHYLENE GLYCOL 107-21-1 1 - 5 form R reporting required for 1.0% de minimis concentration 5000 SARA 311/312 Hazard Class: Acute: yes Chronic: yes Flammability: no Reactivity: no Sudden Pressure: no U.S. STATE REGULATIONS: Right to Know: The specific chemical identity of a component may be withheld as a trade secret under 34 Code, Chapter 317. Product ID: [PHONE REDACTED] Page 5 / 6 Page 520 of 553 Page 520 of 553 Page 520 of 553 Page 520 of 553 ---PAGE BREAK--- Right To Know: ETHYLENE GLYCOL 107-21-1 C.I. PIGMENT BLACK 7 1333-86-4 Additional Non-Hazardous Materials PROPRIETARY INGREDIENT Trade Secret PROPRIETARY RESIN Trade Secret Rule 66 status of product Not photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories US TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. 16. OTHER INFORMATION HMIS Codes Health: 2* Flammability: 1 Reactivity: 1 PPE: X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Preparation Information: Prepared By: Regulatory Affairs Department Print date: 20/Oct/2009 Revision Date: 17/Oct/2009 Product ID: [PHONE REDACTED] Page 6 / 6 Page 521 of 553 Page 521 of 553 Page 521 of 553 Page 521 of 553 ---PAGE BREAK--- Page 522 of 553 Page 522 of 553 Page 522 of 553 Page 522 of 553 ---PAGE BREAK--- Page 523 of 553 Page 523 of 553 Page 523 of 553 Page 523 of 553 ---PAGE BREAK--- WD-40 Page 1 of 4 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER/SUPPLIER: US Office: WD-40 Company 1061 Cudahy Place San Diego, CA 92110 Information Phone (619) 275-1400 Emergency Phone # 24 hr: Chemtrec: (800) 424-9300 – Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals. Canadian Office: WD-40 Products [Canada] Ltd. P.O. Box 220 Toronto, Ontario M9C 4V3 Information Phone (416) 622-9881 Emergency Phone # 24 hr: Canutec: (613) 996-6666 – Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals PRODUCT NAME: WD-40 Aerosol PRODUCT USE: Cleaner, lubricant. MSDS DATE OF PREPARATION: March 13, 2010 SECTION 2 HAZARDS IDENTIFICATION DANGER! Harmful or fatal if swallowed. Flammable aerosol. Contents under pressure. Avoid eye contact. Use with adequate ventilation. Keep away from heat, sparks and all other sources of ignition. POTENTIAL HEALTH EFFECTS: PRIMARY ROUTES OF ENTRY: Inhalation, skin and eye contact. ACUTE EFFECTS: INGESTION: This product has low oral toxicity. Swallowing of the liquid contents may cause irritation, nausea, vomiting and diarrhea. The liquid contents are an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis. EYES: Contact may be mildly irritating to eyes. May cause redness and tearing. SKIN: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. INHALATION: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. May aggravate existing respiratory conditions such as asthma. Intentional abuse may be harmful or fatal. CHRONIC EFFECTS: None expected. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS Ingredient CAS Number Percent Aliphatic Petroleum Distillates 64742-47-8 64742-88-7 45-50% Petroleum Base Oil 64742-58-1 64742-53-6 64742-56-9 64742-65-0 30-35% Non-Hazardous Ingredients Proprietary <10% Surfactant Proprietary Carbon Dioxide 124-38-9 2-3% Page 524 of 553 Page 524 of 553 Page 524 of 553 Page 524 of 553 ---PAGE BREAK--- WD-40 Aerosol 03/13/10 Page 2 of 4 SECTION 4 FIRST AID MEASURES For Medical Emergencies Call 1-[PHONE REDACTED] (24 hours/day) INGESTION: Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-[PHONE REDACTED] immediately. EYE CONTACT: Flush thoroughly with water. Get medical attention if irritation persists. SKIN CONTACT: Wash with soap and water. If irritation develops and persists, get medical attention. INHALATION: If irritation is experienced, move to fresh air. Get medical attention if irritation or other develop and persist. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. UNUSUAL FIRE/EXPLOSION HAZARDS: Contents under pressure. Aerosol containers may burst under fire conditions. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. SECTION 6 ACCIDENTAL RELEASE MEASURES SPILL RESPONSE: Wear appropriate protective clothing (see Section Eliminate all sources of ignition and ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required. SECTION 7 HANDLING AND STORAGE HANDLING: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use with adequate ventilation. Keep away from heat, sparks and open flames. Wash thoroughly with soap and water after handling. Do not puncture or incinerate containers. Keep can away from electrical current or battery terminals. Electrical arcing can cause burn-through (puncture) which may result in flash fire, causing serious injury. Keep out of the reach of children. STORAGE: Do not store above 120°F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. SECTION 8 EXPOSURE CONTROLE/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS: Aliphatic Petroleum Distillates 1200 mg/m3 TWA Manufacturer Recommended Petroleum Base Oil 5 mg/m3 TWA ACGIH TLV 10 mg/m3 STEL ACGIH TLV Non-Hazardous Ingredients None Established Surfactant None Established Carbon Dioxide 5000 ppm TWA, 30,000 ppm STEL ACGIH TLV The Following Controls are Recommended for Normal Consumer Use of this Product Engineering Controls: Use in a well-ventilated area. Personal Protection: Eye Protection: Avoid eye contact. Safety glasses or goggles recommended. Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin contact is likely. Respiratory Protection: None needed for normal use with adequate ventilation. Page 525 of 553 Page 525 of 553 Page 525 of 553 Page 525 of 553 ---PAGE BREAK--- WD-40 Aerosol 03/13/10 Page 3 of 4 For Bulk Processing or Workplace Use the Following Controls are Recommended Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that occupational exposure limits. Personal Protection: Eye Protection: Safety goggles recommended where eye contact is possible. Skin Protection: Wear chemical resistant gloves. Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and concentration. Follow applicable regulations and good Industrial Hygiene practice. Work/Hygiene Practices: Wash with soap and water after handling. SECTION 9 PHYSICAL DATA APPEARANCE AND ODOR: Light amber liquid with a mild odor. Boiling Point: 361 - 369°F (183 - 187°C) Specific Gravity: 0.8 – 0.82 @ 60°F Solubility in Water: Insoluble pH: Not Applicable Vapor Pressure: 95-115 PSI @ 70°F Vapor Density: Greater than 1 Percent Volatile: 70-75% VOC: 412 grams/liter (49.5%) Coefficient of Water/Oil Distribution: Not Determined Kinematic Viscosity: 2.79-2.96cSt @ 100°F Flash Point: 122°F (49°C) Tag Open Cup (concentrate) Flammable Limits: (Solvent Portion) LEL: 0.6% UEL: 8.0% Pour Point: -63°C (-81.4°F ) ASTM D-97 SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable INCOMPATIBILITY: Strong oxidizing agents. Avoid heat and open flames. Do not puncture or incinerate containers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide. SECTION 11 TOXICOLOGICAL INFORMATION The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard. SECTION 12 ECOLOGICAL INFORMATION No data is currently available. SECTION 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: If this product becomes a waste, it would be expected to meet the criteria of a hazardous waste based on flammability. However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local regulations. SECTION 14 TRANSPORT INFORMATION U.S. DOT Hazard Classification: Consumer Commodity, ORM-D Page 526 of 553 Page 526 of 553 Page 526 of 553 Page 526 of 553 ---PAGE BREAK--- WD-40 Aerosol 03/13/10 Page 4 of 4 Canadian TDG Classification: Limited Quantity IMDG Code Hazard Classification: UN1950, Aerosols, 2.1. SECTION 15 REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills as required under federal, state and local regulations. SARA TITLE III: Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. CANADIAN REGULATIONS: Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic Substances List or exempt from notification Canadian WHMIS Classification: Class B-5 (Flammable Aerosol). This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Physical Hazard – 0 (minimal hazard) Revision Date: 03/13/10 