Document douglascountywi_gov_doc_4a6cc9a709

Safety Data Sheets HHS 4th Floor HHS 4th Floor 02/29/2016 ---PAGE BREAK--- Safety Data Sheet Index Binder: HHS 4th Floor - HHS 4th Floor 096-000 106-97-8 Norazza, Inc. 05/05/2015 3 CARPET STAIN REMOVER Spartan Chemical Company, Inc. 01/22/2015 8 Clorox Commercial Solutions Green Works 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Clorox Professional Products Company 05/23/2015 14 Comet Deodorizing Cleanser with Chlorinol Procter & Gamble Professional 06/12/2015 23 Disinfecting Multi-Surface Cleaner Seventh Generation Inc 05/28/2015 30 Expo White Board Cleaner Newell Rubbermaid 08/05/2015 36 Fabuloso Pro APC Cleaner Lavender Colgate-Palmolive Company 44 Febreze Air Effects - Sun Baked Procter & Gamble 02/24/2015 53 Goo Gone Spray Gel Goo Gone 08/14/2014 60 Lemon SHine Furnature Polish Nyco Products Company 08/16/2005 66 MURPHY OIL SOAP WOOD CLEANER SPRAY RTU Colgate-Palmolive Company 05/22/2015 68 Office Max Compressed Gas Duster 75-37-6 Falcon Safety Products, Inc 04/28/2015 75 PLEDGE FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL S.C. Johnson and Son, Limited 05/21/2014 83 PURELL Hand Sanitizing Wipes GOJO Industries, Inc. 03/30/2015 91 Sani-Cloth HB Germicidal Disposable Wipe Professional Disposables International, Inc. NP Nice Pak 105 SHINE M UP AEROSOLSAMPLE, CAN CL CERTIFIED LABS - DIVISION OF NCH CORPORATION 11/18/2009 111 Static Free Hand Guard CHEMTRONICS 05/18/2015 115 ULTRA MARK ICELAND DAWN Mohawk Finishing Products Division of RPM Wood Finishes Group, Inc. 07/04/2015 126 Product Name CAS Number Manufacturer Version Date Page Page 2 of 132 Page 2 of 132 Page 2 of 132 Page 2 of 132 ---PAGE BREAK--- Page 1 of 4 SDS for: 2914011 Printed: 5/5/2015 SAFETY DATA SHEET This document is not intended for general distribution. It can be used as the basis for a general distribution document if appropriate changes are made to the identification section. 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: 096-000 Product Code: 2914011 Chemical Name: Endust for Electronics Screen & Electronics Cleaner 8oz Details of the supplier of the safety data sheet: This Safety Data Sheet has been updated in accordance with the Global Harmonized System (GHS) Manufacturer/Supplier: Norazza, Inc. 3938 Broadway St Buffalo NY 14227 US Supplier Phone Number: Contact Phone [PHONE REDACTED] Emergency telephone number: [PHONE REDACTED] International +01-[PHONE REDACTED] Product Use: Anti-static cleaner for electronic equipment 2. HAZARDS IDENTIFICATION CLASSIFICATION Flammable aerosol 2 Gas under pressure Liquefied gas SIGNAL WORD: Warning Page 3 of 132 Page 3 of 132 Page 3 of 132 Page 3 of 132 ---PAGE BREAK--- Page 2 of 4 SDS for: 2914011 Printed: 5/5/2015 Hazard Statements Flammable aerosol Contains gas under pressure; may explode if heated Precautionary Statements Keep away from heat/sparks/open flames/hot surfaces – No smoking Do not spray on an open flame or other ignition source Pressurized container – Do not pierce or burn, even after use Protect from sunlight. Store in a well ventilated place Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Percent WATER 7732-18-5 97.00 BUTANE 106-97-8 1.90 4. FIRST AID MEASURES INHALATION: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped . Get medical attention. EYE CONTACT: Wash immediately with large volumes of fresh water for at least 15 minutes . Get medical attention. SKIN CONTACT: Wipe off with a towel. Wash with soap and water. Get medical attention if irritation persists. INGESTION: Not a likely route of exposure. Most important acute and delayed: Repeated exposure may cause skin dryness or cracking. May cause drowsiness or dizziness. Indication of immediate medical attention and special treatment needed: None known. 5. FIRE FIGHTING MEASURES Suitable and unsuitable extinguising media: Foam, Alcohol foam, CO2, Dry chemical, Water fog . Water spray may be ineffective. Specific hazards arising from the chemical: Closed containers may explode from internal pressure build-up when exposed to extreme heat and discharge contents. Liquid content of container will support combustion. Overexposure to decomposition products may cause a health hazard. may not be readily apparent. Obtain medical attention. Hazardous decomposition products include carbon dioxide, carbon monoxide, and other toxic fumes Special equipment and precautions for fire-fighters: Water may be used to cool containers to prevent pressure build-up and explosion when exposed to extreme heat. Wear goggles and use self-contained breathing apparatus . If water is used, fog nozzles are preferred. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Avoid breathing vapors. Ventilate area. Remove all sources of ignition. Page 4 of 132 Page 4 of 132 Page 4 of 132 Page 4 of 132 ---PAGE BREAK--- Page 3 of 4 SDS for: 2914011 Printed: 5/5/2015 Methods and materials for containment and cleaning up: Clean up with absorbent material and place in closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling: Do not puncture or incinerate (burn) cans. Do not stick pins, nails, or any other sharp objects into opening on top of can. Do not spray in eyes. Do not take internally. See product label for additional information. Conditions for safe storage, including any incompatibilities: Store and use in cool, dry, well-ventilated areas . Do not store above 120 F. 8. EXPOSURE CONTROL/PERSONAL PROTECTION Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits WATER 7732-18-5 Not established Not established BUTANE 106-97-8 Not established TWA: 1000 ppm Appropriate engineering controls: Ventilation should be sufficient to prevent inhalation of any vapors . General dilution and/or local exhaust ventilation in volume to keep PEL/TLV of most hazardous ingredient below acceptable limit and well below stated limit. Individual protection measures: Respiratory protection: None under normal use. Avoid breathing vapors. In restricted areas , use approved chemical/mechanical filters designed to remove a combination or particles and vapor. In confined areas, use an approved air line respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above PEL/TLV limits. Protective gloves: None under normal use. Use solvent-resistant for prolonged or repeated contact. Eye protection: None under normal use. However, use of safety glasses with splash guards or full face shield should be used if indicated. Other protective clothing or equipment: None under normal use. However, use of solvent- resistant aprons or other clothing is recommended. Eye washes and safety showers in the workplace are recommended. SHOWERS IN THE WORKPLACE ARE RECOMMENDED. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Aerosol product Vapor Pressure: Not determined Vapor Density: Heavier than air Density: 0.985259828 Freezing point: Not determined Boiling point: N/A Evaporation rate: Slower than ether Explosive Limits: Not determined Auto ignition temperature: Not determined Viscosity: Not determined Page 5 of 132 Page 5 of 132 Page 5 of 132 Page 5 of 132 ---PAGE BREAK--- Page 4 of 4 SDS for: 2914011 Printed: 5/5/2015 Odor: Pleasant Odor threshold: Not determined pH: Not determined Melting point: Not determined Solubility: Not determined Flash point: Not determined Flammability: Level 1 Aerosol Partition coefficient Not determined octanol/water): Decomposition temperature: Not determined 10. STABILITY AND REACTIVITY Reactivity: Not reactive under normal conditions of use. Chemical stability: Stable under normal storage and handling conditions. Possibility of hazardous reactions: None known. Incompatible materials: No data Hazardous decomposition products: No data 11. TOXICOLOGICAL INFORMATION Long-term toxicological studies have not been conducted for this product. 12. ECOLOGICAL INFORMATION Long-term ecological studies have not been conducted for this product. 13. DISPOSAL CONSIDERATIONS Page 6 of 132 Page 6 of 132 Page 6 of 132 Page 6 of 132 ---PAGE BREAK--- Page 5 of 4 SDS for: 2914011 Printed: 5/5/2015 Dispose of in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections this document for hazard cautionary information. 14. TRANSPORT INFORMATION By land: DOT Proper Shipping Name: None required per 49 CFR 173 .306(i) for products that conform to the Limited Quantity provisions. Commodity shipping description: Cleaning Compound, NOI By water: DOT & IMDG Proper Shipping Name: UN1950, Aerosols, 2 LTD QTY By air: DOT & IATA Proper Shipping Name: UN1950, Aerosols, flammable, 2 LTD QTY (packing instruction Y203 applies) 15. REGULATORY INFORMATION All ingredients are either listed on the TSCA inventory or are exempt . 16. OTHER INFORMATION Date revised: 2015-05-05 Date Printed: 2015-05-05 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO RESPONSIBILITY FOR ITS USE. Revision 0 Page 7 of 132 Page 7 of 132 Page 7 of 132 Page 7 of 132 ---PAGE BREAK--- Revision Date: 22-Jan-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: CARPET STAIN REMOVER Product Number: 6374 Recommended Use: Cleaning agent Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Serious Eye Damage/Eye Irritation: Category 2A GHS Label Elements Signal Word: Danger Hazard Statements: Causes serious eye irritation Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Wear eye / face protection Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 6 Liquefied gas Symbols: Page 8 of 132 Page 8 of 132 Page 8 of 132 Page 8 of 132 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 Hazards Not Otherwise Classified: Not Applicable Other Information: • May cause skin irritation. • May be harmful if swallowed. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 2-butoxyethanol 111-76-2 5-10 isopropanol 67-63-0 1-5 propane 74-98-6 1-5 N-butane 106-97-8 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 6 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 9 of 132 Page 9 of 132 Page 9 of 132 Page 9 of 132 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH 2-butoxyethanol 111-76-2 TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3 isopropanol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Not required with expected use. Respiratory Protection: Page 3 / 6 Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. Page 10 of 132 Page 10 of 132 Page 10 of 132 Page 10 of 132 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: -Eyes. Respiratory System. -Skin. Blood. Central nervous system. hematopoietic system. kidney. Liver, Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 4331 mg/kg ATEmix (dermal): 11323 mg/kg ATEmix (inhalation-gas): 10511385 ATEmix (inhalation-dust/mist): 23.1 mg/l ATEmix (inhalation-vapor): 22.9 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: White Odor: solvent pH: 10.0-11.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F (Product without propellant) Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: <1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.96 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 4 / 6 Decomposition Temperature: No information available. Viscosity: No information available. Page 11 of 132 Page 11 of 132 Page 11 of 132 Page 11 of 132 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 2-butoxyethanol 111-76-2 = 470 mg/kg ( Rat ) = 2270 mg/kg ( Rat ) = 220 mg/kg ( Rabbit ) = 2.21 mg/L ( Rat ) 4 h = 450 ppm ( Rat ) 4 h isopropanol 67-63-0 = 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rat ) = 12870 mg/kg ( Rabbit ) = 72.6 mg/L ( Rat ) 4 h propane 74-98-6 Not Available Not Available = 658 mg/L ( Rat ) 4 h N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea 2-butoxyethanol 111-76-2 Not Available 1490: 96 h Lepomis macrochirus mg/L LC50 static 2950: 96 h Lepomis macrochirus mg/L LC50 Not Available 1698 - 1940: 24 h Daphnia magna mg/L EC50 1000: 48 h Daphnia magna mg/L EC50 isopropanol 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 9640: 96 h Pimephales promelas mg/L LC50 flow-through 11130: 96 h Pimephales promelas mg/L LC50 static 1400000: 96 h Lepomis macrochirus µg/L LC50 Not Available 13299: 48 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product contains the following listed substances: 2-butoxyethanol CAS No 111-76-2 applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substituted phenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, Chemical Category N230 SARA 311/312 Hazard Categories Page 5 / 6 Acute Health Hazard: Yes Page 12 of 132 Page 12 of 132 Page 12 of 132 Page 12 of 132 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 formaldehyde - 50-00-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 16. OTHER INFORMATION Revision Date: 22-Jan-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 2 Flammability: 1 Instability: 0 Special: N/A HMIS Page 6 / 6 Health Hazards: 2 Flammability: 2 Physical Hazards: 2 Page 13 of 132 Page 13 of 132 Page 13 of 132 Page 13 of 132 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date May 23, 2015 Revision Date New Revision Number 0 Page 1 / 9 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended use Ready-to-use general purpose cleaner dilution from the Clorox® EZ Dilute™ system Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612 Phone: 1-[PHONE REDACTED] Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] Page 14 of 132 Page 14 of 132 Page 14 of 132 Page 14 of 132 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 2 / 9 2. HAZARDS IDENTIFICATION Classification This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). GHS Label elements, including precautionary statements Emergency Overview This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Appearance Clear, colorless-to-very-light green Physical State Thin liquid Odor Lemon Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0.3% of the mixture consists of ingredient(s) of unknown toxicity Other information May cause slight eye irritation. Interactions with Other Chemicals No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS This product contains no substances that at their given concentrations are considered to be hazardous to health. Page 15 of 132 Page 15 of 132 Page 15 of 132 Page 15 of 132 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 3 / 9 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15–20 minutes. If present, remove contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing problems develop, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Most important and effects, both acute and delayed Most Important and Effects May cause slight eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Hazardous Combustion Products Oxides of carbon. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 16 of 132 Page 16 of 132 Page 16 of 132 Page 16 of 132 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 4 / 9 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers closed. Incompatible Products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product does not contain any ingredients with occupational exposure limits that are at concentrations below their cut-off values/concentrations and that contribute to the hazard classification of the product. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Page 17 of 132 Page 17 of 132 Page 17 of 132 Page 17 of 132 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 5 / 9 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid Appearance Clear Odor Lemon Color Colorless-to-very- light green Odor Threshold No information available Property Values Remarks/ Method pH 6 - 9 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point No data available None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.0 None known Water Solubility Complete None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None known. Conditions to avoid None known. Incompatible materials None known. Hazardous Decomposition Products None known. Page 18 of 132 Page 18 of 132 Page 18 of 132 Page 18 of 132 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 6 / 9 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Exposure to vapor or mist may cause slight respiratory tract irritation Eye Contact May cause slight irritation. Skin Contact May cause slight irritation. Ingestion Ingestion of liquid may cause slight irritation to mucous membranes and gastrointestinal tract. