Document douglascountywi_gov_doc_4a6ba77d36

Safety Data Sheets Maintenance - Court House/ Boiler Room Maintenance - Court House / Boiler Room 11/16/2015 ---PAGE BREAK--- Safety Data Sheet Index Binder: Maintenance - Court House / Boiler Room - Maintenance - Court House/ Boiler Room #271 RAID ROACH & ANT KILLER AND TREATMENT S.C. Johnson & Son, Inc. 04/18/2007 7 1404 3M Super 77 Multipurpose Adhesive (Aerosol) FIBRE GLAST DEVELOPMENTS CORPORATION 10/01/2008 11 460-S0222 (SOLN P Indicator Form Liquid) Nalco Company 01/26/2015 20 Acetone - Klean Strip 67-64-1 W.M. BARR & COMPANY - KLEAN-STRIP DIVISION 05/18/2005 30 Advanced Low VOC Interior Latex Semi-Gloss Paint, Ultradeep Base THE SHERWIN-WILLIAMS COMPANY 03/05/2015 35 AIRCRAFT PAINT REMOVER W.M. BARR & COMPANY - KLEAN-STRIP DIVISION 10/01/1985 39 All Purpose Cement Oatey Company 05/20/2004 42 Alpha HP Multi-Surface Cleaner Fragrance Free (1:64 use solution) JohnsonDiversey 03/12/2007 47 Alpha-HP Multi-Surface Cleaner Johnson Wax Professional 06/17/2004 50 ben PREMIUM INTERIOR LATEX EGGSHELL FINISH BENJAMIN MOORE & COMPANY 04/30/2014 54 Black Flag Dry Max Spray Kills Ants Roaches Spiders Kills Biting Asian Beetles BLACK FLAG BRANDS, LLC 10/24/2004 63 BOILERCARE 1012 Ecolab - Water Care Division 10/03/2005 69 Boilercare 1504 Ecolab 01/14/2008 72 BOILERCARE 1504 Ecolab Inc. 02/09/2015 76 BRAKE CLEANER, NON-CHLORINATED AEROSOL ZECOL PRODUCTS COMPANY 01/01/2002 84 Brakleen (Aerosol) CRC INDUSTRIES (AUST) PTY LIMITED 04/01/2010 86 BROMICIDE TABLETS BWA Water Additives US LLC 03/04/2015 91 BRRR-Eaker Drummond American, A Lawson Products Company 09/04/2009 100 BRRR-Eaker Drummond, A Lawson Brand 07/19/2012 107 BRRR-Eaker Drummond, A Lawson Brand 07/19/2012 111 Cannonball Cleaner & Degreaser TRI-CHEM CORPORATION 04/12/2013 115 Product Name CAS Number Manufacturer Version Date Page Page 2 of 495 Page 2 of 495 Page 2 of 495 Page 2 of 495 ---PAGE BREAK--- Carpet and Spot Stain Remover Rubbermaid 07/16/2015 117 CHB Interior Latex Flat Wall Paint, Williamsburg Off White THE SHERWIN-WILLIAMS COMPANY 01/09/2013 119 Chemsearch Naturalizer multi-purpose remover Chemsearch 123 Chlorinating Tablets Utikem 128 CLEAN STRIKE MULTIPURPOSE CLEANER Ecolab Inc. 07/25/2014 132 Clean Strike Restroom CLeaner and Disinfectant Clean Strike 142 Clear Out State Chemical Manufacturing Company 01/01/2006 148 Clear Silicone Adhesive Sealant Loctite Corporation 08/10/1999 154 Cool-It Lawson Products, Inc. 05/02/2014 157 DR-OP Drain Opener SHARE CORPORATION 03/08/2007 161 DR-OP Drain Opener SHARE CORPORATION 03/08/2007 163 DTM Acrylic Coating Semi-Gloss (Waterborne), Pure White THE SHERWIN WILLIAMS COMPANY 01/25/2005 165 DURA CLEAN Ceiling Interior Enamel Paint DUTCH BOY 11/15/2013 170 DURA CLEAN Semi-Gloss Interior Latex Kitchen & Bath Enamel, Base A DUTCH BOY 12/16/2013 174 Durham’s Rock Hard Water Putty DONALD DURHAM COMPANY, INC. 05/16/2015 178 ELMERS CARPENTERS WOOD GLUE Elmer's Products, Inc. 03/04/2009 184 GARDENTECH SEVIN READY-TO-SPRAY BUG KILLER TechPac, LLC. 01/01/2015 191 GLANCE NA Johnson Wax Professional 07/25/2007 203 GOO GONE PAINTER’S PAL MAGIC AMERICAN PRODUCTS, INC. 04/29/2006 206 GREAT STUFF Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO The Dow Chemical Company 01/31/2008 207 GREAT STUFF Pro Gun Cleaner The Dow Chemical Company 09/27/2013 220 Green Envy Driveway Cleaner & Degreaser SUNNYSIDE CORPORATION 08/26/2008 230 HSP Gloss Black Lawson Products, Inc. 09/27/2013 233 Industrial Enamel – VOC Complying, Pure White THE SHERWIN WILLIAMS COMPANY 03/02/2010 237 Industrial Enamel, Pure White THE SHERWIN WILLIAMS COMPANY 03/05/2015 241 Instant Tire Inflator Zecol 245 Product Name CAS Number Manufacturer Version Date Page Page 3 of 495 Page 3 of 495 Page 3 of 495 Page 3 of 495 ---PAGE BREAK--- Interior/Exterior Acrylic Latex Gloss Finish, 5 White THE SHERWIN WILLIAMS COMPANY 04/18/2007 247 KEM KROMIK Universal Metal Primer (VOC Comp.), Brown THE SHERWIN WILLIAMS COMPANY 01/30/2010 252 KRUD KUTTER Concrete & Driveway Cleaner SUPREME CHEMICALS OF GEORGIA, INC. 08/10/2007 258 KRUD KUTTER Concrete Clean and Etch SUPREME CHEMICALS OF GEORGIA, INC. 08/28/2007 264 KRYLON LINE-UP Striping Paint (Solvent Based), Highway Yellow THE SHERWIN WILLIAMS COMPANY 06/06/2007 272 LECTRA SOL TC (AEROSOL) TRI-CHEM CORPORATION 06/19/2012 278 Light Oil Lubricant Lawson Products, Inc. 05/28/2013 280 Liquid Wrench Lubricating Oil RSC Chemical Solutions 05/18/2015 284 LIQUID WRENCH SUPER LUBRICANT Radiator Specialty Company 02/12/1991 292 LiteTak 3751 Adhesive Loctite Corporation 01/27/1999 296 Lock De-Icer & Lubricant 67-63-0 VICTOR AUTOMOTIVE PRODUCTS INC 01/01/2000 302 Lock- Lube Lawson Products, Inc. 03/10/2014 305 Loctite Power Grab All Purpose Adhesive HENKEL CONSUMER ADHESIVES 02/01/2009 308 mineral spirits SUNNYSIDE CORPORATION 05/20/2005 312 Motor Tune / Seafoam Motor Treatment EMCO Chemical Distributors, Inc. 10/02/2014 315 MP HD Heavy Duty Metal Protector (Aerosol) Amsoil, Inc. 09/26/2007 321 Multibrom Tablets 32718-18-6 Ecolab - Water Care Division 04/22/2009 325 New Ceiling Tile Paint White Lawson Products, Inc. 09/27/2013 329 NPI Gun-Grade Polyurethane Sealant NPI 333 NU-KOTE CHEMSEARCH - A DIVISION OF NCH CORPORATION 03/06/2002 340 Oatey-Purple Primer/Cleaner Oatey Company 05/20/2005 344 Onetime Lighten Up Spackling Compound Red Devil, Inc. 06/24/2004 349 ORANGE TOUGH 15 Spartan Chemical Company 09/22/2008 352 PEAK Long Life Antifreeze Old World Industries, Inc. 07/20/2009 356 Pitt-Cryl PLUS Exterior Wood and Stucco Satin 100% Acrylic Latex - 10-1410 Series PITTSBURGH PAINTS 02/01/2006 368 PROMAR 200 Interior Latex Eg-Shel Enamel, Extra White THE SHERWIN WILLIAMS COMPANY 03/05/2010 370 Product Name CAS Number Manufacturer Version Date Page Page 4 of 495 Page 4 of 495 Page 4 of 495 Page 4 of 495 ---PAGE BREAK--- Propane Worthington Cylinders Worthington 07/16/2015 374 Quaker State Advanced Durability SAE 5W-30 Motor Oil Shell Oil Products US 02/05/2014 382 RUST STRIPPER Rust-Oleum Corporation 10/09/2013 391 Rustoleum Epoxy gloss white appliance spray paint Rustoleum 07/16/2015 395 SAIRSET DC ANH Refractories Company 04/21/2009 402 Sprayway Duster Sprayway, Inc. 09/14/2006 409 STATIC GUARD ANTISTATIC SPRAY Alberto-Culver USA, Inc. 03/03/2010 416 STICK•EASE SEAM ADHESIVE Roman Decorating Products 12/18/2001 421 Stride Citrus HC Neutral Cleaner JohnsonDiversey 06/24/2009 423 SUPER HPO MOTOR OIL SAE 40 Valvoline Company 01/14/2002 426 SUPER IRON OUT IRON OUT, INC. 08/22/2008 432 TANGLEFOOT TREE PRUNING SEALER - AEROSOL TANGLEFOOT CO THE 03/01/2009 439 Tef-Coat Lube Lawson Products, Inc. 02/04/2011 441 Tefgel Lawson Products, Inc. 09/17/2014 445 UNITED 101 MOISTURE BARRIER United Laboratories Inc. 02/06/2015 449 UNITED 107 AEROSOL SAFETY SOLVENT United Laboratories Inc. 08/18/2008 451 UNITED 107 AEROSOL SAFETY SOLVENT United Laboratories Inc. 06/03/2015 453 UNITED 107 AEROSOL SAFETY SOLVENT United Laboratories Inc. 02/21/2012 454 United 125 ALL STICK Waterproof Heavy Duty Adhesive Spray United Laboratories Inc. 09/19/2002 456 United 190 UP WHITE Acoustical Ceiling Tile Whitener United Laboratories Inc. 03/17/2003 458 United 199 EVERLAST Rubberized Coating United Laboratories Inc. 03/17/2003 460 Vinyl Spackling Compound Red Devil, Inc. 03/06/2012 462 Water Wash Brush Cleaner WILSON IMPERIAL CO 10/13/1993 465 WHITE LIGHTENING J.W. ETC, INC. 04/14/1993 469 White Lightning Flame Buster High Heat Silicone Sealant, Limestone Sherwin-Williams Company 05/15/2007 473 WINDEX FOAMING GLASS & SURFACE CLEANER S.C. Johnson & Son, Inc. 09/28/2012 478 Windshield De-Icer Lawson Products, Inc. 10/30/2014 486 Product Name CAS Number Manufacturer Version Date Page Page 5 of 495 Page 5 of 495 Page 5 of 495 Page 5 of 495 ---PAGE BREAK--- Product Name CAS Number Manufacturer Version Date Page Zinsser Bulls Eye 123 Primer William Zinsser and Company, Inc. 04/15/2005 490 Page 6 of 495 Page 6 of 495 Page 6 of 495 Page 6 of 495 ---PAGE BREAK--- Page 7 of 495 Page 7 of 495 Page 7 of 495 Page 7 of 495 ---PAGE BREAK--- Page 8 of 495 Page 8 of 495 Page 8 of 495 Page 8 of 495 ---PAGE BREAK--- Page 9 of 495 Page 9 of 495 Page 9 of 495 Page 9 of 495 ---PAGE BREAK--- Page 10 of 495 Page 10 of 495 Page 10 of 495 Page 10 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR FIBRE GLAST DEVELOPMENTS CORP. 385 CARR DRIVE BROOKVILLE, OH 45309 TELEPHONE: (937) 833-5200 FAX: (937) 833-6555 FOR CHEMICAL EMERGENCY CALL (800) 424-9300 24 HRS. SECTION 1 - PRODUCT IDENTIFICATION PRODUCT NAME: #1404 3M ™ SUPER 77™ Multipurpose Adhesive (Aerosol) PRODUCT USE: Intended Use: General purpose aerosol adhesive Specific Use: General purpose aerosol adhesive SECTION 2 - INGREDIENTS Ingredient C.A.S. NO. % byWt. Hydrotreated Light Naphtha (Petroleum) 64742-49-0 15-40 Cyclohexane 110-82-7 10-30 Non-Volatile Ingredients – N.J.T.S. Reg No. 04499600-5776P Trade Secret 10-30 Dimethyl Ether 115-10-6 10-30 Propane 75-28-5 3-7 Isobutane 75-28-5 3-7 Hexane 110-54-3 .01-1 SECTION 3 – HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Odor, Color, Grade: red, solvent odor General Physical Form: Gas Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Page 11 of 495 Page 11 of 495 Page 11 of 495 Page 11 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: may include redness, pain, and tearing. Skin contact: Moderate Skin Irritation: may include localized redness, swelling, itching and dryness. May be absorbed through skin and cause target organ effects. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Peripheral Neuropathy: may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4 – FIRST AID MEASURES FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Page 12 of 495 Page 12 of 495 Page 12 of 495 Page 12 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR Eye Contact: Flush eyes with large amounts of water. If persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5 – FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -42.00°F (Test Method: Tagliabue Closed Cup) Flammable Limits – LEL 1.2% volume Flammable Limits – UEL 27% volume EXTHINGUISHING MEDIA Use fire extinguishers with glass B extinguishing agents dry chemical, carbon dioxide). PROTECTION OF FIRE FIGHTERS. Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers expose to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition sources and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. Page 13 of 495 Page 13 of 495 Page 13 of 495 Page 13 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR SECTION 6 – ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of the MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364- 3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The Spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. Working from around edges and spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spill as possible using non-sparking tools. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state and federal regulations. SECTION 7 – HANDLING AND STORAGE HANDLING Do no eat, drink, or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray near flames or source of ignition. Avoid eye contact with vapors, mists or spray. Keep out of the reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors – open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks and open flame. Do not smoke or ignite matches, lighters, etc. STORAGE Store away from heat. Store out of direct sunlight. Keep in well ventilated area. Keep container closed. Store away from oxidizing agents. Page 14 of 495 Page 14 of 495 Page 14 of 495 Page 14 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS Use with functioning spray booth and local exhaust. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protective equipment. PERSONAL PROTECTIVE EQUIPMENT (PPE) Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect vented Goggles. Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Polyethylene/Ethylene Vinyl Alcohol. Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminates and in accordance with OSHA regulations: Half face piece or full-face air-purifying respirator with organic vapor cartridge. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800- 243-4630 for 3M technical assistance. Organic vapor cartridges may have short service life. Prevention of Swallowing Do not eat, drink, or smoke when using this product. Wash exposed areas thoroughly with soap and water. EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information CYCLOHEXANE ACGIH TWA 100 ppm CYCLOHEXANE OSHA TWA 300 ppm Table Z-1 Dimethyl Ether AIHA TWA 1000 ppm Dimethyl Ether CMRG TWA 1000 ppm HEXANE ACGIH TWA 50 ppm Skin Notation* HEXANE OSHA TWA, vacated 50 ppm Table Z-1A HEXANE OSHA TWA 500 ppm Hydrotreated Light Naphtha (petroleum) CMRG TWA 50 ppm Isobutane ACGIH TWA 1000 ppm PROPANE ACGIH TWA 1000 ppm Page 15 of 495 Page 15 of 495 Page 15 of 495 Page 15 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR PROPANE OSHA TWA 1000 ppm Table Z-1 VAC Vacated PEL: Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGlH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AlHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: red, solvent odor General Physical Form: Gas Autoignition temperature No Data Available Flash Point -50.00°F [Test method: [Close Cup] Flammable Limits - LEL 1.2% volume Flammable Limits - UEL 27% volume Boiling point <=68°F Desity 0.736 g/ml Vapor Density >=1.0 [Ref Std: AIR=1] Specific Gravity 0.726 [Ref Std: WATER=1] pH No Data Available Melting point No Data Available Solubility in Water Nil Evaporation rate No Data Available Hazardous Air Pollutants 4.0 – 5.0% weight Volatile Organic Compounds 534 g/l [Test method:Calculated SCAQMD rule 443.1] VOC Less H2) & Exempt Solvents 534 g/l [Test method:Calculated SCAQMD rule 443.1] Viscosity Not Applicable Solids Content 20-30% SECTION 10 – STABILITY AND REACTITIVY Stability: Stable Materials and Conditions to Avoid: Heat; Sparks and/or flames * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. Page 16 of 495 Page 16 of 495 Page 16 of 495 Page 16 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Formaldehyde During Combustion Carbon monoxide During Combustion Carbon Dioxide During Combustion SECTION 11 – TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components SECTION 12 – ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION - Not Determined CHEMICAL FATE INFORMATION - Not Determined SECTION 13 – DISPOSAL CONSIDERATIONS WASTE DIPOSAL METHOD Incinerate uncured product in a permitted hazardous waste incinerator. Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. The facility should be equipped to handle gaseous waste. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14 – TRANSPORATION INFORMATION Since regulations vary, consult applicable regulations or authorities before disposal Page 17 of 495 Page 17 of 495 Page 17 of 495 Page 17 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR ID Number(s): 62-4976-8030-6, 62-4979-8830-9 SECTION 15- REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories Fire Hazard – Yes Pressure Hazard – Yes Reactivity Hazard – No Immediate Hazard – Yes Delayed Hazard – Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt CYCLOHEXANE 110-82-7 10-30 This material contains a chemical which requires export notification under TSCA section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status HEXANE 110-54-3 Toxic Substances Control Act (TSCA) 4 Test Rule Chemicals Applicable CYCLOHEXANE 110-82-7 Toxic Substance Applicable Control Act (TSCA) 4 Test Rule Chemicals STATE REGULATIONS Contac 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. INTERNATIONAL REGULATIONS Non hazardous according to WHMIS criteria. WHMIS: Non-hazardous This MSDS has been prepared to meet U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. Page 18 of 495 Page 18 of 495 Page 18 of 495 Page 18 of 495 ---PAGE BREAK--- PDCT-MSDS-00125-B-10/08-RR SECTION 16 – OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. No revision information is available. SECTION 17 - COMMENTS The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with Fibre Glast Developments or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their needs. Page 19 of 495 Page 19 of 495 Page 19 of 495 Page 19 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 1 / 10 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : 460-S0222 (SOLN P Indicator Form Liquid) Other means of identification : Not applicable. Recommended use : INDICATOR LIQUID Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits. Company : Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 USA TEL: (630)305-1000 Emergency telephone number : (800) 424-9300 (24 Hours) CHEMTREC Issuing date : 01/26/2015 Section: 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 2 Eye irritation : Category 2A Germ cell mutagenicity : Category 2 Carcinogenicity (Oral) : Category 1B Reproductive toxicity : Category 2 Specific target organ toxicity - single exposure : Category 2 (Eyes) GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : Highly flammable liquid and vapour. Causes serious eye irritation. Suspected of causing genetic defects. May cause cancer if swallowed. Suspected of damaging fertility or the unborn child. May cause damage to organs (Eyes). Precautionary Statements : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving Page 20 of 495 Page 20 of 495 Page 20 of 495 Page 20 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 2 / 10 equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/ eye protection/ face protection. Use personal protective equipment as required. Response: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/ attention. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Concentration: Ethanol 64-17-5 60 - 100 Methanol 67-56-1 5 - 10 77-09-8 1 - 5 Section: 4. FIRST AID MEASURES In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. In case of skin contact : Wash off with soap and plenty of water. Get medical attention if occur. If swallowed : Rinse mouth. Get medical attention if occur. If inhaled : Get medical attention if occur. Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders.Use personal protective equipment as required. Notes to physician : Treat Most important and effects, both acute and delayed : See Section 11 for more detailed information on health effects and Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Page 21 of 495 Page 21 of 495 Page 21 of 495 Page 21 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 3 / 10 Unsuitable extinguishing media : None known. Specific hazards during firefighting : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Special protective equipment for firefighters : Use personal protective equipment. Specific extinguishing methods : Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Flush away traces with water. Section: 7. HANDLING AND STORAGE Advice on safe handling : Avoid contact with skin and eyes. Open drum carefully as content may be under pressure. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Keep away from fire, sparks and heated surfaces. Wash hands thoroughly after handling. Use only with adequate ventilation. Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well- ventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container closed. Store in suitable labeled containers. Suitable material : The following compatibility data is suggested based on similar product data and/or industry experience: Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use. Unsuitable material : not determined Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page 22 of 495 Page 22 of 495 Page 22 of 495 Page 22 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 4 / 10 Components with workplace control parameters Components CAS-No. Form of exposure Permissible concentration Basis Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z1 Methanol 67-56-1 TWA 200 ppm ACGIH STEL 250 ppm ACGIH TWA 200 ppm 260 mg/m3 NIOSH REL STEL 250 ppm 325 mg/m3 NIOSH REL TWA 200 ppm 260 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Safety glasses with side-shields Hand protection : Wear protective gloves. Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Wear suitable protective clothing. Respiratory protection : No personal respiratory protective equipment normally required. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Liquid Colour : Colorless Odour : Alcoholic Flash point : 14 °C Method: ASTM D 56, Tag closed cup minimum pH : 8.8, 100 % Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling range : no data available Page 23 of 495 Page 23 of 495 Page 23 of 495 Page 23 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 5 / 10 Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 0.82 (25 Density : 6.81 lb/gal Water solubility : completely soluble Solubility in other solvents : no data available Partition coefficient: n- octanol/water : no data available Auto-ignition temperature : no data available Thermal decomposition temperature : no data available Viscosity, dynamic : no data available Viscosity, kinematic : no data available VOC : 95 % Section: 10. STABILITY AND REACTIVITY Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : Heat and sources of ignition including static discharges. Incompatible materials : Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes : Causes serious eye irritation. Skin : May cause numbness, weakness, shooting pain in stomach and/or extremities, and blindness. Ingestion : May cause numbness, weakness, shooting pain in stomach Page 24 of 495 Page 24 of 495 Page 24 of 495 Page 24 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 6 / 10 and/or extremities, and blindness. Inhalation : Health injuries are not known or expected under normal use. May cause numbness, weakness, shooting pain in stomach and/or extremities, and blindness. High vapor concentrations can cause headaches, dizziness, drowsiness, and nausea and may lead to unconsciousness. Chronic Exposure : Suspected of damaging fertility or the unborn child. May cause damage to organs. Suspected of causing genetic defects. May cause cancer if swallowed. Experience with human exposure Eye contact : Redness, Pain, Irritation Skin contact : No known or expected. Ingestion : No known or expected. Inhalation : No known or expected. Toxicity Product Acute oral toxicity : no data available Acute inhalation toxicity : Acute toxicity estimate : 34.05 mg/l Exposure time: 4 h Acute dermal toxicity : Acute toxicity estimate : 3,405 mg/kg Skin corrosion/irritation : no data available Serious eye damage/eye irritation : no data available Respiratory or skin sensitization : no data available Carcinogenicity IARC Group 2B: Possibly carcinogenic to humans 77-09-8 OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP Reasonably anticipated to be a human carcinogen 77-09-8 Reproductive effects : no data available Germ cell mutagenicity : no data available Page 25 of 495 Page 25 of 495 Page 25 of 495 Page 25 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 7 / 10 Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Components Acute oral toxicity : LD50 rat: > 2,000 mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects. Components Toxicity to fish : Methanol LC50 : 15,400 mg/l Exposure time: 96 h Components Toxicity to daphnia and other aquatic invertebrates : Methanol EC50 : > 10,000 mg/l Exposure time: 48 h EC50 Daphnia: > 100 mg/l Exposure time: 48 h Components Toxicity to algae : Methanol EC50 : 22,000 mg/l Exposure time: 72 h Components Toxicity to bacteria : Methanol > 1,000 mg/l Components Toxicity to fish (Chronic toxicity) : Methanol NOEC: 7,900 mg/l Exposure time: 8.3 d Persistence and degradability The organic portion of this preparation is expected to be readily biodegradable. Mobility The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the Page 26 of 495 Page 26 of 495 Page 26 of 495 Page 26 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 8 / 10 defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air : 5 - 10% Water : 30 - 50% Soil : 30 - 50% The portion in water is expected to be soluble or dispersible. Bioaccumulative potential This preparation or material is not expected to bioaccumulate. Other information no data available Section: 13. DISPOSAL CONSIDERATIONS If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets the criteria of a hazardous waste. Hazardous Waste: : D001 Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : METHANOL, ETHANOL UN/ID No. : UN 1993 Transport hazard class(es) : 3 Packing group : II Air transport (IATA) Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : ETHANOL, METHANOL UN/ID No. : UN 1993 Transport hazard class(es) : 3 Packing group : II Page 27 of 495 Page 27 of 495 Page 27 of 495 Page 27 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 9 / 10 Sea transport (IMDG/IMO) Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : ETHANOL, METHANOL UN/ID No. : UN 1993 Transport hazard class(es) : 3 Packing group : II Section: 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Methanol 67-56-1 5000 56747 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard Chronic Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: Methanol 67-56-1 5 - 10 % 77-09-8 1 - 5 % California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. 77-09-8 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Methanol 67-56-1 INTERNATIONAL CHEMICAL CONTROL LAWS : TOXIC SUBSTANCES CONTROL ACT (TSCA) The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS). Page 28 of 495 Page 28 of 495 Page 28 of 495 Page 28 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 460-S0222 (SOLN P Indicator Form Liquid) 10 / 10 CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC). EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS). KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL) PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS). Section: 16. OTHER INFORMATION NFPA: HMIS III: Revision Date : 01/26/2015 Version Number : 1.0 Prepared By : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an MSDS visit www.nalco.com and request access. Flammability Health Instability 2 3 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 3 0 2* Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 29 of 495 Page 29 of 495 Page 29 of 495 Page 29 of 495 ---PAGE BREAK--- 1 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET 1 3 0 Special Health Flammability Instability 05/18/2005 05/18/2005 Date Created: Revision: 12/12/2005 Printed: FLAMMABILITY PPE PHYSICAL HAZ. G HEALTH 2 2 3 1. Product and Company Identification Product Code: GAC18 Product Name: Klean-Strip Acetone Reference 1640 Manufacturer Information Company Name: W. M. Barr 2105 Channel Avenue Memphis, TN 38113 Phone Number: (901)775-0100 Emergency Contact: 3E 24 Hour Emergency Contact (800)451-8346 Information: W.M. Barr Customer Service (800)398-3892 Web site address: www.wmbarr.com Preparer Name: W.M. Barr EHS Department (901)775-0100 2. Composition/Information on Ingredients Acetone Hazardous Components (Chemical Name) 67-64-1 CAS # 100.0 -95.0 % Percentage 1000 ppm OSHA PEL 500 ppm ACGIH TWA No data. Other Limits 1. Acetone Hazardous Components (Chemical Name) AL3150000 RTECS # No data. OSHA STEL No data. OSHA CEIL 750 ppm ACGIH STEL No data. ACGIH CEIL 1. 3. Hazards Identification Danger! Extremely Flammable. Keep away from heat, sparks, flame and all other sources of ignition. Vapors may cause flash fire or ignite explosively. Vapors may travel long distances to other areas and rooms away from the work site. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and all other sources of ignition anywhere in the structure, dwelling, or building during use and until all vapors are gone from the work site. Keep away from electrical outlets and switches. Beware of static electricity that may be generated by clothing and other sources. Emergency Overview OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations. Inhalation Acute Exposure Effects: Vapor harmful. May cause dizziness, headache, watering of eyes, irritation of respiratory tract, drowsiness, nausea, and numbness in fingers, arms and legs. Skin Contact Acute Exposure Effects: May cause drying of skin, and numbness in fingers and arms. Liquid is absorbed readily. Eye Contact Acute Exposure Effects: This material is an eye irritant. Ingestion Acute Exposure Effects: Harmful if swallowed. May cause dizziness, headache, nausea, and irritation of the mouth, throat, and stomach. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. May cause weakness, fatigue, skin irritation, and numbness in hands and feet. Potential Health Effects (Acute and Chronic) Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 30 of 495 Page 30 of 495 Page 30 of 495 Page 30 of 495 ---PAGE BREAK--- 05/18/2005 Revision: 12/12/2005 Printed: 2 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Primary Routes of Exposure: Inhalation, ingestion, and dermal. Signs and Of Exposure None known. Medical Conditions Generally Aggravated By Exposure HEALTH HAZARDS : N/E PHYSICAL HAZARDS : N/E TARGET ORGANS & EFFECTS: N/E OSHA Hazard Classes: 4. First Aid Measures Inhalation: If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or artificial respiration until medical assistance can be reached. Skin Contact: Wash with soap and water. Eye Contact: Flush with large quantities of water for at least 15 minutes and seek immediate medical attention. Ingestion: Call your poison control center, hospital emergency room, or physician immediately for instructions. Emergency and First Aid Procedures Call your local poison control center for further instructions. Note to Physician 5. Fire Fighting Measures Flammability Classification: Class IB Flash Pt: -4.00 F Method Used: TCC Explosive Limits: LEL: 2.60 UEL: No data. Autoignition Pt: No data. Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions No data available. Flammable Properties and Hazards Use carbon dioxide, dry powder, or foam. Extinguishing Media No data available. Unsuitable Extinguishing Media 6. Accidental Release Measures Clean Up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. For small spills, take up liquid with sand, earth, or other noncombustible absorbent material and place in a container for disposal. For large spills, dike far ahead of spill and use sand, earth, or other noncombustible absorbent material and then place material in a container for disposal. Steps To Be Taken In Case Material Is Released Or Spilled Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 31 of 495 Page 31 of 495 Page 31 of 495 Page 31 of 495 ---PAGE BREAK--- 05/18/2005 Revision: 12/12/2005 Printed: 3 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Waste Disposal: Dispose in accordance with applicable local, state, and federal regulations. 7. Handling and Storage Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse the container. Precautions To Be Taken in Handling Keep container closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Precautions To Be Taken in Storing 8. Exposure Controls/Personal Protection For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provide protection against vapors. Respiratory Equipment (Specify Type) Safety glasses, chemical goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Eye Protection Wear impermeable gloves. Gloves contaminated with product should be discarded. remove clothing that becomes soiled with product. Protective Gloves Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Other Protective Clothing Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with a cross ventilation of moving fresh air across the work area. If strong odor is noticed or your experience slight dizziness, headache, nausea, or eye-watering - STOP - ventilation is inadequate. Leave area immediately. Engineering Controls (Ventilation etc.) 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: > 133.00 F Autoignition Pt: No data. Flash Pt: -4.00 F Method: TCC Explosive Limits: LEL: 2.60 UEL: No data. Specific Gravity (Water = No data. Bulk Density: 6.572 LB/GA Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = No data. Evaporation Rate (vs Butyl Acetate=1): No data. Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 32 of 495 Page 32 of 495 Page 32 of 495 Page 32 of 495 ---PAGE BREAK--- 05/18/2005 Revision: 12/12/2005 Printed: 4 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Solubility in Water: No data. Percent Volatile: 100.0 % by weight. Corrosion Rate: No data. pH: No data. No data available. Appearance and Odor 10. Stability and Reactivity Stability: Unstable [ ] Stable [ X ] No data available. Conditions To Avoid - Instability Incompatible with strong oxidizing agents and hydrogen peroxide. Incompatibility - Materials To Avoid Decomposition may produce carbon monoxide and carbon dioxide. Hazardous Decomposition Or Byproducts Hazardous Polymerization: Will occur [ ] Will not occur [ X ] No data available. Conditions To Avoid - Hazardous Polymerization 11. Toxicological Information No data available. Toxicological Information No data available. Carcinogenicity/Other Information Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No 12. Ecological Information No data available. Ecological Information 13. Disposal Considerations Dispose in accordance with applicable local, state and federal regulations. Waste Disposal Method RCRA Waste ID Code: D001 14. Transport Information LAND TRANSPORT (US DOT) No data available. DOT Proper Shipping Name 15. Regulatory Information US EPA SARA Title III Acetone Hazardous Components (Chemical Name) 67-64-1 CAS # No Sec.302 (EHS) Yes 5000 LB Sec.304 RQ No Sec.313 (TRI) Yes Sec.110 1. US EPA CAA, CWA, TSCA Acetone Hazardous Components (Chemical Name) 67-64-1 CAS # No EPA CAA No EPA CWA NPDES No EPA TSCA No CA PROP 65 1. SARA (Superfund Amendments and Reauthorization Act of 1986) Lists: Sec.302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000 LB TPQ if not volatile. Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 33 of 495 Page 33 of 495 Page 33 of 495 Page 33 of 495 ---PAGE BREAK--- 05/18/2005 Revision: 12/12/2005 Printed: 5 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. indicates statutory RQ. Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a chemical category. Sec.110: EPA SARA 110 Superfund Site Priority Contaminant List TSCA (Toxic Substances Control Act) Lists: 5A(2): Chemical Subject to Significant New Rules (SNURS) 6A: Commercial Chemical Control Rules 8A: Toxic Substances Subject To Information Rules on Production 8A CAIR: Comprehensive Assessment Information Rules - (CAIR) 8A PAIR: Preliminary Assessment Information Rules - (PAIR) 8C: Records of Allegations of Significant Adverse Reactions 8D: Health and Safety Data Reporting Rules 8D TERM: Health and Safety Data Reporting Rule Terminations Other Important Lists: CWA NPDES: EPA Clean Water Act NPDES Permit Chemical CAA HAP: EPA Clean Air Act Hazardous Air Pollutant CAA ODC: EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC) CA PROP 65: California Proposition 65 This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: EPA Hazard Categories: [ ] Yes No Acute (immediate) Health Hazard [ ] Yes No Chronic (delayed) Health Hazard [ ] Yes No Fire Hazard [ ] Yes No Reactive Hazard [ ] Yes No Sudden Release of Pressure Hazard 16. Other Information The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 34 of 495 Page 34 of 495 Page 34 of 495 Page 34 of 495 ---PAGE BREAK--- page 1 of 4 UEL Not Applicable LEL Not Applicable FLASH POINT Not Applicable HMIS Codes Health 1 Flammability 0 Reactivity 0 DATE OF PREPARATION Mar 5, 2015 MATERIAL SAFETY DATA SHEET B79T4430A 11 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B79T4430A PRODUCT NAME Advanced Low VOC Interior Latex Semi-Gloss Paint, Ultradeep Base MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS No ingredients in this product are hazardous as defined by the Department of Labor. SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. Page 35 of 495 Page 35 of 495 Page 35 of 495 Page 35 of 495 ---PAGE BREAK--- B79T4430A page 2 of 4 During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Required for long or repeated contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.65 lb/gal 1036 g/l SPECIFIC GRAVITY 1.04 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 68% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.00 lb/gal 0 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC Page 36 of 495 Page 36 of 495 Page 36 of 495 Page 36 of 495 ---PAGE BREAK--- B79T4430A page 3 of 4 SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. TOXICOLOGY DATA No LC50 or LD50 data available. SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Page 37 of 495 Page 37 of 495 Page 37 of 495 Page 37 of 495 ---PAGE BREAK--- B79T4430A page 4 of 4 SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 38 of 495 Page 38 of 495 Page 38 of 495 Page 38 of 495 ---PAGE BREAK--- Page 39 of 495 Page 39 of 495 Page 39 of 495 Page 39 of 495 ---PAGE BREAK--- Page 40 of 495 Page 40 of 495 Page 40 of 495 Page 40 of 495 ---PAGE BREAK--- Page 41 of 495 Page 41 of 495 Page 41 of 495 Page 41 of 495 ---PAGE BREAK--- ALL PURPOSE CEMENT Latest Revision: 05/20/04 Last Reviewed: 05/20/04 Page 1 of 5 SECTION 1 IDENTITY OF MATERIAL Trade Name: OATEY ALL PURPOSE CEMENT Product Numbers: 30818, 30821, 30834, 30847, 30848, 31575, 31576, 31577, 31578, 31579, 31650, 31651, 32208, 32209 Formula: PVC & CPVC Resin in Solvent Solution Synonyms: PVC Plastic Pipe Cement Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland, Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com Oatey Phone Number: (216) 267-7100 Emergency Phone For Emergency First Aid call 1-[PHONE REDACTED] COLLECT. For Numbers: chemical transportation emergencies ONLY, call Chemtrec at 1-[PHONE REDACTED] SECTION 2 COMPOSITION INGREDIENTS: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER: Acetone 0 - 5% 67-64-1 500 ppm 1000 ppm 750 ppm STEL Cyclohexanone 7 - 16% 108-94-1 20 ppm(skin) 25 ppm Tetrahydrofuran 30 - 45% 109-99-9 200 ppm 200 ppm 25 ppm (Mfg) 750 ppm STEL Methyl Ethyl Ketone 20 - 40% 78-93-3 200 ppm 200 ppm CPVC Resin 3 - 7% 68648-82-8 10 mg/m3 None (Non-hazardous) Established PVC Resin 8 - 12% 9002-86-2 10 mg/m3 15 mg/m3 (Non-hazardous) Amorphous Fumed Silica 1 - 4% 112945-52-5 10 mg/m3 None (Non-hazardous) Established SECTION 3 EMERGENCY OVERVIEW Milky liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors may cause flash fire. May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory irritation and central nervous system effects. Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney or liver disorders. Aspiration hazard. May be fatal if swallowed. may be delayed. NFPA Hazard Signal: Health: 2 Stability: 1 Flammability: 3 Special: None HMIS Hazard Signal: Health: 3 Stability: 1 Flammability: 3 Special: None OSHA Hazard Classification: Flammable, irritant, organ effects Canadian WHIMS Classification: Class B, Division 2; Class D, Division 2, Subdivision B SECTION 4 EMERGENCY AND FIRST AID PROCEDURES - CALL 1-[PHONE REDACTED] COLLECT Skin: Remove contaminated clothing immediately. Wash all exposed areas with soap and water. Get medical attention if irritation develops. Remove dried cement with Oatey Plumber's Hand Cleaner or baby oil. Eyes: If material gets into eyes or if fumes cause irritation, immediately flush eyes with water for 15 minutes. If irritation persists, seek medical attention. Inhalation: If of exposure develop, remove to fresh air. If breathing becomes difficult, administer oxygen. Administer artificial respiration if breathing has stopped. Seek immediate medical attention. Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center, or hospital emergency room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment center or hospital. Page 42 of 495 Page 42 of 495 Page 42 of 495 Page 42 of 495 ---PAGE BREAK--- ALL PURPOSE CEMENT Latest Revision: 05/20/04 Last Reviewed: 05/20/04 Page 2 of 5 SECTION 5 FIRE FIGHTING MEASURES Flashpoint / Method: 0 - 5 Degrees F. / PMCC Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire Media: exposed container with water. Water may be ineffective as an extinguishing agent. Special Fire Firefighters should wear positive pressure self-contained Fighting breathing apparatus and full protective clothing for fires in Procedure: areas where chemicals are used or stored Unusual Fire and Extremely flammable liquid. Keep away from heat and all Explosion sources of ignition including sparks, flames, lighted Hazards: cigarettes and pilot lights. Containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ignition source and flash back. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. Hazardous Combustion will produce toxic and irritating vapors including Decomposition carbon monoxide, carbon dioxide and hydrogen chloride. Products: SECTION 6 ACCIDENTAL RELEASE MEASURES Spill or Remove all sources of ignition and ventilate area. Stop leak if it Leak can be done without risk. Personnel cleaning up the spill should Procedures: wear appropriate personal protective equipment, including respirators if vapor concentrations are high. Soak up spill with an inert absorbent such as sand, earth or other non-combusting material. Put absorbent material in covered, labeled metal containers. Prevent liquid from entering watercourses, sewers and natural waterways. Report releases to authorities as required. See Section 12 for disposal information. SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to outdoors). Wash thoroughly after handling. Do not eat, drink or smoke in the work area. Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas. Keep containers closed when not in use. Storage: Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not in use. Other: "Empty" containers retain product residue and can be hazardous. Follow all MSDS precautions in handling empty containers. Do not cut or weld on or near empty or full containers. SECTION 8 ECOLOGICAL INFORMATION This product is not expected to be toxic to aquatic organisms. Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l. Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L. Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L. Acetone: 96 hour LC50 for fish is greater than 100 mg/L. VOC This product emits VOC's (volatile organic compounds) in its use. Information: Make sure that use of this product complies with local VOC emission regulations, where they exist. VOC Level: 600 g/l per SCAQMD Test Method 316A. Page 43 of 495 Page 43 of 495 Page 43 of 495 Page 43 of 495 ---PAGE BREAK--- ALL PURPOSE CEMENT Latest Revision: 05/20/04 Last Reviewed: 05/20/04 Page 3 of 5 SECTION 9 EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Open doors & windows. Provide ventilation capable of maintaining emissions at the point of use below recommended exposure limits. If used in enclosed area, use exhaust fans. Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of solvent vapors are not exposed to electrical fixtures or hot surfaces. Respiratory For operations where the exposure limit may be exceeded, a NIOSH Protection: approved organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. Skin Rubber gloves are suitable for normal use of the product. For long Protection: exposures chemical resistant gloves may be required such as 4H(tm) or Silver Shield(tm) to avoid prolonged skin contact. Eye Safety glasses with side shields or safety goggles. Protection: Other: Eye wash and safety shower should be available. SECTION 10 PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 151 Degrees F / 66 C Melting Point: N/A Vapor Pressure: 145 mmHg @ 20 Degrees C Vapor Density: (Air = 1) 2.5 Volatile Components: 84-88% Solubility In Water: Negligible pH: N/A Specific Gravity: 0.93 0.02 Evaporation Rate: (BUAC = 1) = 5.5 - 8.0 Appearance: Milky Liquid Odor: Ether-Like Will Dissolve In: Tetrahydrofuran Material Is: Liquid SECTION 11 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition. Hazardous Combustion will produce toxic and irritating vapors Decomposition including carbon monoxide, carbon dioxide and hydrogen Products: chloride. Incompatibility/ Oxidizing agents, alkalies, amines, ammonia, acids, chlorine Materials To Avoid: compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber. Hazardous Will not occur. Polymerization: SECTION 12 DISPOSAL INFORMATION Waste Disposal: Dispose in accordance with current local, state and federal regulations. Page 44 of 495 Page 44 of 495 Page 44 of 495 Page 44 of 495 ---PAGE BREAK--- ALL PURPOSE CEMENT Latest Revision: 05/20/04 Last Reviewed: 05/20/04 Page 4 of 5 SECTION 13 TOXICOLOGICAL INFORMATION Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation, coughing, headache, dizziness, dullness, nausea, shortness of breath and vomiting. High concentrations may cause central nervous system depression, narcosis and unconsciousness. May cause kidney, liver and lung damage. Skin: May cause irritation with redness, itching and pain. Methyl ethyl ketone and cyclohexanone may be absorbed through the skin causing effects similar to those listed under inhalation. Eye: Vapors may cause irritation. Direct contact may cause irritation with redness, stinging and tearing of the eyes. May cause eye damage. Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea. Aspiration during swallowing or vomiting can cause chemical pneumonia and lung damage. May cause kidney and liver damage. Chronic Prolonged or repeated overexposure cause dermatitis and damage Toxicity: to the kidney, liver, lungs and central nervous system. Toxicity Data: Acetone: Oral rat LD50: 5,800 mg/kg Inhalation rat LC50: 50,100 mg/m3/8 hours Cyclohexanone: Oral rat LD50: 1,620 mg/kg Inhalation rat LC50: 8,000 ppm/4 hours Skin rabbit LD50: 1 mL/kg Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg Inhalation rat LC50: 21,000 ppm/3 hours Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg Inhalation rat LC50: 23,500 mg/m3/8 hours Skin rabbit LD50: 6,480 mg/kg Sensitization: None of the components are known to cause sensitization. Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by NTP, IARC or OSHA. The National Toxicology Program has reported that exposure of mice and rats to Tetrahydrofuran (THF) vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their lifetime caused an increased incidence of kidney tumors in male rats and liver tumors in female mice. The significance of these findings for human health are unclear at this time, and may be related to "species specific" effects. Elevated incidences of tumors in humans have not been reported for THF. ACGIH has classified cyclohexanone (CYH) as “A3,” Confirmed Animal Carcinogen with Unknown Relevance to Humans. Mutagenicity: Acetone has been positive in a mammal cell cytogenic analysis but negative in many other assays. At most, acetone is weakly genotoxic. Cyclohexanone has been positive in bacterial and mammalian assays. Tetrahydrofuran was positive in a bacterial assay. Methyl ethyl ketone is not considered genotoxic based on laboratory studies. Reproductive Methyl ethyl ketone and cyclohexanone have been shown to cause Toxicity: embryofetal toxicity and birth defects in laboratory animals. Acetone and tetrahydrofuran have been found to cause adverse developmental effects only when exposure levels cause other toxic effects to the mother. Medical Persons with pre-existing skin, lung, kidney or liver disorders Conditions may be at increased risk from exposure to this product. Aggravated By Exposure: Page 45 of 495 Page 45 of 495 Page 45 of 495 Page 45 of 495 ---PAGE BREAK--- ALL PURPOSE CEMENT Latest Revision: 05/20/04 Last Reviewed: 05/20/04 Page 5 of 5 SECTION 14 TRANSPORTATION INFORMATION DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) Proper Shipping Name: Consumer Commodity Adhesives Hazard Class/Packing Group: ORM-D 3, PGII UN/NA Number: None UN1133 Hazard Labels: None Flammable Liquid IMDG Proper Shipping Name: Adhesives Adhesives Hazard Class/Packing Group: 3, II 3, II UN Number: UN1133 UN1133 Label: None (Limited Quantities Class 3 (Flammable are excepted Liquid) from labeling) RCRA Hazardous Waste Number: U002, U057, U159, U213 EPA Hazardous Waste ID Number: D001, D035, F003, F005 EPA Hazard Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content) 2000 North American Emergency Response Guidebook Number: 127 or 128 SECTION 15 REGULATIONS Hazard Category for Section Acute Health, Chronic Health, Flammable 311/312: Section 302 Extremely This product does not contain chemicals regulated Hazardous Substances (TPQ): under SARA Section 302. Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: Chemical CAS # % Methyl Ethyl Ketone 78-93-3 25-40% CERCLA 103 Reportable Spills of this product over the RQ (reportable Quantity: quantity) must be reported to the National Response Center. The RQ for the product, based on the RQ for Tetrahydrofuran (45% maximum) of 1,000 lbs, is 2,222 lbs. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. California Proposition 65: This product does not contain any chemicals subject To California Proposition 65 regulation. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. SECTION 16 DISCLAIMER The information herein has been compiled from sources believed to be reliable, up- to-date, and is accurate to the best of our knowledge. However, Oatey cannot give any guarantees regarding information from other sources, and expressly does not make warranties, nor assumes any liability for its use. Page 46 of 495 Page 46 of 495 Page 46 of 495 Page 46 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Alpha HP Multi-Surface Cleaner Fragrance Free (1:64 use solution) Version Number: 1 Preparation date: 2007-03-12 Personal protective equipment NFPA HMIS Reactivity 0 None / Aucune / Ninguno Health Fire Hazard 0 0 0 0 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Alpha HP Multi-Surface Cleaner Fragrance Free (1:64 use solution) MSDS MS0200066D Product code: MS0200066D Recommended use: Cleaning product. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Ingestion. Eye contact: None known. Skin contact: None known. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components None 4. FIRST AID MEASURES Eye contact: Rinse with plenty of water. Skin contact: Rinse with plenty of water. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: None known. Unusual hazards: None known. Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Not relevant for the product itself. Environmental precautions and clean-up methods: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] EMERGENCY OVERVIEW The product contains no substances which at their given concentration, are considered to be hazardous to health. Alpha HP Multi-Surface Cleaner Fragrance Free (1:64 use solution) 1 of 3 Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Page 47 of 495 Page 47 of 495 Page 47 of 495 Page 47 of 495 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling: Handle in accordance with good industrial hygiene and safety practice. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: None known. Conditions to avoid: None known. 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 estimated to be greater than 5000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations Appearance: Decomposition temperature: Not determined Aqueous solution VOC: 0.0 No information available Autoignition temperature: No information available Vapor density: Flash point: 200°F >93.3°C No information available Partition coefficient (n-octanol/water): No information available Liquid Solubility: Soluble Color: Solubility in other solvents: No information available Clear Viscosity: No information available pH: Elemental Phosphorus: 0.0 %P Evaporation Rate No information available 5.4 Odor: Odorless Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: No information available No information available. Melting point/range: Not determined Bulk density: Alpha HP Multi-Surface Cleaner Fragrance Free (1:64 use solution) Density: 2 of 3 No information available. Page 48 of 495 Page 48 of 495 Page 48 of 495 Page 48 of 495 ---PAGE BREAK--- 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia (AICS), Korea (ECL), Philippines (PICCS), China (IECSC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - CERCLA/ SARA None CAA HAP/CAA ODS/CWA Priority Pollutants: None SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class: Non-controlled. 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 Alpha HP Multi-Surface Cleaner Fragrance Free (1:64 use solution) Page 49 of 495 Page 49 of 495 Page 49 of 495 Page 49 of 495 ---PAGE BREAK--- Page 50 of 495 Page 50 of 495 Page 50 of 495 Page 50 of 495 ---PAGE BREAK--- Page 51 of 495 Page 51 of 495 Page 51 of 495 Page 51 of 495 ---PAGE BREAK--- Page 52 of 495 Page 52 of 495 Page 52 of 495 Page 52 of 495 ---PAGE BREAK--- Page 53 of 495 Page 53 of 495 Page 53 of 495 Page 53 of 495 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Name ben PREMIUM INTERIOR LATEX EGGSHELL FINISH Product Code K62601 Product Class WATER THINNED PAINT Color White 2. COMPOSITION INFORMATION ON COMPONENTS Hazardous Components Chemical Name CAS-No Weight % (max) Titanium dioxide 13463-67-7 15 - 40% Nepheline syenite 37244-96-5 5 - 10% Silica, amorphous 7631-86-9 1 - 5% Distillates, petroleum, hydrotreated heavy paraffinic 64742-54-7 0.5 - 1% 3. HAZARDS IDENTIFICATION Potential Health Effects Principal Routes of Exposure Eye contact, skin contact and inhalation. Acute Effects Page 1 / 9 Revision Number: 4 Vapors may be irritating to eyes, nose, throat, and lungs. May cause skin irritation and/or dermatitis. Manufacturer Benjamin Moore & Co. 101 Paragon Drive Montvale, NJ 07645 Phone: [PHONE REDACTED] www.benjaminmoore.com Revision Date: 30-Apr-2014 Emergency Telephone Number(s) CANUTEC: [PHONE REDACTED] Emergency Overview Odor little or no odor Appearance liquid Page 54 of 495 Page 54 of 495 Page 54 of 495 Page 54 of 495 ---PAGE BREAK--- Eyes May cause slight irritation. Skin Substance may cause slight skin irritation. Inhalation May cause irritation of respiratory tract. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Effects Repeated contact may cause allergic reactions in very susceptible persons. See Section 11 for additional Toxicological information. Aggravated Medical Conditions None known Note: The PPE rating has intentionally been left blank. Choose appropriate PPE that will protect employees from the hazards the material will present under the actual normal conditions of use. Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings are not required on under 29 CFR 1910.1200, the preparer, has chosen to provide them. HMIS® ratings are to be used only in conjunction with a fully implemented HMIS® program by workers who have received appropriate HMIS® training. HMIS® is a registered trade and service mark of the NPCA. HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. 4. FIRST AID MEASURES General Advice No hazards which require special first aid measures. Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Inhalation Move to fresh air. If persist, call a physician. Ingestion Clean mouth with water and afterwards drink plenty of water. Consult a physician if necessary. Notes To Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment And Precautions For Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 2 / 9 Reactivity: 0 K62601 - ben PREMIUM INTERIOR LATEX EGGSHELL FINISH PPE: - HMIS HMIS Legend 0 - Minimal Hazard 1 - Slight Hazard 2 - Moderate Hazard 3 - Serious Hazard 4 - Severe Hazard * - Chronic Hazard X - Consult your supervisor or S.O.P. for "Special" handling instructions. Revision Date: 30-Apr-2014 Health: 1* Flammability: 0 Page 55 of 495 Page 55 of 495 Page 55 of 495 Page 55 of 495 ---PAGE BREAK--- Specific Hazards Arising From The Chemical Closed containers may rupture if exposed to fire or extreme heat. Sensitivity To Mechanical Impact No Sensitivity To Static Discharge No Flash Point Data Flash Point Not applicable Flash Point Not applicable Flash Point Method Not applicable Flammability Limits In Air Upper Explosion Limit Not applicable Lower Explosion Limit Not applicable The ratings assigned are only suggested ratings, the contractor/employer has ultimate responsibilities for NFPA ratings where this system is used. Additional information regarding the NFPA rating system is available from the National Fire Protection Agency (NFPA) at www.nfpa.org. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Environmental Precautions Prevent further leakage or spillage if safe to do so. Methods For Clean-Up Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Other Information None known 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors, spray mists or sanding dust. In case of insufficient ventilation, wear suitable respiratory equipment. Storage Keep container closed. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits Page 3 / 9 NFPA Revision Date: 30-Apr-2014 NFPA Legend 0 - Not Hazardous 1 - 2 - Moderate 3 - High 4 - Severe Health: 1 Flammability: 0 Instability: 0 K62601 - ben PREMIUM INTERIOR LATEX EGGSHELL FINISH Special: Not Applicable Page 56 of 495 Page 56 of 495 Page 56 of 495 Page 56 of 495 ---PAGE BREAK--- Hazardous Components Chemical Name ACGIH Alberta British Columbia Ontario Quebec Titanium dioxide 10 mg/m3 - TWA 10 mg/m3 - TWA 10 mg/m3 - TWA 3 mg/m3 - TWA 10 mg/m3 - TWA 10 mg/m3 - TWAEV Nepheline syenite N/E N/E N/E 10 mg/m3 - TWAEV N/E Silica, amorphous N/E N/E N/E N/E N/E Distillates, petroleum, hydrotreated heavy paraffinic N/E N/E N/E N/E N/E Legend ACGIH - American Conference of Governmental Industrial Hygienists Alberta - Alberta Occupational Exposure Limits British Columbia - British Columbia Occupational Exposure Limits Ontario - Ontario Occupational Exposure Limits Quebec - Quebec Occupational Exposure Limits N/E - Not established Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection Protective gloves and impervious clothing Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment. Hygiene Measures Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance liquid Odor little or no odor Density (lbs/gal) 11.1 - 11.5 Specific Gravity 1.34 - 1.37 pH Not available Viscosity (centistokes) Not available Evaporation Rate Not available Vapor Pressure Not available Vapor Density Not available Wt. % Solids 50 - 60 Vol. % Solids 35 - 45 Wt. % Volatiles 40 - 50 Vol. % Volatiles 55 - 65 VOC Regulatory Limit (g/L) < 50 Boiling Point 212 Boiling Point 100 Freezing Point 32 Freezing Point 0 Flash Point Not applicable Flash Point Not applicable Flash Point Method Not applicable Upper Explosion Limit Not available Lower Explosion Limit Not available Page 4 / 9 Revision Date: 30-Apr-2014 K62601 - ben PREMIUM INTERIOR LATEX EGGSHELL FINISH Page 57 of 495 Page 57 of 495 Page 57 of 495 Page 57 of 495 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Conditions To Avoid Prevent from freezing Incompatible Materials No materials to be especially mentioned Hazardous Decomposition Products None under normal use. Possibility Of Hazardous Reactions Hazardous polymerisation will not occur. Page 5 / 9 K62601 - ben PREMIUM INTERIOR LATEX EGGSHELL FINISH Revision Date: 30-Apr-2014 Page 58 of 495 Page 58 of 495 Page 58 of 495 Page 58 of 495 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product No information available Component Chronic Toxicity Carcinogenicity The information below indicates whether each agency has listed any ingredient as a carcinogen: Chemical Name ACGIH IARC NTP OSHA Carcinogen Titanium dioxide 2B - Possible Human Carcinogen Listed Distillates, petroleum, hydrotreated heavy paraffinic 1 - Human Carcinogen • Although IARC has classified titanium dioxide as possibly carcinogenic to humans (2B), their summary concludes: "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium dioxide is bound to other materials, such as paint." Legend ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer NTP - National Toxicity Program OSHA - Occupational Safety & Health Administration 12. ECOLOGICAL INFORMATION Ecotoxicity Effects Page 6 / 9 Sensitization: No sensitizing effects known. K62601 - ben PREMIUM INTERIOR LATEX EGGSHELL FINISH Revision Date: 30-Apr-2014 Silica, amorphous LD50 Dermal: > 10000 mg/m³ (Rabbit) LD50 Oral: > 5000 mg/kg (Rat) Titanium dioxide LD50 Dermal: 2,000 mg/kg (Rabbit) LC50 Inhalation (Dust): > 6.82 mg/L (Rat, 4 hr.) LC50 Inhalation (Dust): > 2 mg/L Nepheline syenite LD50 Oral: > 10000 mg/kg (Rat) Page 59 of 495 Page 59 of 495 Page 59 of 495 Page 59 of 495 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Product Acute Toxicity to Fish No information available Acute Toxicity to Aquatic Invertebrates No information available Acute Toxicity to Aquatic Plants No information available Component Acute Toxicity to Fish Acute Toxicity to Aquatic Invertebrates No information available Acute Toxicity to Aquatic Plants No information available 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with federal, state, provincial, and local regulations. Dry, empty containers may be recycled in a can recycling program. Local requirements may vary, consult your sanitation department or state-designated environmental protection agency for more disposal options. 14. TRANSPORT INFORMATION TDG Not regulated ICAO / IATA Not regulated IMDG / IMO Not regulated 15. REGULATORY INFORMATION International Inventories United States TSCA Yes - All components are listed or exempt. Canada DSL Yes - All components are listed or exempt. National Pollutant Release Inventory (NPRI) Page 7 / 9 K62601 - ben PREMIUM INTERIOR LATEX EGGSHELL FINISH Titanium dioxide Revision Date: 30-Apr-2014 LC50: >1000 mg/L (Fathead Minnow - 96 hr.) Page 60 of 495 Page 60 of 495 Page 60 of 495 Page 60 of 495 ---PAGE BREAK--- 15. REGULATORY INFORMATION NPRI Parts 1- 4 This product contains the following Parts 1-4 NPRI chemicals: This product may contain trace amounts of (other) NPRI Parts I-4 reportable chemicals. Contact the preparer for further information. NPRI Part 5 This product contains the following NPRI Part 5 Chemicals: This product may contain trace amounts of (other) NPRI Part 5 reportable chemicals. Contact the preparer for further information. WHMIS Regulatory Status This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2A Very toxic materials 16. OTHER INFORMATION WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC. EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE, ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a NIOSH approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and a wet mop. Before you start, find out how to protect yourself and your family by logging onto Health Canada @ http://www.hc-sc.gc.ca/hl-vs/iyh-vsv/prod/paint-peinture-eng.php. Prepared By Product Stewardship Department Benjamin Moore & Co. 101 Paragon Drive Montvale, NJ 07645 [PHONE REDACTED] Revision Date: 30-Apr-2014 Revision Summary No information available Page 8 / 9 K62601 - ben PREMIUM INTERIOR LATEX EGGSHELL FINISH Revision Date: 30-Apr-2014 Page 61 of 495 Page 61 of 495 Page 61 of 495 Page 61 of 495 ---PAGE BREAK--- Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, provincial, and local laws and regulations. K62601 End of MSDS Page 9 / 9 K62601 - ben PREMIUM INTERIOR LATEX EGGSHELL FINISH Revision Date: 30-Apr-2014 Page 62 of 495 Page 62 of 495 Page 62 of 495 Page 62 of 495 ---PAGE BREAK--- ACTIO MSDS ID: 875566 View Section : 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 SECTION 1: CHEMICAL PRODUCT and COMPANY IDENTIFICATION (N/A) Product Name: Black Flag Dry Max Spray Kills Ants Roaches Spiders Kills Biting Asian Beetles Synonyms: Crawling Insect Killer F-2548 Distributor Name: Black Flag Brands, LLC Distributor Address: 25 Garden Street NY Mills, New York 13417 TELEPHONE M-F, 8:00-5:00 EST, 14:00-23:00 GMT: (800) 887- 3524 or (315) 624-7695 MSDS & Product Information, 8:00-5:00 EST, 14:00-23:00 GMT: (800) 887-3524 or (315) 624-7695 24 HOUR EMERGENCY PHONE (CHEMTREC) U.S, and CANADA: (800)-424-9300 CHEMTREC (ALL OTHER AREAS): (703) 527- 3887 24 HOUR EMERGENCY PHONE US & CAN: (800)-887-3524 (ALL OTHER AREAS): (315)624-7695 For information regarding MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call the INTERNATIONAL POISON Center at: 1- [PHONE REDACTED] Revision Date: 10/24/2004 Product Description: Aerosol containing a pressurized liquid insecticide. EPA REGISTRATION NO.: 1021-1691-79529 CHEMICAL NAME: Mixture HMIS RATINGS: We assign HMIS ratings to this product based on the hazards of its ingredient(s). Since the customer is most aware of the applications and conditions of use, he must ensure that the proper personal protective equipment is provided consistent with information contained in Section's 7 and 8 of this MSDS. HMIS HEALTH 1 FIRE 4 REACTIVITY 1 PPE To Top of page SECTION 2 : COMPOSITION, INFORMATION ON INGREDIENTS : (N/A) Ingredient Name CAS# Ingredient Percent Prallethrin (ETOC®) [(RS)-2-methyl-4-oxo-3-(2-propynyI) cyclopent-2-enyl-(1RS)-cis, 23031-36-9 0.030% by Weight EINECS: 245-387-9 EC Index Number: 1 Other Exposure Guidelines: Not established Esfenvalerate [(S)-Cyano (3-phenoxyphenyl) methyl 4-chloro- alpha-(1 - methylethyl) benzeneacetate] 66230-04-4 0.050% by Weight EINECS: Not Available EC Index Number: 1 Other Exposure Guidelines: Not established MGK®-264 [N-Octyl bicycloheptene dicarboximide] 113-48-4 0.300% by Weight EINECS: 204-029-1 EC Index Number: 1 Other Exposure Guidelines: Not established Petroleum Gases, Liquefied 68476-85-7 10< >20% by Weight EINECS: 270-703-7 OSHA PEL TWA: 1000 ppm (1800 mg/m3) Black Flag Dry Max Spray Kills Ants Roaches Spiders Kills Biting Asian Beetles Black Flag Brands, LLC Page:1 of 6 Page 63 of 495 Page 63 of 495 Page 63 of 495 Page 63 of 495 ---PAGE BREAK--- ACGIH TLV TWA: 1000 ppm (1800 mg/m3) NIOSH REL: 1000 ppm (1800 mg/m3) EC Index Number: 1 Petroleum Distillates, hydrotreated light 64742-47-8 < 2% by Weight EINECS: 265-149-8 EC Index Number: 1 Other Exposure Guidelines: 100 ppm (525 mg/m3) TWA Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. PEL = Permissible Exposure Limits. TLV = Threshold Limit Value. TWA = Time Weighted Average (8 hr). STEL = Short Term Exposure Limit (15 min.). To Top of page SECTION 3 : HAZARDS IDENTIFICATION : (N/A) Emergency Overview: CAUTION. Contents under pressure. DO NOT use or store near heat, Sparks, Open flame, or any other ignition sources. Causes moderate eye irritation. Harmful if absorbed through the skin. Avoid contact with skin, eyes, and clothing. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Do not expose to temperatures above 130 deg F (54.4 deg C) as bursting may occur. Do not puncture or incinerate container. Applies to all ingredients: Potential Health Effects: Eye Contact: Causes moderate eye irritation. Skin Contact: Can cause skin irritation. Can cause a burning or prickling sensation on more sensitive areas (face, eyes, mouth). Prolonged or frequently repeated skin contact may cause allergic reactions jn some individuals. Skin Absorption: Harmful if absorbed through the skin. Inhalation: Excessive inhalation of vapors or spray mists may cause nasal and respiratory irritation. Ingestion: May be harmful if swallowed. Chronic Health Effects: None known. Applies to all ingredients: Potential Health Effects: Eye Contact: Causes moderate eye irritation. Skin Contact: Can cause skin irritation. Can cause a burning or prickling sensation on more sensitive areas (face, eyes, mouth). Prolonged or frequently repeated skin contact may cause allergic reactions jn some individuals. Skin Absorption: Harmful if absorbed through the skin. Inhalation: Excessive inhalation of vapors or spray mists may cause nasal and respiratory irritation. Ingestion: May be harmful if swallowed. Chronic Health Effects: None known. ECOLOGICAL: See Section's 12 and 15. TOXICOLOGICAL: See Section 11. Applies to all ingredients: Potential Health Effects: Eye Contact: Causes moderate eye irritation. Skin Contact: Can cause skin irritation. Can cause a burning or prickling sensation on more sensitive areas (face, eyes, mouth). Prolonged or frequently repeated skin contact may cause allergic reactions jn some individuals. Skin Absorption: Harmful if absorbed through the skin. Inhalation: Excessive inhalation of vapors or spray mists may cause nasal and respiratory irritation. Ingestion: May be harmful if swallowed. Chronic Health Effects: None known. ECOLOGICAL: See Section's 12 and 15. TOXICOLOGICAL: See Section 11. To Top of page SECTION 4 : FIRST AID MEASURES : (N/A) Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call Black Flag Dry Max Spray Kills Ants Roaches Spiders Kills Biting Asian Beetles Black Flag Brands, LLC Page:2 of 6 Page 64 of 495 Page 64 of 495 Page 64 of 495 Page 64 of 495 ---PAGE BREAK--- a poison control center or doctor for treatment advice. Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15- 20 minutes. Call a poison control center or doctor for treatment advice. Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion: Immediately call a poison control center or doctor for treatment advice. DO NOT give any liquid to the person. