Document douglascountywi_gov_doc_471d2a8d9c

Safety Data Sheets Loading Dock Loading Dock 11/16/2015 ---PAGE BREAK--- Safety Data Sheet Index Binder: Loading Dock - Loading Dock 'LectraSol Safety Solvent Tri-Chem 4 1132-6 - STABIL Fuel Stabilizer GOLD EAGLE COMPANY 07/17/2003 6 1515-01-001 76203 CUTTING OIL 11.75oz (333g) Osborn International 08/27/2013 13 97673 TEF-GEL Lawson Products, Inc. 02/11/2014 17 ACCUCOLOR SANDED GROUT H.B. Fuller Construction Products Inc. 08/28/2012 25 AquaScent Apple Pear AquaScent 31 Battery Cleaner and Acid Detector NOCO COMPANY 03/15/2011 35 Clean Coil SHARE CORPORATION 02/23/2012 39 DIESEL FUEL SUPPLEMENT +CETANE BOOST Power Service Products, Inc. 05/30/2015 41 FENCE POST MIX, FIBER-REINFORCED CONCRETE MIX, CRACK RESISTANT CONCRETE MIX, QUIKRETE 5000 CONCRETE MIX, QUIKRETE 6000 CONCRETE MIX, LIGHTWEIGHT CONCRETE MIX, HANDICRETE CONCRETE MIX, MAXIMUM YIELD CONCRETE MIX, B-CRETE, PRO-FINISH QUIKRETE 5000 The QUIKRETE Companies 08/01/2013 54 FOUNDATION COATING; SAND (TOPPING) MIX; SAND MIX – TYPE II; ALL STAR SAND MIX; HANDICRETE SAND MIX; RITEMIX SAND MIX; DECK MUD; POWERLITE; REVETMENT - RIP RAP BURLAP; 3:1 SAND/CEMENT - BURLAP; VINYL CONCRETE PATCHER; BONDED TOPPING MIX The QUIKRETE Companies 08/29/2011 60 High Performance Cold Patch PLM 66 Hy-Gard Transmission & Hydraulic O John Deere 08/15/1999 68 John Deere Cool Gard II (Concentrate) (TY26573, TY26574) Northland Products Company 02/11/2013 70 John Deere Plus-50 II SAE 15W-40 Northland Products Company 04/02/2012 76 Klean Strip Odorless Mineral Spirits and Odorless Painter's Solvent 64742-47-8 W. M. Barr 04/14/2015 81 Kwikee Penetrating Oil Lawson Products, Inc. 12/16/2013 87 Product Name CAS Number Manufacturer Version Date Page Page 2 of 190 Page 2 of 190 Page 2 of 190 Page 2 of 190 ---PAGE BREAK--- Loggers Choice Bar and Chain Oil Pinnacle Oil, Inc. 91 MiracleGro Tree & Shrub Scott's Miracle Gro 95 PEAK GLOBAL LIFETIME CONCENTRATE ANTIFREEZE & COOLANT Old World Industries, LLC 03/10/2015 107 PEAK Long Life Antifreeze Old World Industries, Inc. 07/20/2009 115 Pennzoil Premium Grease Wheel Bearing 707L Red Shell Canada Products 12/10/2014 127 Permaflex Mixing Concentrate Series 500 NP 452 pearl white SPIES HECKER, Inc. 05/13/2009 134 Rust-Oleium Appliance Epoxy 143 Shell SPIRAX GEAR OIL LS SAE 80W-90 SOPUS Products 07/03/2008 150 Slime SDS Tire Sealant Accessories Marketing Inc 01/22/2014 157 SLUFF Drummond, A Lawson Brand 03/13/2012 165 STIHL 2-CYCLE HP ENGINE OIL OMNI Specialty Packaging 11/18/2013 168 Turf Gard 10W30 John Deere 174 United 101 Moisture Barrier and Electrical Lubricant United Laboratories Inc. 03/17/2003 182 Unleaded Gasoline Gasoline 184 Vinyl Cement Patch Akona Manufacturing, LLC. 11/01/2014 185 Product Name CAS Number Manufacturer Version Date Page Page 3 of 190 Page 3 of 190 Page 3 of 190 Page 3 of 190 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550, MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS LECTRA SOL TC (AEROSOL) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Trichloroethylene (CAS# 79-01-6) >1 50 ppm Carbon Dioxide (CAS# 124-38-9) >1 5000 ppm This product contains 14 ounces of Trichloroethylene per can of product. Trichloroethylene is a regulated chemical under the Emergency Planning and Right-To-Know Act. You are required to file E.P.A. SARA repots once the threshold of 10,000 pounds of Trichloroethylene has been purchased for one location in each calendar year. All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT (ºF) 189° F SPECIFIC GRAVITY (H2O = 1) 1.4 VAPOR PRESSURE (in can PSIG) 95-105 PERCENT VOLATILE BY VOLUME 100 VAPOR DENSITY (AIR = 1) 4 EVAPORATION RATE ( Butyl Acetate faster SOLUBILITY IN WATER insoluble PH N/A APPEARANCE AND ODOR Clear water white liquid with an etherial odor. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) None FLAMMABLE LIMITS 8.0 52.0 EXTINGUISHING MEDIA Use extinguishing media suitable for fighting surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120ºF. (Continued on reverse side) Page 4 of 190 Page 4 of 190 Page 4 of 190 Page 4 of 190 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA THRESHOLD LIMIT VALUE 50 ppm PRIMARY ROUTES OF ENTRY Inhalation x Skin Contact x Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- liquid and vapors may cause irritation. Skin- dry skin, irritation. Inhalation- narcosis, headache, dizziness, carboxyhemoglobinemia. Alcohol consumed before exposure increases effects. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- flush with water and then wash with soap and water, launder contaminated clothing before reuse- get medical if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- DO NOT INDUCE VOMITING- aspiration of material into lungs may cause chemical pneumonitis which can be fatal- get medical attention. Use gastric lavage. Never use adrenalin. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Persons with pre-existing heart or respiratory disorders Carcinogen: NTP IARC OTHER X California Prop 65 SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE x CONDITIONS TO AVOID Temperatures in excess of 120ºF. INCOMPATABILITY (Conditions to avoid) Strong Oxidizers and Alkalies, reactive metals HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon, Hydrogen Chloride, Phosgene MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR x CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Ventilate spill area. Dike area to contain spill and use absorbent material to soak up spill. Shovel or sweep into for container for disposal. WASTE DISPOSAL METHOD Aerosol cans when emptied and depressurized through normal use pose no disposal hazard and should be recycled. Absorbent materials should be disposed of in accordance with all Local, State, and Federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Use NIOSH approved respirator in areas where TLV has been exceeded. LOCAL EXHAUST To control TLV SPECIAL N/A VENTILATION MECHANICAL (General) To control TLV OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical Goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower. SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- do not use in confined, poorly ventilated, or other areas where TLV may be exceeded without proper respiratory protection. Do not take internally. OTHER PRECAUTIONS Do not store in areas where temperatures may exceed 120 degrees F. Keep Out of Reach of Children. HMIS SYMBOL SEVERE 4 SERIOUS 3 MODERATE 2 SLIGHT 1 MINIMAL 0 NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE June 19, 2012 PHONE NUMBER CHEMTREC [PHONE REDACTED] HEALTH 2 FLAMMABILITY 1 REACTIVITY 0 Page 5 of 190 Page 5 of 190 Page 5 of 190 Page 5 of 190 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 1132-6 - STABIL Fuel Stabilizer SEC 1 - PRODUCT AND MANUFACTURER INFO SEC 9 - PHYS, CHEM PROPERTIES SEC 2 - COMPOSITION INFORMATION SEC 10 - STABILITY, REACTIVITY SEC 3 - HAZARDS IDENTIFICATION SEC 11 - TOXICOLOGY INFORMATION SEC 4 - FIRST AID MEASURES SEC 12 - ECOLOGICAL INFORMATION SEC 5 - FIRE FIGHTING MEASURES SEC 13 - DISPOSAL CONSIDERATIONS SEC 6 - ACCIDENTAL RELEASE MEASURES SEC 14 - TRANSPORT INFORMATION SEC 7 - HANDLING AND STORAGE SEC 15 - REGULATORY INFORMATION SEC 8 - EXPOSURE, PERS. PROTECTION SEC 16 - ADDITIONAL INFORMATION SECTION 1 - CHEMICAL PRODUCT AND MANUFACTURER IDENTIFICATION Product Name: 1132-6 - STABIL Fuel Stabilizer Part Number: Product CAS: (None) Product Code: N/A Synonyms: 1132-6 - STABIL Fuel Stabilizer MANUFACTURER IDENTIFICATION Name: Gold Eagle Company Address: 4400 S. Kildare Blvd. City: Chicago State: IL Zip: 60632-4372 For information call: [PHONE REDACTED] Emergency Number: N/A Emergency Agency: INFOTRAC Agency Number: 1-[PHONE REDACTED] MSDS Effective Date: 7/17/2003 MSDS Supersedes Date: 3/1/2013 Miscellaneous: Product CAS: Mixture Brief Description: Fuel stabilizer for gasoline powered engines. Return to top SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS Chemical Name CAS MIN MAX Additive Mixture (none) 0 5 Petroleum Distillate 64742-53-6 0 95 Page 1 of 7 9/11/2013 file://C:\Documents and Settings\Temporary Internet Files\C... Page 6 of 190 Page 6 of 190 Page 6 of 190 Page 6 of 190 ---PAGE BREAK--- Miscellaneous: CHEMICAL NAME LIMIT VALUES Additive Mixture (CAS#:Mixture) N/A Petroleum Distillate N/A Return to top SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: NFPA: Health: 1 Fire: 3 Reactivity: 0 Specific Hazard: None HMIS: Health: 1 Flammability: 3 Reactivity: 0 PPE: B Miscellaneous: This product does not contain any components above de minimus concentrations that are considered carcinogenic by OSHA, IARC or NTP. POTENTIAL HEALTH EFFECTS Target Organs/Primary Route(s) of Entry: Eye: Mild irritant. Skin: Mild irritant Ingestion: Toxicity is relatively low, there is a risk of aspiration of product into the lungs. On ingestion of large quantities, slight GI discomfort diarrhea, and headache may occur. Small doses may produce irritation and diarrhea. Inhalation: Low risk of inhalation. Mists above TLV may cause chemical pneumonitis. Miscellaneous: Return to top SECTION 4 - FIRST AID MEASURES Eye: If the product contacts the eyes, immediately wash the eyes with large quantities of room temperature water for at least 15 minutes, occasionally lifting the lower and upper lids. Get medical attention immediately. Skin: If the product contacts the skin, wash the contaminated skin with soap and water for at least 15 minutes. If this product penetrates the clothing, remove the clothing and wash the skin with soap and water. Ingestion: Do not induce vomiting, product contains petroleum distillate. Get medical Page 2 of 7 9/11/2013 file://C:\Documents and Settings\Temporary Internet Files\C... Page 7 of 190 Page 7 of 190 Page 7 of 190 Page 7 of 190 ---PAGE BREAK--- attention immediately. Inhalation: Move the exposed person to fresh air at once and call emergency medical care. If breathing has stopped, give artificial respiration. If breathing is difficult, give humidified oxygen. Notes to Physician: No data available. Return to top SECTION 5 - FIRE FIGHTING MEASURES Flash Point: 212 F. (101.6 TOC AutoIgnition Temperature: N/A Flammable Limits Lower Limit: Explosive Limit (LEL): 0.8 Upper Limit: Explosive Limit (UEL): 7.0 Extinguishing Media: Use carbon dioxide, dry chemical, foam and/or water fog as extinguishing media. Unusual Fire and Explosion Hazards: Water may cause frothing Special Fire Fighting Procedures: Wear NIOSH approved SCBA respirator in the positive pressure mode and chemical protective clothing. General Information: Flammable Limits: 0.8 to 7.0 Return to top SECTION 6 - ACCIDENTAL RELEASE MEASURES Small Spill: Remove sources of heat or ignition, provide adequate ventilation, contain leak using absorbent, inert, non-combustible material. Large Spill: Contain spill, transfer to secure containers. In the event of an uncontrolled material release, the user should determine if release is reportable under applicable laws and regulations. Return to top SECTION 7 - HANDLING AND STORAGE Handling: See other sections of MSDS. Page 3 of 7 9/11/2013 file://C:\Documents and Settings\Temporary Internet Files\C... Page 8 of 190 Page 8 of 190 Page 8 of 190 Page 8 of 190 ---PAGE BREAK--- Storage: See other sections of MSDS. Return to top SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION GENERAL HYGIENE CONSIDERATIONS: Use normal hygiene practices. OTHER PRECAUTIONS: Product is combustible, handle accordingly. ENGINEERING CONTROLS: Local Exhaust: Provide local ventilation to maintain exposure levels below recommended exposure limits. Mechanical (General): In confined spaces, mechanical ventilation may be required. PERSONAL PROTECTIVE EQUIPMENT Eyes/face: Use splash proof chemical, safety goggles or appropriate full-face respirator. Skin: Use oil impervious gloves as required. Respirators: Normally none is required. If high vapor or mist concentration are expected, use appropriate NIOSH approved respirator for organic vapors and mists. Respirators must be selected based on the airborne levels found in the workplace and must not exceed the working limits of the respirator. Other Protective Clothing/Equipment: If there is a possibility of exposure of an individual's body to the product, wear body-covering work clothes to avoid prolonged or repeated exposure. Return to top SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance/Odor: Red liquid, solvent odor pH: N/A Vapor Pressure: (MM HG): LT 3.0 Vapor Density(Air=1): 4.8 Evaporation Rate: N/A Viscosity: N/A Boiling Point: 180 F. Freezing/Melting Point: N/A Page 4 of 7 9/11/2013 file://C:\Documents and Settings\Temporary Internet Files\C... Page 9 of 190 Page 9 of 190 Page 9 of 190 Page 9 of 190 ---PAGE BREAK--- Decomposition Temperature: N/A Solubility in Water: Negligible Specific Gravity: 0.9 Molecular Formula: N/A Molecular Weight: N/A VOC Coating (minus water): 0 Lbs/Gallon Coating Density : 0 Lbs/Gallon Solvent Density : 0 Lbs/Gallon Percent Solvent (volume): 60 Percent Solids (volume): 0 Percent Water (volume): 0 Percent Volatile by Weight: 0 Miscellaneous: % Volatile/Volume: 100.0 Percent Solvent (Volume): N/A Percent Solids (Volume): N/A Percent Water (Volume): N/A Product is combustible, keep away from sources of ignition, oxidizing materials and acid. Store in an area equipped with automatic sprinklers or fire extinguishing system. Empty containers contain product residues, assume emptied containers to have same hazards as full containers. Return to top SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable: Yes Conditions to Avoid: Store below 150 F. Do not apply high heat or flame to container. Keep separate from strong oxidizing agents. Incompatibilities with Other Materials: Strong oxidants. Hazardous Decomposition Products: Excessive heating and/or incomplete combustion will produce carbon monoxide. Hazardous Polymerization: Hazardous polymerization may occur: No Page 5 of 7 9/11/2013 file://C:\Documents and Settings\Temporary Internet Files\C... Page 10 of 190 Page 10 of 190 Page 10 of 190 Page 10 of 190 ---PAGE BREAK--- Return to top SECTION 11 - TOXICOLOGICAL INFORMATION No data available. Return to top SECTION 12 - ECOLOGICAL INFORMATION No data available. Return to top SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of product in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections of MSDS for hazard warning information. Return to top SECTION 14 - TRANSPORT INFORMATION Transportation Information: Shipping Information (CFR 49 and IMDG): Proper Shipping Name: Gasoline Additive, N.O.I. DOT Hazard Class: None required (Flashpoint GT 200 DOT UN Number: None required. IMDG Shipping Name: Non-Hazardous Gasoline Additive Flashpoint GT 200 F. Label Information: No data available. Return to top SECTION 15 - REGULATORY INFORMATION SARA Title III: Section 302: None Section 304: None Section 311: None Section 313: None CERCLA: Section 311(b)(4): Requires discharges of crude oil and petroleum products in any kind or form to waters must immediately be reported to the National Response Center at (800) 424-8802. Return to top Page 6 of 7 9/11/2013 file://C:\Documents and Settings\Temporary Internet Files\C... Page 11 of 190 Page 11 of 190 Page 11 of 190 Page 11 of 190 ---PAGE BREAK--- SECTION 16 - ADDITIONAL INFORMATION Disclaimer: Information presented herein is believed to be factual, as it has been derived from the works and opinions of persons believed to be qualified experts. However, nothing contained in this information is to be taken as warranty or representation for which the Gold Eagle Co. bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate. Prepared by: Mike Profetto Return to top Page 7 of 7 9/11/2013 file://C:\Documents and Settings\Temporary Internet Files\C... Page 12 of 190 Page 12 of 190 Page 12 of 190 Page 12 of 190 ---PAGE BREAK--- 00007082 MATERIAL SAFETY DATA SHEET Page 1 OSBORN INTERNATIONAL 1100 RESOURCE DRIVE, SUITE 1 BROOKLYN HEIGHTS,; OH; 44131 USA PRODUCT: 1515-01-001 76203 CUTTING OIL 11.75oz (333g) Section 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER MANUFACTURED FOR: OSBORN INTERNATIONAL 1100 RESOURCE DRIVE, SUITE 1 BROOKLYN HEIGHTS, OH 44131 USA [PHONE REDACTED] PRODUCT 1515-01-001 76203 CUTTING OIL 11.75oz (333g) CHEMICAL PETROLEUM. MOLECULAR NOT APPLICABLE. CHEMICAL MIXTURE. TRADE NAMES & 1515-01-001 76203 CUTTING OIL 11.75oz (333g) PRODUCT CUTTING OIL. FORMULA/LAB BOOK 9700-00-018. Section 02: COMPOSITION/INFORMATION INGREDIENTS Hazardous Ingredients % Exposure Limit C.A.S.# LD/50, Route,Species LC/50 Route,Species PETROLEUM HYDROCARBON 60-100 5 mg/m3 NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE MIXTURE ISOBUTANE 3-7 1000 ppm 75-28-5 NOT APPLICABLE 142,500 ppm (4h) INHAL - RAT PROPANE 5-10 1000 ppm 74-98-6 >5000 mg/kg NOT AVAILABLE DERMAL-RABBITS Section 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY: MAY CAUSE HEADACHE, NAUSEA, VOMITING AND WEAKNESS. INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLANT IS A SIMPLE EYE MAY CAUSE IRRITATION. SKIN MAY BE ABSORBED BY THE SKIN. SKIN MAY CAUSE IRRITATION. EFFECTS OF ACUTE DIZZINESS, NAUSEA. IRRITATION TO SKIN & EYES. EFFECTS OF CHRONIC EXPOSURE......... SOLVENTS MAY CAUSE DEFATTING DERMATITIS . EXPOSURE LIMIT OF SEE SECTION 2. Section 04: FIRST AID MEASURES EMERGENCY FIRST AID PROCEDURE IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION. Section 05: FIRE FIGHTING MEASURES AUTO IGNITION TEMPERATURE NOT AVAILABLE. SPECIAL WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILD-UP IF EXPOSED TO EXTREME TEMPERATURES. FULL PROTECTIVE EQUIPMENT INCLUDING SELF CONTAINED BREATHING APPARTATUS SHOULD BE WORN IN A FIRE INVOLVING THIS MATERIAL. NO.SPRAY HAS NO FLAME EXTENSION. IF YES, UNDER WHICH CONDITIONS?..... EXCESSIVE HEAT, SPARKS AND OPEN FLAME. EXTINGUISHING WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM. UPPER FLAMMABLE 9.5. BY VOLUME) LOWER FLAMMABLE 2.6. BY VOLUME) EXPLOSION DATA Page 13 of 190 Page 13 of 190 Page 13 of 190 Page 13 of 190 ---PAGE BREAK--- 00007082 MATERIAL SAFETY DATA SHEET Page 2 PRODUCT: 1515-01-001 76203 CUTTING OIL 11.75oz (333g) Section 05: FIRE FIGHTING MEASURES SENSITIVITY TO STATIC DISCHARGE. NOT APPLICABLE. SENSITIVITY TO NOT APPLICABLE. HAZARDOUS COMBUSTION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE COMBUSTION IS INCOMPLETE. AEROSOL FLAME PROJECTION CLASSIFIED 0-15cm. NONE. FLASH POINT(°C),TAG CLOSED-CUP 171. (CONCENTRATE) Section 06: ACCIDENTAL RELEASE MEASURES REMOVE ALL SOURCES OF IGNITION. USE AN INERT ABSORBENT MATERIAL, AND NON-SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSE. Section 07: HANDLING AND STORAGE STORAGE KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMES. ENGINEERING VENTILATION - LOCAL (MECHANICAL IF USED INDOORS ON A CONTINUOUS BASIS). HANDLING PROCEDURES AND STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C. EQUIPMENT SYNERGISTIC NONE KNOWN. Section 08: EXPOSURE CONTROLS/PERSONAL PROTECTION GLOVES/ WEAR CHEMICAL RESISTANT GLOVES. IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE RESPIRATOR (NIOSH/MSHATC 23C OR EQUIVALENT) IS RECOMMENDED. SAFETY GLASSES. NOT NORMALLY REQUIRED. NOT REQUIRED. Section 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL AEROSOL. DARK BROWN. HYDROCARBON. ODOR Oil mist 5mg/m3 (IF GENERATED). VAPOUR PRESSURE(PSIG)-AEROSOL..... 50-65. @ 20 C BOILING POINT >271. EVAPORATION LESS THAN 1. n-BUTYL ACETATE = 1 VAPOUR DENSITY GREATER THAN 1. (BY WEIGHT) SOLUBILITY IN WATER g/L NEGLIGIBLE. NOT APPLICABLE. SPECIFIC GRAVITY 0.90-0.94. COEFFICIENT OF WATER\OIL NOT AVAILABLE. FREEZING POINT: NOT AVAILABLE. AEROSOL PERCENT 12-13. (BY WEIGHT). SPECIFIC GRAVITY 0.82-0.86. Section 10: STABILITY AND REACTIVITY HAZARDOUS PRODUCTS OF HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE COMBUSTION IS INCOMPLETE. CHEMICAL STABILITY: UNDER NORMAL CONDITIONS. NO, WHICH NOT APPLICABLE. COMPATIBILITY WITH OTHER SUBSTANCES: NO, WHICH STRONG OXIDIZING AGENTS. REACTIVITY NOT APPLICABLE. HAZARDOUS POLYMERIZATION............... WILL NOT OCCUR. Page 14 of 190 Page 14 of 190 Page 14 of 190 Page 14 of 190 ---PAGE BREAK--- 00007082 MATERIAL SAFETY DATA SHEET Page 3 PRODUCT: 1515-01-001 76203 CUTTING OIL 11.75oz (333g) Section 11: TOXICOLOGICAL INFORMATION REPRODUCTIVE NO INFORMATION IS AVAILABLE AND NO ADVERSE REPRODUCTIVE EFFECTS ARE ANTICIPATED. IRRITANCY OF SKIN/EYE IRRITANT. SENSITIZING CAPABILITY OF MATERIAL. UNKNOWN. CARCINOGENICITY OF MATERIAL............ THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOT REGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BY IARC,(INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR BY ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS). NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENIC EFFECTS ARE ANTICIPATED. NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC EFFECTS ARE ANTICIPATED. Section 12: ECOLOGICAL CONSIDERATIONS NOT AVAILABLE. Section 13: DISPOSAL CONSIDERATIONS WASTE DO NOT PUNCTURE OR INCINERATE CONTAINERS, EVEN WHEN EMPTY. DISPOSE OF IN ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS. Section 14: TRANSPORTATION INFORMATION D.O.T. CONSUMER COMMODITY, ORM-D. T.D.G. CONSUMER COMMODITY (AEROSOLS, UN1950, CLASS 2.1). Section 15: REGULATORY INFORMATION CANADIAN REGULATIONS: WHMIS A,D2B. CNFC SECTION LEVEL 3. CEPA (Canadian Enviromental Protection ALL SUBSTANCES IN THIS PRODUCT ARE LISTED ON THE CANADIAN DOMESTIC Act) SUBSTANCES LIST (DSL) OR ARE NOT REQUIRED TO BE LISTED. U.S. REGULATIONS: HMIS RATING 1 SLIGHT HAZARD. HMIS RATING 1 SLIGHT HAZARD. HMIS RATING 0 MINIMAL HAZARD. HMIS RATING PERSONAL PROTECTION.. B. NFPA CODE LEVEL 3. SARA 313 THIS PRODUCT CONTAINS NO INGREDIENTS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372. . CAS CHEMICAL NAME: . N/A. CALIFORNIA PROPOSITION THE FOLLOWING STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986: . WARNING: THIS PRODUCT DOES NOT INTENTIONALLY CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. . CAS CHEMICAL NAME: . N/A. TSCA (Toxic Substances Control ALL COMPONENT OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. ANY IMPURITIES PRESENT IN THIS PRODUCT ARE EXEMPT FROM LISTING. VOC 12-13. Section 16: OTHER INFORMATION NOTICE FROM OSBORN INTERNATIONAL THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET IS PROVIDED BY OSBORN INTERNATIONAL FREE OF CHARGE. WHILE BELIEVED TO BE RELIABLE, IT IS INTENDED FOR USE BY SKILLED PERSONS AT THEIR OWN RISK. OSBORN INTERNATIONAL ASSUMES NO RESPONSIBILITY FOR EVENTS RESULTING OR DAMAGES INCURRED FROM ITS USE. THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS. PREPARED Regulatory Affairs Page 15 of 190 Page 15 of 190 Page 15 of 190 Page 15 of 190 ---PAGE BREAK--- 00007082 MATERIAL SAFETY DATA SHEET Page 4 PRODUCT: 1515-01-001 76203 CUTTING OIL 11.75oz (333g) Section 16: OTHER INFORMATION PREPARATION DATE Aug27/13 Page 16 of 190 Page 16 of 190 Page 16 of 190 Page 16 of 190 ---PAGE BREAK--- SAFETY DATA SHEET. Issuing date 11-Feb-2014 Revision Date 11-Feb-2014 Version 1 Page 1 / 8 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product name 97673 TEF-GEL Recommended use of the chemical and restrictions on use Product code F00829 Product Type Extremely flammable aerosol Synonyms Supplier's details Recommended Use Gel Lubricant. Uses advised against Manufactured For: Lawson Products, Inc 8770 W. Bryn Mawr Avenue - Suite 900 Chicago, IL 60631-3515 Emergency telephone number Company Emergency Phone Number [PHONE REDACTED] Page 17 of 190 Page 17 of 190 Page 17 of 190 Page 17 of 190 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 2 / 8 2. HAZARDS IDENTIFICATION Classification Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Aspiration toxicity Category 1 Flammable aerosols Category 1 GHS Label elements, including precautionary statements Emergency Overview DANGER Hazard Statements May cause genetic defects May cause cancer May be fatal if swallowed and enters airways Extremely flammable aerosol Appearance Hazy Physical state Aerosol Odor Solvent Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information • May be harmful in contact with skin 16.86256% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS # 64742-49-0, COMMERCIAL HEXANES, MAY BE SUBSTITUTED FOR CAS #110-54-3. Synonyms . Page 18 of 190 Page 18 of 190 Page 18 of 190 Page 18 of 190 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 3 / 8 Chemical Name CAS-No Weight % HEXANE 64742-49-0 60 - 70% PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 10 - 20% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Inhalation Move to fresh air. If persist, call a physician. Ingestion Do NOT induce vomiting. If persist, call a physician. Most important acute and delayed Main Not applicable. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. Specific hazards arising from the chemical No information available. Explosion Data Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Page 19 of 190 Page 19 of 190 Page 19 of 190 Page 19 of 190 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 4 / 8 Environmental precautions No special environmental precautions required. Methods and materials for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Conditions for safe storage, including any incompatibilities Technical measures/Storage conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known based on information supplied. Aerosol Level 3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . ACGIH: (American Conference of Governmental Industrial Hygienists) OSHA: (Occupational Safety & Health Administration) NIOSH IDLH: Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Exposure controls Engineering Measures Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Safety glasses with side-shields. Skin and body protection Chemical resistant apron. Protective gloves. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 20 of 190 Page 20 of 190 Page 20 of 190 Page 20 of 190 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 5 / 8 Physical and chemical properties Physical state Aerosol Appearance Hazy Odor Solvent Color amber Odor Threshold No information available Property Values Remarks • Methods pH No information available not applicable Melting/freezing point No information available Boiling point/boiling range No information available Flash Point -96.4 °C / -141 °F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air upper flammability limit No information available lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific Gravity 0.720 Water solubility Practically insoluble Partition coefficient: n-octanol/water No information available Autoignition temperature No information available Not applicable Decomposition temperature No information available Viscosity No information available Explosive properties No information available Other information VOC Content(%) 78.76 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Product does not present an acute toxicity hazard based on known information Inhalation There is no data available for this product. Eye contact There is no data available for this product. Page 21 of 190 Page 21 of 190 Page 21 of 190 Page 21 of 190 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 6 / 8 Skin contact There is no data available for this product. Ingestion There is no data available for this product. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation HEXANE 64742-49-0 > 5000 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) 73680 ppm ( Rat ) 4 h Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ Cell Mutagenicity No information available. Carcinogenicity There are no known carcinogenic chemicals in this product. This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). Reproductive toxicity No information available. Specific target organ systemic toxicity (single exposure) No information available. Specific target organ systemic toxicity (repeated exposure) No information available. Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin. Aspiration hazard No information available. Numerical measures of toxicity - Product Information Unknown Aquatic Toxicty 16.86256% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 6980 mg/kg ATEmix (dermal) 4702 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates HEXANE 64742-49-0 2.6: 96 h Chaetogammarus marinus mg/L LC50 Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name log Pow PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 2.8 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Page 22 of 190 Page 22 of 190 Page 22 of 190 Page 22 of 190 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 7 / 8 Waste treatment Waste Disposal Methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not re-use empty containers. 14. TRANSPORT INFORMATION DOT Ground CONSUMER COMMODITY ORM-D or LIMITED QUANTITY IATA UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD. QTY. IMDG UN1950, AEROSOLS, 2.1, LTD. QTY. 