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Ethanol 64-17-5 - - 125 mg/L (Rat, 4 h) Information on toxicological effects May cause slight redness and tearing of eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage. Chemical Name ACGIH IARC NTP OSHA Ethanol 64-17-5 A3 Group 1 Known X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Contains a known or suspected carcinogen. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage. Contains a known or suspected reproductive toxin. Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Repeated abuse can have long-term health effects. Target Organ Effects Eyes, blood, central nervous system (CNS), liver, reproductive system, respiratory system. Page 19 of 132 Page 19 of 132 Page 19 of 132 Page 19 of 132 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 7 / 9 Aspiration Hazard Not an aspiration hazard. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document No information available. 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Ethanol 64-17-5 LC50: 12.0 - 16.0 mL/L (96 h static) mykiss LC50: 13400 - 15100 mg/L (96 h flow-through) Pimephales promelas LC50: > 100 mg/L (96 h static) Pimephales promelas EC50 = 34634 mg/L 30 min EC50 = 35470 mg/L 5 min LC50: 9268 - 14221 mg/L (48 h ) Daphnia magna EC50: 10800 mg/L (24 h ) Daphnia magna EC50: 2 mg/L (48 h Static) Daphnia magna Persistence and Degradability No information available. Bioaccumulation Chemical Name Log Pow Ethanol 64-17-5 -0.32 Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Not regulated. TDG Not regulated. ICAO Not regulated. IATA Not regulated IMDG/IMO Not regulated Page 20 of 132 Page 20 of 132 Page 20 of 132 Page 20 of 132 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 8 / 9 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. US State Regulations California Proposition 65 This product contains the following Proposition 65 chemical. Ethyl alcohol is only a considered a Proposition 65 developmental and cancer hazard when it is ingested as an alcoholic beverage. Chemical Name California Proposition 65 Ethanol 64-17-5 Developmental Cancer U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Ethanol 64-17-5 X International Regulations Canada WHMIS Hazard Class Not controlled. Page 21 of 132 Page 21 of 132 Page 21 of 132 Page 21 of 132 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 9 / 9 16. OTHER INFORMATION NFPA Health Hazard 0 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 0 Flammability 0 Physical Hazard 0 Personal Protection - Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Preparation/Revision Date May 23, 2015 Revision Note Reference New INT0049 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 22 of 132 Page 22 of 132 Page 22 of 132 Page 22 of 132 ---PAGE BREAK--- 1. IDENTIFICATION Product Name Comet Deodorizing Cleanser with Chlorinol Product Code(s) 3-10 Product ID: 97086927_PROF_NG Product Type: Finished Product - Professional Use Only Recommended Use Hard Surface Cleaner Restrictions on Use Do not mix with other cleaning products or chemicals as irritating fumes may be formed. Manufacturer Procter & Gamble Professional 2 P&G Plaza Cincinnati, Ohio 45202 Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5 1-[PHONE REDACTED] E-mail Address Emergency Telephone Transportation (24 HR) CHEMTREC - 1-[PHONE REDACTED] Canada) or 1-[PHONE REDACTED] Mexico toll free in country: [PHONE REDACTED] 2. HAZARD IDENTIFICATION This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Hazard Category Eye Damage / Irritation Category 2B Page 1 / 7 Hazard pictograms None Issuing Date: 12-Jun-2015 Precautionary Statements - Prevention Wash hands thoroughly after handling Do not mix with other cleaning products or chemicals as irritating fumes may be formed Signal Word WARNING Revision Date: 12-Jun-2015 Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF SWALLOWED: Drink 1 or 2 glasses of water SAFETY DATA SHEET Version 1 Hazard Statements Causes eye irritation Page 23 of 132 Page 23 of 132 Page 23 of 132 Page 23 of 132 ---PAGE BREAK--- 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists. Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if occur. Inhalation Move to fresh air. If persist, call a physician. Most important acute and delayed None under normal use conditions. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Unsuitable Extinguishing Media None. Special hazard None known. Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical None. Page 2 / 7 Revision Date: 12-Jun-2015 Precautionary Statements - Disposal Dispose of contents/container in accordance with local regulation Precautionary Statements - Storage None 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Hazards not otherwise classified (HNOC) None Chemical Name Synonyms Trade Secret CAS-No Weight % Limestone - No 1317-65-3 40 - 100 Sodium carbonate - No 497-19-8 5 - 10 - No 87-90-1 1 - 5 Benzenesulfonic acid, mono-C10-16-alkyl derivs., sodium salts - No 68081-81-2 1 - 5 Page 24 of 132 Page 24 of 132 Page 24 of 132 Page 24 of 132 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Advice for emergency responders Use personal protective equipment as required. Methods and materials for containment and cleaning up Methods for containment Prevent dust cloud. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Dispose of in accordance with local regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products Do not mix with other cleaning products or chemicals as irritating fumes may be formed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL Limestone 1317-65-3 TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 15 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction Mexico: TWA 10 mg/m3 Mexico: STEL 20 mg/m3 Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Limestone 1317-65-3 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 3 mg/m3 STEL: 20 mg/m3 No relevant exposure guidelines for other ingredients Exposure controls Engineering Measures Distribution, Workplace and Household Settings: Ensure adequate ventilation Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction Personal Protective Equipment Page 3 / 7 Revision Date: 12-Jun-2015 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Page 25 of 132 Page 25 of 132 Page 25 of 132 Page 25 of 132 ---PAGE BREAK--- Eye Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection Hand Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves Skin and Body Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Wear suitable protective clothing Respiratory Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20°C solid Appearance white Odor Pine Odor threshold No information available Oxidizing properties These substances will accelerate burning when involved in a fire. VOC Content Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity None under normal use conditions. Page 4 / 7 No information available Lower Flammability Limit No information available Values Vapor pressure No information available Boiling point/boiling range Vapor density Revision Date: 12-Jun-2015 No information available No information available Relative density No information available Note Water solubility Flash point 15% Solubility in other solvents No information available No information available Partition coefficient: n-octanol/waterNo information available pH value Autoignition temperature Evaporation rate No information available . Decomposition temperature No information available No information available . Viscosity of Product No information available 11.5 Flammability (solid, gas) Property No information available (as 1% solution) Flammability Limits in Air Melting/freezing point Upper flammability limit 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol No information available Page 26 of 132 Page 26 of 132 Page 26 of 132 Page 26 of 132 ---PAGE BREAK--- Stability Stable under normal conditions. Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. Conditions to Avoid None under normal processing. Materials to avoid Do not mix with other cleaning products or chemicals as irritating fumes may be formed. Hazardous Decomposition Products None under normal use. 11. TOXICOLOGICAL INFORMATION Product Information Information on likely routes of exposure Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact Irritating to eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation Irritating to eyes. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect. Component Information Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation Sodium carbonate 497-19-8 2800 mg/kg bw > 2000 mg/kg bw (US EPA 16 CFR 1500.40) - 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Page 5 / 7 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Revision Date: 12-Jun-2015 Page 27 of 132 Page 27 of 132 Page 27 of 132 Page 27 of 132 ---PAGE BREAK--- Waste treatment Waste from Residues / Unused Products Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Codes (non-household setting) 331 14. TRANSPORT INFORMATION DOT Not regulated IMDG Not regulated IATA Not regulated 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name CAS-No Hazardous Substances RQs Extremely Hazardous Substances RQs CERCLA/SARA 302 TPQ Piperidine 110-89-4 - 1000 lb 1000 lb Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) Chemical Name CAS-No New Jersey Limestone 1317-65-3 X 87-90-1 X Chemical Name CAS-No Limestone 1317-65-3 X 87-90-1 X Page 6 / 7 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Revision Date: 12-Jun-2015 Page 28 of 132 Page 28 of 132 Page 28 of 132 Page 28 of 132 ---PAGE BREAK--- International Inventories United States All intentionally-added components of this product(s) are listed on the US TSCA Inventory. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act 16. OTHER INFORMATION HMIS Ratings Health hazard 2 Flammability 0 Physical hazard 0 Health hazard 2 Flammability 0 Instability 0 Issuing Date: 12-Jun-2015 Revision Date: 12-Jun-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Revision Date: 12-Jun-2015 Page 29 of 132 Page 29 of 132 Page 29 of 132 Page 29 of 132 ---PAGE BREAK--- 28 May 2015 aqua (water) diluent 7732-18-5 Not applicable thymol (a component of thyme oil) antimicrobial active 8007-46-3 0.05% 980 mg/kg Other ingredients: . 99.95% . Ingredient Function CAS Number Concentration1 LD502 Active ingredient . . Eyes Minimal eye irritant category IV Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients on the consumer product label. Section 3: Composition, Information on Ingredients Precautionary Statements Emergency Overview No or effects under normal use. May cause slight irritation of eyes, skin or respiratory tract. This product is not considered hazardous under the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). This product is not considered hazardous under the WHMIS 2015. Classification U.S. Canada Section 2: Hazards Identification A PERSONAL PROTECTION Not determined Hazardous Materials Identification System (HMIS) Rating 0 0 0 PHYSICAL HAZARDS FLAMMABILITY Skin Slight dermal irritant category IV. Non-sensitizer. Ingestion May cause transient gastrointestinal irritation. HEALTH Legend: 4-Severe, 3-Serious, 2-Moderate, 1-Slight, 0-Minimal Inhalation May cause slight irritation. Hazards not otherwise identified None known Percent ingredients with unknown acute toxicity 0% of the product consists of ingredients of unknown acute oral toxicity. Refer to Section 3. SAFETY DATA SHEET National Fire Protection Association (NFPA) Rating Botanical Disinfecting Multi-Surface Cleaner Hard Surface Disinfecting and Cleaning Seventh Generation, Inc. 60 Lake Street, Burlington, VT 05401, USA This Safety Data Sheet (SDS) is intended to provide product information for workplaces, emergency personnel and other situations where there is potential for longer exposure or exposure to larger quantities of product. For consumer use, applicable precautionary information is provided on the product label. This SDS is designed to cover both U.S. and Canadian requirements. Differences between U.S. and Canadian requirements are noted where applicable. Issue date Emergency Telephone Number U.S. Canada 1-[PHONE REDACTED] 1-[PHONE REDACTED] (ChemTel) Monday -Friday 8 am - 5 pm ET (except holidays) Outside these hours Address Restrictions on Use Follow directions on the product label Section 1: Identification of Product and Company Product Name Synonyms Product Use Manufacturer Name Disinfecting Multi-Surface Cleaner FM000054-00.2 Page 1 of 6 Page 30 of 132 Page 30 of 132 Page 30 of 132 Page 30 of 132 ---PAGE BREAK--- SAFETY DATA SHEET Safe Handling Household Setting Use as directed on product label. Industrial Setting Wear appropriate personal protective equipment (refer to section Section 7: Handling and Storage Section 6: Accidental Release Measures Personal Precautions Protective Equipment and Precautions for Firefighters Fire fighters should wear full protective clothing and self contained breathing apparatus as for surrounding fire. Suitable Extinguishing Media As appropriate for surrounding fire. Use water, dry chemical, carbon dioxide or foam. Unsuitable Extinguishing Media Not available. Most important and effects Acute exposure may result in eye irritation. Specific Hazards arising from the chemical mixture Not available. Hazardous Combustion Products Not available. Section 4: First Aid Measures *Lemongrass Citrus Scent: cymbopogon nardus (citronella) oil, cymbopogon schoenanthus (lemongrass) oil. Citral is a component of these essential oils. 1 Where ranges are shown, the exact concentration has been withheld as a trade secret. 2 LD50 Acute oral toxicity (rat) – This is a value provided by the raw material supplier or scientific literature. It is not a value generated by Seventh Generation by testing using rats. Seventh Generation uses alternative, non-animal based methods and scientific literature to determine the safety classification of our products and their ingredients. sodium citrate water softener 6132-04-3 6730 mg/kg essential oils* fragrance mixture >5000 mg/kg origanum vulgare (oregano) oil fragrance 8007-11-2 1850 mg/kg copper sulfate pentahydrate (bluestone) water mineralizer 7758-99-8 300 mg/kg citric acid water softener 77-92-9 3000 mg/kg sodium lauryl sulfate cleaning agent 151-21-3 1288 mg/kg Eye Contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a doctor or poison control center for treatment advice. Section 5: Fire Fighting Measures Skin Contact Rinse thoroughly with water if skin contact occurs. Call a physician if irritation develops or persists. Ingestion Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a doctor or poison control center. Do not give anything to an unconscious person. Inhalation Remove to fresh air. If breathing is affected, call a physician. Notes to Physician Treat Industrial Setting Wear appropriate personal protective equipment (refer to Section Environmental Precautions Avoid entry into lakes, streams, ponds or public waterways. Methods for Containment and Cleaning Up Household Setting Small spills and leaks may be cleaned up and disposed of in normal household trash or diluted and disposed of via sewer. Industrial Setting Before attempting clean up, refer to hazard data given. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labeled containers. Prevent extremely large spills from entering sewers or waterways. Dispose in accordance with all applicable local, state, and federal regulations. Page 2 of 6 Page 31 of 132 Page 31 of 132 Page 31 of 132 Page 31 of 132 ---PAGE BREAK--- SAFETY DATA SHEET Possibility of Hazardous Reactions None known. Household Setting In general, cleaning products should not be mixed with other household chemicals, unless specifically provided for in the use directions. Section 10: Stability and Reactivity Industrial Setting None known. Hazardous Decomposition Products None known. Conditions to Avoid None known. Incompatible Materials VOC (weight Not available. Partition Coefficient: n-octanol/water Not available. Viscosity Not available. Vapor Density (Air = 1) Not available. Solubility in Water Soluble Specific Gravity (H2O = 1) 1.00-1.02 Relative Density Not available. Lower Explosive Limit (LEL) Not applicable. Vapor Pressure (mmHg) Not available. Evaporation Rate As per water. Upper Explosive Limit (UEL) Not applicable. Flash Point Not available. Aqueous Solution. Freezing Point As per water. Initial Boiling Point and Boiling Range As per water. pH 4.0 - 5.0 Melting Point As per water. Odor Scented. Characteristic of the ingredients Odor Threshold Not available. Color Colorless (water-white) Clarity Clear Physical State Liquid. Section 9: Physical and Chemical Properties Eye Protection Goggles or other protective eye wear may be worn for protection. Skin Protection Gloves may be worn for protection. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Safe Storage KEEP OUT OF REACH OF CHILDREN AND PETS. Nonrefillable container. Store airtight at room temperature in original container and keep container closed when not in use. Avoid freezing. Storage Incompatibilities None known. Industrial Setting Respiratory Protection None required under normal conditions. General ventilation required. Exposure Limits None known. Engineering Controls Not applicable. Personal Protective Equipment (PPE) Household Setting No special precautions necessary as long as product is used as directed. Section 8: Exposure Controls, Personal Protection Reactivity None known. Chemical Stability Stable. Page 3 of 6 Page 32 of 132 Page 32 of 132 Page 32 of 132 Page 32 of 132 ---PAGE BREAK--- SAFETY DATA SHEET Washington Hazardous Waste Code WT02 Industrial Setting When disposed as waste in its original form, this product is not considered hazardous waste under Federal regulations, however regulations may vary by state or province and may designate it as hazardous waste. Check with your local waste and waste water authorities. We are aware of the following state waste classifications: California Hazardous Waste Code 232 Connecticut Hazardous Waste Code CT04 Michigan Liquid Waste Code 029L Vermont Hazardous Waste Code VT06 Product Waste Any disposal must be in compliance with applicable local, state, provincial and federal laws and regulations. Household Setting Product residues in the bottle may be discarded in trash, or diluted with water and disposed via sewer. Compatible with septic systems. Section 13: Disposal Considerations Environmental Fate No adverse effects expected. Bioaccumulative Potential Not applicable. Mobility in Soil Not available. Ecotoxicity Not available. Persistence and Degradability Meets requirements for ready biodegration based on OECD 301B. Section 12: Ecological Information Target Organ Effects Not expected to have chronic health effects. Not expected to have chronic health effects. Reproductive Effects Teratogenicity Not expected to have chronic health effects. Mutagenicity Not expected to have chronic health effects. NTP No Ingredients Listed IARC No Ingredients Listed OSHA No Ingredients Listed Carcinogenicity Not expected to have chronic health effects. Not expected to have chronic health effects. Sensitization Does not indicate a potential for allergic contact sensitization, based on Human Repeat Insult Patch Test (HRIPT). Skin Contact Non to slight dermal irritant category IV, based on ingredients and in-vitro data. Component Information Refer to section 3 for ingredient LD50 (acute oral). Effects of Acute Exposure Section 11: Toxicological Information Oral Toxicity LD50 >5000 mg/kg, calculated based on ingredients. Dermal Toxicity LD50 >5000 mg/kg, calculated based on ingredients. Inhalation Toxicity >20 mg/L/4h, based on ingredients. Eye Contact Potential Route(s) of Exposure Eyes. Skin. Ingestion. Minimal eye irritant category IV, based on ingredients and in-vitro data. Effects of Chronic Exposure Page 4 of 6 Page 33 of 132 Page 33 of 132 Page 33 of 132 Page 33 of 132 ---PAGE BREAK--- SAFETY DATA SHEET Offer empty container for recycling. If recycling is not available, discard in trash. Prepared by Seventh Generation Inc. Issuing Date 28 May 2015 Section 16: Other Information Health Canada Registration Number DIN 02415070 Right to Know Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients on the product label. Please refer to Section 3. of this SDS for ingredient listing. Other Fragrances used in this product comply with applicable International Fragrance Association (IFRA) guidance. California Prop 65 This product is not subject to the labeling requirements of California’s Proposition 65. California Air Resources Board (CARB) Meets applicable California Air Resource Board requirements for consumer products. Canada Domestic Substances List (DSL) This product complies with the inventory requirements under Canada’s Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL) or is otherwise in compliance with the New Substances Notification (NSN) regulations or exemptions. Toxic Substances Control Act (TSCA) This product complies with the inventory requirements of the U.S. Toxic Substances Control Act (TSCA). U.S. EPA Registration Number 84683-3-86066 California DPR Registration Number 84683-3-ZA-86066 Section 15: Regulatory Information IATA (Air Transport) Not regulated. IMDG (Marine Transport) Not regulated. U.S. States (Surface Transport) Not regulated as finished product. Regulated in some states if the product is disposed of in its original form as waste by commercial users/handlers. Refer to Section 13. for applicable state waste codes. Canadian TDG (Surface Transport) Not regulated. U.S. DOT (Surface Transport) Not regulated. Section 14: Transport Information Empty Packaging Revision Date 28 May 2015 Please note: This product is manufactured and marketed for consumer use and should be used as directed on the product label for the intended purpose. Seventh Generation warrants that this product conforms to our standard specification when released to the market and when used according to directions. To the best of our knowledge, the information contained herein is accurate. However, we do not assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any product is the sole responsibility of the user. All products may present unknown hazards and should be used with requisite caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Other abbreviations used in this document: Revision Note Revised format as per OSHA 2012 and WHMIS 2015. Page 5 of 6 Page 34 of 132 Page 34 of 132 Page 34 of 132 Page 34 of 132 ---PAGE BREAK--- SAFETY DATA SHEET End of Safety Data Sheet DOT – Department of Transportation EPA – Environmental Protection Agency IARC – International Agency for Research on Cancer NTP – (U.S. Department of Health and Human Services) National Toxicology Program OSHA – Occupational Safety and Health Administration TDG – (Canadian) Transport of Dangerous Goods WHMIS – (Canadian) Workplace Hazardous Materials Information System Page 6 of 6 Page 35 of 132 Page 35 of 132 Page 35 of 132 Page 35 of 132 ---PAGE BREAK--- Expo White Board Cleaner CHEMTREC (U.S. and Canada) 1-[PHONE REDACTED] SAFETY DATA SHEET Product name Emergency telephone number (with hours of operation) Section 1. Identification : : Manufacturer : Newell Rubbermaid 3500 Lacey Road, 10th Floor Downers Grove, IL 60515 USA [PHONE REDACTED] or [PHONE REDACTED] Material uses : Cleaning solutions. Section 2. Hazards identification Not classified. Classification of the substance or mixture : Signal word : Not applicable Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. GHS label elements General : Read label before use. If medical advice is needed, have product container or label at hand. OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients 3-butoxypropan-2-ol 2 - 5 5131-66-8 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Substance/mixture : Mixture Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 1/8 Page 36 of 132 Page 36 of 132 Page 36 of 132 Page 36 of 132 ---PAGE BREAK--- Expo White Board Cleaner Section 3. Composition/information on ingredients Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 2/8 Page 37 of 132 Page 37 of 132 Page 37 of 132 Page 37 of 132 ---PAGE BREAK--- Expo White Board Cleaner Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling None. Section 8. Exposure controls/personal protection Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Control parameters Individual protection measures Occupational exposure limits Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 3/8 Page 38 of 132 Page 38 of 132 Page 38 of 132 Page 38 of 132 ---PAGE BREAK--- Expo White Board Cleaner Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. Not available. Not available. Not available. Not available. Not available. Odor pH Clear. Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Not available. Not available. Not available. Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Burning rate Not applicable. : Burning time : Not applicable. SADT Not available. : Decomposition temperature : Not available. Solubility in water : Not available. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 4/8 Page 39 of 132 Page 39 of 132 Page 39 of 132 Page 39 of 132 ---PAGE BREAK--- Expo White Board Cleaner Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity 3-butoxypropan-2-ol LD50 Dermal Rabbit 3100 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Reproductive toxicity No known significant effects or critical hazards. Irritation/Corrosion No known significant effects or critical hazards. Sensitization No known significant effects or critical hazards. Information on the likely routes of exposure Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) No known significant effects or critical hazards. No known significant effects or critical hazards. Aspiration hazard No known significant effects or critical hazards. Information on toxicological effects : Not available. Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 5/8 Page 40 of 132 Page 40 of 132 Page 40 of 132 Page 40 of 132 ---PAGE BREAK--- Expo White Board Cleaner Section 11. Toxicological information No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Dermal 63798.6 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name 3-butoxypropan-2-ol 1.2 - low Toxicity No known significant effects or critical hazards. Persistence and degradability No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 6/8 Page 41 of 132 Page 41 of 132 Page 41 of 132 Page 41 of 132 ---PAGE BREAK--- Expo White Board Cleaner Section 14. Transport information - - - - - - - Not regulated. - - Not regulated. Not regulated. - - - DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user No. No. No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : TDG Classification Not regulated. - - - No. - Mexico Classification Not regulated. - - - No. - Section 15. Regulatory information U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted. SARA 311/312 Classification : Not applicable. 3-butoxypropan-2-ol 2 - 5 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients The following components are listed: Propylene glycol butyl ether Not controlled under WHMIS (Canada). None of the components are listed. Canada WHMIS (Canada) Canadian lists Canadian NPRI CEPA Toxic substances : : : Canada inventory : All components are listed or exempted. This product does not contain Chemicals known to State of California to cause cancer, birth defects, or reproductive harm. California Prop. 65 Section 16. Other information History Date of issue/Date of revision Version Prepared by Date of previous issue : : : : 8/5/2015 No previous validation 1 Product Safety. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 7/8 Page 42 of 132 Page 42 of 132 Page 42 of 132 Page 42 of 132 ---PAGE BREAK--- Expo White Board Cleaner Section 16. Other information Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof. Indicates information that has changed from previously issued version. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient UN = United Nations Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 8/8 Page 43 of 132 Page 43 of 132 Page 43 of 132 Page 43 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 1 / 9 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER Product code : 200000038598 : B02703630000 Manufacturer or supplier's details Company : Colgate-Palmolive Co 300 Park Avenue New York, NY 10022 Telephone : US: Consumer Affairs - 1-[PHONE REDACTED] Emergency telephone number : For emergencies involving spill, leak, fire, exposure or acci- dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887. Medical Emergency (24HR): For MEDICAL EMERGENCIES involving this product call: (888) 489-3861 Recommended use of the chemical and restrictions on use Recommended use : Formulated all purpose cleaner for household use. SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance liquid Colour purple GHS Classification Skin irritation : Category 2 Eye irritation : Category 2A Skin sensitisation : Category 1 GHS Label element Hazard pictograms : Signal word : Warning Page 44 of 132 Page 44 of 132 Page 44 of 132 Page 44 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 2 / 9 Hazard statements : H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P362 Take off contaminated clothing and wash before reuse. Disposal: P501 Dispose of contents/ container to an approved waste dis- posal plant. Potential Health Effects Inhalation : No adverse effects due to inhalation are expected. Skin : May cause skin irritation upon prolonged contact. Eyes : Causes eye irritation on direct contact. Ingestion : May be harmful if swallowed in large quantities. Aggravated Medical Condi- tion : None known. Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen Page 45 of 132 Page 45 of 132 Page 45 of 132 Page 45 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 3 / 9 by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration (C10-C16) acid 68584-22-5 1 - < 5 SECTION 4. FIRST AID MEASURES If inhaled : Remove victim to fresh air. Get medical attention, if symp- toms persist. In case of skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention. In case of eye contact : Flush eyes with water at least 15 minutes. Get medical atten- tion if eye irritation develops or persists. If swallowed : Drink 8 ounces of clear water. Get medical attention. Most important and effects, both acute and delayed : Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car- bon dioxide. Hazardous combustion prod- ucts : No hazardous combustion products are known Special protective equipment for firefighters : Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protection recommended in Section 8 of the SDS. Methods and materials for containment and cleaning up : Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa- ter. SECTION 7. HANDLING AND STORAGE Page 46 of 132 Page 46 of 132 Page 46 of 132 Page 46 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 4 / 9 Conditions for safe storage : Store at controlled room temperature at 20-25°C (68-77°F). SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : In an industrial work environment, no special precautions or control measures are required. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally re- quired. Protective measures : In an industrial work environment, if a splash is likely, chemi- cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary. Hygiene measures : In an industrial work environment, avoid eye and prolonged skin contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : purple pH : 7 Flash point : No data available SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reac- tions : Hazardous polymerisation does not occur. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : None known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Page 47 of 132 Page 47 of 132 Page 47 of 132 Page 47 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 5 / 9 Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate : > 10 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Components: (C10-C16) acid: Acute oral toxicity : LD50 (Rat): 1,460 mg/kg Method: No information available. Acute inhalation toxicity : LC50 (Rabbit): > 1.9 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Method: OECD Test Guideline 402 Skin corrosion/irritation Causes skin irritation. Components: (C10-C16) acid: Result: Corrosive after 1 to 4 hours of exposure Serious eye damage/eye irritation Causes serious eye irritation. Components: (C10-C16) acid: Result: Irreversible effects on the eye Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: Not classified based on available information. Components: (C10-C16) acid: Exposure routes: Inhalation Remarks: No data available Exposure routes: Dermal Result: May cause sensitisation by skin contact. Germ cell mutagenicity Not classified based on available information. Page 48 of 132 Page 48 of 132 Page 48 of 132 Page 48 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 6 / 9 Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS. SECTION 12. ECOLOGICAL INFORMATION The product has not been tested as a whole for environmental toxicity. However, environmental infor- mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua- tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients surfactants are biode- gradable) or testing conducted on the final product This product is biodegradable). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state envi- ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground. SECTION 14. TRANSPORT INFORMATION DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. Page 49 of 132 Page 49 of 132 Page 49 of 132 Page 49 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 7 / 9 IMDG : Not regulated. International Regulation Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sulfuric Acid 7664-93-9 1000 * Sulfuric Acid 7664-93-9 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sulfuric Acid 7664-93-9 1000 * Calculated RQ exceeds reasonably attainable upper limit. SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: SODIUM HYDROXIDE 1310-73-2 Sulfuric Acid SULFURIC ACID The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM HYDROXIDE 1310-73-2 Page 50 of 132 Page 50 of 132 Page 50 of 132 Page 50 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 8 / 9 Sulfuric Acid SULFURIC ACID This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know Sulfuric Acid SULFURIC ACID Right To Know WATER Water 2-PHENOXYETHANOL 122-99-6 SODIUM HYDROXIDE 1310-73-2 Sulfuric Acid SULFURIC ACID New Jersey Right To Know WATER Water PROPYLENE GLYCOL PROPYL ETHER 1569-01-3 (C10-C16) acid 68584-22-5 California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. The components of this product are reported in the following inventories: TSCA : All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) Page 51 of 132 Page 51 of 132 Page 51 of 132 Page 51 of 132 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 9 / 9 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im- plied, as to the accuracy, reliability or completeness of the information and assumes no re- sponsibility for injury, damage or loss resulting from the use of the material. Flammability Health Instability 1 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 52 of 132 Page 52 of 132 Page 52 of 132 Page 52 of 132 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date: 24-Feb-2015 Revision Date: 24-Feb-2015 Version 1 1. IDENTIFICATION Product Name Febreze Air Effects - Sun Baked Product ID: 92351338_RET_NG Product Type: Finished Product - Consumer (Retail) Use Only Recommended Use Air freshener Restrictions on Use Safe to use around dogs and cats. As with other care products, not for use around birds. Synonyms Febreze Air Effects - Summer Fruit Bouquet (92351338_A_RET_NG) Febreze Air Effects - Seaside Spring & Escape (92351338_B_RET_NG) Febreze Air Effects - Wintry Mint (96892319_RET_NG) Febreze Air Effects - Pumpkin Bliss (92350451_RET_NG) Febreze Air Effects - Pumpkin Harvest 92350451_A_RET_NG) Febreze Air Effects - Vanilla Latte (92350912_RET_NG) Febreze Air Effects - Pumpkin Harvest (92350912_A_RET_NG) Febreze Air Effects - Fluffy Vanilla (92350912_B_RET_NG) Febreze Air Effects - Cozy Vanilla Sugar (92350912_C_RET_NG) Febreze Air Effects - Morning Herbs & Mist (92351003_RET_NG) Febreze Air Effects - Turquoise Sea & Shimmer (92351003_A_RET_NG) Febreze Air Effects - New Zealand Springs (92351003_B_RET_NG) Manufacturer PROCTER & GAMBLE - Fabric and Home Care Division. Ivorydale Technical Centre. 5289 Spring Grove Avenue, Cincinnati, Ohio 45217-1087 USA E-mail Address Emergency Telephone Transportation (24 HR) CHEMTREC - 1-[PHONE REDACTED] Canada) or 1-[PHONE REDACTED] Mexico toll free in country: [PHONE REDACTED] 2. HAZARD IDENTIFICATION "Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product. This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Not Classified. Hazard Statements None Hazard pictograms None Page 1 / 7 Page 53 of 132 Page 53 of 132 Page 53 of 132 Page 53 of 132 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists. Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if occur. Inhalation Move to fresh air. If persist, call a physician. Most important acute and delayed None under normal use conditions. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Dry chemical. Alcohol-resistant foam. Unsuitable Extinguishing Media None. Special hazard None known. Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical None. Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) None Chemical Name Synonyms Trade Secret CAS-No Weight % Ethanol Page 2 / 7 - No 64-17-5 1 - 5 Page 54 of 132 Page 54 of 132 Page 54 of 132 Page 54 of 132 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Advice for emergency responders Use personal protective equipment as required. Environmental precautions Keep out of waterways. Do not discharge product into natural waters without pre-treatment or adequate dilution. Methods and materials for containment and cleaning up Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known. Aerosol Classification Level 1 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL Ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 Mexico: TWA 1000 ppm Mexico: TWA 1900 mg/m3 Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Ethanol 64-17-5 TWA: 1000 ppm TWA: 1880 mg/m3 TWA: 1000 ppm TWA: 1880 mg/m3 STEL: 1000 ppm STEL: 1000 ppm No relevant exposure guidelines for other ingredients Page 3 / 7 Exposure controls Engineering Measures Distribution, Workplace and Household Settings: Ensure adequate ventilation Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction Page 55 of 132 Page 55 of 132 Page 55 of 132 Page 55 of 132 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 Personal Protective Equipment Eye Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection Hand Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves Skin and Body Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Wear suitable protective clothing Respiratory Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20°C Aerosol Appearance clear Odor Scented Odor threshold No information available VOC Content Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Property Values Note pH value 4.7 - 5.3 Melting/freezing point No information available Boiling point/boiling range No information available Flash point 51.6 - 60 °C / 125 - 140 °F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air Upper flammability limit No information available Lower Flammability Limit No information available Vapor pressure No information available Vapor density No information available Relative density 0.987 - 1.0 Water solubility No information available Solubility in other solvents No information available Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available . Decomposition temperature No information available . Viscosity of Product No information available Page 4 / 7 Page 56 of 132 Page 56 of 132 Page 56 of 132 Page 56 of 132 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 Reactivity None under normal use conditions. Stability Stable under normal conditions. Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. Conditions to Avoid None under normal processing. Materials to avoid None in particular. Hazardous Decomposition Products None under normal use. 11. TOXICOLOGICAL INFORMATION Product Information Information on likely routes of exposure Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact No known effect. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation No known effect. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect. Component Information Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation Ethanol 64-17-5 10470 mg/kg bw (OECD 401) > 15800 mg/kg bw (Rabbit) 116.9 mg/L air (//OECD 403) 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility No information available. Page 5 / 7 Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Page 57 of 132 Page 57 of 132 Page 57 of 132 Page 57 of 132 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 Waste treatment Waste from Residues / Unused Products Aerosol cans, when disposed as waste, are regulated as D003 reactive hazardous waste in some States because of their potential to explode when heated. Check with your State environmental agency for guidance. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Codes (non-household setting) 331 14. TRANSPORT INFORMATION DOT UN no UN1950 UN Proper shipping name Aerosols Description UN1950, Aerosols, 2.2 , Ltd. Qty. Hazard Class 2.2 Emergency Response Guide Number 126 IMDG UN Number UN1950 UN Proper shipping name Aerosols Description UN1950, Aerosols, 2.2 , Ltd. Qty. Transport hazard class(es) 2.2 EmS-No F-D, S-U IATA UN no UN1950 UN Proper shipping name Aerosols, non-flammable Description UN1950, Aerosols, non-flammable, 2.2 , Ltd. Qty. Hazard Class 2.2 ERG Code 2L IATA comment Can also be shipped as ID8000 Consumer Commodity 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. Page 6 / 7 Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Page 58 of 132 Page 58 of 132 Page 58 of 132 Page 58 of 132 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 California Proposition 65 This product is not subject to warning labeling under California Proposition 65. Ethanol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage. U.S. State Regulations (RTK) Chemical Name CAS-No New Jersey Ethanol 64-17-5 X Chemical Name CAS-No Massachusetts Ethanol 64-17-5 X Chemical Name CAS-No Ethanol 64-17-5 X Dipropylene Glycol 25265-71-8 X International Inventories United States All intentionally-added components of this product(s) are listed on the US TSCA Inventory. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act 16. OTHER INFORMATION Issuing Date: 24-Feb-2015 Revision Date: 24-Feb-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text Page 7 / 7 End of SDS Page 59 of 132 Page 59 of 132 Page 59 of 132 Page 59 of 132 ---PAGE BREAK--- Page 60 of 132 Page 60 of 132 Page 60 of 132 Page 60 of 132 ---PAGE BREAK--- Page 61 of 132 Page 61 of 132 Page 61 of 132 Page 61 of 132 ---PAGE BREAK--- Page 62 of 132 Page 62 of 132 Page 62 of 132 Page 62 of 132 ---PAGE BREAK--- Page 63 of 132 Page 63 of 132 Page 63 of 132 Page 63 of 132 ---PAGE BREAK--- Page 64 of 132 Page 64 of 132 Page 64 of 132 Page 64 of 132 ---PAGE BREAK--- Page 65 of 132 Page 65 of 132 Page 65 of 132 Page 65 of 132 ---PAGE BREAK--- Form N051 Page 1 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 8/16/2005 MSDS No: N-051 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: Lemon Shine Furnature Polish Formula: Lemon oil and silicone emulsion with hydrocarbon propellant for use on furnature Chemical Type: Lemon oil and silicone emulsion HMIS RATINGS Health = 1 (Slight) Flammability = 2 (Moderate) Reactivity = 0 (Minimal) Protection = A (Safety Glasses) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Propane 1-5% 1000 ppm No CAS No. 74-98-6 n-Butane 1-5% 600 ppm No CAS No. 106-97-8 SECTION III - CHEMICAL AND PHYSICAL Appearance and Odor: Lemon Odor, Cone Spray Boiling Point: N/A Evaporation Rate (Ether = <1 Melting Point: N/A pH: 10.0-11.0 Spec. Gravity (H20 = <1 Water Solubility: 10% Vapor Density (Air = >1 Vapor Pressure (psig): 117 @ 130F SECTION IV - FIRE AND EXPLOSION HAZARDS Aerosol Flammability: Product is not required to be labeled as flammable as described in 16 CFR 1500.3 and 1500.45. Flash Point (Method): <0F (Propellant) None even until boiling (Conc) Explosion Limits: Upper: 9.5 Lower: 1.9 Extinguishing Media: Carbon Dioxide, foam and/or dry chemical may be used. Special Firefighting Procedures and Hazards: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: At evelated temperatures (over 54C or 130F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening or container structure. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: Avoid heat, open flame and oxidizing agents. Hazardous Decomposition Products: Carbon Monoxide in small amounts and additional toxic chemicals may be formed in small amounts Conditions to Avoid: Do not store above 54C or 130F. Keep away from heat, direct sunlight, open flames or sparks. Dropping of containers may cause bursting. Hazardous Polymerization: Occurs: Does Not Occur: Page 66 of 132 Page 66 of 132 Page 66 of 132 Page 66 of 132 ---PAGE BREAK--- Form N025 Page 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. Skin: Remove contaminated clothing. Flush skin with water followed by washing with soap and water. If irritation occurs, get medical attention. Do not use clothing until cleaned. Eyes: Flush eyes with plents of water for 15 minutes while holding eye lids wide open. Get medical attention if irritation persists. Ingestion: Get medical attention. Most likely routes of entry: Inhilation, eyes, and skin Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Remove all sources of ignition and ventilate area. Soak up spill wiht an inert absorbent and place into a designed disposal container. Consult local regulatory agency for proper disposition of material. Storage and Handling: Avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 130F (54C). Store as level 1 Aerosol (NFPA 30B) Waste Disposal: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gass is expelled. Dispose of container in acordance with local, state, and federal regulations. Empty Containers: Dispose in accordance with local, state, and federal regulations. Other Precautions: Please read and follow the directions on the product label; THey are your best guide to using this product in the most effective way, and give the necessary safety precautions to protect you health. SECTION VIII - REGULATORY INFORMATION Respiratory Protection: None required if good ventilation is maintained. If exposure exceeds occupational exposure limits (Sect. II), use a NIOSH approved repirator to prevent overexposure. Ventilation: General ventilation is adequate under normal conditions. Mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves are recommended - consult glove manufacturer to determine the proper type for a specific operation. Eye Protection: Chemical safety glasses are recommended. Other Protective Clothing or Equipment: Wear impervious clothing to prevent skin contact. Work/Hygienic Practices: Ensure stict sanityar conditions are conformed to when working around chemicals. Protective clothing and equipment should be in accordance with 29 CFR 1910.132 and 1910.133. Reportable for SARA Title III, S.313 (Form The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 67 of 132 Page 67 of 132 Page 67 of 132 Page 67 of 132 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 1 / 7 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : MURPHY OIL SOAP WOOD CLEANER SPRAY RTU Product code : 200000041735 : B02955850000 Manufacturer or supplier's details Company : Colgate-Palmolive Co 300 Park Avenue New York, NY 10022 Telephone : US: Consumer Affairs - 1-[PHONE REDACTED] Emergency telephone number : For emergencies involving spill, leak, fire, exposure or acci- dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887. Medical Emergency (24HR): For MEDICAL EMERGENCIES involving this product call: (888) 489-3861 Recommended use of the chemical and restrictions on use Recommended use : Formulated all purpose cleaner for household use. SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance liquid Colour orange GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Potential Health Effects Inhalation : No adverse effects due to inhalation are expected. Skin : May cause skin irritation upon prolonged contact. Eyes : Causes eye irritation on direct contact. Ingestion : May be harmful if swallowed in large quantities. Aggravated Medical Condi- : None known. Page 68 of 132 Page 68 of 132 Page 68 of 132 Page 68 of 132 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 2 / 7 tion Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components No hazardous ingredients SECTION 4. FIRST AID MEASURES If inhaled : Remove victim to fresh air. Get medical attention, if symp- toms persist. In case of skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention. In case of eye contact : Flush eyes with water at least 15 minutes. Get medical atten- tion if eye irritation develops or persists. If swallowed : Drink 8 ounces of clear water. Get medical attention. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car- bon dioxide. Hazardous combustion prod- ucts : No hazardous combustion products are known Special protective equipment for firefighters : Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. Page 69 of 132 Page 69 of 132 Page 69 of 132 Page 69 of 132 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 3 / 7 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protection recommended in Section 8 of the SDS. Methods and materials for containment and cleaning up : Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa- ter. SECTION 7. HANDLING AND STORAGE Conditions for safe storage : Store at controlled room temperature at 20-25°C (68-77°F). SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : In an industrial work environment, no special precautions or control measures are required. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally re- quired. Protective measures : In an industrial work environment, if a splash is likely, chemi- cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary. Hygiene measures : In an industrial work environment, avoid eye and prolonged skin contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : orange pH : 10.0 Flash point : > 100 °C Density : 1.0 g/cm3 Page 70 of 132 Page 70 of 132 Page 70 of 132 Page 70 of 132 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 4 / 7 SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reac- tions : Hazardous polymerisation does not occur. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : None known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Skin corrosion/irritation Not classified based on available information. Serious eye damage/eye irritation Not classified based on available information. Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available Page 71 of 132 Page 71 of 132 Page 71 of 132 Page 71 of 132 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 5 / 7 safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS. SECTION 12. ECOLOGICAL INFORMATION The product has not been tested as a whole for environmental toxicity. However, environmental infor- mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua- tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients surfactants are biode- gradable) or testing conducted on the final product This product is biodegradable). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state envi- ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground. SECTION 14. TRANSPORT INFORMATION DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. IMDG : Not regulated. International Regulation Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Page 72 of 132 Page 72 of 132 Page 72 of 132 Page 72 of 132 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 6 / 7 FORMALDEHYDE 50-00-0 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) FORMALDEHYDE 50-00-0 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: SODIUM HYDROXIDE 1310-73-2 FORMALDEHYDE 50-00-0 The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM HYDROXIDE 1310-73-2 FORMALDEHYDE 50-00-0 This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know FORMALDEHYDE 50-00-0 HYDROGEN PEROXIDE 7722-84-1 Right To Know WATER Water SODIUM HYDROXIDE 1310-73-2 New Jersey Right To Know WATER Water Sodium tallate 61790-45-2 California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. The components of this product are reported in the following inventories: Page 73 of 132 Page 73 of 132 Page 73 of 132 Page 73 of 132 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 7 / 7 TSCA : All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) In accordance with OSHA 29 CFR 1910.1048 formaldehyde is not listed in Section 3 of this MSDS, however, formaldehyde is regulated by State and Federal regulations at varying concen- trations. State and Federal information can be found above in Section 15. SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im- plied, as to the accuracy, reliability or completeness of the information and assumes no re- sponsibility for injury, damage or loss resulting from the use of the material. Flammability Health Instability 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 74 of 132 Page 74 of 132 Page 74 of 132 Page 74 of 132 ---PAGE BREAK--- Safety Data Sheet Office Max Compressed Gas Duster Section 1. Identification Product Identifier Office Max Compressed Gas Duster Synonyms OM96090, OM96091, OM96092, OM04736, OM04737 Manufacturer Stock Numbers N/A Product Cas 75-37-6 Recommended use Dust Removal Uses advised against Use Only as Directed - Read label instructions carefully. Keep out of reach of children. Intentional misuse by deliberately concentrating and/or inhaling contents may be fatal. Manufacturer Contact Address Falcon Safety Products, Inc. 25 ImClone Drive Branchburg, NJ, 08876 USA Phone Emergency Phone Fax (908) 707-4900 (800) 498-7192 N/A Section 2. Hazards Identification Classification FLAMMABLE GASES - Category 2 GASES UNDER PRESSURE - Compressed gas Signal Word Warning Pictogram Hazard Statements Contains gas under pressure; may explode if heated Flammable gas Precautionary Statements Response Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Prevention Do not spray on an open flame or other ignition source. Keep away from heat. Pressurized container: Do not pierce or burn, even after use. Storage Protect from sunlight. Store in a well-ventilated place. Store at temperatures not exceeding 120 degrees F/49 degrees C Disposal N/A Page 1 of 8 Page 75 of 132 Page 75 of 132 Page 75 of 132 Page 75 of 132 ---PAGE BREAK--- Occupational exposure limits, if available, are listed in Section 8. General Keep out of reach of children Ingredients of unknown toxicity 0% Hazards not Otherwise Classified N/A No Data Available Section 3. Ingredients CAS Ingredient Name Weight % 75-37-6 Ethane, 1,1-difluoro- 100 % Section 4. First-Aid Measures General Advice Never give anything by mouth to an unconscious person. When persist or in all cases of doubt, seek medical advice. Inhalation Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Skin Take off all contaminated clothing immediately. Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician. Eye Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion Is not considered a potential route of exposure. Most important acute and delayed Anaesthetic effects: light-headedness, irregular heartbeat with a strange sensation in the chest, heart thumping, apprehension, feeling of fainting, dizziness or weakness. Protection of First-aiders If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to Physician Because of possible disturbances of cardiac catecholamine drugs, such as epinephrine, which may be used in situations of emergency life support, should be used with special caution. Page 2 of 8 Page 76 of 132 Page 76 of 132 Page 76 of 132 Page 76 of 132 ---PAGE BREAK--- Section 5. Fire Fighting Measures Suitable Extinguishing Media Water spray, water fog, dry chemical, alcohol resistant foam, carbon dioxide (CO2) Unsuitable Extinguishing Media No applicable data available. Specific Hazards Flammable. This substance's fire decomposition by-products will include hydrofluoric acid and possibly carbonyl flouride. Avoid contact with these materials, which are toxic and irritating. Evacuate personnel immediately in the event of a fire involving this substance. Vapors may form explosive mixtures with air. Vapors are heavier than air and may spread along floors. Vapors or gases may travel considerable distances to ignition source and flash back. Special protective equipment for firefighters Use personal protective equipment. Wear neoprene gloves during cleaning up work after a fire. Exposure to decompositon products may be a hazard to health. Further Information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers/tanks with water spray. Section 6. Accidental Release Measures NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) Evacuate personnel to safe areas. Ventilate the area. Refer to protective measures listed in sections 7 and 8. Spill Clean-up If this product is spilled and not recovered, or is recovered as a waste for treatment and disposal, the CERCLA Reportable Quantity is 100 lbs. (release of an Unlisted Hazardous Waste with the Characteristic of Ignitability). Evaporates. Ventilate area using forced ventilation, especially low or enclosed places where heavy vapors might collect. Accidental Release Measures Wear self-contained breathing apparatus (SCBA). Section 7. Handling and Storage Handling (Personnel) Avoid breathing vapors or mist. Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. Handle in accordance with good industrial hygiene and safety practice. Handling (Physical Aspects) Vapors are heavier than air and may spread along floors. Vapors may form flammable mixture with air. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropirate standard. No sparking tools should be used. Take measures to prevent the build up of electrostatic charge. Keep away from open flames, hot surfaces and sources of ignition. When using DO NOT SMOKE. Do not use in areas where vapors may accumulate such as paper shredders. Dust Explosion class Not applicable Storage Keep container closed and in a dry, well-ventilated location. Store in original container. The product has an indefinite shelf life when stored properly. Storage Period Recommended shelf life - 10 years provided product is stored in a dry location as directed. Storage Temperature Do not expose to temperatures above 120 degrees F (49 degrees C) as overheating could cause can to burst. DO NOT leave in direct sunlight or enclosed vehicle. Page 3 of 8 Page 77 of 132 Page 77 of 132 Page 77 of 132 Page 77 of 132 ---PAGE BREAK--- Section 8. Exposure Controls/Personal Protection Occupational Exposure Limits Ingredient Name ACGIH TLV OSHA PEL STEL Ethane, 1,1-difluoro- N/A N/A N/A Personal Protective Equipment N/A Engineering controls Ensure adequate ventilation, especially in confined areas. Use respiratory protection if needed. Eye/Face Protection Wear safety glasses with side shields. Direct contact with liquid may cause frostbite. Respiratory Protection For rescue use self-contained breathing apparatus. Vapors are heavier than air and can cause suffication by reducing oxygen available for breathing. Skin and body protection As required by employer code. If there is risk of skin contact, wear protective clothing, gloves, etc. Direct contact with liquid can cause frostbite. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practices. Page 4 of 8 Page 78 of 132 Page 78 of 132 Page 78 of 132 Page 78 of 132 ---PAGE BREAK--- Section 9. Physical and Chemical Properties Physical State Gas Color Clear Odor slight, ether- like Odor Threshold No applicable data available Solubility Water - Partition coefficient Water/n-octanol N/A VOC% N/A Viscosity No applicable data available Specific Gravity 0.91 Density lbs/Gal 0.9 Pounds per Cubic Foot N/A Flash Point <-58°F C) FP Method N/A Ph Neutral Melting Point No applicable data available Boiling Point -13 °F (-25 ° C) Boiling Range N/A LEL 3.9 UEL 16.9 Evaporation Rate No applicable data available Flammability Flammable Decomposition Temperature N/A Auto-ignition Temperature No applicable data available Vapor Pressure 5,960 KPa at 77F (25C) Vapor Density 2.4 at 77F (25C) (Air=1) Section 10. Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical Stability The product is chemically stable under recommended storage conditions. Conditions to Avoid Aerosol containers are unstable at temperatures above 120 degrees F/49 degrees C Incompatible Materials Incompatible products include Alkali metals, Alkaline earth metals, powdered metals, powdered metal salts. Hazardous Decomposition Products Decomposition products are hazardous. This material can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrofluoric acid and possibly carbonyl fluoride. Page 5 of 8 Page 79 of 132 Page 79 of 132 Page 79 of 132 Page 79 of 132 ---PAGE BREAK--- Section 11. Toxicological Information Component Analysis - LC50 1,1-Difluoroethane - > 64000 ppm rat Component analysis - Oral LD50 1,1-Difluoroethane - 1500 mg/kg rat Effects of Acute Exposure - Eye Contact with liquid may cause frostbite Effects of Acute Exposure - Skin Contact with liquid may cause frostbite Effects of Acute Exposure - Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effect (headaches, dizziness). Vapors may cause dizziness or suffocation. Effects of Acute Exposure - Ingestion Not a normal route of exposure Sensitization Non-hazardous by WHMIS/OSHA criteria. Carcinogenicity Not classifiable as a human carcinogen. Animal testing did not show carcinogenic effects. None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA as a carcinogen. Mutagenicity Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Tests on mammalian cell cultures showed mutagenic effects. Reproductive Toxicity No toxcicity to reproduction. Animal testing showed no reproductive toxicity. Teratogenicity Animal testing showed no developmental toxicity. Further Information Cardiac sensitization threshold limit: 405000 mg/m3 Section 12. Ecological Information Aquatic Toxicity 1,1-Difluoroethane 96 h LC50 : Fish 295.78 mg/l 96 h EC50 : Algae 47.76 mg/l 48 h EC50 : Daphnia (water flea) 146.7 mg/l Section 13. Disposal Waste Disposal Methods Comply with applicable Federal, State/Provincial and Local Regulations. May be a RCRA Hazardous waste due to the ignitability characteristic. Do not puncture or incinerate container. Contaminated Packaging Not Available Page 6 of 8 Page 80 of 132 Page 80 of 132 Page 80 of 132 Page 80 of 132 ---PAGE BREAK--- Section 14. Transport Information UN Number 1030 UN Proper Shipping Name 1,1-Difluoroethane DOT Classification 2.1 Packing Group N/A Packaging Exceptions Note: Falcon Safety Products has been granted a DOT special permit. A copy of DOT Special Permit SP-11516 can be obtained by calling Falcon Safety Products, Inc. at [PHONE REDACTED]. Transportation of Dangerous Goods (TDG - Canada) Proper Shipping name: 1,1-Difluoroethane Hazard Class: 2.1 UN number: 1030 Packaging Exceptions: Limited quantity (containers up to 125mL) IATA/ICAO (Air) Proper Shipping Name: 1,1-Difuoroethane. Hazard Class: 2.1. UN Number: 1030. Maximum Net Quantity Packaging: Cargo Aircraft only - 150 kg maximum (forbidden on passenger aircraft). Maximum Net Quantity packaging cargo only: 150 kg. IMDG (Marine Transport) Proper Shipping Name: 1,1-DIFLUOROETHANE. Hazard Class: 2.1. UN Number: 1030. Additional Information TDG Canada: Falcon Safety Products has been granted Equivalency Certificate SU 9211 (ren. 1) by the TCSS, TDGD to offer for transport by road, rail and marine. Section 15. Regulatory Information Canadian Federal Regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. WHMIS Status Controlled WHMIS Classification Class A - Compressed Gas, Class B - Division 1 - Flammable Gas TSCA On the inventory, or in compliance with the inventory. SARA 313 Regulated Chemical(s) This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. NJ Right to Know Regulated Chemical(s) Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): 1,1-Difluoroethane. California Prop. 