Document douglascountywi_gov_doc_349cc722ca

Safety Data Sheets Government Center / Courthouse All Department SDS Government Center / Courthouse All Department SDS 10/08/2015 ---PAGE BREAK--- Safety Data Sheet Index Binder: Government Center / Courthouse All Department SDS - Government Center / Courthouse All Department SDS 096-000 106-97-8 Norazza, Inc. 05/05/2015 9 3M BRAND DESK AND OFFICE CLEANER 573 3M - Stationery & office Supplies 02/10/2015 14 3M Dust Remover AV152A, AV152A-B, AV152B 3M - Stationery & office Supplies 11/18/2014 24 51640A – No 40 Black HP - Hewlett Packard Company 07/18/2002 33 538AD Germ-X Hand Sanitizer - Morning Fresh Vi-Jon Inc. 05/31/2015 38 787 BLACK FOX Color Master Inc 10/30/2013 49 Ace Hardware Electronic Duster 811-97-2 CRC Industries, Inc. 06/11/2012 52 AIRLIFT FRESH SCENT (AEROSOL) Spartan Chemical Company, Inc. 05/01/2015 58 AIRLIFT LEMON SCENT (BULK CONCENTRATE) Spartan Chemical Company, Inc. 03/29/2015 63 AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Spartan Chemical Company, Inc. 05/18/2015 68 Ajax Dual Action Clean & Ajax Bleach Alternative Regular/HE Heavy Duty Liquid Detergent; All Sizes Phoenix Brands 03/11/2013 73 AJAX SPRAY N WIPE TRIPLE ACTION GLASS Colgate-Palmolive Pty Ltd 10/01/2012 78 ALEENE’S ORIGINAL TACKY GLUE iLOVEtoCREATE - A Duncan Enterprises Company 07/29/2013 79 ALPET D2 Surface Sanitizer Wipes Best Sanitizers Inc 01/15/2015 86 Alpha HP Bathroom Disinfectant Cleaner (1 :64 use solution) Johnson Wax Professional 02/08/2007 95 Applause Hand Sanitizer 75-28-5 QUESTVAPCO CORPORATION 05/26/2013 98 Bar Keepers Friend Cleanser & Polish SERVAAS LABORATORIES, INC. 06/12/2015 101 BLACK SHARP TONER MX51NT SHARP 105 BLOW OFFDUSTER R152A-(3.5 oz, 8 oz. 10 oz)-air duster, 3.5 oz auto duster 75-37-6 MAX PRO 01/15/2015 106 Brillianize kleen Master Products The BRILLIANIZE Company 03/27/2006 115 Bromocresol Purple - Bromothymol Blue Mixed Indicator, 1% / 0.2% (w/v) in Methanol 67-56-1 Ricca Chemical Company 05/01/2015 117 Product Name CAS Number Manufacturer Version Date Page Page 2 of 1069 Page 2 of 1069 Page 2 of 1069 Page 2 of 1069 ---PAGE BREAK--- BRUSH KLEAN (aerosol) TRI-CHEM CORPORATION 07/12/2007 128 C/M DE-STAT CERTIFIED LABS - DIVISION OF NCH CORPORATION 10/18/1991 130 CARPET STAIN REMOVER Spartan Chemical Company, Inc. 01/22/2015 133 CC800.3 Dry Erase Cleaner 67-63-0 CORPORATE EXPRESS 05/25/2007 139 CEB31600 CORPORATE EXPRESS HAND CLEANING WIPES TUB 100 Sourcing Partner Inc 04/07/2008 145 Century Compressed Gas Duster 75-37-6 Falcon Safety Products, Inc 04/28/2015 148 Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) Akorn, Inc. 04/29/2015 156 CLOROX CLEAN UP CLEANER WITH BLEACH The Clorox Company 04/01/2002 167 Clorox Commercial Solutions Clorox Clean-Up Disinfectant Cleaner with Bleach1 CLOROX SALES COMPANY 06/12/2015 168 Clorox Commercial Solutions Green Works 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Clorox Professional Products Company 05/23/2015 178 CLOROX COMMERCIAL SOLUTIONS ULTRA CLOROX DISINFECTING BLEACH Clorox Company of Canada, Ltd. 07/19/2013 187 Clorox Healthcare Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Clorox Professional Products Company 03/26/2015 189 CLOROX REGULAR-BLEACH The Clorox Company 06/12/2015 199 Comet Deodorizing Cleanser with Chlorinol Procter & Gamble Professional 06/12/2015 209 CONSERVE Ecolab - Food & Beverage 11/16/2000 216 Corporate Express EXP Duster Falcon Safety Products, Inc 05/04/2012 218 Countertop Magic MAGIC AMERICAN PRODUCTS, INC. 12/21/2005 224 Coverage Plus Germicidal Surface Wipes Steris Corporation 06/24/2015 225 CP INSTITUTIONAL PRODUCTS AJAX DISINFECTANT BOWL CLEANER COLGATE-PALMOLIVE COMPANY - INSTITUTIONAL PRODUCT DIVISION 09/01/1997 226 CRAYOLA COLOR WONDER MARKERS, CW SPRAYER; CW WATERCOLORS CRAYOLA LLC 03/19/2014 230 CRITERION 90 SRM VESUVIUS USA 06/12/2015 236 Regular Bleach 7681-52-9 James Austin Company 06/15/2015 244 Disinfecting Multi-Surface Cleaner Seventh Generation Inc 05/28/2015 250 DR-OP Drain Opener SHARE CORPORATION 03/08/2007 256 Product Name CAS Number Manufacturer Version Date Page Page 3 of 1069 Page 3 of 1069 Page 3 of 1069 Page 3 of 1069 ---PAGE BREAK--- ELMER'S STICKY OUT Elmer's Products, Inc. 12/15/2010 258 ENDUST FREE NAKOMA PRODUCTS, LLC 05/11/2015 267 ENDUST LEMON NAKOMA PRODUCTS, LLC 05/11/2015 271 Equate Petroleum Jelly Vi-Jon Inc. 01/29/2013 275 Expo White Board Cleaner Newell Rubbermaid 08/05/2015 284 Expo White Board Cleaner, Expo Original Cleaner Sanford L.P. 12/06/2010 292 Fabuloso Pro APC Cleaner Lavender Colgate-Palmolive Company 294 Febreze Air Effects - Sun Baked Procter & Gamble 02/24/2015 303 Febreze Fabric Refresher - Antimicrobial Procter & Gamble, Fabric and Home Care Division 03/16/2015 310 Formula 409 Carpet Spot & Stain Remover (aerosol) The Clorox Company 01/05/2015 317 Formula 409 Glass & Surface Cleaner The Clorox Company 01/05/2015 327 Full Blast Lawson Products, Inc. 07/22/2014 335 GLADE DECOR SCENTS - MAPLE PUMPKIN S.C. Johnson & Son, Inc. 01/12/2012 338 GLADE SUPER FRESH JohnsonDiversey, Inc. 02/08/2008 346 GLANCE Foaming Glass Cleaner JohnsonDiversey, Inc. 10/15/2009 353 GLANCE NA Johnson Wax Professional 07/25/2007 357 Glance Non-Ammoniated Glass Cleaner Johnson Wax Professional 07/08/2004 360 Glance RTU Glass & Multi-Surface Cleaner Diversey, Inc. 04/21/2015 364 Glass Brite Evans International 05/15/1999 369 Glass-Kleen Plus TIFCO INDUSTRIES INC 05/26/2015 371 GOJO E2 Foam Handwash with PCMX GOJO Industries, Inc. 05/05/2015 381 Goo Gone Spray Gel Goo Gone 08/14/2014 401 GRAFFITI AWAY TOWELS TRI-CHEM CORPORATION 05/24/2007 407 Greenworks Natural All Purpose Cleaner Clorox 409 GS NEUTRAL DISINFECTANT CLEANER Spartan Chemical Company, Inc. 08/14/2015 410 Gum Remover Johnson Wax Professional 03/07/2008 415 Gunk Glass Cleaner - Streak Free RSC Chemical Solutions 08/10/2015 418 HOUSEHOLD OIL Aldon Corporation 09/10/2013 427 Isagel SWEEN CORP 01/30/1996 428 Product Name CAS Number Manufacturer Version Date Page Page 4 of 1069 Page 4 of 1069 Page 4 of 1069 Page 4 of 1069 ---PAGE BREAK--- ISOPROPYL RUBBING ALCOHOL 70% 67-63-0 High Valley Products, Inc. 07/18/2015 430 KEYSTONE GLASS CLEANER ECOLAB CO. 08/10/2015 435 KRUD KUTTER Driveway Cleaner & Degreaser Krud Kutter, Inc. 12/11/2013 444 Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner Reckitt Benckiser - Morris Corporate Center IV 04/01/2015 450 Lemon SHine Furnature Polish Nyco Products Company 08/16/2005 462 Liquid Had Dishwashing Detergents and Antibacterial Hand Soaps Procter & Gamble 08/01/2007 464 Liquid Hand Dishwashing Detergents and Antibacterial Hand Soaps Procter & Gamble - P&G Household Care 08/28/2014 469 Liquid Hand Dishwashing Detergents Finished Product The Procter & Gamble Company, P and G Hosehold Care 06/08/2014 474 LOTIONIZED LIQUID HAND CLEANER Spartan Chemical Company, Inc. 07/28/2015 479 LYSOL All Purpose Cleaner - Power White & Shine Trigger with Bleach Reckitt Benckiser - Morris Corporate Center IV 03/31/2015 484 Lysol Brand II Kills 99.9% of Viruses & Bacteria Disinfecting Wipes - Ocean Fresh Reckitt Benckiser - Morris Corporate Center IV 04/27/2015 497 Lysol Brand II Kills 99.9% of Viruses & Bacteria Disinfecting Wipes Lemon Lime Blossom 77182 Reckitt Benckiser - Morris Corporate Center IV 04/27/2015 508 Lysol Dual Action Disinfecting Wipes, Lysol Xtra Large Dual Action Wipes Reckitt Benckiser - Morris Corporate Center IV 12/18/2014 519 Lysol I.C. Brand III Disinfectant Spray Reckitt Benckiser - Morris Corporate Center IV 06/26/2015 531 Magic Countertop Cleaner & Polish MAGIC 01/16/2015 544 Magic Sizing Faultless Starch / Bon Ami Company 11/11/2013 550 Microshield Masking Aid and Protectant Structure Probe, Inc - SPI Supplies Division 01/08/2009 555 MIRACLE GRO SHAKE 'N FEED CONTINUOUS RELEASE BLOOM BOOSTER PLANT FOOD 10-16-10 Scotts Miracle - Gro Products Inc. 05/29/2015 564 Miracle-Gro Growmore The Scotts Company (UK) Limited 05/01/2014 574 MISTY ASPIRE FURNITURE CLEANER & POLISH AMREP, Inc. 08/25/2008 584 Misty Crawling Insect Killer AMREP, Inc. 04/14/2008 585 Misty Surface Disinfectant AMREP, Inc. 05/31/2015 592 Mr. Clean Magic Eraser Procter & Gamble 07/16/2015 604 Multi Metal Polish SHARE CORPORATION 07/19/2005 611 Product Name CAS Number Manufacturer Version Date Page Page 5 of 1069 Page 5 of 1069 Page 5 of 1069 Page 5 of 1069 ---PAGE BREAK--- MURPHY OIL SOAP WOOD CLEANER SPRAY RTU Colgate-Palmolive Company 05/22/2015 613 MX-31NVSA/MX-31 GVSA/MX-31 FVSA, MX- 31AVSA/MX-31CVSA (Cyan Developer) SHARP CORPORATION 03/07/2011 620 MX-31NVSA/MX-31 GVSA/MX-31FVSA (Yellow Developer) SHARP CORPORATION 04/01/2008 624 MX-500NT / MX-500GT / MX-500BT / MX- 500FT / MX-500AT / MX-500CT ( Black Toner) SHARP CORPORATION 08/02/2010 628 MX-C40NVM/MX-C38GVM/MX-C38FVM Magenta Developer) SHARP CORPORATION 04/01/2008 633 NATURALIZER VC CHEMSEARCH DIV. OF NCH CORP. 02/28/2014 637 Office Max Compressed Gas Duster 75-37-6 Falcon Safety Products, Inc 04/28/2015 642 Old English Aerosol - Lemon Reckitt Benckiser - Morris Corporate Center IV 07/20/2015 650 OUST SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT S.C. Johnson & Son, Inc. 08/22/2012 661 PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH Colgate-Palmolive Canada Inc. 09/21/2012 670 Paper / Rubber Cement UNION RUBBER, INC. 05/05/2015 677 Pearl Soft Lotion Hand Cleaner Dalco 01/01/2002 688 PIG Multi-Purpose Repair Putty (MSD-001) NEW PIG CORPORATION 02/13/2015 689 Pledge Clean & Dust Wipes - Citrus Scent S.C. Johnson & Son, Inc. 08/22/2008 692 PLEDGE EVERYDAY CLEANER MULTISURFACE - GLADE SHIMMERING SPRUCE S.C. Johnson & Son, Inc. 02/25/2015 699 PLEDGE FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL S.C. Johnson and Son, Limited 05/21/2014 710 Potassium Hydrogen Phthalate Solutions 877-24-7 GE Analytical Instruments 04/16/2015 718 PROFESSIONAL LYSOL BRAND FOOD SURFACE SANITIZER (TRIGGER) Reckitt Benckiser North America, Inc. 09/23/2009 724 PROFESSIONAL LYSOL BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Reckitt Benckiser North America, Inc. 06/24/2009 731 PROMAR 200 Interior Latex Eg-Shel Enamel, Extra White THE SHERWIN WILLIAMS COMPANY 03/05/2010 741 PROMAR 200 Zero VOC Interior Latex Flat, Ultradeep Base THE SHERWIN WILLIAMS COMPANY 02/25/2011 745 Propanol 71-23-8 The Dow Chemical Company 03/31/2015 748 PURELL Hand Sanitizer GOJO Industries, Inc. 03/19/2015 760 Product Name CAS Number Manufacturer Version Date Page Page 6 of 1069 Page 6 of 1069 Page 6 of 1069 Page 6 of 1069 ---PAGE BREAK--- PURELL HAND SANITIZING SPRAY GOJO Industries, Inc. 03/30/2015 775 PURELL Hand Sanitizing Wipes GOJO Industries, Inc. 03/30/2015 790 ReadRight PowerDuster 75-37-6 Advantus Corporation 11/24/2014 804 Reagent Alcohol Fisher Scientific International 08/27/2015 808 Reference Electrodo Filling Solution 900001 Thermo Electric Company 11/11/2003 817 Renown Blue Tint Flush Toilet Bowl Cleaner AMSAN FLORIDA 03/01/2007 818 RESOLVE High Traffic Area Foam Carpet Cleaner Reckitt Benckiser - Morris Corporate Center IV 05/29/2015 820 RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 (Black toner) Ricoh Americas Corporation 08/22/2014 832 Safetec Cut & Scrape Cleaner - Spray Safetec of America, Inc. 09/01/2010 839 Sani-Cloth HB Germicidal Disposable Wipe Professional Disposables International, Inc. NP Nice Pak 841 Schultz Houseplant & Garden Insect Spray CHEMSICO DIV OF UNITED INDUSTRIES CORP 03/05/2008 847 Scrubbing Bubbles Automatic shower Cleaner - REFR S. C. Johnson & Son, Inc. 09/15/2006 848 SHARP TONER YELLOW SHARP 852 SHINE M UP AEROSOLSAMPLE, CAN CL CERTIFIED LABS - DIVISION OF NCH CORPORATION 11/18/2009 853 Silicone Lubricant Lawson Products, Inc. 07/08/2013 857 Simple Green Degreaser Sunshine Makers, Inc. 06/01/2015 861 Sodium Bicarbonate 144-55-8 EK Industries, Inc. 08/04/2015 866 Sodium Hydroxide, Pellets Avantor Performance Materials, Inc 04/14/2015 870 Sodium Phosphate Monobasic Monohydrate (Certified ACS) 10049-21-5 Fisher Scientific International 08/25/2015 880 SODIUM THISOULFATE 7772-98-7 Mineral Masters 08/21/2014 887 Soft Scrub Spray Gel with Bleach The Dial Corporation, a Henkel Company 04/20/2015 892 Soft Scrub with Lemon, Soft Scrub with Baking Soda The Dial Corporation, a Henkel Company 04/14/2014 898 SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN Colgate-Palmolive Company 05/22/2015 902 Special Stains Trich.III Green Staining Ventana Medical Systems, Inc. 07/16/2012 911 Spic and Span All-Purpose Cleaner - Made from Concentrate Procter & Gamble Professional 04/07/2015 971 Product Name CAS Number Manufacturer Version Date Page Page 7 of 1069 Page 7 of 1069 Page 7 of 1069 Page 7 of 1069 ---PAGE BREAK--- Static Free Hand Guard CHEMTRONICS 05/18/2015 978 STATICIDE General Purpose ACL Incorporated 07/15/2015 989 STERIPHENE II BRAND DISINFECTANT DEODORANT Spartan Chemical Company 09/22/2008 998 SUPER K-GRO WEED & GRASS KILLER Rockland Chemical Co., Inc. 02/01/1985 1002 Super Lube, Multi-Purpose Lubricant TIG Distributing, Inc. 03/10/2010 1004 Target Hand Sanitizer Levlad Inc 09/28/1999 1011 TEF-GEL Lawson Products, Inc. 03/23/2015 1014 Tempratone Tempera Paint Binney & Smith 06/02/1999 1023 TNT FOAMING DISINFECTANT CLEANER Spartan Chemical Company, Inc. 05/08/2015 1027 TRIAD II DISINFECTANT CLEANER Johnson Wax Professional 03/01/2006 1032 Soy Broth BD DIAGNOSTIC SYSTEMS 03/24/2014 1035 U.V CHARCOL WISER R1 Sun Chemical Corporation 08/14/2014 1036 ULTRA MARK ICELAND DAWN Mohawk Finishing Products Division of RPM Wood Finishes Group, Inc. 07/04/2015 1043 Universal Duster 10 OZ 75-37-6 Falcon Safety Products, Inc 06/04/2002 1050 Windex -40°C Windshield Washer Fluid Recochem Inc. 07/14/2015 1053 Windex Glass Cleaner with Ammonia-D Diversey, Inc. 05/06/2015 1061 WINDEX Super Concentrate Glass Cleaner with Ammonia-D Diversey, Inc. 09/18/2014 1066 Product Name CAS Number Manufacturer Version Date Page Page 8 of 1069 Page 8 of 1069 Page 8 of 1069 Page 8 of 1069 ---PAGE BREAK--- Page 1 of 4 SDS for: 2914011 Printed: 5/5/2015 SAFETY DATA SHEET This document is not intended for general distribution. It can be used as the basis for a general distribution document if appropriate changes are made to the identification section. 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: 096-000 Product Code: 2914011 Chemical Name: Endust for Electronics Screen & Electronics Cleaner 8oz Details of the supplier of the safety data sheet: This Safety Data Sheet has been updated in accordance with the Global Harmonized System (GHS) Manufacturer/Supplier: Norazza, Inc. 3938 Broadway St Buffalo NY 14227 US Supplier Phone Number: Contact Phone [PHONE REDACTED] Emergency telephone number: [PHONE REDACTED] International +01-[PHONE REDACTED] Product Use: Anti-static cleaner for electronic equipment 2. HAZARDS IDENTIFICATION CLASSIFICATION Flammable aerosol 2 Gas under pressure Liquefied gas SIGNAL WORD: Warning Page 9 of 1069 Page 9 of 1069 Page 9 of 1069 Page 9 of 1069 ---PAGE BREAK--- Page 2 of 4 SDS for: 2914011 Printed: 5/5/2015 Hazard Statements Flammable aerosol Contains gas under pressure; may explode if heated Precautionary Statements Keep away from heat/sparks/open flames/hot surfaces – No smoking Do not spray on an open flame or other ignition source Pressurized container – Do not pierce or burn, even after use Protect from sunlight. Store in a well ventilated place Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Percent WATER 7732-18-5 97.00 BUTANE 106-97-8 1.90 4. FIRST AID MEASURES INHALATION: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped . Get medical attention. EYE CONTACT: Wash immediately with large volumes of fresh water for at least 15 minutes . Get medical attention. SKIN CONTACT: Wipe off with a towel. Wash with soap and water. Get medical attention if irritation persists. INGESTION: Not a likely route of exposure. Most important acute and delayed: Repeated exposure may cause skin dryness or cracking. May cause drowsiness or dizziness. Indication of immediate medical attention and special treatment needed: None known. 5. FIRE FIGHTING MEASURES Suitable and unsuitable extinguising media: Foam, Alcohol foam, CO2, Dry chemical, Water fog . Water spray may be ineffective. Specific hazards arising from the chemical: Closed containers may explode from internal pressure build-up when exposed to extreme heat and discharge contents. Liquid content of container will support combustion. Overexposure to decomposition products may cause a health hazard. may not be readily apparent. Obtain medical attention. Hazardous decomposition products include carbon dioxide, carbon monoxide, and other toxic fumes Special equipment and precautions for fire-fighters: Water may be used to cool containers to prevent pressure build-up and explosion when exposed to extreme heat. Wear goggles and use self-contained breathing apparatus . If water is used, fog nozzles are preferred. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Avoid breathing vapors. Ventilate area. Remove all sources of ignition. Page 10 of 1069 Page 10 of 1069 Page 10 of 1069 Page 10 of 1069 ---PAGE BREAK--- Page 3 of 4 SDS for: 2914011 Printed: 5/5/2015 Methods and materials for containment and cleaning up: Clean up with absorbent material and place in closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling: Do not puncture or incinerate (burn) cans. Do not stick pins, nails, or any other sharp objects into opening on top of can. Do not spray in eyes. Do not take internally. See product label for additional information. Conditions for safe storage, including any incompatibilities: Store and use in cool, dry, well-ventilated areas . Do not store above 120 F. 8. EXPOSURE CONTROL/PERSONAL PROTECTION Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits WATER 7732-18-5 Not established Not established BUTANE 106-97-8 Not established TWA: 1000 ppm Appropriate engineering controls: Ventilation should be sufficient to prevent inhalation of any vapors . General dilution and/or local exhaust ventilation in volume to keep PEL/TLV of most hazardous ingredient below acceptable limit and well below stated limit. Individual protection measures: Respiratory protection: None under normal use. Avoid breathing vapors. In restricted areas , use approved chemical/mechanical filters designed to remove a combination or particles and vapor. In confined areas, use an approved air line respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above PEL/TLV limits. Protective gloves: None under normal use. Use solvent-resistant for prolonged or repeated contact. Eye protection: None under normal use. However, use of safety glasses with splash guards or full face shield should be used if indicated. Other protective clothing or equipment: None under normal use. However, use of solvent- resistant aprons or other clothing is recommended. Eye washes and safety showers in the workplace are recommended. SHOWERS IN THE WORKPLACE ARE RECOMMENDED. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Aerosol product Vapor Pressure: Not determined Vapor Density: Heavier than air Density: 0.985259828 Freezing point: Not determined Boiling point: N/A Evaporation rate: Slower than ether Explosive Limits: Not determined Auto ignition temperature: Not determined Viscosity: Not determined Page 11 of 1069 Page 11 of 1069 Page 11 of 1069 Page 11 of 1069 ---PAGE BREAK--- Page 4 of 4 SDS for: 2914011 Printed: 5/5/2015 Odor: Pleasant Odor threshold: Not determined pH: Not determined Melting point: Not determined Solubility: Not determined Flash point: Not determined Flammability: Level 1 Aerosol Partition coefficient Not determined octanol/water): Decomposition temperature: Not determined 10. STABILITY AND REACTIVITY Reactivity: Not reactive under normal conditions of use. Chemical stability: Stable under normal storage and handling conditions. Possibility of hazardous reactions: None known. Incompatible materials: No data Hazardous decomposition products: No data 11. TOXICOLOGICAL INFORMATION Long-term toxicological studies have not been conducted for this product. 12. ECOLOGICAL INFORMATION Long-term ecological studies have not been conducted for this product. 13. DISPOSAL CONSIDERATIONS Page 12 of 1069 Page 12 of 1069 Page 12 of 1069 Page 12 of 1069 ---PAGE BREAK--- Page 5 of 4 SDS for: 2914011 Printed: 5/5/2015 Dispose of in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections this document for hazard cautionary information. 14. TRANSPORT INFORMATION By land: DOT Proper Shipping Name: None required per 49 CFR 173 .306(i) for products that conform to the Limited Quantity provisions. Commodity shipping description: Cleaning Compound, NOI By water: DOT & IMDG Proper Shipping Name: UN1950, Aerosols, 2 LTD QTY By air: DOT & IATA Proper Shipping Name: UN1950, Aerosols, flammable, 2 LTD QTY (packing instruction Y203 applies) 15. REGULATORY INFORMATION All ingredients are either listed on the TSCA inventory or are exempt . 16. OTHER INFORMATION Date revised: 2015-05-05 Date Printed: 2015-05-05 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO RESPONSIBILITY FOR ITS USE. Revision 0 Page 13 of 1069 Page 13 of 1069 Page 13 of 1069 Page 13 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 1 of 10 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-0157-7 Version Number: 27.00 Issue Date: 02/10/15 Supercedes Date: 02/12/13 SECTION 1: Identification 1.1. Product identifier 3M BRAND DESK AND OFFICE CLEANER 573 Product Identification Numbers 70-0061-3328-7, 70-0160-6830-9, 70-0701-7945-5, 70-0704-0450-7, 70-0709-0857-2, 70-0711-2910-3 1.2. Recommended use and restrictions on use Recommended use Aerosol Cleaner for Office Surfaces, AEROSOL FOAM CLEANER FOR OFFICE SURFACES 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Stationery and Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Aerosol: Category 1. Specific Target Organ Toxicity (single exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame I Health Hazard I Pictograms Page 14 of 1069 Page 14 of 1069 Page 14 of 1069 Page 14 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 2 of 10 Hazard Statements Extremely flammable aerosol. Causes damage to organs: cardiovascular system I Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. 2% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt WATER 7732-18-5 86 - 92 ISOBUTANE PROPELLANT 75-28-5 1 - 8 Trade Secret * ISOPROPYL ALCOHOL 67-63-0 3 - 5 Trade Secret * ETHOXYLATED TALL-OIL FATTY ACIDS 61791-00-2 1 - 3 Trade Secret * SODIUM CARBONATE 497-19-8 < 1 ETHANOLAMINE 141-43-5 < 0.5 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. Page 15 of 1069 Page 15 of 1069 Page 15 of 1069 Page 15 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 3 of 10 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If you feel unwell, get medical attention. Eye Contact: No need for first aid is anticipated. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that Page 16 of 1069 Page 16 of 1069 Page 16 of 1069 Page 16 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 4 of 10 can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments ETHANOLAMINE 141-43-5 OSHA TWA:6 mg/m3(3 ppm) ETHANOLAMINE 141-43-5 ACGIH TWA:3 ppm;STEL:6 ppm ISOPROPYL ALCOHOL 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ISOPROPYL ALCOHOL 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin ISOBUTANE PROPELLANT 75-28-5 ACGIH STEL:1000 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Page 17 of 1069 Page 17 of 1069 Page 17 of 1069 Page 17 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 5 of 10 Skin/hand protection No chemical protective gloves are required. Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life. For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Foam Odor, Color, Grade: White foam, Lemon odor Odor threshold No Data Available Melting point Not Applicable Boiling Point Not Applicable Flash Point 30 ºF [Test Method: Open Cup] [Details: specific method: D92] Evaporation rate >=1.00 [Ref Std: WATER=1] [Details: product as applied (without propellant)] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.80 % Flammable Limits(UEL) 8.40 % [Details: for isobutane.] Vapor Pressure 31 - 43 psi 70 ºF] [Details: (aerosol can pressure)] Vapor Density No Data Available Density 1 g/ml Specific Gravity Approximately 1 [Ref Std: WATER=1] Solubility In Water 100.00 % Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Volatile Organic Compounds 55 - 115 g/l Percent volatile 96 - 98 % weight VOC Less H2O & Exempt Solvents 702 - 831 g/l SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. Page 18 of 1069 Page 18 of 1069 Page 18 of 1069 Page 18 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 6 of 10 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Single exposure may cause target organ effects: Cardiac Sensitization: may include irregular heartbeat faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Page 19 of 1069 Page 19 of 1069 Page 19 of 1069 Page 19 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 7 of 10 Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg ISOBUTANE PROPELLANT Inhalation- Gas (4 hours) Rat LC50 276,000 ppm ISOPROPYL ALCOHOL Dermal Rabbit LD50 12,870 mg/kg ISOPROPYL ALCOHOL Inhalation- Vapor (4 hours) Rat LC50 72.6 mg/l ISOPROPYL ALCOHOL Ingestion Rat LD50 4,710 mg/kg SODIUM CARBONATE Dermal Rabbit LD50 > 2,000 mg/kg SODIUM CARBONATE Ingestion Rat LD50 2,800 mg/kg ETHANOLAMINE Inhalation- Vapor official classifica tion LC50 estimated to be 10 - 20 mg/l ETHANOLAMINE Dermal Rabbit LD50 1,000 mg/kg ETHANOLAMINE Ingestion Rat LD50 1,720 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value ISOBUTANE PROPELLANT Professio nal judgeme nt No significant irritation ISOPROPYL ALCOHOL Multiple animal species No significant irritation SODIUM CARBONATE Rabbit No significant irritation ETHANOLAMINE Rabbit Corrosive Serious Eye Damage/Irritation Name Species Value ISOBUTANE PROPELLANT Professio nal judgeme nt No significant irritation ISOPROPYL ALCOHOL Rabbit Severe irritant SODIUM CARBONATE Rabbit Corrosive ETHANOLAMINE Rabbit Corrosive Skin Sensitization Name Species Value ISOPROPYL ALCOHOL Guinea pig Not sensitizing ETHANOLAMINE Guinea pig Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value ISOBUTANE PROPELLANT In Vitro Not mutagenic ISOPROPYL ALCOHOL In Vitro Not mutagenic ISOPROPYL ALCOHOL In vivo Not mutagenic SODIUM CARBONATE In Vitro Not mutagenic ETHANOLAMINE In Vitro Not mutagenic ETHANOLAMINE In vivo Not mutagenic Carcinogenicity Name Route Species Value Page 20 of 1069 Page 20 of 1069 Page 20 of 1069 Page 20 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 8 of 10 ISOPROPYL ALCOHOL Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration ISOPROPYL ALCOHOL Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day during organogenesi s ISOPROPYL ALCOHOL Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat LOAEL 9 mg/l during gestation SODIUM CARBONATE Ingestion Not toxic to development Mouse NOAEL 340 mg/kg/day during organogenesi s ETHANOLAMINE Dermal Not toxic to development Rat NOAEL 225 mg/kg/day during organogenesi s ETHANOLAMINE Ingestion Not toxic to development Rat NOAEL 616 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration ISOBUTANE PROPELLANT Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available ISOBUTANE PROPELLANT Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available ISOBUTANE PROPELLANT Inhalation respiratory irritation All data are negative Mouse NOAEL Not available ISOPROPYL ALCOHOL Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available ISOPROPYL ALCOHOL Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available ISOPROPYL ALCOHOL Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 13.4 mg/l 24 hours ISOPROPYL ALCOHOL Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse ETHANOLAMINE Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration ISOBUTANE PROPELLANT Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4,500 ppm 13 weeks ISOPROPYL ALCOHOL Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 12.3 mg/l 24 months ISOPROPYL ALCOHOL Inhalation nervous system All data are negative Rat NOAEL 12 mg/l 13 weeks ISOPROPYL ALCOHOL Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day 12 weeks SODIUM CARBONATE Inhalation respiratory system Some positive data exist, but the Rat LOAEL 0.07 3 months Page 21 of 1069 Page 21 of 1069 Page 21 of 1069 Page 21 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 9 of 10 data are not sufficient for classification mg/l ETHANOLAMINE Inhalation liver I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.656 mg/l 5 weeks ETHANOLAMINE Ingestion hematopoietic system I liver I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Page 22 of 1069 Page 22 of 1069 Page 22 of 1069 Page 22 of 1069 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 10 of 10 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 3 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 1 Flammability: 3 Physical Hazard: 1 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group: 10-0157-7 Version Number: 27.00 Issue Date: 02/10/15 Supercedes Date: 02/12/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 23 of 1069 Page 23 of 1069 Page 23 of 1069 Page 23 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 1 of 9 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 19-7982-2 Version Number: 6.00 Issue Date: 11/18/14 Supercedes Date: 06/30/09 SECTION 1: Identification 1.1. Product identifier 3M(TM) Dust Remover AV152A, AV152A-B, AV152B Product Identification Numbers 44-0051-5415-6, 70-0050-0173-3, 70-0050-0269-9, 70-0050-1903-2, 70-0050-2436-2, 70-0050-3890-9, 70-0050-4373-5, 70- 0050-4565-6, 70-0050-4715-7, 70-0050-7309-6, 70-0050-7316-1, 70-0050-7986-1, 70-0050-8052-1, 70-0051-0911-4, 70- 0051-1956-8, 70-0051-2011-1, 70-0051-2013-7, 70-0051-2070-7, 70-0051-3321-3, 70-0051-4224-8, 70-0051-4480-6, 70- 0051-4540-7, 70-0051-6293-1, 70-0051-6628-8, 70-0051-6856-5, 70-0713-0457-3, 70-0713-0458-1, 70-0713-2085-0, 70- 0713-2286-4, 70-0713-5096-4, 70-0713-6798-4, 70-0713-7295-0, 70-0713-8144-9, 70-0713-8166-2, 70-0713-9180-2, 70- 0713-9333-7, 70-0713-9390-7, 70-0714-1472-9, 70-0714-1595-7, 70-0714-2146-8, 70-0714-2147-6, 70-0714-2212-8, 70- 0714-2417-3, 70-0714-2418-1, 70-0714-2419-9, 70-0714-7652-0, 70-0714-8282-5, 70-0714-8283-3, 70-0714-8298-1, 70- 0714-8977-0, 70-0714-9081-0, 70-0714-9437-4, 70-0715-0658-1 1.2. Recommended use and restrictions on use Recommended use Compressed gas duster. 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Stationery and Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Aerosol: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger Page 24 of 1069 Page 24 of 1069 Page 24 of 1069 Page 24 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 2 of 9 Symbols Flame I Exclamation mark I Health Hazard I Pictograms Hazard Statements Flammable aerosol. May cause drowsiness or dizziness. Causes damage to organs: cardiovascular system I Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified May cause frostbite. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 1,1-DIFLUOROETHANE 75-37-6 > 99.65 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. Page 25 of 1069 Page 25 of 1069 Page 25 of 1069 Page 25 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 3 of 9 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Thaw frosted skin with lukewarm water. Do not rub affected area. Get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbonyl Fluoride During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion 5.3. Special protective actions for fire-fighters When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. Page 26 of 1069 Page 26 of 1069 Page 26 of 1069 Page 26 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 4 of 9 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not breathe thermal decomposition products. Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 1,1-DIFLUOROETHANE 75-37-6 CMRG TWA:1000 ppm 1,1-DIFLUOROETHANE 75-37-6 AIHA TWA:2700 mg/m3(1000 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection No chemical protective gloves are required. Page 27 of 1069 Page 27 of 1069 Page 27 of 1069 Page 27 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 5 of 9 Respiratory protection Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. Thermal hazards Wear cold insulating gloves/face shield/eye protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Gas Odor, Color, Grade: Clear, colorless with slight ethereal odor. Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point -13 ºF Flash Point < -50 ºF [Details: consumer aerosol does not exhibit a flame projection, therefore it is not determined to be flammable as defined in 16 CFR, Section 1500.3(c)(6)(viii).] Evaporation rate Not Applicable Flammability (solid, gas) Flammable Aerosol: Category 2. Flammable Limits(LEL) 3.9 % volume Flammable Limits(UEL) 16.9 % volume Vapor Pressure 87 psia 77 ºF] Vapor Density 2.4 [Ref Std: AIR=1] Density 0.9 g/cm3 [Details: Liquid] Specific Gravity 0.9 [Ref Std: WATER=1] [Details: Liquid] Solubility In Water 0.28 % Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature 849 ºF Decomposition temperature Not Applicable Viscosity Not Applicable SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Page 28 of 1069 Page 28 of 1069 Page 28 of 1069 Page 28 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 6 of 9 Sparks and/or flames 10.5. Incompatible materials Alkali and alkaline earth metals 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Frostbite: may include intense pain, discoloration of skin, and tissue destruction. Eye Contact: Frostbite: may include intense pain, clouding of the cornea, redness, swelling, and blindness. Ingestion: No health effects are expected. Target Organ Effects: Single exposure may cause: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: may include irregular heartbeat faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or Page 29 of 1069 Page 29 of 1069 Page 29 of 1069 Page 29 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 7 of 9 the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Gas(4 hr) No data available; calculated ATE > 50,000 ppm 1,1-DIFLUOROETHANE Inhalation- Gas (4 hours) Rat LC50 > 437,000 ppm 1,1-DIFLUOROETHANE Ingestion Rat LD50 > 1,500 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Serious Eye Damage/Irritation Name Species Value Skin Sensitization Name Species Value Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value 1,1-DIFLUOROETHANE In Vitro Some positive data exist, but the data are not sufficient for classification 1,1-DIFLUOROETHANE In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value 1,1-DIFLUOROETHANE Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation Not toxic to female reproduction Rat NOAEL 25,000 ppm 2 years 1,1-DIFLUOROETHANE Inhalation Not toxic to male reproduction Rat NOAEL 25,000 ppm 2 years 1,1-DIFLUOROETHANE Inhalation Not toxic to development Rat NOAEL 50,000 ppm during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation cardiac sensitization Causes damage to organs Human and animal NOAEL Not available poisoning and/or abuse 1,1-DIFLUOROETHANE Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL 100,000 ppm 1,1-DIFLUOROETHANE Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for Not available NOAEL Not available not available Page 30 of 1069 Page 30 of 1069 Page 30 of 1069 Page 30 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 8 of 9 classification Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation hematopoietic system I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25,000 ppm 2 years Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Page 31 of 1069 Page 31 of 1069 Page 31 of 1069 Page 31 of 1069 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 9 of 9 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 4 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 3 Flammability: 4 Physical Hazard: 1 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group: 19-7982-2 Version Number: 6.00 Issue Date: 11/18/14 Supercedes Date: 06/30/09 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 32 of 1069 Page 32 of 1069 Page 32 of 1069 Page 32 of 1069 ---PAGE BREAK--- Material Safety Data Sheet 1.0 Product and Company Identification Identification of the preparation: 51640A – No 40 Black Use of the preparation: Inkjet printing Company Identification: Hewlett-Packard Company 1000 NE Circle Boulevard Corvallis, Oregon 97330-4239 United States Emergency telephone number Hewlett-Packard Health Effects Line: 1-[PHONE REDACTED] (USA and Canada) [PHONE REDACTED] (USA direct) Singapore: +001-800-332-13321 General information telephone number: [PHONE REDACTED] (USA direct) Local Contact Information: Ireland Liffey Park Technology Campus Barnhall Road, Leixlip, Co. Kildare Phone: 01 6150000 United Kingdom Hewlett-Packard, Ltd. Cain Road, Amen Corner Bracknell, Berkshire, RG12 1HN Phone: 1344 36-0000 Hazard Rating NFPA/HMIS Health 1 Flammability 1 Instability/Reactivity 0 Special none 2.0 Composition/Information on Hazardous Ingredients This ink supply contains an aqueous ink formulation Component/Substance CAS Number EU Number % by Weight EU Classification Diethylene glycol 111-46-6 203-872-2 < 6 Xn; R22 Carbon black 1333-86-4 215-609-9 < 4 not classified Water 7732-18-5 231-791-2 > 50 not classified 3.0 Hazard Identification This ink is not classified according to EU Directive 1999/45/EC. July 18, 2002 Page 1 of 5 Inkjet 51640A – No 40 Black Page 33 of 1069 Page 33 of 1069 Page 33 of 1069 Page 33 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Routes of Exposure: Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Complete toxicity data are not available for this specific formulation. Acute Health Hazards: Any potential hazards are presumed to be due to exposure to the components. Diethylene glycol: Harmful if swallowed. May cause kidney and liver damage. May depress the central nervous system. Chronic Health Hazards: Carbon Black: Chronic inhalation studies performed with fine dust particles resulted in lung tumors in animals. The IARC classification was based upon these results. IARC also concluded “there is inadequate evidence in humans for the carcinogenicity of carbon black.” Inhalation of fine dust particles is not expected to occur during normal conditions of use of this ink. Carcinogenicity: Carbon black has been classified by the International Agency for Research on Cancer (IARC) as Group 2B (possibly human carcinogen). None of the other ingredients have been classified as carcinogens according to EU, IARC, MAK, NTP or OSHA. 4.0 First Aid Measures Emergency telephone number Hewlett-Packard Health Effects Line: 1-[PHONE REDACTED] (USA and Canada) [PHONE REDACTED] (USA direct) Singapore: +001-800-332-13321 Inhalation: Remove to fresh air. If persist, consult a physician. Ingestion: If stomach upset persists, consult a physician. Skin: Wash affected areas thoroughly with soap and water. If irritation persists, consult a physician. Eyes: Do not rub eyes. Immediately flush with large amounts of clean, lukewarm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists, consult a physician. 5.0 Fire Fighting Measures Extinguishing media: Water, dry chemical, carbon dioxide, foam July 18, 2002 Page 2 of 5 Inkjet 51640A – No 40 Black Page 34 of 1069 Page 34 of 1069 Page 34 of 1069 Page 34 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Unsuitable Extinguishing Media: None known Special Firefighting Procedures: None known Unusual fire and explosion hazards: No special hazards known Auto-ignition temperature: Not determined Flashpoint (method): > 200o F, > 93.3o C (US EPA Method 1020) Hazardous Combustion Products: Refer to section 10 6.0 Accidental release measures Spill or Leak Procedures: Standard eye and skin protection is recommended. Environmental precautions: Do not discharge into drains (See also Section 13, Disposal considerations) 7.0 Handling and Storage Storage Temperature: 59oF to 95oF; 15oC to 35oC Handling and Storage precautions: Keep out of the reach of children. Keep away from extreme heat or cold. Shelf Life: 1 year Special Sensitivity: None 8.0 Exposure control/ personal protection Exposure Limit Values: Diethylene glycol: Austria, Germany, Sweden, Switzerland, TWA=10ppm; Ireland, UK TWA=23ppm; Denmark TWA=2.5ppm Carbon black: OSHA, ACGIH, Canada, Denmark, Finland, France, Ireland, Italy, Netherlands, Norway, UK TWA = 3.5mg/m3; Belgium TWA=3.6mg/m3; Germany TWA=6mg/m3 Exposure Controls: Standard eye and skin protection for laboratory chemical safety is recommended. Use in well ventilated area. 9.0 Physical and chemical properties pH: 7.9 – 8.5 Boiling point: Not Determined Flash point: > 200o F, > 93.3o C Flammability: US NFPA/HMIS Flammability rating = 1 July 18, 2002 Page 3 of 5 Inkjet 51640A – No 40 Black Page 35 of 1069 Page 35 of 1069 Page 35 of 1069 Page 35 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Explosive properties: Not applicable Oxidizing properties: Not applicable Vapor Pressure: Not applicable Relative density: Specific Gravity 1.0 to 1.2 Solubility: Soluble in water Partition coefficient: Not determined Viscosity: Not determined Vapor density: >1 (air = 1.0) Evaporation rate: Not applicable Other: Not applicable 10.0 Stability and reactivity Stability: Stable under normal storage conditions Incompatibilities: Strong oxidizers and bases Thermal decomposition products: Oxides of carbon/nitrogen/sulfur, water Hazardous polymerization: None 11.0 Toxicological information Refer to Section 3 for potential heath effects and Section 4 for first aid measures Skin sensitization: Non-sensitizer in guinea pig (OECD 406). Not classified as a skin sensitizer according to EU Directives 67/548/EEC and 1999/45/EC. 12.0 Ecological information Ink Formulation: 96 Hour LC50 LC50 > 750 mg/L Fathead minnow 13.0 Disposal considerations Dispose in accordance with all applicable US Federal, state, local, and country laws. 14.0 Transportation information Not a regulated article under United States DOT, IATA, ADR, or RID. UN Number: Not applicable Class: Not applicable Proper Shipping Name: Not applicable Packing Group: Not applicable Marine Pollutant: Not listed Special Precautions: None noted July 18, 2002 Page 4 of 5 Inkjet 51640A – No 40 Black Page 36 of 1069 Page 36 of 1069 Page 36 of 1069 Page 36 of 1069 ---PAGE BREAK--- Material Safety Data Sheet July 18, 2002 Page 5 of 5 Inkjet 51640A – No 40 Black 15.0 Regulatory information US EPA TSCA Inventory: All ingredients are listed or exempt. US EPA TSCA 12(b): Contains 1-methyl-2-pyrrolidone (CAS 872-50-4). EU Notification: All ingredients are listed on EINECS and/or ELINCS or exempt. EU Hazard Label (1999/45/EC): This product does not require a label according to EU Directive 1999/45/EC. 16.0 Other information Date Prepared: July 18, 2002 HP-DMS Document Control Number: 09000de78022b35a-eng Revision Information: This document replaces all prior versions of the MSDS. EU Risk Phrase definitions: R22: Harmful if swallowed Other Information: This MSDS was prepared in compliance with EU Directive 91/155/EEC as amended by 2001/58/EC and USA OSHA Hazard Communication Standard (29CFR1910.1200). DISCLAIMER: This Material Safety Data Sheet (MSDS) is provided without charge to customers of Hewlett-Packard. Data is the most current known to Hewlett-Packard at the time of preparation of this MSDS and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. Page 37 of 1069 Page 37 of 1069 Page 37 of 1069 Page 37 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Safety Data Sheet The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved. Page 1 / 11 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name 538AD Germ-X Hand Sanitizer - Morning Fresh Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Hand sanitizer Uses advised against Use only as directed. Details of the supplier of the safety data sheet Supplier Name Vi-Jon Inc. Supplier Address Vi-Jon Inc. 8800 Page Avenue Saint Louis MO 63114 US Supplier Phone Number Phone: [PHONE REDACTED] (M-F 8am-4pm CST) Fax:[PHONE REDACTED] Supplier Email [EMAIL REDACTED] Emergency telephone number Chemtrec: 1-[PHONE REDACTED] (24-Hour) Page 38 of 1069 Page 38 of 1069 Page 38 of 1069 Page 38 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 2 / 11 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable liquids Category 3 GHS Label elements, including precautionary statements Emergency Overview Signal word Warning Flammable liquid and vapor Appearance: Clear to Hazy, Pale Blue, Viscous Liquid Physical State: Viscous Liquid Odor: Alcohol, Fresh Precautionary Statements - Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container closed Ground/bond container and receiving equipment Use explosion-proof electrical/ ventilating/ lighting/ equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Skin IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Fire In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0.218% of the mixture consists of ingredient(s) of unknown toxicity Other information Toxic to aquatic life with long lasting effects PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION May cause slight eye irritation Interactions with Other Chemicals None Page 39 of 1069 Page 39 of 1069 Page 39 of 1069 Page 39 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 3 / 11 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Trade Secret Ethyl Alcohol 62 %v/v 64-17-5 50-100 * Benzophenone-4 4065-45-6 0-10 * Blue 1 3844-45-9 0-10 * Carbomer Proprietary 0-10 * Fragrance Proprietary 0-10 * Glycerin 56-81-5 0-10 * Isopropyl Alcohol 67-63-0 0-10 * Isopropyl Myristate 110-27-0 0-10 * Tocopheryl Acetate 7695-91-2 0-10 * Water 7732-18-5 10-50 * *The exact percentage (concentration) of composition has been withheld as a trade secret 4. FIRST AID MEASURES First aid measures General Advice Call 911 or emergency medical service. Remove and isolate contaminated clothing and shoes. Eye Contact If persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Skin Contact In the case of skin irritation or allergic reactions see a physician. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, (trained personnel should) give oxygen. Ingestion Do NOT induce vomiting. Drink plenty of water. If persist, call a physician. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Most important and effects, both acute and delayed Most Important and Effects No information available. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat Page 40 of 1069 Page 40 of 1069 Page 40 of 1069 Page 40 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 4 / 11 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam. Unsuitable Extinguishing Media CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Uniform Fire Code Flammable Liquid: I-C Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge Yes. Protective equipment and precautions for firefighters Move containers from fire area if you can do it without risk. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Other Information Water spray may reduce vapor; but may not prevent ignition in closed spaces. Environmental Precautions Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Methods and material for containment and cleaning up Methods for Containment A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Methods for cleaning up Use clean non-sparking tools to collect absorbed material. Dike far ahead of liquid spill for later disposal. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Use personal protection equipment. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use grounding and bonding connection when transferring this material to prevent static discharge, fire or explosion. Keep in an area equipped with sprinklers. Avoid contact with skin, eyes or clothing. Conditions for safe storage, including any incompatibilities Storage Keep containers closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Keep in properly labeled containers. Do not store near combustible materials. Keep in an area equipped with sprinklers. Store in accordance with the particular national regulations. Store in accordance with local regulations. Incompatible Products Strong oxidizing agents. Acids. Chlorinated compounds. Page 41 of 1069 Page 41 of 1069 Page 41 of 1069 Page 41 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 5 / 11 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines There is no exposure data pertaining to the Product. This section reflects exposure data pertaining to individual ingredients. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethyl Alcohol 62% v/v 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm 10% LEL TWA: 1000 ppm TWA: 1900 mg/m3 Glycerin 56-81-5 TWA: 10 mg/m3 mist TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate (vacated) TWA: 5 mg/m3 mist, respirable fraction Isopropyl Alcohol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm 10% LEL TWA: 980 mg/m3 TWA: 400 ppm STEL: 500 ppm STEL: 1225 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control parameters Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Tight sealing safety goggles. Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant apron. Impervious gloves. Antistatic boots. Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. Page 42 of 1069 Page 42 of 1069 Page 42 of 1069 Page 42 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 6 / 11 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Viscous Liquid Appearance Clear to Hazy, Pale Blue, Viscous Liquid Odor Alcohol, Fresh Color Pale Blue Odor Threshold No information available Property Values Remarks/ Method pH 7.5 None known Melting / freezing point No data available None known Boiling point / boiling range No data available None known Flash Point 23 C / 73 F None known Evaporation Rate No data available None known Flammability (solid, gas) No data available None known Flammability Limit in Air Upper flammability limit No data available Lower flammability limit No data available Vapor pressure No data available None known Vapor density No data available None known Specific Gravity 0.90 None known Water Solubility Miscible in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive properties No data available Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available 10. STABILITY AND REACTIVITY R eactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Heat, flames, and sparks. Incompatible materials None known. Hazardous Decomposition Products Carbon oxides. Other Adverse Effects No information available. When used in accordance with the directions. Page 43 of 1069 Page 43 of 1069 Page 43 of 1069 Page 43 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 7 / 11 11. TOXICOLOGICAL INFORMATION There is no data for this product. The information included in this section describes the potential hazards of the individual ingredients. Information on likely routes of exposure Product Information Product does not present an acute toxicity hazard based on known or supplied information. Inhalation Specific test data for the substance or mixture is not available. Eye Contact Specific test data for the substance or mixture is not available. Skin Contact Specific test data for the substance or mixture is not available. Ingestion Specific test data for the substance or mixture is not available. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Ethyl Alcohol 62% v/v 64-17-5 - - = 124.7 mg/L ( Rat ) 4 h Glycerin 56-81-5 - > 10 g/kg ( Rabbit ) - Isopropyl Alcohol 67-63-0 = 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rabbit ) = 16000 ppm ( Rat ) 8 h Isopropyl Myristate 110-27-0 > 10000 mg/kg ( Rat ) = 5 g/kg ( Rabbit ) > 41 mg/L ( Rat ) Water 7732-18-5 > 90 mL/kg ( Rat ) - - Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Ethyl Alcohol 62% v/v 64-17-5 A3 Group 1 Known X Blue 1 3844-45-9 Group 3 Isopropyl Alcohol 67-63-0 Group 3 X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity None Target Organ Effects Blood. Central Nervous System (CNS). Eyes. Liver. Reproductive System. Respiratory system. Skin. Kidney. Spleen. Systemic Toxicity. Aspiration Hazard No information available. Page 44 of 1069 Page 44 of 1069 Page 44 of 1069 Page 44 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 8 / 11 Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (inhalation-dust/mist) 228.70 mg/l ATEmix (inhalation-vapor) 1,872.36 ATEmix 12. ECOLOGICAL INFORMATION There is no ecological data on the Product. The Product ingredients are expected to be safe for the environment at concentrations predicted under normal use and accidental spill scenarios. Packaging components are compatible with the conventional solid waste management practices. Ecotoxicity Toxic to aquatic life with long lasting effects. Persistence and Degradability No information available. Bioaccumulation No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated Packaging Do not reuse empty containers. US EPA Waste Number D001 California Hazardous Waste Codes 331 14. TRANSPORT INFORMATION DOT Proper Shipping Name CONSUMER COMMODITY Hazard Class ORM-D Description CONSUMER COMMODITY, ORM-D Emergency Response Guide Number 127 TDG UN-No. UN1170 Proper Shipping Name ETHANOL Hazard Class 3 Packing Group III Description UN1170, ETHANOL, 3, PG III MEX UN-No. UN1170 Proper Shipping Name ETHANOL Hazard Class 3 Packing Group III Description UN1170, ETHANOL, 3, III ICAO UN-No. UN1170 Proper Shipping Name ETHANOL SOLUTION Hazard Class 3 Packing Group III Description UN1170, ETHANOL SOLUTION, 3, PG III Page 45 of 1069 Page 45 of 1069 Page 45 of 1069 Page 45 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 9 / 11 IATA UN-No. UN1170 Proper Shipping Name ETHANOL SOLUTION Hazard Class 3 Packing Group III Description UN1170, ETHANOL SOLUTION, 3, PG III IMDG/IMO UN-No. UN1170 Proper Shipping Name ETHANOL Hazard Class 3 Packing Group III EmS No. F-E, S-D Description UN1170, ETHANOL, 3, PG III, FP 34C RID UN-No. UN1170 Proper Shipping Name ETHANOL (ETHYL ALCOHOL) Hazard Class 3 Packing Group III Classification code F1 Description UN1170, ETHANOL (ETHYL ALCOHOL), 3, III ADR UN-No. UN1170 Proper Shipping Name ETHANOL (ETHYL ALCOHOL) Hazard Class 3 Packing Group III Classification code F1 Tunnel restriction code (D/E) Description UN1170, ETHANOL (ETHYL ALCOHOL), 3, III ADN UN-No. UN1170 Proper Shipping Name ETHANOL Hazard Class 3 Packing Group III Classification code F1 Special Provisions 144, 601 Description UN1170, ETHANOL, 3, III Hazard Labels 3 Limited Quantity LQ7 Ventilation VE01 Page 46 of 1069 Page 46 of 1069 Page 46 of 1069 Page 46 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 10 / 11 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL All components are listed either on the DSL or NDSL. IECSC - TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name CAS No. Weight-% SARA 313 - Threshold Values % Isopropyl Alcohol - 67-63-0 67-63-0 0 - 10 1.0 SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) US State Regulations California Proposition 65 - NONE This product contains the following Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Ethyl Alcohol 62% v/v 64-17-5 X Blue 1 3844-45-9 X Glycerin 56-81-5 X X X X Isopropyl Alcohol 67-63-0 X X X X Page 47 of 1069 Page 47 of 1069 Page 47 of 1069 Page 47 of 1069 ---PAGE BREAK--- Product Number: 538AD Product Name: Germ-X Hand Sanitizer-Morning Fresh Issuing Date: May 31, 2015 Revision Date: None Revision Number: 0 Page 11 / 11 International Regulations Mexico National occupational exposure limits Component Carcinogen Status Exposure Limits Ethyl Alcohol 62% v/v 64-17-5 ( 50 - 100 ) Mexico: TWA 1000 ppm Mexico: TWA 1900 mg/m3 Glycerin 56-81-5 ( 0 - 10 ) - 10mg/m3 (mist) TWA Isopropyl Alcohol 67-63-0 ( 0 - 10 ) Mexico: TWA 400 ppm Mexico: TWA 980 mg/m3 Mexico: STEL 500 ppm Mexico: STEL 1225 mg/m3 Mexico - Occupational Exposure Limits - Carcinogens Canada WHMIS Hazard Class B2 D2A 16. OTHER INFORMATION NFPA Health Hazards 1 Flammability 3 Instability 0 Physical and Chemical Hazards - N/A HMIS Health Hazards 0 Flammability 3 Physical Hazard 0 Personal Protection X Prepared By WERCS Professional Services, LLC 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Issuing Date May 31, 2015 Revision Date None Revision Note None General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Approved and Updated by Vi-Jon, Inc. Disclaimer: The information and recommendations contained in the Safety Data Sheet (SDS) are supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. The information and recommendations set forth herein are presented in good faith and believed to be correct as of this date hereof. Vi-Jon, however, makes no representation as to the completeness or accuracy thereof, and information is supplied upon the express condition that the persons receiving the information will be required to make their own determination as to its suitability for their purposes prior to use. In no event will Vi-Jon be responsible for any damages of any nature whatsoever resulting from the use of, reliance upon, or the misuse of this information. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature, are made hereunder with respect to information or the product to which the information refers. The information as supplied herein is simply to be informative and intended solely to alert the user of the substance which is the subject matter of this SDS. The ultimate compliance with federal, state or local regulations concerning the use of this compound, or compliance with respect to product liability, rests solely upon the purchaser thereof. End of Safety Data Sheet Page 48 of 1069 Page 48 of 1069 Page 48 of 1069 Page 48 of 1069 ---PAGE BREAK--- Page 49 of 1069 Page 49 of 1069 Page 49 of 1069 Page 49 of 1069 ---PAGE BREAK--- Page 50 of 1069 Page 50 of 1069 Page 50 of 1069 Page 50 of 1069 ---PAGE BREAK--- Page 51 of 1069 Page 51 of 1069 Page 51 of 1069 Page 51 of 1069 ---PAGE BREAK--- Page 52 of 1069 Page 52 of 1069 Page 52 of 1069 Page 52 of 1069 ---PAGE BREAK--- Page 53 of 1069 Page 53 of 1069 Page 53 of 1069 Page 53 of 1069 ---PAGE BREAK--- Page 54 of 1069 Page 54 of 1069 Page 54 of 1069 Page 54 of 1069 ---PAGE BREAK--- Page 55 of 1069 Page 55 of 1069 Page 55 of 1069 Page 55 of 1069 ---PAGE BREAK--- Page 56 of 1069 Page 56 of 1069 Page 56 of 1069 Page 56 of 1069 ---PAGE BREAK--- Page 57 of 1069 Page 57 of 1069 Page 57 of 1069 Page 57 of 1069 ---PAGE BREAK--- Revision Date: 01-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: AIRLIFT FRESH SCENT (AEROSOL) Product Number: 6095 Recommended Use: Air freshener Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Signal Word: Danger Hazard Statements: Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 5 Liquefied gas Symbols: Page 58 of 1069 Page 58 of 1069 Page 58 of 1069 Page 58 of 1069 ---PAGE BREAK--- 6095 - AIRLIFT FRESH SCENT (AEROSOL) Revision Date: 01-May-2015 Other Information: • May cause skin irritation. • May cause eye irritation. • May be harmful if swallowed. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 N-butane 106-97-8 7-13 petroleum distillates 64742-47-8 5-10 propane 74-98-6 3-7 petroleum distillates 64742-88-7 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 5 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 59 of 1069 Page 59 of 1069 Page 59 of 1069 Page 59 of 1069 ---PAGE BREAK--- 6095 - AIRLIFT FRESH SCENT (AEROSOL) Revision Date: 01-May-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: Colorless Odor: Fresh pH: 6.0-8.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F (Product without propellant) Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: <1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.83 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 60 of 1069 Page 60 of 1069 Page 60 of 1069 Page 60 of 1069 ---PAGE BREAK--- 6095 - AIRLIFT FRESH SCENT (AEROSOL) Revision Date: 01-May-2015 Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 49213 mg/kg ATEmix (dermal): 20804 mg/kg ATEmix (inhalation-gas): 1669319 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h petroleum distillates 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h propane 74-98-6 Not Available Not Available = 658 mg/L ( Rat ) 4 h petroleum distillates 64742-88-7 > 5000 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) > 5.28 mg/L ( Rat ) 4 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea petroleum distillates 64742-47-8 Not Available 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h mykiss mg/L LC50 static Not Available 4720: 96 h Den-dronereides heteropoda mg/L LC50 petroleum distillates 64742-88-7 450: 96 h Pseudokirchneriella subcapitata mg/L EC50 800: 96 h Pimephales promelas mg/L LC50 static Not Available 100: 48 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Page 4 / 5 Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. Page 61 of 1069 Page 61 of 1069 Page 61 of 1069 Page 61 of 1069 ---PAGE BREAK--- 6095 - AIRLIFT FRESH SCENT (AEROSOL) Revision Date: 01-May-2015 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No California Proposition 65 This product does not contain any Proposition 65 chemicals 16. OTHER INFORMATION Revision Date: 01-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 2 Physical Hazards: 2 Page 62 of 1069 Page 62 of 1069 Page 62 of 1069 Page 62 of 1069 ---PAGE BREAK--- Revision Date: 29-Mar-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: AIRLIFT LEMON SCENT (BULK CONCENTRATE) Product Number: 3020 Recommended Use: Air freshener Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Skin Corrosion/Irritation: Category 2 Serious Eye Damage/Eye Irritation: Category 1 GHS Label Elements Signal Word: Danger Hazard Statements: Causes skin irritation. Causes serious eye damage Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Wear eye / face protection Wear protective gloves Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Skin IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Not Applicable Hazards Not Otherwise Classified: Page 1 / 5 Not Applicable Symbols: Page 63 of 1069 Page 63 of 1069 Page 63 of 1069 Page 63 of 1069 ---PAGE BREAK--- 3020 - AIRLIFT LEMON SCENT (BULK CONCENTRATE) Revision Date: 29-Mar-2015 Other Information: • May be harmful if swallowed. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 alcohol ethoxylate 68439-46-3 1-5 isopropanol 67-63-0 1-5 fragrance PROPRIETARY 1-5 citrus terpenes 68608-34-4 1-5 alkyl dimethyl benzyl ammonium chloride 68424-85-1 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. Page 2 / 5 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page 64 of 1069 Page 64 of 1069 Page 64 of 1069 Page 64 of 1069 ---PAGE BREAK--- 3020 - AIRLIFT LEMON SCENT (BULK CONCENTRATE) Revision Date: 29-Mar-2015 Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH isopropanol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Yellow Odor: Lemon pH: 6.0-8.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (BuAc = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.00 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 65 of 1069 Page 65 of 1069 Page 65 of 1069 Page 65 of 1069 ---PAGE BREAK--- 3020 - AIRLIFT LEMON SCENT (BULK CONCENTRATE) Revision Date: 29-Mar-2015 -Eye Contact: Pain, redness, swelling of the conjunctiva and tissue damage. Eye contact may cause permanent damage. -Skin Contact: Pain, redness and cracking of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: -Eyes. Respiratory System. -Skin. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 6183 mg/kg ATEmix (dermal): 14976 mg/kg ATEmix (inhalation-dust/mist): 3295.7 mg/l ATEmix (inhalation-vapor): 708 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available alcohol ethoxylate 68439-46-3 = 1378 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) Not Available isopropanol 67-63-0 = 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rat ) = 12870 mg/kg ( Rabbit ) = 72.6 mg/L ( Rat ) 4 h alkyl dimethyl benzyl ammonium chloride 68424-85-1 = 426 mg/kg ( Rat ) Not Available Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea isopropanol 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 9640: 96 h Pimephales promelas mg/L LC50 flow-through 11130: 96 h Pimephales promelas mg/L LC50 static 1400000: 96 h Lepomis macrochirus µg/L LC50 Not Available 13299: 48 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Page 4 / 5 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) Page 66 of 1069 Page 66 of 1069 Page 66 of 1069 Page 66 of 1069 ---PAGE BREAK--- 3020 - AIRLIFT LEMON SCENT (BULK CONCENTRATE) Revision Date: 29-Mar-2015 All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product contains the following listed substances: isopropanol CAS No 67-63-0 only if manufactured by the strong acid process, no supplier notification SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ethanol - 64-17-5 Carcinogen Developmental methyl eugenol - 93-15-2 Carcinogen acetaldehyde - 75-07-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 16. OTHER INFORMATION Revision Date: 29-Mar-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 2 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 2 Flammability: 0 Physical Hazards: 0 Page 67 of 1069 Page 67 of 1069 Page 67 of 1069 Page 67 of 1069 ---PAGE BREAK--- Revision Date: 18-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Product Number: 6085 Recommended Use: Air freshener Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Signal Word: Danger Hazard Statements: Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 5 Liquefied gas Symbols: Page 68 of 1069 Page 68 of 1069 Page 68 of 1069 Page 68 of 1069 ---PAGE BREAK--- 6085 - AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Revision Date: 18-May-2015 Other Information: • May cause skin irritation. • May cause eye irritation. • May be harmful if swallowed. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 N-butane 106-97-8 7-13 petroleum distillates 64742-47-8 5-10 propane 74-98-6 3-7 petroleum distillates 64742-88-7 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Move victim to fresh air If breathing is irregular or stopped, administer artificial respiration Administer oxygen if breathing is difficult -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 5 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 69 of 1069 Page 69 of 1069 Page 69 of 1069 Page 69 of 1069 ---PAGE BREAK--- 6085 - AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Revision Date: 18-May-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: Colorless Odor: Lemon pH: 6.0-8.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 78 °C / 172 °F (Product without propellant) Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.897 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 70 of 1069 Page 70 of 1069 Page 70 of 1069 Page 70 of 1069 ---PAGE BREAK--- 6085 - AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Revision Date: 18-May-2015 Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 49213 mg/kg ATEmix (dermal): 20804 mg/kg ATEmix (inhalation-gas): 1669319 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h petroleum distillates 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h propane 74-98-6 Not Available Not Available = 658 mg/L ( Rat ) 4 h petroleum distillates 64742-88-7 > 5000 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) > 5.28 mg/L ( Rat ) 4 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea petroleum distillates 64742-47-8 Not Available 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h mykiss mg/L LC50 static Not Available 4720: 96 h Den-dronereides heteropoda mg/L LC50 petroleum distillates 64742-88-7 450: 96 h Pseudokirchneriella subcapitata mg/L EC50 800: 96 h Pimephales promelas mg/L LC50 static Not Available 100: 48 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Page 4 / 5 Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. Page 71 of 1069 Page 71 of 1069 Page 71 of 1069 Page 71 of 1069 ---PAGE BREAK--- 6085 - AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Revision Date: 18-May-2015 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No California Proposition 65 This product does not contain any Proposition 65 chemicals 16. OTHER INFORMATION Revision Date: 18-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 2 Physical Hazards: 2 Page 72 of 1069 Page 72 of 1069 Page 72 of 1069 Page 72 of 1069 ---PAGE BREAK--- M a t e r i a l S a f e t y D a t a S h e e t Ajax Dual Action Clean and Ajax Bleach Alternative Regular/HE Heavy Duty Liquid Detergent; All Sizes Page 1 of 5 Rev. Date 03/11/13 SECTION #1 – PRODUCT AND COMPANY IDENTIFICATION Product: Ajax Dual Action Clean & Ajax Bleach Alternative Regular/HE Heavy Duty Liquid Detergent; All Sizes Phoenix Brands Consumer Service Telephone Number: 1-[PHONE REDACTED] 2855 N. Franklin Rd., #7 Emergency Contact: PROSAR IPC; 1-[PHONE REDACTED] Indianapolis, Indiana 46219 USA Emergency Phone Number: 1-[PHONE REDACTED] Product Description: A water-soluble 2X concentrated consumer liquid laundry detergent. SECTION #2 – COMPOSITION, INFORMATION ON INGREDIENTS INGREDIENTS: Contains cleaning and sudsing agents. EXPOSURE LIMITS IN AIR* ACGIH OSHA CHEMICAL NAME CAS # TLV STEL PEL STEL mg/m3 mg/m3 mg/m3 mg/m3 Linear ethoxylated alcohol 68951-67-7 NA NA Sodium carbonate 497-19-8 NA NA Sodium laureth sulfate 9004-82-4 NA NA Taurus 134 soap Mixture NA NA Tris(N-Hydroxyethyl) Hexahydrotriazine 4719-04-4 NA NA NA = Not Applicable See Section #16 for DEFINITION OF TERMS SECTION #3 – HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: CAUTION: Keep out of reach of children. Do not mix with chlorine bleach or other household cleaning products. If product contacts eye, rinse thoroughly with water. If swallowed, drink a glass of water to dilute. Material may be slippery if spilled. Route of Exposure - Inhalation While inhalation of a product mist is unlikely, such exposure may cause transient upper respiratory irritation. Route of Exposure - Skin No irritation when used according to directions. Possible irritation from prolonged contact to industrial amounts. Route of Exposure - Eyes Causes irritation on direct contact. Route of Exposure - Ingestion May be harmful if swallowed in large quantities. Page 73 of 1069 Page 73 of 1069 Page 73 of 1069 Page 73 of 1069 ---PAGE BREAK--- M a t e r i a l S a f e t y D a t a S h e e t Ajax Dual Action Clean and Ajax Bleach Alternative Regular/HE Heavy Duty Liquid Detergent; All Sizes Page 2 of 5 Rev. Date 03/11/13 SECTION #4 – FIRST AID MEASURES First Aid - Inhalation Give the subject access to fresh air. If do not resolve quickly, seek medical assistance. First Aid - Skin Rinse with water. If skin irritation occurs in use, seek medical assistance. First Aid - Eyes Flush affected areas with water for at least 15 minutes. Seek medical assistance if required. First Aid - Ingestion Drink 1-2 glasses of water. Seek medical attention. Note: If persist, seek medical attention. SECTION #5 – FIRE FIGHTING MEASURES Flash Point: > 200°F (93°C) Autoignition Temperature: Not applicable Flammable Limits (in air, by volume Not applicable Fire and Explosion Hazards Product is not flammable. Use appropriate fire extinguishing agent for the packaging material. Extinguishing Media Water Spray: Yes Carbon Dioxide: Yes Foam: Yes Dry Chemical: Yes Halon: Yes Special Fire Fighting Instructions None. Product is not combustible. Use appropriate fire extinguishing agent for the packaging material. SECTION #6 – ACCIDENTAL RELEASE MEASURES Steps to be Taken in The Event of Spills, Leaks, or Release Disposal is to be performed in compliance with applicable laws. Small or household quantities may be disposed of in refuse or sewer. For large (industrial) releases, cover with inert, absorbent material and remove to disposal container. Material may be slippery if spilled. Flush with plenty of water. Waste Disposal Methods Dispose of unused containers of product in accordance with applicable Federal, State/Provincial, and local regulations. Page 74 of 1069 Page 74 of 1069 Page 74 of 1069 Page 74 of 1069 ---PAGE BREAK--- M a t e r i a l S a f e t y D a t a S h e e t Ajax Dual Action Clean and Ajax Bleach Alternative Regular/HE Heavy Duty Liquid Detergent; All Sizes Page 3 of 5 Rev. Date 03/11/13 SECTION #7 – HANDLING AND STORAGE Work Practices and Hygiene Practices: Use personal protective equipment appropriate for the task. Storing and Handling Practices: Store in a closed container in a cool, dry, well-ventilated area. Protective Practices During Maintenance Or Contaminated Equipment: Use personal protective equipment when contact is likely. SECTION #8 – EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation Use with adequate ventilation. Mechanical ventilation is not required under normal conditions of use. Eye Protection Wear eye protection. Skin Protection Skin protection is not normally required. If gloves are desired for protection against irritation, water- impervious types (e.g. rubber, PVA, or nitrile) are recommended. Respiratory Protection Respiratory protection is not normally required. If this product is used in a manner that generates airborne mist not controlled by ventilation, wear a NIOSH-approved respirator with filters for protection against dusts (type N95 or better). For guidance on the selection and use of respiratory protection, consult American National Standard Z88.2-1992 (ANSI, New York, NY 10036 USA). SECTION #9 – PHYSICAL AND CHEMICAL PROPERTIES pH solution): 10.0 – 11.0 Appearance: This liquid is a blue solution. SECTION #10 – STABILITY AND REACTIVITY Conditions to Avoid This product is stable when maintained at room temperature. Incompatible Materials Avoid contact with acids and strong oxidizing agents. Page 75 of 1069 Page 75 of 1069 Page 75 of 1069 Page 75 of 1069 ---PAGE BREAK--- M a t e r i a l S a f e t y D a t a S h e e t Ajax Dual Action Clean and Ajax Bleach Alternative Regular/HE Heavy Duty Liquid Detergent; All Sizes Page 4 of 5 Rev. Date 03/11/13 SECTION #10 – STABILITY AND REACTIVITY CONTINUED… Hazardous Decomposition Products May produce irritating and/or toxic fumes upon thermal decomposition. Hazardous polymerization will not occur. SECTION #11 – TOXICOLOGICAL INFORMATION This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the MSDS. SECTION #12 – ECOLOGICAL INFORMATION No data available. The product is not expected to present an environmental hazard. SECTION #13 – DISPOSAL CONSIDERATIONS Dispose of unused containers of product in accordance with applicable Federal, State/Provincial, and local regulations. Empty containers should be triple rinsed before disposal. SECTION #14 – TRANSPORTATION INFORMATION This product is not regulated as a DOT hazardous material. HMIS HAZARD RATING (Least=0 Slight=1 Moderate=2 High=3 Extreme=4) Ajax Bleach Alternative OXI HE Heavy Duty Liquid Detergent: 3 SECTION #15 – REGULATORY INFORMATION RCRA (40 CFR 261, Subpart Not Applicable. CLEAN WATER ACT: Not Applicable. CLEAN AIR ACT: Contains methanol which is a Section 111 material. Methanol is also a Section 112 material. SARA; Sections 301-304 (Threshold planning quantity – TPQ) 40 CFR 355: No TPQ for any component. Section 313 (Toxic chemical release reporting) 40 CFR 372: The following chemicals must be reported under SARA 313: Not Applicable. CERCLA: Section 102 (Reportable Quantity – RQ) 40 CFR 302: Not Applicable Page 76 of 1069 Page 76 of 1069 Page 76 of 1069 Page 76 of 1069 ---PAGE BREAK--- M a t e r i a l S a f e t y D a t a S h e e t Ajax Dual Action Clean and Ajax Bleach Alternative Regular/HE Heavy Duty Liquid Detergent; All Sizes Page 5 of 5 Rev. Date 03/11/13 SECTION #15 – REGULATORY INFORMATION CONTINUED… New Jersey Right to Know Hazardous Substance List: This product contains the following components subject to reporting requirements: Methanol. Hazardous Substance List: This product contains the following components subject to reporting requirements: Methanol, sodium sulfate. Massachusetts Substance List: This product contains the following components subject to reporting requirements: Methanol, sodium sulfate. Canada: Workplace Hazardous Materials Information System (WHMIS): This product contains the following components subject to reporting requirements: Sodium carbonate. TSCA Section 8(b) Inventory Status: All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory. SECTION #16 – OTHER INFORMATION – DEFINITON OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following: CAS This is the Chemical Abstract Service Number which uniquely identifies each constituent. It is used for computer-related searching. EXPOSURE LIMITS IN AIR: ACGIH – American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits. TLV – Threshold Limit Value – an airborne concentration of a substance which represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit (STEL), and the instantaneous Ceiling Limit. Skin adsorption effects must also be considered. OSHA – U. S. Occupational Safety and Health Administration. PEL – Permissible Exposure Limit – this exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). LEL – the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL – the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. DISCLAIMER OF EXPRESS AND IMPLIED WARRANTIES The foregoing data has been compiled from sources that the company, in good faith, believes to be dependable and is accurate and reliable to the best of our knowledge and belief. However, the company cannot make any warranty or representation respecting the accuracy or completeness of the data, and assumes no responsibility for any liability or damages relating thereto or for advising you regarding the protection of your employees or others. Users should make their own tests to determine the applicability of such information or the suitability of any products for specific use. Page 77 of 1069 Page 77 of 1069 Page 77 of 1069 Page 77 of 1069 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: AJAX SPRAY N WIPE TRIPLE ACTION GLASS CAS Number: Manufacturer: Colgate-Palmolive Pty Ltd SDS Date: 10/1/2012 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=ds%2bThuSl7VE%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 78 of 1069 Page 78 of 1069 Page 78 of 1069 Page 78 of 1069 ---PAGE BREAK--- Page 1 of 7 MSDS for #23884 - ALEENES TACKY GLUE Page 1 of 7 Safety Data Sheet 1. COMPANY AND PRODUCT IDENTIFICATION iLoveToCreate A Duncan Enterprises Company 5673 East Shields Avenue Fresno, CA 93727 [PHONE REDACTED] [PHONE REDACTED] (Fax) EMERGENCY TELEPHONE NUMBERS Health Emergencies: [PHONE REDACTED] 7:00 am – 3:30 pm Pacific Std. Time Spill and Off-Hour Health Emergencies: [PHONE REDACTED] U.S. and Canada [PHONE REDACTED] Outside U.S. and Canada (Collect) Product Name: ALEENE’S ORIGINAL TACKY GLUE Product Description: Water-Based Adhesive 2. HAZARDS IDENTIFICATION HMIS Hazard Ratings for Product Health 1 Flammability 0 Reactivity 0 Personal Protection See Section 8 Rating Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic Effects Emergency Overview Not considered as hazardous Eye Contact: Slight / mild irritant Skin Contact: Repeated or prolonged skin contact may result in mild irritation Inhalation: Vapor may be an irritant to respiratory tract Ingestion: Ingestion may cause irritation of the gastrointestinal tract 3. COMPOSITION / INGREDIENT INFORMATION Chemical Family: Water based polymer emulsion Component CAS Number Concentration % None Hazardous None None 4. FIRST AID MEASURES Eye Contact: Flush eyes with large amounts of water until irritation subsides. Consult a physician if irritation persists. Skin Contact: Wash affected skin areas thoroughly with soap and water. Remove contaminated clothing. Consult a physician if irritation persists. Inhalation: Move subject to fresh air. If breathing is difficult, give oxygen. Consult a physician if persist. Ingestion: Rinse out mouth. Drink 1-2 glasses of water. DO NOT induce vomiting. If develop and persist, get medical attention. Treat and supportively. Get medical attention. DO NOT attempt to give anything by mouth to an unconscious person. Item Numbers: 23884-1004, 23884-1008, 23884-1016 Page 1 of 7 Page 79 of 1069 Page 79 of 1069 Page 79 of 1069 Page 79 of 1069 ---PAGE BREAK--- Page 2 of 7 MSDS for #23884 - ALEENES TACKY GLUE iLoveToCreate Safety Data Sheet – Aleene’s Original Tacky Glue Page 2 of 7 5. FIRE FIGHTING MEASURES Autoignition Temperature: Not Available Flash Point: No flash point up to 100°C. Aqueous preparation. Upper Explosive Limit Not Applicable Lower Explosive Limit Not Applicable Extinguisher Media: Use extinguishing measures appropriate to local circumstances and the surrounding environment. Water spray or fog foam carbon dioxide. Dry chemical. Special Firefighting Procedures: Fire fighters should be equipped with self- contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: This is a water-based product and presents no particular fire or explosion hazard. Dry polymer film may pose a moderate fire hazard. Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Hazardous Combustion Products: Under decomposition, this product emits carbon monoxide, carbon dioxide, and/or low molecular weight hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Spill or Leak Procedures: Absorb spillages with vermiculite, clay, or other suitable non- biodegradable absorbent material. Sweep up and shovel into waste drums. Wash the spillage area with water. Washings must be prevented from entering surface water drains. Follow all local, state, federal, and provincial regulations for disposal. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. 7. HANDLING AND STORAGE Storage: For safe storage, store between 5°C (41°F) and 37°C (98.6°F). Keep the container closed and in a cool, well-ventilated place. Protect from freezing. Handling: Wash thoroughly after handling. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Do not taste or swallow. Keep container closed. Item Numbers: 23884-1004, 23884-1008, 23884-1016 Page 2 of 7 Page 80 of 1069 Page 80 of 1069 Page 80 of 1069 Page 80 of 1069 ---PAGE BREAK--- Page 3 of 7 MSDS for #23884 - ALEENES TACKY GLUE iLoveToCreate Safety Data Sheet – Aleene’s Original Tacky Glue Page 3 of 7 8. EXPOSURE CONTROL AND PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AKHA WEEL OTHER None None None None None Conditions Under Which Personal Protective Equipment Required: Normal work conditions, maintenance / repair Engineering Controls: Work should be done in an adequately ventilated area ventilation sufficient to effectively prevent buildup of vapor/fume/dust, appropriate NIOSH/MSHA respiratory protection must be provided. Eye Protection Requirements: Wear safety glasses with side shields; protect against splashing. Do not wear contact lenses. Respirator Requirements: None required under normal handling conditions. Use NIOSH approved respirator if vapor or mist levels are irritating. Ventilation Requirements: General Skin Protection: Use of protective coveralls and long sleeves is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Pure Material or Mixture: Mixture Physical Form: Liquid Appearance / Physical Description: White liquid pH: 4.5 Boiling Point: Approx. 100o C (212 F) Melting / Freezing Point: < 5oC 41 F) Odor Threshold: Not Available Solubility in Water: Miscible Partition Coefficient (n-octanol/water): Not Applicable Specific Gravity (Water = 1.08 Volatiles: Not available Vapor Pressure: Not determined Evaporation Rate (Water = Not determined Vapor Density (Air = Not determined Volatile Organic Compounds: Not available Autoignition Temperature: Unknown Flash Point: No flash point up to 100o C (212 F) Oxidizing Properties: Not Applicable 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions Materials to Avoid: Strong oxidizers, materials that react with water NFPA Reactivity Class: 0 = Insignificant Conditions to Avoid: Protect from freezing Hazardous Decomposition Products: Oxides of carbon. Thermal decomposition can lead to release of irritating gases and vapors. Item Numbers: 23884-1004, 23884-1008, 23884-1016 Page 3 of 7 Page 81 of 1069 Page 81 of 1069 Page 81 of 1069 Page 81 of 1069 ---PAGE BREAK--- Page 4 of 7 MSDS for #23884 - ALEENES TACKY GLUE iLoveToCreate Safety Data Sheet – Aleene’s Original Tacky Glue Page 4 of 7 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) None None None None Hazardous components Health Effects/Target Organs None None 12. ECOLOGICAL INFORMATION Ecological Information: No data available 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Waste Disposal Methods: Legal disposition of wastes is the responsibility of the owner/generator of the waste. Waste disposal should be in accordance with existing Federal, State, and Local environmental regulations. Hazardous Waste Number: The product is not listed or does not meet the criteria of hazardous waste is discarded in its purchased form. However, under RCRA, it is the responsibility of the user to determine at the time of disposal whether a product meets any of the RCRA hazardous waste criteria. Product uses, transformations, mixtures processes, etc., may render the resulting material hazardous, under the criteria of ignitability, corrosivity, reactivity, and toxicity characteristics under the new Toxicity Characteristics Leaching Procedure (TCLP) 40 code of Federal Regulations 261.20-24. 14. TRANSPORT INFORMATION U.S. Department of Transportation Information DOT Shipping Name: Not regulated DOT Hazard Class: None DOT Identification Number: None DOT Packing Group: None International Air Transportation Information ICAO/IATA Shipping Name: Not regulated ICAO/IATA Hazard Class: None ICAO/IATA Identification Number: None ICAO/IATA Packing Group: None Water Transportation IMO/IMDG Shipping Name: Not regulated IMO/IMDG Hazard Class: None IMO/IMDG Identification Number: None IMO/IMDG Packing Group: None Item Numbers: 23884-1004, 23884-1008, 23884-1016 Page 4 of 7 Page 82 of 1069 Page 82 of 1069 Page 82 of 1069 Page 82 of 1069 ---PAGE BREAK--- Page 5 of 7 MSDS for #23884 - ALEENES TACKY GLUE iLoveToCreate Safety Data Sheet – Aleene’s Original Tacky Glue Page 5 of 7 15. REGULATORY INFORMATION TSCA 8 All components are on the TSCA Inventory TSCA 12 None above reporting de minimus CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. SARA/Title III: This product contains no substances at or above the reported threshold under Section 313, based on available data. Products bearing the Nontoxic Product Seal are certified in a program of toxicological evaluation by a nationally recognized toxicologist to contain no materials in sufficient quantities to be toxic or injurious to humans or to cause acute or chronic health problems. These products are certified to be labeled in accordance with the voluntary chronic hazard labeling standard ASTM D-4236. In addition, there is no physical hazard as defined within 29 CFR Part 1910.1200(c). CALIFORNIA PROPOSITION 65 WARNING: This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm. 16. OTHER INFORMATION Table of Abbreviations ACGIH American Conference of Governmental Industrial Hygienists ANSI American National Standards Institute ASTM American Society for Testing Materials C Degrees Centigrade CAS Chemical Abstract Service CERCLA Comprehensive Environmental Response, Compensation and Liability Act CFR Code of Federal Regulations CPR Controlled Products Regulations DOT Department of Transportation EPA Environmental Protection Agency F Degrees Fahrenheit FDA Food & Drug Administration g / l Grams per liter DOT Department of Transportation EPA Environmental Protection Agency F Degrees Fahrenheit FDA Food & Drug Administration g / l Grams per liter Hg Mercury HMIS Hazardous Materials Identification System IARC International Agency for Research on Cancer LD Lethal Dose mg / kg Milligram per kilogram mm Millimeter SDS Safety Data Sheet MSHA Mine Safety and Health Administration Item Numbers: 23884-1004, 23884-1008, 23884-1016 Page 5 of 7 Page 83 of 1069 Page 83 of 1069 Page 83 of 1069 Page 83 of 1069 ---PAGE BREAK--- Page 6 of 7 MSDS for #23884 - ALEENES TACKY GLUE iLoveToCreate Safety Data Sheet – Aleene’s Original Tacky Glue Page 6 of 7 16. OTHER INFORMATION (Continued) Table of Abbreviations (Continued) CFR Code of Federal Regulations CPR Controlled Products Regulations DOT Department of Transportation EPA Environmental Protection Agency F Degrees Fahrenheit FDA Food & Drug Administration g / l Grams per liter DOT Department of Transportation EPA Environmental Protection Agency F Degrees Fahrenheit FDA Food & Drug Administration g / l Grams per liter Hg Mercury HMIS Hazardous Materials Identification System IARC International Agency for Research on Cancer LD Lethal Dose mg / kg Milligram per kilogram mm Millimeter SDS Safety Data Sheet MSHA Mine Safety and Health Administration N / A Not Applicable NFPA National Fire Protection Association NIOSH National Institute for Occupational Safety and Health NTP National Toxicology Program OSHA Occupational Safety and Health Administration ppm Parts per million SARA Superfund Amendment and Reauthorization Act STEL Short-Term Exposure Limit TSCA Toxic Substances Control Act TWA Time - Weighted Average U.N. United Nations WHMIS Workplace Hazardous Materials Information System > Greater Than < Less Than Item Numbers: 23884-1004, 23884-1008, 23884-1016 Page 6 of 7 Page 84 of 1069 Page 84 of 1069 Page 84 of 1069 Page 84 of 1069 ---PAGE BREAK--- Page 7 of 7 MSDS for #23884 - ALEENES TACKY GLUE iLoveToCreate Safety Data Sheet – Aleene’s Original Tacky Glue Page 7 of 7 16. OTHER INFORMATION (Continued) Creation Date: 04/06/93 Revision Date: 07/29/13 Technical Contact: Frank Peters Research & Development Manager iLoveToCreate A Duncan Enterprises Company 5673 East Shields Avenue Fresno, CA 93727 [PHONE REDACTED] [PHONE REDACTED] (Fax) Disclaimer The information given and the recommendations made herein apply to our product(s) alone and not combined with any other product(s). Such are based on our research and on data from other reliable sources and are believed to be accurate. No guarantee of accuracy is made. It is the purchaser’s responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their purposes. Item Numbers: 23884-1004, 23884-1008, 23884-1016 Page 7 of 7 Page 85 of 1069 Page 85 of 1069 Page 85 of 1069 Page 85 of 1069 ---PAGE BREAK--- Section 1 Product Description Safety Data Sheet Alpet D2 Surface Sanitizer Wipes Product Name: Recommended Uses: Synonyms: Distributor: Chemical Information Emergency: Alpet D2 Surface Sanitizer Wipes RTU Surface Sanitizer Sanitizer Wipes Best Sanitizers, Inc. PO Box 1360 Penn Valley, CA 95946 Chemtrec 1.[PHONE REDACTED] OSHA Regulatory Status--This chemical is considered hazardous by the 2012 OSHA Hazard Communication, 29 CFR §1910.1200: This material is an EPA Registered Disinfectant for industrial, institutional and consumer use that is safe for consumers with intended and reasonable foreseeable use. Please follow label directions. NOTE: Warnings below are for exposure to large quantities of the product. Normal usage should not create hazardous conditions. Flammable liquids Category 3 Danger Hazard Statements Causes serious eye irritation. Flammable liquid and vapor. Maybe be harmful if swallowed. Precautionary Statements—Prevention Appearance—Aqueous solution Physical state—Liquid Odor— Alcohol Odor Keep away from heat/sparks/open flames/hot surfaces-----No Smoking. Do not use in eyes. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Precautionary Statements—Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin (hair) with water/shower. In case of fire: Use CO2, dry chemical, or foam for extinction. Precautionary Statements—Storage Stored in a well-ventilated place. Keep Cool. Section 2 Hazard Identification Page 86 of 1069 Page 86 of 1069 Page 86 of 1069 Page 86 of 1069 ---PAGE BREAK--- Safety Data Sheet Precautionary Statements—Disposal Dispose of contents/container to an approved waste disposal plant. Hazards not otherwise classified (HNOC) Not Applicable Other Information Unknown Acute Toxicity Ingredients considered hazardous as defined by OSHA, 29 CFR 1910.1200, WHMIS under the HPA (Canada), Chemical Name CAS No. Weight-% Isopropyl Alcohol 67-63-0 55-75 First Aid Measures Eye Contact Skin Contact Hold eye(s) open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing eye(s). If eye irritation persists: Get medical advice/attention. For accidental exposure to large quantities, wash off immediatelywith soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation develops. Inhalation Remove to fresh air. Immediate medical attention is not required. Ingestion Do NOT induce vomiting. Ingestion of large amounts can cause drowsiness, unconsciousness or cramps. Drink plenty of water. Never give anything by mouth to an unconscious person. Call physician. Most important and effects, both acute and delayed See Section 11 for information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat Suitable Extinguishing Media Dry Chemical, Waterspray (fog), Carbon dioxide (CO2), Foam. Unsuitable Extinguishing Media No Information available. Specific hazards arising from the chemical Flammable. Vapors may travel to source of ignition and flash back. Hazardous combustion products Explosion Data Sensitivityto Mechanical Impact Sensitivityto Static Discharge Carbon Monoxide. Carbon Dioxide (CO2). None May be ignited by friction, heat, sparks or flames. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective Section 5 Fire-Fighting Measures Remaining ingredients are non-hazardous and/or present at amounts below reportable limits and considered confidential. Section 4 First Aid Measures Section 3 Composition/Information on Ingredients Page 87 of 1069 Page 87 of 1069 Page 87 of 1069 Page 87 of 1069 ---PAGE BREAK--- Safety Data Sheet gear. Cool containers with flooding quantities of water until well after fire is out. Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Use personal protection recommended in Section 8. Ensure adequate ventilation, especially in confined areas. For emergency responders Isolate area. Keep unnecessary personnel away. Environment Precautions Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (See Section 13). Methods for cleaning up Use clean non-sparking tools to collect absorbed material. May be ignited by friction, heat, sparks or flames. Collect spillage. Soak up with inert absorbent material,. Sweep up and shovel into suitable containers for disposal. Following product recovery, flush area with water. Precautions for Safe Handling Advice on Safe Handling Keep away from heat sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Do not eat, drink or smoke when using this product. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Use only in well-ventilated areas. Avoid breathing vapors or mists. Wash thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials Keep Containers closed in a dry, cool and well-ventilated place. Keep from freezing. Keep away from heat, sparks, flame and other sources of ignition(i.e., pilot lights, electric motors and static electricity). Store between 40 to 100˚F. Heat, sparks, open flame, other ignition sources. Reacts violently with strong oxidants such as nitric acid and silver nitrate causing fire and explosion hazard. Reacts slowly with calcium hypochlorite and ammonia causing fire and explosion hazard. Section 7 Handling and Storage Section 6 Accidental Release Measures Page 88 of 1069 Page 88 of 1069 Page 88 of 1069 Page 88 of 1069 ---PAGE BREAK--- Safety Data Sheet Exposure Guidelines Chemical Name ACGIHTLV OSHA PEL NIOSH IDLH Isopropyl alcohol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 ppm (vacated)STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 Appropriate Engineering Controls Engineering Controls Showers, eyewash stations, ventilation system. Individual Protection Measures, such as personal protective equipment Eye/Face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective NeopreneTM gloves. Rubbergloves. Normal work clothing (long sleeved shirt and long pants is recommended). Apron is recommended. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Wash face, hands and any exposed skin thoroughly after handling. Wash contaminated clothing and shoes before reuse. Do not Eat, Drink or Smoke when using this product. Information on basic physical and chemical properties Formula: Odor: See Section 3 Alcohol Smell Physical State: Appearance: Liquid Aqueous solution Odor Threshold: Property pH Melting Point/Freezing Point Boiling Point/ Boiling Range Flash Point Evaporation rate Flammability (solid, gas) No Information Available Color: Values 5.0-7.0 No Information 180˚F 21.49 ˚C / 70.68˚F No information available No information available Clear Remarks— Method ±1 @21˚C Section 9 Physical and Chemical Properties Section 8 Protection Information Page 89 of 1069 Page 89 of 1069 Page 89 of 1069 Page 89 of 1069 ---PAGE BREAK--- Safety DataSheet Flammability Limit in Air Upper flammability limit: 12.7% Lower flammability limit: Vapor pressure: Vapor density: Specific Gravity Water solubility Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Oxidizing properties 2.0% 30mm Hg @ 20 ˚C No information available 0.89 Soluble in water No information available No information available No information available No information available No information available No information available No information available Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to avoid Incompatible materials Hazardous Decomposition Products No data available. Stable under recommended storage conditions. None under normal processing. Heat, flames and sparks, extreme temperature conditions Heat, sparks, open flame, other ignition sources. Carbon monoxide. Carbon dioxide (CO2). Nitrogen. Information on likely routes of exposure Product Information Inhalation Eye Contact Skin Contact Ingestion Inhalation of vapors in high concentration maycause irritation of respiratory system. Irritating to eyes. No irritant under normal use. May be harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Water, 7732-18-5 > 90 mL/kg (Rat) - - Isopropyl alcohol 67-63-0 = 4396 mg/kg (Rat) = 12800 mg/kg (Rabbit) = 16000 ppm (Rat) 8 h Section 11 Toxicity Data Section 10 Stability and Reactivity Data Page 90 of 1069 Page 90 of 1069 Page 90 of 1069 Page 90 of 1069 ---PAGE BREAK--- Safety Data Sheet Information on toxicological effects No Information Available Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No Information Available Germ cell mutagenicity No Information Available Carcinogenicity IARC: Group 3 (Not classifiable as to its carcinogenicity to humans). Reproductive toxicity No Information Available STOT single exposure No Information Available STOT repeated exposure No Information Available Aspiration hazard No Information Available Numerical measures of toxicity –Product Information Unknown Acute Toxicity <0.5% of the mixture consists of direct food additives and 150 ppm of material of unknown toxicity. The following values are calculated based on Chapter 3.1 of the GHS document ATE mix (dermal) ATE mix(inhalation-vapor 21843mg/kg mg/l NA (Isopropanol Inhalation LC 50 = 16,000 ppm Rat 8 hours) Ecotoxicity <0.5% of the mixture consists of components(s) of unknow hazards to the aquatic environment. Chemical Name Algae/Aquatic Plants Fish Crustacea Isopropyl alcohol 67-63-0 1000: 96 h Desmodesmussubspicatus mg/L EC50 1000: 72 h Desmodesmussubspicatus mg/L EC50 9640: 96 h Pimephales promelas mg/L LC50 flow-through 11130: 96 h Pimephales promelas mg/L LC50 static 1400000: 96 h Lepomis macrochirus µg/L LC50 13299: 48 h Daphnia magna mg/L EC50 Section 12 Ecological Data Page 91 of 1069 Page 91 of 1069 Page 91 of 1069 Page 91 of 1069 ---PAGE BREAK--- Safety Data Sheet Persistence and degradability No Information Available. Bioaccumulation Chemical Name Partition Coefficient Isopropyl alcohol 67-63-0 0.05 Mobility No information available. Other adverse effects No information available Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Dispose of in accordance with federal, state and local regulations. Chemical Name California Hazardous Waste Status Isopropyl alcohol 67-63-0 Toxic Ignitable DOT UN/ID No. Proper shipping name Hazard Class Packing Group 1219 Isopropanol Flammable liquids 3 II Limited Quantities for packages under 1 Liter Exempt DOT-SP 9275 for packages under 1 gallon Section 14 Transport Information Section 13 Disposal Information Page 92 of 1069 Page 92 of 1069 Page 92 of 1069 Page 92 of 1069 ---PAGE BREAK--- Safety DataSheet Section 15 Regulatory Information International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies Legend: TSCA—United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL— Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS—European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Note: Isopropyl alcohol only needs to be reported if it is being manufactured by the strong acid process. Facilities that process or otherwise use isopropyl alcohol are NOT covered and should NOT file a report. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substance regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substance regulated as a hazardous substance under the Comprehensive Environment Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local regional or state level pertaining to releases of this material. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Isopropyl alcohol 67-63-0 X X X U.S. EPA Label Information EPA Pesticide Registration Number 73232-2 This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label includes other important information, including directions for use. Page 93 of 1069 Page 93 of 1069 Page 93 of 1069 Page 93 of 1069 ---PAGE BREAK--- Safety DataSheet NFPA Health Hazards Flammability Instability Physical and Chemical Properties 2 3 0 None HMIS Health Hazards Flammability Physical Hazards Personal protection 2 3 0 B (safety glasses, gloves) Prepared by: Technical Department Revision Date January 15, 2015 Version 0 Revision Note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the d ate of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet LS 104-222-00.004 Section 16 Additional Information Page 94 of 1069 Page 94 of 1069 Page 94 of 1069 Page 94 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET wax 4 s o F E s s , o N m Product name: Alpha HP Bathroom Disinfectant Cleaner (154 use solution) ~ - - - - - - - ~ l ~ h a HP Bathroom Disinfectant Cleaner (1 :64 use solution) HMlS 11 NFPA (1 Personal protective equipment MSDS t: Product code: Recommended use: MS0100708D MSOl00708D Disinfectant Cleaner. m None / Aucune / Ninguno lei Health Fire Hazard Reactivity Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, W~sconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com L Version Number 1 Pre~aration date: 2007-03-08 0 0 (I Emergency telephone number: 1-800-851 -71 45 (Prosar); 1-651 -91 7-61 33 (Int'l Prosar); 01 -800-71 0-3400 (Mexico) he product contains no substances which at their given concentration, are considered to be hazardous to health. Principle routes of exposure: Eye contact. Skin contact. Inhalation. Ingestion Eye contact: None known. Skin contact: None known. Inhalation: None known. Ingestion: None known. Hazardous components None .Tf*C, . . . ' . . - ; - . 7' 5 : LA- - 3 . , . : ~I$~RBP&[@;~~EA~~JRES \ Eye contact: Rinse with plenty of water. Skin contact: Rinse with plenty of water. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. Suitable extinguishing media: Dry chemical, water spray, foam, carbon dioxide Specific hazards: Not applicable Unusual hazards: None known Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHAlNlOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available Personal precautions: Envlronmental precautions and clean-up methods: Not applicable. Use appropriate containment to avoid environmental contamination. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Keep in suitable and closed containers for disposal. Use a water rinse for final clean-up. Alpha HP Bathroom Disinfectant Cleaner (1:64 use solution) l o f 3 Page 95 of 1069 Page 95 of 1069 Page 95 of 1069 Page 95 of 1069 ---PAGE BREAK--- I 7. AND STORAGE Handling: Handle in accordance with good industrial hygiene and safety practice. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. Engineering measures to reduce exposure: No special ventilation requirements. Personal Protective Eauipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Physical State: Liquid pH: 2.3 Appearance: Aqueous solution Color: Colourless Odor: Citrus Specific gravity: 1.033 Density: No information available. VOC: 0.125% Flash point: >2OO0F >93.3"C Solubility: Soluble Viscosity: No information available Bulk density: Dilution pH: Vapor density: Evaporation Rate Boiling pointlrange: Melting pointlrange: Decomposition temperature: Autoignition temperature: No information available 2.3 (1 :64) No information available No information available Not determined Not determined Not determined No information available Partition coefficient (n-octanollwater): No information available Solubility in other solvents: No information available Elemental Phosphorus: 0.02 %P ' - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: Oxidising agents. Conditions to avoid: Do not freeze. Acute toxicity Component Information: Chronic toxicity: s- Carcinogenic effects: Mutagenic eflects: Reproductive toxicity: Target organ effects: Oral LD50 estimated to be greater than 5000 Dermal LD50 estimated to be > 2000 See Section 3 None known None known None known None known None known Environmental Information: No data available Do not contaminate water, food, or feed by storage or disposal Pesticide Storage: Do not reuse empty container. Keep from freezing. Alpha HP Bathroom Disinfectant Cleaner (1:64 use solution) Page 96 of 1069 Page 96 of 1069 Page 96 of 1069 Page 96 of 1069 ---PAGE BREAK--- Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper dlsposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container Disposal: Triple rinse (or equiv;3lent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incinerate, or, if allowed by State and local authorities burn. If burned, stay out of smoke. I- 14. TRANSPORT sINF.C)RMATION DOTKDG: Please refer to the Bill of Ladinglreceiving documents for up to date shipping information International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSLINDSL). Australia (AICS), Korea (ECL), Philippines (PICCS), China (IEC:SC). U.S. Requlations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 CERCLAI SARA None SARA 31 11312 Hazard Cateaories Immediate: Delayed: Flre: Reactivity: Sudden Release of Pressure: Reason for revision: Prepared by: Additional advice: Not applicable NAPRAC None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond selleh control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Alpha HP Bathroom Disinfectant Cleaner (1:64 use solution) Page 97 of 1069 Page 97 of 1069 Page 97 of 1069 Page 97 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Applause Hand Sanitizer PAGE 1 of 3 QuestVapco Corporation P.O. Box 624 Brenham, TX 77834 Emergency Phone Number: (800) 231-0454 DATE PREPARED: May 26, 2013 REVISION DATE: 5/26/2013 CHEM-TEL: [PHONE REDACTED] PRODUCT NUMBER: 6930 SECTION I - IDENTIFICATION PRODUCT NAME: Applause Hand Sanitizer PRODUCT CODE: 6930 PRODUCT USE: Hand Sanitizer SECTION II – COMPOSITION/HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER OSHA PEL ACGIH TLV Ethyl Alcohol 75-28-5 1000 ppm 1000 ppm SECTION III – HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Flammable liquid, keep away from heat, sparks, or open flame. ROUTES OF ENTRY: Eyes, Ingestion, Inhalation, Skin EYES: May cause mild irritation. INGESTION: Not a likely route of exposure under normal product handling conditions. INHALATION: No hazards with normal use. May cause irritation of the respiratory tract. SKIN: Product is meant to be applied to skin. If you suspect a reaction discontinue use take off clothing and rinse skin immediately with water for 15-20 minutes. MEDICAL CONDITION AGGRAVATED: Pre-existing disorders of the skin, respiratory system, and eyes will be aggravated by over exposure. CHRONIC HEALTH HAZARDS: None known CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A SECTION IV - FIRST AID MEASURES EYES: Immediately flush with water for 15 minutes while holding eyelids open. Seek immediate medical attention. INGESTION: Induce vomiting under the direction of a physician. Seek immediate medical attention. INHALATION: Move to fresh air. If breathing difficulty persists, seek medical attention. SKIN: First aid is not normally required. NOTE TO PHYSICIAN: None SECTION V – FIRE-FIGHTING MEASURES FLASH POINT: 65° F TCC FLAMMABLE LIMITS IN AIR, BY VOLUME) UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Carbon dioxide, standard chemical fire extinguisher, and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece operated in a positive pressure demand mode with full body protective clothing when fighting fires. Avoid contact with skin and breathing smoke, fumes, and decomposition products. Cool fire exposed containers with water fog to prevent bursting. UNUSUAL FIRE AND EXPLOSION HAZARDS: FLAMMABLE. Keep away from heat, sparks, open flames and other sources of ignition. HAZARDOUS COMBUSTION PRODUCTS: None known Page 98 of 1069 Page 98 of 1069 Page 98 of 1069 Page 98 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Applause Hand Sanitizer PAGE 2 of 3 SECTION VI – ACCIDENTAL RELEASE MEASURES SPILL: Absorb with non-combustible material like vermiculite, sand or earth and rinse with small amount of soapy water. Do not allow to drain into sewers or storm drains. Dispose of in accordance with local, state and federal regulations. WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Do not dump in sewers. Wrap container and place in trash collection, do not puncture, incinerate, or reuse container. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Store in a cool, dry area. Away from extremes of temperature. Keep container sealed when not in use. Keep out of the reach of children. OTHER PRECAUTIONS: None SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS / VENTILATION: General ventilation and local exhaust should be adequate. RESPIRATORY PROTECTION: Wear NIOSH/MSHA approved respiratory protection if used in confined, poorly ventilated areas. PROTECTIVE CLOTHING: Safety glasses and chemical resistant gloves are recommended. ADDITIONAL MEASURES: Wash hands and clothing in contact with product after use SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, Colorless Liquid ODOR: Citrus-Orange and alcohol scent PHYSICAL STATE: Viscous Liquid BOILING POINT: 212 FREEZING POINT: Not Tested VAPOR PRESSURE (mm Hg): 17.5 @ 77°F (25°C) VAPOR DENSITY (AIR=1): 1 EVAPORATION RATE: > 1 SPECIFIC GRAVITY (H2O=1): 0.90 @ 77° F (25° C) pH: 10.2 SOLIDS Not tested SOLUBILITY IN WATER: 100% VOLATILITY INCLUDING WATER > 80 VOLATILE ORGANIC COMPOUNDS (VOC): 0% DIELECTRIC STRENGTH (Volts): N/A SECTION X – STABILITY AND REACTIVITY DATA CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Excessive heat, open flames, sparks, hot surfaces, and sources of ignition. INCOMPATIBILITY: Strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon HAZARDOUS POLYMERIZATION: Will not occur SECTION XI – TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Ethyl Alcohol (64-17-5) LC50 (Inhalation, Mouse, 4hr) 39 gm/m3; LC50 (Inhalation, Rat, 10hr) 20,000 ppm; LD50 (Oral, Mouse) 3450 mg/kg; LD50 (Oral, Rabbit) 6300 mg/kg; LD50 (Oral, Rabbit) 7060 mg/kg SECTION XII – ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Ethyl Alcohol (64-17-5) LC50 (Fish, 96hr) 12,900-15,300 mg/L; LC50 (Bacteria, 24hr) 11,200 mg/L; EC50 (Bacteria, 5-30 min) 34,900 mg/L SECTION XIII – DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Do not dump in sewers. Wrap container and place in trash collection, do not puncture, incinerate, or reuse container. Page 99 of 1069 Page 99 of 1069 Page 99 of 1069 Page 99 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Applause Hand Sanitizer PAGE 3 of 3 RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION XIV - TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Cleaning Compound, N.O.S. HAZARD CLASS/DIVISION: None PACKAGING GROUP: AIR SHIPMENT PROPER SHIPPING NAME: Ethanol Solution UN/NA NUMBER: UN 1170 PACKAGING GROUP: III SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Ethanol Solution UN/NA NUMBER: UN 1170 PACKAGING GROUP: III NOTE: SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Fire Hazard SARA 311/312 HAZARD CATEGORIES: Ethyl Alcohol (64-17-5) Acute Health, Chronic Health, Fire SARA 313 REPORTABLE INGREDIENTS: Ethyl Alcohol (64-17-5) acute, chronic, flammable. CLEAN WATER ACT: None STATE REGULATIONS: California Proposition 65: None INTERNATIONAL REGULATIONS: Ethyl Alcohol (64-17-5) WHMIS (Canada): CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2B: Material causing other toxic effects (TOXIC). DSCL (EEC): R11- Highly flammable. S7- Keep container closed. S16 - Keep away from sources of ignition - No smoking. NFPA HEALTH: 1 HMIS HEALTH: 1 NFPA FLAMMABILITY: 3 HMIS FLAMMABILITY: 3 NFPA REACTIVITY: 0 HMIS REACTIVITY: 0 NFPA OTHER: N/A HMIS PROTECTION: A SECTION XVI - ADDTIONAL INFORMATION PREPARATION BY: Mitch Whitney DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this MSDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. Page 100 of 1069 Page 100 of 1069 Page 100 of 1069 Page 100 of 1069 ---PAGE BREAK--- PRODUCT NAME: Bar Keepers Friend Cleanser & Polish RELEVANT IDENTIFIED USES OF Relevant identified uses: Cleans and/or polishes most hard, nonporous surfaces. THE MIXTURE AND USES Do not use on cast iron, granite, marble, wood, fabric, leather, painted surfaces, ADVISED AGAINST: mirrors, gold, or silver (sterling silver is OK). Do not use where rinsing thoroughly is difficult, or impossible. MANUFACTURER: SerVaas Laboratories, Inc 5240 Walt Place Indianapolis, IN 46254 USA CALL FOR PRODUCT 1-[PHONE REDACTED] (for USA callers) TECHNICAL INFORMATION: 1-[PHONE REDACTED] (for non-USA callers) www.barkeepersfriend.com EMERGENCY TELEPHONE NUMBER( CHEMTREC): 1-[PHONE REDACTED] SECTION 2 - HAZARDS IDENTIFICATION CLASSIFICATION OF Skin irritation 3 - H316 THE MIXTURE: Eye irritation 2A - H319 LABEL ELEMENTS: SIGNAL WORD: Warning HAZARD PICTOGRAM: HAZARD STATEMENTS: H316 Causes mild skin irritation H319 - Causes serious eye irritation PREVENTION: P264 Wash hands thoroughly after handling P280 Wear eye protection / face protection RESPONSE: P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice / attention. If medical advice is needed, have container at hand. P332+P313 If skin irritation occurs, get medical attention. If medical advice is needed, have container in hand. SECTION I - IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND THE COMPANY 1/4 SAFETY DATA SHEET (SDS) Page 101 of 1069 Page 101 of 1069 Page 101 of 1069 Page 101 of 1069 ---PAGE BREAK--- SECTION 3 - COMPOSITION / INFORMATION ON THE INGREDIENTS INGREDIENT % By Weight CAS Reg. No. FELDSPAR* Confidential 68476-25-5 LINEAR SODIUM DODECYL BENZENE SULFONATE (DDBSA) Confidential 69669-44-9 OXALIC ACID 7.5 - 9.5 144-62-7 *not regulated as hazardous materials SECTION 4 - FIRST AID MEASURES IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice / attention. If medical advice is needed, have container at hand. IF INGESTED: Drink milk or water and call a doctor. Do not induce vomiting. Get medical advice / attention. If medical advice is needed, have container at hand. IF ON SKIN: Wash with soap and water. If skin irritation occurs, get medical attention. If medical advice is needed, have container in hand. SECTION 5 - FIREFIGHTING MEASURES Not a fire hazard. Use extinguishing media appropriate for surrounding fire. SPECIAL FIREFIGHTING Wear NIOSH approved self-contained breathing apparatus and protective clothing INSTRUCTIONS: appropriate for a chemical fire. Cool fire-exposed containers with water spray. Oxalic acid may decompose to carbon monoxide (CO) and formic acid (HCOOH) in fire conditions. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE For a small spill, wipe up with a mop, paper towels, or cloths. For large spills, use MATERIAL IS RELEASED an absorbent such as kitty litter to contain spills. Carefully sweep up, raising a OR SPILLED: minimum amount of dust, and discard into a household waste container for dispos- al. WASTE DISPOSAL METHOD: Dispose according to the local, state, or federal regulations. Use baking soda to neutralize acid. Wear protective equipment as needed (see section SECTION 7 - HANDLING AND STORAGE CONDITIONS FOR SAFE STORAGE: Keep out of reach of children and domestic animals. Store in a dry place. Keep FROM FREEZING. DO NOT STORE WHERE TEMPERATURE MAY EXCEED 140º F. CONDITIONS FOR SAFE USE: Follow use directions on the label. Apply a small amount onto a wet surface or a damp cloth or sponge, then rub gently. Do not mix with other chemicals including bleach or ammonia. Wash hands after use. For prolonged use or sensitive skin, wear waterproof gloves. Respiratory protection is not normally required except as described for firefighting, or if the product is mixed with bleach or ammonia. 2/4 Page 102 of 1069 Page 102 of 1069 Page 102 of 1069 Page 102 of 1069 ---PAGE BREAK--- SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION PRIMARY ROUTES OF EXPOSURE: Dermal contact, hand-to-eye contact. In case of eye contact, see Section 4, First Aid. ACCIDENTAL OR DELIBERATE Bar Keepers Friend Cleanser & Polish is of minimal oral toxicity. For ingestion of a INGESTION: large quantity, see Section 4: First Aid. INDIVIDUAL PROTECTION Prolonged contact may product dry skin or irritation in some individuals. For MEASURES: prolonged contact or sensitive skin, wear protective gloves (e.g. those meant for household cleaning.) EXPOSURE LIMITS: Oxalic acid: ACGIH TLV/ OSHA PEL/ NIOSH REL 1 mg/M3 (TWA) 2 (STEL). SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: . . . . . solid (powder) COLOR: . . . . . . . . . . . . . . white ODOR: . . . . . . . . . . . . . . negligible pH: . . . . . . . . . . . . . . . . . . 1.5 to 2.5(depending on typical dilution) FREEZING: . . . . . . . . . . . NA BOILING POINT: . . . . . . . NA FLASH POINT: . . . . . . . . not flammable EVAPORATION RATE: . . . NA SPECIFIC GRAVITY: . . . . 0.85 - 0.95 SOLUBILITY: . . . . . . . . . . Oxalic acid and surfactant are soluble in water. SECTION 10 - STABILITY AND REACTIVITY STABILITY: Stable REACTIVITY: Incompatible with chlorine bleach, ammonia, and alkaline products. HAZARDOUS DECOMPOSITION PRODUCTS: Oxalic acid may decompose to carbon monoxide (CO) and formic acid (HCOOH) in fire conditions. SECTION 11 - TOXICOLOGICAL INFORMATION ACUTE TOXICITY: OXALIC ACID: Oral LD50 >7500 mg/kg (rat) Dermal LD50 not determinable Eye irritant Slight skin irritant Inhalation LD50 not determined Non sensitizer DDBSA Moderate skin and eye irritant SECTION 12 - ECOLOGICAL INFORMATION Bar Keepers Friend Cleanser & Polish is of minimal risk to terrestrial wildlife. Oxalic acid and DDBSA are water soluble. Dissolution of these substances into bodies of water may cause short-term risk to fish and other aquatic organisms. Dissipation in the environment is rapid. In case of spill, prevent runoff into bodies of water. Clean up spills as described in Section 6. 3/4 Page 103 of 1069 Page 103 of 1069 Page 103 of 1069 Page 103 of 1069 ---PAGE BREAK--- SECTION 13 - DISPOSAL CONSIDERATIONS Bar Keepers Friend Cleanser & Polish may be disposed of in household garbage. SECTION 14 - TRANSPORT INFORMATION NOT REGULATED BY DOT. DOT TRANSPORTATION NUMBER: Not applicable PACKING GROUP: Not applicable MARITIME INFORMATION: Not applicable HAZARDOUS SUBSTANCES REPORT QUANTITY: Not applicable TDG CLASSIFICATION: Consumer Commodity-Transborder Consignment ADR CLASSIFICATION: Not applicable IMDG CLASSIFICATION: Not regulated IATA CLASSIFICATION: Does not qualify in manufactured case lot size SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL AND STATE REGULATIONS: SARA Title III Section 313 Toxic Chemical Notification & RELEASE REPORTING: None OTHER CLASSIFICATION: Not controlled under WHMIS (Canada) SECTION 16 - OTHER INFORMATION NFPA Health Hazards: 2 Flammability: 0 Instability: 0 Special: N/A HMIS Health Hazards: 2 Flammability: 0 Physical Hazards: 0 Disclaimer: The information presented herein is based on available data from reliable sources and is correct to the best of SerVaas Laboratories, Inc. knowledge. SerVaas Laboratories, Inc. makes no warranty, express nor implied, regarding the accuracy of the data or the results obtained from the use of this product. The user is solely responsible for determining the suitability of any material or product for a specific purpose and for adopting any appropriate safety precautions. SerVaas Laboratories, Inc. disclaims all liability for injury or damage stemming from any improper use of the material or product described herein. Revision Date: June 12, 2015 Supersedes document dated: 5/15/2015 Prepared by: P. SerVaas, SerVaas Laboratories, Inc. 4/4 Page 104 of 1069 Page 104 of 1069 Page 104 of 1069 Page 104 of 1069 ---PAGE BREAK--- There was a PDF conversion failure for Uploaded SDS - Product Name: BLACK SHARP TONER MX51NT CAS Number: Manufacturer: SHARP SDS Date: To complete your binder, please upload a different SDS for this product or remove the SDS from your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 105 of 1069 Page 105 of 1069 Page 105 of 1069 Page 105 of 1069 ---PAGE BREAK--- Page 106 of 1069 Page 106 of 1069 Page 106 of 1069 Page 106 of 1069 ---PAGE BREAK--- Page 107 of 1069 Page 107 of 1069 Page 107 of 1069 Page 107 of 1069 ---PAGE BREAK--- Page 108 of 1069 Page 108 of 1069 Page 108 of 1069 Page 108 of 1069 ---PAGE BREAK--- Page 109 of 1069 Page 109 of 1069 Page 109 of 1069 Page 109 of 1069 ---PAGE BREAK--- Page 110 of 1069 Page 110 of 1069 Page 110 of 1069 Page 110 of 1069 ---PAGE BREAK--- Page 111 of 1069 Page 111 of 1069 Page 111 of 1069 Page 111 of 1069 ---PAGE BREAK--- Page 112 of 1069 Page 112 of 1069 Page 112 of 1069 Page 112 of 1069 ---PAGE BREAK--- Page 113 of 1069 Page 113 of 1069 Page 113 of 1069 Page 113 of 1069 ---PAGE BREAK--- Page 114 of 1069 Page 114 of 1069 Page 114 of 1069 Page 114 of 1069 ---PAGE BREAK--- Page 115 of 1069 Page 115 of 1069 Page 115 of 1069 Page 115 of 1069 ---PAGE BREAK--- Page 116 of 1069 Page 116 of 1069 Page 116 of 1069 Page 116 of 1069 ---PAGE BREAK--- Safety Data Sheet 1.1. Product Identifier Trade Name or Designation: Product Number: Other Identifying Product Numbers: Bromocresol Purple - Bromothymol Blue Mixed Indicator, 1% / 0.2% (w/v) in Methanol 1315 1315-4 1.2. Recommended Use and Restrictions on Use General Laboratory Reagent 1.3. Details of the Supplier of the Safety Data Sheet Ricca Chemical Company 448 West Fork Drive Arlington, TX 76012 USA [PHONE REDACTED] Company: Address: Telephone: 1.4. Emergency Telephone Number (24 hr) CHEMTREC (USA) CHEMTREC (International) [PHONE REDACTED] 1+ [PHONE REDACTED] SECTION 1: Identification Product Number: 1315 Page 1 of 11 Page 117 of 1069 Page 117 of 1069 Page 117 of 1069 Page 117 of 1069 ---PAGE BREAK--- Safety Data Sheet Hazard Class Category Hazard Statement Precautionary Statements P264, P270, P301+P310, P321, P330, P405, P501 H301 Category 3 Acute Toxicity - Oral P280, P302+P352, P312, P321, P361, P405, P501 H311 Category 3 Acute Toxicity - Dermal P261, P271, P304+P340, P311, P321, P403+P233, P405, P501 H331 Category 3 Acute Toxicity - Inhalation P264, P280, P305+P351+P338, P337+P313 H319 Category 2A Eye Damage / Irritation P201, P202, P280, P308+P313, P405, P501 H360 Category 1 Reproductive Toxicity P260, P264, P270, P307+P311, P321, P405, P501 H370 Category 1 Specific Target Organs/Systemic Toxicity Following Single Exposure P260, P264, P270, P314, P501 H372 Category 1 Specific Target Organs/Systemic Toxicity Following Repeated Exposure P210, P233, P240, P241, P242, P243, P280, P303+P361+P353, P370+P378, P403+P235, P501 H225 Category 2 Flammable Liquids For the full text of the Hazard and Precautionary Statements listed below, see Section 16. 2.1. Classification of the Substance or Mixture (in accordance with OSHA HCS 29 CFR 1910.1200) SECTION 2: Hazard(s) Identification 2.2. GHS Label Elements Pictograms: Signal Word: Danger Hazard Statements: Hazard Number Hazard Statement H225 Highly flammable liquid and vapor. H301 Toxic if swallowed. H311 Toxic in contact with skin. H319 Causes serious eye irritation. H331 Toxic if inhaled. H360 May damage fertility or the unborn child. H370 Causes damage to organs. H372 Causes damage to organs through prolonged or repeated exposure. Product Number: 1315 Page 2 of 11 Page 118 of 1069 Page 118 of 1069 Page 118 of 1069 Page 118 of 1069 ---PAGE BREAK--- Safety Data Sheet Precautionary Statements: Precautionary Statement Precautionary Number P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks and open flame. No smoking. P233 Keep container closed. P240 Ground container and receiving equipment. P241 Use explosion-proof equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust, fumes or mist. P261 Avoid breathing dust, fumes or mist. P264 Wash arms, hands and face thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves and eye protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or physician. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P307+P311 IF exposed: Call a POISON CENTER or physician. P308+P313 IF exposed or concerned: Get medical attention. P311 Call a POISON CENTER or physician. P312 Call a POISON CENTER or physician if you feel unwell. P314 Get medical attention if you feel unwell. P321 Specific treatment (Wash areas of contact with water). P330 Rinse mouth. P337+P313 If eye irritation persists: Get medical attention. P361 Take off immediately all contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container closed. P405 Store locked up. P501 Dispose of contents in accordance with local, state, federal and international regulations. 2.3. WHMIS Classification WHMIS classification is not included based on the recommended option (Option 4) found in the Canada Gazette Part II, Vol. 149, No.3, page 458 Product Number: 1315 Page 3 of 11 Page 119 of 1069 Page 119 of 1069 Page 119 of 1069 Page 119 of 1069 ---PAGE BREAK--- Safety Data Sheet 2.4. Hazards not Otherwise Classified or Covered by GHS Data not available. SECTION 3: Composition / Information on Ingredients 3.1. Components of Substance or Mixture Chemical Name Formula Molecular Weight CAS Number Weight% Methyl Alcohol CH₃OH 32.04 g/mol 67-56-1 98.50% Bromocresol Purple C₂₁H₁₆Br₂O₅S 540.22 g/mol 115-40-2 1.25% Bromothymol Blue C₂₇H₂₈Br₂O₅S 624.38 g/mol 76-59-5 0.25% Eye Contact: SECTION 4: First-Aid Measures 4.1. General First Aid Information IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. May cause irritation with burning and stinging with possible damage to the cornea and conjunctiva. Inhalation: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Skin Contact: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Results in drying and cracking which can lead to secondary infections and dermatitis. Dermal absorption causes many of the of inhalation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or physician. Dilute immediately with water or milk. Induce vomiting. Call a physician. 4.2. Most Important and Effects, Acute and Delayed Flammable liquid. Primarily toxic by ingestion. Cannot be made non-poisonous. If ingested, give large quantity of water and induce vomiting. Call a physician. Contact may cause dryness and cracking of the skin. May cause irritation to the eyes. Wash areas of contact with water. May cause irritation of the respiratory system. EYE CONTACT: May cause irritation with burning and stinging with possible damage to the cornea and conjunctiva. SKIN CONTACT: Results in drying and cracking which can lead to secondary infections and dermatitis. Dermal absorption causes many of the of inhalation. 4.3. Medical Attention or Special Treatment Needed Specific treatment (Wash areas of contact with water). 5.1. Extinguishing Media Use water spray, dry chemical, alcohol foam, or carbon dioxide for extinguishing the surrounding fire. Water spray can be used to dilute spills to non-flammable mixtures. SECTION 5: Fire-Fighting Measures 5.2. Specific Hazards Arising from the Substance or Mixture Highly flammable liquid and vapor. Moderate explosion hazard and dangerous fire hazard when exposed to heat, sparks and open flames. Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Sensitive to static discharge. Product Number: 1315 Page 4 of 11 Page 120 of 1069 Page 120 of 1069 Page 120 of 1069 Page 120 of 1069 ---PAGE BREAK--- Safety Data Sheet 5.3. Special Protective Equipment for Firefighters Wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6.1. Personal Precautions, Protective Equipment and Emergency Procedures Ground container and receiving equipment. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves and eye protection. SECTION 6: Accidental Release Measures 6.2. Cleanup and Containment Methods and Materials Remove all sources of ignition. Contain spill. Do not flush to sewer. Absorb with suitable inert material (vermiculite, dry sand, etc) and place in a chemical waste container for proper disposal in an approved waste disposal facility. Ventilate area of spill. Have extinguishing agent available in case of fire. Use non-sparking tools and equipment. Dispose of in accordance with local regulations. 7.1. Precautions for Safe Handling and Storage Conditions Store locked up. As with all chemicals, wash hands thoroughly after handling. Avoid contact with eyes and skin. Protect from freezing and physical damage. Store in secure, flammable storage area away from all sources of ignition. Empty containers may be hazardous since they retain product residues. SECTION 7: Handling and Storage 8.1. Control Parameters Chemical Name Country Exposure Limit Limit Type Information Source TWA USA U.S. - OSHA - Final PELs - Time Weighted Averages (TWAs) Methyl Alcohol (67-56-1) 200 ppm TWA 260 mg/m³ TWA TLV-STEL USA ACGIH - Threshold Limit Values - Short Term Exposure Limits (TLV-STEL) Methyl Alcohol (67-56-1) 250 ppm STEL TLV-TWA USA ACGIH - Threshold Limit Values - Time Weighted Averages (TLV-TWA) Methyl Alcohol (67-56-1) 200 ppm TWA SECTION 8: Exposure Controls / Personal Protection 8.2. Exposure Controls Engineering Controls: Use only outdoors or in a well-ventilated area. A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limit. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved atmosphere supplied respirator must be worn. Skin Protection: Wear protective gloves and eye protection. Chemical resistant gloves. Eye Protection: Wear protective gloves and eye protection. Safety glasses or goggles. 8.3. Personal Protective Equipment Wear protective gloves and eye protection. If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved atmosphere supplied respirator must be worn. Chemical resistant gloves. Safety glasses or goggles. Product Number: 1315 Page 5 of 11 Page 121 of 1069 Page 121 of 1069 Page 121 of 1069 Page 121 of 1069 ---PAGE BREAK--- Safety Data Sheet Data not available. Data not available. Data not available. Data not available. Data not available. -0.77 Miscible at 20°C 0.8 1.1 128 hPa at 20°C Data not available. Data not available. 2.1 (butyl acetate = 1) 11°C Approximately 64.5°C - Approximately 64.5°C -98°C Data not available. Data not available. Slight, alcohol-like Liquid Reddish-orange liquid Appearance: Physical State: Odor: Odor Threshold: pH: Melting/Freezing Point: Initial Boiling Point /Range: Flash Point: Evaporation Rate: Flammability: Flammability/Explosive Limits: Vapor Pressure: Vapor Density: Relative Density: Solubility: Partition Coeffieient (n-Octanol/Water): Auto-Ignition Temperature: Decomposition Temperature: Viscosity: ExplosiveProperties: Oxidizing Properties: 9.1. Basic Physical and Chemical Properties SECTION 9: Physical and Chemical Properties 10.1. Reactivity and Chemical Stability Stable under normal conditions of use and storage. SECTION 10: Stability and Reactivity 10.2. Possibility of Hazardous Reactions Data not available. 10.3. Conditions to Avoid and Incompatible Materials Keep away from heat, sparks and open flame. No smoking. Keep container closed. Strong oxidizing agents such as Nitrates, Perchlorates or 10.4. Hazardous Decomposition Products Will not occur. Product Number: 1315 Page 6 of 11 Page 122 of 1069 Page 122 of 1069 Page 122 of 1069 Page 122 of 1069 ---PAGE BREAK--- Safety Data Sheet Acute Toxicity - Oral Exposure: Toxic if swallowed. Wash arms, hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Immediately call a POISON CENTER or physician. Specific treatment (Wash areas of contact with water). Rinse mouth. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. 11.1. Information on Toxicological Effects SECTION 11: Toxicological Information Acute Toxicity - Dermal Exposure: Toxic in contact with skin. Wear protective gloves and eye protection. IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Specific treatment (Wash areas of contact with water). Take off immediately all contaminated clothing and wash it before reuse. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. Acute Toxicity - Inhalation Exposure: Toxic if inhaled. Avoid breathing dust, fumes or mist. Use only outdoors or in a well-ventilated area. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician. Specific treatment (Wash areas of contact with water). Store in a well-ventilated place. Keep container closed. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. Acute Toxicity - Other Information: LD50, Oral, Rat: (Methanol) 5628 mg/kg, details of toxic effects not reported other than lethal dose value. Skin Corrosion and Irritation: Not applicable. Serious Eye Damage and Irritation: Causes serious eye irritation. Wash arms, hands and face thoroughly after handling. Wear protective gloves and eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Respiratory Sensitization: Not applicable. Skin Sensitization: Not applicable. Germ Cell Mutagenicity: Not applicable. Carcinogenicity: Not applicable. Reproductive Toxicity: May damage fertility or the unborn child. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves and eye protection. IF exposed or concerned: Get medical attention. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. Specific Target Organ Toxicity from Single Exposure: Causes damage to organs. Do not breathe dust, fumes or mist. Wash arms, hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. IF exposed: Call a POISON CENTER or physician. Specific treatment (Wash areas of contact with water). Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. Product Number: 1315 Page 7 of 11 Page 123 of 1069 Page 123 of 1069 Page 123 of 1069 Page 123 of 1069 ---PAGE BREAK--- Safety Data Sheet Specific Target Organ Toxicity from Repeated Exposure: Causes damage to organs through prolonged or repeated exposure. Do not breathe dust, fumes or mist. Wash arms, hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. Get medical attention if you feel unwell. Dispose of contents in accordance with local, state, federal and international regulations. Aspiration Hazard: Not applicable. Additional Toxicology Information: Data not available. 12.1. Ecotoxicity Not applicable. SECTION 12: Ecological Information 12.2. Persistence and Degradability Data not available. 12.3. Bioaccumulative Potential Data not available. 12.4. Mobility in Soil Data not available. 12.5. Other Adverse Ecological Effects Data not available. 13.1. Waste Treatment Methods Data not available. SECTION 13: Disposal Considerations II 3 Methanol Solution UN1230 UN Number: Proper Shipping Name: Hazard Class: Packing Group: Hazard Placard Labels: 14.1. Transportation by Land - Department of Transportation (DOT, United States of America) SECTION 14: Transportation Information Product Number: 1315 Page 8 of 11 Page 124 of 1069 Page 124 of 1069 Page 124 of 1069 Page 124 of 1069 ---PAGE BREAK--- Safety Data Sheet II 3 Methanol Solution UN1230 UN Number: Proper Shipping Name: Hazard Class: Packing Group: Hazard Placard Labels: 14.2. Transportation by Air - International Air Transport Association (IATA) 15.1. Occupational Safety and Health Administration (OSHA) Hazards Not listed. SECTION 15: Regulatory Information 15.2. Superfund Amendments and Reauthorization Act (SARA) 302 Extremely Hazardous Substances Not listed. 15.3. Superfund Amendments and Reauthorization Act (SARA) 311/312 Hazardous Chemicals Methyl Alcohol (CAS # 67-56-1): 5000 lb final RQ; 2270 kg final RQ 15.4. Superfund Amendments and Reauthorization Act (SARA) 313 Toxic Release Inventory (TRI) Methyl Alcohol (CAS # 67-56-1): 1.0 % de minimis concentration 15.5. Massachusetts Right-to-Know Substance List Methyl Alcohol (CAS # 67-56-1): Present 15.6. Right-to-Know Hazardous Substances Methyl Alcohol (CAS # 67-56-1): Environmental hazard Methyl Alcohol (CAS # 67-56-1): Present 15.7. New Jersey Worker and Community Right-to-Know Components Methyl Alcohol (CAS # 67-56-1): flammable - third degree; teratogen Methyl Alcohol (CAS # 67-56-1): sn 1222 Methyl Alcohol (CAS # 67-56-1): SN 1222 TPQ: 500 lb 15.8. California Proposition 65 Methyl Alcohol (CAS # 67-56-1): developmental toxicity, initial date 3/16/12 15.9. Canada Domestic Substances List / Non-Domestic Substances List (DSL/NDSL) Bromocresol Purple (CAS # 115-40-2): Present Methyl Alcohol (CAS # 67-56-1): Present Bromothymol Blue (CAS # 76-59-5): Present Product Number: 1315 Page 9 of 11 Page 125 of 1069 Page 125 of 1069 Page 125 of 1069 Page 125 of 1069 ---PAGE BREAK--- Safety Data Sheet 15.10. United States of America Toxic Substances Control Act (TSCA) List Bromocresol Purple (CAS # 115-40-2): Present Methyl Alcohol (CAS # 67-56-1): Present Bromothymol Blue (CAS # 76-59-5): Present 15.11. European Inventory of Existing Commercial Chemical Substances (EINECS), European List of Notified Chemical Substances (ELINCS), and No Longer Polymers (NLP) Not listed. SECTION 16: Other Information 16.1. Full Text of Hazard Statements and Precautionary Statements Highly flammable liquid and vapor. Toxic if swallowed. Toxic in contact with skin. Causes serious eye irritation. Toxic if inhaled. May damage fertility or the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks and open flame. No smoking. Ground container and receiving equipment. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust, fumes or mist. Wash arms, hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye protection. IF SWALLOWED: Immediately call a POISON CENTER or physician. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed: Call a POISON CENTER or physician. Get medical attention if you feel unwell. Specific treatment (Wash areas of contact with water). Rinse mouth. If eye irritation persists: Get medical attention. In case of fire: Use dry chemical, foam or carbon dioxide to extinguish. Store in a well-ventilated place. Keep container closed. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. 16.2. Miscellaneous Hazard Classes Not Applicable. Not Applicable. Not Applicable. Not Applicable. Canadian Carcinogenicity Hazard Class: Physical Hazards Not Otherwise Classified (PHNOC): Health Hazards Not Otherwise Classified (HHNOC): Product Number: 1315 Page 10 of 11 Page 126 of 1069 Page 126 of 1069 Page 126 of 1069 Page 126 of 1069 ---PAGE BREAK--- Safety Data Sheet 16.3. National Fire Protection Association (NFPA) Rating 1 0 3 0 3 1 Health: Flammability: Reactivity: Special Hazard: 16.4. Document Revision Last Revision Date: 5/1/2015 DISCLAIMER When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazard. Alteration of its characteristics by concentration, evaporation, addition of other substances, or other means may present hazards not specifically addressed herein and which must be evaluated by the user. The information furnished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied, is made and RICCA CHEMICAL COMPANY assumes no legal responsibility or liability whatsoever resulting from its use. Product Number: 1315 Page 11 of 11 Page 127 of 1069 Page 127 of 1069 Page 127 of 1069 Page 127 of 1069 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # HR24200 SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. Chemtrec: [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550, MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS BRUSH KLEAN (aerosol) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Sodium Metasilicate CAS #6834-92-0 >1 N/ Citrus Terpene CAS #5989-27-5 >1 Polyethoxylate CAS #9002-93-7 >1 Liquified Petroleum Gas CAS #68476-85-7 >1 1000 ppm All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT (ºF) 212°F SPECIFIC GRAVITY (H2O = 1) 0.99 VAPOR PRESSURE (mm. Hg.) 63 PERCENT VOLATILE BY VOLUME 85 VAPOR DENSITY (AIR = 1) heavier EVAPORATION RATE ( Water 1 SOLUBILITY IN WATER complete PH 7 APPEARANCE AND ODOR SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) None T.O.C. FLAMMABLE LIMITS N/A N/A EXTINGUISHING MEDIA Foam, Dry chemical, Carbon dioxide SPECIAL FIRE FIGHTING PROCEDURES fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120° F. (Continued on reverse side) Page 128 of 1069 Page 128 of 1069 Page 128 of 1069 Page 128 of 1069 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA THRESHOLD LIMIT VALUE 1000 ppm PRIMARY ROUTES OF ENTRY Inhalation Skin Contact Other (Specify) EFFECTS OF OVEREXPOSURE Eyes – slight irritation. Skin – prolonged contact may cause irritation. Inhalation – nasal and respiratory irritation, dizziness, nausea, CNS effects. Ingestion – irritation, nausea, diarrhea EMERGENCY AND FIRST AID PROCEDURE Eyes – flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation – get medical attention. Skin – flush with water and then wash with soap and water, launder contaminated clothing before reuse. Inhalation – remove to fresh air and assist breathing as necessary – get medical attention. Ingestion – DO NOT INDUCE VOMITING – aspiration of material into lungs will be harmful or fatal - get immediate medical attention. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None Known Carcinogen: NTP IARC OTHER No SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE X CONDITIONS TO AVOID Temperatures in excess of 120° F INCOMPATABILITY (Conditions to avoid) Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR X CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Eliminate all sources of ignition and ventilate area. Use absorbent material to soak up spill. Shovel or sweep into container for disposal WASTE DISPOSAL METHOD In accordance with all local, state and federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) None needed for proper use in accordance with label directions. LOCAL EXHAUST Normal ventilation adequate SPECIAL N/A VENTILATION MECHANICAL (General) Normal ventilation adequate OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact – wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors – use only with adequate ventilation. Do not take internally. Do not store in areas where temperatures may exceed 120° F. Read and follow label directions. OTHER PRECAUTIONS Keep Out of Reach of Children HMIS SYMBOL HMIS NFPA NFPA SYMBOL SEVERE 4 EXTREME FIRE REACTIVITY SERIOUS 3 HIGH 0 MODERATE 2 MODERATE 1 1 SLIGHT 1 SLIGHT TOXICITY MINIMAL 0 INSIGNIFICANT SPECIAL NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE July 12, 2007 PHONE NUMBER Chemtrec: [PHONE REDACTED] HEALTH 1 FLAMMABILITY 0 REACTIVITY 1 Page 129 of 1069 Page 129 of 1069 Page 129 of 1069 Page 129 of 1069 ---PAGE BREAK--- Page 130 of 1069 Page 130 of 1069 Page 130 of 1069 Page 130 of 1069 ---PAGE BREAK--- Page 131 of 1069 Page 131 of 1069 Page 131 of 1069 Page 131 of 1069 ---PAGE BREAK--- Page 132 of 1069 Page 132 of 1069 Page 132 of 1069 Page 132 of 1069 ---PAGE BREAK--- Revision Date: 22-Jan-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: CARPET STAIN REMOVER Product Number: 6374 Recommended Use: Cleaning agent Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Serious Eye Damage/Eye Irritation: Category 2A GHS Label Elements Signal Word: Danger Hazard Statements: Causes serious eye irritation Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Wear eye / face protection Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 6 Liquefied gas Symbols: Page 133 of 1069 Page 133 of 1069 Page 133 of 1069 Page 133 of 1069 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 Hazards Not Otherwise Classified: Not Applicable Other Information: • May cause skin irritation. • May be harmful if swallowed. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 2-butoxyethanol 111-76-2 5-10 isopropanol 67-63-0 1-5 propane 74-98-6 1-5 N-butane 106-97-8 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 6 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 134 of 1069 Page 134 of 1069 Page 134 of 1069 Page 134 of 1069 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH 2-butoxyethanol 111-76-2 TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3 isopropanol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Not required with expected use. Respiratory Protection: Page 3 / 6 Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. Page 135 of 1069 Page 135 of 1069 Page 135 of 1069 Page 135 of 1069 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: -Eyes. Respiratory System. -Skin. Blood. Central nervous system. hematopoietic system. kidney. Liver, Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 4331 mg/kg ATEmix (dermal): 11323 mg/kg ATEmix (inhalation-gas): 10511385 ATEmix (inhalation-dust/mist): 23.1 mg/l ATEmix (inhalation-vapor): 22.9 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: White Odor: solvent pH: 10.0-11.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F (Product without propellant) Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: <1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.96 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 4 / 6 Decomposition Temperature: No information available. Viscosity: No information available. Page 136 of 1069 Page 136 of 1069 Page 136 of 1069 Page 136 of 1069 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 2-butoxyethanol 111-76-2 = 470 mg/kg ( Rat ) = 2270 mg/kg ( Rat ) = 220 mg/kg ( Rabbit ) = 2.21 mg/L ( Rat ) 4 h = 450 ppm ( Rat ) 4 h isopropanol 67-63-0 = 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rat ) = 12870 mg/kg ( Rabbit ) = 72.6 mg/L ( Rat ) 4 h propane 74-98-6 Not Available Not Available = 658 mg/L ( Rat ) 4 h N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea 2-butoxyethanol 111-76-2 Not Available 1490: 96 h Lepomis macrochirus mg/L LC50 static 2950: 96 h Lepomis macrochirus mg/L LC50 Not Available 1698 - 1940: 24 h Daphnia magna mg/L EC50 1000: 48 h Daphnia magna mg/L EC50 isopropanol 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 9640: 96 h Pimephales promelas mg/L LC50 flow-through 11130: 96 h Pimephales promelas mg/L LC50 static 1400000: 96 h Lepomis macrochirus µg/L LC50 Not Available 13299: 48 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product contains the following listed substances: 2-butoxyethanol CAS No 111-76-2 applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substituted phenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, Chemical Category N230 SARA 311/312 Hazard Categories Page 5 / 6 Acute Health Hazard: Yes Page 137 of 1069 Page 137 of 1069 Page 137 of 1069 Page 137 of 1069 ---PAGE BREAK--- 6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015 Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 formaldehyde - 50-00-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 16. OTHER INFORMATION Revision Date: 22-Jan-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 2 Flammability: 1 Instability: 0 Special: N/A HMIS Page 6 / 6 Health Hazards: 2 Flammability: 2 Physical Hazards: 2 Page 138 of 1069 Page 138 of 1069 Page 138 of 1069 Page 138 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET CE Item #82125 NAME OF PRODUCT : DRY ERASE CLEANER MSDS Rev.DATE:25/5/07 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: CC800.3 Dry Erase Cleaner SYNONYMS: Board Cleaner and Conditioner PRODUCT CODES: CC800.3 MANUFACTURER: Corporate Express, Inc. DIVISION: ADDRESS: 1 Environmental Way Broomfield CO 80021 EMERGENCY PHONE: CHEMTREC PHONE: [PHONE REDACTED] OTHER CALLS: FAX PHONE: PRODUCT USE: PREPARED BY: SECTION 1 NOTES: SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT: CAS NO. % WT % VOL SARA 313 REPORTABLE PROPAN-2-OL 67-63-0 95 NO Fatty Acid Ester NA 5 NO ppm mg/m3 OSHA PEL: 400 980 ACGIH TLV: Short Term 500 1230 Long Term 400 983 SECTION 2 NOTES: SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: HIGHLY FLAMMABLE ROUTES OF ENTRY: IRRITATING TO EYES VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS POTENTIAL HEALTH EFFECTS EYES: Liquid or vapour will cause conjunctival irritation. SKIN: Repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis. INGESTION: INHALATION: Exposure to vapour may have the following effects:- dizziness, narcosis or coma. ACUTE HEALTH HAZARDS: CHRONIC HEALTH HAZARDS: MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: CARCINOGENICITY OSHA: NO ACGIH: NO NTP: NO IARC: NO OTHER: SECTION 3 NOTES: Page 1 of 6 Page 139 of 1069 Page 139 of 1069 Page 139 of 1069 Page 139 of 1069 ---PAGE BREAK--- SECTION 4: FIRST AID MEASURES EYES: Flush thoroughly with water or other suitable eye solution for contact: at least 15 minutes. If irritation continues, take affected person to hospital or call for an ambulance. SKIN: Remove contaminated clothing. Wash the affected area in flowing water, or warm water and soap for at least 15 minutes. If irritation continues, take the affected person to hospital or call for an ambulance. Wash contaminated clothing before re use INGESTION: Swallowing of small quantities is unlikely to cause any reaction. Swallowing of large quantities can be serious. If this has occurred and the casualty is still conscious, instruct him/her to rinse out the mouth with water. DO NOT induce vomiting. Take the casualty to hospital or call for an ambulance. INHALATION: Remove to fresh air but do not walk. If not breathing, give mouth to mouth resuscitation, if breathing is difficult give Oxygen. Call a physician. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Because rapid absorption may occur through the lungs if aspirated and cause systemic effects, the decision of whether to induce vomiting or not should be made by an attending Physician. If lavage is performed, suggest endotracheal and/or esophageol control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. Exposure may increase myocardial irritability. DO NOT administer sympathomimetic drugs unless absolutely necessary.No specific antidote. Supportive care. Treatment based on judgement of the physician in response to reactions of the patient. SECTION 4 NOTES: SECTION 5: FIRE-FIGHTING MEASURES FLAMMABLE LIMITS IN AIR, UPPER: 2% BY VOLUME) LOWER: 12% FLASH POINT: F: 53.6°F C: 12°C METHOD USED: Open Cup: OC AUTOIGNITION TEMPERATURE: IF: 852.8 °F C: 456°C NFPA HAZARD CLASSIFICATION HEALTH: 1 FLAMMABILITY: 3 REACTIVITY: 0 OTHER: HMIS HAZARD CLASSIFICATION HEALTH: 1 FLAMMABILITY: 3 REACTIVITY: 0 PROTECTION: EXTINGUISHING MEDIA: Select extinguishing agent appropriate to other materials involved. DO NOT use water use. Use alcohol resistant foam, dry chemical or carbon dioxide. Keep containers and surroundings cool with water spray. SPECIAL FIRE FIGHTING PROCEDURES: Fire Fighters should wear self-contained positive breathing apparatus (SCBA) and full turn out gear. UNUSUAL FIRE AND EXPLOSION HAZARDS: Hazardous Combustion Products: Carbon Monoxide HAZARDOUS DECOMPOSITION PRODUCTS: In combustion emits toxic fumes. SECTION 5 NOTES: Page 2 of 6 Page 140 of 1069 Page 140 of 1069 Page 140 of 1069 Page 140 of 1069 ---PAGE BREAK--- SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: Clean-up personnel should use respiratory and/or liquid contact protection. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Run off or release to sewer, waterway or ground forbidden. Collect with absorbent, non-combustible material into suitable containers. If it has entered drains, inform authorities (Fire Service). SECTION 6 NOTES: SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: Usage Precautions : Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Do not reuse empty containers without commercial cleaning or reconditioning. Suitable coatings: carbon/stainless steel, polyethylene, polypropylene. Storage Precautions : Flammable/Combustible. Keep away from oxidisers, heat and flames. May attack some plastics, rubber and coatings. Keep in cool, dry, ventilated storage and closed containers. Ground container and transfer equipment to eliminate static electric sparks. OTHER PRECAUTIONS: Storage Criteria: Flammable liquid storage Shelf Life: - 1 year minimum SECTION 7 NOTES: SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Use engineering controls to reduce air contamination to permissible level. Provide eyewash station, quick drench. VENTILATION : Provide adequate general and local exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment RESPIRATORY PROTECTION: CCROVF, CCR with organic vapour respirator and full face piece EYE PROTECTION: Wear splash-proof eye goggles to prevent any possibility of eye contact. SKIN PROTECTION: Wear appropriate clothing to prevent any possibility of skin contact. PVC or rubber gloves and antistatic footwear. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: WORK HYGIENIC PRACTICES: EXPOSURE GUIDELINES: Long term (8 hour) Time Weighted Average 999mg/m3 Short Term (15 minute exposure) 1250mg/m3 SECTION 8 NOTES: Page 3 of 6 Page 141 of 1069 Page 141 of 1069 Page 141 of 1069 Page 141 of 1069 ---PAGE BREAK--- SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Colourless Liquid ODOR: Alcohol PHYSICAL STATE: Liquid pH AS SUPPLIED: 3.71 pH (Other): BOILING POINT: F: 179.6°F C: 82°C MELTING POINT: F: -190.4°F C: -88°C VAPOR PRESSURE (mmHg): 31.2 @ F: 68°F C: 20°C VAPOR DENSITY (AIR = 2.08 @ F: 68°F C: 20°C SPECIFIC GRAVITY (H2O = @ F: 68°F C: 20°C EVAPORATION RATE: 1.9 BASIS (butyl acetate=1): SOLUBILITY IN WATER: Easily soluble in cold water PERCENT SOLIDS BY WEIGHT: 0% PERCENT VOLATILE: BY WT/ 95% VOLATILE ORGANIC COMPOUNDS (VOC): WITH WATER: LBS/GAL WITHOUT WATER: LBS/GAL MOLECULAR WEIGHT: 60.11 VISCOSITY: 3.06cSt @ F: 68°F C: 20°C SECTION 9 NOTES: SECTION 10: STABILITY AND REACTIVITY STABILITY: This product is stable CONDITIONS TO AVOID (STABILITY): Heat. Hot Surfaces. Sources of ignition. Flames. INCOMPATIBILITY (MATERIAL TO AVOID): Strong oxidizing agents. Strong Acid. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: In combustion emits toxic fumes. SECTION 10 NOTES: Page 4 of 6 Page 142 of 1069 Page 142 of 1069 Page 142 of 1069 Page 142 of 1069 ---PAGE BREAK--- SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Route of entry: Inhalation. Ingestion. Skin and/or eye contact Target Organs: Central nervous system. Eyes. Respiratory system. Lungs & skin . Health warnings: Irritant of eyes and mucous membranes. Narcotic effect CNS depressant. Medical Irritation of eyes & mucous membranes. Dilated pupils. Rhinitis (inflammation of the nasal mucous membranes) Dilated pupils. Rhinitis (inflamation of the nasal mucous membranes). Upper respiratory irritation. General respiratory distress, unproductive cough. Skin irritation, Nausea, vomiting. Central nervous system depression, Drowsiness, dizziness, disorientation, vertigo. Toxicological Information: LC5O/inhalation rat 46.5mg/litre/4h. SECTION 11 NOTES: SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Biodregradeability >99.9% (DOC; coupled units test /OECD 303A) LC50 (idus melanotus) > 1000mg/l 48h Acute Fish toxicity : LC 50/96h/fathead minnows /9600mg/L EC50 /24h/1000mg/L Toxicity threshhold concentration 1800mg/litre algae SECTION 12 NOTES: SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Disposal must be made according to official regulations. Do not allow product to reach sewage system. RCRA HAZARD CLASS: D001 SECTION 13 NOTES: SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: Flammable Liquid n.o.s. (Contains Isopropanol) HAZARD CLASS: 3 ID NUMBER: 1993 PACKING GROUP: II LABEL STATEMENT: 3 WATER TRANSPORTATION PROPER SHIPPING NAME: Flammable Liquid n.o.s. (Contains Isopropanol) HAZARD CLASS: 3 ID NUMBER: 1993 PACKING GROUP: II LABEL STATEMENTS: 3 AIR TRANSPORTATION PROPER SHIPPING NAME: Flammable Liquid n.o.s. (Contains Isopropanol) HAZARD CLASS: 3 ID NUMBER: 1993 PACKING GROUP: II LABEL STATEMENTS: 3 Page 5 of 6 Page 143 of 1069 Page 143 of 1069 Page 143 of 1069 Page 143 of 1069 ---PAGE BREAK--- SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): All ingredients are listed. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): N/A SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): 311/312 HAZARD CATEGORIES: 313 REPORTABLE INGREDIENTS: 67-63-0 propan-2-ol STATE REGULATIONS: California Proposition 65: None of the ingredients are listed. INTERNATIONAL REGULATIONS: Canada WHMIS (Workplace Hazardous Materials Identification): B2, D2b European Union: Label for supply: Harmful flammable Safety risk: R11 Highly flammable R20 Harmful by inhalation Safety advice: S2 Keep out of reach of children S7 Keep container closed S16 Keep away from sources of ignition - No smoking SECTION 15 NOTES: SECTION 16: OTHER INFORMATION OTHER INFORMATION: The information contained herein is based on data considered accurate and is offered solely for information, consideration and investigation. Multichem extends no warranties and assumes no responsibility as to the accuracy, completeness or suitability of this data for any purchaser’s use. The data contained only relates to this product and not to its use with any other material or process. All chemical products should be used under the direction of, technically qualified personnel who are aware of the hazards involved. All employees must be trained on how to use this Material Safety Data sheet as a source of hazard information. CONTACT: Multichem Ltd., Tyne Mills Ind. Est., Hexham, Northumberland, NE46 1XL, UK Tel. +44 1434 606085 Page 6 of 6 Page 144 of 1069 Page 144 of 1069 Page 144 of 1069 Page 144 of 1069 ---PAGE BREAK--- SAFEW DATA SHEET CEB31600 CORPOMTE EXPRESS HAND CLEANING WIPES TUB 1OO Page 1 lssued: 04/07/2008 Revision No: 1 1 . IDENTIFICATION OF THE SUBSTANCE T PREPARATION AND OF THE COMPANY I UNDERTAKING Product name: Product code: Synonyms: Gompany name: CEB31600 CORPOMTE EXPRESS HAND CLEANING WIPES TUB 1OO cE831600 OTHER PRODUCT REFERENCES: 327-50-007 Sourcing Partner Inc 1400 Lavon Drive Suite 200 McKinney TX75069 USA Tel: 001 [PHONE REDACTED] Fax:001 [PHONE REDACTED] 2, HAZARDS IDENTIFICATION Main hazards: No significant hazard. 3. COMPOSITION / INFORMATION ON INGREDIENTS Contains: Propane-1 ,2-DIOL 0.75o/o Cas Nr: 57-55-6 Einecs 200-338-0 No significant hazardous 4. FIRST AID MEASURES Skin contact: Eye contact: Ingestion: Inhalation: No There may be irritation and redness There may be initation of the throat. No 4. FIRST ArD MEASURES (ACTTON) Eye contact: Bathe the eye with running water for 15 minutes. Ingestion: lf conscious, give half a litre of water to drink immediately. 5. FIRE.FIGHTING.MEASURES Extinguishing media: Protection of fire-f i ghters: Suitable extinguishing media for the surrounding fire should be used. Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin ano eyes. 6. ACGIDENTALRELEASE MEASURES Personal precautions: Environmental precautions: Clean-up procedures: Refer to section 8 of SDS for personal protection details. Turn leaking containers leak-side up to prevent the escape of liquid. Do not discharge into drains or rivers. Contain the spillage using bunding. Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. lcont...l Page 145 of 1069 Page 145 of 1069 Page 145 of 1069 Page 145 of 1069 ---PAGE BREAK--- lssued: 04/07/2008 SAFETY DATA SHEET CEB31600 CORPOMTE EXPRESS HAND CLEANING WIPES TUB 1OO Page 2 7. HANDLINGANDSTORAGE Storage conditions: Store in cool, well ventilated area. Keep container closed. Do not allow to freeze Suitable packaging: Must only be kept in original packaging. 8. EXPOSURE CONTROLS I PERSONAL.PROTECTION Workplace exposure limits WEL (15 min STEL): Respirable dust WEL (8 hrTWA): WEL (15 min STEL): Respiratory protection: Eye protection: 10 150 474 Respiratory protection not required. Ensure eye bath is to hand. 9. PHYSICALAND CHEMICAL PROPERTIES State: Colour: Odour: Solubility in water: Boiling poinUrange'C: Relative density: pH: Liquid Colourless Characteristic odour Soluble >1 00 1.00 - 1.10 5.3 - 5.7 10. STABILIW AND REACTIVIW Stability: Stable under normal conditions. Conditions to avoid: Do NOT freeze Materials to avold: Strong oxidising agents. Strong acids. 1 1. TOXICOLOGICAL INFORMATION Chronic toxicity: May cause irritation to the eyes Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding 1 2. ECOLOGICAL INFORMATION Mobility: Persistence and degradability: Bioaccumulative potential : Other adverse effects: Readily absorbed into soil Biodegradable. No data available. No data available. 1 3, DISPOSAL. CONSIDERATIONS NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. lcont...l Page 146 of 1069 Page 146 of 1069 Page 146 of 1069 Page 146 of 1069 ---PAGE BREAK--- lssued: 04/07/2008 SAFETY DATA SHEET CEB31600 CORPORATE EXPRESS HAND CLEANING WIPES TUB 1OO Page 3 14. INFORMATION ADR / RID UN no: Not Classified IMDG / IMO UN no: Not Classified. IATA/ ICAO UN no: Not Classified 1 5. REGULATORY INFORMATION Hazard symbols: Safety phrases: Note: No significant hazard. 52: Keeo out of the reach of children. The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page] Page 147 of 1069 Page 147 of 1069 Page 147 of 1069 Page 147 of 1069 ---PAGE BREAK--- Safety Data Sheet Century Compressed Gas Duster Section 1. Identification Product Identifier Century Compressed Gas Duster Synonyms CDS, CDS2CE, CDS4S, CDS2, CDS6, CDS7, CDS8, CDS10E, CDS12; CDS35, CDS82 Manufacturer Stock Numbers N/A Product Cas 75-37-6 Recommended use Dust Removal Uses advised against Use Only as Directed - Read label instructions carefully. Keep out of reach of children. Intentional misuse by deliberately concentrating and/or inhaling contents may be fatal. Manufacturer Contact Address Falcon Safety Products, Inc. 25 ImClone Drive Branchburg, NJ, 08876 USA Phone Emergency Phone Fax (908) 707-4900 (800) 498-7192 N/A Section 2. Hazards Identification Classification FLAMMABLE GASES - Category 2 GASES UNDER PRESSURE - Compressed gas Signal Word Warning Pictogram Hazard Statements Contains gas under pressure; may explode if heated Flammable gas Precautionary Statements Response Eliminate all ignition sources if safe to do so. Page 1 of 8 Page 148 of 1069 Page 148 of 1069 Page 148 of 1069 Page 148 of 1069 ---PAGE BREAK--- Occupational exposure limits, if available, are listed in Section 8. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Prevention Do not spray on an open flame or other ignition source. Keep away from heat. Pressurized container: Do not pierce or burn, even after use. Storage Protect from sunlight. Store in a well-ventilated place. Store at temperatures not exceeding 120 degrees F/49 degrees C Disposal N/A General Keep out of reach of children Ingredients of unknown toxicity 0% Hazards not Otherwise Classified N/A No Data Available Section 3. Ingredients CAS Ingredient Name Weight % 75-37-6 Ethane, 1,1-difluoro- 100 % Section 4. First-Aid Measures General Advice Never give anything by mouth to an unconscious person. When persist or in all cases of doubt, seek medical advice. Inhalation Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Skin Take off all contaminated clothing immediately. Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician. Eye Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion Is not considered a potential route of exposure. Most important acute and delayed Anaesthetic effects: light-headedness, irregular heartbeat with a strange sensation in the chest, heart thumping, apprehension, feeling of fainting, dizziness or weakness. Protection of First-aiders If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to Physician Because of possible disturbances of cardiac catecholamine drugs, such as epinephrine, which may be used in situations of emergency life support, should be used with special caution. Page 2 of 8 Page 149 of 1069 Page 149 of 1069 Page 149 of 1069 Page 149 of 1069 ---PAGE BREAK--- Section 5. Fire Fighting Measures Suitable Extinguishing Media Water spray, water fog, dry chemical, alcohol resistant foam, carbon dioxide (CO2) Unsuitable Extinguishing Media No applicable data available. Specific Hazards Flammable. This substance's fire decomposition by-products will include hydrofluoric acid and possibly carbonyl flouride. Avoid contact with these materials, which are toxic and irritating. Evacuate personnel immediately in the event of a fire involving this substance. Vapors may form explosive mixtures with air. Vapors are heavier than air and may spread along floors. Vapors or gases may travel considerable distances to ignition source and flash back. Special protective equipment for firefighters Use personal protective equipment. Wear neoprene gloves during cleaning up work after a fire. Exposure to decompositon products may be a hazard to health. Further Information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers/tanks with water spray. Section 6. Accidental Release Measures NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) Evacuate personnel to safe areas. Ventilate the area. Refer to protective measures listed in sections 7 and 8. Spill Clean-up If this product is spilled and not recovered, or is recovered as a waste for treatment and disposal, the CERCLA Reportable Quantity is 100 lbs. (release of an Unlisted Hazardous Waste with the Characteristic of Ignitability). Evaporates. Ventilate area using forced ventilation, especially low or enclosed places where heavy vapors might collect. Accidental Release Measures Wear self-contained breathing apparatus (SCBA). Section 7. Handling and Storage Handling (Personnel) Avoid breathing vapors or mist. Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. Handle in accordance with good industrial hygiene and safety practice. Handling (Physical Aspects) Vapors are heavier than air and may spread along floors. Vapors may form flammable mixture with air. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropirate standard. No sparking tools should be used. Take measures to prevent the build up of electrostatic charge. Keep away from open flames, hot surfaces and sources of ignition. When using DO NOT SMOKE. Do not use in areas where vapors may accumulate such as paper shredders. Dust Explosion class Not applicable Storage Keep container closed and in a dry, well-ventilated location. Store in original container. The product has an indefinite shelf life when stored properly. Storage Period Recommended shelf life - 10 years provided product is stored in a dry location as directed. Storage Temperature Do not expose to temperatures above 120 degrees F (49 degrees C) as overheating could cause can to burst. DO NOT leave in direct sunlight or enclosed vehicle. Page 3 of 8 Page 150 of 1069 Page 150 of 1069 Page 150 of 1069 Page 150 of 1069 ---PAGE BREAK--- Section 8. Exposure Controls/Personal Protection Occupational Exposure Limits Ingredient Name ACGIH TLV OSHA PEL STEL Ethane, 1,1-difluoro- N/A N/A N/A Personal Protective Equipment N/A Engineering controls Ensure adequate ventilation, especially in confined areas. Use respiratory protection if needed. Eye/Face Protection Wear safety glasses with side shields. Direct contact with liquid may cause frostbite. Respiratory Protection For rescue use self-contained breathing apparatus. Vapors are heavier than air and can cause suffication by reducing oxygen available for breathing. Skin and body protection As required by employer code. If there is risk of skin contact, wear protective clothing, gloves, etc. Direct contact with liquid can cause frostbite. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practices. Page 4 of 8 Page 151 of 1069 Page 151 of 1069 Page 151 of 1069 Page 151 of 1069 ---PAGE BREAK--- Section 9. Physical and Chemical Properties Physical State Gas Color Clear Odor slight, ether- like Odor Threshold No applicable data available Solubility Water - Partition coefficient Water/n-octanol N/A VOC% N/A Viscosity No applicable data available Specific Gravity 0.91 Density lbs/Gal 0.9 Pounds per Cubic Foot N/A Flash Point <-58°F C) FP Method N/A Ph Neutral Melting Point No applicable data available Boiling Point -13 °F (-25 ° C) Boiling Range N/A LEL 3.9 UEL 16.9 Evaporation Rate No applicable data available Flammability Flammable Decomposition Temperature N/A Auto-ignition Temperature No applicable data available Vapor Pressure 5,960 KPa at 77F (25C) Vapor Density 2.4 at 77F (25C) (Air=1) Section 10. Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical Stability The product is chemically stable under recommended storage conditions. Conditions to Avoid Aerosol containers are unstable at temperatures above 120 degrees F/49 degrees C Incompatible Materials Incompatible products include Alkali metals, Alkaline earth metals, powdered metals, powdered metal salts. Hazardous Decomposition Products Decomposition products are hazardous. This material can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrofluoric acid and possibly carbonyl fluoride. Page 5 of 8 Page 152 of 1069 Page 152 of 1069 Page 152 of 1069 Page 152 of 1069 ---PAGE BREAK--- Section 11. Toxicological Information Component Analysis - LC50 1,1-Difluoroethane - > 64000 ppm rat Component analysis - Oral LD50 1,1-Difluoroethane - 1500 mg/kg rat Effects of Acute Exposure - Eye Contact with liquid may cause frostbite Effects of Acute Exposure - Skin Contact with liquid may cause frostbite Effects of Acute Exposure - Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effect (headaches, dizziness). Vapors may cause dizziness or suffocation. Effects of Acute Exposure - Ingestion Not a normal route of exposure Sensitization Non-hazardous by WHMIS/OSHA criteria. Carcinogenicity Not classifiable as a human carcinogen. Animal testing did not show carcinogenic effects. None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA as a carcinogen. Mutagenicity Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Tests on mammalian cell cultures showed mutagenic effects. Reproductive Toxicity No toxcicity to reproduction. Animal testing showed no reproductive toxicity. Teratogenicity Animal testing showed no developmental toxicity. Further Information Cardiac sensitization threshold limit: 405000 mg/m3 Section 12. Ecological Information Aquatic Toxicity 1,1-Difluoroethane 96 h LC50 : Fish 295.78 mg/l 96 h EC50 : Algae 47.76 mg/l 48 h EC50 : Daphnia (water flea) 146.7 mg/l Section 13. Disposal Waste Disposal Methods Comply with applicable Federal, State/Provincial and Local Regulations. May be a RCRA Hazardous waste due to the ignitability characteristic. Do not puncture or incinerate container. Contaminated Packaging Not Available Page 6 of 8 Page 153 of 1069 Page 153 of 1069 Page 153 of 1069 Page 153 of 1069 ---PAGE BREAK--- Section 14. Transport Information UN Number 1030 UN Proper Shipping Name 1,1-Difluoroethane DOT Classification 2.1 Packing Group N/A Packaging Exceptions Note: Falcon Safety Products has been granted a DOT special permit. A copy of DOT Special Permit SP-11516 can be obtained by calling Falcon Safety Products, Inc. at [PHONE REDACTED]. Transportation of Dangerous Goods (TDG - Canada) Proper Shipping name: 1,1-Difluoroethane Hazard Class: 2.1 UN number: 1030 Packaging Exceptions: Limited quantity (containers up to 125mL) IATA/ICAO (Air) Proper Shipping Name: 1,1-Difuoroethane. Hazard Class: 2.1. UN Number: 1030. Maximum Net Quantity Packaging: Cargo Aircraft only - 150 kg maximum (forbidden on passenger aircraft). Maximum Net Quantity packaging cargo only: 150 kg. IMDG (Marine Transport) Proper Shipping Name: 1,1-DIFLUOROETHANE. Hazard Class: 2.1. UN Number: 1030. Additional Information TDG Canada: Falcon Safety Products has been granted Equivalency Certificate SU 9211 (ren. 1) by the TCSS, TDGD to offer for transport by road, rail and marine. Section 15. Regulatory Information Canadian Federal Regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. WHMIS Status Controlled WHMIS Classification Class A - Compressed Gas, Class B - Division 1 - Flammable Gas TSCA On the inventory, or in compliance with the inventory. SARA 313 Regulated Chemical(s) This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. NJ Right to Know Regulated Chemical(s) Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): 1,1-Difluoroethane. California Prop. 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Canada Domestic Substances List (DSL) This product is listed on the DSL inventory list and complies with the inventory requirements administered by the governing country. Page 7 of 8 Page 154 of 1069 Page 154 of 1069 Page 154 of 1069 Page 154 of 1069 ---PAGE BREAK--- Section 16. Other Information Revision Date 4/28/2015 Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Prepared By Falcon Safety Products, Inc. [PHONE REDACTED] Page 8 of 8 Page 155 of 1069 Page 155 of 1069 Page 155 of 1069 Page 155 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 1 of 11 SAFETY DATA SHEET 1. Identification Product Identifier: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) Synonyms: Clindamycin 2-dihydrogen phosphate National Drug Code (NDC): 61748-201-60 (60 Pledgets in a jar) Recommended Use: Pharmaceutical. Company: Akorn, Inc. 1925 West Field Court, Suite 300 Lake Forest, Illinois 60045 Contact Telephone: 1-[PHONE REDACTED] E mail: [EMAIL REDACTED] Emergency Phone Number: CHEMTREC 1-[PHONE REDACTED] (U.S. and Canada) 2. Hazard(s) Identification Physical Hazards: Flammable liquid Category 3 Health Hazards: Serious Eye Damage/Eye Irritation Category 2A Skin Sensitization Category 1 Specific target organ systemic Category toxicity (single exposure) Symbol(s): Signal Word: Warning. Hazard Statement(s): H226 Flammable liquid and vapor. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H336 May cause drowsiness and dizziness. Page 156 of 1069 Page 156 of 1069 Page 156 of 1069 Page 156 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 2 of 11 Precautionary Statement(s): P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 Keep container closed. P240 Ground/Bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/protective clothing/eye protection/face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P403 + P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container in accordance with all local and national regulations. P264 Wash hands thoroughly after handling. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P272 Contaminated work clothing should not be allowed out of the workplace. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. Page 157 of 1069 Page 157 of 1069 Page 157 of 1069 Page 157 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 3 of 11 P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P321 Specific treatment (see supplemental instructions on the administration of antidotes on this label). P363 Wash contaminated clothing before reuse. Hazards Not Otherwise Classified: No data available. Supplementary Information: None. 3. Composition/Information on Ingredients Chemical Name CAS Number Synonyms Chemical Formula Molecular Weight Percentage Clindamycin Phosphate 24729-96-2 Clindamycin 2-dihydrogen phosphate C18H34ClN2O8PS 504.96 1% *The formula also contains Isopropyl Alcohol 50% v/v, Propylene Glycol, Sodium Hydroxide (to adjust the pH to between 4.0 – 7.0) and Purified Water. 4. First Aid Measures Ingestion: If a person vomits place them in the recovery position so that vomit will not reenter the mouth and throat. Rinse mouth with water. If swallowed, seek medical advice immediately and show the container or label. Treat and supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Eye Contact: Remove from source of exposure. Flush with copious amounts of water for at least 15 minutes. If irritation persists or signs of toxicity occur, seek medical attention. Provide care as necessary. Ensure that medical personnel are aware of the material(s) involved and are aware of precautions to protect themselves. Skin Contact: Remove from source of exposure. Remove and isolate contaminated clothing and shoes. Flush with copious amounts of water for at least 20 minutes. Use soap. If irritation persists or signs of toxicity occur, seek medical attention. Provide care as necessary. Ensure that medical personnel are aware of the material(s) involved and are aware of precautions to protect themselves. Page 158 of 1069 Page 158 of 1069 Page 158 of 1069 Page 158 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 4 of 11 Inhalation: Remove from source of exposure. Move individual(s) to fresh air. Give artificial respiration if individual(s) are not breathing and call emergency medical service. If signs of toxicity occur, seek medical attention. Provide care as necessary. Ensure that medical personnel are aware of the material(s) involved and are aware of precautions to protect themselves. Protection of First-Aiders: Use personal protective equipment (see section Signs and For information on potential signs and of exposure, See Section 2 – Hazards Identification and/or Section 11 - Toxicological Information. Medical Conditions Aggravated by Exposure: None known. Notes to Physician: None. 5. Firefighting Measures Suitable Extinguishing Media: Extinguish fires with CO2, extinguishing powder, foam, or water. Unsuitable Extinguishing Media: Not determined. Specific Hazards Arising from the Chemical: Hazardous Combustion Products: Emits toxic fumes of carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides and other sulfur-containing compounds. Other Specific Hazards: Flammable liquid. Vapors will form flammable or explosive mixtures with air at room temperature. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. Special Protective Equipment/ Precautions for Firefighters: Wear self-contained breathing apparatus and full and protective gear. 6. Accidental Release Measures Personal Precautions: Use personal protective equipment recommended in Section 8 of this document and isolate the hazard area. Personal Protective Equipment: For personal protection see section 8. Methods for Cleaning Up: Eliminate possible ignition sources heat, sparks, flame, impact, friction, electricity). Contain the source of spill if it is safe to do so. Collect spill with absorbent material. Clean spill area thoroughly. Environmental Precautions: Place waste in an appropriately labeled, sealed container for disposal. Care should be taken to avoid environmental release. Page 159 of 1069 Page 159 of 1069 Page 159 of 1069 Page 159 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 5 of 11 Reference to Other Sections: Refer to Sections 8, 12 and 13 for further information. 7. Handling and Storage Precautions for Safe Handling: Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. When handling, use appropriate personal protective equipment (see section Wash hands and any exposed skin after removal of PPE. Release to the environment should be avoided. Review and implement appropriate technical and procedural waste water and waste disposal measures to prevent occupational exposure or environmental releases. Potential points of process emissions of this material to the atmosphere should be controlled with dust collectors, HEPA filtration systems or other equivalent controls. Handle in accordance with product label and/or product insert information. Handle in accordance with good industrial hygiene and safety practices. Conditions for Safe Storage, Including Any Incompatibilities: Store according to label and/or product insert information. Store away from oxidizing agents and acids. Specific End Use: Pharmaceuticals. 8. Exposure Controls/Personal Protection Occupational Exposure Guidelines: Common or Chemical Name Employee Exposure Limits Isopropyl Alcohol ACGIH Threshold Limit Value (TWA) 200 ppm ACGIH Threshold Limit Value (STEL) 400 ppm ACGIH - Biological Exposure Limit: 40 mg/L OSHA - Final PELS - TWAs: 400 ppm; 980 mg/m3 Clindamycin Phosphate Pfizer OEL: 100μg/m3, 8 Hour TWA Engineering Controls: Engineering controls should be used as the primary means to control exposures. General room ventilation is adequate unless the process generates dust, mist or fumes. Keep airborne contamination levels below the exposure limits listed above in this section. Respiratory Protection: Where respirators are deemed necessary to reduce or control occupational exposures, use NIOSH-approved respiratory protection and have an effective respirator program in place (applicable U.S. regulation OSHA 29 CFR 1910.134). Eyes Protection: Not required for the normal use of this product. Safety glasses with side shields are recommended. Face shields or goggles may be required if splash potential exists or if corrosive materials are present. Approved eye protection bearing the ANSI Z87 or CSA stamp) is preferred. Maintain eyewash facilities in the work area. Page 160 of 1069 Page 160 of 1069 Page 160 of 1069 Page 160 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 6 of 11 Hand Protection: Not required for the normal use of this product. Chemically compatible gloves. For handling solutions, ensure that the glove material is protective against the solvent being used. Use handling practices that minimize direct hand contact. Employees who are sensitive to natural rubber (latex) should use nitrile or other non-latex gloves. Use of powdered latex gloves should be avoided due to the risk of latex allergy. Skin Protection: Not required for the normal use of this product. Wear protective laboratory coat, apron, or disposable garment when working with large quantities. 9. Physical and Chemical Properties Physical State/Color: Clear, colorless liquid. Odor: Characteristic alcohol odor. Odor Threshold: No data available. pH: 4.0 – 7.0. Melting Point: No data available. Freezing Point: No data available. Boiling Point: Refluxes at 55°C (131°F). Flash Point: 24°C (73.4°F). Evaporation Rate: 0.26. Flammability (solid, gas): No data available. Flammability Limit - Lower: 2. Flammability Limit - Upper: 12.7. Vapor Pressure: No data available. Vapor Density: No data available. Relative Density: No data available. Solubility(ies): Soluble in water. Partition Coefficient (n-octanol/water): No data available. Auto-Ignition Temperature: No data available. Decomposition Temperature: No data available. Viscosity: No data available. 10. Stability and Reactivity Reactivity: No data available. Chemical Stability: Stable under recommended storage conditions. Possibility of Hazardous Reactions: No data available. Conditions to Avoid static discharge, shock, or vibration): Keep away from heat, spark, flames and all other sources of ignition. Fine particles (such as dust and mists) may fuel fires/explosions. Incompatible Materials: Oxidizing agents, Acids, Bases. Page 161 of 1069 Page 161 of 1069 Page 161 of 1069 Page 161 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 7 of 11 Hazardous Decomposition Products: If exposed to extremely high temperatures, thermal decomposition may generate irritating fumes and toxic gases carbon oxides, nitrogen oxides, phosphorus oxides, sulfur oxides, and hydrogen chloride). 11. Toxicological Information Information on the Likely Routes of Exposure: Inhalation: Breathing high vapor concentrations may cause central nervous system (CNS) depression resulting in dizziness, light-headedness, headache, nausea, and loss of coordination. Continued inhalation may result in unconsciousness and death. Ingestion: May be harmful if swallowed. Skin Contact: May cause skin irritation. Eye Contact: Vapors irritating to eyes and respiratory tract. Known Clinical Effects: Individuals sensitive to this material or other materials in its chemical class may develop allergic reactions. Clinical use of this drug has caused sore throat, fever, gastrointestinal disturbances, abnormal liver function tests, kidney dysfunction. Pseudomembranous colitis (manifested by watery diarrhea, urge to defecate, abdominal cramps, low-grade fever, bloody stools, and abdominal pain) may also occur. Related to the Physical, Chemical and Toxicological Characteristics: See Section 4. To the best of our knowledge, the chemical, physical and toxicological properties have not been thoroughly investigated. Delayed and Immediate Effects of Exposure: No data available. Acute Toxicity: Compound Species Route Test Type Dose Clindamycin Phosphate Rat Oral LD50 1,832 mg/kg Clindamycin Phosphate Rat Para-periosteal LD50 321 mg/kg Clindamycin Phosphate Rat Intraperitoneal LD50 745 mg/kg Clindamycin Phosphate Mouse Oral LD50 2,359 mg/kg Clindamycin Phosphate Mouse Intravenous LD50 820 mg/kg Isopropyl Alcohol Rat Oral LD50 >2,000 mg/kg Isopropyl Alcohol Mouse Oral LD50 3,600 mg/kg Isopropyl Alcohol Rat Inhalation LC50-8h 16,000 ppm Isopropyl Alcohol Rabbit Dermal LD50 12,800 mg/kg Isopropyl Alcohol Rat Inhalation LC50 30 mg/L Acute Toxicity Comments: A greater than symbol indicates that the toxicity endpoint being tested was not achievable at the highest dose used in the test. Page 162 of 1069 Page 162 of 1069 Page 162 of 1069 Page 162 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 8 of 11 Irritation/Sensitization: Compound Species Study Type Severity Clindamycin Phosphate Rabbit Eye irritation Moderate Clindamycin Phosphate Rabbit Skin irritation Mild Isopropyl Alcohol Rabbit Eye irritation Severe Isopropyl Alcohol Rabbit Skin irritation Mild Propylene Glycol Rabbit Eye irritation Mild Propylene Glycol Rabbit Skin irritation Mild Repeated Dose Toxicity: Compound Species Route End Point Dose Duration Target Organ Clindamycin Phosphate Rat Oral NOAEL 600 mg/kg/d 6 Month(s) No effects at maximum dose Clindamycin Phosphate Dog Oral NOAEL 600 mg/kg/d 6 Month(s) Gastrointestinal system Isopropyl Alcohol Rat Inhalation NOAEL 4,000 ppm 20 Week(s) Liver, Central nervous system Isopropyl Alcohol Rat Inhalation NOAEL 5,000 ppm 104 Week(s) Kidney Reproduction & Development Toxicity: Compound Study Type Species Route End Point Dose Effect(s) Clindamycin Phosphate Prenatal & Postnatal Development Rat Subcutaneous NOAEL 250 mg/kg Not Teratogenic Clindamycin Phosphate Prenatal & Postnatal Development Rat Oral NOAEL 300 mg/kg/d Not Teratogenic Clindamycin Phosphate Parental & Postnatal Development Mouse Oral NOAEL 600 mg/kg/d Not Teratogenic Clindamycin Phosphate Parental & Postnatal Development Rabbit Subcutaneous NOAEL 5 mg/kg/d Not Teratogenic, Maternal Toxicity Clindamycin Phosphate Reproductive & Fertility Rat Oral NOAEL 300 mg/kg/d No effects at maximum dose Isopropyl Alcohol Parental & Postnatal Development Rat Inhalation LOAEL 7,000 ppm Maternal Toxicity, Fetotoxicity, Embryotoxicity Isopropyl Alcohol Parental & Postnatal Development Rat Oral LOAEL 1,200 mg/kg/d No effects at maximum dose Isopropyl Alcohol 2 Generation Reproductive Toxicity Rat Oral LOAEL 1,000 mg/kg/d Maternal Toxicity, Fetal morality Page 163 of 1069 Page 163 of 1069 Page 163 of 1069 Page 163 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 9 of 11 Genetic Toxicity: Compound Study Type Cell Type/Organism Results Clindamycin Phosphate Bacterial Mutagenicity (Ames) Salmonella Negative Clindamycin Phosphate In Vitro Micronucleus Rat Negative Isopropyl Alcohol Bacterial Mutagenicity (Ames) Salmonella Negative Isopropyl Alcohol Mammalian Cell Mutagenicity Chinese Hamster Ovary (CHO) cells Negative Isopropyl Alcohol In Vitro Sister Chromatid Exchange N/A Negative Acute Toxicity – Dermal: No data available. Acute Toxicity – Inhalation: No data available. Corrosivity: No data available. Dermal Irritation: No data available. Eye Irritation: No data available. Sensitization: No data available. Toxicokinetics/Metabolism: No data available. Target Organ Effects: No data available. Reproductive Effects: No data available. Carcinogenicity: None. National Toxicology Program (NTP): Not considered to be a carcinogen. International Agency for Research on Cancer (IARC): Group 3. Not considered to be a carcinogen. Occupational Safety and Health Administration (OSHA): Not considered to be a carcinogen. Mutagenicity: No data available. Aspiration Hazard: Based on available data, the classification criteria are not met. 12. Ecological Information Ecotoxicity Aquatic: Clindamycin phosphate is freely soluble in water (1 g in 2.5-mL water). Based on its solubility data, clindamycin phosphate is expected to be relatively mobile and migrate toward the aquatic compartment. Terrestrial: No data available. Persistence and Degradability: No data available. Bioaccumulative Potential: The octanol/water partition coefficient of Clindamycin Phosphate is not known. However, based on its water solubility, it would be expected to be less than 3 and thus, would have a low potential to bioaccumulate in aquatic organisms. Mobility in Soil: No data available. Page 164 of 1069 Page 164 of 1069 Page 164 of 1069 Page 164 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 10 of 11 Mobility in Environment: Clindamycin phosphate melts with decomposition at approximately 142°C. It has no measurable vapor pressure; therefore it is not expected to enter the air. Other Adverse Effects: No data available. 13. Disposal Considerations Dispose of all waste in accordance with Federal, State and Local regulations. 14. Transport Information UN Number: UN 1993 UN Proper Shipping Name: Flammable liquid, n.o.s. (contains isopropanol) Transport Hazard Class(es): 3 Packing Group: III Flash Point 24 Exceptions: For small quantities packed in combination packaging, exceptions, may apply. Please refer to the applicable dangerous goods regulations for additional information. Department of Transportation: Regulated as a hazardous material. International Air Transport Association (IATA): Regulated as a dangerous good. International Maritime Dangerous Good (IMDG): Regulated as a dangerous good. 15. Regulatory Information US Federal Regulations: Toxic Substance Control Act (TSCA): Isopropyl Alcohol: Listed. CERCLA Hazardous Substance and Reportable Quantity: Isopropyl Alcohol: SARA 313: Isopropyl Alcohol: Listed. SARA 302: Not listed. WHMIS - Canada: Class B, Division 2 Class D, Division 2, Subdivision B State Regulations California Proposition 65: Not listed. Page 165 of 1069 Page 165 of 1069 Page 165 of 1069 Page 165 of 1069 ---PAGE BREAK--- SDS: Clindamycin Phosphate Topical Solution USP, 1% (Pledgets) 11 of 11 16. Other Information Revision Date: 04/29/2015 Revision Number: 1 Disclaimer: This document is generated to distribute health, safety and environmental data. It is not a specification sheet and none of the displayed data should be construed as a specification. Information on this SDS sheet was obtained from sources which we believe are reliable, and we believe that the information is complete and accurate. However, the information is provided without any warranty, express or implied, regarding its correctness. Some of the information presented and conclusions drawn are from sources other than direct test data of the substance. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may also be beyond our knowledge. It is the user’s responsibility to determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary. If the product is used as a component in another product, this SDS information may not be applicable. For these reasons, we do not assume any responsibility and expressly disclaim liability for any loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this product. Page 166 of 1069 Page 166 of 1069 Page 166 of 1069 Page 166 of 1069 ---PAGE BREAK--- Page 167 of 1069 Page 167 of 1069 Page 167 of 1069 Page 167 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Date June 12, 2015 Revision Number 1 Page 1 / 10 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox Commercial Solutions® Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Other means of identification EPA Registration Number 67619-17 Recommended use of the chemical and restrictions on use Recommended use Disinfecting bleach spray cleaner Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612 Phone: 1-[PHONE REDACTED] Emergency telephone number Emergency Phone Numbers For Medical Emergencies, call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] Page 168 of 1069 Page 168 of 1069 Page 168 of 1069 Page 168 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 2 / 10 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Skin corrosion/irritation Category 3 Serious eye damage/eye irritation Category 2A GHS Label elements, including precautionary statements Emergency Overview Signal word Warning Hazard Statements Causes mild skin irritation Causes serious eye irritation Appearance Clear, pale yellow Physical State Liquid Odor Citrus, herbaceous, bleach Precautionary Statements - Prevention Wash hands and any exposed skin thoroughly after handling. Wear eye protection/face protection such as safety glasses. Precautionary Statements - Response Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin If skin irritation occurs: Get medical advice/attention. Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) The following medical conditions may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, or obstructive lung disease. Unknown Toxicity 0.08% of the mixture consists of ingredient(s) of unknown toxicity Other information Toxic to aquatic life with long lasting effects Page 169 of 1069 Page 169 of 1069 Page 169 of 1069 Page 169 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 3 / 10 Interactions with Other Chemicals Reacts with other household chemicals such as products containing ammonia, toilet bowl cleaners, rust removers, or acids to produce hazardous gases, such as chlorine and other chlorinated compounds. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Trade Secret Sodium hypochlorite 7681-52-9 1 - 5 * Sodium hydroxide 1310-73-2 0.1 - 1 * * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Get medical attention if irritation develops and persists. Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. If irritation develops, call a doctor. Inhalation Move to fresh air. If breathing is affected, call a doctor. Ingestion Call a poison control center or doctor immediately. Have person sip a glassful of water if able to swallow. DO NOT induce vomiting unless told to do so by a poison control center or doctor. Protection of First-aiders Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section Most important and effects, both acute and delayed Most Important and Effects Stinging and irritation of eyes. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat Page 170 of 1069 Page 170 of 1069 Page 170 of 1069 Page 170 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 4 / 10 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical No information available. Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes, skin, and clothing. Use personal protective equipment as required. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers closed in a dry, cool and well-ventilated place. Incompatible Products Products containing ammonia, toilet bowl cleaners, rust removers, or acids. Page 171 of 1069 Page 171 of 1069 Page 171 of 1069 Page 171 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 5 / 10 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m 3 TWA: 2 mg/m 3 IDLH: 10 mg/m 3 Ceiling: 2 mg/m 3 Sodium hypochlorite 7681-52-9 None None None ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection If splashes are likely to occur: Wear safety glasses with side shields (or goggles). None required for consumer use. Skin and Body Protection Wear protective gloves and protective clothing. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Page 172 of 1069 Page 172 of 1069 Page 172 of 1069 Page 172 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 6 / 10 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Liquid Appearance Clear Odor Citrus, herbaceous, bleach Color Pale yellow Odor Threshold No information available Property Values Remarks/ Method pH 12.4 - 12.8 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point Not flammable None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.03 None known Water Solubility Soluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available 10. STABILITY AND REACTIVITY Reactivity Reacts with other household chemicals such as products containing ammonia, toilet bowl cleaners, rust removers, or acids to produce hazardous gases, such as chlorine and other chlorinated compounds. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials Products containing ammonia, toilet bowl cleaners, rust removers, vinegar, or acids. Hazardous Decomposition Products None known based on information supplied. Page 173 of 1069 Page 173 of 1069 Page 173 of 1069 Page 173 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 7 / 10 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Exposure to vapor or mist may irritate respiratory tract. Eye Contact May cause eye irritation. Skin Contact Prolonged contact may cause irritation. Ingestion Ingestion may cause irritation to mucous membranes and gastrointestinal tract, nausea, vomiting, and diarrhea. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium hypochlorite 7681-52-9 8200 mg/kg (Rat) >10000 mg/kg (Rabbit) - Sodium hydroxide 1310-73-2 - 1350 mg/kg (Rabbit) - Information on toxicological effects May cause redness and tearing of the eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Mutagenic Effects No information available. No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Sodium hypochlorite 7681-52-9 - Group 3 - - IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Carcinogenic potential is unknown. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI). Aspiration Hazard No information available. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document Not applicable Page 174 of 1069 Page 174 of 1069 Page 174 of 1069 Page 174 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 8 / 10 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life with long lasting effects. Persistence and Degradability No information available. Bioaccumulation No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Not restricted. TDG Not restricted for road or rail. ICAO Not restricted, as per Special Provision A197, Environmentally Hazardous Substance exception. IATA Not restricted, as per Special Provision A197, Environmentally Hazardous Substance exception. IMDG/IMO Not restricted, as per IMDG Code 2.10.2.7, Marine Pollutant exception. 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Page 175 of 1069 Page 175 of 1069 Page 175 of 1069 Page 175 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 9 / 10 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium hypochlorite 7681-52-9 100 lb X Sodium hydroxide 1310-73-2 1000 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Sodium hypochlorite 7681-52-9 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ Sodium hydroxide 1310-73-2 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: WARNING: EYE AND SKIN IRRITANT. Causes substantial but temporary eye injury. Do not get in eyes or on clothing. Avoid contact with skin. Wear protective eyewear. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. Harmful if swallowed. For sensitive skin or prolonged use, wear gloves. Vapors may irritate. Avoid prolonged breathing of vapors. Use only in well ventilated areas. Not recommended for use by persons with heart conditions or chronic respiratory problems such as asthma, or obstructive lung disease. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Sodium hypochlorite 7681-52-9 X X X X Sodium hydroxide 1310-73-2 X X X X Page 176 of 1069 Page 176 of 1069 Page 176 of 1069 Page 176 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015 Page 10 / 10 International Regulations Canada WHMIS Hazard Class D2B - Toxic materials 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 2 Flammability 0 Physical Hazard 0 Personal Protection B Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Revision Date June 12, 2015 Revision Note Reference Revisions Sections 8 and 14. 1103369/50546003.004 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 177 of 1069 Page 177 of 1069 Page 177 of 1069 Page 177 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date May 23, 2015 Revision Date New Revision Number 0 Page 1 / 9 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended use Ready-to-use general purpose cleaner dilution from the Clorox® EZ Dilute™ system Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612 Phone: 1-[PHONE REDACTED] Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] Page 178 of 1069 Page 178 of 1069 Page 178 of 1069 Page 178 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 2 / 9 2. HAZARDS IDENTIFICATION Classification This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). GHS Label elements, including precautionary statements Emergency Overview This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Appearance Clear, colorless-to-very-light green Physical State Thin liquid Odor Lemon Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0.3% of the mixture consists of ingredient(s) of unknown toxicity Other information May cause slight eye irritation. Interactions with Other Chemicals No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS This product contains no substances that at their given concentrations are considered to be hazardous to health. Page 179 of 1069 Page 179 of 1069 Page 179 of 1069 Page 179 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 3 / 9 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15–20 minutes. If present, remove contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing problems develop, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Most important and effects, both acute and delayed Most Important and Effects May cause slight eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Hazardous Combustion Products Oxides of carbon. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 180 of 1069 Page 180 of 1069 Page 180 of 1069 Page 180 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 4 / 9 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers closed. Incompatible Products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product does not contain any ingredients with occupational exposure limits that are at concentrations below their cut-off values/concentrations and that contribute to the hazard classification of the product. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Page 181 of 1069 Page 181 of 1069 Page 181 of 1069 Page 181 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 5 / 9 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid Appearance Clear Odor Lemon Color Colorless-to-very- light green Odor Threshold No information available Property Values Remarks/ Method pH 6 - 9 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point No data available None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.0 None known Water Solubility Complete None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None known. Conditions to avoid None known. Incompatible materials None known. Hazardous Decomposition Products None known. Page 182 of 1069 Page 182 of 1069 Page 182 of 1069 Page 182 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 6 / 9 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Exposure to vapor or mist may cause slight respiratory tract irritation Eye Contact May cause slight irritation. Skin Contact May cause slight irritation. Ingestion Ingestion of liquid may cause slight irritation to mucous membranes and gastrointestinal tract. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Ethanol 64-17-5 - - 125 mg/L (Rat, 4 h) Information on toxicological effects May cause slight redness and tearing of eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage. Chemical Name ACGIH IARC NTP OSHA Ethanol 64-17-5 A3 Group 1 Known X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Contains a known or suspected carcinogen. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage. Contains a known or suspected reproductive toxin. Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Repeated abuse can have long-term health effects. Target Organ Effects Eyes, blood, central nervous system (CNS), liver, reproductive system, respiratory system. Page 183 of 1069 Page 183 of 1069 Page 183 of 1069 Page 183 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 7 / 9 Aspiration Hazard Not an aspiration hazard. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document No information available. 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Ethanol 64-17-5 LC50: 12.0 - 16.0 mL/L (96 h static) mykiss LC50: 13400 - 15100 mg/L (96 h flow-through) Pimephales promelas LC50: > 100 mg/L (96 h static) Pimephales promelas EC50 = 34634 mg/L 30 min EC50 = 35470 mg/L 5 min LC50: 9268 - 14221 mg/L (48 h ) Daphnia magna EC50: 10800 mg/L (24 h ) Daphnia magna EC50: 2 mg/L (48 h Static) Daphnia magna Persistence and Degradability No information available. Bioaccumulation Chemical Name Log Pow Ethanol 64-17-5 -0.32 Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Not regulated. TDG Not regulated. ICAO Not regulated. IATA Not regulated IMDG/IMO Not regulated Page 184 of 1069 Page 184 of 1069 Page 184 of 1069 Page 184 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 8 / 9 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. US State Regulations California Proposition 65 This product contains the following Proposition 65 chemical. Ethyl alcohol is only a considered a Proposition 65 developmental and cancer hazard when it is ingested as an alcoholic beverage. Chemical Name California Proposition 65 Ethanol 64-17-5 Developmental Cancer U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Ethanol 64-17-5 X International Regulations Canada WHMIS Hazard Class Not controlled. Page 185 of 1069 Page 185 of 1069 Page 185 of 1069 Page 185 of 1069 ---PAGE BREAK--- Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Revision Date New Page 9 / 9 16. OTHER INFORMATION NFPA Health Hazard 0 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 0 Flammability 0 Physical Hazard 0 Personal Protection - Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Preparation/Revision Date May 23, 2015 Revision Note Reference New INT0049 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 186 of 1069 Page 186 of 1069 Page 186 of 1069 Page 186 of 1069 ---PAGE BREAK--- The Clorox Company of Canada, Ltd. Material Safety 150 Biscayne Crescent Data Sheet Brampton, Ontario L6W 4V3 SECTION 1 - PRODUCT IDENTIFICATION AND USE PRODUCT NAME: CLOROX® COMMERCIAL SOLUTIONS™ ULTRA CLOROX® DISINFECTING BLEACH - DIN 02333007 PRODUCT IDENTIFICATION NUMBER: Not applicable. PRODUCT USE: Hard surface disinfecting bleach MANUFACTURER SUPPLIER The Clorox Company of Canada, Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3 EMERGENCY PHONE NO.: 1-[PHONE REDACTED] The Clorox Company of Canada, Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3 EMERGENCY PHONE NO.: 1-[PHONE REDACTED] SECTION 2 - HAZARDOUS INGREDIENTS Hazardous Ingredient % (w/w) CAS Number LD50 of Material (Specify Species & Route) LC50 of Material (Specify Species) Sodium hypochlorite 5 - 8 7681-52-9 13 g/kg (5.25% NaOCl, rat, oral) Not available. SECTION 3 - PHYSICAL DATA Physical State: Liquid Odour & Appearance: Clear, lime-yellow, thin liquid with characteristic bleach odour. Odour Threshold: Not available. Specific Gravity: 1.1 at 20°C Vapour Pressure: Not available. Vapour Density: N. Av. Evaporation Rate: N. Av. Boiling Point: N. Av. Freezing Point: N. Av. % Volatile (by volume): 85 - 90 Solubility in Water: Complete. pH: 11 - 12 Coeff. of Water/Oil Dist.: Not available. SECTION 4 - FIRE AND EXPLOSION DATA Flammability: Yes: No: X If yes, under which conditions? Means of Extinction: Not flammable. Special Procedures: In a fire, cool containers to prevent rupture and release of sodium chlorate. Flashpoint & Method: Not applicable. Upper Flammable Limit by volume): Not applicable. Lower Flammable Limit by volume): Not applicable. Autoignition Temperature: N. Ap. Hazardous Combustion Products: Not applicable. Explosion Data - Sensitivity to Impact: Not applicable. Explosion Data - Sensitivity to Static Discharge: Not applicable. SECTION 5 - REACTIVITY DATA Chemical Stability: Yes: X No: If no, under which conditions? Incompatibility with other substances: Yes: X No: If so, which ones? Reacts with other chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Avoid contact with metals, reducing agents, and other oxidizing agents. Reactivity, if any, and under what conditions? See above. Hazardous decomposition products? Exposure to extreme heat may release sodium chlorate. Clorox® Commercial Solutions™ Ultra Clorox® Disinfecting Bleach, Page 1 of 2 Page 187 of 1069 Page 187 of 1069 Page 187 of 1069 Page 187 of 1069 ---PAGE BREAK--- SECTION 6 - TOXICOLOGICAL PROPERTIES Route of Entry? Skin Contact: X Skin Absorption: Eye Contact: X Inhalation Acute: X Inhalation Chronic: Ingestion: X . Effects of Acute Exposure to Material: May cause severe irritation or damage (burns) to eyes, skin, gastrointestinal tract, and respiratory tract. Harmful if swallowed. Exposure to high concentrations of vapour or mist may aggravate the following medical conditions: heart conditions or chronic respiratory problems such as asthma, chronic bronchitis, or obstructive lung disease. Effects of Chronic Exposure to Material: See Sensitization section below. Exposure Limits (TLV, ACGIH): Not applicable. Irritancy of Material: Corrosive to eyes. Severely irritating or corrosive to skin, nose, lungs, throat, and gastrointestinal tract. Sensitization Property of Material: Some clinical reports suggest a low potential for skin sensitization upon exaggerated exposure to sodium hypochlorite if skin damage occurs during exposure. Carcinogenicity of Material: Not a carcinogen. Teratogenicity/Embryotoxicity: Not teratogenic or embryotoxic. Reproductive Toxicity: Not a reproductive toxicant. Mutagenicity: Not mutagenic. Synergistic Materials: None known. SECTION 7 - PREVENTATIVE MEASURES Personal Protective Equipment: Gloves (specify): Wear nitrile, neoprene, butyl rubber, or other protective gloves. Respirator (specify): In situations where high concentrations of vapour or mist may be generated, a NIOSH-approved respirator is advised. Eye (specify): Safety glasses. Footwear (specify): Not applicable. Clothing (specify): Not applicable. Other (specify): Not applicable. Engineering Controls (specify, e.g. ventilation, enclosed process): Use general ventilation to minimize exposure to product vapour or mist. Leak and Spill Procedure: Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. For spills of multiple products, responders should evaluate the MSDS’s of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed and/or poorly-ventilated areas until hazard assessment is complete. Waste Disposal: Dispose of in accordance with existing federal, provincial, and municipal environmental regulations. Handling Procedures & Equipment: Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Do not reuse empty container. Rinse container and replace cap before recycling or discarding. Storage Requirements: STORE AWAY FROM CHILDREN. Reclose cap after each use. Store this product upright in a cool, dry area away from direct sunlight and heat to avoid deterioration. Special Shipping Information: Not restricted per TDG regulations. SECTION 8 - FIRST AID MEASURES Eye Contact: If in eyes, rinse with water for 15 minutes. Call a doctor immediately. Skin Contact: If on skin, rinse well with water. If on clothes, remove clothes. If irritation persists, call a doctor. Ingestion: If swallowed, call a poison control centre or doctor immediately. Do not induce vomiting. Inhalation: If breathed in, move person to fresh air. If breathing problems develop, call a doctor. SECTION 9 - PREPARATION DATE OF MSDS Prepared by (group, department, etc.) Phone Number: Date: Clorox Services Company 1-[PHONE REDACTED] July 19, 2013 V1 This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of The Clorox Company of Canada, Ltd. The data on these sheets relates only to the specific material designated herein. The Clorox Company of Canada, Ltd. assumes no legal responsibility for use or reliance upon this data. The CLOROX name and logo are registered trademarks of The Clorox Company. N. Av. = Not available. N. Ap. = Not applicable. © 1996 The Clorox Company Clorox® Commercial Solutions™ Ultra Clorox® Disinfecting Bleach, Page 2 of 2 Page 188 of 1069 Page 188 of 1069 Page 188 of 1069 Page 188 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date March 26, 2015 Revision Date New Revision Number 0 Page 1 / 10 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended use Moistened disinfecting wipes Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612 Phone: 1-[PHONE REDACTED] Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] Page 189 of 1069 Page 189 of 1069 Page 189 of 1069 Page 189 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 2 / 10 2. HAZARDS IDENTIFICATION Classification This product is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Serious eye damage/eye irritation Category 2B Flammable liquids Category 3 GHS Label elements, including precautionary statements Emergency Overview Signal word Warning Hazard statements Causes eye irritation Flammable liquid and vapor Appearance Clear, colorless liquid absorbed into white, non-woven wipes Physical State Thin liquid absorbed into non-woven wipes Odor Solvent, alcohol Precautionary Statements - Prevention Wash hands and any exposed skin thoroughly after handling. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear eye protection such as safety glasses. Precautionary Statements - Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water. In case of fire: Use dry chemical, carbon dioxide (CO2), foam, or water spray to extinguish. Precautionary Statements - Storage Store in a well-ventilated place. Keep cool. Precautionary Statements - Disposal Dispose of contents in accordance with all applicable federal, state, and local regulations. Hazards not otherwise classified (HNOC) Inhalation of high concentrations of vapor or mist may cause irritation of the respiratory tract, headaches, dizziness, nausea, vomiting, and malaise. Ingestion of liquid may cause central nervous system depression, gastrointestinal irritation, nausea, vomiting, and diarrhea. Unknown Toxicity No information available. Page 190 of 1069 Page 190 of 1069 Page 190 of 1069 Page 190 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 3 / 10 Other information Toxic to aquatic life with long lasting effects. Interactions with Other Chemicals Can react with strong oxidizers, inorganic acids, and halogens. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight % Trade Secret Isopropyl alcohol 67-63-0 15 - 25 * n-Alkyl (68% C12, 32% C14) dimethyl ammonium chloride 85409-23-0 0.1 - 0.2 * n-Alkyl C12, 60% C14, 30% C16, 5% C18) dimethyl benzyl ammonium chloride 53516-76-0 0.1 - 0.2 * * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15–20 minutes. If present, remove contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing problems develop, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Protection of First-aiders Remove all ignition sources. Use personal protective equipment as required. Wear personal protective clothing (see section Most important and effects, both acute and delayed Most Important and Effects Liquid may cause eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat Page 191 of 1069 Page 191 of 1069 Page 191 of 1069 Page 191 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 4 / 10 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Dry chemical, carbon dioxide (CO2), foam, or water spray. Unsuitable Extinguishing Media Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Alcohol flames may not be readily visible. Vapors are heavier than air and may travel to source of ignition and flash back. Vapors may form explosive mixtures with air. Hazardous Combustion Products Oxides of carbon. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge Yes. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep containers cool with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Eliminate all potential sources of ignition. Take precautionary measures against static discharges. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions Prevent entry into surface water or sanitary sewers. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Eliminate all potential sources of ignition, and ventilate area. Absorb and containerize. Do not flush into surface water or sanitary sewer system. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Store in accordance all applicable regulations and fire codes. Keep containers closed in a cool, well-ventilated place away from heat, sparks, open flames, and hot surfaces. Incompatible Products Strong oxidizers, inorganic acids, and halogens. Page 192 of 1069 Page 192 of 1069 Page 192 of 1069 Page 192 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 5 / 10 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Isopropyl alcohol 67-63-0 TWA - 200 ppm STEL - 400 ppm TWA - 400 ppm IDLH - 2000 ppm (10% LEL) TWA - 400 ppm STEL - 500 ppm n-Alkyl (68% C12, 32% C14) dimethyl ammonium chloride 85409-23-0 None None None n-Alkyl C12, 60% C14, 30% C16, 5% C18) dimethyl benzyl ammonium chloride 53516-76-0 None None None ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection None required for normal use. If splashes are likely to occur, wear safety glasses. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Page 193 of 1069 Page 193 of 1069 Page 193 of 1069 Page 193 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 6 / 10 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid absorbed into non-woven wipes Appearance Clear liquid absorbed into non-woven wipes Odor Solvent, alcohol Color Colorless liquid - white non-woven wipes Odor Threshold No information available Property Values Remarks/ Method pH ~7.5 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point ~30°C (liquid, closed cup) None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~0.95 (liquid) None known Water Solubility Complete (liquid) None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available 10. STABILITY AND REACTIVITY Reactivity Can react with strong oxidizers, inorganic acids, and halogens. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None known. Conditions to avoid Keep away from heat, sparks, open flames, and hot surfaces. Incompatible materials Strong oxidizers, inorganic acids, and halogens. Hazardous Decomposition Products None known. Page 194 of 1069 Page 194 of 1069 Page 194 of 1069 Page 194 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 7 / 10 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Inhalation of high concentrations of vapor or mist may cause irritation of the respiratory tract, headaches, dizziness, nausea, vomiting, and malaise. Eye Contact Liquid may cause irritation. Skin Contact Prolonged or repeated use may cause dryness and/or slight irritation. Ingestion Ingestion of liquid may cause central nervous system depression, gastrointestinal irritation, nausea, vomiting, and diarrhea. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Isopropyl alcohol 67-63-0 4.4 g/kg (Rat) 12.9 g/kg (Rabbit) 16000 (Rat, 8 h) Information on toxicological effects Liquid may cause redness and tearing of eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Isopropyl alcohol 67-63-0 - Group 3 - X 2-Butoxyethanol 111-76-2 - Group 3 - - IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans; Group 3 - Not Classifiable as to Carcinogenicity in Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive Toxicity STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity No information available. Target Organ Effects Eyes, central nervous system (CNS), respiratory system. Aspiration Hazard Not an aspiration hazard. Numerical measures of toxicity - Product Information No information available. Page 195 of 1069 Page 195 of 1069 Page 195 of 1069 Page 195 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 8 / 10 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life with long lasting effects. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Isopropyl alcohol 67-63-0 96h EC50: > 1000 mg/L (Desmodesmus subspicatus) 72h EC50: > 1000 mg/L (Desmodesmus subspicatus) 96h LC50: = 9640 mg/L (Pimephales promelas) 96h LC50: = 11130 mg/L (Pimephales promelas) 96h LC50: > 1400000 µg/L (Lepomis macrochirus) 48h EC50: 13299 mg/L Persistence and Degradability No information available. Bioaccumulation Chemical Name Log Pow Isopropyl alcohol 67-63-0 0.05 Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Not regulated per 49CFR 173.150(e)(2) - Aqueous solution of alcohol containing 24 percent or less alcohol by volume, no less than 50% water, and no other hazardous material is not subject to the requirements of the subchapter. TDG Exempted from regulations per TDG Regulations Part 1.36(b). ICAO Not regulated per ICAO Special Provision A58 - An aqueous solution containing 24% or less alcohol by volume is not subject to these regulations. IATA Not regulated per IATA Special Provision A58 - An aqueous solution containing 24% or less alcohol by volume is not subject to these regulations. IMDG/IMO Not regulated per IMDG Special Provision 144 - An aqueous solution containing 24% or less alcohol by volume is not subject to these regulations. Page 196 of 1069 Page 196 of 1069 Page 196 of 1069 Page 196 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 9 / 10 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Harmful if inhaled or absorbed through skin. Causes moderate eye irritation. Avoid breathing vapors and contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before reuse. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Isopropyl alcohol 67-63-0 X X X X 2-Butoxyethanol 111-76-2 X X X Page 197 of 1069 Page 197 of 1069 Page 197 of 1069 Page 197 of 1069 ---PAGE BREAK--- Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes Revision Date New Page 10 / 10 International Regulations Canada WHMIS Hazard Class B2 - Flammable liquid 16. OTHER INFORMATION NFPA Health Hazard 1 Flammability 3 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 1 Flammability 3 Physical Hazard 0 Personal Protection - Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Revision Date New Revision Note Reference New 1204522/202911.001 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 198 of 1069 Page 198 of 1069 Page 198 of 1069 Page 198 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Date June 12, 2015 Revision Number 1 Page 1 / 10 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox® Regular-Bleach1 Other means of identification EPA Registration Number 5813-100 Recommended use of the chemical and restrictions on use Recommended use Household disinfecting, sanitizing, and laundry bleach Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address The Clorox Company 1221 Broadway Oakland, CA 94612 Phone: 1-[PHONE REDACTED] Emergency telephone number Emergency Phone Numbers For Medical Emergencies, call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] Page 199 of 1069 Page 199 of 1069 Page 199 of 1069 Page 199 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 2 / 10 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 GHS Label elements, including precautionary statements Emergency Overview Signal word Danger Hazard Statements Causes severe skin burns and eye damage Causes serious eye damage Appearance Clear, pale yellow Physical State Thin liquid Odor Bleach Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves, protective clothing, face protection, and eye protection such as safety glasses. Precautionary Statements - Response Immediately call a poison center or doctor. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Specific treatment (see supplemental first aid instructions on this label). If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Precautionary Statements - Storage Store locked up. Precautionary Statements - Disposal Dispose of contents in accordance with all applicable federal, state, and local regulations. Hazards not otherwise classified (HNOC) Although not expected, heart conditions or chronic respiratory problems such as asthma, chronic bronchitis, or obstructive lung disease may be aggravated by exposure to high concentrations of vapor or mist. Product contains a strong oxidizer. Always flush drains before and after use. Page 200 of 1069 Page 200 of 1069 Page 200 of 1069 Page 200 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 3 / 10 Unknown Toxicity Not applicable. Other information Very toxic to aquatic life with long lasting effects. Interactions with Other Chemicals Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, or products containing ammonia to produce hazardous irritating gases, such as chlorine and other chlorinated compounds. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Trade Secret Sodium hypochlorite 7681-52-9 5 - 10 * * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General Advice Call a poison control center or doctor immediately for treatment advice. Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Inhalation Move to fresh air. If breathing is affected, call a doctor. Ingestion Have person sip a glassful of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Call a poison control center or doctor immediately for treatment advice. Protection of First-aiders Avoid contact with skin, eyes, and clothing. Use personal protective equipment as required. Wear personal protective clothing (see section Most important and effects, both acute and delayed Most Important and Effects Burning of eyes and skin. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat Probable mucosal damage may contraindicate the use of gastric lavage. Page 201 of 1069 Page 201 of 1069 Page 201 of 1069 Page 201 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 4 / 10 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical This product causes burns to eyes, skin, and mucous membranes. Thermal decomposition can release sodium chlorate and irritating gases and vapors. Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes, skin, and clothing. Ensure adequate ventilation. Use personal protective equipment as required. For spills of multiple products, responders should evaluate the of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed and/or poorly-ventilated areas until hazard assessment is complete. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions This product is toxic to fish, aquatic invertebrates, oysters, and shrimp. Do not allow product to enter storm drains, lakes, or streams. See Section 12 for ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. Page 202 of 1069 Page 202 of 1069 Page 202 of 1069 Page 202 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 5 / 10 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Store away from children. Reclose cap after each use. Store this product upright in a cool, dry area, away from direct sunlight and heat to avoid deterioration. Do not contaminate food or feed by storage of this product. Incompatible Products Toilet bowl cleaners, rust removers, acids, and products containing ammonia. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sodium hypochlorite 7681-52-9 None None None ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection If splashes are likely to occur: Wear safety glasses with side shields (or goggles) or face shield. Skin and Body Protection Wear rubber or neoprene gloves and protective clothing such as long-sleeved shirt. Respiratory Protection If irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Remove and wash contaminated clothing before re-use. Do not eat, drink, or smoke when using this product. Page 203 of 1069 Page 203 of 1069 Page 203 of 1069 Page 203 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 6 / 10 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid Appearance Clear Odor Bleach Color Pale yellow Odor Threshold No information available Property Values Remarks/ Method pH ~12 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point Not flammable None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.1 None known Water Solubility Soluble None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available 10. STABILITY AND REACTIVITY Reactivity Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, or products containing ammonia to produce hazardous irritating gases, such as chlorine and other chlorinated compounds. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials Toilet bowl cleaners, rust removers, acids, and products containing ammonia. Hazardous Decomposition Products None known based on information supplied. Page 204 of 1069 Page 204 of 1069 Page 204 of 1069 Page 204 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 7 / 10 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Exposure to vapor or mist may irritate respiratory tract and cause coughing. Inhalation of high concentrations may cause pulmonary edema. Eye Contact Corrosive. May cause severe damage to eyes. Skin Contact May cause severe irritation to skin. Prolonged contact may cause burns to skin. Ingestion Ingestion may cause burns to gastrointestinal tract and respiratory tract, nausea, vomiting, and diarrhea. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium hypochlorite 7681-52-9 8200 mg/kg (Rat) >10000 mg/kg (Rabbit) - Information on toxicological effects May cause redness and tearing of the eyes. May cause burns to eyes. May cause redness or burns to skin. Inhalation may cause coughing. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Sodium hypochlorite 7681-52-9 - Group 3 - - IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Carcinogenic potential is unknown. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI). Aspiration Hazard No information available. Page 205 of 1069 Page 205 of 1069 Page 205 of 1069 Page 205 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 8 / 10 Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 54 g/kg ATEmix (inhalation-dust/mist) 58 mg/L 12. ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects. This product is toxic to fish, aquatic invertebrates, oysters, and shrimp. Do not allow product to enter storm drains, lakes, or streams. Persistence and Degradability No information available. Bioaccumulation No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Do not contaminate food or feed by disposal of this product. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Not restricted. TDG Not restricted for road or rail. ICAO Not restricted, as per Special Provision A197, Environmentally Hazardous Substance exception. IATA Not restricted, as per Special Provision A197, Environmentally Hazardous Substance exception. IMDG/IMO Not restricted, as per IMDG Code 2.10.2.7, Marine Pollutant exception. Page 206 of 1069 Page 206 of 1069 Page 206 of 1069 Page 206 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 9 / 10 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium hypochlorite 7681-52-9 100 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Sodium hypochlorite 7681-52-9 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: DANGER: CORROSIVE. Causes irreversible eye damage and skin burns. Harmful if swallowed. Do not get in eyes, on skin, or on clothing. Wear protective eyewear and rubber gloves when handling this product. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the restroom. Avoid breathing vapors and use only in a well-ventilated area. Page 207 of 1069 Page 207 of 1069 Page 207 of 1069 Page 207 of 1069 ---PAGE BREAK--- Clorox® Regular-Bleach1 Revision Date June 12, 2015 Page 10 / 10 US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Sodium hypochlorite 7681-52-9 X X X X Sodium chlorate 7775-09-9 X X X International Regulations Canada WHMIS Hazard Class E - Corrosive material 16. OTHER INFORMATION NFPA Health Hazard 3 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 3 Flammability 0 Physical Hazard 0 Personal Protection B Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Revision Date June 12, 2015 Revision Note Reference Revision Section 14. 1096036/164964.159 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 208 of 1069 Page 208 of 1069 Page 208 of 1069 Page 208 of 1069 ---PAGE BREAK--- 1. IDENTIFICATION Product Name Comet Deodorizing Cleanser with Chlorinol Product Code(s) 3-10 Product ID: 97086927_PROF_NG Product Type: Finished Product - Professional Use Only Recommended Use Hard Surface Cleaner Restrictions on Use Do not mix with other cleaning products or chemicals as irritating fumes may be formed. Manufacturer Procter & Gamble Professional 2 P&G Plaza Cincinnati, Ohio 45202 Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5 1-[PHONE REDACTED] E-mail Address Emergency Telephone Transportation (24 HR) CHEMTREC - 1-[PHONE REDACTED] Canada) or 1-[PHONE REDACTED] Mexico toll free in country: [PHONE REDACTED] 2. HAZARD IDENTIFICATION This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Hazard Category Eye Damage / Irritation Category 2B Page 1 / 7 Hazard pictograms None Issuing Date: 12-Jun-2015 Precautionary Statements - Prevention Wash hands thoroughly after handling Do not mix with other cleaning products or chemicals as irritating fumes may be formed Signal Word WARNING Revision Date: 12-Jun-2015 Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF SWALLOWED: Drink 1 or 2 glasses of water SAFETY DATA SHEET Version 1 Hazard Statements Causes eye irritation Page 209 of 1069 Page 209 of 1069 Page 209 of 1069 Page 209 of 1069 ---PAGE BREAK--- 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists. Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if occur. Inhalation Move to fresh air. If persist, call a physician. Most important acute and delayed None under normal use conditions. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Unsuitable Extinguishing Media None. Special hazard None known. Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical None. Page 2 / 7 Revision Date: 12-Jun-2015 Precautionary Statements - Disposal Dispose of contents/container in accordance with local regulation Precautionary Statements - Storage None 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Hazards not otherwise classified (HNOC) None Chemical Name Synonyms Trade Secret CAS-No Weight % Limestone - No 1317-65-3 40 - 100 Sodium carbonate - No 497-19-8 5 - 10 - No 87-90-1 1 - 5 Benzenesulfonic acid, mono-C10-16-alkyl derivs., sodium salts - No 68081-81-2 1 - 5 Page 210 of 1069 Page 210 of 1069 Page 210 of 1069 Page 210 of 1069 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Advice for emergency responders Use personal protective equipment as required. Methods and materials for containment and cleaning up Methods for containment Prevent dust cloud. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Dispose of in accordance with local regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products Do not mix with other cleaning products or chemicals as irritating fumes may be formed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL Limestone 1317-65-3 TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 15 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction Mexico: TWA 10 mg/m3 Mexico: STEL 20 mg/m3 Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Limestone 1317-65-3 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 3 mg/m3 STEL: 20 mg/m3 No relevant exposure guidelines for other ingredients Exposure controls Engineering Measures Distribution, Workplace and Household Settings: Ensure adequate ventilation Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction Personal Protective Equipment Page 3 / 7 Revision Date: 12-Jun-2015 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Page 211 of 1069 Page 211 of 1069 Page 211 of 1069 Page 211 of 1069 ---PAGE BREAK--- Eye Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection Hand Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves Skin and Body Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Wear suitable protective clothing Respiratory Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20°C solid Appearance white Odor Pine Odor threshold No information available Oxidizing properties These substances will accelerate burning when involved in a fire. VOC Content Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity None under normal use conditions. Page 4 / 7 No information available Lower Flammability Limit No information available Values Vapor pressure No information available Boiling point/boiling range Vapor density Revision Date: 12-Jun-2015 No information available No information available Relative density No information available Note Water solubility Flash point 15% Solubility in other solvents No information available No information available Partition coefficient: n-octanol/waterNo information available pH value Autoignition temperature Evaporation rate No information available . Decomposition temperature No information available No information available . Viscosity of Product No information available 11.5 Flammability (solid, gas) Property No information available (as 1% solution) Flammability Limits in Air Melting/freezing point Upper flammability limit 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol No information available Page 212 of 1069 Page 212 of 1069 Page 212 of 1069 Page 212 of 1069 ---PAGE BREAK--- Stability Stable under normal conditions. Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. Conditions to Avoid None under normal processing. Materials to avoid Do not mix with other cleaning products or chemicals as irritating fumes may be formed. Hazardous Decomposition Products None under normal use. 11. TOXICOLOGICAL INFORMATION Product Information Information on likely routes of exposure Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact Irritating to eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation Irritating to eyes. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect. Component Information Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation Sodium carbonate 497-19-8 2800 mg/kg bw > 2000 mg/kg bw (US EPA 16 CFR 1500.40) - 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Page 5 / 7 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Revision Date: 12-Jun-2015 Page 213 of 1069 Page 213 of 1069 Page 213 of 1069 Page 213 of 1069 ---PAGE BREAK--- Waste treatment Waste from Residues / Unused Products Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Codes (non-household setting) 331 14. TRANSPORT INFORMATION DOT Not regulated IMDG Not regulated IATA Not regulated 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name CAS-No Hazardous Substances RQs Extremely Hazardous Substances RQs CERCLA/SARA 302 TPQ Piperidine 110-89-4 - 1000 lb 1000 lb Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) Chemical Name CAS-No New Jersey Limestone 1317-65-3 X 87-90-1 X Chemical Name CAS-No Limestone 1317-65-3 X 87-90-1 X Page 6 / 7 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Revision Date: 12-Jun-2015 Page 214 of 1069 Page 214 of 1069 Page 214 of 1069 Page 214 of 1069 ---PAGE BREAK--- International Inventories United States All intentionally-added components of this product(s) are listed on the US TSCA Inventory. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act 16. OTHER INFORMATION HMIS Ratings Health hazard 2 Flammability 0 Physical hazard 0 Health hazard 2 Flammability 0 Instability 0 Issuing Date: 12-Jun-2015 Revision Date: 12-Jun-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7 97086927_PROF_NG - Comet Deodorizing Cleanser with Chlorinol Revision Date: 12-Jun-2015 Page 215 of 1069 Page 215 of 1069 Page 215 of 1069 Page 215 of 1069 ---PAGE BREAK--- 922433 MATERIAL SAFETY DATA SHEET MEDICAL EMERGENCIES ONLY (24 Hour Service): 1-[PHONE REDACTED] Medical Calls from Outside of the USA: 1-[PHONE REDACTED] ECOLAB FOOD & BEVERAGE DIVN. Ecolab Center St. Paul MN 55102 Product Information: 1-[PHONE REDACTED] Issue Date: November 16, 2000 1.0 IDENTIFICATION / 1.1 Product Name: CONSERVE 1.2 Product Type: Liquid High Chelant Alkaline Cleaner 1.3 Hazard Rating: Health: 2 Fire: 0 Reactivity: 0 Substances Subject to SARA 313 Reporting Are Indicated by 2.0 HAZARDOUS COMPONENTS / (in mg/m3) CAS No. % PEL TWA 2.1 Chelating agents mixture 20-50 No No 2.2 Triethanolamine 102-71-6 1-5 No 5 2.3 Nonionic surfactant proprietary 1-5 No No PEL = OSHA 8 Hour Average in Air TWA = ACGIH 8 Hour Average in Air 3.0 PHYSICAL DATA / 3.1 Appearance: Clear, light amber liquid 3.2 Solubility in Water: Mixes with water in all proportions 3.3 pH: 9.5 3.4 Initial Boiling Point: > 212 deg F / 100 deg C 3.5 Specific Gravity: 1.195 @ 68 deg F / 20 deg C 4.0 FIRE AND EXPLOSION DATA / 4.1 Special Fire Hazards: None, does not support combustion. 4.2 Fire Fighting Methods: Use method appropriate for surrounding fire. 5.0 REACTIVITY DATA / 5.1 Stability: Stable under normal conditions of use and handling. 5.2 Conditions to Avoid: No special requirements; use standard industrial practices. Use as directed. 6.0 SPILL OR LEAK PROCEDURES / USE PROPER PROTECTIVE EQUIPMENT 6.1 Cleanup: Dike or dam large spills. Pump to containers or soak up on inert absorbent. Flush residue to sanitary sewer. 6.2 Waste Disposal: Consult state/local authorities for limits on chemical waste disposal. 7.0 HEALTH HAZARD DATA / WARNING 7.1 Effects of Overexposure to Concentrate: Eyes: Causes minor to moderate irritation. Skin: Prolonged or repeated exposure may cause minor irritation. If Swallowed: May cause stomach distress, nausea or vomiting. 8.0 FIRST AID / 8.1 Eyes: Flush with cool running water. Remove contact lenses and continue flushing for 15 minutes. 8.2 Skin: Flush skin with water; wash with soap and water. Remove and wash contaminated clothing before reuse. Page 1 of 2 Material Safety Data Sheet - Product #46641 2007-03-17 Created with novaPDF Printer (www.novaPDF.com). Please register to remove this message. Page 216 of 1069 Page 216 of 1069 Page 216 of 1069 Page 216 of 1069 ---PAGE BREAK--- 8.3 If Swallowed: Rinse mouth; then drink 1 or 2 large glasses of water. DO NOT induce vomiting. NEVER give anything by mouth to an unconscious person. IF IRRITATION OR DISCOMFORT PERSISTS, CALL A PHYSICIAN. 9.0 PROTECTIVE MEASURES / 9.1 FOR CONCENTRATE: Eyes: Wear chemical splash goggles. Skin: Wear any impervious glove. 10.0 ADDITIONAL INFORMATION / 10.1 Purpose of 11/16/2000 issue: Minor formula change; associated edits. QC and editorial update. Replaces August 27, 1997 issue. KEEP OUT OF REACH OF CHILDREN The above information is believed to be correct with respect to the formula used to manufacture the product. As data, standards and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 2 of 2 Material Safety Data Sheet - Product #46641 2007-03-17 Created with novaPDF Printer (www.novaPDF.com). Please register to remove this message. Page 217 of 1069 Page 217 of 1069 Page 217 of 1069 Page 217 of 1069 ---PAGE BREAK--- #19638 Page 1 of 6 Issue date 4-May-2012 Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 MATERIAL SAFETY DATA SHEET . 1. Product and Company Identification space Product Name Corporate Express EXP Duster space Synonym(s) Model # EXP1300 Model EXP1301 Model EXP6038 Model Model # space CAS # Mixture space Product use Dust control space Manufacturer Falcon Safety Products, Inc. 25 Imclone Drive Branchburg, NJ 08876 US Phone: 1-[PHONE REDACTED] space Supplier Corporate Express 1 Environmental Way Broomfield, CO 80027 Phone 1-[PHONE REDACTED] space LEGEND HMIS/NFPA Health / 1 4 Flammability 4 1 1 Physical Hazard 1 Personal Protection X . 2. Hazards Identification space Emergency overview DANGER Flammable gas. Contents under pressure. Containers may explode when heated. space Potential short term health effects Routes of exposure Eye, Skin contact, Inhalation. space space space space space Eyes Contact with liquid may cause frostbite. Skin Contact with liquid may cause frostbite. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Vapors may cause dizziness or suffocation. Ingestion Not a normal route of exposure. Target organs Eyes. Skin. Respiratory system. space Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. space Signs and may include redness, edema, drying, defatting and cracking of the skin. . 