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS HEXANE X X X X X Present X X PROPANE/ISOBUTAN E/N-BUTANE X X X Not listed X Present X X TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances CHINA - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard no Reactive Hazard no Page 23 of 190 Page 23 of 190 Page 23 of 190 Page 23 of 190 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 8 / 8 Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): U.S. State Regulations California Proposition 65 This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 4 Instability 0 Physical and chemical hazards - HMIS Health Hazard 2* Flammability 4 Physical Hazard 1 Personal protection B Chronic Hazard Star Legend Chronic Health Hazard; Repeated or prolonged exposure may cause central nervous system damage Prepared By Maureen Ruggeberg, Regulatory Affairs Specialist Issuing date 11-Feb-2014 Revision Date 11-Feb-2014 Revision Note No information available Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 24 of 190 Page 24 of 190 Page 24 of 190 Page 24 of 190 ---PAGE BREAK--- Page 1 of 6 10-02-2012 805153PM MATERIAL SAFETY DATA SHEET REVISION DATE: 08-28-2012 SUPERSEDES: 08-24-2009 SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION COMPANY INFORMATION H.B. Fuller Construction Products Inc. 1105 S. Frontenac Street Aurora, IL 60504 Phone: 1-[PHONE REDACTED] Medical Emergency Phone Number (24 Hours): 1-[PHONE REDACTED] Transport Emergency Phone Number (CHEMTREC): 1-[PHONE REDACTED] PRODUCT INFORMATION PRODUCT NUMBER: TA0650 957 PRODUCT NAME: ACCUCOLOR SANDED GROUT PRODUCT DESCRIPTION: Cement PRODUCT IDENTIFIER: 805153PM SECTION 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW PHYSICAL STATE: Solid COLOR: Opaque Gray ODOR: Odorless Moderate eye irritant. Causes skin irritation. Moderate respiratory tract irritant. Harmful if swallowed. Cancer hazard. POTENTIAL HEALTH EFFECTS BY ROUTE OF ENTRY EYE: Can cause moderate irritation, tearing and reddening. SKIN: Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. INHALATION: Can cause moderate respiratory irritation. Inhalation of dusts produced during cutting, grinding or sanding of this product may cause irritation of the respiratory tract. Nasal perforation is possible from a single large or repeated smaller inhalation overexposures. Overexposure to silica may cause silicosis. Overexposure to iron oxide dust/fume may cause siderosis. Inhalation of high concentrations may result in central nervous system (CNS) effects such as dizziness, weakness, fatigue, nausea, headache, and lack of coordination. Overexposure to nickel dust may cause perforated nasal septum, chest pain, coughing, lung disease, cyanosis, and blood disorders. INGESTION: Ingestion is not an anticipated route of exposure. Harmful if swallowed. Severely irritating to mouth, throat, and stomach. LONG-TERM (CHRONIC) HEALTH EFFECTS TARGET ORGAN(S): Lungs Central nervous system Skin REGULATED CARCINOGEN STATUS: Unless noted below, this product does not contain regulated levels of NTP, IARC, ACGIH, or OSHA listed carcinogens. silica Titanium dioxide Nickel compounds Page 25 of 190 Page 25 of 190 Page 25 of 190 Page 25 of 190 ---PAGE BREAK--- Page 2 of 6 10-02-2012 805153PM MATERIAL SAFETY DATA SHEET EXISTING HEALTH CONDITIONS AFFECTED BY EXPOSURE: Lung disease; Skin disease including eczema and sensitization SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS # PERCENT silica 14808-60-7 50 - 70 Portland cement 65997-15-1 10 - 30 Calcium carbonate 471-34-1 5 - 10 Iron oxide 1309-37-1 1 - 5 Calcium sulfate 7778-18-9 1 - 5 Calcium oxide, CaO 1305-78-8 1 - 5 Magnesium Oxide 1309-48-4 1 - 5 Titanium dioxide 13463-67-7 0.1 - 1 Nickel compounds 0.1 - 1 Unlisted ingredients are not 'hazardous' per the Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200) and/or are not found on the Canadian Workplace Hazardous Materials Information System ingredient disclosure list. See Section 8 for exposure limit guidelines. SECTION 4: FIRST AID MEASURES IF IN EYES: Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention. IF ON SKIN: Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. IF VAPORS INHALED: Remove to fresh air. Restore breathing, if necessary. Call a physician if persist. IF SWALLOWED: Severely irritating. Do not induce vomiting. Seek medical attention immediately. Drink 2 glasses of water or milk to dilute. Do not give anything by mouth to an unconscious person. SECTION 5: FIRE FIGHTING MEASURES FLASH POINT: Non flammable AUTOIGNITION TEMPERATURE: Not established LOWER EXPLOSIVE LIMIT in air): Not established UPPER EXPLOSIVE LIMIT in air): Not established EXTINGUISHING MEDIA: Use methods suitable to fight surrounding fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: Material will not burn. SPECIAL FIRE FIGHTING INSTRUCTIONS: Use methods for the surrounding fire. HAZARDOUS COMBUSTION PRODUCTS: Carbon dioxide, Carbon monoxide Sulfur containing gases SECTION 6: ACCIDENTAL RELEASE MEASURES SPECIAL PROTECTION: Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this MSDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Page 26 of 190 Page 26 of 190 Page 26 of 190 Page 26 of 190 ---PAGE BREAK--- Page 3 of 6 10-02-2012 805153PM MATERIAL SAFETY DATA SHEET CLEAN-UP: Avoid creating dusts. Cover material with absorbent and moisten and collect for disposal. Transport Emergency Phone Number (CHEMTREC): 1-[PHONE REDACTED] SECTION 7: HANDLING AND STORAGE Handling: Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Avoid breathing material. This product contains an ingredient that may release formaldehyde at heated cure temperatures. Storage: Store in a cool, dry place. Consult the Technical Data Sheet for specific storage instructions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION: Wear safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne material. Have an eye wash station available. SKIN PROTECTION: Avoid skin contact by wearing chemically resistant gloves and long sleeved shirt. An apron may be appropriate if splashing can occur. GLOVES: Nitrile RESPIRATORY PROTECTION: Respiratory protection may be required to avoid overexposure when handling this product. Use a respirator if general room ventilation is not available or sufficient to eliminate NIOSH approved air purifying respirator with dust/mist filter. Respirators should be selected by and used following requirements found in OSHA's respirator standard (29 CFR 1910.134). VENTILATION: Use local exhaust ventilation or other engineering controls to minimize exposures. EXPOSURE LIMITS: Chemical Name ACGIH EXPOSURE LIMITS OSHA PEL silica 0.025 mg/m3 TWA (respirable fraction) ((250)/(%SiO2 + 5) TWA (respirable)); ((10)/(%SiO2 + 2) mg/m3 TWA (respirable)); ((30)/(%SiO2 + 2) mg/m3 TWA (total dust)) Portland cement 1 mg/m3 TWA (particulate matter containing no asbestos and silica, respirable fraction) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Calcium carbonate Not established 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Iron oxide 5 mg/m3 TWA (respirable fraction) 10 mg/m3 TWA (as fume) Calcium sulfate 10 mg/m3 TWA (inhalable fraction) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Calcium oxide, CaO 2 mg/m3 TWA 5 mg/m3 TWA Magnesium Oxide 10 mg/m3 TWA (inhalable fraction) 15 mg/m3 TWA (total particulate) (as fume) Titanium dioxide 10 mg/m3 TWA 15 mg/m3 TWA (total dust) Page 27 of 190 Page 27 of 190 Page 27 of 190 Page 27 of 190 ---PAGE BREAK--- Page 4 of 6 10-02-2012 805153PM MATERIAL SAFETY DATA SHEET Nickel compounds 0.1 mg/m3 TWA (inhalable fraction, as Ni, soluble inorganic compounds); 0.1 mg/m3 TWA (inhalable fraction, as Ni, insoluble inorganic compounds) 1 mg/m3 TWA (as Ni) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Solid COLOR: Opaque Gray ODOR: Odorless ODOR THRESHOLD: Not established WEIGHT PER GALLON (lbs.): 11.60 SPECIFIC GRAVITY: 1.390 SOLIDS by weight): 100.0 Not applicable pH: Not established FLASH POINT: Non flammable BOILING POINT (deg. Not established FREEZING/MELTING POINT (deg. Not established VAPOR PRESSURE (mm Hg): Not established VAPOR DENSITY: Not established EVAPORATION RATE: Not established OCTANOL/WATER COEFFICIENT: Not established VOC, weight percent 0.00 SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. CHEMICAL INCOMPATIBILITY: Not established HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide Sulfur containing gases SECTION 11: TOXICOLOGICAL INFORMATION COMPONENT LD50/LC50 silica Not established Portland cement Not established Calcium carbonate Oral LD50 Rat = 6,450 mg/kg Iron oxide Not established Calcium sulfate Not established Calcium oxide, CaO Not established Magnesium Oxide Not established Titanium dioxide Not established Nickel compounds Not established TOXICOLOGY SUMMARY: No additional health information available. Page 28 of 190 Page 28 of 190 Page 28 of 190 Page 28 of 190 ---PAGE BREAK--- Page 5 of 6 10-02-2012 805153PM MATERIAL SAFETY DATA SHEET SECTION 12: ECOLOGICAL INFORMATION OVERVIEW: No ecological information available SECTION 13: DISPOSAL CONSIDERATIONS To the best of our knowledge, this product does not meet the definition of hazardous waste under the U.S. EPA Hazardous Waste Regulations 40 CFR 261. Dispose of in an approved landfill. Consult your state, local or provincial authorities and your local waste vendor for more restrictive requirements. SECTION 14: TRANSPORTATION INFORMATION Consult Bill of Lading for transportation information. DOT: NOT REGULATED IATA: NOT REGULATED SECTION 15: REGULATORY INFORMATION INVENTORY STATUS U.S. EPA TSCA: This product is in compliance with the Toxic Substances Control Act's Inventory requirements. CANADIAN CEPA DSL: The components of this product are included on the DSL or are exempt from DSL requirements. EUROPEAN EINECS: As a result of the introduction of REACH into Europe, this product cannot be imported into Europe unless the REACH requirements are met. If you need more information about the inventory status of this product call [PHONE REDACTED]. This product may contain chemical substances that are regulated for export by various government agencies (such as the Environmental Protection Agency, the Bureau of Industry and Security, or the Drug Enforcement Administration, among others). Before exporting this product from the USA or Canada, we recommend you contact us at [PHONE REDACTED] (USA) or [PHONE REDACTED] x227 (Canada) to request an export review. FEDERAL REPORTING EPA SARA Title III Section 313 Unless listed below, this product does not contain toxic chemical(s) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR part 372. EPA has advised that when a percentage range is listed the midpoint may be used to fulfill reporting obligations. Chemical Name CAS# % Nickel compounds 0.1 - 1 WHMIS STATUS: Unless listed below, this product is not controlled under the Canadian Workplace Hazardous Materials Information System. D2A D2B STATE REPORTING Proposition 65, The Safe Drinking Water and Toxic Enforcement Act of 1986: Unless listed below, this product does not contain known levels of any chemical known to the State of California to cause cancer or reproductive harm. Chemical Name/List CAS Percent Quartz (Carcinogen) 14808-60-7 50 - 70 Titanium dioxide (Carcinogen) 13463-67-7 0.1 - 1 Nickel (Carcinogen) 0.1 - 1 Methanol (Developmental toxin) 67-56-1 < 10 ppm Page 29 of 190 Page 29 of 190 Page 29 of 190 Page 29 of 190 ---PAGE BREAK--- Page 6 of 6 10-02-2012 805153PM MATERIAL SAFETY DATA SHEET SECTION 16: ADDITIONAL INFORMATION This Material Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200) and the Canadian Workplace Hazardous Materials Information System (WHMIS). HMIS RATING: HEALTH 2 FLAMMABILITY 0 REACTIVITY 0 See SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for personal protective equipment recommendations. Prepared by: The Global Regulatory Department Phone: [PHONE REDACTED] The information and recommendations set forth herein are believed to be accurate. Because some of the information is derived from information provided to H.B. Fuller Construction Products, Inc. from its suppliers, and because H.B. Fuller Construction Products, Inc. has no control over the conditions of handling and use, H.B. Fuller Construction Products, Inc. makes no warranty, expressed or implied, regarding the accuracy of the data or the results to be obtained from the use thereof. The information is supplied solely for your information and consideration, and H.B. Fuller Construction Products, Inc. assumes no responsibility for use or reliance thereon. It is the responsibility of the user of H.B. Fuller Construction Products, Inc. products to comply with all applicable federal, state and local laws and regulations. Page 30 of 190 Page 30 of 190 Page 30 of 190 Page 30 of 190 ---PAGE BREAK--- Material Safety Data Sheet Material Name: AquaScent (Apple-Pear) Page 1 of 4 Issue Date: 09/24/08 Revision: 1.0000 Print Date: 11/3/2008 * * * Section 1 - Chemical Product and Company Identification * * * Manufactured for F-MATIC Inc. Phone: [PHONE REDACTED] 299 S Millpond Dr Fax: [PHONE REDACTED] Lehi, UT 84043 * * * Section 2 - Hazards Identification * * * Emergency Overview May cause skin and eye irritation. Potential Health Effects: Eyes May cause eye irritation. Potential Health Effects: Skin May cause irritation. Potential Health Effects: Ingestion Not a likely route of exposure under normal product use conditions. May cause gastrointestinal irritation if swallowed. Potential Health Effects: Inhalation None anticipated under normal product use conditions. May cause dizziness and nausea from prolonged inhalation. HMIS Ratings: Health: 1 Fire: 1 HMIS Reactivity 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard * * * Section 3 - Composition / Information on Ingredients * * * CAS # Component 51229-78-8 3,5,7-Triaza-1-azoniatricyclo[3.3.1.13, ]decane, 1-(3-chloro-2-propenyl)-, chloride, 8050-81-5 Simethicone 1934-21-0 FD&C yellow No. 5 2353-45-9 Fast green Trade Secret Fragrance 7732-18-5 Water * * * Section 4 - First Aid Measures * * * First Aid: Eyes Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists get medical attention. First Aid: Skin For skin contact, wash immediately with soap and water. First Aid: Ingestion If the material is swallowed, get immediate medical attention or advice Do not induce vomiting. First Aid: Inhalation Move person to non-contaminated air. If the affected person is not breathing, apply artificial respiration. * * * Section 5 - Fire Fighting Measures * * * General Fire Hazards See Section 9 for Flammability Properties. None Hazardous Combustion Products Not Determined. Extinguishing Media Use extinguishing media appropriate for surrounding fire. Fire Fighting Equipment/Instructions Firefighters should wear full protective gear. Page 31 of 190 Page 31 of 190 Page 31 of 190 Page 31 of 190 ---PAGE BREAK--- Material Safety Data Sheet Material Name: AquaScent (Apple-Pear) Page 2 of 4 Issue Date: 09/24/08 Revision: 1.0000 Print Date: 11/3/2008 NFPA Ratings: Health: 1 Fire: 1 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures Contain the discharged material. Clean-Up Procedures Contain spilled material with a suitable absorbent material. Evacuation Procedures Isolate area. Keep unnecessary personnel away. Special Procedures Follow all Local, State, Federal and Provincial regulations for disposal. * * * Section 7 - Handling and Storage * * * Handling Procedures No special handling procedures necessary. Storage Procedures Keep this material in a cool, well-ventilated place. * * * Section 8 - Exposure Controls / Personal Protection * * * A: Component Exposure Limits ACGIH, OSHA, and NIOSH have not developed exposure limits for any of this product's components. Engineering Controls Local exhaust is suggested for use, where possible, in enclosed or confined spaces. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Wear safety glasses with side shields. Personal Protective Equipment: Skin None necessary. Personal Protective Equipment: Respiratory Not normally needed. Personal Protective Equipment: General Eye wash fountain is recommended. * * * Section 9 - Physical & Chemical Properties * * * Appearance: Light Green Odor: Apple-Pear Physical State: Liquid pH: ND Vapor Pressure: ND Vapor Density: ND Boiling Point: >100°C Melting Point: ND Solubility (H2O): Complete Specific Gravity: 1.028@25°C Octanol/H2O Coeff.: ND Flash Point: NA Flash Point Method: ND Upper Flammability Limit (UFL): NA Lower Flammability Limit (LFL): NA Burning Rate: NA Auto Ignition: NA * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability This is a stable material. Chemical Stability: Conditions to Avoid None Incompatibility None Hazardous Decomposition Not Determined Page 32 of 190 Page 32 of 190 Page 32 of 190 Page 32 of 190 ---PAGE BREAK--- Material Safety Data Sheet Material Name: AquaScent (Apple-Pear) Page 3 of 4 Issue Date: 09/24/08 Revision: 1.0000 Print Date: 11/3/2008 Possibility of Hazardous Reactions Will not occur. * * * Section 11 - Toxicological Information * * * Acute Dose Effects A: General Product Information No information available for the product. B: Component Analysis - LD50/LC50 FD&C yellow No. 5 (1934-21-0) Oral LD50 Mouse: 12750 mg/kg Fast green (2353-45-9) Oral LD50 Rat: >2 g/kg Water (7732-18-5) Oral LD50 Rat: >90 mL/kg Carcinogenicity A: General Product Information No information available for the product. B: Component Carcinogenicity Fast green (2353-45-9) IARC: Supplement 7 [1987], Monograph 16 [1978] (Group 3 (not classifiable)) * * * Section 12 - Ecological Information * * * Ecotoxicity A: General Product Information No information available for the product. B: Component Analysis - Ecotoxicity - Aquatic Toxicity No ecotoxicity data are available for this product's components. * * * Section 13 - Disposal Considerations * * * US EPA Waste Number & Descriptions Component Waste Numbers No EPA Waste Numbers are applicable for this product's components. Disposal Instructions All wastes must be handled in accordance with local, state and federal regulations. See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations. * * * Section 14 - Transportation Information * * * US DOT Information Shipping Name: Not Regulated * * * Section 15 - Regulatory Information * * * US Federal Regulations Component Analysis None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4). State Regulations Page 33 of 190 Page 33 of 190 Page 33 of 190 Page 33 of 190 ---PAGE BREAK--- Material Safety Data Sheet Material Name: AquaScent (Apple-Pear) Page 4 of 4 Issue Date: 09/24/08 Revision: 1.0000 Print Date: 11/3/2008 Component Analysis - State The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA RI Fast green 2353-45-9 Yes No No No No No Component Analysis - WHMIS IDL No components are listed in the WHMIS IDL. Additional Regulatory Information Component Analysis - Inventory Component CAS # TSCA CAN EEC FD&C yellow No. 5 1934-21-0 Yes DSL EINECS Fast green 2353-45-9 Yes DSL EINECS 3,5,7-Triaza-1-azoniatricyclo[3.3.1.13, ]decane, 1-(3- chloro-2-propenyl)-, chloride, 51229-78-8 No DSL ELINCS Water 7732-18-5 Yes DSL EINECS Simethicone 8050-81-5 No DSL No * * * Section 16 - Other Information * * * Other Information The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial, and local laws. Key/Legend EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration., = New Jersey Trade Secret Registry. Page 34 of 190 Page 34 of 190 Page 34 of 190 Page 34 of 190 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET E404 Section I PRODUCT & COMPANY IDENTIFICATION PRODUCT NUMBER E404 PRODUCT NAME Battery Cleaner and Acid Detector HMIS CODES Health: 2, Flammability: 4, Reactivity: 0 MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. DATE OF PREPARATION The Noco® Company (800) 424-9300 15-MARCH-2011 Cleveland, OH 44122 INFORMATION TELEPHONE NO. (800) 456-6626 Section II COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 3 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 7 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 6 67-63-0 2-Propanol ACGIH TLV 400 ppm 33 mm ACGIH TLV 500 ppm STEL OSHA PEL 400 ppm OSHA PEL 500 ppm STEL 1 1333-86-4 Carbon Black ACGIH TLV 3.5 mg/m3 OSHA PEL 150 ppm Section III HAZARDOUS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE Irritation of eyes, skin and upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. MSDS Continued on page 2 Page 35 of 190 Page 35 of 190 Page 35 of 190 Page 35 of 190 ---PAGE BREAK--- Section IV FIRST AID MEASURES If INHALED: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWED: Do not induce vomiting. Get medical attention immediately. Section V FIRE FIGHTING MEASURES FLASH POINT LEL UEL Propellant <0 °F 1.9 12.7 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode (due to the build-up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decompositon products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build- up and possible autoignition or explosion when exposed to extreme heat. Section VI ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section VII HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120 Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Section VIII EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. Continued on page 3 E404 PAGE 2 Page 36 of 190 Page 36 of 190 Page 36 of 190 Page 36 of 190 ---PAGE BREAK--- EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section IX PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.70 lb/gal 922 g/l SPECIFIC GRAVITY 0.93 BOILING POINT <0 - 213 °F <-18 - 100 °C MELTING POINT Not available VOLATILE VOLUME 98 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile weight 15.90% Less Water and Federally Exempt Solvents Section X STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known INCOMPATIBILITY None known HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section XI TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDOUS No ingredient in this product is an IARC, NTP or OSHA list carcinogen. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 67-63-0 2-Propanol LC50 RAT 4HR Not Available LD50 RAT 5045 mg/kg Section XII ECOLOGICAL INFORMATION ECOTOXICOLOGAL INFORMATION No data available Section XIII DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulation regarding pollution. Section XIV TRANSPORT INFORMATION No data available Continued on page 4 E404 PAGE 3 Page 37 of 190 Page 37 of 190 Page 37 of 190 Page 37 of 190 ---PAGE BREAK--- Section XV REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section XVI OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formatted, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. E404 PAGE 4 Page 38 of 190 Page 38 of 190 Page 38 of 190 Page 38 of 190 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Share Corporation P.O. Box 245013 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER: (800) 776-7192 REVISION DATE: February 23, 2012 CHEMTREC: (800) 424-9300 DATE OF ISSUE: February 24, 2012 I - Product Identification Clean Coil PRODUCT CODE: 0103 CHEMICAL FORMULATION: Inorganic acid cleaner. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 4 FLAMMABILITY: 0 REACTIVITY: 1 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. SUBSTANCE APPROX % OSHA PEL ACGIH TLV EPA 40 CFR: CAS # 302 355 372 Sulfuric Acid 10.0-20.0 1 mg/m3 1 mg/m3 Y Y Y 7664-93-9 Hydrofluoric Acid 5.0-10.0 3 ppm 3 ppm C Y Y Y 7664-39-3 Quaternary ammonium compounds <5.0 N/E N/E N N N 68187-69-9 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = 1.139 VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): <5.0 VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = N/D SOLUBILITY IN WATER: Soluble pH: 1.00 APPEARANCE AND ODOR: Clear, slight yellow liquid; characteristic acid odor. IV - Fire and Explosion Hazard Data FLASH POINT None. (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Water spray, foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters must be equipped with full protective gear, including self-contained breathing apparatus. Cool fire exposed containers with water spray. Run-off from fire control may cause pollution. Neutralize run-off with lime, soda ash, etc. UNUSUAL FIRE AND EXPLOSION HAZARD: Acid may react with metals to create explosive hydrogen accumulations. Fire may produce toxic fumes. Product generates heat upon addition of water, with possible spattering. Page 39 of 190 Page 39 of 190 Page 39 of 190 Page 39 of 190 ---PAGE BREAK--- PRODUCT NAME: Clean Coil PRODUCT CODE: 0103 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Alkaline materials, metal salts, oxidizing materials and organic materials. CONDITIONS TO AVOID: Do not mix with chlorine bleach, ammonia or any other cleaning chemical. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can produce a wide variety of toxic gases and vapors. HAZARDOUS POLYMERIZATION: Will not occur. VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: DANGER Corrosive-Severe irritation, burns, destruction of tissue, blindness. IF ON SKIN: DANGER Corrosive-Severe irritation, deep ulcerations that may not be immediately painful or evident. Hydrofluoric acid will penetrate the skin and attack underlying tissues and bone. Large burns may also cause hypocalcemia and other toxic effects which may be fatal. IF SWALLOWED: MAY BE HARMFUL OR FATAL IF SWALLOWED. Severe burns, destruction of tissue. Small amounts or dilute solutions fatal hypocalcemia and systemic toxicity is likely to occur unless medical treatment is immediately obtained. IF INHALED: Short-term exposure causes nose, throat & respiratory irritation which may be delayed for several hours. Long-term exposure causes nose and throat burns, lung inflammation, pulmonary edema and fatal hypocalcemia. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. Obtain immediate medical attention. IF ON SKIN: Flush with plenty of cool water for at least 15 minutes while removing contaminated clothing and shoes. Pay close attention to area under nails. Obtain medical attention immediately! Follow by immersing affected skin in an ice cold solution of magnesium sulfate (Epsom Salt) or using a calcium gluconate gel. IF SWALLOWED: DO NOT INDUCE VOMITING. Give large quantities of water followed with several glasses of milk or several ounces of milk of magnesia. Never give anything by mouth to an unconscious person. Obtain medical attention immediately. IF INHALED: Remove person to fresh air. Administer artificial respiration if indicated. If breathing is difficult, give oxygen. Keep person warm and quiet. Obtain medical attention immediately. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area. Contain spill. Soak up spilled material with inert absorbent material and place in a properly marked closed container for proper disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. Do not breathe vapors or mists. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Recommended PROTECTIVE GLOVES: Chemical resistant gauntlet type gloves. EYE PROTECTION: Chemical goggles and/or face shield. OTHER PROTECTIVE EQUIPMENT: Protective clothing, emergency shower and eye wash station. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Corrosive material. Store in a cool, dry place away from alkaline materials and reactive chemicals. Do not mix with any other cleaning chemicals. Always add this product to water, never add water to this product. Wash thoroughly after handling. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT ID UN2922 DOT PROPER SHIPPING NAME: Corrosive Liquids, Toxic, N.O.S. (hydrofluoric acid, sulfuric acid) DOT CLASS: 8, (6.1) DOT PACKING GROUP: II The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: February 23, 2012 Prepared by: Technical Dept. DATE OF ISSUE: February 24, 2012 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Share Corporation assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material. Page 40 of 190 Page 40 of 190 Page 40 of 190 Page 40 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 1 of 13 POWER SERVICE PRODUCTS, INC. SAFETY DATA SHEET SECTION 1 - IDENTIFICATION PRODUCT NAME: DIESEL FUEL SUPPLEMENT +CETANE BOOST Unless otherwise noted, all sections of this SDS apply to each of the following products and part numbers. PART NUMBERS: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11080-06 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 COMPANY IDENTIFICATION: Power Service Products, Inc. P.O. Box 1089 Weatherford, TX 76086 Email: [EMAIL REDACTED] Phone: [PHONE REDACTED] or [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone Number: Within USA 1-[PHONE REDACTED]. Outside USA 001-[PHONE REDACTED] (Call Collect). RECOMMENDED USES: Diesel fuel additive SECTION 2 – HAZARD(S) IDENTIFICATION CLASSIFICATION UNDER 29 CFR 1910.1200(d) (NC=product does not meet classification criteria) 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Acute Toxicity, Oral: NC NC NC Acute Toxicity, Dermal: NC NC NC Acute Toxicity, Inhalation, Vapors: 3 3 3 Page 41 of 190 Page 41 of 190 Page 41 of 190 Page 41 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 2 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Skin Corrosion/Irritation: 2 2 2 Serious Eye Damage/Eye Irritation: 2 2 2 Respiratory Sensitization: NC NC NC Skin Sensitization: NC NC NC Germ Cell Mutagenicity: NC NC NC Carcinogenicity: 2 2 2 Reproductive Toxicity: NC NC NC Specific Target Organ Toxicity, Single Exposure: 3 3 3 Specific Target Organ Toxicity, Repeated or Prolonged Exposure: NC NC NC Aspiration Hazard: 1 1 1 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Physical Properties Criteria Category Category Category Explosives: NC NC NC Flammable Gases: NC NC NC Flammable Aerosols: NC NC NC Oxidizing Gases: NC NC NC Gases Under Pressure: NC NC NC Flammable Liquids: 3 3 3 Flammable Solids: NC NC NC Self-Reactive Chemicals: NC NC NC Pyrophoric Liquids: NC NC NC Pyrophoric Solids: NC NC NC Self-Heating Chemicals: NC NC NC Chemicals Which, in Contact with Water, Emit Flammable Gases: NC NC NC Oxidizing Liquids: NC NC NC Oxidizing Solids: NC NC NC Organic Peroxides: NC NC NC Corrosive to Metals: NC NC NC LABEL SIGNAL WORD, HAZARD STATEMENTS, SYMBOLS AND PRECAUTIONARY STATEMENTS UNDER 29 CFR 1910.1200(f): Please see the Note regarding product labeling in Section 16. Page 42 of 190 Page 42 of 190 Page 42 of 190 Page 42 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 3 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Signal Word Danger Danger Danger Hazard Statement(s): Flammable liquid and vapor. Toxic if inhaled. May be fatal if swallowed and enters airways. Harmful if swallowed. Causes skin and serious eye irritation. May cause respiratory irritation and drowsiness or dizziness. Symbols: The following symbols are for all treatment ratios. Precautionary Statement(s): Keep away from sparks and open flames. No smoking. Keep container closed. Use only non-sparking tools. Ground/Bond container and receiving equipment. Use explosion-proof pumps when pumping. Take precautionary measures against static discharge. Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves and eye protection. Store locked up and in cool, well ventilated place. KEEP OUT OF REACH OF CHILDREN. Hazards Not Otherwise Classified: None SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS The specific chemical identity and exact concentration percentage has been withheld as a Trade Secret. Specific chemical information will be made available to health professionals in accordance with 29 CFR 1910.1200. INGREDIENTS CLASSIFIED AS HEALTH HAZARDS TREATMENT RATIO 1:400 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 50 - 90 Hydroxy alkoxylate Trade secret Trade secret 4 - 10 Alkyl Nitrates Trade secret Trade secret 2 - 6 Naphthalene Not available 91-20-3 0.05 – 0.2 Page 43 of 190 Page 43 of 190 Page 43 of 190 Page 43 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 4 of 13 TREATMENT RATIO 1:1000 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 40 - 90 Alkyl Nitrates Trade secret Trade secret 5 - 15 Aromatic Hydrocarbons Trade secret Trade secret 2 - 5 Hexan-1-ol, 2-ethyl Trade secret Trade secret 1 - 4 Naphthalene Not available 91-20-3 0.1 – 0.5 TREATMENT RATIO 1:1500 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 20 - 55 Alkyl Nitrates Trade secret Trade secret 10 – 20 Aromatic Hydrocarbons Trade secret Trade secret 3 - 8 Hexan-1-ol, 2-ethyl Trade secret Trade secret 2 – 5 Naphthalene Not available 91-20-3 0.2 – 0.9 SECTION 4 - FIRST AID MEASURES As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. EYE CONTACT: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice. SKIN CONTACT: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs get medical advice/attention. INHALATION: Remove person to fresh air and keep comfortable for breathing. Call a doctor. INGESTION: If swallowed, IMMEDIATELY call a doctor. Do NOT induce vomiting. SECTION 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPECIFIC HAZARDS: Vapors are heavier than air and may travel along the ground to a distant ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH Page 44 of 190 Page 44 of 190 Page 44 of 190 Page 44 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 5 of 13 EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY CONTAINER. PROTECTIVE EQUIPMENT AND PRECAUTIONS: Use standard protective equipment including self-contained breathing apparatus (SCBA). SECTION 6 - ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures. See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment. SPILL CONTAINMENT AND CLEAN-UP: Eliminate potential sources of ignition. Stop leak if it can be done without risk. Dike and contain spill. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. A vapor suppressing foam may be used to reduce vapors. Local, state and federal laws and/or regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up releases. The user/responder will need to determine which local, state and federal laws and/or regulations are applicable. The National Response Center can be reached at 1-[PHONE REDACTED]. SECTION 7 - HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Avoid contact with eyes and skin. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and flames. No smoking. CONDITIONS FOR SAFE STORAGE: DO NOT USE OR STORE near heat, sparks, or flame. USE AND STORE ONLY IN A WELL-VENTILATED AREA. Handle containers with care. Keep container closed when not in use. Store locked up. STORAGE TEMPERATURE: Treatment Ratio Part Numbers: Storage Temperature: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11041-04, 11080-06 -20F to 104F (-29C to 40C) 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 0F to 104F (-18C to 40C) Page 45 of 190 Page 45 of 190 Page 45 of 190 Page 45 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 6 of 13 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 10F to 104F (-12C to 40C) EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: CAS # OSHA ACGIH NIOSH PEL TLV STEL REL STEL IDLH Note 100-41-4 100 ppm 20 ppm not est. 100 ppm 125 ppm 800 ppm (LEL) n/a Naphthalene 91-20-3 10 ppm 10 ppm not est. 10 ppm 15 ppm 250 ppm skin Petroleum Distillates n/a 500 ppm not est. not est. not est. not est. not est. n/a Cumene 98-82-8 50 ppm 50 ppm not est. 50 ppm not est. 900 ppm (LEL) Skin Toluene 108-88-3 100 ppm 20 ppm not est. 100 ppm 150 ppm 500 ppm Skin Hydroxy Alkoxylate Proprietary 50 ppm 20 ppm not est. 5 ppm not est. not est. skin ENGINEERING CONTROLS: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Local exhaust ventilation is recommended to control exposure. PERSONAL PROTECTIVE EQUIPMENT (PPE): Eyes and Face: Eye protection such as safety glasses or chemical goggles is recommended if contact is likely. Skin: Protective chemical/oil resistant gloves are recommended. Wear additional protective clothing as appropriate. Respiratory: Wear a NIOSH/MSHA approved respirator as necessary. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Practice good housekeeping. NOTE: These precautions are for room temperature handling. Page 46 of 190 Page 46 of 190 Page 46 of 190 Page 46 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 7 of 13 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Appearance Liquid, brown Liquid, brown Liquid, brown Odor Aromatic solvent Aromatic solvent Aromatic solvent Odor Threshold Not available Not available Not available pH 7 – 8 basic) 7 – 8 basic) 7 – 8 basic) Melting point/Freezing point Not available Not available Not available Initial Boiling Point and Boiling Range 300F (149C) 300F (149C) 300F (149C) Flash Point 105F (40.5C) 116F (46.6C) 121F (49.4C) Evaporation Rate Not available Not available Not available Flammability Not available Not available Not available Upper / lower Flammability or Explosive Limits Not available Not available Not available Vapor Pressure 0.2 – 0.95 0.2 – 0.95 0.2 – 0.95 Vapor Density >5.0 >5.0 >5.0 Relative Density/Specific Gravity (at 60°F) 0.910 0.912 0.896 Solubility Not available Not available Not available Partition Coefficient; n-octanol / water Not available Not available Not available Auto-ignition Temperature Not available Not available Not available Decomposition temperature Not available Not available Not available Viscosity Not available Not available Not available Pour Point -55F (-13C) -30F (1.1C) -15F (9.4C) SECTION 10 - STABILITY AND REACTIVITY REACTIVITY: see Incompatible Materials below CHEMICAL STABILITY: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. POSSIBILITY OF HAZARDOUS REACTION: Hazardous polymerization will not occur. CONDITIONS TO AVOID: Flames, high energy ignition sources, and elevated temperatures. INCOMPATIBLE MATERIALS: May react with strong oxidizing agents, such as; chlorates, nitrates, peroxides, nitrogen oxides, sulfur oxides, etc.; alkalis; nitric acid; sulfuric acid; aluminum; brass; copper; reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, products of incomplete combustion. Page 47 of 190 Page 47 of 190 Page 47 of 190 Page 47 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 8 of 13 SECTION 11 - TOXICOLOGICAL INFORMATION LIKELY ROUTES OF EXPOSURE INGESTION INHALATION SKIN CONTACT EYE CONTACT SKIN ABSORPTION 1:400 Treatment Ratio X X X X 1:1000 Treatment Ratio X X X X 1:1500 Treatment Ratio X X X X RELATED TO PHYSICAL, CHEMICAL AND TOXICOLOGICAL CHARACTERISTICS: Breathing of high vapor concentrations may cause dizziness, light- headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors, or convulsions, loss of consciousness, coma or death. DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND LONG-TERM EXPOSURE: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in the presence of maternal toxicity in animals. NUMERICAL MEASURES OF TOXICITY Note: the information provided below are estimates; testing of the product is not available. Treatment Ratio Acute Oral Toxicity (ATEmix estimate) Acute Dermal Toxicity (ATEmix estimate) Acute Inhalation (ATEmix estimate) 1:400 Treatment Ratio Does not meet criteria Does not meet criteria 7.10 (vapors) 1:1,000 Treatment Ratio Does not meet criteria Does not meet criteria 8.56 (vapors) 1:1,500 Treatment Ratio Does not meet criteria Does not meet criteria 7.48 (vapors) SENSITIZATION: No information available. MUTAGENICITY: No information available. CARCINOGENICITY LISTINGS – the following chemicals are listed as indicated: Page 48 of 190 Page 48 of 190 Page 48 of 190 Page 48 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 9 of 13 Chemical List Cumene IARC, NTP IARC Naphthalene IARC, NTP REPODUCTIVE TOXICITY: No information available. TERATOGENICITY/EMBRYOTOXICITY: Hydroxy Alkoxylate has caused fetotoxicity with maternal toxicity. This product contains a component of a complex mixture (Xylenes (1330-20- that has been shown to cause teratogenicity and/or embryotoxicity. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Respiratory tract irritation, drowsiness/dizziness. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): No information available ASPIRATION HAZARD: Aspiration hazard identified. SECTION 12 - ECOLOGICAL INFORMATION ECOTOXICITY: This material is expected to be toxic to aquatic organisms. PERSISTENCE AND DEGRADABILITY: No information available. BIOACCUMULATIVE POTENTIAL: No information available. MOBILITY IN SOIL: No information available. OTHER ADVERSE EFFECTS: No information available. SECTION 13 - DISPOSAL CONSIDERATIONS RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste regulations (40 CFR Part 261). Disposal of the used product may also be regulated as hazardous waste due to resulting mixture characteristics, mixture components or product use. Such changes to the product may result in different and/or additional hazardous waste codes. Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY State or local laws may impose additional regulatory requirements regarding disposal. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION Page 49 of 190 Page 49 of 190 Page 49 of 190 Page 49 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 10 of 13 HAZARD DATA. Dispose or recycle empty containers appropriately per local, state and federal regulations. SECTION 14 - TRANSPORTATION INFORMATION The following part numbers are not regulated by DOT: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 1080-06 1:1,000 Treatment Ratio 1128-04 1:1,500 Treatment Ratio 1050-02, 1055-01 The following part numbers are regulated by DOT: 1:1,000 Treatment Ratio 1060-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes 1:1,000 Treatment Ratio 1000 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) RQ (Xylene, Naphthalene) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes PRODUCT RQ: 100 lbs. (45.45 kg) – Xylene, Naphthalene 1:1,500 Treatment Ratio 1260-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes Page 50 of 190 Page 50 of 190 Page 50 of 190 Page 50 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 11 of 13 SECTION 15 - REGULATORY INFORMATION §14(a) Consumer Product Safety Act General Certificate of Conformity Power Service Products, Inc. certifies that this product meets the statutory and regulatory requirements of the US Consumer Products Safety Act, the Federal Hazardous Substances Act, and the Poison Prevention Packaging Act of 1970, as applicable. The Power Service products are manufactured in the United States in Weatherford, Texas, unless otherwise indicated on the product label. The product manufacture lot code is stamped on the product container. This Certification is based upon a reasonable testing program conducted by Power Service Products, Inc. which includes a quality control program incorporating, as necessary, confirmation of compliance by component suppliers. Third-party testing is not required to certify compliance. Further details may be obtained by contacting the Power Service Products, Inc. EHS Manager at 1-[PHONE REDACTED]. Contents of this SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act inventory reporting requirements. EPA SARA TITLE III CHEMICAL LISTINGS: Section 302 Extremely Hazardous Substances: None Sections 311/ 312 Hazard Class: Acute Health Effects: Yes Sudden Release of Pressure Hazard: No Chronic Health Effects: Yes Reactivity Hazard: No Fire Hazard: Yes NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) RATING: HEALTH: 2 FIRE: 2 REACTIVITY: 0 Section 313: Specific chemical information is being withheld as a Trade Secret. The following chemicals subject to the reporting requirements of EPCRA Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (40 CFR Part 372) may be present in this product at a concentration that does not exceed the specified upper weight percentage. Treatment Ratio CAS Number Chemical Name Max % 1:400 Treatment Ratio 100-41-4 24.0 NA Glycol Ether Category 8.0 Page 51 of 190 Page 51 of 190 Page 51 of 190 Page 51 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 12 of 13 Treatment Ratio CAS Number Chemical Name Max % 91-20-3 Naphthalene 1.0 98-82-8 Cumene 4.0 108-88-3 Toluene 4.0 1:1000 Treatment Ratio 100-41-4 19.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 3.5 108-88-3 Toluene 3.5 1:1,500 Treatment Ratio 100-41-4 12.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 2.0 108-88-3 Toluene 2.0 State or local laws may impose additional regulatory requirements for components of this material. It is the responsibility solely of the Employer to maintain compliance with State and Local reporting. This product contains a chemical known to the state of California to cause cancer and/or birth defects or other reproductive harm: toluene, cumene, naphthalene. SECTION 16 – OTHER INFORMATION DATE OF PREPARATION / REVISION: May 30, 2015 NOTE regarding product labeling: The OSHA Hazard Communication Standard applies to hazardous chemicals known to be present in the workplace. However, the labeling and Safety Data Sheet requirements do not apply to consumer products when they are used in the workplace for the purposes intended by the manufacturer and the use results in a duration and frequency of exposure which is not greater than the range of exposures that could reasonably be experienced by consumers when used for the intended purpose. Power Service Products intends for product packaged in 1 gallon or smaller containers to be used by consumers and has labeled those containers as required under the Consumer Product Safety Commission regulations. Power Service Products intends for product packaged in containers larger than 1 gallon to be used in the workplace and has labeled those products as required by the OSHA Hazard Communication Standard. The Consumer Product Safety Commission and OSHA Hazard Communication Standard labeling requirements are different and variations between the consumer and industrial labels may occur. It is the employer’s responsibility to purchase the appropriate product for use in the workplace. The information contained herein is offered in good faith and is believed to be accurate based on the data available to us as of the date of SDS preparation. The information in this document applies to this specific product as supplied. It may not be appropriate for this product if the product is used in combination with other materials. The information in this document is not intended to constitute product performance information. Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product. No statement shall be construed as an endorsement of any product or process. The recommended Page 52 of 190 Page 52 of 190 Page 52 of 190 Page 52 of 190 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 13 of 13 industrial hygiene and safe handling procedures are believed to be valid in the context of the intended use as described in product labeling. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. You are urged to obtain material safety data sheets for all products you buy, process, use or distribute, and are encouraged to advise those who may come in contact with such products of the information contained therein. Regulatory requirements are subject to change and may differ between locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. No warranty or guarantee is expressed or implied with respect to this product, the accuracy and sufficiency of the data or recommendations herein, or the results to be obtained from the use of this product. IN NO EVENT SHALL POWER SERVICE PRODUCTS, INC. BE LIABLE FOR ANY LOSS, CLAIM, DAMAGE OR LIABILITY OF ANY KIND, WHICH MAY ARISE FROM OR IN CONNECTION WITH THE INFORMATION CONTAINED IN THIS DOCUMENT OR FROM THE USE, HANDLING OR STORAGE OF THE PRODUCT BY THE BUYER/USER, WHETHER DIRECT, INDIRECT, OR CONSEQUENTIAL, OR FOR ANY CLAIM BY ANY THIRD PARTY, BEYOND THE PURCHASE PRICE OR REPLACEMENT OF THE PRODUCT IN CONNECTION WITH WHICH SUCH LOSS, CLAIM, DAMAGE OR LIABILITY AROSE. THE FOREGOING LIMITATIONS APPLY REGARDLESS OF THE CAUSES OR CIRCUMSTANCES GIVING RISE TO SUCH LOSS, CLAIM, DAMAGE OR LIABILITY, EVEN IF SUCH LOSS, CLAIM, DAMAGE, OR LIABILITY IS BASED ON NEGLIGENCE OR OTHER TORTS OR BREACH OF CONTRACT. Page 53 of 190 Page 53 of 190 Page 53 of 190 Page 53 of 190 ---PAGE BREAK--- Portland Cement Based Concrete Products MATERIAL SAFETY DATA SHEET (Complies with OSHA 29 CFR 1910.1200) SECTION I: PRODUCT IDENTIFICATION The QUIKRETE® Companies Emergency Telephone Number One Securities Centre (770) 216-9580 3490 Piedmont Road, Suite 1300 Atlanta, GA 30329 Information Telephone Number (770) 216-9580 MSDS J1 Revision: Aug-13 QUIKRETE® Product Name Code # CONCRETE MIX 1101 FENCE POST MIX 1005 FIBER-REINFORCED CONCRETE MIX 1006 CRACK RESISTANT CONCRETE MIX 1006-80 QUIKRETE 5000 CONCRETE MIX 1007 QUIKRETE 6000 CONCRETE MIX 1007 LIGHTWEIGHT CONCRETE MIX 1008 HANDICRETE CONCRETE MIX 1141-59, -60, -80 MAXIMUM YIELD CONCRETE MIX 1100-80 B-CRETE 1101-81 PRO-FINISH QUIKRETE 5000 1007-85 BASIC CONCRETE MIX 1015 RIP RAP 1129 ALL-STAR CONCRETE MIX 1121 ALL-STAR CRACK RESISTANT CONCRETE MIX 1470-03 ALL-STAR 5000 CONCRETE MIX 1470-01 RED-E-CRETE CONCRETE MIX 1101-91, -87; 1141-62, -63, -92, -93 RIP RAP SCRIM 1134-80 FIBER REINFORCED DECK MIX 1251-80, -81 PRO-FINISH CRACK RESISTANT CONCRETE MIX 1006-68 COUNTERTOP MIX 1106-80 RITEMIX CONCRETE 1171-60 GREEN CONCRETE MIX 1101-63, -73 FLOWCRETE 5000 (MIX 801) 8080026/NR80026 Product Use: Portland cement-based, aggregated products for general construction SECTION II - HAZARD IDENTIFICATION Route(s) of Entry: Inhalation, Skin, Ingestion Page 54 of 190 Page 54 of 190 Page 54 of 190 Page 54 of 190 ---PAGE BREAK--- Acute Exposure: Product becomes alkaline when exposed to moisture. Exposure can dry the skin, cause alkali burns and affect the mucous membranes. Dust can irritate the eyes and upper respiratory system. Toxic effects noted in animals include, for acute exposures, alveolar damage with pulmonary edema. Chronic Exposure: Dust can cause inflammation of the lining tissue of the interior of the nose and inflammation of the cornea. Hypersensitive individuals may develop an allergic dermatitis. Carcinogenicity: Since Portland cement and blended cements are manufactured from raw materials mined from the earth (limestone, marl, sand, shale, etc.) and process heat is provided by burning fossil fuels, trace, but detectable, amounts of naturally occurring, and possibly harmful, elements may be found during chemical analysis. Under ASTM standards, Portland cement may contain 0.75 % insoluble residue. A fraction of these residues may be free silica. Respirable silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs and possibly cancer. There is evidence that exposure to respirable silica or the disease silicosis is associated with an increased incidence of Scleroderma, tuberculosis and kidney disorders. Carcinogenicity Listings: NTP: Known carcinogen OSHA: Not listed as a carcinogen IARC Monographs: Group 1 Carcinogen California Proposition 65: Known carcinogen NTP: The National Toxicology Program, in its “Ninth Report on Carcinogens” (released May 15, 2000) concluded that “Respirable silica (RCS), primarily quartz dusts occurring in industrial and occupational settings, is known to be a human carcinogen, based on sufficient evidence of carcinogenicity from studies in humans indicating a causal relationship between exposure to RCS and increased lung cancer rates in workers exposed to silica dust (reviewed in IAC, 1997; Brown et al., 1997; Hind et al., 1997) IARC: The International Agency for Research on Cancer (“IARC”) concluded that there was “sufficient evidence in humans for the carcinogenicity of silica in the forms of quartz or cristobalite from occupational sources”, and that there is “sufficient evidence in experimental animals for the carcinogenicity of quartz or cristobalite.” The overall IARC evaluation was that silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group The IARC evaluation noted that “carcinogenicity was not detected in all industrial circumstances or studies. Carcinogenicity may be dependent on inherent characteristics of the silica or on external factors affecting its biological activity or distribution of its polymorphs.” For further information on the IARC evaluation, see IARC Monographs on the Evaluation of carcinogenic Risks to Humans, Volume 68, “Silica, Some Silicates.” (1997) Signs and of Exposure: of excessive exposure to the dust include shortness of breath and reduced pulmonary function. Excessive exposure to skin and eyes especially when mixed with water can cause caustic burns as severe as third degree. Medical Conditions Generally Aggravated by Exposure: Individuals with sensitive skin and with pulmonary and/or respiratory disease, including, but not limited to, asthma and bronchitis, or subject to eye irritation, should be precluded from exposure. Exposure to silica or the disease silicosis is associated with increased incidence of scleroderma, Tuberculosis and possibly increased incidence of kidney lesions. Chronic Exposure: Dust can cause inflammation of the lining tissue of the interior of the nose and inflammation of the cornea. Hypersensitive individuals may develop an allergic dermatitis. (May contain trace (<0.05 amounts of chromium salts or compounds including hexavalent chromium, or other metals found to be hazardous or toxic in some chemical forms. These metals are mostly present as trace substitutions within the principal minerals) Page 55 of 190 Page 55 of 190 Page 55 of 190 Page 55 of 190 ---PAGE BREAK--- Medical Conditions Generally Aggravated by Exposure: Individuals with sensitive skin and with pulmonary and/or respiratory disease, including, but not limited to, asthma and bronchitis, or subject to eye irritation, should be precluded from exposure. SECTION III - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Hazardous Components CAS No. % PEL (OSHA) TLV (ACGIH) mg/M3 mg/M3 Portland Cement 65997-15-1 10-30 5 5 Lime 01305-62-0 0-5 5 5 Silica Sand, 14808-60-7 70-90 10 0.025 (respirable) %SiO2+2 May contain one or more of the following ingredients: Amorphous Silica 07631-86-9 80 10 (From fly Ash) %SiO2+2 Alumina (From Fly Ash) 01344-28-1 5 5 Limestone Dust 01317-65-3 5 5 Calcium Sulfate 10101-41-4 or 5 5 13397-24-5 Other Limits: National Institute for Occupational Safety and Health (NIOSH). Recommended standard maximum permissible concentration=0.05 mg/M3 (respirable free silica) as determined by a full-shift sample up to 10-hour working day, 40-hour work week. See NIOSH Criteria for a Recommended Standard Occupational Exposure to Silica. SECTION IV – First Aid Measures Eyes: Immediately flush eye thoroughly with water. Continue flushing eye for at least 15 minutes, including under lids, to remove all particles. Call physician immediately. Skin: Wash skin with cool water and pH-neutral soap or a mild detergent. Seek medical treatment if irritation or inflammation develops or persists. Seek immediate medical treatment in the event of burns. Inhalation: Remove person to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial respiration. Seek medical help if coughing and other do not subside. Inhalations of large amounts of Portland cement require immediate medical attention. Ingestion: Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately. SECTION V - FIRE AND EXPLOSION HAZARD DATA Flammability: Noncombustible and not explosive. Auto-ignition Temperature: Not Applicable Flash Points: Not Applicable SECTION VI – ACCIDENTAL RELEASE MEASURES If spilled, use dustless methods (vacuum) and place into covered container for disposal (if not contaminated or wet). Use adequate ventilation to keep exposure to airborne contaminants below the exposure limit. Page 56 of 190 Page 56 of 190 Page 56 of 190 Page 56 of 190 ---PAGE BREAK--- SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND STORAGE Do not allow water to contact the product until time of use. DO NOT BREATHE DUST. In dusty environments, the use of an OSHA, MSHA or NIOSH approved respirator and tight fitting goggles is recommended. SECTION VIII – EXPOSURE CONTROL MEASURES Engineering Controls: Local exhaust can be used, if necessary, to control airborne dust levels. Personal Protection: The use of barrier creams or impervious gloves, boots and clothing to protect the skin from contact is recommended. Following work, workers should shower with soap and water. Precautions must be observed because burns occur with little warning little heat is sensed. WARN EMPLOYEES AND/OR CUSTOMERS OF THE HAZARDS AND REQUIRED OSHA PRECAUTIONS ASSOCIATED WITH THE USE OF THIS PRODUCT. Exposure Limits: Consult local authorities for acceptable exposure limits SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS Appearance: Gray to gray-brown colored powder; Some products contain coarse aggregates. Specific Gravity: 2.6 to 3.15 Melting Point: >2700oF Boiling Point: >2700oF Vapor Pressure: Not Available Vapor Density: Not Available Evaporation Rate: Not Available Solubility in Water: Slight Odor: Not Available pH: 13 (10%) Volatile Organic Content (VOC): 0 g/L SECTION X - REACTIVITY DATA Stability: Stable. Incompatibility (Materials to Avoid): Contact of silica with powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, or oxygen difluoride may cause fires Hazardous Decomposition or By-products: Silica will dissolve in Hydrofluoric Acid and produce a corrosive gas – silicon tetrafluoride. Hazardous Polymerization: Will Not Occur. Condition to Avoid: Keep dry until used to preserve product utility. SECTION XI – TOXICOLOGICAL INFORMATION Routes of Entry: Inhalation, Ingestion Toxicity to Animals: LD50: Not Available LC50: Not Available Chronic Effects on Humans: Conditions aggravated by exposure include eye disease, skin disorders and Chronic Respiratory conditions. Special Remarks on Toxicity: Not Available Page 57 of 190 Page 57 of 190 Page 57 of 190 Page 57 of 190 ---PAGE BREAK--- SECTION XII – ECOLOGICAL INFORMATION Ecotoxicity: Not Available BOD5 and COD: Not Available Products of Biodegradation: Not available Toxicity of the Products of Biodegradation: Not available Special Remarks on the Products of Biodegradation: Not available SECTION XIII – DISPOSAL CONSIDERATIONS Waste Disposal Method: The packaging and material may be land filled; however, material should be covered to minimize generation of airborne dust. This product is not classified as a hazardous waste under the authority of the RCRA (40CFR 261) or CERCLA (40CFR 117&302). SECTION XIV – TRANSPORT INFORMATION Not hazardous under U.S. DOT and TDG regulations. SECTION XV – OTHER REGULATORY INFORMATION US OSHA 29CFR 1910.1200: Considered hazardous under this regulation and should be included in the employers’ hazard communication program SARA (Title III) Sections 311 & 312: Qualifies as a hazardous substance with delayed health effects SARA (Title III) Section 313: Not subject to reporting requirements TSCA (May 1997): Some substances are on the TSCA inventory list Federal Hazardous Substances Act: Is a hazardous substance subject to statues promulgated under the subject act California Regulation: WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Canadian Environmental Protection Act: Not listed Canadian WHMIS Classification: Considered to be a hazardous material under the Hazardous Products Act as defined by the Controlled Products Regulations (Class D2A, E- Corrosive Material) and subject to the requirements of Health Canada’s Workplace Hazardous Material Information (WHMIS). This product has been classified according to the hazard criteria of the Controlled Products Regulation (CPR). This document complies with the WHMIS requirements of the Hazardous Products Act (HPA) and the CPR. SECTION XVI – OTHER INFORMATION HMIS-III: Health – 0 = No significant health risk 1 = Irritation or minor reversible injury possible 2 = Temporary or minor injury possible 3 = Major injury possible unless prompt action is taken 4 = Life threatening, major or permanent damage possible Flammability- 0 = Material will not burn 1 = Material must be preheated before ignition will occur 2 = Material must be exposed to high temperatures before ignition Page 58 of 190 Page 58 of 190 Page 58 of 190 Page 58 of 190 ---PAGE BREAK--- 3 = Material capable of ignition under normal temperatures 4 = Flammable gases or very volatile liquids; may ignite spontaneously Physical Hazard- 0 = Material is normally stable, even under fire conditions 1 = Material normally stable but may become unstable at high temps 2 = Materials that are unstable and may undergo react at room temp 3 = Materials that may form explosive mixtures with water 4 = Materials that are readily capable of explosive water reaction Abbreviations: ACGIH American Conference of Government Industrial Hygienists CAS Chemical Abstract Service CERCLA Comprehensive Environmental Response, Compensation and Liability Act CFR Code of Federal Regulations CPR Controlled Products Regulations (Canada) DOT Department of Transportation IARC International Agency for Research MSHA Mine Safety and Health Administration NIOSH National Institute for Occupational Safety and Health NTP National Toxicity Program OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit RCRA Resource Conservation and Recovery Act SARA Superfund Amendments and Reauthorization Act TLV Threshold Limit Value TWA Time-weighted Average WHMIS Workplace Hazardous Material Information System Last Updated: August 23, 2013 NOTE: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products. END OF MSDS. Page 59 of 190 Page 59 of 190 Page 59 of 190 Page 59 of 190 ---PAGE BREAK--- Portland Cement Based Repair Materials MATERIAL SAFETY DATA SHEET (Complies with OSHA 29 CFR 1910.1200) SECTION I: PRODUCT IDENTIFICATION The QUIKRETE® Companies Emergency Telephone Number One Securities Centre (770) 216-9580 3490 Piedmont Road, Suite 1300 Atlanta, GA 30329 Information Telephone Number (770) 216-9580 MSDS J5 Revision: Aug-11 QUIKRETE® Product Name Code # FOUNDATION COATING 1215 SAND (TOPPING) MIX 1103 SAND MIX – TYPE II 1103-88, NR83003 ALL STAR SAND MIX 1123 HANDICRETE SAND MIX 1143 RITEMIX SAND MIX 1173 DECK MUD 1548-55 POWERLITE NR3004 REVETMENT - RIP RAP BURLAP NR83994 3:1 SAND/CEMENT - BURLAP NR83999 VINYL CONCRETE PATCHER 1133, 1132 BONDED TOPPING MIX 1133-18, -04 Product Use: Portland cement-based materials for repairing Concrete SECTION II - HAZARD IDENTIFICATION Route(s) of Entry: Inhalation, Skin, Ingestion Acute Exposure: Product becomes alkaline when exposed to moisture. Exposure can dry the skin, cause alkali burns and affect the mucous membranes. Dust can irritate the eyes and upper respiratory system. Toxic effects noted in animals include, for acute exposures, alveolar damage with pulmonary edema. Chronic Exposure: Dust can cause inflammation of the lining tissue of the interior of the nose and inflammation of the cornea. Hypersensitive individuals may develop an allergic dermatitis. Carcinogenicity: Since Portland cement and blended cements are manufactured from raw materials mined from the earth (limestone, marl, sand, shale, etc.) and process heat is provided by burning fossil fuels, trace, but detectable, amounts of naturally occurring, and possibly harmful, elements may be found during chemical analysis. Under ASTM standards, Portland cement may contain 0.75 % insoluble residue. A fraction of these residues may be free silica. Respirable silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs and possibly cancer. There is evidence that exposure to respirable silica or the Page 60 of 190 Page 60 of 190 Page 60 of 190 Page 60 of 190 ---PAGE BREAK--- disease silicosis is associated with an increased incidence of Scleroderma, tuberculosis and kidney disorders. Carcinogenicity Listings: NTP: Known carcinogen OSHA: Not listed as a carcinogen IARC Monographs: Group 1 Carcinogen California Proposition 65: Known carcinogen NTP: The National Toxicology Program, in its “Ninth Report on Carcinogens” (released May 15, 2000) concluded that “Respirable silica (RCS), primarily quartz dusts occurring in industrial and occupational settings, is known to be a human carcinogen, based on sufficient evidence of carcinogenicity from studies in humans indicating a causal relationship between exposure to RCS and increased lung cancer rates in workers exposed to silica dust (reviewed in IAC, 1997; Brown et al., 1997; Hind et al., 1997) IARC: The International Agency for Research on Cancer (“IARC”) concluded that there was “sufficient evidence in humans for the carcinogenicity of silica in the forms of quartz or cristobalite from occupational sources”, and that there is “sufficient evidence in experimental animals for the carcinogenicity of quartz or cristobalite.” The overall IARC evaluation was that silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group The IARC evaluation noted that “carcinogenicity was not detected in all industrial circumstances or studies. Carcinogenicity may be dependent on inherent characteristics of the silica or on external factors affecting its biological activity or distribution of its polymorphs.” For further information on the IARC evaluation, see IARC Monographs on the Evaluation of carcinogenic Risks to Humans, Volume 68, “Silica, Some Silicates.” (1997) Signs and of Exposure: of excessive exposure to the dust include shortness of breath and reduced pulmonary function. Excessive exposure to skin and eyes especially when mixed with water can cause caustic burns as severe as third degree. Medical Conditions Generally Aggravated by Exposure: Individuals with sensitive skin and with pulmonary and/or respiratory disease, including, but not limited to, asthma and bronchitis, or subject to eye irritation, should be precluded from exposure. Exposure to silica or the disease silicosis is associated with increased incidence of scleroderma, Tuberculosis and possibly increased incidence of kidney lesions. Chronic Exposure: Dust can cause inflammation of the lining tissue of the interior of the nose and inflammation of the cornea. Hypersensitive individuals may develop an allergic dermatitis. (May contain trace (<0.05 amounts of chromium salts or compounds including hexavalent chromium, or other metals found to be hazardous or toxic in some chemical forms. These metals are mostly present as trace substitutions within the principal minerals) Medical Conditions Generally Aggravated by Exposure: Individuals with sensitive skin and with pulmonary and/or respiratory disease, including, but not limited to, asthma and bronchitis, or subject to eye irritation, should be precluded from exposure. SECTION III - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Page 61 of 190 Page 61 of 190 Page 61 of 190 Page 61 of 190 ---PAGE BREAK--- Hazardous Components CAS No. PEL (OSHA) TLV (ACGIH) mg/M3 mg/M3 Portland Cement 65997-15-1 5 5 Silica Sand, 14808-60-7 10 0.05 (respirable) %SiO2+2 May contain one or more of the following ingredients: Lime 01305-62-0 5 5 Amorphous Silica 07631-86-9 80 10 (From fly Ash) %SiO2+2 Alumina (From Fly Ash) 01344-28-1 5 5 Limestone Dust 01317-65-3 5 5 Calcium Sulfate 10101-41-4 or 5 5 13397-24-5 Other Limits: National Institute for Occupational Safety and Health (NIOSH). Recommended standard maximum permissible concentration=0.05 mg/M3 (respirable free silica) as determined by a full-shift sample up to 10-hour working day, 40-hour work week. See NIOSH Criteria for a Recommended Standard Occupational Exposure to Silica. SECTION IV – First Aid Measures Eyes: Immediately flush eye thoroughly with water. Continue flushing eye for at least 15 minutes, including under lids, to remove all particles. Call physician immediately. Skin: Wash skin with cool water and pH-neutral soap or a mild detergent. Seek medical treatment if irritation or inflammation develops or persists. Seek immediate medical treatment in the event of burns. Inhalation: Remove person to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial respiration. Seek medical help if coughing and other do not subside. Inhalations of large amounts of Portland cement require immediate medical attention. Ingestion: Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately. SECTION V - FIRE AND EXPLOSION HAZARD DATA Flammability: Noncombustible and not explosive. Auto-ignition Temperature: Not Applicable Flash Points: Not Applicable SECTION VI – ACCIDENTAL RELEASE MEASURES If spilled, use dustless methods (vacuum) and place into covered container for disposal (if not contaminated or wet). Avoid washing into waterways. Use adequate ventilation to keep exposure to airborne contaminants below the exposure limit. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND STORAGE Do not allow water to contact the product until time of use. DO NOT BREATHE DUST. In dusty environments, the use of an OSHA, MSHA or NIOSH approved respirator and tight fitting goggles is recommended. Page 62 of 190 Page 62 of 190 Page 62 of 190 Page 62 of 190 ---PAGE BREAK--- SECTION VIII – EXPOSURE CONTROL MEASURES Engineering Controls: Local exhaust can be used, if necessary, to control airborne dust levels. Personal Protection: The use of barrier creams or impervious gloves, boots and clothing to protect the skin from contact is recommended. Following work, workers should shower with soap and water. Precautions must be observed because burns occur with little warning little heat is sensed. WARN EMPLOYEES AND/OR CUSTOMERS OF THE HAZARDS AND REQUIRED OSHA PRECAUTIONS ASSOCIATED WITH THE USE OF THIS PRODUCT. Exposure Limits: Consult local authorities for acceptable exposure limits SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS Appearance: Gray to gray-brown colored powder; Some products contain coarse aggregates. QUIKRETE Vinyl Concrete Patcher is available in white. Specific Gravity: 2.6 to 3.15 Melting Point: >2700oF Boiling Point: >2700oF Vapor Pressure: Not Available Vapor Density: Not Available pH of Wet Product: 12+ Solubility in Water: Slight Odor: Not Available SECTION X - REACTIVITY DATA Stability: Stable. Incompatibility (Materials to Avoid): Contact of silica with powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, or oxygen difluoride may cause fires Hazardous Decomposition or By-products: Silica will dissolve in Hydrofluoric Acid and produce a corrosive gas – silicon tetrafluoride. Hazardous Polymerization: Will Not Occur. Condition to Avoid: Keep dry until used to preserve product utility. SECTION XI – TOXICOLOGICAL INFORMATION Routes of Entry: Inhalation, Ingestion Toxicity to Animals: LD50: Not Available LC50: Not Available Chronic Effects on Humans: Conditions aggravated by exposure include eye disease, skin disorders and Chronic Respiratory conditions. Special Remarks on Toxicity: Not Available SECTION XII – ECOLOGICAL INFORMATION Ecotoxicity: Not Available BOD5 and COD: Not Available Products of Biodegradation: Not available Page 63 of 190 Page 63 of 190 Page 63 of 190 Page 63 of 190 ---PAGE BREAK--- Toxicity of the Products of Biodegradation: Not available Special Remarks on the Products of Biodegradation: Not available SECTION XIII – DISPOSAL CONSIDERATIONS Waste Disposal Method: The packaging and material may be land filled; however, material should be covered to minimize generation of airborne dust. This product is not classified as a hazardous waste under the authority of the RCRA (40CFR 261) or CERCLA (40CFR 117&302). SECTION XIV – TRANSPORT INFORMATION Not hazardous under U.S. DOT and TDG regulations. SECTION XV – OTHER REGULATORY INFORMATION US OSHA 29CFR 1910.1200: Considered hazardous under this regulation and should be included in the employers’ hazard communication program SARA (Title III) Sections 311 & 312: Qualifies as a hazardous substance with delayed health effects SARA (Title III) Section 313: Not subject to reporting requirements TSCA (May 1997): Some substances are on the TSCA inventory list Federal Hazardous Substances Act: Is a hazardous substance subject to statues promulgated under the subject act Canadian Environmental Protection Act: Not listed Canadian WHMIS Classification: Considered to be a hazardous material under the Hazardous Products Act as defined by the Controlled Products Regulations (Class D2A, E- Corrosive Material) and subject to the requirements of Health Canada’s Workplace Hazardous Material Information (WHMIS). This product has been classified according to the hazard criteria of the Controlled Products Regulation (CPR). This document complies with the WHMIS requirements of the Hazardous Products Act (HPA) and the CPR. SECTION XVI – OTHER INFORMATION HMIS-III: Health – 0 = No significant health risk 1 = Irritation or minor reversible injury possible 2 = Temporary or minor injury possible 3 = Major injury possible unless prompt action is taken 4 = Life threatening, major or permanent damage possible Flammability- 0 = Material will not burn 1 = Material must be preheated before ignition will occur 2 = Material must be exposed to high temperatures before ignition 3 = Material capable of ignition under normal temperatures 4 = Flammable gases or very volatile liquids; may ignite spontaneously Physical Hazard- 0 = Material is normally stable, even under fire conditions 1 = Material normally stable but may become unstable at high temps 2 = Materials that are unstable and may undergo react at room temp 3 = Materials that may form explosive mixtures with water 4 = Materials that are readily capable of explosive water reaction Abbreviations: ACGIH American Conference of Government Industrial Hygienists Page 64 of 190 Page 64 of 190 Page 64 of 190 Page 64 of 190 ---PAGE BREAK--- CAS Chemical Abstract Service CERCLA Comprehensive Environmental Response, Compensation and Liability Act CFR Code of Federal Regulations CPR Controlled Products Regulations (Canada) DOT Department of Transportation IARC International Agency for Research MSHA Mine Safety and Health Administration NIOSH National Institute for Occupational Safety and Health NTP National Toxicity Program OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit RCRA Resource Conservation and Recovery Act SARA Superfund Amendments and Reauthorization Act TLV Threshold Limit Value TWA Time-weighted Average WHMIS Workplace Hazardous Material Information System Revision #10-01, supersedes all previous revisions Created: 10/25/2006 Last Updated: August 29, 2011 NOTE: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products. Page 65 of 190 Page 65 of 190 Page 65 of 190 Page 65 of 190 ---PAGE BREAK--- Material Safety Data Sheet High Performance Cold Patch date prepared: 01-02-02 by PLM tech dept. This data is offered as good faith and not as product specifications. No warranty is expressed or implied is hereby made. Recommended industrial hygiene and safe handling are believed to be valid in the context of the intended use as described. It is incumbent upon each user to evaluate the specific circumstances and to determine whether recommendations are appropriate. 1 1.0 Product Information and Material Identification and Use Manufacturer PLM Corporation Address 7424 Bessemer Ave Cleveland, Ohio 44127 Phone [PHONE REDACTED] or [PHONE REDACTED] Material name High Performance Cold Patch Material use Repairing exterior asphalt pavement, driveways, and parking lots Trade/Synonym Name “HIGH PERFORMANCE CHUCKHOLE PATCH” Classification Flammable solid – toxic material TDG Classification Not regulated 2.0 Hazardous Ingredients Defined In HPA Ingredients CAS Number % by weight Limestone 1317-65-3 91-97 Petroleum Asphalt Base 8052-42-4 2-8 Petroleum Solvent 68476-33-2 1-3 3.0 Physical Data for Material Physical State Granular solid Odor and Appearance Petroleum odor, black tarry appearance Odor Threshold 1 ppm Specific Gravity N/A Vapor Pressure N/A Vapor Density N/A Evaporation Rate N/A Boiling Point 295° C - 705° C Freezing Point N/A PH N/A Percent Volatile (by vol.) 1% (approximately) Coefficient of water/oil distribution – Insoluble in water 4.0 Fire and Explosion Data Conditions of Flammability: Heating to flash point and external ignition source Means of Extinction: Dry chemical, CO, water/fog spray Do not direct water stream into burning material. Flashpoint Method: 350° F COC Upper/Lower Flammable Limit: N/A Auto-Ignition Temperature: N/A Hazardous Combustion Products: Carbon monoxide, carbon dioxide, smoke, and oxides of sulphur and nitrogen Sensitivity to Mechanical Impact: Not sensitive Sensitivity to Static Discharge: Fumes from hot material may ignite 5.0 Reactivity Data Chemical Stability Stable Incompatibility Avoid strong oxidizing materials Reactivity conditions Non-reactive Hazardous decomposition of by-products: Carbon dioxide, carbon monoxide, aidehydes, and other compounds may form upon combustion Hazardous polymerization: Will not occur Page 66 of 190 Page 66 of 190 Page 66 of 190 Page 66 of 190 ---PAGE BREAK--- Material Safety Data Sheet High Performance Cold Patch date prepared: 01-02-02 by PLM tech dept. This data is offered as good faith and not as product specifications. No warranty is expressed or implied is hereby made. Recommended industrial hygiene and safe handling are believed to be valid in the context of the intended use as described. It is incumbent upon each user to evaluate the specific circumstances and to determine whether recommendations are appropriate. 2 6.0 Toxicological Properties Primary Routes of Entry: Skin contact, eye contact, and inhalation Effects of Acute Exposure to Fumes: Headache, dizziness, nausea, and irritation of skin, eyes, and upper respiratory tract Effects of Chronic Exposure to Material: Repeated exposure to fumes may cause liver or kidney damage, and skin dermatitis Exposure Limits: TWAEV Asphalt fumes-5mg/m3 H2S fumes-14mg/m3 Sensitization to Material: N/A Carcinogenicity: Not listed by IARC or ACGIH as carcinogen Teratogenicity: N/A Reproductive Toxicicity: N/A Mutagenicity: N/A Synergistic Material: N/A 7.0 Preventative Measures Personal Protective Equipment: Gloves (oil-impervious type), Chemical resistant safety goggles, Full-face organic vapor respirator if fumes exceed limits. Clothing should be long sleeve shirts, cuffed long pants, or coveralls. Engineering Controls : Provide sufficient ventilation in confined or enclosed areas. Use explosion- proof local exhaust as required to maintain allowable limits of fumes. Leak and Spill Procedure: Contain spill. Remove all sources of ignition. Do not flush to sewers. Shovel into drums for re-use or disposal. Waste Disposal: Dispose of material to approved landfill or to licensed reclaimer in accordance with local requirements. Handling Procedures and Equipment: DO NOT HEAT MATERIAL for use. Use only in well- ventilated areas. Keep away from ignition sources. Use electrically grounded containers or equipment to prevent static. Storage Requirements: Store in well-ventilated areas in closed containers away from ignition sources and strong oxidizing agents. 8.0 First Aid Measures Inhalation: Evacuate to fresh air. Apply cardiopulmonary resuscitation or oxygen if required. Seek medical assistance if required. Skin Contact: First wash with soap and water. Then if necessary seek medical assistance. Eye Contact: Flush with water for at least 15 minutes. Seek medical attention if irritation persists. Ingestion: Not expected, but if so, drink 25ml of water. Do not induce vomiting. Obtain medical attention. Page 67 of 190 Page 67 of 190 Page 67 of 190 Page 67 of 190 ---PAGE BREAK--- Page 68 of 190 Page 68 of 190 Page 68 of 190 Page 68 of 190 ---PAGE BREAK--- Page 69 of 190 Page 69 of 190 Page 69 of 190 Page 69 of 190 ---PAGE BREAK--- Page 1 of 5 Updated 02-11-2013 MATERIAL SAFETY DATA SHEET Supersedes 07-27-11 MSDS# 81C1 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: John Deere Cool Gard II (Concentrate) (TY26573, TY26574) Product description: Ethylene Glycol based Antifreeze/Coolant MANUFACTURER: EMERGENCY TELEPHONE NUMBERS: Northland Products Company Chemtrec: 1-[PHONE REDACTED] 1000 Rainbow Drive Waterloo, IA 50704 [PHONE REDACTED], 1-[PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS wt. Percent CAS Registry # Monoethylene Glycol > 90 000107-21-1 Diethylene Glycol 5 max 000111-46-6 Proprietary Inhibitors 1-5 Mixture Water 3 max 007732-18-5 3. HAZARD IDENTIFICATION Emergency Overview: Liquid, dyed golden with a mild odor. Excessive exposure may cause irritation to the upper respiratory tract. Ingestion of very large amounts of Ethylene Glycol may cause birth defects. Exposure through inhalation and skin contact did not cause birth defects in animal reproduction. In-vitro (test tube) and animal mutagenicity tests have been negative. Exposure should be minimized. POTENTIAL HEALTH EFFECTS: INHALATION: Vapors are minimal under normal conditions but should be avoided, concentrations may reach levels that could cause irritation. EYE CONTACT: May cause slight temporary eye irritation. Corneal injury is unlikely. Vapors or mists may irritate eyes. SKIN CONTACT: Potentially irritating to the skin (irritant, Sensitizer). INGESTION: Excessive exposure may cause central nervous system effects, cardiopulmonary effects, and kidney failure. Single dose oral toxicity is moderate. Single dose oral LD50(Rat) Accute=4700ppm, (Hamster) Accute=12565ppm. Amounts ingested incidental to normal handling are not likely to cause injury; however ingestion to larger amounts could cause serious injury, even death. Page 70 of 190 Page 70 of 190 Page 70 of 190 Page 70 of 190 ---PAGE BREAK--- John Deere Cool Gard II Page 2 of 5 3. HAZARD IDENTIFICATION (Continued) OTHER: Excessive exposure may cause irritation to upper respiratory tract. Observations in long term high dose animal studies with ethylene glycol and diethylene glycol include bladder stones, kidney and liver effects and deposition of calcium salts in various tissues. Ethylene glycol did not cause cancer in long term animal studies. Based on animal studies, ingestion of very large amounts of ethylene glycol appears to be the only way to produce birth defects. Birth defects are unlikely from exposure to diethylene glycol. Results of in-vitro mutagenicity tests have been negative. Results of mutagenicity tests in animals have also been negative. Hazardous Material Identification System (HMIS): Health-2, Flammability-1, Reactivity-0 (Based on components) 4. FIRST AID MEASURES INHALATION: Remove the victim from the area to fresh air. Call a physician. Give oxygen if victim is breathing hard. EYE CONTACT: Flush eyes with large amounts of water immediately for 15 minutes or until irritation subsides. If irritation persists, get medical attention. SKIN CONTACT: Wash affected areas thoroughly with soap and water. Remove contaminated clothing and wash them before wearing again. Call a physician if irritation persists. INGESTION: If swallowed, IMMEDIATELY contact a poison control center, emergency treatment center or a physician. Never give anything by mouth to an unconscious person. NOTE TO DOCTOR: Supportive care. Treatment based on judgement of the physician in response to reactions of the patient. In treatment of intoxication, the use of ethanol, hemodialysis and intravenous fluids to control acidosis should be considered. 5. FIRE FIGHTING MEASURES Flash point : 248oF Minimum (COC) Flammable limits : Upper=15.3%, Lower=3.2% Autoignition Temperature: 442oF, (228oC) approximately Page 71 of 190 Page 71 of 190 Page 71 of 190 Page 71 of 190 ---PAGE BREAK--- Flammability: : Combustible John Deere Cool Gard II Page 3 of 5 5. FIRE FIGHTING MEASURES (Continued) GENERAL HAZARD: No hazards under normal conditions; however, engine components can be at temperatures above the flash, fire and autoignition point. Avoid spills in the engine compartment. FIRE FIGHTING INSTRUCTIONS: Either allow fire to burn out under controlled conditions or extinguish with foam, CO2, or dry chemical. Try to cover liquid spills with foam. Shut off fuel to fire if possible to do so without hazard. FIRE FIGHTING EQUIPMENT: NIOSH approved self-contained breathing apparatus and eye protection are required for fire fighting personnel on all indoor fires and any significant outdoor fires. HAZARDOUS COMBUSTION PRODUCTS: Smoke, fumes, carbon monoxide, carbon dioxide and water. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) Health-2, Flammability-1, Reactivity-0 (Based on components) 6. ACCIDENTAL RELEASE MEASURES Notify the appropriate authorities immediately. Take all actions necessary to prevent adverse effects of the spill. Eliminate ignition sources. Shut off leak if safe to do so. Dike spilled liquid with sand/earth and dispose of properly. DO NOT use sawdust or other combustible materials. Prevent product from entering sewers or waterways. National Response Center 1-[PHONE REDACTED] 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient STORAGE PRESSURE: Atmospheric GENERAL: Keep container closed. Loosen closure cautiously before opening. Store in well ventilated area away from incompatible materials. (See Section 10) Keep away from heat, sparks and flames. Empty container may still retain hazardous properties. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Use mechanical ventilation to control vapor concentrations in confined spaces. General ventilation should be sufficient for Page 72 of 190 Page 72 of 190 Page 72 of 190 Page 72 of 190 ---PAGE BREAK--- most operations. John Deere Cool Gard II Page 4 of 5 8. EXPOSURE CONTROL / PERSONAL PROTECTION (Continued) PERSONAL PROTECTION: Respirator: Use an air supplied respirator when concentrations are over the exposure limits. Protective Clothing: For brief contact, no precautions are necessary. Wear nitrile/neoprene gloves, nitrile/neoprene boots, a chemical worker's suit and chemical splash goggles as appropriate. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling point : 330oF approximately Vapor pressure : Very low (0.05mmHg @ 20oC) Vapor density : > 1 Solubility in water : Completely miscible Specific gravity : 1.11 - 1.14 @ 60oF pH : Basic: 9-11 Odor : Sweet Appearance : Golden Physical state : Liquid 10. STABILITY AND REACTIVITY GENERAL: This product is stable under normal storage conditions. INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID: Oxidizing agents. HAZARDOUS DECOMPOSITION: None. HAZARDOUS POLYMERIZATION: Will not occur 11. TOXICOLOGICAL INFORMATION No component of this product present at levels greater than 0.1 is identified as a carcinogen by NTP, IARC or OSHA. Data on animal testing is provided in section 3 (other). No data on humans; Exposure can cause Nausea, Headache & Vomiting. Page 73 of 190 Page 73 of 190 Page 73 of 190 Page 73 of 190 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION No data is available. John Deere Cool Gard II Page 5 of 5 13. DISPOSAL CONSIDERATIONS Ensure disposal is in compliance with Federal-State-Local laws. Do not landfill or dispose of in sink drains or sewers. 14. TRANSPORTATION INFORMATION DOT (Department of Transportation): Proper shipping name : Environmentally Hazardous Substance, Liquid, n.o.s.,(Contains Ethylene Glycol), UN 3082, PG III Hazard class : 9 Labeling : Warning! Harmful or fatal if swallowed. Avoid excessive exposure. Avoid breathing sprays or mists. * This product is only regulated in single containers over 5000 pounds 15. REGULATORY INFORMATION TSCA(Toxic Substance Control Act): All components of this product are listed on the U.S. TSCA inventory. CERCLA(Comprehensive Response Compensation, and Liability Act): This product is not subject to any special reporting under the requirements of CERCLA under 5000 pounds. We recommend you contact local authorities to determine local reporting requirements. SARA TITLE III(Superfund Amendments and Reauthorization Act): 311/312 Hazard Categories: This material is defined as hazardous by OSHA under 29 CFR part 1910.1200(d). Immediate health hazard and delayed health hazard. 313 Reportable Ingredients: Contains approximately 90 weight percent of Ethylene Glycol. 16. OTHER INFORMATION THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED TO BE DEPENDABLE AND IS ACCURATE TO THE BEST OF NORTHLAND PRODUCTS COMPANY'S KNOWLEDGE; HOWEVER, NORTHLAND PRODUCTS COMPANY MAKES NO WARRANTY WHATSOEVER, EXPRESSED OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR THE PARTICULAR PURPOSE, REGARDING THE ACCURACY OF SUCH DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NORTHLAND PRODUCTS COMPANY ASSUMES NO RESPONSIBILITY FOR THE INJURY TO THE RECIPIENT OR TO Page 74 of 190 Page 74 of 190 Page 74 of 190 Page 74 of 190 ---PAGE BREAK--- THIRD PARTY PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY AND RECIPIENT ASSUMES ALL SUCH RISKS. Page 75 of 190 Page 75 of 190 Page 75 of 190 Page 75 of 190 ---PAGE BREAK--- Page 1 of 5 Updated 04-02-2012 MATERIAL SAFETY DATA SHEET Supersedes 12-01-10 MSDS# 11B8 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: John Deere Plus-50 II SAE 15W-40 Product description: API CJ-4 Engine Oil/Lubricant TY26682, TY26686 MANUFACTURER: EMERGENCY TELEPHONE NUMBERS: Northland Products Company Chemtrec: 1-[PHONE REDACTED] 1000 Rainbow Drive Waterloo, IA 50704 [PHONE REDACTED], 1-[PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS wt. Percent CAS Registry # Lube Oil Base Stock 75-82 064742-54-7 Petroleum Additives 18-25 Mixture 3. HAZARD IDENTIFICATION Emergency Overview: Clear, Amber, Liquid. (May be dyed or odor-masked.) Health studies have shown that petroleum hydrocarbons pose potential human health risks which may vary from person to person. Exposure to liquids, mists, vapors and fumes should be minimized. POTENTIAL HEALTH EFFECTS: INHALATION: Vapors are minimal under normal conditions but should be avoided, concentrations may reach levels that could cause slight irritation. EYE CONTACT: May cause slight temporary eye irritation. Corneal injury is unlikely. Vapors or mists may irritate eyes. SKIN CONTACT: May cause skin irritation. Discontinue use if irritation persists. INGESTION: Ingestion of oil may irritate the digestive tract and could cause diarrhea. Single dose oral toxicity of oil is greater than 5000 mg/Kg in rats. OTHER: The TLV has not been determined for this material. The TLV for oil mists is 5 mg/cubic meter. Hazardous Material Identification System (HMIS): Health-1, Flammability-1, Reactivity-0 (Based on components) Page 76 of 190 Page 76 of 190 Page 76 of 190 Page 76 of 190 ---PAGE BREAK--- John Deere Plus-50 II 15W40 Page 2 of 5 4. FIRST AID MEASURES INHALATION: Remove the exposed person from the area to fresh air. Call a physician. Give oxygen if victim is breathing hard. EYE CONTACT: Flush eyes with large amounts of water immediately for 15 minutes or until irritation subsides. If irritation persists, get medical attention. SKIN CONTACT: Wash affected areas thoroughly with soap and water. Remove contaminated clothing and wash them before wearing again. Call a physician if irritation persists. INGESTION: Call a doctor immediately. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. 5. FIRE FIGHTING MEASURES Flash point : 425oF (COC) Flammable limits : Not Determined Auto-ignition Temperature: Not Available GENERAL HAZARD: May release vapors that form flammable mixtures when temperatures are at or above the flash point. Toxic gases will form upon combustion. FIRE FIGHTING INSTRUCTIONS: Either allow fire to burn out under controlled conditions or extinguish with foam, CO , or dry chemical. Try to cover 2 liquid spills with foam. Shut off fuel to fire if possible to do so without hazard. FIRE FIGHTING EQUIPMENT: NIOSH approved self-contained breathing apparatus and eye protection are required for firefighting personnel on all indoor fires and any significant outdoor fires. HAZARDOUS COMBUSTION PRODUCTS: Smoke, fumes, carbon monoxide, carbon dioxide and water. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) Health-1, Flammability-1, Reactivity-0 (Based on components) 6. ACCIDENTAL RELEASE MEASURES Notify the appropriate authorities immediately. Take all actions necessary to prevent adverse effects of the spill. Eliminate ignition sources. Shut off leak if safe to do so. Dike spilled liquid with sand/earth and dispose of properly. DO NOT use sawdust or other combustible materials. Prevent product from entering sewers or waterways. National Response Center 1-[PHONE REDACTED] Page 77 of 190 Page 77 of 190 Page 77 of 190 Page 77 of 190 ---PAGE BREAK--- John Deere Plus-50 II 15W40 Page 3 of 5 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient STORAGE PRESSURE: Atmospheric GENERAL: Keep container closed. Loosen closure cautiously before opening. Store in well ventilated area away from incompatible materials. (See Section 10) Keep away from heat, sparks and flames. Empty container may still retain hazardous properties. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Use mechanical ventilation to control vapor concentrations in confined spaces. General ventilation should be sufficient for most operations. PERSONAL PROTECTION: Respirator: Use an air supplied respirator when concentrations are over the exposure limits. Protective Clothing: Wear rubber gloves, rubber boots, a chemical worker's suit and chemical splash goggles as appropriate. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling point : Not Available Vapor pressure : Negligible at ambient Vapor density : Not determined Solubility in water : Negligible Specific gravity : 0.878 pH : Not available Odor : Petroleum (Could be masked) Appearance : Clear Amber (Could be dyed) Physical state : Liquid 10. STABILITY AND REACTIVITY GENERAL: This product is stable and will not polymerize. INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID: Strong oxidizing agents. HAZARDOUS DECOMPOSITION: Alkyl Mercaptans, Hydrogen Sulfide Page 78 of 190 Page 78 of 190 Page 78 of 190 Page 78 of 190 ---PAGE BREAK--- John Deere Plus-50 II 15W40 Page 4 of 5 11. TOXICOLOGICAL INFORMATION No component of this product present at levels greater than 0.1% are identified as a carcinogen by NTP, IARC or OSHA. 12. ECOLOGICAL INFORMATION This material is expected be toxic to aquatic animals and is not expected to be readily biodegradable based on data for the additive. 13. DISPOSAL CONSIDERATIONS Ensure disposal is in compliance with Federal-State-Local laws. Do not landfill or dispose of in sink drains or sewers. Recycle is possible. 14. TRANSPORTATION INFORMATION DOT (Department of Transportation): Proper shipping name : Petroleum Lubricating Oil. Hazard class : Not regulated Identification number : Not regulated Labeling : Not regulated 15. REGULATORY INFORMATION CERCLA(Comprehensive Response Compensation, and Liability Act): This product is not subject to any special reporting under the requirements of CERCLA. We recommend you contact local authorities to determine local reporting requirements. SARA TITLE III(Superfund Amendments and Reauthorization Act): 311/312 Hazard Categories: This material is not classified as hazardous by OSHA under 29 CFR part 1910.1200(d). 313 Reportable Ingredients: Contains less than 1 weight percent of Zinc compounds. International Inventory Status: United States : All components on TSCA Inventory Page 79 of 190 Page 79 of 190 Page 79 of 190 Page 79 of 190 ---PAGE BREAK--- John Deere Plus-50 II 15W40 Page 5 of 5 15. REGULATORY INFORMATION (Continued) Canada : All components comply with DSL Europe : All components on EINECS (Secondary notification by importer may be required.) Japan : All components on MITI or MOL Australia : All components notified but may not be on NICNAS (Secondary notification by importer may be required.) Korea : All components notified but may not be on ECL (Secondary notification by importer may be required.) China : One or more additive components do not comply with the chemical inventory requirements of IECSC Philippines : All components on PICCS 16. OTHER INFORMATION THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED TO BE DEPENDABLE AND IS ACCURATE TO THE BEST OF NORTHLAND PRODUCTS COMPANY'S KNOWLEDGE; HOWEVER, NORTHLAND PRODUCTS COMPANY MAKES NO WARRANTY WHATSOEVER, EXPRESSED OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR THE PARTICULAR PURPOSE, REGARDING THE ACCURACY OF SUCH DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NORTHLAND PRODUCTS COMPANY ASSUMES NO RESPONSIBILITY FOR THE INJURY TO THE RECIPIENT OR TO THIRD PARTY PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY AND RECIPIENT ASSUMES ALL SUCH RISKS. Page 80 of 190 Page 80 of 190 Page 80 of 190 Page 80 of 190 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 1 Klean Strip Odorless Mineral Spirits and Odorless Painter's Solvent SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Klean Strip Odorless Mineral Spirits and Odorless Painter's Solvent Product Name: W. M. Barr Company Name: 2105 Channel Avenue Memphis, TN 38113 3E 24 Hour Emergency Contact Emergency Contact: (800)451-8346 W.M. Barr Customer Service Information: (800)398-3892 (901)775-0100 Phone Number: For thinning oil-based paint, stain and varnish. Intended Use: www.wmbarr.com Web site address: QKSP94205CA, GKSP94214CA, QKSP94005CA, QKSP94005LCA, GKSP94006CA, GKSP94006PCA, GKSP94006SC, GKSP94006PSC, GKSP94214SC, QKSP94205SC, QKSP94005SC Synonyms: 1. PRODUCT AND COMPANY IDENTIFICATION This product is regulated by the United States Consumer Product Safety Commission and is subject to certain labeling requirements under the Federal Hazardous Substances Act. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS). The product label also includes other important information, including directions for use, and should always be read in its entirety prior to using the product. Additional Information 2. HAZARDS IDENTIFICATION No phrases apply. GHS Precaution Phrases: P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. GHS Response Phrases: P405: Store locked up. P501: Dispose of contents/container according to local, state and federal regulations. GHS Storage and Disposal Phrases: H304: May be fatal if swallowed and enters airways. H336: May cause drowsiness or dizziness. GHS Hazard Phrases: Aspiration Toxicity, Category 1 Danger GHS Signal Word: Hazard Rating System: Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PPE PHYSICAL 1 0 1 X 1 1 0 NFPA: HMIS: This material is classified as hazardous under OSHA regulations. OSHA Regulatory Status: INHALATION: Vapor harmful. Danger of serious damage to health by prolonged exposure through inhalation. SKIN CONTACT: Prolonged skin contact may cause skin irritation and/or dermatitis. EYE CONTACT: Liquid contact may cause irritation. INGESTION: Potential Health Effects (Acute and Chronic): Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 81 of 190 Page 81 of 190 Page 81 of 190 Page 81 of 190 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 2 Klean Strip Odorless Mineral Spirits and Odorless Painter's Solvent SAFETY DATA SHEET 03/26/2015 Supersedes Revision: None known. Medical Conditions Generally Aggravated By Exposure: Harmful or fatal if swallowed. May cause gastrointestinal irritation, nausea, vomiting, and diarrhea. CHRONIC EFFECTS: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. TARGET ORGANS: skin, central nervous system PRIMARY ROUTES OF ENTRY: inhalation, skin contact CAS # Hazardous Components (Chemical Name) 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration RTECS # 64742-47-8 Hydrotreated light distillate (petroleum) 100.0 % OA5504000 4. FIRST AID MEASURES Skin: Wash the skin thoroughly with water and soap, if available, while removing contaminated clothing. Seek medical attention if irritation develops or persists. Eyes: Immediately begin to flush eyes with water, remove any contact lens. Continue to flush the eyes for at least 15 minutes. Seek medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Seek immediate medical attention. Call a physician, hospital emergency room, or poison control center immediately. Never give anything by mouth to an unconscious person. Emergency and First Aid Procedures: See Potential Health Effects. Signs and Of Exposure: 5. FIRE FIGHTING MEASURES Flash Pt: 218.00 F Method Used: Pensky-Marten Closed Cup Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions: No data available. Flammable Properties and Hazards: Autoignition Pt: 456.80 F Explosive Limits: LEL: 0.6 % UEL: 5.5 % NFPA Class IIIB Use carbon dioxide, dry powder, foam, or water spray / fog. Suitable Extinguishing Media: None known. Unsuitable Extinguishing Media: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 82 of 190 Page 82 of 190 Page 82 of 190 Page 82 of 190 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 3 Klean Strip Odorless Mineral Spirits and Odorless Painter's Solvent SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Flammability Classification: 6. ACCIDENTAL RELEASE MEASURES Isolate the immediate area. Prevent unauthorized entry. Eliminate all sources of ignition in area and downwind of the spill area. Stay upwind, out of low areas, and ventilate closed spaces before entering. All equipment used when handling this product must be grounded or non-sparking. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to compatible containers. For large spills, dike ahead of the spill for possible collection and reuse or disposal. Steps To Be Taken In Case Material Is Released Or Spilled: 7. HANDLING AND STORAGE Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Do not use near any source of heat or open flame, furnace areas, pilot lights, stoves, etc. Ensure all equipment is electrically grounded before beginning transfer operations. Avoid prolonged skin contact. Precautions To Be Taken in Handling: Keep container closed when not in use. Store in a cool, dry place. Do not store near any source of heat or open flame, furnace areas, pilot lights, stoves, etc. Precautions To Be Taken in Storing: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA TWA ACGIH TWA CAS # Partial Chemical Name Other Limits No data. TLV: 200 mg/m3 64742-47-8 Hydrotreated light distillate (petroleum) No data. For use in areas with inadequate ventilation or fresh air, wear a properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. For OSHA controlled work places and other regular users - Use only with adequate ventilation under engineered air control systems designed to prevent exceeding the appropriate TLV. A dust mask does not provide protection against vapors. Respiratory Equipment (Specify Type): Chemical splash goggles should be worn to prevent eye contact. Eye Protection: Wear gloves with as much resistance to the chemical ingredients as possible. Glove materials such as nitrile rubber may provide protection. Glove selection should be based on chemicals being used and conditions of use. Consult your glove supplier for additional information. Gloves contaminated with product should be discarded and not reused. Protective Gloves: Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Other Protective Clothing: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Engineering Controls (Ventilation etc.): Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 83 of 190 Page 83 of 190 Page 83 of 190 Page 83 of 190 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 4 Klean Strip Odorless Mineral Spirits and Odorless Painter's Solvent SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Use only with adequate ventilation to prevent buildup of vapors. Do not use in areas where vapors can accumulate and concentrate, such as basements, bathrooms or small enclosed areas. Whenever possible, use outdoors in an open air area. If using indoors open all windows and doors and maintain a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea or eye-watering STOP ventilation is inadequate. Leave area immediately and move to fresh air. Wash hands thoroughly after use and before eating, drinking, or smoking. Do not eat, drink, or smoke in the work area. Facilities storing or handling this material should be equipped with an emergency eyewash and safety shower. Work/Hygienic/Maintenance Practices: 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: -72.40 F Boiling Point: 449.00 F - 505.00 F Autoignition Pt: 456.80 F Flash Pt: 218.00 F Method Used: Pensky-Marten Closed Cup Explosive Limits: LEL: 0.6 % UEL: 5.5 % Specific Gravity (Water = 0.8102 at 25.0 C Density: 6.84 LB/GL Aromatic hydrocarbon-like odor. Clear liquid. Appearance and Odor: Vapor Pressure (vs. Air or mm Hg): 0.05 MM HG at 78.0 F Vapor Density (vs. Air = 5.9 Air = 1 Evaporation Rate: 0.02 Solubility in Water: Not Soluble Percent Volatile: 100.0 % by weight. VOC / Volume: 0.0000 G/L Additional Physical Information This product is not a VOC as defined by the California Air Resources Board (CARB). 10. STABILITY AND REACTIVITY No data available. Conditions To Avoid - Instability: Unstable [ ] Stable [ X ] Stability: Incompatible with oxidizing agents. Incompatibility - Materials To Avoid: Thermal decomposition may produce carbon monoxide and carbon dioxide. Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ] Possibility of Hazardous Reactions: No data available. Conditions To Avoid - Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 84 of 190 Page 84 of 190 Page 84 of 190 Page 84 of 190 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 5 Klean Strip Odorless Mineral Spirits and Odorless Painter's Solvent SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Hazardous Reactions: CAS # Hazardous Components (Chemical Name) NTP 11. TOXICOLOGICAL INFORMATION Refer to section 2 for acute and chronic effects. Toxicological Information: Chronic Toxicological Effects: ACGIH A4 - Not Classifiable as a Human Carcinogen. Carcinogenicity/Other Information: IARC ACGIH OSHA 64742-47-8 Hydrotreated light distillate (petroleum) n.a. n.a. A4 n.a. No data available. General Ecological Information: 12. ECOLOGICAL INFORMATION Dispose in accordance with applicable local, state, and federal regulations. Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION Paint Related Material, Not Regulated DOT Proper Shipping Name: DOT Hazard Class: UN/NA Number: LAND TRANSPORT (US DOT): The shipper / supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Additional Transport Information: CAS # Hazardous Components (Chemical Name) 15. REGULATORY INFORMATION S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 64742-47-8 Hydrotreated light distillate (petroleum) No No No Yes [ ] No Acute (immediate) Health Hazard Yes [ ] No Chronic (delayed) Health Hazard [ ] Yes No Fire Hazard [ ] Yes No Sudden Release of Pressure Hazard [ ] Yes No Reactive Hazard This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 64742-47-8 Hydrotreated light distillate (petroleum) CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 85 of 190 Page 85 of 190 Page 85 of 190 Page 85 of 190 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 6 Klean Strip Odorless Mineral Spirits and Odorless Painter's Solvent SAFETY DATA SHEET 03/26/2015 Supersedes Revision: All components of this material are listed on the TSCA Inventory or are exempt. Regulatory Information Statement: 16. OTHER INFORMATION No data available. Additional Information About This Product: The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer: 04/14/2015 Revision Date: W.M. Barr EHS Department (901)775-0100 Preparer Name: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 86 of 190 Page 86 of 190 Page 86 of 190 Page 86 of 190 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 16-Dec-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19910C Product name Kwikee Penetrating Oil Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin. Inhalation. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Reddening. Itching. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Upper respiratory tract irritation. Extreme overexposure may cause. Headaches. Dizziness. Nausea. Loss of coordination. Central nervous system depression. Liver damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion No information available. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Tetrachloroethylene 127-18-4 40-70 Butane 106-97-8 7-13 Propane 74-98-6 7-13 Solvent naphtha (petroleum), medium aliphatic 64742-88-7 7-13 Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 3-7 Petroleum distillates, solvent-refined light paraffinic 64741-89-5 1-5 n-Butyl alcohol 71-36-3 0.5-1.5 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Ingestion Do Not induce vomiting. Seek medical attention immediately. Inhalation Remove to fresh air. Restore breathing. Keep warm and quiet. 5. FIRE FIGHTING MEASURES Flash point °C < -17.78 Flash point °F < 0 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 11.2 Lower 1.0 Specific Information for Aerosol Products Flame extension 30" w/o extension tube; 36" w/ extension tube Flashback None Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Flammable. Contents under pressure. Irritating to eyes. Irritating to skin. Page 87 of 190 Page 87 of 190 Page 87 of 190 Page 87 of 190 ---PAGE BREAK--- Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Vapors may accumulate readily and may ignite explosively. Turn off other sources of ignition prior to use and until all vapors have dissipated. Ensure adequate ventilation. Do not smoke. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Thoroughly wash hands and exposed skin after handling. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Contents under pressure. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Do not puncture or incinerate. Do not take internally. Keep out of reach of children. Storage Store in temperatures below 120 degrees F (50 degrees C) . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Solvent naphtha (petroleum), medium aliphatic 100 ppm - - - Tetrachloroet hylene 100 ppm 200 ppm 25 ppm 100 ppm Petroleum distillates, solvent- refined light paraffinic - - - - Petroleum distillates, hydrotreated heavy naphthenic - - - - n-Butyl alcohol 100 ppm 300 mg/m3 - 20 ppm - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Local: recommended. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands after handling the product. Other precautions Avoid breathing vapors or mists. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Gloves are not required in normal use. The following gloves are recommended for prolonged or repeated contact: . Chemical resistant gloves. Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity 1.00 Vapor pressure No data available Density 8.33 lb/gal; 998 g/l Vapor density >Air Evaporation Rate >1 (Ether Water solubility No data available VOC Content 30.00% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 201 Boiling point/range °F < -0 - 395 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17.78 Flash point °F < 0 10. STABILITY AND REACTIVITY Page 2 / 4 Product name Kwikee Penetrating Oil Product code 19910C Page 88 of 190 Page 88 of 190 Page 88 of 190 Page 88 of 190 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None known. Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Hydrogen chloride. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Solvent naphtha (petroleum), medium aliphatic 64742-88-7 5000 mg/kg 3000 mg/kg 5.28 mg/L Tetrachloroethyle ne 127-18-4 2629 mg/kg - 4000 ppm Petroleum distillates, solvent-refined light paraffinic 64741-89-5 5000 mg/kg 5 g/kg 2.18 mg/L Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 28710 mg/kg - - n-Butyl alcohol 71-36-3 - - 8000 ppm Synergistic Products None known Specific Hazards Reports have associated repeated and prolonged occupational exposure to solvents with permanent brain damage. Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2. Urinary system. Carcinogenic effects NTP and IARC have determined that exposure to tetrachloroethylene (perchloroethylene) is reasonably anticipated to be carcinogenic to humans (IARC Group 2A). Risk of cancer depends on duration and level of exposure. . Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Solvent naphtha (petroleum), medium aliphatic Not Listed Not Listed Not Listed Not Listed Not Listed Tetrachloroet hylene A3 Group 2A Not Listed Reasonabl y Anticipated To Be A Human Carcinoge n Listed Petroleum distillates, solvent- refined light paraffinic Not Listed Not Listed Not Listed Not Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Not Listed Not Listed n-Butyl alcohol Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Page 3 / 4 Microtox Data Tetrahymena pyriformis EC50=100 mg/L (24 h) Nitrosomonas EC50=112 mg/L (24 h) Photobacterium phosphoreum EC50=120.0 mg/L (30 min) Petroleum distillates, hydrotreated heavy naphthenic Product name Kwikee Penetrating Oil Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Water Flea Data Daphnia magna EC506.1 - 9.0 mg/L (48 h) Tetrachloroethylene Solvent naphtha (petroleum), medium aliphatic Product code 19910C Water Flea Data Daphnia magna hEC50 48 (>100 mg/L) Page 89 of 190 Page 89 of 190 Page 89 of 190 Page 89 of 190 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Discard container or liner in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Tetrachloroethyle ne Listed n-Butyl alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane Listed Listed Not Listed Butane Listed Listed Not Listed Solvent naphtha (petroleum), medium aliphatic Not Listed Not Listed Not Listed Tetrachloroethylene Listed Listed Carcinogen Petroleum distillates, solvent-refined light paraffinic Not Listed Not Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed n-Butyl alcohol Listed Listed Not Listed WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane X X - X Butane X X - X Solvent naphtha (petroleum), medium aliphatic X X - X Tetrachloroethylene X X - X Petroleum distillates, solvent-refined light paraffinic X X - X Petroleum distillates, hydrotreated heavy naphthenic X X - X n-Butyl alcohol X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 * Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 n-Butyl alcohol Petroleum distillates, solvent-refined light paraffinic Microtox Data Photobacterium phosphoreum EC50=2041.4 mg/L (5 min) Photobacterium phosphoreum EC50=2186 mg/L (30 min) Aerobic heterotroph EC50=3980 mg/L (24 h) Pseudomonas putida EC50=4400 mg/L (17 h) Product code 19910C Product name Kwikee Penetrating Oil Water Flea Data Daphnia magna EC501897 - 2072 mg/L (48 h) Daphnia magna EC50=1983 mg/L (48 h) Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Page 90 of 190 Page 90 of 190 Page 90 of 190 Page 90 of 190 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Brand Name: National Product Name(s): Bar & Chain Manufacturer: Pinnacle Oil, Inc. Address: 5009 W. 81st Street City: Indianapolis State: IN Zip: 46268 Phone: (800) 829-8899 Fax: (317) 875-0889 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Name: CAS#: % Volume: ACGIH TLV ACGIH STEL OSHA PEL Emergency Number: (800) 829-8899 Oil Mist, If Generated None N/A 5 mg/m3, 8 hr. TWA 10 mg/m3, 8 hr. TWA 5 mg/m3, 8 hr. TWA Lubricant Base Oil(Petroleum) Mixture 100 See Oil Mist, if Generated See Oil Mist, if Generated See Oil Mist, If Generated Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness, and a burning sensation. Prolonged or repeated contact can worsen irritation by causing drying and cracking of the skin leading to dermatitis(inflammation). No harmful effects from skin absorption are expected. Inhalation: No information available. Studies by other exposure routes suggest a low degree of toxicity by inhalation. Ingestion: No harmful effects expected from ingestion. Chronic Effects: Effects of overexposure may include irritation of the nose and throat, irritation of the digestive tract, nausea and diarrhea. 3. HAZARDS IDENTIFICATION Potential Health Effects 4. FIRST AID MEASURES Skin: Wipe material from skin and remove contaminated shoes and clothing. Cleanse affected area(s) thoroughly by washing with mild soap and water and, if necessary, a waterless skin cleanser. If irritation or redness develops and persists, seek medical attention. Inhalation: If respiratory develop, move victim away from source of exposure and into fresh air. If persist, seek medical attention. If victim is not breathing, clear airway and immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention. Ingestion: First aid is not normally required; however, if swallowed and develop, seek medical attention. The base oil for this product can be a mixture of any of the following highly refined petroleum streams: 64741-88-4,64742-01-4,64742-54-7,64742-65-0,64742-47-8,8042-47-5,64742-46-7,64742-52-5,64742-54-7,72623-84-8,72623-85-9,72623-86- 0,72623-87-1,178603-63-9,178603-64-0,178603-65-1,178603-66-2, 68037-01-4, 151006-63-2 Note: State, local, or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. All components are listed on the TSCA inventory. Emergency Overview: Oily Liquid with Hydrocarbon Odor. Can cause eye irritation. Can burn in fire, releasing toxic vapors, gases and fumes. Extremely slippery when spilled. Potential Environmental Effects: See Ecological Information, See Section 12. Eye: If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes with clean water. If persist, seek medical attention. Tuesday, November 29, 2011 Page 1 of 4 Date Printed: Page 91 of 190 Page 91 of 190 Page 91 of 190 Page 91 of 190 ---PAGE BREAK--- Note to Physicans: High pressure hydrocarbon injection injuries may produce a substantial necrosis of underlying tissue despite an innocuous appearing external wound. Often these injuries require extensive emergency surgical debridement and all injuries should be evaluated by a specialist in order to assess the extent of the injury. Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term effects. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. 5. FIRE FIGHTING MEASURES Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant(see Section Isolate immediate hazard area, keep unauthorized personnel out. Stop spill release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES Accidental Release Measures: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment including respiratory protection as conditions warrant(see Section 8).
Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate absorbent material.
Notify fire authorities and appropriate federal, state and local agencies. Immediate cleanup of any spill is recommended. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center(phone number [PHONE REDACTED]). 7. HANDLING AND STORAGE Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits(See Section 2 and 8).

Do not wear contaminated clothing or shoes. Use good personal hygiene practices.

High pressure injection of hydrocarbon fuels, hydraulic oils or greases under the skin may have serious consequences even though no or injury may be apparent. This can happen accidentally when using high pressure equipment such as high pressure grease guns, fuel injectiton apparatus or from pinhole leaks in tubing of high pressure hydraulic oil equipment.

Empty containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. Empty drums should be completely drained, properly bunged, and shipped to the supplier or drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations.

Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1 and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Storage: Keep container(s) closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Storage temperatures above 113F may lead to thermal decomposition, resulting in the generation of hydrogen sulfide and other sulfur containing gases. Store only in approved containers. Keep away from any incompatible material(see Section 10). Protect container(s) against physical damage. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits(see Section additional ventilation of exhaust system may be required. Skin: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted physical requirements and other substances in the workplace. Suggested materials for protective gloves include: 4H (PE/EVAL), Nitrile rubber, Silver Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending on conditions of use, a face shield may be necessary. Other Protective Equipment: A source of clean water should be available in the work area for flushing eyes and skin. Impervious clothing should be worn as needed. LEL/UEL % No Data Auto Igniton Temperature: No Data OSHA Flammability Class: Not applicable Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire and Explosion Hazards: This material may burn, but will not ignite readily. Vapors are heavier than air and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat of a fire. Flash Point: 400F-D92 Tuesday, November 29, 2011 Page 2 of 4 Date Printed: Page 92 of 190 Page 92 of 190 Page 92 of 190 Page 92 of 190 ---PAGE BREAK--- Respiratory: A NIOSH certified air purifying respirator with a Type 95(R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits(see Section Shield, Viton. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Brown Physical State: Liquid Odor Characteristic Petroleum pH: Not applicable Vapor Pressure(mm Hg): Not determined Vapor Density(air=1): Not determined Boiling Point/Range: Not determined Freezing/Melting Point: Not applicable Solubility in Water: Not soluble Flash Point: 400F-D92 Flammable/Explosive Limits(%): Not determined NFPA Health: 1 NFPA Flammability: 1 NFPA Reactivity: 0 HMIS Health: 1 HMIS Fire: 1 HMIS Reactivity: 0 10. STABILITY AND REACTIVITY Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid(Incompatibl e Materials): Avoid contact with strong oxidizing agents. Hazardous Decomposition Products: Combustion can yield aldehydes and carbon, nitrogen, sulfur, phosphorus and zinc oxides. Hydrogen sulfide and alkyl mercaptans may also be released. Thermal decomposition may produce hydrogen sulfide and other sulfur-containing gases at temperatures greater than 113F. Hazardous Polymerization: Will not occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including solvent extraction, hydrotreating, and dewaxing to remove aromatics and improve performance characteristic. None of the oils used are listed as a carcinogen by NTP, IARC, or OSHA. Ecological Information: Not Evaluated at this Time Disposal Consideration: This material under most intended uses would become used oil due to contamination by physical or chemical impurities. RECYCLE ALL USED OIL. While being recycled, used oil is regulated by 40 CFR 279. Use resulting in chemical or physical change or contamination may also subject it to regulation as hazardous waste. Under federal regulations, used oil is a solid waste managed under 40 CFR 279. However, in California, used oil is managed as hazardous waste until tested to show it is not hazardous. Consult state and local regulations regarding the proper handling of used oil. In the case of used oil, the intent to discard it may cause the used oil to be regulated as hazardous waste. NOTE: Unless otherwise stated, values are determined at 20C(68F) and 760mm Hg(1 atm) General Hygiene Considerations: There are no known hazards associated with this material when used as recommended. The following general hygiene considerations are recognized as common good industrial hygiene practices: avoid breathing vapor or mist, avoid contact with eyes and skin, wash thoroughly after handling and before eating or drinking. Exposure Guidelines: See Section 2, Composition/Information on Ingredients. Tuesday, November 29, 2011 Page 3 of 4 Date Printed: Page 93 of 190 Page 93 of 190 Page 93 of 190 Page 93 of 190 ---PAGE BREAK--- 14. TRANSPORT INFORMATION 15. REGULATORY INFORMATION 16. OTHER INFORMATION Note: Not classified as hazardous Acute Health: No Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No CERCLA(RQ) : This product is not subject to CERCLA reporting requirements. SARA 313, Toxic Component(s): This Product does not contain >1.0 greater than 0.1% for Carcinogenic substance) of any chemical substances listed under SARA Section 313. Disclamation: This information relates only to the specific material designated and may not be valid for such material used for in combination with other materials or in any process. Such information is, to the best of Pinnacle Oil's knowledge and belief, accurate and reliable as of the date indicated. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitableness and completeness of such information for his particular use. Preparers Info: Pinnacle Oil, Inc. Date Revised: 11/29/2011 Date Prepared: 2 /20/2004 SARA 311/312: OSHA Hazard Determination: This material is not known to be hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. TSCA Inventory: All of the components of this material are listed on the Toxic Chemical Substances Inventor. This product is in compliance with Toxic Substances Control Act(TSCA). SARA 302/304: There are no components in this product on the SARA 302/304 list. California Prop 65: Warning: This material contains the following chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm, and are subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): None Known --
Used engine oils, while not a component of this material, is on the Proposition 65 list of chemicals known to the State of California to cause cancer. Tuesday, November 29, 2011 Page 4 of 4 Date Printed: Page 94 of 190 Page 94 of 190 Page 94 of 190 Page 94 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name : Levington Rose, Tree & Shrub Compost Product code : Not applicable Product description : Growing media Specification Number : 320000001348 Product type : Fibrous solid. Other means of identification : 300000001453 1.2 Relevant identified uses of the substance or mixture and uses advised against Recommended use and restrictions : For use as a home garden growing media/soil conditioner 1.3 Details of the supplier of the safety data sheet The Scotts Company (UK) Limited Salisbury House, Weyside Park, Catteshall Lane Godalming, Surrey GU7 1XE United Kingdom Email: [EMAIL REDACTED] 1.4 Emergency telephone number National advisory body/Poison Center 24 h. EMERGENCY TELEPHONE NUMBER : 01865 407 333 Non-Emergency Calls : 0845 190 1881 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Not classified. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 95 of 190 Page 95 of 190 Page 95 of 190 Page 95 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:2/12 Classification according to Directive 1999/45/EC [DPD] The product is not classified as dangerous according to Directive 67/548/EEC and its amendments. Classification : Not classified. See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and 2.2 Label elements Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : P101 If medical advice is needed: Have product container or label at hand. P103 Read label before use. Response : Not applicable. Storage : P234 Keep only in original container. Disposal : P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Risk phrases : This product is not classified according to EU legislation. Safety phrases : Not applicable. Supplemental label elements : Avoid breathing dust. Wash hands thoroughly after handling. Wear protective gloves. Use only in well-ventilated areas. Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles : Not applicable. 2.3 Other hazards Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII : Not available. Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII : Not available. Other hazards which do not result in classification : None known. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 96 of 190 Page 96 of 190 Page 96 of 190 Page 96 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:3/12 SECTION 3: Composition/information on ingredients Substance/mixture : Mixture There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. SECTION 4: First aid measures 4.1 Description of first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Skin contact : Wash with plenty of soap and water. Get medical attention if occur. Ingestion : Wash out mouth with water. Get medical attention if occur. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. 4.2 Most important and effects, both acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 97 of 190 Page 97 of 190 Page 97 of 190 Page 97 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:4/12 SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. Unsuitable extinguishing media : None known. 5.2 Special hazards arising from the substance or mixture Hazards from the substance or mixture : No specific fire or explosion hazard. Hazardous thermal decomposition products : No specific data. 5.3 Advice for firefighters Special protective actions for fire-fighters : isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Additional information : Not available. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". 6.2 Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3 Methods and materials for containment and cleaning up Small spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Large spill : Move containers from spill area. Vacuum or sweep up material and place in container for disposal. Do not allow to enter drains or watercourses. Dispose of via a licensed waste disposal contractor. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 98 of 190 Page 98 of 190 Page 98 of 190 Page 98 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:5/12 6.4 Reference to other sections : See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. SECTION 7: Handling and storage The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 7.1 Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) Recommendations : Not available. Industrial sector specific solutions : Not available. SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 8.1 Control parameters Occupational exposure limits Ingredient name Occupational exposure limits No exposure limit value known. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 99 of 190 Page 99 of 190 Page 99 of 190 Page 99 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:6/12 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required. DNEL/DMEL Summary : Not available. PNEC Summary : Not available. 8.2 Exposure controls Appropriate engineering controls : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 100 of 190 Page 100 of 190 Page 100 of 190 Page 100 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:7/12 environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state : Fibrous solid. Color : Brown. Odor : Earthy odor Density : 340 kg/m3 pH : 5.8 9.2 Other information No additional information. SECTION 10: Stability and reactivity 10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical stability : The product is stable. 10.3 Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to avoid : No specific data. 10.5 Incompatible materials : No specific data. 10.6 Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Conclusion/Summary : Not available. Acute toxicity estimates Not available. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 101 of 190 Page 101 of 190 Page 101 of 190 Page 101 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:8/12 Irritation/Corrosion Conclusion/Summary Skin : Not available. Eyes : Not available. Respiratory : Not available. Sensitization Conclusion/Summary Skin : Not available. Respiratory : Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely routes of exposure : Not available. Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Long term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Potential chronic health effects Conclusion/Summary : Not available. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 102 of 190 Page 102 of 190 Page 102 of 190 Page 102 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:9/12 General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. SECTION 12: Ecological information 12.1 Toxicity Conclusion/Summary : Not available. 12.2 Persistence and degradability Conclusion/Summary : Not available. 12.3 Bioaccumulative potential Product/ingredient name LogPow BCF Potential Not Applicable - - - 12.4 Mobility in soil Soil/water partition coefficient (KOC) : Not available. Mobility : Not available. 12.5 Results of PBT and vPvB assessment PBT : P: Not available. B: Not available. T: Not available. vPvB : vP: Not available. vB: Not available. 12.6 Other adverse effects : No known significant effects or critical hazards. SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Product Methods of disposal : Do not contaminate water with the product or its container. Do not re-use empty container. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 103 of 190 Page 103 of 190 Page 103 of 190 Page 103 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:10/12 Hazardous waste : Within the present knowledge of the supplier, this product is not regarded as hazardous waste, as defined by EU Directive 91/689/EEC. European waste catalogue (EWC) Waste code Waste designation Not available. Not available. Packaging Methods of disposal : This material and its container must be disposed of in a safe way. SECTION 14: Transport information ADR/RID ADN IMDG IATA 14.1 UN number - - - - 14.2 UN proper shipping name Not classified as dangerous Not classified as dangerous Not classified as dangerous Not classified as dangerous 14.3 Transport hazard class(es) Not available. Not available. Not available. Not available. 14.4 Packing group - - - - 14.5. Environmental hazards No. No. No. No. Additional information 14.6 Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.’ 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not available. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 104 of 190 Page 104 of 190 Page 104 of 190 Page 104 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:11/12 SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization Substances of very high concern Carcinogen: Not listed Mutagen: Not listed Toxic to reproduction: Not listed PBT: Not listed vPvB: Not listed Other EU regulations Europe inventory : Not determined. Integrated pollution prevention and control list (IPPC) - Air : Not listed Integrated pollution prevention and control list (IPPC) - Water : Not listed Aerosol dispensers : Not applicable. Seveso III Directive This product is not controlled under the Seveso III Directive. 15.2 Chemical Safety Assessment : Not available. SECTION 16: Other information Abbreviations and acronyms : ADN = European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR = European Agreement concerning the International Carriage of Dangerous Goods by Inland Road IATA = International Air Transport Association IMDG = International Maritime Dangerous Good Code ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level DMEL = Derived Minimal Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number PBT = Persistent, Bioaccumulative and Toxic vPvB = Very Persistent and Very Bioaccumulative Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification Justification Not classified. Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Page 105 of 190 Page 105 of 190 Page 105 of 190 Page 105 of 190 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Levington Rose, Tree & Shrub Compost Page:12/12 Version: 1.1 Date of issue/Date of revision: 02.10.2013 Date of previous issue: 09.11.2012 Full text of abbreviated H statements : Not applicable. Full text of classifications [CLP/GHS] : Not applicable. Full text of abbreviated R phrases : Not applicable. Full text of classifications [DSD/DPD] : Not applicable. Date of printing : 02.10.2013 Date of issue/ Date of revision : 02.10.2013 Date of previous issue : 09.11.2012 Version : 1.1 Prepared by : SSOUCH Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 106 of 190 Page 106 of 190 Page 106 of 190 Page 106 of 190 ---PAGE BREAK--- Peak Global Lifetime Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Peak Global Lifetime Concentrate Antifreeze & Coolant 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Automotive Engine Antifreeze & Coolant 1.3. Details of the supplier of the safety data sheet Old World Industries, LLC 4065 Commercial Ave. IL 60062 - USA T (847) 559-2000 www.oldworldind.com 1.4. Emergency telephone number Emergency number : (800) 424-9300; (703) 527 3887 (International) Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Acute Tox. 4 (Oral) H302 STOT RE 2 H373 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 GHS08 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H302 - Harmful if swallowed H373 - May cause damage to organs (kidneys) through prolonged or repeated exposure (oral) Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe mist, spray, vapors P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear personal protective equipment as required P301+P310 - If swallowed: Immediately call doctor/physician or poison center P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose of contents/container, in a safe manner, to appropriate waste disposal facility, in accordance with local/regional/national/international regulations 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available Page 107 of 190 Page 107 of 190 Page 107 of 190 Page 107 of 190 ---PAGE BREAK--- Peak Global Lifetime Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 2/8 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % by wt GHS-US classification ethylene glycol (CAS No) 107-21-1 90 - 97 Acute Tox. 4 (Oral), H302 diethylene glycol (CAS No) 111-46-6 < 5 Acute Tox. 4 (Oral), H302 STOT RE 2, H373 water (CAS No) 7732-18-5 < 4 Not classified denatonium benzoate (CAS No) 3734-33-6 30 - 50 ppm Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Seek immediate medical advice. Allow the victim to rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. First-aid measures after skin contact : Remove contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Rinse immediately with plenty of water (for at least 15 minutes). Get medical advice/attention. Specific treatment (see supplemental first aid instructions on this label). First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse immediately with plenty of water for 15 minutes, lifting lower and upper lids. If eye irritation persists: Get medical advice and attention. First-aid measures after ingestion : Obtain emergency medical attention. Rinse mouth. If the person is fully conscious, make him/her drink two glasses of water. Never give an unconscious person anything to drink. Do NOT induce vomiting. Call a POISON CENTER/doctor/physician if you feel unwell. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whiskey. For children, give proportionally less liquor, according to weight. Rinse mouth. Call a POISON CENTER/doctor/physician if you feel unwell. 