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Canada Domestic Substances List (DSL) This product is listed on the DSL inventory list and complies with the inventory requirements administered by the governing country. Page 7 of 8 Page 81 of 132 Page 81 of 132 Page 81 of 132 Page 81 of 132 ---PAGE BREAK--- Section 16. Other Information Revision Date 4/28/2015 Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Prepared By Falcon Safety Products, Inc. [PHONE REDACTED] Page 8 of 8 Page 82 of 132 Page 82 of 132 Page 82 of 132 Page 82 of 132 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 1/8 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Use of the Substance/Mixture : Furniture Polish/Cleaner Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : yellow / liquid / pleasant Immediate Concerns : Caution Avoid contact with skin, eyes and clothing. May be harmful if swallowed. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : Prolonged or repeated contact may dry skin and cause irritation. Inhalation : Excessive exposures may affect human health, as follows: Inhalation may cause central nervous system effects. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aspiration hazard if swallowed - can enter lungs and cause damage. Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. Page 83 of 132 Page 83 of 132 Page 83 of 132 Page 83 of 132 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 2/8 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Hydrocarbons, C16-C20, n- alkanes, isoalkanes, cyclics, aromatics 64742-46-7 30.00 - 60.00 White Mineral Oil, (Petroleum) 8042-47-5 30.00 - 60.00 Citrus, Extract 94266-47-4 1.00 - 5.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Container may melt and leak in heat of fire. Further information : Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. Flash point : 102 °C Page 84 of 132 Page 84 of 132 Page 84 of 132 Page 84 of 132 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 3/8 215.6 °F Method: Tag Closed Cup (TCC) Lower explosion limit : Note: not applicable Upper explosion limit : Note: not applicable 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Material can create slippery conditions. Personal precautions : No special precautions required. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Normal measures for preventive fire protection. Storage Requirements for storage areas and containers : Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis White Mineral Oil, (Petroleum) 8042-47-5 5 mg/m3 - - ACGIH TWA Personal protective equipment Page 85 of 132 Page 85 of 132 Page 85 of 132 Page 85 of 132 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 4/8 Respiratory protection No personal respiratory protective equipment normally required. Hand protection : No special requirements. Eye protection No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : yellow Odor : pleasant pH : not applicable Boiling point : no data available Freezing point : no data available Flash point : 102 °C 215.6 °F Method: Tag Closed Cup (TCC) Evaporation rate : no data available Flammability (solid, gas) : Does not sustain combustion. Lower explosion limit : not applicable Upper explosion limit : not applicable Vapour pressure : no data available Density : 0.8424 g/cm3 at 40 °C Water solubility : negligible Viscosity, dynamic : 24 mPa.s at 40 °C Page 86 of 132 Page 86 of 132 Page 86 of 132 Page 86 of 132 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 5/8 Viscosity, kinematic : 28.5 mm2/s at 40 °C Volatile Organic Compounds Total VOC (wt. : 1.1 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations 10. STABILITY AND REACTIVITY Conditions to avoid : Direct sources of heat. Materials to avoid : Strong oxidizing agents Materials to avoid : None known. Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 Calculated > 5,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Chronic effects Carcinogenicity : no data available Mutagenicity : None Anticipated Reproductive effects : no data available Teratogenicity : no data available Page 87 of 132 Page 87 of 132 Page 87 of 132 Page 87 of 132 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 6/8 Sensitisation : Substance is not a sensitizer. 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport  U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport  IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport  ICAO/IATA: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Page 88 of 132 Page 88 of 132 Page 88 of 132 Page 88 of 132 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 7/8 Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 1 Flammability 1 Reactivity 0 NFPA Ratings Health 1 Fire 1 Reactivity 0 Special - This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 89 of 132 Page 89 of 132 Page 89 of 132 Page 89 of 132 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 8/8 Page 90 of 132 Page 90 of 132 Page 90 of 132 Page 90 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 1 / 14 SECTION 1. IDENTIFICATION Product name : PURELL® Hand Sanitizing Wipes Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-[PHONE REDACTED] CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal Word : Warning Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation. Page 91 of 132 Page 91 of 132 Page 91 of 132 Page 91 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 2 / 14 Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration Ethanol 64-17-5 10 - < 20 Benzethonium chloride 121-54-0 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Page 92 of 132 Page 92 of 132 Page 92 of 132 Page 92 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 3 / 14 Get medical attention. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Page 93 of 132 Page 93 of 132 Page 93 of 132 Page 93 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 4 / 14 Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Page 94 of 132 Page 94 of 132 Page 94 of 132 Page 94 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 5 / 14 Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 STEL 1,000 ppm ACGIH Hazardous components without workplace control parameters Ingredients CAS-No. Benzethonium chloride 121-54-0 Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Page 95 of 132 Page 95 of 132 Page 95 of 132 Page 95 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 6 / 14 Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety goggles Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : impregnated cloth Color : colorless, clear, cloudy Odor : citrus Odor Threshold : No data available pH : 4.0 - 7.5 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 37.8 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Page 96 of 132 Page 96 of 132 Page 96 of 132 Page 96 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 7 / 14 Density : 0.9780 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : No data available Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Page 97 of 132 Page 97 of 132 Page 97 of 132 Page 97 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 8 / 14 Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Benzethonium chloride: Acute oral toxicity : LD50 (Rat): 295 mg/kg Method: OECD Test Guideline 401 Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Benzethonium chloride: Species: Rabbit Result: Corrosive after 1 to 4 hours of exposure Serious eye damage/eye irritation Causes serious eye irritation. Ingredients: Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Benzethonium chloride: Page 98 of 132 Page 98 of 132 Page 98 of 132 Page 98 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 9 / 14 Test Type: Magnusson-Kligman-Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative Benzethonium chloride: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Carcinogenicity Not classified based on available information. Ingredients: Benzethonium chloride: Species: Rat Application Route: Skin contact Exposure time: 2 Years Result: negative IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Page 99 of 132 Page 99 of 132 Page 99 of 132 Page 99 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 10 / 14 Method: OECD Test Guideline 416 Result: negative STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Benzethonium chloride: Toxicity to fish : LC50 mykiss (rainbow trout)): 1.15 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.22 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Page 100 of 132 Page 100 of 132 Page 100 of 132 Page 100 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 11 / 14 Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 0.12 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 M-Factor (Acute aquatic tox- icity) : 1 Toxicity to bacteria : EC50: 35.70 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Benzethonium chloride: Biodegradability : Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 301B Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: n- octanol/water : log Pow: -0.35 Benzethonium chloride: Partition coefficient: n- octanol/water : log Pow: 1.08 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. Page 101 of 132 Page 101 of 132 Page 101 of 132 Page 101 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 12 / 14 SECTION 14. TRANSPORT INFORMATION International Regulation Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Right To Know Water 7732-18-5 70 - 90 % Ethanol 64-17-5 10 - 20 % Propan-2-ol 67-63-0 0.1 - 1 % New Jersey Right To Know Water 7732-18-5 70 - 90 % Ethanol 64-17-5 10 - 20 % D-Glucitol, ethoxylated 53694-15-8 1 - 5 % Page 102 of 132 Page 102 of 132 Page 102 of 132 Page 102 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 13 / 14 California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: REACH : All ingredients (pre-)registered or exempt. TSCA : All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption. DSL : All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL). AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek OSHA Z-1 / TWA : 8-hour time weighted average Flammability Health Instability 2 2 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 2 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 103 of 132 Page 103 of 132 Page 103 of 132 Page 103 of 132 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 14 / 14 Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 03/30/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid- ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8 Page 104 of 132 Page 104 of 132 Page 104 of 132 Page 104 of 132 ---PAGE BREAK--- #19617 Page: 1 of 6 Issue date 11-February-2015 SAFETY DATA SHEET 1. Product and Company Identification Product identifier Sani-Cloth HB Germicidal Disposable Wipe SDS0042 Other means of identification Not available Recommended use Hard, Nonporous Surface Disinfectant Recommended restrictions For Professional and Hospital Use Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Address Professional Disposables International, Inc. Two Nice-Pak Park, Orangeburg, NY 10962-1376 Telephone 1-[PHONE REDACTED] (M-F 9am - 5pm) Emergency phone number 1-[PHONE REDACTED] 2. Hazards Identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Hazard symbol Not classified. Not classified. Not determined. Not classified. None. Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information Not applicable. 3. Composition/Information on Ingredients Mixtures Chemical name Common name and synonyms CAS number % ammonium chlorides Quaternary ammonium compounds, methyl, chlorides 68391-01-5 85409-23-0 0.07 0.07 4. First Aid Measures Inhalation Not a normal route of exposure. Skin contact If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centre or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Page 105 of 132 Page 105 of 132 Page 105 of 132 Page 105 of 132 ---PAGE BREAK--- #19617 Page: 2 of 6 Issue date 11-February-2015 Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Ingestion Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Most important acute and delayed Indication of immediate medical attention and special treatment needed Direct contact with eyes may cause temporary irritation. Treat patient General information If you feel unwell, seek medical advice (show the label where possible). Show this safety data sheet to the doctor in attendance. Avoid contact with eyes, skin and clothing. Keep out of reach of children. 5. Fire Fighting Measures Suitable extinguishing media Treat for surrounding material. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions None known. Firefighters should wear a self-contained breathing apparatus. Firefighters should wear full protective clothing including self contained breathing apparatus. In the event of fire, cool product with water spray. Specific methods Cool product exposed to flames with water until well after the fire is out. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Prevent entry into waterways, sewers or confined areas. Pick up and discard towel. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and Storage Precautions for safe handling Use good industrial hygiene practices in handling this material. Do not reuse towelette. Do not reuse the empty container. When using do not eat or drink. Conditions for safe storage, including any incompatibilities Store in a closed container away from incompatible materials. Store away from incompatible materials (see Section 10 of the SDS). Keep out of reach of children. 8. Exposure Controls/Personal Protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines This material does not have established exposure limits. Appropriate engineering controls Ensure adequate ventilation. Individual protection measures, such as personal protective equipment Eye/face protection Wear gear as deemed necessary. Follow label directions. Skin protection Hand protection Wear as deemed necessary, follow label directions. Other As required by employer code. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact. When using do not eat or drink. Page 106 of 132 Page 106 of 132 Page 106 of 132 Page 106 of 132 ---PAGE BREAK--- #19617 Page: 3 of 6 Issue date 11-February-2015 9. Physical and Chemical Properties Appearance Liquid saturated on wipe Physical state Solid. Form Liquid saturated on wipe Color White Odor Mild quat Odor threshold Not available. pH 10.75 (liquid) Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Pour point Not available. Specific gravity 1.0027 g/mL (liquid) Partition coefficient (n-octanol/water) Not available. Flash point > 212.0 °F 100.0 Tag Closed Cup (Liquid) Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Flammability limit - upper Not available. Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Wipe is not soluble Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. 10. Stability and Reactivity Reactivity May react with incompatible materials. Possibility of hazardous reactions Hazardous polymerization does not occur. Chemical stability Stable under recommended storage conditions. Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals. Contact with incompatible materials. Incompatible materials Acids. Oxidizers. Caustics. Hazardous decomposition products May include and are not limited to: Oxides of carbon. Chloride compounds Ammonia. 11. Toxicological Information Information on likely routes of exposure Ingestion Not applicable under normal conditions of use. Inhalation Health injuries are not known or expected under normal use. Skin contact Prolonged skin contact may cause skin irritation. Eye contact Health injuries are not known or expected under normal use. related to the physical, chemical and toxicological characteristics may include stinging, tearing, redness, swelling of the eyes, and blurred vision. may include redness, drying, defatting and cracking of the skin. may include stomach distress, nausea or vomiting. Information on toxicological effects Acute toxicity Page 107 of 132 Page 107 of 132 Page 107 of 132 Page 107 of 132 ---PAGE BREAK--- #19617 Page: 4 of 6 Issue date 11-February-2015 Components Species ammonium chlorides (CAS 68391-01-5) Acute Dermal LD50 Rat Inhalation LC50 Not available Oral LD50 Mouse Test Results 2000 mg/kg 1420 mg/kg 150 mg/kg Rat 240 mg/kg Quaternary ammonium compounds, chlorides (CAS 85409-23-0) Acute Dermal LD50 Not available Inhalation LC50 Not available Oral LD50 Rat 300 - 2000 mg/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Exposure minutes Not available. Erythema value Not available. Oedema value Not available. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Corneal opacity value Not available. Iris lesion value Not available. Conjunctival reddening value Not available. Conjunctival oedema value Not available. Recover days Not available. Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity Non-hazardous by OSHA criteria. Carcinogenicity Non-hazardous by OSHA criteria. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Non-hazardous by OSHA criteria. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Not classified. Not classified. Aspiration hazard Not classified. Chronic effects Non-hazardous by OSHA criteria. Further information This product has no known adverse effect on human health. 12. Ecological Information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. See below Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Mobility in soil No data available. Mobility in general Not available. Page 108 of 132 Page 108 of 132 Page 108 of 132 Page 108 of 132 ---PAGE BREAK--- #19617 Page: 5 of 6 Issue date 11-February-2015 Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal Considerations Disposal instructions Dispose of used towelette in trash. Do not flush in toilet. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code This product is not a hazardous waste. Waste from residues / unused products Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty packaging may be disposed in trash. 14. Transport Information U.S. Department of Transportation (DOT) Not regulated as dangerous goods. 15. Regulatory Information US federal regulations This product is NOT known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. PRECAUTIONARY STATEMENTS: Hazard to humans and domestic animals. CAUTION: Causes moderate eye irritation. Harmful if absorbed through skin. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or tobacco. Remove contaminated clothing and wash before reuse. EPA Reg. # 61178-4-9480 EPA Est. # 9480-NY-1. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely No hazardous substance SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Food and Drug Administration (FDA) Not regulated. Not regulated. US state regulations This product is not subject to warning labeling under the California Proposition 65 regulation. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. Page 109 of 132 Page 109 of 132 Page 109 of 132 Page 109 of 132 ---PAGE BREAK--- #19617 Page: 6 of 6 Issue date 11-February-2015 US - Texas Effects Screening Levels: Listed substance ammonium chlorides (CAS 68391-01-5) US. Massachusetts RTK - Substance List Not regulated. US. RTK - Hazardous Substances Not regulated. US. Rhode Island RTK Not regulated. Listed. Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) 16. Other Information Yes LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 HEALTH / 1 0 FLAMMABILITY 0 1 0 PHYSICAL HAZARD 0 PERSONAL X PROTECTION Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date 11-February-2015 Further information For any questions surrounding this SDS, please contact the supplier/manufacturer listed on the first page of the document. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Not for use on skin. Not a baby wipe. For use on hard surfaces only. Revision 0. Bulk Liquid # 4BQ08401. Other information This Safety Data Sheet was prepared to comply with the current OSHA Hazard Communication Standard (HCS) adoption of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Prepared by Dell Tech Laboratories, Ltd. Phone: (519) 858-5021 Page 110 of 132 Page 110 of 132 Page 110 of 132 Page 110 of 132 ---PAGE BREAK--- Material Safety Data Sheet: SHINE M UP AEROSOLSAMPLE, CAN CL Supercedes Date 02/23/2006 Issuing Date 11/18/2009 1. PRODUCT AND COMPANY IDENTIFICATION Product Name SHINE M UP AEROSOLSAMPLE, CAN CL Product Code 5056 Recommended Use Cleaning agent Chemical Nature Aerosol Information on Manufacturer Emergency Telephone Number CERTIFIED LABS, DIV. OF NCH CORP. CHEMTREC ® [PHONE REDACTED] BOX 152170 IRVING, TEXAS 75015 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION May be harmful if inhaled May cause skin irritation May cause eye irritation May be harmful if swallowed Contents under pressure Color Off-white Physical State Liquid Odor Ammoniacal Potential Health Effects Principle Route of Exposure Skin contact, Eye contact, Inhalation. Primary Routes of Entry Inhalation Acute Effects Eyes May cause eye irritation. Skin May cause skin irritation. Inhalation May cause irritation of respiratory tract. Inhalation may cause central nervous system effects. and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Chronic Toxicity Occupational health effects due to inhalation of mineral dusts incorporating silica (quartz, cristobalite, tridymite), silicates (kaolin, talc) graphite or coal, Kidney injury may occur, May cause cancer after repeated inhalation of spray or dust. Target Organ Effects Eyes, Skin, Respiratory system, Central nervous system, Heart, Liver, Kidney, Lungs. Aggravated Medical Conditions Respiratory disorders, Skin disorders, Liver disorders, Kidney disorders, Heart disease. Potential Environmental Effects See Section 12 for additional Ecological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No Silica (Quartz) 14808-60-7 Propane 74-98-6 Butane 106-97-8 Ammonium tallate 68132-50-3 4. FIRST AID MEASURES General Advice Avoid contact with skin, eyes, and clothing. Avoid breathing vapors, mist, or gas. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists. Skin Contact Wipe up with absorbent material (e.g. cloth, fleece). Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use. Inhalation If inhaled, remove to fresh air. Get medical attention if occur. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if occur. Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Flash Point >212°F/>100°C Method Seta closed cup Autoignition Temperature No information available. Flammability Limits in Air % Propellant. Upper 1.8 Lower 9.5 Suitable Extinguishing Media Foam. Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific Hazards Arising from the Chemical Solvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Material can create slippery conditions. Flame extension: 0 inches / 0 cm and Burnback: 0 inches / 0 cm. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Aerosol Level (NFPA 30B) - 1 NFPA Health 2 Flammability 1 Instability 0 HMIS Health 2 Flammability 1 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes, and clothing. Remove all sources of ignition. Environmental Precautions Prevent further leakage or spillage if safe to do so. Page 1 / 4 Page 111 of 132 Page 111 of 132 Page 111 of 132 Page 111 of 132 ---PAGE BREAK--- Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Pick up and transfer to properly labeled containers. Neutralizing Agent Not applicable. 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes, and clothing. Avoid breathing dust/fume/gas/mist/vapours/spray. Contents under pressure. Do not puncture. Storage Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Storage Temperature Minimum 35°F/2°C Maximum 120°F/49°C Storage Conditions Indoor X Outdoor Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH Silica (Quartz) TWA: 0.025 mg/m3 No data available IDLH: 50 mg/m3 TWA: 0.05 mg/m3 Propane TWA: 1000 ppm TWA: 1800 mg/m3 TWA: 1000 ppm IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Butane TWA: 1000 ppm No data available TWA: 1900 mg/m3 TWA: 800 ppm Ammonium tallate No data available No data available No data available Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection For prolonged or repeated contact, use protective gloves Respiratory Protection In case of inadequate ventilation wear respiratory protection. General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity Viscous Color Off-white Odor Ammoniacal Appearance Opaque pH @10% -10 Specific Gravity 1.180 Evaporation Rate 12.3 (Butyl acetate=1) Percent Volatile (Volume) 76.4 VOC Content 6.5 VOC Photoreactive (Y/N) Yes Vapor Pressure 136.9 mmHg @ 70 °F Vapor Density 1.3 (Air = 1.0) Solubility Completely soluble Boiling Point/Range 212°F/100°C 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Hazardous polymerization does not occur. Conditions to Avoid Heat, flames, and sparks. Incompatible Products Oxidizing agents, Acids, Highly halogenated compounds, Fluorinated hydrocarbons. Hazardous Decomposition Products Carbon oxides, Nitrogen oxides (NOx). Possibility of Hazardous Reactions Dangerous fumes form when mixed with other products. Chlorine. 11. TOXICOLOGICAL INFORMATION Product Information No information available. Component Information Acute toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other Silica (Quartz) 500 mg/kg ( Rat ) no data available no data available no data available no data available Propane no data available no data available 658 mg/L ( Rat ) 4 h no data available no data available Butane no data available no data available 658 mg/L ( Rat ) 4 h no data available no data available Ammonium tallate no data available no data available no data available no data available no data available Chronic Toxicity Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects Silica (Quartz) no data available no data available no data available no data available eyes, respiratory system (in animals: lung cancer) Propane no data available no data available no data available no data available CNS Butane no data available no data available no data available no data available CNS Ammonium tallate no data available no data available no data available no data available no data available Carcinogenicity Component ACGIH IARC NTP OSHA Other Silica (Quartz) A2 Group 1 Known X not applicable Propane not applicable not applicable not applicable not applicable not applicable Butane not applicable not applicable not applicable not applicable not applicable Ammonium tallate not applicable not applicable not applicable not applicable not applicable 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Page 2 / 4 Page 112 of 132 Page 112 of 132 Page 112 of 132 Page 112 of 132 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Product Information No information available. Component Information Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow Silica (Quartz) no data available no data available no data available no data available N/A Propane no data available no data available no data available no data available 2.3 Butane no data available no data available no data available no data available 2.89 Ammonium tallate no data available no data available no data available no data available N/A Persistence and Degradability No information available. Bioaccumulation No information available. Mobility No information available. 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations. Container Disposal Contents under pressure. Do not puncture. Empty remaining contents. Empty containers should be taken for local recycling, recovery or waste disposal. 14. TRANSPORT INFORMATION DOT DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity ,ORM-D TDG Proper shipping name Aerosols Hazard Class 2.1 UN-No UN1950 Description AEROSOLS,2.1,UN1950, LTD QTY ICAO UN-No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 Shipping Description Aerosols,UN1950, LTD QTY IATA UN-No UN1950 Proper Shipping Name Aerosols, flammable Hazard Class 2.1 ERG Code 10L Shipping Description UN1950,Aerosols, flammable,2.1, LTD QTY IMDG/IMO Proper Shipping Name Aerosols Hazard Class 2 UN-No UN1950 EmS No. F-D, S-U Shipping Description UN1950, Aerosols,2, LTD QTY 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard Yes Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs Silica (Quartz) Not applicable Not applicable Propane Not applicable Not applicable 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Page 3 / 4 Page 113 of 132 Page 113 of 132 Page 113 of 132 Page 113 of 132 ---PAGE BREAK--- Butane Not applicable Not applicable Ammonium tallate Not applicable Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class A Compressed gases, D2A Very toxic materials. 