Supersedes: 08/25/09 Prepared By: Industrial Health & Safety Consultants, Inc. 1-[PHONE REDACTED] This MSDS complies with OSHA guidelines set by 29 CFR 1910.1200 and the Canadian WHMIS regulations. The foregoing information has been compiled from sources believed to be accurate but is not warranted to be. Recipients are advised to confirm in advance of need that data is correct. Standards change without notice. It is the responsibility of the recipient to insure that their personnel have been notified of any changes which may affect them. The data provided on this MSDS are not meant to be used as specifications, only as guideline information as to the safe use of this product. User should refer to applicable laws before use. N/D = Not Determined N/E = Not Established N/A = Not Applicable Page 527 of 553 Page 527 of 553 Page 527 of 553 Page 527 of 553 ---PAGE BREAK--- Page 1 Material Safety Data Sheet EMERGENCY PHONE:1-[PHONE REDACTED] CHEMTREC: [PHONE REDACTED] SECTION 1 IDENTIFICATION PRODUCT NAME: Whink Rust Flush® CAS NO: None SUPPLIER: Whink Products Company 1901 15th Avenue P.O. Box 230 Eldora, IA 50627 USA TEL: 001-[PHONE REDACTED] Fax: 001-[PHONE REDACTED] SECTION 2 COMPOSITION INFORMATION ON HAZARDOUS INGREDIENTS (As per OSHA Hazardous Communication Standard, CFR29 1910.1200 and Canadian WHMIS Regulations) AGGIH OSHA VOC INGREDIENTS CAS NO WT% TLV STEL PEL STEL Reportable Hydrochloric Acid 7647-01-0 9-12 5 ppm 3 ppm 5 ppm 3 ppm 0% Other Specific Acids Proprietary Blend CAS# Various * This product and/or components are listed in the Toxic Substances Control Act (TSCA) Inventory of Chemicals; hence, it may be subject to applicable TSCA provisions and restrictions. SECTION 3 HAZARDS IDENTIFICATION Emergency Overview: A water white liquid with a bland or no odor. Mists and liquid are moderately irritating to the eyes, skin and respiratory tract. Potential Health Effects: Eye Contact: Exposure to mists, or liquid may cause eye irritation. of exposure may include tearing, redness and painful burning sensation. Exposure is not expected to cause corneal damage or visual impairment. Skin Contact: Exposure to mists, or liquid may cause moderate skin irritation. off exposure may include redness, swelling a stinging sensation and burning. No published reports indicate this product is absorbed through the skin. Inhalation: Exposure to mists may cause irritation to the nose, throat and lungs of exposure may include headache, dizziness, burning of the nose and throat. Ingestion: Aspiration hazard. This product can enter the lungs and cause severe lung damage during swallowing or vomiting. of exposure may include burning of the nose, throat and mouth. Page 528 of 553 Page 528 of 553 Page 528 of 553 Page 528 of 553 ---PAGE BREAK--- Page 2 SECTION 4 FIRST AID MEASURES EYE CONTECT: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medical attention. SKIN CONTACT: Flush skin with water, if irritation occurs get medical attention. INGESTION: Aspiration hazard. If swallowed. Get medical attention immediately. DO NOT induce vomiting or give anything by mouth. If vomited, this material can enter the lungs and cause severe damage. If victim is drowsy or unconscious, lay victim on side with head down. Get medical attention. INHALATION: If inhaled immediately move to fresh air. If not breathing give artificial respiration, preferably mouth to mouth. If breathing is difficult, give oxygen. Get medical attention. SECTION 5 FIRE-FIGHTING MEASURES GENERAL HAZARD: This is an acid based product and water and is not flammable. EXTINGUISHING MEDIA: Water fog, CO2 or dry chemicals Use a water spray to cool containers exposed to fire SPECIAL FIRE FIGHTING PROCEDURES: Usual fire fighting procedures may be used. Self-contained breathing apparatus is recommended, contains hydrochloric acid and could release hydrogen gas which may become flammable. UNUSUAL FIRE & EXPLOSION HAZARDS: None. HAZARDDOUS COMBUSTION PRODUCTS: When heated to decomposition, it emits toxic hydrogen gas. SECTION 6 ACCIDENTAL RELEASE MEASURES LAND