3. Composition / Information on Ingredients space Ingredient(s) CAS # Percent Ethane, 1,1-difluoro- 75-37-6 60 - 100 . 4. First Aid Measures space First aid procedures Eye contact space Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Skin contact Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. Page 218 of 1069 Page 218 of 1069 Page 218 of 1069 Page 218 of 1069 ---PAGE BREAK--- #19638 Page 2 of 6 Issue date 4-May-2012 space space space Inhalation If develop, move victim to fresh air. If persist, obtain medical attention. If breathing has stopped, trained personnel should administer CPR immediately. Ingestion Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. General advice Do not puncture or incinerate container. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. . 5. Fire Fighting Measures space Flammable properties Flammable by WHMIS/OSHA criteria. Containers may explode when heated. space Extinguishing media Suitable extinguishing media Do not extinguish burning gas if flow cannot be shut off immediately. Use water spray or fog nozzle to keep cylinder cool space space Small Fires: Dry chemical. Carbon dioxide. Water spray. Fog. Unsuitable extinguishing media Not available Protection of firefighters Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. Cool containers with flooding quantities of water until well after fire is out. space space Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. Hazardous combustion products May include and are not limited to: Oxides of carbon. Fluoride gases. space Explosion data space Sensitivity to mechanical impact Not available Sensitivity to static discharge Not available . 6. Accidental Release Measures space Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. space Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. space Methods for cleaning up Before attempting clean up, refer to hazard data given above. Remove sources of ignition. Although the chance of a significant spill or leak is unlikely in aerosol containers, in the event of such an occurrence, absorb spilled material with a non-flammable absorbent such as sand or vermiculite. . 7. Handling and Storage space Handling Avoid breathing mists or aerosols of this product. Use good industrial hygiene practices in handling this material. space Storage Keep out of reach of children. Do not store at temperatures above 49 °C (120.2°F). Keep away from heat, open flames or other sources of ignition. . 8. Exposure Controls / Personal Protection space Exposure limits Ingredient(s) Ethane, 1,1-difluoro- Exposure Limits ACGIH-TLV Not established OSHA-PEL Not established space Engineering controls Use only under good ventilation conditions or with respiratory protection. space Personal protective equipment Eye / face protection Wear safety glasses with side shields. Page 219 of 1069 Page 219 of 1069 Page 219 of 1069 Page 219 of 1069 ---PAGE BREAK--- #19638 Page 3 of 6 Issue date 4-May-2012 space space space space Hand protection If there is constant skin contact, rubber gloves are recommended. Skin and body protection As required by employer code. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands and face before breaks and immediately after handling the product. . 9. Physical and Chemical Properties space Appearance Clear. space Color Colorless space Form Liquefied gas space Odor Slight ethereal. space Odor threshold Not available space Physical state Gas space pH Not applicable space Melting point Not available space Freezing point Not available space Boiling point -25 °C (-13.00 space Flash point -50 °C (-58.00 space Pour point Not available space Evaporation rate Not available space Flammability limits in air, lower, % by volume space Flammability limits in air, upper, % by volume space 3.9 16.9 Vapor pressure 599.43 kPa @25°C space Vapor density 2.4 @25°C (air=1) space Specific gravity 0.91 space Relative density 0.9 g/cc @25°C space Octanol/water coefficient Not available space Solubility (H2O) space Auto-ignition temperature 454 °C (849.20 space Percent volatile 100 . 10. Stability and Reactivity space Chemical stability Stable under recommended storage conditions. space Conditions to avoid Aerosol containers are unstable at temperatures above 49°C (120.2°F). space Incompatible materials Alkaline materials. Alkaline earth metals. space Hazardous decomposition products May include and are not limited to: Oxides of carbon. Fluoride gases. space Possibility of hazardous reactions Hazardous polymerization does not occur. . 11. Toxicological Information space Component analysis - LC50 Ingredient(s) Ethane, 1,1-difluoro- space Component analysis - Oral LD50 Ingredient(s) Ethane, 1,1-difluoro- space Effects of acute exposure Eye LC50 > 64000 ppm rat LD50 1500 mg/kg rat Contact with liquid may cause frostbite. space Skin Contact with liquid may cause frostbite. Page 220 of 1069 Page 220 of 1069 Page 220 of 1069 Page 220 of 1069 ---PAGE BREAK--- #19638 Page 4 of 6 Issue date 4-May-2012 space space space Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Vapors may cause dizziness or suffocation. Ingestion Not a normal route of exposure. Sensitization Non-hazardous by WHMIS/OSHA criteria. space Chronic effects Non-hazardous by WHMIS/OSHA criteria. space Carcinogenicity Non-hazardous by WHMIS/OSHA criteria. space Mutagenicity Non-hazardous by WHMIS/OSHA criteria. space Reproductive effects Non-hazardous by WHMIS/OSHA criteria. space Teratogenicity Non-hazardous by WHMIS/OSHA criteria. space Synergistic Materials Not available . 12. Ecological Information space Ecotoxicity Not available space Environmental effects Not available space Aquatic toxicity Not available space Persistence / degradability Not available space Bioaccumulation / accumulation Not available space Partition coefficient Not available space Mobility in environmental media Not available space Chemical fate information Not available space Other adverse effects Not available . 13. Disposal Considerations space Waste codes Not available space Disposal instructions Review federal, state/provincial, and local government requirements prior to disposal. space Waste from residues / unused products space Not available Contaminated packaging Not available . 14. Transport Information space U.S. Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Packaging exceptions 1,1-Difluoroethane 2.1 1030 NOTE: Falcon Safety Products has been granted a DOT exemption that allows this product to be shipped similar to a Consumer Commodity (ORM-D). A copy of the DOT exemption can be obtained by calling Falcon Safety Products, Inc at [PHONE REDACTED]. Page 221 of 1069 Page 221 of 1069 Page 221 of 1069 Page 221 of 1069 ---PAGE BREAK--- #19638 Page 5 of 6 Issue date 4-May-2012 space Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Packaging exceptions space IATA/ICAO (Air) Basic shipping requirements: Proper shipping name Hazard class UN number Additional information: Maximum net quantity packaging . 1,1-Difluoroethane 2.1 1030 Limited quantity (containers up to 125mL) 1,1-Difluoroethane 2.1 1030 Cargo aircraft only – 150 kg maximum (Forbidden on passenger aircraft) 15. Regulatory Information space Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada - CEPA - Schedule I - List of Toxic Substances Ethane, 1,1-difluoro- 75-37-6 Totally halogenated chlorofluorocarbons that have the molecular formula quantities that may be manufactured or imported; Prohibition on manufacture, use, sale, offer for sale, import or export except for authorized uses [SOR/89-351, s. 16; 90-453, s. 5; 94-408, s. 24; 92-507, s. 17; 96-237, s. 5] space US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. space CERCLA/SARA Hazardous Substances - Not applicable. Occupational Safety and Health Administration (OSHA) space 29 CFR 1910.1200 hazardous chemical Yes CERCLA (Superfund) reportable quantity None space Superfund Amendments and Reauthorization Act of 1986 (SARA) space space Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No No space Section 311 hazardous chemical Yes Clean Air Act (CAA) Not available space Clean Water Act (CWA) Not available Page 222 of 1069 Page 222 of 1069 Page 222 of 1069 Page 222 of 1069 ---PAGE BREAK--- #19638 Page 6 of 6 Issue date 4-May-2012 space WHMIS status Controlled space WHMIS classification Class A - Compressed Gas, Class B - Division 1 - Flammable Gas space WHMIS labeling space State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. U.S. - Louisiana - Reportable Quantity List for Pollutants Ethane, 1,1-difluoro- 75-37-6 5000 Lb final RQ; 2270 kg final RQ U.S. - Massachusetts - Right To Know List Ethane, 1,1-difluoro- 75-37-6 Present U.S. - New Jersey - Right to Know Hazardous Substance List Ethane, 1,1-difluoro- 75-37-6 sn 0715 space Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory No Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) . 16. Other Information space Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. space Issue date 4-May-2012 space Effective date 4-May-2012 space Expiry date 4-May 2015 space Prepared by Falcon Safety Products, Inc. (908) 707-4900 space Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. Page 223 of 1069 Page 223 of 1069 Page 223 of 1069 Page 223 of 1069 ---PAGE BREAK--- MSDS-FM04 Date Prepared: 12/21/05 MATERIAL SAFETY DATA SHEET/COMPLIES WITH OSHA’S HAZARD COMMUNICATION STANDARD (29CFR 1910.1200) SECTION I – PRODUCT IDENTIFICATION COUNTERTOP MAGIC CONTAINER SIZE: 4, 12, 16, 22, 32 fl oz, one-gallon, 55-gallon STOCK NO.: FM04, FM12, FMTR12, FMTR16, FM22, FZ91, SP91, FM01, FM55 SUPPLIER’S NAME: MAGIC AMERICAN PRODUCTS, INC. ADDRESS: 23700 MERCANTILE ROAD; CLEVELAND OH 44122 24 Hour Emergency Phone: CHEMTEL 1-[PHONE REDACTED] Information Phone: MAGIC AMERICAN PRODUCTS, INC. M-F, 9-5 EST 1-[PHONE REDACTED] DOT SHIPPING INFORMATION HAZARDS RATING INFORMATION DOT SHIPPING NAME: Not Regulated DOT HAZARD CLASS: None DOT LABEL: None DOT PACKING GROUP: None Health Flammability Reactivity Personal Protection NFPA 0 0 0 N/A NPCA(HMIS) 0 0 0 B 0 – Minimal 1 – Slight 2 – Moderate 3 – Serious 4 – Extreme B – Glasses, gloves SECTION II - INGREDIENTS CHEMICAL NAME CAS NO. % WT 313/CHEMICAL PEL SKIN TWA/TLV CARCINOGEN Proprietary Mixture (Emulsion of Mineral Oil and Water) None 100% No ingredients regulated N/A N/A N/A No All ingredients used in this proprietary mixture are listed on the TSCA Inventory List and none is listed as carcinogenic by OSHA, IARC or NTP. SECTION III – PHYSICAL DATA SECTION IV – FIRE AND EXPLOSION DATA Boiling Point: 212 F Vapor Pressure: N/D Solubility in Water: Complete pH: 7.5 to 8.5 Specific Gravity: 0.97 g/ml Evaporation Rate: Less than 1 (H20=1) Appearance/Odor: White, Opaque Liquid with Orange/Citrus Fragrance VOC Content: 4.0% VOC by CARB Flash Point: >200°F (93°C) (Pensky-Marten Closed Cup) Explosive Hazard: Not an explosive. Extinguishing Media: Use extinguishing media suitable for other combustible materials in area. Special Fire Fighting Procedures: None; material is not combustible. Unusual Fire and Explosion Hazards: None SECTION V – REACTIVITY DATA SECTION VI – STORAGE AND HANDLING Stability: Stable Hazardous Polymerization: Will not occur Hazardous Decomposition Products: None known Incompatibility: None known KEEP OUT OF THE REACH OF CHILDREN Store in a cool, dry area away from heat or open flame. SECTION VII – HEALTH EFFECTS AND FIRST AID PRIMARY ROUTES OF ENTRY AND EFFECTS OF OVEREXPOSURE FIRST AID PROCEDURES EYES: According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.42, and based upon laboratory tests on an analogous material this product was shown not to be an eye irritant. EYES: Remove any contact lenses and flush both eyes with cool running water for at least 15 minutes. Seek medical attention if irritation persists. SKIN: According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.41, and based upon laboratory tests on an analogous material, this product was shown not to be a primary skin irritant. SKIN: Wash with soap and water. INHALATION: Not expected to be an inhalation hazard. INHALATION: Remove person to fresh air. INGESTION: According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.3(c)(2)(i), and based upon laboratory tests on an analogous material, this product was shown to be non-toxic by the oral route of exposure and is not considered an ingestion hazard. INGESTION: Do not induce vomiting. Seek medical attention immediately. LONG TERM EFFECTS: No long term effects expected. SECTION VIII – SPECIAL PROTECTION DATA SECTION IX – SPILL OR LEAK PRECAUTIONS RESPIRATORY PROTECTION: None normally needed. STEPS TO BE TAKEN IN CASE OF SPILLAGE OR LEAKAGE: Ventilate area and apply inert absorbent. VENTILATION: Mechanical (general) ventilation is usually adequate. WASTE DISPOSAL METHOD: Sweep up and place in empty container and close. Dispose of according to local, state and federal regulations PROTECTIVE GLOVES: Protective gloves are recommended for prolonged use. EYE PROTECTION: Not needed. WASTE DISPOSAL CAUTION: Hazardous substances cleaned with this product may create hazardous waste that must be properly characterized and disposed of in accordance with RCRA, state and local regulations. N/A = NOT APPLICABLE N/E = NOT ESTABLISHED N/D = NOT DETERMINED < = LESS THAN > = MORE THAN NOTICE: The information contained on this Material Safety Data Sheet is for Industrial and Institutional use only and considered accurate as of the date of publication. It is not necessarily all inclusive or fully adequate in every circumstance. The suggestions should not be confused with or followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, express or implied, of merchantability, fitness, accuracy of data, or the results to be obtained from the use thereof is made. The vendor assumes no responsibility for injury or damages resulting from the inappropriate use of this product. Magic American assumes no responsibility for any product information placed on the Internet by individuals who are not affiliated with Magic American. Page 224 of 1069 Page 224 of 1069 Page 224 of 1069 Page 224 of 1069 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Coverage Plus Germicidal Surface Wipes CAS Number: Manufacturer: Steris Corporation SDS Date: 6/24/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 225 of 1069 Page 225 of 1069 Page 225 of 1069 Page 225 of 1069 ---PAGE BREAK--- Page 226 of 1069 Page 226 of 1069 Page 226 of 1069 Page 226 of 1069 ---PAGE BREAK--- Page 227 of 1069 Page 227 of 1069 Page 227 of 1069 Page 227 of 1069 ---PAGE BREAK--- Page 228 of 1069 Page 228 of 1069 Page 228 of 1069 Page 228 of 1069 ---PAGE BREAK--- Page 229 of 1069 Page 229 of 1069 Page 229 of 1069 Page 229 of 1069 ---PAGE BREAK--- Safety Data Sheet Material Name: CRAYOLA® COLOR WONDER MARKERS, CW SPRAYER; CW WATERCOLORS SDS ID: 00228442 Page 1 of 6 Issue Date: 03/19/2014 Revision: 1.0105 Print Date: 01/29/2015 * * *Section 1 - PRODUCT AND COMPANY IDENTIFICATION* * * Material Name: CRAYOLA® COLOR WONDER MARKERS, CW SPRAYER; CW WATERCOLORS CRAYOLA LLC Phone: 1-[PHONE REDACTED] 1100 Church Lane Easton, PA 18044 Health Emergency - Call local Poison Control Center [EMAIL REDACTED] Transportation Emergency: 1-[PHONE REDACTED] Synonyms CRAYOLA COLOR WONDER MARKERS; COLOR WONDER MINI MARKERS; COLOR WONDER SPRAY MAGIC; COLOR WONDER SPRAY MAGIC AIR BRUSH SYSTEM; COLOR WONDER KITS; COLOR WONDER PAPER; CW WATERCOLOR PAINT BRUSHES; COLOR WONDER BRUSH TIP MARKERS; PRODUCT CODE(S): 07-2311; 07-2402; 07-2404; 75-0208; 75-0222; 75-0224; 75-0226; 75-0227; 75-0228; 75-0229; 75- 0230; 75-0231; 75-0238; 75-0240; 75-0241; 75-0242; 75-0243; 75-0244; 75-0247; 75-1036; 75-1037; 75-1291; 75-1297; 75-1398; 75-1300; 75-1301; 75-1335; 75-1336; 75-1510; 75-1650; 75-1651; 75-1668; 75-1716; 75- 1700; 75-1717; 75-1799; 75-1800; 75-1801; 75-1802; 75-1803; 75-1804; 75-1805; 75-1806; 75-1807; 75-1808; 75-1809; 75-1810; 75-1811; 75-1812; 75-1813; 75-1815; 75-1816; 75-1818; 75-1819; 75-1821; 75-1824; 75- 1825; 75-1827; 75-1832; 75-1833; 75-1834; 75-1835; 75-1840; 75-1841; 75-1860; 75-1861; 75-1902; 75-1903; 75-1904; 75-1905; 75-1907; 75-1908; 75-1909; 75-1910; 75-1911; 75-1912; 75-1913, 75-1914; 75-1915; 75- 1916; 75-1917; 75-1918; 75-1919; 75-1921; 75-1923; 75-1924; 75-1925; 75-1992; 75-2002; 75-2036; 75-2040; 75-2046; 75-2047; 75-2048; 75-2066; 75-2068; 75-2069; 75-2070; 75-2071; 75-2055; 75-2116; 75-2105.; 75- 2106; 75-2113; 75-2114; 75-2115; 75-2117; 75-2128; 75-2129; 75-2133; 75-2134; 75-2135; 75-2140; 75-2136; 75-2141; 75-2142; 75-2143; 75-2144; 75-2145; 75-2146; 75-2148; 75-2149; 75-2150; 75-2152; 75-2166; 75- 2167; 75-2168; 75-2170; 75-2174; 75-2175; 75-2180; 75-2186; 75-2184; 75-2196; 75-2197; 75-2206; 75-2211; 75-2213; 75-2215; 75-2210; 75-2216; 75-2217; 75-2218; 75-2219; 75-2220; 75-2224; 75-2229; 75-2232; 75- 2233; 75-2235; 75-2236; 75-2234; 75-2242; 75-2236; 75-2240; 75-2245; 75-2246; 75-2247; 75-2248; 75-2249; 75-2250; 75-2253; 75-2254; 75-2257; 75-2258; 75-2264; 75-2265; 75-2270; 75-2271; 75-2278; 75-2279; 75- 2280; 75-2281; 75-2282; 75-2283; 75-2284; 75-2285; 75-2286; 75-2287; 75-2288; 75-2289; 75-2290; 75-2291; 75-2292; 75-2293; 75-2294; 75-2295; 75-2296; 75-2298; 75-2305; 75-2311; 75-2313; 75-2323; 75-2324; 75- 2329; 75-2331; 75-2332; 75-2333; 75-2334; 75-2335; 75-2337; 75-2338; 75-2339; 75-3240; 75-2341; 75-2351; 75-2352; 75-2360; 75-2361; 75-2369; 75-2402; 75-2421; 75-2500; 75-2501; 75-2525; 75-2526; 75-2527; 75- 2528; 75-2600; 75-2607; 75-2614; 75-2703; 75-2705; 75-2706; 75-3505; 75-3506; 75-3507; 75-3508; 75-3509; 75-3510; 75-3511; 75-3512; 75-3522; 75-3549; 75-3651; 75-5122; 75-7713; 75-8211A; 75-3818; 75-3819; 04- 3832; 75-8402; 75-8600; 75-8601; 75-8603; 75-8602; 75-8612; 80-6862 Product Use Arts and Crafts * * *Section 2 - HAZARDS IDENTIFICATION* * * EMERGENCY OVERVIEW Color: various colors Physical Form: article containing liquid Page 230 of 1069 Page 230 of 1069 Page 230 of 1069 Page 230 of 1069 ---PAGE BREAK--- Safety Data Sheet Material Name: CRAYOLA® COLOR WONDER MARKERS, CW SPRAYER; CW WATERCOLORS SDS ID: 00228442 Page 2 of 6 Issue Date: 03/19/2014 Revision: 1.0105 Print Date: 01/29/2015 POTENTIAL HEALTH EFFECTS Inhalation: none Skin Contact: none Eye Contact: none Ingestion: none * * *Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS* * * CAS Component Percent Symbol(s) Risk Phrase(s) Not Available Product has been certified as non-toxic by the art and creative materials institute, inc. and conforms to astm D-4236 standard practice for labeling art materials for acute and chronic adverse health hazards. 100 * * *Section 4 - FIRST AID MEASURES* * * Inhalation It is unlikely that emergency treatment will be required. Remove from exposure. Get medical attention, if needed. Skin It is unlikely that emergency treatment will be required. If adverse effects occur, wash with soap or mild detergent and large amounts of water. Get medical attention, if needed. Eyes It is unlikely that emergency treatment will be required. Wash with large amounts of water or normal saline until no evidence of chemical remains (at least 15-20 minutes). Get medical attention immediately. Ingestion Contact local poison control center or physician immediately. * * *Section 5 - FIRE FIGHTING MEASURES* * * See Section 9 for Flammability Properties NFPA Ratings: Health: 1 Fire: 1 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Flammable Properties Slight fire hazard. Extinguishing Media regular dry chemical, carbon dioxide, water, regular foam Fire Fighting Measures Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by- products. * * *Section 6 - ACCIDENTAL RELEASE MEASURES* * * Occupational spill/release Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Page 231 of 1069 Page 231 of 1069 Page 231 of 1069 Page 231 of 1069 ---PAGE BREAK--- Safety Data Sheet Material Name: CRAYOLA® COLOR WONDER MARKERS, CW SPRAYER; CW WATERCOLORS SDS ID: 00228442 Page 3 of 6 Issue Date: 03/19/2014 Revision: 1.0105 Print Date: 01/29/2015 * * *Section 7 - HANDLING AND STORAGE* * * Storage Procedures Store and handle in accordance with all current regulations and standards. See original container for storage recommendations. Keep separated from incompatible substances. * * *Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION* * * Component Exposure Limits ACGIH and EU have not developed exposure limits for any of this product's components. Ventilation Based on available information, additional ventilation is not required. PERSONAL PROTECTIVE EQUIPMENT Eyes/Face Eye protection not required under normal conditions. Protective Clothing Protective clothing is not required under normal conditions. Glove Recommendations Protective gloves are not required under normal conditions. Respiratory Protection No respirator is required under normal conditions of use. * * *Section 9 - PHYSICAL AND CHEMICAL PROPERTIES* * * Physical State: Liquid Appearance: Not available Color: various colors Physical Form: article containing liquid Odor: Not Available Odor Threshold: Not available pH: Not available Melting Point: Not available Boiling Point: Not available Flash Point: >93.3 °C estimated ink Evaporation Rate: Not available OSHA Flammability Class: IIIB Vapor Pressure: Not available Vapor Density (air = Not available Density: Not available Specific Gravity (water = Not available Water Solubility: Not available Coeff. Water/Oil Dist: Not available Viscosity: Not available Volatility: Not available * * *Section 10 - STABILITY AND REACTIVITY* * * Chemical Stability Stable at normal temperatures and pressure. Conditions to Avoid None reported. Materials to Avoid oxidizing materials Decomposition Products oxides of carbon Page 232 of 1069 Page 232 of 1069 Page 232 of 1069 Page 232 of 1069 ---PAGE BREAK--- Safety Data Sheet Material Name: CRAYOLA® COLOR WONDER MARKERS, CW SPRAYER; CW WATERCOLORS SDS ID: 00228442 Page 4 of 6 Issue Date: 03/19/2014 Revision: 1.0105 Print Date: 01/29/2015 Possibility of Hazardous Reactions Will not polymerize. * * *Section 11 - TOXICOLOGICAL INFORMATION* * * Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and no selected endpoints have been identified. RTECS Acute Toxicity (selected) The components of this material have been reviewed and RTECS publishes no data as of the date on this document. Component Carcinogenicity None of this product's components are listed by ACGIH, IARC, or DFG. RTECS Irritation The components of this material have been reviewed and RTECS publishes no data as of the date on this document. * * *Section 12 - ECOLOGICAL INFORMATION* * * Component Analysis - Aquatic Toxicity No LOLI ecotoxicity data are available for this product's components. * * *Section 13 - DISPOSAL CONSIDERATIONS* * * Disposal Methods Dispose in accordance with all applicable regulations. Component Waste Numbers The U.S. EPA has not published waste numbers for this product's components. * * *Section 14 - TRANSPORT INFORMATION* * * US DOT Information Not regulated as a hazardous material. TDG Information Not regulated as dangerous goods. ADR Information Not regulated as dangerous goods. RID Information Not regulated as dangerous goods. IATA Information Not regulated as dangerous goods. ICAO Information Not regulated as dangerous goods. IMDG Information Not regulated as dangerous goods. Page 233 of 1069 Page 233 of 1069 Page 233 of 1069 Page 233 of 1069 ---PAGE BREAK--- Safety Data Sheet Material Name: CRAYOLA® COLOR WONDER MARKERS, CW SPRAYER; CW WATERCOLORS SDS ID: 00228442 Page 5 of 6 Issue Date: 03/19/2014 Revision: 1.0105 Print Date: 01/29/2015 * * *Section 15 - REGULATORY INFORMATION* * * Component Analysis None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan. SARA Section 311/312 (40 CFR 370 Subparts B and C) Acute Health: No Chronic Health: No Fire: No Pressure: No Reactive: No Component Analysis - State None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA. Not regulated under California Proposition 65 Canada This product has been classified in accordance with the criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. WHMIS Classification: Not a Controlled Product under Canada's Workplace Hazardous Material Information System. Canadian WHMIS Ingredients Disclosure List Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List and no components were found on the list. Component Analysis - Inventory No information is available. * * *Section 16 - OTHER INFORMATION* * * Key / Legend ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™- ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States Page 234 of 1069 Page 234 of 1069 Page 234 of 1069 Page 234 of 1069 ---PAGE BREAK--- Safety Data Sheet Material Name: CRAYOLA® COLOR WONDER MARKERS, CW SPRAYER; CW WATERCOLORS SDS ID: 00228442 Page 6 of 6 Issue Date: 03/19/2014 Revision: 1.0105 Print Date: 01/29/2015 End of Sheet 00228442 Page 235 of 1069 Page 235 of 1069 Page 235 of 1069 Page 235 of 1069 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 1 of 8 Vesuvius USA 495 Emma Street, Bettsville, Ohio 44815 Safety Data Sheet CRITERION® 90 SRM SDS Number SDS-30567 Revision: 1 Legacy Number: LEB31741 Preparation Information: Site: All Contact Deb Cook @ (419) 986-5126 for further product information or medical emergency during normal business hours. Section 1: Product and Company Identification Product Name: CRITERION® 90 SRM Chemical Name: Mixture Formula: N/A CAS Number: N/A Product Use: Advanced Refractories Supplier Information: Supplier Name: Vesuvius USA Supplier Phone: (419) 986-5126 Supplier Address: 495 Emma Street Bettsville, OH 44815 Manufacturer Information: Manufacturer Name: Vesuvius USA Manufacturer Phone: (419) 986-5126 Manufacturer Address: 495 Emma Street Bettsville, OH 44815 Emergency Contact Information: CHEMTREC (800) 424-9300 (USA) CANUTEC (613) 996-6666 (CANADA) Page 236 of 1069 Page 236 of 1069 Page 236 of 1069 Page 236 of 1069 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 2 of 8 Section 2: Hazard(s) Identification Hazard Classification: Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 2 Specific Target Organ Toxicity, Repeated or Prolonged Exposure - Category 2 Signal Word: Warning Hazard Statement(s): Causes mild skin irritation Causes eye irritation May cause respiratory irritation Pictograms: Precautionary Statement(s): Prevention Do not eat, drink, or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. Wash thoroughly after handling. Response If eye irritation persists, remove contact lenses if necessary and rinse eyes with water. Seek medical attention if needed. If skin is irritated, wash with plenty of soap and water. Seek medical attention if needed. If breathing is difficult, remove victim to fresh air and keep at rest in comfortable position, seek medical advice/attention. Storage Product contains chemicals, which will upon exposure to moisture result in product consolidation. Store in a dry place. Disposal This product, as manufactured, does not exhibit any characteristics of a hazardous waste. It is suitable for landfill disposal. However, debris generated during installation, maintenance or tear-out procedures may be contaminated with other hazardous materials. Therefore, appropriate waste analysis may be necessary to determine proper disposal. A qualified environmental professional in accordance with applicable federal, state, and local regulations should determine waste characterisation and disposal/treatment methods. Hazards not Otherwise Classified: N/A Percentage of the mixture consisting of ingredients of unknown toxicity: N/A Section 3: Composition/Information on Ingredients Ingredient: CAS No. / Other Identifiers: % Weight: Aluminum Oxide, non-fibrous 1344-28-1 85-95 Calcium Aluminate 12042-68-1 3-7 Magnesium Oxide 1309-48-4 3-7 Page 237 of 1069 Page 237 of 1069 Page 237 of 1069 Page 237 of 1069 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 3 of 8 Section 4: First Aid Measures Emergency Overview: Product is only an issue at tear-out when dust can occur. Potential Health Effects: Respiratory irritation can occur at tear-out when dust can occur. Chronic Health Hazards: Prolonged inhalation of product dust may cause lung damage. Medical Conditions Generally Aggravated by Exposure: Pre-existing skin and respiratory ailments. Routes of Entry: Eyes? Yes Skin? Yes Inhalation? Yes Ingestion? No Other? Carcinogenicity: NTP? No IARC? No OSHA? No WHMIS? No Other? Details: Dust from mixture can cause respiratory irritation. Calcium aluminate, when wet, can be a skin and eye irritant. Eye Contact: Immediately flush with water for a t least 15 minutes. If irritations persists, consult physician. Skin Contact: Immediately wash with cold water. If irritations persists, consult physician. Inhalation: Remove person to fresh air. If problems persist, consult physician. Ingestion: N/A Section 5: Fire-Fighting Measures Flash Point: N/A Auto-Ignition: N/A LEL: N/A UEL: N/A NFPA Hazard Classification: Health: 1 Flammable: 0 Reactivity: 0 Special Hazard: N/A HMIS Hazard Classification: Health: 1 Flammable: 0 Reactivity: 0 PPE: B Extinguishing Media: No special instructions or conditions. Special Fire Fighting Procedures: No special instructions other than use of approved respirators. Page 238 of 1069 Page 238 of 1069 Page 238 of 1069 Page 238 of 1069 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 4 of 8 Product is not combustable. No hazardous decomposition products. Unusual Fire and Explosion Hazards: SENSITIVITY TO MECHANICAL IMPACT: N/A SENSITIVITY TO STATIC DISCHARGE: N/A OTHER: N/A Section 6: Accidental Release Measures Sweep or pick up with vacuum cleaner. Minimize dust levels and wear dust mask. Section 7: Handling and Storage Store in dry place to minimize exposure to moisture. Section 8: Exposure Controls/Personal Protection Exposure Limits Ingredient PEL-OSHA TLV-ACGIH Other Calcium Aluminate 5 mg/M3 (respirable) 5 mg/M3 (respirable) N/A Aluminum Oxide, non-fibrous 5 mg/M3 (respirable) 1 mg/M3 (respirable) N/A Magnesium Oxide 15 mg/M3 10 mg/M3 (inhalable) N/A Details: N/A Respiratory Protection: If PEL/TLV is exceeded, use NIOSH approved mask/respriator for above listed ingredients. Ventilation LOCAL: N/A SPECIAL: N/A MECHANICAL: As required to maintain levels below the listed PEL/TLVs. ENGINEERING CONTROLS: N/A Protective Equipment: GLOVES: anti slip gloves EYE: safety glasses CLOTHING: long sleeves Personnel Sampling Procedure: N/A PPE Symbols Displayed: Page 239 of 1069 Page 239 of 1069 Page 239 of 1069 Page 239 of 1069 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 5 of 8 Section 9: Physical and Chemical Properties Chemical Properties Appearance (physical state, color, etc.): A dry gray mixture of fine materials. Odor: N/A Odor threshold: N/A pH: N/A Melting point/freezing point: N/A Initial boiling point and boiling range: N/A Flash point: N/A Evaporation rate: N/A Flammability (solid, gas): N/A Upper/lower flammability or explosive limits: N/A Vapor pressure: N/A Vapor density: N/A Relative density: N/A Solubility(ies): N/A Partition coefficient: n-octanol/water: N/A Auto ignition temperature: N/A Decomposition temperature: N/A Viscosity: N/A Other Relevant Properties: N/A Section 10: Stability and Reactivity Stability: Stable Avoid: N/A Reactivity: N/ANone Avoid: N/A Other: N/A Incompatibility: None Hazardous Decomposition of By-products None Polymerization: Will not occur Avoid: N/A Page 240 of 1069 Page 240 of 1069 Page 240 of 1069 Page 240 of 1069 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 6 of 8 Section 11: Toxicological Information Chemical Name % Wt. LD50 LC50 Route of Exposure: Short / Long Term Exposure Effects: Known Carcinogen: N/A Other Studies: Section 12: Ecological Information Ecotoxicity: N/AV Environmental Fate: N/AV Section 13: Disposal Considerations Dispose of in accordance with local, state and federal regulations. Section 14: Transport Information International N/A United States N/A Canada SHIPPING NAME: N/A P.I.N/UN: N/A PRIMARY CLASS: N/A SUBSIDIARY CLASS: N/A PACKING GROUP: N/A European Community N/A Section 15: Regulatory Information US Federal Regulations TSCA All components of this product are included on the EPA TSCA Chemical Substance Inventory. SARA 311 and 312 Hazard Categories: Immediate (Acute) Health Hazard: Yes Delayed (Chronic) Health Hazard: No Fire Hazard: No Reactivity: No Page 241 of 1069 Page 241 of 1069 Page 241 of 1069 Page 241 of 1069 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 7 of 8 Sudden Release of Pressure: No SARA Section 313 Notification: This product contains no toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372, based upon our knowledge of the raw materials comprising this product. Ozone Depleting Substances: N/A Volatile Organic Compounds (VOC): N/A US State Regulation: N/A Canadian Regulation: WHMIS CLASSIFICATION: E This Product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. European Regulation: N/A Other Regulation: N/A MITI: N/A N/A is Not Applicable N/K is Not Known N/AV is Not Available Section 16: Other Information The product is a fired refractory brick/shape available in various sizes and shapes. It is composed of the mineral phases in Section 3, some of which may be present in dust generated by sawing, cutting, or crushing during installation or tear-out. Document Revision History: Revision: 1 Date Created: 06/12/2015 Date of Last Revision: 06/12/2015 Last Approval Date: 06/12/2015 Document Author: Deb Cook SDS Status: Page 242 of 1069 Page 242 of 1069 Page 242 of 1069 Page 242 of 1069 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 8 of 8 Disclaimer Information contained within this safety data sheet is based on the current state of knowledge and relates to such products, their intended usage and the required safety precautions. Although every effort has been made to ensure that this information is correct and gives adequate safety margins in line with current knowledge, it does not constitute a specification and no information for other purposes, particularly information regarding properties of the delivered materials, may be inferred. Determination of the technical suitability of each material and complying with any guidance relating to safe usage remain the sole responsibility of the user. Consequently, beyond any separately agreed contractual arrangements, the aforementioned manufacturer and its subsidiaries exclude any and all liability resulting from the use of the product. Unknown hazards may be inherent in all materials; therefore these materials shall be treated with caution. Although certain hazards are described herein, we are unable to guarantee that these are the only hazards. Page 243 of 1069 Page 243 of 1069 Page 243 of 1069 Page 243 of 1069 ---PAGE BREAK--- PRODUCT AND COMPANY IDENTIFICATION 1 Manufacturer James Austin Company 115 Downieville Road PO Box 827 Mars, PA 16046 [PHONE REDACTED] [PHONE REDACTED] www.jamesaustin.com Emergency phone number: CHEMTREC US: 1-[PHONE REDACTED] Canada: 1-[PHONE REDACTED] Poison Control Center: 1-[PHONE REDACTED] Regular Bleach 6/15/2015 1 28 Sodium Hypochlorite 7681-52-9 54200-04028, 54200-03753 NaOCl Bleach, Liquid Bleach, Soda Bleach 90037530, 90040280 Product Name: Revision Date: Version: SDS Number: Common Name: CAS Number: Product Code: Chemical Formula: Synonyms: Internal ID: Phone: Fax: Web: HAZARDS IDENTIFICATION 2 GHS Signal Word: WARNING GHS Hazard Pictograms: GHS Classifications: Health, Skin corrosion/irritation, 2 Health, Serious Eye Damage/Eye Irritation, 2 B Health, Specific target organ toxicity - Single exposure, 3 Environmental, Hazards to the aquatic environment - Acute, 1 Environmental, Hazards to the aquatic environment - Chronic, 4 GHS Phrases: H315 - Causes skin irritation H320 - Causes eye irritation H335 - May cause respiratory irritation Regular Bleach Safety Data Sheet Revision Date: 6/15/2015 SDS Number: 28 Page of 1 6 James Austin Company Page 244 of 1069 Page 244 of 1069 Page 244 of 1069 Page 244 of 1069 ---PAGE BREAK--- GHS Precautionary Statements: P220 - Keep/Store away from clothing/combustible materials. P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P264 - Wash exposed skin thoroughly after handling. P262 - Do not get in eyes, on skin, or on clothing. P270 - Do not eat, drink or smoke when using this product. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P273 - Avoid release to the environment. P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P303+361+353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 - IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P309+311 - IF exposed or you feel unwell: Call a POISON CENTER or doctor/physician. P401 - Store upright in a cool, dry place. P501 - Dispose of contents/container to an approved waste disposal plant. H400 - Very toxic to aquatic life H413 - May cause long lasting harmful effects to aquatic life COMPOSITION/INFORMATION ON INGREDIENTS 3 Cas # I Percentage I Chemical Name 7681-52-9 I 1.00-5.00% I Sodium hypochlorite 7732-18-5 I 95.00-99.00% I Water Ingredients: FIRST AID MEASURES 4 In the event of exposure to excessive vapor levels, move the individual to fresh air and seek medical attention if develop or persist. Immediately rinse with plenty of water while removing any contaminated clothing. If irritation develops or persists, seek medical attention. Wash contaminated clothing before resuse. Rinse immediately with plenty of water. Keep eye(s) wide open while rinsing. Avoid rubbing the affected area. Seek medical attention if needed. Do NOT induce vomiting. Rinse mouth thoroughly with water. Drink plenty of water. Call a physician or poison control center. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Inhalation: Skin Contact: Eye Contact: Ingestion: Regular Bleach Safety Data Sheet Revision Date: 6/15/2015 SDS Number: 28 Page of 2 6 James Austin Company Page 245 of 1069 Page 245 of 1069 Page 245 of 1069 Page 245 of 1069 ---PAGE BREAK--- FIRE FIGHTING MEASURES 5 Highly exothermic reactions with organic materials and oxidizable materials may cause fires. In the event of a fire, wear full protective clothing and MSHA/NIOSH self-contained breathing apparatus with a full facepiece operated in the pressure-demand or other positive pressure mode. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment; Water spray may be used to keep fire exposed containers cool. Flammability: Not flammable Flash Point: No information available LEL: No information available UEL: No information available Flash Point Method: No information available Burning Rate: No information available Autoignition Temp: No information available ACCIDENTAL RELEASE MEASURES 6 Use personal protective equipment as required/recommended. Evacuate public to a safe area. Avoid contact with skin, eyes, and clothing. Prevent spills from entering sewers or waterways. Contain run-off using diking composed of a suitable material. Soak up liquid on inert absorbant and transfer to an approved container. Clean contaminated surface thoroughly. HANDLING AND STORAGE 7 Use personal protective equipment as required/recommended. Use only with adequate ventilation. Avoid contact with skin, eyes, and clothing. Use suitable respiratory equipment in case of inadequate ventilation. Store using properly labeled containers in a cool, dry, well ventilated area. Keep out of reach of children. Separate from incompatible materials. Handling Precautions: Storage Requirements: EXPOSURE CONTROLS/PERSONAL PROTECTION 8 Use adequate ventilation, especially in confined spaces Chemical splash goggles; Face shield; Neoprene gloves; NIOSH approved respirator; Apron. Engineering Controls: Personal Protective Equip: Regular Bleach Safety Data Sheet Revision Date: 6/15/2015 SDS Number: 28 Page of 3 6 James Austin Company Page 246 of 1069 Page 246 of 1069 Page 246 of 1069 Page 246 of 1069 ---PAGE BREAK--- PHYSICAL AND CHEMICAL PROPERTIES 9 Liquid 1.040 - 1.055 11.50 - 12.50 Physical State: Spec Grav./Density: pH: Odor: Solubility: Pungent; Chlorine Completely miscible in water Appearance: Clear yellow STABILITY AND REACTIVITY 10 The product is stable and non-reactive under normal conditions of use, storage and transport. Contact with incompatible materials. Excessive heat and exposure to light. Reacts violently with strong acids producing chlorine gas. Contact with amines will result in chloramines. Strong oxidizing agents, acids, metals, organic compounds, ammonia. Oxidizable or combustible materials. None under normal processing. Will not occur. Stability: Conditions to Avoid: Materials to Avoid: Hazardous Decomposition: Hazardous Polymerization: TOXICOLOGICAL INFORMATION 11 Toxicity Data: Eye Effects: Causes eye burns. Skin Effects: Causes skin irritation and may cause burns to broken skin. Acute Inhalation Effects: Vapors and mist may irritate throat and respiratory system; may cause coughing. Chronic Effects: Prolonged or repeated overexposure may cause lung damage. Carcinogenicity: Not a known carcinogen. Mutagenicity: Not Known. Teratogenicity: Not Known. Acute Toxicity: Oral ( LD 50): No data available Inhalation ( LC 50): No data available Skin irritation: Causes severe skin irritation and may cause burns to broken skin Eye irritation: Causes serious eye damage Sensitation: No data available Chronic Toxicity: IARC Group 3; Not classifiable as a human carcinogen Regular Bleach Safety Data Sheet Revision Date: 6/15/2015 SDS Number: 28 Page of 4 6 James Austin Company Page 247 of 1069 Page 247 of 1069 Page 247 of 1069 Page 247 of 1069 ---PAGE BREAK--- ECOLOGICAL INFORMATION 12 This product is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a national pollutant discharge elimination system (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your state water board or regional office of the EPA. DISPOSAL CONSIDERATIONS 13 Disposal should be in accordance with applicable regional, national, and local laws and regulations. Do not reuse container but place in trash collection or offer for recycling where facilities accept colored HDPE bottles. TRANSPORT INFORMATION 14 DOT: Not regulated. Classified as non-hazardous. REGULATORY INFORMATION 15 COMPONENT/(CAS/PERC)/CODES *Sodium hypochlorite (7681529 1.00 - 5.00%) CERCLA, MASS, PA, TSCA *Water (7732185 95.00 - 99.00%) TSCA REGULATORY KEY DESCRIPTIONS CERCLA = Superfund clean up substance = Clean Water Act Hazardous substances MASS = MA Massachusetts Hazardous Substances List PA = PA Right-To-Know List of Hazardous Substances TSCA = Toxic Substances Control Act OSHAWAC = OSHA Workplace Air Contaminants TXAIR = TX Air Contaminants with Health Effects Screening Level Regular Bleach Safety Data Sheet Revision Date: 6/15/2015 SDS Number: 28 Page of 5 6 James Austin Company Page 248 of 1069 Page 248 of 1069 Page 248 of 1069 Page 248 of 1069 ---PAGE BREAK--- OTHER INFORMATION 16 Author: James Austin Company Publication Date: 12/11/2014 Revision Note: MSDS converted to GHS SDS format Disclaimer: James Austin Company provides this information without warranty. The information is believed to be accurate, but James Austin Company makes no representations as to its accuracy. The information should be used to make an independant determination and therefore, users are responsible to verify this data under their own operating conditions and methods. This information relates only to the product designated herein, and does not relate to its use in combination with other materials or processes. Regular Bleach Safety Data Sheet Revision Date: 6/15/2015 SDS Number: 28 Page of 6 6 James Austin Company Page 249 of 1069 Page 249 of 1069 Page 249 of 1069 Page 249 of 1069 ---PAGE BREAK--- 28 May 2015 aqua (water) diluent 7732-18-5 Not applicable thymol (a component of thyme oil) antimicrobial active 8007-46-3 0.05% 980 mg/kg Other ingredients: . 99.95% . Ingredient Function CAS Number Concentration1 LD502 Active ingredient . . Eyes Minimal eye irritant category IV Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients on the consumer product label. Section 3: Composition, Information on Ingredients Precautionary Statements Emergency Overview No or effects under normal use. May cause slight irritation of eyes, skin or respiratory tract. This product is not considered hazardous under the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). This product is not considered hazardous under the WHMIS 2015. Classification U.S. Canada Section 2: Hazards Identification A PERSONAL PROTECTION Not determined Hazardous Materials Identification System (HMIS) Rating 0 0 0 PHYSICAL HAZARDS FLAMMABILITY Skin Slight dermal irritant category IV. Non-sensitizer. Ingestion May cause transient gastrointestinal irritation. HEALTH Legend: 4-Severe, 3-Serious, 2-Moderate, 1-Slight, 0-Minimal Inhalation May cause slight irritation. Hazards not otherwise identified None known Percent ingredients with unknown acute toxicity 0% of the product consists of ingredients of unknown acute oral toxicity. Refer to Section 3. SAFETY DATA SHEET National Fire Protection Association (NFPA) Rating Botanical Disinfecting Multi-Surface Cleaner Hard Surface Disinfecting and Cleaning Seventh Generation, Inc. 60 Lake Street, Burlington, VT 05401, USA This Safety Data Sheet (SDS) is intended to provide product information for workplaces, emergency personnel and other situations where there is potential for longer exposure or exposure to larger quantities of product. For consumer use, applicable precautionary information is provided on the product label. This SDS is designed to cover both U.S. and Canadian requirements. Differences between U.S. and Canadian requirements are noted where applicable. Issue date Emergency Telephone Number U.S. Canada 1-[PHONE REDACTED] 1-[PHONE REDACTED] (ChemTel) Monday -Friday 8 am - 5 pm ET (except holidays) Outside these hours Address Restrictions on Use Follow directions on the product label Section 1: Identification of Product and Company Product Name Synonyms Product Use Manufacturer Name Disinfecting Multi-Surface Cleaner FM000054-00.2 Page 1 of 6 Page 250 of 1069 Page 250 of 1069 Page 250 of 1069 Page 250 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Safe Handling Household Setting Use as directed on product label. Industrial Setting Wear appropriate personal protective equipment (refer to section Section 7: Handling and Storage Section 6: Accidental Release Measures Personal Precautions Protective Equipment and Precautions for Firefighters Fire fighters should wear full protective clothing and self contained breathing apparatus as for surrounding fire. Suitable Extinguishing Media As appropriate for surrounding fire. Use water, dry chemical, carbon dioxide or foam. Unsuitable Extinguishing Media Not available. Most important and effects Acute exposure may result in eye irritation. Specific Hazards arising from the chemical mixture Not available. Hazardous Combustion Products Not available. Section 4: First Aid Measures *Lemongrass Citrus Scent: cymbopogon nardus (citronella) oil, cymbopogon schoenanthus (lemongrass) oil. Citral is a component of these essential oils. 1 Where ranges are shown, the exact concentration has been withheld as a trade secret. 2 LD50 Acute oral toxicity (rat) – This is a value provided by the raw material supplier or scientific literature. It is not a value generated by Seventh Generation by testing using rats. Seventh Generation uses alternative, non-animal based methods and scientific literature to determine the safety classification of our products and their ingredients. sodium citrate water softener 6132-04-3 6730 mg/kg essential oils* fragrance mixture >5000 mg/kg origanum vulgare (oregano) oil fragrance 8007-11-2 1850 mg/kg copper sulfate pentahydrate (bluestone) water mineralizer 7758-99-8 300 mg/kg citric acid water softener 77-92-9 3000 mg/kg sodium lauryl sulfate cleaning agent 151-21-3 1288 mg/kg Eye Contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a doctor or poison control center for treatment advice. Section 5: Fire Fighting Measures Skin Contact Rinse thoroughly with water if skin contact occurs. Call a physician if irritation develops or persists. Ingestion Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a doctor or poison control center. Do not give anything to an unconscious person. Inhalation Remove to fresh air. If breathing is affected, call a physician. Notes to Physician Treat Industrial Setting Wear appropriate personal protective equipment (refer to Section Environmental Precautions Avoid entry into lakes, streams, ponds or public waterways. Methods for Containment and Cleaning Up Household Setting Small spills and leaks may be cleaned up and disposed of in normal household trash or diluted and disposed of via sewer. Industrial Setting Before attempting clean up, refer to hazard data given. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labeled containers. Prevent extremely large spills from entering sewers or waterways. Dispose in accordance with all applicable local, state, and federal regulations. Page 2 of 6 Page 251 of 1069 Page 251 of 1069 Page 251 of 1069 Page 251 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Possibility of Hazardous Reactions None known. Household Setting In general, cleaning products should not be mixed with other household chemicals, unless specifically provided for in the use directions. Section 10: Stability and Reactivity Industrial Setting None known. Hazardous Decomposition Products None known. Conditions to Avoid None known. Incompatible Materials VOC (weight Not available. Partition Coefficient: n-octanol/water Not available. Viscosity Not available. Vapor Density (Air = 1) Not available. Solubility in Water Soluble Specific Gravity (H2O = 1) 1.00-1.02 Relative Density Not available. Lower Explosive Limit (LEL) Not applicable. Vapor Pressure (mmHg) Not available. Evaporation Rate As per water. Upper Explosive Limit (UEL) Not applicable. Flash Point Not available. Aqueous Solution. Freezing Point As per water. Initial Boiling Point and Boiling Range As per water. pH 4.0 - 5.0 Melting Point As per water. Odor Scented. Characteristic of the ingredients Odor Threshold Not available. Color Colorless (water-white) Clarity Clear Physical State Liquid. Section 9: Physical and Chemical Properties Eye Protection Goggles or other protective eye wear may be worn for protection. Skin Protection Gloves may be worn for protection. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Safe Storage KEEP OUT OF REACH OF CHILDREN AND PETS. Nonrefillable container. Store airtight at room temperature in original container and keep container closed when not in use. Avoid freezing. Storage Incompatibilities None known. Industrial Setting Respiratory Protection None required under normal conditions. General ventilation required. Exposure Limits None known. Engineering Controls Not applicable. Personal Protective Equipment (PPE) Household Setting No special precautions necessary as long as product is used as directed. Section 8: Exposure Controls, Personal Protection Reactivity None known. Chemical Stability Stable. Page 3 of 6 Page 252 of 1069 Page 252 of 1069 Page 252 of 1069 Page 252 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Washington Hazardous Waste Code WT02 Industrial Setting When disposed as waste in its original form, this product is not considered hazardous waste under Federal regulations, however regulations may vary by state or province and may designate it as hazardous waste. Check with your local waste and waste water authorities. We are aware of the following state waste classifications: California Hazardous Waste Code 232 Connecticut Hazardous Waste Code CT04 Michigan Liquid Waste Code 029L Vermont Hazardous Waste Code VT06 Product Waste Any disposal must be in compliance with applicable local, state, provincial and federal laws and regulations. Household Setting Product residues in the bottle may be discarded in trash, or diluted with water and disposed via sewer. Compatible with septic systems. Section 13: Disposal Considerations Environmental Fate No adverse effects expected. Bioaccumulative Potential Not applicable. Mobility in Soil Not available. Ecotoxicity Not available. Persistence and Degradability Meets requirements for ready biodegration based on OECD 301B. Section 12: Ecological Information Target Organ Effects Not expected to have chronic health effects. Not expected to have chronic health effects. Reproductive Effects Teratogenicity Not expected to have chronic health effects. Mutagenicity Not expected to have chronic health effects. NTP No Ingredients Listed IARC No Ingredients Listed OSHA No Ingredients Listed Carcinogenicity Not expected to have chronic health effects. Not expected to have chronic health effects. Sensitization Does not indicate a potential for allergic contact sensitization, based on Human Repeat Insult Patch Test (HRIPT). Skin Contact Non to slight dermal irritant category IV, based on ingredients and in-vitro data. Component Information Refer to section 3 for ingredient LD50 (acute oral). Effects of Acute Exposure Section 11: Toxicological Information Oral Toxicity LD50 >5000 mg/kg, calculated based on ingredients. Dermal Toxicity LD50 >5000 mg/kg, calculated based on ingredients. Inhalation Toxicity >20 mg/L/4h, based on ingredients. Eye Contact Potential Route(s) of Exposure Eyes. Skin. Ingestion. Minimal eye irritant category IV, based on ingredients and in-vitro data. Effects of Chronic Exposure Page 4 of 6 Page 253 of 1069 Page 253 of 1069 Page 253 of 1069 Page 253 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Offer empty container for recycling. If recycling is not available, discard in trash. Prepared by Seventh Generation Inc. Issuing Date 28 May 2015 Section 16: Other Information Health Canada Registration Number DIN 02415070 Right to Know Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients on the product label. Please refer to Section 3. of this SDS for ingredient listing. Other Fragrances used in this product comply with applicable International Fragrance Association (IFRA) guidance. California Prop 65 This product is not subject to the labeling requirements of California’s Proposition 65. California Air Resources Board (CARB) Meets applicable California Air Resource Board requirements for consumer products. Canada Domestic Substances List (DSL) This product complies with the inventory requirements under Canada’s Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL) or is otherwise in compliance with the New Substances Notification (NSN) regulations or exemptions. Toxic Substances Control Act (TSCA) This product complies with the inventory requirements of the U.S. Toxic Substances Control Act (TSCA). U.S. EPA Registration Number 84683-3-86066 California DPR Registration Number 84683-3-ZA-86066 Section 15: Regulatory Information IATA (Air Transport) Not regulated. IMDG (Marine Transport) Not regulated. U.S. States (Surface Transport) Not regulated as finished product. Regulated in some states if the product is disposed of in its original form as waste by commercial users/handlers. Refer to Section 13. for applicable state waste codes. Canadian TDG (Surface Transport) Not regulated. U.S. DOT (Surface Transport) Not regulated. Section 14: Transport Information Empty Packaging Revision Date 28 May 2015 Please note: This product is manufactured and marketed for consumer use and should be used as directed on the product label for the intended purpose. Seventh Generation warrants that this product conforms to our standard specification when released to the market and when used according to directions. To the best of our knowledge, the information contained herein is accurate. However, we do not assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any product is the sole responsibility of the user. All products may present unknown hazards and should be used with requisite caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Other abbreviations used in this document: Revision Note Revised format as per OSHA 2012 and WHMIS 2015. Page 5 of 6 Page 254 of 1069 Page 254 of 1069 Page 254 of 1069 Page 254 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET End of Safety Data Sheet DOT – Department of Transportation EPA – Environmental Protection Agency IARC – International Agency for Research on Cancer NTP – (U.S. Department of Health and Human Services) National Toxicology Program OSHA – Occupational Safety and Health Administration TDG – (Canadian) Transport of Dangerous Goods WHMIS – (Canadian) Workplace Hazardous Materials Information System Page 6 of 6 Page 255 of 1069 Page 255 of 1069 Page 255 of 1069 Page 255 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Share Corporation P.O. Box 245013 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER: (800) 776-7192 REVISION DATE: March 8, 2007 CHEMTREC: (800) 424-9300 DATE OF ISSUE: March 12, 2007 I - Product Identification DR-OP Drain Opener PRODUCT CODE: 0617 CHEMICAL FORMULATION: Granular alkaline drain opener. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 3 FLAMMABILITY: 0 REACTIVITY: 2 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. EPA 40 CFR: SUBSTANCE APPROX % OSHA PEL ACGIH TLV 302 355 372 CAS # Sodium Hydroxide > 50.0 2 mg/m3 C 2 mg/m3 C Y N N 1310-73-2 Sodium Nitrate > 18.0 N/E N/E N N N 7631-99-4 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = N/D VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): 0 VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = N/A SOLUBILITY IN WATER: Complete pH: > 14.0 APPEARANCE AND ODOR: Yellow pellets with aluminum granules; no odor. IV - Fire and Explosion Hazard Data FLASH POINT None (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical. Do not use water. Water will heat up mixture. SPECIAL FIRE FIGHTING PROCEDURES: Move containers from fire if possible without risk. Cool closed containers with water from the side until well after fire is out. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. Runoff may be corrosive. Contain and isolate runoff for proper disposal. UNUSUAL FIRE AND EXPLOSION HAZARD: Addition of water to this compound will generate heat and hydrogen gas. Product contains oxidizers. Page 256 of 1069 Page 256 of 1069 Page 256 of 1069 Page 256 of 1069 ---PAGE BREAK--- P RODUCT NAME: DR-OP Drain Opener PRODUCT CODE: 0617 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Acids, reducing agents, water. Product will generate large amounts of heat when wetted. CONDITIONS TO AVOID: Moisture. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce flammable hydrogen gas upon wetting. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Severe destruction of tissue, possibly resulting in blindness. IF ON SKIN: Severe irritation, severe burns and ulcerations. IF SWALLOWED: Danger-Poison! May be fatal if swallowed. Causes severe burns to mucous membranes, destruction of tissue, burns. IF INHALED: Severe irritation of respiratory tract. Pulmonary edema, laryngeal spasms. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes, or wash with a 5% boric acid solution. Obtain medical attention and continue flushing until medical attention arrives. IF ON SKIN: Immediately flood skin with water. Remove and launder contaminated clothing before re-use. Wash skin thoroughly with vinegar and water. IF SWALLOWED: Contact physician or poison control center immediately. Do not induce vomiting. Give person large quantities of water, followed with citrus fruit juice. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air. If not breathing, administer artificial respiration. Obtain medical attention. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spill and remove all sources of moisture. Ventilate area. Sweep up spilled material and place in a properly labeled closed container for re-use or disposal WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. Do not breath dust or vapors. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Recommended PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety goggles. OTHER PROTECTIVE EQUIPMENT: Emergency shower and eyewash station. Protective clothing. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT ID NUMBER: N/A DOT PROPER SHIPPING NAME: Consumer Commodity DOT CLASS: ORM-D DOT PACKING GROUP: N/A The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: March 8, 2007 Prepared by: Technical Dept. DATE OF ISSUE: March 12, 2007 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Share Corporation assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material. Page 257 of 1069 Page 257 of 1069 Page 257 of 1069 Page 257 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 1/9 Material Safety Data Sheet F 1. Chemical Product and Company Identification DESCRIPTION: ELMER'S STICKY OUT PRODUCT TYPE: SOLVENT BASED CLEANER APPLICATION: 171, 53295 · Manufacturer/Supplier Information MSDS Prepared by: Elmer's Products, Inc. Emergency Phone Number 1 Easton Oval Poison Control Center Columbus, OH 43219 1-[PHONE REDACTED] For additional health, safety or regulatory information, call 1-[PHONE REDACTED]. Call 1-[PHONE REDACTED] to place an order or request additional 2. Composition, Information on Ingredients The ingredients listed below have been associated with one or more immediate and/or delayed(*) health hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS. % by weight 5989-27-5 *D-Limonene 30-50 64742-46-7 *Hydrotreated Middle Distillate (petroleum) >70 68131-39-5 Alcohols, C12-15, Ethoxylated 5-10 3. Hazards Identification 3.1 Emergency Overview Page 258 of 1069 Page 258 of 1069 Page 258 of 1069 Page 258 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 2/9 Appearance Clear pale yellow liquid Odor Citrus CAUTION! COMBUSTIBLE May be harmful if inhaled. May cause irritation of nose, throat and lungs. Can cause central nervous system depression. Causes skin irritation. Causes eye irritation. · HMIS Rating HEALTH = 2 (moderate) FLAMMABILITY = 2 (moderate) REACTIVITY = 0 (minimal) CHRONIC = * 3.2 Potential Health Effects · Immediate Hazards INGESTION: Not expected to be harmful under normal conditions of use. If accidentally swallowed, burns or irritation to mucous membranes, esophagus or GI tract can result. INHALATION: May be harmful if inhaled. Liquid or vapor may cause irritation of nose, throat and lungs. Can cause central nervous system depression. SKIN: Causes irritation. EYES: Causes irritation. Hydrotreated Middle Distillate (petroleum) 64742-46-7 Can cause central nervous system depression. Signs and may include headache, dizziness, nausea, vomiting, unconsciousness and even Alcohols, C12-15, Ethoxylated 68131-39-5 Can cause central nervous system depression. Signs and may include headache, dizziness, nausea, vomiting and drowsiness. · Delayed Hazards D-Limonene 5989-27-5 May cause allergic skin reaction and photosensitivity. Ingestion may cause kidney damage. See Footnote C. Hydrotreated Middle Distillate (petroleum) 64742-46-7 Can cause lung inflammation. Pre-existing respiratory disorders Page 259 of 1069 Page 259 of 1069 Page 259 of 1069 Page 259 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 3/9 may be aggravated by exposure. See Footnote C. Footnote C: As of the date of issuance of this document, this material has not been listed by NTP, classified by IARC nor regulated by OSHA as a carcinogen. 4. First Aid Measures INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Call a physician. SKIN: Flush with plenty of water. Remove contaminated clothing. Call a physician if irritation persists. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held apart during irrigation to insure water contact with entire surface of eyes and lids. Call a physician. 5. Fire Fighting Measures Autoignition Temperature Not available Upper/Lower Flammable Limits Not available Up/Lower Explosive Limits, % by Vol 6.1/0.7 % Flash Point 46°C (114°F) COMBUSTIBLE. Keep away from heat and flame. In case of fire, use dry chemical, "alcohol" foam or CO2; water may be ineffective, but should be used to keep fire-exposed containers cool. 6. Accidental Release Measures Eliminate all ignition sources. Soak up with absorbent material and remove to a chemical disposal area. Prevent entry into natural bodies of water. 7. Handling and Storage 7.1 Handling Page 260 of 1069 Page 260 of 1069 Page 260 of 1069 Page 260 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 4/9 Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). INHALATION: Avoid breathing vapor. Use with adequate ventilation. SKIN: Avoid contact with skin and clothing. EYES: Avoid contact with eyes. 7.2 Storage Store at room temperature. Store in a cool, well-ventilated area. Store in cool, dry area away from sun, heat, oxidizing materials and alkaline materials. Keep containers closed. Keep away from heat, sparks, flame and other ignition sources. 8. Exposure Controls/Personal Protection 8.1 Exposure Controls ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and remote control in combination with appropriate use of personal protective equipment and prudent work practices. These techniques may not necessarily address all issues pertaining to your operations. We, therefore, recommend that you consult with experts of your choice to determine whether or not your programs are adequate. If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria. 8.2 Personal Protection Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA approved respiratory protection equipment. Respirators should be selected based on the form and concentration of contaminants in air in accordance with OSHA laws and regulations or other applicable standards or guidelines, including ANSI standards regarding respiratory protection. Use goggles if contact is likely. Wear impervious gloves as required to prevent skin contact. Page 261 of 1069 Page 261 of 1069 Page 261 of 1069 Page 261 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 5/9 8.3 Exposure Guidelines D-Limonene 5989-27-5 ACGIH TLV: NONE ESTABLISHED OSHA PEL: NONE ESTABLISHED Hydrotreated Middle Distillate (petroleum) 64742-46-7 ACGIH TLV: 5 mg/m³ TWA Oil mist, mineral; 10 mg/m³ STEL OSHA PEL: 5 mg/m³ TWA Oil mist, mineral Alcohols, C12-15, Ethoxylated 68131-39-5 ACGIH TLV: NONE ESTABLISHED OSHA PEL: NONE ESTABLISHED 9. Physical and Chemical Properties Percent Volatiles >95 pH @ 25 C Not applicable Specific Gravity 0.85 Appearance Clear pale yellow liquid Autoignition Temperature Not available Boiling Point 175°C (initial) Vapor Density (Air=1) <1 Vapor Pressure, mm Hg @ 20 C Not available Evaporation Rate (Butyl Acetate=1) 1 Upper/Lower Flammable Limits Not available Up/Lower Explosive Limits, % by Vol 6.1/0.7 % Flash Point 46°C (114°F) Freezing Point Not applicable Melting point Not applicable Odor Citrus Solubility in Water Emulsifiable in water 10. Stability and Reactivity Normally stable as defined in NFPA 704-12(4-3.1). · Conditions to Avoid: Keep away from combustibles, ignition sources and oxidizers. · Incompatibilities: Strong oxidizers. Page 262 of 1069 Page 262 of 1069 Page 262 of 1069 Page 262 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 6/9 · Decomposition products may include: Oxides of carbon. · Hazardous polymerization: Will not occur. · Other Hazards: None known to company. 11. Toxicological Information See Section 3 Hazards Identification information. D-Limonene 5989-27-5 LC50: Not available LD50: Not available Hydrotreated Middle Distillate (petroleum) 64742-46-7 LC50: Not available LD50: Not available Alcohols, C12-15, Ethoxylated 68131-39-5 LC50: Not available LD50: Not available 12. Ecological Information Not determined. 13. Disposal Considerations Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal requirements. Empty container: May contain explosive vapors. DO NOT cut, puncture or weld on or nearby. 14. Transport Information Page 263 of 1069 Page 263 of 1069 Page 263 of 1069 Page 263 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 7/9 14.1 U.S. Department of Transportation (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Non-Regulated. 14.2 Canadian Transportation of Dangerous Goods (TDG) Non-Regulated. 15. Regulatory Information (Selected Regulations) 15.1 U.S. Federal Regulations · OSHA Hazard Communication Standard 29CFR1910.1200 This material is a "health hazard" and/or a "physical hazard" as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard. · SARA Title III: Section 311/312 Fire hazard Immediate health hazard Delayed health hazard · SARA Title III Section 313 and 40 CFR Part 372 This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. None required per SARA TITLE III SECTION 313. Page 264 of 1069 Page 264 of 1069 Page 264 of 1069 Page 264 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 8/9 · TSCA Section 8(b) Inventory All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us. 15.2 Canadian Regulations · Workplace Hazardous Materials Information System (WHMIS) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. CLASS D, DIV 2B CLASS B, DIV 3 · Canadian Environmental Protection Act (CEPA) All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. · National Pollutant Release Inventory (NPRI) This product contains the following chemical(s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required. 16. Other Information · User's Responsibility The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts Page 265 of 1069 Page 265 of 1069 Page 265 of 1069 Page 265 of 1069 ---PAGE BREAK--- 12/17/13 E-00171 ELMER'S STICKY OUT www.elmers.com/msds/me-00171.htm 9/9 to guard against hazards associated with use of this product and its ingredients. · Disclaimer SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. CURRENT ISSUE: 15-DEC-10 PREVIOUS ISSUE: 07-JAN-08 Page 266 of 1069 Page 266 of 1069 Page 266 of 1069 Page 266 of 1069 ---PAGE BREAK--- Page 1 of 4 SDS for: 507050 Printed: 5/25/2015 SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: ENDUST FREE Product Code: 507050 COMPANY NAME: NAKOMA PRODUCTS LLC ADDRESS : 8407 S. 77th Avenue Bridgeview, IL 60455 EMERGENCY PHONE : [PHONE REDACTED] INFORMATION PHONE : [PHONE REDACTED] Product Use: Dusting aid 2. HAZARDS IDENTIFICATION CLASSIFICATION Flammable aerosol 2 Gas under pressure Liquefied gas SIGNAL WORD: Warning Hazard Statements Flammable aerosol Contains gas under pressure; may explode if heated Precautionary Statements Keep away from heat/sparks/open flames/hot surfaces – No smoking Do not spray on an open flame or other ignition source Pressurized container – Do not pierce or burn, even after use IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Dispose of contents/container to comply with all local, state, and federal regulations 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Percent WATER 7732-18-5 56.70 PROCESSED PARAFINNIC FLUIDS 8042-47-5 19.40 ISOPARAFINNIC SOLVENT 64742-47-8 13.50 BUTANE 106-97-84 7.40 PROPANE 74-98-6 2.60 4. FIRST AID MEASURES INHALATION: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped. Get medical attention. Page 267 of 1069 Page 267 of 1069 Page 267 of 1069 Page 267 of 1069 ---PAGE BREAK--- Page 2 of 4 SDS for: 507050 Printed: 5/25/2015 EYE CONTACT: Wash immediately with large volumes of fresh water for at least 15 minutes. Get medical attention. SKIN CONTACT: Wipe off with a towel. Wash with soap and water. Get medical attention if irritation persists. INGESTION: Not a likely route of exposure. Most important acute and delayed: Repeated exposure may cause skin dryness or cracking. May cause drowsiness or dizziness. Indication of immediate medical attention and special treatment needed: None known. 5. FIRE FIGHTING MEASURES Suitable and unsuitable extinguishing media: Foam, Alcohol foam, CO2, Dry chemical, Water fog. Water spray may be ineffective. Specific hazards arising from the chemical: Closed containers may explode from internal pressure build-up when exposed to extreme heat and discharge contents. Liquid content of container will not support combustion. Overexposure to decomposition products may cause a health hazard. may not be readily apparent. Obtain medical attention. Hazardous decomposition products include carbon dioxide, carbon monoxide, and other toxic fumes. Special equipment and precautions for fire-fighters: Water may be used to cool containers to prevent pressure build-up and explosion when exposed to extreme heat. Wear goggles and use self-contained breathing apparatus. If water is used, fog nozzles are preferred. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Avoid breathing vapors. Ventilate area. Remove all sources of ignition. Methods and materials for containment and cleaning up: Clean up with absorbent material and place in closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling: Do not puncture or incinerate (burn) cans. Do not stick pins, nails, or any other sharp objects into opening on top of can. Do not spray in eyes. Do not take internally. See product label for additional information. Conditions for safe storage, including any incompatibilities: Store and use in cool, dry, well-ventilated areas. .Do not store above 120 F. 8. EXPOSURE CONTROL/PERSONAL PROTECTION Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits WATER 7732-18-5 Not established Not established PROCESSED PARAFINNIC FLUIDS 8042-47-5 PEL-TWA: Mist 5 mg/m3 TLV-TWA: Mist 5 mg/m3 ISOPARAFINNIC SOLVENT 64742-47-8 Not established Not established BUTANE 74-98-6 Not established TWA: 1000 ppm PROPANE 74-98-6 Not established TWA: 1000 ppm Page 268 of 1069 Page 268 of 1069 Page 268 of 1069 Page 268 of 1069 ---PAGE BREAK--- Page 3 of 4 SDS for: 507050 Printed: 5/25/2015 Appropriate engineering controls: Ventilation should be sufficient to prevent inhalation of any vapors. General dilution and/or local exhaust ventilation in volume to keep PEL/TLV of most hazardous ingredient below acceptable limit and lel below stated limit. Individual protection measures: Respiratory protection: None under normal use. Avoid breathing vapors. In restricted areas, use approved chemical/mechanical filters designed to remove a combination or particles and vapor. In confined areas, use an approved air line respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above PEL/TLV limits. Protective gloves: None under normal use. Use solvent-resistant for prolonged or repeated contact. Eye protection: None under normal use. However, use of safety glasses with splash guards or full face shield should be used if indicated. Other protective clothing or equipment: None under normal use. However, use of solvent- resistant aprons or other clothing is recommended. Eye washes and safety showers in the workplace are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Aerosol product Vapor Pressure: Not determined Vapor Density: Heavier than air Density: 0.876937333 Freezing point: Not determined Boiling point: N/A Evaporation rate: Slower than ether Explosive Limits: Not applicable Autoignition temperature: Not determined Viscosity: Not determined Odor: None Odor threshold: Not determined pH: Not applicable Melting point: Not determined Solubility: Not determined Flash point: Not determined Flammability: Level 1 Aerosol Partition coefficient Not determined octanol/water): Decomposition temperature: Not determined 10. STABILITY AND REACTIVITY Reactivity: Not reactive under normal conditions of use. Chemical stability: Stable under normal storage and handling conditions. Possibility of hazardous reactions: None known. Incompatible materials: No data Hazardous decomposition products: No data 11. TOXICOLOGICAL INFORMATION Long-term toxicological studies have not been conducted for this product. 12. ECOLOGICAL INFORMATION Long-term ecological studies have not been conducted for this product. Page 269 of 1069 Page 269 of 1069 Page 269 of 1069 Page 269 of 1069 ---PAGE BREAK--- Page 4 of 4 SDS for: 507050 Printed: 5/25/2015 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections of this document for hazard cautionary information. 14. TRANSPORT INFORMATION By land: DOT Proper Shipping Name: None required per 49 CFR 173 .306(i) for products that conform to the Limited Quantity provisions. Commodity shipping description: Cleaning compound, NOI By water: DOT & IMDG Proper Shipping Name: UN1950, Aerosols, 2 LTD QTY By air: DOT & IATA Proper Shipping Name: UN1950, Aerosols, flammable, 2 LTD QTY (packing instruction Y203 applies. 15. REGULATORY INFORMATION All ingredients are either listed on the TSCA inventory or are exempt 16. OTHER INFORMATION Date revised: 2015-05-11 Date Printed: 2015-05-25 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO RESPONSIBILITY FOR ITS USE. Revision 0 Page 270 of 1069 Page 270 of 1069 Page 270 of 1069 Page 270 of 1069 ---PAGE BREAK--- Page 1 of 4 SDS for: 508010 Printed: 5/25/2015 SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: ENDUST LEMON Product Code: 508010 COMPANY NAME: NAKOMA PRODUCTS LLC ADDRESS : 8407 S. 77th Avenue Bridgeview, IL 60455 EMERGENCY PHONE : [PHONE REDACTED] INFORMATION PHONE : [PHONE REDACTED] Product Use: Dusting aid 2. HAZARDS IDENTIFICATION CLASSIFICATION Flammable aerosol 2 Gas under pressure Liquefied gas SIGNAL WORD: Warning Hazard Statements Flammable aerosol Contains gas under pressure; may explode if heated Precautionary Statements Keep away from heat/sparks/open flames/hot surfaces – No smoking Do not spray on an open flame or other igntion source Pressurized container – Do not pierce or burn, even after use IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Dispose of contents/container to comply with all local, state, and federal regulations 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Percent WATER 7732-18-5 56.50 PROCESSED PARAFINNIC FLUIDS 8042-47-5 25.20 ISOPARAFINNIC SOLVENT 64742-47-8 7.90 PROPANE 74-98-6 7.00 ORANGE TERPENES 68647-72-3 1.50 4. FIRST AID MEASURES INHALATION: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped. Get medical attention. Page 271 of 1069 Page 271 of 1069 Page 271 of 1069 Page 271 of 1069 ---PAGE BREAK--- Page 2 of 4 SDS for: 508010 Printed: 5/25/2015 EYE CONTACT: Wash immediately with large volumes of fresh water for at least 15 minutes. Get medical attention. SKIN CONTACT: Wipe off with a towel. Wash with soap and water. Get medical attention if irritation persists. INGESTION: Not a likely route of exposure. Most important acute and delayed: Repeated exposure may cause skin dryness or cracking. May cause drowsiness or dizziness. Indication of immediate medical attention and special treatment needed: None known. 5. FIRE FIGHTING MEASURES Suitable and unsuitable extinguishing media: Foam, Alcohol foam, CO2, Dry chemical, Water fog. Water spray may be ineffective. Specific hazards arising from the chemical: Closed containers may explode from internal pressure build-up when exposed to extreme heat and discharge contents. Liquid content of container will not support combustion. Overexposure to decomposition products may cause a health hazard. may not be readily apparent. Obtain medical attention. Hazardous decomposition products include carbon dioxide, carbon monoxide, and other toxic fumes. Special equipment and precautions for fire-fighters: Water may be used to cool containers to prevent pressure build-up and explosion when exposed to extreme heat. Wear goggles and use self-contained breathing apparatus. If water is used, fog nozzles are preferred. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Avoid breathing vapors. Ventilate area. Remove all sources of ignition. Methods and materials for containment and cleaning up: Clean up with absorbent material and place in closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling: Do not puncture or incinerate (burn) cans. Do not stick pins, nails, or any other sharp objects into opening on top of can. Do not spray in eyes. Do not take internally. See product label for additional information. Conditions for safe storage, including any incompatibilities: Store and use in cool, dry, well-ventilated areas. .Do not store above 120 F. 8. EXPOSURE CONTROL/PERSONAL PROTECTION Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits WATER 7732-18-5 Not established Not established PROCESSED PARAFINNIC FLUIDS 8042-47-5 PEL-TWA: Mist 5 mg/m3 TLV-TWA: Mist 5 mg/m3 ISOPARAFINNIC SOLVENT 64742-47-8 Not established Not established PROPANE 74-98-6 Not established TWA: 1000 ppm ORANGE TERPENES 68647-72-3 Not established Not established AIHA Workplace TWA 30 ppm Page 272 of 1069 Page 272 of 1069 Page 272 of 1069 Page 272 of 1069 ---PAGE BREAK--- Page 3 of 4 SDS for: 508010 Printed: 5/25/2015 Appropriate engineering controls: Ventilation should be sufficient to prevent inhalation of any vapors. General dilution and/or local exhaust ventilation in volume to keep PEL/TLV of most hazardous ingredient below acceptable limit and lel below stated limit. Individual protection measures: Respiratory protection: None under normal use. Avoid breathing vapors. In restricted areas, use approved chemical/mechanical filters designed to remove a combination or particles and vapor. In confined areas, use an approved air line respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above PEL/TLV limits. Protective gloves: None under normal use. Use solvent-resistant for prolonged or repeated contact. Eye protection: None under normal use. However, use of safety glasses with splash guards or full face shield should be used if indicated. Other protective clothing or equipment: None under normal use. However, use of solvent- resistant aprons or other clothing is recommended. Eye washes and safety showers in the workplace are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Aerosol product Vapor Pressure: Not determined Vapor Density: Heavier than air Density: 0.876937333 Freezing point: Not determined Boiling point: N/A Evaporation rate: Slower than ether Explosive Limits: Not applicable Autoignition temperature: Not determined Viscosity: Not determined Odor: Lemon Odor threshold: Not determined pH: Not applicable Melting point: Not determined Solubility: Not determined Flash point: Not determined Flammability: Level 1 Aerosol Partition coefficient Not determined octanol/water): Decomposition temperature: Not determined 10. STABILITY AND REACTIVITY Reactivity: Not reactive under normal conditions of use. Chemical stability: Stable under normal storage and handling conditions. Possibility of hazardous reactions: None known. Incompatible materials: No data Hazardous decomposition products: No data 11. TOXICOLOGICAL INFORMATION Long-term toxicological studies have not been conducted for this product. 