16. OTHER INFORMATION Prepared By Dan Hollas Supercedes Date 02/23/2006 Issuing Date 11/18/2009 Reason for Revision No information available. Glossary No information available. List of References. No information available. CERTIFIED LABS, DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Page 4 / 4 Page 114 of 132 Page 114 of 132 Page 114 of 132 Page 114 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Antistatic agents Liquid. Chemtrec - 1-[PHONE REDACTED] CANTUC (Canadian Transportation): (613) 996-6666 Emergency phone: (800) 858-4043 24/7 SAFETY DATA SHEET GHS product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Supplier's details : Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152 Tel. [PHONE REDACTED] or toll free [PHONE REDACTED] Static Free™ Hand Guard™ Relevant identified uses of the substance or mixture and uses advised against Not applicable. Section 2. Hazards identification Not classified. Classification of the substance or mixture : Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 82.5% OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Other means of identification : Antistatic agents CAS number : Not applicable. Substance/mixture Product code : C805 CAS number/other identifiers : Mixture Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 1/11 Page 115 of 132 Page 115 of 132 Page 115 of 132 Page 115 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 3. Composition/information on ingredients stearic acid 1 - 5 57-11-4 glycerol 1 - 2 56-81-5 octadecan-1-ol 1 - 2 112-92-5 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Description of necessary first aid measures Specific treatments : No specific treatment. Most important acute and delayed Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Harmful if swallowed. : Ingestion Skin contact : No known significant effects or critical hazards. May cause eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. Adverse may include the following: nausea or vomiting diarrhea No specific data. : : : Eye contact : Adverse may include the following: irritation redness watering Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 2/11 Page 116 of 132 Page 116 of 132 Page 116 of 132 Page 116 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 3/11 Page 117 of 132 Page 117 of 132 Page 117 of 132 Page 117 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : glycerol OSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust OSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 10 mg/m³ 8 hours. Form: Total dust Section 8. Exposure controls/personal protection Ingredient name Exposure limits Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 4/11 Page 118 of 132 Page 118 of 132 Page 118 of 132 Page 118 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Viscous liquid.] 0°C (32°F) 1 Not available. Not available. Not available. Pleasant. Odor pH White. Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Not available. Not available. 7.2 Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : 100°C (212°F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity stearic acid LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 4600 mg/kg - glycerol LD50 Oral Rat 12600 mg/kg - octadecan-1-ol LD50 Oral Rat >5000 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Information on toxicological effects Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 5/11 Page 119 of 132 Page 119 of 132 Page 119 of 132 Page 119 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. stearic acid Skin - Mild irritant Human - 72 hours 75 milligrams Intermittent - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - glycerol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - octadecan-1-ol Eyes - Mild irritant Rabbit - 24 hours 100 milligrams - Skin - Mild irritant Man - 48 hours 30 Percent - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on the likely routes of exposure Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Harmful if swallowed. : Ingestion Skin contact : No known significant effects or critical hazards. May cause eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Inhalation No specific data. No specific data. : : Eye contact : Adverse may include the following: irritation redness watering Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. : Not available. Potential acute health effects Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 6/11 Page 120 of 132 Page 120 of 132 Page 120 of 132 Page 120 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 11. Toxicological information Not available. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Ingestion Adverse may include the following: nausea or vomiting diarrhea : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 26833.3 mg/kg Dermal 58333.3 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name stearic acid 8.23 238 to 288 low glycerol -1.76 - low octadecan-1-ol 7.4 - high Toxicity Not available. Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 7/11 Page 121 of 132 Page 121 of 132 Page 121 of 132 Page 121 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Section 14. Transport information - - - - - - - Not regulated. - - Not regulated. Not regulated. - - - DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : TDG Classification Not regulated. - - - No. - ADR/RID Not regulated. - - - No. - Mexico Classification Not regulated. - - - No. - Section 15. Regulatory information U.S. Federal regulations : Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed TSCA 8(a) CDR Exempt/Partial exemption: Not determined Commerce control list precursor: 2,2',2''-nitrilotriethanol Not determined. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 8/11 Page 122 of 132 Page 122 of 132 Page 122 of 132 Page 122 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 15. Regulatory information The following components are listed: TRIETHANOLAMINE; GLYCERINE MIST WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. Massachusetts : retinyl palmitate Yes. No. No. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level California Prop. 65 DEA List II Chemicals (Essential Chemicals) : Not listed New York : None of the components are listed. New Jersey : The following components are listed: TRIETHANOLAMINE; ETHANOL, NITRILOTRIS-; GLYCERIN; 1,2,3-PROPANETRIOL; PROPYLENE GLYCOL; 1, 2-PROPANEDIOL : The following components are listed: ETHANOL, 2,2',2"-NITRILOTRIS-; 1,2, 3-PROPANETRIOL; 1,2-PROPANEDIOL State regulations SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Not applicable. stearic acid 1 - 5 Yes. No. No. Yes. No. glycerol 1 - 2 No. No. No. Yes. No. octadecan-1-ol 1 - 2 No. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. Triethanolamine Schedule III Listed Ingredient name List name Status UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. International lists National inventory Australia : All components are listed or exempted. Canada : All components are listed or exempted. China : All components are listed or exempted. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 9/11 Page 123 of 132 Page 123 of 132 Page 123 of 132 Page 123 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 15. Regulatory information Europe : Not determined. Japan : Not determined. Republic of Korea : Not determined. Malaysia : Not determined. New Zealand : All components are listed or exempted. Philippines : All components are listed or exempted. Taiwan : Not determined. Section 16. Other information 5/18/2015. History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 5/18/2015. No previous validation. 1 Hazardous Material Information System 0 0 0 0 0 0 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 10/11 Page 124 of 132 Page 124 of 132 Page 124 of 132 Page 124 of 132 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 11/11 Page 125 of 132 Page 125 of 132 Page 125 of 132 Page 125 of 132 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 Safety Data Sheet 1. Identification Product Information: M282-3928 Product Name: ULTRA® MARK ICELAND DAWN Recommended Use: Surface Preparation or Protection Mohawk Finishing Products Division of RPM Wood Finishes Group, Inc. 22 South Center Street Hickory, NC 28602 USA Supplied by: Company Phone No: (800) 522-8266 Emergency Phone No. CHEMTREC: (800) 424-9300 (703) 527-3887 (Collect calls are accepted) International Emergency No. CHEMTREC: 2. Hazards Identification GHS Classification Carc. 1B, Eye Dam. 1, Flam. Liq. 2, Muta. 1B, Skin Irrit. 2 Symbol(s) of Product Signal Word Danger GHS HAZARD STATEMENTS Flammable Liquid, category 2 H225 Highly flammable liquid and vapour. Skin Irritation, category 2 H315 Causes skin irritation. Serious Eye Damage, category 1 H318 Causes serious eye damage. Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Carcinogenicity, category 1B H350 May cause cancer. GHS LABEL PRECAUTIONARY STATEMENTS P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container closed. P264 Wash hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Page 1 / 7 Page 126 of 132 Page 126 of 132 Page 126 of 132 Page 126 of 132 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. GHS SDS PRECAUTIONARY STATEMENTS P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. 3. Composition/Information on ingredients Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements ethanol 64-17-5 40-55 GHS02 H225 butanol 71-36-3 10-25 GHS02-GHS05- GHS07 H226-302-315-318-332-335-336 pm acetate 108-65-6 10-25 GHS02-GHS07 H226-332 titanium dioxide 13463-67-7 2.5-10 No Information No Information isopropanol 67-63-0 1.0-2.5 GHS02-GHS07 H225-302-319-336 carbon black 1333-86-4 1.0-2.5 GHS02 H251 aliphatic hydrocarbons 8052-41-3 0.1-1.0 GHS08 H304-340-350-372 aliphatic petroleum distillates 64742-88-7 0.1-1.0 GHS06-GHS08 H304-331-372 100-41-4 0.1-1.0 GHS02-GHS07- GHS08 H225-304-332-373 The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section. 4. First-aid Measures FIRST AID - EYE CONTACT: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. FIRST AID - SKIN CONTACT: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. FIRST AID - INGESTION: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. FIRST AID - INHALATION: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. 5. Fire-fighting Measures SPECIAL FIREFIGHTING PROCEDURES: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly Page 2 / 7 Page 127 of 132 Page 127 of 132 Page 127 of 132 Page 127 of 132 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. FIREFIGHTING EQUIPMENT: This is a NFPA/OSHA Class 1B or less flammable liquid. Follow NFPA30, Chapter 16 for fire protection and fire suppression. Use a dry chemical, carbon dioxide, or similar ABC fire extinguisher for incipeint fires. Water may be used to cool and prevent rupture of containers that are exposed to heat from fire. 6. Accidental Release Measures ENVIRONMENTAL MEASURES: No Information STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage system or open waterways. 7. Handling and Storage HANDLING: Avoid inhalation and contact with eyes, skin, and clothing. Wash hands thoroughly after handling and before eating or drinking. In keeping with safe handling practices, avoid ignition sources (smoking, flames, pilot lights, electrical sparks); ground and bond containers when transferring the material to prevent static electricity sparks that could ignite vapor and use spark proof tools and explosion proof equipment. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can potentially cause an explosion that may lead to injury. STORAGE: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. 8. Exposure Controls/Personal Protection Ingredients with Occupational Exposure Limits Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING ethanol N.D. 1000 ppm 1000 ppm N.D. butanol 20 ppm N.D. 100 ppm N.D. pm acetate N.D. N.D. N.D. N.D. titanium dioxide 10 mg/m3 N.D. 15 mg/m3 N.D. isopropanol 200 ppm 400 ppm 400 ppm N.D. carbon black 3 mg/m3 N.D. 3.5 mg/m3 N.D. aliphatic hydrocarbons 100 ppm N.D. 500 ppm N.D. aliphatic petroleum distillates N.D. N.D. N.D. N.D. 20 ppm N.D. 100 ppm N.D. Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation Sk = Skin Sensitizer N.E. = Not Established N.D. = Not Determined Personal Protection RESPIRATORY PROTECTION: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying Page 3 / 7 Page 128 of 132 Page 128 of 132 Page 128 of 132 Page 128 of 132 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 respirators may not provide adequate protection. SKIN PROTECTION: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. EYE PROTECTION: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. OTHER PROTECTIVE EQUIPMENT: No Information HYGIENIC PRACTICES: It is good practice to avoid contact with the product and/or its vapors, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. 9. Physical and Chemical Properties Colored Liquid LIQUID Appearance: Physical State: Moderately Strong Alcohol Not determined Odor: Odor Threshold: 0.916 Not determined Density, g/cm3: pH: Not determined Not determined Freeze Point, Viscosity: Not determined Partition Coefficient, n-octanol/ water: Not determined Solubility in Water: Not determined Not determined Decomposition temperature, Explosive Limits, > 100 °F 55 ° F Boiling Range, Flash Point, Supports Combustion Not determined Combustibility: Auto-Ignition Temperature, Faster than Diethyl Ether Not determined Evaporation Rate: Vapor Pressure, mmHg: Not determined Vapor Density: N.I. = No Information 10. Stability and reactivity STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Heat, flames and sparks. INCOMPATIBILITY: Acids, Bases, Oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: Not determined. Page 4 / 7 Page 129 of 132 Page 129 of 132 Page 129 of 132 Page 129 of 132 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 11. Toxicological information Practical Experiences EMERGENCY OVERVIEW: No Information EFFECT OF OVEREXPOSURE - EYE CONTACT: No Information EFFECT OF OVEREXPOSURE - INGESTION: No Information EFFECT OF OVEREXPOSURE - INHALATION: No Information EFFECT OF OVEREXPOSURE - SKIN CONTACT: No Information CARCINOGENICITY: May cause cancer. This product contains Titanium Dioxide, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This classification is relevant when exposed to titanium dioxide in dust or powder form only, including cured product that is subject to sanding, grinding, cutting, or other surface preparation activities. PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Skin Contact Acute Toxicity Values The acute effects of this product have not been tested. Data on individual components are tabulated below CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 64-17-5 ethanol 7060 mg/kg Rat N.I. 124.7 mg/L Rat 71-36-3 butanol 700 mg/kg Rat 3402 mg/kg Rabbit 8000 mg/l Rat 108-65-6 pm acetate 8532 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L 13463-67-7 titanium dioxide >10000 mg/kg Rat >10000 mg/kg Rabbit >20 mg/l 67-63-0 isopropanol 1870 mg/kg Rat 4059 mg/kg Rabbit 72.6 mg/L Rat 1333-86-4 carbon black >5000 mg/kg Rat >3000 mg/kg Rabbit >20 mg/l 8052-41-3 aliphatic hydrocarbons >5000 mg/kg Rat >3160 mg/kg Rat 21 mg/L Rat 64742-88-7 aliphatic petroleum distillates >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat 100-41-4 3500 mg/kg Rat 15400 mg/kg Rabbit 17.2 mg/L Rat N.I. = No Information 12. Ecological information ECOLOGICAL INFORMATION: Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. 13. Disposal Information Product DISPOSAL METHOD: Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, Page 5 / 7 Page 130 of 132 Page 130 of 132 Page 130 of 132 Page 130 of 132 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage system or open waterways. 14. Transport Information SPECIAL TRANSPORT PRECAUTIONS: No Information DOT: CONSUMER COMMODITY IATA: ID8000, CONSUMER COMMODITY, 9 IMDG: LIMITED QUANTITY UN1263 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Fire Hazard, Acute Health Hazard, Chronic Health Hazard SARA SECTION 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. butanol 71-36-3 isopropanol 67-63-0 TOXIC SUBSTANCES CONTROL ACT This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA components exist in this product. U.S. State Regulations: CALIFORNIA PROPOSITION 65 CARCINOGENS WARNING: This product contains a chemical known to the State of California to cause cancer. CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Page 6 / 7 Page 131 of 132 Page 131 of 132 Page 131 of 132 Page 131 of 132 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 16. Other Information 5/16/2015 Supersedes Date: Revision Date: 7/4/2015 Reason for revision: Product Composition Changed Datasheet produced by: Regulatory Department HMIS Ratings: Health: 2 Flammability: 3 Reactivity: 0 Personal Protection: X Volatile Organic Compounds, gr/ltr: 683 Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H251 Self-heating: may catch fire. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS02 GHS05 GHS06 GHS07 GHS08 The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions and recommendations are not followed. 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