SPILL: Large quantities should be picked up with absorbent small quantites should be neutralized to a pH between 6 and 9. WATER SPILL: Contain the area around the spill and neutralize to a pH between 6 and 9. SECTION 7 HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient STORAGE PRESSURE: Ambient GENERAL: Store in a cool, dry, well ventilated area away from incompatible materials and products. Wear recommended personal protective equipment when handling this product. Protect eyes, skin and clothing from contact with product. Do not breathe vapors or mists. Use with adequate ventilation. Do not take internally. Wash thoroughly with soap and water after handling this product. The empty container may be hazardous. It may contain flammable residues and vapors. Do not cut, puncture or weld on or near this container. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION CONTROL MEASURES: use local mechanical exhaust capable of maintaining emissions, in the work area, below the ACGIH-TLV, OSHA-PEL or levels that may cause irritation. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT: Page 529 of 553 Page 529 of 553 Page 529 of 553 Page 529 of 553 ---PAGE BREAK--- Page 3 Respiratory: For exposures above thee ACGIH-TLV, OSHA-PEL or levels that may cause irritation, wear a NIOSH approved full facepiece or half mask air-purifying cartridge equipped with a organic vapor cartridge or supplied air. Eyes: Wear chemical goggles, unless a full facepiece respirator is worn. Hands: Gloves if irritation is suspected. Other: Wear a nitrile or PVA apron when handling this product also wear boots. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: Above 212° F VAPOR PRESSURE: No Data Available VAPOR DENSITY: No Data Available EVAPORATION RATE: Same as Water SPECIFIC GRAVITY (H2O=1): 1.06 MELTING POINT: NA SOLUBITY: Liquid. VOC Content: NA APPEARANCE: Clear ODOR: None FLASH POINT: None pH Solution): 0.1 to 1.0 SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: Strong caustic solutions. HAZARDOUS DECOMPOSITION: Hydrogen Gas. INCOMPATIBILITY (MATERIAL TO AVOID): Strong caustic agents HAZARDOUS POLYMERIZATION: Unknown SENSITIVITY TO STATIC DISCHARGE: None SECTION 11 TOXICOLOGICAL INFORMATION Components: Hydrochloric Acid Eye contact No Data Available Skin Contact: No Data Available Oral Rat LD50: 3.6 mg/L Dermal Rabbit LD50: 5 ppm Inhalation Rat LC50: 5 ppm Human Data: No Data Available Other Toxicological Data: Inhalation Rat LD50 5 ppm Carcinogenicity: Skin Mouse TD50 330 gm/kg 86 weeks Teratogenicity: No Data Available Mutagenicity: No Data Available Synergistic Products: None Reported Target Organs: Eyes, Skin, Mucus membranes Medical Conditions Aggravated by exposure: Skin or Respiratory disorders SECTION 12 ECOLOGICAL INFORMATION ENVIRONMENTAL FATE: The environmental fate of this product is expected to be: Land—biodegrades into carbon dioxide, carbon and water. Water–Disperses into water with slight pH change to water. Air—Forms water vapor and carbon dioxide. This product is not expected to bioaccumulate. Page 530 of 553 Page 530 of 553 Page 530 of 553 Page 530 of 553 ---PAGE BREAK--- Page 4 ENVIRONMENTAL CONSIDERATIONS: The aquatic toxicity for this product has not been determined. SECTION 13 DISPOSAL CONSIDERATIONS All disposals of this material must be done in accordance with local, state , and federal regulations. Waste characterization and compliance with disposal regulations are the responsibilities of the waste generator. SECTION 14 TRANSPORT INFORMATION DOT PROPER SHIPPING NAME: Corrosive liquid N.O.S. (Contains Hydrochloric Acid),8, UN1789, PGII, ERG60 HAZARD CLASS: 8 UN NUMBER: 1789 PACKING GROUP: II PRIMARY LABEL: Corrosive SUDSIDIARY LABEL(S): None Required PRIMARY/SUBSIDIARY PLACARDS: None Required (in less than bulk) DOT Reportable Quantity (RQ): Not Applicable RQ for product: Not Applicable Marine Pollutant: No DOT 1996 North American Emergency Response Guidebook No: 60 TDG PROPER SHIPPING NAME: Corrosive Liquids N.O.S. HAZARD CLASS: 8 UN NUMBER: UN1789 PACKING GROUP: II PRIMARY LABEL: Corrosive SUBSIDIARY LABEL(S) None Required PRIMARY/SUBSIDIARY PLACARDS: Corrosive TDG Reportable Quantity (RQ): Not listed TDG Schedule XII: Not Listed Regulated Limit (RL): Not Listed RL for Product: Not applicable Other Shipping Information: None D.O.T. Proper shipping name: Hydrochloric Acid Other requirements: NA SECTION 15 REGULATORY INFORMATION COMPONENTS: Hydrochloric Acid OSHA Target Organs: Skin, Lungs and Eyes Carcinogenic Potential: Regulated by ODHA: No Listed on NTP Report No Listed by ARC: No ARC Group: Not Applicable ACGLH Appendix A: Not Listed A1 Confirmed Human Not Applicable A2 Suspected Human: Not Applicable U.S EPA Requirements: Release Reporting CERCLA (40 CFR 302) Listed Substance: Not Listed Reportable Quantity: Not Applicable Category: Not Applicable RCRA Waste No: Not Applicable Page 531 of 553 Page 531 of 553 Page 531 of 553 Page 531 of 553 ---PAGE BREAK--- Page 5 Unlisted Substance: Yes Reportable Quantity: 5,000 pounds Characteristic: Corrosive RCRA Waste No: Unknown SARA TITLE III Section 302 & 303 (40 CFR 355): Listed Substance Listed Reportable Quantity: 5,000 lbs. Planning threshold: 5,000 lbs Section 311 & 312 (40 CFR 370): Hazard Categories (Product): Fire: N Sudden Release of Pressure: N Reactive: N Acute Health: N Chronic Health: N Planning Threshold: 5,000 pounds Section 313 (40CFR 372): Listed Toxic Chemical: Listed Reporting Threshold: 5,000 lbs U.S. TSCA Status Listed (40 CFR 710): Yes State Regulations: State of California: Safe Drinking Water and Toxins Enforcement Act, 1986 (Proposition 65): Carcinogen: No Reproductive Toxin: No Other Regulations: State Right to Know Laws: CA, CT, FL, IL, LA, MA, ME, MN, NJ, PA, RI Canadian Regulations: Product Information: Controlled Product: Yes WHMIS Hazard Symbols: Corrosive Liquid: Material Causing other Toxic Effects. WHMIS Class & Division: 8.3, D.28 Ingredient Information: IDL Substances: Listed Domestic Substance List: Yes Page 532 of 553 Page 532 of 553 Page 532 of 553 Page 532 of 553 ---PAGE BREAK--- Page 6 SECTION 16 OTHER INFORMATION EPA Registration Number: Not Applicable Approved Product Uses: Not Applicable Additional Toxicological Information (Continued form section 11) Components: HMIS Rating: Health: 1 Flammability: 0 Reactivity: 0 Personal Protective Index: B This information relates only to the specific product designated and may not be valid for such product used in combination with any other products or in any other process. The stated MSDS is reliable to the best of the company’s knowledge and believed accurate as of the date indicated. However, no representation, warranty or guarantee of any kind, expressed or implied is made as to its accuracy, reliability or completeness and we assume no responsibility for any loss, damage or expense, direct or consequential, arising out of use. It is the user’s responsibility to satisfy himself as to the suitableness and completeness of such information for his own particular use. Joe Armer Date: Director of Technical Services Page 533 of 553 Page 533 of 553 Page 533 of 553 Page 533 of 553 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : WHITE MARKING SPRAY PAINT IDENTIFICATION NUMBER: 1893 838 DATE PRINTED : 02/14/01 PRODUCT USE/CLASS : Industrial Choice Marking SUPPLIER: MANUFACTURER: Rust-Oleum Corporation Rust-Oleum Corporation 11 Hawthorn Parkway 11 Hawthorn Parkway Vernon Hills, Illinois Vernon Hills, Illinois 60061 USA 60061 USA (847) 367-7700 Rust-Oleum Corp. (847) 367-7700 Rust-Oleum Corp. 8:00 AM-4:30 PM/24-hr Emer.Assist 8:00 AM-4:30 PM/24-hr Emer.Assist PREPARER: MTM, PHONE: [PHONE REDACTED], PREPARE DATE: 02/13/01 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 LIQUIFIED PETROLEUM GAS 68476-85-7 30.0 % 02 XYLENE 1330-20-7 15.0 % 03 Calcium Carbonate (Limestone) 1317-65-3 10.0 % 04 Titanium Dioxide 13463-67-7 10.0 % 05 TOLUENE 108-88-3 10.0 % 06 100-41-4 5.0 % 07 VM&P NAPHTHA 64742-89-8 5.0 % EXPOSURE LIMITS ACGIH OSHA MEXICAN ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 1000 PPM N.E. 1000 PPM N.E. N.E. NO 02 100PPM 150PPM 100PPM N.E. 100 PPM YES 03 10mg/m3 N.E. 15mg/m3 N.E. N.E. NO Page 534 of 553 Page 534 of 553 Page 534 of 553 Page 534 of 553 ---PAGE BREAK--- 04 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO 05 50 PPM N.E. 200 PPM 300 PPM N.E. YES 06 100 PPM 125 PPM 100 PPM N.E. N.E. YES 07 300 PPM N.E. 300 ppm N.E. N.E. NO (See Section 16 for abbreviation legend) (Continued on Page 2) Product: 1893 838 Preparation Date: 02/13/01 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW Harmful if inhaled. Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Harmful if inhaled. May effect the brain or nervous system causing dizziness, headache or nausea. Contents Under Pressure. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing vapors or mists. High vapor concentrations are irritating to the eyes, nose, throat and lungs. EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e,g.,narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Overexposure to toluene in laboratory animals has been associated with liver abnormalities, kidney, lung and spleen damage. Effects in humans have included liver and cardiac abnormalities. PRIMARY ROUTE(S) OF ENTRY: INHALATION EYE CONTACT Page 535 of 553 Page 535 of 553 Page 535 of 553 Page 535 of 553 ---PAGE BREAK--- I SECTION 4 - FIRST AID MEASURES I FIRST AID - EYE CONTACT: Hold eyelids apart and flush with plenty of water for at lease 15 minutes. Get medical attention. FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. (Continued on Page 3) Product: 1893 838 Preparation Date: 02/13/01 Page 3 I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: -99 F LOWER EXPLOSIVE LIMIT: 0.9 % UPPER EXPLOSIVE LIMIT: 9.5 % AUTOIGNITION TEMPERATURE: N.D. EXTINGUISHING MEDIA: DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate the area, remove all sources of ignition and ventilate well. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as Page 536 of 553 Page 536 of 553 Page 536 of 553 Page 536 of 553 ---PAGE BREAK--- sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. STORAGE: Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 degrees F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 degrees F. (Continued on Page 4) Product: 1893 838 Preparation Date: 02/13/01 Page 4 I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Page 537 of 553 Page 537 of 553 Page 537 of 553 Page 537 of 553 ---PAGE BREAK--- SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : -34 - 285 F VAPOR DENSITY : Is heavier than air ODOR : Solvent ODOR THRESHOLD : N.D. APPEARANCE : Liquid EVAPORATION RATE: Is faster than Ether SOLUBILITY IN H2O : Soluble FREEZE POINT : N.D. SPECIFIC GRAVITY: 0.9564 VAPOR PRESSURE : N.D. pH @ 0.0 % : N.D. PHYSICAL STATE : LIQUID VISCOSITY : N.D. COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D. (See Section 16 for abbreviation legend) I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Avoid temperatures above 120 degrees F. Avoid all possible sources of ignition. (Continued on Page 5) Product: 1893 838 Preparation Date: 02/13/01 Page 5 I SECTION 10 - STABILITY AND REACTIVITY I INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION PRODUCTS: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition it emits acrid smoke and irritating fumes. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. Page 538 of 553 Page 538 of 553 Page 538 of 553 Page 538 of 553 ---PAGE BREAK--- STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME LD50 LC50 LIQUIFIED PETROLEUM GAS N.E. N.E. XYLENE RAT 4300MG/KG RAT 5000PPM 4HR Calcium Carbonate (Limestone) No Information No Information Titanium Dioxide 24000mg/kg Rats 6820mg/m3 Rats TOLUENE RAT 5000MG/KG MOUSE 5320PPM 8HR RAT 3500MG/KG N.A. VM&P NAPHTHA N.D. N.D. I SECTION 12 - ECOLOGICAL INFORMATION I ECOLOGICAL INFORMATION: Product is a mixture of listed components. According to our raw material suppliers, all components are listed on the TSCA inventory as required or meet the polymer exemption as defined in Section 5.5.2 of the Toxic Substances Control Act. I SECTION 13 - DISPOSAL CONSIDERATIONS I DISPOSAL METHOD: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: AEROSOLS DOT TECHNICAL NAME: (Continued on Page 6) Product: 1893 838 Preparation Date: 02/13/01 Page 6 I SECTION 14 - TRANSPORTATION INFORMATION I Page 539 of 553 Page 539 of 553 Page 539 of 553 Page 539 of 553 ---PAGE BREAK--- DOT HAZARD CLASS: 2.1 HAZARD SUBCLASS: 1 DOT UN/NA NUMBER: UN1950 PACKING GROUP: RESP. GUIDE PAGE: 126 I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN XYLENE 1330-20-7 15.0 % TOLUENE 108-88-3 10.0 % 100-41-4 5.0 % U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER WATER DEIONIZED 7732-18-5 RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER WATER DEIONIZED 7732-18-5 RESIN SOLUTION NOT AVAILABLE Page 540 of 553 Page 540 of 553 Page 540 of 553 Page 540 of 553 ---PAGE BREAK--- (Continued on Page 7) Product: 1893 838 Preparation Date: 02/13/01 Page 7 I SECTION 15 - REGULATORY INFORMATION I CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER TOLUENE 108-88-3 INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: B5 D2A D2B I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 4 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 07/12/00 LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined : No Information. Page 541 of 553 Page 541 of 553 Page 541 of 553 Page 541 of 553 ---PAGE BREAK--- The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. Page 542 of 553 Page 542 of 553 Page 542 of 553 Page 542 of 553 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : WHITE MARKING SPRAY PAINT IDENTIFICATION NUMBER: 203039 DATE PRINTED : 09/19/01 PRODUCT USE/CLASS : I.C. WATER BASE MARKING PAINT SUPPLIER: MANUFACTURER: Rust-Oleum Corporation Rust-Oleum Corporation 11 Hawthorn Parkway 11 Hawthorn Parkway Vernon Hills, Illinois Vernon Hills, Illinois 60061 USA 60061 USA (847) 367-7700 Rust-Oleum Corp. (847) 367-7700 Rust-Oleum Corp. 8:00 AM-4:30 PM/24-hr Emer.Assist 8:00 AM-4:30 PM/24-hr Emer.Assist PREPARER: MTM, PHONE: [PHONE REDACTED], PREPARE DATE: 09/19/01 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 LIQUIFIED PETROLEUM GAS 68476-85-7 30.0 % 02 XYLENE 1330-20-7 15.0 % 03 Calcium Carbonate (Limestone) 1317-65-3 10.0 % 04 Titanium Dioxide 13463-67-7 10.0 % 05 TOLUENE 108-88-3 10.0 % 06 100-41-4 5.0 % 07 VM&P NAPHTHA 64742-89-8 5.0 % EXPOSURE LIMITS ACGIH OSHA MEXICAN ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 1000 PPM N.E. 1000 PPM N.E. N.E. NO 02 100PPM 150PPM 100PPM N.E. 100 PPM YES 03 10mg/m3 N.E. 15mg/m3 N.E. N.E. NO Page 543 of 553 Page 543 of 553 Page 543 of 553 Page 543 of 553 ---PAGE BREAK--- 04 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO 05 50 PPM 150 PPM 200 PPM 300 PPM N.E. YES 06 100 PPM 125 PPM 100 PPM N.E. N.E. YES 07 300 PPM N.E. 300 ppm N.E. N.E. NO (See Section 16 for abbreviation legend) (Continued on Page 2) Product: 203039 Preparation Date: 09/19/01 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW Harmful if inhaled. Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Harmful if inhaled. May effect the brain or nervous system causing dizziness, headache or nausea. Contents Under Pressure. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing vapors or mists. High vapor concentrations are irritating to the eyes, nose, throat and lungs. EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e,g.,narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Overexposure to toluene in laboratory animals has been associated with liver abnormalities, kidney, lung and spleen damage. Effects in humans have included liver and cardiac abnormalities. PRIMARY ROUTE(S) OF ENTRY: SKIN ABSORPTION INHALATION EYE CONTACT Page 544 of 553 Page 544 of 553 Page 544 of 553 Page 544 of 553 ---PAGE BREAK--- I SECTION 4 - FIRST AID MEASURES I FIRST AID - EYE CONTACT: Hold eyelids apart and flush with plenty of water for at lease 15 minutes. Get medical attention. FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. (Continued on Page 3) Product: 203039 Preparation Date: 09/19/01 Page 3 I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: -99 F LOWER EXPLOSIVE LIMIT: 0.9 % UPPER EXPLOSIVE LIMIT: 9.5 % AUTOIGNITION TEMPERATURE: ND EXTINGUISHING MEDIA: DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate the area, remove all sources of ignition and ventilate well. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as Page 545 of 553 Page 545 of 553 Page 545 of 553 Page 545 of 553 ---PAGE BREAK--- sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. STORAGE: Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 degrees F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 degrees F. (Continued on Page 4) Product: 203039 Preparation Date: 09/19/01 Page 4 I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Page 546 of 553 Page 546 of 553 Page 546 of 553 Page 546 of 553 ---PAGE BREAK--- SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : -34 - 285 F VAPOR DENSITY : Is heavier than air ODOR : SOLVENT ODOR THRESHOLD : ND APPEARANCE : LIQUID EVAPORATION RATE: Is faster than Ether SOLUBILITY IN H2O : SOLUBLE FREEZE POINT : ND SPECIFIC GRAVITY: 0.9280 VAPOR PRESSURE : ND pH @ 0.0 % : ND PHYSICAL STATE : LIQUID VISCOSITY : ND COEFFICIENT OF WATER/OIL DISTRIBUTION: ND (See Section 16 for abbreviation legend) I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Avoid temperatures above 120 degrees F. Avoid all possible sources of ignition. (Continued on Page 5) Product: 203039 Preparation Date: 09/19/01 Page 5 I SECTION 10 - STABILITY AND REACTIVITY I INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION PRODUCTS: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition it emits acrid smoke and irritating fumes. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. Page 547 of 553 Page 547 of 553 Page 547 of 553 Page 547 of 553 ---PAGE BREAK--- STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME LD50 LC50 LIQUIFIED PETROLEUM GAS N.E. N.E. XYLENE RAT 4300MG/KG RAT 5000PPM 4HR Calcium Carbonate (Limestone) No Information No Information Titanium Dioxide 24000mg/kg Rats 6820mg/m3 Rats TOLUENE RAT 5000MG/KG MOUSE 5320PPM 8HR RAT 3500MG/KG N.A. VM&P NAPHTHA N.D. N.D. I SECTION 12 - ECOLOGICAL INFORMATION I ECOLOGICAL INFORMATION: Product is a mixture of listed components. According to our raw material suppliers, all components are listed on the TSCA inventory as required or meet the polymer exemption as defined in Section 5.5.2 of the Toxic Substances Control Act. I SECTION 13 - DISPOSAL CONSIDERATIONS I DISPOSAL METHOD: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: AEROSOL DOT TECHNICAL NAME: (Continued on Page 6) Product: 203039 Preparation Date: 09/19/01 Page 6 I SECTION 14 - TRANSPORTATION INFORMATION I Page 548 of 553 Page 548 of 553 Page 548 of 553 Page 548 of 553 ---PAGE BREAK--- DOT HAZARD CLASS: 2 HAZARD SUBCLASS: 1 DOT UN/NA NUMBER: UN1950 PACKING GROUP: RESP. GUIDE PAGE: 126 I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN XYLENE 1330-20-7 15.0 % TOLUENE 108-88-3 10.0 % 100-41-4 5.0 % U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER WATER DEIONIZED 7732-18-5 RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER WATER DEIONIZED 7732-18-5 RESIN SOLUTION NOT AVAILABLE Page 549 of 553 Page 549 of 553 Page 549 of 553 Page 549 of 553 ---PAGE BREAK--- (Continued on Page 7) Product: 203039 Preparation Date: 09/19/01 Page 7 I SECTION 15 - REGULATORY INFORMATION I CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER TOLUENE 108-88-3 INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: A B5 D2A D2B I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 4 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 09/19/01 LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined : No Information. Page 550 of 553 Page 550 of 553 Page 550 of 553 Page 550 of 553 ---PAGE BREAK--- The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. Page 551 of 553 Page 551 of 553 Page 551 of 553 Page 551 of 553 ---PAGE BREAK--- Page 552 of 553 Page 552 of 553 Page 552 of 553 Page 552 of 553 ---PAGE BREAK--- Page 553 of 553 Page 553 of 553 Page 553 of 553 Page 553 of 553