12. ECOLOGICAL INFORMATION Long-term ecological studies have not been conducted for this product. Page 273 of 1069 Page 273 of 1069 Page 273 of 1069 Page 273 of 1069 ---PAGE BREAK--- Page 4 of 4 SDS for: 508010 Printed: 5/25/2015 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections of this document for hazard cautionary information. 14. TRANSPORT INFORMATION By land: DOT Proper Shipping Name: None required per 49 CFR 173 .306(i) for products that conform to the Limited Quantity provisions. Commodity shipping description: Polishing compound, NOI By water: DOT & IMDG Proper Shipping Name: UN1950, Aerosols, 2 LTD QTY By air: DOT & IATA Proper Shipping Name: UN1950, Aerosols, flammable, 2 LTD QTY (packing instruction Y203 applies. 15. REGULATORY INFORMATION All ingredients are either listed on the TSCA inventory or are exempt 16. OTHER INFORMATION Date revised: 2015-05-11 Date Printed: 2015-05-25 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO RESPONSIBILITY FOR ITS USE. Revision 0 Page 274 of 1069 Page 274 of 1069 Page 274 of 1069 Page 274 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date No data available Revision Date 29-Jan-2013 Revision Number 1 The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved. 2. HAZARDS IDENTIFICATION Classification This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) GHS Label elements, including precautionary statements Emergency Overview 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Equate Petroleum Jelly Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Skin-care (non-aerosol) Uses advised against No information available Details of the supplier of the safety data sheet Supplier Name Vi-Jon Inc. Supplier Address 8515 Page Avenue Saint Louis MO 63114 US Supplier Phone Number Phone:18004249300 Fax:[PHONE REDACTED] Contact Phone3145921474 Supplier Email [EMAIL REDACTED] Emergency telephone number Page 1 / 9 Page 275 of 1069 Page 275 of 1069 Page 275 of 1069 Page 275 of 1069 ---PAGE BREAK--- 1085880_WM - Equate Petroleum Jelly Revision Date 29-Jan-2013 Precautionary Statements - Prevention Obtain special instructions before use Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity Other information May cause slight eye irritation PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION Interactions with Other Chemicals No information available. 4. FIRST AID MEASURES First aid measures Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If persist, call a physician. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. The product contains no substances which at their given concentration, are considered to be hazardous to health 3. COMPOSITION/INFORMATION ON INGREDIENTS The product contains no substances which at their given concentration, are considered to be hazardous to health. Chemical Name CAS No Weight-% Trade Secret Petrolatum (USP Grade) 8009-03-8 60 - 100 * BHT 128-37-0 < 0.1 * Appearance Opaque white Page 2 / 9 Physical State Solid Gel Consistency Solid Odor Petroleum Page 276 of 1069 Page 276 of 1069 Page 276 of 1069 Page 276 of 1069 ---PAGE BREAK--- 1085880_WM - Equate Petroleum Jelly Revision Date 29-Jan-2013 Inhalation Remove to fresh air. If persist, call a physician. Ingestion Do NOT induce vomiting. Drink plenty of water. If persist, call a physician. Most important and effects, both acute and delayed Most Important and Effects No information available. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical No information available. Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes. Environmental Precautions Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Page 3 / 9 Pick up and transfer to properly labeled containers. Page 277 of 1069 Page 277 of 1069 Page 277 of 1069 Page 277 of 1069 ---PAGE BREAK--- 1085880_WM - Equate Petroleum Jelly Revision Date 29-Jan-2013 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH BHT 128-37-0 TWA: 2 mg/m3 inhalable fraction and vapor (vacated) TWA: 10 mg/m3 TWA: 10 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Solid Gel Consistency Solid 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Conditions for safe storage, including any incompatibilities Storage Keep container closed. Incompatible Products None known based on information supplied. Appearance Opaque white Odor Petroleum Color No information available Page 4 / 9 Odor Threshold No information available Page 278 of 1069 Page 278 of 1069 Page 278 of 1069 Page 278 of 1069 ---PAGE BREAK--- 1085880_WM - Equate Petroleum Jelly Revision Date 29-Jan-2013 Explosive properties No data available Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Property Values Remarks Method pH No data available None known Melting / freezing point No data available None known Boiling point / boiling range No data available None known Flash Point No data available None known Evaporation Rate No data available None known Flammability (solid, gas) No data available None known Flammability Limit in Air Upper flammability limit No data available Lower flammability limit No data available Vapor pressure No data available None known Vapor density No data available None known Specific Gravity No data available None known Water Solubility Insoluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/waterNo data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous Decomposition Products Carbon oxides. Page 5 / 9 No data available. Page 279 of 1069 Page 279 of 1069 Page 279 of 1069 Page 279 of 1069 ---PAGE BREAK--- 1085880_WM - Equate Petroleum Jelly Revision Date 29-Jan-2013 Product Information Product does not present an acute toxicity hazard based on known or supplied information. . Inhalation Specific test data for the substance or mixture is not available. Eye Contact Specific test data for the substance or mixture is not available. Skin Contact Specific test data for the substance or mixture is not available. Ingestion Specific test data for the substance or mixture is not available. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Petrolatum (USP Grade) 8009-03-8 - - - BHT 128-37-0 = 890 mg/kg ( Rat ) - - Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity Contains no ingredient listed as a carcinogen. Chemical Name ACGIH IARC NTP OSHA BHT 128-37-0 Group 3 Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity No known effect based on information supplied. Target Organ Effects None known. Aspiration Hazard No information available. Numerical measures of toxicity Product Information Page 6 / 9 The following values are calculated based on chapter 3.1 of the GHS document Not applicable Page 280 of 1069 Page 280 of 1069 Page 280 of 1069 Page 280 of 1069 ---PAGE BREAK--- 1085880_WM - Equate Petroleum Jelly Revision Date 29-Jan-2013 14. TRANSPORT INFORMATION DOT NOT REGULATED Proper Shipping Name NON REGULATED Hazard Class N/A TDG Not regulated MEX Not regulated ICAO Not regulated IATA Not regulated 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) BHT 128-37-0 72h EC50: = 6 mg/L (Pseudokirchneriella subcapitata) 72h EC50: > 0.42 mg/L (Desmodesmus subspicatus) 48h LC50: = 5 mg/L (Oryzias latipes) EC50 = 7.82 mg/L 5 min EC50 = 8.57 mg/L 15 min EC50 = 8.98 mg/L 30 min Persistence and Degradability No information available. Bioaccumulation Chemical Name Log Pow BHT 128-37-0 4.17 Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Contaminated Packaging Dispose of contents/containers in accordance with local regulations. California Hazardous Waste Codes Page 7 / 9 331 Page 281 of 1069 Page 281 of 1069 Page 281 of 1069 Page 281 of 1069 ---PAGE BREAK--- 1085880_WM - Equate Petroleum Jelly Revision Date 29-Jan-2013 Proper Shipping Name NON REGULATED Hazard Class N/A IMDG/IMO Not regulated Hazard Class N/A RID Not regulated ADR Not regulated ADN Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL All components are listed either on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations . Chemical Name New Jersey Massachusetts Rhode Island Illinois BHT 128-37-0 X X X International Regulations Page 8 / 9 Page 282 of 1069 Page 282 of 1069 Page 282 of 1069 Page 282 of 1069 ---PAGE BREAK--- 1085880_WM - Equate Petroleum Jelly Revision Date 29-Jan-2013 Component Carcinogen Status Exposure Limits BHT 128-37-0 ( < 0.1 ) Mexico: TWA 10 mg/m3 Mexico: STEL 20 mg/m3 Canada WHMIS Hazard Class Non-controlled 16. OTHER INFORMATION Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Revision Date 29-Jan-2013 Revision Note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet NFPA Health Hazards 0 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazards 0 Flammability 0 Page 9 / 9 Physical Hazard 0 Personal Protection X Page 283 of 1069 Page 283 of 1069 Page 283 of 1069 Page 283 of 1069 ---PAGE BREAK--- Expo White Board Cleaner CHEMTREC (U.S. and Canada) 1-[PHONE REDACTED] SAFETY DATA SHEET Product name Emergency telephone number (with hours of operation) Section 1. Identification : : Manufacturer : Newell Rubbermaid 3500 Lacey Road, 10th Floor Downers Grove, IL 60515 USA [PHONE REDACTED] or [PHONE REDACTED] Material uses : Cleaning solutions. Section 2. Hazards identification Not classified. Classification of the substance or mixture : Signal word : Not applicable Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. GHS label elements General : Read label before use. If medical advice is needed, have product container or label at hand. OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients 3-butoxypropan-2-ol 2 - 5 5131-66-8 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Substance/mixture : Mixture Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 1/8 Page 284 of 1069 Page 284 of 1069 Page 284 of 1069 Page 284 of 1069 ---PAGE BREAK--- Expo White Board Cleaner Section 3. Composition/information on ingredients Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 2/8 Page 285 of 1069 Page 285 of 1069 Page 285 of 1069 Page 285 of 1069 ---PAGE BREAK--- Expo White Board Cleaner Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling None. Section 8. Exposure controls/personal protection Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Control parameters Individual protection measures Occupational exposure limits Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 3/8 Page 286 of 1069 Page 286 of 1069 Page 286 of 1069 Page 286 of 1069 ---PAGE BREAK--- Expo White Board Cleaner Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. Not available. Not available. Not available. Not available. Not available. Odor pH Clear. Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Not available. Not available. Not available. Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Burning rate Not applicable. : Burning time : Not applicable. SADT Not available. : Decomposition temperature : Not available. Solubility in water : Not available. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 4/8 Page 287 of 1069 Page 287 of 1069 Page 287 of 1069 Page 287 of 1069 ---PAGE BREAK--- Expo White Board Cleaner Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity 3-butoxypropan-2-ol LD50 Dermal Rabbit 3100 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Reproductive toxicity No known significant effects or critical hazards. Irritation/Corrosion No known significant effects or critical hazards. Sensitization No known significant effects or critical hazards. Information on the likely routes of exposure Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) No known significant effects or critical hazards. No known significant effects or critical hazards. Aspiration hazard No known significant effects or critical hazards. Information on toxicological effects : Not available. Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 5/8 Page 288 of 1069 Page 288 of 1069 Page 288 of 1069 Page 288 of 1069 ---PAGE BREAK--- Expo White Board Cleaner Section 11. Toxicological information No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Dermal 63798.6 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name 3-butoxypropan-2-ol 1.2 - low Toxicity No known significant effects or critical hazards. Persistence and degradability No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 6/8 Page 289 of 1069 Page 289 of 1069 Page 289 of 1069 Page 289 of 1069 ---PAGE BREAK--- Expo White Board Cleaner Section 14. Transport information - - - - - - - Not regulated. - - Not regulated. Not regulated. - - - DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user No. No. No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : TDG Classification Not regulated. - - - No. - Mexico Classification Not regulated. - - - No. - Section 15. Regulatory information U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted. SARA 311/312 Classification : Not applicable. 3-butoxypropan-2-ol 2 - 5 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients The following components are listed: Propylene glycol butyl ether Not controlled under WHMIS (Canada). None of the components are listed. Canada WHMIS (Canada) Canadian lists Canadian NPRI CEPA Toxic substances : : : Canada inventory : All components are listed or exempted. This product does not contain Chemicals known to State of California to cause cancer, birth defects, or reproductive harm. California Prop. 65 Section 16. Other information History Date of issue/Date of revision Version Prepared by Date of previous issue : : : : 8/5/2015 No previous validation 1 Product Safety. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 7/8 Page 290 of 1069 Page 290 of 1069 Page 290 of 1069 Page 290 of 1069 ---PAGE BREAK--- Expo White Board Cleaner Section 16. Other information Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof. Indicates information that has changed from previously issued version. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient UN = United Nations Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 8/8 Page 291 of 1069 Page 291 of 1069 Page 291 of 1069 Page 291 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MSDS # 81800 December 6, 2010 Page 1 of 3 Section One: Identification Sanford, L.P. 2707 Butterfield Road Oak Brook, IL 60523 USA [PHONE REDACTED] or [PHONE REDACTED] EMERGENCY MEDICAL NUMBER: [PHONE REDACTED] Product Name: Expo White Board Cleaner, Expo Original Cleaner Colors: Clear Sanford is a member of The Art and Creative Materials Institute, Inc. This product is certified by the Institute to be labeled in accordance with the voluntary chronic hazard labeling standard ASTM D-4236 and is labeled with the CL (Cautionary Label) Seal. Products bearing the CL Seal are certified to be properly labeled in a program of toxicological evaluation by a medical expert for any known health risks and with information on safe and proper use of these materials. Conforms to ASTM D-4236. Section Two: Hazard Identification WARNING: COMBUSTIBLE. VAPOR HARMFUL. MAY BE HARMFUL IF SWALLOWED, OR BY SKIN CONTACT. EYE IRRITANT. CONTAINS: 2-BUTOXYETHANOL, ISOPROPYL ALCOHOL. PRECAUTIONS: Avoid ingestion. Keep away from eyes. Do not store or use near heat or flame. Use only with adequate ventilation. KEEP OUT OF REACH OF CHILDREN. FIRST AID: If eye contact occurs, rinse with tap water for 5-10 minutes. If irritation persists, seek medical care. If skin contact occurs, wash with soap and water for 5 minutes. If swallowed, get prompt medical attention. For further health information, contact a poison control center or call [PHONE REDACTED]. Section Three: Composition Water, 2-Butoxyethanol (111-76-2), isopropyl alcohol (67-63-0) Section Four: First Aid Measures Inhalation: If occur, move to fresh air. Skin Contact: If skin contact occurs, wash with soap and water for 5 minutes. Eye Contact: If eye contact occurs, rinse with tap water for 5-10 minutes. If irritation persists, seek medical care. Ingestion: If swallowed, get prompt medical attention. Section Five: Fire Fighting Measures Flash Point: 105F (TCC) Flammability Limits by volume): Lower: 2.2% (isopropyl alcohol) Upper: Not available Extinguishing Media: As appropriate for surrounding area. Special Fire Fighting Measures: None Unusual Fire and Explosion Hazards: None Section Six: Accidental Release Measures In Case of Spill or Accidental Release: Wipe up with absorbent material. Section Seven: Handling and Storage Handling: Use in a well-ventilated area. Aim nozzle away from eyes. Storage: Do not store or use near heat or flame. Section Eight: Exposure Controls and Personal Protection Eye Protection: None under normal use conditions. Avoid prolonged eye contact. Clothing: None under normal use conditions. Respirator: None under normal use conditions. Ventilation: None under normal use conditions. Use in a well ventilated area. Page 292 of 1069 Page 292 of 1069 Page 292 of 1069 Page 292 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MSDS # 81800 December 6, 2010 Page 2 of 3 Section Nine: Physical and Chemical Properties For product unless otherwise specified: Boiling Point: 180F (isopropyl alcohol) Specific Gravity: 0.96 Vapor Pressure: 33 mg Hg (isopropyl alcohol) Solubility in Water: complete Evaporation Rate: Not available Appearance/Odor: Clear liquid; alcoholic odor Section Ten: Stability and Reactivity Stability: Stable Conditions to Avoid: None known Chemical Incompatibility: Strong oxidizers, acids, isocyanates Hazardous Decomposition: None known Hazardous Polymerization: Will not occur. Section Eleven: Toxicological Information See Section Two: Hazard Identification for any hazards Section Twelve: Ecological Information Not available Section Thirteen: Disposal Considerations Dispose in accordance with Federal, State, and Local Regulations. Section Fourteen: Transport Information DOT: ORM-D Consumer Commodity IATA: Consumer Commodity, 9, ID8000, packing instruction 910 IMO: Flammable Liquid, n.o.s. (isopropanol), 3, UN1993, PGIII (105F TCC), Ltd. Qtys, EmS#3-07 Section Fifteen: Regulatory Information TSCA: The product listed on this Material Safety Data Sheet is not listed on the Toxic Substances Control Act Inventory. All ingredients used to manufacture this product are listed on the TSCA Inventory Section Sixteen: Other Information HMIS Code Health 2 Flammability 2 Reactivity 0 Personal Protection H 0=Minimal / 4 = Severe Sanford has been advised by Counsel that the OSHA Hazard Communication Standard does not apply to the Sanford Product described in this Material Safety Data Sheet. The reason for the exemption is contained in 29 CFR 1910.1200(b)(6)(ix) as amended July 1, 2006 per the Code of Federal Regulations. The information contained in this MSDS is forwarded to you for your information, but is not meant to imply that the product is covered by the Hazard Communication Standard nor is this MSDS meant to comply with all requirements of the Hazard Communication Standard. Page 293 of 1069 Page 293 of 1069 Page 293 of 1069 Page 293 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 1 / 9 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER Product code : 200000038598 : B02703630000 Manufacturer or supplier's details Company : Colgate-Palmolive Co 300 Park Avenue New York, NY 10022 Telephone : US: Consumer Affairs - 1-[PHONE REDACTED] Emergency telephone number : For emergencies involving spill, leak, fire, exposure or acci- dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887. Medical Emergency (24HR): For MEDICAL EMERGENCIES involving this product call: (888) 489-3861 Recommended use of the chemical and restrictions on use Recommended use : Formulated all purpose cleaner for household use. SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance liquid Colour purple GHS Classification Skin irritation : Category 2 Eye irritation : Category 2A Skin sensitisation : Category 1 GHS Label element Hazard pictograms : Signal word : Warning Page 294 of 1069 Page 294 of 1069 Page 294 of 1069 Page 294 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 2 / 9 Hazard statements : H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P362 Take off contaminated clothing and wash before reuse. Disposal: P501 Dispose of contents/ container to an approved waste dis- posal plant. Potential Health Effects Inhalation : No adverse effects due to inhalation are expected. Skin : May cause skin irritation upon prolonged contact. Eyes : Causes eye irritation on direct contact. Ingestion : May be harmful if swallowed in large quantities. Aggravated Medical Condi- tion : None known. Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen Page 295 of 1069 Page 295 of 1069 Page 295 of 1069 Page 295 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 3 / 9 by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration (C10-C16) acid 68584-22-5 1 - < 5 SECTION 4. FIRST AID MEASURES If inhaled : Remove victim to fresh air. Get medical attention, if symp- toms persist. In case of skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention. In case of eye contact : Flush eyes with water at least 15 minutes. Get medical atten- tion if eye irritation develops or persists. If swallowed : Drink 8 ounces of clear water. Get medical attention. Most important and effects, both acute and delayed : Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car- bon dioxide. Hazardous combustion prod- ucts : No hazardous combustion products are known Special protective equipment for firefighters : Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protection recommended in Section 8 of the SDS. Methods and materials for containment and cleaning up : Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa- ter. SECTION 7. HANDLING AND STORAGE Page 296 of 1069 Page 296 of 1069 Page 296 of 1069 Page 296 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 4 / 9 Conditions for safe storage : Store at controlled room temperature at 20-25°C (68-77°F). SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : In an industrial work environment, no special precautions or control measures are required. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally re- quired. Protective measures : In an industrial work environment, if a splash is likely, chemi- cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary. Hygiene measures : In an industrial work environment, avoid eye and prolonged skin contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : purple pH : 7 Flash point : No data available SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reac- tions : Hazardous polymerisation does not occur. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : None known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Page 297 of 1069 Page 297 of 1069 Page 297 of 1069 Page 297 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 5 / 9 Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate : > 10 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Components: (C10-C16) acid: Acute oral toxicity : LD50 (Rat): 1,460 mg/kg Method: No information available. Acute inhalation toxicity : LC50 (Rabbit): > 1.9 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Method: OECD Test Guideline 402 Skin corrosion/irritation Causes skin irritation. Components: (C10-C16) acid: Result: Corrosive after 1 to 4 hours of exposure Serious eye damage/eye irritation Causes serious eye irritation. Components: (C10-C16) acid: Result: Irreversible effects on the eye Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: Not classified based on available information. Components: (C10-C16) acid: Exposure routes: Inhalation Remarks: No data available Exposure routes: Dermal Result: May cause sensitisation by skin contact. Germ cell mutagenicity Not classified based on available information. Page 298 of 1069 Page 298 of 1069 Page 298 of 1069 Page 298 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 6 / 9 Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS. SECTION 12. ECOLOGICAL INFORMATION The product has not been tested as a whole for environmental toxicity. However, environmental infor- mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua- tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients surfactants are biode- gradable) or testing conducted on the final product This product is biodegradable). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state envi- ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground. SECTION 14. TRANSPORT INFORMATION DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. Page 299 of 1069 Page 299 of 1069 Page 299 of 1069 Page 299 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 7 / 9 IMDG : Not regulated. International Regulation Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sulfuric Acid 7664-93-9 1000 * Sulfuric Acid 7664-93-9 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sulfuric Acid 7664-93-9 1000 * Calculated RQ exceeds reasonably attainable upper limit. SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: SODIUM HYDROXIDE 1310-73-2 Sulfuric Acid SULFURIC ACID The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM HYDROXIDE 1310-73-2 Page 300 of 1069 Page 300 of 1069 Page 300 of 1069 Page 300 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 8 / 9 Sulfuric Acid SULFURIC ACID This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know Sulfuric Acid SULFURIC ACID Right To Know WATER Water 2-PHENOXYETHANOL 122-99-6 SODIUM HYDROXIDE 1310-73-2 Sulfuric Acid SULFURIC ACID New Jersey Right To Know WATER Water PROPYLENE GLYCOL PROPYL ETHER 1569-01-3 (C10-C16) acid 68584-22-5 California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. The components of this product are reported in the following inventories: TSCA : All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) Page 301 of 1069 Page 301 of 1069 Page 301 of 1069 Page 301 of 1069 ---PAGE BREAK--- NA FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015 9 / 9 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im- plied, as to the accuracy, reliability or completeness of the information and assumes no re- sponsibility for injury, damage or loss resulting from the use of the material. Flammability Health Instability 1 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 302 of 1069 Page 302 of 1069 Page 302 of 1069 Page 302 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date: 24-Feb-2015 Revision Date: 24-Feb-2015 Version 1 1. IDENTIFICATION Product Name Febreze Air Effects - Sun Baked Product ID: 92351338_RET_NG Product Type: Finished Product - Consumer (Retail) Use Only Recommended Use Air freshener Restrictions on Use Safe to use around dogs and cats. As with other care products, not for use around birds. Synonyms Febreze Air Effects - Summer Fruit Bouquet (92351338_A_RET_NG) Febreze Air Effects - Seaside Spring & Escape (92351338_B_RET_NG) Febreze Air Effects - Wintry Mint (96892319_RET_NG) Febreze Air Effects - Pumpkin Bliss (92350451_RET_NG) Febreze Air Effects - Pumpkin Harvest 92350451_A_RET_NG) Febreze Air Effects - Vanilla Latte (92350912_RET_NG) Febreze Air Effects - Pumpkin Harvest (92350912_A_RET_NG) Febreze Air Effects - Fluffy Vanilla (92350912_B_RET_NG) Febreze Air Effects - Cozy Vanilla Sugar (92350912_C_RET_NG) Febreze Air Effects - Morning Herbs & Mist (92351003_RET_NG) Febreze Air Effects - Turquoise Sea & Shimmer (92351003_A_RET_NG) Febreze Air Effects - New Zealand Springs (92351003_B_RET_NG) Manufacturer PROCTER & GAMBLE - Fabric and Home Care Division. Ivorydale Technical Centre. 5289 Spring Grove Avenue, Cincinnati, Ohio 45217-1087 USA E-mail Address Emergency Telephone Transportation (24 HR) CHEMTREC - 1-[PHONE REDACTED] Canada) or 1-[PHONE REDACTED] Mexico toll free in country: [PHONE REDACTED] 2. HAZARD IDENTIFICATION "Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product. This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Not Classified. Hazard Statements None Hazard pictograms None Page 1 / 7 Page 303 of 1069 Page 303 of 1069 Page 303 of 1069 Page 303 of 1069 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists. Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if occur. Inhalation Move to fresh air. If persist, call a physician. Most important acute and delayed None under normal use conditions. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Dry chemical. Alcohol-resistant foam. Unsuitable Extinguishing Media None. Special hazard None known. Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical None. Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) None Chemical Name Synonyms Trade Secret CAS-No Weight % Ethanol Page 2 / 7 - No 64-17-5 1 - 5 Page 304 of 1069 Page 304 of 1069 Page 304 of 1069 Page 304 of 1069 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Advice for emergency responders Use personal protective equipment as required. Environmental precautions Keep out of waterways. Do not discharge product into natural waters without pre-treatment or adequate dilution. Methods and materials for containment and cleaning up Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known. Aerosol Classification Level 1 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL Ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 Mexico: TWA 1000 ppm Mexico: TWA 1900 mg/m3 Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Ethanol 64-17-5 TWA: 1000 ppm TWA: 1880 mg/m3 TWA: 1000 ppm TWA: 1880 mg/m3 STEL: 1000 ppm STEL: 1000 ppm No relevant exposure guidelines for other ingredients Page 3 / 7 Exposure controls Engineering Measures Distribution, Workplace and Household Settings: Ensure adequate ventilation Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction Page 305 of 1069 Page 305 of 1069 Page 305 of 1069 Page 305 of 1069 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 Personal Protective Equipment Eye Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection Hand Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves Skin and Body Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Wear suitable protective clothing Respiratory Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20°C Aerosol Appearance clear Odor Scented Odor threshold No information available VOC Content Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Property Values Note pH value 4.7 - 5.3 Melting/freezing point No information available Boiling point/boiling range No information available Flash point 51.6 - 60 °C / 125 - 140 °F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air Upper flammability limit No information available Lower Flammability Limit No information available Vapor pressure No information available Vapor density No information available Relative density 0.987 - 1.0 Water solubility No information available Solubility in other solvents No information available Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available . Decomposition temperature No information available . Viscosity of Product No information available Page 4 / 7 Page 306 of 1069 Page 306 of 1069 Page 306 of 1069 Page 306 of 1069 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 Reactivity None under normal use conditions. Stability Stable under normal conditions. Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. Conditions to Avoid None under normal processing. Materials to avoid None in particular. Hazardous Decomposition Products None under normal use. 11. TOXICOLOGICAL INFORMATION Product Information Information on likely routes of exposure Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact No known effect. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation No known effect. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect. Component Information Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation Ethanol 64-17-5 10470 mg/kg bw (OECD 401) > 15800 mg/kg bw (Rabbit) 116.9 mg/L air (//OECD 403) 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility No information available. Page 5 / 7 Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Page 307 of 1069 Page 307 of 1069 Page 307 of 1069 Page 307 of 1069 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 Waste treatment Waste from Residues / Unused Products Aerosol cans, when disposed as waste, are regulated as D003 reactive hazardous waste in some States because of their potential to explode when heated. Check with your State environmental agency for guidance. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Codes (non-household setting) 331 14. TRANSPORT INFORMATION DOT UN no UN1950 UN Proper shipping name Aerosols Description UN1950, Aerosols, 2.2 , Ltd. Qty. Hazard Class 2.2 Emergency Response Guide Number 126 IMDG UN Number UN1950 UN Proper shipping name Aerosols Description UN1950, Aerosols, 2.2 , Ltd. Qty. Transport hazard class(es) 2.2 EmS-No F-D, S-U IATA UN no UN1950 UN Proper shipping name Aerosols, non-flammable Description UN1950, Aerosols, non-flammable, 2.2 , Ltd. Qty. Hazard Class 2.2 ERG Code 2L IATA comment Can also be shipped as ID8000 Consumer Commodity 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. Page 6 / 7 Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Page 308 of 1069 Page 308 of 1069 Page 308 of 1069 Page 308 of 1069 ---PAGE BREAK--- 92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015 California Proposition 65 This product is not subject to warning labeling under California Proposition 65. Ethanol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage. U.S. State Regulations (RTK) Chemical Name CAS-No New Jersey Ethanol 64-17-5 X Chemical Name CAS-No Massachusetts Ethanol 64-17-5 X Chemical Name CAS-No Ethanol 64-17-5 X Dipropylene Glycol 25265-71-8 X International Inventories United States All intentionally-added components of this product(s) are listed on the US TSCA Inventory. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act 16. OTHER INFORMATION Issuing Date: 24-Feb-2015 Revision Date: 24-Feb-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text Page 7 / 7 End of SDS Page 309 of 1069 Page 309 of 1069 Page 309 of 1069 Page 309 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date: 16-Mar-2015 Revision Date: 16-Mar-2015 Version 1 1. IDENTIFICATION Product Name Febreze Fabric Refresher - Antimicrobial Product ID: 15158068_RET_NG Product Type: Finished Product - Consumer (Retail) Use Only Recommended Use Fabric Refresher Restrictions on Use Safe to use around dogs and cats. As with other care products, not for use around birds. Manufacturer PROCTER & GAMBLE - Fabric and Home Care Division. Ivorydale Technical Centre. 5289 Spring Grove Avenue, Cincinnati, Ohio 45217-1087 USA E-mail Address Emergency Telephone Transportation (24 HR) CHEMTREC - 1-[PHONE REDACTED] Canada) or 1-[PHONE REDACTED] Mexico toll free in country: [PHONE REDACTED] 2. HAZARD IDENTIFICATION "Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product. This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Not Classified. Hazard Statements None Hazard pictograms None Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Page 1 / 7 Precautionary Statements - Disposal None Page 310 of 1069 Page 310 of 1069 Page 310 of 1069 Page 310 of 1069 ---PAGE BREAK--- 15158068_RET_NG - Febreze Fabric Refresher - Antimicrobial Revision Date: 16-Mar-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists. Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if occur. Inhalation Move to fresh air. If persist, call a physician. Most important acute and delayed None under normal use conditions. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Dry chemical. Alcohol-resistant foam. Unsuitable Extinguishing Media None. Special hazard None known. Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical None. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Advice for emergency responders Use personal protective equipment as required. Environmental precautions Keep out of waterways. Do not discharge product into natural waters without pre-treatment or adequate dilution. Methods and materials for containment and cleaning up Hazards not otherwise classified (HNOC) None Chemical Name Synonyms Trade Secret CAS-No Weight % Ethanol Page 2 / 7 - No 64-17-5 1 - 5 Page 311 of 1069 Page 311 of 1069 Page 311 of 1069 Page 311 of 1069 ---PAGE BREAK--- 15158068_RET_NG - Febreze Fabric Refresher - Antimicrobial Revision Date: 16-Mar-2015 Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL Ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 Mexico: TWA 1000 ppm Mexico: TWA 1900 mg/m3 Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Ethanol 64-17-5 TWA: 1000 ppm TWA: 1880 mg/m3 TWA: 1000 ppm TWA: 1880 mg/m3 STEL: 1000 ppm STEL: 1000 ppm No relevant exposure guidelines for other ingredients Exposure controls Engineering Measures Distribution, Workplace and Household Settings: Ensure adequate ventilation Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction Personal Protective Equipment Eye Protection Page 3 / 7 Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection Hand Protection Distribution, Workplace and Household Settings: No special protective equipment required Page 312 of 1069 Page 312 of 1069 Page 312 of 1069 Page 312 of 1069 ---PAGE BREAK--- 15158068_RET_NG - Febreze Fabric Refresher - Antimicrobial Revision Date: 16-Mar-2015 Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves Skin and Body Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Wear suitable protective clothing Respiratory Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20°C liquid Appearance clear Odor Perfume Odor threshold No information available VOC Content Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity None under normal use conditions. Stability Stable under normal conditions. Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. Conditions to Avoid None under normal processing. Materials to avoid None in particular. Hazardous Decomposition Products None under normal use. Property Values Note pH value 6.0 - 8.0 Melting/freezing point No information available Boiling point/boiling range 100 °C / 212 °F Flash point 57.8 - 70.5 °C / 136 - 159 °F Product is an aqueous solution containing 24% alcohol and> 50% water Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air Upper flammability limit No information available Lower Flammability Limit No information available Vapor pressure No information available Vapor density No information available Relative density 1.0 Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available . Decomposition temperature No information available . Viscosity of Product No information available Page 4 / 7 Page 313 of 1069 Page 313 of 1069 Page 313 of 1069 Page 313 of 1069 ---PAGE BREAK--- 15158068_RET_NG - Febreze Fabric Refresher - Antimicrobial Revision Date: 16-Mar-2015 11. TOXICOLOGICAL INFORMATION Product Information Information on likely routes of exposure Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact No known effect. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation No known effect. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment Waste from Residues / Unused Products Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Codes (non-household setting) 331 14. TRANSPORT INFORMATION Page 5 / 7 DOT Not regulated Page 314 of 1069 Page 314 of 1069 Page 314 of 1069 Page 314 of 1069 ---PAGE BREAK--- 15158068_RET_NG - Febreze Fabric Refresher - Antimicrobial Revision Date: 16-Mar-2015 IMDG Not regulated IATA Not regulated 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) Chemical Name CAS-No New Jersey Ethanol 64-17-5 X Chemical Name CAS-No Massachusetts Ethanol 64-17-5 X Chemical Name CAS-No Ethanol 64-17-5 X 2,2'-Oxybisethanol 111-46-6 X International Inventories United States All intentionally-added components of this product(s) are listed on the US TSCA Inventory. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act Page 6 / 7 16. OTHER INFORMATION Page 315 of 1069 Page 315 of 1069 Page 315 of 1069 Page 315 of 1069 ---PAGE BREAK--- 15158068_RET_NG - Febreze Fabric Refresher - Antimicrobial Revision Date: 16-Mar-2015 Issuing Date: 16-Mar-2015 Revision Date: 16-Mar-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text Page 7 / 7 End of SDS Page 316 of 1069 Page 316 of 1069 Page 316 of 1069 Page 316 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Date New Revision Number 0 Page 1 / 10 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Formula 409® Carpet Spot & Stain Remover (aerosol) Other means of identification Synonyms None. Recommended use of the chemical and restrictions on use Recommended Use Aerosol carpet cleaner Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address The Clorox Company 1221 Broadway Oakland, CA 94612 Phone: 1-[PHONE REDACTED] Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] Page 317 of 1069 Page 317 of 1069 Page 317 of 1069 Page 317 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 2 / 10 2. HAZARDS IDENTIFICATION Classification This mixture is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Reproductive toxicity Category 1B Gases under pressure Compressed gas GHS Label elements, including precautionary statements Emergency Overview Signal word Danger Hazard statements May cause genetic effects May cause cancer May damage fertility or the unborn child Contains gas under pressure; may explode if heated Appearance Clear, colorless Physical State Thin liquid Odor Lavender, floral, citrus Precautionary Statements - Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear eye protection such as safety glasses. Precautionary Statements - Response If exposed or concerned: Get medical attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention. Precautionary Statements - Storage Store locked up. Precautionary Statements - Disposal Dispose of contents/container in accordance with all applicable federal, state, and local regulations. Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0.7% of the mixture consists of ingredient(s) of unknown toxicity Other information Harmful to aquatic life. Interactions with Other Chemicals None known. Page 318 of 1069 Page 318 of 1069 Page 318 of 1069 Page 318 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 3 / 10 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Trade Secret Isopropyl alcohol 67-63-0 1 - 5 * Isobutane 75-28-5 1 - 5 * Sodium lauryl sulfate 151-21-3 0.5 - 2 * Sodium tetraborate pentahydrate 12179-04-3 0.1 - 1 * Sodium nitrite 7632-00-0 0.1 - 1 * * The exact percentage (concentration) of composition has been withheld as a trade secret 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin Contact Wash skin with soap and water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing is affected, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Most important and effects, both acute and delayed Most Important May cause slight eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Dry chemical, carbon dioxide (CO2), foam, or water spray. Unsuitable Extinguishing Media Do not extinguish a leaking gas fire unless leak can be stopped. Specific Hazards Arising from the Chemical Containers may rupture at temperatures greater than 49C. NFPA Aerosol Classification: Level 1 CPSC Aerosol Classification: Not flammable. Explosion Data Sensitivity to Mechanical Impact None Sensitivity to Static Discharge None Protective Equipment and Precautions for Firefighters Containers may rupture at temperatures greater than 49C. Cool exposed containers to avoid potential bursting or venting. Use equipment or shielding to protect personnel from bursting containers. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 319 of 1069 Page 319 of 1069 Page 319 of 1069 Page 319 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 4 / 10 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes, skin, and clothing. Other Information Ventilate area. Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions Prevent entry into waterways, sewers, basements, and confined areas. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Keep out of drains, sewers, ditches, and waterways. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. Avoid breathing vapors. Contents under pressure. Do not puncture or incinerate containers. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Store in accordance with NFPA 30B for Level 1 aerosols. Do not store at temperatures above 49C. Keep containers in a dry, cool, and well-ventilated place. Protect from sunlight. Incompatible Products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Isopropyl alcohol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m 3 IDLH: 2000 ppm 10% LEL TWA: 980 mg/m 3 TWA: 400 ppm STEL: 500 ppm STEL: 1225 mg/m 3 Isobutane 75-28-5 STEL: 1000 ppm None TWA: 800 ppm TWA: 1900 mg/m 3 Sodium lauryl sulfate 151-21-3 None None None Sodium tetraborate pentahydrate 12179-04-3 STEL - 6 mg/m 3 (inhalable fraction) a STEL - 2 mg/m 3 (inhalable fraction) a aListed under borate compounds, inorganic None TWA - 1 mg/m 3 Sodium nitrite 7632-00-0 None None None ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Page 320 of 1069 Page 320 of 1069 Page 320 of 1069 Page 320 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 5 / 10 Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Wear safety glasses. None required for consumer use. Skin and Body Protection Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Do not eat, drink, or smoke when using this product. Wash hands with soap and water after use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid Appearance Clear Odor Lavender, floral, citrus Color Colorless Odor Threshold No information available Property Values Remarks/ Method pH 9 - 10 (liquid) None known Melting/freezing point No data available None known Boiling Point/Range No data available None known Flash Point No data available None known Flame extension None Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.03 (liquid) None known Water Solubility Soluble in water. None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties No data available Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available Page 321 of 1069 Page 321 of 1069 Page 321 of 1069 Page 321 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 6 / 10 10. STABILITY AND REACTIVITY Reactivity None known. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Do not store at temperatures above 49C. Incompatible materials None known. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Exposure to vapor or mist may irritate respiratory tract. Eye Contact May cause slight eye irritation. Skin Contact Prolonged contact may cause slight irritation. Ingestion Ingestion may cause slight irritation to mucous membranes and gastrointestinal irritation, nausea, vomiting, and diarrhea. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Isopropyl alcohol 67-63-0 1.87 g/kg (Rat) 4.06 g/kg (Rat) 72.6 g/m 3 (Rat) 4 h Isobutane 75-28-5 - - 658 mg/L (Rat) 4 h Sodium tetraborate pentahydrate 12179-04-3 2.4 g/kg (Rat) >2 g/kg (Rabbit) - Sodium nitrite 7632-00-0 85 mg/kg (Rat) - 5.5 mg/L (Rat) 4 h Information on toxicological effects May cause redness and tearing of the eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Page 322 of 1069 Page 322 of 1069 Page 322 of 1069 Page 322 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 7 / 10 Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Isopropyl alcohol 67-63-0 Group 3 Sodium nitrite 7632-00-0 Group 2A X ACGIH (American Conference of Governmental Industrial Hygienists) IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans NTP (National Toxicology Program) OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive Toxicity Contains a known or suspected reproductive toxin (sodium tetraborate pentahydrate). STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Contains a known or suspected mutagen. Contains a known or suspected carcinogen. Sodium nitrite produced stomach tumors in female mice when fed exaggerated doses. Contains a known or suspected reproductive toxin. Possible risk of irreversible effects. Target Organ Effects Respiratory system, eyes, skin, reproductive system, gastrointestinal tract, central nervous system, blood, heart, liver, spleen, kidney, stomach, systemic toxicity cardiovascular system. May affect the genetic material in germ cells (sperm and eggs). Aspiration Hazard No information available. Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 54 g/kg ATEmix (dermal) 35.4 g/kg ATEmix (inhalation-gas) 9,886,000 ATEmix (inhalation-vapor) 1850 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Persistence and Degradability No information available. Bioaccumulation Chemical Name Log Pow Sodium nitrite 7632-00-0 -3.7 Other Adverse Effects No information available. Page 323 of 1069 Page 323 of 1069 Page 323 of 1069 Page 323 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 8 / 10 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Limited quantity. TDG UN-No UN1950 Proper Shipping Name AEROSOLS Hazard Class 2.2 Description UN1950, AEROSOLS, 2.2 ICAO UN-No UN1950 Proper Shipping Name AEROSOLS Hazard Class 2.2 Description UN1950, AEROSOLS, 2.2 IATA UN-No UN1950 Proper Shipping Name AEROSOLS, NON-FLAMMABLE Hazard Class 2.2 Description UN1950, AEROSOLS, NON-FLAMMABLE, 2.2 IMDG/IMO UN-No UN1950 Proper Shipping Name AEROSOLS Hazard Class 2.2 EMs No. F-D, S-U Description UN1950, AEROSOLS, 2.2 Page 324 of 1069 Page 324 of 1069 Page 324 of 1069 Page 324 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 9 / 10 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains the following chemical that is subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Chemical Name CAS-No Weight % SARA 313 Threshold Values % Sodium nitrite 7632-00-0 7632-00-0 0.1 - 1 1.0 SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard Yes Reactive Hazard No Clean Water Act This product contains the following substance that is regulated as a pollutant pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium nitrite 7632-00-0 100 lb. X CERCLA This material, as supplied, contain the following substance regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Sodium nitrite 7632-00-0 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ Page 325 of 1069 Page 325 of 1069 Page 325 of 1069 Page 325 of 1069 ---PAGE BREAK--- Formula 409® Carpet Spot & Stain Remover (aerosol) Revision Date New Page 10 / 10 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Isopropyl alcohol 67-63-0 X X X Isobutane 75-28-5 X X X Propane 74-98-6 X X X Sodium nitrite 7632-00-0 X X X X International Regulations Canada WHMIS Hazard Class D2A Very toxic Materials A Compressed gases 16. OTHER INFORMATION NFPA Health Hazard 0 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 0* Flammability 0 Physical Hazard 0 Personal Protection - *Indicates a chronic health hazard Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Preparation/Revision Date January 5, 2015 Revision Date New Revision Note Reference New 1050720/50787001.001 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 326 of 1069 Page 326 of 1069 Page 326 of 1069 Page 326 of 1069 ---PAGE BREAK--- Page 327 of 1069 Page 327 of 1069 Page 327 of 1069 Page 327 of 1069 ---PAGE BREAK--- Page 328 of 1069 Page 328 of 1069 Page 328 of 1069 Page 328 of 1069 ---PAGE BREAK--- Page 329 of 1069 Page 329 of 1069 Page 329 of 1069 Page 329 of 1069 ---PAGE BREAK--- Page 330 of 1069 Page 330 of 1069 Page 330 of 1069 Page 330 of 1069 ---PAGE BREAK--- Page 331 of 1069 Page 331 of 1069 Page 331 of 1069 Page 331 of 1069 ---PAGE BREAK--- Page 332 of 1069 Page 332 of 1069 Page 332 of 1069 Page 332 of 1069 ---PAGE BREAK--- Page 333 of 1069 Page 333 of 1069 Page 333 of 1069 Page 333 of 1069 ---PAGE BREAK--- Page 334 of 1069 Page 334 of 1069 Page 334 of 1069 Page 334 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 22-Jul-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83571 Product name Full Blast Recommended Use Cleaner Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Ingestion. Inhalation. Skin absorption. Skin contact. Potential health effects Eyes May cause the following effects:. Irritation. Frostbite. Burn. Skin Substance may cause slight skin irritation. dermatitis. Extreme overexposure may cause. Skin burns. Frostbite. Red blood cell hemolysis. Inhalation Shortness of breath. Dizziness. Light headedness. Headaches. Nausea. Extreme overexposure may cause. Upper respiratory tract irritation. Possible Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion Extreme overexposure may cause. Nausea. Diarrhea. Vomiting. Can burn mouth, throat, and stomach. May cause chemical pneumonitis if aspirated into lungs. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Butane 106-97-8 1-5 2-Butoxyethanol 111-76-2 1-5 Propane 74-98-6 1-5 Trisodium Phosphate 7601-54-9 1-5 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 20 minutes. Seek medical attention. Skin contact Wash area thoroughly with soap and water. Ingestion If a large quantity of liquid is swallowed, do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician immediately. Inhalation Remove to fresh air. Provide oxygen if breathing is difficult. If not breathing, give artificial respiration. Keep warm and quiet. Seek medical attention. 5. FIRE FIGHTING MEASURES Flash point °C No data available Flash point °F No data available Method Not Applicable Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5% Lower 1.8% Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Flammable . Material is highly volatile and readily gives off vapors. Vapors may form explosive mixture in air between upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Page 1 / 3 (Bad file name or number) Emergency Overview Extremely flammable. Irritant. May be harmful if inhaled. May be harmful if swallowed. Contents under pressure. Page 335 of 1069 Page 335 of 1069 Page 335 of 1069 Page 335 of 1069 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Evacuate area of unprotected and unnecessary personnel. Ventilate area to maintain exposure below permissible exposure limits. Shut off source of leak if safe to do so. Dike or dam large spills. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. 7. HANDLING AND STORAGE Handling Keep container closed when not in use. Storage Keep container closed. Keep away from direct sunlight. Keep away from open flames, hot surfaces and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) 2- Butoxyethanol 50 ppm 240 mg/m3 - 20 ppm - Trisodium Phosphate - - - - Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use with adequate explosion-proof ventilation to meet the limits in Section 8 . Hygiene measures Remove and wash contaminated clothing before re-use. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand Protection Chemical resistant gloves. Eye protection ANSI approved safety glasses or splash goggles with face shield are recommended. Skin and body protection Wear appropriate clothing to minimize skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor Solvent Odor Threshold No information available pH 12.5 Specific Gravity 0.98 @ 70°F calculated Vapor pressure No data available Density No data available Vapor density No data available Evaporation Rate Slower than Ether Water solubility No data available VOC Content 7.85% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C 97.8° (concentrate); -26° (propellant) Boiling point/range °F 208° (concentrate); -14.8° (propellant) Melting point/range °C No data available Melting point/range °F No data available Flash point °C No data available Flash point °F No data available 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Heat, flames and sparks. Do not store above 120 degrees F. Incompatability Strong acids. Halogens. Zinc. Magnesium. Aluminum. Boron. Ethylene oxide. Chlorites. Mercury. Chromium trioxide. Gold. Nitrogen Tetroxide. Oleum (or fuming sulfuric acid). Hazardous Decomposition Products Carbon monoxide. Carbon dioxide. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) 2-Butoxyethanol 111-76-2 470 mg/kg 220 mg/kg 450 ppm Trisodium Phosphate 7601-54-9 2000 mg/kg 2 mg/kg 2.16 mg/L Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Synergistic Products None known Potential health effects Sensitization None known . Page 2 / 3 Product code 83571 Product name Full Blast Page 336 of 1069 Page 336 of 1069 Page 336 of 1069 Page 336 of 1069 ---PAGE BREAK--- Chronic toxicity None known . Mutagenic effects None known . Teratogenic effects None known . Reproductive toxicity None known . Target Organ Effects Kidney. Liver. Cardiovascular system. Carcinogenic effects See Table Below. Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns 2- Butoxyethanol A3 Not Listed Not Listed Not Listed Not Listed Trisodium Phosphate Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. Full or partially full containers are considered hazardous waste. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION US EPA SARA 313 Glycol ethers are listed under the Hazardous Air Pollutants (HAPS) category "glycol ethers" as specified in the Clean Air Act, and here for Clean Air Act reporting purposes Chemical Name US EPA SARA 313 Emission Reporting 2-Butoxyethanol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 2-Butoxyethanol Listed Listed Not Listed Trisodium Phosphate Not Listed Listed Not Listed Propane Listed Listed Not Listed Butane Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA 2-Butoxyethanol X X - X Trisodium Phosphate X X - X Propane X X - X Butane X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION NFPA Health - 3 Flammability - 4 Reactivity - 0 Health - 3 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Product code 83571 2-Butoxyethanol Product name Full Blast Page 337 of 1069 Page 337 of 1069 Page 337 of 1069 Page 337 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Version 1.0 Print Date 02/01/2012 Revision Date 01/12/2012 MSDS Number 350000019486 SITE_FORM Number 30000000000000014459.001 1/8 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Use of the Substance/Mixture : Air Freshener Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : orange / gel / pleasant Immediate Concerns : Caution COMBUSTIBLE: CAUSES EYE IRRITATION. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : Causes: Moderate eye irritation Skin : May cause skin reactions in rare cases. Prolonged or repeated contact may dry skin and cause irritation. Inhalation : No adverse effects expected when used as directed. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. Page 338 of 1069 Page 338 of 1069 Page 338 of 1069 Page 338 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Version 1.0 Print Date 02/01/2012 Revision Date 01/12/2012 MSDS Number 350000019486 SITE_FORM Number 30000000000000014459.001 2/8 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Fragrance - Trade Secret Mixture 60.00 - 100.00 Silica 7631-86-9 1.00 - 5.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Inhalation : No special requirements Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Container may melt and leak in heat of fire. Do not use a solid water stream as it may scatter and spread fire. Further information : Cool and use caution when approaching or handling fire- exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Flash point : 77 °C 170.6 °F Lower explosion limit : Note: no data available Page 339 of 1069 Page 339 of 1069 Page 339 of 1069 Page 339 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Version 1.0 Print Date 02/01/2012 Revision Date 01/12/2012 MSDS Number 350000019486 SITE_FORM Number 30000000000000014459.001 3/8 Upper explosion limit : Note: no data available 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid contact with skin, eyes and clothing. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge. Storage Requirements for storage areas and containers : Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above. Personal protective equipment Respiratory protection Page 340 of 1069 Page 340 of 1069 Page 340 of 1069 Page 340 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Version 1.0 Print Date 02/01/2012 Revision Date 01/12/2012 MSDS Number 350000019486 SITE_FORM Number 30000000000000014459.001 4/8 Industrial setting : No personal respiratory protective equipment normally required. Household setting : Use only with adequate ventilation. Hand protection : No special requirements. Eye protection Industrial setting : Safety glasses with side-shields Household setting : Avoid contact with eyes. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : gel Color : orange Odor : pleasant pH : not applicable Melting point : no data available Boiling point : no data available Freezing point : no data available Flash point : 77 °C 170.6 °F Evaporation rate : no data available Flammability (solid, gas) : The product is not flammable. Autoignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Page 341 of 1069 Page 341 of 1069 Page 341 of 1069 Page 341 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Version 1.0 Print Date 02/01/2012 Revision Date 01/12/2012 MSDS Number 350000019486 SITE_FORM Number 30000000000000014459.001 5/8 Vapour pressure : no data available Density : 0.9731 g/cm3 Water solubility : negligible Partition coefficient: n- octanol/water : no data available Viscosity, dynamic : no data available Viscosity, kinematic : no data available Relative vapour density : no data available Volatile Organic Compounds Total VOC (wt. : 87.2 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Thermal decomposition : Note: no data available Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 estimated > 5,000 mg/kg Acute inhalation toxicity : LC50 estimated > 2 mg/l Page 342 of 1069 Page 342 of 1069 Page 342 of 1069 Page 342 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Version 1.0 Print Date 02/01/2012 Revision Date 01/12/2012 MSDS Number 350000019486 SITE_FORM Number 30000000000000014459.001 6/8 Acute dermal toxicity : LD50 estimated > 2,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : Not known to be a sensitizer. 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Land transport ƒ U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name Combustible Liquid, N.O.S. Class: 3 NA number 1993 Packaging group: III Note: SC Johnson ships this product as "Non-Regulated" per TDG and per DOT exception for Combustible Liquids. (49 CFR 173.150) Page 343 of 1069 Page 343 of 1069 Page 343 of 1069 Page 343 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Version 1.0 Print Date 02/01/2012 Revision Date 01/12/2012 MSDS Number 350000019486 SITE_FORM Number 30000000000000014459.001 7/8 Sea transport ƒ IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport ƒ ICAO/IATA: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 2 Reactivity 0 NFPA Ratings Health 2 Page 344 of 1069 Page 344 of 1069 Page 344 of 1069 Page 344 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 GLADE® DECOR SCENTS™ - MAPLE PUMPKIN Version 1.0 Print Date 02/01/2012 Revision Date 01/12/2012 MSDS Number 350000019486 SITE_FORM Number 30000000000000014459.001 8/8 Fire 2 Reactivity 0 Special - Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 345 of 1069 Page 345 of 1069 Page 345 of 1069 Page 345 of 1069 ---PAGE BREAK--- Page 346 of 1069 Page 346 of 1069 Page 346 of 1069 Page 346 of 1069 ---PAGE BREAK--- Page 347 of 1069 Page 347 of 1069 Page 347 of 1069 Page 347 of 1069 ---PAGE BREAK--- Page 348 of 1069 Page 348 of 1069 Page 348 of 1069 Page 348 of 1069 ---PAGE BREAK--- Page 349 of 1069 Page 349 of 1069 Page 349 of 1069 Page 349 of 1069 ---PAGE BREAK--- Page 350 of 1069 Page 350 of 1069 Page 350 of 1069 Page 350 of 1069 ---PAGE BREAK--- Page 351 of 1069 Page 351 of 1069 Page 351 of 1069 Page 351 of 1069 ---PAGE BREAK--- Page 352 of 1069 Page 352 of 1069 Page 352 of 1069 Page 352 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET GLANCE Foaming Glass Cleaner 1. PRODUCT AND COMPANY IDENTIFICATION Product name: GLANCE Foaming Glass Cleaner MSDS MS0200109 Product Code: 04553 Recommended use: Glass Cleaner. This product is intended to be used neat . Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: None know n. Inhalation: None know n. Ingestion: None know n. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat Sodium nitrite 7632-00-0 1 - 5% 88 Not available 5500 µg/m3 (4 h) Isopropyl alcohol 67-63-0 5 - 10% 4396 12870 mg/kg 72.6 mg/L (4 h) 2-butoxyethanol 111-76-2 5 - 10% 470 220 mg/kg 2.21 mg/L (4 450 ppm (4 h) Butane 106-97-8 5 - 10% 2000 Not available =658 mg/L (4 h) Propane 74-98-6 5 - 10% 2400 Not available =658 mg/L (4 h) 4. FIRST AID MEASURES Eye contact: Flush immediately w ith plenty of w ater. If irritation develops, get medical attention. Skin contact: Rinse w ith plenty of w ater. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None know n. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Not applicable Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. Unusual hazards: None know n Specific methods: Use w ater spray to keep fire-exposed containers cool. Special protective equipment for firefighters: As in any fire, w ear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available NFPA Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: w w w .johnsondiversey.com Version Number: 2 Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] Preparation date: 2009-10-15 Personal protective equipment HMIS GLANCE Foaming Glass Cleaner EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. CONTENTS UNDER PRESSURE. USE ONLY IN WELL-VENTILATED AREAS. 1 of 4 1 Fire Hazard None / Aucune / Ninguno 4 1 Health 4 Reactivity 0 0 Page 353 of 1069 Page 353 of 1069 Page 353 of 1069 Page 353 of 1069 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: No information available 7. HANDLING AND STORAGE Handling: Avoid contact w ith eyes. CONTENTS UNDER PRESSURE. Do not puncture or incinerate. Keep aw ay from open flames, hot surfaces and sources of ignition. Use only w ith adequate ventilation. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: NFPA 30B Level 1 Aerosol . Protect from freezing. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Do not pierce or burn, even after use. Keep closed in a dry, cool and w ell-ventilated place. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance w ith good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Isopropyl alcohol 67-63-0 400 ppm (STEL) 200 ppm (TWA) 400 ppm (TWA) 980 mg/m3 (TWA) 500 ppm (STEL) 1225 mg/m3 (STEL) 980 mg/m3 (TWA) 400 ppm (TWA) 2-butoxyethanol 111-76-2 20 ppm (TWA) Skin 240 mg/m3 (TWA) 50 ppm (TWA) 75 ppm (STEL) 360 mg/m3 (STEL) 26 ppm (TWA) 120 mg/m3 (TWA) Butane 106-97-8 1000 ppm (TWA) 1900 mg/m3 (TWA) 800 ppm (TWA) Propane 74-98-6 1000 ppm (TWA) 1000 ppm (TWA) 1800 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Flame Extension (inches): 0 inches Explosion limits: - lower: Not determined- upper: Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: None know n. Conditions to avoid: Extremes of temperature and direct sunlight. Keep aw ay from open flames, hot surfaces and sources of ignition. No information available Partition coefficient (n-octanol/water): No information available Aerosol Solubility: Partially Soluble Color: Solubility in other solvents: No information available Clear Colorless Viscosity: No information available pH: Elemental Phosphorus: 0% by w t. Evaporation Rate No information available 11 Odor: Solvent Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: 0.943 No information available. Melting point/range: Not determined Bulk density: Density: No information available. Appearance: Decomposition temperature: Not determined Aerosol VOC: 8.7% * No information available Autoignition temperature: No information available GLANCE Foaming Glass Cleaner Vapor density: 2 of 4 Flash point: -156°F -104°C Page 354 of 1069 Page 354 of 1069 Page 354 of 1069 Page 354 of 1069 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be betw een 2000 - 3000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None know n Specific effects Carcinogenic effects: None know n Mutagenic effects: None know n Reproductive toxicity: None know n Target organ effects: None know n Hazardous ingredients Ingredient(s) CAS # NTP IARC OSHA Isopropyl alcohol 67-63-0 3 X 2-butoxyethanol 111-76-2 3 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Use up contents if possible before disposal . If possible, recycle empty aerosol cans to the nearest steel recycling center . RCRA Hazard Class: D001 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the follow ing inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Sodium nitrite 7632-00-0 X X X - Isopropyl alcohol 67-63-0 X X X X 2-butoxyethanol 111-76-2 X X X X Butane 106-97-8 X X X X Propane 74-98-6 X X X X CERCLA/ SARA Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Sodium nitrite 7632-00-0 1 - 5% 100 X Isopropyl alcohol 67-63-0 5 - 10% X 2-butoxyethanol 111-76-2 5 - 10% X Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants 2-butoxyethanol X SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: x Reactivity: - Sudden Release of Pressure: x Canada WHMIS hazard class: A Compressed gases. W HMIS graphic:Class A Compressed Gases 3 of 4 GLANCE Foaming Glass Cleaner Page 355 of 1069 Page 355 of 1069 Page 355 of 1069 Page 355 of 1069 ---PAGE BREAK--- 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: Does not contain an added fragrance. Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 4 of 4 GLANCE Foaming Glass Cleaner Page 356 of 1069 Page 356 of 1069 Page 356 of 1069 Page 356 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Glance NA Version Number: 2 Preparation date: 2007-07-25 Personal protective equipment NFPA HMIS Reactivity 0 None / Aucune / Ninguno Health Fire Hazard 1 0 0 1 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Glance NA MSDS MS0200011 Product Code: 3361936, 3172641 Recommended use: Cleaning product. This product is intended to be diluted prior to use. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - Rabbit LC50 Inhalation - Rat Sodium lauryl sulfate 151-21-3 1 - 5% Not available Not available Not available Ethyl alcohol 64-17-5 0.1 - 1.5% Not available Not available Not available 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Skin contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: None known. Unusual hazards: None known. Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Glance NA Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] 1 of 3 EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. Page 357 of 1069 Page 357 of 1069 Page 357 of 1069 Page 357 of 1069 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Clean up affected area with water. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Ethyl alcohol 64-17-5 1000 ppm (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: None known. Conditions to avoid: Do not freeze. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known HAZARDOUS COMPONENTS Ingredient(s) CAS # NTP IARC OSHA Ethyl alcohol 64-17-5 X 1 X Bulk density: Density: 8.35 Appearance: Decomposition temperature: Not determined Aqueous solution VOC: 0.25 No information available Autoignition temperature: No information available Vapor density: Flash point: >200°F >93.3°C No information available Partition coefficient (n-octanol/water): No information available Liquid Solubility: Soluble Color: Solubility in other solvents: No information available Blue Viscosity: No information available pH: Elemental Phosphorus: 0.0 %P Evaporation Rate No information available >7.0 7.0 Odor: Characteristic Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: .999 No information available. Glance NA 2 of 3 Melting point/range: Not determined Page 358 of 1069 Page 358 of 1069 Page 358 of 1069 Page 358 of 1069 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia (AICS), Korea (ECL), Japan (ENCS), Philippines (PICCS), China (IECSC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Sodium lauryl sulfate 151-21-3 - - - - Alcohol ethoxylates 68439-46-3 - - - - Ethyl alcohol 64-17-5 X X X X Sodium lauryl ether sulfate 9004-82-4 - - - - CERCLA/ SARA CAA HAP/CAA ODS/CWA Priority Pollutants: None SARA 311/312 Hazard Categories Immediate: X Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class: Non-controlled. Ingredient(s) CAS # NPRI Ethyl alcohol 64-17-5 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 Glance NA Page 359 of 1069 Page 359 of 1069 Page 359 of 1069 Page 359 of 1069 ---PAGE BREAK--- JohnsonDiversey, Inc. 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.johnsondiversey.com JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] Canadian Headquarters GLANCE NON-AMMONIATED GLASS CLEANER 3172641 & 3361936 Industrial/Institutional: Cleaning product. 7/8/2004 7/8/2004 Material Safety Data Sheet Product Name Product Use Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Supersedes 9/24/2003. Health 1 0 0 Fire Hazard Reactivity Specific Hazard Health Fire Hazard Reactivity Protective Clothing 0 0 1 (800) 851-7145 U.S. Headquarters Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) Code MSDS# F-00424001 3191797 Blue. Liquid. See Section 9. CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. Emergency Overview None required. PMS# GLANCE NON-AMMONIATED GLASS CLEANER Ethyl Alcohol 64-17-5 0.1-1 OSHA (United States). TWA: 1900 mg/m3 ACGIH (United States). TWA: 1880 mg/m3 ORAL (LD50): Acute: 7060 mg/kg [Rat]. VAPOR (LC50): Acute: 20000 ppm 10 hour(s) [Rat]. Alcohol Ethoxylates 68439-46-3 1-5 Not available. ORAL (LD50): Acute: 1378 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mg/kg [Rabbit]. Sodium Lauryl Sulfate 151-21-3 1-5 Not available. ORAL (LD50): Acute: 1288 mg/kg [Rat]. DUST (LC50): Acute: >3900 mg/m3 1 hour(s) [Rat]. Sodium Lauryl Ether Sulfate 9004-82-4 1-5 Not available. ORAL (LD50): Acute: 1600 mg/kg [Rat]. Water 7732-18-5 60-100 Not available. Not available. Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits LC50/LD50 Inhalation. Skin contact. Eye contact. Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects None known. May be mildly irritating to eyes. None known. May be mildly irritating to skin. Eyes Skin Inhalation Ingestion Continued on Next Page Page: 1/4 Page 360 of 1069 Page 360 of 1069 Page 360 of 1069 Page 360 of 1069 ---PAGE BREAK--- Material Safety Data Sheet GLANCE NON-AMMONIATED GLASS CLEANER Medical Conditions Aggravated by Overexposure: None known. See Toxicological Information (section 11) No specific first aid measures are required. Flush immediately with plenty of water. Get medical attention if irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion None known. None known. None. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Put on appropriate personal protective equipment (see Section Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. Avoid contact with skin and eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Section 7. Handling and Storage Handling Storage No special ventilation requirements. General room ventilation is adequate. Section 8. Exposure Controls/Personal Protection Engineering Controls No special requirements under normal use conditions. No special requirements under normal use conditions. No special protective clothing is required. No special requirements under normal use conditions. No special requirements under normal use conditions. Personal Protection Eyes Hands Respiratory Feet Body 100°C (212°F) Liquid. 0°C (32°F) 1 Mild. Blue. Boiling/Condensation Point Melting/Freezing Point Section 9. Physical and Chemical Properties Physical State and Appearance pH Specific Gravity Odor Color Continued on Next Page Page: 2/4 Page 361 of 1069 Page 361 of 1069 Page 361 of 1069 Page 361 of 1069 ---PAGE BREAK--- Material Safety Data Sheet GLANCE NON-AMMONIATED GLASS CLEANER Solubility in water Complete. The product is stable. None known. Will not occur. When exposed to fire: Produces normal products of combustion. None known. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Section 11. Toxicological Information Effects of Chronic Exposure Other Toxic Effects None known. ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). DERMAL (LD50) Estimated to be greater than 2000 mg/kg (rat). Acute toxicity None known. Section 12. Ecological Information Not available. No special precautions. Dispose of according to all federal, state and local regulations. Waste Information Section 13. Disposal Considerations Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 14. Transport Information DOT Classification DOT Proper Shipping Name TDG Classification TDG Proper Shipping Name TDG Class Please refer to the Bill of Lading/receiving documents for up to date shipping information. State Section 15. Regulatory Information Federal Canadian Regulations Not controlled under WHMIS (Canada). Registered Product Information Reporting in this section is based on ingredients disclosed in Section 2 WHMIS Classification WHMIS Icon New Jersey: Ethyl Alcohol Massachusetts spill list: Ethyl Alcohol Massachusetts RTK: Ethyl Alcohol RTK: Ethyl Alcohol CERCLA: Hazardous substances.: Ethyl Alcohol Not applicable. US Regulations This product is not subject to the reporting requirements under California's Proposition 65. Continued on Next Page Page: 3/4 Page 362 of 1069 Page 362 of 1069 Page 362 of 1069 Page 362 of 1069 ---PAGE BREAK--- Material Safety Data Sheet GLANCE NON-AMMONIATED GLASS CLEANER Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Registered Product Information Not applicable. Not available. Section 16. Other Information Other Special Considerations Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Version 1.01 Page 363 of 1069 Page 363 of 1069 Page 363 of 1069 Page 363 of 1069 ---PAGE BREAK--- Glance RTU Glass & Multi-Surface Cleaner SAFETY DATA SHEET Version Number: 2 Preparation date: 2015-04-21 1. IDENTIFICATION Product name: Glance RTU Glass & Multi-Surface Cleaner Product Code: 04705, 04554 SDS MS0800662 Recommended use: • Glass Cleaner • This product is intended to be used neat. Uses advised against: Uses other than those identified are not recommended Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Classification for the undiluted product This product is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and Canadian Hazardous Products Regulations (HPR) (WHMIS 2015-GHS). Precautionary Statements None required. Health hazards not otherwise classified (HHNOC) - Not applicable Physical hazards not otherwise classified (PHNOC) - Not applicable 3. COMPOSITION/INFORMATION ON INGREDIENTS Classified Ingredients None of the components of this product are classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and Canadian Hazardous Products Regulations (HPR) (WHMIS 2015-GHS). Manufacturer, importer, supplier: US Headquarters Diversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.diversey.com Canadian Headquarters Diversey, Inc. - Canada 3755 Laird Road Mississauga, Ontario L5L 0B3 Phone: 1-[PHONE REDACTED] Classification for the diluted product @ RTU This product is intended to be used neat. Glance RTU Glass & Multi-Surface Cleaner 1 of 5 Precautionary Statements See undiluted product information above. Page 364 of 1069 Page 364 of 1069 Page 364 of 1069 Page 364 of 1069 ---PAGE BREAK--- 4. FIRST AID MEASURES Undiluted Product: Eyes: Rinse with plenty of water. If irritation occurs and persists, get medical attention. Skin: Rinse with plenty of water. If irritation occurs and persists, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: Rinse mouth with water. Most Important No information available. Immediate medical attention and special treatment needed Not applicable. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Specific methods: No special methods required Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Not applicable. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures required. Environmental precautions and clean-up methods: Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Handle in accordance with good industrial hygiene and safety practice. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. Aerosol Level (if applicable) : Not applicable 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines: . Undiluted Product: Engineering measures to reduce exposure: No special ventilation requirements Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions. Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Diluted Product: This product is intended to be used neat. Eyes: See undiluted product information above. Skin: See undiluted product information above. Inhalation: See undiluted product information above. Ingestion: See undiluted product information above. Diluted Product: Glance RTU Glass & Multi-Surface Cleaner 2 of 5 This product is intended to be used neat. Personal Protective Equipment Page 365 of 1069 Page 365 of 1069 Page 365 of 1069 Page 365 of 1069 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES: Explosion limits: - upper: Not determined - lower: Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Reactivity: Not Applicable Stability: The product is stable Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: Do not mix with any other product or chemical unless specified in the use directions. Conditions to avoid: No information available. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure: Eye contact, Skin contact, Inhalation, Ingestion Delayed, immediate, or chronic effects and from short and long-term exposure Skin contact: Unlikely to be irritant in normal use. Eye contact: May be mildly irritating to eyes. Ingestion: No information available. Inhalation: No information available. Sensitization: No known effects. Target Organs (SE): None known Target Organs (RE): None known Numerical measures of toxicity ATE - Oral (mg/kg): >5000 mg/kg ATE - Dermal (mg/kg): >2000 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity: No information available. Persistence and Degradability: No information available. Bioaccumulation: No information available. Eye protection: No personal protective equipment required under normal use conditions. Hand protection: No personal protective equipment required under normal use conditions. Skin and body protection: No personal protective equipment required under normal use conditions. Respiratory protection: No personal protective equipment required under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Physical State: Liquid Color: Clear, Light, Blue Evaporation Rate: No information available Odor: Ammonia Odor threshold: No information available. Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Solubility: Completely Soluble Solubility in other solvents: No information available Relative Density (relative to water): 1 Density: 8.34 lbs/gal 1 Kg/L Vapor density: No information available Bulk density: No information available Vapor pressure: No information available. Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available Dilution Flash Point: 200 °F 93.3 °C Viscosity: No information available Elemental Phosphorus: 0.00 % by wt. VOC: 0.33 % * pH: 10.5 VOC % by wt. at use dilution 0.33 % * Glance RTU Glass & Multi-Surface Cleaner 3 of 5 Dilution pH: 10.5 @ RTU Flammability (Solid or Gas): Not applicable Metal Corrosion: Not determined Page 366 of 1069 Page 366 of 1069 Page 366 of 1069 Page 366 of 1069 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: This product, as sold, if discarded or disposed, is not a hazardous waste according to Federal regulations (40 CFR 261.4 Dispose in compliance with all Federal, state, provincial, and local laws and regulations. Contaminated Packaging: Do not re-use empty containers. RCRA Hazard Class (undiluted product): Not Regulated 14. TRANSPORT INFORMATION DOT/TDG/IMDG: Proper shipping descriptions can vary by pack size. Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information. DOT (Ground) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID IMDG (Ocean) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID 15. REGULATORY INFORMATION International Inventories at CAS# Level All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65. RIGHT TO KNOW (RTK) Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Diethylene glycol butyl ether 112-34-5 - X - - 2-butoxyethanol 111-76-2 X X X - Sodium lauryl sulfate 151-21-3 - - - - Ammonium hydroxide 1336-21-6 X X X X CERCLA/ SARA Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Diethylene glycol butyl ether 112-34-5 > 0.1% - < 1% X 2-butoxyethanol 111-76-2 > 0.1% - < 1% X Ammonium hydroxide 1336-21-6 < 0.1% 1000 X Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants Diethylene glycol butyl ether X 2-butoxyethanol X SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canadian Regulations WHMIS hazard class: None. Ingredient(s) CAS # NPRI Diethylene glycol butyl ether 112-34-5 X 2-butoxyethanol Glance RTU Glass & Multi-Surface Cleaner 4 of 5 111-76-2 X Page 367 of 1069 Page 367 of 1069 Page 367 of 1069 Page 367 of 1069 ---PAGE BREAK--- 16. OTHER INFORMATION NFPA (National Fire Protection Association) Rating Scale: (Low Hazard) 0 - 4 (Extreme Hazard) Health 0 Flammability 0 Instability 0 Version Number: 2 Preparation date: 2015-04-21 Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: Glance RTU Glass & Multi-Surface Cleaner 5 of 5 • Does not contain an added fragrance Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 368 of 1069 Page 368 of 1069 Page 368 of 1069 Page 368 of 1069 ---PAGE BREAK--- Page 369 of 1069 Page 369 of 1069 Page 369 of 1069 Page 369 of 1069 ---PAGE BREAK--- Page 370 of 1069 Page 370 of 1069 Page 370 of 1069 Page 370 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product number Product identifier Company information Emergency telephone US Version # 12 Recommended use Cleaner Recommended restrictions None known. 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Not classified. Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Response Wash hands after handling. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 111-76-2 2-Butoxyethanol 2.5 - 10 67-63-0 Isopropyl Alcohol 2.5 - 10 106-97-8 Butane 1 - 2.5 74-98-6 Propane Other components below reportable levels 90 - 100 1 - 2.5 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if develop or persist. 1 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 371 of 1069 Page 371 of 1069 Page 371 of 1069 Page 371 of 1069 7609, 9447, 9914, 8027 Glass-Kleen Plus Tifco Industries, Inc. PO Box 40277 Houston, TX 77240 Chem-Tel: [PHONE REDACTED] ---PAGE BREAK--- Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if occur. Most important acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 2 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 372 of 1069 Page 372 of 1069 Page 372 of 1069 Page 372 of 1069 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 240 mg/m3 2-Butoxyethanol (CAS 111-76-2) 50 ppm PEL 980 mg/m3 Isopropyl Alcohol (CAS 67-63-0) 400 ppm PEL 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values Value Components Type TWA 20 ppm 2-Butoxyethanol (CAS 111-76-2) STEL 1000 ppm Butane (CAS 106-97-8) STEL 400 ppm Isopropyl Alcohol (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 24 mg/m3 2-Butoxyethanol (CAS 111-76-2) 5 ppm TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm STEL 1225 mg/m3 Isopropyl Alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm TWA 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine * 2-Butoxyethanol (CAS 111-76-2) 40 mg/l Acetone Urine * Isopropyl Alcohol (CAS 67-63-0) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. 3 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 373 of 1069 Page 373 of 1069 Page 373 of 1069 Page 373 of 1069 ---PAGE BREAK--- Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 23.01 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.977 estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 4 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 374 of 1069 Page 374 of 1069 Page 374 of 1069 Page 374 of 1069 ---PAGE BREAK--- Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Fire or intense heat may cause violent rupture of packages. Incompatible materials Strong oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Test Results Components Species 2-Butoxyethanol (CAS 111-76-2) LD50 Guinea pig Dermal Acute 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit Inhalation 400 ppm, 7 Hours Rat 450 ppm, 4 Hours LD100 Rabbit Oral 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l Isopropyl Alcohol (CAS 67-63-0) LD50 Rabbit Dermal Acute 16.4 ml/kg, 24 Hours 5 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 375 of 1069 Page 375 of 1069 Page 375 of 1069 Page 375 of 1069 ---PAGE BREAK--- Test Results Components Species LC50 Rat Inhalation > 10000 ppm, 6 Hours LD50 Rat Oral 5.84 g/kg Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Not applicable. Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Test Results Species 2-Butoxyethanol (CAS 111-76-2) Aquatic LC50 Fish 1250 mg/l, 96 hours Inland silverside (Menidia beryllina) Isopropyl Alcohol (CAS 67-63-0) Aquatic IC50 Algae 1000.0001 mg/L, 72 Hours Algae EC50 Crustacea 13299 mg/L, 48 Hours Daphnia * Estimates for product may be based on additional component data not shown. LC50 Fish > 1400 mg/l, 96 hours Bluegill (Lepomis macrochirus) Persistence and degradability No data is available on the degradability of this product. 6 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 376 of 1069 Page 376 of 1069 Page 376 of 1069 Page 376 of 1069 ---PAGE BREAK--- Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Isopropyl Alcohol 0.05 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950 UN number Aerosols, flammable, (each not exceeding 1 L capacity) UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950 UN number Aerosols, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only LTD QTY Packaging Exceptions 7 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 377 of 1069 Page 377 of 1069 Page 377 of 1069 Page 377 of 1069 ---PAGE BREAK--- IMDG UN1950 UN number AEROSOLS UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group No. Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTY Packaging Exceptions Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No 8 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 378 of 1069 Page 378 of 1069 Page 378 of 1069 Page 378 of 1069 ---PAGE BREAK--- SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Isopropyl Alcohol (CAS 67-63-0) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Isopropyl Alcohol (CAS 67-63-0) Propane (CAS 74-98-6) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Isopropyl Alcohol (CAS 67-63-0) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Isopropyl Alcohol (CAS 67-63-0) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) Yes Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 9 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 379 of 1069 Page 379 of 1069 Page 379 of 1069 Page 379 of 1069 ---PAGE BREAK--- 16. Other information, including date of preparation or last revision Issue date 05-26-2015 Version # 12 Disclaimer We cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 10 / 10 Version 12 Issue date: 05-26-2015 SDS US Page 380 of 1069 Page 380 of 1069 Page 380 of 1069 Page 380 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 1 / 20 SECTION 1. IDENTIFICATION Product name : GOJO® E2 Foam Handwash with PCMX Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-[PHONE REDACTED] CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Antibacterial Soap Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Serious eye damage : Category 1 GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : H226 Flammable liquid and vapor. H318 Causes serious eye damage. Page 381 of 1069 Page 381 of 1069 Page 381 of 1069 Page 381 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 2 / 20 Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration Ethanol 64-17-5 5 - < 10 Dodecanoic acid 143-07-7 5 - < 10 Ethanolamine 141-43-5 1 - < 5 l-(+)-Lactic acid 79-33-4 1 - < 5 88-04-0 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Page 382 of 1069 Page 382 of 1069 Page 382 of 1069 Page 382 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 3 / 20 If easy to do, remove contact lens, if worn. Get medical attention immediately. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : Causes serious eye damage. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Nitrogen oxides (NOx) Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Page 383 of 1069 Page 383 of 1069 Page 383 of 1069 Page 383 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 4 / 20 Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Page 384 of 1069 Page 384 of 1069 Page 384 of 1069 Page 384 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 5 / 20 Strong oxidizing agents Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 STEL 1,000 ppm ACGIH Ethanolamine 141-43-5 TWA 3 ppm ACGIH STEL 6 ppm ACGIH TWA 3 ppm 8 mg/m3 NIOSH REL ST 6 ppm 15 mg/m3 NIOSH REL TWA 3 ppm 6 mg/m3 OSHA Z-1 Hazardous components without workplace control parameters Ingredients CAS-No. Dodecanoic acid 143-07-7 l-(+)-Lactic acid 79-33-4 88-04-0 Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Dust formation may be relevant in the processing of this product. In addition to substance-specific OELs, general limitations of concentrations of particulates in the air at workplaces have to be considered in workplace risk assessment. Relevant limits include: OSHA PEL for Particulates Not Otherwise Regulated of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for Particles (insoluble or poorly soluble) Not Otherwise Specified of 3 mg/m3 - respirable particles, 10 mg/m3 - inhalable particles. Page 385 of 1069 Page 385 of 1069 Page 385 of 1069 Page 385 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 6 / 20 Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Chemical resistant goggles must be worn. If splashes are likely to occur, wear: Face-shield Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : Odor : Page 386 of 1069 Page 386 of 1069 Page 386 of 1069 Page 386 of 1069 Clear, colorless to pale yellow Fragrance free ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 7 / 20 Odor Threshold : No data available pH : 7.8 - 9.7 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 45.6 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 1 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 10 - 20 mm2/s (20 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Page 387 of 1069 Page 387 of 1069 Page 387 of 1069 Page 387 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 8 / 20 Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate: > 40 mg/l Exposure time: 4 h Test atmosphere: vapor Method: Calculation method Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Dodecanoic acid: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : LC50 (Rat): > 0.162 mg/l Exposure time: 4 h Test atmosphere: vapor Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials Ethanolamine: Acute oral toxicity : LD50 (Rat): 1,515 mg/kg Acute inhalation toxicity : Acute toxicity estimate: 11 mg/l Page 388 of 1069 Page 388 of 1069 Page 388 of 1069 Page 388 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 9 / 20 Test atmosphere: vapor Method: Expert judgment Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI Acute dermal toxicity : LD50 (Rabbit): 1,025 mg/kg l-(+)-Lactic acid: Acute oral toxicity : LD50 (Rat, female): 3,543 mg/kg Acute inhalation toxicity : LC50 (Rat): > 7.94 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Acute oral toxicity : Acute toxicity estimate: 500 mg/kg Method: Expert judgment Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI Acute inhalation toxicity : LC50 (Rat): > 6.29 mg/l Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Dodecanoic acid: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Ethanolamine: Species: Rabbit Result: Corrosive after 3 minutes to 1 hour of exposure l-(+)-Lactic acid: Species: Rabbit Result: Skin irritation Page 389 of 1069 Page 389 of 1069 Page 389 of 1069 Page 389 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 10 / 20 Result: Skin irritation Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI Serious eye damage/eye irritation Causes serious eye damage. Ingredients: Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Dodecanoic acid: Species: Rabbit Result: Irreversible effects on the eye Method: OECD Test Guideline 405 Ethanolamine: Species: Rabbit Result: Irreversible effects on the eye l-(+)-Lactic acid: Species: Chicken eye Result: Irreversible effects on the eye Result: Irreversible effects on the eye Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Dodecanoic acid: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative Ethanolamine: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative Page 390 of 1069 Page 390 of 1069 Page 390 of 1069 Page 390 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 11 / 20 l-(+)-Lactic acid: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Result: negative Assessment: Probability or evidence of skin sensitization in humans Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative Dodecanoic acid: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Remarks: Based on data from similar materials Ethanolamine: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Genotoxicity in vivo : Test Type: Mammalian micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 474 Result: negative l-(+)-Lactic acid: Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro Metabolic activation: with and without metabolic activation Result: negative Remarks: Based on data from similar materials : Test Type: Bacterial reverse mutation assay (AMES) Metabolic activation: with and without metabolic activation Result: negative Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Page 391 of 1069 Page 391 of 1069 Page 391 of 1069 Page 391 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 12 / 20 Carcinogenicity Not classified based on available information. Ingredients: l-(+)-Lactic acid: Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative Remarks: Based on data from similar materials IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Dodecanoic acid: Effects on fertility : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Remarks: Based on data from similar materials Effects on fetal development : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Remarks: Based on data from similar materials Ethanolamine: Effects on fertility : Test Type: Two-generation reproduction toxicity study Page 392 of 1069 Page 392 of 1069 Page 392 of 1069 Page 392 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 13 / 20 Species: Rat Application Route: Ingestion Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative STOT-single exposure Not classified based on available information. Ingredients: Ethanolamine: Assessment: May cause respiratory irritation. l-(+)-Lactic acid: Assessment: May cause respiratory irritation. STOT-repeated exposure Not classified based on available information. Ingredients: Ethanolamine: Routes of exposure: inhalation (dust/mist/fume) Assessment: No significant health effects observed in animals at concentrations of 0.2 mg/l/6h/d or less. Repeated dose toxicity Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Dodecanoic acid: Species: Rat NOAEL: 10,000 mg/kg Application Route: Ingestion Exposure time: 18 w Ethanolamine: Species: Rat NOAEL: 150 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 28 d l-(+)-Lactic acid: Species: Rat NOAEL: 886 mg/kg Page 393 of 1069 Page 393 of 1069 Page 393 of 1069 Page 393 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 14 / 20 Application Route: Skin contact Exposure time: 13 w Species: Rabbit LOAEL: 180 mg/kg Application Route: Skin contact Exposure time: 90 d Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Dodecanoic acid: Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): 5 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 3.6 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): > 7.6 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: No toxicity at the limit of solubility. NOEC (Selenastrum capricornutum (green algae)): > 7.6 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: No toxicity at the limit of solubility. Page 394 of 1069 Page 394 of 1069 Page 394 of 1069 Page 394 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 15 / 20 Toxicity to fish (Chronic toxicity) : NOEC (Danio rerio (zebra fish)): 2 mg/l Exposure time: 28 d Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 0.47 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Toxicity to bacteria : EC10 (Pseudomonas putida): > 1,000 mg/l Exposure time: 30 min Method: OECD Test Guideline 209 Ethanolamine: Toxicity to fish : LC50 (Cyprinus carpio (Carp)): 349 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 65 mg/l Exposure time: 48 h Toxicity to algae : ErC50 (Selenastrum capricornutum (green algae)): 2.8 mg/l Exposure time: 72 h NOEC (Scenedesmus capricornutum (fresh water algae)): 1 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Oryzias latipes (Orange-red killifish)): 1.24 mg/l Exposure time: 41 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 0.85 mg/l Exposure time: 21 d Toxicity to bacteria : EC50 (Pseudomonas putida): 110 mg/l Exposure time: 17 h l-(+)-Lactic acid: Toxicity to fish : LC50 mykiss (rainbow trout)): 130 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 250 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : NOEC (Selenastrum capricornutum (fresh water algae)): 1.9 g/l Exposure time: 72 h Method: OECD Test Guideline 201 EC50 (Selenastrum capricornutum (fresh water algae)): 3.5 g/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 3 h Page 395 of 1069 Page 395 of 1069 Page 395 of 1069 Page 395 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 16 / 20 Method: OECD Test Guideline 209 Toxicity to fish : LC50 mykiss (rainbow trout)): 0.76 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 7.7 mg/l Exposure time: 48 h M-Factor (Acute aquatic tox- icity) : 1 Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Dodecanoic acid: Biodegradability : Result: Readily biodegradable. Biodegradation: 86 % Exposure time: 30 d Method: OECD Test Guideline 301D Ethanolamine: Biodegradability : Result: Readily biodegradable. Biodegradation: > 90 % Exposure time: 21 d l-(+)-Lactic acid: Biodegradability : Result: Not readily biodegradable. Biodegradation: 67 % Exposure time: 20 d Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: n- octanol/water : log Pow: -0.35 Dodecanoic acid: Bioaccumulation : Species: Fish Bioconcentration factor (BCF): 234 - 288 Remarks: Based on data from similar materials Partition coefficient: n- octanol/water : Pow: 4.6 Ethanolamine: Partition coefficient: n- octanol/water : log Pow: -1.91 Page 396 of 1069 Page 396 of 1069 Page 396 of 1069 Page 396 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 17 / 20 l-(+)-Lactic acid: Partition coefficient: n- octanol/water : log Pow: -0.6 Partition coefficient: n- octanol/water : log Pow: 3.27 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulation UN number : UN 1993 Proper shipping name : FLAMMABLE LIQUID, N.O.S. (Ethanol) Class : 3 Packing group : III Labels : 3 IATA-DGR UN/ID No. : UN 1993 Proper shipping name : Flammable liquid, n.o.s. (Ethanol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo aircraft) : 366 Packing instruction (passenger aircraft) : 355 IMDG-Code UN number : UN 1993 Page 397 of 1069 Page 397 of 1069 Page 397 of 1069 Page 397 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 18 / 20 Proper shipping name : FLAMMABLE LIQUID, N.O.S. (Ethanol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-E Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : NA 1993 Proper shipping name : COMBUSTIBLE LIQUID, N.O.S. (Ethanol) Class : CBL Packing group : III Labels : None ERG Code : 128 Marine pollutant : no Remarks : Above applies only to containers over 119 gallons or 450 liters. Not regulated if shipped in packages less than or equal to 119 gallons (450 liters). SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Right To Know Water 7732-18-5 70 - 90 % Ethanol 64-17-5 5 - 10 % Dodecanoic acid 143-07-7 5 - 10 % Page 398 of 1069 Page 398 of 1069 Page 398 of 1069 Page 398 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 19 / 20 Ethanolamine 141-43-5 1 - 5 % Dipropylene glycol 25265-71-8 1 - 5 % Propan-2-ol 67-63-0 0.1 - 1 % New Jersey Right To Know Water 7732-18-5 70 - 90 % Ethanol 64-17-5 5 - 10 % Dodecanoic acid 143-07-7 5 - 10 % Ethanolamine 141-43-5 1 - 5 % Dipropylene glycol 25265-71-8 1 - 5 % California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour Flammability Health Instability 3 2 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 2 0 3 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 399 of 1069 Page 399 of 1069 Page 399 of 1069 Page 399 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® E2 Foam Handwash with PCMX Version 3.0 Revision Date: 05/05/2015 MSDS Number: 36491-00004 Date of last issue: 04/17/2015 Date of first issue: 12/11/2014 20 / 20 workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 05/05/2015 Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines. The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid- ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8 Page 400 of 1069 Page 400 of 1069 Page 400 of 1069 Page 400 of 1069 ---PAGE BREAK--- Page 401 of 1069 Page 401 of 1069 Page 401 of 1069 Page 401 of 1069 ---PAGE BREAK--- Page 402 of 1069 Page 402 of 1069 Page 402 of 1069 Page 402 of 1069 ---PAGE BREAK--- Page 403 of 1069 Page 403 of 1069 Page 403 of 1069 Page 403 of 1069 ---PAGE BREAK--- Page 404 of 1069 Page 404 of 1069 Page 404 of 1069 Page 404 of 1069 ---PAGE BREAK--- Page 405 of 1069 Page 405 of 1069 Page 405 of 1069 Page 405 of 1069 ---PAGE BREAK--- Page 406 of 1069 Page 406 of 1069 Page 406 of 1069 Page 406 of 1069 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # 162 SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P.O. BOX 71550 MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS GRAFFITI AWAY TOWELS CHEMICAL FAMILY Premoistened Towels FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Dimethyl Glutarate (CAS# 1119-40-0) >1 N/A n-Methyl Pyrrolidine (CAS# 872-50-4) >1 not est. Dimethyl Succinate (CAS# 106-65-0) >1 N/A Dimethyl Adipate (CAS# 627-93-0) >1 N/A All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT °F N/A SPECIFIC GRAVITY (H2O = 1) 1.08 VAPOR PRESSURE (mm. Hg.) 0.1 PERCENT VOLATILE BY VOLUME 90 VAPOR DENSITY (AIR = 1) 1.1 EVAPORATION RATE ( n-Butyl Acetate N/A SOLUBILITY IN WATER soluble PH N/A APPEARANCE AND ODOR Light green cloth impregnated with a clear, water white liquid- no odor. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) 200+ºF T.O.C. FLAMMABLE LIMITS N/A N/A EXTINGUISHING MEDIA Dry Chemical, Carbon Dioxide, Foam, Water SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. UNUSUAL FIRE AND EXPLOSION HAZARDS None (Continued on reverse side) n-Methyl Pyrrolidine is listed as “Developmental” on the California Prop 65 Chemicals List. No conclusive detrimental data has been found to date. All other components are California Prop 65 Compliant. Page 407 of 1069 Page 407 of 1069 Page 407 of 1069 Page 407 of 1069 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA THRESHOLD LIMIT VALUE not established PRIMARY ROUTES OF ENTRY Inhalation X Skin Contact X Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- irritation. Skin- irritation. Inhalation- irritation to upper respiratory tract, dizziness, headache. Ingestion- irritation to digestive tract, nausea, cramps, vomiting. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amoutns of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- wash with soap and water, launder contaminated clothing before reuse- get medical attention if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- DO NOT INDUCE VOMITING- give water if conscious- get medical attention immediately. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None Known CARCINOGEN: No NTP IARC OTHER SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE X CONDITIONS TO AVOID Excessive heat, open flames INCOMPATIBILITY (Materials to avoid) Strong Oxidizers, Acids, Alkalies HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon and Nitrogen MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR X CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Pickup and place in conatiner for disposal. Flush area with water. WASTE DISPOSAL METHOD In accordance with all local, state, and federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Not required LOCAL EXHAUST normal ventilation adequate SPECIAL N/A VENTILATION MECHANICAL (General) normal ventilation adequate OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Safety Glasses OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- use only with adequate ventilation. Do not take internally. Do not store in areas of excessive heat. Do not use near sources of ignition. OTHER PRECAUTIONS Keep container closed when not in use. Keep Out of Reach of Children. HMIS SYMBOL NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE May 24, 2007 PHONE NUMBER CHEMTREC [PHONE REDACTED] PAGE TWO: GRAFFITI AWAY TOWELS HEALTH 1 FLAMMABILITY 1 REACTIVITY 0 HMIS NFPA SEVERE 4 EXTREME 1 SERIOUS 3 HIGH 1 0 MODERATE 2 MODERATE SLIGHT 1 SLIGHT MINIMAL 0 INSIGNIFICANT NFPA SYMBOL TOXICITY FIRE REACTIVITY SPECIAL Page 408 of 1069 Page 408 of 1069 Page 408 of 1069 Page 408 of 1069 ---PAGE BREAK--- The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000 Material Safety Data Sheet I Product: GREEN WORKS™ NATURAL ALL PURPOSE CLEANER Description: LIQUID WITH LEMON ODOR Other Designations Distributor Emergency Telephone Nos. Clorox Sales Company 1221 Broadway Oakland, CA 94612 For Medical Emergencies call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] II Health Hazard Data III Hazardous Ingredients Eye irritant. May cause skin irritation. No medical conditions are known to be aggravated by exposure to this product. FIRST AID: EYE CONTACT: Immediately rinse with plenty of water. If irritation persists, call a doctor. INGESTION: Drink a glassful of water. Call a doctor or poison control center. SKIN CONTACT: Rinse with plenty of water. If irritation persists, call a doctor. INHALATION: Move person to fresh air. If breathing problems develop, call a doctor. Ingredient Concentration Worker Exposure Limit Alkyl polyglucoside 1 - 5% not established CAS # 68515-73-1 Ethyl alcohol 1 - 5% 1000 ppm - TLV-TWA CAS # 64-17-5 1000 ppm - OSHA PEL TLV-TWA = ACGIH Threshold Limit Value - Time Weighted Average OSHA-PEL = OSHA Permissible Exposure Limit - Time Weighted Average None of the materials in this product are on the IARC, OSHA, or NTP carcinogen lists. IV Special Protection and Precautions V Transportation and Regulatory Data Hygienic Practices: Wash hands after direct contact. Do not wear product- contaminated clothing for prolonged periods. Engineering Controls: Use local exhaust to minimize exposure to product mist. Personal Protective Equipment: Wear safety glasses. Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact. In situations where exposure limits may be exceeded, a NIOSH- approved respirator is advised. DOT/IATA/IMDG: Not restricted. EPA - SARA Title III/CERCLA: This product is regulated under Sections 311/312. This product contains no chemicals which are regulated under Section 313 or regulated under Section 304/CERCLA. VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations. Stable under normal use and storage conditions. VIII Fire and Explosion Data IX Physical Data Flash Point: >200°F (closed cup) Fire Extinguishing Agents: Dry chemical, carbon dioxide (CO2), foam, or water spray. ~7.0 Specific gravity 1.0 Solubility in water Soluble ©1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 10/07 Page 409 of 1069 Page 409 of 1069 Page 409 of 1069 Page 409 of 1069 ---PAGE BREAK--- Revision Date: 14-Aug-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: GS NEUTRAL DISINFECTANT CLEANER Product Number: 3502 , 3513 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Acute Toxicity - Oral: Category 4 Skin Corrosion/Irritation: Category 1 Serious Eye Damage/Eye Irritation: Category 1 GHS Label Elements Signal Word: Danger Hazard Statements: Harmful if swallowed. Causes severe skin burns and serious eye damage. Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product Do not breathe mist, vapors or spray. Wear protective gloves. Wear eye / face protection. Wear protective clothing. Response: IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. -Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. -Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. -Ingestion: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Store locked up. Page 1 / 5 Disposal: Dispose of contents and container in accordance with local, state and federal regulations. Symbols: Page 410 of 1069 Page 410 of 1069 Page 410 of 1069 Page 410 of 1069 ---PAGE BREAK--- 3502 - GS NEUTRAL DISINFECTANT CLEANER Revision Date: 14-Aug-2015 Hazards Not Otherwise Classified: Not Applicable Other Information: • Corrosive. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. • NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 0.134% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 dialkyl dimethyl ammonium chloride 68424-95-3 1-5 alkyl dimethyl benzyl ammonium chloride 68424-85-1 1-5 ethanol 64-17-5 1-5 tetrasodium ethylenediaminetetraacetate 64-02-8 0.1-1 alcohol ethoxylate 68439-46-3 0.1-1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Skin Contact: Take off immediately all contaminated clothing and shoes. Rinse with water or shower for at least 15 minutes. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Wash contaminated clothing before reuse. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Ingestion: Rinse mouth. Do NOT induce vomiting. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Never give anything by mouth to an unconscious person. Note to Physicians: NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). Page 2 / 5 7. HANDLING AND STORAGE Page 411 of 1069 Page 411 of 1069 Page 411 of 1069 Page 411 of 1069 ---PAGE BREAK--- 3502 - GS NEUTRAL DISINFECTANT CLEANER Revision Date: 14-Aug-2015 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Eye wash stations and shower facilities should be readily accessible in areas where the product is handled. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Clear Odor: Mild pH: 6.0-7.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.0 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 412 of 1069 Page 412 of 1069 Page 412 of 1069 Page 412 of 1069 ---PAGE BREAK--- 3502 - GS NEUTRAL DISINFECTANT CLEANER Revision Date: 14-Aug-2015 Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and tissue damage. Eye contact may cause permanent damage. -Skin Contact: Pain, redness, blistering and possible chemical burn. -Inhalation: Nasal discomfort and coughing. -Ingestion: Damage or chemical burns to mouth, throat and stomach. Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 1837 mg/kg ATEmix (dermal): 5528 mg/kg ATEmix (inhalation-dust/mist): 23 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available alkyl dimethyl benzyl ammonium chloride 68424-85-1 = 426 mg/kg ( Rat ) Not Available Not Available ethanol 64-17-5 = 7060 mg/kg ( Rat ) Not Available = 124.7 mg/L ( Rat ) 4 h tetrasodium ethylenediaminetetraacetate 64-02-8 = 10 g/kg ( Rat ) Not Available Not Available alcohol ethoxylate 68439-46-3 = 1378 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea ethanol 64-17-5 Not Available 12.0 - 16.0: 96 h mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through Not Available 9268 - 14221: 48 h Daphnia magna mg/L LC50 10800: 24 h Daphnia magna mg/L EC50 2: 48 h Daphnia magna mg/L EC50 Static tetrasodium ethylenediaminetetraacetate 64-02-8 1.01: 72 h Desmodesmus subspicatus mg/L EC50 41: 96 h Lepomis macrochirus mg/L LC50 static 59.8: 96 h Pimephales promelas mg/L LC50 static Not Available 610: 24 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Page 4 / 5 Other Adverse Effects: No information available. Page 413 of 1069 Page 413 of 1069 Page 413 of 1069 Page 413 of 1069 ---PAGE BREAK--- 3502 - GS NEUTRAL DISINFECTANT CLEANER Revision Date: 14-Aug-2015 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non-Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. IMDG: Not Regulated Proper Shipping Name: Non-Hazardous Product 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product is not subject to warning requirements under California Proposition 65. EPA Pesticide Registration Number: 1839-169-5741 EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Danger. Keep out of reach of children. Corrosive. Causes irreversible eye damage and skin burns. Do not get in eyes, on skin or on clothing. May be fatal if absorbed through the skin. Harmful if swallowed. Wear goggles or face shield, rubber gloves, and protective clothing. Remove contaminated clothing and wash before reuse. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. 16. OTHER INFORMATION Revision Date: 14-Aug-2015 Reasons for Revision: Section 11 Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 3 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 3 Flammability: 0 Physical Hazards: 0 Page 414 of 1069 Page 414 of 1069 Page 414 of 1069 Page 414 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET GUM REMOVER 1. PRODUCT AND COMPANY IDENTIFICATION Product name: GUM REMOVER MSDS 126330001 Product Code: 05257, 04198 Recommended use: Carpet Care. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat 1,1,1,2-tetrafluoroethane 811-97-2 90 - 100% Not available Not available Not available Pentane 109-66-0 10 - 20% Not available =3000 mg/kg =364 g/m3 (4 h) 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Skin contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. Unusual hazards: None known Specific methods: Aerosol Product - Containers may rocket or expode in heat of fire. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available HMIS EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. NFPA Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Version Number: 1 Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] GUM REMOVER Preparation date: 2008-03-07 1 of 3 Personal protective equipment 1 Fire Hazard None / Aucune / Ninguno 0 1 Health 0 Reactivity 0 0 Page 415 of 1069 Page 415 of 1069 Page 415 of 1069 Page 415 of 1069 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. Do not spray towards face . CONTENTS UNDER PRESSURE. Do not puncture or incinerate. Use only in well- ventilated areas. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Do not pierce or burn, even after use. Do not pierce or burn, even after use . KEEP OUT OF REACH OF CHILDREN. NFPA 30B Level 1 Aerosol . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Pentane 109-66-0 600 ppm (TWA) 1000 ppm (TWA) 2950 mg/m3 (TWA) 760 ppm (STEL) 2250 mg/m3 (STEL) 600 ppm (TWA) 1800 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: direct sunlight . Conditions to avoid: Strong sunlight for prolonged periods.. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known Not determined Dilution pH: Specific gravity: 1.11 Not applicable Melting point/range: Not determined Bulk density: Density: 9.30 lbs/gal Appearance: Decomposition temperature: Not determined Aerosol VOC: 10% * No information available Autoignition temperature: No information available Vapor density: Flash point: >200°F >93.3°C No information available Partition coefficient (n-octanol/water): No information available Aerosol Solubility: Insoluble Color: Solubility in other solvents: No information available Clear Colorless Viscosity: No information available pH: Elemental Phosphorus: 0 %P Evaporation Rate No information available Not applicable Odor: Hydrocarbon GUM REMOVER 2 of 3 Physical State: Boiling point/range: Page 416 of 1069 Page 416 of 1069 Page 416 of 1069 Page 416 of 1069 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), New Zealand (NZIoC), China (IECSC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Pentane 109-66-0 X X X X 1,1,1,2-tetrafluoroethane 811-97-2 - X - - CERCLA/ SARA SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: X Canada WHMIS hazard class: A Compressed gases. 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 GUM REMOVER Page 417 of 1069 Page 417 of 1069 Page 417 of 1069 Page 417 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Gunk Glass Cleaner - Streak Free Product identifier Other means of identification GC1 SDS number GC1 Part No. 3402.90.5030 Tariff code Glass Cleaner Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service: (704) 821-7643 Technical: (704) 684-1811 Emergency phone number Emergency Telephone: (303) 623-5716 Emergency Contact: ([PHONE REDACTED]) E-mail United States Indian Trail, NC 28079 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Category 4 Acute toxicity, inhalation Health hazards Category 3 Hazardous to the aquatic environment, acute hazard Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Harmful if inhaled. Harmful to aquatic life. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information 6.07% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures 1 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 418 of 1069 Page 418 of 1069 Page 418 of 1069 Page 418 of 1069 ---PAGE BREAK--- CAS number % Common name and synonyms Chemical name 75-28-5 Isobutane 3 - < 5 67-63-0 Isopropyl Alcohol 1 - < 3 1336-21-6 AMMONIUM HYDROXIDE < 1 Other components below reportable levels 90 - 100 7632-00-0 SODIUM NITRITE < 0.2 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists. Skin contact Rinse with water. Get medical attention if irritation develops and persists. Eye contact In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Ingestion Direct contact with eyes may cause temporary irritation. Most important acute and delayed Provide general supportive measures and treat Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Specific methods Extremely flammable aerosol. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors and spray mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Refer to attached safety data sheets and/or instructions for use. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Environmental precautions 2 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 419 of 1069 Page 419 of 1069 Page 419 of 1069 Page 419 of 1069 ---PAGE BREAK--- 7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid inhalation of vapors and spray mists. Avoid prolonged exposure. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 35 mg/m3 AMMONIUM HYDROXIDE (CAS 1336-21-6) 50 ppm PEL 980 mg/m3 Isopropyl Alcohol (CAS 67-63-0) 400 ppm US. ACGIH Threshold Limit Values Value Components Type STEL 35 ppm AMMONIUM HYDROXIDE (CAS 1336-21-6) TWA 25 ppm STEL 1000 ppm Isobutane (CAS 75-28-5) STEL 400 ppm Isopropyl Alcohol (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type STEL 27 mg/m3 AMMONIUM HYDROXIDE (CAS 1336-21-6) 35 ppm TWA 18 mg/m3 25 ppm TWA 1900 mg/m3 Isobutane (CAS 75-28-5) 800 ppm STEL 1225 mg/m3 Isopropyl Alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 40 mg/l Acetone Urine * Isopropyl Alcohol (CAS 67-63-0) * - For sampling details, please see the source document. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls 3 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 420 of 1069 Page 420 of 1069 Page 420 of 1069 Page 420 of 1069 ---PAGE BREAK--- Individual protection measures, such as personal protective equipment Chemical respirator with organic vapor cartridge and full facepiece. Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Wear suitable protective clothing. Other Chemical respirator with organic vapor cartridge and full facepiece. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Clear. Liquid. Appearance Liquid. Physical state Aerosol. Form Colorless Color Ammonia Odor Odor threshold Not available. pH 10.5 - 11.5 Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point None Evaporation rate Not available. Not applicable. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 0.00001 hPa estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Density 8.17 lbs/gal estimated Not explosive. Explosive properties Flame extension No Extension Flammability (flash back) No Heat of combustion (NFPA 30B) 2.09 kJ/g estimated Not oxidizing. Oxidizing properties Percent volatile 94.15 % estimated 4 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 421 of 1069 Page 421 of 1069 Page 421 of 1069 Page 421 of 1069 ---PAGE BREAK--- Specific gravity 0.98 - 1 VOC (Weight 5.94 % w/w 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Contact with incompatible materials. Conditions to avoid Strong oxidizing agents. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Harmful if inhaled. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Harmful if inhaled. Test Results Components Species AMMONIUM HYDROXIDE (CAS 1336-21-6) Oral Acute LD50 Rat 350 mg/kg Isobutane (CAS 75-28-5) Inhalation Acute LC50 Mouse 52 mg/l, 1 Hours Isopropyl Alcohol (CAS 67-63-0) Dermal Acute LD50 Rabbit 12800 mg/kg Oral LD50 Dog 4797 mg/kg Mouse 3600 mg/kg Rabbit 5.03 g/kg Rat 4.7 g/kg SODIUM NITRITE (CAS 7632-00-0) Inhalation Acute LC50 Rat 5.5 mg/l, 4 Hours Oral LD50 Mouse 175 mg/kg Rabbit 186 mg/kg * Estimates for product may be based on additional component data not shown. Rat 85 mg/kg 5 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 422 of 1069 Page 422 of 1069 Page 422 of 1069 Page 422 of 1069 ---PAGE BREAK--- Prolonged skin contact may cause temporary irritation. Skin corrosion/irritation Direct contact with eyes may cause temporary irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Harmful to aquatic life. Ecotoxicity Components Test Results Species AMMONIUM HYDROXIDE (CAS 1336-21-6) Aquatic LC50 Fish 15 mg/l, 96 hours Western mosquitofish (Gambusia affinis) Isopropyl Alcohol (CAS 67-63-0) Aquatic LC50 Fish > 1400 mg/l, 96 hours Bluegill (Lepomis macrochirus) SODIUM NITRITE (CAS 7632-00-0) Aquatic EC50 Crustacea 16.14 - 26.61 mg/l, 48 hours Greasyback shrimp (Metapenaeus ensis) * Estimates for product may be based on additional component data not shown. LC50 Fish 0.15 - 0.25 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Isobutane 2.76 Isopropyl Alcohol 0.05 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code 6 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 423 of 1069 Page 423 of 1069 Page 423 of 1069 Page 423 of 1069 ---PAGE BREAK--- Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT Not available. UN number Consumer Commodity UN proper shipping name ORM-D Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 19, T50 Special provisions 306 Packaging exceptions 304 Packaging non bulk 314, 315 Packaging bulk IATA Not regulated as dangerous goods. IMDG UN1950 UN number AEROSOLS UN proper shipping name 2 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IMDG 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) SODIUM NITRITE (CAS 7632-00-0) 1.0 % One-Time Export Notification only. CERCLA Hazardous Substance List (40 CFR 302.4) AMMONIUM HYDROXIDE (CAS 1336-21-6) Listed. Isobutane (CAS 75-28-5) Listed. Isopropyl Alcohol (CAS 67-63-0) Listed. SODIUM NITRITE (CAS 7632-00-0) Listed. SARA 304 Emergency release notification Not regulated. 7 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 424 of 1069 Page 424 of 1069 Page 424 of 1069 Page 424 of 1069 ---PAGE BREAK--- OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Isopropyl Alcohol 67-63-0 1 - < 3 AMMONIUM HYDROXIDE 1336-21-6 < 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Isobutane (CAS 75-28-5) Not regulated. Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) US. Massachusetts RTK - Substance List AMMONIUM HYDROXIDE (CAS 1336-21-6) Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) SODIUM NITRITE (CAS 7632-00-0) US. New Jersey Worker and Community Right-to-Know Act AMMONIUM HYDROXIDE (CAS 1336-21-6) Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) SODIUM NITRITE (CAS 7632-00-0) US. Worker and Community Right-to-Know Law AMMONIUM HYDROXIDE (CAS 1336-21-6) Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) SODIUM NITRITE (CAS 7632-00-0) US. Rhode Island RTK AMMONIUM HYDROXIDE (CAS 1336-21-6) Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) SODIUM NITRITE (CAS 7632-00-0) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) 8 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 425 of 1069 Page 425 of 1069 Page 425 of 1069 Page 425 of 1069 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 05-08-2015 Issue date 08-10-2015 Revision date Version # 02 Health: 2 Flammability: 4 Physical hazard: 0 HMIS® ratings Health: 2 Flammability: 4 Instability: 0 NFPA ratings NFPA ratings 0 2 4 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer Physical & Chemical Properties: Multiple Properties Physical and chemical properties: Odor Stability and reactivity: Possibility of hazardous reactions Transport Information: Material Transportation Information GHS: Classification Revision Information 9 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 426 of 1069 Page 426 of 1069 Page 426 of 1069 Page 426 of 1069 ---PAGE BREAK--- Product MATERIAL SAFETY DATA SHEET CHEMTREC 24 Hour Emergency Phone Number (800) 424-9300 The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Section 1 Chemical Product and Company Information Section 5 Fire Fighting Measures Section 6 Accidental Release Measures Section 7 Handling & Storage Section 8 Exposure Controls / Personal Protection Section 12 Ecological Information Section 13 Disposal Considerations Section 14 Transport Information Section 16 Additional Information NFPA 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Synonyms Section 15 Regulatory Information Section 9 Physical & Chemical Properties Section 10 Stability & Reactivity Section 11 Toxicological Information Section 4 First Aid Measures Emergency Overview Section 2 Hazards Identification HMIS * 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Health Fire Reactivity Contact Section 2 Composition / Information on Ingredients Chemical Name CAS # % TLV Units Section 3 Composition / Information on Ingredients OX0008 September 10, 2013 James A. GENERAL STORAGE CODE GREEN HOUSEHOLD OIL Household oil None assigned. ~ 90% TWA: 5 mg/m3 as oil mist Proprietary additive (mixture) > 10% (ACGIH 2001) Effects of overexposure: Prolonged or repeated skin contact may cause dermatitis. Contact with eyes may cause irritation. Ingestion of product has a low order of acute oral toxicity, but minute amounts aspirated into the lungs during ingestion or vomiting may cause mild to severe pulomonary injury and possibly death. Exercise ap- propriate procedures to minimize potential hazards. Data not yet available. These disposal guidelines are intended for the disposal of catalog-size quantities only. Federal regulations may ap- ply to empty container. State and/or local regulations may be different. Dispose of in accordance with all local, state and federal regulations or contract with a licensed chemical disposal agency. UN/NA number: N/A Shipping name: Not Regulated. Hazard class: N/A Packing group: N/A Exceptions: N/A INGESTION: Call physician or Poison Control Center immediately. Induce vomiting only if advised by appropriate medical personnel. Never give anything by mouth to an unconscious person. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. EYE CONTACT: Check for and remove contact lenses. Flush thoroughly with water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get immediate medical attention. SKIN CONTACT: Remove contaminated clothing. Flush thoroughly with mild soap and water. If irritation occurs, get medical attention. Extinguishing Media: Dry chemical, carbon dioxide, foam. Water or foam may cause frothing. Flash Point: 380°F (>190°C) (COC) Autoignition temperature: > 500°F (260°C) Explosion Limits: Lower: N/A Upper: N/A MSDS No.: Revision Date: Approved by: Petroleum Lubricating Oil Data not yet available. Chemical stability: Stable Hazardous polymerization: Will not occur. Conditions to avoid: Avoid excessive temperature and heat. Incompatibilities with other materials: Strong oxidizers such as hydrogen peroxide, bromine, and chromic acid. Hazardous decomposition products: Carbon oxides, phosphorous oxides and sulfur oxides. MSDS No.: OX0008 Read label on container before using. Do not wear contact lenses when working with chemicals. Keep container closed. For laboratory use only. Not for drug, food or household use. Keep out of reach of children. Handling: Use with adequate ventilation. Avoid contact with eyes, skin and clothing. Avoid ingestion. Do not inhale vapors, spray or mists. Wash thoroughly after handling. Remove and wash clothing before reuse. Storage: Store in a cool, well-ventilated area away from incompatible substances. CAUTION! Avoid contact with skin, eyes and clothing. Do not ingest. Avoid inhalation of oil mist. Store in a cool place. Wash thoroughly after handling. Target organs: None known. 1 1 0 1 General information: In fire conditions, wear a NIOSH/MSHA-approved self-contained breathing apparatus and full protective gear. Fire or excessive heat may produce hazardous decomposition products to be produced as dust or fume. Use water spray to keep fire-exposed containers cool. Engineering controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower and fire extinguishing material. Personnel should wear safety glasses, goggles, or faceshield, lab coat or apron, appropriate protective gloves. Use adequate ventilation to keep airborne concentrations low. Respiratory protection: None should be needed in normal laboratory handling at room temperatures. If misty conditions prevail, work in fume hood or wear a NIOSH/MSHA-approved respirator. Physical state: Liquid. Appearance: Dark amber. Odor: Bland petroleum odor. pH: N/A Vapor pressure (mm Hg): 0 @ 20°C Vapor Density (Air = N/A Evaporation rate (Butyl acetate = N/A Viscosity: N/A Boiling point: 625°F (330°C) Freezing / Melting point: 10°F -12°C) Decomposition temperature: N/A Solubility: 0% @ 20°C Specific gravity (H2O = .86 - .89 Percent volatile N/A Molecular formula: Mixture. Molecular weight: Mixture. 1 0 1 Evacuate personnel to safe area. Use proper personal protective equipment as indicated in Section 8. Provide adequate ventilation. Absorb with inert dry material, sweep or vacuum up and place in a suitable container for proper disposal. Wash spill area with soap and water. Avoid runoff into storm sewers and ditches which lead to waterways. Aldon Corporation 221 Rochester Street Avon, NY 14414 (585) 226-6177 Page 427 of 1069 Page 427 of 1069 Page 427 of 1069 Page 427 of 1069 ---PAGE BREAK--- Page 428 of 1069 Page 428 of 1069 Page 428 of 1069 Page 428 of 1069 ---PAGE BREAK--- Page 429 of 1069 Page 429 of 1069 Page 429 of 1069 Page 429 of 1069 ---PAGE BREAK--- 7/18/2015 ISOPROPYL RUBBING ALCOHOL 70% MSDS http://sds.hvchemical.com/isal­70.htm 1/5 ISOPROPYL RUBBING ALCOHOL 70% 1. Product Identification Synonyms: Isopropyl alcohol; sec­propyl alcohol; isopropanol; sec­propanol; CAS No.: 67­63­0 Molecular Weight: 60.10 Chemical Formula: (CH3)2 CHOH 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Isopropyl Alcohol 67­63­0 70% Yes Water 7732­18­5 30% No 3. Hazards Identification Emergency Overview WARNING! FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE IRRITATION TO SKIN. Potential Health Effects Inhalation: Inhalation of vapors irritates the respiratory tract. Exposure to high concentrations has a narcotic effect, producing of dizziness, drowsiness, headache, staggering, unconsciousness and possibly death. Ingestion: Can cause drowsiness, unconsciousness, and death. Gastrointestinal pain, cramps, nausea, vomiting, and diarrhea may also result. The single lethal dose for a human adult = about 250 mls (8 ounces). Skin Contact: May cause irritation with redness and pain. May be absorbed through the skin with possible systemic effects. Eye Contact: Vapors cause eye irritation. Splashes cause severe irritation, possible corneal burns and eye damage. Chronic Exposure: Chronic exposure may cause skin effects. Aggravation of Pre­existing Conditions: Persons with pre­existing skin disorders or impaired liver, kidney, or pulmonary function may be more susceptible to the effects of this agent. 4. ===First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Call a physician if irritation develops. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Page 430 of 1069 Page 430 of 1069 Page 430 of 1069 Page 430 of 1069 ---PAGE BREAK--- 7/18/2015 ISOPROPYL RUBBING ALCOHOL 70% MSDS http://sds.hvchemical.com/isal­70.htm 2/5 Fire: Flash point: 12C (54F) CC Autoignition temperature: 399C (750F) Flammable limits in air % by volume: lel: 2.0; uel: 12.7 Listed fire data is for Pure Isopropyl Alcohol. Explosion: Above flash point, vapor­air mixtures are explosive within flammable limits noted above. Contact with strong oxidizers may cause fire or explosion. Vapors can flow along surfaces to distant ignition source and flash back. Sensitive to static discharge. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Water spray may be used to keep fire exposed containers cool, dilute spills to nonflammable mixtures, protect personnel attempting to stop leak and disperse vapors. Special Information: In the event of a fire, wear full protective clothing and NIOSH­approved self­contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Use non­sparking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures. 7. Handling and Storage Protect against physical damage. Store in a cool, dry well­ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non­sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. Small quantities of peroxides can form on prolonged storage. Exposure to light and/or air significantly increases the rate of peroxide formation. If evaporated to a residue, the mixture of peroxides and isopropanol may explode when exposed to heat or shock. 8. Exposure Controls /Personal Protection Airborne Exposure Limits: For Isopropyl Alcohol (2­Propanol): ­OSHA Permissible Exposure Limit (PEL): 400 ppm (TWA) ­ACGIH Threshold Limit Value (TLV): 200 ppm (TWA), 400 ppm (STEL), A4 ­ not classifiable as a human carcinogen. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with organic vapor cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full­facepiece positive­pressure, air­supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen­deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Neoprene and nitrile rubber are recommended materials. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick­drench facilities in work area. 9. Physical/Chemical Properties Appearance: Clear, colorless liquid. Odor: Rubbing alcohol. Solubility: Miscible in water. Specific Gravity: 0.8691 ­ 0.8771 @ 20C/4C Page 431 of 1069 Page 431 of 1069 Page 431 of 1069 Page 431 of 1069 ---PAGE BREAK--- 7/18/2015 ISOPROPYL RUBBING ALCOHOL 70% MSDS http://sds.hvchemical.com/isal­70.htm 3/5 pH: No information found. % Volatiles by volume @ 21C (70F): 100 Boiling Point: 82C (180F) Melting Point: ­89C (­128F) Vapor Density (Air=1): 2.1 Vapor Pressure (mm Hg): 44 @ 25C (77F) Evaporation Rate (BuAc=1): 2.83 10. Stability and Reactivity Data Stability: Stable under ordinary conditions of use and storage. Heat and sunlight can contribute to instability. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Heat, flame, strong oxidizers, acetaldehyde, acids, chlorine, ethylene oxide, hydrogen­palladium combination, hydrogen peroxide­sulfuric acid combination, potassium tert­butoxide, hypochlorous acid, isocyanates, nitroform, phosgene, aluminum, oleum and perchloric acid. Conditions to Avoid: Heat, flames, ignition sources and incompatibles. 11. Toxicological Information Oral rat LD50: 5045 mg/kg; skin rabbit LD50: 12.8 gm/kg; inhalation rat LC50: 16,000 ppm/8­hour; investigated as a tumorigen, mutagen, reproductive effector. ‐‐‐‐‐‐‐‐\Cancer ‐‐‐NTP Carcinogen‐‐‐ Ingredient Known Anticipated IARC Category Isopropyl Alcohol (67‐63‐0) No No 3 Water (7732‐18‐5) No No None 12. Ecological Information Environmental Fate: When released into the soil, this material is expected to quickly evaporate. When released into the soil, this material may leach into groundwater. When released into the soil, this material may biodegrade to a moderate extent. When released to water, this material is expected to quickly evaporate. When released into the water, this material is expected to have a half­life between 1 and 10 days. When released into water, this material may biodegrade to a moderate extent. This material is not expected to significantly bioaccumulate. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to have a half­life between 1 and 10 days. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. Environmental Toxicity: The LC50/96­hour values for fish are over 100 mg/l. This material is not expected to be toxic to aquatic life. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. MSDS Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: ISOPROPANOL Hazard Class: 3 UN/NA: UN1219 Page 432 of 1069 Page 432 of 1069 Page 432 of 1069 Page 432 of 1069 ---PAGE BREAK--- 7/18/2015 ISOPROPYL RUBBING ALCOHOL 70% MSDS http://sds.hvchemical.com/isal­70.htm 4/5 Packing Group: II Information reported for product/size: 355LB International (Water, I.M.O.) Proper Shipping Name: ISOPROPANOL Hazard Class: 3 UN/NA: UN1219 Packing Group: II Information reported for product/size: 355LB 15. Regulatory Information ‐‐‐‐‐‐‐‐\Chemical Inventory Status ‐ Part Ingredient TSCA EC Japan Australia Isopropyl Alcohol (67‐63‐0) Yes Yes Yes Yes Water (7732‐18‐5) Yes Yes Yes Yes ‐‐‐‐‐‐‐‐\Chemical Inventory Status ‐ Part ‐‐Canada‐‐ Ingredient Korea DSL NDSL Phil. Isopropyl Alcohol (67‐63‐0) Yes Yes No Yes Water (7732‐18‐5) Yes Yes No Yes ‐‐‐‐‐‐‐‐\Federal, State & International Regulations ‐ Part ‐SARA 302‐ ‐‐‐‐‐‐SARA Ingredient RQ TPQ List Chemical Catg. Isopropyl Alcohol (67‐63‐0) No No Yes No Water (7732‐18‐5) No No No No ‐‐‐‐‐‐‐‐\Federal, State & International Regulations ‐ Part ‐RCRA‐ ‐TSCA‐ Ingredient CERCLA 261.33 8(d) Isopropyl Alcohol (67‐63‐0) No No No Water (7732‐18‐5) No No No Chemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: No (Mixture / Liquid) Australian Hazchem Code: 2[S]2 Poison Schedule: None allocated. WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. 16. Other Information Label Hazard Warning: WARNING! FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE IRRITATION TO SKIN. Label Precautions: Keep away from heat, sparks and flame. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. Label First Aid: If swallowed, give large amounts of water to drink. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent. Page 433 of 1069 Page 433 of 1069 Page 433 of 1069 Page 433 of 1069 ---PAGE BREAK--- 7/18/2015 ISOPROPYL RUBBING ALCOHOL 70% MSDS http://sds.hvchemical.com/isal­70.htm 5/5 High Valley Products, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. HIGH VALLEY PRODUCTS, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, HIGH VALLEY PRODUCTS, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. 6/14 Page 434 of 1069 Page 434 of 1069 Page 434 of 1069 Page 434 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 1 / 9 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : KEYSTONE GLASS CLEANER Other means of identification : Not applicable. Recommended use : Glass Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information : 3.13 % - 6.25 % Company : Ecolab Co. 5105 Tomken Road Mississauga, Ontario Canada L4W 2X5 1-[PHONE REDACTED] Emergency health information : 1-[PHONE REDACTED] (US/Canada), 1-[PHONE REDACTED] (outside US) Issuing date : 08/10/2015 Section: 2. HAZARDS IDENTIFICATION GHS Classification Product AS SOLD Eye irritation : Category 2B Product AT USE DILUTION Not a hazardous substance or mixture. GHS Label element Product AS SOLD Signal Word : Warning Hazard Statements : Causes eye irritation. Precautionary Statements : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Product AT USE DILUTION Precautionary Statements : Prevention: Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. Product AS SOLD Other hazards : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Page 435 of 1069 Page 435 of 1069 Page 435 of 1069 Page 435 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 2 / 9 Product AS SOLD Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: d-glucopyranose, oligomeric, decyl octyl glycosides 68515-73-1 5 - 10 Product AT USE DILUTION No hazardous ingredients Section: 4. FIRST AID MEASURES Product AS SOLD In case of eye contact : Rinse with plenty of water. In case of skin contact : Rinse with plenty of water. If swallowed : Rinse mouth. Get medical attention if occur. If inhaled : Get medical attention if occur. Protection of first-aiders : No special precautions are necessary for first aid responders. Notes to physician : Treat Most important and effects, both acute and delayed : See Section 11 for more detailed information on health effects and Product AT USE DILUTION In case of eye contact : Rinse with plenty of water. In case of skin contact : Rinse with plenty of water. If swallowed : Rinse mouth. Get medical attention if occur. If inhaled : Get medical attention if occur. Section: 5. FIREFIGHTING MEASURES Product AS SOLD Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during firefighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Special protective equipment : Use personal protective equipment. Page 436 of 1069 Page 436 of 1069 Page 436 of 1069 Page 436 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 3 / 9 for firefighters Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Risk of explosion. : Not available. Section: 6. ACCIDENTAL RELEASE MEASURES Product AS SOLD Personal precautions, protective equipment and emergency procedures : Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Product AT USE DILUTION Personal precautions, protective equipment and emergency procedures : Refer to protective measures listed in sections 7 and 8. Environmental precautions : No special environmental precautions required. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Section: 7. HANDLING AND STORAGE Product AS SOLD Advice on safe handling : Wash hands thoroughly after handling. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 5 °C to 50 °C Product AT USE DILUTION Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Product AS SOLD Components with workplace control parameters Contains no substances with occupational exposure limit values. Page 437 of 1069 Page 437 of 1069 Page 437 of 1069 Page 437 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 4 / 9 Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : No special protective equipment required. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Product AT USE DILUTION Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : No special protective equipment required. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Product AS SOLD Product AT USE DILUTION Appearance : liquid liquid Colour : blue blue Odour : Perfumes, fragrances Perfumes, fragrances pH : 10.9, 100 % 7.2 - 7.9 Flash point : Not applicable., Does not sustain combustion. Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling range : 100 °C Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 0.99 - 1.05 Water solubility : soluble Page 438 of 1069 Page 438 of 1069 Page 438 of 1069 Page 438 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 5 / 9 Solubility in other solvents : no data available Partition coefficient: n- octanol/water : no data available Auto-ignition temperature : no data available Thermal decomposition : no data available Viscosity, kinematic : no data available Explosive properties : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Molecular weight : no data available VOC : no data available Section: 10. STABILITY AND REACTIVITY Product AS SOLD Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : None known. Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Product AS SOLD Eyes : Causes eye irritation. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Product AT USE DILUTION Eyes : Health injuries are not known or expected under normal use. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Page 439 of 1069 Page 439 of 1069 Page 439 of 1069 Page 439 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 6 / 9 Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Product AS SOLD Eye contact : Redness, Irritation Skin contact : No known or expected. Ingestion : No known or expected. Inhalation : No known or expected. Product AT USE DILUTION Eye contact : No known or expected. Skin contact : No known or expected. Ingestion : No known or expected. Inhalation : No known or expected. Toxicity Product AS SOLD Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye irritation : Mild eye irritation Respiratory or skin sensitization : no data available Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Components Acute dermal toxicity : d-glucopyranose, oligomeric, decyl octyl glycosides LD50 rabbit: > 2,000 mg/kg Section: 12. ECOLOGICAL INFORMATION Product AS SOLD Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects. Page 440 of 1069 Page 440 of 1069 Page 440 of 1069 Page 440 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 7 / 9 Product Toxicity to fish : no data available Toxicity to daphnia and other aquatic invertebrates : no data available Toxicity to algae : no data available Components Toxicity to algae : d-glucopyranose, oligomeric, decyl octyl glycosides 72 h EC50: 18 mg/l Persistence and degradability Taking into consideration the properties of several components, the product is estimated to be biodegradable according to OECD classification. Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Product AS SOLD Disposal methods : Diluted product can be flushed to sanitary sewer. Disposal considerations : Dispose of in accordance with local, state, and federal regulations. Product AT USE DILUTION Disposal methods : Diluted product can be flushed to sanitary sewer. Disposal considerations : Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION Product AS SOLD The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (TDG) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Product AT USE DILUTION Not intended for transport. Section: 15. REGULATORY INFORMATION Page 441 of 1069 Page 441 of 1069 Page 441 of 1069 Page 441 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 8 / 9 This product has been classified according to the hazard criteria of the HPR and the SDS contains all of the information required by the HPR. The components of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : not determined United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : On the inventory, or in compliance with the inventory Japan. ENCS - Existing and New Chemical Substances Inventory : On the inventory, or in compliance with the inventory Japan. ISHL - Inventory of Chemical Substances (METI) : not determined Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory Philippines Inventory of Chemicals and Chemical Substances (PICCS) : On the inventory, or in compliance with the inventory China Inventory of Existing Chemical Substances : On the inventory, or in compliance with the inventory Section: 16. OTHER INFORMATION Product AS SOLD NFPA: HMIS III: Product AT USE DILUTION Flammability Health Instability 1 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 1 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 442 of 1069 Page 442 of 1069 Page 442 of 1069 Page 442 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET KEYSTONE GLASS CLEANER 914266-04 9 / 9 NFPA: HMIS III: Issuing date : 08/10/2015 version : 1.1 Prepared by : Regulatory Affairs 1-[PHONE REDACTED] REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 0 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 443 of 1069 Page 443 of 1069 Page 443 of 1069 Page 443 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 1 of 6 Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Directives 1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): KRUD KUTTER® Driveway Cleaner & Degreaser SYNONYMS: Not Applicable CHEMICAL SHIPPING NAME/CLASS: NON-REGULATED MATERIAL U.N. NUMBER: NA MANUFACTURER'S NAME: Krud Kutter,Inc.(Formerly Supreme Chemicals of Georgia, Inc.) ADDRESS: 1535 Oak Industrial Lane, Suite B, Cumming, GA 30041 USA EMERGENCY PHONE: (800) 424-9300 (CHEMTREC - US) (703) 527-3887 (Outside USA) BUSINESS PHONE: (800) 466-7126 DATE OF PREPARATION: December 11, 2013 DATE OF REVISION: December 11, 2013 2. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: Warning! Product Description: This product is a clear liquid with a mild odor. Health Hazards: May cause eye and/or skin irritation. The product is expected to be a low inhalation hazard. Flammability Hazards: Non-Flammable Reactivity Hazards: This product is not reactive. Environmental Hazards: Release of this product is not expected to cause significant adverse effects to the aquatic environment. Emergency Recommendations: Emergency responders must have personal protective equipment and fire protection appropriate for the situation to which they are responding. EU LABELING AND CLASSIFICATION: This product meets the definition of a hazardous substance or preparation according to EU Regulations (EC) No 1272/2008. INDEX NUMBER: EC# 229-912-9Annex I – Index# 014-010-00-8 GHS CLASSIFICATIONS: Skin Corrosive Category 2 SIGNAL WORD : Warning! HAZARD STATEMENT: H315 Causes skin irritation PREVENTION STATEMENT : P264 Wash hands thoroughly after handling P271 Use in well ventilated areas P280 Wear protective gloves/protective clothing/eye protection/ face protection HEALTH HAZARD FLAMMABILITY HAZARD REACTIVITY PROTECTIVE EQUIPMENT 1 EYES RESPIRATORY HANDS BODY (BLUE) (RED) For Routine Industrial Use and Handling Applications SEE SECTION 8 HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (YELLOW) 0 0 SEE SECTION 8 Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard HEALTH FLAMMABILITY REACTIVITY OTHER 1 0 0 Page 444 of 1069 Page 444 of 1069 Page 444 of 1069 Page 444 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 2 of 6 RESPONSE STATEMENT: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 IF IN EYES : Rinse cautionously with water for several minutes P333 + P313 IF skin irritation or rash occurs : Get medical advice/attention HEALTH EFFECTS OR RISKS FROM EXPOSURE: ACUTE: INHALATION: Mist or vapor not expected to cause irritation to the respiratory tract. SKIN: Prolonged contact may cause skin irritation. Exposure can cause redness, itching and inflammation. EYES: Contact causes eye irritation. Exposure may cause tearing, redness and discomfort. INGESTION: Not expected to be an ingestion hazard for intended use. Exposure may cause nausea, vomiting, diarrhea and other systemic effects. CHRONIC: None known 3. COMPOSITION AND INFORMATION ON INGREDIENTS Hazardous Ingredients: WT% CAS# EINECS # Hazard Classification Risk Phrases Sodium Metasilicate Pentahydrate 6834-92-0 229-912-9 Corrosive R34 Alcohol Ethoxylate Proprietary Proprietary [Xi] Irritant R36/38 Balance of other ingredients is less than 1% in concentration (or 0.1% for carcinogens, reproductive toxins, or respiratory sensitizers). None NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250: 2000. 4. FIRST-AID MEASURES SKIN EXPOSURE: If this product contaminates the skin, wash with soap and water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. The contaminated individual should seek medical attention if any adverse effect occurs. EYE EXPOSURE: If this product enter the eyes, open contaminated individual's eyes while under gently running water. Use sufficient force to open eyelids. Remove contact lenses if worn. Have contaminated individual "roll" eyes. Minimum flushing is for 15 minutes. Contaminated individual must seek medical attention if irritation develops or persists or if visual changes occur. INHALATION: If vapors/mists generated by this product are inhaled, or individual has difficulty breathing remove contaminated individual to fresh air. If necessary, use artificial respiration to support vital functions. SEEK IMMEDIATE MEDICAL ATTENTION. INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT induce vomiting; if vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow. SEEK IMMEDIATE MEDICAL ATTENTION. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing skin may be more susceptible to effects of this material. RECOMMENDATIONS TO PHYSICIANS: Treat and eliminate overexposure. 5. FIRE-FIGHTING MEASURES FLASH POINT: Not Applicable AUTOIGNITION TEMPERATURE: Not Applicable FLAMMABLE LIMITS (in air by volume, Lower NA Upper NA FIRE EXTINGUISHING MATERIALS: Use fire extinguishing methods listed below: Water Spray: Yes Carbon Dioxide: Yes Foam: Yes Dry Chemical: Yes Halon: Yes Other: Any Class Page 445 of 1069 Page 445 of 1069 Page 445 of 1069 Page 445 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 3 of 6 UNUSUAL FIRE AND EXPLOSION HAZARDS: None known Explosion Sensitivity to Mechanical Impact: No Explosion Sensitivity to Static Discharge: No SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Isolate materials not yet involved in the fire and protect personnel. Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Evacuate unprotected personnel from the area. Maintain adequate ventilation. Follow personal protective equipment recommendations found in section 8. Contain and recover if possible. Cover or absorb spilled liquid with sand, earth or other inert material. Clean up spill immediately and place in appropriate containers. U.S. Regulations (CERCLA) requires reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal regulations and those of Canada and its Provinces, those of Australia, Japan and EU Member States (see Section 13, Disposal Considerations). 7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid breathing vapors/mists/dusts generated by this product. Use in a well-ventilated location. Remove contaminated clothing immediately. STORAGE AND HANDLING PRACTICES: Protect against physical damage. Store in a cool, dry well-ventilated location. Keep containers closed. Keep out of the reach of children. Observe all warnings and precautions listed for the product. 8. EXPOSURE CONTROLS - PERSONAL PROTECTION Chemical Name CAS# ACGIH TLV OSHA TWA Sodium Metasilicate Pentahydrate 6834-92-0 Not Listed Not Listed Alcohol Ethoxylate Proprietary Not Listed Not Listed VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided below. Use a chemical fume hood or local exhaust ventilation, and process enclosure if necessary, to control airborne dust. Ensure eyewash/safety shower stations are available near areas where this product is used. The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, or standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection), and those of Japan. Please reference applicable regulations and standards for relevant details. RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, the European Standard EN149, or EU member states. EYE PROTECTION: Use chemical safety goggles and/or a full face shield where dusting or splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. If necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian Standards, and the European Standard EN166, Australian Standards, or relevant Japanese Standards. HAND PROTECTION: Use chemically-resistant gloves when handling this product. If necessary, refer to U.S. OSHA 29 CFR 1910.138, the European Standard DIN EN 374, the appropriate Standards of Canada, Australian Standards, or relevant Japanese Standards. BODY PROTECTION: Use body protection appropriate for task (e.g. lab coat, overalls). If necessary, refer to appropriate Standards of Canada, or appropriate Standards of the EU, Australian Standards, or relevant Japanese Standards. If a Page 446 of 1069 Page 446 of 1069 Page 446 of 1069 Page 446 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 4 of 6 hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136. 9. PHYSICAL and CHEMICAL PROPERTIES VAPOR DENSITY: >1 EVAPORATION RATE (n-BuAc=1): <1 % VOLATILE: 1% MELTING/FREEZING POINT: 0°C (32°F) SOLUBILITY IN WATER: Complete BOILING POINT: 100°C (212°F) VAPOR PRESSURE: 17 mm Hg @ 20°C (68°F) pH: <12 ODOR: Mild Odor SPECIFIC GRAVITY: 1.0 APPEARANCE and COLOR: This product is a clear liquid with a mild odor. 10. STABILITY and REACTIVITY STABILITY: Stable under conditions of normal storage and use. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition produces carbon oxides, silicon oxides and sodium oxides. MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizing agents, strong acids. POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur. CONDITIONS TO AVOID: Incompatible materials. 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: No Data Available for this product. CARCINOGENS None of the components of this product are listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard. /ON 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: No data are available on the adverse effects of this material on the environment. This product is biodegradable. None of the ingredients in this mixture are classified as a Marine Pollutant. CHEMICAL EFFECT ON PLANTS, ANIMALS AND AQUATIC LIFE: This product is non-toxic and biodegradable. 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations, those of Canada, Australia, EU Member States and Japan. 14. TRANSPORTATION INFORMATION US DOT, IATA, IMO, ADR: U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS: This product is classified (per 49 CFR 172.101) by the U.S. Department of Transportation, as follows. PROPER SHIPPING NAME: NON-REGULATED MATERIAL HAZARD CLASS NUMBER and DESCRIPTION: NA UN IDENTIFICATION NUMBER: NA PACKING GROUP: NA DOT LABEL(S) REQUIRED: NA Page 447 of 1069 Page 447 of 1069 Page 447 of 1069 Page 447 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 5 of 6 NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER: NA RQ QUANTITY: NA MARINE POLLUTANT: The components of this product are not designated by the Department of Transportation to be Marine Pollutants (49 CFR 172.101, Appendix INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This product is not considered as dangerous goods. INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is notconsidered as dangerous goods. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR): This product is not considered by the United Nations Economic Commission for Europe to be dangerous goods. 