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Note to Physicians: For skin effects, a highly efficient therapeutic agent for Pyrethroid exposure is topical application of Tocopherol Acetate (Vitamin Treatment is supportive and Diazepam has been recommended to reduce the CNS effects of Esfenvalerate. To Top of page SECTION 5 : FIRE FIGHTING MEASURES : (N/A) Fire: This aerosol is classified as Nonflammable by the Flame-Extension Test Method described in 16 CFR 1500.45. Upper Flammable or Explosive Limit: Not established. Lower Flammable or Explosive Limit: Not established. Auto Ignition Temperature: Not established. Extinguishing Media: Foam, carbon dioxide, or dry chemical. Hazardous Combustion Byproducts: Under fire conditions this product may support combustion and may decompose to give off toxic gasses such as carbon monoxide, carbon dioxide, nitrogen oxides, and Hydrogen Cyanide. Fire Fighting Instructions: Treat as an oil fire. Use a full-faced self-contained breathing apparatus along with full protective gear. Keep nearby containers and equipment cool with a water stream. Contain the run-off, if possible, for proper disposal. To Top of page SECTION 6 : ACCIDENTAL RELEASE MEASURES : (N/A) Large Spill: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. Collect product into drums, etc. via drains, pumps, etc. Absorb with appropriate absorbent. Clean spill area of residues and absorbent Small Spill: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. Absorb with appropriate absorbent. Clean spill area of residues and absorbent. WASTE DISPOSAL METHOD: Contaminated absorbent and wash water should be disposed of according to local, state, and federal regulations. To Top of page SECTION 7 : HANDLING and STORAGE : (N/A) Handling: DO NOT use near heat, sparks, open flame, or any other ignition source. Contents under pressure. Take prudent precautions to avoid contact with skin, eyes and clothing. Mechanical ventilation should be used when handling this product in enclosed spaces. Take prudent precautions to avoid breathing vapors or spray mists of this product. Wearing a respirator is not required when handling this product, but recommended in absence of good mechanical ventilation. Do not contaminate water, feed or food by storage, handling or disposal. Read and observe all precautions and instructions on the label. Storage: Keep away from heat, sparks, and open flame. Contents under pressure. Exposure to Temperatures above 130 deg F (54.4 deg C) may cause bursting. Store containers upright and closed. Store in areas that are cool, dry and well ventilated, Keep away from heat, ignition sources, strong oxidizers and strong acids and bases. Emptied containers may retain product residues. Do not puncture or incinerate container. KEEP OUT OF REACH OF CHILDREN. Hygiene Practices: DO NOT SMOKE, EAT, DRINK OR APPLY COSMETICS IN WORK AREA! Wash if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking, and using the toilet. GENERAL PROCEDURES: DO NOT APPLY THIS PRODUCT IN OR ON ELECTRICAL EQUIPMENT DUE TO THE POSSIBILITY OF SHOCK HAZARD. To Top of page SECTION 8 : EXPOSURE CONTROLS, PERSONAL PROTECTION : (N/A) Ventilation System: Mechanical ventilation should be used when handling this product in enclosed spaces. Local Exhaust: Local exhaust ventilation may be necessary. Skin Protection Description: Take prudent precautions to avoid contact with skin and clothing. Eye/Face Protection: Take prudent precautions to avoid contact with eyes. Black Flag Dry Max Spray Kills Ants Roaches Spiders Kills Biting Asian Beetles Black Flag Brands, LLC Page:3 of 6 Page 65 of 495 Page 65 of 495 Page 65 of 495 Page 65 of 495 ---PAGE BREAK--- Respiratory Protection: Not normally required. Use in well ventilated areas. Exposure Limits: Not established by OSHA or ACGIH (see Section 2 for individual components). To Top of page SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES : (N/A) Physical State/Appearance: Non-Volatiles emulsion. Color: Opaque, creamy-white COLOR, (GARDNER): Not established Odor: Petroleum distillate odor Physical State: Liquid pH: 6.65 Vapor Pressure: Not established Vapor Density: Not established Boiling Point: Not established Melting Point: Not established Solubility: In Water: Partially soluble in water. Specific Gravity: 0.992 @ 20 deg C (68 deg F) Volatile Organic Compound Content: < 17% Viscosity: Not established This section will refer to the Non-Volatile portion of EVERCIDE® Crawling Insect Killer 2548 REFRACTIVE INDEX: Not established To Top of page SECTION 10 : STABILITY and REACTIVITY : (N/A) Chemical Stability: Stable. Incompatibilities with Other Materials: Not compatible with strong acidic or alkaline materials. Not compatible with strong oxidizers. Hazardous Polymerization: Will not occur Hazardous Decomposition Products: Hydrogen cyanide may be formed by thermal decomposition or by contact with alkaline substances such as soda ash and lye. To Top of page SECTION 11 : TOXICOLOGICAL INFORMATION : (N/A) Applies to All Ingredients : Skin Effects: ACUTE STUDIES: Acute Dermal LD50 (Albino rabbit): > 2.0 gm/kg Ingestion Effects: ACUTE STUDIES: Acute Oral LD50 (Albino rat): > 5.0 gm/kg Inhalation Effects: ACUTE STUDIES: Acute Inhalation LC50 (rat): > 2.93 mg/l. Rats exposed for 4 hours to test atmosphere. Subchronic Effects: Not established Carcinogenicity: None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as being carcinogens. Sensitization: Dermal Sensitization (Albino guinea pig): Possible dermal sensitizer. Irritation: Primary skin irritation (Albino rabbit): No irritation at 72 hours. Skin Irritation Index = 0.38. Note: This study was dosed as a 5% w/w dilution in deionized water. Primary eye irritation (rabbit): Irritation clearing in 7 days. Comments: GENERAL COMMENTS: Some or all of the toxicity data reported above was bridged from a substantially similar formula. To Top of page SECTION 12 : ECOLOGICAL INFORMATION : (N/A) Ecotoxicity: This product is toxic to fish and other aquatic invertebrates. For terrestrial uses, do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water by cleaning of equipment or disposal of wastes. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product into sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. PERSISTENCE IN THE ENVIRONMENT BIODEGRADATION: Unknown CHEMICAL DEGRADATION: Unknown TOXIC EFFECTS ON ORGANISMS: FISH: LC50: Not established Black Flag Dry Max Spray Kills Ants Roaches Spiders Kills Biting Asian Beetles Black Flag Brands, LLC Page:4 of 6 Page 66 of 495 Page 66 of 495 Page 66 of 495 Page 66 of 495 ---PAGE BREAK--- BIRD: LC50: Not established TOXICITY TO USEFUL INSECTS: Unknown To Top of page SECTION 13 : DISPOSAL CONSIDERATIONS : (N/A) Waste Disposal: Do not puncture or incinerate! If empty: Do not reuse this container. Place in trash or offer for recycling if available. If partially filled: Call your local solid waste agency or 1-800-CLEANUP for disposal instructions. Never place unused product down any indoor or outdoor drain. Contaminated absorbent and wash water should be disposed of according to local, state, and federal regulations. RCRA Hazard Class: RCRA\CERCLA HAZARDOUS WASTE INGREDIENT: None RCRA ID CERCLA RQ-VALUE To Top of page SECTION 14 : TRANSPORT INFORMATION : (N/A) DOT Shipping Name: Consumer Commodity DOT Hazard Class: ORM-D IMO Shipping Name: Consumer Commodity IMO Hazard Class: 9 IMO UN Number: UN 8000 IATA Shipping Name: Consumer Commodity IATA Hazard Class: 9 IATA UN Number: UN 8000 Maritime Transportation CGVS/GGVE/IMDG: PROPER SHIPPING NAME: Consumer Commodity CGVS/GGVE/IMDG UN or NA Identification Number: UN 8000 CGVS/GGVE/IMDG Class: 9 ICAO DESCRIPTION: Consumer Commodity, 9, UN 8000 To Top of page SECTION 15 : REGULATORY INFORMATION : (N/A) Applies to all ingredients: TSCA 8(b): Inventory Status: All chemical substances found in this product comply with the Toxic Substances Control Act's inventory reporting requirements. SARA: SARA TITLE III: (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) Section 302: 302/304 EMERGENCY PLANNING: EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances present in this formulation (40 CFR 355). Section 304: 302/304 EMERGENCY PLANNING: There are no components that are subject to emergency requirements under CERCLA Section 103(a)(40 CFR 302.4) in this formulation. Section 312 Hazard Category: 311/312 HAZARD CATEGORIES: Acute: Yes Fire: No Reactive: No Pressure: Yes Section 313 Toxic Release Form: SECTION 313 REPORTABLE INGREDIENTS: This product contains the following toxic chemicals of the subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: This product contains no SARA Title III Section 313 chemicals that exceed the reporting limits. VOLATILE ORGANIC COMPOUNDS (VOC): This product contains less than 17% VOC's. To Top of page SECTION 16 : ADDITIONAL INFORMATION : (N/A) HMIS: Health Hazard: 1 Fire Hazard: 4 Black Flag Dry Max Spray Kills Ants Roaches Spiders Kills Biting Asian Beetles Black Flag Brands, LLC Page:5 of 6 Page 67 of 495 Page 67 of 495 Page 67 of 495 Page 67 of 495 ---PAGE BREAK--- Reactivity: 1 MSDS Revision Date: 10/24/2004 Disclaimer: The data contained herein is based on information currently available to Black Flag Brands, LLC., and believed to be factual and the opinions expressed to be those of qualified experts; however, this data is not to be taken as a warranty or representation for which Black Flag Brands, LLC. assumes legal responsibility. HMIS RATINGS: We assign HMIS ratings to this product based on the hazards of its ingredient(s). Since the customer is most aware of the applications and conditions of use, he must ensure that the proper personal protective equipment is provided consistent with information contained in Section's 7 and 8 of this MSDS. Copyright© 1996-2009 Actio Corporation. All Rights Reserved. To Top of page Black Flag Dry Max Spray Kills Ants Roaches Spiders Kills Biting Asian Beetles Black Flag Brands, LLC Page:6 of 6 Page 68 of 495 Page 68 of 495 Page 68 of 495 Page 68 of 495 ---PAGE BREAK--- BOILERCARE 1012 900133 EMERGENCY HEALTH INFORMATION: 1-[PHONE REDACTED] Outside United States and Canada CALL 1-[PHONE REDACTED] (in USA) 03-October-2005 Material Safety Data Sheet Trade name Supplier Code Date of issue Section 1. Chemical product and company identification BOILERCARE 1012 : : : : Ecolab Inc. Water Care Division 370 N. Wabasha Street St. Paul, MN 55102 1-800-75-WATER Product use : Water Treatment Section 2. Composition, Information on Ingredients Name CAS number % by weight sulfurous acid, monopotassium salt 7773-03-7 20 - 50 Emergency overview Section 3. Hazards identification Physical state Liquid. (Liquid.) WARNING! HARMFUL IF INHALED. CAUSES SEVERE RESPIRATORY TRACT IRRITATION. Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. Avoid breathing vapor or mist. Keep container closed. Use only with adequate ventilation. : : Potential acute health effects Toxic by inhalation. Severely irritating to the respiratory system. Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Eyes Skin Inhalation Ingestion : : : : See toxicological Information (section 11) Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : > 100°C Product does not support combustion. Section 5. Fire fighting measures Flash point : Use an extinguishing agent suitable for surrounding fires. Fire fighting media and instructions Dike area of fire to prevent product run-off. No specific hazard. Special protective equipment for fire-fighters Fire fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full facepiece operated in positive pressure mode. : : Page 69 of 495 Page 69 of 495 Page 69 of 495 Page 69 of 495 ---PAGE BREAK--- BOILERCARE 1012 Page: 2/3 Ventilate area of leak or spill. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment (Section Stop leak if without risk. Prevent entry into sewers, water courses, basements or confined areas. If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid-proof container for disposal. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.-- Environmental precautions Section 6. Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Personal precautions : Methods for cleaning up : Keep out of the reach of children. Keep container closed. Keep container in a cool, well- ventilated area. Keep container closed. Use only with adequate ventilation. Avoid breathing vapor or mist. Wash thoroughly after handling. Section 7. Handling and storage Handling Storage : : Do not store below 0°C Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Section 8. Exposure Controls, Personal Protection Engineering controls Personal protection Consult local authorities for acceptable exposure limits. : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. Eyes Skin Respiratory : : : No protective equipment is needed under normal use conditions. Hands : >100 °C Liquid. (Liquid.) 7.2 (100%) 1.31 (Water = 1) Odorless. Clear. Boiling/condensation point Section 9. Physical and chemical properties Physical state pH Specific gravity Solubility Odor Color : : : : : : : Easily soluble in cold water, hot water. The product is stable. Section 10. Stability and reactivity Stability : reactive to reactive with acids, alkalis. : Reactivity Section 11. Toxicological information Potential chronic health effects Potential acute health effects Toxic by inhalation. Severely irritating to the respiratory system. Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Eyes Skin Inhalation Ingestion : : : : Page 70 of 495 Page 70 of 495 Page 70 of 495 Page 70 of 495 ---PAGE BREAK--- BOILERCARE 1012 Page: 3/3 These products are sulfur oxides (SO 2, Some metallic oxides. Section 12. Ecological information Products of degradation : The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste disposal Section 13. Disposal considerations : Consult your local or regional authorities. Section 14. Transport information - DOT Classification - - Regulatory information UN number Proper shipping name Packing group Class Additional information Not regulated. - APPLIES ONLY DURING ROAD TRANSPORT Any variation of the shipping description based on the packaging is not addressed. Irritating material HCS Classification Section 15. Regulatory information : U.S. Federal regulations : All materials are listed or exempt. TSCA 8(b) inventory : California prop. 65 : No products were found. SARA 302/304/311/312 extremely hazardous substances: None. SARA 302/304 emergency planning and notification: None. Section 16. Other information Hazardous Material Information System 2 0 0 Health Fire hazard Reactivity Personal protection Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Date of issue Date of previous issue 03-October-2005. No Previous Validation. : : : Responsible name : Regulatory Affairs Page 71 of 495 Page 71 of 495 Page 71 of 495 Page 71 of 495 ---PAGE BREAK--- Page 72 of 495 Page 72 of 495 Page 72 of 495 Page 72 of 495 ---PAGE BREAK--- Page 73 of 495 Page 73 of 495 Page 73 of 495 Page 73 of 495 ---PAGE BREAK--- Page 74 of 495 Page 74 of 495 Page 74 of 495 Page 74 of 495 ---PAGE BREAK--- Page 75 of 495 Page 75 of 495 Page 75 of 495 Page 75 of 495 ---PAGE BREAK--- SAFETY DATA SHEET BOILERCARE 1504 922070 1 / 8 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : BOILERCARE 1504 Other means of identification : Not applicable Recommended use : Water treatment chemical Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab Inc. 370 N. Wabasha Street St. Paul, Minnesota USA 55102 1-[PHONE REDACTED] Emergency telephone : 1-[PHONE REDACTED] (US/Canada), 1-[PHONE REDACTED] (outside US) Issuing date : 02/09/2015 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin corrosion : Category 1A Serious eye damage : Category 1 GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : Causes severe skin burns and eye damage. Precautionary Statements : Prevention: Wash skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Wash contaminated clothing before reuse. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Page 76 of 495 Page 76 of 495 Page 76 of 495 Page 76 of 495 ---PAGE BREAK--- SAFETY DATA SHEET BOILERCARE 1504 922070 2 / 8 Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration potassium hydroxide 1310-58-3 5 - 10 2-diethylaminoethanol 100-37-8 1 - 5 SECTION 4. FIRST AID MEASURES In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. If inhaled : Remove to fresh air. Treat Get medical attention if occur. Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to physician : Treat Most important and effects, both acute and delayed : See Section 11 for more detailed information on health effects and SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus Special protective equipment for fire-fighters : Use personal protective equipment. Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Page 77 of 495 Page 77 of 495 Page 77 of 495 Page 77 of 495 ---PAGE BREAK--- SAFETY DATA SHEET BOILERCARE 1504 922070 3 / 8 Personal precautions, protective equipment and emergency procedures : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Use only with adequate ventilation. Wash hands thoroughly after handling. Conditions for safe storage : Do not store near acids. Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 0 °C to 35 °C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Form of exposure Permissible concentration Basis potassium hydroxide 1310-58-3 Ceiling 2 mg/m3 ACGIH Ceiling 2 mg/m3 NIOSH REL 2-diethylaminoethanol 100-37-8 TWA 2 ppm ACGIH TWA 10 ppm 50 mg/m3 NIOSH REL TWA 10 ppm 50 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Wear eye protection/ face protection. Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing Page 78 of 495 Page 78 of 495 Page 78 of 495 Page 78 of 495 ---PAGE BREAK--- SAFETY DATA SHEET BOILERCARE 1504 922070 4 / 8 Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : clear, dark brown Odor : slight pH : 13.0 - 14.0, 100 % Flash point : Not applicable Odor Threshold : No data available Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Relative density : 1.0983 - 1.1383 Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Autoignition temperature : No data available Thermal decomposition : No data available Viscosity, kinematic : No data available Explosive properties : No data available Oxidizing properties : No data available Molecular weight : No data available VOC : No data available SECTION 10. STABILITY AND REACTIVITY Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Page 79 of 495 Page 79 of 495 Page 79 of 495 Page 79 of 495 ---PAGE BREAK--- SAFETY DATA SHEET BOILERCARE 1504 922070 5 / 8 Incompatible materials : Acids Metals Organic materials Bases Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes : Causes serious eye damage. Skin : Causes severe skin burns. Ingestion : Causes digestive tract burns. Inhalation : May cause nose, throat, and lung irritation. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Pain, Corrosion Skin contact : Redness, Pain, Corrosion Ingestion : Corrosion, Abdominal pain Inhalation : Respiratory irritation, Cough Toxicity Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : 4 h Acute toxicity estimate : > 40 mg/l Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Skin corrosion/irritation : No data available Serious eye damage/eye irritation : No data available Respiratory or skin sensitization : Contains an ingredient that can cause asthmatic-like reactions in sulfite-sensitive individuals. Carcinogenicity : No data available Reproductive effects : No data available Germ cell mutagenicity : No data available Teratogenicity : No data available STOT-single exposure : No data available Page 80 of 495 Page 80 of 495 Page 80 of 495 Page 80 of 495 ---PAGE BREAK--- SAFETY DATA SHEET BOILERCARE 1504 922070 6 / 8 STOT-repeated exposure : No data available Aspiration toxicity : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects. Product Toxicity to fish : No data available Toxicity to daphnia and other aquatic invertebrates : No data available Toxicity to algae : No data available Ingredients Toxicity to fish : potassium hydroxide 96 h LC50: 80 mg/l 2-diethylaminoethanol 96 h LC50 Fish: 147 mg/l Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. RCRA - Resource Conservation and Recovery Authorization Act Hazardous waste : D002 (Corrosive) SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Page 81 of 495 Page 81 of 495 Page 81 of 495 Page 81 of 495 ---PAGE BREAK--- SAFETY DATA SHEET BOILERCARE 1504 922070 7 / 8 Land transport (DOT) UN number : 1814 Description of the goods : Potassium hydroxide, solution Class : 8 Packing group : II Environmentally hazardous : no Sea transport (IMDG/IMO) UN number : 1814 Description of the goods : POTASSIUM HYDROXIDE SOLUTION Class : 8 Packing group : II Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity Ingredients CAS-No. Component RQ (lbs) Calculated product RQ (lbs) potassium hydroxide 1310-58-3 1000 11530 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia Inventory of Chemical Substances (AICS) : not determined New Zealand. Inventory of Chemical Substances : not determined Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Japan. ISHL - Inventory of Chemical Substances (METI) : Page 82 of 495 Page 82 of 495 Page 82 of 495 Page 82 of 495 ---PAGE BREAK--- SAFETY DATA SHEET BOILERCARE 1504 922070 8 / 8 not determined Korea. Korean Existing Chemicals Inventory (KECI) : not determined Philippines Inventory of Chemicals and Chemical Substances (PICCS) : not determined China. Inventory of Existing Chemical Substances in China (IECSC) : not determined SECTION 16. OTHER INFORMATION NFPA: HMIS III: Issuing date : 02/09/2015 Version : 1.0 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 3 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 3 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 83 of 495 Page 83 of 495 Page 83 of 495 Page 83 of 495 ---PAGE BREAK--- Page 84 of 495 Page 84 of 495 Page 84 of 495 Page 84 of 495 ---PAGE BREAK--- Page 85 of 495 Page 85 of 495 Page 85 of 495 Page 85 of 495 ---PAGE BREAK--- 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 9 Gladstone Road, Castle Hill, NSW, AUSTRALIA, 2154 (02) 9634 2088 (02) 9634 2088 (02) 9680 4914 [EMAIL REDACTED] http://www.crcind.com.au/ CRC INDUSTRIES (AUST) PTY LIMITED BRAKLEEN (AEROSOL) BRAKE CLEANER • CLEANING AGENT BRAKLEEN (AEROSOL) • CRC BRAKLEEN (AEROSOL) (FORMERLY) • SOLVENT BRAKE CLEANER 01 Apr 2010 Fax Supplier Name Address Telephone Emergency Email Web Site Synonym(s) Use(s) SDS Date Product Name CLASSIFIED AS HAZARDOUS ACCORDING TO ASCC CRITERIA 2. HAZARDS IDENTIFICATION RISK PHRASES R40 Limited evidence of a carcinogenic effect. SAFETY PHRASES S23 Do not breathe gas/fumes/vapour/spray (where applicable). S24/25 Avoid contact with skin and eyes. S36/37 Wear suitable protective clothing and gloves. CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE 1950 2.1 None Allocated None Allocated 2Y 2D1 UN No. Packing Group DG Class Hazchem Code Subsidiary Risk(s) EPG 3. COMPOSITION/ INFORMATION ON INGREDIENTS Ingredient Formula CAS No. Content TETRACHLOROETHYLENE (PERCHLOROETHYLENE) C2-Cl4 127-18-4 30-60% DICHLOROMETHANE (METHYLENE CHLORIDE) C-H2-Cl2 75-09-2 10-30% LIQUEFIED PETROLEUM GAS (LPG) C3H8/C3H6/C4H10 68476-85-7 10-30% PETROLEUM DISTILLATE(S) Not Available Not Available 30-60% CARBON DIOXIDE (PROPELLANT) Not Available 124-38-9 1-10% Page 1 of 5 Reviewed: 01 Apr 2010 Printed: 13 Apr 2010 RMT Page 86 of 495 Page 86 of 495 Page 86 of 495 Page 86 of 495 ---PAGE BREAK--- BRAKLEEN (AEROSOL) Product Name Eye If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor, or for at least 15 minutes. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air- line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form. Advice to Doctor Treat 4. FIRST AID MEASURES Fire and Explosion Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. Extinguishing Dry agent, carbon dioxide or foam. Prevent contamination of drains or waterways. Flammability Highly flammable. May evolve toxic gases (chlorides, fluorides, phosgene, carbon oxides, hydrocarbons) when heated to decomposition. Vapour may form explosive mixtures with air. Eliminate all ignition sources inluding cigarettes, open flames, spark producing switches/tools, pilot lights, heaters, naked lights etc. when handling. Aerosol cans may explode when heated above 50°C. Hazchem Code 2Y 5. FIRE FIGHTING MEASURES Spillage Contact emergency services where appropriate. Use personal protective equipment. Clear area of all unprotected personnel. Ventilate area where possible. Contain spillage, then cover / absorb spill with non-combustible absorbant material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Eliminate all ignition sources. Handling Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, alkalis, active metals, amines, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Storage Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 6. ACCIDENTAL RELEASE MEASURES 7. STORAGE AND HANDLING 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION TWA STEL ppm mg/m3 ppm mg/m3 Exposure Stds Ingredient Reference Carbon dioxide ASCC (AUS) 5000 9000 Carbon dioxide in coal mines ASCC (AUS) 12500 30000 Methylene chloride ASCC (AUS) 50 174 LIQUEFIED PETROLEUM GAS (LPG) ASCC (AUS) 1000 1800 1000 1800 Oil mists ASCC (AUS) 5 Perchloroethylene ASCC (AUS) 50 [PHONE REDACTED] Ingredient Reference Sampling Time Determinant BEI Biological Limits DICHLOROMETHANE (METHYLENE CHLORIDE) ACGIH BEI Dichloromethane in urine End of shift 0.3 mg/L TETRACHLOROETHYLEN E (PERCHLOROETHYLENE) ACGIH BEI Tetrachloroethylene in end -exhaled air Prior to last shift of workweek 5 ppm Page 2 of 5 Reviewed: 01 Apr 2010 Printed: 13 Apr 2010 RMT Page 87 of 495 Page 87 of 495 Page 87 of 495 Page 87 of 495 ---PAGE BREAK--- BRAKLEEN (AEROSOL) Product Name Ingredient Reference Sampling Time Determinant BEI ACGIH BEI Tetrachloroethylene in blood Prior to last shift of workweek 0.5 mg/L ACGIH BEI Trichloroacetic acid in urine End of shift at end of workweek 3.5 mg/L Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proof extraction ventilation is recommended. Flammable/explosive vapours may accumulate in poorly ventilated areas. Vapours are heavier than air and may travel some distance to an ignition source and flash back. Maintain vapour levels below the recommended exposure standard. Maintain vapour levels below the recommended exposure standard. Wear splash-proof goggles and viton or PVA gloves. When using large quantities or where heavy contamination is likely, wear: coveralls. Where an inhalation risk exists, wear: an Air-line or a Type A-Class P1 (Organic gases/vapours and Particulate) respirator. PPE 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance CLEAR COLOURLESS LIQUID (AEROSOL DISPENSED) Solubility (Water) SOLUBLE Odour ETHEREAL ODOUR Specific Gravity 1.07 pH NOT AVAILABLE % Volatiles 100 % Vapour Pressure 26.6 kPa @ 20°C Flammability HIGHLY FLAMMABLE Vapour Density > 1 (Air = 1) Flash Point 10°C Boiling Point 40°C (Initial) Upper Explosion Limit 22 % Melting Point NOT AVAILABLE Lower Explosion Limit 1.4 % Evaporation Rate NOT AVAILABLE 10. STABILITY AND REACTIVITY Material to Avoid Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), alkalis (eg. hydroxides), metals, heat and ignition sources. Will attack most forms of plastic. Decomposition May evolve toxic gases (chlorides, fluorides, phosgene, carbon oxides, hydrocarbons) when heated to decomposition. Health Hazard Summary Toxic - irritant. This product has the potential to cause adverse health effects. Use safe work practices to avoid eye or skin contact and inhalation. Over exposure may result in central nervous system (CNS), liver, kidney and lung damage. Tetrachloroethylene is classified as probably carcinogenic to humans (IARC Group 2A), and dichloromethane is classified as a possible human carcinogen (IARC Group 2B). Individuals with pre-existing respiratory impairment (eg asthmatics) or nervous system, liver and kidney disease are advised to avoid exposure. Eye Irritant. Contact may result in irritation, lacrimation, pain, redness and conjunctivitis. May result in burns with prolonged contact. Inhalation Toxic - irritant. Over exposure may result in irritation of the nose and throat, coughing, nausea, dizziness and headache. High level exposure may result in breathing difficulties, anaesthesia, cardiac pulmonary oedema, unconsciousness and possible respiratory failure. Chronic exposure may result in kidney, liver and CNS damage. Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis. May be absorbed through skin with harmful effects. Ingestion Toxic. Ingestion may result in nausea, vomiting, abdominal pain, dizziness, fatigue and diarrhoea. Ingestion of 11. TOXICOLOGICAL INFORMATION Page 3 of 5 Reviewed: 01 Apr 2010 Printed: 13 Apr 2010 RMT Page 88 of 495 Page 88 of 495 Page 88 of 495 Page 88 of 495 ---PAGE BREAK--- BRAKLEEN (AEROSOL) Product Name large quantities may result in liver and kidney damage, and unconsciousness. Aspiration may result in chemical pneumonitis and pulmonary oedema. Toxicity Data TETRACHLOROETHYLENE (PERCHLOROETHYLENE) (127-18-4) LCLo (Inhalation): 4000 ppm/4 hour (rat) LD50 (Ingestion): 2629 mg/kg (rat) LD50 (Intraperitoneal): 2100 mg/kg (dog) LD50 (Skin): 65 gm/kg (mouse) LDLo (Ingestion): 4000 mg/kg (dog) LDLo (Subcutaneous): 2200 mg/kg (rabbit) TDLo (Ingestion): 195 g/kg/50 Weeks intermittent (mouse - cancer) DICHLOROMETHANE (METHYLENE CHLORIDE) (75-09-2) LC50 (Inhalation): 52 g/m3 (rat) LCLo (Inhalation): 5000 ppm/2 hours (guinea pig) LD50 (Ingestion): 1600 mg/kg (rat) LD50 (Subcutaneous): 6460 mg/kg (mouse) LDLo (Ingestion): 357 mg/kg human (CNS effects) LDLo (Subcutaneous): 2700 mg/kg (rabbit) TCLo (Inhalation): 500 ppm/8 hours (human - euphoria) CARBON DIOXIDE (PROPELLANT) (124-38-9) LCLo (Inhalation): 9 pph/5M (human) Environment If dichloromethane released into the atmosphere will degrade by reaction with hydroxyl radicals (half life: 19 to 194 days). Dichloromethane evaporates from the near surface soil and water surface. Biodegradation is possible but will probably be quite slow when compared with the evaporation rate. 12. ECOLOGICAL INFORMATION Waste Disposal For small amounts absorb contents with sand or similar and dispose of to an approved landfill site. Do not puncture or incinerate aerosol cans. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation. 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE 1950 2.1 None Allocated None Allocated 2Y 2D1 Shipping Name UN No. Packing Group DG Class Hazchem Code Subsidiary Risk(s) EPG AEROSOLS Poison Schedule Classified as a Schedule 6 (S6) Poison using the criteria in the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS). 15. REGULATORY INFORMATION Additional Information WORK PRACTICES - SOLVENTS: Organic solvents may present both a health and flammability hazard. It is recommended that engineering controls should be adopted to reduce exposure where practicable (for example, if using indoors, ensure explosion proof extraction ventilation is available). Flammable or combustible liquids with explosive limits have the potential for ignition from static discharge. Refer to AS 1020 (The control of undesirable static electricity) and AS 1940 (The storage and handling of flammable and combustible liquids) for control procedures. SYNERGISM - ANTAGONISM: Ingredients in this product may act together to aggravate or reduce adverse effects. Accordingly the time weighted average concentration (TWA) provided for single ingredients should be considered as a guide only and all due care exercised when handling. 16. OTHER INFORMATION Page 4 of 5 Reviewed: 01 Apr 2010 Printed: 13 Apr 2010 RMT Page 89 of 495 Page 89 of 495 Page 89 of 495 Page 89 of 495 ---PAGE BREAK--- BRAKLEEN (AEROSOL) Product Name IARC - GROUP 2B - POSSIBLE HUMAN CARCINOGEN: This product contains an ingredient which has demonstrated sufficient evidence to have been classified by the International Agency for Research into Cancer (IARC) as possibly carcinogenic to humans and whose use should be strictly monitored and controlled. DICHLOROMETHANE VAPOUR may only produce a flammable mixture with air in a vacuum (1.7 bar @ 27°C). It may produce a flammable mixture with pure oxygen between 15.5% and 66.4% dichloromethane. ABBREVIATIONS: ADB - Air-Dry Basis. BEI - Biological Exposure Indice(s) CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. CNS - Central Nervous System. EINECS - European INventory of Existing Commercial chemical Substances. IARC - International Agency for Research on Cancer. M - moles per litre, a unit of concentration. mg/m3 - Milligrams per cubic metre. NOS - Not Otherwise Specified. NTP - National Toxicology Program. OSHA - Occupational Safety and Health Administration. pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm - Parts Per Million. RTECS - Registry of Toxic Effects of Chemical Substances. TWA/ES - Time Weighted Average or Exposure Standard. HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a Chem Alert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate. PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this Chem Alert report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the manufacturer's Safety Data Sheet It is based on information concerning the product which has been provided to RMT by the manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [EMAIL REDACTED] Web: www.rmt.com.au 01 Apr 2010 End of Report SDS Date: Page 5 of 5 Reviewed: 01 Apr 2010 Printed: 13 Apr 2010 RMT Page 90 of 495 Page 90 of 495 Page 90 of 495 Page 90 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 1 Revision Date 4th March, 2015 Revision 6 Revision 6 SAFETY DATA SHEET BROMICIDE TABLETS 1. IDENTIFICATION Product Name BROMICIDE TABLETS Chemical Name 1-Bromo-3-chloro-5, Product No. 100404, 100408, 100411, 100870, 100423, 101335 Identification No. 1479 Identified uses Biocides for water treatment. BWA Water Additives US LLC Supplier 1979 Lakeside Parkway Suite 925, Tucker, GA30084 USA T: +1 [PHONE REDACTED] T: +1 [PHONE REDACTED] E: [EMAIL REDACTED] Emergency Telephone CHEMTREC Phone: 1-[PHONE REDACTED] 2. HAZARD(S) IDENTIFICATION EMERGENCY OVERVIEW EPA REGISTRATION No: 83451-4 EPA SIGNAL WORD: DANGER. EPA FIFRA Labelling information in Section 15 (PRN 2012-1) Appearance Tablet. Color White / off-white. Odor Slight odor. Halogen GHS Pictogram Signal Word Danger Hazard Statements H272 May intensify fire; oxidizer. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. Precautionary Statements P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+330+331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Page 91 of 495 Page 91 of 495 Page 91 of 495 Page 91 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 2 Revision 6 BROMICIDE TABLETS P310 Immediately call a POISON CENTER or doctor/physician. P501 Dispose of contents/container in accordance with national regulations. Contains GHS Classification Physical and Chemical Hazards Ox. Sol. 3 - H272 Human health Acute Tox. 4 - H302;Skin Corr. 1B - H314;Skin Sens. 1 - H317 Environment Aquatic Acute 1 - H400 WHMIS Label WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS Oxidizing Material. Corrosive Material. Controlled Product Classification Canadian WHMIS Classification C E Inhalation May cause irritation to the respiratory system. Ingestion Harmful if swallowed. Skin Contact Causes burns. May cause sensitization by skin contact. Eye Contact Causes burns. Health Warnings This substance is corrosive. Contact with acids liberates toxic gas. Route Of Entry Skin and/or eye contact. Ingestion. Inhalation. Other Health Effects This substance has no evidence of carcinogenic properties. 3. COMPOSITION/INFORMATION ON INGREDIENTS 60-100% CAS No.: 16079-88-2 EC No.: 240-230-0 GHS Classification Ox. Sol. 3 - H272; Acute Tox. 4 - H302; Skin Corr. 1B - H314; Skin Sens. 1 - H317; Aquatic Acute 1 - H400 Composition Comments 1-bromo-3-chloro-5, 4. FIRST-AID MEASURES Description of first aid measures Inhalation Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. Get medical attention. Ingestion DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical attention immediately! Skin Contact Remove contaminated clothing. Rinse the skin immediately with lots of water. Get medical attention immediately! Page 92 of 495 Page 92 of 495 Page 92 of 495 Page 92 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 3 Revision 6 BROMICIDE TABLETS Eye Contact Remove victim immediately from source of exposure. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately Most important and effects , both acute and delayed Inhalation Inhaltion of dust may cause irritation of the respiritory tract. Ingestion May cause stomach pain or vomiting. May cause chemical burns in mouth and throat. Due to the physical nature of this material it is unlikely that swallowing will occur. Skin Contact Chemical burns. Burning pain and severe corrosive skin damage. Eye Contact Extreme irritation of eyes and mucous membranes, including burning and tearing. Indication of any immediate medical attention and special treatment needed Notes To The Physician If lavage is performed suggest endotracheal and/or esophageal control.Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. The decision of whether to induce vomiting or not should be made by a physician.Chemical eye burns may require extended irrigation.Obtain prompt consultation preferably from an opthalmologist.If burn is present, treat as any thermal burn, after decontamination.No specific antidote.Treatment of exposure should be directed at the control of and the clinical condition of the patient. 5. FIRE-FIGHTING MEASURES Auto Ignition Temperature Not available. Flammability Limit - Lower(%) Not applicable. Flammability Limit - Upper(%) Not applicable. Flash point Not available. Extinguishing Media Use: Water spray, fog or mist. Alcohol resistant foam. DO NOT use CO2 or dry chemicals. Unsuitable extinguishing media Carbon dioxide (CO2). Dry chemicals. Unusual Fire & Explosion Hazards Fire causes formation of toxic gases. Specific Hazards Toxic gases/vapors/fumes of: Bromine. Chlorine. Oxides of: Carbon. Nitrogen. Special Fire Fighting Procedures Move container from fire area if it can be done without risk. Keep run-off water out of sewers and water sources. Dike for water control. Protective Equipment For Fire-Fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Follow precautions for safe handling described in this material safety data sheet. For personal protection, see section 8. Environmental Precautions Avoid release to the environment. To prevent release, place container with damaged side up. Spill Clean Up Methods Provide ventilation and confine spill. Do not allow runoff to sewer. Collect and reclaim or dispose in sealed containers in licensed waste. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Wash thoroughly after dealing with a spillage. Avoid generation and spreading of dust. Avoid contact with water. Page 93 of 495 Page 93 of 495 Page 93 of 495 Page 93 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 4 Revision 6 BROMICIDE TABLETS Reference to other sections For personal protection, see section 8. For waste disposal, see section 13. 7. HANDLING AND STORAGE Handling Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Do not use in confined spaces without adequate ventilation and/or respirator. Avoid spilling, skin and eye contact. Avoid acids, moisture, and combustible materials. Avoid handling which leads to dust formation. Storage Store in closed original container in a dry, cool and well-ventilated place. Keep containers closed. Protect from light, including direct sunrays. Keep away from heat, sparks and open flame. Storage Class Oxidizer storage. NFPA STORAGE CLASSIFICATION:NFPA Oxidiser Class 2. Specific end use(s) The identified uses for this product are detailed in Section 1.2. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredient Comments No exposure limits noted for ingredient(s). Protective Equipment Process Conditions Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station. Engineering Measures All handling to take place in well-ventilated area. Respiratory Equipment Use specified dust masks. Hand Protection Selection of a suitable glove depends on work conditions and whether the product is present on its own or in combination with other substances. Use protective gloves made of: Neoprene, nitrile, polyethylene or PVC. Gloves should be replaced immediately if signs of degradation are observed. Eye Protection Use approved safety goggles or face shield. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Wear dust masks in dusty areas. Hygiene Measures No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. Isolate contaminated clothing and wash before reuse. Skin Protection Wear apron or protective clothing in case of contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Tablet. Color White / off-white. Odor Slight odor. Halogen Solubility soluble in water. Initial boiling point and boiling range Not available. Page 94 of 495 Page 94 of 495 Page 94 of 495 Page 94 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 5 Revision 6 BROMICIDE TABLETS Melting point 156 - 162 Relative density Not applicable. Bulk Density ~900 kg/m3 Vapor density (air=1) Not available. Vapor pressure 0.0038 Pa 25°C Evaporation rate Not available. Evaporation Factor Not available. pH-Value, Conc. Solution Not available. pH-Value, Diluted Solution 3.5 @ 0.15 % Viscosity Not available. Solubility Value (G/100G H2O@20°C) 0.15 Decomposition temperature 162°C Odour Threshold, Lower Not available. Odour Threshold, Upper Not available. Flash point Not available. Auto Ignition Temperature Not available. Flammability Limit - Lower(%) Not applicable. Flammability Limit - Upper(%) Not applicable. Partition Coefficient (N-Octanol/Water) log Pow 0.35 Explosive properties Scientifically unjustified. This material is oxidising keep away from fire/heat/sources of ignition. Not available. 10. STABILITY AND REACTIVITY Reactivity This material has oxidising properties. Stability Stable under normal temperature conditions. Avoid Moisture. Hazardous Polymerisation Will not polymerise. Conditions To Avoid Generates toxic gas in contact with acid. Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolonged periods of time. Materials To Avoid Strong acids. Strong alkalis. Strong reducing agents. Hazardous Decomposition Products Toxic gases/vapors/fumes of: Hydrogen bromide (HBr). Bromine. Hydrogen chloride (HCl). Chlorine. Oxides of: Carbon. Nitrogen. Page 95 of 495 Page 95 of 495 Page 95 of 495 Page 95 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 6 Revision 6 BROMICIDE TABLETS 11. TOXICOLOGICAL INFORMATION Other Health Effects This substance has no evidence of carcinogenic properties. Acute toxicity : Acute Toxicity (Oral LD50) 578 mg/kg Rat Acute Toxicity (Dermal LD50) > 2000 mg/kg Rabbit Germ cell mutagenicity : Genotoxicity - In Vitro Ames Test Negative. 12. ECOLOGICAL INFORMATION Ecotoxicity The product contains a substance which is very toxic to aquatic organisms. Acute Toxicity - Fish LC50 96 hours 0.87 mg/l mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates EC50 48 hours 0.46 mg/l Daphnia magna Degradability DMH is readily biodegradable in a CO2 Evolution study and passes the 10-day window criteria. DMH has also been shown to be rapidly degraded in a water/sediment system. Chemical Oxygen Demand 1.005 g O2/g substance Bioaccumulative potential Low bioaccumulation potential Partition coefficient log Pow 0.35 Mobility: Information not available. Results of PBT and vPvB assessment An assessment of the substance's properties indicates it is neither a PBT or vPVB. Acute Toxicity. Lc50 96 Hours, Mg/L 640 American Oyster 13. DISPOSAL CONSIDERATIONS Waste Management When handling waste, consideration should be made to the safety precautions applying to handling of the product. Disposal Methods Dispose of waste and residues in accordance with local authority requirements. Absorb in vermiculite or dry sand and dispose of at a licenced hazardous waste collection point. Liquid material should be incinerated. Material absorbed onto sand or earth should be disposed of as solid waste in accordance with local regulations. Empty packaging may contain product residues and due consideration should be given prior to disposal. 14. TRANSPORT INFORMATION UN No. (DOT/TDG) 1479 NA No. 1479 Page 96 of 495 Page 96 of 495 Page 96 of 495 Page 96 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 7 Revision 6 BROMICIDE TABLETS UN No. (IMDG) 1479 UN No. (ICAO) 1479 DOT Proper Shipping Name OXIDIZING SOLID, N.O.S., (contains 5.1, PGIII, MARINE POLLUTANT TDG Proper Shipping Name OXIDIZING SOLID, N.O.S., (contains 5.1, PGIII, MARINE POLLUTANT DOT Hazard Class 5.1 DOT Hazard Label Oxidiser TDG Class 5.1 IMDG Class 5.1 ICAO Class 5.1 Transport Labels OXIDIZING AGENT 5.1 DOT Pack Group III TDG Pack Group III IMDG Pack Group III Air Pack Group III Environmentally Hazardous Substance/Marine Pollutant EMS F-A, S-Q Markings MARINE POLLUTANT Transport in Bulk according to Annex II of MARPOL 73/78 and the IBC Code Notes Not applicable. Classification Code (Adr) O2 15. REGULATORY INFORMATION Regulatory Status (US) SECTION 313: This product does not contain toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372. PROPOSITION 65: This product does not contain chemicals considered by the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 as causing cancer or reproductive toxicity and for which warnings are now required. TSCA: The ingredients of this product are on the TSCA Inventory. TSCA Export Notification Section 12b. EPA REGISTRATION NUMBER: 83451-4 Regulatory References 29 CFR 1910.1010 Federal Regulations (OSHA Standard). US Federal Regulations Page 97 of 495 Page 97 of 495 Page 97 of 495 Page 97 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 8 Revision 6 BROMICIDE TABLETS SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) None of the ingredients are listed. SARA 313 Emission Reporting None of the ingredients are listed. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins None of the ingredients are listed. Massachusetts "Right To Know" List None of the ingredients are listed. Rhode Island "Right To Know" List None of the ingredients are listed. Minnesota "Right To Know" List None of the ingredients are listed. New Jersey "Right To Know" List None of the ingredients are listed. "Right To Know" List None of the ingredients are listed. Fifra Information This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: DANGER. Causes irreversible eye damage and skin burns. Harmful if swallowed. Irritating to nose and throat. Do not get in eyes, on skin, or on clothing. International Inventories EU - EINECS/ELINCS The following ingredients are listed. 1-Bromo-3-chloro-5, Canada – DSL/NDSL All ingredients are listed or exempt. US - TSCA All ingredients are listed or exempt. US – TSCA 12(b) Export Notification All ingredients are listed or exempt. Australia - AICS All ingredients are listed or exempt. Japan – MITI All ingredients are listed or exempt. Korea - KECI All ingredients are listed or exempt. China - IECSC All ingredients are listed or exempt. Phillippines – PICCS All ingredients are listed or exempt. 16. OTHER INFORMATION Page 98 of 495 Page 98 of 495 Page 98 of 495 Page 98 of 495 ---PAGE BREAK--- Report Date : 19/03/2015 9 / 9 Revision 6 BROMICIDE TABLETS HEALTH FLAMMABILITY PHYSICAL PERSONAL PROTECTION C 1 1 3 HAZARDOUS MATERIAL INFORMATION SYSTEM (HMIS) NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HEALTH SPECIAL OX FIRE INSTABILITY General Information For advice on chemical emergencies, spillages, fires or first aid in relation to this product please contact the relevant emergency number below : EU/English Speakers - +44 1235 239 670 (NCEC) Arabic Speakers - +44 1235 239 671 Asia/Pacific countries - +65 3158 1074 Within Mainland China: +86 532 8388 9090 (NRCC). To/From China: +86 10 5100 3039 (NCEC) Revision Comments Conversion to GHS (HCS 2012 / WHMIS 2015) Issued By BWA Water Additives Regulatory Group, +44(0)[PHONE REDACTED] Revision Date 4th March, 2015 Revision 6 Sds No. 10804 Disclaimer For safety reasons it is IMPERATIVE that customers:- 1. Ensure that all those within their control who use the products are supplied with all relevant information contained within the Safety Data Sheet and Technical Bulletin concerning the applications for which the product is designed and any instructions and warnings contained therein. 2. Consult BWA Water Additives before using or supplying the product for any other applications. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not therefore be construed as guaranteeing specific properties. Page 99 of 495 Page 99 of 495 Page 99 of 495 Page 99 of 495 ---PAGE BREAK--- Page 100 of 495 Page 100 of 495 Page 100 of 495 Page 100 of 495 ---PAGE BREAK--- Page 101 of 495 Page 101 of 495 Page 101 of 495 Page 101 of 495 ---PAGE BREAK--- Page 102 of 495 Page 102 of 495 Page 102 of 495 Page 102 of 495 ---PAGE BREAK--- Page 103 of 495 Page 103 of 495 Page 103 of 495 Page 103 of 495 ---PAGE BREAK--- Page 104 of 495 Page 104 of 495 Page 104 of 495 Page 104 of 495 ---PAGE BREAK--- Page 105 of 495 Page 105 of 495 Page 105 of 495 Page 105 of 495 ---PAGE BREAK--- Page 106 of 495 Page 106 of 495 Page 106 of 495 Page 106 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 19-Jul-2012 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code DA8060 Product name BRRR-Eaker Recommended Use Lubricant Supplier Drummond, A Lawson Brand Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Asthma. Allergies. Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes Contact with eyes may cause irritation. Causes burns. Frostbite. Pain. Tearing. Redness. Conjunctivitis. Skin May cause the following effects: . Skin Irritation. Frostbite. Skin burns. Repeated or prolonged exposure may cause:. May cause skin irritation. Exposure can dry the skin. Inhalation Harmful by inhalation. May cause irritation of respiratory tract. Possible May cause the following effects. Drowsiness . Dizziness. Aspiration hazard. Chemical pneumonitis. Ingestion No hazard under normal industrial and institutional use. May be harmful if swallowed. Aspiration hazard. May cause severe lung damage if aspirated into the lungs from ingestion or vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % 1,1-Difluoroethane 75-37-6 60-100 Methylisobutyl ketone 108-10-1 1-5 Oleic Acid 112-80-1 1-5 4. FIRST AID MEASURES General advice S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Show this safety data sheet to the doctor in attendance. Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with plenty of water. Remove contaminated clothing and footwear. Wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to physician of poisoning may not appear for several hours. Keep under medical supervision for at least 48 hours. 5. FIRE FIGHTING MEASURES Flash point °C -58 Flash point °F -72 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Dry powder. Foam. Carbon dioxide. Extinguishing media which must NOT be used for safety reasons Do not use water. Do not use a solid water stream as it may scatter and spread fire . Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special Fire-Fighting Procedures Keep people away from and upwind of spill/leak. Specific hazards Flammable . Page 1 / 4 Emergency Overview Flammable. Harmful by inhalation. May cause eye/skin irritation. Contents under pressure. CONTAINER MAY EXPLODE IF HEATED . Page 107 of 495 Page 107 of 495 Page 107 of 495 Page 107 of 495 ---PAGE BREAK--- Fire and Explosion Hazards CONTAINER MAY EXPLODE IF HEATED . Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Environmental precautions Concentrated vapors of this product are heavier than air and will collect in low areas, pits, storage tanks and other confined spaces. Do not enter those areas. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Evacuate area of unprotected and unnecessary personnel. Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Eliminate all sources of ignition. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use caution as spill may create a slip hazard. Clean up by sweeping or vacuum. Place in suitable container for disposal as hazardous waste. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Allow to evaporate. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Do not smoke. Avoid contact with skin and eyes. Do not swallow. Do not breathe vapors or spray mist. Avoid breathing fumes. Use in a well ventilated area. Handle and open container with care. When using, do not eat, drink or smoke. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Do not puncture or incinerate. Storage Keep out of the reach of children. Keep containers closed in a cool, well-ventilated place. Store in temperatures below 120 degrees F (50 degrees C) . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) 1,1- Difluoroethan e - - - - Methylisobutyl ketone 100 ppm 410 mg/m3 - 20 ppm 75 ppm Oleic Acid - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures General industrial hygiene practice. When using, do not eat, drink or smoke. A safety shower and eye wash station should be available for emergency use. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Protective gloves. Eye protection S39 - Wear eye/face protection. Use safety eyewear designed to protect against splash of liquids. Skin and body protection Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless - Light yellow Odor Characteristic Odor Threshold No information available pH Not Applicable Specific Gravity 0.91 Vapor pressure No data available Vapor density >1 (Air = 1) Evaporation Rate No data available Water solubility Negligible VOC Content 4.8% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C -58 Flash point °F -72 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Heating may cause an explosion. Conditions to avoid Avoid heat. Do not store or use near incompatible materials. Incompatability Oxidizers. Bases. Alkali metals. Page 2 / 4 Product code DA8060 Product name BRRR-Eaker Page 108 of 495 Page 108 of 495 Page 108 of 495 Page 108 of 495 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Hydrofluoric acid. Carbonyl Fluoride. Polymerization Stable under normal storage conditions. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) 1,1- Difluoroethane 75-37-6 - - - Methylisobutyl ketone 108-10-1 2080 mg/kg 16000 mg/kg 8.2 mg/L Oleic Acid 112-80-1 25 g/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns 1,1- Difluoroethan e Not Listed Not Listed Not Listed Not Listed Not Listed Methylisobutyl ketone A3 Group 2B Not Listed Not Listed Listed Oleic Acid Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Harmful to aquatic organisms Do not let product enter drains 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Methylisobutyl ketone Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 1,1-Difluoroethane Listed Not Listed Not Listed Methylisobutyl ketone Listed Listed Carcinogen Oleic Acid Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA 1,1-Difluoroethane X X - X Methylisobutyl ketone X X - X Oleic Acid X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 2 Flammability - 3 Reactivity - 0 HMIS Health - 2 Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=79.6 mg/L (5 min) Product name BRRR-Eaker Water Flea Data Daphnia magna EC50=170 mg/L (48 h) Methylisobutyl ketone Product code DA8060 Page 109 of 495 Page 109 of 495 Page 109 of 495 Page 109 of 495 ---PAGE BREAK--- 16. OTHER INFORMATION Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name BRRR-Eaker Product code DA8060 Page 110 of 495 Page 110 of 495 Page 110 of 495 Page 110 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 19-Jul-2012 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code DA8060 Product name BRRR-Eaker Recommended Use Lubricant Supplier Drummond, A Lawson Brand Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Asthma. Allergies. Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes Contact with eyes may cause irritation. Causes burns. Frostbite. Pain. Tearing. Redness. Conjunctivitis. Skin May cause the following effects: . Skin Irritation. Frostbite. Skin burns. Repeated or prolonged exposure may cause:. May cause skin irritation. Exposure can dry the skin. Inhalation Harmful by inhalation. May cause irritation of respiratory tract. Possible May cause the following effects. Drowsiness . Dizziness. Aspiration hazard. Chemical pneumonitis. Ingestion No hazard under normal industrial and institutional use. May be harmful if swallowed. Aspiration hazard. May cause severe lung damage if aspirated into the lungs from ingestion or vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % 1,1-Difluoroethane 75-37-6 60-100 Methylisobutyl ketone 108-10-1 1-5 Oleic Acid 112-80-1 1-5 4. FIRST AID MEASURES General advice S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Show this safety data sheet to the doctor in attendance. Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with plenty of water. Remove contaminated clothing and footwear. Wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to physician of poisoning may not appear for several hours. Keep under medical supervision for at least 48 hours. 5. FIRE FIGHTING MEASURES Flash point °C -58 Flash point °F -72 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Dry powder. Foam. Carbon dioxide. Extinguishing media which must NOT be used for safety reasons Do not use water. Do not use a solid water stream as it may scatter and spread fire . Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special Fire-Fighting Procedures Keep people away from and upwind of spill/leak. Specific hazards Flammable . Page 1 / 4 Emergency Overview Flammable. Harmful by inhalation. May cause eye/skin irritation. Contents under pressure. CONTAINER MAY EXPLODE IF HEATED . Page 111 of 495 Page 111 of 495 Page 111 of 495 Page 111 of 495 ---PAGE BREAK--- Fire and Explosion Hazards CONTAINER MAY EXPLODE IF HEATED . Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Environmental precautions Concentrated vapors of this product are heavier than air and will collect in low areas, pits, storage tanks and other confined spaces. Do not enter those areas. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Evacuate area of unprotected and unnecessary personnel. Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Eliminate all sources of ignition. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use caution as spill may create a slip hazard. Clean up by sweeping or vacuum. Place in suitable container for disposal as hazardous waste. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Allow to evaporate. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Do not smoke. Avoid contact with skin and eyes. Do not swallow. Do not breathe vapors or spray mist. Avoid breathing fumes. Use in a well ventilated area. Handle and open container with care. When using, do not eat, drink or smoke. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Do not puncture or incinerate. Storage Keep out of the reach of children. Keep containers closed in a cool, well-ventilated place. Store in temperatures below 120 degrees F (50 degrees C) . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) 1,1- Difluoroethan e - - - - Methylisobutyl ketone 100 ppm 410 mg/m3 - 20 ppm 75 ppm Oleic Acid - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures General industrial hygiene practice. When using, do not eat, drink or smoke. A safety shower and eye wash station should be available for emergency use. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Protective gloves. Eye protection S39 - Wear eye/face protection. Use safety eyewear designed to protect against splash of liquids. Skin and body protection Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless - Light yellow Odor Characteristic Odor Threshold No information available pH Not Applicable Specific Gravity 0.91 Vapor pressure No data available Vapor density >1 (Air = 1) Evaporation Rate No data available Water solubility Negligible VOC Content 4.8% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C -58 Flash point °F -72 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Heating may cause an explosion. Conditions to avoid Avoid heat. Do not store or use near incompatible materials. Incompatability Oxidizers. Bases. Alkali metals. Page 2 / 4 Product code DA8060 Product name BRRR-Eaker Page 112 of 495 Page 112 of 495 Page 112 of 495 Page 112 of 495 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Hydrofluoric acid. Carbonyl Fluoride. Polymerization Stable under normal storage conditions. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) 1,1- Difluoroethane 75-37-6 - - - Methylisobutyl ketone 108-10-1 2080 mg/kg 16000 mg/kg 8.2 mg/L Oleic Acid 112-80-1 25 g/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns 1,1- Difluoroethan e Not Listed Not Listed Not Listed Not Listed Not Listed Methylisobutyl ketone A3 Group 2B Not Listed Not Listed Listed Oleic Acid Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Harmful to aquatic organisms Do not let product enter drains 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Methylisobutyl ketone Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 1,1-Difluoroethane Listed Not Listed Not Listed Methylisobutyl ketone Listed Listed Carcinogen Oleic Acid Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA 1,1-Difluoroethane X X - X Methylisobutyl ketone X X - X Oleic Acid X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 2 Flammability - 3 Reactivity - 0 HMIS Health - 2 Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=79.6 mg/L (5 min) Product name BRRR-Eaker Water Flea Data Daphnia magna EC50=170 mg/L (48 h) Methylisobutyl ketone Product code DA8060 Page 113 of 495 Page 113 of 495 Page 113 of 495 Page 113 of 495 ---PAGE BREAK--- 16. OTHER INFORMATION Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name BRRR-Eaker Product code DA8060 Page 114 of 495 Page 114 of 495 Page 114 of 495 Page 114 of 495 ---PAGE BREAK--- Page 115 of 495 Page 115 of 495 Page 115 of 495 Page 115 of 495 ---PAGE BREAK--- Page 116 of 495 Page 116 of 495 Page 116 of 495 Page 116 of 495 ---PAGE BREAK--- Acuity Specialty Products Group, Inc. P.O. Box 1060 Cartersville, GA 30120 1-[PHONE REDACTED] Section 1. Chemical Product and Company Identification Material Safety Data Sheet and Safe Handling and Disposal Information Product name Carpet Spot Remover Emergency Telephone Numbers Prepared by Compliance Services Group Acuity Specialty Products Group 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Date of issue 06/09/03 Product Code Supersedes For MSDS Information: Compliance Services (404) 352-1680 For a Medical Emergency: INFOTRAC (877) 541-2016 (Toll Free - Calls Recorded) For a Transportation Emergency: CHEMTREC (800) 424-9300 (Toll Free - Calls Recorded) ETHYLENE GLYCOL MONOBUTYL ETHER; 2-butoxyethanol; butyl cellosolve 111-76-2 15-25 ACGIH TLV (United States). Skin TWA: 20 ppm Form: Vapor OSHA PEL (United States). Skin TWA: 25 ppm Form: Vapor BLEND OF ISOBUTANE, PROPANE & n-BUTANE 75-28-5; 74-98-6; 106-97-8 1-5 ACGIH TLV (United States). TWA: 800 ppm OSHA PEL (United States). TWA: 1000 ppm Section 2. Composition, Information on Ingredients Name of Hazardous Ingredients CAS # % by Weight Exposure Limits Reactivity Fire Hazard B 0 0 1 Personal Protection HMIS Health Repeated or prolonged exposure to the substance can produce damage to the liver, kidneys, and red blood cells. Eye contact. Inhalation. Section 3. Hazards Identification Routes of Entry Acute Effects Direct inhalation of the spray mist may produce irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Hazardous in case of eye contact (irritant). Ingestion not likely under normal use conditions. Hazardous in case of skin contact (irritant, permeator). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Harmful if absorbed through the skin. Eyes Skin Inhalation Ingestion See Toxicological Information (section 11) Chronic Effects Carcinogenic Effects Not listed as carcinogen by OSHA, NTP or IARC. Ingestion is unlikely in this form. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention. In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If inhaled, remove to fresh air. Get medical attention if irritation develops. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion 2 0 0 Section 5. Fire Fighting Measures Not determined. Not applicable. Not applicable. Flammability Flash Point Flammable Limits Fire Hazard Fire-Fighting Procedures Not applicable. Non-flammable. (CSMA) Unlikely in this form. Section 6. Accidental Release Measures Spill Clean up Page: 1/2 Page 117 of 495 Page 117 of 495 Page 117 of 495 Page 117 of 495 ---PAGE BREAK--- Material Safety Data Sheet Product Name Carpet Spot Remover Product Code Store below 120°F. Store and use away from heat, sparks, open flame, or any other ignition source. Avoid breathing vapors or spray mists. Avoid prolonged contact with skin. After handling, always wash hands thoroughly with soap and water. Section 7. Handling and Storage Handling Storage Section 8. Exposure Controls, Personal Protection A respirator is not needed under normal and intended conditions of product use. Safety glasses. Protective gloves should be worn under conditions of prolonged use. Personal Protection Eyes Body Respiratory Protective Clothing (Pictograms) Section 9. Physical and Chemical Properties Physical State pH Boiling Point Specific Gravity Solubility Aerosol. (Liquid fill) 9 - 9.5 100°C (212°F) 0.996 (Water = 1) Soluble Color Odor Vapor Pressure Vapor Density Evaporation Rate VOC (Consumer) Clear. Colorless. Butyl. N/D >1 (Air = 1) 1 compared to Water 249 The product is stable. None identified. Will not occur. Carbon oxides (CO, CO2) and organic chemicals. Section 10. Stability and Reactivity Stability and Reactivity Incompatibility Hazardous Decomposition Products Hazardous Polymerization Ethylene glycol monobutyl ether: ORAL (LD50): Acute: 1746 mg/kg [Rat]. Section 11. Toxicological Information Toxicity to Animals Not available. Section 12. Ecological Information Biodegradable/OECD Not available. Ecotoxicity Waste must be disposed of in accordance with federal, state and local environmental control regulations. Code: Not applicable. Classification: N/A Origin: N/A Waste Information Waste Stream Section 13. Disposal Considerations Consult your local or regional authorities. ORM-D Consumer Commodity Consumer Commodity ORM-D Section 14. Transport Information DOT Classification TDG Classification Proper shipping name UN number Not available. U.S. Federal Regulations Section 15. Regulatory Information California prop. 65: No products were found. Clean Water Act (CWA) 311: No products were found. Clean air act (CAA) 112 regulated toxic substances: Ethylene Glycol Monobutyl Ether State Regulations WHMIS (Canada) Class D-2B: Material causing other toxic effects (TOXIC). SARA 313 toxic chemical notification and release reporting: Ethylene glycol monobutyl ether Section 16. Other Information To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 118 of 495 Page 118 of 495 Page 118 of 495 Page 118 of 495 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 1* Flammability 0 Reactivity 0 DATE OF PREPARATION Jan 9, 2013 MATERIAL SAFETY DATA SHEET B30WCF406 04 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B30WCF406 PRODUCT NAME CHB® Interior Latex Flat Wall Paint, Williamsburg Off White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 17 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 3 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 4 1332-58-7 Kaolin ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 11 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 119 of 495 Page 119 of 495 Page 119 of 495 Page 119 of 495 ---PAGE BREAK--- B30WCF406 page 2 of 4 UEL Not Applicable LEL Not Applicable FLASH POINT Not Applicable SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Page 120 of 495 Page 120 of 495 Page 120 of 495 Page 120 of 495 ---PAGE BREAK--- B30WCF406 page 3 of 4 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 11.33 lb/gal 1357 g/l SPECIFIC GRAVITY 1.36 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 70% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH 9.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.47 lb/gal 57 g/l Less Water and Federally Exempt Solvents 0.14 lb/gal 17 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 1332-58-7 Kaolin LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Page 121 of 495 Page 121 of 495 Page 121 of 495 Page 121 of 495 ---PAGE BREAK--- B30WCF406 page 4 of 4 SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 122 of 495 Page 122 of 495 Page 122 of 495 Page 122 of 495 ---PAGE BREAK--- Material Safety Data Sheet: NATURALIZER Supercedes Date 09/11/2009 Issuing Date 09/04/2012 1. PRODUCT AND COMPANY IDENTIFICATION Product Name NATURALIZER Product Code 0480 Recommended use Cleaning agent Chemical nature Aqueous surfactant solution Information on Manufacturer Emergency Telephone Number CHEMSEARCH DIV. OF NCH CORP. CHEMTREC® [PHONE REDACTED] BOX 152170 IRVING, TX 75015 2. HAZARDS IDENTIFICATION Emergency Overview WARNING Combustible Liquid Causes skin irritation Severe eye irritation May cause allergic skin reaction May be harmful if inhaled May cause allergic respiratory reaction Harmful or fatal if swallowed Color Yellow-orange - red orange Physical State Liquid Odor Orange Potential Health Effects Principle Route of Exposure Skin contact, Eye contact, Inhalation. Primary Routes of Entry Inhalation, Skin Absorption. Acute Effects Eyes Severe eye irritant. Skin Causes skin irritation. May cause allergic skin reaction. Inhalation May cause irritation of respiratory tract. Inhalation may cause central nervous system effects. May cause central nervous system depression. and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. May cause allergic respiratory reaction. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration hazard if swallowed - can enter lungs and cause damage. Chronic Toxicity May cause sensitization by inhalation. May cause sensitization by skin contact. Liver and kidney injuries may occur. Contains a known or suspected carcinogen. Target Organ Effects Central nervous system, Respiratory system, Kidney, Liver, Immune system, Skin, Eyes. Aggravated Medical Conditions Neurological disorders, Respiratory disorders, Kidney disorders, Liver disorders, Skin disorders. Potential Environmental Effects See Section 12 for additional Ecological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No D-Limonene 5989-27-5 Triethanolamine salt of tall oil fatty acid 68132-46-7 Hexylene glycol 107-41-5 Diethanolamine salt of tall oil fatty acid 61790-66-7 Soyamide diethanolamine 68425-47-8 Coconut fatty acid 68936-15-8 Cocamide DEA 68603-42-9 4. FIRST AID MEASURES General advice Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists. Inhalation Move to fresh air. In case of shortness of breath, give oxygen. If breathing has stopped, apply artificial respiration. Get medical attention immediately. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately. Never give anything by mouth to an unconscious person. Notes to physician May cause sensitization of susceptible persons. Aspiration hazard if swallowed - can enter lungs and cause damage. Page 1 / 5 Page 123 of 495 Page 123 of 495 Page 123 of 495 Page 123 of 495 ---PAGE BREAK--- 5. FIRE-FIGHTING MEASURES Flash Point 119 °F / 48 °C Method Seta closed cup Autoignition Temperature No information available. Flammability Limits in Air % Solvent mixture. Upper 6.1 Lower 0.7 Suitable Extinguishing Media Water spray. Carbon dioxide (CO2). Foam. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards arising from the chemical Combustible Liquid. Solvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Material can create slippery conditions. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 2 Instability 0 HMIS Health 2 Flammability 2 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Remove all sources of ignition. Ensure adequate ventilation. Prevent further leakage or spillage if safe to do so. Material can create slippery conditions. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13) Methods for Cleaning Up Use clean non-sparking tools to collect absorbed material. Pick up and transfer to properly labeled containers. Neutralizing Agent Not applicable. 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Storage Keep away from heat and sources of ignition. Store in original container. Keep in a dry, cool and well- ventilated place. Storage Temperature Minimum 35 °F / 2 °C Maximum 100 °F / 38 °C Storage Conditions Indoor X Outdoor Heated Refrigerated X 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH D-Limonene No data available No data available No data available Triethanolamine salt of tall oil fatty acid No data available No data available No data available Hexylene glycol Ceiling: 25 ppm No data available Ceiling: 25 ppm Ceiling: 125 mg/m3 Diethanolamine salt of tall oil fatty acid No data available No data available No data available Soyamide diethanolamine No data available No data available No data available Coconut fatty acid No data available No data available No data available Cocamide DEA No data available No data available No data available Engineering Measures Ensure adequate ventilation, especially in confined areas. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Personal Protective Equipment Eye/Face Protection fitting safety goggles. Skin Protection Wear suitable protective clothing, Impervious gloves. Respiratory Protection In case of inadequate ventilation wear respiratory protection. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. General Hygiene Considerations Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity Non viscous Color Yellow-orange - red orange Odor Orange Appearance Transparent - hazy pH 8.5 Specific Gravity 0.885 Evaporation Rate 0.2 (Butyl acetate=1) Percent Volatile (Volume) 83.1 VOC Content 73.4 VOC Photoreactive (Y/N) Yes VOC Max Use Dilution (g/L) 38.6 VOC Max Use Dilution (wt%) 2.41 VOC Content (g/L) 617 0480 - NATURALIZER 0480 - NATURALIZER 0480 - NATURALIZER 0480 - NATURALIZER Issuing Date 09/04/2012 Issuing Date 09/04/2012 Issuing Date 09/04/2012 Issuing Date 09/04/2012 Page 2 / 5 Page 124 of 495 Page 124 of 495 Page 124 of 495 Page 124 of 495 ---PAGE BREAK--- Vapor Pressure 11.6 mmHg @ 70°F Vapor Density 1.0 (Air = 1.0) Solubility soluble Boiling Point/Range 378 °F / 192 °C 10. STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous polymerization does not occur. Conditions to Avoid Keep away from open flames, hot surfaces, and sources of ignition Incompatible Products Strong oxidizing agents, Reducing agents, Strong acids, Strong bases. Hazardous Decomposition Products Carbon oxides, Sulfur oxides, Nitrogen oxides (NOx). Possibility of Hazardous Reactions None under normal processing 11. TOXICOLOGICAL INFORMATION Product Information No information available. Component Information Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other D-Limonene = 4400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) no data available no data available no data available Triethanolamine salt of tall oil fatty acid no data available no data available no data available no data available no data available Hexylene glycol = 3692 mg/kg ( Rat ) = 8560 µL/kg ( Rabbit ) > 310 mg/m3 ( Rat ) 1 h no data available no data available Diethanolamine salt of tall oil fatty acid no data available no data available no data available no data available no data available Soyamide diethanolamine no data available no data available no data available no data available no data available Coconut fatty acid no data available no data available no data available no data available no data available Cocamide DEA = 12400 µL/kg ( Rat ) no data available no data available no data available no data available Chronic Toxicity Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects D-Limonene no data available Skin sensitization, Respiratory sensitization no data available no data available CNS, immune system, lungs, liver, kidneys Triethanolamine salt of tall oil fatty acid no data available no data available no data available no data available no data available Hexylene glycol no data available Skin sensitization no data available no data available eyes, CNS, respiratory system, skin, immune system Diethanolamine salt of tall oil fatty acid no data available no data available no data available no data available no data available Soyamide diethanolamine no data available no data available no data available no data available no data available Coconut fatty acid no data available no data available no data available no data available no data available Cocamide DEA no data available no data available no data available no data available no data available Carcinogenicity Component ACGIH IARC NTP OSHA Other D-Limonene not applicable not applicable not applicable not applicable not applicable Triethanolamine salt of tall oil fatty acid not applicable not applicable not applicable not applicable not applicable Hexylene glycol not applicable not applicable not applicable not applicable not applicable Diethanolamine salt of tall oil fatty acid not applicable not applicable not applicable not applicable not applicable Soyamide diethanolamine not applicable not applicable not applicable not applicable not applicable Coconut fatty acid not applicable not applicable not applicable not applicable not applicable Cocamide DEA not applicable Group 2B not applicable not applicable not applicable 12. ECOLOGICAL INFORMATION Product Information No information available. Component Information Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow D-Limonene no data available LC50 0.619 - 0.796 mg/L Pimephales promelas 96 h LC50 = 35 mg/L mykiss 96 h no data available no data available N/A Triethanolamine salt of tall oil fatty acid no data available no data available no data available no data available N/A Hexylene glycol no data available LC50 10500 - 11000 mg/L Pimephales EC50 = 3038 mg/L 5 min EC50 2700 - 3700 mg/L 48 <0.14 0480 - NATURALIZER 0480 - NATURALIZER 0480 - NATURALIZER 0480 - NATURALIZER Issuing Date 09/04/2012 Issuing Date 09/04/2012 Issuing Date 09/04/2012 Issuing Date 09/04/2012 Page 3 / 5 Page 125 of 495 Page 125 of 495 Page 125 of 495 Page 125 of 495 ---PAGE BREAK--- promelas 96 h LC50 = 10000 mg/L Lepomis macrochirus 96 h LC50 = 8690 mg/L Pimephales promelas 96 h LC50 = 10700 mg/L Pimephales promelas 96 h h Diethanolamine salt of tall oil fatty acid no data available no data available no data available no data available N/A Soyamide diethanolamine no data available no data available no data available no data available N/A Coconut fatty acid no data available no data available no data available no data available N/A Cocamide DEA no data available LC50 = 3.6 mg/L Brachydanio rerio 96 h EC50 = 6000 mg/L 16 h EC50= 4.2 mg/L 24 h N/A Persistence and Degradability No information available. Bioaccumulation No information available. Mobility No information available. 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations. Container Disposal Empty containers should be taken for local recycling, recovery, or waste disposal 14. TRANSPORT INFORMATION DOT Proper Shipping Name COMBUSTIBLE LIQUIDS, N.O.S., (D-LIMONENE) Hazard Class 3 UN-No UN2052 Packing Group III Description Dipentene Solution ,3,UN2052,PG III TDG Proper shipping name Dipentene Solution Hazard Class 3 UN-No UN2052 Packing Group III Description DIPENTENE SOLUTION,3,UN2052,PG III ICAO UN-No UN2052 Proper Shipping Name Dipentene Solution Hazard Class 3 Packing Group III Shipping Description Dipentene Solution,3,UN2052,PG III IATA UN-No UN2052 Proper Shipping Name Dipentene Solution Hazard Class 3 Packing Group III ERG Code 3L Shipping Description UN2052,Dipentene Solution,3,PG III IMDG/IMO Proper Shipping Name Dipentene Solution Hazard Class 3 UN-No UN2052 Packing Group III EmS No. F-E, S-E Shipping Description UN2052, Dipentene Solution,3,PG III 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations 0480 - NATURALIZER 0480 - NATURALIZER 0480 - NATURALIZER 0480 - NATURALIZER Issuing Date 09/04/2012 Issuing Date 09/04/2012 Issuing Date 09/04/2012 Issuing Date 09/04/2012 Page 4 / 5 Page 126 of 495 Page 126 of 495 Page 126 of 495 Page 126 of 495 ---PAGE BREAK--- SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs D-Limonene Not applicable Not applicable Triethanolamine salt of tall oil fatty acid Not applicable Not applicable Hexylene glycol Not applicable Not applicable Diethanolamine salt of tall oil fatty acid Not applicable Not applicable Soyamide diethanolamine Not applicable Not applicable Coconut fatty acid Not applicable Not applicable Cocamide DEA Not applicable Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class B3 Combustible liquid, D2A Very toxic materials, D2B Toxic materials. 16. OTHER INFORMATION Prepared By Rachael Mohochi Supercedes Date 09/11/2009 Issuing Date 09/04/2012 Reason for Revision No information available. Glossary No information available. List of References. No information available. CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 0480 - NATURALIZER 0480 - NATURALIZER 0480 - NATURALIZER 0480 - NATURALIZER Issuing Date 09/04/2012 Issuing Date 09/04/2012 Issuing Date 09/04/2012 Issuing Date 09/04/2012 Page 5 / 5 Page 127 of 495 Page 127 of 495 Page 127 of 495 Page 127 of 495 ---PAGE BREAK--- Material Safety Data Sheet U.S. Department of Labor May be used to comply with Occupational Safety and Health Administration OSHA’s Hazard Communication Standard, (Non-Mandatory Form) 29 CFR 1910.1200. Standard must be Form Approved consulted for specific requirements. OMB No. 1218-0072 IDENTITY (As Used on Label and List) UTIKEM MINI 1” CHLORINATING TABLETS Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Section I – General Information Manufacturer’s Name: QUALCO, INC. Telephone Number for Information: [PHONE REDACTED] Address (Number, Street, City, State and ZIP Code) 225 Passaic Street Emergency Telephone Number (973) 473-1222 or (CHEMTREC) 1-[PHONE REDACTED] Passaic, NJ 07055 Date Prepared JUNE 2002 Signature of Preparer (optional) Section II – Hazardous Ingredients/Identity Information Hazardous Components (Specific Chemical Identity: Common Name(s) OSHA PEL ACGIH TLV Other Limits Recommended % (optional) Trichloro-s-triazinetrione 1 PPM CL 1 PPM CL (CAS #87-90-1)(Trichloroisocyanuric Acid) Other Limits Oral LD 50 (Rats) 750-150 Mg/Kg Inhal. LC50 2 to 200 Mg/Liter Dermal LD50 (Rabbit) 10,000 Mg/Kg Material Corrosive D.O.T. Trichloroisocyanuric Acid, Dry Oxidizer UN2468 Material considered a severe eye & skin irritant EPA Registered Pesticide 3525-113 NFPA Class II Oxidizer Section III – Physical/Chemical Characteristics Boiling Point N/A Specific Gravity (H2O = 1) Bulk Density < 1 Vapor Pressure (mm Hg.) N/A Melting Point – Decomposes @ 350oF Vapor Density (AIR = 1) N/A Evaporation Rate (Butyl Acetate = 1) N/A Solubility in Water Moderate pH: Solution): 2.5 to 3.7 Appearance and Odor Solid White Tablets With A Chlorinous Odor Section IV – Fire and Explosion Hazard Data Flash Point (Method Used) N/A Flammable Limits Non-Flammable LEL ND UEL ND Extinguished Media Deluge with water. Special Fire Fighting Procedures: Use NIOSH certified gas mask with canister for chlorine. If possible, remove container to open air and flood with water. Damp or decomposing material may be shock sensitive. Rap container sharply with a pole from a distant, protected position prior to handling. Unusual Fire and Explosion Hazards Decomposition products: Chlorine, cyanogens chloride, carbon dioxide, ammonia, nitrogen trichloride. (Reproduce locally) OSHA 174, Sept., 1985 Page 128 of 495 Page 128 of 495 Page 128 of 495 Page 128 of 495 ---PAGE BREAK--- Page 2 Utikem Mini 1” Chlorinating Tablets Section V – Reactivity Data Unstable Conditions to Avoid: Open storage, excessive heat, moisture, moist air, combinations with oxidizers or oxidizable materials. Stability Stable X Wet material decomposes at room temperature. Incompatibility (Materials to Avoid) Nitrogen compounds – Ammonia, Amines, Ammonium compounds, Reducing Agents, Oxidizable or Combustible organics, Strong Oxidizers, Acids, Alkali. Hazardous Decomposition of Byproducts Chlorine, Cyanogen chloride, Nitrogen trichloride, Ammonia, Carbon dioxide. May Occur Conditions to Avoid N/A Hazardous Polymerization Will Not Occur X Section VI – Health Hazard Data Route(s) of Entry Inhalation? Yes Skin? Yes Ingestion? Yes Health Hazards (Acute and Chronic) Acute: Eye: Extreme irritant, cornea damage, Inhalation: Extreme irritant. Chronic: Eye damage, Lung damage. Carcinogenicity N/A NTP? N/A IARC Monographs? N/A OSHA Regulated? N/A Signs and of Exposure: Eye & Skin: Irritation, burning, redness, eye tearing. Inhalation: Coughing, irritation to nose, throat, and mouth; headache, dizziness. Ingestion: GI discomfort, nausea, vomiting. Medical Conditions Generally Aggravated by Exposure Persons with pre-existing eye, skin and respiratory disorders may be susceptible to aggravation due to irritant nature of product. Emergency and First Aid Procedures Eyes & Skin: Immediately flush with water. Call physician immediately. Inhalation: Move to fresh air. Call physician. Aid breathing, if necessary. Ingestion: If conscious, feed milk, followed by olive oil. Induce vomiting if large amount has been ingested. Call physician and follow all instructions. Section VII – Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spilled Wear proper protective gear. Keep away from combustibles. Major spills or bulk decomposition should be deluged with water and retained in a dyked area (use inert material such as dirt or absorbent pads) until reaction has been quenched. Do not drain into fresh water, streams, or lakes. Considered toxic. Waste Disposal Method Spilled or wet material should be dissolved in water and dechlorinated with a reducing agent. (Hydrogen peroxide, sodium nitrate, sodium thiosulfate). Dispose of material as per all local, state and federal regulations. Precautions To Be Taken In Handling And Storing Store in a cool, dry, well ventilated area away from combustibles and reactive materials. Keep container closed when not in use. Do not reuse container. Wear proper protective gear when handling to minimize contact with product. Other Precautions Keep away from children. Use product only as directed. Handle with care. Section VIII – Control Measures Respiratory Protection (Specify Type) Wear NIOSH certified gas mask with canister for chlorine if above permissible limits. Local Exhaust Adequate Special If permissible limits are exceeded, additional ventilation/exhaust is necessary. Ventillation Mechanical (General) Other Protective Gloves Liquid Proof Rubber Eye Protection Do not wear contact lenses. Use gas tight chemical goggles. Other Protective Clothing or Equipment Eye wash & safety shower in work/storage areas. Wear full cover clothing as necessary to minimize contact with product. Work/Hygienic Practices Remove contaminated clothing and launder before reuse. Wash well after use and observe good, personal hygiene. *U.S.G.P.O.: 1986-491-529/45775 Page 2 Page 129 of 495 Page 129 of 495 Page 129 of 495 Page 129 of 495 ---PAGE BREAK--- Addendum – Page 1 Handling & Storage of: Trichloroisocyanuric Acid Keep Out Of Reach Of Children Danger: Do not mix with anything but water. Replace container cover after use. Strong Oxidizer: Contact with other material may cause fire or explosion. Keep from contact with clothing and other combustible materials. Do not store near combustible materials. Remove and wash contaminated clothing and before reuse. 1. Do not smoke when handling material. 2. While product by itself is not a combustible material, it must not be mixed or contaminated with any foreign materials such as: household products, soap products, paint products, solvents, acids, pool chemicals, garbage, vinegar, beverages, oils, pine oil, dirty rags, etc. Contamination or mixing with these type of items may result in fire or explosion, and the fire can be of great intensity. NOTE: Dampened material and/or excessive moisture to product can also result in fire or reaction. 3. Prevent any burning material, such as a lighted cigarette from falling into any container of product. 4. If fire occurs, wear proper protective gear. Drench with water and cool the surrounding drums and area with water. 5. Use only a clean, dry cup or measuring device to remove product from container. Any contamination or foreign matter on the cup/measuring device may result in fire. Always keep material in original container to avoid contamination. 6. Keep in a cool, dry, well ventilated area which is clean. Keep in original container. Always replace container cover. Do not store in any other container. 7. Handle material with care. Do not drop, roll or skid. Keep upright. 8. Dispose of spilled material by dissolving in large amounts of water. (Always add SMALL amounts of product to LARGE amounts of water. Let stand after dissolving and check for PPM (parts per million) available chlorine using a pool water test kit. If regulations and/or your sewer authority permit discharge of material (usually less than 1 ppm available chlorine, then material can be discharged to sewer. Do not discharge without prior approval of authority. 9. Do not reuse empty container. Wash thoroughly with plenty of water and discard to trash. 10. Product may produce severe chemical burns. Do not allow contact with eyes, skin, mucous membranes or clothing. Harmful or fatal if swallowed. Page 130 of 495 Page 130 of 495 Page 130 of 495 Page 130 of 495 ---PAGE BREAK--- Addendum – Page 2 TRICHLOROISOCYANURIC ACID FIRST AID: EXTERNAL: Flood skin or eyes with copious amounts of water for 15 minutes. For eyes, call physician immediately. If skin irritation persists, get medical attention. INTERNAL: If conscious, drink large quantities of water. Do not induce vomiting, (unless instructed by physician). Get immediate medical attention. INHALATION: Move victim to fresh air. Call physician. Aid breathing, if necessary. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: NOTE: Use extreme caution in handling spilled material. Contamination with organic or combustible material may cause fire or violent decomposition. If fire or composition occurs in area of spill, immediately dose with large amounts of water. Otherwise, sweep up all visible material using a CLEAN, DRY shovel or broom, and dissolve in large amounts of water before disposing of wastes. Dispose of waste materials as outlined below. Wear proper protective gear: Coveralls, splash apron, goggles, impervious gloves, NIOSH certified gas mask with canister for chlorine. WASTE DISPOSAL METHOD: Spilled material that has been swept up and dissolved in large amounts of water should be used immediately in the normal application for which the product is being consumed. If this is not possible, CAREFULLY neutralize material as follows: This procedure can only be used for small spills of 10 pounds or less, and only if regulation permits disposal of solutions containing 1 ppm (or less) available chlorine to the sewer. DO NOT discharge to sewer without prior approval of authority. Place clean drum (about 55 gallon size) outdoors away from spill. Fill drum with tap water (3/4 full). Add spilled chemical (10 pounds maximum). Allow to dissolve in solution and let stand until available chlorine is less than 1 ppm (as determined by a pool water test kit). Then flush to sewer if permitted. NOTE: Only properly neutralized material should be flushed to sewer. Un-neutralized material can cause environmental damage to receiving water, or can interfere with treatment plant operations. STORAGE AND HANDLING PRECAUTIONS: • Do not get in eyes, on skin or on clothing. • Keep in original container in cool, dry, well ventilated area. • Keep container closed when not in use. • Keep away from heat, sparks, flame, fire and sources of ignition. • Use only a clean, dry scoop/measuring aid each time material is taken from container. • Fire can result if material is contaminated with acids, combustibles, organic materials and dirt. • Wear protective gear required when handling. Wash well after handling. • Do not reuse empty container. Rinse well with plenty of water to dissolve all materials before discarding container. Page 131 of 495 Page 131 of 495 Page 131 of 495 Page 131 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 1 / 10 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : CLEAN STRIKE MULTIPURPOSE CLEANER Other means of identification : not applicable Recommended use : All Purpose Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information : 3.1 % - 25.0 % Company : Ecolab Inc. 201 E. John Carpenter Freeway; Suite. 500 Irving, Texas USA 75062 1-[PHONE REDACTED] Emergency telephone : 1-[PHONE REDACTED] (US/Canada), [PHONE REDACTED] (outside US) Issuing date : 07/25/2014 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Product AS SOLD Eye irritation : Category 2B Skin sensitization : Category 1 Product AT USE DILUTION Skin sensitization : Category 1 GHS Label element Product AS SOLD Hazard pictograms : Signal Word : Warning Hazard Statements : May cause an allergic skin reaction. Causes eye irritation. Precautionary Statements : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Wash contaminated clothing before reuse. Disposal: Dispose of contents/ container to an approved waste disposal plant. Page 132 of 495 Page 132 of 495 Page 132 of 495 Page 132 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 2 / 10 Product AT USE DILUTION Hazard pictograms : Signal Word : Warning Hazard Statements : May cause an allergic skin reaction. Precautionary Statements : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/ attention. Wash contaminated clothing before reuse. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Product AS SOLD Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration sodium dodecylbenzene sulfonate 25155-30-0 1 - 5 Linear 27323-41-7 1 - 5 Poly(oxy-1,2-ethanediyl), .alpha.-(phenylmethyl)- .omega.-hydroxy- 26403-74-7 1 - 5 d-Limonene 5989-27-5 0.1 - 1 Product AT USE DILUTION Chemical Name CAS-No. Concentration d-Limonene 5989-27-5 0.1 - 1 SECTION 4. FIRST AID MEASURES Product AS SOLD In case of eye contact : Rinse with plenty of water. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If swallowed : Rinse mouth. Get medical attention if occur. If inhaled : Get medical attention if occur. Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to physician : Treat Product AT USE DILUTION Page 133 of 495 Page 133 of 495 Page 133 of 495 Page 133 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 3 / 10 In case of eye contact : Rinse with plenty of water. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If swallowed : Rinse mouth. Get medical attention if occur. If inhaled : Get medical attention if occur. See toxicological information (Section 11) SECTION 5. FIRE-FIGHTING MEASURES Product AS SOLD Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus Special protective equipment for fire-fighters : Use personal protective equipment. Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Product AS SOLD Personal precautions, protective equipment and emergency procedures : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Product AT USE DILUTION Personal precautions, protective equipment and emergency procedures : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Page 134 of 495 Page 134 of 495 Page 134 of 495 Page 134 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 4 / 10 Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Product AS SOLD Advice on safe handling : Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 0 °C to 50 °C Product AT USE DILUTION Advice on safe handling : Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Product AS SOLD Ingredients with workplace control parameters Ingredients CAS-No. Form of exposure Permissible concentration Basis ethanol 64-17-5 TWA 1,000 ppm ACGIH TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Page 135 of 495 Page 135 of 495 Page 135 of 495 Page 135 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 5 / 10 Product AT USE DILUTION Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Product AS SOLD Product AT USE DILUTION Appearance : liquid liquid Color : clear, light orange light orange Odor : citrus slight pH : 7.0 - 9.0, 100 % 7.0 - 9.0 Flash point : not applicable Odor Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling range : > 100 °C Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapor pressure : no data available Relative vapor density : no data available Relative density : 1.0 - 1.016 Water solubility : soluble Solubility in other solvents : no data available Partition coefficient: n- octanol/water : no data available Autoignition temperature : no data available Thermal decomposition : no data available Viscosity, kinematic : no data available Explosive properties : no data available Oxidizing properties : no data available Molecular weight : no data available Page 136 of 495 Page 136 of 495 Page 136 of 495 Page 136 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 6 / 10 VOC : no data available SECTION 10. STABILITY AND REACTIVITY Product AS SOLD Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : None known. Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Product AS SOLD Eyes : Causes eye irritation. Skin : May cause allergic skin reaction. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Product AT USE DILUTION Eyes : Health injuries are not known or expected under normal use. Skin : May cause allergic skin reaction. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Product AS SOLD Eye contact : Redness, Irritation Skin contact : Redness, Irritation, Allergic reactions Ingestion : No known or expected. Inhalation : No known or expected. Page 137 of 495 Page 137 of 495 Page 137 of 495 Page 137 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 7 / 10 Product AT USE DILUTION Eye contact : No known or expected. Skin contact : Redness, Irritation, Allergic reactions Ingestion : No known or expected. Inhalation : No known or expected. Toxicity Product AS SOLD Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye irritation : Mild eye irritation Respiratory or skin sensitization : no data available Carcinogenicity IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT-single exposure : no data available STOT-repeated exposure : no data available Aspiration toxicity : no data available Ingredients Acute dermal toxicity : d-Limonene LD50 rabbit: > 5,000 mg/kg SECTION 12. ECOLOGICAL INFORMATION Product AS SOLD Ecotoxicity Environmental Effects : Harmful to aquatic life with long lasting effects. Product Toxicity to fish : no data available Page 138 of 495 Page 138 of 495 Page 138 of 495 Page 138 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 8 / 10 Toxicity to daphnia and other aquatic invertebrates : no data available Toxicity to algae : no data available Ingredients Toxicity to fish : sodium dodecylbenzene sulfonate 96 h LC50: 3.2 mg/l Poly(oxy-1,2-ethanediyl), .alpha.-(phenylmethyl)-.omega.-hydroxy- 96 h LC50: > 100 mg/l Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available SECTION 13. DISPOSAL CONSIDERATIONS Product AS SOLD Disposal methods : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Product AT USE DILUTION Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. SECTION 14. TRANSPORT INFORMATION Product AS SOLD The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Page 139 of 495 Page 139 of 495 Page 139 of 495 Page 139 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 9 / 10 Sea transport (IMDG/IMO) Not dangerous goods Product AT USE DILUTION Not intended for transport. SECTION 15. REGULATORY INFORMATION Product AS SOLD EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity Ingredients CAS-No. Component RQ (lbs) Calculated product RQ (lbs) sodium dodecylbenzene sulfonate 25155-30-0 1000 51459 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: 1907/2006 (EU) : not determined Switzerland. New notified substances and declared preparations : The mixture contains substances listed on the Swiss Inventory not determined United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : This product contains one or several components listed in the Canadian NDSL. Australia Inventory of Chemical Substances (AICS) : not determined New Zealand. Inventory of Chemical Substances : not determined Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Japan. ISHL - Inventory of Chemical Substances (METI) : not determined Page 140 of 495 Page 140 of 495 Page 140 of 495 Page 140 of 495 ---PAGE BREAK--- SAFETY DATA SHEET CLEAN STRIKE MULTIPURPOSE CLEANER 913730-01 10 / 10 Korea. Korean Existing Chemicals Inventory (KECI) : not determined Philippines Inventory of Chemicals and Chemical Substances (PICCS) : not determined China. Inventory of Existing Chemical Substances in China (IECSC) : not determined SECTION 16. OTHER INFORMATION Product AS SOLD NFPA: HMIS III: Product AT USE DILUTION NFPA: HMIS III: Issuing date : 07/25/2014 Version : 1.0 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 2 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 2* Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Flammability Health Instability 2 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 2* Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 141 of 495 Page 141 of 495 Page 141 of 495 Page 141 of 495 ---PAGE BREAK--- RESTROOM CLEANER & DISINFECTANT Cleaner and disinfectant SAFETY DATA SHEET Product name Recommended use and restrictions : Supplier's information : RESTROOM CLEANER & DISINFECTANT Use only for the purpose on the product label. : Section 1. Chemical product and company identification Product dilution information : Not applicable Ecolab 201 E. John Carpenter Freeway, Ste. 500 Irving, TX 75062 1-[PHONE REDACTED] www.cleanstrikecleaners.com EMERGENCY HEALTH INFORMATION: 1-[PHONE REDACTED] Outside United States and Canada CALL 1-[PHONE REDACTED] (in USA) Code Date of issue EPA Registration No. : : : 21 May 2013 [PHONE REDACTED]-235 GHS Classification : Signal word : Hazard statements : Symbol : Precautionary statements Prevention : Response : Storage : Section 2. Hazards identification GHS label elements Product AS SOLD Product AT USE DILUTION No other specific measures identified. SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B SKIN SENSITIZATION - Category 1 Warning Causes eye irritation. May cause an allergic skin reaction. Wear protective gloves. Avoid breathing vapor. Mixing this product with acid or ammonia releases chlorine gas. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Product is sold ready to use. Page: 1/6 Page 142 of 495 Page 142 of 495 Page 142 of 495 Page 142 of 495 ---PAGE BREAK--- RESTROOM CLEANER & DISINFECTANT 21 May 2013 Section 2. Hazards identification Disposal : Other hazards : See section 13 for waste disposal information. None known. Mixture Section 3. Composition/information on ingredients Substance/mixture : sodium hypochlorite 2.15 7681-52-9 Hazardous ingredients CAS number Concentration Range Product is sold ready to use. Hazardous ingredients CAS number Concentration Range Product AS SOLD Product AT USE DILUTION Eye contact Skin contact Inhalation Ingestion : : : : Protection of first- aiders : Notes to physician : See toxicological information (section 11) Section 4. First aid measures Product AS SOLD Product AT USE DILUTION Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation persists. Product is sold ready to use. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. No special measures required. Treat Get medical attention if occur. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Hazardous thermal decomposition products Specific hazards arising from the chemical Special protective equipment for fire-fighters : : : Suitable fire extinguishing media : Specific fire-fighting methods : Section 5. Fire-fighting measures Product AS SOLD Use water spray, fog or foam. In a fire or if heated, a pressure increase will occur and the container may burst. Decomposition products may include the following materials: halogenated compounds metal oxide/oxides isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Page: 2/6 Page 143 of 495 Page 143 of 495 Page 143 of 495 Page 143 of 495 ---PAGE BREAK--- RESTROOM CLEANER & DISINFECTANT 21 May 2013 Environmental precautions Personal precautions : : Methods for cleaning up : Section 6. Accidental release measures Product AS SOLD Product AT USE DILUTION Use personal protective equipment as required. Product is sold ready to use. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Handling Storage : : Section 7. Handling and storage Product AS SOLD Product AT USE DILUTION Store between the following temperatures: -5 and 30°C Avoid contact with eyes, skin and clothing. Mixing this product with acid or ammonia releases chlorine gas. Wash thoroughly after handling. Product is sold ready to use. Keep out of reach of children. Keep container closed. Hand protection Eye protection Respiratory protection : : : Skin protection : Appropriate engineering controls : Hygiene measures : Control parameters Personal protection Section 8. Exposure controls/personal protection Product AS SOLD Product AT USE DILUTION sodium hypochlorite AIHA WEEL (United States, 10/2011). STEL: 2 mg/m³ 15 minutes. chlorine ACGIH TLV (United States, 3/2012). STEL: 2.9 mg/m³ 15 minutes. STEL: 1 ppm 15 minutes. TWA: 1.5 mg/m³ 8 hours. TWA: 0.5 ppm 8 hours. OSHA PEL (United States, 6/2010). CEIL: 3 mg/m³ CEIL: 1 ppm NIOSH REL (United States, 6/2009). CEIL: 0.5 ppm 15 minutes. CEIL: 1.45 mg/m³ 15 minutes. Ingredient name Exposure limits Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Product is sold ready to use. No protective equipment is needed under normal use conditions. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Use chemical-resistant, impervious gloves. Use suitable protective equipment. A respirator is not needed under normal and intended conditions of product use. Page: 3/6 Page 144 of 495 Page 144 of 495 Page 144 of 495 Page 144 of 495 ---PAGE BREAK--- RESTROOM CLEANER & DISINFECTANT 21 May 2013 Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 1.028 to 1.057 (Water = 1) Not available. Not available. Easily soluble in the following materials: cold water and hot water. chlorine Odor pH Yellowish [Light] Color Evaporation rate (butyl acetate = 1) Not available. Auto-ignition temperature Flash point Not available. > 100°C Product does not support combustion. Not available. 12 to 12.8 (100%) Viscosity Not available. Partition coefficient: n-octanol/water : : : : : : : : : : : : : : Boiling point : 100°C (212°F) Flammability (solid, gas) : Not available. Explosion limits : Not available. Section 9. Physical and chemical properties Product AS SOLD Product AT USE DILUTION Product is sold ready to use. Decomposition temperature Odor threshold : : Not available. Not available. Hazardous decomposition products Conditions to avoid Stability Reactive or incompatible with the following materials: metals and acids. Mixing this product with acid or ammonia releases chlorine gas. reactive or incompatible with the following materials: organic materials. Mixing this product with acid or ammonia releases chlorine gas. : : : Materials to avoid : Possibility of hazardous reactions : Section 10. Stability and reactivity Product AS SOLD The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Route of exposure : Skin contact, Eye contact, Inhalation, Ingestion Section 11. Toxicological information Page: 4/6 Page 145 of 495 Page 145 of 495 Page 145 of 495 Page 145 of 495 ---PAGE BREAK--- RESTROOM CLEANER & DISINFECTANT 21 May 2013 Section 11. Toxicological information Toxicity data Product/ingredient name Carcinogenicity : Mutagenicity : Teratogenicity : Developmental effects : Fertility effects : Chronic toxicity Acute toxicity Inhalation : : Ingestion Skin contact : : Eye contact Skin contact Ingestion Inhalation : : : Eye contact : Product AS SOLD Product AT USE DILUTION Adverse may include the following: irritation watering redness Product is sold ready to use. Adverse may include the following: irritation redness No specific data. No specific data. Causes eye irritation. May cause an allergic skin reaction. No known significant effects or critical hazards. No known significant effects or critical hazards. sodium hypochlorite LD50 Dermal Rabbit >10000 mg/kg LD50 Oral Rat 5230 mg/kg No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Other adverse effects : Aquatic and terrestrial toxicity Product/ingredient name Species Result Exposure Ecotoxicity : No known significant effects or critical hazards. Section 12. Ecological information Product AS SOLD Not available. No known significant effects or critical hazards. : Disposal methods Section 13. Disposal considerations Product AS SOLD Product AT USE DILUTION Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Product is sold ready to use. RCRA classification : Unused product is D002 (Corrosive) Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification IMO/IMDG Not regulated. Page: 5/6 Page 146 of 495 Page 146 of 495 Page 146 of 495 Page 146 of 495 ---PAGE BREAK--- RESTROOM CLEANER & DISINFECTANT 21 May 2013 Section 14. Transport information Product AT USE DILUTION Not intended for transport. IMO/IMDG Classification Not regulated. For transport in bulk, see shipping documents for specific transportation information. Section 15. Regulatory information U.S. Federal regulations 1677-235 : TSCA 8(b) inventory : All components are listed or exempted. EPA Registration No. Product AS SOLD SARA 302/304/311/312 extremely hazardous substances: No listed substance No listed substance SARA 302/304 emergency planning and notification: No listed substance SARA 313 Product name CAS number Concentration No listed substance Form R - Reporting requirements : California Prop. 65 : Date of issue The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Notice to reader : Section 16. Other information Prepared by : Regulatory Affairs 21 May 2013 Product AS SOLD Hazardous Material Information System 0 0 2 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards : : 2 0 0 1-[PHONE REDACTED] Page: 6/6 Page 147 of 495 Page 147 of 495 Page 147 of 495 Page 147 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET State Chemical Division – State Industrial Products State Chemical Ltd. 3100 Hamilton Avenue, Cleveland, OH 44114 (216) 861-7114 1745 Meyerside Dr., Unit Mississauga, Ontario L5T 1C6 (905) 670-4669 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: CLEAR OUT 24 Hour CHEMTREC Number: [PHONE REDACTED] Product Description: A lemon-scented granular drain opener. MSDS Number: M01303 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients CAS Number Weight ACGIH OSHA Sodium Hydroxide 1310-73-2 < 45% 2 mg/m3 2 mg/m3 Aluminum 7429-90-5 < 10% 2 mg/m3 NA Sodium Nitrate 7631-99-4 < 35% NE NE 3. HAZARDS IDENTIFICATION ***EMERGENCY OVERVIEW*** Danger. Poison. Harmful or fatal if swallowed. Causes severe burns to eyes and skin on contact. POTENTIAL HEALTH EFFECTS Eye Contact: Causes severe eye irritation and burns. include stinging, tearing, redness and swelling. Skin Contact: Causes severe skin irritation and burns. include redness, burning and swelling of skin, burns and other skin damage. Inhalation: May be harmful or fatal. May cause respiratory tract irritation. include severe irritation and burns to the nose, throat and respiratory tract. Ingestion: May be harmful or fatal. May cause severe stomach and intestinal irritation (nausea, vomiting, diarrhea). include severe irritation and burns of the mouth, throat and digestive tract. General: Pre-existing lung and skin disorders may be aggravated by exposure to this material. 4. FIRST AID MEASURES Eye Contact: Flush eyes immediately with plenty of cool water for at least 15 minutes. Get immediate medical attention. Do not wear contact lenses while using this product. Skin Contact: Immediately flush skin with plenty of water. If the product penetrates through clothing, remove clothing immediately and flush the skin with water. Launder clothing before reuse. Get immediate medical attention. Inhalation: Remove person to fresh air. Restore breathing if necessary. If irritation persists, consult a physician. Ingestion: Do not induce vomiting. Give large amounts of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. 5. FIRE FIGHTING MEASURES Flashpoint: None by TCC or TOC. Lower Explosive Limit(LEL): NA Upper Explosive Limit(UEL): NA Autoignition Temperature: NA Flammable Properties: Contact with flammable liquids, acids and organic halogen compounds may cause fires. Extinguishing Media: Use an extinguishing media appropriate for surrounding fire. Fire Fighting Instructions: Wear a self-contained breathing apparatus with full protective clothing. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Wear protective goggles and gloves. Sweep the excess powder up and return to container. Flush any residues with plenty of water and follow with a mild hydrochloric acid rinse. Follow All Federal, State and Local Regulations regarding waste disposal. 7. HANDLING AND STORAGE Handling: Wear goggles or face shield and a long-sleeved shirt. Contact lenses should not be worn when working with this product. Wash hands thoroughly after handling. Never mix with any acid or any other chemicals. Do not allow water to get into container. Read and follow all label directions and precautions carefully. Avoid contact with eyes, skin and clothing. Do not take internally. Storage: Keep containers closed when not in use. Do not store below freezing temperatures. Keep out of reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: Provide sufficient mechanical ventilation to maintain exposure below TLV limit. Personal Protective Equipment: Respiratory: None normally required. If workplace exposure limit is exceeded, a NIOSH-approved respirator is advised in the absence of environmental control. Eye: Wear approved safety glasses or goggles with unperforated sideshields. Skin: Wear chemically- resistant gloves. Wear long sleeves and long pants. Other: An emergency eyewash station or source of clean potable water should be available in case of accidental eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Yellow Odor: Lemon Physical State: Granular powder pH: NA Solubility in Water: Soluble Specific Gravity: NA Boiling Point: NA VOC Content: 0% 10. STABILITY AND REACTIVITY Stability: Stable. Hazardous Polymerization: Will not occur. Conditions to Avoid: Do not allow water to get into containers. Never use this product in an Aluminum container. Never mix with any other chemicals. Incompatibility: Acids, flammable liquids and halogenated materials. May affect some plastics. The heat generated by overuse of this product may distort plastic (PVC) pipes. Hazardous Decomposition Products: Ammonia. Page 148 of 495 Page 148 of 495 Page 148 of 495 Page 148 of 495 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION IARC / NTP / OSHA: This product contains no ingredient at 0.1% or greater that is listed as a human carcinogen. Hazardous Ingredients CAS Number LD50 LC50 Sodium Hydroxide 1310-73-2 500 mg/kg (oral rabbit) 179 mg/l/96 hr (flathead minnow) Aluminum 7429-90-5 NE NE Sodium Nitrate 7631-99-4 180 mg/kg (oral rat) 7.5 ppm/48 hr (mosquito fish) 12. ECOLOGICAL INFORMATION NA 13. DISPOSAL CONSIDERATIONS Dispose of residue in chemical receptacle in a sanitary landfill. Do not reuse empty containers. Follow All Federal, State and Local Regulations regarding waste disposal. 14. TRANSPORT INFORMATION DOT Shipping Data: Consumer Commodity, ORM-D Canadian TDG: Shipped in accordance with 49 CFR as part of a transborder shipment authorized under Section 5.2 of the Canadian Transportation of Dangerous Goods. For International Shipments by Air: Corrosive Solid, Basic, Inorganic, N.O.S. (Sodium-Hydroxide), 8, UN3262, II For International Shipments by Vessel: Corrosive Solid, Basic, Inorganic, N.O.S., (Sodium Hydroxide), 8, UN3262, II, Limited Quantity 15. REGULATORY INFORMATION TSCA: All chemicals in this product are listed or exempt from listing on the TSCA inventory. CEPA: All chemicals in this product are listed or exempt from listing on the Canadian DSL/NDSL. Propostion 65: Raw materials used in this product have identified the opportunity for the presence of very low levels of the following Proposition 65 chemicals: Arsenic (7440-38-2) < 0.001 ppm Cadmium Fume (7440-43-9) < 688 ppm Chromium (7440-43-9) < 0.001 ppm Lead (7439-92-1) < 68 ppm Nickel (7440-02-0) < 68 ppm SARA 313: This product contains no toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). HMIS RATING: Health = 3 Flammability = 0 Reactivity = 1 Personal Protection = B WHIMS RATING: Class D, Division 1B; Class E 16. OTHER INFORMATION NA = Not Available or Not Applicable NE = Not Established Read and follow all label directions and precautions before using the product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consideration, investigation, and verification. Any use of these data and information must be determined by the user to be in accordance with applicable Federal, State, and Local Laws and regulations. HEALTH AND SAFETY INFORMATION: (216) 861-7114 Completed On: January 2006 Replaces: August 2005 Completed By: Regulatory Affairs Specialist Page 149 of 495 Page 149 of 495 Page 149 of 495 Page 149 of 495 ---PAGE BREAK--- FICHE SIGNALÉTIQUE State Chemical Division – State Industrial Products State Chemical Ltd. 3100 Hamilton Avenue, Cleveland, OH 44114 (216) 861-7114 1745 Meyerside Dr., Unit Mississauga, Ontario L5T 1C6 (905) 670-4669 1. IDENTIFICATION DU PRODUIT CHIMIQUE ET DE LA SOCIÉTÉ Nom du produit : CLEAR OUT Numéro CHEMTREC 24 h/24 : [PHONE REDACTED] Description du produit : déboucheur de canalisations granulaire parfumé au citron Numéro de fiche signalétique : M01303 2. COMPOSITION/INFORMATION SUR LES INGRÉDIENTS Ingrédients dangereux Numéro CAS Poids ACGIH OSHA Hydroxide de sodium 1310-73-2 < 45% 2 mg/m3 2 mg/m3 Aluminium 7429-90-5 < 10% 2 mg/m3 néant Nitrate de sodium 7631-99-4 < 35% n.e. n.e. 3. IDENTIFICATION DES DANGERS ***SITUATIONS D’URGENCE*** Danger. Poison. Nocif voire mortel en cas d'ingestion. Le contact peut causer des brûlures graves de la peau et des yeux. EFFETS POSSIBLES SUR LA SANTÉ Contact oculaire : Provoque irritation et brûlures graves des yeux. Les sont notamment picotement, larmoiement, rougeur et tuméfaction. Contact cutané : Provoque irritation et brûlures graves de la peau. Les sont notamment rougeur, tuméfaction, brûlures et autres lésions cutanées. Inhalation : Peut être nocif voire mortel. Peut causer une irritation des voies respiratoires. Les sont notamment irritation grave et brûlures du nez, de la gorge et des voies respiratoires. Ingestion : Peut être nocif voire mo rtel. Peut causer une irritation grave de l'estomac et des intestins (nausée, vomissement, diarrhée). Les sont notamment irritation grave et brûlures de la bouche, de la gorge et du tube digestif. En général : L'exposition au produit peut avoir pour effet d'aggraver les problèmes cutanés et pulmonaires existants. 4. PREMIERS SOINS Contact oculaire : Rincer immédiatement les yeux avec beaucoup d'eau froide pendant 15 minutes au minimum. Obtenir des soins médicaux immédiats. Ne pas porter de lentilles de contact pour utiliser ce produit. Contact cutané : Rincer immédiatement la peau à grande eau. Si le produit traverse les vêtements, se dévêtir immédiatement et rincer la peau à l’eau. Laver les vêtements avant réutilisation. Obtenir des soins médicaux immédiats. Inhalation : Faire sortir la victime à l’air frais. Le cas échéant, rétablir la respiration. Si l'irritation persiste, consulter un médecin. Ingestion : Ne pas provoquer de vomissement. Faire boire de grandes quantités d'eau. Ne jamais rien administrer par voie orale à une personne inconsciente. Obtenir des soins médicaux immédiats. 5. EN CAS D’INCENDIE Point d'éclair : néant par vase clos Tag ou vase ouvert Tag Limite d’explosivité inférieure (LEL) : néant Limite d’explosivité supérieure (UEL) : néant Température d’auto-inflammation : néant Propriétés d’inflammabilité : Le contact avec des liquides inflammables, des acides ou des composés halogénés organiques peut provoquer un feu. Moyens d’extinction : Utiliser des moyens d'extinction adéquats pour le feu environnant. Lutte contre l’incendie : Porter un appareil respiratoire autonome et une tenue protectrice intégrale. 6. ÉMISSIONS ACCIDENTELLES Ventiler la zone. Porter des lunettes et des gants de protection. Balayer l'excès de poudre et le remettre dans le récipient. Laver tout résidu avec beaucoup d'eau, suivi d'un rinçage à l'acide léger. Respecter toutes les réglementations fédérales, provinciales et locales en vigueur en matière d'élimination des déchets. 7. MANUTENTION ET ENTREPOSAGE Manutention : Porter des lunettes ou un écran facial et une chemise à manches longues. Ne pas porter de lentilles de contact pour travailler avec ce produit. Se laver les mains avec soin après manipulation. Ne jamais mélanger avec un acide ni aucun autre produit chimique. Ne pas laisser d'eau pénétrer dans les récipients. Lire et suivre avec soins toutes les instructions et les précautions d’emploi. Éviter tout contact avec les yeux, la peau et les vêtements. Ne pas ingérer. Entreposage : Garder les récipients fermés hermétiquement lorsqu'ils ne sont pas utilisés. Ne pas entreposer à des températures inférieures au gel. Garder hors de portée des enfants. 8. CONTRÔLE DE L’EXPOSITION / PROTECTION PERSONNELLE Moyens techniques : Prévoir une ventilation mécanique suffisante pour maintenir l'exposition en dessous des limites admissibles. Équipement de protection individuelle : respiratoire : Aucun requis normalement. Si la limite d'exposition au travail est dépassée, il est conseillé d'utiliser un appareil respiratoire agréé NIOSH en l'absence de système de contrôle d'ambiance. oculaire : Porter des lunettes de sécurité à écrans latéraux non perforés. cutanée : Porter des gants résistants aux produits chimiques. Porter des manches longues et un pantalon long. autre : Une station d'eyewash de secours ou une source de l'eau potable propre devrait être disponible en cas de contact d'oeil accidentel. 9. PROPRIÉTÉS PHYSIQUES ET CHIMIQUES Aspect : jaune Odeur : citron État physique : poudre granulaire pH : néant Solubilité dans l’eau : soluble Densité : néant Point d’ébullition : néant Contenu de VOC : 0% Page 150 of 495 Page 150 of 495 Page 150 of 495 Page 150 of 495 ---PAGE BREAK--- 10. STABILITÉ ET RÉACTIVITÉ Stabilité : stable. Polymérisation dangereuse : ne se produit pas. Conditions à éviter : Ne pas laisser d'eau pénétrer dans les récipients. Ne jamais utiliser ce produit dans un récipient en aluminium. Ne jamais mélanger avec un autre produit chimique. Incompatibilité : Acides, liquides inflammables et produits halogénés. Peut abîmer certains plastiques. La chaleur dégagée par un emploi excessif de ce produit peut déformer les tuyaux plastique (PVC). Produits de décomposition dangereux : ammoniac. 11. INFORMATIONS TOXICOLOGIQUES CIRC / NTP / OSHA : Ce produit ne contient aucun ingrédient déclaré cancérogène humain à des teneurs supérieures ou égales à 0,1%. Ingrédients dangereux Numéro CAS LD50 LC50 Hydroxide de sodium 1310-73-2 500 mg/kg (oral rabbit) 179 mg/l/96 hr (flathead minnow) Aluminium 7429-90-5 n.e. n.e. Nitrate de sodium 7631-99-4 180 mg/kg (oral rat) 7,5 ppm/48 hr (mosquito fish) 12. INFORMATIONS ÉCOLOGIQUES néant 13. ÉLIMINATION Éliminer les résidus dans une décharge contrôlée en utilisant un récipient pour produits chimiques. Ne pas réutiliser les récipients vides. Respecter toutes les réglementations fédérales, provinciales et locales en vigueur en matière d'élimination des déchets. 14. TRANSPORT Données D.O.T.: Bien de consommation (Consumer Commodity), AAR-D (ORM-D) TMD (Canada) : Expédié en conformité avec 49 CFR dans le cadre d’un envoi transfrontalier autorisé aux termes de la Section 5.2(1) de la loi canadienne sur le transport des marchandises dangereuses. Pour les expéditions internationales par Air : Solide corrosif, Basique, Inorganique, n.s.a. (hydroxyde de sodium), 8, UN3262, II Pour les expéditions internationales par Vessel : Solide corrosif, Basique, Inorganique, n.s.a. (hydroxyde de sodium), 8, UN3262, II, Quantité Limitée 15. INFORMATIONS RÉGLEMENTAIRES TSCA : Toutes les substances chimiques contenues dans ce produit figurent ou sont dispensées de figurer sur l’inventaire du TSCA. LCPE (Canada) : Toutes les substances chimiques contenues dans ce produit figurent ou sont dispensées de figurer sur les LIS/LES. Proposition 65 (Californie) : Les matières premières premières utilisées dans ce produit ont identifié l'occasion pour la présence des niveaux très bas des produits chimiques suivants de la proposition 65: Arsenic (7440-38-2) < 0.001 ppm Vapeur de Cadmium (7440-43-9) < 688 ppm Chrome (7440-43-9) < 0.001 ppm Fil (7439-92-1) < 68 ppm Nickel (7440-02-0) < 68 ppm SARA 313 : Ne produit ne contient aucune substance chimique toxique devant être déclarée aux termes de la section 313 de la loi Emergency Planning and Community Right-To-Know Act de 1986 (40 CFR 372). CLASSIFICATION HMIS : Santé = 3 Inflammabilité = 0 Réactivité = 1 Protection individuelle = B CLASSIFICATION SIMDUT : Classe D, Division 1B ; Classe E 16. AUTRES INFORMATIONS néant = non disponible ou sans objet n.e. = non établi Lire et suivre toutes les instructions et les précautions d’emploi figurant sur l’étiquette avant d’utiliser le produit. Ces produits sont destinés à l’industrie et aux collectivités uniquement. CES PRODUITS NE SONT PAS DESTINÉS À UN USAGE DOMESTIQUE OU À LA REVENTE. GARDER HORS DE PORTÉE DES ENFANTS. Bien que les informations ci-dessus soient jugées exactes et que les avis exprimés soient ceux d’experts qualifiés, les données fournies ne tiennent pas lieu de garantie ou de déclaration engageant la responsabilité juridique de la société. Ces informations sont fournies à des fins d’examen, de recherche et de vérification. L’utilisation de ces informations sera déterminée par l’utilisateur, conformément aux lois et réglementations nationales, provinciales et locales en vigueur. INFORMATIONS SUR LA SANTÉ ET LA SÉCURITÉ : (216 ) 861-7114 Terminé : Janvier 2006 Remplace : Aout 2005 Par : Spécialiste des affaires réglementaires Page 151 of 495 Page 151 of 495 Page 151 of 495 Page 151 of 495 ---PAGE BREAK--- PLANILLA DE DATOS DE SEGURIDAD DEL PRODUCTO State Chemical Division – State Industrial Products State Chemical Ltd. 3100 Hamilton Avenue, Cleveland, OH 44114 (216) 861-7114 1745 Meyerside Dr., Unit Mississauga, Ontario L5T 1C6 (905) 670-4669 1. PRODUCTO QUÍMICO Y DATOS DE LA COMPAÑÍA Nombre del producto: CLEAR OUT Núm. CHEMTREC (emergencias) las 24 horas: [PHONE REDACTED] Descripción del producto: Destapador granular de drenajes, con aroma a limón. Núm. MSDS: M01303 2. COMPOSIC IÓN/INFORMACIÓN SOBRE LOS COMPONENTES Componentes peligrosos Núm. CAS Peso ACGIH OSHA Hidróxido de sodio 1310-73-2 < 45% 2 mg/m3 2 mg/m3 Aluminio 7429-90-5 < 10% 2 mg/m3 NA Nitrato de sodio 7631-99-4 < 35% NE NE 3. ENUMERACIÓN DE PELIGROS ***DESCRIPCIÓN GENERAL DE LAS SITUACIONES DE EMERGENCIA*** Peligro. Venenoso. Nocivo o fatal si se ingiriera. El contacto con el producto provoca quemaduras graves en ojos y piel. POSIBLES EFECTOS SOBRE LA SALUD Contacto con los ojos: Causa grave irritación ocular y provoca quemaduras. Los síntomas incluyen sensación punzante, lagrimeo, enrojecimiento e inflamación. Contacto con la piel: Causa grave irritación de la piel y provoca quemaduras. Los síntomas incluyen enrojecimiento e inflamación de la piel, así como quemaduras y otras lesiones. Inhalación: Puede ser nocivo o fatal. Puede irritar el tracto respiratorio. Los síntomas incluyen grave irritación y quemaduras de nariz, garganta y tracto respiratorio. Ingestión: Puede ser nocivo o fatal. Puede provocar grave irritación estomacal e intestinal (náuseas, vómitos, diarrea). Los síntomas incluyen grave irritación y quemaduras de boca, garganta y tracto digestivo. Aviso general: La exposición podría agravar trastornos ya existentes en piel y pulmones. 4. MEDIDAS DE PRIMEROS AUXILIOS Contacto con los ojos: Lávese inmediatamente con abundante agua fría durante al menos 15 minutos. Obtenga atención médica de inmediato. Mientras manipule este producto, no use lentes de contacto. Contacto con la piel: Lávese inmediatamente con abundante agua. Si el producto penetrara a través de la ropa, quítesela de inmediato y lávese con agua. Lave la ropa antes de volver a usarla. Obtenga atención médica de inmediato. Inhalación: Traslade a la víctima a un sitio con aire fresco. Si fuera necesario, restaure la respiración. Si la irritación no desapareciera, consulte a un médico. Ingestión: No induzca el vómito. Administre varios vasos de agua. Jamás administre nada por vía oral a una persona que haya perdido el conocimiento. Obtenga atención médica de inmediato. 5. MEDIDAS PARA COMBATIR INCENDIOS Pto. inflamabilidad: No por TCC o TOC. Límite explosivo inferior (LEL): NA Límite explosivo superior (UEL): NA Temperatura de autoignición: NA Inflamabilidad: El contacto con líquidos inflamables, ácidos y compuestos orgánicos halogenados podría provocar un incendio. Medio extinguidor: Use el medio extinguidor más apropiado para el medio que lo rodea. Instrucciones para combatir incendios: Use un aparato autónomo para respirar e indumentaria de protección. 6. MEDIDAS APLICABLES EN CASO DE DERRAME ACCIDENTAL Ventile el área. Use anteojos y guantes de protección. Barra y recoja el producto, y regréselo a su recipiente. Elimine los residuos con agua en abundancia y luego enjuague con una solución diluida de ácido clorhídrico. Obedezca todos los reglamentos federales, estatales y locales relativos a la disposición final de residuos. 7. MANIPULACIÓN Y ALMACENAMIENTO Manipulación: Use anteojos o máscara para proteger el rostro y camisa de manga larga. Cuando manipule este producto, no use lentes de contacto. Lávese bien luego de manipular este producto. Jamás mezcle con ácidos ni con ningún otro producto químico. No permita que ingrese agua al recipiente. Lea y obedezca las instrucciones y precauciones de la etiqueta. Evite el contacto con los ojos, la piel y la ropa. No ingerir. Almacenamiento: Cuando no los use, mantenga los recipientes bien cerrados. No guarde a temperaturas inferiores a la temperatura de congelación. Mantenga fuera del alcance de los niños. 8. CONTROL DE EXPOSICIÓN/PROTECCIÓN PERSONAL Controles de ingeniería: Utilice suficiente ventilación mecánica para mantener la exposición por debajo de los límites TLV. Equipo de protección personal: Respiratorio: Por lo general, no se necesita. Si en el lugar de trabajo no se contara con controles del medio ambiente y se superara el límite de exposición, se aconseja usar un aparato para respirar aprobado por NIOSH. Ojos: Use anteojos de seguridad con protección lateral sin perforaciones. Piel: Use guantes resistentes a productos químicos. Use pantalones largos y ropa de manga larga. Otros: Una estación del eyewash de la emergencia o una fuente del agua potable limpia debe estar disponible en caso de que del contacto visual accidental.ra ojos. 9. PROPIEDADES FÍSICAS Y QUÍMICAS Aspecto: Amarillo Olor: Limón Estado de agregación: Polvo granulado pH: NA Solubilidad en agua: Soluble Peso específico: NA Pto. ebullición: NA Contenido de VOC: 05 Page 152 of 495 Page 152 of 495 Page 152 of 495 Page 152 of 495 ---PAGE BREAK--- 10. ESTABILIDAD Y REACTIVIDAD Estabilidad: Estable. Polimerización peligrosa: No ocurrirá. Condiciones a evitar: No permita que ingrese agua al recipiente. Jamás coloque este producto en un recipiente de aluminio. Jamás mezcle con ningún otro producto químico. Incompatibilidad: Ácidos, líquidos inflamables y compuestos halogenados. Podría afectar algunos plásticos. El calor generado por el exceso de uso de este producto podría deformar las tuberías de plástico (PVC). Productos de descomposición peligrosos: Amoníaco. 11. INFORMACIÓN TOXICOLÓGICA IARC / NTP / OSHA: Este producto no contiene componentes en cantidades = 0.1%, los cuales figuren como carcinógenos para seres humanos. Componentes peligrosos Núm. CAS LD50 LC50 Hidróxido de sodio 1310-73-2 500 mg/kg (oral rabbit) 179 mg/l/96 hr (flathead minnow) Aluminio 7429-90-5 NE NE Nitrato de sodio 7631-99-4 180 mg/kg (oral rat) 7.5 ppm/48 hr (mosquito fish) 12. INFORMACIÓN ECOLÓGICA NA 13. SUGERENCIAS PARA SU DISPOSICIÓN FINAL Coloque los residuos en un recipiente para residuos químicos y deshágase de todo en un terreno de relleno sanitario. No vuelva a usar los recipientes vacíos. Obedezca todos los reglamentos federales, estatales y locales relativos a la disposición final de residuos. 14. INFORMACIÓN SOBRE TRANSPORTE Datos del embarque según el DOT (Ministerio de Transporte de los EE.UU.): Producto para el consumidor, ORM-D. TDG canadiense: Envíos de acuerdo con 49 CFR como parte de un envío que cruce la frontera autorizado según el Artículo 5.2 de la Ley Canadiense de Transporte de Productos Peligrosos. Para los envíos internacionales de Air: Sólido Corrosivo, Básico, Inorgánico, N.O.S. (Hidróxido de sodio), 8, UN3262, II Para los envíos internacionales de Vessel: Sólido Corrosivo, Básico, Inorgánico, N.O.S. (Hidróxido de sodio), 8, UN3262, II, Cantidad Limitada 15. INFORMACIÓN SOBRE REGLAMENTOS TSCA: Todos los componentes de este producto figuran en la lista de inventario de sustancias químicas de TSCA o están exentas de ese requisito. CEPA: Todos los componentes de este producto figuran en la lista canadiense DSL/NDSL o están exentos de ese requisito. Propuesta 65: Las materias primas usadas en este producto han identificado la oportunidad para la presencia de los niveles muy bajos de los productos químicos siguientes del asunto 65: Arsénico (7440-38-2) < 0.001 ppm Humo Del Cadmio (7440-43-9) < 688 ppm Cromo (7440-43-9) < 0.001 ppm Plomo (7439-92-1) < 68 ppm Níquel (7440-02-0) < 68 ppm SARA 313: Este producto no contiene sustancias tóxicas sujetas a los requisitos de información del Artículo 313 de la ley de 1986 (40 CFR 372) de Planeamiento ante emergencias y Derecho a Estar Informado de la Comunidad. CLASIFICACIÓN HMIS: Salud = 3 Inflamabilidad = 0 Reactividad = 1 Equipo de Protección Personal = B CLASIFICACIÓN WHIMS: Clase D, División 1B; Clase E 16. OTRA INFORMACIÓN NA = No disponible o No se aplica NE = No se ha establecido Antes de utilizar este producto, lea y obedezca todas las instrucciones y precauciones. Este producto fue formulado para utilizarse únicamente en el ámbito industrial e institucional. NO ES PARA REVENTA NI PARA USO EN EL ÁMBITO HOGAREÑO. MANTENGA FUERA DEL ALCANCE DE LOS NIÑOS. Si bien se considera que los datos contenidos en esta planilla son correctos y las opiniones expresadas son las de calificados expertos, los datos no deberán considerarse como garantía ni como declaración por las que la compañía asume responsabilidad legal alguna. Estos datos se brindan sólo para evaluación, investigación y verificación por parte del cliente. El usuario es quien deberá determinar si cualquier uso que se dé a estos datos e información está de acuerdo con las leyes y reglamentos federales, estatales y locales aplicables. INFORMACIÓN DE SEGURIDAD Y SALUD (216) 861-7114 Finalizada en: Enero de 2006 Reemplaza: Agosto de 2005 Preparada por: Especialista en reglamentos. Page 153 of 495 Page 153 of 495 Page 153 of 495 Page 153 of 495 ---PAGE BREAK--- Page 154 of 495 Page 154 of 495 Page 154 of 495 Page 154 of 495 ---PAGE BREAK--- Page 155 of 495 Page 155 of 495 Page 155 of 495 Page 155 of 495 ---PAGE BREAK--- Page 156 of 495 Page 156 of 495 Page 156 of 495 Page 156 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 02-May-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 81765 Product name Cool-It Recommended Use Solvent Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Eyes. Skin contact. Inhalation. Potential health effects Eyes May cause the following effects:. Irritation. Redness. Itching. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Repeated or prolonged exposure may cause the following effects:. Upper respiratory tract irritation. Headaches. Dizziness. Nausea. Loss of coordination. Central nervous system depression. Extreme overexposure may cause. Cardiac abnormalities. Liver damage. Urinary system effects. Reproductive system damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Heptane 142-82-5 30-60 Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 10-30 Propane 74-98-6 7-13 Butane 106-97-8 7-13 Petroleum distillates, solvent-refined heavy naphthenic 64741-96-4 3-7 Toluene 108-88-3 0.5-1.5 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Ingestion Do Not induce vomiting. Immediate medical attention is required. Inhalation Remove from exposure. Restore breathing. Keep warm and quiet. Contact physician if breathing difficulty develops. Notes to physician of poisoning may not appear for several hours. Keep under medical supervision for at least 48 hours. 5. FIRE FIGHTING MEASURES Flash point °C < -17 Flash point °F < 0 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5 Lower 1.0 Specific Information for Aerosol Products Flame extension 28" w/o extension tube Flashback Yes Suitable extinguishing media Carbon dioxide (CO2). Dry chemical powder. Foam. Page 1 / 4 Emergency Overview Extremely flammable. Contents under pressure. Irritant. Harmful by inhalation. Page 157 of 495 Page 157 of 495 Page 157 of 495 Page 157 of 495 ---PAGE BREAK--- Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Containers exposed to extreme heat may burst. Keep product and empty container away from heat and sources of ignition. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . In the event of fire and/or explosion do not breathe fumes. During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. 7. HANDLING AND STORAGE Handling Keep in a well-ventilated place. Turn off other sources of ignition prior to use and until all vapors have dissipated. Vapors may accumulate readily and may ignite explosively. Remove all sources of ignition. Keep away from open flame. Do not smoke. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Contents under pressure. Do not puncture or incinerate. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of reach of children. Storage Keep away from open flames, hot surfaces and sources of ignition. Keep away from direct sunlight. Store in temperatures below 120 degrees F (50 degrees C) . Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Butane 800 ppm - - 1000 ppm Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Petroleum distillates, hydrotreated heavy naphthenic - - - - Heptane 500 ppm 2000 mg/m3 - 400 ppm 500 ppm Petroleum distillates, solvent- refined heavy naphthenic - - - - Toluene 200 ppm 300 ppm 20 ppm - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Local: recommended. Hygiene measures Wash hands before breaks and immediately after handling the product. Other precautions Avoid contact with the skin and the eyes. Avoid breathing vapors or mists. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Hand Protection Gloves are not required in normal use. For prolonged or repeated skin contact, use a chemically resistant glove such as nitrile or neoprene. Wash hands with soap and water after removing gloves. Dry hands thoroughly before re-applying gloves. . Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity 0.69 Vapor pressure No data available Density 5.77 lb/gal, 691g/l Vapor density >1 (air=1) Evaporation Rate >1 (ether = 1) Water solubility No data available VOC Content 70% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 114 Boiling point/range °F < 0 - 238 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17 Flash point °F < 0 10. STABILITY AND REACTIVITY Stability Stable. Page 2 / 4 Product name Cool-It Product code 81765 Page 158 of 495 Page 158 of 495 Page 158 of 495 Page 158 of 495 ---PAGE BREAK--- Conditions to avoid None known. Incompatability None. Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Butane 106-97-8 - - 658 g/m3 Propane 74-98-6 - - 658 mg/L Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 28710 mg/kg - - Heptane 142-82-5 - 3000 mg/kg 103 g/m3 Petroleum distillates, solvent-refined heavy naphthenic 64741-96-4 - - - Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Repeated and prolonged exposure to solvents may cause brain and nervous system damage. Mutagenic effects None known Teratogenic effects None known Reproductive toxicity May cause adverse reproductive effects. Target Organ Effects See Section 2. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Butane Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Not Listed Not Listed Heptane Not Listed Not Listed Not Listed Not Listed Not Listed Petroleum distillates, solvent- refined heavy naphthenic Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION State Regulations Page 3 / 4 Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Product code 81765 Petroleum distillates, solvent-refined heavy naphthenic Petroleum distillates, hydrotreated heavy naphthenic Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Product name Cool-It Toluene Page 159 of 495 Page 159 of 495 Page 159 of 495 Page 159 of 495 ---PAGE BREAK--- Chemical Name New Jersey - RTK - RTK California Prop. 65 Butane Listed Listed Not Listed Propane Listed Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Heptane Listed Listed Not Listed Petroleum distillates, solvent-refined heavy naphthenic Not Listed Not Listed Not Listed Toluene Listed Listed Development al Female Reproductive Chemical Name Type Toluene - 108-88-3 Female Reproductive International Inventories Chemical Name EINECS DSL NDSL TSCA Butane X X - X Propane X X - X Petroleum distillates, hydrotreated heavy naphthenic X X - X Heptane X X - X Petroleum distillates, solvent-refined heavy naphthenic X X - X Toluene X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 81765 Product name Cool-It Page 160 of 495 Page 160 of 495 Page 160 of 495 Page 160 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Share Corporation P.O. Box 245013 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER: (800) 776-7192 REVISION DATE: March 8, 2007 CHEMTREC: (800) 424-9300 DATE OF ISSUE: March 12, 2007 I - Product Identification DR-OP Drain Opener PRODUCT CODE: 0617 CHEMICAL FORMULATION: Granular alkaline drain opener. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 3 FLAMMABILITY: 0 REACTIVITY: 2 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. EPA 40 CFR: SUBSTANCE APPROX % OSHA PEL ACGIH TLV 302 355 372 CAS # Sodium Hydroxide > 50.0 2 mg/m3 C 2 mg/m3 C Y N N 1310-73-2 Sodium Nitrate > 18.0 N/E N/E N N N 7631-99-4 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = N/D VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): 0 VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = N/A SOLUBILITY IN WATER: Complete pH: > 14.0 APPEARANCE AND ODOR: Yellow pellets with aluminum granules; no odor. IV - Fire and Explosion Hazard Data FLASH POINT None (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical. Do not use water. Water will heat up mixture. SPECIAL FIRE FIGHTING PROCEDURES: Move containers from fire if possible without risk. Cool closed containers with water from the side until well after fire is out. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. Runoff may be corrosive. Contain and isolate runoff for proper disposal. UNUSUAL FIRE AND EXPLOSION HAZARD: Addition of water to this compound will generate heat and hydrogen gas. Product contains oxidizers. Page 161 of 495 Page 161 of 495 Page 161 of 495 Page 161 of 495 ---PAGE BREAK--- P RODUCT NAME: DR-OP Drain Opener PRODUCT CODE: 0617 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Acids, reducing agents, water. Product will generate large amounts of heat when wetted. CONDITIONS TO AVOID: Moisture. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce flammable hydrogen gas upon wetting. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Severe destruction of tissue, possibly resulting in blindness. IF ON SKIN: Severe irritation, severe burns and ulcerations. IF SWALLOWED: Danger-Poison! May be fatal if swallowed. Causes severe burns to mucous membranes, destruction of tissue, burns. IF INHALED: Severe irritation of respiratory tract. Pulmonary edema, laryngeal spasms. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes, or wash with a 5% boric acid solution. Obtain medical attention and continue flushing until medical attention arrives. IF ON SKIN: Immediately flood skin with water. Remove and launder contaminated clothing before re-use. Wash skin thoroughly with vinegar and water. IF SWALLOWED: Contact physician or poison control center immediately. Do not induce vomiting. Give person large quantities of water, followed with citrus fruit juice. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air. If not breathing, administer artificial respiration. Obtain medical attention. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spill and remove all sources of moisture. Ventilate area. Sweep up spilled material and place in a properly labeled closed container for re-use or disposal WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. Do not breath dust or vapors. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Recommended PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety goggles. OTHER PROTECTIVE EQUIPMENT: Emergency shower and eyewash station. Protective clothing. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT ID NUMBER: N/A DOT PROPER SHIPPING NAME: Consumer Commodity DOT CLASS: ORM-D DOT PACKING GROUP: N/A The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: March 8, 2007 Prepared by: Technical Dept. DATE OF ISSUE: March 12, 2007 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Share Corporation assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material. Page 162 of 495 Page 162 of 495 Page 162 of 495 Page 162 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Share Corporation P.O. Box 245013 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER: (800) 776-7192 REVISION DATE: March 8, 2007 CHEMTREC: (800) 424-9300 DATE OF ISSUE: March 12, 2007 I - Product Identification DR-OP Drain Opener PRODUCT CODE: 0617 CHEMICAL FORMULATION: Granular alkaline drain opener. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 3 FLAMMABILITY: 0 REACTIVITY: 2 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. EPA 40 CFR: SUBSTANCE APPROX % OSHA PEL ACGIH TLV 302 355 372 CAS # Sodium Hydroxide > 50.0 2 mg/m3 C 2 mg/m3 C Y N N 1310-73-2 Sodium Nitrate > 18.0 N/E N/E N N N 7631-99-4 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = N/D VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): 0 VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = N/A SOLUBILITY IN WATER: Complete pH: > 14.0 APPEARANCE AND ODOR: Yellow pellets with aluminum granules; no odor. IV - Fire and Explosion Hazard Data FLASH POINT None (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical. Do not use water. Water will heat up mixture. SPECIAL FIRE FIGHTING PROCEDURES: Move containers from fire if possible without risk. Cool closed containers with water from the side until well after fire is out. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. Runoff may be corrosive. Contain and isolate runoff for proper disposal. UNUSUAL FIRE AND EXPLOSION HAZARD: Addition of water to this compound will generate heat and hydrogen gas. Product contains oxidizers. Page 163 of 495 Page 163 of 495 Page 163 of 495 Page 163 of 495 ---PAGE BREAK--- P RODUCT NAME: DR-OP Drain Opener PRODUCT CODE: 0617 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Acids, reducing agents, water. Product will generate large amounts of heat when wetted. CONDITIONS TO AVOID: Moisture. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce flammable hydrogen gas upon wetting. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Severe destruction of tissue, possibly resulting in blindness. IF ON SKIN: Severe irritation, severe burns and ulcerations. IF SWALLOWED: Danger-Poison! May be fatal if swallowed. Causes severe burns to mucous membranes, destruction of tissue, burns. IF INHALED: Severe irritation of respiratory tract. Pulmonary edema, laryngeal spasms. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes, or wash with a 5% boric acid solution. Obtain medical attention and continue flushing until medical attention arrives. IF ON SKIN: Immediately flood skin with water. Remove and launder contaminated clothing before re-use. Wash skin thoroughly with vinegar and water. IF SWALLOWED: Contact physician or poison control center immediately. Do not induce vomiting. Give person large quantities of water, followed with citrus fruit juice. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air. If not breathing, administer artificial respiration. Obtain medical attention. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spill and remove all sources of moisture. Ventilate area. Sweep up spilled material and place in a properly labeled closed container for re-use or disposal WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. Do not breath dust or vapors. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Recommended PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety goggles. OTHER PROTECTIVE EQUIPMENT: Emergency shower and eyewash station. Protective clothing. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT ID NUMBER: N/A DOT PROPER SHIPPING NAME: Consumer Commodity DOT CLASS: ORM-D DOT PACKING GROUP: N/A The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: March 8, 2007 Prepared by: Technical Dept. DATE OF ISSUE: March 12, 2007 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Share Corporation assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material. Page 164 of 495 Page 164 of 495 Page 164 of 495 Page 164 of 495 ---PAGE BREAK--- Page 165 of 495 Page 165 of 495 Page 165 of 495 Page 165 of 495 ---PAGE BREAK--- Page 166 of 495 Page 166 of 495 Page 166 of 495 Page 166 of 495 ---PAGE BREAK--- Page 167 of 495 Page 167 of 495 Page 167 of 495 Page 167 of 495 ---PAGE BREAK--- Page 168 of 495 Page 168 of 495 Page 168 of 495 Page 168 of 495 ---PAGE BREAK--- Page 169 of 495 Page 169 of 495 Page 169 of 495 Page 169 of 495 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 1* Flammability 0 Reactivity 0 DATE OF PREPARATION Nov 15, 2013 MATERIAL SAFETY DATA SHEET DB150-00 26 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DB150-00 PRODUCT NAME DURA CLEAN® Ceiling Interior Enamel Paint MANUFACTURER'S NAME DUTCH BOY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.dutchboy.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 0.3 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 4 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 7 1332-58-7 Kaolin ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 14 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 170 of 495 Page 170 of 495 Page 170 of 495 Page 170 of 495 ---PAGE BREAK--- DB150-00 page 2 of 4 UEL Not Applicable LEL Not Applicable FLASH POINT Not Applicable SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Page 171 of 495 Page 171 of 495 Page 171 of 495 Page 171 of 495 ---PAGE BREAK--- DB150-00 page 3 of 4 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 11.69 lb/gal 1401 g/l SPECIFIC GRAVITY 1.41 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 64% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH 8.8 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.37 lb/gal 44 g/l Less Water and Federally Exempt Solvents 0.13 lb/gal 16 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 1332-58-7 Kaolin LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Page 172 of 495 Page 172 of 495 Page 172 of 495 Page 172 of 495 ---PAGE BREAK--- DB150-00 page 4 of 4 SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 173 of 495 Page 173 of 495 Page 173 of 495 Page 173 of 495 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 1* Flammability 0 Reactivity 0 DATE OF PREPARATION Dec 16, 2013 MATERIAL SAFETY DATA SHEET DB130-03 30 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DB130-03 PRODUCT NAME DURA CLEAN™ Semi-Gloss Interior Latex Kitchen & Bath Enamel, Base A MANUFACTURER'S NAME DUTCH BOY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.dutchboy.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 0.1 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 22 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES Page 174 of 495 Page 174 of 495 Page 174 of 495 Page 174 of 495 ---PAGE BREAK--- DB130-03 page 2 of 4 UEL Not Applicable LEL Not Applicable FLASH POINT Not Applicable FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.47 lb/gal 1254 g/l SPECIFIC GRAVITY 1.26 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 67% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH 9.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.38 lb/gal 46 g/l Less Water and Federally Exempt Solvents Page 175 of 495 Page 175 of 495 Page 175 of 495 Page 175 of 495 ---PAGE BREAK--- DB130-03 page 3 of 4 0.13 lb/gal 16 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Page 176 of 495 Page 176 of 495 Page 176 of 495 Page 176 of 495 ---PAGE BREAK--- DB130-03 page 4 of 4 TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 177 of 495 Page 177 of 495 Page 177 of 495 Page 177 of 495 ---PAGE BREAK--- DONALD DURHAM COMPANY, INC. SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Product Identity: Durham’s Rock Hard Water Putty Recommended use of the chemical and restrictions on use: Supplier: Donald Durham Company, Inc. PO Box 804 Des Moines, Iowa 50304-0004 Phone: (515)243-0491 SDS Date of Preparation: 05/16/2015 2. HAZARDS IDENTIFICATION GHS Classification: Physical: Health: Environmental Not Hazardous Carcinogenicity Category 1 Specific Target Organ Toxicity – Repeat Exposure Category 1 Not Hazardous GHS Label Elements: Danger! Contains: Silica Statements of Hazard Prevention H350 May cause cancer by inhalation. H372 Causes damage to lungs through prolonged or repeated exposure by inhalation. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves, protective clothing, eye protection or face protection. P308 + P313 IF exposed or concerned: Get medical attention P405 Store locked up. Page 1 of 6 Page 178 of 495 Page 178 of 495 Page 178 of 495 Page 178 of 495 ---PAGE BREAK--- Durham’s Rock Hard Putty 05/16/2015 P501 Dispose of contents and container in accordance with local and national regulations. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. Amount Plaster of Paris 26499-65-0 70-80 Talc 14807-96-6 5-15 Dextrin 9004-53-9 5-9 Silica- Quartz 14808-60-7 <1 Yellow Iron Oxide 51274-00-1 <1 The exact concentration is being withheld as a trade secret. 4. FIRST AID MEASURES Eye: Flush victim's eyes with large quantities of water, while holding the eyelids apart. Get medical attention if irritation develops and persists. Skin: Wash contact area thoroughly with soap and water. Get medical attention if irritation or of exposure develop. Ingestion: Do not induce vomiting unless directed to do so by a medical professional. Get medical attention if you feel unwell. Inhalation: Remove victim to fresh air. If irritation or other persist, get medical attention. Most important May cause eye and skin irritation. Inhalation of dust may cause mucous membrane and respiratory irritation. Prolonged inhalation of dust may cause lung damage. Contains silica. Prolonged overexposure to respirable silica may cause lung disease (silicosis) and increase the risk of lung cancer. Risk of cancer depends on duration and level of exposure. Indication of immediate medical attention/special treatment: Get immediate medical attention if large quantities of dust are inhaled. 5. FIRE FIGHTING MEASURES Suitable (and Unsuitable) Extinguishing Media: Use media appropriate to the surrounding fire. Specific hazards arising from the chemical: Decomposition may release oxides of carbon and metal fumes. Special Protective Equipment and Precautions for Fire-Fighters: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. Explosion Data (sensitivity to mechanical impact or static discharge): None known. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures: Avoid creating airborne dust. Do not breathe dust. Avoid contact with eyes. Wear appropriate protective clothing and equipment. Methods and Materials for Containment and Cleaning Up: Collect using dustless method (HEPA vacuum or wet method) and place in appropriate container for use. Do not use compressed air. Do not sweep up. Place dry material into an appropriate container for disposal. Flush spill area with water to remove residue. Page 2 of 6 Page 179 of 495 Page 179 of 495 Page 179 of 495 Page 179 of 495 ---PAGE BREAK--- Durham’s Rock Hard Putty 05/16/2015 7. HANDLING AND STORAGE Precautions for Safe Handling: Do not breathe dust. Avoid dust generation. Avoid contact with eyes. Wear protective clothing and equipment. Use only with adequate ventilation. Wash thoroughly after handling. Keep container closed. Silica dust may be in the air without a visible dust cloud. Practice good housekeeping to prevent accumulation of dust in work areas. Conditions for Safe Storage, Including Any Incompatibilities: Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not in use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: Plaster of Paris 15 mg/m3 TWA OSHA PEL (total dust) 5 mg/m3 TWA OSHA PEL (respirable fraction) Dextrin None Established Talc 2 mg/m3 TWA ACGIH TLV (Respirable) 20 OSHA PEL Silica- Quartz 0.025 mg/m3 TWA ACGIH TLV (Respirable) 10 mg/m3 TWA OSHA PEL (Respirable fraction) % SiO2 + 2 30 mg/m3 TWA OSHA PEL (Total dust) % SiO2 + 2 Yellow Iron Oxide None Established Engineering Controls: Use with adequate local exhaust ventilation to maintain exposures below the occupational exposure limits. Respiratory Protection: In operations where the occupational exposure limits are exceeded, an approved respirator with dust/mist cartridges or supplied air respirator should be used. Respirator selection and use should be based on contaminant type, form and concentration. Follow applicable regulations and good Industrial Hygiene practice. Skin Protection: None required under normal conditions of use. Eye Protection: Follow facility requirements. Chemical safety glasses or dust goggles recommended to avoid eye contact. Other: None required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor: Cream colored, odorless powder. Physical State: Solid Odor Threshold: Not available Vapor Density: Not applicable Initial Boiling Point/Range: Not applicable Solubility In Water: Insoluble Vapor Pressure: Not applicable Relative Density: Not available Evaporation Rate: Not applicable Melting/Freezing Point: Not available pH: Not applicable VOC Content: No VOC’s. Octanol/Water Coefficient: Not applicable Page 3 of 6 Page 180 of 495 Page 180 of 495 Page 180 of 495 Page 180 of 495 ---PAGE BREAK--- Durham’s Rock Hard Putty 05/16/2015 Solubility: Insoluble in water Decomposition Temperature: Not available Viscosity: Not applicable Flammability (solid, gas): Not flammable Flashpoint: Not applicable Autoignition Temperature: None Flammable Limits: LEL: Not applicable UEL: Not applicable 10. STABILITY AND REACTIVITY Reactivity: Stable. Chemical Stability: Stable under normal storage and handling conditions. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. silica will dissolve in hydrofluoric acid and produce silicone tetrafluoride. Conditions to Avoid: None known. Incompatible Materials: None known. Hazardous Decomposition Products: Oxides of carbon 11. TOXICOLOGICAL INFORMATION HEALTH HAZARDS: Eye: Dust may cause mechanical irritation and corneal abrasion. Skin: May cause mechanical irritation, skin abrasions or dry skin. Ingestion: No adverse effects expected for normal incidental ingestion. Large amounts may cause gastrointestinal irritation. Inhalation: Inhalation of dust may cause irritation to the nose, throat and upper respiratory tract with coughing and shortness of breath. Chronic: This product contains silica. Repeated inhalation of respirable silica may cause may cause a progressive, disabling and sometimes fatal lung disease called silicosis. include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Sensitization: Not expected to cause sensitization. Carcinogenicity: silica quartz is listed as “Carcinogenic to Humans” (Group 1) by IARC and “Known to be a Human Carcinogen" by NTP. None of the other components are listed as carcinogens by OSHA, IARC, NTP, ACGIH or the EU Directive. Germ Cell Mutagenicity: None of the components of this product are suspected to cause mutagenicity. Reproductive Toxicity: No data available. Numerical Measures of Toxicity: Plaster of Paris: Oral rat LD50 >2000 mg/kg Silicon dioxide: Oral rat LD50 > 5000 mg/kg, inhalation rat LC50 > 0.69 mg/L, dermal rabbit LD50 > 2000 mg/kg Yellow Iron Oxide: Oral rat LD50 > 10000 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity: Silica Quartz: LC50 Carp - >10,000 mg/L/72hr. This product is not expected to present an environmental hazard. Page 4 of 6 Page 181 of 495 Page 181 of 495 Page 181 of 495 Page 181 of 495 ---PAGE BREAK--- Durham’s Rock Hard Putty 05/16/2015 Persistence and Degradability: Biodegradability does not apply to inorganic compounds. Bioaccumulative Potential: No data available. Mobility in Soil: No data available. Other Adverse Effects: No data available. 13. DISPOSAL CONSIDERATIONS Dispose in accordance with local, state and federal environmental regulations. 14. TRANSPORT INFORMATION DOT Hazardous Materials Description: Proper Shipping Name: Not Regulated UN Number: None Hazard Class/Packing Group: None Labels Required: None IMDG Shipping Name: Not Regulated UN Number: None IMDG Hazard Class/ Packing Group: None IMDG Hazard Labels Required: None IATA Shipping Name: Not Regulated UN Number: None IATA Hazard Class/ Packing Group: None IATA Hazard Labels Required: None 15. REGULATORY INFORMATION CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. Hazard Category for Section 311/312: Chronic Health Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: Components C.A.S. # WT % None None None State Regulations California: This product contains the following substances known to the state of California to cause cancer and/or reproductive toxicity: Page 5 of 6 Page 182 of 495 Page 182 of 495 Page 182 of 495 Page 182 of 495 ---PAGE BREAK--- Durham’s Rock Hard Putty 05/16/2015 Components C.A.S. # WT % Silica-Quartz 14808-60-7 <1 Personal air sampling has been conducted during end-use of the product, and no detectable levels of silica were measured. Section 302 Extremely Hazardous Substances (TPQ): None 16. OTHER INFORMATION NFPA Rating: Health = 1 Flammability = 0 Instability = 0 HMIS Rating: Health = 1* Flammability = 0 Physical Hazard = 0 Revision Summary: 02/15/2015: New GHS SDS Page 6 of 6 Page 183 of 495 Page 183 of 495 Page 183 of 495 Page 183 of 495 ---PAGE BREAK--- Material Safety Data Sheet F 1. Chemical Product and Company Identification DESCRIPTION: ELMER'S CARPENTERS WOOD GLUE PRODUCT TYPE: PVAC BASED ADHESIVE APPLICATION: FOR PRODUCT CODES SEE SECTION 16 • Manufacturer/Supplier Information MSDS Prepared by: Elmer's Products, Inc. Emergency Phone Number 1 Easton Oval Poison Control Center Columbus, OH 43219 1-[PHONE REDACTED] For additional health, safety or regulatory information, call 1-[PHONE REDACTED] Call 1-[PHONE REDACTED] to place an order or request additional 2. Composition, Information on Ingredients No hazardous ingredients known to company. 3. Hazards Identification 3.1 Emergency Overview Appearance Light yellow liquid Odor Mild acetic aroma Not an immediate health hazard. • HMIS Rating Page 1 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 184 of 495 Page 184 of 495 Page 184 of 495 Page 184 of 495 ---PAGE BREAK--- HEALTH = 0 (minimal) FLAMMABILITY = 0 (minimal) REACTIVITY = 0 (minimal) 3.2 Potential Health Effects • Immediate Hazards INGESTION: No hazards known to company. INHALATION: No hazards known to company. SKIN: No hazards known to company. EYES: No hazards known to company. • Delayed Hazards None of the components present in this product at concentrations equal to or greater than 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen. 4. First Aid Measures INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. EYES: Immediately flush eyes with plenty of water. Call a physician if irritation persists. 5. Fire Fighting Measures Autoignition Temperature Not available Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Will not burn unless water has evaporated. Dried material may burn. In case of fire, water should be used to keep fire-exposed containers cool. 6. Accidental Release Measures Soak up with absorbent material and remove to a chemical disposal Page 2 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 185 of 495 Page 185 of 495 Page 185 of 495 Page 185 of 495 ---PAGE BREAK--- area. Prevent entry into natural bodies of water. 7. Handling and Storage 7.1 Handling Handle in accordance with good industrial hygiene and safety practices. 7.2 Storage Keep from freezing. Store in a cool, dry place. Keep containers closed. 8. Exposure Controls/Personal Protection 8.1 Exposure Controls No special control measures necessary under normal conditions of use. 8.2 Personal Protection No special protection necessary. 8.3 Exposure Guidelines None established 9. Physical and Chemical Properties Percent Volatiles 54.5 pH @ 25 C 5.0 Specific Gravity 1.08 Appearance Light yellow liquid Autoignition Temperature Not available Page 3 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 186 of 495 Page 186 of 495 Page 186 of 495 Page 186 of 495 ---PAGE BREAK--- Boiling Point 100°C (212°F) Vapor Density (Air=1) <1 Vapor Pressure, mm Hg @ 20 C 17.5 Evaporation Rate (Butyl Acetate=1) <1 Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Freezing Point 0°C (32°F) Odor Mild acetic aroma Odor Threshold, ppm Not available Solubility in Water Dispersible Coefficient of Water/Oil Distrib. Not available 10. Stability and Reactivity Normally stable as defined in NFPA 704-12(4-3.1). • Incompatibilities: Strong acids and alkaline materials. • Decomposition products may include: CO, CO2. • Hazardous polymerization: Will not occur. • Other Hazards: None known to company. 11. Toxicological Information INGESTION: A similar product was found to be non-toxic orally when tested as described in 16 CFR Part 1500.3(c)(1) and INHALATION: A similar product was found to be non-toxic by inhalation when tested as described in 16 CFR Part 1500.3 and SKIN A similar product was found to be non-toxic dermally ABSORPTION: when tested as described in 16 CFR Part 1500.3 and Page 4 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 187 of 495 Page 187 of 495 Page 187 of 495 Page 187 of 495 ---PAGE BREAK--- SKIN: A similar product was not an irritant when tested as described in 16 CFR Part 1500.41. EYES: A similar product was not an irritant when tested as described in 16 CFR Part 1500.42. 12. Ecological Information Not determined. 13. Disposal Considerations Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal requirements. 14. Transport Information 14.1 U.S. Department of Transportation (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Non-Regulated. 14.2 Canadian Transportation of Dangerous Goods (TDG) Non-Regulated. 15. Regulatory Information (Selected Regulations) 15.1 U.S. Federal Regulations • OSHA Hazard Communication Standard 29CFR1910.1200 This material is not a "health hazard" or a "physical hazard" as Page 5 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 188 of 495 Page 188 of 495 Page 188 of 495 Page 188 of 495 ---PAGE BREAK--- determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard. • SARA Title III: Section 311/312 Does not meet any hazard category • SARA Title III Section 313 and 40 CFR Part 372 This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. None required per SARA TITLE III SECTION 313. • TSCA Section 8(b) Inventory All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us. 15.2 Canadian Regulations • Workplace Hazardous Materials Information System (WHMIS) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. Not a controlled product • Canadian Environmental Protection Act (CEPA) All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. • National Pollutant Release Inventory (NPRI) This product contains the following chemical(s) subject to the Page 6 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 189 of 495 Page 189 of 495 Page 189 of 495 Page 189 of 495 ---PAGE BREAK--- reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required. 16. Other Information AP (Non-Toxic): Products bearing the AP (Non-Toxic) Product Seal of The Art & Creative Materials Institute, Inc. (ACMI) are certified in a program of toxicological evaluation by a medical expert to contain no materials in sufficient quantities to be toxic or injurious to humans or to cause acute or chronic health problems. This program is reviewed by ACMI's Toxicological Advisory Board. These products are certified by ACMI to be labeled in accordance with the chronic hazard labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695. In addition, there is no physical hazard as defined within 29 CFR Part 1910.1200(c). MSDS covers items: U.S.: E614, E700, E701, E702, E704, E705, E706, E970, E980, E1367, E1825, E1850 Canada: 60613, 60614, 60615, 60616, 60617, 60618, 60619, 61367 • User's Responsibility The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients. • Disclaimer SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. CURRENT ISSUE: 04-MAR-09 PREVIOUS ISSUE: 28-FEB-08 Page 7 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 190 of 495 Page 190 of 495 Page 190 of 495 Page 190 of 495 ---PAGE BREAK--- Safety Data Sheet GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER EPA Reg. No. 264-334-71004 Relevant identified uses of the substance or mixture and uses advised against Use Insecticide Restrictions on use See product label for restrictions. Information on manufacturer TechPac, LLC. 1000 Parkwood Circle Suite 700 Atlanta, GA 30339 Emergency telephone no. Emergency Telephone Number (24hr/ 7 days) Product Information Telephone Number 1-[PHONE REDACTED] 1-[PHONE REDACTED] SDS Information or Request 1-[PHONE REDACTED] SECTION 2: HAZARDS IDENTIFICATION Classification in accordance with regulation HCS 29CFR §1910.1200 Carcinogenicity : Category 2 Acute toxicity (Inhalation): Category 3 Acute toxicity (Oral): Category 4 Signal word: Danger Hazard statements Toxic if inhaled. Suspected of causing cancer. Harmful if swallowed. Page 191 of 495 Page 191 of 495 Page 191 of 495 Page 191 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 Precautionary statements Avoid breathing mist and spray. Use only outdoors or in a well-ventilated area. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor/physician. Specific treatment (see supplemental first aid instructions on this label). IF exposed or concerned: Get medical advice/ attention. IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell. Rinse mouth. Store in a well-ventilated place. Keep container closed. Store locked up. Dispose of contents/container in accordance with local regulation. Other hazards This product contains an cholinesterase inhibitor. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Concentration % by weight Carbaryl 63-25-2 22.50 1,2-Propanediol 57-55-6 3.50 Naphthalene and alkyl naphthalene sulphonic acids formaldehyde condensate, sodium salt 68425-94-5 1.50 SECTION 4: FIRST AID MEASURES Description of first aid measures General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Page 192 of 495 Page 192 of 495 Page 192 of 495 Page 192 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 Ingestion Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important and effects, both acute and delayed Temporary blurred vision due to contraction of the pupils (miosis) following contact with the eyes., Bradycardia, Low blood pressure, Salivation, Bronchial hypersecretion, Vomiting, Diarrhoea, Sweating, Muscular fasciculation, Spasm, Breathing difficulties, Respiratory paralysis, Somnolence, Coma, Respiratory failure, Hypothermia, Convulsions, Nausea Indication of any immediate medical attention and special treatment needed Risks This product is a cholinesterase inhibitor carbamate. Treatment The product inhibits cholinesterase resulting in stimulation of the central nervous system, the parasympathetic nervous system, and the somatic motor nerves. The following antidote is generally accepted: atropine. Do not use oximes such as 2-PAM unless organophosphate intoxication is suspected. Watch for pulmonary edema, which may develop in serious cases of poisoning even after 24-48 hours. At first sign of pulmonary edema, the patient should be placed in an oxygen tent and treated Contraindications: derivatives of morphine. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable Water spray, Foam, Carbon dioxide (CO2), Dry powder Unsuitable None known. Special hazards arising from the substance or mixture In the event of fire the following may be released:, Nitrogen oxides (NOx), Carbon monoxide (CO) Advice for firefighters Special protective equipment for fire-fighters Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing. Further information Evacuate personnel to safe areas. Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. Flash point > 93.4 °C Page 193 of 495 Page 193 of 495 Page 193 of 495 Page 193 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 Autoignition temperature no data available Lower explosion limit no data available Upper explosion limit no data available Explosivity not applicable SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect and transfer the product into a properly labelled and closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations. Additional advice Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal. Inform appropriate authorities immediately if contamination occurs. Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Maintain exposure levels below the exposure limit through the use of general and local exhaust ventilation. Hygiene measures Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area. Page 194 of 495 Page 194 of 495 Page 194 of 495 Page 194 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 Advice on common storage Keep away from food, drink and animal feedingstuffs. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components CAS-No. Control parameters Update Basis Carbaryl (Inhalable fraction and vapor.) 63-25-2 0.5 mg/m3 (TWA) 02 2012 ACGIH Carbaryl 63-25-2 5 mg/m3 (REL) 2010 NIOSH Carbaryl 63-25-2 5 mg/m3 (PEL) 02 2006 OSHA Z1 Carbaryl 63-25-2 5 mg/m3 (TWA) 1989 OSHA Z1A Carbaryl 63-25-2 5 mg/m3 (TWA) 06 2008 TN OEL Carbaryl 63-25-2 5ug/m3 (ST ESL) 07 2011 TX ESL Carbaryl 63-25-2 0.5ug/m3 (AN ESL) 07 2011 TX ESL Carbaryl 63-25-2 5 mg/m3 (TWA PEL) 08 2010 US CA OEL Carbaryl 63-25-2 0.5 mg/m3 (TWA) OES BCS* 1,2-Propanediol (Vapor.) 57-55-6 1000ug/m3 (ST ESL) 02 2013 TX ESL 1,2-Propanediol (Vapor.) 57-55-6 50ppb (AN ESL) 02 2013 TX ESL 1,2-Propanediol (Vapor.) 57-55-6 500ppb (ST ESL) 02 2013 TX ESL 1,2-Propanediol (Vapor.) 57-55-6 100ug/m3 (AN ESL) 02 2013 TX ESL 1,2-Propanediol (Aerosol.) 57-55-6 10 mg/m3 (TWA) 2010 WEEL amorphous silica 112926-00-8 6 mg/m3 (REL) 2010 NIOSH amorphous silica 112926-00-8 6 mg/m3 (TWA) 1989 OSHA Z1A amorphous silica 112926-00-8 6 mg/m3 (TWA) 06 2008 TN OEL amorphous silica (Particulate.) 112926-00-8 2ug/m3 (AN ESL) 02 2013 TX ESL amorphous silica (Particulate.) 112926-00-8 27ug/m3 (ST ESL) 02 2013 TX ESL Page 195 of 495 Page 195 of 495 Page 195 of 495 Page 195 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 amorphous silica 112926-00-8 20millions of particles per cubic foot of air (TWA) 2000 Z3 amorphous silica 112926-00-8 0.8 mg/m3 (TWA) 2000 Z3 *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" Exposure controls Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Under conditions immediately dangerous to life or health, or emergency conditions with unknown concentrations, use a full-face positive pressure air-supplied respirator equipped with an emergency escape air supply unit or use a self-contained breathing apparatus unit. Hand protection Chemical resistant nitrile rubber gloves Eye protection fitting safety goggles Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks. General protective measures Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. Do not allow children or pets to enter the treated area until it has dried. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance white to light beige Physical State liquid Odor weak Odour Threshold no data available pH 4.0 - 5.0 at 100 % (23 Vapor Pressure no data available Vapor Density (Air = 1) no data available Density 1.05 g/cm³ at 20 °C Page 196 of 495 Page 196 of 495 Page 196 of 495 Page 196 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 Evapouration rate no data available Boiling Point no data available Melting / Freezing Point no data available Water solubility miscible Minimum Ignition Energy not applicable Decomposition temperature no data available Partition coefficient: n- octanol/water no data available Viscosity 500 - 700 cps Flash point > 93.4 °C Autoignition temperature no data available Lower explosion limit no data available Upper explosion limit no data available Explosivity not applicable SECTION 10: STABILITY AND REACTIVITY Reactivity Thermal decomposition no data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions No hazardous reactions when stored and handled according to prescribed instructions. Conditions to avoid Heat, flames and sparks. Elevated temperatures Incompatible materials no data available Hazardous decomposition products Nitrogen oxides (NOx) Carbon oxides Methyl isocyanate (trace; no adverse effects expected) SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Ingestion, Inhalation, Skin Absorption, Eye contact Immediate Effects Eye Causes redness, irritation, tearing. Moderate eye irritation. Page 197 of 495 Page 197 of 495 Page 197 of 495 Page 197 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 Skin Harmful if absorbed through skin. May produce similar to those from ingestion. Ingestion Harmful if swallowed. This product causes reversible cholinesterase inhibition without long term effects. Repeated overexposure may cause more severe cholinesterase inhibition with more pronounced May lead to rapid onset of nausea, vomiting, diarrhea, abdominal pain, involuntary shaking, excess salivation, pinpoint pupils, blurred vision, profuse sweating, temporary paralysis, respiratory depression, and convulsions. Inhalation Harmful if inhaled.May produce similar to those from ingestion. Information on toxicological effects Acute oral toxicity LD50 (male/female combined rat) ca. 1,820 mg/kg Acute inhalation toxicity LC50 (male rat) 3.1 mg/l Exposure time: 1 h Determined in the form of liquid aerosol. Acute dermal toxicity LD50 (rabbit) > 2,000 mg/kg Skin irritation Slight irritation (rabbit) Eye irritation Minimally irritating. (rabbit) Assessment repeated dose toxicity Carbaryl caused reversible cholinesterase inhibition without long term effects in animal studies. Assessment Mutagenicity Carbaryl was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests. Assessment Carcinogenicity Carbaryl caused at high dose levels an increased incidence of tumours in the following organ(s): liver, Thyroid, kidneys, cardio-vascular system. The mechanism that triggers tumours in rodents is not relevant for the low exposures encountered under normal use conditions. ACGIH Carbaryl 63-25-2 Group A4 NTP None. IARC Carbaryl 63-25-2 Overall evaluation: 3 OSHA None. Assessment toxicity to reproduction Page 198 of 495 Page 198 of 495 Page 198 of 495 Page 198 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 Carbaryl did not cause reproductive toxicity in a two-generation study in rats. Assessment developmental toxicity Carbaryl did not cause developmental toxicity in rats and rabbits. Further information Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s). SECTION 12: ECOLOGICAL INFORMATION Toxicity to fish LC50 mykiss (rainbow trout)) 3.3 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient carbaryl. Toxicity to aquatic invertebrates EC50 (Daphnia magna (Water flea)) 0.0164 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient carbaryl. Toxicity to aquatic plants EC50 (Pseudokirchneriella subcapitata) 1.75 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient carbaryl. Biodegradability Carbaryl: ; rapidly biodegradable Koc Carbaryl: Koc: 624 Bioaccumulation Carbaryl: Bioconcentration factor (BCF) 44; Does not bioaccumulate. Mobility in soil Carbaryl: mobile in soils Environmental precautions Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Do not apply when weather conditions favor runoff or drift. Drift or runoff from treated areas may adversely affect non-target plants. Apply this product as specified on the label. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area. Inform appropriate authorities immediately if contamination occurs. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Page 199 of 495 Page 199 of 495 Page 199 of 495 Page 199 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 Product It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Never place unused product down any indoor or outdoor drain. Contaminated packaging Follow advice on product label and/or leaflet. Do not re-use empty containers. Triple rinse containers. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke. RCRA Information Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply. SECTION 14: TRANSPORT INFORMATION 49CFR UN number 3082 Class 9 Packaging group III Marine pollutant Marine pollutant Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (CARBARYL) RQ Reportable Quantity is reached with 444 lb of product. IMDG UN number 3082 Class 9 Packaging group III Marine pollutant YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CARBARYL SOLUTION) IATA UN number 3082 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CARBARYL SOLUTION ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. Page 200 of 495 Page 200 of 495 Page 200 of 495 Page 200 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 SECTION 15: REGULATORY INFORMATION US Federal Regulations TSCA list Carbaryl 63-25-2 1,2-Propanediol 57-55-6 Naphthalene and alkyl naphthalene sulphonic acids formaldehyde condensate, sodium salt 68425-94-5 US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting Carbaryl 63-25-2 1.0% US States Regulatory Reporting CA Prop65 This product contains a chemical known to the State of California to cause cancer. Carbaryl 63-25-2 This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Carbaryl 63-25-2 Developmental toxin. Carbaryl 63-25-2 Male reproductive toxin. US State Right-To-Know Ingredients Carbaryl 63-25-2 CA, CT, IL, MN, NJ, RI 1,2-Propanediol 57-55-6 MN Canadian Regulations Canadian Domestic Substance List Naphthalene and alkyl naphthalene sulphonic acids formaldehyde condensate, sodium salt 68425-94-5 Environmental CERCLA Carbaryl 63-25-2 100 lbs Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification Page 201 of 495 Page 201 of 495 Page 201 of 495 Page 201 of 495 ---PAGE BREAK--- GARDENTECH® SEVIN® READY-TO-SPRAY BUG KILLER January 2015 criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Caution! Hazard statements: Harmful if swallowed, inhaled or absorbed through the skin. Avoid contact with skin, eyes and clothing. Wash thoroughly and put on clean clothing. Avoid breathing spray mist. Avoid inhalation of vapour or mist. SECTION 16: OTHER INFORMATION NFPA 704 (National Fire Protection Association): Health - 2 Flammability - 1 Instability - 1 Others - none HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 0 PPE - 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR1910.1200) This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. Page 202 of 495 Page 202 of 495 Page 202 of 495 Page 202 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Glance NA Version Number: 2 Preparation date: 2007-07-25 Personal protective equipment NFPA HMIS Reactivity 0 None / Aucune / Ninguno Health Fire Hazard 1 0 0 1 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Glance NA MSDS MS0200011 Product Code: 3361936, 3172641 Recommended use: Cleaning product. This product is intended to be diluted prior to use. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - Rabbit LC50 Inhalation - Rat Sodium lauryl sulfate 151-21-3 1 - 5% Not available Not available Not available Ethyl alcohol 64-17-5 0.1 - 1.5% Not available Not available Not available 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Skin contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: None known. Unusual hazards: None known. Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Glance NA Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] 1 of 3 EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. Page 203 of 495 Page 203 of 495 Page 203 of 495 Page 203 of 495 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Clean up affected area with water. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Ethyl alcohol 64-17-5 1000 ppm (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: None known. Conditions to avoid: Do not freeze. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known HAZARDOUS COMPONENTS Ingredient(s) CAS # NTP IARC OSHA Ethyl alcohol 64-17-5 X 1 X Bulk density: Density: 8.35 Appearance: Decomposition temperature: Not determined Aqueous solution VOC: 0.25 No information available Autoignition temperature: No information available Vapor density: Flash point: >200°F >93.3°C No information available Partition coefficient (n-octanol/water): No information available Liquid Solubility: Soluble Color: Solubility in other solvents: No information available Blue Viscosity: No information available pH: Elemental Phosphorus: 0.0 %P Evaporation Rate No information available >7.0 7.0 Odor: Characteristic Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: .999 No information available. Glance NA 2 of 3 Melting point/range: Not determined Page 204 of 495 Page 204 of 495 Page 204 of 495 Page 204 of 495 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia (AICS), Korea (ECL), Japan (ENCS), Philippines (PICCS), China (IECSC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Sodium lauryl sulfate 151-21-3 - - - - Alcohol ethoxylates 68439-46-3 - - - - Ethyl alcohol 64-17-5 X X X X Sodium lauryl ether sulfate 9004-82-4 - - - - CERCLA/ SARA CAA HAP/CAA ODS/CWA Priority Pollutants: None SARA 311/312 Hazard Categories Immediate: X Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class: Non-controlled. Ingredient(s) CAS # NPRI Ethyl alcohol 64-17-5 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 Glance NA Page 205 of 495 Page 205 of 495 Page 205 of 495 Page 205 of 495 ---PAGE BREAK--- MSDS-PPS14 Date Prepared:4/29/06 MATERIAL SAFETY DATA SHEET/COMPLIES WITH OSHA’S HAZARD COMMUNICATION STANDARD (29CFR 1910.1200) SECTION I – PRODUCT IDENTIFICATION GOO GONE PAINTER’S PAL CONTAINER SIZE: 14 fl oz, 55 gallon STOCK NO.: PPS14, PPS14DO, PPS14BM SUPPLIER’S NAME: MAGIC AMERICAN PRODUCTS, INC. ADDRESS: 23700 MERCANTILE ROAD; CLEVELAND, OH 44122 24 Hour Emergency Phone: CHEMTEL 1-[PHONE REDACTED] Information Phone: MAGIC AMERICAN PRODUCTS, INC. M-F, 9-5 EST 1-[PHONE REDACTED] DOT SHIPPING INFORMATION HAZARDS RATING INFORMATION DOT SHIPPING NAME: Not regulated DOT HAZARD CLASS: None DOT LABEL: None DOT PACKING GROUP: None Health Flammability Reactivity Personal Protection NFPA 1 0 0 N/A NPCA(HMIS) 2 0 0 C 0-Minimal 1-Slight 2-Moderate 3-Serious 4-Extreme C-Glasses, gloves, apron SECTION II - INGREDIENTS CHEMICAL NAME CAS NO. 313/CHEMICAL PEL TWA/TLV CARCINOGEN Proprietary Mixture None No ingredients are regulated N/A N/A No (Alkaline Water-based Surfactant and 2-Butoxyethanol Solution) All ingredients used in this proprietary mixture are listed on the TSCA Inventory List and none is listed as carcinogenic by OSHA, IARC or NTP. SECTION III – PHYSICAL DATA SECTION IV – FIRE AND EXPLOSION DATA Boiling Point: 207°F (97°C) Vapor Pressure: 24.2 mm Hg (25°C) Solubility in Water: Complete pH: 8.3 – 8.8 Specific Gravity: 1.03 g/ml Evaporation Rate: Similar to Water Appearance/Odor: Translucent Orange with Citrus, Orange-like Fragrance VOC Content: 25% VOC by CARB Flash Point: Greater than 200°F (93°C) Explosive Hazard: Not an explosive. Extinguishing Media: Use extinguishing media suitable for other combustible materials in area. Special Fire Fighting Procedures: None; material is not combustible. Unusual Fire and Explosion Hazards: None. SECTION V – REACTIVITY DATA SECTION VI – STORAGE AND HANDLING Stability: Stable Hazardous Polymerization: Will not occur. Hazardous Decomposition Products: None known. Incompatibility: None known. KEEP OUT OF THE REACH OF CHILDREN Store in a cool, dry area away from heat or open flame. Do not store at temperatures above 120ºF. SECTION VII – HEALTH EFFECTS AND FIRST AID PRIMARY ROUTES OF ENTRY AND EFFECTS OF OVEREXPOSURE FIRST AID PROCEDURES EYES: According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.42, this product was shown to be an eye irritant in laboratory tests. Therefore, this material is labeled an eye irritant. EYES: Remove any contact lenses and flush both eyes with cool running water for at least 15 minutes. Seek medical attention if irritation persists. SKIN: Irritant. According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.41, this product was shown not to be a primary skin irritant in laboratory tests. Therefore, this product is not considered a skin irritant. SKIN: Wash with soap and water. With extended periods of use, a skin emollient should be applied after use to prevent drying. INHALATION: Not expected to be an inhalation hazard. INHALATION: Remove person to fresh air. INGESTION: According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.3(c)(2)(i), this product was shown to be non-toxic by the oral route of exposure. This material is not considered an ingestion hazard. INGESTION: Rinse mouth and then drink a large glass of water and seek immediate medical attention. LONG TERM EFFECTS: No long term effects expected. SECTION VIII – SPECIAL PROTECTION DATA SECTION IX – SPILL OR LEAK PRECAUTIONS STEPS TO BE TAKEN IN CASE OF SPILLAGE OR LEAKAGE: Ventilate area. Spilled material can be picked up with sorbant material. Use caution where surfaces may become slippery from spilled material. WASTE DISPOSAL METHOD: Sweep up and place in empty container and close. Dispose of according to local, state and federal regulations. RESPIRATORY PROTECTION: Not needed. VENTILATION: Not needed. PROTECTIVE GLOVES: Chemically resistant gloves (neoprene) are recommended for prolonged use. EYE PROTECTION: Recommended if splashing during transfer is possible. WASTE DISPOSAL CAUTION: Hazardous substances cleaned with this product may create hazardous waste that must be properly characterized and disposed of in accordance with RCRA, state and local regulations. N/A = NOT APPLICABLE N/E = NOT ESTABLISHED N/D = NOT DETERMINED < = LESS THAN > = MORE THAN NOTICE: The information contained on this Material Safety Data Sheet is for Industrial and Institutional use only and considered accurate as of the date of publication. It is not necessarily all inclusive or fully adequate in every circumstance. The suggestions should not be confused with or followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, express or implied, of merchantability, fitness, accuracy of data, or the results to be obtained from the use thereof is made. The vendor assumes no responsibility for injury or damages resulting from the inappropriate use of this product. Magic American assumes no responsibility for any product information placed on the Internet by individuals who are not affiliated with Magic American. Page 206 of 495 Page 206 of 495 Page 206 of 495 Page 206 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Print Date: 14 Nov 2009 ®(TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 13 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. Product and Company Identification Product Name GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center Midland, MI 48674 USA Customer Information Number: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. Hazards Identification Emergency Overview Color: Yellow Physical State: Foam Odor: Mild Hazards of product: DANGER! Flammable gas - May cause flash fire. May cause allergic skin reaction. May cause allergic respiratory reaction. May cause eye irritation. May cause skin irritation. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause respiratory tract irritation. Vapors may travel a long distance; ignition and/or flash back may occur. Evacuate area. Keep upwind of spill. Stay out of low areas. Aerosol cans exposed to fire can rupture becoming flaming projectiles. Elevated temperatures can cause hazardous polymerization. Toxic fumes may be released in fire situations. Containers are under high pressure. Avoid temperatures above 49 °C (120 OSHA Hazard Communication Standard Material Safety Data Sheet The Dow Chemical Company Page 207 of 495 Page 207 of 495 Page 207 of 495 Page 207 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 2 of 13 This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Health Effects Eye Contact: May cause eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Cancer Information: Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Component CAS # Amount Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 10.0 - 30.0 % Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3- propanetriyltris[.omega.-hydroxypoly 57029-46-6 30.0 - 60.0 % Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer 53862-89-8 10.0 - 30.0 % Tris(1-chloro-2-propyl) phosphate 13674-84-5 5.0 - 10.0 % Paraffin waxes and Hydrocarbon waxes, chlorinated 63449-39-8 5.0 - 10.0 % Isobutane 75-28-5 5.0 - 10.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. 3. Composition Information Page 208 of 495 Page 208 of 495 Page 208 of 495 Page 208 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 3 of 13 4. First-aid measures Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Skin Contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. May cause asthma-like (reactive airways) Bronchodilators, expectorants, antitussives and corticosteroids may be of help. May cause respiratory sensitization or asthma-like Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Although cholinesterase depression has been reported with this material, it is not of benefit in determining exposure and need not be considered in the treatment of persons exposed to the material. No specific antidote. Treatment of exposure should be directed at the control of and the clinical condition of the patient. Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. bronchitis, reactive airways dysfunction 5. Fire Fighting Measures Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire- exposed containers and fire-affected zone until fire is out. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections. Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Page 209 of 495 Page 209 of 495 Page 209 of 495 Page 209 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 4 of 13 Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. 6. Accidental Release Measures Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use non- sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Collect in suitable and properly labeled containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See Section 10 for more specific information. See Section 13, Disposal Considerations, for additional information. Personal Precautions: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. See Section 10 for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to Section 7, Handling, for additional precautionary measures. Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. 7. Handling and Storage Handling General Handling: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Never use air pressure for transferring product. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Storage Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Shelf life: Use within 12 Months 20 - 30 °C 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value I 4,4' -Methylenediphenyl diisocyanate ACGIH TWA 0.005 ppm Page 210 of 495 Page 210 of 495 Page 210 of 495 Page 210 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 5 of 13 OSHA Table Z-1 Ceiling 0.2 mg/m3 0.02 ppm I Methyl ether WEEL TWA 1,880 mg/m3 1,000 ppm I Isobutane ACGIH TWA 1,000 ppm I Propane OSHA Table Z-1 PEL 1,800 mg/m3 1,000 ppm ACGIH TWA 1,000 ppm I Personal Protection Eye/Face Protection: Use safety glasses. Eye wash fountain should be located in immediate work area. Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Remove contaminated clothing immediately, wash skin area with soap and water, and launder clothing before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and watchbands, should be removed and disposed of properly. Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive-pressure self- contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter. Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating. Engineering Controls Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. 9. Physical and Chemical Properties Physical State Foam Color Yellow Odor Mild Flash Point - Closed Cup -104 °C (-155 Estimated Flammable Limits In Air Lower: No test data available Upper: No test data available Autoignition Temperature No test data available Vapor Pressure 1,151 kPa @ 55 °C Calculated Boiling Point (760 mmHg) Not applicable. Vapor Density (air = 1) No test data available Specific Gravity (H2O = 1) 1.06 Estimated Page 211 of 495 Page 211 of 495 Page 211 of 495 Page 211 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 6 of 13 Freezing Point No test data available Melting Point No test data available Solubility in Water (by weight) Insoluble pH Not applicable Kinematic Viscosity Not applicable 10. Stability and Reactivity Stability/Instability Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Conditions to Avoid: Avoid temperatures above 49 °C (120 Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose. Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Hazardous Polymerization Can occur. Elevated temperatures can cause hazardous polymerization. Thermal Decomposition Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. Toxicological Information Acute Toxicity Ingestion Single dose oral LD50 has not been determined. Estimated LD50, Rat > 10,000 mg/kg Skin Absorption The LD50 has not been determined. Estimated LD50, Rabbit > 2,000 mg/kg Inhalation The LC50 has not been determined. Estimated LC50, Aerosol, Rat > 0.5 mg/l Sensitization Skin Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Respiratory May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Repeated Dose Toxicity Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, Page 212 of 495 Page 212 of 495 Page 212 of 495 Page 212 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 7 of 13 tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Chronic Toxicity and Carcinogenicity Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Developmental Toxicity In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Genetic Toxicology In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. 12. Ecological Information CHEMICAL FATE Data for Component: Diphenylmethane Diisocyanate, isomers and homologues Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Tris(1-chloro-2-propyl) phosphate Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < Potential for mobility in soil is low (Koc between 500 and 2000). Page 213 of 495 Page 213 of 495 Page 213 of 495 Page 213 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 8 of 13 Henry's Law Constant < 1.35E-5 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): 2.59 Measured Partition coefficient, soil organic carbon/water (Koc): 1,300 Estimated Bioconcentration Factor (BCF): 0.8 - 4.6; common carp (Cyprinus carpio); Measured Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 4.47E-11 cm3/s 0.24 d Estimated OECD Biodegradation Tests: Biodegradation Exposure Time Method 14 % 28 d OECD 301E Test Theoretical Oxygen Demand: 1.17 mg/mg Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Movement & Partitioning Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Henry's Law Constant < 1.0E-07 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): > 6 Estimated Persistence and Degradability Expected to degrade only slowly in the environment. Data for Component: Isobutane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 1.19E+00 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.76 Measured Partition coefficient, soil organic carbon/water (Koc): 35 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability Biodegradation may occur under aerobic conditions (in the presence of oxygen). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.44E-12 cm3/s 4.4 d Estimated Theoretical Oxygen Demand: 3.58 mg/mg Data for Component: Methyl ether Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 9.78E-4 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 0.10 Measured Partition coefficient, soil organic carbon/water (Koc): 1.29 - 14 Estimated Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.66E-12 cm3/s 6.4 d Estimated OECD Biodegradation Tests: Page 214 of 495 Page 214 of 495 Page 214 of 495 Page 214 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 9 of 13 Biodegradation Exposure Time Method 5 % 28 d OECD 301A Test Theoretical Oxygen Demand: 2.08 mg/mg Data for Component: Propane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 7.07E-01 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.36 Measured Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability No relevant information found. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.27E-12 cm3/s 8.4 d Estimated Theoretical Oxygen Demand: 3.64 mg/mg Data for Component: 4,4' -Methylenediphenyl diisocyanate Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. ECOTOXICITY Data for Component: Diphenylmethane Diisocyanate, isomers and homologues The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Tris(1-chloro-2-propyl) phosphate Material is toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). Page 215 of 495 Page 215 of 495 Page 215 of 495 Page 215 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 10 of 13 Fish Acute & Prolonged Toxicity LC50, bluegill (Lepomis macrochirus), 96 h: 84 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, 48 h, immobilization: 63 mg/l Aquatic Plant Toxicity EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96 h: 47 mg/l EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 45 mg/l Toxicity to Micro-organisms EC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: 784 mg/l Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L). Material is very highly toxic to aquatic invertebrates on an acute basis (LC50/EC50 < 0.1 mg/L). Fish Acute & Prolonged Toxicity LC50, rainbow trout mykiss), static, 96 h: > 100 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, immobilization: 0.037 mg/l Data for Component: Isobutane No relevant information found. Data for Component: Methyl ether Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, guppy (Poecilia reticulata), 96 h: > 4,000 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, 48 h: > 4,000 mg/l Data for Component: Propane No relevant information found. Data for Component: 4,4' -Methylenediphenyl diisocyanate The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg 13. Disposal Considerations DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device. As a service to its customers, Dow can provide names of information resources to help identify waste management companies and other facilities which recycle, reprocess or manage chemicals or plastics, and that manage used drums. Telephone Dow's Customer Information Group at 1-[PHONE REDACTED] or 1-989- 832-1556 or 1-[PHONE REDACTED] (Canada) for further details. Page 216 of 495 Page 216 of 495 Page 216 of 495 Page 216 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 11 of 13 14. Transport Information DOT Non-Bulk CONSUMER COMMODITY RECLASSIFIED AS ORM-D MATERIAL DOT Bulk NOT AVAILABLE IN BULK CONTAINERS IMDG Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950 EMS Number: F-D,S-U LIMITED QUANTITY ICAO/IATA Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203 Passenger Packing Instruction: 203 LIMITED QUANTITY This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. Regulatory Information OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard Yes Fire Hazard Yes Reactive Hazard No Sudden Release of Pressure Hazard Yes Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 10.0 - 30.0 % (Worker and Community Right-To-Know Act): Hazardous Substances List and/or Environmental Hazardous Substance List: The following product components are cited in the Hazardous Substance List and/or the Environmental Substance List, and are present at levels which require reporting. Page 217 of 495 Page 217 of 495 Page 217 of 495 Page 217 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 12 of 13 Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % Isobutane 75-28-5 5.0 - 10.0 % (Worker and Community Right-To-Know Act): Special Hazardous Substances List: To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed. 16. Other Information Recommended Uses and Restrictions Polyurethane foam. Revision Identification Number: 63952 / 0000 / Issue Date 01/31/2008 / Version: 2.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend N/A Not available W/W Weight/Weight OEL Occupational Exposure Limit STEL Short Term Exposure Limit TWA Time Weighted Average ACGIH American Conference of Governmental Industrial Hygienists, Inc. DOW IHG Dow Industrial Hygiene Guideline WEEL Workplace Environmental Exposure Level HAZ_DES Hazard Designation Action Level A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded. The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have Page 218 of 495 Page 218 of 495 Page 218 of 495 Page 218 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 12oz HC PDQ PROMO Issue Date: 01/31/2008 Page 13 of 13 obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 219 of 495 Page 219 of 495 Page 219 of 495 Page 219 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Print Date: 30 Sep 2013 ®(TM)*Trademark Page 1 of 10 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. Product and Company Identification Product Name GREAT STUFF(TM) Pro Gun Cleaner COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center Midland, MI 48674 United States Customer Information Number: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. Hazards Identification Emergency Overview Color: Colorless Physical State: Liquid. Odor: Mild Hazards of product: WARNING! Causes eye irritation. May cause central nervous system effects; can cause death if too much is breathed. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause respiratory tract irritation. Aspiration hazard. Can enter lungs and cause damage. Vapor explosion hazard. Isolate area. Keep upwind of spill. Warn public of downwind explosion hazard. Aerosol cans exposed to fire can rupture becoming flaming projectiles. Eliminate ignition sources. Contents under pressure. OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Material Safety Data Sheet The Dow Chemical Company Page 220 of 495 Page 220 of 495 Page 220 of 495 Page 220 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 2 of 10 Potential Health Effects Eye Contact: May cause severe eye irritation. May cause slight corneal injury. Effects may be slow to heal. Vapor may cause eye irritation experienced as mild discomfort and redness. Skin Contact: Essentially nonirritating to skin. May cause drying and flaking of the skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). May cause respiratory irritation and central nervous system depression. At air concentrations <1000 ppm, propane exerts very little physiological action; at 100,000 ppm and above it may produce dizziness or other central nervous system effects. Excessive exposure may cause headache, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects, including death. Ingestion: Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts. Aspiration hazard: Aspiration into the lungs may occur during ingestion or vomiting, causing lung damage or even death due to chemical pneumonia. Effects of Repeated Exposure: Contains component(s) which have been reported to cause effects on the following organs in animals: Blood. Kidney. Liver. Development of cataracts has been reported in laboratory animals after prolonged repeated skin exposure to acetone. Birth Defects/Developmental Effects: Contains component(s) which, in laboratory animals, have been toxic to the fetus only at doses toxic to the mother. Component CAS # Amount Acetone 67-64-1 60.0 - 100.0 % Propane 74-98-6 10.0 - 30.0 % 4. First-aid measures Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin Contact: Wash skin with plenty of water. Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. Most important and effects, both acute and delayed Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), no additional and effects are anticipated. Indication of immediate medical attention and special treatment needed Maintain adequate ventilation and oxygenation of the patient. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. The decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. No specific antidote. 3. Composition Information Page 221 of 495 Page 221 of 495 Page 221 of 495 Page 221 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 3 of 10 Treatment of exposure should be directed at the control of and the clinical condition of the patient. Skin contact may aggravate preexisting dermatitis. 5. Fire Fighting Measures Suitable extinguishing media Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Extinguishing Media to Avoid: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Special hazards arising from the substance or mixture Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Container may vent and/or rupture due to fire. Electrically ground and bond all equipment. Flammable mixtures of this product are readily ignited even by static discharge. Vaporizes quickly at room temperature. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Water may not be effective in extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Do not use direct water stream. May spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Warning - flashback potential. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate area of leak or spill. Confined space entry procedures must be followed before entering the area. For large spills, warn public of downwind explosion hazard. Vapor explosion hazard. Keep out of sewers. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Refer to Section 7, Handling, for additional precautionary measures. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Contain spilled material if possible. Absorb with materials such as: Dirt. Sand. Sawdust. Pump with explosion-proof equipment. If available, use foam to smother or suppress. Collect in suitable and properly labeled containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional information. Page 222 of 495 Page 222 of 495 Page 222 of 495 Page 222 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 4 of 10 7. Handling and Storage Handling General Handling: Avoid contact with eyes. Wash thoroughly after handling. Do not swallow. Avoid breathing vapor. Use only with adequate ventilation. Keep container closed. No smoking, open flames or sources of ignition in handling and storage area. Ignition sources can include and are not limited to pilot lights, flames, smoking, sparks, heaters, electrical equipment, and static discharges. Electrically bond and ground all containers and equipment before transfer or use of material. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Do not enter confined spaces unless adequately ventilated. This material is hygroscopic in nature. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Other Precautions: Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion. Storage Protect from atmospheric moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Store in the following material(s): Carbon steel. Stainless steel. Polypropylene. Polyethylene-lined container. Teflon. Glass-lined container. Aluminum. Plasite 3066 lined container. Plasite 3070 lined container. 316 stainless steel. Store away from direct sunlight. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed. Minimize sources of ignition, such as static build- up, heat, spark or flame. See Section 10 for more specific information. Storage Period: 36 Months 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value I Acetone ACGIH TWA 500 ppm BEI ACGIH STEL 750 ppm BEI OSHA Table Z-1 PEL 2,400 mg/m3 1,000 ppm I Propane OSHA Table Z-1 PEL 1,800 mg/m3 1,000 ppm ACGIH A BEI notation following the exposure guideline refers to a guidance value for assessing biological monitoring results as an indicator of the uptake of a substance from all routes of exposures. Personal Protection Eye/Face Protection: Use chemical goggles. If exposure causes eye discomfort, use a full-face respirator. Skin Protection: Wear clean, body-covering clothing. Hand protection: Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Examples of preferred glove barrier materials include: Natural rubber ("latex"). Neoprene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl alcohol Polyvinyl chloride ("PVC" or "vinyl"). Viton. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant Page 223 of 495 Page 223 of 495 Page 223 of 495 Page 223 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 5 of 10 workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline. Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in the work area; wash hands and face before smoking or eating. Engineering Controls Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. Lethal concentrations may exist in areas with poor ventilation. 9. Physical and Chemical Properties Appearance Physical State Liquid. Color Colorless Odor Mild Odor Threshold No test data available pH No test data available Melting Point No test data available Freezing Point No test data available Boiling Point (760 mmHg) No test data available. Flash Point - Closed Cup flammable Evaporation Rate (Butyl Acetate = 1) No test data available Flammability (solid, gas) Not applicable to liquids Flammable Limits In Air Lower: 2.1 Vendor Upper: 8.5 Vendor (propane) Vapor Pressure 4,482 hPa Vendor Vapor Density (air = 1) greater than air Specific Gravity (H2O = 1) 0.87 20 °C/20 °C Vendor Solubility in water (by weight) Complete Partition coefficient, n- octanol/water (log Pow) No data available for this product. See Section 12 for individual component data. Autoignition Temperature 450 °C (842 Estimated. Decomposition Temperature No test data available Kinematic Viscosity No test data available Explosive properties Not explosive Oxidizing properties No Volatile Organic Compounds 50.8 g/l 10 Wt% Supplier 10. Stability and Reactivity Reactivity No dangerous reaction known under conditions of normal use. Chemical stability Thermally stable at typical use temperatures. Possibility of hazardous reactions Polymerization will not occur. Page 224 of 495 Page 224 of 495 Page 224 of 495 Page 224 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 6 of 10 Conditions to Avoid: Elevated temperatures can cause container to vent and/or rupture. Avoid static discharge. Incompatible Materials: Avoid contact with: Acids. Bases. Oxidizers. Hazardous decomposition products Decomposition products depend upon temperature, air supply and the presence of other materials. 