4.2. Most important and effects, both acute and delayed : Causes damage to organs (kidneys) (Oral). after skin contact : Causes skin irritation. after eye contact : Causes serious eye damage. after ingestion : Swallowing a small quantity of this material will result in serious health hazard. The lethal dose in humans is estimated to be 100 mL (3 oz). 4.3. Indication of any immediate medical attention and special treatment needed A more effective intravenous antidote for physician uses is a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occured. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water fog. Fine water spray. Alcohol-resistant foam. Foam. Carbon dioxide. Dry chemical powder. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. May spread fire. 5.2. Special hazards arising from the substance or mixture Fire hazard : During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Reactivity : No dangerous reactions known under normal conditions of use. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Page 108 of 190 Page 108 of 190 Page 108 of 190 Page 108 of 190 ---PAGE BREAK--- Peak Global Lifetime Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 3/8 Special protective equipment for fire fighters : Wear positive pressure self-contained breathing apparatus (SCBA). Protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Refer to section 8.2. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Avoid breathing dust/fume/gas/mist/vapors/spray. Hygiene measures : Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. Product may become solid at temperatures below -18 ºC (0 ºF). Do not store near food, foodstuffs, drugs or potable water supplies. Do not cut, drill, weld, use a blowtorch on, etc. containers even when empty. Incompatible products : Keep away from strong acids, strong bases and oxidizing agents. Incompatible materials : Sources of ignition. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters ethylene glycol (107-21-1) USA ACGIH ACGIH Ceiling (mg/m³) 100.00 mg/m³ USA ACGIH Remark (ACGIH) Upper Respiratory Tract (URT) & Eye irritant 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Gloves. Safety glasses. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : If exposed to levels above exposure limits wear appropriate respiratory protection. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Page 109 of 190 Page 109 of 190 Page 109 of 190 Page 109 of 190 ---PAGE BREAK--- Peak Global Lifetime Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 4/8 Color : Amber Odor : Mild Odor threshold : No data available pH 50% water solution : 8 Relative evaporation rate (butylacetate=1) : Nil Freezing point : -18 °C (0 ºF) Boiling point : 158 °C (317 ºF) Flash point : 116 °C (241 ºF) [100% Ethylene Glycol] ASTM D56 Auto-ignition temperature : 400 °C (752 ºF) [100% Ethylene Glycol] Literature Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : < 0.1 @ 20 ºC Relative vapor density at 20 °C : No data available Specific Gravity : 1.12 Density : 1.12 kg/l (9.3 lbs/gal) Solubility : Water: Complete Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : 3.2 - 15.3 vol % 9.2. Other information VOC content : 0.00 % SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reactions known under normal conditions of use. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Extremely high or low temperatures. Keep away from any flames or sparking source. 10.5. Incompatible materials Keep away from strong acids, strong bases and oxidizing agents. 10.6. Hazardous decomposition products Carbon dioxide. Carbon monoxide. Fume. alcohols. Aldehydes. Ethers. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. denatonium benzoate (3734-33-6) LD50 oral rat 584 mg/kg (Rat) LD50 dermal rabbit > 2,000 mg/kg (Rabbit) ATE US (oral) 584 mg/kg bodyweight ethylene glycol (107-21-1) LD50 oral rat > 5,000 mg/kg (Rat) ATE US (oral) 500 mg/kg bodyweight Page 110 of 190 Page 110 of 190 Page 110 of 190 Page 110 of 190 ---PAGE BREAK--- Peak Global Lifetime Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 5/8 diethylene glycol (111-46-6) LD50 oral rat 12,565 mg/kg (Rat) LD50 dermal rabbit 11,890 mg/kg (Rabbit) ATE US (oral) 500 mg/kg bodyweight ATE US (dermal) 11,890 mg/kg bodyweight Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : May cause damage to organs (kidneys) through prolonged or repeated exposure (oral). Aspiration hazard : Not classified Potential adverse human health effects and : Based on available data, the classification criteria are not met. Harmful if swallowed. after skin contact : Causes skin irritation. after eye contact : Causes serious eye damage. after ingestion : Swallowing a small quantity of this material will result in serious health hazard. The lethal dose in humans is estimated to be 100 mL (3 oz). SECTION 12: Ecological information 12.1. Toxicity denatonium benzoate (3734-33-6) LC50 fish 1 > 1,000 mg/l 96 h; Salmo gairdneri mykiss) EC50 Daphnia 1 13 mg/l (48 h; Daphnia magna) ethylene glycol (107-21-1) LC50 fish 1 53,000 mg/l (96 h; Pimephales promelas; Static system) EC50 Daphnia 1 > 10,000 mg/l (24 h; Daphnia magna) LC50 fish 2 40,761 mg/l (96 h; Salmo gairdneri mykiss); Static system) Threshold limit algae 1 > 10,000 mg/l (168 h; Scenedesmus quadricauda) Threshold limit algae 2 2,000 mg/l (192 h; Microcystis aeruginosa) diethylene glycol (111-46-6) LC50 fish 1 > 5,000 ppm (24 h; Carassius auratus) LC50 other aquatic organisms 1 1,174 mg/l (Xenopus laevis) EC50 Daphnia 1 > 10,000 mg/l (24 h; Daphnia magna) LC50 fish 2 61,072 ppm (168 h; Poecilia reticulata) TLM fish 1 > 32,000 mg/l (96 h; Gambusia affinis) TLM other aquatic organisms 1 > 1,000 ppm (96 h) Threshold limit other aquatic organisms 1 1,174 mg/l (72 h; Xenopus laevis; Toxicity test) Threshold limit other aquatic organisms 2 10,745 mg/l (16 h; Protozoa; Toxicity test) Threshold limit algae 1 2,700 mg/l (168 h; Scenedesmus quadricauda) Threshold limit algae 2 100 mg/l (Selenastrum capricornutum) 12.2. Persistence and degradability denatonium benzoate (3734-33-6) Persistence and degradability Biodegradability in water: no data available. No (test) data on mobility of the substance available. ethylene glycol (107-21-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established. Biochemical oxygen demand (BOD) 0.47 g O2/g substance Chemical oxygen demand (COD) 1.24 g O2/g substance ThOD 1.29 g O2/g substance BOD of ThOD) 0.36 % ThOD Page 111 of 190 Page 111 of 190 Page 111 of 190 Page 111 of 190 ---PAGE BREAK--- Peak Global Lifetime Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 6/8 diethylene glycol (111-46-6) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Biochemical oxygen demand (BOD) 0.02 g O2/g substance Chemical oxygen demand (COD) 1.51 g O2/g substance ThOD 1.51 g O2/g substance BOD of ThOD) 0.015 % ThOD 12.3. Bioaccumulative potential denatonium benzoate (3734-33-6) Log Pow 1.78 (Estimated value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < ethylene glycol (107-21-1) BCF fish 1 10 (72 h; Leuciscus idus) BCF other aquatic organisms 1 0.21 - 0.6 (Procambarus sp.; Chronic) BCF other aquatic organisms 2 190 (24 h; Algae) Log Pow -1.34 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. diethylene glycol (111-46-6) Log Pow -1.98 Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil ethylene glycol (107-21-1) Surface tension 0.048 N/m (20 ºC / 68 ºF) diethylene glycol (111-46-6) Surface tension 0.0485 N/m 12.5. Other adverse effects Effect on ozone layer : No known effect on the ozone layer Effect on global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose of contents/container, in a safe manner, to appropriate waste disposal facility, in accordance with local/regional/national/international regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Transport document description : UN3082 Environmentally hazardous substances, liquid, n.o.s., 9, III UN-No.(DOT) : 3082 DOT NA no. : UN3082 Proper Shipping Name (DOT) : Environmentally hazardous substances, liquid, n.o.s. Department of Transportation (DOT) Hazard Classes : 9 - Class 9 - Miscellaneous hazardous material 49 CFR 173.140 Hazard labels (DOT) : 9 - Class 9 (Miscellaneous dangerous materials) DOT Symbols : G - Identifies PSN requiring a technical name Packing group (DOT) : III - Minor Danger DOT Packaging Exceptions (49 CFR 173.xxx) : 155 DOT Packaging Non Bulk (49 CFR 173.xxx) : 203 Page 112 of 190 Page 112 of 190 Page 112 of 190 Page 112 of 190 ---PAGE BREAK--- Peak Global Lifetime Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 7/8 DOT Packaging Bulk (49 CFR 173.xxx) : 241 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : No limit DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : No limit DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel. Other information : Non Bulk: Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package). ADR No additional information available Transport by sea UN-No. (IMDG) : Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package) Air transport UN-No.(IATA) : Not regulated by IATA (in quantities under 5,000 lbs in any one inner package) SECTION 15: Regulatory information 15.1. US Federal regulations Peak Global Lifetime Concentrate Antifreeze & Coolant EPA TSCA Regulatory Flag Toxic Substances Control Act (TSCA): The intentional ingredients of this product are listed denatonium benzoate (3734-33-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory ethylene glycol (107-21-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 RQ (Reportable quantity, section 304 of EPA's List of Lists) 5000 lb(s) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Ethylene glycol is subject to Tier 1 and/or Tier II annual inventory reporting. SARA Section 313 - Emission Reporting Ethylene glycol is subject to Form R Reporting requirements. diethylene glycol (111-46-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA Peak Global Lifetime Concentrate Antifreeze & Coolant WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects EU-Regulations No additional information available Page 113 of 190 Page 113 of 190 Page 113 of 190 Page 113 of 190 ---PAGE BREAK--- Peak Global Lifetime Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 8/8 Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations Peak Global Lifetime Concentrate Antifreeze & Coolant DSL (Canada): The intentional ingredients of this product are listed ECL (South Korea): The intentional ingredients of this product are listed. EINECS (Europe): The intentional ingredients of this product are listed ENCS (Japan): The intentional ingredients of this product are listed \ \ \ \ 15.3. US State regulations ethylene glycol (107-21-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - - RTK (Right to Know) List SECTION 16: Other information Full text of H-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H302 Harmful if swallowed H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H373 May cause damage to organs through prolonged or repeated exposure NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS GHS US (GHS HazCom 2012) OWI Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this SDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Page 114 of 190 Page 114 of 190 Page 114 of 190 Page 114 of 190 ---PAGE BREAK--- Page 115 of 190 Page 115 of 190 Page 115 of 190 Page 115 of 190 ---PAGE BREAK--- Page 116 of 190 Page 116 of 190 Page 116 of 190 Page 116 of 190 ---PAGE BREAK--- Page 117 of 190 Page 117 of 190 Page 117 of 190 Page 117 of 190 ---PAGE BREAK--- Page 118 of 190 Page 118 of 190 Page 118 of 190 Page 118 of 190 ---PAGE BREAK--- Page 119 of 190 Page 119 of 190 Page 119 of 190 Page 119 of 190 ---PAGE BREAK--- Page 120 of 190 Page 120 of 190 Page 120 of 190 Page 120 of 190 ---PAGE BREAK--- Page 121 of 190 Page 121 of 190 Page 121 of 190 Page 121 of 190 ---PAGE BREAK--- Page 122 of 190 Page 122 of 190 Page 122 of 190 Page 122 of 190 ---PAGE BREAK--- Page 123 of 190 Page 123 of 190 Page 123 of 190 Page 123 of 190 ---PAGE BREAK--- Page 124 of 190 Page 124 of 190 Page 124 of 190 Page 124 of 190 ---PAGE BREAK--- Page 125 of 190 Page 125 of 190 Page 125 of 190 Page 125 of 190 ---PAGE BREAK--- Page 126 of 190 Page 126 of 190 Page 126 of 190 Page 126 of 190 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 1/7 Print Date 2014-12-10 MSDS_CA 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Pennzoil Premium Grease Wheel Bearing 707L Red Uses : Automotive and industrial grease. Product Code : 001B1160 Manufacturer/Supplier : Shell Canada Products 400 - 4th Avenue S.W Calgary AB T2P 0J4 Canada Telephone : [PHONE REDACTED] Fax : [PHONE REDACTED] Emergency Telephone Number CHEMTREC (24 hr) : CHEMTREC (24 hr): [PHONE REDACTED] Canutec (24 hr) : CANUTEC (24 hr): [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Preparation description : A lubricating grease containing highly-refined mineral oils and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. Refer to Chapter 8 for Occupational Exposure Guidelines. 3. HAZARDS IDENTIFICATION WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Physical Description : A lubricating grease containing highly-refined mineral oils and additives. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Health Hazards : Not expected to be a health hazard when used under normal conditions. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. High-pressure injection under the skin may cause serious damage including local necrosis. Used grease may contain harmful impurities. Signs and : Local necrosis is evidenced by delayed onset of pain and tissue damage a few hours following injection. Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Page 127 of 190 Page 127 of 190 Page 127 of 190 Page 127 of 190 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 2/7 Print Date 2014-12-10 MSDS_CA 4. FIRST AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. When using high pressure equipment, injection of product under the skin can occur. If high pressure injuries occur, the casualty should be sent immediately to a hospital. Do not wait for to develop. Obtain medical attention even in the absence of apparent wounds. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat High pressure injection injuries require prompt surgical intervention and possibly steroid therapy, to minimise tissue damage and loss of function. Because entry wounds are small and do not reflect the seriousness of the underlying damage, surgical exploration to determine the extent of involvement may be necessary. Local anaesthetics or hot soaks should be avoided because they can contribute to swelling, vasospasm and ischaemia. Prompt surgical decompression, debridement and evacuation of foreign material should be performed under general anaesthetics, and wide exploration is essential. 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : Typical 274 °C / 525 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V)(based on mineral oil) Auto ignition temperature : > 320 °C / 608 °F Hazardous Combustion Products and Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Page 128 of 190 Page 128 of 190 Page 128 of 190 Page 128 of 190 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 3/7 Print Date 2014-12-10 MSDS_CA Protective Measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Shovel into a suitable clearly marked container for disposal or reclamation in accordance with local regulations. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Storage Temperature: 0 - 50 °C / 32 - 122 °F Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Oil mist, mineral ACGIH TWA 5 mg/m3 ACGIH STEL 10 mg/m3 Consult local authorities for acceptable exposure limits within their jurisdiction. Additional Information : Due to the product's semi-solid consistency, generation of mists and dusts is unlikely to occur. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Page 129 of 190 Page 129 of 190 Page 129 of 190 Page 129 of 190 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 4/7 Print Date 2014-12-10 MSDS_CA Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65 °C (149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Red. Liquid at room temperature. Odour : Slight hydrocarbon. Odour threshold : Data not available pH : Not applicable. Initial Boiling Point and Boiling Range : Data not available Dropping point : Data not available Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.905 at 15 °C / 59 °F Density : Typical 890 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Page 130 of 190 Page 130 of 190 Page 130 of 190 Page 130 of 190 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 5/7 Print Date 2014-12-10 MSDS_CA Kinematic viscosity : Typical 107 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. Hazardous Polymerisation : Data not available Sensitivity to Mechanical Impact : Data not available Sensitivity to Static Discharge : Data not available 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Product contains mineral oils of types shown to be non- carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Other components are not known to be associated with carcinogenic effects. Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used grease may contain harmful impurities that have accumulated during use. The concentration of such harmful impurities will depend on use and they may present risks to health and the environment on disposal. ALL used grease should be handled with caution and skin contact avoided as far as possible. Page 131 of 190 Page 131 of 190 Page 131 of 190 Page 131 of 190 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 6/7 Print Date 2014-12-10 MSDS_CA High pressure injection of product into the skin may lead to local necrosis if the product is not surgically removed. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Acute Toxicity : Poorly soluble mixture.May cause physical fouling of aquatic organisms.Expected to be practically non toxic:LL/EL/IL50 > 100 mg/l(to aquatic organisms)(LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract).Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. Mobility : Semi-solid under most environmental conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION Canadian Road and Rail Shipping Classification This product is not regulated under the Canadian Transportation of Dangerous Goods Regulations for transport by road and rail. Page 132 of 190 Page 132 of 190 Page 132 of 190 Page 132 of 190 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 7/7 Print Date 2014-12-10 MSDS_CA 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Inventory Status EINECS : All components listed. TSCA : All components listed. DSL : All components listed. 16. OTHER INFORMATION MSDS Version Number : 2.2 MSDS Effective Date : 2014-12-10 MSDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. MSDS Regulation : The content and format of this (M)SDS is in accordance with the Controlled Product Regulations. MSDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 133 of 190 Page 133 of 190 Page 133 of 190 Page 133 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 1 - 9 1. Identification of the substance/preparation and of the company/undertaking Product name Permaflex Mixing Concentrate Series 500 NP 452 pearl white Product code 4025331708278 Intended use of the substance/preparation Coating for professional use Company/Undertaking Identification Producer/Supplier SPIES HECKER GMBH Street/Box Postfach 40 02 07 Nat.-Code/Postal code/City DE 50832 Köln Telephone +49 (0)2234/60 19-06 Information on SDS Responsible Department Regulatory Affairs Telephone +49 (0)[PHONE REDACTED] Telefax +49 (0)[PHONE REDACTED] E-mail address [EMAIL REDACTED] Emergency Information Emergency telephone +44 (0)[PHONE REDACTED] For further information, please also consult our Internet site http://www.spieshecker.com 2. Hazards identification The preparation is classified as dangerous in accordance with Directive 1999/45/EC. Human health hazards Classification : Harmful; Irritant; Flammable; Flammable. Harmful by inhalation and in contact with skin. Irritating to skin. Special hazard instructions for humans and environment Contains: methyl methacrylate; n-butyl methacrylate; 2-hydroxyethyl acrylate. May produce an allergic reaction. 3. Composition/information on ingredients Chemical characterization Mixture of resins, pigments, and solvents Hazardous components Substances presenting a health or environmental hazard within the meaning of the DSD 67/548/EEC refering to 1272/ 2008 annex VI EC-No. CAS-No. Chemical Name Concentration Classification 215-535-7 1330-20-7 xylene 25.00 - < 35.00 % R10 Xn; R20/21 Xi; R38 204-658-1 123-86-4 n-butyl acetate 7.00 - < 10.00 % R10 R66 R67 202-849-4 100-41-4 5.00 - < 7.00 % F; R11 Xn; R20 Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 134 of 190 Page 134 of 190 Page 134 of 190 Page 134 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 2 - 9 EC-No. CAS-No. Chemical Name Concentration Classification 201-297-1 80-62-6 methyl methacrylate 0.50 - < 1.00 % R43 Xi; R37/38 F; R11 202-615-1 97-88-1 n-butyl methacrylate 0.25 - < 0.50 % R10 Xi; R36/37/38 R43 NotaD 212-454-9 818-61-1 2-hydroxyethyl acrylate 0.10 - < 0.20 % N; R50 R43 C; R34 T; R24 Up to the given revision date of this safety data sheet no REACh registration numbers are assigned to the chemical substances used in this preparation. Additional advice See full text of R-phrases in chapter 16. 4. First aid measures General advice When persist or in all cases of doubt seek medical advice. Never give anything by mouth to an unconscious person. Inhalation Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped, administer artificial respiration. If unconscious place in recovery position and seek medical advice. If persist, call a physician. Skin contact Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or use recognized skin cleanser. If skin irritation persists, call a physician. Eye contact Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek medical advice. Ingestion If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting. Keep at rest. 5. Fire-fighting measures Hazardous combustion products Fire will produce dense black smoke containing hazardous combustion products (see heading 10). Exposure to decomposition products may be a hazard to health. Fire and Explosion Hazards Flammable liquid. Vapours may form explosive mixtures with air. Remove all sources of ignition. Suitable extinguishing media Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical, Water spray. Extinguishing media which shall not be used for safety reasons High volume water jet Special Protective Equipment and Fire Fighting Procedures Wear as appropriate: Full protective flameproof clothing. Wear self contained breathing apparatus for fire fighting if necessary. In the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter drains or water courses. Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 135 of 190 Page 135 of 190 Page 135 of 190 Page 135 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 3 - 9 Additional advice Cool closed containers exposed to fire with water spray. 6. Accidental release measures Personal precautions Keep in a well-ventilated place. Keep away from sources of ignition. Comply with safety directives (see chapters 7 and Do not inhale vapours. Environmental precautions Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of rivers, lakes or waste water systems. Methods for cleaning up Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in container for disposal according to local regulations. Clean preferably with a detergent; avoid use of solvents. 7. Handling and storage Handling Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this preparation is being used. Safe handling advice Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Preparation may charge electrostatically: always use grounded leads when transferring from one container to another. Operators should wear antistatic footwear and clothing. No sparking tools should be used. Avoid skin and eye contact. Do not breathe vapours or spray mist. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Comply with the health and safety at work laws. If material is a coating, do not sand, flame cut, braze or weld dry coating without an appropriate respirator or appropriate ventilation, and gloves. Advice on protection against fire and explosion Solvent vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Never use pressure to empty container: container is not a pressure vessel. Always keep in containers of same material as the original one. The accumulation of contaminated rags may result in spontaneous combustion. Good housekeeping standards and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other fire hazards. Storage Requirements for storage areas and containers Observe label precautions. Store between 5 and 25 ◦C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage. The storage and use of this product is subject to the requirements of the Dangerous Substances and Explosive Atmospheres Regulations (DSEAR). Up to 50 litres of such highly flammable liquids may be stored in a work area provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE ACOP L135, “Storage of Dangerous Substances.” Advice on common storage Store separately from oxidizing agents and strongly alkaline and strongly acidic materials. 8. Exposure controls/personal protection Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this preparation is being used. Additional technical information on the plant Provide adequate ventilation. This should be achieved by a good general extraction and -if practically feasible- by the use of a local exhaust ventilation. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL, suitable respiratory protection must be worn. Mask with gas filter, type A (EN 141) National occupational exposure limits Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 136 of 190 Page 136 of 190 Page 136 of 190 Page 136 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 4 - 9 CAS-No. Chemical Name Source Time Type Value Note 1330-20-7 xylene STEL 441 mg/m3 STEL 100 ppm TWA 220 mg/m3 TWA 50 ppm 123-86-4 n-butyl acetate STEL 966 mg/cm3 STEL 200 ppm TWA 724 mg/cm3 TWA 150 ppm 100-41-4 STEL 552 mg/m3 STEL 125 ppm TWA 441 mg/m3 TWA 100 ppm 80-62-6 methyl methacrylate STEL 416 mg/cm3 STEL 100 ppm TWA 208 mg/cm3 TWA 50 ppm Protective equipment Personal protective equipment should be worn to prevent contact with eyes, skin or clothing. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand protection The breakthrough time of gloves is unknown for the product itself. The glove material given is recommended on basis of the substances in the preparation. Chemical Name Glove material Glove thickness Break through time xylene Nitrile rubber 0.33 mm 30 min Viton R ⃝ 0.7 mm 480 min n-butyl acetate Viton R ⃝ 0.7 mm 10 min Nitrile rubber 0.33 mm 30 min The protective glove should be checked in each case for their work specific suitability (e.g. mechanical stability, product compatibility, and anti-static properties). When the intended use is for spray application a nitrile glove of the chemical resistance group 3 (e.g. Dermatril R ⃝glove) is to be used. After contamination, the glove has to be changed. If immersing the hands into the product is not avoidable (e.g. maintenance work) a butyl or fluorocarbon rubber glove should be used. When skin exposure may occur to materials specified in section 3 of this SDS, advice should be sought from the glove supplier as to appropriate type to use with this product and the permeation breakthrough times. Care should be taken when working with sharp edged articles as these can easily damage the gloves and make them ineffective. The instructions and information provided by the glove supplier on use, storage, maintenance and replacement must be followed. Damaged gloves or those showing signs of wear should be replaced immediately. Eye protection Wear protective eyewear for protection against solvent spatter. Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 137 of 190 Page 137 of 190 Page 137 of 190 Page 137 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 5 - 9 Skin and body protection Wear suitable protective clothing. Personnel should wear antistatic clothings made of natural fiber or of high temperature resistant fiber. Hygiene measures Wash skin thoroughly with soap and water or use recognized skin cleanser. Do not use organic solvents! Environmental exposure controls Do not let product enter drains. For ecological information refer to section 12. 9. Physical and chemical properties Appearance Form: liquid Colour: white Odour: Characteristic Paint Odor Important health, safety and environmental information Value Method Flash point 23 ◦C Ignition temperature 370 ◦C DIN 51794 Boiling point/boiling range 125 ◦C Lower explosion limit 1 % Upper explosion limit 12.3 % Vapour pressure 4.4 hPa Relative density 1.13 g/cm3 DIN 53217/ISO 2811 Water solubility partly miscible Viscosity (23 <20 s ISO 2431-1993 6 mm Solvent separation test < 3% ADR/RID Content of volatile components (including water) 47.1% Basis Vapour pressure 0.01 kPa pH Not applicable. 10. Stability and reactivity Stability Stable Conditions to avoid Stable under recommended storage and handling conditions (see section Materials to avoid Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions. Hazardous decomposition products When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke, oxides of nitrogen. 11. Toxicological information General observations There is no data available on the product. The product is classified and labelled in accordance with EC directives or respective national laws. See sections 3 and 15 for details. Practical experience Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Contains methyl methacrylate, n-butyl methacrylate, 2-hydroxyethyl acrylate. May produce an allergic reaction. Toxicity Test Type Value Time Species xylene Oral LD50 4,300 mg/kg rat Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 138 of 190 Page 138 of 190 Page 138 of 190 Page 138 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 6 - 9 Toxicity Test Type Value Time Species Dermal LD50 > 1,700 mg/kg rabbit Inhalation LC50 5,000 ppm 4 h rat n-butyl acetate Oral LD50 > 5,000 ml/kg rat Dermal LD50 > 5,000 ml/kg rabbit Inhalation LC50 > 6,335 ppm 4 h rat Oral LD50 3,500 mg/kg rat Dermal LD50 17.8 g/kg rabbit Inhalation LC50 4,000 ppm 4 h rat methyl methacrylate Oral LD50 > 5,000 mg/kg rat Dermal LD50 > 5,000 mg/kg rabbit Inhalation LC50 7,094 ppm 4 h rat n-butyl methacrylate Oral LD50 22,600 mg/kg rat Dermal LD50 11,300 mg/kg rabbit Inhalation LC50 4,910 ppm 4 h rat 2-hydroxyethyl acrylate Oral LD50 548 mg/kg rat Oral LD50 300 mouse Dermal LD50 298 mg/kg rabbit 12. Ecological information There are no data available on the product itself. The product should not be allowed to enter drains or watercourses. The data in this section is consistent with data from chemical safety reports available at the date of revision. Product does not contain organic linked halogens contributing to AOX. Acute toxicity aquatic invertebrates EINECS-No. Chemical Name Species Type Expo- sure time Value Method 212-454-9 2-hydroxyethyl acrylate Water flea LC50 0 0.78 mg/l Acute and extended toxicity of fishes EINECS-No. Chemical Name Species Type Expo- sure time Value Method 212-454-9 2-hydroxyethyl acrylate Pimephales promelas (fat- head minnow) LC50 96 h 4.8 mg/l 212-454-9 2-hydroxyethyl acrylate Cyprinodon variegatus (sheepshead minnow) 4 days 18 mg/l Mobility No information available. Persistence and degradability No information available. Bioaccumulative potential No information available. Other adverse effects The preparation was evaluated in accordance with the conventional method of the preparations directive 1999/45/EC, and it was not classified as dangerous for the environment, but it does contain environmentally dangerous materials. For details, see section 3 Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 139 of 190 Page 139 of 190 Page 139 of 190 Page 139 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 7 - 9 13. Disposal considerations Dispose of in accordance with local regulations. Product: Recommendation: A disposal process that converts the waste into energy is recommended. If this is not possible the hazardous waste must be disposed of by incineration. Waste Key Number Description 08 01 11 waste paint and varnish containing organic solvents or other dangerous substances Uncleaned packaging: Recommendation: Properly emptied containers are to be scrap processed or reconditioned. Improperly emptied containers are considered hazardous waste (waste key number 150110). Waste, including emptied containers, is controlled waste. Do not allow into drains or watercourses or dispose of where ground or surface waters may be affected. If fully drained containers are compacted they can be regarded as Controlled Waste and disposed of in accordance with the requirements of the Control of Pollution Act 1974 and the Environmental Protection Act 1990 (GB), the Pollution Control and Local Government (NI) Order 1978 (NI) or of the EC (Waste) Regulations 1979 and the EC (Toxic & Dangerous Waste) Regulations 1982 (IRL). 