15. REGULATORY INFORMATION UNITED STATES REGULATIONS: U.S. SARA REPORTING REQUIREMENTS: The components of this product are not subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act. Section 313 Toxic Release Inventory (40 CFR 372): None U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for the components of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore applies, per 40 CFR 370.20. U.S. CERCLA REPORTABLE QUANTITY (RQ): None U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory or are exempted form listing. OTHER U.S. FEDERAL REGULATIONS: None STATE REGULATIONS: STATE RIGHT TO KNOW LISTS: None CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): Ingredients within this product are not on the Proposition 65 Lists. CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL Inventory, or are exempted from listing. OTHER CANADIAN REGULATIONS: Not applicable. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: CANADIAN WHMIS CLASSIFICATION and SYMBOLS: Class E Corrosive EUROPEAN ECONOMIC COMMUNITY INFORMATION: EU LABELING AND CLASSIFICATION: This product meets the definition of the following hazard class as defined by the European Economic Community Guidelines. EU CLASSIFICATION: Corrosive EU RISK PHRASES: R34: Causes burns; R36/38: Irritating to eyes and skin. EU SAFETY PHRASES: S20/21: When using do not eat, drink or smoke; S24/25: Avoid contact with skin and eyes; S36/37: Wear suitable protective clothing and gloves; S39: Wear suitable eye/face protection. AUSTRALIAN INFORMATION FOR PRODUCT: The components of this product are not listed on the International Chemical Inventory list. Page 448 of 1069 Page 448 of 1069 Page 448 of 1069 Page 448 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 6 of 6 JAPANESE INFORMATION FOR PRODUCT: JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) STATUS: The components of this product are not listed as Class I Specified Chemical Substances, Class II Specified Chemical Substances, or Designated Chemical Substances by the Japanese MITI. JAPANESE ENCS INVENTORY: The components of this product are on the ENCS Inventory as indicated in the section on International Chemical Inventories, below. POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW: No component of this product is a listed Specified Poisonous Substance under the Poisonous and Deleterious Substances Control Law. INTERNATIONAL CHEMICAL INVENTORIES: Listing of the components on individual country Chemical Inventories is as follows: Asia-Pac: Not Listed Australian Inventory of Chemical Substances (AICS): Listed Korean Existing Chemicals List (ECL): Listed Japanese Existing National Inventory of Chemical Substances (ENCS): Listed Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed Swiss Giftliste List of Toxic Substances: Listed U.S. TSCA: Listed 16. OTHER INFORMATION PREPARED BY: Paul Eigbrett – (GHS MSDS Compliance PLUS) DATE OF PRINTING: December 11, 2013 The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of the need that information is current, applicable and suited to the circumstances of use. Krud Kutter, Inc. assumes no responsibility for injury to vendee or third party person proximately caused by the material if reasonable safety procedures are no adhered to as stipulated in the data sheet. Furthermore, Krud Kutter, Inc. assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. END OF MSDS SHEET Page 449 of 1069 Page 449 of 1069 Page 449 of 1069 Page 449 of 1069 ---PAGE BREAK--- Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner Hard Surface Disinfectant. Professional use SAFETY DATA SHEET Product name Distributed by Product use 1. Product and company identification : : : D0060203 v3.0 : SDS # EPA ID No. 777-82-675 Formulation : 1201-147 (374055 v2.0) UPC Code / Sizes : 36241 76334 01 (128 fl. oz.) : Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner : Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Classification of the substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A : Signal word : Warning Hazard statements : Causes serious eye irritation. Hazard pictograms : GHS label elements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Precautionary statements 1/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 450 of 1069 Page 450 of 1069 Page 450 of 1069 Page 450 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Supplemental label elements : None known. Hazards not otherwise classified : None known. Prevention : Wear eye or face protection. Wash hands thoroughly after handling. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Not applicable. Disposal : Not applicable. 3. Composition/information on ingredients Mixture : Substance/mixture Alcohols, C12-15, ethoxylated 5 - 10 68131-39-5 2-(2-butoxyethoxy)ethanol 2.5 - 5 112-34-5 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, sodium salt, hydrate (1:3:2) < 2.5 6132-04-3 Quaternary ammonium compounds, chlorides 0.1 - 1 68424-85-1 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures 2/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 451 of 1069 Page 451 of 1069 Page 451 of 1069 Page 451 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Most important acute and delayed Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. Causes serious eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : 3/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 452 of 1069 Page 452 of 1069 Page 452 of 1069 Page 452 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling 8. Exposure controls/personal protection Control Occupational exposure limits 4/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 453 of 1069 Page 453 of 1069 Page 453 of 1069 Page 453 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection 2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 6/2013). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor Ingredient name Exposure limits Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and chemical properties Physical state Melting point Liquid. [Clear.] Not available. Citrus Lemon-like. Odor pH Green-Yellow Color 10.7 to 11.8 [Conc. w/w): 100%] Not available. Odor threshold : : : : : : Appearance Boiling point : Not available. 5/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 454 of 1069 Page 454 of 1069 Page 454 of 1069 Page 454 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 1.008 to 1.018 Not available. Not available. Easily soluble in the following materials: cold water and hot water. Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: >93.3°C (>199.9°F) Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : : : : : : : Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Not classified Harmful. *Information is based on toxicity test result of a similar product. Irritation/Corrosion Information on toxicological effects Quaternary ammonium compounds, benzyl- chlorides LD50 Oral Rat 344 mg/kg - 2-(2-butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg - LD50 Oral Rat 4500 mg/kg - *Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rabbit >5000 mg/kg - 6/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 455 of 1069 Page 455 of 1069 Page 455 of 1069 Page 455 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Quaternary ammonium compounds, benzyl- chlorides Skin - Severe irritant Rabbit - 25 milligrams - 2-(2-butoxyethoxy)ethanol Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams - Eyes - Severe irritant Rabbit - 20 milligrams - *Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner Eyes - Cornea opacity Rat 1 - - Skin - Erythema/Eschar Rat 0 - 24 hours Product/ingredient name Result Score Exposure Observation Conclusion/Summary Skin : Non-irritant to skin. *Information is based on toxicity test result of a similar product. Eyes : Irritating to eyes. *Information is based on toxicity test result of a similar product. Species Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Sensitization *Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner skin In vitro Not sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Non-sensitizer to skin. *Information is based on toxicity test result of a similar product. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Information on the likely routes of exposure Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Causes serious eye irritation. : Eye contact : Not available. Potential acute health effects 7/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 456 of 1069 Page 456 of 1069 Page 456 of 1069 Page 456 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Not available. Irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 90000 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. 12. Ecological information Toxicity 8/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 457 of 1069 Page 457 of 1069 Page 457 of 1069 Page 457 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 12. Ecological information Quaternary ammonium compounds, benzyl- chlorides Acute EC50 0.016 mg/l Daphnia 48 hours Acute LC50 64 ppb Fresh water Fish - mykiss 96 hours 2-(2-butoxyethoxy)ethanol Acute LC50 1300000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Product/ingredient name Species Result Exposure LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name 2-(2-butoxyethoxy)ethanol 1 - low Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods 14. Transport information Not a DOT controlled material (United States). Not a TDG-controlled material. This preparation is not classified as dangerous according to international transport regulations (ADR/RID, IMDG or ICAO/IATA). 15. Regulatory information U.S. Federal regulations TSCA 4(a) proposed test rules: Quaternary ammonium compounds, benzyl- chlorides Clean Water Act (CWA) 311: sodium hydroxide; ammonia, : TSCA 8(a) PAIR: decanal; nonanal; octanal; α-hexylcinnamaldehyde; 2-methylundecanal TSCA 8(a) CDR Exempt/Partial exemption: Not determined Commerce control list precursor: 2,2',2''-nitrilotriethanol United States inventory (TSCA 8b): All components are listed or exempted. 9/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 458 of 1069 Page 458 of 1069 Page 458 of 1069 Page 458 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information WARNING Signal word: : Label elements Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed The following components are listed: TRIETHANOLAMINE Massachusetts : SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. 2-(2-butoxyethoxy)ethanol 112-34-5 5 2-(2-butoxyethoxy)ethanol 112-34-5 5 Form R - Reporting requirements Supplier notification New York : None of the components are listed. New Jersey : The following components are listed: GLYCOL ETHERS; TRIETHANOLAMINE; ETHANOL, 2,2',2"-NITRILOTRIS-; ETHYL ALCOHOL; ALCOHOL : The following components are listed: GLYCOL ETHERS; ETHANOL, NITRILOTRIS-; DENATURED ALCOHOL State regulations SARA 302/304 SARA 304 RQ : 200000000 lbs / 90800000 kg [23678995.4 gal / 89634748.3 L] Ammonia < 0.01 Yes. 500 - 100 - Composition/information on ingredients Name % EHS (lbs) (lbs) (gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification : Immediate (acute) health hazard 2-(2-butoxyethoxy)ethanol 2.5 - 5 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients 10/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 459 of 1069 Page 459 of 1069 Page 459 of 1069 Page 459 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information Hazard statements Causes substantial but temporary eye injury Keep out of reach of children. Do not get in eyes, on skin, or on clothing. Use safety eyewear designed to protect against splash of liquids. After handling, always wash hands thoroughly with soap and water. Remove contaminated clothing and wash it before reuse. Precautionary measures : : 16. Other information Hazardous Material Information System 1 0 0 0 0 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Date of issue Date of previous issue : : : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. 01/04/2015. 15/04/2011. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Personal protection A Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 11/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 460 of 1069 Page 460 of 1069 Page 460 of 1069 Page 460 of 1069 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Version : Indicates information that has changed from previously issued version. 3 Prepared by : Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: [PHONE REDACTED] Revision comments : Update as per US GHS. RB is a member of the CSPA Product Care Product Stewardship Program. 12/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 461 of 1069 Page 461 of 1069 Page 461 of 1069 Page 461 of 1069 ---PAGE BREAK--- Form N051 Page 1 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 8/16/2005 MSDS No: N-051 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: Lemon Shine Furnature Polish Formula: Lemon oil and silicone emulsion with hydrocarbon propellant for use on furnature Chemical Type: Lemon oil and silicone emulsion HMIS RATINGS Health = 1 (Slight) Flammability = 2 (Moderate) Reactivity = 0 (Minimal) Protection = A (Safety Glasses) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Propane 1-5% 1000 ppm No CAS No. 74-98-6 n-Butane 1-5% 600 ppm No CAS No. 106-97-8 SECTION III - CHEMICAL AND PHYSICAL Appearance and Odor: Lemon Odor, Cone Spray Boiling Point: N/A Evaporation Rate (Ether = <1 Melting Point: N/A pH: 10.0-11.0 Spec. Gravity (H20 = <1 Water Solubility: 10% Vapor Density (Air = >1 Vapor Pressure (psig): 117 @ 130F SECTION IV - FIRE AND EXPLOSION HAZARDS Aerosol Flammability: Product is not required to be labeled as flammable as described in 16 CFR 1500.3 and 1500.45. Flash Point (Method): <0F (Propellant) None even until boiling (Conc) Explosion Limits: Upper: 9.5 Lower: 1.9 Extinguishing Media: Carbon Dioxide, foam and/or dry chemical may be used. Special Firefighting Procedures and Hazards: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: At evelated temperatures (over 54C or 130F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening or container structure. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: Avoid heat, open flame and oxidizing agents. Hazardous Decomposition Products: Carbon Monoxide in small amounts and additional toxic chemicals may be formed in small amounts Conditions to Avoid: Do not store above 54C or 130F. Keep away from heat, direct sunlight, open flames or sparks. Dropping of containers may cause bursting. Hazardous Polymerization: Occurs: Does Not Occur: Page 462 of 1069 Page 462 of 1069 Page 462 of 1069 Page 462 of 1069 ---PAGE BREAK--- Form N025 Page 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. Skin: Remove contaminated clothing. Flush skin with water followed by washing with soap and water. If irritation occurs, get medical attention. Do not use clothing until cleaned. Eyes: Flush eyes with plents of water for 15 minutes while holding eye lids wide open. Get medical attention if irritation persists. Ingestion: Get medical attention. Most likely routes of entry: Inhilation, eyes, and skin Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Remove all sources of ignition and ventilate area. Soak up spill wiht an inert absorbent and place into a designed disposal container. Consult local regulatory agency for proper disposition of material. Storage and Handling: Avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 130F (54C). Store as level 1 Aerosol (NFPA 30B) Waste Disposal: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gass is expelled. Dispose of container in acordance with local, state, and federal regulations. Empty Containers: Dispose in accordance with local, state, and federal regulations. Other Precautions: Please read and follow the directions on the product label; THey are your best guide to using this product in the most effective way, and give the necessary safety precautions to protect you health. SECTION VIII - REGULATORY INFORMATION Respiratory Protection: None required if good ventilation is maintained. If exposure exceeds occupational exposure limits (Sect. II), use a NIOSH approved repirator to prevent overexposure. Ventilation: General ventilation is adequate under normal conditions. Mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves are recommended - consult glove manufacturer to determine the proper type for a specific operation. Eye Protection: Chemical safety glasses are recommended. Other Protective Clothing or Equipment: Wear impervious clothing to prevent skin contact. Work/Hygienic Practices: Ensure stict sanityar conditions are conformed to when working around chemicals. Protective clothing and equipment should be in accordance with 29 CFR 1910.132 and 1910.133. Reportable for SARA Title III, S.313 (Form The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 463 of 1069 Page 463 of 1069 Page 463 of 1069 Page 463 of 1069 ---PAGE BREAK--- Page 464 of 1069 Page 464 of 1069 Page 464 of 1069 Page 464 of 1069 ---PAGE BREAK--- Page 465 of 1069 Page 465 of 1069 Page 465 of 1069 Page 465 of 1069 ---PAGE BREAK--- Page 466 of 1069 Page 466 of 1069 Page 466 of 1069 Page 466 of 1069 ---PAGE BREAK--- Page 467 of 1069 Page 467 of 1069 Page 467 of 1069 Page 467 of 1069 ---PAGE BREAK--- Page 468 of 1069 Page 468 of 1069 Page 468 of 1069 Page 468 of 1069 ---PAGE BREAK--- Ultra Dawn Hand Dishwashing Liquids and Antibacterial Hand Soaps Page 1 of 5 The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS RQ1405032/ RQ1405221/ RQ1402590/ / RQ1309178(AB) Issue Date: 08/28/2014 Supersedes: RQ1311865/RQ1312426/RQ1400299/RQ1400459/RQ1402104 Issue Date: 06/08/2014 SECTION I - PRODUCT IDENTIFICATION Identity: Liquid Hand Dishwashing Detergents and Antibacterial Hand Soaps Brand: ULTRA DAWN Finished Products Covered: Ultra Dawn Original [96849942] Lemon [96866886] Pomegranate Awakening [96869507] Apple Ocrchard Harverst [96915999] Orange Dishwashing Liquid/Antibacterial Hand Soap [99488499] Apple Blossom Dishwashing Liquid/Antibacterial Hand Soap [96528376] Dawn Pure Essentials Sparkling Mist [96866925] Citrus Infusion [96866926] Dawn Escape Hawaiian Pineapple [96866893] Thai Dragonfruit [96866890] New Zealand Springs [96866897] Mediteranean Lavender [96866914] Fuji Cherry Blossom [96866916] Caribbean Breeze [96866921] Malibu Sunrise [96866924] P&G Telephone Number: 1-[PHONE REDACTED] or call Local Poison Control Center or your physician. SECTION II - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Inhalation: N/A Page 469 of 1069 Page 469 of 1069 Page 469 of 1069 Page 469 of 1069 ---PAGE BREAK--- Ultra Dawn Hand Dishwashing Liquids and Antibacterial Hand Soaps Page 2 of 5 Signs and of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. Inhalation: N/A Potential Environmental Effects: (See Section 12 for more information) SECTION III - COMPOSITION AND INGREDIENTS Ingredients listed on the product label are: biodegradable surfactants and no phosphate. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA: CHEMICAL NAME COMMON NAME CAS RN COMPOSITI ON RANGE LD50/LC50 Ethyl alcohol Ethanol 64-17-5 1 - 5% LD50(oral, rat) – 7.06 g/kg Alcohol Ethoxysulfate, sodium salt Sodium Laureth Sulfate 68585-34-2 10-30% total anionic surfactant LD50 (oral, rat) - >2g/kg Alcohol Sulfates, sodium salt Sodium Lauryl Sulfate 68585-47-7 LD50 (oral, rat) - >2g/kg Amines, C10-16 N-oxides Alkyl Dimethyl Amine Oxide 70592-80-2 1 - 5% LD50 (oral, rat) - 1.33 g/kg These substances are listed because in their pure bulk form they meet the OSHA and/or WHMIS definition of hazardous. Any hazards associated with this finished product are listed in Section II of this MSDS. SECTION IV – FIRST AID INFORMATION First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If persist or recur, seek medical attention. Inhalation: N/A Other: Consumer product package has the following precautionary statement on the back label: “For external use only. Keep out of the reach of children. If Dawn gets in eyes, rinse thoroughly with water. If swallowed, drink a glass of water to dilute.” SECTION V - FIRE FIGHTING INFORMATION Flammable Properties: The liquid hand dishwashing detergents have a flashpoint of 115-135°F (46.1-57.2°C) Pensky-Martens (Closed cup). However, the detergents do not sustain combustion according to ASTM D4206. Flammable Properties: Upper Flammable Limit: N/A Lower Flammable Limit: N/A Explosive Limits: UEL: N/A LEL: N/A Auto-ignition Temperature: N/A Hazardous Combustion Products: N/A Explosion Data (Sensitivity to Mechanical Impact): N/A Explosion Data (Sensitivity to Static Discharge): N/A Extinguishing Media: Suitable: CO2, water or dry chemical may be used. Unsuitable: N/K Protection of Firefighters: Specific Hazards Arising from the Material: None. SECTION VI - ACCIDENTAL RELEASE MEASURES Page 470 of 1069 Page 470 of 1069 Page 470 of 1069 Page 470 of 1069 ---PAGE BREAK--- Ultra Dawn Hand Dishwashing Liquids and Antibacterial Hand Soaps Page 3 of 5 Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer - First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information. SECTION VII – HANDLING AND STORAGE Precautions To Be Taken in Handling: No special precautions necessary. Precautions To B e Taken in Storage: No special precautions necessary. SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION Recommended Exposure Guidelines: Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm OSHA Z-1 PEL 1000 ppm Engineering Controls: N/A Personal Protective Equipment (PPE): N/A Eye/Face Protection: None required with normal household use. Industrial Setting: For splash protection, use chemical goggles. Eye wash fountain is recommended. Skin Protection: None required with normal household use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Respiratory Protection: No special precautions for casual exposure. Ventilation Local Exhaust: None required with normal consumer use. Special: None Industrial (General): Normal/general dilution ventilation is acceptable. Other: None SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Clear, opaque or colored liquids. Flash Point (Method Used): 115-135°F (46.1-57.2°C) Pensky-Martens (Closed cup) but do not sustain combustion according to ASTM D4206. Odor: Perfumed Reserve Alkalinity: N/A Odor Threshold: N/A Solubility in Water: Complete Physical State: Liquid hand dishwashing solution Decomposition Temperature: N/K Vapor Pressure (mm Hg): N/K Evaporation Rate (nBuOAc=1): N/K Vapor Density (Air=1): N/K Specific Gravity/Density: ca. 1 Boiling Point: N/K Melting/Freezing Point: ~ 30 °F Partition Coefficient (n-octanol/water): N/K pH (10% solution): 9 Volatile Organic Compound (VOC): Not applicable - Product not regulated for VOC Content at State or Federal level SECTION X - STABILITY AND REACTIVITY Chemical Stability: Stable Conditions to Avoid: None known Incompatible Materials: None Hazardous Decomposition Products: None known Possibility of Hazardous Reactions: None known SECTION XI - TOXICOLOGICAL INFORMATION Page 471 of 1069 Page 471 of 1069 Page 471 of 1069 Page 471 of 1069 ---PAGE BREAK--- Ultra Dawn Hand Dishwashing Liquids and Antibacterial Hand Soaps Page 4 of 5 Liquid hand dishwashing detergents have a relatively low order of toxicity, may cause transient irritation and are expected to be emetic. Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: This finished product is not carcinogenic. NTP: No IARC: No OSHA: No SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL AND LOCAL REGULATIONS Non Household Setting: Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations. Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. California Hazardous Waste: Not hazardous, in accordance with 22 CCR 66261.20 through 22 CCR 66261.24 Household Use: Household product is safe for disposal down the drain during detergent use or in the trash. Dispose of empty bottle in the trash or recyle where facilities exist. SECTION XIV - TRANSPORT INFORMATION Products covered by this MSDS, in their original form, are not regulated for transportation. Ground Transport (US DOT): Not regulated Air Transport (IATA): Not regulated Marine/Water Transport (IMDG): Not regulated SECTION XV - REGULATORY INFORMATION United States All intentionally-added components of this product are listed on the US TSCA Inventory. This product is not subject to warning labeling under California Proposition 65. EPA Reg. No.: Not Applicable This product contains the following SARA 313/302/304/311/312 chemicals: None This product contains the following CERCLA chemicals: Chemical Name CAS Number Max Range in Product Ethanol 64-17-5 5.0% State Right-to-Know: The following ingredients present in the finished product are listed on state right-to-know lists or state worker exposure lists: INGREDIENT CAS RN MAX LEVEL STATE IL MA NJ PA RI Ethanol 64-17-5 1.0 % X X X X X Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance Page 472 of 1069 Page 472 of 1069 Page 472 of 1069 Page 472 of 1069 ---PAGE BREAK--- Ultra Dawn Hand Dishwashing Liquids and Antibacterial Hand Soaps Page 5 of 5 Canada All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations. SECTION XVI - OTHER INFORMATION Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance. P&G Hazard Rating: Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/A. - Not Applicable *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all- inclusive document on worldwide hazard communication regulations. This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the product. Page 473 of 1069 Page 473 of 1069 Page 473 of 1069 Page 473 of 1069 ---PAGE BREAK--- Ultra Dawn Plus Hand Dishwashing Liquid and Antibacterial Hand Soaps Page 1 of 5 The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS RQ1311863/ RQ1400590 Issue Date: 06/08/2014 Supersedes: RQ1310079 / RQ1310080 Issue Date: 01/29/2014 SECTION I - PRODUCT IDENTIFICATION Identity: Liquid Hand Dishwashing Detergents Finished Product Brand: ULTRA DAWN PLUS Finished Products Covered: Ultra Dawn Plus Power Clean/Power Lift (Refreshing Rain [96661908], Vibrant Fresh [96661906]) Ultra Dawn with Bleach Alternative Plus (Fresh Rapids [96661987], Morning Mist [96661988]) Ultra Dawn Advanced Power [96708559] Ultra Dawn Plus Oxi (Citrus Zest [96708563], Invigorating Berry [96708566]) P&G Telephone Number: 1-[PHONE REDACTED] or call Local Poison Control Center or your physician. SECTION II - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Inhalation: N/A Signs and of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. Inhalation: N/A Potential Environmental Effects: (See Section 12 for more information) SECTION III - COMPOSITION AND INGREDIENTS Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA: CHEMICAL NAME COMMON NAME CAS RN COMPOSITION RANGE LD50/LC50 Ethyl alcohol Ethanol 64-17-5 1 - 5% LD50(oral, rat) – 7.06 g/kg Alcohol Ethoxysulfate, sodium salt Sodium Laureth Sulfate 68585-34-2 10-30% total anionic surfactant LD50 (oral, rat) - >2g/kg Alcohol Sulfates, sodium salt Sodium Lauryl Sulfate 68585-47-7 LD50 (oral, rat) - >2g/kg Amines, C10-16 N-oxides Alkyl Dimethyl Amine Oxide 70592-80-2 3 - 7% LD50 (oral, rat) - 1.33 g/kg Page 474 of 1069 Page 474 of 1069 Page 474 of 1069 Page 474 of 1069 ---PAGE BREAK--- Ultra Dawn Plus Hand Dishwashing Liquid and Antibacterial Hand Soaps Page 2 of 5 These substances are listed because in their pure bulk form they meet the OSHA and/or WHMIS definition of hazardous. Any hazards associated with this finished product are listed in Section II of this MSDS. SECTION IV – FIRST AID INFORMATION First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If persist or recur, seek medical attention. Inhalation: N/A Other: Consumer product package has the following precautionary statement on the back label: “For external use only. Keep out of the reach of children. If Dawn gets in eyes, rinse thoroughly with water. If swallowed, drink a glass of water to dilute.” SECTION V - FIRE FIGHTING INFORMATION Flammable Properties: The liquid hand dishwashing detergents have a flashpoint of 115-135°F (46.1-57.2°C) Pensky-Martens (Closed cup). However, the detergents do not sustain combustion according to ASTM D4206. Flammable Properties: Upper Flammable Limit: N/A Lower Flammable Limit: N/A Explosive Limits: UEL: N/A LEL: N/A Auto-ignition Temperature: N/A Hazardous Combustion Products: N/A Explosion Data (Sensitivity to Mechanical Impact): N/A Explosion Data (Sensitivity to Static Discharge): N/A Extinguishing Media: Suitable: CO2, water or dry chemical may be used. Unsuitable: N/K Protection of Firefighters: Specific Hazards Arising from the Material: None. SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer - First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information. SECTION VII – HANDLING AND STORAGE Precautions To Be Taken in Handling: No special precautions necessary. Precautions To Be Taken in Storage: No special precautions necessary. Page 475 of 1069 Page 475 of 1069 Page 475 of 1069 Page 475 of 1069 ---PAGE BREAK--- Ultra Dawn Plus Hand Dishwashing Liquid and Antibacterial Hand Soaps Page 3 of 5 SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION Recommended Exposure Guidelines: Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm OSHA Z-1 PEL 1000 ppm Engineering Controls: N/A Personal Protective Equipment (PPE): N/A Eye/Face Protection: None required with normal household use. Industrial Setting: For splash protection, use chemical goggles. Eye wash fountain is recommended. Skin Protection: None required with normal household use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Respiratory Protection: No special precautions for casual exposure. Ventilation Local Exhaust: None required with normal consumer use. Special: None Industrial (General): Normal/general dilution ventilation is acceptable. Other: None SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Clear, opaque or colored liquids. Flash Point (Method Used): 115-135°F (46.1-57.2°C) Pensky-Martens (Closed cup) but do not sustain combustion according to ASTM D4206. Odor: Perfumed Reserve Alkalinity: N/A Odor Threshold: N/A Solubility in Water: Complete Physical State: Liquid hand dishwashing solution Decomposition Temperature: N/K Vapor Pressure (mm Hg): N/K Evaporation Rate (nBuOAc=1): N/K Vapor Density (Air=1): N/K Specific Gravity/Density: ca. 1 Boiling Point: N/K Melting/Freezing Point: ~ 30 °F Partition Coefficient (n-octanol/water): N/K pH (10% solution): 9 Volatile Organic Compound (VOC): Not applicable - Product not regulated for VOC Content at State or Federal level SECTION X - STABILITY AND REACTIVITY Chemical Stability: Stable Conditions to Avoid: None known Incompatible Materials: None Hazardous Decomposition Products: None known Possibility of Hazardous Reactions: None known SECTION XI - TOXICOLOGICAL INFORMATION Liquid hand dishwashing detergents have a relatively low order of toxicity, may cause transient irritation and are expected to be emetic. Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: This finished product is not carcinogenic. NTP: No IARC: No OSHA: No SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable. Page 476 of 1069 Page 476 of 1069 Page 476 of 1069 Page 476 of 1069 ---PAGE BREAK--- Ultra Dawn Plus Hand Dishwashing Liquid and Antibacterial Hand Soaps Page 4 of 5 SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL AND LOCAL REGULATIONS Non Household Setting: Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations. Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. California Hazardous Waste: Not hazardous, in accordance with 22 CCR 66261.20 through 22 CCR 66261.24 Household Use: Household product is safe for disposal down the drain during detergent use or in the trash. Dispose of empty bottle in the trash or recyle where facilities exist. SECTION XIV - TRANSPORT INFORMATION Products covered by this MSDS, in their original form, are not regulated for transportation. Ground Transport (US DOT): Not regulated Air Transport (IATA): Not regulated Marine/Water Transport (IMDG): Not regulated SECTION XV - REGULATORY INFORMATION United States All intentionally-added components of this product are listed on the US TSCA Inventory. This product is not subject to warning labeling under California Proposition 65. EPA Reg. No.: Not Applicable This product contains the following SARA 313/302/304/311/312 chemicals: None This product contains the following CERCLA chemicals: Ethanol 64-17-5 5.0% Chemical Name CAS Number Max Range in Product State Right-to-Know: The following ingredients present in the finished product are listed on state right-to-know lists or state worker exposure lists: INGREDIENT CAS RN MAX LEVEL STATE IL MA NJ PA RI Ethanol 64-17-5 1.0 % X X X X X Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance Canada All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations. Page 477 of 1069 Page 477 of 1069 Page 477 of 1069 Page 477 of 1069 ---PAGE BREAK--- Ultra Dawn Plus Hand Dishwashing Liquid and Antibacterial Hand Soaps Page 5 of 5 SECTION XVI - OTHER INFORMATION Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance. P&G Hazard Rating: Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/A. - Not Applicable *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all- inclusive document on worldwide hazard communication regulations. This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the product. Page 478 of 1069 Page 478 of 1069 Page 478 of 1069 Page 478 of 1069 ---PAGE BREAK--- Revision Date: 28-Jul-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: LOTIONIZED LIQUID HAND CLEANER Product Number: 3003 , 3006 Recommended Use: Hand cleaner Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Not Classified Not dangerous according to the Globally Harmonized System (GHS) GHS Label Elements Signal Word: No signal word Hazard Statements: No hazard statements Precautionary Statements: Prevention: Not Applicable Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • May cause eye irritation. 5.07657% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 cocamide DIPA 68855-69-6 1-5 sodium lauryl sulfate 151-21-3 1-5 Page 1 / 5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. Symbols: No symbols Page 479 of 1069 Page 479 of 1069 Page 479 of 1069 Page 479 of 1069 ---PAGE BREAK--- 3003 - LOTIONIZED LIQUID HAND CLEANER Revision Date: 28-Jul-2015 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Page 2 / 5 Not required with expected use. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. Page 480 of 1069 Page 480 of 1069 Page 480 of 1069 Page 480 of 1069 ---PAGE BREAK--- 3003 - LOTIONIZED LIQUID HAND CLEANER Revision Date: 28-Jul-2015 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: No known hazard in contact with skin -Inhalation: No known effect. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 42706 mg/kg ATEmix (dermal): 19231 mg/kg ATEmix (inhalation-dust/mist): 49.7 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available sodium lauryl sulfate 151-21-3 = 1288 mg/kg ( Rat ) = 580 mg/kg ( Rabbit ) > 3900 mg/m3 ( Rat ) 1 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Pink Odor: Floral fragrance pH: 7.0-8.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.01 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 481 of 1069 Page 481 of 1069 Page 481 of 1069 Page 481 of 1069 ---PAGE BREAK--- 3003 - LOTIONIZED LIQUID HAND CLEANER Revision Date: 28-Jul-2015 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea sodium lauryl sulfate 151-21-3 53: 72 h Desmodesmus subspicatus mg/L EC50 30 - 100: 96 h Desmodesmus subspicatus mg/L EC50 117: 96 h Pseudokirchneriella subcapitata mg/L EC50 3.59 - 15.6: 96 h Pseudokirchneriella subcapitata mg/L EC50 static 8 - 12.5: 96 h Pimephales promelas mg/L LC50 static 15 - 18.9: 96 h Pimephales promelas mg/L LC50 static 22.1 - 22.8: 96 h Pimephales promelas mg/L LC50 static 4.3 - 8.5: 96 h mykiss mg/L LC50 static 4.62: 96 h mykiss mg/L LC50 flow-through 4.2: 96 h mykiss mg/L LC50 7.97: 96 h Brachydanio rerio mg/L LC50 flow-through 9.9 - 20.1: 96 h Brachydanio rerio mg/L LC50 semi-static 4.06 - 5.75: 96 h Lepomis macrochirus mg/L LC50 static 4.2 - 4.8: 96 h Lepomis macrochirus mg/L LC50 flow-through 4.5: 96 h Lepomis macrochirus mg/L LC50 5.8 - 7.5: 96 h Pimephales promelas mg/L LC50 static 10.2 - 22.5: 96 h Pimephales promelas mg/L LC50 semi-static 6.2 - 9.6: 96 h Pimephales promelas mg/L LC50 13.5 - 18.3: 96 h Poecilia reticulata mg/L LC50 semi-static 10.8 - 16.6: 96 h Poecilia reticulata mg/L LC50 static 1.31: 96 h Cyprinus carpio mg/L LC50 semi-static Not Available 1.8: 48 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. IMDG: Not Regulated Proper Shipping Name: Page 4 / 5 Non Hazardous Product 15. REGULATORY INFORMATION Page 482 of 1069 Page 482 of 1069 Page 482 of 1069 Page 482 of 1069 ---PAGE BREAK--- 3003 - LOTIONIZED LIQUID HAND CLEANER Revision Date: 28-Jul-2015 TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product is not subject to warning requirements under California Proposition 65. 16. OTHER INFORMATION Revision Date: 28-Jul-2015 Reasons for Revision: Section 14 and 15 Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 0 Physical Hazards: 0 Page 483 of 1069 Page 483 of 1069 Page 483 of 1069 Page 483 of 1069 ---PAGE BREAK--- LYSOL® All Purpose Cleaner - Power White & Shine Trigger with Bleach Multipurpose Cleaner SAFETY DATA SHEET Product name Distributed by Product use 1. Product and company identification : : D0004478 v5.0 : SDS # EPA ID No. 777-83 Formulation : 292-017A (0003419 v4.0) UPC Code / Sizes : 19200-78914-30 (32 oz. Trigger HDPE Bottle) : LYSOL® All Purpose Cleaner - Power White & Shine Trigger with Bleach : Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Classification of the substance or mixture CORROSIVE TO METALS - Category 1 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B SKIN SENSITIZATION - Category 1 : Signal word : Warning Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 2.5% 1/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 484 of 1069 Page 484 of 1069 Page 484 of 1069 Page 484 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Hazard statements : May be corrosive to metals. Causes skin and eye irritation. May cause an allergic skin reaction. Supplemental label elements : None known. Hazards not otherwise classified : None known. General Prevention : Wear protective gloves. Wear eye or face protection. Keep only in original container. Avoid breathing vapor. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Response : Absorb spillage to prevent material damage. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store in corrosive resistant container with a resistant inner liner. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Precautionary statements 3. Composition/information on ingredients Mixture : Substance/mixture sodium hypochlorite, solution 1 - 2.5 7681-52-9 sodium hydroxide < 0.25 1310-73-2 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4. First aid measures Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Eye contact Skin contact Inhalation : : : Description of necessary first aid measures 2/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 485 of 1069 Page 485 of 1069 Page 485 of 1069 Page 485 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. Adverse may include the following: irritation redness : : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : None known. Suitable extinguishing media : Unsuitable extinguishing media : 3/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 486 of 1069 Page 486 of 1069 Page 486 of 1069 Page 486 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Decomposition products may include the following materials: halogenated compounds metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Special protective actions for fire-fighters : 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Absorb spillage to prevent material damage. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Absorb spillage to prevent material damage. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Keep away from acids. Empty containers retain product residue and can be hazardous. Do not reuse container. Absorb spillage to prevent material damage. : Precautions for safe handling 4/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 487 of 1069 Page 487 of 1069 Page 487 of 1069 Page 487 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store in corrosive resistant container with a resistant inner liner. Separate from acids. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : sodium hypochlorite, solution AIHA WEEL (United States, 10/2011). STEL: 2 mg/m³ 15 minutes. sodium hydroxide ACGIH TLV (United States, 6/2013). C: 2 mg/m³ OSHA PEL 1989 (United States, 3/1989). CEIL: 2 mg/m³ NIOSH REL (United States, 10/2013). CEIL: 2 mg/m³ OSHA PEL (United States, 2/2013). TWA: 2 mg/m³ 8 hours. 8. Exposure controls/personal protection Ingredient name Exposure limits Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control Individual protection measures Occupational exposure limits Skin protection 5/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 488 of 1069 Page 488 of 1069 Page 488 of 1069 Page 488 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Clear.] Not available. 1.042 to 1.048@ 20°C Not available. Not available. Easily soluble in the following materials: cold water and hot water. Characteristic. Odor pH Straw. [Light] Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: >93.3°C (>199.9°F) Not available. 12.3 to 12.7 [Conc. w/w): 100%][25°C] Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Reactive or incompatible with the following materials: acids Do not mix with household chemicals. May be corrosive to metals. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 6/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 489 of 1069 Page 489 of 1069 Page 489 of 1069 Page 489 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Not classified Harmful. * Information is based on toxicity test result of a similar product. Irritation/Corrosion sodium hydroxide Eyes - Severe irritant Monkey - 24 hours 1 Percent - Eyes - Mild irritant Rabbit - 400 Micrograms - Eyes - Severe irritant Rabbit - 24 hours 50 Micrograms - Eyes - Severe irritant Rabbit - 1 Percent - Eyes - Severe irritant Rabbit - 0.5 minutes 1 milligrams - Skin - Mild irritant Human - 24 hours 2 Percent - Skin - Severe irritant Rabbit - 24 hours 500 milligrams - sodium hypochlorite, solution Eyes - Mild irritant Rabbit - 1.31 milligrams - Eyes - Moderate irritant Rabbit - 10 milligrams - *LYSOL® All Purpose Cleaner - Power White & Shine Trigger with Bleach Eyes - Iris lesion Rat >1 - - Skin - Erythema/Eschar Rat 5.25 - - Product/ingredient name Result Score Exposure Observation Conclusion/Summary Skin : Severely irritating to the skin. *Information is based on toxicity test result of a similar product. Eyes : Moderately irritating to eyes. *Information is based on toxicity test result of a similar product. Species Information on toxicological effects Mutagenicity Sensitization *LYSOL® All Purpose Cleaner - Power White & Shine Trigger with Bleach skin Guinea pig Sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Skin sensitizer * Information is based on toxicity test result of a similar product. *LYSOL® All Purpose Cleaner - Power White & Shine Trigger with Bleach LC50 Inhalation Vapor Rat 200 mg/l 4 hours LD50 Dermal Rat >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - 7/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 490 of 1069 Page 490 of 1069 Page 490 of 1069 Page 490 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Carcinogenicity Not available. Not available. Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Classification sodium hypochlorite, solution - 3 - Product/ingredient name NTP IARC OSHA Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. Adverse may include the following: irritation redness : : : Eye contact : Adverse may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Long term exposure 8/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 491 of 1069 Page 491 of 1069 Page 491 of 1069 Page 491 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Not available. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Not available. Acute toxicity estimates Potential immediate effects : Not available. Potential delayed effects : Not available. 12. Ecological information Toxicity sodium hypochlorite, solution Acute EC50 46000 µg/l Marine water Algae - Gracilaria tenuistipitata 4 days Acute LC50 56400 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 32 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 32 µg/l Marine water Fish - kisutch - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Chronic NOEC 10000 µg/l Marine water Algae - Gracilaria tenuistipitata 4 days Chronic NOEC 0.1 ppm Fresh water Fish - Cyprinus carpio - Young 30 days Product/ingredient name Species Result Exposure Bioaccumulative potential Other adverse effects : Release of large quantities into water may cause a pH-change resulting in danger for aquatic life. Not available. Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. 9/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 492 of 1069 Page 492 of 1069 Page 492 of 1069 Page 492 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 12. Ecological information Release of large quantities into water may cause a pH-change resulting in danger for aquatic life. 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods 14. Transport information 8 Limited quantity DOT Classification TDG Classification 8 Corrosive liquid, basic, inorganic, n.o.s. (Sodium hypochlorite , sodium hydroxide) II UN3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (sodium hypochlorite, solution, sodium hydroxide) II IMDG Class CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Sodium hypochlorite , sodium hydroxide). 8 II Corrosive liquid, basic, inorganic, n.o.s. (sodium hypochlorite, solution, sodium hydroxide) UN3266 IATA-DGR Class 8 Regulatory information UN number Proper shipping name Classes PG* Label Additional information II UN3266 Limited quantity See DG List. UN3266 Limited quantity Mexico Classification UN3266 LIQUIDO CORROSIVO, BASICO, INORGANICO, N.E.P. (sodium hypochlorite, solution, sodium hydroxide) 8 II Limited quantity PG* : Packing group 10/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 493 of 1069 Page 493 of 1069 Page 493 of 1069 Page 493 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information WARNING Signal word: Hazard statements Causes moderate eye irritation Causes skin irritation. Do not get in eyes, on skin, or on clothing. Precautionary measures : : : Label elements U.S. Federal regulations Clean Water Act (CWA) 311: sodium hypochlorite, solution; sodium hydroxide : TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined. Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed The following components are listed: SODIUM HYPOCHLORITE Massachusetts : New York : The following components are listed: Sodium hypochlorite New Jersey : The following components are listed: SODIUM HYPOCHLORITE; HYPOCHLOROUS ACID, SODIUM SALT : The following components are listed: HYPOCHLOROUS ACID, SODIUM SALT State regulations SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Reactive Immediate (acute) health hazard sodium hypochlorite, solution 1 - 2.5 No. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients 11/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 494 of 1069 Page 494 of 1069 Page 494 of 1069 Page 494 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals : Skin sensitizer: Vapor may be irritating to eyes and respiratory system. Use only in a well-ventilated area. Avoid breathing vapor or spray. Not recommended for use by persons with heart conditions or chronic respiratory problems such as asthma, or obstructive lung disease. Harmful if swallowed. For sensitive skin, the use of gloves is recommended. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Additional information Short term Skin Bleaching agent. IF ON SKIN: Rinse skin with water. : 16. Other information Hazardous Material Information System 3 0 0 0 0 3 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Personal protection D Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 12/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 495 of 1069 Page 495 of 1069 Page 495 of 1069 Page 495 of 1069 ---PAGE BREAK--- D0004478 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Date of previous issue Version : : : Indicates information that has changed from previously issued version. 31/03/2015. 15/06/2006. 5 Prepared by : Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: [PHONE REDACTED] Revision comments : Update as per US GHS. RB is a member of the CSPA Product Care Product Stewardship Program. 13/13 31/03/2015. Date of issue : SDS # FF0003419 (D0004478) : Code # D0004478 v5.0 : Page 496 of 1069 Page 496 of 1069 Page 496 of 1069 Page 496 of 1069 ---PAGE BREAK--- Lysol Brand II Kills 99.9% of Viruses & Bacteria Disinfecting Wipes - Ocean Fresh Surface Disinfectant. SAFETY DATA SHEET Product name Distributed by Product use 1. Product and company identification : : : D0314689 v6.0 : SDS # EPA ID No. 777-114 Formulation : (1671-112A) 0314190 v1.0 (1934-065C) 8184601 v1.0 (1934-065C) 8029615 v1.0 (2096-032H) 8169603 v1.0 (e0002-071) 8065149 v1.0 DIN # : 02359014 UPC Code / Sizes : Ocean Fresh/Spring Waterfall: 19200 81146 0 (35 Wet Wipes 7" X 8" sheets) 19200 77925 8 (80 Wet Wipes 7" X 8" sheets) 59631 89015 3 (24 Wet Wipes 8.4" X 10" sheets) : Lysol Brand II Kills 99.9% of Viruses & Bacteria Disinfecting Wipes - Ocean Fresh : Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue, Unit #2 Mississauga, Ontario L4W 5S9 CANADA Telephone: +1 [PHONE REDACTED] 1/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 497 of 1069 Page 497 of 1069 Page 497 of 1069 Page 497 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Classification of the substance or mixture Not classified : Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Hazard pictograms : GHS label elements Supplemental label elements : None known. Hazards not otherwise classified : None known. General Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Precautionary statements Not applicable. 3. Composition/information on ingredients Mixture : Substance/mixture Ethyl alcohol 1 - 2.5 64-17-5 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4. First aid measures Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : No known significant effects or critical hazards. May cause eye irritation upon direct contact with eyes. : Eye contact Potential acute health effects 2/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 498 of 1069 Page 498 of 1069 Page 498 of 1069 Page 498 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide No specific fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 3/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 499 of 1069 Page 499 of 1069 Page 499 of 1069 Page 499 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 6. Accidental release measures Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling Ethyl alcohol ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. 8. Exposure controls/personal protection Ingredient name Exposure limits Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control Individual protection measures Occupational exposure limits 4/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 500 of 1069 Page 500 of 1069 Page 500 of 1069 Page 500 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection Hand protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Solid. [Presaturated Wipes] Not available. 0.985 [liquid preparations] Not available. Not available. Not available. Characteristic. Odor pH Presaturated Wipes (Clear. liquid) Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: >93.3°C (>199.9°F) liquid preparations Not available. 10.5 [liquid preparations] Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. 5/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 501 of 1069 Page 501 of 1069 Page 501 of 1069 Page 501 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Do not use with other products. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Ethyl alcohol Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Eyes - Moderate irritant Rabbit - 100 microliters - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 400 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - *Lysol® Disinfectant Wipes, Ocean Fresh Skin - Slight irritant Rabbit 1.5 - - Eyes - Cornea opacity Rabbit 0 - - Product/ingredient name Result Score Exposure Observation Conclusion/Summary Skin : Non-irritant to skin. Eyes : Non-irritating to the eyes. Information is based on toxicity test result of a similar product. Species Information on toxicological effects Sensitization *Lysol® Disinfectant Wipes, Ocean Fresh_D0314689 skin Guinea pig Not sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Non-sensitizer to skin. Ethyl alcohol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours LD50 Oral Rat 7 g/kg - *Lysol® Disinfectant Wipes, Ocean Fresh LC50 Inhalation Vapor Rat >2.04 mg/l 24 hours LD50 Dermal Rat >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - 6/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 502 of 1069 Page 502 of 1069 Page 502 of 1069 Page 502 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Classification Ethyl alcohol - 1 - Product/ingredient name NTP IARC OSHA Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. May cause eye irritation upon direct contact with eyes. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. 7/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 503 of 1069 Page 503 of 1069 Page 503 of 1069 Page 503 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Not available. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Not available. Acute toxicity estimates 12. Ecological information Toxicity Ethyl alcohol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 µg/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 µg/l Fresh water Fish - mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Product/ingredient name Species Result Exposure LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Ethyl alcohol -0.35 - low Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. 8/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 504 of 1069 Page 504 of 1069 Page 504 of 1069 Page 504 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods 14. Transport information Not a DOT controlled material (United States). Not a TDG-controlled material. This preparation is not classified as dangerous according to international transport regulations (ADR/RID, IMDG or ICAO/IATA). 15. Regulatory information U.S. Federal regulations TSCA 4(a) proposed test rules: Quaternary ammonium compounds, benzyl- chlorides : TSCA 8(a) PAIR: 2-(4-tert-butylbenzyl)propionaldehyde; bornan-2-one; 2-ol; nonanal; octanal; dodecanal; decanal; 2-methylundecanal; cinnamaldehyde; 3-p- α-hexylcinnamaldehyde; 2-benzylideneheptanal TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined. Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Not applicable. Composition/information on ingredients 9/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 505 of 1069 Page 505 of 1069 Page 505 of 1069 Page 505 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information CAUTION Signal word: Hazard statements May cause eye irritation. Wash hands after use. Avoid contact with eyes. Precautionary measures : : : Label elements The following components are listed: ETHYL ALCOHOL Massachusetts : New York : None of the components are listed. New Jersey : The following components are listed: ETHYL ALCOHOL; ALCOHOL : The following components are listed: DENATURED ALCOHOL State regulations Ethyl alcohol 1 - 2.5 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard 16. Other information Hazardous Material Information System 1 0 0 0 0 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Personal protection B 10/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 506 of 1069 Page 506 of 1069 Page 506 of 1069 Page 506 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Date of previous issue Version : : : Indicates information that has changed from previously issued version. 27/04/2015. 21/04/2015 6 Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Prepared by : Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: [PHONE REDACTED] Revision comments : Addition of formula #s and separated by fragrance. RB is a member of the CSPA Product Care Product Stewardship Program. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 11/11 27/04/2015. Date of issue : SDS # D0314689 (Ocean Fresh) : Code # D0314689 v6.0 : Page 507 of 1069 Page 507 of 1069 Page 507 of 1069 Page 507 of 1069 ---PAGE BREAK--- Lysol Brand II Kills 99.9% of Viruses & Bacteria Disinfecting Wipes Lemon Lime Blossom Surface Disinfectant. SAFETY DATA SHEET Product name Distributed by Product use 1. Product and company identification : : : D0314689 v6.0 : SDS # EPA ID No. 777-114 Formulation : (e0002-078) 0314159 v3.0 (1934-064A) 8184600 v1.0 (2096-032F) 8169597 v1.0 (1934-064A) 8029609 v1.0 DIN # : 02359014 UPC Code / Sizes : Lemon & Lime Blossom: 19200 84460 4 (9 Wet Wipes 7" X 8" sheets) 19200 81145 3 (35 Wet Wipes 7" X 8" sheets) 19200 77182 5 (80 Wet Wipes 7" X 8" sheets) 19200 78849 6 (110 Wet Wipes 7" X 8" sheets) 19200 84383 6 (24 Wet Wipes 8.4" X 10" sheets) 19200 84384 6 (54 Wet Wipes 8.4" X 10" sheets) : Lysol Brand II Kills 99.9% of Viruses & Bacteria Disinfecting Wipes Lemon Lime Blossom : Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue, Unit #2 Mississauga, Ontario L4W 5S9 CANADA Telephone: +1 [PHONE REDACTED] 1/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 508 of 1069 Page 508 of 1069 Page 508 of 1069 Page 508 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Classification of the substance or mixture Not classified : Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Hazard pictograms : GHS label elements Supplemental label elements : None known. Hazards not otherwise classified : None known. General Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Precautionary statements Not applicable. 3. Composition/information on ingredients Mixture : Substance/mixture Ethyl alcohol 1 - 2.5 64-17-5 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4. First aid measures Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : No known significant effects or critical hazards. May cause eye irritation upon direct contact with eyes. : Eye contact Potential acute health effects 2/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 509 of 1069 Page 509 of 1069 Page 509 of 1069 Page 509 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide No specific fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 3/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 510 of 1069 Page 510 of 1069 Page 510 of 1069 Page 510 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 6. Accidental release measures Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling Ethyl alcohol ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. 8. Exposure controls/personal protection Ingredient name Exposure limits Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control Individual protection measures Occupational exposure limits 4/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 511 of 1069 Page 511 of 1069 Page 511 of 1069 Page 511 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection Hand protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Solid. [Presaturated Wipes] Not available. 0.985 [liquid preparations] Not available. Not available. Not available. Characteristic. Odor pH Presaturated Wipes (Clear. liquid) Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: >93.3°C (>199.9°F) liquid preparations Not available. 10.5 [liquid preparations] Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. 5/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 512 of 1069 Page 512 of 1069 Page 512 of 1069 Page 512 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Do not use with other products. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Ethyl alcohol Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Eyes - Moderate irritant Rabbit - 100 microliters - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 400 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - *Lysol® Disinfectant Wipes Lemon Lime Blossom Skin - Slight irritant Rabbit 1.5 - - Eyes - Cornea opacity Rabbit 0 - - Product/ingredient name Result Score Exposure Observation Conclusion/Summary Skin : Non-irritant to skin. Eyes : Non-irritating to the eyes. Information is based on toxicity test result of a similar product. Species Information on toxicological effects Sensitization *Lysol® Disinfectant Wipes Lemon Lime Blossom skin Guinea pig Not sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Non-sensitizer to skin. Ethyl alcohol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours LD50 Oral Rat 7 g/kg - *Lysol® Disinfectant Wipes Lemon Lime Blossom LC50 Inhalation Vapor Rat >2.04 mg/l 24 hours LD50 Dermal Rat >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - 6/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 513 of 1069 Page 513 of 1069 Page 513 of 1069 Page 513 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Classification Ethyl alcohol - 1 - Product/ingredient name NTP IARC OSHA Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. May cause eye irritation upon direct contact with eyes. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. 7/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 514 of 1069 Page 514 of 1069 Page 514 of 1069 Page 514 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Not available. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Not available. Acute toxicity estimates 12. Ecological information Toxicity Ethyl alcohol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 µg/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 µg/l Fresh water Fish - mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Product/ingredient name Species Result Exposure LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Ethyl alcohol -0.35 - low Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. 8/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 515 of 1069 Page 515 of 1069 Page 515 of 1069 Page 515 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods 14. Transport information Not a DOT controlled material (United States). Not a TDG-controlled material. This preparation is not classified as dangerous according to international transport regulations (ADR/RID, IMDG or ICAO/IATA). 15. Regulatory information U.S. Federal regulations TSCA 4(a) proposed test rules: Quaternary ammonium compounds, benzyl- chlorides : TSCA 8(a) PAIR: 2-(4-tert-butylbenzyl)propionaldehyde; bornan-2-one; 2-ol; nonanal; octanal; dodecanal; decanal; 2-methylundecanal; cinnamaldehyde; 3-p- α-hexylcinnamaldehyde; 2-benzylideneheptanal TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined. Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Not applicable. Composition/information on ingredients 9/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 516 of 1069 Page 516 of 1069 Page 516 of 1069 Page 516 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information CAUTION Signal word: Hazard statements May cause eye irritation. Wash hands after use. Avoid contact with eyes. Precautionary measures : : : Label elements The following components are listed: ETHYL ALCOHOL Massachusetts : New York : None of the components are listed. New Jersey : The following components are listed: ETHYL ALCOHOL; ALCOHOL : The following components are listed: DENATURED ALCOHOL State regulations Ethyl alcohol 1 - 2.5 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard 16. Other information Hazardous Material Information System 1 0 0 0 0 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Personal protection B 10/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 517 of 1069 Page 517 of 1069 Page 517 of 1069 Page 517 of 1069 ---PAGE BREAK--- D0314689 v6.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Date of previous issue Version : : : Indicates information that has changed from previously issued version. 27/04/2015. 21/04/2015 6 Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Prepared by : Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: [PHONE REDACTED] Revision comments : Addition of formula numbers and separated by fragrance. RB is a member of the CSPA Product Care Product Stewardship Program. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 11/11 27/04/2015. Date of issue : SDS # D0314689 (Lemon Lime Blossom) : Code # D0314689 v6.0 : Page 518 of 1069 Page 518 of 1069 Page 518 of 1069 Page 518 of 1069 ---PAGE BREAK--- Lysol® Dual Action Disinfecting Wipes Lysol® Xtra Large Dual Action Wipes Disinfectant. Wipes SAFETY DATA SHEET Product name Distributed by Product use 1. Product and company identification : : : D0289451 v5.0 : SDS # EPA ID No. 777-114 Formulation : Citrus (0356376 v1.0) 1825-054C Crisp Linen (0356378 v1.0) 1825-106B UPC Code / Sizes : 19200 81143 9 (35 wet wipes 7" x 8" sheets, Citrus) 19200 82050 9 (35 wet wipes 7" x 8" sheets, Crisp Linen) 19200 81700 4 (75 wet wipes 7" x 8" sheets, Citrus) 19200 83678 4 (24 wet wipes 8.4" x 10" sheets, Citrus) 19200 83679 1 (50 wet wipes 8.4" x 10" sheets, Citrus) : Lysol® Dual Action Disinfecting Wipes Lysol® Xtra Large Dual Action Wipes Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Classification of the substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B : Signal word : Warning Hazard statements : Causes eye irritation. Hazard pictograms : GHS label elements Not applicable. 1/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 519 of 1069 Page 519 of 1069 Page 519 of 1069 Page 519 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Supplemental label elements : None known. Hazards not otherwise classified : None known. General Prevention : Wear eye or face protection. Wash hands thoroughly after handling. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Not applicable. Disposal : Not applicable. : Keep out of reach of children. If medical advice is needed, have product container or label at hand. Precautionary statements 3. Composition/information on ingredients Mixture : Substance/mixture Ethyl alcohol 1 - 2.5 64-17-5 Quaternary ammonium compounds, chlorides 0.1-1 68424-85-1 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. If irritation persists, get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures 2/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 520 of 1069 Page 520 of 1069 Page 520 of 1069 Page 520 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. May be irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. Causes eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide No specific fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : 3/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 521 of 1069 Page 521 of 1069 Page 521 of 1069 Page 521 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section Do not ingest. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling 8. Exposure controls/personal protection Control Occupational exposure limits 4/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 522 of 1069 Page 522 of 1069 Page 522 of 1069 Page 522 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection Ethyl alcohol ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. Ingredient name Exposure limits Hand protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 5/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 523 of 1069 Page 523 of 1069 Page 523 of 1069 Page 523 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Solid. [Presaturated Wipes] Not available. 0.97 to 0.996 g/cm³ [20 to 25°C] (liquid preparation) Not available. Not available. Easily soluble in the following materials: cold water and hot water. Characteristic. Odor pH Not available. Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: >93.3°C (>199.9°F) (liquid preparation) Not available. 10.5 [Conc. w/w): 100%] (liquid preparation) Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Information on toxicological effects Ethyl alcohol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours LD50 Oral Rat 7 g/kg - *Lysol® Dual Action Disinfecting Wipes LC50 Inhalation Vapor Rat >2.04 mg/l 14 days LD50 Dermal Rat >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - 6/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 524 of 1069 Page 524 of 1069 Page 524 of 1069 Page 524 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Conclusion/Summary : Not classified Harmful *Information is based on toxicity test result of the concentrate of a similar product. Irritation/Corrosion Ethyl alcohol Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Eyes - Moderate irritant Rabbit - 100 microliters - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 400 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - *Lysol® Dual Action Disinfecting Wipes Eyes - Moderate irritant Rabbit - - - Skin - Slight irritant Rabbit 1.2 - - Product/ingredient name Result Score Exposure Observation Conclusion/Summary Skin : irritating to the skin. *Information is based on toxicity test result of the concentrate of a similar product. Eyes : Moderately irritating to eyes. *Information is based on toxicity test result of the concentrate of a similar product. Species Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Sensitization *Lysol® Dual Action Disinfecting Wipes skin Guinea pig Not sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Non-sensitizer to skin. *Information is based on toxicity test result of the concentrate of a similar product. Classification Ethyl alcohol - 1 - Product/ingredient name NTP IARC OSHA 7/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 525 of 1069 Page 525 of 1069 Page 525 of 1069 Page 525 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Not available. Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. May be irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. Causes eye irritation. : Eye contact No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. 8/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 526 of 1069 Page 526 of 1069 Page 526 of 1069 Page 526 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Not available. Acute toxicity estimates 12. Ecological information Toxicity Ethyl alcohol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 µg/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 µg/l Fresh water Fish - mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Product/ingredient name Species Result Exposure LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Ethyl alcohol -0.35 - low Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods 9/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 527 of 1069 Page 527 of 1069 Page 527 of 1069 Page 527 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 14. Transport information Not a DOT controlled material (United States). Not a TDG-controlled material. This preparation is not classified as dangerous according to international transport regulations (ADR/RID, IMDG or ICAO/IATA). 15. Regulatory information CAUTION Signal word: Hazard statements May cause eye irritation. : : Label elements U.S. Federal regulations TSCA 4(a) proposed test rules: Quaternary ammonium compounds, benzyl- chlorides : TSCA 8(a) PAIR: octanal; decanal; 2-methylundecanal; α- hexylcinnamaldehyde; phenylacetaldehyde TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined. Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed The following components are listed: ETHYL ALCOHOL Massachusetts : New York : None of the components are listed. New Jersey : The following components are listed: ETHYL ALCOHOL; ALCOHOL : The following components are listed: DENATURED ALCOHOL State regulations SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Immediate (acute) health hazard Ethyl alcohol 1 - 2.5 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients 10/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 528 of 1069 Page 528 of 1069 Page 528 of 1069 Page 528 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information Wash hands after use. Keep out of reach of children. Avoid contact with eyes. Precautionary measures : 16. Other information Hazardous Material Information System 1 1 0 0 1 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Date of issue Date of previous issue Version : : : : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. 18/12/2014. 17/08/2011 5 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Personal protection A Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 11/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 529 of 1069 Page 529 of 1069 Page 529 of 1069 Page 529 of 1069 ---PAGE BREAK--- D0289451 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Indicates information that has changed from previously issued version. Prepared by : Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: [PHONE REDACTED] Revision comments : Update of SDS per US GHS. RB is a member of the CSPA Product Care Product Stewardship Program. 12/12 18/12/2014. Date of issue : SDS # FF0356376_1_FF0356378_1 D0289451 v5.0 US GHS : Code # D0289451 v5.0 : Page 530 of 1069 Page 530 of 1069 Page 530 of 1069 Page 530 of 1069 ---PAGE BREAK--- Lysol® I.C. Brand III Disinfectant Spray Disinfectant. Professional use SAFETY DATA SHEET Product name Distributed by Product use 1. Product and company identification : : : D0313648 v5.0 : SDS # EPA ID No. 777-99-675 Formulation : 1589-023 (0271639 v1.0) UPC Code / Sizes : 36241-95029-08 (19 oz. Aerosol Can) : Lysol® I.C. Brand III Disinfectant Spray : Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] 2. Hazards identification Classification of the substance or mixture FLAMMABLE AEROSOLS - Category 2 : Signal word : Warning Hazard statements : Flammable aerosol. Pressurized container: may burst if heated. Hazard pictograms : GHS label elements Precautionary statements 1/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 531 of 1069 Page 531 of 1069 Page 531 of 1069 Page 531 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Supplemental label elements : None known. Hazards not otherwise classified : None known. General Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Response : Not applicable. Storage : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Disposal : Not applicable. : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. 3. Composition/information on ingredients Mixture : Substance/mixture Ethyl alcohol 30 - 60 64-17-5 butane 1 - 5 106-97-8 propane < 2.5 74-98-6 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures 2/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 532 of 1069 Page 532 of 1069 Page 532 of 1069 Page 532 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. May cause eye irritation upon direct contact with eyes. : Eye contact Over-exposure Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : 3/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 533 of 1069 Page 533 of 1069 Page 533 of 1069 Page 533 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 7. Handling and storage Conditions for safe storage, including any incompatibilities Do not store above the following temperature: 50°C (122°F). Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling 4/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 534 of 1069 Page 534 of 1069 Page 534 of 1069 Page 534 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM Ethyl alcohol ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. butane OSHA PEL 1989 (United States, 3/1989). TWA: 800 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. propane OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. 8. Exposure controls/personal protection Ingredient name Exposure limits Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Eye/face protection : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control Individual protection measures Occupational exposure limits 5/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 535 of 1069 Page 535 of 1069 Page 535 of 1069 Page 535 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Aerosol.] Not available. 0.8667 to 0.8967 g/cm³ [20 to 25°C] Not available. Not available. Easily soluble in the following materials: cold water and hot water. Characteristic. Odor pH Clear. Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: 25.6°C (78.1°F) Not available. 10.8 to 11.8 [Conc. w/w): 100%] Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Type of aerosol : Spray Aerosol product 6/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 536 of 1069 Page 536 of 1069 Page 536 of 1069 Page 536 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 9. Physical and chemical properties Heat of combustion : 17.99 kJ/g Ignition distance : <45.72 cm 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Do not mix with household chemicals. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Not classified Harmful. *Information is based on toxicity test result of the concentrate of a similar product. Irritation/Corrosion Ethyl alcohol Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Eyes - Moderate irritant Rabbit - 100 microliters - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 400 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - *Lysol I.C. Brand III Disinfectant Spray Eyes - Cornea opacity Rabbit < 1 72 hours 4 days Skin - Primary dermal irritation index (PDII) Rabbit 0.3 4 hours 72 hours Product/ingredient name Result Score Exposure Observation Conclusion/Summary Skin : irritating to the skin. *Information is based on toxicity test result of the concentrate of a similar product. Eyes : Moderately irritating to eyes. *Information is based on toxicity test result of the concentrate of a similar product. Species Information on toxicological effects Sensitization Ethyl alcohol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours LD50 Oral Rat 7 g/kg - *Lysol I.C. Brand III Disinfectant Spray LC50 Inhalation Vapor Rat >2.12 mg/l 4 hours Maximum attainable concentration 7/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 537 of 1069 Page 537 of 1069 Page 537 of 1069 Page 537 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Classification Ethyl alcohol - 1 - Product/ingredient name NTP IARC OSHA Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. May cause eye irritation upon direct contact with eyes. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation redness Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. 8/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 538 of 1069 Page 538 of 1069 Page 538 of 1069 Page 538 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Not available. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Not available. Acute toxicity estimates Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. 12. Ecological information Toxicity Ethyl alcohol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 µg/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 µg/l Fresh water Fish - mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Product/ingredient name Species Result Exposure LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Ethyl alcohol -0.35 - low Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. 9/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 539 of 1069 Page 539 of 1069 Page 539 of 1069 Page 539 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods 14. Transport information 2.1 Limited quantity DOT Classification TDG Classification 2.1 Aerosols, flammable - UN1950 Aerosols, flammable - IMDG Class Aerosols, flammable 2.1 - Aerosols, flammable UN1950 IATA-DGR Class 2.1 Regulatory information UN number Proper shipping name Classes PG* Label Additional information - UN1950 Limited quantity See DG List UN1950 Limited quantity Mexico Classification UN1950 Aerosols, flammable 2.1 - Limited quantity PG* : Packing group 15. Regulatory information U.S. Federal regulations Clean Water Act (CWA) 311: ammonia Clean Air Act (CAA) 112 regulated flammable substances: butane; propane : TSCA 8(a) PAIR: 2-(4-tert-butylbenzyl)propionaldehyde TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined. Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed 10/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 540 of 1069 Page 540 of 1069 Page 540 of 1069 Page 540 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information CAUTION Signal word: Hazard statements Causes moderate eye irritation Keep out of the reach of children. CONTENTS UNDER PRESSURE. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 120 Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Do not get in eyes, on skin or on clothing. Wash thoroughly after handling. Wash with soap and water. Precautionary measures : : : Label elements Hazard statements : Flammable DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed The following components are listed: ETHYL ALCOHOL; BUTANE; PROPANE Massachusetts : New York : None of the components are listed. New Jersey : The following components are listed: ETHYL ALCOHOL; ALCOHOL; BUTANE; PROPANE : The following components are listed: DENATURED ALCOHOL; BUTANE; PROPANE State regulations SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Fire hazard Ethyl alcohol 30 - 60 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients 11/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 541 of 1069 Page 541 of 1069 Page 541 of 1069 Page 541 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Hazardous Material Information System 1 3 0 0 3 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Date of issue Date of previous issue Version : : : : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. 