11. Toxicological Information Acute Toxicity Ingestion As product: Single dose oral LD50 has not been determined. Estimated. LD50, rat > 5,000 mg/kg Dermal As product: The dermal LD50 has not been determined. Estimated. LD50, rabbit > 2,000 mg/kg Inhalation As product: The LC50 has not been determined. Eye damage/eye irritation May cause severe eye irritation. May cause slight corneal injury. Effects may be slow to heal. Vapor may cause eye irritation experienced as mild discomfort and redness. Skin corrosion/irritation Essentially nonirritating to skin. May cause drying and flaking of the skin. Sensitization Skin No relevant data found. Respiratory No relevant data found. Repeated Dose Toxicity Contains component(s) which have been reported to cause effects on the following organs in animals: Blood. Kidney. Liver. Development of cataracts has been reported in laboratory animals after prolonged repeated skin exposure to acetone. Chronic Toxicity and Carcinogenicity No relevant data found. Developmental Toxicity Contains component(s) which, in laboratory animals, have been toxic to the fetus only at doses toxic to the mother. Reproductive Toxicity For the major component(s): In animal studies, did not interfere with reproduction. Genetic Toxicology Genetic toxicity studies on tested components were predominantly negative. 12. Ecological Information Toxicity Data for Component: Acetone Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, mykiss (rainbow trout), 96 h: 5,500 - 6,100 mg/l Aquatic Invertebrate Acute Toxicity EC50, Daphnia magna (Water flea), 48 h, immobilization: 6,084 mg/l LC50, Ceriodaphnia Dubia (water flea), 48 h: 8,098 mg/l Aquatic Plant Toxicity Page 225 of 495 Page 225 of 495 Page 225 of 495 Page 225 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 7 of 10 EC50, Skeletonema costatum, biomass growth inhibition, 5 d: 11,800 - 14,400 mg/l Toxicity to Micro-organisms EC50, activated sludge test (OECD 209), Respiration inhibition, 3 h: > 1,000 mg/l Data for Component: Propane No relevant data found. Persistence and Degradability Data for Component: Acetone Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. OECD Biodegradation Tests: Biodegradation Exposure Time Method 10 Day Window 91 % 28 d OECD 301B Test pass Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.04E-13 cm3/s 52 d Estimated. Theoretical Oxygen Demand: 2.20 mg/mg Data for Component: Propane No relevant data found. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.27E-12 cm3/s 8.4 d Estimated. Theoretical Oxygen Demand: 3.64 mg/mg Bioaccumulative potential Data for Component: Acetone Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient, n-octanol/water (log Pow): -0.24 Measured Bioconcentration Factor (BCF): 0.69; Fish; Measured Data for Component: Propane Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient, n-octanol/water (log Pow): 2.36 Measured Mobility in soil Data for Component: Acetone Mobility in soil: Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient, soil organic carbon/water (Koc): 0.37 - 2.0 Estimated. Henry's Law Constant 1.38E-05 atm*m3/mole; 25 °C Estimated. Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 44.3 % 55.6 % < 0.1 % < 0.1 % < 0.1 % Data for Component: Propane Mobility in soil: Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated. Henry's Law Constant 7.07E-01 atm*m3/mole; 25 °C Measured Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % 13. Disposal Considerations Page 226 of 495 Page 226 of 495 Page 226 of 495 Page 226 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 8 of 10 DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section 10 Regulatory Information, MSDS Section 15 14. Transport Information DOT Non-Bulk Proper Shipping Name: AEROSOLS Hazard Class: 2.1 ID Number: UN1950 LIMITED QUANTITY DOT Bulk Proper Shipping Name: AEROSOLS Hazard Class: 2.1 ID Number: UN1950 IMDG Proper Shipping Name: AEROSOLS Hazard Class: 2 ID Number: UN1950 EMS Number: F-D,S-U Marine pollutant.: No LIMITED QUANTITY ICAO/IATA Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203 Passenger Packing Instruction: 203 LIMITED QUANTITY HAZCHEM CODE: 2YE This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. Regulatory Information OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard No Page 227 of 495 Page 227 of 495 Page 227 of 495 Page 227 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 9 of 10 Fire Hazard Yes Reactive Hazard No Sudden Release of Pressure Hazard Yes Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute. (Worker and Community Right-To-Know Act): Hazardous Substances List and/or Environmental Hazardous Substance List: The following product components are cited in the Hazardous Substance List and/or the Environmental Substance List, and are present at levels which require reporting. Component CAS # Amount Acetone 67-64-1 60.0 - 100.0 % Propane 74-98-6 10.0 - 30.0 % (Worker and Community Right-To-Know Act): Special Hazardous Substances List: To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed. 16. Other Information Recommended Uses and Restrictions Identified uses Cleaner. We recommend that you use this product in a manner consistent with the listed use. If your intended use is not consistent with the stated use, please contact your sales or technical service representative. Revision Identification Number: 64097 / 0000 / Issue Date 09/27/2013 / Version: 4.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend N/A Not available W/W Weight/Weight OEL Occupational Exposure Limit STEL Short Term Exposure Limit TWA Time Weighted Average ACGIH American Conference of Governmental Industrial Hygienists, Inc. DOW IHG Dow Industrial Hygiene Guideline Page 228 of 495 Page 228 of 495 Page 228 of 495 Page 228 of 495 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 09/27/2013 Page 10 of 10 WEEL Workplace Environmental Exposure Level HAZ_DES Hazard Designation Action Level A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded. The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 229 of 495 Page 229 of 495 Page 229 of 495 Page 229 of 495 ---PAGE BREAK--- Page 230 of 495 Page 230 of 495 Page 230 of 495 Page 230 of 495 ---PAGE BREAK--- Page 231 of 495 Page 231 of 495 Page 231 of 495 Page 231 of 495 ---PAGE BREAK--- Page 232 of 495 Page 232 of 495 Page 232 of 495 Page 232 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 27-Sep-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 98761 Product name HSP Gloss Black Recommended Use Coating Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Eyes. Inhalation. Ingestion. Potential health effects Eyes Irritating to eyes. Skin No adverse affects expected. Inhalation Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Repeated or prolonged exposure may cause the following effects:. Kidney damage. Lung damage. Liver damage. Cardiac abnormalities. Damage to blood . Avoid breathing vapors or mists. Exposure to vapors may cause the following effects. Drowsiness . Dizziness. Narcosis. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Acetone 67-64-1 10-30 Propane 74-98-6 10-30 N-Butane 106-97-8 7-13 Barium Sulfate 7727-43-7 5-10 Ethylene glycol monopropyl ether 2807-30-9 5-10 Methylisobutyl ketone 108-10-1 3-7 Methyl Propyl Ketone 107-87-9 1-5 Xylene (mix) 1330-20-7 1-5 PM Acetate 108-65-6 1-5 Isobutyl acetate 110-19-0 .1-1 Carbon Black 1333-86-4 .1-1 Ethyl benzene 100-41-4 .1-1 4. FIRST AID MEASURES Eye contact Remove to fresh air. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash area thoroughly with soap and water. Remove and wash contaminated clothing before re-use. Ingestion Call a physician or Poison Control Center immediately. Inhalation Move to fresh air. If persist, call a physician. 5. FIRE FIGHTING MEASURES Flash point °C -19 Flash point °F -2 Method No information available Autoignition temperature °C Product is not self-igniting Autoignition temperature °F Flammability Limits in Air) Upper 10.9 Lower 1.7 Suitable extinguishing media Carbon dioxide (CO2). Water spray. Alcohol-resistant foam . Sand. Dry powder. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Specific hazards Keep product and empty container away from heat and sources of ignition. Page 1 / 4 Emergency Overview Extremely flammable liquid and vapor. Contents under pressure. Harmful by inhalation. Irritating to eyes. Keep out of reach of children. Page 233 of 495 Page 233 of 495 Page 233 of 495 Page 233 of 495 ---PAGE BREAK--- Fire and Explosion Hazards Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. Vapors may form explosive mixture in air between upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Evacuate personnel to safe areas. Ensure adequate ventilation. Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Evacuate area of unprotected and unnecessary personnel. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Do not spray on a naked flame or any other incandescent material. Do not smoke. Protect against electrostatic charges. Storage Observe pressurized container storage regulations. Consult with local authorities.. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Barium Sulfate 15 mg/m3 - 10 mg/m3 - Ethylene glycol monopropyl ether - - - - Methyl Propyl Ketone 200 ppm 700 mg/m3 - - 150 ppm PM Acetate - - - - Methylisobutyl ketone 100 ppm 410 mg/m3 - 20 ppm 75 ppm Xylene (mix) 100 ppm 435 mg/m3 - 100 ppm 150 ppm N-Butane - - - 1000 ppm Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Ethyl benzene 100 ppm 435 mg/m3 - 20 ppm - Carbon Black 3.5 mg/m3 - 3 mg/m3 - Isobutyl acetate 150 ppm 700 mg/m3 - 150 ppm - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures Keep away from food, drink and animal feeding stuffs. Wash hands before breaks and immediately after handling the product. Respiratory protection None required if adequate ventilation is provided. Follow OSHA respirator regulations (29 CFR 1910.134) and if necessary, wear a MSHA/NIOSH approved respirator. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Chemical resistant gloves. Impervious gloves. Consult glove manufacturer to determine the proper type for a specific operation. Eye protection fitting safety goggles. Skin and body protection None necessary under normal conditions Other Protective Equipment An eye wash station should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Black Odor Aromatic Odor Threshold No information available pH No data available Specific Gravity 0.77-0.85 Vapor pressure 40 PSI, 2750 hPa Density No data available Vapor density No data available Evaporation Rate No data available Water solubility No data available VOC Content 46.2%; 496.0 g/l; 4.14 lb/gl Solids content 30.9% MIR value 1.12 Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -44 Boiling point/range °F -47 Melting point/range °C No data available Melting point/range °F No data available Flash point °C -19 Flash point °F -2 10. STABILITY AND REACTIVITY Page 2 / 4 Product code 98761 Product name HSP Gloss Black Page 234 of 495 Page 234 of 495 Page 234 of 495 Page 234 of 495 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Do not store in temperatures above 120 degrees F. Incompatability None known. Hazardous Decomposition Products None known. Polymerization Hazardous polymerization does not occur 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Acetone 67-64-1 - - 50100 mg/m3 Barium Sulfate 7727-43-7 - - - Ethylene glycol monopropyl ether 2807-30-9 - - - Methyl Propyl Ketone 107-87-9 - - - PM Acetate 108-65-6 8532 mg/kg 5 g/kg - Methylisobutyl ketone 108-10-1 2080 mg/kg 16000 mg/kg 8.2 mg/L Xylene (mix) 1330-20-7 4300 mg/kg - 47635 mg/L N-Butane 106-97-8 - - 658 g/m3 Propane 74-98-6 - - 658 mg/L Ethyl benzene 100-41-4 3500 mg/kg 15354 mg/kg 17.2 mg/L Carbon Black 1333-86-4 - - - Isobutyl acetate 110-19-0 13400 mg/kg 17400 mg/kg - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Prolonged or repeated occupational overexposure may affect the following:. Kidney. Lungs. Liver. Heart. Blood. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Acetone A4 Not Listed Not Listed Not Listed Not Listed Barium Sulfate Not Listed Not Listed Not Listed Not Listed Not Listed Ethylene glycol monopropyl ether Not Listed Not Listed Not Listed Not Listed Not Listed Methyl Propyl Ketone Not Listed Not Listed Not Listed Not Listed Not Listed PM Acetate Not Listed Not Listed Not Listed Not Listed Not Listed Methylisobutyl ketone A3 Group 2B Not Listed Not Listed Listed Xylene (mix) A4 Not Listed Not Listed Not Listed Not Listed N-Butane Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Ethyl benzene A3 Group 2B Not Listed Not Listed Listed Carbon Black A3 Group 2B Not Listed Not Listed Listed Isobutyl acetate Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=0.0084 mg/L (24 h) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Water Flea Data Gammarus lacustris LC50=0.6 mg/L (48 h) water flea EC50=3.82 mg/L (48 h) Acetone PM Acetate Methylisobutyl ketone Water Flea Data Daphnia magna EC50>500 mg/L (48 h) Product code 98761 Microtox Data Photobacterium phosphoreum EC50=79.6 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data Daphnia magna EC50=170 mg/L (48 h) Product name HSP Gloss Black Xylene (mix) Page 235 of 495 Page 235 of 495 Page 235 of 495 Page 235 of 495 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Aquatic toxicity Hazardous for water, do not empty into drains. Ecotoxicity effects This product does not contain any chlorofluorocarbons (CFC's), hydrochlorofluorocarbons (HCFC's), perfluorocarbons (PCF's), or chlorinated solvents. 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. Do not puncture or incinerate. Please recycle empty container whenever possible. Do not heat or cut empty containers with electric or gas torches . 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Consumer commodity, ORM-D. TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Barium Sulfate Listed Ethylene glycol monopropyl ether Listed Methylisobutyl ketone Listed Xylene (mix) Listed Ethyl benzene Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Acetone Not Listed Listed Not Listed Barium Sulfate Not Listed Listed Not Listed Ethylene glycol monopropyl ether Not Listed Not Listed Not Listed Methyl Propyl Ketone Not Listed Listed Not Listed PM Acetate Not Listed Not Listed Not Listed Methylisobutyl ketone Listed Listed Carcinogen Xylene (mix) Not Listed Listed Not Listed N-Butane Not Listed Listed Not Listed Propane Listed Listed Not Listed Ethyl benzene Listed Listed Carcinogen Carbon Black Not Listed Listed Carcinogen Isobutyl acetate Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Acetone X X - X Barium Sulfate X X - X Ethylene glycol monopropyl ether X X - X Methyl Propyl Ketone X X - X PM Acetate X X - X Methylisobutyl ketone X X - X Xylene (mix) X X - X N-Butane X X - X Propane X X - X Ethyl benzene X X - X Carbon Black X X - X Isobutyl acetate X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 1 Flammability - 4 Reactivity - 3 HMIS Health - 1 Flammability - 4 Physical Hazard - 3 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Isobutyl acetate Water Flea Data Daphnia magna EC50>5600 mg/L (24 h) Product code 98761 Product name HSP Gloss Black Ethyl benzene Water Flea Data Daphnia magna EC50=168 mg/L (24 h) Microtox Data Photobacterium phosphoreum EC50=9.68 mg/L (30 min) Nitrosomonas EC50=96 mg/L (24 h) Water Flea Data Daphnia magna EC501.8 - 2.4 mg/L (48 h) Carbon Black Page 236 of 495 Page 236 of 495 Page 236 of 495 Page 236 of 495 ---PAGE BREAK--- Page 237 of 495 Page 237 of 495 Page 237 of 495 Page 237 of 495 ---PAGE BREAK--- Page 238 of 495 Page 238 of 495 Page 238 of 495 Page 238 of 495 ---PAGE BREAK--- Page 239 of 495 Page 239 of 495 Page 239 of 495 Page 239 of 495 ---PAGE BREAK--- Page 240 of 495 Page 240 of 495 Page 240 of 495 Page 240 of 495 ---PAGE BREAK--- Page 241 of 495 Page 241 of 495 Page 241 of 495 Page 241 of 495 ---PAGE BREAK--- Page 242 of 495 Page 242 of 495 Page 242 of 495 Page 242 of 495 ---PAGE BREAK--- Page 243 of 495 Page 243 of 495 Page 243 of 495 Page 243 of 495 ---PAGE BREAK--- Page 244 of 495 Page 244 of 495 Page 244 of 495 Page 244 of 495 ---PAGE BREAK--- Page 245 of 495 Page 245 of 495 Page 245 of 495 Page 245 of 495 ---PAGE BREAK--- Page 246 of 495 Page 246 of 495 Page 246 of 495 Page 246 of 495 ---PAGE BREAK--- Page 247 of 495 Page 247 of 495 Page 247 of 495 Page 247 of 495 ---PAGE BREAK--- Page 248 of 495 Page 248 of 495 Page 248 of 495 Page 248 of 495 ---PAGE BREAK--- Page 249 of 495 Page 249 of 495 Page 249 of 495 Page 249 of 495 ---PAGE BREAK--- Page 250 of 495 Page 250 of 495 Page 250 of 495 Page 250 of 495 ---PAGE BREAK--- Page 251 of 495 Page 251 of 495 Page 251 of 495 Page 251 of 495 ---PAGE BREAK--- page 1 of 6 DATE OF PREPARATION Jan 30, 2010 MATERIAL SAFETY DATA SHEET B50NZ6 30 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B50NZ6 PRODUCT NAME KEM KROMIK® Universal Metal Primer (VOC Comp.), Brown MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * Page 252 of 495 Page 252 of 495 Page 252 of 495 Page 252 of 495 ---PAGE BREAK--- B50NZ6 page 2 of 6 HMIS Codes Health 2* Flammability 3 Reactivity 0 SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 5 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 PPM (Skin) OSHA PEL 150 PPM (Skin) STEL 2 100-41-4 ACGIH TLV 100 PPM 7.1 mm ACGIH TLV 125 PPM STEL OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 10 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 1 64742-95-6 Light Aromatic Hydrocarbons ACGIH TLV Not Available 3.8 mm OSHA PEL Not Available 2 95-63-6 ACGIH TLV 25 PPM 2.03 mm OSHA PEL 25 PPM 4 108-94-1 Cyclohexanone ACGIH TLV 25 PPM (Skin) 2 mm OSHA PEL 25 PPM (Skin) 0.2 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 4 14807-96-6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust 43 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 1 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 0.1 1333-86-4 Carbon Black ACGIH TLV 3.5 MG/M3 OSHA PEL 3.5 MG/M3 SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 253 of 495 Page 253 of 495 Page 253 of 495 Page 253 of 495 ---PAGE BREAK--- B50NZ6 page 3 of 6 UEL 8.1 LEL 0.7 FLASH POINT 80 °F PMCC SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION RED LABEL Flammable, Flash below 100 °F (38 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IC PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Page 254 of 495 Page 254 of 495 Page 254 of 495 Page 254 of 495 ---PAGE BREAK--- B50NZ6 page 4 of 6 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 12.63 lb/gal 1513 g/l SPECIFIC GRAVITY 1.52 BOILING POINT 222 - 360 °F 105 - 182 °C MELTING POINT Not Available VOLATILE VOLUME 47% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 3.46lb/gal 414g/l Less Water and Federally Exempt Solvents 3.46lb/gal 414g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. Page 255 of 495 Page 255 of 495 Page 255 of 495 Page 255 of 495 ---PAGE BREAK--- B50NZ6 page 5 of 6 TOXICOLOGY DATA CAS No. Ingredient Name 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 64742-95-6 Light Aromatic Hydrocarbons LC50 RAT 4HR Not Available LD50 RAT Not Available 95-63-6 LC50 RAT 4HR Not Available LD50 RAT Not Available 108-94-1 Cyclohexanone LC50 RAT 4HR 8000 ppm LD50 RAT 1535 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available 1333-86-4 Carbon Black LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION US Ground (DOT) 1 Gallon and Less may be Classed as CONSUMER COMMODITY, ORM-D Larger Containers are Regulated as: UN1263, PAINT, 3, PG III, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Toluene 1000 lb RQ Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): RQ, UN1263, PAINT, 3, PG III, (XYLENES (ISOMERS AND MIXTURE)), (ERG#128) Canada (TDG) UN1263, PAINT, CLASS 3, PG III, LIMITED QUANTITY, (ERG#128) IMO UN1263, PAINT, CLASS 3, PG III, (27 C EmS F-E, S-E, ADR (D/E) Page 256 of 495 Page 256 of 495 Page 256 of 495 Page 256 of 495 ---PAGE BREAK--- B50NZ6 page 6 of 6 SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 5 100-41-4 2 1330-20-7 Xylene 10 95-63-6 2 Zinc Compound 2 1.0 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 257 of 495 Page 257 of 495 Page 257 of 495 Page 257 of 495 ---PAGE BREAK--- KRUD KUTTER® Concrete & Driveway Cleaner 8/10/07 1/6 MATERIAL SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION Product Name: KRUD KUTTER® Concrete & Driveway Cleaner Synonyms: Not applicable Molecular Formula: Not applicable Molecular Weight: Not applicable Supplier: Supreme Chemicals of Georgia, Inc. 1535 Oak Industrial Lane, Suite B Cumming, GA 30041 USA Emergency Telephone: (CHEMTREC) [PHONE REDACTED] (Non-emergency Telephone) 800- 466-7126 Intended Use: Cleaning Agent 2 HAZARDS IDENTIFICATION Emergency Overview Physical State: Liquid Color: Orange Odor: Sweet Low hazard for usual industrial, commercial or consumer handling practices. Potential Health Effects Inhalation: Expected to be a low inhalation hazard. Eye Contact: May cause transient irritation. Skin Contact: May cause mild skin irritation in sensitive individuals. Exposure may cause transient redness, itching, and inflammation of skin. Ingestion: Not expected to be an ingestion hazard with product use. Chronic Health Effects: None known Target Organ(s): Skin OSHA Regulatory Status: Nonhazardous Page 258 of 495 Page 258 of 495 Page 258 of 495 Page 258 of 495 ---PAGE BREAK--- KRUD KUTTER® Concrete & Driveway Cleaner 8/10/07 2/6 3 COMPOSITION / INFORMATION ON INGREDIENTS Active Ingredients CAS-No. Weight % ethylene glycol monobutyl ether 111-76-2 < 6 4 FIRST AID MEASURES Inhalation: If move to fresh air. Get medical attention if persist. Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention. Skin Contact: Wash with soap and water. Get medical attention if occur. Ingestion: If swallowed, DO NOT induce vomiting, unless directed by medical personnel. Get medical attention. 5 FIRE-FIGHTING MEASURES Extinguishing Media: Water spray, dry chemical, carbon dioxide and alcohol foam Unsuitable Extinguishing Media: Not applicable Special Fire Fighting Procedures: Wear self-contained breathing apparatus and protective clothing. Unusual Fire & Explosion Hazards: None known Hazardous Combustion Products: Carbon oxides 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate personal protective equipment. See Section 8. Spill Cleanup Methods: Small Liquid Spills: Wipe up or use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Large Spillages: Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. 7 HANDLING AND STORAGE Handling: No special precautionary health measures should be needed under anticipated conditions of use. Wash thoroughly after handling. Prevention of Fire and Explosion: None Storage: Keep container closed. Store in original container. Keep out of reach of children. Page 259 of 495 Page 259 of 495 Page 259 of 495 Page 259 of 495 ---PAGE BREAK--- KRUD KUTTER® Concrete & Driveway Cleaner 8/10/07 3/6 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Industrial Exposures: Exposure Limits: Chemical Name Source Type Exposure Limits Notes 2-Butoxyethanol (EGBE) ACGIH TWA 20 ppm Irritation, CNS 2-Butoxyethanol OSHA TWA 50 ppm Skin 2-Butoxyethanol NIOSH REL 5 ppm Skin 2-Butoxyethanol NIOSH IDLH 700 ppm Skin 2-Butoxyethanol Cal OSHA TWA 20 ppm Skin 2-Butoxyethanol Alberta TWA 20 ppm Skin 2-Butoxyethanol (EGBE) British Columbia TWA 20 ppm Skin 2-Butoxyethanol Ontario TWAEV 20 ppm Skin 2-Butoxyethanol Quebec TWA 20 ppm Skin Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne contaminants below established exposure limits. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. Eye Protection: Wear splash goggles and a face shield where a splash hazard exists. Hand Protection: Wear chemical-resistant gloves. Contact health and safety professionals for additional information. Skin Protection: Wear protective clothing appropriate for the risk of exposure. Hygiene Measures: Eye wash, washing facilities 9 PHYSICAL AND CHEMICAL PROPERTIES Color: Orange Odor: Sweet Physical State: Liquid pH: No data available Boiling Point: 212º C (413.6º F) Melting Point: < -1.1° C (30° F) Flash Point: None Evaporation Rate: < 1 (Water = 1) Flammability: None Flammability Limit – Upper Not applicable Page 260 of 495 Page 260 of 495 Page 260 of 495 Page 260 of 495 ---PAGE BREAK--- KRUD KUTTER® Concrete & Driveway Cleaner 8/10/07 4/6 Flammability Limit – Lower Not applicable Vapor Pressure: 17 mm Hg 20 ºC) (68° F) Vapor Density (Air=1): 3.2 Specific Gravity: 1.01 Solubility in Water: Complete Partition Coefficient (n-Octanol/water): No data available Autoignition Temperature: Not applicable Decomposition Temperature: No data available Volatile Organic Compounds (VOC): 0% Viscosity: No data available Percent Volatile: 0 % 10 STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: None known Incompatible Materials: Strong oxidizing agents Hazardous Decomposition Products: Carbon oxides, nitrogen oxides Possibility of Hazardous Reactions: Will not occur. 11 TOXICOLOGICAL INFORMATION Acute Toxicity –Available upon request. Listed Carcinogens: None 12 ECOLOGICAL INFORMATION Krud Kutter® Concrete & Driveway Cleaner is non-toxic and biodegradable. 13 DISPOSAL CONSIDERATIONS General Information: Dispose in accordance with applicable federal, state, and local regulations. Disposal Methods: No specific disposal method required. Container: Since emptied containers retain product residue, follow label warnings even after container is emptied. 14 TRANSPORT INFORMATION DOT: Not regulated TDG: Not regulated IATA: Not regulated Page 261 of 495 Page 261 of 495 Page 261 of 495 Page 261 of 495 ---PAGE BREAK--- KRUD KUTTER® Concrete & Driveway Cleaner 8/10/07 5/6 IMDG: Not regulated 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS Classification: Noncontrolled Mexico: Nonhazardous Inventory Status This product or all components are listed on the following inventory: TSCA DSL Inventory: No information available US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Component Reportable Quantity Glycol ethers SARA Title III Section 302Extremely Hazardous Substance (40 CFR 355, Appendix None Section 311/312 (40 CFR 370): None Section 313 Toxic Release Inventory (40 CFR 372): Component CAS No. Concentration Certain glycol ethers 111-76-2 <6 % Clean Air Act (CCA) Section 112, 1990 Amendments, Statutory Hazardous Air Pollutants: None Clean Air Act (CAA) Section 112(i) High-Risk Hazardous Air Pollutants (40 CFR 63.74): None Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): None Clean Water Act Section 307 Toxic Pollutants (40 CFR 401.15): None Clean Water Act Section 311 Hazardous Chemical (40 CFR 116.4): None Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): None Drug Enforcement Act: None TSCA: None State Regulations Page 262 of 495 Page 262 of 495 Page 262 of 495 Page 262 of 495 ---PAGE BREAK--- KRUD KUTTER® Concrete & Driveway Cleaner 8/10/07 6/6 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): None Massachusetts Right-To-Know List: 2-butoxyethanol New Jersey Right-To-Know List: 2-butoxyethanol 16 OTHER INFORMATION Hazard Ratings Health Hazard Fire Hazard Reactivity Hazard Special Hazard NFPA 1 0 0 None Health Hazard Fire Hazard Reactivity Hazard HMIS 1 0 0 0 – Minimal; 1 – Slight; 2 – Moderate; 3 – Serious; 4 – Severe; Chronic health effect Revision Information: Revised all sections of the MSDS based on new toxicity data. Prepared by: Supreme Chemicals of Georgia, Inc. Issue Date: 08/10/07 Supersedes Date: 06/12/07 Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 263 of 495 Page 263 of 495 Page 263 of 495 Page 263 of 495 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 MATERIAL SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION Product Name: KRUD KUTTER® Concrete Clean and Etch Synonyms: Not applicable Molecular Formula: Not applicable Molecular Weight: Not applicable Supplier: Supreme Chemicals of Georgia, Inc. 1535 Oak Industrial Lane, Suite B Cumming, GA 30041 USA Emergency Telephone: (CHEMTREC) [PHONE REDACTED] (Non-emergency Telephone) 800- 466-7126 Intended Use: Cleaning agent 2 HAZARDS IDENTIFICATION Emergency Overview Physical State: Liquid Color: Translucent orange Odor: Bland WARNING! Causes skin and eye irritation. Mist or vapors irritating to eyes and respiratory tract. Potential Health Effects Inhalation: Mist or vapor irritating to eyes and respiratory tract. Exposure may cause coughing, asthmatic breathing and irritation. Eye Contact: Causes eye irritation. Exposure may cause eye tearing, redness and discomfort. Skin Contact: Causes skin irritation. Exposure may cause redness, itching and inflammation. Ingestion: Not expected to be an ingestion hazard for intended use. Exposure may cause gastrointestinal irritation, nausea, vomiting, diarrhea and other systemic effects. Chronic Health Effects: None known Target Organ(s): Eye, skin, respiratory tract OSHA Regulatory Status: Hazardous; consumer product use is exempt. North America MSDS 1/8 Page 264 of 495 Page 264 of 495 Page 264 of 495 Page 264 of 495 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 3 COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight % phosphoric acid 7664-38-2 < 40 % Components not listed are not hazardous or are below reportable limits 4 FIRST AID MEASURES Inhalation: If inhaled, remove to fresh air. Get medical attention if persist. Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. If vomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything by mouth to an unconscious person. Get medical attention. 5 FIRE-FIGHTING MEASURES Extinguishing Media: Water spray, carbon dioxide, dry chemical or alcohol foam Unsuitable Extinguishing Media: None known Special Fire Fighting Procedures: Wear self-contained breathing apparatus and protective clothing. Unusual Fire & Explosion Hazards: None known Hazardous Combustion Products: Carbon oxides, phosphorous oxides 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate personal protective equipment. See Section 8. Spill Cleanup Methods: Small Liquid Spills: Wipe up or use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Large Spillages: Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use water spray to reduce vapors or divert vapor cloud drift. Isolate and stay upwind. Ventilate enclosed areas. Keep unauthorized personnel away. Prevent entry into waterways, sewer, basements or confined areas. 7 HANDLING AND STORAGE Handling: Avoid breathing mist or vapors. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wash thoroughly after handling. North America MSDS 2/8 Page 265 of 495 Page 265 of 495 Page 265 of 495 Page 265 of 495 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Prevention of Fire and Explosion: None Storage: Keep container closed. Store in original container. Keep out of reach of children. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Industrial Exposures: Exposure Limits: Chemical Name Source Type Exposure Limits Notes phosphoric acid NIOSH REL 1 mg/m³ phosphoric acid NIOSH STEL 3 mg/m³ phosphoric acid NIOSH IDLH 1000 mg/m³ phosphoric acid ACGIH TWA 1 mg/m³ Upper respiratory tract eye & skin irritant phosphoric acid ACGIH STEL 3 mg/m³ Upper respiratory tract eye & skin irritant phosphoric acid OSHA Z-1 PEL 1 mg/m³ phosphoric acid California TWA 1 mg/m³ phosphoric acid California STEL 3 mg/m³ phosphoric acid Alberta, Canada TWA 1 mg/m³ Irritation phosphoric acid Alberta, Canada STEL 3 mg/m³ Irritation phosphoric acid British Columbia, Canada TWA 1 mg/m³ phosphoric acid British Columbia, Canada STEL 3 mg/m³ phosphoric acid Ontario, Canada TWA 1 mg/m³ phosphoric acid Ontario, Canada STEL 3 mg/m³ phosphoric acid Quebec, Canada TWA 1 mg/m³ phosphoric acid Quebec, Canada STEL 3 mg/m³ phosphoric acid Mexico TWA 1 mg/m³ phosphoric acid Mexico STEL 3 mg/m³ Engineering Controls: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. North America MSDS 3/8 Page 266 of 495 Page 266 of 495 Page 266 of 495 Page 266 of 495 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Eye Protection: Wear splash goggles and a face shield or safety glasses with side shields. Hand Protection: Wear chemical resistant gloves. Skin Protection: Wear protective clothing appropriate for the risk of exposure. Hygiene Measures: Eye wash, washing facilities, safety shower 9 PHYSICAL AND CHEMICAL PROPERTIES Color: Translucent orange Odor: Bland Physical State: Liquid pH: No data available Boiling Point: 218º C (424.4º F) Melting Point: < -1.1° C (30° F) Flash Point: None Evaporation Rate: < 1 (Water = 1) Flammability: None Flammability Limit – Upper Not applicable Flammability Limit – Lower Not applicable Vapor Pressure: 17 mm Hg 20 ºC) (68° F) Vapor Density (Air=1): 3.2 Specific Gravity: 1.1 – 1.3 Solubility in Water: Complete Partition Coefficient (n-Octanol/water): No data available Autoignition Temperature: Not applicable Decomposition Temperature: No data available Volatile Organic Compounds (VOC): No data available Viscosity: No data available Percent Volatile: No data available 10 STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: None known Incompatible Materials: Strong oxidizing agents, alkalis Hazardous Decomposition Products: Carbon oxides, phosphorous oxides Possibility of Hazardous Reactions: Will not occur. 11 TOXICOLOGICAL INFORMATION Information available upon request. Listed Carcinogens: None North America MSDS 4/8 Page 267 of 495 Page 267 of 495 Page 267 of 495 Page 267 of 495 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 12 ECOLOGICAL INFORMATION Krud Kutter® Concrete Clean and Etch is biodegradable. 13 DISPOSAL CONSIDERATIONS General Information: Dispose in accordance with applicable federal, state, and local regulations. Disposal Methods: No specific disposal method required. Container: Since emptied containers retain product residue, follow label warnings even after container is emptied. 14 TRANSPORT INFORMATION DOT: ORM-D Proper Shipping Name: Consumer Commodity Packaging Requirements: Inner packagings not over 5.0 Liters (1.3 Gallons) net capacity each for liquids, and packed in strong outer packagings. Packages over 5.0 Liters (1.3 Gallons): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 TDG: UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 IATA: For Limited Quantities of liquids of Class 8 Packing Group III: Passenger & Cargo Aircraft Packing Instructions: Y819 Passenger & Cargo Aircraft Limited Quantity Maximum Quantity Package: 1 Liter Single packagings are not permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. The maximum quantity must not exceeded. Inner packagings: glass earthenware, plastic, metal (not aluminum), or glass ampoule. Outer Packaging: Steel packagings must be corrosion-resistant or with protection against corrosion. Glass or earthenware inner packagings and glass ampoules must be packaged with absorbent material in closed metal or rigid plastic receptacles in outer packagings. Glass or earthenware inner packagings and glass ampoules are permitted if this item is free from hydrofluoric acid. Outer Packaging: Drums: Steel, aluminum, plywood, fiber, plastic. Jerricans: Steel, aluminum, plastic Boxes: UN Certified Box, steel, aluminum, wood, plywood, reconstituted wood, fiber board and plastic North America MSDS 5/8 Page 268 of 495 Page 268 of 495 Page 268 of 495 Page 268 of 495 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Passenger & Cargo Aircraft Packing Instructions: 819 Passenger & Cargo Aircraft Maximum Quantity/Package: 5 Liters Single packagings are not permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. The maximum quantity must not exceeded. Inner packagings: glass earthenware, plastic, metal (not aluminum), or glass ampoule. Outer Packaging: Steel packagings must be corrosion-resistant or with protection against corrosion. Glass or earthenware inner packagings and glass ampoules must be packaged with absorbent material in closed metal or rigid plastic receptacles in outer packagings. Glass or earthenware inner packagings and glass ampoules are permitted if this item is free from hydrofluoric acid. Outer Packaging: Drums: Steel (1A2), aluminum (1B2), plywood (1D), fiber (1G), plastic (1H2). Jerricans: Steel (4A), Aluminum (4B), Plastic (3H2); Boxes: UN Certified Box, Steel (4A), aluminum (3B2), wood (4C1,4C2), plywood (4D), reconstituted wood (5F), fiber board (4G) and plastic (4H1, 4H2). Cargo Aircraft Only Package Instruction: 821 Cargo Aircraft Only Maximum Quantity/Package: 60 Liters Combination and single packagings are permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. Combination packagings: inner packagings: Glass or earthenware, plastic, metal (not aluminum) or glass ampoule. Outer packaging: Drums: Steel (1A2), aluminum (1B2), plywood (1D), fiber (1G), plastic (1H2). Jerricans: Steel (3A2), aluminum (3B2), plastic (1H2); Boxes: UN Certified Box, steel(4A), aluminum (4B), wood (4C1,4C2), plywood (4D), reconstituted wood (4F), fiber board (4G) and plastic (4H1, 4H2). Special Provisions: A3 ERG Code: 8L Packages over 5.0 Liters (1.3 Gallons): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 IMDG: Limited Quantities Exception: Dangerous Goods in limited quantities of Class 8. Limited quantities must be packed in combination packaging. The inner packaging must be within the quantity limit specified in the Dangerous Goods List (DGL) for the substance being prepared for shipment and be packaged in suitable outer packaging (i.e. UN certified box). The gross mass of the package must not exceed 30 kilograms (66 pounds). For over 30 kilograms (66 pounds): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III EMS No: F-A, S-B Special Provision: 223 Packing Instructions: P001, LP01 North America MSDS 6/8 Page 269 of 495 Page 269 of 495 Page 269 of 495 Page 269 of 495 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 IBC 03 Portable tanks and bulk containers: IMO Tank Instructions: T3 UN Tank Instructions: T4 Provisions: TP1 Stowage and Segregation: Category A 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS Classification: D2B Mexico: Hazard Identification Guidance List: Phosphoric Acid: 3-0-0 PPE: F Inventory Status This product or all components are listed on the following inventory: TSCA DSL Inventory: No information available US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Component Reportable Quantity phosphoric acid 5,000 lbs SARA Title III Section 302Extremely Hazardous Substance (40 CFR 355, Appendix None Section 311/312 (40 CFR 370): X Acute (Immediate) Chronic (Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory (40 CFR 372): None Clean Air Act (CCA) Section 112, 1990 Amendments, Statutory Hazardous Air Pollutants: None Clean Air Act (CAA) Section 112(i) High-Risk Hazardous Air Pollutants (40 CFR 63.74): None Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): None Clean Water Act Section 307 Toxic Pollutants (40 CFR 401.15): None Clean Water Act Section 311 Hazardous Chemical (40 CFR 116.4): Phosphoric acid Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Component Reportable Quantity phosphoric acid 5,000 lbs North America MSDS 7/8 Page 270 of 495 Page 270 of 495 Page 270 of 495 Page 270 of 495 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Drug Enforcement Act: None TSCA: None . State Regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): None Massachusetts Right-To-Know List: Phosphoric Acid Minnesota Hazardous Substances List: Phosphoric Acid New Jersey Right-To-Know List: Phosphoric Acid Right-To-Know Substances: Phosphoric Acid 16 OTHER INFORMATION Hazard Ratings Health Hazard Fire Hazard Reactivity Hazard Special Hazard NFPA 2 0 0 N/A Health Hazard Fire Hazard Reactivity Hazard HMIS 2 0 0 0 – Minimal; 1 – Slight; 2 – Moderate; 3 – Serious; 4 – Severe; Chronic health effect Revision Information: New Prepared by: Supreme Chemicals of Georgia, Inc. Issue Date: 8/28/2007 Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. North America MSDS 8/8 Page 271 of 495 Page 271 of 495 Page 271 of 495 Page 271 of 495 ---PAGE BREAK--- Page 272 of 495 Page 272 of 495 Page 272 of 495 Page 272 of 495 ---PAGE BREAK--- Page 273 of 495 Page 273 of 495 Page 273 of 495 Page 273 of 495 ---PAGE BREAK--- Page 274 of 495 Page 274 of 495 Page 274 of 495 Page 274 of 495 ---PAGE BREAK--- Page 275 of 495 Page 275 of 495 Page 275 of 495 Page 275 of 495 ---PAGE BREAK--- Page 276 of 495 Page 276 of 495 Page 276 of 495 Page 276 of 495 ---PAGE BREAK--- Page 277 of 495 Page 277 of 495 Page 277 of 495 Page 277 of 495 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550, MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS LECTRA SOL TC (AEROSOL) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Trichloroethylene (CAS# 79-01-6) >1 50 ppm Carbon Dioxide (CAS# 124-38-9) >1 5000 ppm This product contains 14 ounces of Trichloroethylene per can of product. Trichloroethylene is a regulated chemical under the Emergency Planning and Right-To-Know Act. You are required to file E.P.A. SARA repots once the threshold of 10,000 pounds of Trichloroethylene has been purchased for one location in each calendar year. All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT (ºF) 189° F SPECIFIC GRAVITY (H2O = 1) 1.4 VAPOR PRESSURE (in can PSIG) 95-105 PERCENT VOLATILE BY VOLUME 100 VAPOR DENSITY (AIR = 1) 4 EVAPORATION RATE ( Butyl Acetate faster SOLUBILITY IN WATER insoluble PH N/A APPEARANCE AND ODOR Clear water white liquid with an etherial odor. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) None FLAMMABLE LIMITS 8.0 52.0 EXTINGUISHING MEDIA Use extinguishing media suitable for fighting surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120ºF. (Continued on reverse side) Page 278 of 495 Page 278 of 495 Page 278 of 495 Page 278 of 495 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA THRESHOLD LIMIT VALUE 50 ppm PRIMARY ROUTES OF ENTRY Inhalation x Skin Contact x Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- liquid and vapors may cause irritation. Skin- dry skin, irritation. Inhalation- narcosis, headache, dizziness, carboxyhemoglobinemia. Alcohol consumed before exposure increases effects. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- flush with water and then wash with soap and water, launder contaminated clothing before reuse- get medical if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- DO NOT INDUCE VOMITING- aspiration of material into lungs may cause chemical pneumonitis which can be fatal- get medical attention. Use gastric lavage. Never use adrenalin. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Persons with pre-existing heart or respiratory disorders Carcinogen: NTP IARC OTHER X California Prop 65 SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE x CONDITIONS TO AVOID Temperatures in excess of 120ºF. INCOMPATABILITY (Conditions to avoid) Strong Oxidizers and Alkalies, reactive metals HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon, Hydrogen Chloride, Phosgene MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR x CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Ventilate spill area. Dike area to contain spill and use absorbent material to soak up spill. Shovel or sweep into for container for disposal. WASTE DISPOSAL METHOD Aerosol cans when emptied and depressurized through normal use pose no disposal hazard and should be recycled. Absorbent materials should be disposed of in accordance with all Local, State, and Federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Use NIOSH approved respirator in areas where TLV has been exceeded. LOCAL EXHAUST To control TLV SPECIAL N/A VENTILATION MECHANICAL (General) To control TLV OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical Goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower. SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- do not use in confined, poorly ventilated, or other areas where TLV may be exceeded without proper respiratory protection. Do not take internally. OTHER PRECAUTIONS Do not store in areas where temperatures may exceed 120 degrees F. Keep Out of Reach of Children. HMIS SYMBOL SEVERE 4 SERIOUS 3 MODERATE 2 SLIGHT 1 MINIMAL 0 NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE June 19, 2012 PHONE NUMBER CHEMTREC [PHONE REDACTED] HEALTH 2 FLAMMABILITY 1 REACTIVITY 0 Page 279 of 495 Page 279 of 495 Page 279 of 495 Page 279 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 28-May-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19907 Product name Light Oil Lubricant Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Ingestion. Inhalation. Skin contact. Skin absorption. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Chronic exposure causes drying effect on the skin . Inhalation Harmful by inhalation. Repeated or prolonged exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Chronic overexposure can cause: . Lung damage. Ingestion Harmful or fatal if swallowed. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Extreme overexposure may cause. Kidney damage. Liver abnormalities. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % VM&P Naphtha 8032-32-4 10-30 Propane/Isobutane/N- Butane 68476-86-8 10-30 Paraffinic Mineral Oil 8042-47-5 3-7 4. FIRST AID MEASURES Eye contact Flush eyes with plenty of water. Seek medical attention if irritation persists. Skin contact Flush skin with water. Remove and wash contaminated clothing before re-use. Seek medical attention immediately. Ingestion Seek medical attention immediately. Do not induce vomiting. Give victim a glass of water or milk. Call a physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5 Lower 1.1 Suitable extinguishing media Alcohol foam. Carbon dioxide. Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Page 1 / 4 Emergency Overview Vapors extremely irritating to eyes and respiratory tract. Vapors may cause flash fire or explosion. Page 280 of 495 Page 280 of 495 Page 280 of 495 Page 280 of 495 ---PAGE BREAK--- Fire and Explosion Hazards Flash back possible over considerable distance. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Remove and wash contaminated clothing before re-use. Ensure adequate ventilation. Use only according to label directions. Avoid contact with skin, eyes and clothing. Avoid breathing vapors from heated material . Storage Keep away from heat and sources of ignition. Do not freeze. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) VM&P Naphtha - - - - Propane/Isob utane/N- Butane - - - - Paraffinic Mineral Oil - - - - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Wash hands before breaks and immediately after handling the product. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. where exposure levels are not known. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Hand Protection Chemical resistant gloves. Eye protection Use safety eyewear designed to protect against impact. Skin and body protection None necessary under normal conditions Other Protective Equipment Wear appropriate clothing to prevent skin contact. Rubber boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Clear Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity 0.8428 Vapor pressure 80-90 Vapor density >Air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Negligible VOC Content 2.04 lbs/gal; 244 g/l Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -41 - 142 Boiling point/range °F -43 - 287 Melting point/range °C 0 Melting point/range °F 32 Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Do not use near other sources of ignition. Do not use near welding arcs. Avoid open flames. Page 2 / 4 Product code 19907 Product name Light Oil Lubricant Page 281 of 495 Page 281 of 495 Page 281 of 495 Page 281 of 495 ---PAGE BREAK--- Incompatability Strong acids. Alkalies. Oxidizers. Amines. Hazardous Decomposition Products Sulphur oxides. Carbon oxides. Nitrogen oxides (NOx). Chlorides. Chlorine. Phosgene . Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) VM&P Naphtha 8032-32-4 - - 3400 ppm Propane/Isobutan e/N-Butane 68476-86-8 - - - Paraffinic Mineral Oil 8042-47-5 5000 mg/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects May cause damage to liver. May cause damage to kidneys. Central nervous system. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns VM&P Naphtha Not Listed Not Listed Not Listed Not Listed Not Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity <1L 15. REGULATORY INFORMATION State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 VM&P Naphtha Not Listed Listed Not Listed Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA VM&P Naphtha X X - X Propane/Isobutane/N- Butane X X - X Paraffinic Mineral Oil X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer Page 3 / 4 Product code 19907 Product name Light Oil Lubricant Page 282 of 495 Page 282 of 495 Page 282 of 495 Page 282 of 495 ---PAGE BREAK--- The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 19907 Product name Light Oil Lubricant Page 283 of 495 Page 283 of 495 Page 283 of 495 Page 283 of 495 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Liquid Wrench Lubricating Oil Product identifier Other means of identification L204 SDS number L204 Part No. 3403.19.1000 Tariff code Lubricant Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service: (704) 821-7643 Technical: (704) 684-1811 Emergency phone number Emergency Telephone: (303) 623-5716 Emergency Contact: ([PHONE REDACTED]) E-mail United States Not available. Indian Trail, NC 28079 2. Hazard(s) identification Not classified. Physical hazards Category 4 Acute toxicity, dermal Health hazards Category 4 Acute toxicity, inhalation Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Warning Hazard statement Harmful in contact with skin. Harmful if inhaled. Precautionary statement Prevention Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing. Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Take off contaminated clothing and wash before reuse. Storage Store away from incompatible materials. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information 90.23% of the mixture consists of component(s) of unknown acute dermal toxicity. 3. Composition/information on ingredients Mixtures 1 / 8 Material name: Liquid Wrench Lubricating Oil L204 Version 02 Revision date: 05-18-2015 Issue date: 04-29-2015 SDS US Page 284 of 495 Page 284 of 495 Page 284 of 495 Page 284 of 495 ---PAGE BREAK--- CAS number % Common name and synonyms Chemical name 64742-52-5 Distillates (petroleum), Hydrotreated Heavy Naphthenic 90 - 100 Other components below reportable levels 5 - < 10 111-76-2 2-Butoxyethanol 1 - < 3 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Wash off with soap and water. Get medical advice/attention if you feel unwell. Get medical attention if irritation develops and persists. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. Get medical advice/attention if you feel unwell. Ingestion Direct contact with eyes may cause temporary irritation. Most important acute and delayed Provide general supportive measures and treat Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Specific methods No unusual fire or explosion hazards noted. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors and spray mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Do not get in eyes, on skin, or on clothing. Avoid inhalation of vapors and spray mists. Avoid prolonged exposure. When using, do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Observe good industrial hygiene practices. Precautions for safe handling 2 / 8 Material name: Liquid Wrench Lubricating Oil L204 Version 02 Revision date: 05-18-2015 Issue date: 04-29-2015 SDS US Page 285 of 495 Page 285 of 495 Page 285 of 495 Page 285 of 495 ---PAGE BREAK--- Store in original closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Form Type PEL 240 mg/m3 2-Butoxyethanol (CAS 111-76-2) 50 ppm PEL 5 mg/m3 Mist. Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) 2000 mg/m3 500 ppm US. ACGIH Threshold Limit Values Value Components Form Type TWA 20 ppm 2-Butoxyethanol (CAS 111-76-2) TWA 5 mg/m3 Inhalable fraction. Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Form Type TWA 24 mg/m3 2-Butoxyethanol (CAS 111-76-2) 5 ppm Ceiling 1800 mg/m3 Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) STEL 10 mg/m3 Mist. Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine * 2-Butoxyethanol (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennessee OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection 3 / 8 Material name: Liquid Wrench Lubricating Oil L204 Version 02 Revision date: 05-18-2015 Issue date: 04-29-2015 SDS US Page 286 of 495 Page 286 of 495 Page 286 of 495 Page 286 of 495 ---PAGE BREAK--- Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Wear appropriate chemical resistant clothing. Other In case of insufficient ventilation, wear suitable respiratory equipment. Dust & vapor respirator. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Liquid. Clear. Appearance Liquid. Physical state Liquid. Form Yellow Color Sweet Vanilla Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 680 °F (360 estimated Flash point > 200.0 °F 93.3 Tag Closed Cup Evaporation rate Not available. Not applicable. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 500 °F (260 estimated Decomposition temperature Not available. Viscosity Not available. Other information Density 7.67 lbs/gal Not explosive. Explosive properties Flammability class Combustible IIIB estimated Not oxidizing. Oxidizing properties Percent volatile 1.8 % estimated Specific gravity 0.92 VOC (Weight 1.8 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity 4 / 8 Material name: Liquid Wrench Lubricating Oil L204 Version 02 Revision date: 05-18-2015 Issue date: 04-29-2015 SDS US Page 287 of 495 Page 287 of 495 Page 287 of 495 Page 287 of 495 ---PAGE BREAK--- Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong oxidizing agents. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Harmful if inhaled. Skin contact Harmful in contact with skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Harmful if inhaled. Harmful in contact with skin. Test Results Components Species 2-Butoxyethanol (CAS 111-76-2) Dermal Acute LD50 Rabbit 400 mg/kg Inhalation LC50 Mouse 700 ppm, 7 Hours Rat 450 ppm, 4 Hours Oral LD50 Guinea pig 1.2 g/kg Mouse 1.2 g/kg Rabbit 0.32 g/kg * Estimates for product may be based on additional component data not shown. Rat 560 mg/kg Prolonged skin contact may cause temporary irritation. Skin corrosion/irritation Direct contact with eyes may cause temporary irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) Known To Be Human Carcinogen. 5 / 8 Material name: Liquid Wrench Lubricating Oil L204 Version 02 Revision date: 05-18-2015 Issue date: 04-29-2015 SDS US Page 288 of 495 Page 288 of 495 Page 288 of 495 Page 288 of 495 ---PAGE BREAK--- This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects May be harmful if absorbed through skin. Prolonged inhalation may be harmful. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test Results Species * Estimates for product may be based on additional component data not shown. 2-Butoxyethanol (CAS 111-76-2) Aquatic LC50 Fish 1250 mg/l, 96 hours Inland silverside (Menidia beryllina) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. 6 / 8 Material name: Liquid Wrench Lubricating Oil L204 Version 02 Revision date: 05-18-2015 Issue date: 04-29-2015 SDS US Page 289 of 495 Page 289 of 495 Page 289 of 495 Page 289 of 495 ---PAGE BREAK--- CERCLA Hazardous Substance List (40 CFR 302.4) 2-Butoxyethanol (CAS 111-76-2) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. 2-Butoxyethanol 111-76-2 1 - < 3 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. 2-Butoxyethanol (CAS 111-76-2) Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) US. Rhode Island RTK 2-Butoxyethanol (CAS 111-76-2) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* No Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) 7 / 8 Material name: Liquid Wrench Lubricating Oil L204 Version 02 Revision date: 05-18-2015 Issue date: 04-29-2015 SDS US Page 290 of 495 Page 290 of 495 Page 290 of 495 Page 290 of 495 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 04-29-2015 Issue date 05-18-2015 Revision date Version # 02 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer Regulatory Information: TSCA 12b Exported Products Regulatory information: US federal regulations HazReg Data: International Inventories GHS: Classification Revision Information 8 / 8 Material name: Liquid Wrench Lubricating Oil L204 Version 02 Revision date: 05-18-2015 Issue date: 04-29-2015 SDS US Page 291 of 495 Page 291 of 495 Page 291 of 495 Page 291 of 495 ---PAGE BREAK--- LIQUID WRENCH SUPER LUBRICANT Page 1 of 4 OSU COLLEGE OF BIOLOGICAL SCIENCES MSDS FILE ~ RADIATOR SPECIALTY L2-4 LIQUID WRENCH SUPER LUBRICANT PETROLEUM SOLVENTS, RUST INHIBITOR MATERIAL SAFETY DATA SHEET FSC: 9150 NUN: 00FO14159 Manufacturer's CAGE: 77628 Part No. Indicator: A Part Number/Trade Name: L2-4 LIQUID WRENCH SUPER LUBRICANT 4,-34 L2-- L2- General Information Item Name: PETROLEUM SOLVENTS, RUST INHIBITOR Company's Name:.RADIATOR SPECIALTY COMPANY Company'sStreet:1400W.INDEPENDENCEBLVD Company's City: CHARLOTTE Company's State: NC Company's Zip Code: 28208 Company's Emerg Ph (704) 377-6555 Company's Info Ph (704) 377-6555 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Date MSDS Prepared: 01SEP85 Safety Data Review Date: 12FEB91 Preparer's Company: RADIATOR SPECIALTY COMPANY Preparer's St Or P. O. Box: 1400 W. INDEPENDENCEBLVD Preparer's City: CHARLOTTE Preparer's State: NC Preparer's Zip Code: 28208 MSDS Serial Number: Ingredients/Identity Information Proprietary: NO Ingredient: ALIPHATIC PETROLEUM DISTILLATE Ingredient Sequence Number: 01 Percent: >70% NIOSH (RTECS) Number: 1004498AP CAS Number: 64742-38-7 ACGIH TLV: 300 PPM Proprietary: NO Ingredient: NAPHTHENIC PETROLEUM OIL, NAPHTHENIC OIL Ingredient Sequence Number: 02 Percent: http://www.biosci.ohio-state.edu/~jsmith/MSDS/LIQUID%20WRENCH%20SUPER%20LUl... 7/26/02 Page 292 of 495 Page 292 of 495 Page 292 of 495 Page 292 of 495 ---PAGE BREAK--- , LIQUID WRENCH SUPER LUBRICANT Page 2 of 4 ~ NIOSH (RTECS) Number: 1000661NO CAS Number: 64741-53-3 ACGIH TLV: 5 MG/CUM Proprietary: NO Ingredient: 2-BUTOXYETHANOL Ingredient Sequence Number: 03 Percent: 1-5% NIOSH (RTECS) Number: KJ8575000 CAS Number: 111-76-2 OSHA PEL: S, 50 PPM ACGIH TLV: S, 25 PPM; 9293 Other Recommended Limit: 25 PPM (SKIN) Proprietary: NO Ingredient: ALKYL AMINE DERIVATIVE Ingredient Sequence Number: 04 Percent: 0.5-5% NIOSH (RTECS) Number: 1004556AA Physical/Chemical Characteristics Appearance And Odor: DARK LIQUID W/PETROLEUM ODOR. Boiling Point: >300F Specific Gravity: 0.8 Solubility In Water: INSOLUBLE Percent Volatiles By Volume: >80% pH: >7 Fire and Explosion Hazard Data Flash Point: >1OOF Extinguishing Media: FOAM, CO2, DRY CHEMICAL Special Fire Fighting Proc: WEAR SELF-CONTAINEDBREATHING APPARATUS & FULL PROTECTIVE CLOTHING. Reactivity Data Stability: YES Cond To Avoid (Stability): HIGH TEMPERATURES, IGNITION SOURCES Materials To Avoid: ACIDS, OXIDIZING AGENTS Hazardous Decomp Products: CO2, CO, SMOKE & NITROGEN OXIDES Hazardous Poly Occur: NO http://www.biosci.ohio-state.edul~jsmith/MSDS/LIQUID%20WRENCH%20SUPER%20LU1.. 7/26/02 Page 293 of 495 Page 293 of 495 Page 293 of 495 Page 293 of 495 ---PAGE BREAK--- LIQUID WRENCH SUPER LUBRICANT Page 3 of 4 Health Hazard Data ~ RouteOfEntry- Inhalation:YES RouteOfEntry- Skin:YES RouteOf Entry- Ingestion:YES Health Haz Acute And Chronic: EYE: IRRITANT. SKIN: IRRITANT/MAY BE ABSORBED. INGESTION: HARMFUL. INHALATION: HEADACHE, DIZZINESS, NAUSEA. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NONE OfOverexp: EYE: IRRITANT. SKIN: IRRITANT/ABSORBED. INHALATION: HEADACHE, DIZZINESS, NAUSEA. INGESTION: HARMFUL. Emergency/First Aid Proc: EYE: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. IF IRRITATED, USE EMOLLIENT CREAM. INHALATION: MOVE TO FRESH AIR. INGESION: DON'T INDUCE VOMITING. CONSULT PHYSICIAN IN ALL CASES. Precautions for Safe Handling and Use Steps IfMatl Released/Spill: WIPE UP W/RAGES. OBSERVING HEALTH HAZARDS DESCRIBED ABOVE, CONFINE SPILL & TRANSFER TO WASTE DURM. Waste Disposal Method: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. Precautions-Handling/Storing: STORE AWAY FROM IGNITION SOURCES & OXIDIZING AGENTS. KEEP AWAY FROM CHILDREN. WEAR CONTACT LENSES IS INADVISABLE. Control Measures Respiratory Protection: IF TLV IS EXCEEDED, USE NIOSH APPROVED RESPIRATOR. Ventilation: USE MECHANICAL W/ADEQUATE VENTILATION Protective Gloves: OIL-RESISTANT Eye Protection: GOGGLES Transportation Data Disposal Data LabelData http://www.biosci.ohio-state.edu/~jsmith/MSDS/LIQUID%20WRENCH%20SUPER%20LUJ... 7/26/02 Page 294 of 495 Page 294 of 495 Page 294 of 495 Page 294 of 495 ---PAGE BREAK--- LIQUID WRENCH SUPER LUBRICANT Page4of4 Label Required: YES Label Status: G Common Name: L2-4 LIQUID WRENCH SUPER LUBRICANT 4,-34 Special Hazard Precautions: EYE: IRRITANT. SKIN: IRRITANTIMAYBE ABSORBED. INGESTION: HARMFUL. INHALATION: HEADACHE, DIZZINESS, NAUSEA. EYE: IRRITANT. SKIN: IRRITANT/ ABSORBED. INHALATION: HEADACHE, DIZZINESS, NAUSEA. INGESTION: HARMFUL. Label Name: RADIATOR SPECIALTY COMPANY Label Street: 1400 W. INDEPENDENCE BLVD Label City: CHARLOTTE Label State: NC Label Zip Code: 28208 Label Emergency Number: (704) 377-6555 L2- URL for this msds http://hazard.com. If you wish to change, add to, or delete information in this archive please sent updates to [EMAIL REDACTED]. http://www.biosci.ohio-state.edu/~jsmith/MSDS/LIQUID%20WRENCH%20SUPER%20LUl... 7/26/02 Page 295 of 495 Page 295 of 495 Page 295 of 495 Page 295 of 495 ---PAGE BREAK--- LOCTITE CORPORATION 08/26/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 LiteTak(R) 3751 Adhesive 21362 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: LiteTak(R) 3751 Adhesive Item No.: 21362 Product Type: UV 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polyurethane acrylate resin 116958-43-1 50-55 Modified acrylamide 2680-03-7 15-20 Substituted hydroxyalkyl methacrylate Proprietary 10-15 Acrylate ester 7328-17-8 5-10 Triacrylate ester 28961-43-5 5-10 Photoinitiator 24650-42-8 3-5 Benzoic acid derivative 10287-53-3 1-3 SILICA, AMORPHOUS, FUMED, 112945-52-5 1-3 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) SILICA, AMORPHOUS, FUMED, 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Contact may injure eyes, skin or respiratory tract Eye, skin, and inhalation irritant. Possible sensitizer. Moderately toxic by ingestion. Tests have indicated that the triacrylate ester may cause in mice. Breathing heated vapors may cause nausea, dizziness, or respiratory irritation resulting in severe or permanent allergic respiratory reaction. Modified acrylamide may be absorbed through skin Product Name: LiteTak(R) 3751 Adhesive http://www.loctite.com/datasheets/msds/21362.html (1 of 6) [8/31/2001 4:31:41 AM] Page 296 of 495 Page 296 of 495 Page 296 of 495 Page 296 of 495 ---PAGE BREAK--- in harmful amounts. May be harmful if inhaled. Primary Routes of Entry: Eyes, skin. LOCTITE CORPORATION 08/26/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: LiteTak(R) 3751 Adhesive Item No.: 21362 3. HAZARDS IDENTIFICATION (continued) Signs and of Exposure: Irritation of eyes, skin, or respiratory tract. Existing Conditions Aggravated by Exposure: Skin, eye, lung, and systemic diseases. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polyurethane acrylate resin No Data NO NO NO Modified acrylamide EYE IRR KID MUT 100 NO NO NO Substituted hydroxyalkyl methacrylate ALG IRR NO NO NO Acrylate ester ALG IRR NO NO NO Triacrylate ester ALG IRR NO NO NO Photoinitiator NTO NO NO NO Benzoic acid derivative NTO NO NO NO SILICA, AMORPHOUS, FUMED, NUI NO N/A NO Abbreviations N/A Not Applicable ALG Allergen EYE Eyes IRR Irritant KID Kidney MUT Mutagen NTO No Target Organs NUI Nuisance dust 100 Less weight gain and food intake. 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. If persist, obtain medical attention. Skin Contact: Immediately wash with soap and water. Wash contaminated clothing before reuse. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. Product Name: LiteTak(R) 3751 Adhesive http://www.loctite.com/datasheets/msds/21362.html (2 of 6) [8/31/2001 4:31:41 AM] Page 297 of 495 Page 297 of 495 Page 297 of 495 Page 297 of 495 ---PAGE BREAK--- 5. FIRE FIGHTING MEASURES Flash Point: 189°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Special Firefighting Procedures: Not available LOCTITE CORPORATION 08/26/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: LiteTak(R) 3751 Adhesive Item No.: 21362 5. FIRE FIGHTING MEASURES (continued) Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors; oxides of carbon and nitrogen. Unusual Fire or Explosion Hazards: None Explosive Limits: by volume in air)Lower Not available by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Remove sources of ignition. Maintain adequate ventilation. Soak up with an inert absorbent. Store in partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100°F away from sources of ignition. (Contact Loctite Customer Service 1-[PHONE REDACTED] for shelf life information) Handling: Avoid prolonged skin contact. Keep away from eyes. Avoid breathing vapors. Keep away from sources of ignition. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Neoprene gloves. Ventilation: Local, explosion-proof exhaust ventilation should be used. Respiratory Not available Product Name: LiteTak(R) 3751 Adhesive http://www.loctite.com/datasheets/msds/21362.html (3 of 6) [8/31/2001 4:31:41 AM] Page 298 of 495 Page 298 of 495 Page 298 of 495 Page 298 of 495 ---PAGE BREAK--- See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, water-white liquid Odor: Mild ester and amine Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.062 Volatile Organic Compound (EPA Method 24) 32.94%; 350 grams per liter Vapor Pressure: Less than 5mm at 80°F Vapor Density: Not available LOCTITE CORPORATION 08/26/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: LiteTak(R) 3751 Adhesive Item No.: 21362 9. PHYSICAL AND CHEMICAL PROPERTIES (continued) Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Unstable Hazardous Polymerization: May occur Incompatibility: Strong oxidizers, peroxides, copper and alloys, carbon steel, iron, rust, strong bases, amines, acids, free radical producing initiators. These incompatibilities do not preclude the use of this product as an adhesive for any substrate mentioned above; however, this product should not be stored in a container composed in whole or in part of these substrates. See Technical Data Sheet for any restrictions other than incompatibility. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): Dimethylamine 11. TOXICOLOGICAL INFORMATION Modified acrylamide: LD50(oral,rat) 316 mg/kg LD50(dermal,rabbit) 518 mg/kg LC50(vapor,1hr,rat) >776 ppm 12. ECOLOGICAL INFORMATION Product Name: LiteTak(R) 3751 Adhesive http://www.loctite.com/datasheets/msds/21362.html (4 of 6) [8/31/2001 4:31:41 AM] Page 299 of 495 Page 299 of 495 Page 299 of 495 Page 299 of 495 ---PAGE BREAK--- No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted (Not more than 450 liters); Combustible liquids, n.o.s. (N,N-Dimethylacrylamide solution)(More than 450 liters) Hazard Class or Division: Unrestricted (Not more than 450 liters); Combustible liquid (More than 450 liters) LOCTITE CORPORATION 08/26/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: LiteTak(R) 3751 Adhesive Item No.: 21362 14. TRANSPORTATION INFORMATION (continued) Identification Number: None (Not more than 450 liters); NA 1993 (More than 450 liters) Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. toluene, phenyl glycidyl ether, ethylene oxide, acetaldehyde, dioxane 16. OTHER INFORMATION Estimated NFPA(R) Code: Product Name: LiteTak(R) 3751 Adhesive http://www.loctite.com/datasheets/msds/21362.html (5 of 6) [8/31/2001 4:31:41 AM] Page 300 of 495 Page 300 of 495 Page 300 of 495 Page 300 of 495 ---PAGE BREAK--- Health Hazard: 2 Fire Hazard: 2 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 2 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist; Safety,Health&Regulatory Affairs Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 27, 1999 Revision: 0008 application assistance . browse catalog . troubleshooting . equipment datasheets . distributor locator .what's new . career opportunities about loctite . contact loctite . literature . loctite world wide . search . home copyright © 1997-2000 Loctite Product Name: LiteTak(R) 3751 Adhesive http://www.loctite.com/datasheets/msds/21362.html (6 of 6) [8/31/2001 4:31:41 AM] Page 301 of 495 Page 301 of 495 Page 301 of 495 Page 301 of 495 ---PAGE BREAK--- Page 302 of 495 Page 302 of 495 Page 302 of 495 Page 302 of 495 ---PAGE BREAK--- Page 303 of 495 Page 303 of 495 Page 303 of 495 Page 303 of 495 ---PAGE BREAK--- Page 304 of 495 Page 304 of 495 Page 304 of 495 Page 304 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 10-Mar-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 58570 Product name Lock- Lube Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin. Inhalation. Ingestion. Potential health effects Eyes Prolonged or repeated exposure may cause . Slight irritation. Skin Prolonged skin contact may cause skin irritation and/or dermatitis. Inhalation Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Extreme overexposure may cause. Lung damage. Central nervous system damage. Kidney damage. Ingestion Harmful or fatal if swallowed. Can burn mouth, throat, and stomach. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Stoddard solvent 8052-41-3 60-100 Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 10-30 Dripless Base Compound Mixture 3-7 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with soap and plenty of water. If skin irritation persists, call a physician. Ingestion Seek medical attention immediately. Do Not induce vomiting. Give victim a glass of water or milk. Call a physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C 37 Flash point °F 100 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F Flammability Limits in Air) Upper 6% Lower 0.7% Suitable extinguishing media Foam. Water fog. Alcohol foam. Carbon dioxide (CO2). Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Special Fire-Fighting Procedures Firefighters should wear NIOSH/MSHA approved (or equivalent) self- contained pressure-demand breathing apparatus and full protective clothing. Fire and Explosion Hazards Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Page 1 / 3 Emergency Overview Irritant. Vapors may cause flash fire or explosion. Page 305 of 495 Page 305 of 495 Page 305 of 495 Page 305 of 495 ---PAGE BREAK--- Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with inert absorbent material. Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Storage Keep closed in a dry and cool place. Keep away from open flames, hot surfaces and sources of ignition. Do not freeze. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Stoddard solvent 500 ppm 2900 mg/m3 - 100 ppm - Petroleum distillates, hydrotreated heavy naphthenic - - - - Dripless Base Compound - - - - Ventilation and Environmental Controls Provide local exhaust ventilation. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection Use NIOSH approved respirator if TLV limit is exceeded. Hand Protection Chemical resistant gloves. Eye protection ANSI approved safety glasses or splash goggles with face shield are recommended. Skin and body protection Lightweight protective clothing. Other Protective Equipment Wear appropriate clothing to prevent skin contact. Rubber boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Liquid Color Black Odor Solvent Odor Threshold No information available pH No data available Specific Gravity No data available Vapor pressure 1-5 Vapor density > 1 (Air=1) Evaporation Rate < 1 (ether = 1) Water solubility Negligible VOC Content 5.74 Partition Coefficient (n-octanol/water) No data available Boiling point/range °C 155-197 Boiling point/range °F No data available Melting point/range °C 0 Melting point/range °F 32 Flash point °C 37 Flash point °F 100 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Avoid sources of ignition. Do not use near welding arcs. Avoid open flames. Incompatability Oxidizers. Strong acids. Alkalies. Amines. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Chlorine. Chloride. phosgene. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Stoddard solvent 8052-41-3 - - - Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 28710 mg/kg - - Dripless Base Compound Mixture - - - Synergistic Products None known Page 2 / 3 Product code 58570 Product name Lock- Lube Page 306 of 495 Page 306 of 495 Page 306 of 495 Page 306 of 495 ---PAGE BREAK--- Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Stoddard solvent Not Listed Not Listed Not Listed Not Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Not Listed Not Listed Dripless Base Compound Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG 15. REGULATORY INFORMATION State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Stoddard solvent Listed Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Dripless Base Compound Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Stoddard solvent X X - X Petroleum distillates, hydrotreated heavy naphthenic X X - X Dripless Base Compound - - - - CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION Health - 0 Flammability - 2 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Product name Lock- Lube Petroleum distillates, hydrotreated heavy naphthenic Product code 58570 Page 307 of 495 Page 307 of 495 Page 307 of 495 Page 307 of 495 ---PAGE BREAK--- Page 308 of 495 Page 308 of 495 Page 308 of 495 Page 308 of 495 ---PAGE BREAK--- Page 309 of 495 Page 309 of 495 Page 309 of 495 Page 309 of 495 ---PAGE BREAK--- Page 310 of 495 Page 310 of 495 Page 310 of 495 Page 310 of 495 ---PAGE BREAK--- Page 311 of 495 Page 311 of 495 Page 311 of 495 Page 311 of 495 ---PAGE BREAK--- 803 M A T E R I A L S A F E T Y D A T A S H E E T Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Date of Prep: 05/20/05 SECTION 1 SUNNYSIDE CORPORATION FOR INFORMATION: (847) 541-5700 225 CARPENTER AVENUE WHEELING, ILLINOIS 60090 (847) 541-5700 - SUNNYSIDE CORPORATION EMERGENCY TELEPHONE (800) 424-9300 - CHEM TREC Product Class: Petroleum Hydrocarbon Manufacturer's Code: 803 Trade Name: MINERAL SPIRITS NPCA HMIS: Health: 1 Fire: 2 Reactivity: 0 Product Appearance and Odor: Clear, water-white liquid; petroleum odor. SECTION 2 HAZARDOUS INGREDIENTS OCCUPATIONAL EXPOSURE LIMITS ACGIH ACGIH OSHA OSHA INGREDIENT CAS # PERCENT TLV TLV PEL PEL VAPOR PRESSURE (TWA) (STEL) (TWA) (STEL) Mineral Spirits 64742-88-7 100 PPM 100 PPM 2.0 MM Hg @ 20O C. (For Stoddard Solvent - CAS #8052- 41-3) SECTION 3 EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Flush eyes with plenty of water for 15 minutes while holding eyelids open. Get medical attention. Skin Contact: Remove contaminated clothing/shoes. Flush skin with water. Follow by washing with soap and water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned. Inhalation: Remove victim to fresh air and if breathing is difficult, oxygen should be provided by qualified personnel. Give artificial respiration if not breathing. Get medical attention. Ingestion: Do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into the lungs. Get medical attention. SECTION 4 PHYSICAL DATA The following data represent approximate or typical values. They do not constitute product specifications. Boiling Range: 315-395O Vapor Density: Heavier than air Evaporation Rate: Slower than ether % Volatile By Volume: Approx. 100% Weight Per Gallon: 6.43 lbs. Solubility in Water: Negligible; less than 0.1% SECTION 5 FIRE AND EXPLOSION DATA Flammability Classification: Combustible Liquid - Class II. Flash Point: 102O(F) Tag. Closed cup Autoignition Temperature: 445OF Lower Explosive Limit: 0.7% Extinguishing Media: Carbon dioxide, foam, dry chemical, water spray. Do not use direct water stream; it will spread fire. Unusual Fire and Explosion Hazards: Do not store or mix with strong oxidants. Special Fire Fighting Procedures: Use air-supplied rescue equipment for enclosed areas. Cool exposed containers with water. Page 312 of 495 Page 312 of 495 Page 312 of 495 Page 312 of 495 3190K751,752,753,754 ---PAGE BREAK--- Trade Name: MINERAL SPIRITS Page 2 of 3 SECTION 6 HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: See Section 2. EFFECTS OF OVEREXPOSURE Acute Eye Contact: May cause irritation, discomfort, redness and swelling of the eye. Skin Contact: Liquid is irritating to the skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis. Inhalation: Vapors may cause irritation to nose, throat and respiratory tract. Breathing of high vapor concentrations may result in headaches, dizziness and other signs of nervous system depression. These effects have been observed after misuse or abuse of this product. When used in a reasonable and foreseeable manner, no adverse effects are anticipated from exposure to this product. Ingestion: Ingestion may result in vomiting, aspiration (breathing) of vomitus into the lungs must be avoided as even small quantities may result in aspiration pneumonitis. Chronic: Repeated skin contact may aggravate an existing dermatitis (skin condition). Carcinogenicity: This product has not been identified as a carcinogen by NTP, IARC, or OSHA. Medical Conditions Aggravated by Exposure: Conditions aggravated by exposure may include skin disorders and respiratory (asthma-like) disorders. SECTION 7 REACTIVITY DATA Stability: Stable Conditions to Avoid: Heat, sparks and flame. Incompatibility (Materials to Avoid): Strong oxidizing agents like liquid chlorine or concentrated oxygen. Hazardous Decomposition Products: Thermal decomposition may yield carbon dioxide and carbon monoxide. Hazardous Polymerization: Will not occur. SECTION 8 SPILL OR LEAK PROCEDURES Steps to be taken in case material is spilled or released: Remove ignition sources, evacuate area, avoid breathing vapor or contact with liquid. Recover free liquid or stop leak if possible. Dike large spills and use absorbent material for small spills. Keep spilled material out of sewers, ditches and bodies of water. Waste disposal method: Incinerate under safe conditions; dispose of in accordance with local, state and federal regulations. SECTION 9 SAFE HANDLING AND USE INFORMATION Respiratory Protection: Appropriate vapor canister, self-contained breathing apparatus or supplied-air hose mask, if needed. Ventilation: Sufficient, in volume and pattern, to keep workroom concentration below current applicable OSHA safety and health requirements. See Section 2. Use explosion-proof equipment. No smoking. Protective Gloves: Rubber or neoprene. Eye Protection: Chemical safety goggles. Other Protective Equipment: Impervious clothing or boots, if needed. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Page 313 of 495 Page 313 of 495 Page 313 of 495 Page 313 of 495 ---PAGE BREAK--- Trade Name: MINERAL SPIRITS Page 3 of 3 SECTION 10 SPECIAL PRECAUTIONS Dept. of Labor Storage Category: Combustible Liquid - Class II Hygienic Practices: Keep away from heat, sparks and open flame. Keep containers closed when not in use. Avoid eye contact. Avoid prolonged or repeated contact with skin. Wash skin with soap and water after contact. Additional Precautions: Ground containers when transferring liquid to prevent static accumulation and discharge. Additional information regarding safe handling of products with static accumulation potential can be ordered by contacting the American Petroleum Institute (API) for API Recommended Practice 2003, entitled "Protection Against Ignitions Arising Out of Static, Lighting, and Stray Currents" (American Petroleum Institute, 1720 L Street Northwest, Washington, DC 20005), or the National Fire Protection Association (NFPA) for NFPA 77 entitled "Static Electricity" (National Fire Protection Association, 1 Batterymarch Park, P.O. Box 9101, Quincy, MA 02269-9101). Empty Container Warning: "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, flame, sparks or other sources of ignition; they may explode and cause injury or death. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly bunged and returned to supplier or disposed of in an environmentally safe manner and in accordance with governmental regulations. SECTION 11 ADDITIONAL INFORMATION This product contains the following toxic chemical(s) which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: APPROXIMATE TOXIC CHEMICAL CAS # % BY WEIGHT NONE NONE NONE SARA Title III Hazard Categories: Fire Hazard, immediate (Acute) and Delayed (Chronic) Health Hazard Common Names: Solvent Naphtha (Petroleum), Aliphatic Hydrocarbon, Petroleum Distillate California Proposition 65: This product may contain trace amounts of Benzene, Ethyl Benzene and Toluene- which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65. TRANSPORTATION U.S. D.O.T. Proper Shipping Name: Petroleum Distillates, N.O.S. U.S. D.O.T. Hazard Class & Packing Group: Combustible Liquid, III U.S. D.O.T. Identification Number: UN 1268 R fer to 49 CFR for possible exceptions and exemptions. e Page 314 of 495 Page 314 of 495 Page 314 of 495 Page 314 of 495 ---PAGE BREAK--- Date Printed: 10/2/2014 Product:34066 Safety Data Sheet according to OSHA Hazard Communication 29 CFR Part 1910.1200 SECTION 1. Identification Product Code 34066 Product Name: Motor Tune / Seafoam Motor Treatment 24 Hour Emergency: INFOTRAC: 1-[PHONE REDACTED] EMCO Chemical Distributors, Inc. 8601 95th Street Pleasant Prairie, Wisconsin 53158 (262) 427-0400 E-Mail: [EMAIL REDACTED] Outside U.S. and Canada Supplied by: Infotrac: [PHONE REDACTED] NOTE: INFOTRAC and National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals SECTION 2. Hazard(s) Identification EMERGENCY OVERVIEW Highly flammable liquid and vapor. May be fatal if inhaled. May be fatal if swallowed. GHS Classification Eye Irrit. 2, Flam. Liq. 2, STOT SE 3 NE, Skin Irrit. 2 Symbol(s) of Product Signal Word Danger GHS HAZARD STATEMENTS Flammable Liquid, category 2 H225 Highly flammable liquid and vapor. Skin Irritation, category 2 H315 Causes skin irritation. Eye Irritation, category 2 H319 Causes serious eye irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. GHS PRECAUTIONARY STATEMENTS P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Page 1 / 6 Page 315 of 495 Page 315 of 495 Page 315 of 495 Page 315 of 495 ---PAGE BREAK--- Date Printed: 10/2/2014 Product:34066 P312 Call a POISON CENTER/doctor/physician if you feel unwell. P321 Specific treatment (see first aid section on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P370+P378 In case of fire: Use appropriate method to extinguish. P403+P233 Store in a well-ventilated place. Keep container closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. SECTION 3. Composition/Information on Ingredients Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements Solvent-dewaxed heavy paraffinic petroleum distillate 64742-65-0 50-75 GHS06 H331 Aliphatic Hydrocarbon 64742-49-0 25-50 GHS02-GHS06 H225-315-331-336 2-propanol 67-63-0 10-25 GHS02-GHS07 H225-319-336 The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section. SECTION 4. First-Aid Measures FIRST AID - EYE CONTACT: Immediately flush eyes with water. Flush eyes with water for a minimum of 15 minutes, occasionally lifting and lowering upper lids. Get medical attention Remove contact lenses if worn. FIRST AID - SKIN CONTACT: Immediately flush skin with plenty of water. Remove clothing. Get medical attention immediately. Wash clothing separately and clean shoes before reuse. FIRST AID - INHALATION: Rescuers should put on appropriate protective gear. Remove from area of exposure. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Keep victim warm. Get immediate medical attention. To prevent aspiration, keep head below knees. FIRST AID - INGESTION: Do not induce vomiting. Do not give liquids. Obtain emergency medical attention. SECTION 5. Fire-Fighting Measures UNUSUAL FIRE AND EXPLOSION HAZARDS: Highly flammable liquid and vapor. Can release vapors that form explosive mixtures at or above the flashpoint. Vapors/dust may cause flash fire or explosion. Vapors can travel to a source of ignition and flash back. Empty containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. Also, do not reuse container without commercial cleaning or reconditioning. Closed container may explode under extreme heat. SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Avoid use of solid water streams. Water spray to cool containers or protect personnel. Use with caution. Use water spray to knock down vapors. Water spray and foam must be applied carefully to avoid frothing. Water runoff can cause environmental damage. Dike and collect water used to fight fire. For large fires: Water fog, use fog to control vapors; For small fires: dry chemical, carbon dioxide, and foam. EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog SECTION 6. Accidental Release Measures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASE OR SPILLED: Wear appropriate personal protective equipment. (See Exposure Controls / Personal Protection Section.)Eliminate all ignition sources. Evacuate unnecessary personnel. Prevent additional discharge of material if able to do so safely. Do not touch or walk through spilled material. Avoid runoff into storm sewers and ditches which lead to waterways. Ventilate spill area. Stay upwind of spill. A vapor supressing foam may be used to reduce vapors. If leak or spill has not ignited, use water spray to disperse the vapors. Use only non-combustible material for clean-up. Use clean, non-sparking tools to collect absorbed materials. Remove from surface by skimming or with suitable absorbents. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Recover by pumping (use an explosion proof or hand pump). Page 2 / 6 Page 316 of 495 Page 316 of 495 Page 316 of 495 Page 316 of 495 ---PAGE BREAK--- Date Printed: 10/2/2014 Product:34066 SECTION 7. Handling and Storage HANDLING: Use only in a well ventilated area. Avoid breathing vapor, fumes or mist. Avoid contact with eyes, skin, and clothing. Take precautionary measures against static discharge. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Always open containers slowly to allow any excess pressure to vent. Follow all MSDS/label precautions even after containers are emptied because they may retain product residues. STORAGE: Keep away from heat, sparks, and flame. Containers can build up pressure if exposed to heat (fire). Store containers in a cool, well ventilated place. Keep container closed when not in use. Protect from direct sunlight. Static Discharge, materials can accumulate static charges which can cause an incendiary electrical discharge. Material is a static accumulator which has the potential of forming ignitable vapor-air mixtures in storage tanks. SECTION 8. Exposure Controls/Personal Protection Ingredients with Occupational Exposure Limits Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING Solvent-dewaxed heavy paraffinic petroleum distillate 5 mg/m3 N.A. 5 mg/m3 N.A. Aliphatic Hydrocarbon 5 mg/m3 N.D. 5 mg/m3 N.D. 2-propanol 200 ppm 400 ppm 400 ppm N.D. Personal Protection RESPIRATORY PROTECTION: Wear a MSHA/NIOSH approved (or equivalent) full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. SKIN PROTECTION: Wear impervious gloves to prevent contact with the skin. Wear long sleeves when contact is likely to occur. Wear protective gear as needed - apron, suit, boots. EYE PROTECTION: Use chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent). OTHER PROTECTIVE EQUIPMENT: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. HYGENIC PRACTICES: Do not eat, drink, or smoke in areas where this material is used. Avoid breathing vapors. Remove contaminated clothing and wash before reuse. Wash thoroughly after handling. Wash hands before eating. SECTION 9. Physical and Chemical Properties Appearance: Clear liquid Physical State: Liquid Odor: Typical Odor Threshold: N.D. Density, g/cm3: 0.819 pH: N.D. Freeze Point, N.D. Viscosity: N.D. Solubility in Water: Insoluble Explosive Limits, vol%: 1.3 - 12.0 180 - 537 Boiling Range, Flash Point, 55 Evaporation Rate: N.D. Auto-ignition Temp., N.D. Vapor Density: N.D. Vapor Pressure: N.D. (See "Other information" Section for abbreviation legend) SECTION 10. Stability and Reactivity STABILITY: No Information Page 3 / 6 Page 317 of 495 Page 317 of 495 Page 317 of 495 Page 317 of 495 ---PAGE BREAK--- Date Printed: 10/2/2014 Product:34066 CONDITIONS TO AVOID: Avoid impact, friction, heat, sparks, flame and source of ignition. INCOMPATIBILITY: Avoid contact with caustics. Keep separate from alkalies. Prevent contact with aldehydes. Avoid contact with chlorinated compounds. Prevent contact with halogens. Prevent contact with strong oxidizing agents. Avoid contact with amines. Keep away from acids. HAZARDOUS DECOMPOSITION PRODUCTS: Toxic gases/fumes are given off during burning or thermal decomposition. During combustion carbon monoxide may be formed. During combustion carbon dioxide may be formed. HAZARDOUS POLYMERIZATION: No Information SECTION 11. Toxicological Information Information on Toxicological Effects EFFECTS OF OVEREXPOSURE - INHALATION: May be fatal if inhaled. Vapors can cause irritation of the respiratory tract. High concentrations can cause headache, nausea, weakness, lightheadedness, and stupor (CNS depression). EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Causes skin irritation. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Personnel with pre-existing skin disorders should avoid contact with this product. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Moderately irritating to the eyes causing transient corneal injury. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. Harmful or fatal if liquid is aspirated into lungs. Irritating to mouth, throat, and stomach. Can be readily absorbed by the stomach and intestinal tract. include burning sensation of the mouth and esophagus, nausea, vomiting, diarrhea, dizziness, staggering gait, drowsiness, loss of consciousness and delerium as well as additional central nervous system effects. Overexposure may cause nausea, diarrhea, and/or vomiting. May cause central nervous system depression. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Possible brain damage from overexposure. Overexposure may cause nervous system damage. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Chronic effects of ingestion and subsequent aspiration into the lungs may cause pneumatocele (lung cavity) formation and chronic lung dysfunction. Vapors irritating to eyes and respiratory tract. Significant exposure to this chemical may adversely affect people with chronic disease of the respiratory system, skin, and/or eyes. Significant exposure to this chemical may adversely affect people with chronic disease of the central nervous system. Primary Route(s) of Entry: Eye Contact, Ingestion, Inhalation, Skin Contact Acute Toxicity Values The acute effects of this product have not been tested. Data on individual components are tabulated below: CAS-No. Name according to EEC Oral LD50, mg/kg Dermal LD50, mg/kg Vapor LC50, mg/L 64742-65-0 Solvent-dewaxed heavy paraffinic petroleum distillate >5,000 >2,000 >2.18 64742-49-0 Aliphatic Hydrocarbon >5,170 >2,000 >7.63 67-63-0 2-propanol >5,840 >12,800 >25,000 SECTION 12. Ecological Information ECOLOGICAL INFORMATION: No Information SECTION 13. Disposal Considerations For more guidance and information contact our Waste Services Division at (262) 658-4000. Always dispose of any waste in accordance with all local, state, and federal regulations. DISPOSAL METHOD: Dispose of waste in accordance with all local, state and federal regulations. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASE OR SPILLED: Wear appropriate personal protective equipment. (See Exposure Controls / Personal Protection Section.)Eliminate all ignition sources. Evacuate unnecessary personnel. Prevent additional discharge of material if able to do so safely. Do not touch or walk through spilled material. Avoid runoff into storm sewers and ditches which lead to waterways. Ventilate spill area. Stay upwind of spill. A vapor supressing foam may be used to reduce Page 4 / 6 Page 318 of 495 Page 318 of 495 Page 318 of 495 Page 318 of 495 ---PAGE BREAK--- Date Printed: 10/2/2014 Product:34066 vapors. If leak or spill has not ignited, use water spray to disperse the vapors. Use only non-combustible material for clean-up. Use clean, non-sparking tools to collect absorbed materials. Remove from surface by skimming or with suitable absorbents. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Recover by pumping (use an explosion proof or hand pump). SECTION 14. Transport Information DOT Proper Shipping Name: Flammable liquids, n.o.s. (naphtha solvent, isopropanol) Packing Group: II DOT Hazard Class: 3 Hazard SubClass: No Information DOT UN/NA Number: UN1993 Resp. Guide Page: 128 SECTION 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Fire Hazard, Acute Health Hazard, Chronic Health Hazard SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: No Sara 313 components exist in this product. TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA components exist in this product. U.S. State Regulations: NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product. No NJ Right-To-Know components exist in this product. RIGHT-TO-KNOW The following non-hazardous ingredients are present in the product are at or greater than No PA Right-To-Know components exist in this product. CALIFORNIA PROPOSITION 65 CARCINOGENS Warning: The following ingredients present in the product are known to the state of California to cause Cancer: No Proposition 65 Carcinogens exist in this product. CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other reproductive hazards. No Proposition 65 Reproductive Toxins exist in this product. International Regulations: As follows - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. Page 5 / 6 Page 319 of 495 Page 319 of 495 Page 319 of 495 Page 319 of 495 ---PAGE BREAK--- Date Printed: 10/2/2014 Product:34066 WHMIS Class: No Information SECTION 16. Other Information Revision Date: 10/2/2014 Supersedes Date: New SDS Datasheet produced by: EH&S - Regulatory Department HMIS Ratings: Health: 1 Flammability: 3 Reactivity: 0 - No Hazard Personal Protection: X Volatile Organic Compounds, gr/ltr: 367 DISCLAIMER: THE VOLATILE ORGANIC COMPOUND (VOC) CONTENT REPORTED HEREIN, IF ANY, IS BASED ON A MATERIAL VOC CALCULATION. NOTE THAT SEVERAL METHODS ARE USED FOR CALCULATING VOC CONTENT AND THAT STANDARDS/ REQUIREMENTS REGARDING VOC CONTENT VARY BY LOCATION/JURISDICTION. ACCORDINGLY, EMCO MAKES NO REPRESENTATIONS OR WARRANTIES, EXPRESS OR IMPLIED, REGARDING THIS MATERIAL’S COMPLIANCE WITH VOC STANDARDS/ REQUIREMENTS APPLICABLE IN LOCATIONS/JURISDICTIONS WHERE THIS MATERIAL MAY BE SOLD OR USED. Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness. Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS02 GHS06 GHS07 Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined, N.I. - No Information The information on this SDS was obtained from sources which we believe to be reliable. However, the information provided is without any warranty, expressed or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information and recommendations are offered for the user's consideration and examination and should be used to make an independent determination of the methods to safeguard workers and the environment. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For these reasons we do not assume responsibility and expressly disclaim any liability for loss, damage, or expense arising out of or in any way connected with handling, storage, use, or disposal of this product. If the product is used as a component in another product, this SDS may not be applicable. It is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. Page 6 / 6 Page 320 of 495 Page 320 of 495 Page 320 of 495 Page 320 of 495 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: September 26, 2007 Supersedes: November 15, 2004 Product Code: AMH, Hydrocarbon-Based Rust Preventative Fluid. Page 1 of 4 Section 1: Product and Company Identification Manufacturer: AMSOIL, Inc. Telephone: 925 Tower Avenue CHEMTREC (Spill Emergency Only): 1-[PHONE REDACTED] Superior, WI 54880 Information: [PHONE REDACTED] AMSOIL Product Product Label Name…………………..MP HD Heavy Duty Metal Protector (Aerosol) Product Hydrocarbon-Based Rust Preventative Fluid Section 2: Composition/Information on Ingredients OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) Stoddard Solvent, CAS# 8052-41-3, appx weight=16% ACGIH TLV : 525 mg/m3 (mist), OSHA PEL: 100 ppm Heptane, CAS# 142-82-5, appx wt=24% ACGIH TLV: 400 ppm & OSHA PEL: 100 ppm Propane, CAS# 74-98-6, appx wt=21% ACGIH TLV: & OSHA PEL: 1000 ppm Petroleum Oil, CAS# 64742-52-5, appx wt=2% OSHA PEL 5 mg/ m3 (mist) Butane, CAS# 106-97-8 ACGIH TLV: 800 ppm & OSHA PEL: 800 ppm Section 3: Hazards Identification WARNING! Extremely Flammable Liquid, vapor may cause flash fire POTENTIAL HEALTH EFFECTS: Eye, inhalation, skin irritation. Section 4: First Aid Measures EYE: Flush with water for 15-20 minutes. Seek immediate medical attention. SKIN: Wash immediately with soap and water. Immediately remove contaminated clothing and launder before reuse. Discard shoes and leather articles saturated with the product. Obtain medical advice if irritation occurs. INHALATION: Remove exposed person to fresh air. If breathing is labored give oxygen. If breathing has stopped apply artificial respiration. Get immediate medical attention. INGESTION: DO NOT INDUCE VOMITING. If conscious, give 2 glasses of water. If vomiting does occur, keep head below hips to reduce risk of aspiration. Get immediate medical attention. CAUTION: Harmful or Fatal if Swallowed Section 5: Fire Fighting Measures FLAMMABILITY PROPERTIES: Flash Point <156 F(54 C) Method Estimated LFL/UFL 0.7 / 9.5 Auto-ignition Temperature Not Determined EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, and alcohol foam. UNUSUAL FIRE & EXPLOSION HAZARDS: Closed containers may explode from internal pressure build-up when exposed to extreme heat and discharge contents. Vapor accumulation can flash or explode if ignited. Thermal decomposition of product may include toxic oxides of carbon. Overexposure may cause health hazards. Red Flammability 4 Blue Health 2 Yellow Instability 0 White Special N/A NFPA & HMIS Rating Page 321 of 495 Page 321 of 495 Page 321 of 495 Page 321 of 495 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: September 26, 2007 Supersedes: November 15, 2004 Product Code: AMH, Hydrocarbon-Based Rust Preventative Fluid. Page 2 of 4 FIREFIGHTING EQUIPMENT: Full bunker gear recommended. Including a positive pressure self-contained breathing apparatus. Section 6: Accidental Release Measures Isolate spill area. Provide adequate ventilation. Wear appropriate personal protection. Recover free product for recycle and/or disposal. Add sand, earth or other suitable absorbent to spill area. Prevent entry into sewers and waterways. Check under Transportation and Labeling (DOT/CERCLA) and Other Regulator Information Section (SARA) for hazardous substances to determine regulatory reporting requirements for spill. Section 7: Handling and Storage HANDLING: Avoid contact with eyes, skin or clothing. Wash hands after handling. Empty container may retain product residue, which may exhibit hazards of product. STORAGE: Store and use in cool, dry, well-ventilated areas. Keep away from heat or flame. Section 8: Exposure Controls/Personal Protection VENTILATION: Use adequate general or local exhaust ventilation to keep airborne concentrations below exposure limits. RESPIRATORY: Use a NIOSH approved respirator when necessary. SKIN: Use Viton or Nitrile gloves to avoid prolonged or repeated skin contact. EYE: Use splash goggles or face shield where splashing is expected or can occur. EXPOSURE LIMITS: The Threshold Limit Value (TLV) of 5 mg/m3 is suggested for oil mist. Section 9: Physical and Chemical Properties Physical State Liquid Boiling Point <0-305 F (Aerosol) Freezing/Melting Point Not Applicable Vapor Pressure Not Determined Vapor Density (Air=1) >1 Evaporation Rate Not Determined Solubility in Water Not Available Specific Gravity (Water=1) 0.6500 Density, lb./gal. 5.45 Volatility (Volume) 95% (Less Federally Exempt Solvents) VOC Unknown pH Not Determined Coefficient of Water/Oil Distribution Not Determined Odor Mild Petroleum Odor Threshold Not Determined Appearance Clear, Fluid Spray Viscosity, cSt @ 100 C Not Applicable Viscosity, cSt @ 40 C Not Applicable Viscosity Index Not Applicable Section 10: Stability and Reactivity STABILITY: Stable. Avoid applications to hot surfaces. INCOMPATIBILITY: Avoid contact with strong oxidizers. Page 322 of 495 Page 322 of 495 Page 322 of 495 Page 322 of 495 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: September 26, 2007 Supersedes: November 15, 2004 Product Code: AMH, Hydrocarbon-Based Rust Preventative Fluid. Page 3 of 4 HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION OF PRODUCT: May produce fumes when heated to decomposition. Fumes may contain toxic oxides of carbon. Section 11: Toxicological Information ACUTE EXPOSURE Eye Irritation: Moderate to strong eye irritation. Based on data from components or similar material. Skin Irritation: Not expected to be a primary skin irritant. Based on data from components or similar material. Prolonged or repeated skin contact as from clothing wet with material may cause dermatitis. may include redness, edema, drying, defatting, and cracking of the skin. Respiratory Irritation: If material is misted or if vapors are generated from heating, exposure may cause irritation of mucous membranes and the upper respiratory tract similar to that observed with mineral oil. Based on data from components or similar materials. Under good industrial hygiene practices where all exposure limits are observed, respiratory irritation should not be a problem. CHRONIC EXPOSURE Chronic Toxicity: No data available to indicate product present at greater than 1.0% are chronic health hazards. Carcinogenicity: No data available to indicate product present at greater than 0.1% are a carcinogenic hazard. Mutagenicity: No data available to indicate product present at greater than 1.0% present a mutagenic or genotoxic hazard. Reproductive Toxicity: No data available to indicate product present at greater than 1.0% present a reproductive hazard. Teratogenicity: No data available to indicate product present at greater than 1.0% present a teratogenic hazards. ADDITIONAL INFORMATION Exposure Limits: Under conditions, which may generate mists, observe the OSHA PEL of 5 mg per cubic meter, ACGIH STEL of 10 mg per cubic meter. There are extensive toxicological data available on the various components of this product. An adequate representation of all these data is beyond the scope of this document. Please contact the AMSOIL Material Safety Data Sheet Coordinator for more details. Section 12: Ecological Information No data available on the adverse effects of this product on the environment. Section 13: Disposal Considerations Material is expected to be hazardous when disposed. Dispose of in accordance with all local, state and federal regulations. Page 323 of 495 Page 323 of 495 Page 323 of 495 Page 323 of 495 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: September 26, 2007 Supersedes: November 15, 2004 Product Code: AMH, Hydrocarbon-Based Rust Preventative Fluid. Page 4 of 4 Section 14: Transport Information This product is not classified as hazardous material for DOT shipping. For further information relative to spills resulting from transportation incidents, refer to the latest DOT Emergency Response Guidebook for Hazardous Materials. Section 15: Regulatory Information U.S. Federal Regulations OSHA Table Z Not Applicable TSCA Listed CERCLA 40 CFR CAS# 110-54-3 CAS# 110-82-7 SARA Title III Section 302 Extremely Hazardous Not Applicable Section 311/312 Fire Hazard Yes Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard No Section 313 Toxic Chemical Hexane, CAS# 110-54 3 Cyclohexane, CAS# 110-82-7 U.S. State Regulations California (Prop 65) Does not contain chemicals known to the state of California to cause cancer. International Regulations WHMIS All components listed Section 16: Other Information The information and recommendations contained herein are, to the best of AMSOIL’s knowledge and belief, accurate and reliable as of the date issued. AMSOIL makes no warranty or guarantee, expressed or implied, of their accuracy or reliability, and AMSOIL shall not be liable for any loss or damage based upon the criteria supplied by the developers of these rating systems, together with AMSOIL’s interpretation of the available data. Page 324 of 495 Page 324 of 495 Page 324 of 495 Page 324 of 495 ---PAGE BREAK--- Page 325 of 495 Page 325 of 495 Page 325 of 495 Page 325 of 495 ---PAGE BREAK--- Page 326 of 495 Page 326 of 495 Page 326 of 495 Page 326 of 495 ---PAGE BREAK--- Page 327 of 495 Page 327 of 495 Page 327 of 495 Page 327 of 495 ---PAGE BREAK--- Page 328 of 495 Page 328 of 495 Page 328 of 495 Page 328 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 27-Sep-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 96214 Product name New Ceiling Tile Paint White Recommended Use Coating Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Eyes. Inhalation. Ingestion. Potential health effects Eyes May cause slight irritation. Skin No adverse affects expected. Inhalation Harmful by inhalation. Narcosis. Reports have associated repeated and prolonged occupational exposure to solvents with permanent brain damage. Repeated or prolonged exposure may cause the following effects:. Kidney damage. Lung damage. Liver damage. Cardiac abnormalities. Damage to blood . Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Possible risk of harm to the unborn fetus. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane 74-98-6 10-30 Toluene 108-88-3 10-30 N-Butane 106-97-8 7-13 Titanium dioxide 13463-67-7 7-13 Naphtha, petroleum, hydrotreated light 64742-49-0 3-7 Calcium Carbonate 1317-65-3 3-7 Mineral Spirits 64742-47-8 1-5 Xylene (mix) 1330-20-7 1-5 PM Acetate 108-65-6 1-5 Ethyl benzene 100-41-4 0.1-1 4. FIRST AID MEASURES Eye contact Remove to fresh air. Rinse thoroughly with plenty of water, also under the eyelids. Seek medical attention if irritation persists. Skin contact Remove and wash contaminated clothing before re-use. Wash area thoroughly with soap and water. Ingestion Call a physician or Poison Control Center immediately. Inhalation Move to fresh air. If persist, call a physician. 5. FIRE FIGHTING MEASURES Flash point °C -19 Flash point °F -2 Method Pensky-Martens C.C. Autoignition temperature °C Product is not self-igniting Autoignition temperature °F Flammability Limits in Air) Upper 10.9% Lower 1.5% Suitable extinguishing media Carbon dioxide (CO2). Water spray. Sand. Dry powder. Alcohol-resistant foam . Water spray. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Fire and Explosion Hazards Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. Vapors may form explosive mixture in air between upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Page 1 / 4 Emergency Overview Extremely flammable liquid and vapor. Harmful by inhalation. Contents under pressure. Keep out of reach of children. Page 329 of 495 Page 329 of 495 Page 329 of 495 Page 329 of 495 ---PAGE BREAK--- Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Ensure adequate ventilation. Take precautionary measures against static discharges. Evacuate personnel to safe areas. Use personal protective equipment. Environmental precautions Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Prevent product from entering drains. Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Evacuate area of unprotected and unnecessary personnel. Ventilate area to maintain exposure below permissible exposure limits. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. 7. HANDLING AND STORAGE Handling Do not spray on a naked flame or any other incandescent material. Do not smoke. Protect against electrostatic charges. Keep away from heat, sparks, and open flame. Storage Keep away from open flames, hot surfaces and sources of ignition. Observe pressurized container storage regulations. Consult with local authorities.. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Toluene 200 ppm 300 ppm 20 ppm - PM Acetate - - - - Ethyl benzene 100 ppm 435 mg/m3 - 20 ppm - Mineral Spirits - - - - N-Butane - - - 1000 ppm Naphtha, petroleum, hydrotreated light - - - - Titanium dioxide 15 mg/m3 - 10 mg/m3 - Calcium Carbonate 15 mg/m3 - - - Xylene (mix) 100 ppm 435 mg/m3 - 100 ppm 150 ppm Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures Keep away from food, drink and animal feeding stuffs. Wash hands before breaks and immediately after handling the product. Respiratory protection None required if adequate ventilation is provided. Use NIOSH approved respirator if TLV limit is exceeded. Hand Protection Chemical resistant gloves. Impervious gloves. Consult glove manufacturer to determine the proper type for a specific operation. Eye protection fitting safety goggles. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color White Odor Aromatic Odor Threshold No information available pH No data available Specific Gravity 0.77-0.85 Vapor pressure 40 PSI, 2750 hPA Density 0.83 g/cm³ @ 20°C (68°F) Vapor density No data available Evaporation Rate No data available Water solubility No data available VOC Content 56.9%; 573.0 g/L; 4.78 lb/gl Solids content 21.7% MIR value 1.10 Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -44 Boiling point/range °F -47 Melting point/range °C No data available Melting point/range °F No data available Flash point °C -19 Flash point °F -2 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Do not store in temperatures above 120 degrees F. Incompatability None known. Page 2 / 4 Product code 96214 Product name New Ceiling Tile Paint White Page 330 of 495 Page 330 of 495 Page 330 of 495 Page 330 of 495 ---PAGE BREAK--- Hazardous Decomposition Products None known. Polymerization Hazardous polymerization does not occur 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane 74-98-6 - - 658 mg/L Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L 26700 ppm PM Acetate 108-65-6 8532 mg/kg 5 g/kg - Ethyl benzene 100-41-4 3500 mg/kg 15354 mg/kg 17.2 mg/L Mineral Spirits 64742-47-8 5000 mg/kg 2000 mg/kg 5.2 mg/L N-Butane 106-97-8 - - 658 g/m3 Naphtha, petroleum, hydrotreated light 64742-49-0 5000 mg/kg 3160 mg/kg 73680 ppm Titanium dioxide 13463-67-7 10000 mg/kg - - Calcium Carbonate 1317-65-3 - - - Xylene (mix) 1330-20-7 4300 mg/kg - 47635 mg/L Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Prolonged or repeated occupational overexposure may affect the following:. Kidney. Lungs. Liver. Heart. Blood. Other adverse effects Possible risk of harm to the unborn fetus . Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 Not Listed Not Listed Not Listed Not Listed PM Acetate Not Listed Not Listed Not Listed Not Listed Not Listed Ethyl benzene A3 Group 2B Not Listed Not Listed Listed Mineral Spirits Not Listed Not Listed Not Listed Not Listed Not Listed N-Butane Not Listed Not Listed Not Listed Not Listed Not Listed Naphtha, petroleum, hydrotreated light Not Listed Not Listed Not Listed Not Listed Not Listed Titanium dioxide A4 Group 2B Not Listed Not Listed Listed Calcium Carbonate Not Listed Not Listed Not Listed Not Listed Not Listed Xylene (mix) A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Hazardous for water, do not empty into drains. Ecotoxicity effects This product does not contain any chlorofluorocarbons (CFC's), hydrochlorofluorocarbons (HCFC's), perfluorocarbons (PCF's), or chlorinated solvents. Page 3 / 4 PM Acetate Product name New Ceiling Tile Paint White Water Flea Data Daphnia magna EC50>500 mg/L (48 h) Water Flea Data Chaetogammarus marinus LC50=2.6 mg/L (96 h) Ethyl benzene Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Microtox Data Photobacterium phosphoreum EC50=9.68 mg/L (30 min) Nitrosomonas EC50=96 mg/L (24 h) Mineral Spirits Water Flea Data Daphnia magna EC501.8 - 2.4 mg/L (48 h) Water Flea Data Den-dronereides heteropoda LC50=4720 mg/L (96 h) Product code 96214 Xylene (mix) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Microtox Data Photobacterium phosphoreum EC50=0.0084 mg/L (24 h) Toluene Water Flea Data Gammarus lacustris LC50=0.6 mg/L (48 h) water flea EC50=3.82 mg/L (48 h) Naphtha, petroleum, hydrotreated light Page 331 of 495 Page 331 of 495 Page 331 of 495 Page 331 of 495 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. Do not puncture or incinerate. Do not heat or cut empty containers with electric or gas torches . Please recycle empty container whenever possible. Waste from residues / unused products Please recycle empty container whenever possible. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Consumer commodity, ORM-D. TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Toluene Listed Ethyl benzene Listed Xylene (mix) Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane Listed Listed Not Listed Toluene Listed Listed Development al Female Reproductive PM Acetate Not Listed Not Listed Not Listed Ethyl benzene Listed Listed Carcinogen Mineral Spirits Not Listed Not Listed Not Listed N-Butane Not Listed Listed Not Listed Naphtha, petroleum, hydrotreated light Not Listed Not Listed Not Listed Titanium dioxide Not Listed Listed Carcinogen Calcium Carbonate Not Listed Listed Not Listed Xylene (mix) Not Listed Listed Not Listed Chemical Name Type Toluene - 108-88-3 Female Reproductive WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane X X - X Toluene X X - X PM Acetate X X - X Ethyl benzene X X - X Mineral Spirits X X - X N-Butane X X - X Naphtha, petroleum, hydrotreated light X X - X Titanium dioxide X X - X Calcium Carbonate X - X X Xylene (mix) X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 1 Flammability - 3 Reactivity - 3 HMIS Health - 1 Flammability - 3 Physical Hazard - 3 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name New Ceiling Tile Paint White Product code 96214 Page 332 of 495 Page 332 of 495 Page 332 of 495 Page 332 of 495 ---PAGE BREAK--- Material Safety Data Sheet NP 1 Version 2.0 7/5/06 Page 1 of 7 1. COMPANY AND PRODUCT INFORMATION Company : BASF Building Systems, Inc. 889 Valley Park Drive Shakopee, MN 55379 , Phone : [PHONE REDACTED] Fax : Emergency contact : 1-[PHONE REDACTED] Productname : NP 1 MSDS : 11022 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 calcium oxide 1305-78-8 5.0 % 02 Limestone, Calcium carbonate 1317-65-3 20.0 % 03 titanium dioxide 13463-67-7 5.0 % 04 talc 14807-96-6 5.0 % 05 Silica, quartz 14808-60-7 1.0 % 06 Mineral spirits [Stoddard type] 8052-41-3 10.0 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 2 mg/m3 N.E. 5 mg/m3 N.E. N.E. NO 02 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO 03 10 mg/m3 N.E. 15 mg/m3 N.E. NO 04 2 mg/m3 N.E. 2 mg/m3 N.E. NO 05 .1 mg/m3 N.E. .1 mg/m3 N.E. N.E. NO 06 100 ppm N.E. 525 mg/m3 N.E. N.E. NO (See Section 16 for abbreviation legend) Page 333 of 495 Page 333 of 495 Page 333 of 495 Page 333 of 495 ---PAGE BREAK--- Material Safety Data Sheet NP 1 Page 2 of 7 SECTION 3 - HAZARDOUS IDENTIFICATION EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Causes skin irritation. Allergic reactions are possible. Repeated or prolonged contact with skin may cause sensitization. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. EFFECTS OF OVEREXPOSURE - INGESTION: Irritating to mouth, throat and stomach. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: This product contains solvents. Reports associate repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Reports also indicate that solvents cause liver damage, kidney damage, and mucous membrane irritation. Be warned that intentional misuse by deliberately inhaling the vapors and/or the product contents (a process often called "sniffing") may be harmful or fatal. Preexisting respiratory or skin condition(s) may be aggravated by exposure. This product may contain a small amount [ <0.1% ] of toluene diisocyanate. NIOSH, NTP and IARC list toluene diisocyanate as a suspected carcinogen. Note also that prolonged repeated exposure to isocyanates can lead to skin sensitation. For persons so sensitized even breif exposures to the isocyanate can produce reddening, swelling, rash, or blisters. Similarly, prolonged and repeated exposure to isocyanates can lead to respiratory sensitization. In such individuals brief exposures to isocyanates at levels well below the TLV can produce chemical asthma, and nonspecific asthmatic conditions. This product contains silicon dioxide [quartz] which has been listed as a suspected human carcinogen by NTP and IARC. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION EYE CONTACT INGESTION SECTION 4 - FIRST AID MEASURES FIRST AID - EYE CONTACT: Flush eye with water for 15 minutes. Get medical attention. FIRST AID - SKIN CONTACT: Remove contaminated clothing and shoes. Wash affected area(s) throughly with soap and water. If irritation persist, seek medical attention. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Page 334 of 495 Page 334 of 495 Page 334 of 495 Page 334 of 495 ---PAGE BREAK--- Material Safety Data Sheet NP 1 Page 3 of 7 SECTION 4 - FIRST AID MEASURES CONT’D FIRST AID - INGESTION: If swallowed, DO NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Should vomiting occur, be sure to keep victum's head below hips to avoid aspiration of vomitus into lungs. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: 121 F LOWER EXPLOSIVE LIMIT: 0.9 % (SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: 9.5 % AUTOIGNITION TEMPERATURE: N/A EXTINGUISHING MEDIA: CO2 DRY CHEMICAL WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: Fire produces irritating or poisonous gas. Vapors can travel to a source of ignition and flash back. Solid stream of water or foam may cause frothing. SPECIAL FIREFIGHTING PROCEDURES: May be ignited by heat, sparks or flame. Containers exposed to fire should be kept cool with water spray. Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Ventilate the area and remove all sources of ignition. Evacuate unneccessary personnel. Large spills should be handled carefully. Put on respiratory protection and necessary personal protective equipment. Dike or impound spilled liquid. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Repeat sorbent/sweep cycle until the spill has dried up. Avoid runoff into storm sewers and ditches which lead to waterways. SECTION 7 - HANDLING AND STORAGE HANDLING: Use only in a well ventilated area. Keep out of reach of children. If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminents below the exposure limit. STORAGE: Keep container closed when not in use. Page 335 of 495 Page 335 of 495 Page 335 of 495 Page 335 of 495 ---PAGE BREAK--- Material Safety Data Sheet NP 1 Page 4 of 7 SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. RESPIRATORY PROTECTION: Wear NIOSH/MSHA approved respiratory protection when the product is mixed or applied in a poorly ventilated area or if workplace levels of ingredients exceed the TLV. Follow applicable federal, state, and local regulations. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical resistant gloves, chemical safety goggles with a face sheild, and clean protective clothing to cover arms and legs to keep exposure to a minimum. HYGIENIC PRACTICES: Do not take internally. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid breathing vapors from heated material. Avoid contact with eyes, skin, and clothing. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE : 312 - 484 F VAPOR DENSITY : Is heavier than air ODOR : Mild odor ODOR THRESHOLD : N/D APPEARANCE : Pigmented paste EVAPORATION RATE: Is slower than Butyl SOLUBILITY IN H2O : Slight <0.1 % Acetate FREEZE POINT : N/D SPECIFIC GRAVITY: 1.1800 VAPOR PRESSURE : N/D pH @ 0.0 % : N/A PHYSICAL STATE : Solid VISCOSITY : N/A COEFFICIENT OF WATER/OIL DISTRIBUTION: N/A (See Section 16 for abbreviation legend) SECTION 10 - STABILITY AND REACTIVITY CONDITIONS TO AVOID: Long term exposure to elevated temperatures. INCOMPATIBILITY: Avoid contact with oxidizing material. Contact with water vapor. HAZARDOUS DECOMPOSITION PRODUCTS: Acrid fumes. Oxides of carbon. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. Page 336 of 495 Page 336 of 495 Page 336 of 495 Page 336 of 495 ---PAGE BREAK--- Material Safety Data Sheet NP 1 Page 5 of 7 SECTION 11 - TOXICOLOGICAL PROPERTIES PRODUCT DERMAL LD50: No Information PRODUCT ORAL LD50: No Information PRODUCT LC50: No Information COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME DERMAL LD50 ORAL LD50 LC50 calcium oxide No Information No Information No Information Limestone, Calcium carb No Information 6450 mg/kg No Information titanium dioxide No Information > 7500 mg/kg No Information talc No Information No Information 11mg/m3/1y-I Silica, quartz No Information No Information No Information Mineral spirits [Stodda No Information > 5 g/kg >5500mg/m3/4H SECTION 12 - ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No Information. SECTION 13 - DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Review all local, state, and federal regulations concerning health and pollution for appropriate disposal procedures. SECTION 14 - TRANSPORTATION INFORMATION This material has been tested, and determined to be a non-combustible solid by ASTM test methods. DOT PROPER SHIPPING NAME: Not Regulated DOT TECHNICAL NAME: N/A DOT HAZARD CLASS: N/A HAZARD SUBCLASS: N/A DOT UN/NA NUMBER: N/A PACKING GROUP: N/A RESP. GUIDE PAGE: DOT PLACARD AT: N/A DOT CLASS NUMBER: N/A UN PROPER SHIPPING NAME: Not Regulated Page 337 of 495 Page 337 of 495 Page 337 of 495 Page 337 of 495 ---PAGE BREAK--- Material Safety Data Sheet NP 1 Page 6 of 7 SECTION 14 - TRANSPORTATION INFORMATION CONT’D UN HAZARD CLASS: N/A UN CLASS NUMBER: AIR N/A MARINE N/A HAZARD SUBCLASS: AIR N/A MARINE N/A UN UN/NA NUMBER: N/A UN PACKING GROUP: AIR N/A MARINE N/A UN PLACARD AT: N/A SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN % TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER Chlorobenzene 108-90-7 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: Page 338 of 495 Page 338 of 495 Page 338 of 495 Page 338 of 495 ---PAGE BREAK--- Material Safety Data Sheet NP 1 Page 7 of 7 SECTION 15 - REGULATORY INFORMATION CONT’D CHEMICAL NAME CAS NUMBER toluene 108-88-3 Silica, quartz 14808-60-7 2,4-toluene diisocyanate 584-84-9 INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. SECTION 16 - OTHER INFORMATION HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTION: G PREVIOUS MSDS REVISION DATE: 07/22/98 REASON FOR REVISION: Formula update. VOLATILE ORGANIC COMPOUNDS (VOCS): 0.77 lbs/gal, 93 grams/ltr LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined This information is furnished without warranty, representation, or license of any kind, except that this information is accurate to the best of ChemRex's knowledge, or is obtained from sources believed by ChemRex to be accurate. No warranty is expressed or implied regarding the accuracy of this information or the results to be obtained from its use thereof. Chemrex assumes no responsibility for injuries proximately caused by use of the Material if reasonable safety procedures are not followed as stipulated in this Data Sheet. Additionally, ChemRex assumes no responsibility for injuries proximately caused by abnormal use of the Material even if reasonable safety procedures are followed. Buyer assumes the risk in its use of the Material. Page 339 of 495 Page 339 of 495 Page 339 of 495 Page 339 of 495 ---PAGE BREAK--- file:///CI/Documents%20and%20Settings/sosborne/Desktop/MSDS--NU-KOTE.txt MATERIAL SAFETY DATA SHEET NU-KOTE DATE OF ISSUE: 03/06/2002 SUPERCEDES: 12/27/2000 SECTION I - GENERAL INFORMATION Chemical Name & Synonyms: Trade Name & Synonyms: N/A NU-KOTE Chemical Family: Formula Mixture: AQUEOUS SILICONE EMULSION X Manufacturer's Name: CHEMSEARCH DIV. OF NCH CORP. Address: BOX 152170 IRVING, TX 75015 Prepared By: K Dickinson/Chemist Product Code Number: 0422 Emergency Phone Number: [PHONE REDACTED] SECTION II - HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS: Chemical Name (Ingredients): ALKOXY POLYETHOXY ETHANOL Hazard: IRRITANT TLV: NOT EST 1 PEL: NOT EST 2 STEL: NOT EST CAS#: 60828-78-6 SECTION III - PHYSICAL DATA Boiling Point 210° Specific Gravity (H20=1): 1.02 Vapor Pressure (MM HG): 18 Color: WHITE Vapor Density (Air=1): 0.6 Odor: LEMON PH @ 100%: 8.3 Clarity: OPAQUE Volatile by Volume: 70 Evaporation Rate (BU A/C=1): >1 H20 Solubility: COMPLETE Viscosity: NON-VISCOUS SECTION IV - FIRE AND EXPLOSION HAZARD Flash Point: > 200°F / SETAFLASH Flammable Limits: N/A LEL: N/A UEL:N/A Extinguishing Media: Foam: X Alcohol Foam: CO2: X Dry Chemical: X Water Spray: X Other: Special Fire Fighting Procedures: file:///CI/Documents%20and%20Settings/sosborne/Desktop/MSDS--NU-KOTE.txt (1 of 4) [3/8/2004 1:34:53 PM] Page 340 of 495 Page 340 of 495 Page 340 of 495 Page 340 of 495 ---PAGE BREAK--- file:///CI/Documents%20and%20Settings/sosborne/Desktop/MSDS--NU-KOTE.txt FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire and Explosion Hazards: USE CARE AS SPILLS MAY BE SLIPPERY. THERMAL BREAKDOWN OF THIS PRODUCT DURING FIRE OR VERY HIGH HEAT CONDITIONS MAY EVOLVE THE FOLLOWING HAZARDOUS DECOMPOSITION PRODUCTS: SULFUR OXIDES, SILICON DIOXIDE, FORMALDEHYDE, METAL OXIDES, CARBON OXIDES AND TRACES OF INCOMPLETELY BURNED CARBON COMPOUNDS. Aerosol Level (NFPA 30B): N/A NFPA 704 Hazard Rating: (0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme) Health: 1 Flammability: 1 Instability: 0 Special: SECTION V - HEALTH HAZARD DATA Threshold Limit Value: NOT ESTABLISHED. Effects of Overexposure: -Acute(Short Term Exposure) SKIN CONTACT: MAY CAUSE IRRITATION SEEN AS ITCHING AND REDNESS. EYE CONTACT: DIRECT CONTACT CAUSES SEVERE IRRITATION SEEN AS TEARING, REDNESS, A BURNING SENSATION AND POSSIBLE CORNEAL INJURY. INHALATION: MAY CAUSE RESPIRATORY IRRITATION SEEN AS COUGHING AND SNEEZING. INGESTION: MAY CAUSE IRRITATION WITH POSSIBLE NAUSEA, VOMITING AND DIARRHEA. -Chronic (Long Term Exposure) NO HUMAN CHRONIC EFFECTS KNOWN. MEDICAL CONDITIONS AGGRAVATED: NONE KNOWN. TARGET ORGANS: NONE KNOWN. THERE IS NO PRIMARY ROUTE OF ENTRY INTO THE BODY. THE PRIMARY ROUTES OF EXPOSURE ARE SKIN AND EYE CONTACT. Primary Routes of Entry: Inhalation: Ingestion: Absorption: Emergency and First Aid Procedures: -Inhalation: REMOVE FROM THE AREA TO FRESH AIR. SEEK MEDICAL ATTENTION IF RESPIRATORY IRRITATION DEVELOPS OR IF BREATHING BECOMES DIFFICULT. -Eye Contact: IMMEDIATELY RINSE THE EYES WITH WATER. REMOVE ANY CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. HOLD THE EYELIDS APART TO ENSURE RINSING OF THE ENTIRE SURFACE OF THE EYES AND LIDS WITH WATER. GET IMMEDIATE MEDICAL ATTENTION. -Skin Contact: WASH AFFECTED AREAS WITH PLENTY OF SOAP AND WATER FOR SEVERAL MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS. -Ingestion: GIVE 3 TO 4 GLASSES OF WATER, BUT DO NOT INDUCE VOMITING. IF VOMITING OCCURS, GIVE FLUIDS AGAIN. SEEK MEDICAL ATTENTION IF DISCOMFORT OCCURS. -Notes to Physician: THERE IS NO SPECIFIC ANTIDOTE. TREAT THE PATIENT SECTION VI - TOXICITY INFORMATION Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By: IARC: No NTP: No OSHA: No ACGIH: No OTHER: No file:///CI/Documents%20and%20Settings/sosborne/Desktop/MSDS--NU-KOTE.txt (2 of 4) [3/8/2004 1:34:53 PM] Page 341 of 495 Page 341 of 495 Page 341 of 495 Page 341 of 495 ---PAGE BREAK--- file:///CI/Documents%20and%20Settings/sosborne/Desktop/MSDS--NU-KOTE.txt ALKOXY POLYETHOXY ETHANOL EYE-RBT: 100 MG SEVERE 3. ORL-RAT LD50: 7460 UL/KG 3. SKN-RBT LD50: 8480 UL/KG 3. WHEN HEATED TO TEMPERATURES ABOVE 302 F IN THE PRESENCE OF AIR, PRODUCT CAN FORM FORMALDEHYDE VAPORS. FORMADEHYDE IS A POTENTIAL CANCER HAZARD, A KNOWN SKIN AND RESPIRATORY SENSITIZER; AND AN IRRITANT TO THE EYES, NOSE, THROAT, SKIN AND DIGESTIVE SYSTEM. 4. SECTION VII - REACTIVITY DATA Stability: Stable: X Unstable: Conditions to Avoid: NONE KNOWN. Incompatibility (Materials to Avoid): STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH AND CONCENTRATED HYDROGEN PEROXIDE; STRONG ACIDS AND BASES. Hazardous Decomposition Products: OXIDES OF CARBON, SULFUR, METAL AND TRACES OF INCOMPLETELY BURNED CARBON COMPOUNDS. SILICON DIOXIDE AND FORMALDEHYDE. Hazardous Polymerization: May Occur: Will Not Occur: X Conditions to Avoid: N/A. SECTION VIII - SPILL OR LEAK PROCEDURES Steps to be Taken if Material is Released or Spilled: WEAR APPROPRIATE PROTECTIVE CLOTHING. USE CARE AS SPILLS MAY BE SLIPPERY. VENTILATE THE AREA. DIKE AND CONTAIN SPILL. ABSORB WITH AN INERT MATERIAL AND TRANSFER ALL MATERIAL INTO A PROPERLY LABELED CONTAINER FOR DISPOSAL. PREVENT PRODUCT FROM CONTAMINATING SOIL OR FROM ENTERING SEWAGE AND DRAINAGE SYSTEMS AND BODIES OF WATER. FLUSH AREA WITH WATER. Waste Disposal Method(s): DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Neutralizing Agent: NONE KNOWN. SECTION IX - SPECIAL PROTECTION INFORMATION Required Ventilation: LOCAL VENTILATION IS RECOMMENDED TO CONTROL EXPOSURE FROM OPERATIONS THAT CAN GENERATE MISTS. Respiratory Protection: A NIOSH/MSHA APPROVED RESPIRATOR WHERE MISTING EXISTS. Glove Protection: NEOPRENE OR NITRILE RUBBER GLOVES IF REPEATED OR PROLONGED SKIN CONTACT IS LIKELY. Eye Protection: SAFETY GLASSES WITH SIDE SHIELDS SHOULD BE WORN WHEN HANDLING. Other Protection: WEAR PROTECTIVE CLOTHING WHEN HANDLING. SECTION X - STORAGE AND HANDLING INFORMATION file:///CI/Documents%20and%20Settings/sosborne/Desktop/MSDS--NU-KOTE.txt (3 of 4) [3/8/2004 1:34:53 PM] Page 342 of 495 Page 342 of 495 Page 342 of 495 Page 342 of 495 ---PAGE BREAK--- file:///CI/Documents%20and%20Settings/sosborne/Desktop/MSDS--NU-KOTE.txt Storage Temperature: Indoors: X Outdoors: Heated: Refrigerated: Minimum Temperature: 32°F Maximum Temperature: 120°F Precautions to be taken in Handling and Storing: ALWAYS STORE MATERIAL IN ITS ORIGINAL CONTAINER. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP FROM FREEZING. IF PRODUCT FREEZES ALLOW IT TO SLOWLY WARM TO ROOM TEMPERATURE AND STIR THOROUGHLY BEFORE USING. Other Precautions: KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL BEFORE USING THE PRODUCT. SECTION XI - REGULATORY INFORMATION Chemical Name CAS Number Upper % Limit Those Ingredients listed above are subject to the reporting requirements of 313 of Title III and of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. SECTION XII - REFERENCES THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS AND BIOLOGICAL EXPOSURE INDICES, ACGIH, 2001. OSHA PEL. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES, CCINFODisc, 2001. ALL COMPONENTS IN THIS PRODUCT CAN BE FOUND IN THE CURRENT TSCA INVENTORY. IRR:IRRITANT, FLAM/FLAMM:FLAMMABLE, COMB:COMBUSTIBLE, CORR:CORROSIVE CARC:CARCINOGENIC, TOX:TOXIC, N/A:NOT APPLICABLE, N/E:NOT ESTABLISHED, COC:CLEVELAND OPEN CUP, PMCC:PENSKY-MARTIN CLOSED CUP, TCC:TAGLIABUE CLOSED CUP, LEL:LOWER EXPLOSION LIMIT, UEL:UPPER EXPLOSION LIMIT, NFPA:NATIONAL FIRE PROTECTION ASSOCIATION, IARC:INTERNATIONAL AGENCY FOR THE RESEARCH ON CANCER, NTP:NATIONAL TOXICOLOGY PROGRAM, OSHA:OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION, ACGIH:AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS, TLV:THRESHOLD LIMIT VALUE, PEL:PERMISSIBLE EXPOSURE LIMIT, STEL:SHORT-TERM EXPOSURE LIMIT, MLD:MILD, MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC, PNOS: PARTICULATES (INSOLUBLE) NOT OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST, ORL: ORAL, HMN: HUMAN, IHL:INHALATION THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use,storage or disposal of the product. file:///CI/Documents%20and%20Settings/sosborne/Desktop/MSDS--NU-KOTE.txt (4 of 4) [3/8/2004 1:34:53 PM] Page 343 of 495 Page 343 of 495 Page 343 of 495 Page 343 of 495 ---PAGE BREAK--- Page 344 of 495 Page 344 of 495 Page 344 of 495 Page 344 of 495 ---PAGE BREAK--- Page 345 of 495 Page 345 of 495 Page 345 of 495 Page 345 of 495 ---PAGE BREAK--- Page 346 of 495 Page 346 of 495 Page 346 of 495 Page 346 of 495 ---PAGE BREAK--- Page 347 of 495 Page 347 of 495 Page 347 of 495 Page 347 of 495 ---PAGE BREAK--- Page 348 of 495 Page 348 of 495 Page 348 of 495 Page 348 of 495 ---PAGE BREAK--- Material Safety Data Sheet (MSDS) Series: #0572: _ Pint, 0574: Quart MSDS # 0041 NFPA Rating: HMIS Rating: 1-0-0 1-0-0-B SECTION I EMERGENCY TELEPHONE NO. TRADE NAME (IF NONE, PUT CHEMICAL) Onetime Lighten Up Spackling Compound (918) 825-5744 (24 Hrs.) MANUFACTURER'S NAME AND TELEPHONE NO. Red Devil, Incorporated (918) 825-5744 ADDRESS (Number, Street, City, State, Zip Code) 4175 Webb Street, Pryor, Oklahoma 74361 SECTION II - HAZARDOUS INGREDIENTS % TLV PEL UNITS PRODUCT CONSISTS OF: Titanium Dioxide*** (13463-67-7) <0.20 <1.50 UN 10 UN 10 mg/m3 Propylene Glycol (57-55-6) Calcium Carbonate*** (1317-65-3) (as nuisance particulate, total) <1.25 <20 400*** * 10 NE 15 ppm mg/m3 Soda Lime Borosilicate Filler*** (65997-17-3 Non-Hazardous Ingredients* <20 <50.0 NE NA NE NA *Unlisted ingredients are not considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). **Refer to statement in Section IX ***Inhalation of particulates unlikely due to products physical state ****TWA VOC: 3.6%/wt. CARB Compliance: YES. Prop 65 Ingredients: YES (Contains a chemical known to the State of California to cause cancer or reproductive toxicity.) SECTION III - PHYSICAL DATA BOILING POINT NE SPECIFIC GRAVITY (H20=1) 0.41 VAPOR PRESSURE (MM Hg.) NE PERCENT VOLATILES BY VOLUME <5 VAPOR DENSITY (AIR=1) <1 pH 10.75 SOLUBILITY IN WATER Soluble EVAPORATION RATE <0.4 (BuAc = 1) APPEARANCE AND ODOR Pink in Container, white when dry. Mild acrylate/ammonia odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) >200F (TCC) FLAMMABLE LIMITS LEL NA UEL NA EXTINGUISHING MEDIA Use media suitable for adjacent materials. SPECIAL FIRE FIGHTING PROCEDURES No special procedures are required. UNUSUAL FIRE AND EXPLOSION HAZARDS None known. Page 349 of 495 Page 349 of 495 Page 349 of 495 Page 349 of 495 ---PAGE BREAK--- NA - Not Applicable NE - Not Established UN - Unavailable Page 350 of 495 Page 350 of 495 Page 350 of 495 Page 350 of 495 ---PAGE BREAK--- SECTION V - HEALTH HAZARD INFORMATION OR OVEREXPOSURE May cause eye, skin, nose & throat irritation. FIRST AID EYES Immediately flush eyes with large amounts of water while holding eyelids open. Get medical attention if irritation persists. SKIN Wipe material from skin with cloth or paper towel, then wash exposed area with soap and water. Get medical help if irritation persists. INHALATION Move victim to fresh air and treat with artificial respiration if needed. Seek medical attention if irritation persists. Should product sanding be desired, fresh air should be supplied such that dust can not be detected while sanding. Use of a dust mask is also recommended if product is sanded. SANDING NOT NORMALLY REQUIRED WITH THIS PRODUCT. INGESTION Do not induce vomiting. Contact local poison control center or physician IMMEDIATELY! SECTION VI - REACTIVITY DATA STABILITY Stable INCOMPATIBLE MATERIALS None known HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide, carbon dioxide, acrylic acid SECTION VII - SPILL OR LEAK PROCEDURES PROCEDURES Wipe up spilled material. Wash area with detergent. WASTE DISPOSAL METHOD Dispose of in accordance with Local, State and Federal regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY Not normally required. Wear appropriate respirator if product to be sanded. EYEWEAR Wear safety glasses. CLOTHING/GLOVES Not normally required; in situations of extended skin contact, neoprene or other chemical resistant gloves are recommended. VENTILATION Provide adequate general dilution ventilation. SECTION IX - SPECIAL PRECAUTIONS Store in a closed container in cool dry area. Protect from freezing & excessive heat. Formula contains @ < 0.20%/wt, a chemical known to the State of California to cause cancer or reproductive toxicity. DOT Proper Shipping Name: Not Regulated by DOT. DOT Hazard Class: None. DOT UN/NA Number: None. PACKING GROUP: None. Reviewed By: Larry G. Brandon VP Technology & General Manager June 24, 2004 NAME TITLE DATE The information contained herein has been developed based upon current available scientific data. New information may be developed from time to time which may render the conclusions of this report obsolete. Therefore, no warranty is extended as to the applicability of this information to the user's intended purpose or for the consequences of its use or misuse. Page 351 of 495 Page 351 of 495 Page 351 of 495 Page 351 of 495 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: ORANGE TOUGH 15 Product Number: 2215; 2216 Janitorial Spartan Chemical Company, Inc. Product/Technical Information:1-(800)-537-8990 1110 Spartan Drive Medical Emergency:1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil Emergency:CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: Cleaning compounds, liquid, n.o.s. NFPA Ratings: HMIS Ratings: Health: 2 - Moderate Health: 2 - Moderate Fire: 1- Slight Fire: 1- Slight Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Chemical Name(s) % W CAS Registry No. Table Z- 1 - A NTP, IARC or OSHA Carcinogen TWA mg/m3 STEL mg/m 3 CELING mg/m3 Triethanolamine dodecylbenzenesulfonate 5-10 27323-41-7 Not Established Not Established Not Established No Dipropropylene glycol monobutyl ether 5-10 29911-28-2 Not Established Not Established Not Established No Triethanolamine 1-5 102-71-6 5 (ACGIH) Not Established Not Established No Soybean oil methyl esters 1-5 67784-80-9 Not Established Not Established Not Established No d-Limonene 1-5 5989-27-5 Not Established Not Established Not Established No Alcohol ethoxylate 1-5 34398-01-1 Not Established Not Established Not Established No Page 352 of 495 Page 352 of 495 Page 352 of 495 Page 352 of 495 ---PAGE BREAK--- SECTION III: PHYSICAL DATA Boiling Point: 212 °F Vapor Pressure: Unknown Vapor Density (AIR = Unknown Solubility in Water: Complete pH: 8.5-9.0 Specific Gravity (H2O=1): 0.995 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 15-20 Physical State: Liquid Appearance & Odor: Clear orange liquid, Orange fragrance SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: 210°F Method Used: ASTM-D56 Flammable Limits: Not Established Flame Extension: N/A Extinguishing Media: Water, carbon dioxide or dry chemical. Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- Conditions to Avoid: Causes eye irritation: may include pain, redness and swelling of the conjunctiva. Causes skin irritation: may include redness, pain and swelling. Harmful if swallowed: may include pain, nausea, vomiting and diarrhea. Breathing product vapors or mist may cause respiratory irritation: may include nasal discomfort and coughing. Contains d-limonene and triethanolamine which may cause skin sensitization with repeated contact. Repeated overexposure to triethanolamine may cause liver and kidney damage. Avoid contact with eyes, skin and clothing. Avoid breathing product vapors or mists. Do not swallow. Use with adequate ventilation. Wash thoroughly after handling. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin: Remove contaminated clothing. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. Inhalation: Move person to fresh air. Get medical attention if irritation persists. Page 353 of 495 Page 353 of 495 Page 353 of 495 Page 353 of 495 ---PAGE BREAK--- SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Strong acids and oxidizing agents Hazardous Decomposition Products: Carbon dioxide, carbon monoxide Hazardous Polymerization: Will Not Occur Page 354 of 495 Page 354 of 495 Page 354 of 495 Page 354 of 495 ---PAGE BREAK--- SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, commercial absorbent, etc.) and transfer to containers for disposal. Keep spill out of storm sewers and waterways. Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However if exposure limits are exceeded (see Section II) or if respiratory irritation occurs, the use of a NIOSH approved respirator suitable for the use-conditions and chemicals listed in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or other impervious gloves. Eye Protection(Specify Type): Splash goggles are recommended to prevent eye contact. Other Protective Equipment: See 29 CFR 1910.132-138 for further guidance. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Keep container closed. Store in a cool, dry area. Do not freeze. Do not store above 120°F. Do not mix with other chemicals. Other Precautions: Keep out of reach of children © SCC 09/22/2008 Name: Ronald T. Cook Title: Manager, Regulatory Affairs ORANGE TOUGH 15 Effective Date: 09/22/2008 Supercedes: 06/30/2005 Ref: 29 CFR 1910.1200 (OSHA) Changes: Review This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 355 of 495 Page 355 of 495 Page 355 of 495 Page 355 of 495 ---PAGE BREAK--- Page 356 of 495 Page 356 of 495 Page 356 of 495 Page 356 of 495 ---PAGE BREAK--- Page 357 of 495 Page 357 of 495 Page 357 of 495 Page 357 of 495 ---PAGE BREAK--- Page 358 of 495 Page 358 of 495 Page 358 of 495 Page 358 of 495 ---PAGE BREAK--- Page 359 of 495 Page 359 of 495 Page 359 of 495 Page 359 of 495 ---PAGE BREAK--- Page 360 of 495 Page 360 of 495 Page 360 of 495 Page 360 of 495 ---PAGE BREAK--- Page 361 of 495 Page 361 of 495 Page 361 of 495 Page 361 of 495 ---PAGE BREAK--- Page 362 of 495 Page 362 of 495 Page 362 of 495 Page 362 of 495 ---PAGE BREAK--- Page 363 of 495 Page 363 of 495 Page 363 of 495 Page 363 of 495 ---PAGE BREAK--- Page 364 of 495 Page 364 of 495 Page 364 of 495 Page 364 of 495 ---PAGE BREAK--- Page 365 of 495 Page 365 of 495 Page 365 of 495 Page 365 of 495 ---PAGE BREAK--- Page 366 of 495 Page 366 of 495 Page 366 of 495 Page 366 of 495 ---PAGE BREAK--- Page 367 of 495 Page 367 of 495 Page 367 of 495 Page 367 of 495 ---PAGE BREAK--- Page 368 of 495 Page 368 of 495 Page 368 of 495 Page 368 of 495 ---PAGE BREAK--- Page 369 of 495 Page 369 of 495 Page 369 of 495 Page 369 of 495 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 2* Flammability 0 Reactivity 0 DATE OF PREPARATION Mar 5, 2010 MATERIAL SAFETY DATA SHEET B20W2251 19 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B20W2251 PRODUCT NAME PROMAR® 200 Interior Latex Eg-Shel Enamel, Extra White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 2 107-21-1 Ethylene Glycol ACGIH TLV 100 MG/M3 CEILING (aerosol) 0.12 mm OSHA PEL 50 PPM CEILING 0.1 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 15 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 13 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 370 of 495 Page 370 of 495 Page 370 of 495 Page 370 of 495 ---PAGE BREAK--- B20W2251 page 2 of 4 UEL N.A. LEL N.A. FLASH POINT Not Applicable SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Page 371 of 495 Page 371 of 495 Page 371 of 495 Page 371 of 495 ---PAGE BREAK--- B20W2251 page 3 of 4 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.85 lb/gal 1299 g/l SPECIFIC GRAVITY 1.31 BOILING POINT 212 - 388 °F 100 - 197 °C MELTING POINT Not Available VOLATILE VOLUME 58% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.2 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.78lb/gal 94g/l Less Water and Federally Exempt Solvents 0.35lb/gal 42g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans. TOXICOLOGY DATA CAS No. Ingredient Name 107-21-1 Ethylene Glycol LC50 RAT 4HR Not Available LD50 RAT 4700 mg/kg 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Page 372 of 495 Page 372 of 495 Page 372 of 495 Page 372 of 495 ---PAGE BREAK--- B20W2251 page 4 of 4 SECTION 14 — TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 107-21-1 Ethylene Glycol 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 373 of 495 Page 373 of 495 Page 373 of 495 Page 373 of 495 ---PAGE BREAK--- Page 374 of 495 Page 374 of 495 Page 374 of 495 Page 374 of 495 ---PAGE BREAK--- Page 375 of 495 Page 375 of 495 Page 375 of 495 Page 375 of 495 ---PAGE BREAK--- Page 376 of 495 Page 376 of 495 Page 376 of 495 Page 376 of 495 ---PAGE BREAK--- Page 377 of 495 Page 377 of 495 Page 377 of 495 Page 377 of 495 ---PAGE BREAK--- Page 378 of 495 Page 378 of 495 Page 378 of 495 Page 378 of 495 ---PAGE BREAK--- Page 379 of 495 Page 379 of 495 Page 379 of 495 Page 379 of 495 ---PAGE BREAK--- Page 380 of 495 Page 380 of 495 Page 380 of 495 Page 380 of 495 ---PAGE BREAK--- Page 381 of 495 Page 381 of 495 Page 381 of 495 Page 381 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 1/9 Print Date 07/03/2014 000000018029 MSDS_US 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Quaker State Advanced Durability SAE 5W-30 Motor Oil Product Code : 001D7554 Uses : Engine oil. Manufacturer/Supplier : Shell Oil Products US P.O. Box 4427 Houston TX 77210-4427 USA SDS Request : [PHONE REDACTED] Emergency Telephone Number Spill Information : [PHONE REDACTED] Health Information : [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Highly refined mineral oils and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. 3. HAZARDS IDENTIFICATION Emergency Overview Appearance and Odour : Amber. Liquid at room temperature. Slight hydrocarbon. Health Hazards : Not classified as dangerous for supply or conveyance. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Health Hazards : Not expected to be a health hazard when used under normal conditions. Health Hazards Inhalation : Under normal conditions of use, this is not expected to be a primary route of exposure. Skin Contact : Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Contact : May cause slight irritation to eyes. Ingestion : Low toxicity if swallowed. Other Information : Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Aggravated Medical Conditions : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Page 382 of 495 Page 382 of 495 Page 382 of 495 Page 382 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 2/9 Print Date 07/03/2014 000000018029 MSDS_US Environmental Hazards : Not classified as dangerous for the environment. Additional Information : Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. 4. FIRST-AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE-FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : > 220 °C / 428 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V)(based on mineral oil) Auto ignition temperature : > 320 °C / 608 °F Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. Observe the relevant local and international regulations. Protective measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or Page 383 of 495 Page 383 of 495 Page 383 of 495 Page 383 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 3/9 Print Date 07/03/2014 000000018029 MSDS_US other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Product Transfer : This material has the potential to be a static accumulator. Proper grounding and bonding procedures should be used during all bulk transfer operations. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhalabl e fraction.) 5 mg/m3 Oil mist, mineral OSHA Z1 PEL(Mist.) 5 mg/m3 Biological Exposure Index (BEI) No biological limit allocated. Page 384 of 495 Page 384 of 495 Page 384 of 495 Page 384 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 4/9 Print Date 07/03/2014 000000018029 MSDS_US Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For Page 385 of 495 Page 385 of 495 Page 385 of 495 Page 385 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 5/9 Print Date 07/03/2014 000000018029 MSDS_US short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hse.gov.uk/ Institut für Deutschen Gesetzlichen Unfallversicherung (IFA), Germany. http://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil Environmental Exposure Controls : Take appropriate measures to fulfil the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Amber. Liquid at room temperature. Odour : Slight hydrocarbon. pH : Not applicable. Page 386 of 495 Page 386 of 495 Page 386 of 495 Page 386 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 6/9 Print Date 07/03/2014 000000018029 MSDS_US Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -38 °C / -36 °F Flash point : > 220 °C / 428 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 (based on mineral oil) Auto-ignition temperature : > 320 °C / 608 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.88 at 15 °C / 59 °F Density : Typical 886 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : > 50 cSt at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Electrical conductivity : This material is not expected to be a static accumulator. Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Not expected to be carcinogenic. Product contains mineral oils of types shown to be non-carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Page 387 of 495 Page 387 of 495 Page 387 of 495 Page 387 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 7/9 Print Date 07/03/2014 000000018029 MSDS_US Material : Carcinogenicity Classification Highly refined mineral oil (IP346 : ACGIH Group A4: Not classifiable as a human carcinogen. Highly refined mineral oil (IP346 : IARC 3: Not classifiable as to carcinogenicity to humans. Highly refined mineral oil (IP346 : GHS / CLP: No carcinogenicity classification Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. Continuous contact with used engine oils has caused skin cancer in animal tests. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic organisms. Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l (to aquatic organisms) LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract. Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. Mobility : Liquid under most environmental conditions. If it enters soil, it will adsorb to soil particles and will not be mobile. Floats on water. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical Page 388 of 495 Page 388 of 495 Page 388 of 495 Page 388 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 8/9 Print Date 07/03/2014 000000018029 MSDS_US properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation Classification (49CFR) This material is not subject to DOT regulations under 49 CFR Parts 171-180. IMDG This material is not classified as dangerous under IMDG regulations. IATA (Country variations may apply) This material is either not classified as dangerous under IATA regulations or needs to follow country specific requirements. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. Federal Regulatory Status Notification Status EINECS All components listed or polymer exempt. TSCA All components listed. DSL All components listed. Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reportable under CERCLA. Page 389 of 495 Page 389 of 495 Page 389 of 495 Page 389 of 495 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878DA Version 1.3 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 9/9 Print Date 07/03/2014 000000018029 MSDS_US State Regulatory Status California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. 16. OTHER INFORMATION NFPA Rating (Health, Fire, Reactivity) : 0, 1, 0 SDS Version Number : 1.3 SDS Effective Date : 02/05/2014 SDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. SDS Regulation : The content and format of this MSDS is in accordance with the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 390 of 495 Page 390 of 495 Page 390 of 495 Page 390 of 495 ---PAGE BREAK--- Date Printed: 10/9/2013 Material Safety Data Sheet 24 Hour Assistance: 24 Hour Assistance: 24 Hour Assistance: 24 Hour Assistance: 1-[PHONE REDACTED] 1-[PHONE REDACTED] 1-[PHONE REDACTED] 1-[PHONE REDACTED] Rust-Oleum Corp. Rust-Oleum Corp. Rust-Oleum Corp. Rust-Oleum Corp. www.rustoleum.com www.rustoleum.com www.rustoleum.com www.rustoleum.com 1. Identification 1. Identification 1. Identification 1. Identification Product Name: Product Name: Product Name: Product Name: RUST STRIPPER Revision Date: Revision Date: Revision Date: Revision Date: 10/9/2013 Product Number: Product Number: Product Number: Product Number: F7840402 Product Use/Class: Product Use/Class: Product Use/Class: Product Use/Class: Rust Remover/Acidic Supplier: Supplier: Supplier: Supplier: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Manufacturer: Manufacturer: Manufacturer: Manufacturer: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Prepared by: Prepared by: Prepared by: Prepared by: Regulatory Department 2. Hazard Identification 2. Hazard Identification 2. Hazard Identification 2. Hazard Identification EMERGENCY OVERVIEW: EMERGENCY OVERVIEW: EMERGENCY OVERVIEW: EMERGENCY OVERVIEW: May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaledHarmful if swallowed. Causes severe skin and eye burns. Causes eye irritation. Vapors extremely irritating to eyes and respiratory tract. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Avoid contact with eyes, skin and clothing. EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE - EYE CONTACT: EYE CONTACT: EYE CONTACT: EYE CONTACT: Substance causes severe eye irritation. Injury may be permanent. EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE - SKIN CONTACT: SKIN CONTACT: SKIN CONTACT: SKIN CONTACT: Severely irritating; may cause permanent skin damage. EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE - INHALATION: INHALATION: INHALATION: INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE - INGESTION: INGESTION: INGESTION: INGESTION: Corrosive and may cause severe and permanent damage to mouth, throat and stomach. Substance may be harmful if swallowed. EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: CHRONIC HAZARDS: CHRONIC HAZARDS: CHRONIC HAZARDS: Repeated exposure to low concentrations of HCl vapor or mist may cause bleeding of nose and gums. PRIMARY ROUTE(S) OF ENTRY: PRIMARY ROUTE(S) OF ENTRY: PRIMARY ROUTE(S) OF ENTRY: PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact 3. Composition/Information On Ingredients 3. Composition/Information On Ingredients 3. Composition/Information On Ingredients 3. Composition/Information On Ingredients Chemical Name Chemical Name Chemical Name Chemical Name CAS-No. CAS-No. CAS-No. CAS-No. Weight % Weight % Weight % Weight % Less Than Less Than Less Than Less Than ACGIH TLV- ACGIH TLV- ACGIH TLV- ACGIH TLV- TWA TWA TWA TWA ACGIH TLV- ACGIH TLV- ACGIH TLV- ACGIH TLV- STEL STEL STEL STEL OSHA PEL-TWA OSHA PEL-TWA OSHA PEL-TWA OSHA PEL-TWA OSHA PEL- OSHA PEL- OSHA PEL- OSHA PEL- CEILING CEILING CEILING CEILING Hydrochloric Acid 7647-01-0 45.0 N.E. N.E. 5 ppm N.E. Phosphoric Acid 7664-38-2 5.0 1 mg/m3 3 mg/m3 1 mg/m3 N.E. 4. First-aid Measures 4. First-aid Measures 4. First-aid Measures 4. First-aid Measures FIRST AID FIRST AID FIRST AID FIRST AID - EYE CONTACT: EYE CONTACT: EYE CONTACT: EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed. FIRST AID FIRST AID FIRST AID FIRST AID - SKIN CONTACT: SKIN CONTACT: SKIN CONTACT: SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. Immediately flush skin with plenty of water for at least 15 minutes while removing clothing. Get medical attention immediately. Wash clothing separately before reuse. Destroy contaminated shoes. FIRST AID FIRST AID FIRST AID FIRST AID - INHALATION: INHALATION: INHALATION: INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. Page 1 / 4 Page 391 of 495 Page 391 of 495 Page 391 of 495 Page 391 of 495 ---PAGE BREAK--- Date Printed: 10/9/2013 FIRST AID FIRST AID FIRST AID FIRST AID - INGESTION: INGESTION: INGESTION: INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat and supportively. Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately. 5. Fire-fighting Measures 5. Fire-fighting Measures 5. Fire-fighting Measures 5. Fire-fighting Measures Flash Point, °F >200 (Calculated) Extinguishing Media: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. Keep containers closed. SPECIAL FIREFIGHTING PROCEDURES: Containers can rupture and release highly toxic material if exposed to heat. Substance is non-combustible but reacts with many metals to form explosive hydrogen gas. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. 6. Accidental Release Measures STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Avoid runoff into sewers and waterways. Provide ventilation and approach spill from upwind using proper personal protective equipment as indicated in Section 8. Carefully neutralize spill with sodium bicarbonate (NaHCO3). Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. 7. Handling and Storage HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing. STORAGE: Store in a dry, well ventilated place. Keep container closed when not in use. 8. Exposure Controls/Personal Protection ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross- ventilation. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse. Page 2 / 4 Page 392 of 495 Page 392 of 495 Page 392 of 495 Page 392 of 495 ---PAGE BREAK--- Date Printed: 10/9/2013 9. Physical and Chemical Properties Vapor Density Heavier than Air Odor: Acrid Appearance: Liquid Evaporation Rate: Slower than Ether Solubility in Water: Soluble Freeze Point: N.D. Specific Gravity: 1.099 pH: <1 Physical State: Liquid (See section 16 for abbreviation legend) 10. Stability and Reactivity CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases. Avoid contact with metals. INCOMPATIBILITY: Product slowly corrodes copper, aluminum,zinc, and galvanized surfacesIncompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION: Decomposition produces hydrogen chloride, chlorine and hydrogen gases. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. 11. Toxicological Information Chemical Name LD50 LC50 Hydrochloric Acid 900 mg/kg (Rabbit) 3124 ppm (Rat, 1Hr) Phosphoric Acid 4400 mg/kg (Rat) N.E. 12. Ecological Information ECOLOGICAL INFORMATION: Product is a mixture of listed components. 13. Disposal Information DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter waterways, wastewater. soil, storm drains or sewer systems. 14. Transport Information Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada) UN Number: UN3264 UN3264 UN3264 UN3264 Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S. Corrosive Liquid, Acidic, Inorganic, N.O.S. Corrosive Liquid, Acidic, Inorganic, N.O.S. Corrosive Liquid, Acidic, Inorganic, N.O.S. Hazard Class: 8 8 8 8 Packing Group: II II II II Limited Quantity: No No No No 15. Regulatory Information Page 3 / 4 Page 393 of 495 Page 393 of 495 Page 393 of 495 Page 393 of 495 ---PAGE BREAK--- Date Printed: 10/9/2013 U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Acute Health Hazard, Chronic Health Hazard Sara Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. Phosphoric Acid 7664-38-2 Toxic Substances Control Act: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA 12(b) components exist in this product. International Regulations: CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. Canadian WHMIS Class: D2B E 16. Other Information HMIS Ratings: Health: 3 Flammability: 1 Physical Hazard: 1 Personal Protection: X NFPA Ratings: Health: 3 Flammability: 1 Instability 1 VOLATILE ORGANIC COMPOUNDS, g/L: 0 REASON FOR REVISION: Regulatory Update Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations. Page 4 / 4 Page 394 of 495 Page 394 of 495 Page 394 of 495 Page 394 of 495 ---PAGE BREAK--- Page 395 of 495 Page 395 of 495 Page 395 of 495 Page 395 of 495 ---PAGE BREAK--- Page 396 of 495 Page 396 of 495 Page 396 of 495 Page 396 of 495 ---PAGE BREAK--- Page 397 of 495 Page 397 of 495 Page 397 of 495 Page 397 of 495 ---PAGE BREAK--- Page 398 of 495 Page 398 of 495 Page 398 of 495 Page 398 of 495 ---PAGE BREAK--- Page 399 of 495 Page 399 of 495 Page 399 of 495 Page 399 of 495 ---PAGE BREAK--- Page 400 of 495 Page 400 of 495 Page 400 of 495 Page 400 of 495 ---PAGE BREAK--- Page 401 of 495 Page 401 of 495 Page 401 of 495 Page 401 of 495 ---PAGE BREAK--- Page 1/7 Safety Data Sheet According to 91/155 EEC Printing date 04/21/2009 Revision: 04/21/2009 DR 1 Identification of the substance/preparation and of the company/undertaking · Product details · Trade name: 'SAIRSET DC · Manufacturer/Supplier: ANH Refractories Company 400 Fairway Drive Moon Township, PA 15108 General Phone: (412)375-6600 · Information in case of emergency: CHEMTREC 24 HOUR EMERGENCY PHONE NUMBER: 1-[PHONE REDACTED]. 2 Composition/information on ingredients · Chemical characterization · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: 1302-93-8 alumina silicate 30-60% 1344-09-8 Silicic acid, sodium salt Warning: Exclamation mark 3.2/2, 3.3/2A, 3.8/3 20-30% 14808-60-7 silica (quartz) Danger: Health hazard 3.6/1B 10-20% 14464-46-1 silica (cristobalite) Danger: Health hazard 3.6/1B 10-20% 7631-86-9 silicon dioxide, chemically prepared 5-10% * 3 Hazards identification · Hazard description: Toxic · Information concerning to particular hazards to man and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. May cause cancer by inhalation. Irritating to eyes, respiratory system and skin. Danger of serious damage to health by prolonged exposure. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. · GHS label elements Health hazard Danger 3.6/1B - May cause cancer. Exclamation mark Warning 3.2/2 - Causes skin irritation. 3.3/2A - Causes serious eye irritation. 3.8/3 - May cause respiratory irritation. (Contd. on page 2) CDN Page 402 of 495 Page 402 of 495 Page 402 of 495 Page 402 of 495 ---PAGE BREAK--- Page 2/7 Safety Data Sheet According to 91/155 EEC Printing date 04/21/2009 Revision: 04/21/2009 Trade name: 'SAIRSET DC (Contd. of page 1) DR · Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. · Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. · Storage: Store in a well-ventilated place. Keep container closed. Store locked up. · Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations. 4 First-aid measures · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Flush eyes with water for 15 minutes. If irritation persists, consult a doctor. · After swallowing: This product is intended for industrial applications; in the unlikely event that this product is swallowed, consult a physician if any adverse medical conditions occur. 5 Fire-fighting measures · Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. · Protective equipment: No special measures required. 6 Accidental release measures · Person-related safety precautions: Not required. · Measures for environmental protection: No special measures required. · Measures for cleaning/collecting: Dispose contaminated material as waste according to item 13. (Contd. on page 3) CDN Page 403 of 495 Page 403 of 495 Page 403 of 495 Page 403 of 495 ---PAGE BREAK--- Page 3/7 Safety Data Sheet According to 91/155 EEC Printing date 04/21/2009 Revision: 04/21/2009 Trade name: 'SAIRSET DC (Contd. of page 2) DR Ensure adequate ventilation. 7 Handling and storage · Handling: · Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of dust. · Information about fire - and explosion protection: Keep respiratory protective device available. · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Store product inside, out of extreme weather conditions. 8 Exposure controls/personal protection · Ingredients with limit values that require monitoring at the workplace: 14808-60-7 silica (quartz) EL (Canada) PEL (USA) REL (USA) TLV (USA) 0.025 mg/m³ ACGIH A2; IARC 1 see Quartz listing 0.05* mg/m³ *respirable dust 0.025* mg/m³ *as respirable fraction 14464-46-1 silica (cristobalite) EL (Canada) PEL (USA) REL (USA) TLV (USA) 0.025 mg/m³ ACGIH A2; IARC 1 ½ value from respirable dust formulae for Quartz 0.05* mg/m³ *respirable dust 0.025* mg/m³ *as respirable fraction 1332-58-7 hydrous alumina silicate EL (Canada) PEL (USA) REL (USA) TLV (USA) 2 mg/m³ 15* mg/m³ *total dust **respirable fraction 10* mg/m³ *total dust **respirable fraction 2* mg/m³ E; as respirable fraction (Contd. on page 4) CDN Page 404 of 495 Page 404 of 495 Page 404 of 495 Page 404 of 495 ---PAGE BREAK--- Page 4/7 Safety Data Sheet According to 91/155 EEC Printing date 04/21/2009 Revision: 04/21/2009 Trade name: 'SAIRSET DC (Contd. of page 3) DR · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. · Respiratory protection: NIOSH approved respirators should be used if dust is present. A respiratory protection program should be implemented if exposures exceed OSHA PELs. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses * 9 Physical and chemical properties · General Information Form: Solid Colour: According to product specification Odour: No specific odor. · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. · Flash point: Not applicable. · Self-igniting: Product is not selfigniting. · Danger of explosion: Product does not present an explosion hazard. (Contd. on page 5) CDN Page 405 of 495 Page 405 of 495 Page 405 of 495 Page 405 of 495 ---PAGE BREAK--- Page 5/7 Safety Data Sheet According to 91/155 EEC Printing date 04/21/2009 Revision: 04/21/2009 Trade name: 'SAIRSET DC (Contd. of page 4) DR · Density: Not determined. · Solubility in / Miscibility with water: Insoluble. · Solvent content: Organic solvents: 0.0 % 10 Stability and reactivity · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Dangerous reactions No dangerous reactions known. · Dangerous decomposition products: Refractories containing silica may, after service,contain more or less silica. Care must be taken to avoid and/or control dust from demolition. If in doubt of the proper protection, seek advice from a safety professional. 11 Toxicological information · Acute toxicity: · LD/LC50 values relevant for classification: 7631-86-9 silicon dioxide, chemically prepared Oral LD50 10000 mg/kg (rat) · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant Carcinogenic if inhaled. 12 Ecological information · General notes: At present there are no ecotoxicological assessments. 13 Disposal considerations · Recommendation As sold, this product is not RCRA hazardous. Final used condition must be evaluated prior to disposal. Dispose of waste product in accordance with Federal, State and Local regulations. (Contd. on page 6) CDN Page 406 of 495 Page 406 of 495 Page 406 of 495 Page 406 of 495 ---PAGE BREAK--- Page 6/7 Safety Data Sheet According to 91/155 EEC Printing date 04/21/2009 Revision: 04/21/2009 Trade name: 'SAIRSET DC (Contd. of page 5) DR Dust created during demolition of used product may contain silica. · Recommendation: Reuse, recycle or treat as industrial waste. 14 Transport information · Maritime transport IMDG: · Marine pollutant: No · Transport/Additional information: Not dangerous according to the above specifications. * 15 Regulatory information · Domestic Substances List All ingredients are listed. · Labelling according to EU guidelines: · Code letter and hazard designation of product: Toxic · Hazard-determining components of labelling: silica (quartz) silica (cristobalite) · Risk phrases: May cause cancer by inhalation. Irritating to eyes, respiratory system and skin. Danger of serious damage to health by prolonged exposure. · Safety phrases: Avoid exposure - obtain special instructions before use. When using do not eat or drink. Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Contact: Dylan L. Miller [PHONE REDACTED] · Creation date: 08/14/2000 · Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods GHS: Globally Harmonized System of Classification and Labelling of Chemicals (Contd. on page 7) CDN Page 407 of 495 Page 407 of 495 Page 407 of 495 Page 407 of 495 ---PAGE BREAK--- Page 7/7 Safety Data Sheet According to 91/155 EEC Printing date 04/21/2009 Revision: 04/21/2009 Trade name: 'SAIRSET DC (Contd. of page 6) DR LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent · * Data compared to the previous version altered. CDN Page 408 of 495 Page 408 of 495 Page 408 of 495 Page 408 of 495 ---PAGE BREAK--- Home Page Material Safety Data Sheet Product No. 81700 Sprayway® Duster Issue Date (03-14-01) Review Date (09-14-06) Section 1: Product and Company Identification Product Name: Sprayway® Duster Manufacture: Sprayway, Addison, Il 60101 Synonym: Lint & Dust Remover Company Name Ted Pella, Inc. and PELCO International, P.O. Box 492477, Redding, CA 96049-2477 Domestic Phone (800) 237-3526 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST) International Phone (01) (530) 243-2200 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST) Chemtrec Emergency Number 1-[PHONE REDACTED] 24 hrs a day. Section 2: Composition / Information on Ingredients Principle Hazardous Component(s) (chemical and common name(s)) (Cas. No) % OSHA PEL mg/m3 ACGIH TLV mg/m3 NTP IARC OSHA regulated Liquefied Gas Mixture 70-80 NA NA No No No Dimethyl ether (115-10-6) ND NE NE No No No Isobutane (75-28-5) ND NE NE No No No Propane (74-98-6) ND 1000 ppm NE No No No 1,1,1,2-Tetrafluoroethane (811-97-2) 20-30 NE NE No No No Section 3: Hazard Identification Sprayway Duster, 81700, MSDS, Ted Pella, Inc. http://www.tedpella.com/msds_html/81700msd.htm (1 of 7) [9/11/2007 4:19:25 PM] Page 409 of 495 Page 409 of 495 Page 409 of 495 Page 409 of 495 ---PAGE BREAK--- Emergency overview Appearance: Clear, colorless gas Immediate effects: Irritation and dizziness. Potential health effects Primary Routes of entry: Inhalation, eyes, skin. Signs and of Overexposure: Eyes: Irritant. Liquid may cause freezing. Skin: Contact with liquid may cause freezing or frost bite. Ingestion: Not considered a potential route of exposure. Inhalation: High concentrations of vapor are harmful and may cause heart irregularities, unconscious, or death. Chronic Exposure: ND Chemical Listed As Carcinogen Or Potential Carcinogen: None See Toxicological Information (Section11) Potential environmental effects See Ecological Information (Section 12) Section 4: First Aid Measures If accidental overexposure is suspected Eye(s) Contact: Flush eyes with large amounts of water and allow to evaporate. Get medical attention if irritation persists. Skin Contact: Wash with copious amounts of water for at least 15 minutes. Contact medical attention if complications arise. Inhalation: If unconscious, remove to fresh air and call a physician. Ingestion: Consult poison center and physician for additional guidance. Note to physician Treatment: NIF Medical Conditions generally Aggravated by Exposure: Preexisting diseases of the central nervous system may be aggravated by exposure to this product. Section 5: Fire Fighting Measures Flash Point: <0 deg F (Propellant): NA (Concentrate) Flammable Limits: % Volume In Air (Propellant): (approx)LEL: 1.8 UEL: 18.0 Sprayway Duster, 81700, MSDS, Ted Pella, Inc. http://www.tedpella.com/msds_html/81700msd.htm (2 of 7) [9/11/2007 4:19:25 PM] Page 410 of 495 Page 410 of 495 Page 410 of 495 Page 410 of 495 ---PAGE BREAK--- Auto-ignition point: ND Fire Extinguishing Media: Carbon dioxide, foam and/or dry chemical may be used. Special Fire Fighting Procedures: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from containers bursting, rupturing or venting. Unusual Fire and Explosion Hazards: At elevated temperatures (over 54C-130F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening of container structure. Hazardous combustion products: Oxides of carbon. Hydrofluoric acid, carbonyl fluoride, and additional toxic chemicals may be formed in small amounts. DOT Class: ORM-D Section 6: Accidental Release Measures Steps to be Taken in Case Material is Released or Spilled: Remove all sources of ignition and provide good ventilation. Waste Disposal Methods: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gas is expelled. Dispose of waste according to Federal, State and Local Regulations. Section 7: Handling and Storage Precautions to be Taken in Handling and Storage: Avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not puncture of incinerate containers. Do not expose to direct sunlight or store at temperatures above 130F (54C). Store as Level 3 Aerosol (NFPA 30B). Storage temperature: Ambient Storage Pressure: Atmospheric Section 8: Exposure Controls / Personal Protection Engineering Controls Ventilation required: Provide sufficient mechanical ventilation to maintain exposure below TLV(s). Overexposure to vapors and mist may be prevented by ensuring ventilation controls, local exhausts and/or fresh air entry. Personal Protection Equipment Respiratory protection: None if adequate ventilation is maintained. Protective gloves: Optional: Chemical resistant gloves. Skin protection: Wear impervious clothing to prevent skin contact. Eye protection: Chemical safety glasses are recommended. Additional clothing and/or equipment: ND Exposure Guidelines See Composition/Information on Ingredients (Section2) Sprayway Duster, 81700, MSDS, Ted Pella, Inc. http://www.tedpella.com/msds_html/81700msd.htm (3 of 7) [9/11/2007 4:19:25 PM] Page 411 of 495 Page 411 of 495 Page 411 of 495 Page 411 of 495 ---PAGE BREAK--- Section 9 Physical and Chemical Properties Appearance and Physical State: Clear, colorless Odor (threshold): Ethereal odor Specific Gravity (H2O=1): <1 Vapor Pressure (mm Hg): 158@ 130F (54.4 C) Vapor Density (air=1): >1 Percent Volatile by volume: ND Evaporation Rate (butyl acetate=1): <1 Boiling Point: NA Freezing point / melting point: ND pH: ND Solubility in Water: Negligible Molecular Weight: NA Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Do not store above 54C (130F). Keep away from heat, direct sunlight, open flames or sparks. Dropping containers may cause bursting. Materials to Avoid (Incompatibility): Oxidizing agents. Hazardous Decomposition Products: Hydrofluoric acid, carbonyl fluoride, oxides of carbon and additional toxic chemicals may be formed in small amounts. Hazardous Polymerization: Section 11: Toxicological Information Results of component toxicity test performed: NIF Human experience: NIF This product does not contain any compounds listed by NTP or IARC or regulated by OSHA as a carcinogen. Section 12: Ecological Information Ecological Information: NIF Chemical Fate Information: NIF Section 13 Disposal Considerations Sprayway Duster, 81700, MSDS, Ted Pella, Inc. http://www.tedpella.com/msds_html/81700msd.htm (4 of 7) [9/11/2007 4:19:25 PM] Page 412 of 495 Page 412 of 495 Page 412 of 495 Page 412 of 495 ---PAGE BREAK--- RCRA 40 CFR 261 Classification: NIF Federal, State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal. Section 14: Transportation Information US DOT Information: Proper shipping name: Consumer Commodity Hazard Class: ORM-D Packaging group: UN Number: Limitations: IATA: Proper shipping name: NA Hazard Class: NA Packing group: NA UN Number: NA Limitations: Forbidden by Air Domestic shipments only: IMO: Proper shipping name: Consumer Commodity Class: ORM-D UN Number: Packing group: EMS: ND MFAG: ND Marine Pollutant: None Canadian TDG: NA IMDG Page: NA Limitations: NA Section 15: Regulatory Information United States Federal Regulations MSDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200. Sprayway Duster, 81700, MSDS, Ted Pella, Inc. http://www.tedpella.com/msds_html/81700msd.htm (5 of 7) [9/11/2007 4:19:25 PM] Page 413 of 495 Page 413 of 495 Page 413 of 495 Page 413 of 495 ---PAGE BREAK--- SARA: ND SARA Title III: No RCRA: ND TSCA: Ingredients of this product are listed on the EPA/TSCA Inventory of Chemical Substance. CERCLA: ND State Regulations California Proposition 65: None International Regulations Canada WHMIS: NIF Europe EINECS Numbers: NIF Section 16: Other Information Label Information: Flammable European Risk and Safety Phrases: NA European symbols needed: NA Canadian WHMIS Symbols: NA Hazard Rating: Health: 1; Fire: 4; Reactivity: 1 (0=least, 1=Slight, 2=Moderate, 3=High, 4=Extreme) Abbreviations used in this document NE= Not established NA= Not applicable NIF= No Information Found ND= No Data Disclaimer Ted Pella, Inc. makes no warranty of any kind regarding the information furnished herein. Users should independently determine the suitability and completeness of information from all sources. While this data is presented in good faith and believed to be accurate, it should be considered only as a supplement to other information gathered by the user. It is the User's responsibility to assure the proper use and disposal of these materials as well as the safety and health of all personnel who may work with or otherwise come in contact with these materials. Sprayway Duster, 81700, MSDS, Ted Pella, Inc. http://www.tedpella.com/msds_html/81700msd.htm (6 of 7) [9/11/2007 4:19:25 PM] Page 414 of 495 Page 414 of 495 Page 414 of 495 Page 414 of 495 ---PAGE BREAK--- MSDS Form 0013F1 V2 Sprayway Duster, 81700, MSDS, Ted Pella, Inc. http://www.tedpella.com/msds_html/81700msd.htm (7 of 7) [9/11/2007 4:19:25 PM] Page 415 of 495 Page 415 of 495 Page 415 of 495 Page 415 of 495 ---PAGE BREAK--- 0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$<  0L[WXUH $17,67$7,&635$< 0HOURVH3DUN,/86 (PHUJHQF\3KRQH (PHUJHQF\ (PHUJHQF\3KRQH (PHUJHQF\RYHUYLHZ &217(17681'(535(6685(  (\HV XVH 6NLQ 7DUJHWRUJDQV &HQWUDOQHUYRXVV\VWHP(\HV5HVSLUDWRU\V\VWHP6NLQ &KURQLFHIIHFWV 3HUFHQW +\GURIOXRURFDUERQ$  )LUVWDLG  )LUVW$LG0HDVXUHV 0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$< )RUPXOD 0$53ULQWGDWH 06'686 Page 416 of 495 Page 416 of 495 Page 416 of 495 Page 416 of 495 ---PAGE BREAK--- V  KD]DUGV  6PDOO)LUHV /DUJH)LUHV :DWHUVSUD\IRJRUUHJXODUIRDP 3URSHOODQW 6WRS  /DUJH6SLOOV 6PDOO6SLOOV :LSHXSZLWKDEVRUEHQWPDWHULDO HJFORWKIOHHFH WKRURXJKO\ +DQGOLQJ  +DQGOLQJDQG6WRUDJH 6WRUDJH /HYHO$HURVRO DSSURSULDWHFHUWLILHGUHVSLUDWRUV  DVUHTXLUHG 0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$< )RUPXOD 0$53ULQWGDWH 06'686 Page 417 of 495 Page 417 of 495 Page 417 of 495 Page 417 of 495 ---PAGE BREAK---  3K\VLFDO )ODPPDELOLW\ 1RWDYDLODEOH )RUP $HURVRO 3HUFHQWYRODWLOH 9DSRUSUHVVXUH 92&  6WDELOLW\   /RFDOHIIHFWV 86$&*,+7KUHVKROG/LPLW9DOXHV &KURQLFWR[LFLW\ (FRWR[LFLW\ ,QYHUWHEUDWH7R[LFLW\ (&YDOXH :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD /&YDOXH 7XUEHOODULDQIODWZRUP   0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$< )RUPXOD 0$53ULQWGDWH 06'686 Page 418 of 495 Page 418 of 495 Page 418 of 495 Page 418 of 495 ---PAGE BREAK--- '27 250' 1RQH 1RQH +D]DUGFODVV (5*QXPEHU  '27 $HURVROVIODPPDEOH 81 1RQH 1RQH +D]DUGFODVV 81QXPEHU (5*QXPEHU  +D]DUGFODVV 81QXPEHU $HURVROVIODPPDEOH  +D]DUGFODVV 81QXPEHU $(5262/6IODPPDEOH    +D]DUGFODVV 81QXPEHU ,WHP /DEHOVUHTXLUHG 0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$< )RUPXOD 0$53ULQWGDWH 06'686 Page 419 of 495 Page 419 of 495 Page 419 of 495 Page 419 of 495 ---PAGE BREAK---  26+$  2 g/kg Not available Dipropylene glycol methyl ether 34590-94-8 1 - 5% 5135 9500 mg/kg Not available 4. FIRST AID MEASURES Eye contact: Immediately flush eyes w ith running w ater for at least 15 minutes, keeping eyelids open. Get medical attention. Skin contact: Flush immediately w ith plenty of w ater. If irritation persists, get medical attention. Inhalation: If breathing is affected, remove to fresh air. Get medical attention. Ingestion: Give a cupful of w ater or milk . THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Aggravated Medical Conditions: Persons w ith pre-existing skin disorders may be more susceptable to irritating effects. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Not applicable Unusual hazards: None know n Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, w ear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] Preparation date: 2009-06-24 Personal protective equipment HMIS EMERGENCY OVERVIEW WARNING. CAUSES EYE AND SKIN IRRITATION. NFPA Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: w w w .johnsondiversey.com Stride Citrus HC Neutral Cleaner 1 of 3 Version Number: 2 2 Fire Hazard 0 2 Health 0 Reactivity 0 0 Page 423 of 495 Page 423 of 495 Page 423 of 495 Page 423 of 495 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Clean-up methods - large spillage. Absorb spill w ith inert material (e.g. dry sand or earth), then place in a chemical w aste container. Use a w ater rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact w ith skin, eyes and clothing. Do not taste or sw allow . Remove and w ash contaminated clothing and footw ear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and w ell-ventilated place. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: Chemical-splash goggles. Hand protection: Chemical-resistant gloves Skin and body protection: No special protective clothing is required. Respiratory protection: No special protective clothing is required. Hygiene measures: Handle in accordance w ith good industrial hygiene and safety practice Ingredient(s) CAS # ACGIH OSHA Mexico Dipropylene glycol methyl ether 34590-94-8 150 ppm (STEL) 100 ppm (TWA) Skin 100 ppm (TWA) 600 mg/m3 (TWA) 900 mg/m3 (STEL) 150 ppm (STEL) 100 ppm (TWA) 60 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: Oxidising agents. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be betw een 2000 - 5000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg. Component Information: See Section 3 Chronic toxicity: None know n Specific effects Carcinogenic effects: None know n Mutagenic effects: None know n Reproductive toxicity: None know n Target organ effects: None know n 12. ECOLOGICAL INFORMATION Specific gravity: 1.007 7.4 @ 1:375 Melting point/range: Not determined Bulk density: Density: 8.4 lbs/gal 1.007 Kg/L Appearance: Decomposition temperature: Not determined Aqueous solution VOC: 0% * No information available Autoignition temperature: No information available Vapor density: Flash point: >200°F >93.4°C No information available Partition coefficient (n-octanol/water): No information available Liquid Solubility: Completely Soluble Color: Solubility in other solvents: No information available Clear Orange Viscosity: No information available pH: Elemental Phosphorus: 0.00% by w t. Evaporation Rate No information available 6.5 Odor: Citrus Physical State: Stride Citrus HC Neutral Cleaner Boiling point/range: Not determined 2 of 3 Dilution pH: Page 424 of 495 Page 424 of 495 Page 424 of 495 Page 424 of 495 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the follow ing inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Coconut fatty acid 61788-47-4 - - - - Water 7732-18-5 - - - - Sodium xylene sulfonate 1300-72-7 - - - - Alcohol ethoxylates 68439-46-3 - - - - Dipropylene glycol methyl ether 34590-94-8 X X X X CERCLA/ SARA SARA 311/312 Hazard Categories Immediate: x Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class: D2B Toxic materials. 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: Contains an added fragrance, see "Odor" heading in section 9 for specific description. When used through dispensing/autodose equipment, this product meets Green Seal's requirements for skin and eye irritation and acute toxicity at the as-used dilution. Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 Stride Citrus HC Neutral Cleaner Page 425 of 495 Page 425 of 495 Page 425 of 495 Page 425 of 495 ---PAGE BREAK--- Page 426 of 495 Page 426 of 495 Page 426 of 495 Page 426 of 495 ---PAGE BREAK--- Page 427 of 495 Page 427 of 495 Page 427 of 495 Page 427 of 495 ---PAGE BREAK--- Page 428 of 495 Page 428 of 495 Page 428 of 495 Page 428 of 495 ---PAGE BREAK--- Page 429 of 495 Page 429 of 495 Page 429 of 495 Page 429 of 495 ---PAGE BREAK--- Page 430 of 495 Page 430 of 495 Page 430 of 495 Page 430 of 495 ---PAGE BREAK--- Page 431 of 495 Page 431 of 495 Page 431 of 495 Page 431 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Product Name Super Iron Out® . 1. Product and Company Identification space CAS # Mixture space Product use Rust & Stain Remover space Manufacturer Iron Out dba Summit Brands 7201 Engle Road Fort Wayne, IN 46804-5875 US Phone: [PHONE REDACTED] Emergency Phone: 1-[PHONE REDACTED] (CHEMTREC) space Personal Protection Physical Hazard Flammability Health B 1 0 2 * Minimal Slight Moderate Serious LEGEND 4 3 2 1 0 Severe 0 2 1 HMIS/NFPA space Emergency overview CAUTION EYE AND SKIN IRRITANT. May cause sensitization by inhalation. . 2. Hazards Identification space Routes of exposure Potential short term health effects Eye, Skin contact, Inhalation, Ingestion. space Eyes Causes irritation. space Skin Causes irritation. space Inhalation Dusts of this product may cause irritation of the nose, throat, and respiratory tract. space Ingestion May cause stomach distress, nausea or vomiting. space Target organs Eyes. Respiratory system. Skin. space Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. space Signs and may include redness, edema, drying, defatting and cracking of the skin. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. space Ingredient(s) CAS # Percent 30 - 60 7775-14-6 Sodium hydrosulfite 3 - 7 497-19-8 Sodium carbonate 15 - 40 7647-14-5 Sodium chloride 15 - 40 7681-57-4 Sodium metabisulfite 1 - 5 77-92-9 Citric acid 0.1 - 1 7631-90-5 Sodium bisulfite . 3. Composition / Information on Ingredients space Eye contact First aid procedures Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention if irritation develops or persists. . 4. First Aid Measures space Skin contact Immediately flush with water. Wash with soap and water. Obtain medical attention if irritation persists. space Inhalation If develop move victim to fresh air. If persist, obtain medical attention. space Page 1 of 7 #7840 22-Aug-2008 Issue date Page 432 of 495 Page 432 of 495 Page 432 of 495 Page 432 of 495 ---PAGE BREAK--- Ingestion Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. space Notes to physician may be delayed. space General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. space Flammable properties Not flammable by WHMIS/OSHA criteria. . 5. Fire Fighting Measures space Suitable extinguishing media Extinguishing media Dry chemical. Carbon dioxide. Foam. space Unsuitable extinguishing media Not available space Specific hazards arising from the chemical Protection of firefighters Not available space Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. space Hazardous combustion products May include and are not limited to: Oxides of sulphur. Hydrogen sulphide. Oxides of carbon. Hydrogen chloride. space Sensitivity to mechanical impact Explosion data Not available space Sensitivity to static discharge Not available space Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. . 6. Accidental Release Measures space Methods for containment Prevent entry into waterways, sewers, basements or confined areas. space Methods for cleaning up Should not be released into the environment. Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect material for proper disposal without raising dust. Rinse area with water. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. space Handling Use good industrial hygiene practices in handling this material. . 7. Handling and Storage space Storage Keep out of reach of children. Store in a closed container away from incompatible materials. space Page 2 of 7 #7840 22-Aug-2008 Issue date Page 433 of 495 Page 433 of 495 Page 433 of 495 Page 433 of 495 ---PAGE BREAK--- Exposure limits Ingredient(s) Citric acid Exposure Limits TWA: 10 mg/m3 ACGIH-TLV OSHA-PEL TWA: 10 mg/m3 Sodium bisulfite TWA: 5 mg/m3 ACGIH-TLV OSHA-PEL Not established Sodium carbonate Not established ACGIH-TLV OSHA-PEL Not established Sodium chloride Not established ACGIH-TLV OSHA-PEL Not established Sodium hydrosulfite Not established ACGIH-TLV OSHA-PEL Not established Sodium metabisulfite TWA: 5 mg/m3 ACGIH-TLV OSHA-PEL Not established . 8. Exposure Controls / Personal Protection space Engineering controls Use only under good ventilation conditions or with respiratory protection. space Eye / face protection Personal protective equipment Wear safety glasses with side shields. space Hand protection Rubber gloves. Confirm with a reputable supplier first. space Skin and body protection As required by employer code. space Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. space General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. space Appearance Powder . 9. Physical & Chemical Properties space Color White space Form Powder space Odor Characteristic space Odor threshold Not available space Physical state Solid space pH Not available space Melting point Not available space Freezing point Not available space Boiling point Not available space Flash point None space Evaporation rate Not available space Page 3 of 7 #7840 22-Aug-2008 Issue date Page 434 of 495 Page 434 of 495 Page 434 of 495 Page 434 of 495 ---PAGE BREAK--- Flammability limits in air, lower, % by volume Not applicable space Flammability limits in air, upper, % by volume Not applicable space Vapor pressure Not available space Vapor density Not available space Specific gravity Not available space Octanol/water coefficient Not available space Auto-ignition temperature Not available space Percent volatile Not available space Chemical stability Stable under recommended storage conditions. . 10. Chemical Stability & Reactivity Information space Conditions to avoid Do not mix with other chemicals. space Incompatible materials Acids. Oxidizers. space Hazardous decomposition products May include and are not limited to: Oxides of sulphur. Hydrogen sulphide. Oxides of carbon. Hydrogen chloride. space Possibility of hazardous reactions Hazardous polymerization does not occur. space Component analysis - LC50 Ingredient(s) Citric acid LC50 Not available Sodium bisulfite Not available Sodium carbonate 400 mg/m3 guinea pig Sodium chloride > 21000 mg/m3 rat Sodium hydrosulfite Not available Sodium metabisulfite Not available . 11. Toxicological Information space Component analysis - Oral LD50 Ingredient(s) Citric acid LD50 5040 mg/kg mouse; 3000 mg/kg rat Sodium bisulfite 1420 mg/kg rat Sodium carbonate 4090 mg/kg rat Sodium chloride 3000 mg/kg rat; 4000 mg/kg mouse Sodium hydrosulfite 2500 mg/kg rat Sodium metabisulfite 1131 mg/kg rat space Eye Effects of acute exposure Causes irritation. space Skin Causes irritation. space Inhalation Dusts of this product may cause irritation of the nose, throat, and respiratory tract. space Ingestion May cause stomach distress, nausea or vomiting. space Sensitization Hazardous by WHMIS/OSHA criteria. May cause sensitization by inhalation. space Chronic effects Not classified or listed by IARC, NTP, OSHA and ACGIH. space Page 4 of 7 #7840 22-Aug-2008 Issue date Page 435 of 495 Page 435 of 495 Page 435 of 495 Page 435 of 495 ---PAGE BREAK--- ACGIH - Threshold Limit Values - Carcinogens Sodium bisulfite 7631-90-5 A4 - Not Classifiable as a Human Carcinogen Sodium metabisulfite 7681-57-4 A4 - Not Classifiable as a Human Carcinogen IARC - Group 3 (Not Classifiable) Sodium bisulfite 7631-90-5 Monograph 54 [1992] (listed under Sulfur dioxide and some sulfites bisulfites and metabisulfites) Sodium metabisulfite 7681-57-4 Monograph 54 [1992] (listed under Sulfur dioxide and some sulfites bisulfites and metabisulfites) Carcinogenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Mutagenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Reproductive effects Not classified or listed by IARC, NTP, OSHA and ACGIH. space Teratogenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Ecotoxicity - Freshwater Algae Data Sodium carbonate 497-19-8 120 Hr EC50 242 mg/L Sodium hydrosulfite 7775-14-6 72 Hr EC50 Scenedesmus subspicatus: 120 mg/L; 96 Hr EC50 Scenedesmus subspicatus: 87 mg/L Sodium metabisulfite 7681-57-4 72 Hr EC50 Scenedesmus subspicatus: 48 mg/L; 96 Hr EC50 Scenedesmus subspicatus: 40 mg/L Ecotoxicity - Freshwater Fish Species Data Citric acid 77-92-9 96 Hr LC50 Lepomis macrochirus: 1516 mg/L [static]; 96 Hr LC50 Leuciscus idus: 440 mg/L [static] Sodium bisulfite 7631-90-5 96 Hr LC50 Gambusia affinis: 240 mg/L [static] Sodium carbonate 497-19-8 96 Hr LC50 Lepomis macrochirus: 300 mg/L [static] Sodium hydrosulfite 7775-14-6 96 Hr LC50 Leuciscus idus: 46-68 mg/L [static] Sodium metabisulfite 7681-57-4 96 Hr LC50 Lepomis macrochirus: 32 mg/L [static] Ecotoxicity - Microtox Data Citric acid 77-92-9 15 Min EC50 Photobacterium phosphoreum: 14 mg/L Sodium hydrosulfite 7775-14-6 17 Hr EC50 Pseudomonas putida: 107 mg/L Sodium metabisulfite 7681-57-4 17 Hr EC50 Pseudomonas putida: 56 mg/L Ecotoxicity - Water Flea Data Citric acid 77-92-9 72 Hr EC50 Daphnia magna: 120 mg/L Sodium bisulfite 7631-90-5 48 Hr EC50 Daphnia magna: 119 mg/L Sodium carbonate 497-19-8 48 Hr EC50 Daphnia magna: 265 mg/L Sodium hydrosulfite 7775-14-6 48 Hr EC50 Daphnia magna Straus: 98 mg/L Sodium metabisulfite 7681-57-4 24 Hr EC50 Daphnia magna Straus: 89 mg/L Ecotoxicity Not available . 12. Ecological Information space Environmental effects Not available space Aquatic toxicity Not available space Persistence / degradability Not available space Bioaccumulation / accumulation Not available space Partition coefficient Not available space Mobility in environmental media Not available space Chemical fate information Not available space Waste codes Not available . 13. Disposal Considerations space Disposal instructions Review federal, provincial, and local government requirements prior to disposal. space Waste from residues / unused products Not available space Contaminated packaging Not available space U.S. Department of Transportation (DOT) Not regulated as dangerous goods. . 14. Transport Information space Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. space Page 5 of 7 #7840 22-Aug-2008 Issue date Page 436 of 495 Page 436 of 495 Page 436 of 495 Page 436 of 495 ---PAGE BREAK--- Canada - WHMIS - Ingredient Disclosure List Citric acid 77-92-9 1 % Sodium bisulfite 7631-90-5 1 % Sodium carbonate 497-19-8 1 % Sodium metabisulfite 7681-57-4 1 % Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. . 15. Regulatory Information space U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities Sodium bisulfite 7631-90-5 5000 Lb final RQ; 2270 kg final RQ US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. space 29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA) Yes space CERCLA (Superfund) reportable quantity Sodium bisulfite: 5000.0000 Sodium tripolyphosphate: 5000.0000 Metaphosphoric acid, trisodium salt: 5000.0000 space Hazard categories Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes space Section 302 extremely hazardous substance No space Section 311 hazardous chemical Yes space Clean Air Act (CAA) Not available space Clean Water Act (CWA) Not available space Safe Drinking Water Act (SDWA) Not available space Drug Enforcement Agency (DEA) Not available space Food and Drug Administration (FDA) Not available space WHMIS status Controlled space WHMIS classification Class D - Division 2A, 2B space WHMIS labeling space Page 6 of 7 #7840 22-Aug-2008 Issue date Page 437 of 495 Page 437 of 495 Page 437 of 495 Page 437 of 495 ---PAGE BREAK--- U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances Sodium bisulfite 7631-90-5 Present Sodium metabisulfite 7681-57-4 Present U.S. - Louisiana - Reportable Quantity List for Pollutants Sodium bisulfite 7631-90-5 5000 Lb final RQ; 2270 kg final RQ U.S. - Massachusetts - Right To Know List Sodium bisulfite 7631-90-5 Present Sodium hydrosulfite 7775-14-6 Present Sodium metabisulfite 7681-57-4 Present U.S. - Minnesota - Hazardous Substance List Sodium bisulfite 7631-90-5 Present Sodium metabisulfite 7681-57-4 Present U.S. - New Jersey - Right to Know Hazardous Substance List Sodium bisulfite 7631-90-5 sn 1685 Sodium hydrosulfite 7775-14-6 sn 1697 Sodium metabisulfite 7681-57-4 sn 1708 U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances Sodium bisulfite 7631-90-5 5000 Lb RQ (air); 100 lb RQ (land/water) U.S. - - RTK (Right to Know) List Sodium bisulfite 7631-90-5 Environmental hazard Sodium hydrosulfite 7775-14-6 Present Sodium metabisulfite 7681-57-4 Present U.S. - Rhode Island - Hazardous Substance List Sodium bisulfite 7631-90-5 Toxic Sodium hydrosulfite 7775-14-6 Flammable Sodium metabisulfite 7681-57-4 Toxic State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. space A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada No Non-Domestic Substances List (NDSL) United States & Puerto Rico Yes Toxic Substances Control Act (TSCA) Inventory space Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. . 16. Other Information space Issue date 22-Aug-2008 space Effective date 15-Aug-2008 space Expiry date 15-Aug-2011 space Prepared by Dell Tech Laboratories Ltd. (519) 858-5021 space Page 7 of 7 #7840 22-Aug-2008 Issue date Page 438 of 495 Page 438 of 495 Page 438 of 495 Page 438 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET TANGLEFOOT® TREE PRUNING SEALER - AEROSOL Emergency Phone: [PHONE REDACTED] The Tanglefoot Company Grand Rapids MI 49504 Date of Preparation: 03/01/09 The Tanglefoot Company FORMULA 10/12/06 SECTION I: IDENTIFICATION MANUFACTURER: THE TANGLEFOOT COMPANY PHONE: 616/459-4139 314 STRAIGHT ST. SW FAX: 616/459-4140 GRAND RAPIDS, MI 49504 E-MAIL: [EMAIL REDACTED] TRADE NAME: Tanglefoot® Tree Pruning Sealer Aerosol HAZARD CLASSIFICATION: HEALTH 1 FIRE 2 REACTIVITY 0 SECTION II: HAZARDOUS INGREDIENTS WT / WT % Hazardous components (Specific Chemical Identity; Common Names(s) OSHA PEL OSHA STEL Less than Formula (9/06) Asphalt CAS # 8052-42-4 N.E. N.E. 15 % PROPANE/ISOBUTENE/N-BUTENE CAS # 68476-86-8 N.E. N.E. 20 % CALCIUM CARBONATE CAS # 1317-65-3 15 MG/M3 N.E. 10 % STODDARD SOLVENT CAS # 8052-41-3 100 PPM N.E. 10 % CAS # 1330-20-7 100 PPM N.E. 10% CAS # 100-41-4 100 PPM N.E. 5 % SECTION III; PHYSICAL DATA BOILING POINT: NA SPECIFIC GRAVITY: 0.8876 VAPOR PRESSURE(MM Hg): 55-70 FLASH POINT: Propellent < 0o F (-18 o C) VAPOR DENSITY (AIR = Is heavier than air EVAPORATION RATE: Faster than Butyl FREEZE POINT 32 o F (32 o C) Acetate SOLUBILITY IN WATER: Partial VISCOSITY: Not Determined APPEARANCE AND ODOR: DK Brown Petroleum SECTION IV: FIRE AND EXPLOSION HAZARD DATA GENERAL HAZARD: Low hazard FLASH POINT: Propellent < 0o F (-18 o C) FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: Foam, Water fog, Carbon Dioxide, Dry Chemical. SPECIAL FIRE FIGHTING PROCEDURES: Containers can build pressure if heated. Keep containers cool. Use equipment breathing apparatus & shielding to protect fire fighting personnel against bursting, rupturing or venting containers. UNUSUAL FIRE & EXPLOSION HAZARDS: At elevated temperatures (over 54oC/130oF), containers may vent, rupture or burst. SECTION V: HEALTH HAZARD DATA & EMERGENCY FIRST AID PROCEDURES ROUTES OF ENTRY: Eyes: Yes SKIN: Yes INHALATION: Yes INGESTION: Yes EYES: Effect: May cause eye irritation. First Aid: Flush with large amounts of water until irritation subsides. If irritation continues seek medical attention. Protection: None required; however, use of eye protection is good practice. Page 1 of 2 Page 439 of 495 Page 439 of 495 Page 439 of 495 Page 439 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET TANGLEFOOT® TREE PRUNING SEALER - AEROSOL Emergency Phone: [PHONE REDACTED] The Tanglefoot Company Grand Rapids MI 49504 Date of Preparation: 03/01/09 The Tanglefoot Company SECTION V: HEALTH HAZARD DATA & EMERGENCY FIRST AID PROCEDURES (continued) SKIN: Effect: May cause skin irritation. First Aid: Wash skin with soap and water Protection: None required; however, use of protective gloves/clothing is good practice INHALATION: Effect: No significant health hazards however should avoid breathing vapors. First Aid: If adverse effects occur, remove to ventilated area. Protection: None required; however, use of adequate ventilation is recommended. INGESTION: Effect: (Swallowing) Harmful or fatal if swallowed. First Aid: If swallowed get medical attention immediately. SECTION VI: REACTIVITY DATA STABILITY: Stable CONDITIONS TO AVOID: Ignition sources, Welding Arcs, Temperatures above 1300F HAZARDOUS DECOMPOSITION PRODUCTS. N/A HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. SECTION VII: SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED OR RELEASED: Avoid breathing vapors. Remove ignition sources. Avoid skin contact with liquid. WASTE DISPOSAL METHOD: Do not puncture or incinerate container. Absorb spill with inert material (ex. dry sand, earth ) along with leaking containers to a facility qualified to dispose of pressured containers. SECTION VIII: REGULATORY INFORMATION OSHA Hazard Communication Standard: Irritant. Contains a component listed by OSHA. SARA Title III Section 302 Extremely Hazardous Substances (40 CFR Part 355) This product is exempt from the reporting requirements of this section. SARA Title III Section 311/312 Hazardous Categorization (40 CFR Part 370) This product is defined as hazardous by OSHA under 29 CFR Part 1910.1200(d). SARA Title III Section 313 (40 CFR Part 372) This product is exempt from the reporting requirements of this section. CERCLA Sections 102A/103 Hazardous Substances (40 CFR Part 302.4) This product is exempt from the CERCLA reporting requirements under 40 CFR Part 302.4. Ingredients listed by NTP, OSHA or LARC as Carcinogens or potential carcinogens: NONE SECTION IX: SHIPPING INFORMATION DOT CLASSIFICATION: CONSUMER COMMODITY, ORM-D BILL OF LADING DESCRIPTION: Asphalt By products, in containers in boxes. NMFC 15220 class 55 IMDG: Aerosols (max. 1 liter). Hazard Class 2 UN-1950 IATA: Aerosols, Flammable (each not exceeding 1 liter Capacity) Hazard class 2.1 UN-1950 SECTION X: DISCLAIMER AND/OR COMMENTS This information in this MSDS was obtained from sources we believe are reliable. However, the information is provided without any representation or warranty, expressed or implied, regarding its accuracy or corrections. The conditions of handling storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use of disposal of the product. Page 2 of 2 Page 440 of 495 Page 440 of 495 Page 440 of 495 Page 440 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 04-Feb-2011 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19901 Product name Tef-Coat Lube Recommended Use Lubricant Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Pre-existing skin conditions may be aggravated by exposure to this product. Principal Routes of Exposure Eyes. Skin contact. Skin absorption. Inhalation. Ingestion. Potential health effects Eyes May cause the following effects:. Moderately irritating to the eyes. Severe irritation. Severity depends on degree of exposure. Skin May cause the following effects: . Skin Irritation. Repeated or prolonged exposure may cause:. Defatting. Dermatitis. Chronic exposure causes drying effect on the skin . Inhalation Harmful by inhalation. Repeated or prolonged exposure may cause the following effects. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. May cause irritation of the nose and throat. May cause irritation to the lungs. Central nervous system depression. Confusion. Loss of coordination. Light headedness. Weakness. Possible cardiac Drowsiness . Kidney damage. Lung damage. Liver damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion No hazard under normal industrial and institutional use. Harmful or fatal if swallowed. Aspiration hazard. May cause severe lung damage if aspirated into the lungs from ingestion or vomiting. Central nervous system damage. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane/Isobutane/N- Butane 68476-86-8 50-60 Hexane 64742-49-0 20-30 2-Propanone 67-64-1 10-20 100-41-4 0.1-1 Xylenes p- isomers) 1330-20-7 1-10 Toluene 108-88-3 0.0 Benzene 71-43-2 0.0 4. FIRST AID MEASURES Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do not induce vomiting. Call a physician immediately. Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES Flash point °C -96 Flash point °F -141 Method Seta closed cup Autoignition temperature °C Not Applicable Autoignition temperature °F Not Applicable Flammability Limits in Air) Upper 12.8 Lower 1.0 Suitable extinguishing media Water fog. Dry chemical. Carbon dioxide (CO2). Alcohol foam. Foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Extremely flammable. Vapors may cause flash fire or explosion. Contents under pressure. Harmful by inhalation. Aspiration hazard. May enter lungs and cause damage. May cause eye/skin irritation. Harmful or fatal if swallowed. Page 441 of 495 Page 441 of 495 Page 441 of 495 Page 441 of 495 ---PAGE BREAK--- Fire and Explosion Hazards Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Flash back possible over considerable distance. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect leaking liquid in sealable containers. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Keep in a well- ventilated place. Avoid breathing vapors. Avoid contact with skin, eyes and clothing. Avoid using sparking tools. Containers can contain residues. Keep container closed when not in use. Do not puncture or incinerate. Keep out of reach of children. Storage Keep away from open flames, hot surfaces and sources of ignition. Do not freeze. Store in temperatures below 120 degrees F. Keep away from direct sunlight. NFPA Storage Code Store as Level 3 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane/Isob utane/N- Butane - - - N/D Hexane - - - - 2-Propanone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Xylenes p- isomers) 100 ppm 435 mg/m3 - 100 ppm 150 ppm 100 ppm 435 mg/m3 - 100 ppm 125 ppm Toluene 200 ppm 300 ppm 20 ppm - Benzene 1 ppm 10 ppm applies to industry segments exempt from the benzene standard at 29 CFR 1910.1028 25 ppm applies to industry segments exempt from the 1 ppm TWA and 5 ppm STEL of the benzene standard 0.5 ppm 2.5 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use with adequate explosion-proof ventilation to meet the limits in Section 8 . Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re- use. Handle in accordance with good industrial hygiene and safety practice. Respiratory protection Follow OSHA respirator regulations (29 CFR 1910.134) and if necessary, wear a MSHA/NIOSH approved respirator. Seek professional advise prior to respirator selection and use. Hand Protection Impervious gloves. Eye protection Use safety eyewear designed to protect against splash of liquids. Skin and body protection Wear appropriate clothing to minimize skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Cloudy White Odor Solvent Odor Threshold Not Applicable pH Not Applicable Specific Gravity 0.6551 Vapor pressure No data available Vapor density >Air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Negligible VOC Content 76.02%; 3.59 lbs/gal; 430 g/L Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C -41 - 175 Boiling point/range °F -24 - 284 Melting point/range °C No data available Melting point/range °F No data available Flash point °C -96 Flash point °F -141 10. STABILITY AND REACTIVITY Page 2 / 4 Product code 19901 Product name Tef-Coat Lube Page 442 of 495 Page 442 of 495 Page 442 of 495 Page 442 of 495 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Contact with ignition sources, hot-glowing surfaces, electrical arcs, sparks, and open flame. Do not store in temperatures above 120 degrees F. Avoid direct sunlight. Incompatability Oxygen. Strong oxidizing agents. Chlorates. Nitrates. Peroxides. Strong oxidizers. Hazardous Decomposition Products Acrid fumes. Carbon oxides. Halogens. Polymerization None under normal processing. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbi t) LC50 (inhalation,rat) Propane/Isobutan e/N-Butane 68476-86-8 - - - Hexane 64742-49-0 5000 mg/kg 3160 mg/kg 73680 ppm 2-Propanone 67-64-1 5800 mg/kg - - Xylenes p- isomers) 1330-20-7 4300 mg/kg 1700 mg/kg 47635 mg/L 5000 ppm 100-41-4 3500 mg/kg 15354 mg/kg 17.2 mg/L Toluene 108-88-3 636 mg/kg 12124 mg/kg 8390 mg/kg 12.5 mg/L 26700 ppm Benzene 71-43-2 1800 mg/kg - 13050 - 14380 ppm Synergistic Products None known Specific Hazards Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Potential health effects Sensitization None known . Chronic toxicity See Section 2 . Mutagenic effects None known . Teratogenic effects None known . Reproductive toxicity None known . Target Organ Effects See Section 2. Other adverse effects This product contains trace amounts of benzene which presents a carcinogenic risk to humans based upon the evaluation of the IARC WORKING GROUP . Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed Hexane Not Listed Not Listed Not Listed Not Listed Not Listed 2-Propanone Listed Not Listed Not Listed Not Listed Not Listed Xylenes p- isomers) Listed Not Listed Not Listed Not Listed Not Listed Listed Group 2B Not Listed Not Listed Listed Toluene Listed Not Listed Not Listed Not Listed Not Listed Benzene Listed Group 1 Listed Not Listed Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Do not let product enter drains Harmful to aquatic organisms Page 3 / 4 Water Flea Data Daphnia magna hEC50 48 (1.8 - 2.4 mg/L) 2-Propanone Toluene Xylenes p- isomers) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Product code 19901 Water Flea Data water flea hEC50 48 (11.3 mg/L) water flea hEC50 48 (310 mg/L) Daphnia magna hEC50 48 (11.3 mg/L) water flea hEC50 48 (11.3 mg/L) Microtox Data Photobacterium phosphoreum EC50=0.0084 mg/L (24 h) Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data water flea hEC50 48 (3.82 mg/L) Gammarus lacustris hLC50 48 (0.6 mg/L) water flea hEC50 48 (3.82 mg/L) Product name Tef-Coat Lube Microtox Data Photobacterium phosphoreum EC50=9.68 mg/L (30 min) Nitrosomonas EC50=96 mg/L (24 h) Water Flea Data water flea hEC50 48 (0.0039 mg/L) water flea hEC50 48 (12700 mg/L) Daphnia magna hEC50 48 (12600 mg/L) water flea hEC50 48 (0.0039 mg/L) Page 443 of 495 Page 443 of 495 Page 443 of 495 Page 443 of 495 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. Do not puncture or incinerate. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D TDG Consumer commodity, ORM-D 15. REGULATORY INFORMATION US EPA SARA 313 Chemical Name US EPA SARA 313 Emission Reporting Xylenes p- isomers) Listed Listed Toluene Listed Benzene Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed Hexane Not Listed Not Listed Not Listed 2-Propanone Not Listed Listed Not Listed Xylenes p- isomers) Listed Listed Not Listed Not Listed Listed Carcinogen Toluene Listed Listed Development al Benzene Listed Listed Carcinogen Development al Male Reproductive Chemical Name Type Benzene - 71-43-2 Male Reproductive WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane/Isobutane/N- Butane X X - X Hexane X X - X 2-Propanone X X - X Xylenes p- isomers) X X - X X X - X Toluene X X - X Benzene X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 2 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name Tef-Coat Lube Product code 19901 Page 444 of 495 Page 444 of 495 Page 444 of 495 Page 444 of 495 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 17-Sep-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 97673 Product name Tefgel Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin contact. Skin absorption. Inhalation. Ingestion. Potential health effects Eyes May cause the following effects:. Irritation. Skin Skin Irritation. Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Defatting. Repeated exposure may cause skin dryness or cracking. Inhalation Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion Not likely to occur. May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Hexane 110-54-3 40-70 Olefin Polymer Proprietary 10-30 Propane 74-98-6 10-30 Paraffinic Mineral Oil 8042-47-5 3-7 4. FIRST AID MEASURES General advice Show this safety data sheet to the doctor in attendance. Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. If skin irritation persists, call a physician. Ingestion Do not induce vomiting. Contact physician or poison control center immediately. Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES Flash point °C -104°C Flash point °F -156°F Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5 Lower 1.2 Suitable extinguishing media Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special Fire-Fighting Procedures Water spray may be ineffective. If water is used, fog nozzles are preferable . Fire and Explosion Hazards Containers can build up pressure if exposed to heat (fire). Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Page 1 / 4 Emergency Overview Extremely flammable. Vapors may cause flash fire or explosion. Contents under pressure. May cause eye/skin irritation. May cause irritation of respiratory tract. Page 445 of 495 Page 445 of 495 Page 445 of 495 Page 445 of 495 ---PAGE BREAK--- Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Avoid breathing of vapors. Ensure adequate ventilation. Use personal protective equipment. Remove all sources of ignition. Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Soak up with noncombustible inert absorbent material. Place in non- leaking, sealed container for proper disposal. 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate. Do not stick pin, nail, or any other sharp object into opening on top of can. Thoroughly wash hands and exposed skin after handling. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Use only according to label directions. Handle empty containers as if they were full. Storage Keep out of the reach of children. Keep away from heat. Keep away from open flames, hot surfaces and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . NFPA Storage Code Store as Level 3 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Hexane 500 ppm 1800 mg/m3 - 50 ppm N/D Paraffinic Mineral Oil - - - - Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Olefin Polymer - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Seek professional advise prior to respirator selection and use. Hand Protection Chemical resistant gloves. Eye protection Safety glasses with side-shields. Skin and body protection Wear appropriate clothing to prevent skin contact. Impervious clothing. Rubber or plastic boots. Apron. Coveralls. Other Protective Equipment A safety shower and eye wash station should be available for emergency use. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Amber Odor Solvent Odor Threshold No information available pH No data available Specific Gravity 0.67 Vapor pressure 80-90 Vapor density heavier than air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Negligible VOC Content 79% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F -44°F - 611°F Melting point/range °C No data available Melting point/range °F No data available Flash point °C -104°C Flash point °F -156°F 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Conditions to avoid Avoid sources of ignition. Incompatability Strong oxidizing agents. Strong bases. Hazardous Decomposition Products Carbon oxides. Fumes. Page 2 / 4 Product name Tefgel Product code 97673 Page 446 of 495 Page 446 of 495 Page 446 of 495 Page 446 of 495 ---PAGE BREAK--- Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Hexane 110-54-3 - 3000 mg/kg 48000 ppm Paraffinic Mineral Oil 8042-47-5 5000 mg/kg - - Propane 74-98-6 - - 658 mg/L Olefin Polymer Proprietary - - - Synergistic Products None known Specific Hazards Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Central nervous system. Eyes. Peripheral nervous system. Respiratory system. Skin. Carcinogenic effects None known . Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Hexane Not Listed Not Listed Not Listed Not Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Olefin Polymer Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Full or partially full containers are considered hazardous waste. Emptied container retains product residue. Do not reuse container. Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT May be classed as Consumer Commodity, ORM-D, UN1950, AEROSOLS, 2.1 LIMITED QUANTITY TDG May be classed as Consumer Commodity, ORM-D, UN1950, AEROSOLS, 2.1 LIMITED QUANTITY 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Hexane Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Hexane Listed Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed Propane Listed Listed Not Listed Olefin Polymer Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Hexane X X - X Paraffinic Mineral Oil X X - X Propane X X - X Olefin Polymer - - - - CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Page 3 / 4 Product code 97673 Product name Tefgel Page 447 of 495 Page 447 of 495 Page 447 of 495 Page 447 of 495 ---PAGE BREAK--- 16. OTHER INFORMATION Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name Tefgel Product code 97673 Page 448 of 495 Page 448 of 495 Page 448 of 495 Page 448 of 495 ---PAGE BREAK--- - 1 - UNITED 101 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 101 MOISTURE BARRIER Moisture Barrier and Electrical Lubricant February 6, 2015 HMIS III HEALTH (0 = Maximum Safety) 1 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Food grade mineral oil 8042-47-5 40-70 5 mg/m3 5 mg/m3 NE NE 556-67-2 1-5 10 ppm* NE NE NE Dipropylene glycol monomethyl ether 34590-94-8 1-5 100 ppm (Skin) 100 ppm (Skin) NE NE 541-02-6 1-5 10 ppm* NE NE NE Carbon dioxide 124-38-9 1-5 5000 ppm 5000 ppm NE NE * Manufacturer’s recommended TWA exposure limit. 3. HAZARDS IDENTIFICATION Eyes: May cause slight irritation; does not injure eye tissue. Skin: Prolonged or repeated contact may cause moderate irritation. Inhalation: Exposure to massive amount of vapors may cause dizziness, drowsiness, throat irritation, unconsciousness and CNS effects. Ingestion: May cause upset stomach, nausea, vomiting, and diarrhea. Possible aspiration hazard may cause inflammation of the lungs. 4. FIRST AID MEASURES Eyes: Flush with large amounts of cool running water for at least 15 minutes while holding upper and lower lids open. If irritation persists call a physician. Skin: Wash with soap and water. If irritation persists call a physician. Inhalation: Remove to fresh air immediately. Apply artificial respiration if needed. Call a physician immediately. Ingestion: DO NOT induce vomiting. Call a physician immediately. Aspiration may cause chemical pneumonitis. 5. FIRE FIGHTING MEASURES Flash Point (TOC) : >200°F/93.3°C Explosive Limits: Lower (LEL): NE Upper (UEL): NE Flame Projection (Aerosol): Non- flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of carbon. Fire and Explosion Hazards: Aerosol container (pressurized) may burst if heated over 120°F/48°C. Extinguishing Media: Foam, Dry chemical, Carbon dioxide. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing in chemical fires. Cool fire exposed containers with water to prevent pressure build up. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.com [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: B Page 449 of 495 Page 449 of 495 Page 449 of 495 Page 449 of 495 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly. 7. HANDLING AND STORAGE Keep away from heat, sparks, and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Store as NFPA Code 30B Rating: Level 1 Aerosol. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses or chemical splash goggles are recommended. Skin: Chemical resistant gloves are recommended. Respiratory: Not normally required. If vapor concentration exceeds TLV, use a NIOSH or MSHA approved respirator. Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 500°F/260°C Specific Gravity: 0.840 (H2O=1) Vapor Pressure: 68 psig Melting Point: ND Vapor Density: > 1 (air=1) Evaporation Rate: ND Solubility in Water: Slight pH: N/A Appearance and Odor: Aerosol; Brown liquid with solvent scent. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce oxides of carbon. Chemical Stability: Stable Incompatibility: Oxidizing agents such as bleach. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? None 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): 3.34% TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: None SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 101 MOISTURE BARRIER PREPARED BY: TechDept.AD Page 450 of 495 Page 450 of 495 Page 450 of 495 Page 450 of 495 ---PAGE BREAK--- UNITED 107 320 37th Avenue, St. Charles, Illinois 60174 • 214 Dolomite Drive, Downsview, Ontario M3J2N2 To Reorder Call: www.unitedlabsinc.com [PHONE REDACTED] MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 107 AEROSOL SAFETY SOLVENT Multi Purpose Cleaner August 18, 2008 HEALTH (0 = Maximum Safety) 2 REACTIVITY (0 = Maximum Safety) 0 Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 Always follow Label Directions and Cautions. 4 Extreme 3 High 2 Moderate 1 Slight 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. FLAMMABILITY (0 = Maximum Safety) 1 - 1 - Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: O 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Trichloroethylene 79-01-6 >90 50 ppm NE NE NE Carbon Dioxide 124-38-9 3-5 5000 ppm 5000 ppm NE NE ACGIH (STEL) Trichloroethylene CAS#79-01-6 100 ppm, Carbon Dioxide CAS #124-38-9 30,000 ppm 3. HAZARDS IDENTIFICATION Eyes: May cause slight irritation. Skin: May cause irritation. Prolonged or repeated contact can result in defatting and drying of the skin, irritation and dermatitis. Inhalation: Intentional misuse by inhaling the product can be harmful or fatal. High concentrations or prolonged exposure to lower concentrations may be irritating to mucous membranes. Ingestion: Exposure by ingestion of an aerosol is unlikely. May cause delayed lung damage. Components of the product may be absorbed into the body by ingestion. 4. FIRST AID MEASURES Eyes: Flush with plenty of water for at least 15 minutes. If irritation persists call a physician or poison center. Skin: Wash with soap and water and remove any contaminated clothing. If irritation persists, call a physician. Inhalation: Remove to fresh air immediately and apply CPR as needed. Call a physician or poison center immediately. Ingestion: Have victim rinse mouth thorougly with water. DO NOT induce vomiting. Call a physician or poison center immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): Not flammable & not combustible by OSHA Explosive Limits: Lower (LEL): 7.3 Upper (UEL): 36.0 Flame Projection (Aerosol): Non-flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: When strongly heated, as in a fire, may produce oxides of carbon, phosgene, hydrogen chloride, vapors and other toxic chemicals. Fire and Explosion Hazards: Exposure to temperature above 130°F/ 54.4°C may cause container to burst, rupture, or vent. Containers should be cooled with water to prevent vapor pressure build up. Extinguishing Media: Water, Water fog, Foam, Dry chemical, Carbon dioxide. Fire Fighting Instructions: Wear self-contained breathing apparatus and protective clothing. Cool fire exposed containers to prevent rupturing. Page 451 of 495 Page 451 of 495 Page 451 of 495 Page 451 of 495 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. After removal flush contaminated area thoroughly with water. Large Spills: Ventilate area and remove all sources of ignition. Cover with absorbent material and place in a disposal container. Clean contaminated surface thoroughly. Prevent entry into waterways, sewers 7. HANDLING AND STORAGE Store in a cool, dry place away from heat, sparks or open flame. Do not store at temperatures above 49°C/ 120°F. Keep out of sunlight. Contents under pressure. Do not puncture, incinerate or crush. For Industrial and Institutional use only. NFPA Code 30B Rating: Level 1 Aerosol. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Chemical safety googles are recommended. Skin: Chemical resistant gloves are recommended. Respiratory: None needed for proper use in accordance with label directions. If recommended exposure limits are exceeded wear a NIOSH approved respirator with mechanical filter/organic vapor cartridge. Engineering Controls: Insure adequate ventilation, especially in confined areas. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 186.8°F/ 86.1°C Specific Gravity: 1.5 (H2O=1) Vapor Pressure: 75-85 psig@70°F Melting Point: Concentrate -86°C Vapor Density: > 1 Evaporation Rate: < 1 Solubility in Water: Negligible pH: NA Appearance and Odor: Aerosol, clear, colorless, liquid with ether-like odor. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: Material decomposed by fire may produce oxides of carbon, phosgene, hydrogen chloride, vapors and other toxic chemicals. Chemical Stability: Stable Incompatibility: Oxidizing agents, heat, flames and sparks. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): Trichloroethylene CAS# 79-01-6 California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? Yes – Trichloroethylene CAS# 79-01--6 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC(Volatile Organic Compounds): 96.60 % TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: No SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: Trichloroethylene CAS# 79-01-6 (0.97 lb)* * Pounds of reportable material per can of UNITED product. WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 107 AEROSOL SAFETY SOLVENT PREPARED BY: Sandy Kopacz Page 452 of 495 Page 452 of 495 Page 452 of 495 Page 452 of 495 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: UNITED 107 AEROSOL SAFETY SOLVENT CAS Number: Manufacturer: United Laboratories Inc. SDS Date: 6/3/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=SyoR1zpP2E8%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 453 of 495 Page 453 of 495 Page 453 of 495 Page 453 of 495 ---PAGE BREAK--- - 1 - UNITED 107 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 107 AEROSOL SAFETY SOLVENT Multi Purpose Cleaner February 21, 2012 HMIS III HEALTH (0 = Maximum Safety) *2 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 2 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Trichloroethylene 79-01-6 > 90 10 ppm 100 ppm NE NE Carbon Dioxide 124-38-9 3 - 5 5,000 ppm 5,000 ppm NE NE ACGIH (STEL) Trichloroethylene CAS#79-01-6 25 ppm, Carbon Dioxide CAS #124-38-9 30,000 ppm 3. HAZARDS IDENTIFICATION Eyes: May cause slight irritation. Skin: May cause irritation. Prolonged or repeated contact can result in defatting and drying of the skin, irritation and dermatitis. Inhalation: Intentional misuse by inhaling the product can be harmful or fatal. High concentrations or prolonged exposure to lower concentrations may be irritating to mucous membranes. Ingestion: Exposure by ingestion of an aerosol is unlikely. May cause delayed lung damage. Components of the product may be absorbed into the body by ingestion. Chronic Effects: May cause central nervous system disorder and/or damage. May cause delayed lung damage. Prolonged skin contact may defat the skin and produce dermatitis. 4. FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops or persists. Skin: Wash off with warm water and soap. Get medical attention if irritation develops or persists. Inhalation: Move to fresh air. Oxgen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled to substance. Call a physician if develop or persist. Ingestion: If material is ingested, immediately contact a poison control center. Rinse mouth. Do not induce vomiting without advice from poiso control center. If vomiting occurs naturally, have vixtim lean forward to reduce risk of aspiration. 5. FIRE FIGHTING MEASURES Flash Point (TCC): Not flammable & not combustible by OSHA Explosive Limits: Lower (LEL): 7.3 Upper (UEL): 36.0 Flame Projection (Aerosol): Non-flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: Material decomposed by fire may produce irritating, corrosive and/or toxic gases. Fire and Explosion Hazards: Exposure to temperature above 130°F/ 54.4°C may cause container to burst, rupture, or vent. Containers should be cooled with water to prevent vapor pressure build up. Runoff to sewer may cause fire or explosion hazard. Extinguishing Media: Water, Water fog, Foam, Dry chemical, Carbon dioxide. Fire Fighting Instructions: Wear self-contained breathing apparatus and protective clothing. Cool fire exposed containers to prevent rupturing. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: X Consult Supervisor Page 454 of 495 Page 454 of 495 Page 454 of 495 Page 454 of 495 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. After removal flush contaminated area thoroughly with water. Large Spills: Ventilate area and remove all sources of ignition. Cover with absorbent material like vermiculite, sand or earth to soak up product and place in a disposal container. Clean contaminated surface thoroughly. Prevent entry into waterways, sewers or confined spaces. 7. HANDLING AND STORAGE Store in a cool, dry place away from heat, sparks or open flame. Do not store at temperatures above 49°C/ 120°F. Keep out of sunlight. Contents under pressure. Do not puncture, incinerate or crush. For Industrial and Institutional use only. NFPA Code 30B Rating: Level 1 Aerosol. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Chemical safety googles are recommended. Skin: Chemical resistant gloves are recommended. Wear appropriate chemical resistant clothing. Respiratory: None needed for proper use in accordance with label directions. If recommended exposure limits are exceeded wear a NIOSH approved respirator with mechanical filter/organic vapor cartridge. Engineering Controls: Insure adequate ventilation, especially in confined areas. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 186.8°F/ 86.1°C Specific Gravity: 1.47 (H2O=1) Vapor Pressure: 72-91 psig@70°F Melting Point: Concentrate -86°C Vapor Density: > 1 Evaporation Rate: ND Solubility in Water: Negligible pH: NA Appearance and Odor: Aerosol, clear, colorless, liquid with ether-like odor. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: Material decomposed by fire may produce irritating and/or toxic gases. Chemical Stability: Stable Incompatibility: Oxidizing agents, heat, flames and sparks. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): Trichloroethylene CAS# 79-01-6 California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? Yes – Trichloroethylene CAS# 79-01--6 12. ECOLOGICAL INFORMATION Components of this product are hazardous to aquatic life. 13. DISPOSAL CONSIDERATIONS Consult your local, state and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. Waste codes: D040: Waste Trichloroethylene 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): 96.60 % TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: No SARA Title III Section 311/312: Yes SARA Title III Section 313 Toxic Chemicals: Trichloroethylene CAS# 79-01-6 (0.97 lb.)* * Pounds of reportable material per can of UNITED product. WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 107 AEROSOL SAFETY SOLVENT PREPARED BY: Sandy Kopacz Page 455 of 495 Page 455 of 495 Page 455 of 495 Page 455 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 320 37th Avenue • St. Charles, Illinois 60174 • To Reorder, Call [PHONE REDACTED] PRODUCT IDENTIFICATION USE / DESCRIPTION REVISION DATE FOR MEDICAL AND UNITED 125 Waterproof Adhesive Spray September 19, 2002 TRANSPORTATION EMERGENCIES: ALL STIK INFOTRAC: [PHONE REDACTED] HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety) Always follow Label Directions and Cautions. Susceptible to Release of Energy. 4 Extreme. 3 High. 2 Moderate. 1 Slight. 0 Minimal. See Health Hazard Data Section of this M.S.D.S. for more detailed information. FLAMMABILITY (0 = Maximum Safety) Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated to burn. 3 Ignites at normal temperature. 0 Will not burn. 2 Ignites when moderately heated. HAZARDOUS CAS ACGIH ACGIH OSHA OTHER S.A.R.A. TITLE III COMPONENTS NUMBER TWA STEL PEL RECOMMENDED LIMITS QUANTITIES Acetone 67-64-1 500 ppm 750 ppm 1000 ppm NIOSH TWA None 1188 mg/m3 1782 mg/m3 2400 mg/m3 250 ppm 590mg/m3 Hexane 110-54-3 Skin: 50 ppm 500 ppm 500 ppm NIOSH TWA 0.184* 176 mg/m3 1800 mg/m3 1800 mg/m3 50 ppm 180mg/m3 n-Butane 106-97-8 800 ppm Not Not NIOSH TWA None 1900 mg/m3 established established 800 ppm 1900 mg/m3 Propane 74-98-6 2500 ppm Not 1000 ppm NIOSH TWA None 4508 mg/m3 established 1800mg/m3 1000 ppm 1800 mg/m3 * Pounds of reportable material per can of United product. BOILING POINT SPECIFIC GRAVITY (H20 = 1) Not determined 0.6717 VAPOR PRESSURE (Psig) MELTING POINT (At 70° F) 117 Psig Not determined VAPOR DENSITY (Air = 1) EVAPORATION RATE Not determined (Butyl Acetate = 1) Not determined SOLUBILITY IN WATER VOLATILE ORGANIC COMPOUNDS None (Pounds Per Can Of Product) 0.56 APPEARANCE AND ODOR pH: Aerosol spray with characteristic odor Not applicable FLASH POINT (Method Used) FLAMMABLE LIMITS LEL UEL Flammable as per USA flame projection test 16 CFR 1500.3 and 1500.45 Propellant 1.9% 9.5% EXTINGUISHING MEDIA Foam, dry chemical, carbon dioxide, water SPECIAL FIRE FIGHTING PROCEDURES Use water fog to cool containers to prevent rupturing and exploding containers. Provide shielding for personnel. Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS Do not expose aerosols to temperatures above 130° F or the container may burst. 4 May detonate-vacate area if 2 Violent chemical change Materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. PERSONAL PROTECTION Recommended UNITED 125 HAZARDOUS COMPONENTS IDENTITY, EXPOSURE LIMITS AND S.A.R.A. TITLE III INFORMATION PHYSICAL / CHEMICAL CHARACTERISTICS FIRE AND EXPLOSION HAZARD DATA 0 1 4 PAGE (CONTINUED ON REVERSE SIDE) L A B O R A T O R I E S Page 456 of 495 Page 456 of 495 Page 456 of 495 Page 456 of 495 ---PAGE BREAK--- STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE X Open flame, welding arcs, heat, sparks INCOMPATIBILITY (Materials To Avoid) Strong oxidizing agents HAZARDOUS DECOMPOSITION OR BY PRODUCTS Carbon monoxide, carbon dioxide HAZARDOUS POLYMERIZATION:WILL NOT OCCUR X CONDITIONS TO AVOID MAY OCCUR X None known HEALTH HAZARDS EYES: May cause mild irritation. SKIN: May cause mild irritation INHALATION: Excessive inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness, nausea, headache, possible unconsciousness or IF SWALLOWED: Aspiration of material into the lungs during vomiting may cause chemical pneumonitis CARCINOGENICITY: NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No This product contains a chemical known to the state of California to cause cancer or reproductive toxicity? No SIGNS AND OF OVEREXPOSURE EYES: Irritation SKIN: Irritation due to defatting of skin INHALATION: Nasal and respiratory irritation, dizziness, weakness, nausea, headache IF SWALLOWED: Chemical pneumonitis TARGET ORGANS Liver, kidneys MEDICAL CONDITIONS GENERALLY AGGRAVATED BY OVEREXPOSURE May aggravate existing eye, skin or upper respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with cool water for at least 15 minutes while holding eyelids open. If irritation persists, call a physician or poison control center. SKIN: Wash with soap and water. If irritation persists, call a physician or poison control center. INHALATION: Remove to fresh air. Apply CPR if needed. Call a physician or poison control center. IF SWALLOWED: DO NOT INDUCE VOMITING. Call a physician or poison control center immediately. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Ventilate area and eliminate all sources of ignition. Contain spill and soak up spilled material with inert absorbent material and place in a properly labeled closed container for proper disposal. WASTE DISPOSAL METHOD Consult local, state and federal authorities for proper disposal guidelines. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store in a cool (<130°F), dry, well-ventilated area away from sources of ignition. RESPIRATORY PROTECTION (Specify Type) If TLV is exceeded, use NIOSH approved respirator to prevent overexposure. VENTILATION: MECHANICAL (General) LOCAL EXHAUST Provide adequate ventilation Generally adequate PROTECTIVE GLOVES EYE PROTECTION Neoprene or Nitrile rubber gloves Safety glasses or goggles OTHER PROTECTIVE CLOTHING OR EQUIPMENT Normal WORK HYGENIC PRACTICES Wash hands and face with soap and water after using this product. Remove contaminated clothing and launder before reusing. REACTIVITY DATA HEALTH HAZARD DATA PRECAUTIONS FOR SAFE HANDLING AND USE CONTROL MEASURES FOR USE WHERE SIGNIFICANT EYE, SKIN OR INHALATION EXPOSURE IS LIKELY PAGE UNITED 125 ALL STIK Page 457 of 495 Page 457 of 495 Page 457 of 495 Page 457 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 320 37th Avenue • St. Charles, Illinois 60174 • To Reorder, Call [PHONE REDACTED] PRODUCT IDENTIFICATION USE / DESCRIPTION REVISION DATE FOR MEDICAL AND UNITED 190 Acoustical Ceiling Tile Whitener March 17, 2003 TRANSPORTATION EMERGENCIES: UP WHITE INFOTRAC: [PHONE REDACTED] HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety) Always follow Label Directions and Cautions. Susceptible to Release of Energy. 4 Extreme. 3 High. 2 Moderate. 1 Slight. 0 Minimal. See Health Hazard Data Section of this M.S.D.S. for more detailed information. FLAMMABILITY (0 = Maximum Safety) Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated to burn. 3 Ignites at normal temperature. 0 Will not burn. 2 Ignites when moderately heated. HAZARDOUS CAS ACGIH ACGIH OSHA OTHER S.A.R.A. TITLE III COMPONENTS NUMBER TWA STEL PEL RECOMMENDED LIMITS QUANTITIES Isopropanol 67-63-0 400 ppm 500 ppm 400 ppm NIOSH TWA 400 ppm None 983 mg/m3 1,230 mg/m3 980 mg/m3 980 mg/m3 Propane 74-98-6 2,500 ppm Not 1,000 ppm NIOSH TWA 1,000 ppm None 4,508 mg/m3 established 1,800 mg/m3 1,800 mg/m3 Isobutane 75-28-5 Not Not Not NIOSH TWA 800 ppm None established established established 1,900 mg/m3 Trichloroethylene 79-01-6 50 ppm 100 ppm 100 ppm NIOSH TWA 25 ppm 0.263* 269 mg/m3 537 mg/m Acetone 67-64-1 500 ppm 750 ppm 1,000 ppm NIOSH TWA 250 ppm None 1,188 mg/m3 1,782 mg/m3 590 mg/m3 Paraffinic Naphthenic 64742-47-8 Not Not Not None None Solvent established established established * Pounds of reportable material per can of UNITED product. BOILING POINT SPECIFIC GRAVITY (H20 = 1) Not determined 1.123 VAPOR PRESSURE (PSIg) MELTING POINT (At 25° C) 55 Not determined VAPOR DENSITY (Air = 1) EVAPORATION RATE Greater than 1.0. (Butyl Acetate = 1) Less than 1.0 SOLUBILITY IN WATER VOLATILE ORGANIC COMPOUNDS Insoluble (Pounds Per Can Of Product) 0.43 APPEARANCE AND ODOR pH: Spray with sweet etheral odor. Not applicable FLASH POINT (Method Used) FLAMMABLE LIMITS LEL UEL Flame projection: Flammable (Greater than 18 inches) Not determined Not determined Not determined EXTINGUISHING MEDIA Carbon dioxide, foam, dry chemical, Halon. SPECIAL FIRE FIGHTING PROCEDURES Keep containers cool with water spray. Do not allow runoff to enter lakes, ponds, sewers or public water courses. Use equipment or shielding required to protect personnel against rupturing, bursting or venting containers. Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS Exposure to temperatures over 120°F may cause bursting or venting. Heat or fire may cause hazardous fumes: Carbon Monoxide, Phosgene, Chlorine and Hydrogen Chloride. 4 May detonate-vacate area if 2 Violent chemical change Materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. PERSONAL PROTECTION UNITED 190 HAZARDOUS COMPONENTS IDENTITY, EXPOSURE LIMITS AND S.A.R.A. TITLE III INFORMATION PHYSICAL / CHEMICAL CHARACTERISTICS FIRE AND EXPLOSION HAZARD DATA 0 2 3 PAGE (CONTINUED ON REVERSE SIDE) L A B O R A T O R I E S Page 458 of 495 Page 458 of 495 Page 458 of 495 Page 458 of 495 ---PAGE BREAK--- STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE X Temperatures above 120°F. INCOMPATIBILITY (Materials To Avoid) Oxidizing materials. HAZARDOUS DECOMPOSITION OR BY PRODUCTS Open flames can cause thermal degradation with the evolution of carbon monoxide, hydrogen chloride, phosgene and chlorine. HAZARDOUS POLYMERIZATION:WILL NOT OCCUR X CONDITIONS TO AVOID MAY OCCUR X Avoid sources of heat. HEALTH HAZARDS EYES: May cause pain, irritation, redness, slight corneal injury SKIN: May cause drying or flaking, irritation, burning sensation INHALATION: Prolonged exposure may cause dizziness, nausea, headache, upper respiratory discomfort. IF SWALLOWED: May cause upset stomach, nausea, vomiting, headache, diarrhea. CARCINOGENICITY: Trichloroethylene NTP? No IARC MONOGRAPHS? Yes OSHA REGULATED? No This product contains a chemical known to the state of California to cause cancer or reproductive toxicity? Yes SIGNS AND OF OVEREXPOSURE EYES: Pain, irritation, redness SKIN: Burning sensation INHALATION: Dizziness, nausea, headache, respiratory discomfort, irregular heartbeat IF SWALLOWED: Upset stomach, vomiting, nausea, headache, diarrhea TARGET ORGANS: Central nervous system, heart, liver, skin, eyes MEDICAL CONDITIONS GENERALLY AGGRAVATED BY OVEREXPOSURE Skin sensitivity, chemical allergies, heart condition EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with plenty of cool water for at least 15 minutes while holding eyelids open.. Call a physician or poison center. SKIN: Wash with soap and water. If irritation persists, call a physician or poison center. Remove contaminated clothing. INHALATION: Remove to fresh air. Apply CPR as needed. Call a physician or poison center immediately. IF SWALLOWED: DO NOT induce vomiting. Call a physician or poison center immediately. Note to Physician: If lavage is performed, suggest endotracheal and/or esophageal control. Do not administer sympathomimetic drugs unless absolutely necessary. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Small spills: Mop up, soak up immediately. Remove to out of doors. Large spills: Evacuate area. Remove all sources of ignition. Contain liquid; transfer to closed metal containers. Keep out of water supply. WASTE DISPOSAL METHOD Consult local, state, and federal authorities for proper disposal guidelines. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store in cool, dry, well ventilated area away from heat, sparks or open flame. Exposure to temperatures above 120°F may cause bursting. Keep out of reach of children. NFPA 30B Storage Level: I RESPIRATORY PROTECTION (Specify Type) If TLV is exceeded, use NIOSH approved respirator. VENTILATION: MECHANICAL (General) LOCAL EXHAUST Provide adequate ventilation Provide adequate ventilation PROTECTIVE GLOVES EYE PROTECTION Rubber gloves Safety glasses OTHER PROTECTIVE CLOTHING OR EQUIPMENT Long sleeves WORK HYGENIC PRACTICES Wash hands and face with soap and water after using this product. REACTIVITY DATA HEALTH HAZARD DATA PRECAUTIONS FOR SAFE HANDLING AND USE CONTROL MEASURES FOR USE WHERE SIGNIFICANT EYE, SKIN OR INHALATION EXPOSURE IS LIKELY PAGE UNITED 190 UP WHITE Page 459 of 495 Page 459 of 495 Page 459 of 495 Page 459 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 320 37th Avenue • St. Charles, Illinois 60174 • To Reorder, Call [PHONE REDACTED] PRODUCT IDENTIFICATION USE / DESCRIPTION REVISION DATE FOR MEDICAL AND UNITED 199 Rubberized Coating March 17, 2003 TRANSPORTATION EMERGENCIES: EVERLAST INFOTRAC: [PHONE REDACTED] HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety) Always follow Label Directions and Cautions. Susceptible to Release of Energy. 4 Extreme. 3 High. 2 Moderate. 1 Slight. 0 Minimal. See Health Hazard Data Section of this M.S.D.S. for more detailed information. FLAMMABILITY (0 = Maximum Safety) Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated to burn. 3 Ignites at normal temperature. 0 Will not burn. 2 Ignites when moderately heated. HAZARDOUS CAS ACGIH ACGIH OSHA OTHER S.A.R.A. TITLE III COMPONENTS NUMBER TWA STEL PEL TWA RECOMMENDED LIMITS QUANTITIES Aliphatic petroleum 64742-89-8 300 ppm Not 300 ppm None 0.25* solvent established Calcium carbonate 1317-65-3 10 mg/m3 Not 15 mg/m3 NIOSH TWA None 471-34-1 established (Total dust) 10 mg/m3 (Total dust) Toluene 108-88-3 SKIN: 50 ppm Not 200 ppm NIOSH TWA 0.15* established 100 ppm Liquified petroleum gas 68476-85-7 1000 ppm Not 1000 ppm NIOSH TWA None 1800 mg/m3 established 1800 mg/m3 1000 ppm1800 mg/m3 * Pounds of reportable material per can of UNITED product. BOILING POINT SPECIFIC GRAVITY (H20 = 1) Not determined Less than 1 VAPOR PRESSURE (psig) MELTING POINT (At 130° 90 psig Not determined VAPOR DENSITY (Air = 1) EVAPORATION RATE Greater than 1 (Ether = 1) Less than 1.0 SOLUBILITY IN WATER VOLATILE ORGANIC COMPOUNDS Negligible (Pounds Per Can Of Product) 0.658 APPEARANCE AND ODOR pH: Thick black liquid with petroleum odor. Not applicable FLASH POINT (Method Used) FLAMMABLE LIMITS LEL UEL Extremely flammable as described in 16CFR1500.45 % Volume in air (Propellant) 1.8 9.2 EXTINGUISHING MEDIA CO2, foam, dry chemical SPECIAL FIRE FIGHTING PROCEDURES Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS At elevated temperatures (over 130° F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening of container structure. 4 May detonate-vacate area if 2 Violent chemical change Materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. PERSONAL PROTECTION UNITED 199 HAZARDOUS COMPONENTS IDENTITY, EXPOSURE LIMITS AND S.A.R.A. TITLE III INFORMATION PHYSICAL / CHEMICAL CHARACTERISTICS FIRE AND EXPLOSION HAZARD DATA 0 2 4 PAGE (CONTINUED ON REVERSE SIDE) L A B O R A T O R I E S Page 460 of 495 Page 460 of 495 Page 460 of 495 Page 460 of 495 ---PAGE BREAK--- STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE X Do not store above 130° F. INCOMPATIBILITY (Materials To Avoid) Oxidizing agents HAZARDOUS DECOMPOSITION OR BYPRODUCTS CO, CO2, oxides of sulfur and additional toxic chemicals may be formed in small amounts HAZARDOUS POLYMERIZATION:WILL NOT OCCUR X CONDITIONS TO AVOID MAY OCCUR X None known HEALTH HAZARDS EYES: Can cause irritation SKIN: Prolonged contact on skin may cause dermatitis INHALATION: Excessive breathing of vapor or spray mists may produce dizziness, nausea, headaches and incoordination. IF SWALLOWED: May cause abdominal spasms and other that parallel over-exposure from inhalation. Aspiration of material into the lungs during vomiting may cause chemical pneumonitis. CARCINOGENICITY: NTP? No IARC MONOGRAPHS? Yes* OSHA REGULATED? No This product contains a chemical known to the state of California to cause cancer or reproductive toxicity? Yes (Toluene and silica) *Calcium carbonate contains variable quantities of silica. IARC has classified silica as probably carcinogenic to humans. SIGNS AND OF OVEREXPOSURE EYES: Irritation SKIN: Dermatitis INHALATION: Dizzines, nausea, headaches, incoordination IF SWALLOWED: Abdominal spasms, dizziness, nausea, headache, incoordination MEDICAL CONDITIONS GENERALLY AGGRAVATED BY OVEREXPOSURE Pre-existing skin, eye, and respiratory disorders may be aggravated TARGET ORGANS: Eyes, skin, Central Nervous System EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with water for at least 15 minutes while holding eyelids open. Call a physician or poison center. SKIN: Wash with soap and water. Remove contaminated clothing. If irritation persists, call a physician or poison center. INHALATION: Remove to fresh air. Apply CPR as needed. Call a physician or poison center. IF SWALLOWED: DO NOT induce vomiting. Call a physician or poison center immediately. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent and place into a designated disposal container. WASTE DISPOSAL METHOD Consult local, state and federal authorities for proper disposal guidelines. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not expose to direct sunlight or store at temperatures above 130° F. Store as a Level 3 Aerosol NFPA 30B. RESPIRATORY PROTECTION (Specify Type) If TLV is exceeded, use NOISH approved respirator VENTILATION: MECHANICAL (General) LOCAL EXHAUST Provide adequate ventilation Generally adequate PROTECTIVE GLOVES EYE PROTECTION Chemical resistant gloves Safety glasses OTHER PROTECTIVE CLOTHING OR EQUIPMENT Long sleeves recommended WORK HYGENIC PRACTICES Remove contaminated clothing immediately and launder before reusing. Wash hands and face with soap and water after using this product. REACTIVITY DATA HEALTH HAZARD DATA PRECAUTIONS FOR SAFE HANDLING AND USE CONTROL MEASURES FOR USE WHERE SIGNIFICANT EYE, SKIN OR INHALATION EXPOSURE IS LIKELY PAGE UNITED 199 EVERLAST Page 461 of 495 Page 461 of 495 Page 461 of 495 Page 461 of 495 ---PAGE BREAK--- 1 Material Safety Data Sheet 0531, 0532, 0534, 0538, 0615 Vinyl Spackling Compound MSDS No. 0035 Rev. 5 Emergency Phone No. [PHONE REDACTED] - INFOTRAC SECTION 1 – PRODUCT NAME & MANUFACTURER INFORMATION PRODUCT NAME Vinyl Spackling Compound MANUFACTURER’S NAME & TELEPHONE NUMBER Red Devil, Inc. [PHONE REDACTED] STREET ADDRESS 4175 Webb Street CITY / STATE / ZIP Pryor, Oklahoma 74361 SECTION 2 – COMPOSITION / HAZARDOUS INGREDIENTS % TLV PEL UNITS PRODUCT CONSISTS OF: Aqueous Vinyl Acrylic Emulsion (mixture) < 20 NE NE Soda Lime Borosilicate (65997-17-3) < 4 NE NE Calcium Carbonate (1317-65-3) (as nuisance particulate, total) < 70 10 15 mg/m3 Amino Methyl Propanol (AMP-95) (124-68-5) < 0.10 NE NE Propylene Glycol (57-55-6) < 1 400*** NE ppm Non-hazardous ingredients * <10 NA NA *Unlisted ingredients are not considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). Inhalation not likely due to products physical state. TWA. Contains no EG. Calculated VOC: < 0.5%/wt, < 10 g/L. CARB Compliance: Yes. Prop 65 Ingredients: Yes (See Section 16) SECTION 3 – HAZARDS IDENTIFICATION PRIMARY ROUTE(S) OF ENTRY Skin Contact Skin Absorption Eye Contact Inhalation Ingestion EMERGENCY OVERVIEW White to off-white paste w/ a sweet odor. May cause eye, skin, nose, throat & respiratory tract irritation. EFFECTS OF OVEREXPOSURE May cause eye, skin, nose, throat & respiratory tract irritation. Harmful if swallowed. Inhalation of dust may result in pulmonary & respiratory damages. Prolonged or repeated exposure to dust may cause lung damage. This product may contain small amounts of vinyl acetate, identified by IARC as a potential carcinogen; however there should be minimal risk when used w/ ventilation adequate to keep the atmospheric concentration of vinyl acetate below the recommended exposure limit. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE If dry sanded, asthma & asthma-like conditions may worsen from prolonged or repeated exposure to dust. SECTION 4 – FIRST AID MEASURES SKIN CONTACT Wash w/ soap & water for @ least 15 minutes. Get medical attention if persist. Remove & wash contaminated clothing. EYE CONTACT Immediately flush w/ large quantities of water for @ least 15 minutes until irritation subsides. Get medical attention. INHALATION If inhaled, remove to fresh air. If breathing difficult, leave area to obtain fresh air. If breathing remains difficult, get medical attention. INGESTION DO NOT INDUCE VOMITING. Get immediate medical attention. Page 462 of 495 Page 462 of 495 Page 462 of 495 Page 462 of 495 ---PAGE BREAK--- 2 SECTION 5 – FIRE FIGHTING MEASURES FLAMMABLE Yes No EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam, Water Fog FLASHPOINT & METHOD >200F (Seta Closed Cup) UPPER EXPLOSIVE LIMIT BY VOLUME) NE LOWER EXPLOSIVE LIMIT BY VOLUME) NE AUTOIGNITION TEMPERTURE NE UNUSUAL FIRE & EXPLOSION HAZARDS None known. SPECIAL FIREFIGHTING PROCEDURES Wear self-contained breathing apparatus pressure demand (NIOSH approved or equivalent) & full protective gear. Use water spray to cool exposed surfaces. SECTION 6 – ACCIDENTAL RELEASE MEASURES PROCEDURES Wear proper protective equipment (Section Use absorbent material or scrape up dried material & place in approved container. SECTION 7 – HANDLING & STORAGE HANDLING PROCEDURES & EQUIPMENT Keep out of reach of children & pets. Do not take internally. Do not breathe vapors or inhale dusts of this product. Avoid contact w/ skin & eyes. Do not get on clothing. Use w/ adequate ventilation. Ensure fresh air during application & drying by opening windows & doors. STORAGE REQUIREMENTS Close container after each use. Store containers away from excessive heat & freezing. Do not store @ temperatures above 120F. Store away from caustics & oxidizers. SECTION 8 – EXPOSURE CONTROL / PERSONAL PROTECTION RESPIRATORY In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator w/ organic vapor cartridge may be necessary under circumstances where concentrations are expected to exceed exposure limits. Prevent build-up of dust & vapors by opening windows & doors. Wet sanding is recommended to avoid generation of dust. EYEWEAR Goggles or safety glasses w/ side shields. CLOTHING / GLOVES Gloves recommended for prolonged or repeated skin contact. HYGENIC PRACTICES Remove & wash contaminated clothing before re-use. Wash hands before breaks & @ end of workday. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Paste ODOR & APPEARANCE Slight sweet. off-white paste. SPECIFIC GRAVITY Approximately 1.75 to 2.0 VAPOR DENSITY (AIR=1) NE EVAPORATION RATE NE BOILING RANGE NE pH Approximately 7.5 to 9.5 SOLUBILITY IN WATER NE VAPOR PRESSURE (MM Hg) NE %/WT VOLATILE (TNV) 18 to 22% SECTION 10 – STABILITY AND REACTIVITY STABILITY Yes No Stable under normal conditions. INCOMPATABILITY Yes No Incompatible w/ strong bases & strong oxidizing agents. CONDITIONS TO AVOID Excessive heat & freezing. HAZARDOUS POLYMERIZATION/HAZARDOUS DECOMPOSITION PRODUCTS Hazardous polymerization will not occur under normal conditions. Normal decomposition products, ie: COx, NOx. Page 463 of 495 Page 463 of 495 Page 463 of 495 Page 463 of 495 ---PAGE BREAK--- 3 SECTION 11 – TOXICOLOGICAL INFORMATION / CARCINOGENICITY ACGIH Silica, (14808-60-7), present in Calcium Carbonate filler is a suspected human carcinogen. Vinyl acetate (108-05-4), present in base emulsion is a confirmed animal carcinogen w/ unknown relevance to humans. OSHA NE IARC Silica, (14808-60-7), present in Calcium Carbonate filler identified as a human carcinogen. Vinyl acetate (108-05-4), present in base emulsion identified as a possible carcinogen. NTP Silica, (14808-60-7), present in Calcium Carbonate filler identified as a Known carcinogen. DATA WITH POSSIBLE RELEVANCE TO HUMANS Product may contain trace amounts of vinyl acetate, identified by IARC as a potential carcinogen. There is presently no evidence that it has caused cancer in humans. Silica is known to the State of California to cause cancer. SECTION 12 – ECOLOGICAL INFORMATION AQUATIC TOXICITY Ecological injuries are not known or expected under normal use. SECTION 13 – DISPOSAL CONSIDERATIONS WASTE DISPOSAL EPA WASTE CODE IF DISCARDED (40CFR Sec.261) Dispose of material in accordance w/ Federal, State & Local regulations. None. SECTION 14 – TRANSPORT INFORMATION SPECIAL SHIPPING INFORMATION Product not regulated by DOT. SECTION 15 – REGULATORY INFORMATION CERCLA – SARA HAZARD CATEGORY SARA 311 & 312: Immediate health hazard, Chronic health hazard. U.S. STATE REGS See Section 16. SARA 313 None. TSCA All ingredients either on TSCA Inventory or exempt. SECTION 16 – OTHER INFORMATION / SPECIAL PRECAUTIONS / LEGEND NJ Right-to-Know: (Top 5 Ingredients): Vinyl Acrylic Emulsion (mixture), Water (7732-18-5), Petroleum Distillate (64742-48-9), Soda Lime Borosilicate (Glass Bubbles) (65997-17-3), Propylene Glycol (57-55-6) Right-to-Know (Non-Haz @ Water (7732-18-5). Ingredients Known to State of California to cause cancer, birth defects or reproductive harm: Vinyl acetate (108-05-4) residual in base emulsion, Silica, (14808-60-7) @ .1 to .7%/wt in calcium carbonate filler. Canadian WHMIS Class: Not regulated. HMIS Ratings: Health: 1, Flammability: 0, Reactivity: 0, Personal Protection: X. WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. INTERNATIONAL EMERGENCY NUMBER: [PHONE REDACTED] - INFOTRAC LEGEND: NA – Not Applicable, NE – Not Established, UN – Unavailable, VOC – Volatile Organic Compound, PEL – Permissible Exposure Limit, TLV – Threshold Limit Value, STEL – Short Term Exposure Limit, MSDS – Material Safety Data Sheet, ACGIH – American Conference of Governmental Industrial Hygienists, SARA – Superfund Amendments & Reauthorization Act of 1986, OSHA – Occupational Safety & Health Administration, HMIS – Hazardous Materials Identification System, NTP – National Toxicology Program, CEIL – Ceiling Exposure Limit, CASRN (CAS Number) – Chemical Abstracts Service Registry Number, TSCA – Toxic Substances Control Act Reviewed By: _Larry G. Brandon__________ VP Technology & General March 6, 2012__ NAME TITLE DATE The information contained herein has been developed based upon currently available scientific data. New information may be developed from time to time which may render the conclusions of this report obsolete. Therefore, no warranty is extended as to the applicability of this information to the user’s intended purpose or for the consequences of its use or misuse. Page 464 of 495 Page 464 of 495 Page 464 of 495 Page 464 of 495 ---PAGE BREAK--- Page 465 of 495 Page 465 of 495 Page 465 of 495 Page 465 of 495 ---PAGE BREAK--- Page 466 of 495 Page 466 of 495 Page 466 of 495 Page 466 of 495 ---PAGE BREAK--- Page 467 of 495 Page 467 of 495 Page 467 of 495 Page 467 of 495 ---PAGE BREAK--- Page 468 of 495 Page 468 of 495 Page 468 of 495 Page 468 of 495 ---PAGE BREAK--- Page 469 of 495 Page 469 of 495 Page 469 of 495 Page 469 of 495 ---PAGE BREAK--- Page 470 of 495 Page 470 of 495 Page 470 of 495 Page 470 of 495 ---PAGE BREAK--- Page 471 of 495 Page 471 of 495 Page 471 of 495 Page 471 of 495 ---PAGE BREAK--- Page 472 of 495 Page 472 of 495 Page 472 of 495 Page 472 of 495 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET WL8802020 01 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER HMIS CODES Health 2 WL8802020 Flammability 0 Reactivity 0 PRODUCT NAME WHITE LIGHTNING® FLAME BUSTER™ High Heat Silicone Sealant, Limestone MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. THE SHERWIN-WILLIAMS CO. (216) 566-2917 Consumer Group - Industrial Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 15-MAY-07 (216) 566-2902 Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 5 7631-86-9 Amorphous Silica ACGIH TLV 10 mg/m3 as Dust OSHA PEL 6 mg/m3 as Dust 35 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE EYE or SKIN contact with product. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE May cause allergic skin reaction in susceptible persons or skin sensitization. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Continued on page 2 Page 473 of 495 Page 473 of 495 Page 473 of 495 Page 473 of 495 ---PAGE BREAK--- WL8802020 page 2 Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. If irritation persists or occurs later, get medical attention. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove with inert absorbent. Section 7 HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Continued on page 3 Page 474 of 495 Page 474 of 495 Page 474 of 495 Page 474 of 495 ---PAGE BREAK--- WL8802020 page 3 Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PROTECTIVE EQUIPMENT Use of barrier cream on exposed skin is recommended. Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.94 lb/gal 1310 g/l SPECIFIC GRAVITY 1.32 BOILING POINT Not Applicable MELTING POINT Not Available VOLATILE VOLUME 0 % EVAPORATION RATE N.A. VAPOR DENSITY N.A. SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.00 lb/gal 0 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC Continued on page 4 Page 475 of 495 Page 475 of 495 Page 475 of 495 Page 475 of 495 ---PAGE BREAK--- WL8802020 page 4 Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. TOXICOLOGY DATA CAS No. Ingredient Name 7631-86-9 Amorphous Silica LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 TRANSPORT INFORMATION US Ground (DOT) Information is not Available Canada (TDG) Information is not Available IMO Information is not Available Continued on page 5 Page 476 of 495 Page 476 of 495 Page 476 of 495 Page 476 of 495 ---PAGE BREAK--- WL8802020 page 5 Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 477 of 495 Page 477 of 495 Page 477 of 495 Page 477 of 495 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 WINDEX® FOAMING GLASS & SURFACE CLEANER Version 1.0 Print Date 07/16/2013 Revision Date 09/28/2012 MSDS Number 350000021130 SITE_FORM Number 30000000000000015559.001 1/8 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : WINDEX® FOAMING GLASS & SURFACE CLEANER Use of the Substance/Mixture : Hard Surface Cleaner Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : translucent / liquid / characteristic Immediate Concerns : Caution Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg as container may burst. Contents under pressure. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : Prolonged or repeated contact may dry skin and cause irritation. Inhalation : No adverse effects expected when used as directed. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. Page 478 of 495 Page 478 of 495 Page 478 of 495 Page 478 of 495 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 WINDEX® FOAMING GLASS & SURFACE CLEANER Version 1.0 Print Date 07/16/2013 Revision Date 09/28/2012 MSDS Number 350000021130 SITE_FORM Number 30000000000000015559.001 2/8 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Isobutane 75-28-5 1.00 - 5.00 Propylene glycol monobutyl ether 5131-66-8 1.00 - 5.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : Rinse mouth with water. 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Aerosol Product - Containers may rocket or explode in heat of fire. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Flash point : < -7 C < 19.4 °F Method: Tag Closed Cup (TCC) Note: Propellant Page 479 of 495 Page 479 of 495 Page 479 of 495 Page 479 of 495 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 WINDEX® FOAMING GLASS & SURFACE CLEANER Version 1.0 Print Date 07/16/2013 Revision Date 09/28/2012 MSDS Number 350000021130 SITE_FORM Number 30000000000000015559.001 3/8 Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Advice on safe handling : Do not puncture or incinerate. Avoid breathing vapors, mist or gas. Do not spray toward face. Do not use in areas without adequate ventilation. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Storage Requirements for storage areas and containers : Do not store at temperatures above 120 Deg. F (50 Deg as container may burst. Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. Page 480 of 495 Page 480 of 495 Page 480 of 495 Page 480 of 495 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 WINDEX® FOAMING GLASS & SURFACE CLEANER Version 1.0 Print Date 07/16/2013 Revision Date 09/28/2012 MSDS Number 350000021130 SITE_FORM Number 30000000000000015559.001 4/8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Isobutane 75-28-5 - 1,000 ppm - ACGIH TWA Personal protective equipment Respiratory protection No personal respiratory protective equipment normally required. Hand protection : No special requirements. Eye protection No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : translucent Odor : characteristic pH : 11 at 25 C(undiluted) Melting point : no data available Boiling point : no data available Freezing point : no data available Flash point : < -7 C < 19.4 °F Method: Tag Closed Cup (TCC) Propellant Page 481 of 495 Page 481 of 495 Page 481 of 495 Page 481 of 495 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 WINDEX® FOAMING GLASS & SURFACE CLEANER Version 1.0 Print Date 07/16/2013 Revision Date 09/28/2012 MSDS Number 350000021130 SITE_FORM Number 30000000000000015559.001 5/8 Evaporation rate : no data available Flammability (solid, gas) : Does not sustain combustion. Auto-ignition temperature : not auto-flammable Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 8.327 lb/gal at 20 C Water solubility : soluble Partition coefficient: n- octanol/water : no data available Viscosity, dynamic : no data available Viscosity, kinematic : no data available Relative vapor density : no data available Volatile Organic Compounds Total VOC (wt. : 6.9 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Strong acids Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Thermal decomposition : Note: no data available Hazardous reactions : Stable under recommended storage conditions. Page 482 of 495 Page 482 of 495 Page 482 of 495 Page 482 of 495 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 WINDEX® FOAMING GLASS & SURFACE CLEANER Version 1.0 Print Date 07/16/2013 Revision Date 09/28/2012 MSDS Number 350000021130 SITE_FORM Number 30000000000000015559.001 6/8 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 Measured > 5,000 mg/kg Acute inhalation toxicity : LC50 Measured > 5.59 mg/l Acute dermal toxicity : LD50 Measured > 5,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : Did not cause sensitization on laboratory animals. 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle Page 483 of 495 Page 483 of 495 Page 483 of 495 Page 483 of 495 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 WINDEX® FOAMING GLASS & SURFACE CLEANER Version 1.0 Print Date 07/16/2013 Revision Date 09/28/2012 MSDS Number 350000021130 SITE_FORM Number 30000000000000015559.001 7/8 where facilities exist. 14. TRANSPORT INFORMATION Land transport ƒ U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1, LTD QTY Class: 2.1 UN number 1950 Packaging group: None. Note: Limited quantities derogation may be applicable to this product, please check transport documents. Sea transport ƒ IMDG: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1, LTD QTY Class: 2 UN number: 1950 Packaging group: None. EmS: F-D, S-U Note: Limited quantities derogation may be applicable to this product, please check transport documents. Air transport ƒ ICAO/IATA: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1, LTD QTY Class: 2.1 UN/ID No.: UN 1950 Packaging group: None. Note: SC Johnson typically does not ship products via air. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under Page 484 of 495 Page 484 of 495 Page 484 of 495 Page 484 of 495 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 WINDEX® FOAMING GLASS & SURFACE CLEANER Version 1.0 Print Date 07/16/2013 Revision Date 09/28/2012 MSDS Number 350000021130 SITE_FORM Number 30000000000000015559.001 8/8 California's Proposition 65. Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 1 Flammability 4 Reactivity 0 NFPA Ratings Health 1 Fire 4 Reactivity 0 Special - Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 485 of 495 Page 485 of 495 Page 485 of 495 Page 485 of 495 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 1 of 4 SECTION I - IDENTIFICATION PRODUCT NAME: Windshield De-Icer PRODUCT CODE: 95101 PRODUCT USE: Ice removal COMPANY NAME: Lawson Products, Inc. COMPANY ADDRESS: 8770 W. Bryn Mawr Suite 900, Chicago, Il 60631 COMPANY PHONE: [PHONE REDACTED] EMERGENCY PHONE: [PHONE REDACTED] SECTION II – HAZARDS IDENTIFICATION CLASSIFICATION: Flammable Aerosol: Category 1 Dissolved Gas Actue Toxicity (Oral / Inhalation / Dermal): Category 3 Skin Irritant: Category 2 Eye Irritant: Category 2b Specific Target Organ Toxicity (Single Exposure): Category 1 HAZARD STATEMENT(S): DANGER: Extremely Flammable Aerosol Contains gas under pressure; May explode if heated. Toxic if swallowed, in contact with skin, and if inhaled. Causes eye and skin irritation. Causes damage to Eyes and Central nervous system. This product contains the following percentage of chemicals of unknown toxicity: 0% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Wash hands thoroughly after handling. Do not eat, drink, or smoke when using this product. Wear safety glasses and protective gloves. Do not breathe mist, vapors, or spray. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Take off immediately all contaminated clothing and wash before reuse. If swallowed: Immediately call a poison center or doctor. Rinse Mouth. Call a poison center or doctor if exposed or you feel unwell. Use only outdoors or in a well-ventilated area. Store locked up. Dispose of contents and container in accordance with local, state, and national regulations. If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical attention. SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT Carbon Dioxide 124-38-9 3-7% Ethylene Glycol 107-21-1 5-10% Isopropyl Alcohol 67-63-0 1-5% Methyl Alchol 67-56-1 60-100% SECTION IV - FIRST AID MEASURES EYES: Immediately flush with water for 15 minutes while holding eyelids open. Seek immediate medical attention. INGESTION: Seek immediate medical attention. INHALATION: Move to fresh air. If breathing is difficult, administer oxygen. If not breathing administer artificial respiration or at any sign of loss of consciousness seek immediate medical attention. SKIN: Immediately wash with soap and water for 15 minutes. ACUTE HEALTH HAZARDS: Eyes: Redness and tearing Skin: Absor\pbtion of large amounts of product causes Eye and Central nervous system damage, and possibly death. Inhalation: Anesthetic, irritation, prolonged exposure may lead to unconsciousness and death. Page 486 of 495 Page 486 of 495 Page 486 of 495 Page 486 of 495 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 2 of 4 Oral: abdominal irritation, nausea, vomiting, and diarrhea, consumption of large quantities causes Eye, Central Nervous System damage, and death CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone marrow, central nervous system (CNS). NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of and the clinical condition of the patient. SECTION V – FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, standard chemical fire extinguisher, and water fog. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece operated in a positive pressure demand mode with full body protective clothing when fighting fires. Avoid contact with skin and breathing smoke, fumes, and decomposition products. Cool fire exposed containers with water fog to prevent bursting. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon SECTION VI – ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Absorb with non-combustible material like vermiculite, sand or earth and rinse with small amount of soapy water. Do not allow to drain into sewers or storm drains. Dispose of in accordance with local, state and federal regulations. WASTE DISPOSAL: Dispose of in accordance with local, state and federal regulations. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Pressurized container: Do not pierce or burn, even after use. OTHER PRECAUTIONS: Keep out of the reach of children. INCOMPATIBILITY: Strong oxidizing agents. SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV Carbon Dioxide 5000 ppm 5000 ppm Ethylene Glycol 125 mg/m3 100 mg/m3 Isopropyl Alcohol 400 ppm 200 ppm Methyl Alchol 200 ppm 200 ppm ENGINEERING CONTROLS / VENTILATION: General ventilation and local exhaust should be adequate. RESPIRATORY PROTECTION: Wear NIOSH/MSHA approved respiratory protection if used in confined, poorly ventilated areas. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses ADDITIONAL MEASURES: Wash hands thoroughly after handling. Do not breathe vapors. Do not eat, drink, or smoke while using product. Get medical attention if you feel unwell. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, Colorless Aerosol ODOR: Alcohol Odor ODOR THRESHOLD: N/D BOILING POINT: > 148°F (64.4°C) FREEZING POINT: N/D FLAMMABILITY: Extremely Flammable Aerosol FLASH POINT: 65°F (18°C) AUTOIGNITION TEMPERATURE: N/D Page 487 of 495 Page 487 of 495 Page 487 of 495 Page 487 of 495 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 3 of 4 LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): 89 mmHg VAPOR DENSITY (AIR=1): > 1 EVAPORATION RATE: > 1 SPECIFIC GRAVITY (H2O=1): 0.815 @ 77° F (25° C) pH: N/A SOLIDS N/D SOLUBILITY IN WATER: 100% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER 100% VOLATILE ORGANIC COMPOUNDS (VOC): 96% DIELECTRIC STRENGTH (Volts): N/A DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Temperatures greater than 120°F may cause bursting. INCOMPATIBILITY: Strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon POSSIBLE HAZARDOUS REACTIONS: None Known SECTION XI – TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Isopropyl Alcohol (67-63-0) LD50 (Oral,Rat) 5045 mg/kg; LD50 (Oral, Rabbit) 5045 mg/kg; LD50 (Dermal, Rabbit) 12,800 mg/kg; LC50 (Inhalation, Rat, 8hr) 16,000 ppm Methyl Alcohol (67-56-1) LD50 (Oral, Man) 5628 mg/kg; LD50 (Dermal, Rabbit) 20,000 mg/kg Ethylene Glycol (107-21-1) LD50 (Oral, Rat) 4700 mg/kg; LC50 (Rat, 4 hrs) > 200 mg/m3 ROUTES OF ENTRY: Eyes, Ingestion, Inhalation, Skin EYES: Causes severe irritation, redness, tearing. INGESTION: Not a likely route of exposure under normal product handling conditions. INHALATION: Acute exposure may cause nausea, vomiting, coughing and pulmonary irritation. SKIN: Causes localized defatting, irritation. MEDICAL CONDITION AGGRAVATED: Pre-existing disorders of the skin, respiratory system, and eyes will be aggravated by over exposure. ACUTE HEALTH HAZARDS: Eyes: Redness and tearing Skin: Absor\pbtion of large amounts of product causes Eye and Central nervous system damage, and possibly death. Inhalation: Anesthetic, irritation, prolonged exposure may lead to unconsciousness and death. Oral: abdominal irritation, nausea, vomiting, and diarrhea, consumption of large quantities causes Eye, Central Nervous System damage, and death CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone marrow, central nervous system (CNS). CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A SECTION XII – ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Isopropyl Alcohol (67-63-0) LC50 (Fathead Minnow, 96 hrs) 100,000 mg/L Methyl Alcohol (67- 56-1) LC50 (Fathead Minnow, 96hrs) 29400 mg/L The half-life of methanol in surface water ranges from 24 - 168 hrs. Ethylene Glycol (107-21-1) LC50 (Trout, 96 hrs) 41,000 mg/L; (Water Flea, 48 hrs) 46,300 mg/L; (Bluegill Fish, 96 hrs) 34,250 mg/L; (Goldfish, 72 hrs) 34,250 mg/L BIODEGRADABILITY: This product is biodegradable. BIOACCUMULATION: This product is not expected to bioaccumulate. SOIL MOBILITY: This product is mobile in soil. OTHER ECOLOGICAL HAZARDS: None Known Page 488 of 495 Page 488 of 495 Page 488 of 495 Page 488 of 495 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 4 of 4 SECTION XIII – DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with local, state and federal regulations. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION XIV - TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: N/A AIR SHIPMENT PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 ENVIRONMENTAL HAZARDS WATER: N/A SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Methanol (67-56-1) Reportable Quantity = 5,000 lbs Ethylene Glycol (107-21-1) Reportable Quantity = 5,000 lbs SARA 311/312 HAZARD CATEGORIES: Fire Hazard SARA 313 REPORTABLE INGREDIENTS: Methanol (67-56-1), Ethylene Glycol (107-21-1) CLEAN WATER ACT: None STATE REGULATIONS: Isopropyl Alcohol (67-63-0) Right-to-Know acts for Rhode Island, Florida, Minnesota, Massachusetts, New Jersey, Tennesee Connecticut hazardous material survey. Isopropyl alcohol Illinois toxic substances disclosure to employee act INTERNATIONAL REGULATIONS: All components are listed or exempted. NFPA HEALTH: 3 HMIS HEALTH: 3 NFPA FLAMMABILITY: 3 HMIS FLAMMABILITY: 3 NFPA REACTIVITY: 1 HMIS REACTIVITY: 1 NFPA OTHER: None HMIS PROTECTION: B SECTION XVI - ADDTIONAL INFORMATION PREPARATION BY: Maureen Ruggeberg, Regulatory Affairs Specialist DATE PREPARED: 01/16/2014 REVISION DATE: 10/30/2014 N/A = Not Applicable; N/D = Not Determined DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance. Page 489 of 495 Page 489 of 495 Page 489 of 495 Page 489 of 495 ---PAGE BREAK--- Material Safety Data Sheet N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated 1-2-3 MSDS (04-15-05) Page 1 of 6 pages. Section 1 General Information Manufacturer: Zinsser Company, Inc. 173 Belmont Drive Somerset, NJ 08875 (732) 469-8100 Emergency Telephone: Chemtrec (800) 424-9300 Date: April 15, 2005 Product Name: BULLS EYE 1-2-3 Product Codes: 2000, 2001, 2004, 2010, 2011, 2012, 2014, 2025 Section 2 Hazardous Ingredients OSHA ACGIH Hazardous Component CAS# PEL TLV Calcium Carbonate 471-34-1 15 mg/m33 * 5 mg/m3 3 mg/m3 10 mg/m3 † Ethylene Glycol 107-21-1 N/E 100 mg/m3 (aerosol only) Limestone 1317-65-3 15 mg/m3 * 3 mg/m3 10 mg/m3 † Talc 14807-96-6 15 mg/m3 * 10 mg/m3 Titanium Dioxide 13463-67-7 15 mg/m3 * 10 mg/m3 Zinc Oxide 1314-13-2 15 mg/m3 * 5 mg/m3 2 mg/m3 * 10 mg/m3 (STEL) * Total Dust Respirable particles C = Ceiling Value † Inhalable particles Section 3 Hazard Identification Emergency Overview: This material is paint primer. It is a stable, non-flammable, white flowable liquid with a flash point above 200° Fahrenheit. Primary Routes of Exposure: Skin Contact Eye Contact Potential Acute Health Effects: Eye: May cause slight eye irritation. Skin: May cause slight skin irritation in certain individuals. However, absorption through skin contact is not considered to be a significant route of exposure. Page 490 of 495 Page 490 of 495 Page 490 of 495 Page 490 of 495 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated 1-2-3 MSDS (04-15-05) Page 2 of 6 pages. Ingestion: Ingestion not considered a significant route of exposure. Inhalation: Inhalation not considered a significant route of exposure. Potential Chronic Health Effects: None known. Signs and N/A (See also Sections 4, 8, and 11for related information) Section 4 First Aid Measures Eye contact: Flush eye with water for 15 minutes. If persist, consult a physician. Skin contact: Wash with soap and water. If occur, consult a physician. Ingestion: Swallowing less than an ounce is not expected to cause significant harm. For larger amounts, do not induce vomiting, give one or two glasses of water to drink and call a physician or poison control center. Inhalation: No specific treatment is necessary since this material is not likely to be hazardous by inhalation. If exposed to excessive levels of vapor, remove person to fresh air. Seek medical attention if develop. Note to Physician: According to the Federal Hazardous Substance Act this material is not considered to be a primary eye irritant or a primary dermal irritant, and it is not considered to be an acute oral toxin. Section 5 Fire Fighting Measures Flash Point (method): > 200° F Extinguishing Media: Foam, Alcohol Foam, CO2 Dry Chemical, Water Fog. Protection of Firefighters: No special protection required. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards: This liquid material will not burn. However, the dried paint film may burn in a fire. Section 6 Accidental Release Measures Page 491 of 495 Page 491 of 495 Page 491 of 495 Page 491 of 495 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated 1-2-3 MSDS (04-15-05) Page 3 of 6 pages. Clean Up Methods: Keep unnecessary people away. Contain spills with inert material (sand, earth, etc.) and transfer to containers for recovery or disposal. Keep spill out of sewer and open bodies of water. Floors may be slippery; care should be exercised to avoid falls. (See also Section 8 for information on Exposure Controls and Personal Protective Equipment) Section 7 Handling and Storage Handling: Avoid contact with eyes, skin, and clothing. Storage: Keep from freezing. Keep container closed when not in use. Section 8 Exposure Controls / Personal Protection Engineering Controls: If exposure conditions warrant, use local exhaust ventilation or general dilution ventilation to reduce vapor concentrations. Personal Protective Equipment (PPE): Eye Protection: Wear safety glasses, goggles, or face shield to prevent eye contact. Skin Protection: Wear gloves to prevent prolonged skin contact. Respiratory Protection: None required under normal intended use conditions. In areas of poor ventilation or if vapor exposure causes discomfort, wear NIOSH approved respirator with organic vapor cartridges. Protective Clothing: For brief contact, no special precautions other than clean body-covering clothing should be needed. When prolonged or frequent, repeated contact with the material could occur, use protective clothing that is impervious to this material (such as tyvek). General Hygiene Practices: Wash after handling. Prevent Eye contact. Avoid prolonged skin and inhalation contact. Wash thoroughly before handling food. Section 9 Physical Data Appearance: White emulsion. Odor: Acrylic like odor. Physical State: Liquid pH: 9.0 – 10.0 Boiling Point: Approximately 212° F Melting Point: Approximately 32° F Vapor Pressure: N/D Vapor Density: N/D Viscosity: 3000 – 8000 cps (at 74° F) Solubility in Water: Dilutable in water. Page 492 of 495 Page 492 of 495 Page 492 of 495 Page 492 of 495 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated 1-2-3 MSDS (04-15-05) Page 4 of 6 pages. Specific Gravity (water = 1.26 (10.5 lb/gal) Section 10 Stability and Reactivity Stability: This material is stable, not reactive. Hazardous Polymerization: Will not occur. Hazardous Decomposition Products: None known. Conditions to Avoid: None known. Incompatibility: None known. Section 11 Toxicological Information Carcinocenicity: Not considered carcinogen by IARC or NTP and is not regulated as a carcinogen by OSHA. Target Organs Effected: None known. Eye Irritant: This material has been tested for primary eye irritation in accordance with the FHSA. This material is not considered to be a primary eye irritant. Dermal Irritant: This material has been tested for primary dermal irritation in accordance with the FHSA. This material is not considered to be a primary dermal irritant. Inhalation Irritant: This material has been tested for acute oral toxicity in accordance with the FHSA. This material is not considered to be an acute oral toxin. (See also Section 15 for related information) Section 12 Ecological Information Chemical Fate and Effects: No data available. Section 13 Disposal Considerations RCRA Hazardous Waste: No Recommended Waste Disposal Method: This material is not considered hazardous waste under Federal Hazardous Waste Regulations (40CFR 261). However, state and local requirements for waste disposal may be more restrictive or otherwise differ from federal regulations. Chemical additions, processing or otherwise altering this material may render the Page 493 of 495 Page 493 of 495 Page 493 of 495 Page 493 of 495 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated 1-2-3 MSDS (04-15-05) Page 5 of 6 pages. waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Consult all applicable federal, state, and local regulations regarding the proper disposal of this material. Section 14 Transportation Information Not regulated by the US Department of Transportation (DOT) Section 15 Regulatory Information CERCLA: The Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires notification to the National Response Center for releases of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in 40 CFR 302.4 (for CERCLA 102). Components present in this product at a level which could require reporting under the statute are: Chemical Name CAS# Maximum Concentration (Wt. Ethylene Glycol 107-21-1 3% SARA Title III, section 311/312: The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304, 311 and 312). Components present in this product at a level which could require reporting under the statute are: Chemical Name CAS# Maximum Concentration (Wt. None N/A N/A SARA Title III, section 313: The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). Components present in this product at a level which could require reporting under the statute are: Chemical Name CAS# Maximum Concentration (Wt. Ethylene Glycol 107-21-1 3% Zinc Compounds N 982 1% TSCA: The components of this mixture are listed in the Toxic Substance Control Act Inventory of Chemical Substances. Page 494 of 495 Page 494 of 495 Page 494 of 495 Page 494 of 495 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated 1-2-3 MSDS (04-15-05) Page 6 of 6 pages. This product does not contain any chemicals that require export notification under Section 12(b) of the TSCA regulation. Section 16 Other Information Legend: N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required STEL: Short Term Exposure Limit C: OSHA Ceiling Value PPM: Parts Per Million PPB: Parts Per Billion PEL: Permissible Exposure Limit TLV: Threshold Limit Value TWA: Time Weighted Average mg/m3: Milligrams per cubic Meter Million particles per cubic foot of air. ACGIH: American Conference of Governmental Industrial Hygienists OSHA: Occupational Safety and Health Administration (US Dept. of Labor) RCRA: Resource Conservation and recovery Act SARA: Superfund Amendment and Reauthorization Act TSCA: Toxic Substance Control Act FHSA: Federal Hazardous Substance Act Prepared By: Zinsser Health and Safety Manager, Regulatory Compliance Dept. 173 Belmont Drive Somerset, NJ 08875 (732) 469-8100 Disclaimer: Zinsser Company, Inc. believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials and make no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and data and to comply with all applicable international, federal, state, and local laws and regulations. Page 495 of 495 Page 495 of 495 Page 495 of 495 Page 495 of 495