14. Transport information Transport only in accordance with the requirements of the Carriage of Dangerous Goods by Road and Rail (Classification, Packaging and Labeling), ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport. ADR/RID (Land transport) Proper shipping name: PAINT UN-Number: 1263 Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: III Tunnel restriction code: D/E Special Provision: 640E Hazchem: 3Y IMDG (Sea transport) Proper shipping name: PAINT UN-Number: 1263 Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: III Marine Pollutant: N EmS: F-E,S-E ICAO/IATA (Air transport) Proper shipping name: PAINT UN-Number: 1263 Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: III 15. Regulatory information The product is labelled according to the Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 as amended (CHIP Regulations). The risk associated with the use of this product must be assessed in accordance with the Control of Substances Hazardous to Health (COSHH) Regulations and the Dangerous Substances and Explosive Atmospheres Regulations. Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 140 of 190 Page 140 of 190 Page 140 of 190 Page 140 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 8 - 9 Symbol and indication of hazard. Xn Harmful Contains xylene. R-phrase(s) R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. S-phrase(s) S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S38 In case of insufficient ventilation, wear suitable respiratory equipment. Contains: methyl methacrylate; n-butyl methacrylate; 2-hydroxyethyl acrylate. May produce an allergic reaction. National legislation This safety datasheet has been prepared according to British legislation. The product is labeled according to the Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 as amended (CHIP Regulations). The risk associated with the use of this product must be assessed in accordance with the Control of Substances Hazardous to Health (COSHH) Regulations and the Dangerous Substances and Explosive Atmospheres Regulations. 16. Other information Full text of R phrases with no. appearing in section 3 R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R21 Harmful in contact with skin. R24 Toxic in contact with skin. R34 Causes burns. R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R37/38 Irritating to respiratory system and skin. R38 Irritating to skin. R43 May cause sensitization by skin contact. R50 Very toxic to aquatic organisms. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Information taken from reference works and the literature. Substance No. CAS no: www.cas.org./EO/regsys.html EC no: http://ecb.jrc.it/esis/index.php?PGM=ein Substances presenting a health or environ- mental hazard within the meaning of Directive 67/548/EEC. http://ecb.jrc.it/existing-chemicals/ http://ecb.jrc.it/classification-labelling/ http://www.cdc.gov/niosh/ipcs/icstart.html Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 141 of 190 Page 141 of 190 Page 141 of 190 Page 141 of 190 ---PAGE BREAK--- B11933941 SAFETY DATA SHEET according to 1907/2006/EC 4025331708278 v8.0 Revision Date: 2009-05-13 Print Date: 2009-05-19 en/GB Page 9 - 9 Other directives, limitations and prohibitory regulations Directive 76/769/EC Directive 98/24/EC Directive 90/394/EC Directive 793/93/EC Directive 1999/45/EC Directive 2006/8/EC EUR-LEX: http://europa.eu.int/eur-lex/lex Exposure limit for the pure substance http://osha.europa.eu/OSHA Training advice Directive 76/769/EC Directive 98/24/EC Further information The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties. Report version Version Changes 8.0 1 Revision Date: 2009-05-13 Annex - Exposure scenarios An exposure scenario is a description of use conditions which allows the risk of a substance or mixture to humans or the environment to be controlled. The exposure scenario is based on the initial scenarios of the chemicals used in this preparation. Up to the time of issuing this SDS there were no initial exposure scenarios available. The product is only for industrial and/or professional use, not for any consumer use. Copyright 2009 DuPont. Permacron R Permasolid R ⃝and Permahyd R ⃝are registered trademarks of E. I. du Pont de Nemours and Company for its brands of performance coatings materials. All rights reserved. Page 142 of 190 Page 142 of 190 Page 142 of 190 Page 142 of 190 ---PAGE BREAK--- Date Printed: 10/13/2014 Safety Data Sheet * Trusted Quality Since 1921 * www.rustoleum.com 1. Identification Product Name: SPECLT SSPR 6PK EPOXY GLOSS WHITE 12 OZ Revision Date: 10/10/2014 Product Identifier: 7881830 Supercedes Date: New SDS Product Use/Class: Appliance Epoxy/White Aerosol Supplier: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Manufacturer: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Preparer: Regulatory Department 24 Hour Hotline: [PHONE REDACTED] Emergency Telephone: 2. Hazard Identification EMERGENCY OVERVIEW: Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Contents Under Pressure. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Causes eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. Classification Symbol(s) of Product Signal Word Danger GHS HAZARD STATEMENTS Flammable Aerosol, category 1 H222 Extremely flammable aerosol. Flammable Liquid, category 1 H224 Extremely flammable liquid and vapour. Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed. Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways. Eye Irritation, category 2B H320 Causes eye irritation. Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated GHS PRECAUTIONARY STATEMENTS P211 Do not spray on an open flame or other ignition source. P220 Keep/Store away from clothing/…/combustible materials. Page 1 / 7 Page 143 of 190 Page 143 of 190 Page 143 of 190 Page 143 of 190 ---PAGE BREAK--- Date Printed: 10/13/2014 P235 Keep cool. P251 Pressurized container: Do not pierce or burn, even after use. P375 Fight fire remotely due to the risk of explosion. P102 Keep out of reach of children. P103 Read label before use. P202 Do not handle until all safety precautions have been read and understood. P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P351 Rinse cautiously with water for several minutes. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370+P378 In case of fire: Use … for extinction. P403+P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container to … P321 Specific treatment (see … on this label). P352 Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container closed. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water. 3. Composition/Information On Ingredients HAZARDOUS SUBSTANCES Chemical Name CAS-No. Wt.% Range GHS Symbols GHS Statements Liquefied Petroleum Gas 25-50 68476-86-8 Acetone 10-25 GHS02 H225 67-64-1 Medium Oil Alkyd 10-25 Proprietary Titanium Dioxide 10-25 13463-67-7 Xylene (mixed isomers) 2.5-10 GHS02 H226 1330-20-7 n-Butyl Acetate 2.5-10 GHS02 H225 123-86-4 2.5-10 GHS02-GHS07 H225-332 100-41-4 Barium Sulfate 2.5-10 7727-43-7 Page 2 / 7 Page 144 of 190 Page 144 of 190 Page 144 of 190 Page 144 of 190 ---PAGE BREAK--- Date Printed: 10/13/2014 The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section. 4. First-aid Measures FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed. FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention. 5. Fire-fighting Measures EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat due to buildup of steam. No unusual fire or explosion hazards noted. SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. 6. Accidental Release Measures STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non- sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. 7. Handling and Storage HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. STORAGE: Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 ° F. Product should be stored in sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container closed when not in use. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat. 8. Exposure Controls/Personal Protection Chemical Name CAS-No. Weight % Less Than ACGIH TLV- TWA ACGIH TLV- STEL OSHA PEL-TWA OSHA PEL- CEILING Liquefied Petroleum Gas 68476-86-8 30.0 N.E. N.E. N.E. N.E. Acetone 67-64-1 25.0 500 ppm 750 ppm 1000 ppm N.E. Medium Oil Alkyd Proprietary 20.0 N.E. N.E. N.E. N.E. Titanium Dioxide 13463-67-7 15.0 10 mg/m3 (Total Dust) N.E. 15 mg/m3 [Total Dust] N.E. Xylene (mixed isomers) 1330-20-7 10.0 100 ppm 150 ppm 100 ppm N.E. n-Butyl Acetate 123-86-4 10.0 150 ppm 200 ppm 150 ppm N.E. 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E. Barium Sulfate 7727-43-7 5.0 10 mg/m3 N.E. 15 mg/m3 [Total Dust] N.E. PERSONAL PROTECTION Page 3 / 7 Page 145 of 190 Page 145 of 190 Page 145 of 190 Page 145 of 190 ---PAGE BREAK--- Date Printed: 10/13/2014 ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse. 9. Physical and Chemical Properties Appearance: Aerosolized Mist Physical State: Liquid Odor: Solvent Like Odor Threshold: N.E. Relative Density: 0.843 pH: N.D. Freeze Point, N.D. Viscosity: N.D. Solubility in Water: Slight Partition Coefficient, n-octanol/ water: No Information Decompostion Temp., No Information Boiling Range, -34 - 415 Explosive Limits, vol%: 0.7 - 13.0 Flammability: Does not Support Combustion Flash Point, -105 Evaporation Rate: Faster than Ether Auto-ignition Temp., No Information Vapor Density: Heavier than Air Vapor Pressure: N.D. (See "Other information" Section for abbreviation legend) 10. Stability and Reactivity CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid all possible sources of ignition. Avoid contact with strong acid and strong bases. INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. 11. Toxicological information EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. May cause skin irritation. Allergic reactions are possible. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation. EFFECTS OF OVEREXPOSURE - INGESTION: Aspiration hazard if swallowed; can enter lungs and cause damage. Harmful if swallowed. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists as a possible human carcinogen (group 2B). Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)May cause central nervous system disorder narcosis involving a Page 4 / 7 Page 146 of 190 Page 146 of 190 Page 146 of 190 Page 146 of 190 ---PAGE BREAK--- Date Printed: 10/13/2014 loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below: CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I. 1330-20-7 Xylene (mixed isomers) 4300 mg/kg Rat N.I. 47635 mg/L Rat 123-86-4 n-Butyl Acetate N.I. >17600 mg/kg Rabbit N.I. 100-41-4 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat N.I. - No Information 12. Ecological Information ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components. 13. Disposal Information DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems. 14. Transport Information Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada) UN Number: N.A. 1950 1950 N.A. Proper Shipping Name: Paint Products in Limited Quantities Aerosols Aerosols Paint Products in Limited Quantities Hazard Class: N.A. 2.1 2.1 N.A. Packing Group: N.A. N.A. N.A. N.A. Limited Quantity: Yes Yes Yes Yes 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard Sara Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. Xylene (mixed isomers) 1330-20-7 100-41-4 Toxic Substances Control Act: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA components exist in this product. Page 5 / 7 Page 147 of 190 Page 147 of 190 Page 147 of 190 Page 147 of 190 ---PAGE BREAK--- Date Printed: 10/13/2014 Inventory Information Country Value USA (TSCA) No Information Canada (DSL) No Information Mexico(INSQ) No Information Europe (EINECS) No Information Japan (ENCS) No Information Philippines (PICCS) No Information China (IECSC) No Information Australia (AICS) No Information Korea (KECI) No Information New Zealand (NZIOC) No Information No Information CALIFORNIA PROPOSITION 65: Warning: This products contains a substance known to the State of California to cause cancer. Chemical Name CAS-No. Titanium Dioxide 13463-67-7 100-41-4 CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive harm. Chemical Name CAS-No. Toluene 108-88-3 International Regulations: CANADIAN WHMIS: This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. 16. Other Information HMIS RATINGS Health: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X CANADIAN WHMIS CLASS: AB5 D2A NFPA RATINGS Health: 2 Flammability: 4 Instability 0 VOLATILE ORGANIC COMPOUNDS, g/L: 500 MSDS REVISION DATE: 10/10/2014 REASON FOR REVISION: No Information Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined Page 6 / 7 Page 148 of 190 Page 148 of 190 Page 148 of 190 Page 148 of 190 ---PAGE BREAK--- Date Printed: 10/13/2014 Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H332 Harmful if inhaled. Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS02 GHS07 Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations. Page 7 / 7 Page 149 of 190 Page 149 of 190 Page 149 of 190 Page 149 of 190 ---PAGE BREAK--- Shell SPIRAX® GEAR OIL LS SAE 80W-90 MSDS# 400844E Version 2.0 Material Safety Data Sheet Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 1/7 Print Date 04/30/2011 MSDS_US 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Shell SPIRAX® GEAR OIL LS SAE 80W-90 Uses : Transmission oil. Manufacturer/Supplier : SOPUS Products PO BOX 4427 Houston, TX 77210-4427 USA MSDS Request : [PHONE REDACTED] Emergency Telephone Number Spill Information : [PHONE REDACTED] Health Information : [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Blend of severely hydrotreated slack wax, esters, polyolefins and additives. 3. HAZARDS IDENTIFICATION Emergency Overview Appearance and Odour : May be dyed. Liquid at room temperature. Slight hydrocarbon. Health Hazards : Not classified as dangerous for supply or conveyance. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Health Hazards : Not expected to be a health hazard when used under normal conditions. Health Hazards Inhalation : Under normal conditions of use, this is not expected to be a primary route of exposure. Skin Contact : Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Contact : May cause slight irritation to eyes. Ingestion : Low toxicity if swallowed. Other Information : Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Aggravated Medical Condition : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Environmental Hazards : Not classified as dangerous for the environment. Additional Information : Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous Page 150 of 190 Page 150 of 190 Page 150 of 190 Page 150 of 190 ---PAGE BREAK--- Shell SPIRAX® GEAR OIL LS SAE 80W-90 MSDS# 400844E Version 2.0 Material Safety Data Sheet Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 2/7 Print Date 04/30/2011 MSDS_US chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. 4. FIRST AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : Typical 350 °C / 662 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto ignition temperature : > 320 °C / 608 °F Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. Observe all relevant local and international regulations. Protective measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, Page 151 of 190 Page 151 of 190 Page 151 of 190 Page 151 of 190 ---PAGE BREAK--- Shell SPIRAX® GEAR OIL LS SAE 80W-90 MSDS# 400844E Version 2.0 Material Safety Data Sheet Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 3/7 Print Date 04/30/2011 MSDS_US sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Storage Temperature: 0 - 50 °C / 32 - 122 °F Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Contains no components with occupational exposure limit values Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Page 152 of 190 Page 152 of 190 Page 152 of 190 Page 152 of 190 ---PAGE BREAK--- Shell SPIRAX® GEAR OIL LS SAE 80W-90 MSDS# 400844E Version 2.0 Material Safety Data Sheet Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 4/7 Print Date 04/30/2011 MSDS_US Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65 °C (149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : May be dyed. Liquid at room temperature. Odour : Slight hydrocarbon. pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -10 °C / 14 °F Flash point : Typical 350 °C / 662 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto-ignition temperature : > 320 °C / 608 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.885 Density : Typical 7.51 g/cm3 Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : Typical 400 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Evaporation rate (nBuAc=1) : Data not available Page 153 of 190 Page 153 of 190 Page 153 of 190 Page 153 of 190 ---PAGE BREAK--- Shell SPIRAX® GEAR OIL LS SAE 80W-90 MSDS# 400844E Version 2.0 Material Safety Data Sheet Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 5/7 Print Date 04/30/2011 MSDS_US 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Components are not known to be associated with carcinogenic effects. Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic organisms. Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l (to aquatic organisms) (LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract). Mobility : Liquid under most environmental conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product Page 154 of 190 Page 154 of 190 Page 154 of 190 Page 154 of 190 ---PAGE BREAK--- Shell SPIRAX® GEAR OIL LS SAE 80W-90 MSDS# 400844E Version 2.0 Material Safety Data Sheet Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 6/7 Print Date 04/30/2011 MSDS_US contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation Classification (49CFR) This material is not subject to DOT regulations under 49 CFR Parts 171-180. IMDG This material is not classified as dangerous under IMDG regulations. IATA (Country variations may apply) This material is not classified as dangerous under IATA regulations. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. Federal Regulatory Status Notification Status EINECS All components listed. TSCA All components listed. DSL All components listed. SARA Hazard Categories (311/312) Page 155 of 190 Page 155 of 190 Page 155 of 190 Page 155 of 190 ---PAGE BREAK--- Shell SPIRAX® GEAR OIL LS SAE 80W-90 MSDS# 400844E Version 2.0 Material Safety Data Sheet Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 7/7 Print Date 04/30/2011 MSDS_US No SARA 311/312 Hazards. State Regulatory Status California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. 16. OTHER INFORMATION NFPA Rating (Health, Fire, Reactivity) : 0, 1, 0 MSDS Version Number : 2.0 MSDS Effective Date : 07/03/2008 MSDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. MSDS Regulation : The content and format of this MSDS is in accordance with the OSHA Hazard Communication Standard, 29 CFR 1910.1200. MSDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 156 of 190 Page 156 of 190 Page 156 of 190 Page 156 of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age 157 of 190 Page 157 of 190 Page 157 of 190 Page 157 of 190 ---PAGE BREAK--- (064  *,,7:-260 <7       % (A8=C8=6 30C4  )4E8B8>=  6*5. %425.  >=C3 >5 ?064  M %206*4 )46D;0C43 M *B*:--.<.:526260 ,75876.6<; 7/ 4*+.44260 M )46D;0C43 M -.;,:28<276 M ) %;A5+74; 70I0A3>DB D=34A M :*<260;  !40;C7  8A4  )402C8E8CH  M   !40;C7  8A4  )402C8E8CH  M % 760 .*4<1 >5 C74 8=6A4384=CB 8B ;8BC43 M  M 7/ M 0??;8201;4 M 0??;8201;4 7587;2<276 26/7:5*<276 76 260:.-2.6<; M  M .;,:28<276 %8GCDA4 >5 BD1BC0=24B ;8BC43 14;>F F8C7 =>=70I0A3>DB 0338C8>=B M ,75876.6<; 8= A4?>AC01;4 @D0=C8C84B M --2<276*4 26/7:5*<276 >A C74 F>A38=6 >5 C74 ;8BC43 A8B: ?7A0B4B A454A C> B42C8>=   M .;,:28<276 7/ M 26/7:5*<276 B?4280; <40BDA4B A4@D8A43 M 261*4*<276 5A4B7 08A 2>=BD;C 3>2C>A 8= 20B4 >5 2>0? "5 B:8= 8AA8C0C8>= 2>=C8=D4B 2>=BD;C 0 3>2C>A M )4<>E4 2>=C02C ;4=B4B 85 F>A= )8=B4 >?4=43 4H4 5>A B4E4A0; <8=DC4B D=34A AD==8=6 F0C4A "5 BH=BD;C 0 3>2C>A M ;?*447?260 > 8=3D24 E><8C8=6 20;; 5>A <43820; 74;? 8<<4380C4;H M 2587:<*6< ;A58<75; +7<1 0BCA82 >A 8=C4BC8=0; 38B>A34AB 8II8=4BB  >=C3 ?064 Page 158 of 190 Page 158 of 190 Page 158 of 190 Page 158 of 190 ---PAGE BREAK--- (064   *,,7:-260 <7       % (A8=C8=6 30C4  )4E8B8>=  6*5. %425.  >=C3 >5 ?064  >D678=6 M 5DAC74A A4;4E0=C 8=5>A<0C8>= 0E08;01;4 M 6-2,*<276 7/ *6A 255.-2*<. 5.-2,*4 *<<.6<276 ;8.,2*4 5DAC74A A4;4E0=C 8=5>A<0C8>= 0E08;01;4  2:./201<260 M @<260=2;1260 5.-2* M .@<260=2;1260 '  ?>F34A >A F0C4A B?A0H 867C ;0A64A 58A4B F8C7 F0C4A B?A0H >A 0;2>7>; A4B8BC0=C 5>0< M .@<260=2;1260 M %8.,2*4 *:2;260 /:75 7: 0=64A >5 A424?C02;4B 1DABC8=6 1420DB4 >5 7867 E0?>DA ?A4BBDA4 F74= 740C43 M M .9=285.6< .40A B4;52>=C08=43 A4B?8A0C>AH ?A>C42C8E4 34E824 M --2<276*4 26/7:5*<276 4=30=64A43 A424?C02;4B F8C7 F0C4A B?A0H  M .9=285.6< .5.:0.6,A =BDA4 034@D0C4 E4=C8;0C8>= M 6>2:765.6<*4 > 0;;>F C> 4=C4A B4F4AB BDA5024 >A 6A>D=3 F0C4A 8;DC4 F8C7 ?;4=CH >5 F0C4A M ,76<*265.6< ,4.*6260 C> B>;8385H (82: D? <4270=820;;H 1B>A1 F8C7 ;8@D8318=38=6 <0C4A80; B0=3 380C><8C4 0283 18=34AB D=8E4AB0; 18=34AB B0F3DBC M <7 7<1.: 30=64A>DB BD1BC0=24B 0A4 A4;40B43 *44 *42C8>=  5>A 8=5>A<0C8>= B054 70=3;8=6 *44 *42C8>=  5>A 8=5>A<0C8>= ?4AB>=0; ?A>C42C8>= 4@D8?<4=C *44 *42C8>=  5>A 38B?>B0; 8=5>A<0C8>=  *6-4260 M 1*6-4260 B?4280; <40BDA4B A4@D8A43 M 6/7:5*<276  .@847;276 8:7<.,<276 B?4280; <40BDA4B A4@D8A43 M 76-2<276; 26,4=-260 *6A 26,758*<2+242<2.; M M <7 +A ;<7:.:775; B?4280; A4@D8A4<4=CB M 6/7:5*<276 26 76. ,75576 /*,242C42C 5A>< 2>=C0<8=0C8>= #44? 2>=C08=4A C867C;H B40;43  >=C3 ?064 Page 159 of 190 Page 159 of 190 Page 159 of 190 Page 159 of 190 ---PAGE BREAK--- (064   *,,7:-260 <7       % (A8=C8=6 30C4  )4E8B8>=  6*5. %425.  >=C3 >5 ?064 M 5DAC74A A4;4E0=C 8=5>A<0C8>= 0E08;01;4  ,76<:74; 8.:;76*4 8:7<.,<276 M --2<276*4 26/7:5*<276 -.;206 7/ <.,162,*4 5DAC74A 30C0 B44 8C4<  M 76<:74 M 60:.-2.6<; ?2<1 4252< 5762<7:260 ?7:384*,. +74 ?A>3D2C 3>4B 2>=C08= 0=H A4;4E0=C @D0=C8C84B >5 <0C4A80;B F8C7 2A8C820; E0;D4B C70C 70E4 C> 14 <>=8C>A43 0C C74 F>A:?;024 M ; 5DAC74A A4;4E0=C 8=5>A<0C8>= 0E08;01;4 M 5DAC74A A4;4E0=C 8=5>A<0C8>= 0E08;01;4 M --2<276*4 26/7:5*<276 +74 ;8BCB E0;83 3DA8=6 C74 <0:8=6 F4A4 DB43 0B 10B8B M ,76<:74; M .9=285.6< M 1A02.62, 5DAC74A A4;4E0=C 8=5>A<0C8>= 0E08;01;4 M 8:7<.,<276 A4@D8A43 M #:7<.,<276 7/ A4@D8A43 M 8:7<.,<276 *054CH 6;0BB4B M 7-A 8:7<.,<276 A4@D8A43 M 252<*<276 ;=8.:>2;276 7/ 26<7 .6>2:765.6< B?4280; A4@D8A4<4=CB M $2;3 5*6*0.5.6< B?4280; A4@D8A4<4=CB  #1A;2,*4 ,1.52,*4 8:78.:<2.; M 6/7:5*<276 76 81A;2,*4 ,1.52,*4 8:78.:<2.; M 6/7:5*<276 M 7:5 (0BCH 747=: 8554A4=C 022>A38=6 C> 2>;>DA8=6 M $867C M <1:.;174- 34C4A<8=43 M 8 K  M 1*60. 26 ,76-2<276 .4<260 8726< .4<260 4C4A<8=43 [PHONE REDACTED]< 724260   J M 4*;1 8726<  J M 4*55*+242=C3 ?064 Page 160 of 190 Page 160 of 190 Page 160 of 190 Page 160 of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age 161 of 190 Page 161 of 190 Page 161 of 190 Page 161 of 190 ---PAGE BREAK--- (064   *,,7:-260 <7       % (A8=C8=6 30C4  )4E8B8>=  6*5. %425.  >=C3 >5 ?064 M %.6;2<2B*<276 B4=B8C8I8=6 45542CB M --2<276*4 <7@2,74702,*4 26/7:5*<276 +74 ?A>3D2C 8B BD1942C C> 2;0BB85820C8>= 022>A38=6 C> C74 20;2D;0C8>= <4C7>3 >5 C74 4=4A0; , ;0BB85820C8>= D834;8=4B 5>A (A4?0A0C8>=B 0B 8BBD43 8= C74 ;0C4BC E4AB8>= .74= DB43 0=3 70=3;43 022>A38=6 C> B?4285820C8>=B C74 ?A>3D2C 3>4B 70E4 0=H 70A<5D; 45542CB C> >DA 4G?4A84=24 0=3 C74 8=5>A<0C8>= ?A>E8343 C> DB ,74702,*4 26/7:5*<276 M  &7@2,2A<0C8>= 0E08;01;4 M  +74 ?A>3D2C 8B 18>346A0301;4 05C4A ?A>;>=643 030?C0C8>= M  87<.6<2*4 5DAC74A A4;4E0=C 8=5>A<0C8>= 0E08;01;4 M 7+242A<0C8>= 0E08;01;4 M ,7<7@2,*4 M D4 C> <4270=820; 02C8>=B >5 C74 ?A>3D2C 4 6 066;DC8=0C8>=B 30<064B <0H >22DA M --2<276*4 .,74702,*4 26/7:5*<276 M +78B BC0C4<4=C F0B 343D243 5A>< ?A>3D2CB F8C7 0 B8<8;0A BCAD2CDA4 >A 2>B8C8>= E>83 CA0=B54A 8=C> C74 4=E8A>=<4=C D4 C> 0E08;01;4 30C0 4;8<8=018;8CH 342>B8C8>= 0=3 18>022D= ?>C4=C80; 0 ?A>;>=643 30<064 >5 C74 4=E8A>=<4=C 8B D=;8:4;H .0C4A 70I0A3 2;0BB  4A<0= )46D;0C8>= *4;50BB4BB<4=C B;867C;H 70I0A3>DB 5>A F0C4A > 0;;>F D=38;DC43 ?A>3D2C >A ;0A64 @D0=C8C84B >5 8C C> A4027 6A>D=3 F0C4A F0C4A 2>DAB4 >A B4F064 BHBC4< M 7/ M 0??;8201;4 M 0??;8201;4 M 5DAC74A A4;4E0=C 8=5>A<0C8>= 0E08;01;4 2;87;*4 ,76;2-.:*<276; M  5.<17-; M $.,755.6-*<276 *<0;;4A @D0=C8C84B 20= 14 38B?>B43 >5 F8C7 7>DB47>;3 F0BC4 0= 14 1DA=43 F8C7 7>DB47>;3 60A1064 05C4A 2>=BD;C8=6 F8C7 C74 F0BC4 38B?>B0; 5028;8CH >?4A0C>A 0=3 C74 ?4AC8=4=C 0DC7>A8C84B 0=3 0374A8=6 C> C74 =424BB0AH C427=820; A46D;0C8>=B 0= 14 38B?>B43 >5 F8C7 7>DB47>;3 60A1064 05C4A B>;8385820C8>= 5>;;>F8=6 2>=BD;C0C8>= F8C7 C74 F0BC4 38B?>B0; 5028;8CH >?4A0C>A 0=3 C74 ?4AC8=4=C 0DC7>A8C84B 0=3 0374A8=6 C> C74 =424BB0AH C427=820; A46D;0C8>=B M 8*,3*0260 M $.,755.6-*<276 8B?>B0; A38=6 C> >558280; A46D;0C8>=B M ,4.*6;260 .0C4A 85 =424BB0AH C>64C74A F8C7 2;40=B8=6 064=CB  >=C3 ?064 Page 162 of 190 Page 162 of 190 Page 162 of 190 Page 162 of 190 ---PAGE BREAK--- (064   *,,7:-260 <7       % (A8=C8=6 30C4  )4E8B8>=  6*5. %425.  >=C3 >5 ?064  26/7:5*<276 M M )46D;0C43 M 8:78.: ;1288260 6*5. M )46D;0C43 M M M )46D;0C43 M #*,3260 0:7=8 M )46D;0C43 M 6>2:765.6<*4 M *:26. 8744=<*6< M %8.,2*4 0??;8201;4 M 26 +=43 *,,7:-260 <7 66.@ 7/  0??;8201;4 M
7-.4 $.0=4*<276
   $.0=4*<7:A 26/7:5*<276 M 1.*4<1 .6>2:765.6<*4 :.0=4*<276; 4.02;4*<276 7: M M M %.,<276 >5 C74 8=6A4384=CB 8B ;8BC43 M %.,<276 <7@2, ,1.52,*4 42;<260; >5 C74 8=6A4384=CB 8B ;8BC43 M 76<:74 8=6A4384=CB 0A4 ;8BC43 M #:787;2<276 M 1.52,*4; 367?6 <7 >5 C74 8=6A4384=CB 8B ;8BC43 M 1.52,*4; 367?6 <7 <7@2,25 C74 8=6A4384=CB 8B ;8BC43 M 1.52,*4; 367?6 <7 <7@2,25 C74 8=6A4384=CB 8B ;8BC43 M 1.52,*4; 367?6 <7 -.>.4785.6<*4 <7@2,25 C74 8=6A4384=CB 8B ;8BC43  >=C3 ?064 Page 163 of 190 Page 163 of 190 Page 163 of 190 Page 163 of 190 ---PAGE BREAK--- (064   *,,7:-260 <7       % (A8=C8=6 30C4  )4E8B8>=  6*5. %425.  >=C3 >5 ?064 M *:,2670.62, M 6>2:765.6<*4 #:7<.,<276 0.6,A >5 C74 8=6A4384=CB 8B ;8BC43 M  6<.:6*<276*4 0.6,A 76 >5 C74 8=6A4384=CB 8B ;8BC43 M & ( &1:.;174- 252< +A  >5 C74 8=6A4384=CB 8B ;8BC43 M ! !*<276*4 ",,=8*<276*4 >5 C74 8=6A4384=CB 8B ;8BC43 M  .*4<1 -5262;<:*<276 >5 C74 8=6A4384=CB 8B ;8BC43 M M  8=6A4384=CB 0A4 ;8BC43 M 60:.-2.6< 42;< 4252<  >5 C74 8=6A4384=CB 8B ;8BC43 M 60:.-2.6< 42;< 4252< >5 C74 8=6A4384=CB 8B ;8BC43 M 1.52,*4  74<820; *054CH BB4BB<4=C 70B 144= 20AA843 >DC  26/7:5*<276 +78B 8=5>A<0C8>= 8B 10B43 >DA ?A4B4=C :=>F;4364 !>F4E4A C78B B70;; 2>=BC8CDC4 0 6D0A0=C44 5>A 0=H B?428582 ?A>3D2C 540CDA4B 0=3 B70;; 4BC01;8B7 0 ;460;;H E0;83 2>=CA02CD0; A4;0C8>=B78? M *,:76A5;  22>A3 4DA>?N4= BDA ;4 CA0=B?>AC 34B <0A270=38B4B 30=64A4DB4B ?0A )>DC4  DA>?40= 6A44<4=C 2>=24A=8=6 C74 "=C4A=0C8>=0; 0AA8064 >5 0=64A>DB >>3B 1H )>03  "=C4A=0C8>=0; %0A8C8<4 >34 5>A 0=64A>DB >>3B 4?0AC<4=C >5 +A0=B?>AC0C8>= "=C4A=0C8>=0; 8A +A0=B?>AC BB>280C8>= ;>10;;H !0A<>=8I43 *HBC4< >5 ;0BB85820C8>= 0=3 $014;;8=6 >5 74<820;B  <4A820= >=54A4=24 >5 >E4A=<4=C0; "=3DBCA80; !H684=8BCB & &0C8>=0; 8A4 (A>C42C8>= BB>280C8>= !0I0A3>DB %0C4A80;B "34=C85820C8>= *HBC4< .>A:?;024 !0I0A3>DB %0C4A80;B "=5>A<0C8>= *HBC4<  0=030 & 4A8E43 5542C $4E4;   (A4382C43 5542C >=24=CA0C8>=  M * * (A4?0A43 1H 74<+4;   &>AC7 ;>A830 E4=D4 ;>A830   A44 &>AC7 <4A820    .41B8C4 FFF 2742000 mg/kg Rabbit >2000 mg/kg Rat > 2.18 mg/L 4 hours Petroleum Distillates, Solvent Dewaxed heavy Paraffinic 64742-65-0 Rat >2000 mg/kg Rabbit >2000 mg/kg Rat > 2.18 mg/L 4 hours Chronic Toxicity Chronic Toxicity Prolonged exposure may cause chronic effects. Carcinogenicity Not considered a potential carcinogen base on IP346 DMSO of less than 3.0 wt% Target Organ Effects Respiratory system, Eyes, Skin, Central nervous system (CNS) Page 171 of 190 Page 171 of 190 Page 171 of 190 Page 171 of 190 ---PAGE BREAK--- STIHL 2-CYCLE HP ENGINE OIL Packaged for Stihl Incorporated, 536 Viking Drive, Virginia Beach, VA 23452 Revision Date: November 18. 2013 Page 5 of 6 Genotoxicity This product is considered non-mutagenic and has negative potential for tumor development based on from Modified Ames Assay, with Mutagenic Index of less than 1.0. 12. ECOLOGICAL INFORMATION Ecotoxicity If applied to leaves, this product may kill grasses and small plants by interfering with transpiration and respiration. This product is not toxic to fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. Product may be moderately toxic to amphibians by preventing dermal respiration. This product may cause gastrointestinal distress to birds and mammals through ingestion during pelage grooming. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with local regulations. Keep this product out of sewers and waterways. Contaminated Packaging Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT Not regulated IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION International Inventories TSCA DSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Petroleum Distillates, Hydrotreated Heavy Paraffinic 64742-54-7 Present X 265-157-1 X X X X X Petroleum Distillates, Solvent Dewaxed heavy Paraffinic 64742-65-0 Present X 265-169-7 X X X X X U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act Page 172 of 190 Page 172 of 190 Page 172 of 190 Page 172 of 190 ---PAGE BREAK--- STIHL 2-CYCLE HP ENGINE OIL Packaged for Stihl Incorporated, 536 Viking Drive, Virginia Beach, VA 23452 Revision Date: November 18. 2013 Page 6 of 6 If spilled into navigable waters it is reportable to National Response Center, [PHONE REDACTED]. Reportable Quantity = Oil Sheen present on navigable water surface. (40 CFR 116; 401.15) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. CERCLA U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. Florida No listed ingredients are present Massachusetts RTK No listed ingredients are present Minnesota RTK No listed ingredients are present New Jersey RTK Lists petroleum oil, but this product does not contain hazardous ingredients. RTK Lists petroleum oil, but this product does not contain hazardous ingredients greater than Illinois DOL TSL No listed ingredients are present International Regulations Mexico – Grade No information available. Canada Not listed on the Canadian Controlled Product Ingredient Disclosure and is compliant with Controlled Products Regulation CONEG Metals Since cadmium, chromium, lead and mercury are not detectable and it does not exceed 100 ppm total in this product, it is compliant with CONEG Metals regulation. EEC (Europe) This product is not known to be a dangerous good internationally. No known R-Phrases or S-Phrases Hazard Label None Danger Symbol None This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION Prepared By Jim Prothro Issuing Date August 16, 2010 Revision Date November 18, 2013 Revision Note Updated product numbers Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. The End Page 173 of 190 Page 173 of 190 Page 173 of 190 Page 173 of 190 ---PAGE BREAK--- John Deere Turf-GardTM 10W30 Safety Data Sheet according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) Date of issue: 11/22/2013 Version: 1.0 12/11/2013 EN (English) SDS ID: 11D0 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : John Deere Turf-GardTM 10W30 Product code : TY22029, TY22075, TY22076 Other means of identification : API SN Engine Oil 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : API SN Engine Oil 1.3. Details of the supplier of the safety data sheet MANUFACTURER: Northland Products 1000 Rainbow Drive Waterloo, IA 50704 Tel: +1-[PHONE REDACTED] +1-[PHONE REDACTED] SUPPLIER: Deere & Company One John Deere Place Moline, IL 61265 E-mail: [EMAIL REDACTED] 1.4. Emergency telephone number Emergency number : Chemtrec 1-[PHONE REDACTED] Chemtrec (Outside USA) +1 [PHONE REDACTED] (24 hours) Supplier: +1-[PHONE REDACTED] or 1-[PHONE REDACTED] (24 hours) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labelling No labelling applicable 2.3. Other hazards other hazards which do not result in classification : This product contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. Spills of this product present a serious slipping hazard. Used oil, may contain harmful impurities. Used motor oil was associated with cancer in lifetime skin painting studies with laboratory animals. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section 16 3.2. Mixture Name Product identifier % GHS-US classification Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS No) 68649-42-3 <1 Skin Irrit. 2, H315 Eye Dam. 1, H318 Distillates, petroleum, solvent-dewaxed heavy paraffinic (CAS No) 64742-65-0 0.1 - 5 Asp. Tox. 1, H304 Page 174 of 190 Page 174 of 190 Page 174 of 190 Page 174 of 190 ---PAGE BREAK--- John Deere Turf-GardTM 10W30 Safety Data Sheet according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) 12/11/2013 EN (English) SDS ID: 11D0 2/8 Name Product identifier % GHS-US classification Distillates, petroleum, solvent-refined heavy paraffinic (CAS No) 64741-88-4 0.1 - 5 Acute Tox. 4 (Inhalation:dust,mist), H332 Asp. Tox. 1, H304 Distillates, petroleum, solvent-refined light paraffinic (CAS No) 64741-89-5 0.1 - 5 Acute Tox. 4 (Inhalation:dust,mist), H332 Asp. Tox. 1, H304 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. In case of breathing difficulties administer oxygen. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Subsequently consult an ophthalmologist. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important and effects, both acute and delayed : This product contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. after inhalation : In the event of insufficient ventilation: Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. after skin contact : Frequent or prolonged contact with skin may cause dermal irritation. Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. Injection under the skin can cause inflammation and swelling. after eye contact : If user operations generate dust or fumes, . May cause eye irritation. Exposure to vapor may cause intense watering and irritation to eyes. 4.3. Indication of any immediate medical attention and special treatment needed Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. Immediate treatment at a surgical emergency center is recommended. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : When heated above the flash point, releases flammable vapours. Leaks/ruptures in high pressure system can create a fire hazard when in the vicinity of ignition sources (eg. open flame, pilot lights, sparks, or electric arcs). 5.3. Advice for firefighters Precautionary measures fire : Stop and contain spill/release if it can be done safely. If this cannot be done, allow fire to burn under control. Gases/vapours, toxic. Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protective equipment for firefighters : Do not enter fire area without proper protective equipment, including respiratory protection. Wear self-contained respiratory apparatus during longer or intensive exposition or spraying processing. Other information : Special danger of slipping by leaking/spilling product. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protective equipment as required. Special danger of slipping by leaking/spilling product. Stop leak if safe to do so. Relevant water authorities should be notified of any large spillage to water course or drain. This material can burn but will not readily ignite. Under fire conditions closed containers may rupture or explode. Page 175 of 190 Page 175 of 190 Page 175 of 190 Page 175 of 190 ---PAGE BREAK--- John Deere Turf-GardTM 10W30 Safety Data Sheet according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) 12/11/2013 EN (English) SDS ID: 11D0 3/8 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. Avoid breathing mist or vapor . Avoid direct eye contact with product, also via contamination on hands. Avoid contact with skin, eyes and clothes. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : The low volatility of this product does not require ventilation. However depending on the condition an adequate ventalation might be required. 6.2. Environmental precautions Prevent entry to sewers and public waters. An environmental fate analysis is not available for this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum products. Petroleum-based (mineral) lubricating oils normally will float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway may be sufficient to cause a fish kill or create an anaerobic environment. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as fabric absorbents, clay or diatomaceous earth as soon as possible. Recover large spills by pumping (use an explosion proof or hand pump). Collect spillage. Store away from other materials. Consult the appropriate authorities about waste disposal. This material and its container must be disposed of in a safe way, and as per local legislation. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Special danger of slipping by leaking/spilling product. Never use pressure to empty containers. Over pressure may rupture containers, cause serious injury, cause or accelerate fire. Precautions for safe handling : Keep out of reach of children. Avoid contact with skin, eyes and clothes. Personal protective equipment should be selected based upon the conditions under which this product is handled or used. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing dust/fume/gas/mist/vapours/spray. Empty container retains product residue. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Ground/bond container and receiving equipment. Never use pressure to empty container. Do not use in high pressure systems in the vicinity of flames, sparks and hot surfaces. Hygiene measures : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ensure adequate ventilation of the storage area. A washing facility/water for eye and skin cleaning purposes should be present. Storage conditions : Keep container closed when not in use. Keep only in the original container in a cool, well- ventilated place away from highly flammable substances. Incompatible materials : Strong acid. Base. Oxidizing agents. Storage temperature : Store at ambient temperature Heat and ignition sources : Remove all sources of ignition. Storage area : Well-ventilated area. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Use adequate general or local ventilation to keep airborne concentrations below the exposure limits. Ensure adequate ventilation. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Personal protective equipment : Personal protective equipment should be selected based upon the conditions under which this product is handled or used. Avoid all unnecessary exposure. Gloves. Protective clothing. Protective goggles. Hand protection : Wear protective gloves, rubber gloves. Page 176 of 190 Page 176 of 190 Page 176 of 190 Page 176 of 190 ---PAGE BREAK--- John Deere Turf-GardTM 10W30 Safety Data Sheet according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) 12/11/2013 EN (English) SDS ID: 11D0 4/8 Eye protection : Wear goggles if splashing or spraying is anticipated. Chemical goggles or safety glasses. with side-shields. Skin and body protection : Wear protective clothing. Wear rubber boots. Respiratory protection : Protection factors vary depending upon the type of respirator used. In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazard protection : In case of insufficient ventilation, wear suitable respiratory equipment. Wear a self-contained breathing apparatus and appropriate personal protective equipment (PPE). Environmental exposure controls : Do not allow run-off from fire-fighting to enter drains or water courses. Ensure waste is collected and contained. Notify authorities if product enters sewers or public waters. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Clear to light amber. Odour : Petroleum. Characteristic. Odour threshold : No data available pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : > 320 °C (608 ºF) Flash point : 225 °C (437 ºF) Test method: COC Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : Lower Flammability Limit (LFL) 0.9 Upper Flammability Limit (UFL) 7.0 Vapour pressure : < 0,01 mm Hg Maximum @ 37.8 °C (100 Relative vapour density at 20 °C : > 1 Relative density : 0,873 g/cm³ at 15.6 °C / 60 °F Solubility : Water: insoluble Organic solvent:completely soluble Log Pow : No data available Log Kow : Base oil hydrocarbons: log Kow > 4 (estimate) Viscosity, kinematic : 69 cSt (40 °C/104 Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable at normal temperatures and pressures. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Do not pressurize, cut, weld, braze, solder, drill, grind, or expose containers to flames, sparks, heat, or other potential ignition sources. 10.5. Incompatible materials Strong acid. Strong bases. Oxidizing agents. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Page 177 of 190 Page 177 of 190 Page 177 of 190 Page 177 of 190 ---PAGE BREAK--- John Deere Turf-GardTM 10W30 Safety Data Sheet according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) 12/11/2013 EN (English) SDS ID: 11D0 5/8 SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) LD50 dermal rabbit > 2000 mg/kg Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2,18 mg/l/4h ATE (dust,mist) 2,180 mg/l/4h Distillates, petroleum, solvent-refined light paraffinic (64741-89-5) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5 g/kg LC50 inhalation rat (mg/l) 2,18 mg/l/4h ATE (dust,mist) 2,180 mg/l/4h Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classifiedBased on available data, the classification criteria are not met Carcinogenicity : Not classified Reproductive toxicity : Not classifiedBased on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classifiedBased on available data, the classification criteria are not met Aspiration hazard : Not classifiedMay be fatal if swallowed and enters airways Potential Adverse human health effects and : Based on available data, the classification criteria are not met. after inhalation : In the event of insufficient ventilation: Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. after skin contact : Frequent or prolonged contact with skin may cause dermal irritation. Injection under the skin of pressurized hydrocarbons can cause severe, permanent tissue damage. Injection under the skin can cause inflammation and swelling. after eye contact : If user operations generate dust or fumes, . May cause eye irritation. Exposure to vapor may cause intense watering and irritation to eyes. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May be toxic to aquatic life. Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) EC50 Daphnia 1 1 - 1,5 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC50 fish 2 10,0 - 35,0 mg/l (Exposure time: 96 h - Species: Pimephales promelas [semi-static]) Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0) LC50 fishes 1 > 5000 mg/l (Exposure time: 96 h - Species: mykiss) EC50 Daphnia 1 > 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) LC50 fishes 1 > 5000 mg/l (Exposure time: 96 h - Species: mykiss) EC50 Daphnia 1 > 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) Distillates, petroleum, solvent-refined light paraffinic (64741-89-5) LC50 fishes 1 > 5000 mg/l (Exposure time: 96 h - Species: mykiss) EC50 Daphnia 1 > 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) 12.2. Persistence and degradability John Deere Turf-GardTM 10W30 Persistence and degradability Not established. Page 178 of 190 Page 178 of 190 Page 178 of 190 Page 178 of 190 ---PAGE BREAK--- John Deere Turf-GardTM 10W30 Safety Data Sheet according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) 12/11/2013 EN (English) SDS ID: 11D0 6/8 12.3. Bioaccumulative potential John Deere Turf-GardTM 10W30 Log Kow Base oil hydrocarbons: log Kow > 4 (estimate) 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Sewage disposal recommendations : Prevent entry to sewers and public waters. An environmental fate analysis is not available for this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum products. Petroleum-based (mineral) lubricating oils normally will float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway may be sufficient to cause a fish kill or create an anaerobic environment. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Liquid product may not be disposed of with household waste or landfilled. Do not allow to enter into drains/waters or in the soil. Do not pressurize, cut, weld, braze solder, drill, grind, or expose containers to flames, sparks, heat, or other potential ignition sources. Additional information : Used oil, may contain harmful impurities. Used motor oil was associated with cancer in lifetime skin painting studies with laboratory animals. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number Not applicable 14.2. UN proper shipping name Not applicable 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, solvent-refined light paraffinic (64741-89-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the Canadian DSL (Domestic Sustances List) inventory. Page 179 of 190 Page 179 of 190 Page 179 of 190 Page 179 of 190 ---PAGE BREAK--- John Deere Turf-GardTM 10W30 Safety Data Sheet according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) 12/11/2013 EN (English) SDS ID: 11D0 7/8 Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0) Listed on the Canadian DSL (Domestic Sustances List) inventory. Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) Listed on the Canadian DSL (Domestic Sustances List) inventory. Distillates, petroleum, solvent-refined light paraffinic (64741-89-5) Listed on the Canadian DSL (Domestic Sustances List) inventory. EU-Regulations Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) substances. Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) substances. Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) substances. Distillates, petroleum, solvent-refined light paraffinic (64741-89-5) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) substances. Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 15.2.2. National regulations Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the AICS (the Australian Inventory of Chemical Substances) Listed on Inventory of Existing Chemical Substances (IECSC) Listed on the Japanese ENCS (Existing & New Chemicals Substances) inventory. Listed on the Korean ECL (Existing Chemical List) inventory. Listed on New Zealand - Inventory of Chemicals (NZIoC) Listed on Inventory of Chemicals and Chemical Substances (PICCS) Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0) Listed on the AICS (the Australian Inventory of Chemical Substances) Listed on Inventory of Existing Chemical Substances (IECSC) Listed on the Japanese ENCS (Existing & New Chemicals Substances) inventory. Listed on the Korean ECL (Existing Chemical List) inventory. Listed on New Zealand - Inventory of Chemicals (NZIoC) Listed on Inventory of Chemicals and Chemical Substances (PICCS) Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) Listed on the AICS (the Australian Inventory of Chemical Substances) Listed on Inventory of Existing Chemical Substances (IECSC) Listed on the Japanese ENCS (Existing & New Chemicals Substances) inventory. Listed on the Korean ECL (Existing Chemical List) inventory. Listed on New Zealand - Inventory of Chemicals (NZIoC) Listed on Inventory of Chemicals and Chemical Substances (PICCS) Distillates, petroleum, solvent-refined light paraffinic (64741-89-5) Listed on the AICS (the Australian Inventory of Chemical Substances) Listed on Inventory of Existing Chemical Substances (IECSC) Listed on the Japanese ENCS (Existing & New Chemicals Substances) inventory. Listed on the Korean ECL (Existing Chemical List) inventory. Listed on New Zealand - Inventory of Chemicals (NZIoC) Listed on Inventory of Chemicals and Chemical Substances (PICCS) 15.3. US State regulations Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) U.S. - Texas - Effects Screening Levels - Long Term Page 180 of 190 Page 180 of 190 Page 180 of 190 Page 180 of 190 ---PAGE BREAK--- John Deere Turf-GardTM 10W30 Safety Data Sheet according to the federal final rule of hazard communication revised on 2012 (HazCom 2012) 12/11/2013 EN (English) SDS ID: 11D0 8/8 Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) U.S. - Texas - Effects Screening Levels - Short Term Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0) U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Distillates, petroleum, solvent-refined light paraffinic (64741-89-5) U.S. - Massachusetts - Right To Know List U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Asp. Tox. 1 Aspiration hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Irrit. 2 skin corrosion/irritation Category 2 H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H318 Causes serious eye damage SDS US (GHS HazCom 2012) The information presented herein has been compiled from sources considered to be dependable and is accurate to the best of Northland Products Company's knowledge; however, Northland Products Company makes no warranty whatsoever, expressed or implied, of merchantability or fitness for the particular purpose, regarding the accuracy of such data or the results to be obtained from the use thereof. Northland Products Company assumes no responsibility for the injury to the recipient or to third party persons or for any damage to any property and recipient assumes all such risks Page 181 of 190 Page 181 of 190 Page 181 of 190 Page 181 of 190 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 320 37th Avenue • St. Charles, Illinois 60174 • To Reorder, Call [PHONE REDACTED] PRODUCT IDENTIFICATION USE / DESCRIPTION REVISION DATE FOR MEDICAL AND UNITED 101 Moisture Barrier and March 17, 2003 TRANSPORTATION EMERGENCIES: Electrical Lubricant INFOTRAC: [PHONE REDACTED] HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety) Always follow Label Directions and Cautions. Susceptible to Release of Energy. 4 Extreme. 3 High. 2 Moderate. 1 Slight. 0 Minimal. See Health Hazard Data Section of this M.S.D.S. for more detailed information. FLAMMABILITY (0 = Maximum Safety) Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated to burn. 3 Ignites at normal temperature. 0 Will not burn. 2 Ignites when moderately heated. HAZARDOUS CAS ACGIH ACGIH OSHA OTHER S.A.R.A. TITLE III COMPONENTS NUMBER TWA STEL PEL RECOMMENDED LIMITS QUANTITIES Isoparaffinic hydrocarbon 64742-46-7 200 ppm Not 200 ppm None None established Food grade mineral oil 8042-47-5 5 mg/m3 Not 5 mg/m3 NIOSH STEL None established 10 mg/m3 Dipropylene glycol 34590-94-8 SKIN: 100 ppm SKIN: 150 ppm SKIN: 100 ppm NIOSH TWA None monomethyl ether SKIN: 606 mg/m3 SKIN: 909 mg/m3 SKIN: 600 mg/m3 100 ppm 600 mg/m3 Carbon dioxide 124-38-9 5000 ppm 30,000 ppm 5000 ppm NIOSH STEL None 9000 mg/m3 54,000 mg/m3 9000 mg/m3 30,000 ppm 54,000 mg/m3 BOILING POINT SPECIFIC GRAVITY (H20 = 1) Approximately 500°F 75°F) 0.830 VAPOR PRESSURE (psig) MELTING POINT (At 70° F) 90 Not determined VAPOR DENSITY (Air = 1) EVAPORATION RATE Greater than 1.0 (Butyl Acetate = 1) Not determined SOLUBILITY IN WATER VOLATILE ORGANIC COMPOUNDS Slight (Pounds Per Can Of Product) 0.023 APPEARANCE AND ODOR pH: Brown liquid with solvent odor Not applicable FLASH POINT (Method Used) Concentrate: 216°F FLAMMABLE LIMITS LEL UEL This product is nonflammable as per USA Flame Projection Test Not determined Not determined Not determined EXTINGUISHING MEDIA Foam, dry chemical, carbon dioxide SPECIAL FIRE FIGHTING PROCEDURES Keep containers cool with water spray Do not allow runoff to enter lakes, ponds, sewers or public water courses. Use equipment or shielding required to protect personnel against rupturing, bursting or venting containers. Fire fighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS Exposure to temperatures above 120°F may cause bursting. 4 May detonate-vacate area if 2 Violent chemical change Materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. PERSONAL PROTECTION UNITED 101 HAZARDOUS COMPONENTS IDENTITY, EXPOSURE LIMITS AND S.A.R.A. TITLE III INFORMATION PHYSICAL / CHEMICAL CHARACTERISTICS FIRE AND EXPLOSION HAZARD DATA 0 1 1 PAGE (CONTINUED ON REVERSE SIDE) L A B O R A T O R I E S Page 182 of 190 Page 182 of 190 Page 182 of 190 Page 182 of 190 ---PAGE BREAK--- STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE X Do not expose to temperatures above 120° F INCOMPATIBILITY (Materials To Avoid) Strong oxidizing agents HAZARDOUS DECOMPOSITION OR BY PRODUCTS In a fire, this product may produce carbon dioxide and carbon monoxide. HAZARDOUS POLYMERIZATION:WILL NOT OCCUR X CONDITIONS TO AVOID MAY OCCUR X None known HEALTH HAZARDS EYES: May cause slight irritation, but does not injure eye tissue. SKIN: Prolonged or repeated contact may cause moderate irritation. INHALATION: May cause irritation of nasal and respiratory passages. Abusive or excessive inhalation may cause dizziness, drowsiness, throat irritation, unconsciousness and other CNS effects. IF SWALLOWED: May cause upset stomach, nausea, vomiting and diarrhea. Aspiration of material into lungs may cause chemical pneumonitis. Minimal toxicity. CARCINOGENICITY: NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No This product contains a chemical known to the state of California to cause cancer or reproductive toxicity? No SIGNS AND OF OVEREXPOSURE EYES: Irritation SKIN: Irritation INHALATION: Irritation of nasal and respiratory passage Dizziness, drowsiness, throat irritation, unconsciousness and other CNS effects. IF SWALLOWED: Upset stomach, nausea, vomiting and diarrhea. Aspiration of material into lungs may cause chemical pneumonitis. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY OVEREXPOSURE None known TARGET ORGANS: Central nervous system EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with water lifting upper and lower lids, for at least 15 minutes. If irritation persists, call a physician or poison center. SKIN: Wash with soap and water. If irritation persists, call a physician or poison center. INHALATION: Remove to fresh air. Apply CPR as needed and call a physician or poison center immediately. IF SWALLOWED: Do not induce vomiting. Call a physician or poison center immediately. Aspiration of material into the lungs may cause chemical pneumonitis. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Eliminate all sources of ignition. Ventilate area. Allow propellant to evaporate. Absorb with inert, non-combustible material. Place in a suitable container for disposal. WASTE DISPOSAL METHOD Consult local, state, and federal authorities for proper disposal guidelines. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store in a cool, dry place away from direct sunlight and sources of ignition. Do not expose to temperatures above 120° F. Store as NFPA code 30B Level 1 Aerosol. Avoid skin contact and do not get in eyes. Replace cap when not in use. Direct spray away from face. Keep out of reach of children. RESPIRATORY PROTECTION (Specify Type) If TLV is exceeded, use NIOSH/MSHA approved respirator. VENTILATION: MECHANICAL (General) LOCAL EXHAUST Provide adequate ventilation Generally adequate PROTECTIVE GLOVES EYE PROTECTION Neoprene or nitrile rubber gloves Safety glasses OTHER PROTECTIVE CLOTHING OR EQUIPMENT Long sleeves WORK HYGENIC PRACTICES Wash hands and face with soap and water after using this product. REACTIVITY DATA HEALTH HAZARD DATA PRECAUTIONS FOR SAFE HANDLING AND USE CONTROL MEASURES FOR USE WHERE SIGNIFICANT EYE, SKIN OR INHALATION EXPOSURE IS LIKELY PAGE UNITED 101 MOISTURE BARRIER and ELECTRICAL LUBRICANT Page 183 of 190 Page 183 of 190 Page 183 of 190 Page 183 of 190 ---PAGE BREAK--- There was a PDF conversion failure for Uploaded SDS - Product Name: Unleaded Gasoline CAS Number: Manufacturer: Gasoline SDS Date: To complete your binder, please upload a different SDS for this product or remove the SDS from your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 184 of 190 Page 184 of 190 Page 184 of 190 Page 184 of 190 ---PAGE BREAK--- Safety Data Sheet Vinyl Cement Patch © Akona Manufacturing LLC. Version 1.2 Page 1 of 6 Akona Manufacturing, LLC. Emergency Telephone Number: Revision Date 2025 Centre Point Boulevard, Suite 300 [PHONE REDACTED] Nov. 2014 Mendota Heights, MN 55120-1221 Information Telephone Number [PHONE REDACTED] Section 1: Product Identification Product Type: Dry Packaged Cement-Based Products Akona Product Name: Vinyl Cement Patch Section 2: Hazard Identification The most immediate and likely hazards are burns from dust in the eye. When the product is mixed with water, it will form an alkaline solution, which can cause skin irritation. Dust from the product is irritating to breathe. Prolonged overexposure to dust from the product is harmful to breathe, because it will contain silica. Applicable hazard statement based on cement content Danger. H318: Causes serious eye damage H315: Causes skin irritation Applicable hazard statement based on silica content Danger. H350: May cause cancer from inhaling dust. H372: Causes damage to respiratory system (silicosis) through prolonged or repeated exposure to inhaled dust. This product has been evaluated according to GHS and 29CFR1910.1200, Appendix A. It is categorized as a Health Hazard Carcinogen Category 1A, because it contains silica (quartz). It is categorized as a Health Hazard (serious eye damage/eye irritation - Category 1 and skin irritation – Category 2) because it contains Portland cement. Applicable Precautionary Statements: Based on silica content P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dusts P270: Do not eat, drink or smoke when using this product. P280: Wear eye protection P308+313/314. If exposed or concerns, or if you feel unwell: Get medical advice P501: Dispose of contents in accord with local regulations Page 185 of 190 Page 185 of 190 Page 185 of 190 Page 185 of 190 ---PAGE BREAK--- Safety Data Sheet Vinyl Cement Patch © Akona Manufacturing LLC. Version 1.2 Page 2 of 6 Based on cement content: P280: Wear skin and eye protection (water resistant protective gloves. Goggles recommended to prevent any dust in eyes). P264: Wash any exposed skin thoroughly after handling material P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352: IF ON SKIN: wash with plenty of water. P332+P313: If skin irritation occurs, get medical attention. P310: Immediately call a doctor if any eye irritation or discomfort develops HMIS® Rating: Health: 1* Fire: 0 Reactivity: 0 HMIS® is a registered trademark of the National Paint and Coatings Association Section 3: Hazardous Ingredients/Composition Ingredient Typical Percentage CAS # Portland Cement 20-40% 65997-15-1 Calcium aluminate cement 0-55% 65997-16-2 Silica Sand (as quartz) 60-75% 14808-60-7 Lime 0-7% 1305-78-8 Calcium carbonate 0-4% 471-34-1 Polymeric binder 0-4% * *Specific chemical identities and concentrations withheld as trade secret. They are available upon request to health professionals, employees and their designated representatives in accord with 29CFR1910.1200(i). Section 4: First Aid Measures Inhalation: If irritation develops, get to fresh air. Eye contact: Immediately rinse eyes: hold eyelids apart and flush eyes with plenty of water. At least fifteen minutes of flushing is recommended. Get prompt medical attention for any discomfort or irritation. Skin Contact: wash off with plenty of soap and water. Get medical attention for any burns or persistent rashes. Ingestion: Check with the Poison Control Center or a doctor. Do not induce vomiting unless directed to do so by medical personnel. of overexposure: Inhalation: Breathing the dust may cause coughing, wheezing, sore throat. Repeated exposure to the dust can cause a runny nose, chronic coughing and impaired Page 186 of 190 Page 186 of 190 Page 186 of 190 Page 186 of 190 ---PAGE BREAK--- Safety Data Sheet Vinyl Cement Patch © Akona Manufacturing LLC. Version 1.2 Page 3 of 6 lung function. Long term exposure to respirable silica in the dust can cause silicosis (lung scarring) and lung cancer. Eye contact: eye irritation from the mechanical effect. Eye irritation, burning from cement Cement reacts with moisture to form a very alkaline solution, which can severely irritate or burn eyes. Skin Contact: Can cause skin irritation and can dry the skin. Because cement reacts with moisture exothermically to form an alkaline solution, contact with damp skin can cause irritation or burns, which may not be felt immediately. Severe burns of the feet have resulted from cement getting into footwear. Some people may develop an allergic dermatitis (cement itch) from chromate contaminants in Portland cement. Note to physician: Treat according to No known specific antidote. Section 5: Fire Fighting Measures Fire extinguishing media: Appropriate for surrounding materials. Product is not flammable. Special fire fighting procedures: none Unusual fire and explosion hazards: None Hazardous combustion products: None expected. Section 6: Accidental Release Measures Contain and clean up. Avoid creating dust. Do not wash down drains or allow product to enter sewers – product will harden upon contact with water. Section 7: Handling and Storage Avoid breathing dust. Wash hands after use. Do not eat, drink, or use tobacco products when handling any chemical products. Section 8: Exposure Controls/Personal Protection Occupational Exposure Limits: OSHA PEL OSHA 1989 PEL* ACGIH TLV NIOSH REL Portland cement 50 10 mg/m3 (total) 5 mg/m3 (respirable) 1 mg/m3 (respirable) 10 mg/m3 (total) 5 mg/m3 (respirable) silica (quartz) 10 mg/m3 (%silica+2) 0.1 mg/m3 (respirable) 0.025 mg/m3 (respirable) 0.05 mg/m3 Calcium aluminate cement Use exposure limits for Portland cement. Page 187 of 190 Page 187 of 190 Page 187 of 190 Page 187 of 190 ---PAGE BREAK--- Safety Data Sheet Vinyl Cement Patch © Akona Manufacturing LLC. Version 1.2 Page 4 of 6 Lime (calcium oxide) 5 mg/m3 5 mg/m3 2 mg/m3 2 mg/m3 Calcium carbonate 15 mg/m3 (total) 5 mg/m3 (respirable) 15 mg/m3 (total) 5 mg/m3 (respirable) None (TLV withdrawn in 2007) 10 mg/m3 (total) 5 mg/m3 (respirable) Polymeric binder None established *For states that adopted the 1989 PEL revisions (Minnesota, Oregon, Washington, California) Engineering Controls: Avoid creating dust. Local exhaust ventilation is usually not required. If cutting or grinding material after it has hardened, water can be used as a dust suppressant. Personal protective equipment Respiratory protection: Usually not required when working with virgin product, but take measures to minimize dust exposure. May be required, depending on work done, for grinding or cutting material after it has hardened. For protection against irritation from dust or up to ten times the recommended exposure limits, use a NIOSH-approved N-95 filtering facepiece or a half mask respirator equipped with N-95 filters. A more protective respirator P100 filters or full face respirator) may be substituted. Skin protection: Avoid any skin contact, particularly when skin may be wet from sweat. Wear any water-impermeable gloves such as PVC gloves, particularly for prolonged contact. Wear waterproof boots, high enough to prevent any cement from getting into them. wash off of skin and remove contaminated clothing. Eye protection: Safety glasses with side shields. If used in dusty or windy conditions, goggles are recommended. Section 9: Physical and Chemical Properties Appearance and odor: grey or grey-brown powder. May contain some coarse aggregate. No significant odor. Flash point: noncombustible. Flammable limits: N/A Boiling Point: >2700°F Melting point: >2700°F Specific Gravity: 2.6 to 3.15 Solubility in water: slight pH: 11-13 (cements in water) Evaporation Rate: not applicable. Product does not evaporate. Evaporation rate (butyl acetate = not applicable Page 188 of 190 Page 188 of 190 Page 188 of 190 Page 188 of 190 ---PAGE BREAK--- Safety Data Sheet Vinyl Cement Patch © Akona Manufacturing LLC. Version 1.2 Page 5 of 6 Section 10: Stability and Reactivity Stability: stable Conditions to avoid: none known. Incompatibility: will react with water, hydrating product, hardening it, and giving off heat. Avoid strong oxidizers, strong acids Hazardous polymerization: will not occur Hazardous decomposition products: Silica will dissolve in hydrofluoric acid and produce a corrosive gas - silicon tetrafluoride. Section 11: Toxicological Information Not considered acutely toxic. Can damage the eyes, skin and respiratory system. Portland and calcium aluminate cements are caustic and abrasive to the skin. In contact with water or moisture, they can form alkaline hydroxides, which can cause burns that may not be felt immediately. Portland cement may contain trace amounts of hexavalent chromium. Hexavalent chromium can cause allergic contact dermatitis. Respirable silica is categorized as a Health Hazard Carcinogen Category 1A (known to have carcinogenic potential for humans) and a Health Hazard Specific Target Organ Toxicity – Repeated Exposure Category 1. Respirable silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs. There is evidence that exposure to respirable silica or the disease silicosis is associated with an increased incidence of Scleroderma, tuberculosis and kidney disorders. silica is listed as carcinogenic according to IARC. ACGIH classified silica as a suspected human carcinogen. Portland and calcium aluminate cements are categorized as Health Hazard Serious Eye Damage/Eye Irritation Category 1 and Serious Skin Category 2, because they form a strong alkaline solution in water. Polymeric binder: toxicological testing has been conducted with similar products Acute toxicity (oral, rat): LD50 >2000 mg/kg Irritation (rabbit): mildly irritating to skin. Not irritating to eyes Section 12: Ecological Information Product as a whole has not been tested but is expected to have low acute toxicity. Ecotoxicity: . Not considered hazardous to the aquatic environment or to the ozone layer. Persistence and degradability: Not likely to biodegrade Page 189 of 190 Page 189 of 190 Page 189 of 190 Page 189 of 190 ---PAGE BREAK--- Safety Data Sheet Vinyl Cement Patch © Akona Manufacturing LLC. Version 1.2 Page 6 of 6 Mobility in soil: no information available. Bioaccumulation: based on ingredients, not likely to bioaccumulate Section 13: Disposal Considerations Do not sewer or dump on the ground As provided, not a RCRA-regulated waste. Dispose of in accordance with federal, state, and local regulations. Section 14: Transportation Not a DOT-regulated hazardous material. Not classified as dangerous goods for DOT, IATA, IMDG, TDG Section 15: Regulatory Information This product contains 0.1% or more of silica, regulated under California Proposition 65 as a chemical known to the state of California to cause cancer or reproductive effects. It is on the New Jersey Right to Know Hazardous Substance List. This product does not contain any  chemicals regulated under: CERCLA SARA 302 EHS SARA 311/312 SARA 313  Hazardous Air Pollutants Section 16: Other Information Additional information on the products is available at. www.akonallc.com NOTE: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products. Before using any product, read its label and safety data sheet. Page 190 of 190 Page 190 of 190 Page 190 of 190 Page 190 of 190