26/06/2015. 12/05/2015. 5 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Personal protection B Level 1 NFPA (30B) aerosol Flammability Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 12/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 542 of 1069 Page 542 of 1069 Page 542 of 1069 Page 542 of 1069 ---PAGE BREAK--- D0313648 v5.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Indicates information that has changed from previously issued version. Prepared by : Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: [PHONE REDACTED] Revision comments : Revision as per US GHS. Correction to NFPA 30B level. RB is a member of the CSPA Product Care Product Stewardship Program. 13/13 26/06/2015. Date of issue : SDS # FF0271639 (D0313648) : Code # D0313648 v5.0 : Page 543 of 1069 Page 543 of 1069 Page 543 of 1069 Page 543 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Magic Countertop Cleaner & Polish January 16, 2015 1 / 6 Section 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Magic Countertop Cleaner & Polish Product Number: 3064C Product Use: Cleaner. Manufacturer/Supplier: Magic® 755 Tri-State Parkway Gurnee IL 60031 Phone Number: [PHONE REDACTED] Emergency Phone: 1-[PHONE REDACTED] Date of Preparation: January 16, 2015 Section 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER FLAMMABLE. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTENTS UNDER PRESSURE. CONTAINER MAY EXPLODE IF HEATED. Potential Health Effects: See Section 11 for more information. Likely Routes of Exposure: Skin contact, eye contact, inhalation, and ingestion. Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. Chronic Effects: Prolonged or repeated contact may dry skin and cause irritation. Signs and may include discomfort or pain, excess blinking and tear production. may include redness, edema, drying, defatting and cracking of the skin. May cause stomach distress, nausea or vomiting. Medical Conditions Aggravated By Exposure: Asthma. Allergies. Target Organs: Skin, eyes, gastrointestinal tract, respiratory system. Potential Environmental Effects: May cause long-term adverse effects in the aquatic environment. See Section 12 for more information. Section 3: COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS # Wt. % Propane 74-98-6 1 - 5 n-Butane 106-97-8 3 - 7 Section 4: FIRST AID MEASURES Eye Contact: In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if worn. If irritation persists, get medical attention. Skin Contact: If irritation occurs, flush skin with plenty of water. Call a physician if irritation persists. Page 544 of 1069 Page 544 of 1069 Page 544 of 1069 Page 544 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Magic Countertop Cleaner & Polish January 16, 2015 2 / 6 Inhalation: If breathed in, move person into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. Ingestion: DO NOT induce vomiting. If victim is conscious and alert, give 2 cupfuls of water. Never give anything by mouth to an unconscious person. Seek medical attention or call poison control immediately. General Advice: In case of accident or if you feel unwell, seek medical advice immediately (show the label or MSDS where possible). Note to Physicians: may not appear immediately. Section 5: FIRE FIGHTING MEASURES Flammability: Flammable by WHMIS criteria. Means of Extinction: Suitable Extinguishing Media: Powder, water spray, foam, carbon dioxide. Unsuitable Extinguishing Media: Not available. Products of Combustion: May include, and are not limited to: oxides of carbon. Explosion Data: Sensitivity to Mechanical Impact: Not available. Sensitivity to Static Discharge: Not available. Protection of Firefighters: Containers may explode when heated. Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. Ruptured cylinders may rocket. Environmental Precautions: Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of drains, sewers, ditches, and waterways. Minimize use of water to prevent environmental contamination. Methods for Containment: Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for Clean-Up: Scoop up material and place in a disposal container. Provide ventilation. Other Information: Not available. Section 7: HANDLING AND STORAGE Handling: Keep away from sources of ignition. No smoking. Avoid contact with skin and eyes. Do not swallow. Do not breathe gas/fumes/vapor/spray. Use only in well-ventilated areas. Handle container with care. When using do not eat or drink. Wash hands before eating, drinking, or smoking. Page 545 of 1069 Page 545 of 1069 Page 545 of 1069 Page 545 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Magic Countertop Cleaner & Polish January 16, 2015 3 / 6 Storage: Keep out of the reach of children. Keep container in a well-ventilated place. Do not store at temperatures above 49 °C / 120 Store away from direct sunlight or other heat sources. Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Exposure Limits Ingredient ACGIH-TLV Propane 1000 ppm n-Butane Not available. Engineering Controls: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal Protective Equipment: Eye/Face Protection: Wear eye/face protection. Hand Protection: Wear suitable gloves. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. General Hygiene Considerations: Handle according to established industrial hygiene and safety practices. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Foam. Colour: White. Odour: Citrus. Odour Threshold: Not available. Physical State: Gas/Pressurized Liquid. pH: Not available. Viscosity: 850cPs @ 40°C (100°F) Freezing Point: Not available. Boiling Point: Not available. Flash Point: Not available. Evaporation Rate: Not available. Lower Flammability Limit: Not available. Upper Flammability Limit: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Specific Gravity: 0.94 Solubility in Water: Not available. Coefficient of Water/Oil Distribution: Not available. Auto-ignition Temperature: Not available. Page 546 of 1069 Page 546 of 1069 Page 546 of 1069 Page 546 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Magic Countertop Cleaner & Polish January 16, 2015 4 / 6 Percent Volatile, wt. Not available. VOC content, wt. Not available. Section 10: STABILITY AND REACTIVITY Stability: Stable under normal storage conditions. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. Keep in a cool place. Conditions of Reactivity: Heat. Incompatible materials. Incompatible Materials: Strong oxidizers. Hazardous Decomposition Products: May include, and are not limited to: oxides of carbon. Possibility of Hazardous Reactions: No dangerous reaction known under conditions of normal use. Section 11: TOXICOLOGY INFORMATION EFFECTS OF ACUTE EXPOSURE Component Analysis Ingredient LD50 (oral) LC50 Propane Not available. 658 mg/L 4hr, rat n-Butane Not available. 658 g/m3 4hr, rat Eye: May cause eye irritation. may include discomfort or pain, excess blinking and tear production. Skin: May cause skin irritation. may include redness, edema, drying, defatting and cracking of the skin. Ingestion: May be harmful if swallowed. May cause stomach distress, nausea or vomiting. Inhalation: May cause respiratory tract irritation. EFFECTS OF CHRONIC EXPOSURE Target Organs: Not available. Chronic Effects: Not hazardous by WHMIS criteria. Carcinogenicity: Not hazardous by WHMIS criteria. Ingredient Chemical Listed as Carcinogen or Potential Carcinogen * Propane Not listed. n-Butane Not listed. * See Section 15 for more information. Mutagenicity: Not hazardous by WHMIS criteria. Reproductive Effects: Not hazardous by WHMIS criteria. Developmental Effects: Teratogenicity: Not hazardous by WHMIS criteria. Embryotoxicity: Not hazardous by WHMIS criteria. Respiratory Sensitization: Not hazardous by WHMIS criteria. Page 547 of 1069 Page 547 of 1069 Page 547 of 1069 Page 547 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Magic Countertop Cleaner & Polish January 16, 2015 5 / 6 Skin Sensitization: Not hazardous by WHMIS criteria. Toxicologically Synergistic Materials: Not available. Section 12: ECOLOGICAL INFORMATION Ecotoxicity: May cause long-term adverse effects in the aquatic environment. Persistence / Degradability: Not available. Bioaccumulation / Accumulation: Not available. Mobility in Environment: Not available. Section 13: DISPOSAL CONSIDERATIONS Disposal Instructions: This material must be disposed of in accordance with all local, state, provincial, and federal regulations. Section 14: TRANSPORTATION INFORMATION TDG Classification UN1950; Aerosols, flammable; Class 2.1 Limited Quantity 1L) Section 15: REGULATORY INFORMATION Federal Regulations Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Global Inventories Ingredient Canada DSL/NDSL Propane DSL n-Butane DSL HMIS - Hazardous Materials Identification System Health - 0 Flammability - 2 Physical Hazard - 0 PPE – B NFPA - National Fire Protection Association: Health - 0 Fire - 2 Reactivity - 0 Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme WHMIS Classification(s): Class A - Compressed Gas Class B5 - Flammable Aerosol WHMIS Hazard Symbols: Page 548 of 1069 Page 548 of 1069 Page 548 of 1069 Page 548 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Magic Countertop Cleaner & Polish January 16, 2015 6 / 6 SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: ACGIH American Conference of Governmental Industrial Hygienists. A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen. IARC International Agency for Research on Cancer. 1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans. 4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans. NTP National Toxicology Program. 1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens. Section 16: OTHER INFORMATION Disclaimer: The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use. Expiry Date: January 16, 2018 Version 1.0 Prepared by: Nexreg Compliance Inc. Phone: (519) 488-5126 www.nexreg.com Page 549 of 1069 Page 549 of 1069 Page 549 of 1069 Page 549 of 1069 ---PAGE BREAK--- Magic® Sizing Page 1 MSDS Number: 00502 November 11, 2013 MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Identification Product Name: Magic® Sizing Product Number: 00502, 00522, 00562, 00601, 00504, 00520, 00530, 00516, 00519 Company Identification Faultless Starch / Bon Ami Co. 1025 W 8th Street Kansas City, MO 64101 1-[PHONE REDACTED] (For product information) 1-[PHONE REDACTED] or 1-[PHONE REDACTED] (For emergencies) 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Amount CAS Number BUTANE Confidential 106-97-8 PROPANE Confidential 74-98-6 ISOBUTANE Confidential 75-28-5 (See Section 8 for exposure guidelines) (See Section 15 for regulatory information) 3. HAZARDS IDENTIFICATION NFPA Rating: Health - 1, Flammability - 0, Reactivity - 1 POTENTIAL HEALTH EFFECTS INHALATION RISKS AND OF EXPOSURE: No hazard in normal industrial use. SKIN / EYE CONTACT RISKS AND OF EXPOSURE: Not a skin or eye irritant. SKIN ABSORPTION RISKS AND OF EXPOSURE: None known. Page 550 of 1069 Page 550 of 1069 Page 550 of 1069 Page 550 of 1069 ---PAGE BREAK--- Magic® Sizing Page 2 MSDS Number: 00502 November 11, 2013 (section 3 continued) INGESTION RISKS AND OF EXPOSURE: Not toxic according to Federal Hazardous Substance and Labeling Act. HEALTH HAZARDS (ACUTE AND CHRONIC): Not an eye, skin, or respiratory irritant, nor toxic by ingestion according to Federal Hazardous Substances & Labeling Act Regulations. No health hazards known after many years of constant exposure to production employees, laboratory personnel, and consumers. CARCINOGENICITY INFORMATION: Not listed by IARC or NTP as a carcinogen. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known. 4. FIRST AID MEASURES EYE CONTACT FIRST AID: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. INHALATION FIRST AID: No specific treatment is necessary since this material is not likely to be hazardous by inhalation. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES COC Flash Point: N/A Autoignition Temperature: N/A FLAMMABLE LIMITS IN AIR LEL: N/A UEL: N/A EXTINGUISHING MEDIA: Water, carbon dioxide, foam or dry powder. SPECIAL FIRE FIGHTING PROCEDURES: Use procedures recommended when aerosols are present. UNUSUAL FIRE AND EXPLOSION HAZARDS: As with all aerosols, fire or excessive heat can cause containers to rupture. Page 551 of 1069 Page 551 of 1069 Page 551 of 1069 Page 551 of 1069 ---PAGE BREAK--- Magic® Sizing Page 3 MSDS Number: 00502 November 11, 2013 6. ACCIDENTAL RELEASE MEASURES ACTIONS IF MATERIAL IS RELEASED OR SPILLED: No special requirements. 7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Contents under pressure. Do not expose to heat or store at temperatures above 120 Deg F (as required with all aerosols). Use reasonable care when using. OTHER PRECAUTIONS: Avoid spraying into eyes and inhaling spray. Read and follow label CAUTIONS carefully. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: Not required. VENTILATION: All aerosol products should be used with adequate ventilation. PROTECTIVE GLOVES: Not required. EYE PROTECTION: Recommend approved safety glasses. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None required. WORK / HYGIENIC PRACTICES: Observe resonable care, cleanliness, and caution. EXPOSURE GUIDELINES: BUTANE OSHA PEL: 800 ppm PROPANE OSHA PEL: 1000 ppm Page 552 of 1069 Page 552 of 1069 Page 552 of 1069 Page 552 of 1069 ---PAGE BREAK--- Magic® Sizing Page 4 MSDS Number: 00502 November 11, 2013 9. PHYSICAL AND CHEMICAL PROPERTIES FORM Aerosol COLOR Clear ODOR Pleasant BOILING POINT 212 F VAPOR DENSITY N/A (Air = 1) SOLUBILITY IN WATER 95% - 96% SPECIFIC GRAVITY 1.005 g/ml (Water = 1) PH ~9.8 10. STABILITY AND REACTIVITY STABILITY: Stable. CONDITIONS TO AVOID: Exposure to heat. INCOMPATIBILITY (MATERIALS TO AVOID): Oxygen and strong oxidizing materials. HAZARDOUS DECOMPOSITION OR BYPRODUCTS: If incinerated, carbon dioxide and carbon monoxide will be generated. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL INFORMATION No information available. 12. ECOLOGICAL INFORMATION No information available. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: No special method required. Liquid can be flushed into sewer because no hazardous materials are contained in the liquid phase. Page 553 of 1069 Page 553 of 1069 Page 553 of 1069 Page 553 of 1069 ---PAGE BREAK--- Magic® Sizing Page 5 MSDS Number: 00502 November 11, 2013 14. TRANSPORTATION INFORMATION PRODUCT Magic® Sizing D.O.T. SHIPPING NAME...: Consumer Commodity D.O.T. HAZARD CLASS....: ORM-D UN 1950 Class 2.2 15. REGULATORY INFORMATION CHEMICAL INVENTORY INFORMATION: This material or all of its components are listed on the Inventory of Existing Chemical Substances under the Toxic Substance Control Act (TSCA). MISCELLANEOUS INFORMATION: No toxic chemical(s) subject to the reporting requirements of section 313 Title III and of 40 CFR 372 are present. 16. OTHER INFORMATION Reason For Issue...: Revise approval date Approval November 11, 2013 Supercedes Date....: June 20, 2011 MSDS Number........: 00502 RTN 00000502 (Official Copy) The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable and suitable to their circumstances. END OF MSDS Page 554 of 1069 Page 554 of 1069 Page 554 of 1069 Page 554 of 1069 ---PAGE BREAK--- SPI-Chem™SPI Supplies Division Structure Probe, Inc. P.O. Box 656 West Chester, PA 19381-0656 USA Phone: 1-(610)-436-5400 Fax: 1-(610)-436-5755 E-mail: [EMAIL REDACTED] WWW: http://www.2spi.com Manufacturer's CAGE: 1P573 Material Safety Data Sheet SPI# 17022-AB/#17022-AA Microshield™Masking Aid and Protectant Section 01 Identification Date Effective......... January 8, 2009 (most recent revision) Chemical Name/Synonyms. Microshield Chemical Family........ Organic solvents and polymers Emergencies Contacting CHEMTREC 24 Hour Emergency Use Only Worldwide phone : 1-(703)-527-3887 Worldwide FAX : 1-(703)-741-6090 Toll-free phone : 1-(800)-424-9300 USA only Product or Trade Name.. Microshield Varnish and Protectant CAS None assigned to formulated composition (see below) Section 2 Composition See below, Section 3. Section 3: Hazard Identification Chemical Names CAS # % Wt TLV-TWA PEL Sec.313 7KH LP DJ H EH GLVSOD\ HG 7KH ILOH P D\ KDYH EHHQ P RYHG UHQDP HG R« 7KH LP DJ H EH GLVSOD\ HG 7KH ILOH P D\ KDYH EHHQ P RYHG UHQDP HG R« Page 555 of 1069 Page 555 of 1069 Page 555 of 1069 Page 555 of 1069 ---PAGE BREAK--- Methyl ethyl ketone 78-93-3 5-15 200 ppm 200 ppm Yes Toluene 108-88-3 40-50 100 ppm 100 ppm Yes Tetrahydrofuran 109-99-9 15-25 200 ppm 200 ppm No Propylene oxide 75-56-9 1-3 20 ppm 20 ppm Yes Orange pigment solvent yellow 14 842-07-9 0.6 Yes Emergency overview: Material is highly volatile and flammable. Vapors are heavier than air and may travel along low areas to source of ignition. Physical Health Hazards: Can cause eye irritation on contact, inhalation can cause dizziness and ingestion can cause serious gastrointestinal difficulties including nausea and vomiting. Skin contact can cause defatting of the skin and solvents can penetrate the skin in to the body. Physical state: Liquid Color: Reddish orange Odor: Ketone type Odor threshold: No data available Potential Health Effects: Routes of exposure Eye contact, ingestion, skin contact, inhalation Section 4: First Aid Measures Take proper precautions to ensure your own health and safety before attempting to rescue and providing first aid. For specific information refer to the Emergency Overview in Section of this MSDS. Inhalation: Remove to fresh air. Never give liquids to an unconscious person. Page 556 of 1069 Page 556 of 1069 Page 556 of 1069 Page 556 of 1069 ---PAGE BREAK--- Call medical assistance at once. Eye Contact: Wash eyes with clean low-pressure water. Seek medical advice. Skin Contact: Wash with soap and water. Ingestion: Do not induce vomiting, seek medical attention at once. Section 5: Fire Fighting Measures Flammability classification: HMIS rating: Health Hazard: 3 Fire Hazard: 3 Reactivity: 0 Flash Point/Method: -1.1°C (30°F) Auto-Ignition Temperature: Not determined Flammable Limits Lower: LEL: 2% Upper: UEL: 10% Hazardous Combustion Products: Thermal decomposition may liberate carbon monoxide and carbon dioxide. Special Conditions to Avoid: Materials to avoid: Strong oxidizing agents Conditions to avoid: Heat or ignition sources Extinguishing Media: Small fires: Use dry chemicals, CO2, alcohol type foam. Fire Fighting Instructions: Special exposure hazards: None known Special protective equipment: Self contained breathing apparatus and personal protective equipment. Page 557 of 1069 Page 557 of 1069 Page 557 of 1069 Page 557 of 1069 ---PAGE BREAK--- Section 6: Accidental Release Measures Release response: Personal precautions: Spilled product constitutes a slip hazard. Environmental precautions: Try to keep liquid from getting into sewers or drainage of building. Decontamination procedures: Use absorbent materials, to soak up spilled liquid, which is then placed in containers for later disposal as a hazardous waste. See paragraph 13 regarding disposal. Section 7: Handling and Storage Handling: Wear NIOSH approved respirator is point-of-use generates vapors above recommended limits. Ventilation: Local exhaust is required. Protective clothing: Long sleeve shirt, trousers, safety shoes, solvent resistant gloves. Eye protection: Chemical splash goggles Other precautions: Wash hands with soap and water before handling food. Material is flammable, store in a cool dry area away from heat sources. Page 558 of 1069 Page 558 of 1069 Page 558 of 1069 Page 558 of 1069 ---PAGE BREAK--- Storage: Keep cap screwed on to protect integrity of the product and to keep vapors from escaping into the environment. Empty containers may contain residual vapors. Section 8: Exposure Controls and Personal Protection Engineering Controls: Local exhaust ventilation Personal Protection: Inhalation: Wash hands after use, using soap and water to remove all residues of the product. Skin: Solvent resistant gloves Eye: Always use safety chemical goggles when handling this material. Section 9: Physical and Chemical Properties Physical State: Liquid Odor: Ketone Flash Point: > -1.1°C (30°F) Boiling Point/Range 760 mm Hg: 65°C (149°F) Explosive Limits: Not determined Water Solubility: Not soluble Color: Reddish orange liquid Melting Point: Not known Autoignition Point: Not determined pH: Not applicable Vapor Pressure: Not determined Viscosity: Not applicable Vapor density (air = 2.9 Page 559 of 1069 Page 559 of 1069 Page 559 of 1069 Page 559 of 1069 ---PAGE BREAK--- Octanol/Water Partition Coefficient in Kow: Specific value not known Evaporation Rate: Very low Specific Gravity: 0.95 Evaporation Rate (BuAc = 3.5 Section 10: Stability and Reactivity Chemical Stability: The product is stable and will not polymerize. Conditions to Avoid: Elevated temperatures and ignition sources Incompatibility with: Strong oxidizing agents. Hazardous Products of Deposition: Thermal decomposition may liberate carbon monoxide and carbon dioxide. Reactions with Air and Water: Does not react with air, water or other common materials. Section 11: Toxicological Information Based on the product's components: Acute Health Effects: Eyes: May cause transient irritation from vapors, irritation and blurred vision from prolonged exposure to vapors or direct contact. Inhalation: Dizziness, nausea, headache, fatigue Ingestion: Gastrointestinal discomfort including irritation of Page 560 of 1069 Page 560 of 1069 Page 560 of 1069 Page 560 of 1069 ---PAGE BREAK--- gastrointestinal tract, nausea, and vomiting. Chronic Health Effects: Dizziness, fatigue, nausea, possible vomiting, possible skin irritation. Prolonged exposure may aggravate preexisting lung and skin disorders. Chronic Effects/Carcinogenicity: Not known about formulated composition, however exposure to toluene is thought to be carcinogenic. Reproductive/Development Effects: Not known Section 12: Ecological Information Environmental: When used and/or disposed of as indicated, no adverse environmental effects are foreseen. Mobility: Non-volatile/Insoluble in water. Degradability: Not known. Section 13: Disposal Considerations Product and packaging must be disposed of in accordance with local and national regulations. Maybe incinerated. This material IS classified as a hazardous waste. It must be disposed of in accordance with all federal, state, and local regulations. Use only licensed transporters and permitted disposal facilities and conform to all laws. Section 14: Transport Information Material is classified as hazardous for transport by air, sea, or road. Page 561 of 1069 Page 561 of 1069 Page 561 of 1069 Page 561 of 1069 ---PAGE BREAK--- Proper Shipping Name: Flammable Liquid Class 3 DOT Hazard Class: Flammable Liquid Class 3, UN #1263 Packing Group: II Labels: Flammable Marine Pollutant: Not known NAER Guidebook: Not known DOT Status: Flammable Section 15: Regulatory Information TSCA: All components of this product are listed on the TSCA 8(b) inventory. If identified components of this product are listed under the TSCA 12(b) Export Notification Rule, they will be listed below. TSCA 12(b) Component Listed under TSCA Section SARA-Section 313 Emissions Reporting: Component Reporting Threshold Methyl ethyl ketone Toluene Propylene Oxide Orange pigment solvent Yellow 14 SARA-Section 311/312: . CERCLA Hazardous Substances and their Reportable Quantities: Component Reportable Quantity Section 16: Other Information Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or Page 562 of 1069 Page 562 of 1069 Page 562 of 1069 Page 562 of 1069 ---PAGE BREAK--- blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids. The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. To Ask a Question or Make a Comment To Place an Order or Request a Quote Return to: • Microshield™Masking Aid Main Page • SPI Supplies MSDS Safety Sheets Table of Contents • SPI Supplies Catalog Table of Contents • SPI Supplies Home Page Wednesday October 06, 2010 © Copyright 1999 - 2010. By Structure Probe, Inc. Contacting SPI Supplies and Structure Probe, Inc. All rights reserved. All trademarks and trade names are the property of their respective owners. Privacy Policy Worldwide Distributors, Representatives, and Agents 7KH LP DJ H EH GLVSOD\ HG 7KH ILOH P D\ KDYH EHHQ P RYHG UHQDP HG R« 7KH LP DJ H EH GLVSOD\ HG 7KH ILOH P D\ KDYH EHHQ P RYHG UHQDP HG R« 7KH LP DJ H EH GLVSOD\ HG 7KH ILOH P D\ KDYH EHHQ P RYHG UHQDP HG R« 7KH LP DJ H EH GLVSOD\ HG 7KH ILOH P D\ KDYH EHHQ P RYHG UHQDP HG R« Page 563 of 1069 Page 563 of 1069 Page 563 of 1069 Page 563 of 1069 ---PAGE BREAK--- Page:1/10 Latest revision date: 05/29/2015 Version: 1.0 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 United States Material Safety Data Sheet Scotts Miracle-Gro Products Inc. 14111 Scottslawn Road Marysville, Ohio 43041 United States MIRACLE GRO SHAKE 'N FEED CONTINUOUS RELEASE BLOOM BOOSTER PLANT FOOD 10-16-10 Section 1. Identification GHS product identifier : MIRACLE GRO SHAKE 'N FEED CONTINUOUS RELEASE BLOOM BOOSTER PLANT FOOD 10-16-10 Product type : Fertilizer SDS # : 320000000193 Relevant identified uses of the substance or mixture and uses advised against Use only in accordance with label directions. Section 2. Hazards identification This product is regulated by the Consumer Product Safety Commission (CPSC) for label precautionary text see Section 15. OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this MSDS contains valuable information critical to the safe handling and proper use of the product. This MSDS should be retained and available for employees and other users of this product. Classification of the substance or mixture : Not classified. GHS label elements Signal word : None Hazard statements : No known significant effects or critical hazards. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Not applicable. Page 564 of 1069 Page 564 of 1069 Page 564 of 1069 Page 564 of 1069 ---PAGE BREAK--- Page:2/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. Supplemental label elements : None known. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Substance/mixture : Mixture Chemical name : Not available. Other means of identification : Not available. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Most important acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Indication of immediate medical attention and special treatment needed, if necessary Over-exposure Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Page 565 of 1069 Page 565 of 1069 Page 565 of 1069 Page 565 of 1069 ---PAGE BREAK--- Page:3/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. Unsuitable extinguishing media : None known. Specific hazards arising from the chemical : No specific fire or explosion hazard. Hazardous thermal decomposition products : No specific data. Special protective actions for fire- fighters : isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Page 566 of 1069 Page 566 of 1069 Page 566 of 1069 Page 566 of 1069 ---PAGE BREAK--- Page:4/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 Spill : Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, including any incompatibilities : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used Page 567 of 1069 Page 567 of 1069 Page 567 of 1069 Page 567 of 1069 ---PAGE BREAK--- Page:5/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state : solid [Granular] Color : Green. Odor : Fertilizer Odor threshold : Not available. pH : Not available. Melting point : Not available. Boiling point : Not available. Flash point : Not available. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: Not available. Upper: Not available. Vapor pressure : Not available. Vapor density : Not available. Relative density : Not available. Solubility : Not available. Partition coefficient: n- octanol/water : Not available. Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Dynamic: Not available. Page 568 of 1069 Page 568 of 1069 Page 568 of 1069 Page 568 of 1069 ---PAGE BREAK--- Page:6/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 Kinematic: Not available. Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure LD50 Oral Rat > 5,000 mg/kg - LC50 Inhalation Rat > 5 mg/l 4 h LD50 Dermal Rat > 5,000 mg/kg - Conclusion/Summary : No known significant effects or critical hazards. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Eyes - Redness of the conjunctivae Rabbit 1.0 - Skin - Erythema/Es char Rabbit 1.0 - Conclusion/Summary Skin : Non-irritating Eyes : May cause eye irritation. Respiratory : May cause respiratory irritation Sensitization Product/ingredient name Route of exposure Species Result Skin Guinea pig Not sensitizing Page 569 of 1069 Page 569 of 1069 Page 569 of 1069 Page 569 of 1069 ---PAGE BREAK--- Page:7/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 Conclusion/Summary Skin : Not sensitizing - based on the individual components. Respiratory : Not sensitizing - based on the individual components. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity Conclusion/Summary : No known significant effects or critical hazards. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Velcro Closure Information on the likely routes of exposure : Not available. Potential chronic health effects Conclusion/Summary : No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Section 12. Ecological information Toxicity Conclusion/Summary : Not available. Page 570 of 1069 Page 570 of 1069 Page 570 of 1069 Page 570 of 1069 ---PAGE BREAK--- Page:8/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 Persistence and degradability Conclusion/Summary : Not available. Mobility in soil Soil/water partition coefficient (KOC) : Not available. Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information Regulatory information UN no. Proper shipping name Class PG* Note DOT Not Regulated IATA Not Regulated IATA IMDG Not Regulated TDG Not Regulated PG* : Packing group Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Page 571 of 1069 Page 571 of 1069 Page 571 of 1069 Page 571 of 1069 ---PAGE BREAK--- Page:9/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 Section 15. Regulatory information Precautionary statements Signal word : No signal word. Emergency Overview : Keep out of reach of children. U.S. Federal regulations : United States inventory (TSCA 8b): Not determined. State regulations California Prop. 65 Not available. International lists National inventory Australia : Not determined. Canada : Not determined. China : Not determined. Europe : Not determined. Japan : Not determined. Malaysia : Not determined. New Zealand : Not determined. Philippines : Not determined. Republic of Korea : Not determined. Taiwan : Not determined. Section 16. Other information National Fire Protection Association Flammability Health Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity 0 0 1 Page 572 of 1069 Page 572 of 1069 Page 572 of 1069 Page 572 of 1069 ---PAGE BREAK--- Page:10/10 Version: Report version.Re port version Date of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of issue/Date of revision : Validity date***. Version : Report version.Report version Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 573 of 1069 Page 573 of 1069 Page 573 of 1069 Page 573 of 1069 ---PAGE BREAK--- Page:1/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name : Miracle-Gro Growmore Product code : Not available Product description : Fertiliser Specification Number : 320000005041 Product type : Solid Other means of identification : 300000004822 1.2 Relevant identified uses of the substance or mixture and uses advised against Specific uses : For use only as a home garden fertiliser. 1.3 Details of the supplier of the safety data sheet The Scotts Company (UK) Limited Salisbury House, Weyside Park, Catteshall Lane Godalming, Surrey GU7 1XE United Kingdom Email: [EMAIL REDACTED] 1.4 Emergency telephone number National advisory body/Poison Center 24 h. EMERGENCY TELEPHONE NUMBER : 01865 407 333 Non-Emergency Calls : 0845 190 1881 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Mixture Classification according to Directive 1999/45/EC [DPD] The product is not classified as dangerous according to Directive 67/548/EEC and its amendments. Classification : Not classified. Page 574 of 1069 Page 574 of 1069 Page 574 of 1069 Page 574 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:2/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 See Section 16 for the full text of the R phrases declared above. See Section 11 for more detailed information on health effects and 2.2 Label elements Risk phrases : This product is not classified according to EU legislation. Safety phrases : S2 Keep out of the reach of children. Supplemental label elements : Not applicable. Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles : Not applicable. Special packaging requirements Containers to be fitted with child-resistant fastenings : Not applicable. Tactile warning of danger : Not applicable. 2.3 Other hazards Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII : Not available. Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII : Not available. Other hazards which do not result in classification : None known. SECTION 3: Composition/information on ingredients Substance/mixture : Mixture There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. SECTION 4: First aid measures 4.1 Description of first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Skin contact : Wash contaminated skin with plenty of soap and water. Remove contaminated clothing. Wash before reuse. Get medical attention if occur. Page 575 of 1069 Page 575 of 1069 Page 575 of 1069 Page 575 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:3/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. 4.2 Most important and effects, both acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. Unsuitable extinguishing media : None known. 5.2 Special hazards arising from the substance or mixture Hazards from the substance or mixture : No specific fire or explosion hazard. Hazardous thermal decomposition products : No specific data. 5.3 Advice for firefighters Special protective actions for fire-fighters : isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Additional information : Not available. Page 576 of 1069 Page 576 of 1069 Page 576 of 1069 Page 576 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:4/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". 6.2 Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3 Methods and materials for containment and cleaning up Small spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Large spill : Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. 6.4 Reference to other sections : See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. SECTION 7: Handling and storage The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 7.1 Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Page 577 of 1069 Page 577 of 1069 Page 577 of 1069 Page 577 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:5/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 7.3 Specific end use(s) Recommendations : Not available. Industrial sector specific solutions : Not available. SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 8.1 Control parameters Occupational exposure limits Ingredient name Occupational exposure limits No exposure limit values known. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required. DNEL/DMEL Summary : Not available. PNEC Summary : Not available. 8.2 Exposure controls Appropriate engineering controls : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Page 578 of 1069 Page 578 of 1069 Page 578 of 1069 Page 578 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:6/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state : Solid, granular Color : Beige Odour : Fertiliser 9.2 Other information No additional information. SECTION 10: Stability and reactivity 10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical stability : The product is stable. 10.3 Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to avoid : No specific data. 10.5 Incompatible materials : No specific data. 10.6 Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Page 579 of 1069 Page 579 of 1069 Page 579 of 1069 Page 579 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:7/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Conclusion/Summary : Not available. Acute toxicity estimates Not available. Irritation/Corrosion Conclusion/Summary Skin : Not available. Eyes : Not available. Respiratory : Not available. Sensitization Conclusion/Summary Skin : Not available. Respiratory : Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely routes of exposure : Not available. Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Page 580 of 1069 Page 580 of 1069 Page 580 of 1069 Page 580 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:8/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 Long term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Potential chronic health effects Conclusion/Summary : Not available. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. SECTION 12: Ecological information 12.1 Toxicity Conclusion/Summary : Not available. 12.2 Persistence and degradability Conclusion/Summary : Not available. 12.3 Bioaccumulative potential Product/ingredient name LogPow BCF Potential Not Applicable - - - 12.4 Mobility in soil Soil/water partition coefficient (KOC) : Not available. Mobility : Not available. 12.5 Results of PBT and vPvB assessment PBT : P: Not available. B: Not available. T: Not available. vPvB : vP: Not available. vB: Not available. 12.6 Other adverse effects : No known significant effects or critical hazards. SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Product Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products Page 581 of 1069 Page 581 of 1069 Page 581 of 1069 Page 581 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:9/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Do not contaminate water with the product or its container. Hazardous waste : Within the present knowledge of the supplier, this product is not regarded as hazardous waste, as defined by EU Directive 91/689/EEC. Packaging Methods of disposal : Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. SECTION 14: Transport information ADR/RID ADN IMDG IATA 14.1 UN number - - - - 14.2 UN proper shipping name Not classified as dangerous Not classified as dangerous Not classified as dangerous Not classified as dangerous 14.3 Transport hazard class(es) Not applicable Not applicable Not applicable Not applicable 14.4 Packing group - - - - 14.5. Environmental hazards No. No. No. No. Additional information Tunnel code: - 14.6 Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.’ 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not available. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization Substances of very high concern Carcinogen: Not listed Mutagen: Not listed Toxic to reproduction: Not listed PBT: Not listed vPvB: Not listed Page 582 of 1069 Page 582 of 1069 Page 582 of 1069 Page 582 of 1069 ---PAGE BREAK--- Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Miracle-Gro Growmore Page:10/10 Version: 1.1 Date of issue/Date of revision: 01.05.2014 Date of previous issue: 30.08.2013 Other EU regulations Europe inventory : Not determined. Integrated pollution prevention and control list (IPPC) - Air : Not listed Integrated pollution prevention and control list (IPPC) - Water : Not listed Aerosol dispensers : Not applicable. Seveso III Directive This product is not controlled under the Seveso III Directive. 15.2 Chemical Safety Assessment : Not available. SECTION 16: Other information Abbreviations and acronyms : ADN = European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR = European Agreement concerning the International Carriage of Dangerous Goods by Inland Road IATA = International Air Transport Association IMDG = International Maritime Dangerous Good Code ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level DMEL = Derived Minimal Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number PBT = Persistent, Bioaccumulative and Toxic vPvB = Very Persistent and Very Bioaccumulative Full text of abbreviated H statements : Not applicable. Full text of classifications [CLP/GHS] : Not applicable. Full text of abbreviated R phrases : Not applicable. Full text of classifications [DSD/DPD] : Not applicable. Date of printing : 01.05.2014 Date of issue/ Date of revision : 01.05.2014 Date of previous issue : 30.08.2013 Version : 1.1 Prepared by : SSouch Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 583 of 1069 Page 583 of 1069 Page 583 of 1069 Page 583 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET This MSDS complies with OSHA'S Hazard Communication Standard 29 CFR 1910.1200 and OSHA Form 174 IDENTITY AND MANUFACTURER'S INFORMATION NFPA Rating: Health-1; Flammability-1; Reactivity-0; Special- - HMIS Rating: Health-1; Flammability-1; Reactivity-0; Personal Protection-B Manufacturer's Name: AMREP, INC. Address: 990 Industrial Park Drive Marietta, GA 30062 DOT Hazard Classification: ORM-D Identity (trade name as used on label): MISTY ASPIRE FURNITURE CLEANER & POLISH Date Prepared: 08/25/08 Prepared By: IB MSDS Number: A00133 Revision- first issue Information Calls: (770)422-2071 EMERGENCY RESPONSE NUMBER: 1(800)255-3924 NOTICE: JUDGEMENT BASED ON INDIRECT TEST DATA SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION COMPONENTS-CHEMICAL NAMES AND COMMON NAMES (Hazardous Components 1% or greater; Carcinogens 0.1% or greater) CAS Number SARA III LIST OSHA PEL (ppm) ACGIH TLV (ppm) Carcinogen Ref. Source NEW JERSEY TRADE SECRET REGISTRY NUMBER AMR-A00133 proprietary No NE NE d SECTION 2 - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: N/A Specific Gravity (H2O=1): Concentrate Only = 0.95 Vapor Pressure: PSIG @ 70°F (Aerosols): Max. 120 Vapor Pressure (Non-Aerosols)(mm Hg and Temperature): N/A Vapor Density (Air = N/E Evaporation Rate ( BuAc = Slower Solubility in Water: Soluble Water Reactive: No Appearance and Odor: Foaming spray with lemon odor. SECTION 3 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY as per USA FLAME PROJECTION TEST (aerosols) : NO FLAME PROJECTION: NOT CATEGORIZED AS FLAMMABLE Auto Ignition Temperature N/E Flammability Limits in Air by % in Volume: % LEL: N/E % UEL: N/E FLASH POINT AND METHOD USED (non-aerosols): N/A SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus. EXTINGUISHER MEDIA: Foam, dry chemical, carbon dioxide. Unusual Fire & Explosion Hazards: Do not expose aerosols to temperatures above 130°F or the container may rupture. SECTION 4 - REACTIVITY HAZARD DATA STABILITY [ X ] STABLE [ ] UNSTABLE HAZARDOUS POLYMERIZATION [ ] WILL [ X ] WILL NOT OCCUR Incompatibility (Mat. to avoid):Strong oxidizers. Conditions to Avoid: Open flame, welding arcs, heat, sparks. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, oxides of nitrogen. SECTION 5 - HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: [ X ] INHALATION [ ] INGESTION [ X ] SKIN ABSORPTION EYE [ ] NOT HAZARDOUS ACUTE EFFECTS Inhalation: Excessive inhalation of vapors can be harmful & may cause headache, dizziness, anesthetic effects & possible unconsciousness. Eye Contact: May cause slight irritation. Skin Contact: May cause slight irritation. Ingestion: Possible chemical pneumonitis if aspirated into lungs. CHRONIC EFFECTS: None Known. Medical Conditions Generally Aggravated by Exposure: May aggravate existing eye, skin, or upper respiratory conditions. EMERGENCY FIRST AID PROCEDURES Eye Contact: Flush with water for 15 minutes. If irritated, seek medical attention. Skin Contact: Wash with soap and water. If irritated, seek medical attention. Inhalation: Remove to fresh air. Resuscitate if necessary. Get medical attention. Ingestion: DO NOT INDUCE VOMITING. Drink two large glasses of water. Get immediate medical attention. SECTION 6 - CONTROL AND PROTECTIVE MEASURES Respiratory Protection (specify type): If vapor concentration exceeds TLV, use respirator approved by NIOSH to be used in a positive pressure mode. Protective Gloves: Gloves suggested. Nitrile, latex. Eye Protection: Safety glasses recommended. Ventilation Requirements: Adequate ventilation to keep vapor concentration below TLV. Other Protective Clothing & Equipment: None Hygienic Work Practices: Wash with soap and water before handling food. Remove contaminated clothing. SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE Steps To Be Taken If Material Is Spilled Or Released: Flush to sewer with water. Waste Disposal Methods: Aerosol cans when vented to atmospheric pressure through normal use, pose no disposal hazard. Precautions To Be Taken In Handling & Storage: Do not puncture or incinerate containers. Do not store at temperatures above 130°F. Other Precautions &/or Special Hazards: KEEP OUT OF REACH OF CHILDREN. Avoid food contamination. Avoid breathing vapors. We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. Chemical Listed as Carcinogen or Potential Carcinogen. NTP IARC Monograph OSHA Not Listed Animal Data Only Page 584 of 1069 Page 584 of 1069 Page 584 of 1069 Page 584 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Misty Crawling Insect Killer Page 1 of 7 Section 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Misty Crawling Insect Killer Product Number: A00423 Product Use: Insecticide. Manufacturer/Supplier: Amrep, Inc. 990 Industrial Park Drive Marietta, GA 30062 Phone Number: (770) 422-2071 (Mon - Fri / 8am - 5pm ET) D.O.T. Emergency Phone: CHEM TEL (800) 255-3924 INTERNATIONAL: +01-[PHONE REDACTED] Date of Preparation: April 14, 2008 Revision 1.0 Section 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: See Section 15 DANGER FLAMMABLE. HARMFUL BY INHALATION. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTENTS UNDER PRESSURE. CONTAINER MAY EXPLODE IF HEATED. Potential Health Effects: See Section 11 for more information. Likely Routes of Exposure: Skin contact, eye contact, inhalation, and ingestion. Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: Not a normal route of exposure. Harmful: may cause lung damage if swallowed. Inhalation: Harmful by inhalation. May cause respiratory tract irritation. May cause product may be aspirated into the lungs and cause chemical pneumonitis. Chronic Effects: Prolonged or repeated contact may dry skin and cause irritation. Signs and may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Handling can cause dry skin. Vapours may cause drowsiness and dizziness. Medical Conditions Aggravated By Exposure: Asthma. Allergies. Target Organs: Skin, eyes, gastrointestinal tract, respiratory system. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Environmental Effects: May cause long-term adverse effects in the aquatic environment See Section 12 for more information. Section 3: COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS # Wt. % Distillates (petroleum), hydrotreated light 64742-47-8 10 - 30 Isobutane 75-28-5 5 - 10 Propane 74-98-6 3 - 7 Page 585 of 1069 Page 585 of 1069 Page 585 of 1069 Page 585 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Misty Crawling Insect Killer Page 2 of 7 Pyrethrins and Pyrethroids 8003-34-7 0.1 - 1 Deltamethrin 52918-63-5 < 0.1 Section 4: FIRST AID MEASURES Eye Contact: In case of contact, immediately flush eyes with plenty of water. If easy to do, remove contact lenses, if worn. Skin Contact: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Ingestion: If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. General Advice: In case of accident or if you feel unwell, seek medical advice immediately (show the label or MSDS where possible). Note to Physicians: may not appear immediately. Section 5: FIRE FIGHTING MEASURES Flammability: Flammable by WHMIS/OSHA criteria. Means of Extinction: Suitable Extinguishing Media: Powder, foam, carbon dioxide. Unsuitable Extinguishing Media: Water. Products of Combustion: May include, and are not limited to: oxides of carbon. Explosion Data: Sensitivity to Mechanical Impact: Not available. Sensitivity to Static Discharge: Not available. Protection of Firefighters: Containers may explode when heated. Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. Ruptured cylinders may rocket. Environmental Precautions: Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). This material is a water pollutant. Keep out of drains, sewers, ditches, and waterways. Minimize use of water to prevent environmental contamination. Methods for Containment: Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for Clean-Up: Vacuum or sweep material and place in a disposal container. Allow gas to dissipate harmlessly into the atmosphere. Other Information: Not available. Page 586 of 1069 Page 586 of 1069 Page 586 of 1069 Page 586 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Misty Crawling Insect Killer Page 3 of 7 Section 7: HANDLING AND STORAGE Handling: Keep away from sources of ignition. - No smoking. Avoid contact with skin and eyes. Do not swallow. Do not breathe gas/fumes/vapor/spray. Use only in well-ventilated areas. Handle and open container with care. When using do not eat or drink. Wash hands before eating, drinking, or smoking. Storage: Keep out of the reach of children. Keep container in a well-ventilated place. Do not store at temperatures above 49 °C / 120 Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Exposure Limits Ingredient OSHA-PEL ACGIH-TLV Distillates (petroleum), hydrotreated light 100 ppm 200 mg/m³ Isobutane Not available. Not available. Propane 1000 ppm 1000 ppm Pyrethrins and Pyrethroids 5 mg/m3 5 mg/m3 Deltamethrin Not available. Not available. Engineering Controls: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal Protective Equipment: HMIS: See Section 15 Eye/Face Protection: Wear eye/face protection. Hand Protection: Wear suitable gloves. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. General Hygiene Considerations: Handle according to established industrial hygiene and safety practices. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Opaque. Color: White to off white. Odour: Low odor. Odour Threshold: Not available. Physical State: Gas/Pressurized Liquid. pH: Not applicable. Viscosity: Not available. Freezing Point: Not available. Boiling Point: Not available. Flash Point: Not available. Evaporation Rate: Not available. Page 587 of 1069 Page 587 of 1069 Page 587 of 1069 Page 587 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Misty Crawling Insect Killer Page 4 of 7 Lower Flammability Limit: Not available. Upper Flammability Limit: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Specific Gravity: 0.958 (Liquid Concentrate) Solubility in Water: Dispersible. Coefficient of Water/Oil Distribution: Not available. Auto-ignition Temperature: Not available. Percent Volatile, wt. Not available. VOC content, wt. 15.0% (US federal/CARB/OTC/LADCO) Section 10: STABILITY AND REACTIVITY Stability: Stable under normal storage conditions. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. Keep in a cool place. Conditions of Reactivity: Heat. Incompatible materials. Incompatible Materials: Oxidizers. Acids. Hazardous Decomposition Products: May include, and are not limited to: oxides of carbon. Possibility of Hazardous Reactions: No dangerous reaction known under conditions of normal use. Section 11: TOXICOLOGY INFORMATION EFFECTS OF ACUTE EXPOSURE Component Anaylsis Ingredient LD50 (oral) LC50 Distillates (petroleum), hydrotreated light > 5000 mg/kg, rat Not available. Isobutane Not available. Not available. Propane Not available. Not available. Pyrethrins and Pyrethroids 200 mg/kg, rat Not available. Deltamethrin 9.36 mg/kg, rat 785 mg/m3 2hr, rat Eye: May cause eye irritation. may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Skin: May cause skin irritation. Handling can cause dry skin. Ingestion: Not a normal route of exposure. Harmful: may cause lung damage if swallowed. Inhalation: Harmful by inhalation. May cause respiratory tract irritation. May cause product may be aspirated into the lungs and cause chemical pneumonitis. Vapours may cause drowsiness and dizziness. EFFECTS OF CHRONIC EXPOSURE Target Organs: Not available. Chronic Effects: High concentration of vapors may cause eye and respiratory tract irritation, dizziness, headaches, drowsiness and central nervous system effects. Carcinogenicity: Not hazardous by WHMIS/OSHA criteria. Page 588 of 1069 Page 588 of 1069 Page 588 of 1069 Page 588 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Misty Crawling Insect Killer Page 5 of 7 Ingredient Chemical Listed as Carcinogen or Potential Carcinogen * Distillates (petroleum), hydrotreated light I G-A3 Isobutane Not listed. Propane Not listed. Pyrethrins and Pyrethroids Not listed. Deltamethrin I-3 * See Section 15 for more information. Mutagenicity: Not hazardous by WHMIS/OSHA criteria. Reproductive Effects: Not hazardous by WHMIS/OSHA criteria. Developmental Effects: Teratogenicity: Not hazardous by WHMIS/OSHA criteria. Embryotoxicity: Not hazardous by WHMIS/OSHA criteria. Respiratory Sensitization: Not hazardous by WHMIS/OSHA criteria. Skin Sensitization: Not hazardous by WHMIS/OSHA criteria. Toxicologically Synergistic Materials: Not available. Section 12: ECOLOGICAL INFORMATION Ecotoxicity: May cause long-term adverse effects in the aquatic environment Persistence / Degradability: Not available. Bioaccumulation / Accumulation: Not available. Mobility in Environment: Not available. Section 13: DISPOSAL CONSIDERATIONS Disposal Instructions: This material must be disposed of in accordance with all local, state, provincial, and federal regulations. Section 14: TRANSPORTATION INFORMATION DOT Classification ORM-D TDG Classification Limited Quantity Section 15: REGULATORY INFORMATION Federal Regulations Canadian: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. US: MSDS prepared pursuant to the Hazard Communication Standard (29 CFR 1910.1200). Page 589 of 1069 Page 589 of 1069 Page 589 of 1069 Page 589 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Misty Crawling Insect Killer Page 6 of 7 SARA Title III Ingredient Section 302 (EHS) TPQ (lbs.) Section 304 EHS RQ (lbs.) CERCLA RQ (lbs.) Section 313 Distillates (petroleum), hydrotreated light Not listed. Not listed. Not listed. Not listed. Isobutane Not listed. Not listed. Not listed. Not listed. Propane Not listed. Not listed. Not listed. Not listed. Pyrethrins and Pyrethroids Not listed. Not listed. Not listed. Not listed. Deltamethrin Not listed. Not listed. Not listed. Not listed. State Regulations California Proposition 65: This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Global Inventories Ingredient Canada DSL/NDSL USA TSCA Distillates (petroleum), hydrotreated light DSL Yes. Isobutane DSL Yes. Propane DSL Yes. Pyrethrins and Pyrethroids DSL No. Deltamethrin None. No. HMIS - Hazardous Materials Identification System Health - 2 Flammability - 2 Physical Hazard - 0 PPE – B NFPA - National Fire Protection Association: Health - 2 Fire - 2 Reactivity - 0 Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme WHMIS Classification(s): Class A - Compressed Gas Class B5 - Flammable Aerosol WHMIS Hazard Symbols: SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: OSHA Occupational Safety and Health Administration. ACGIH American Conference of Governmental Industrial Hygienists. A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen. IARC International Agency for Research on Cancer. Page 590 of 1069 Page 590 of 1069 Page 590 of 1069 Page 590 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Misty Crawling Insect Killer Page 7 of 7 1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans. 4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans. NTP National Toxicology Program. 1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens. Section 16: OTHER INFORMATION Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use. Expiry Date: April 14, 2011 Prepared by: Prepared for: Nexreg Compliance Inc. Amrep, Inc. Phone: (770) 422-2071 (Mon - Fri / 8am - 5pm ET) Page 591 of 1069 Page 591 of 1069 Page 591 of 1069 Page 591 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 1 / 12 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : Misty(R) Surface Disinfectant EPA ID Number: 33176-5-10807 Material number : 000000000001001788 Manufacturer or supplier's details Company : Amrep, Inc. Address : 990 Industrial Park Drive Marietta, GA 30062 Telephone : [PHONE REDACTED] Emergency telephone numbers For SDS Information : Compliance Services 1-[PHONE REDACTED] For a Medical Emergency : [PHONE REDACTED] Toll Free - All Calls Recorded For a Transportation Emergency : CHEMTREC: [PHONE REDACTED] - All Calls Recorded. In the District of Columbia [PHONE REDACTED] SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Aerosol containing a liquefied gas Colour clear, colourless Odour odourized GHS Classification Flammable aerosols : Category 2 Gases under pressure : Liquefied gas Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal word : Warning Hazard statements : H223 Flammable aerosol. H280 Contains gas under pressure; may explode if heated. H319 Causes serious eye irritation. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after Page 592 of 1069 Page 592 of 1069 Page 592 of 1069 Page 592 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 2 / 12 use. P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 122 Disposal: P501 Dispose of contents/container in accordance with local regulation. Potential Health Effects Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical Name CAS-No. Concentration ethanol 64-17-5 30 - < 50 butane 106-97-8 10 - < 20 propane 74-98-6 1 - < 5 propan-2-ol 67-63-0 1 - < 5 sodium nitrite 7632-00-0 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious place in recovery position and seek medical advice. Page 593 of 1069 Page 593 of 1069 Page 593 of 1069 Page 593 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 3 / 12 If persist, call a physician. In case of skin contact : If on clothes, remove clothes. If persist, call a physician. Call a physician if irritation persists. Wash off immediately with plenty of water for at least 15 minutes. In case of eye contact : If in eyes, rinse with water for 15 minutes. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. If persist, call a physician. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Water spray jet Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : Carbon dioxide (CO2) Carbon monoxide Smoke Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and : Use personal protective equipment. Ensure adequate ventilation. Page 594 of 1069 Page 594 of 1069 Page 594 of 1069 Page 594 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 4 / 12 emergency procedures Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Sweep up or vacuum up spillage and collect in suitable container for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not breathe vapours or spray mist. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Always replace cap after use. Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Keep in a dry, cool and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid : Oxidizing agents SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis ethanol 64-17-5 TWA 1,000 ppm ACGIH TWA 1,000 ppm NIOSH REL Page 595 of 1069 Page 595 of 1069 Page 595 of 1069 Page 595 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 5 / 12 1,900 mg/m3 TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,900 mg/m3 OSHA P0 butane 106-97-8 TWA 800 ppm 1,900 mg/m3 NIOSH REL TWA 800 ppm 1,900 mg/m3 OSHA P0 propane 74-98-6 TWA 1,000 ppm ACGIH TWA 1,000 ppm 1,800 mg/m3 NIOSH REL TWA 1,000 ppm 1,800 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,800 mg/m3 OSHA P0 propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm 980 mg/m3 NIOSH REL ST 500 ppm 1,225 mg/m3 NIOSH REL TWA 400 ppm 980 mg/m3 OSHA Z-1 TWA 400 ppm 980 mg/m3 OSHA P0 STEL 500 ppm 1,225 mg/m3 OSHA P0 Biological occupational exposure limits Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis PROPAN-2-OL 67-63-0 Acetone Urine End of shift at end of workwee k 40 mg/l ACGIH BEI Personal protective equipment Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Ensure that eyewash stations and safety showers are close to the workstation location. fitting safety goggles Skin and body protection : impervious clothing Choose body protection according to the amount and Page 596 of 1069 Page 596 of 1069 Page 596 of 1069 Page 596 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 6 / 12 concentration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Aerosol containing a liquefied gas Colour : clear, colourless Odour : odourized Odour Threshold : no data available pH : no data available Melting point/freezing point : no data available Boiling point : not applicable Flash point : not applicable Evaporation rate : no data available Flammability (solid, gas) : Flammable aerosol. Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : not applicable Density : no data available Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : no data available Auto-ignition temperature : not determined Thermal decomposition : no data available Viscosity Viscosity, kinematic : no data available Heat of combustion : 24.21 kJ/g SECTION 10. STABILITY AND REACTIVITY Reactivity : Stable Chemical stability : Stable under normal conditions. Page 597 of 1069 Page 597 of 1069 Page 597 of 1069 Page 597 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 7 / 12 Possibility of hazardous reactions : No decomposition if stored and applied as directed. Vapours may form explosive mixture with air. Conditions to avoid : Heat, flames and sparks. Extremes of temperature and direct sunlight. Incompatible materials : Oxidizing agents Ammonium salts Reducing agents Hazardous decomposition products : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: ethanol: Acute oral toxicity : LD50 Oral rat: 7,060 mg/kg Acute inhalation toxicity : LC50 rat: 124.7 mg/l Exposure time: 4 h butane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 1,355 mg/l propane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 658 mg/l Exposure time: 4 h LC50 rat: 1,355 mg/l propan-2-ol: Acute oral toxicity : LD50 Oral rat: 4,396 mg/kg Method: Calculation method Skin corrosion/irritation Product: Page 598 of 1069 Page 598 of 1069 Page 598 of 1069 Page 598 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 8 / 12 Remarks: May cause skin irritation in susceptible persons. Serious eye damage/eye irritation Product: Remarks: Severe eye irritation Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity no data available Reproductive toxicity no data available ethanol: butane: propane: propan-2-ol: sodium nitrite: STOT - single exposure no data available STOT - repeated exposure no data available Aspiration toxicity no data available Further information Product: Remarks: no data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity no data available Persistence and degradability no data available Bioaccumulative potential Product: Partition coefficient: n- : Remarks: no data available Page 599 of 1069 Page 599 of 1069 Page 599 of 1069 Page 599 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 9 / 12 octanol/water Components: butane : Partition coefficient: n- octanol/water : Pow: 2.89 Mobility in soil no data available Other adverse effects no data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, 2.1, - Limited quantity Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Page 600 of 1069 Page 600 of 1069 Page 600 of 1069 Page 600 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 10 / 12 Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, 2.1, - Limited quantity SECTION 15. REGULATORY INFORMATION This product is regulated under the United States Federal Insecticide, Fungicide and Rodenticide Act (FIFRA). Pesticide Labeling Information Required Under U.S. FIFRA Regulations This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Harmful if inhaled. Causes moderate eye irritation. EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) sodium nitrite 7632-00-0 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) ammonia, 7664-41-7 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 311/312 Hazards : Fire Hazard Sudden Release of Pressure Hazard Acute Health Hazard SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. biphenyl-2-ol 90-43-7 The components of this product are reported in the following inventories: Page 601 of 1069 Page 601 of 1069 Page 601 of 1069 Page 601 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 11 / 12 TSCA On TSCA Inventory DSL This product contains one or several components that are not on the Canadian DSL nor NDSL. AICS Not in compliance with the inventory NZIoC Not in compliance with the inventory PICCS Not in compliance with the inventory IECSC Not in compliance with the inventory Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: OSHA GHS Label Information: Hazard pictograms : Signal w ord : Warning: Hazard statements : Flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Precautionary statements : Prevention: Keep aw ay from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash skin thoroughly after handling. Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 122 Disposal: Dispose of contents/container in accordance with local regulation. Version: 1.1 Revision Date: 05/31/2015 Flammability Health Instability 3 3 0 Special hazard. FLAMMABILITY PHYSICAL HAZARD HEALTH 3 2 3 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 602 of 1069 Page 602 of 1069 Page 602 of 1069 Page 602 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 12 / 12 Print Date: 06/09/2015 We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Zep Inc. markets products under well recognized and established brand names such as Zep®, Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands. Page 603 of 1069 Page 603 of 1069 Page 603 of 1069 Page 603 of 1069 ---PAGE BREAK--- 1. IDENTIFICATION Product Name Mr. Clean Magic Eraser Product ID: 98969188_RET_NG Product Type: Finished Product - Consumer (Retail) Use Only Recommended Use Cleaning agent Restrictions on Use Use only as directed on label. Manufacturer PROCTER & GAMBLE - Fabric and Home Care Division Ivorydale Technical Centre 5289 Spring Grove Avenue Cincinnati, Ohio 45217-1087 USA Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5 1-[PHONE REDACTED] E-mail Address Emergency Telephone Transportation (24 HR) CHEMTREC - 1-[PHONE REDACTED] Canada) or 1-[PHONE REDACTED] Mexico toll free in country: [PHONE REDACTED] 2. HAZARD IDENTIFICATION "Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product. This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Not Classified. Page 1 / 7 Version 1 Hazard Statements None Hazard pictograms None Issuing Date: 16-Jul-2015 Precautionary Statements - Prevention None Signal Word None Revision Date: 16-Jul-2015 SAFETY DATA SHEET Page 604 of 1069 Page 604 of 1069 Page 604 of 1069 Page 604 of 1069 ---PAGE BREAK--- 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists. Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists. Ingestion If ingested, contact a physician immediately. Blockage of the gastrointestinal tract may occur. Inhalation Move to fresh air. If persist, call a physician. Most important acute and delayed None under normal use conditions. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Unsuitable Extinguishing Media None. Special hazard None known. Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical None. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Page 2 / 7 None Precautionary Statements - Response None 98969188_RET_NG - Mr. Clean Magic Eraser Precautionary Statements - Disposal None Hazardous ingredients None. Revision Date: 16-Jul-2015 Hazards not otherwise classified (HNOC) None Precautionary Statements - Storage Page 605 of 1069 Page 605 of 1069 Page 605 of 1069 Page 605 of 1069 ---PAGE BREAK--- Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Advice for emergency responders Use personal protective equipment as required. Methods and materials for containment and cleaning up Methods for containment Prevent dust cloud. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Dispose of in accordance with local regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines No exposure limits noted for ingredient(s). Exposure controls Engineering Measures Distribution, Workplace and Household Settings: Ensure adequate ventilation Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction Personal Protective Equipment Eye Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection Hand Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves Skin and Body Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Page 3 / 7 98969188_RET_NG - Mr. Clean Magic Eraser Revision Date: 16-Jul-2015 Page 606 of 1069 Page 606 of 1069 Page 606 of 1069 Page 606 of 1069 ---PAGE BREAK--- Wear suitable protective clothing Respiratory Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20°C solid Appearance white Odor None Odor threshold No information available VOC Content Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity None under normal use conditions. Stability Stable under normal conditions. Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. Conditions to Avoid None under normal processing. Materials to avoid Strong oxidizing agents. Hazardous Decomposition Products None under normal use. 11. TOXICOLOGICAL INFORMATION Product Information Information on likely routes of exposure Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact No known effect. Page 4 / 7 Flash point No information available Solubility in other solvents No information available No information available Revision Date: 16-Jul-2015 Partition coefficient: n-octanol/waterNo information available pH value Autoignition temperature Evaporation rate No information available . Decomposition temperature No information available No information available . Viscosity of Product No information available No information available Flammability (solid, gas) Property No information available Flammability Limits in Air Melting/freezing point Upper flammability limit No information available No information available Lower Flammability Limit No information available Values Vapor pressure No information available Boiling point/boiling range Vapor density 98969188_RET_NG - Mr. Clean Magic Eraser No information available No information available Relative density No information available Note Water solubility Page 607 of 1069 Page 607 of 1069 Page 607 of 1069 Page 607 of 1069 ---PAGE BREAK--- Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation No known effect. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment Waste from Residues / Unused Products Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Codes (non-household setting) 331 14. TRANSPORT INFORMATION DOT Not regulated IMDG Not regulated IATA Not regulated 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any Page 5 / 7 Revision Date: 16-Jul-2015 98969188_RET_NG - Mr. Clean Magic Eraser Page 608 of 1069 Page 608 of 1069 Page 608 of 1069 Page 608 of 1069 ---PAGE BREAK--- chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) This product does not contain any substances regulated by state right-to-know regulations International Inventories United States Not applicable. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act 16. OTHER INFORMATION HMIS Ratings Health hazard 1 Flammability 2 Physical hazard 1 NFPA Ratings Health hazard 1 Flammability 2 Instability 1 Issuing Date: 16-Jul-2015 Revision Date: 16-Jul-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless Page 6 / 7 Revision Date: 16-Jul-2015 98969188_RET_NG - Mr. Clean Magic Eraser Page 609 of 1069 Page 609 of 1069 Page 609 of 1069 Page 609 of 1069 ---PAGE BREAK--- specified in the text End of SDS Page 7 / 7 98969188_RET_NG - Mr. Clean Magic Eraser Revision Date: 16-Jul-2015 Page 610 of 1069 Page 610 of 1069 Page 610 of 1069 Page 610 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Share Corporation P.O. Box 245013 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER: (800) 776-7192 REVISION DATE: July 19, 2005 CHEMTREC: (800) 424-9300 DATE OF ISSUE: March 2, 2009 I - Product Identification Multi Metal Polish PRODUCT CODE: 0670 CHEMICAL FORMULATION: Water based cleaner and polish. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. EPA 40 CFR: SUBSTANCE APPROX % OSHA PEL ACGIH TLV CAS # 302 355 372 Ammonium hydroxide (as ammonia) < 2.0 (50 ppm) (25 ppm) Y N Y 1336-21-6 Oxalic Acid 1.00-3.00 1 mg/m3 1 mg/m3 N N N 144-62-7 Mineral Spirits 1.00-3.00 N/E 100 ppm N N N 8052-41-3 Poly (oxyethylene) 1.00-3.00 N/E N/E N N N 9016-45-9 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = 1.141 VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): 1.00-3.00 VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = < 1.0 SOLUBILITY IN WATER: Soluble pH: 9.00-10.00 APPEARANCE AND ODOR: Opaque, tan viscous liquid; pungent odor. IV - Fire and Explosion Hazard Data FLASH POINT > 200 (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Water, foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should be equipped with full protective gear including self-contained breathing apparatus. Cool drums in vicinity of fire with water fog. UNUSUAL FIRE AND EXPLOSION HAZARD: None. Page 611 of 1069 Page 611 of 1069 Page 611 of 1069 Page 611 of 1069 ---PAGE BREAK--- P RODUCT NAME: Multi Metal Polish PRODUCT CODE: 0670 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong acids CONDITIONS TO AVOID: None HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon and nitrogen. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Severe irritation, redness, tearing. Possible corneal damage. IF ON SKIN: Moderate irritation with prolonged or repeated exposure. IF SWALLOWED: Nausea, vomiting, diarrhea, cramps, burns to mucous membranes. IF INHALED: Irritation of respiratory tract. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. Obtain medical attention. IF ON SKIN: Flush skin with water while removing contaminated clothing. Wash skin thoroughly with soap and water. Obtain medical attention, if irritation persists. Launder skin before re-use IF SWALLOWED: Contact physician or poison control center immediately. Rinse mouth with water. Give person several glasses of water. Do not induce vomiting unless told to do so by a physician or poison control center. Never give anything to an unconscious person. IF INHALED: Remove person to fresh air. If breathing has stopped, administer artificial respiration. If breathing is difficult, administer oxygen. Obtain medical attention. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spill and ventilate area. Soak up on absorbent material and place in a labeled closed container for disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety glasses or goggles. OTHER PROTECTIVE EQUIPMENT: Eye wash station. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place. Keep container closed when not in use. Wash thoroughly after handling. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT PROPER SHIPPING NAME: None DOT CLASS: None DOT ID NUMBER: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: July 19, 2005 Prepared by: Technical Dept. DATE OF ISSUE: March 2, 2009 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Share Corporation assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material. Page 612 of 1069 Page 612 of 1069 Page 612 of 1069 Page 612 of 1069 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 1 / 7 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : MURPHY OIL SOAP WOOD CLEANER SPRAY RTU Product code : 200000041735 : B02955850000 Manufacturer or supplier's details Company : Colgate-Palmolive Co 300 Park Avenue New York, NY 10022 Telephone : US: Consumer Affairs - 1-[PHONE REDACTED] Emergency telephone number : For emergencies involving spill, leak, fire, exposure or acci- dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887. Medical Emergency (24HR): For MEDICAL EMERGENCIES involving this product call: (888) 489-3861 Recommended use of the chemical and restrictions on use Recommended use : Formulated all purpose cleaner for household use. SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance liquid Colour orange GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Potential Health Effects Inhalation : No adverse effects due to inhalation are expected. Skin : May cause skin irritation upon prolonged contact. Eyes : Causes eye irritation on direct contact. Ingestion : May be harmful if swallowed in large quantities. Aggravated Medical Condi- : None known. Page 613 of 1069 Page 613 of 1069 Page 613 of 1069 Page 613 of 1069 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 2 / 7 tion Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components No hazardous ingredients SECTION 4. FIRST AID MEASURES If inhaled : Remove victim to fresh air. Get medical attention, if symp- toms persist. In case of skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention. In case of eye contact : Flush eyes with water at least 15 minutes. Get medical atten- tion if eye irritation develops or persists. If swallowed : Drink 8 ounces of clear water. Get medical attention. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car- bon dioxide. Hazardous combustion prod- ucts : No hazardous combustion products are known Special protective equipment for firefighters : Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. Page 614 of 1069 Page 614 of 1069 Page 614 of 1069 Page 614 of 1069 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 3 / 7 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protection recommended in Section 8 of the SDS. Methods and materials for containment and cleaning up : Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa- ter. SECTION 7. HANDLING AND STORAGE Conditions for safe storage : Store at controlled room temperature at 20-25°C (68-77°F). SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : In an industrial work environment, no special precautions or control measures are required. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally re- quired. Protective measures : In an industrial work environment, if a splash is likely, chemi- cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary. Hygiene measures : In an industrial work environment, avoid eye and prolonged skin contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : orange pH : 10.0 Flash point : > 100 °C Density : 1.0 g/cm3 Page 615 of 1069 Page 615 of 1069 Page 615 of 1069 Page 615 of 1069 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 4 / 7 SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reac- tions : Hazardous polymerisation does not occur. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : None known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Skin corrosion/irritation Not classified based on available information. Serious eye damage/eye irritation Not classified based on available information. Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available Page 616 of 1069 Page 616 of 1069 Page 616 of 1069 Page 616 of 1069 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 5 / 7 safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS. SECTION 12. ECOLOGICAL INFORMATION The product has not been tested as a whole for environmental toxicity. However, environmental infor- mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua- tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients surfactants are biode- gradable) or testing conducted on the final product This product is biodegradable). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state envi- ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground. SECTION 14. TRANSPORT INFORMATION DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. IMDG : Not regulated. International Regulation Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Page 617 of 1069 Page 617 of 1069 Page 617 of 1069 Page 617 of 1069 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 6 / 7 FORMALDEHYDE 50-00-0 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) FORMALDEHYDE 50-00-0 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: SODIUM HYDROXIDE 1310-73-2 FORMALDEHYDE 50-00-0 The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM HYDROXIDE 1310-73-2 FORMALDEHYDE 50-00-0 This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know FORMALDEHYDE 50-00-0 HYDROGEN PEROXIDE 7722-84-1 Right To Know WATER Water SODIUM HYDROXIDE 1310-73-2 New Jersey Right To Know WATER Water Sodium tallate 61790-45-2 California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. The components of this product are reported in the following inventories: Page 618 of 1069 Page 618 of 1069 Page 618 of 1069 Page 618 of 1069 ---PAGE BREAK--- NA MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015 7 / 7 TSCA : All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) In accordance with OSHA 29 CFR 1910.1048 formaldehyde is not listed in Section 3 of this MSDS, however, formaldehyde is regulated by State and Federal regulations at varying concen- trations. State and Federal information can be found above in Section 15. SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im- plied, as to the accuracy, reliability or completeness of the information and assumes no re- sponsibility for injury, damage or loss resulting from the use of the material. Flammability Health Instability 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 619 of 1069 Page 619 of 1069 Page 619 of 1069 Page 619 of 1069 ---PAGE BREAK--- Page 620 of 1069 Page 620 of 1069 Page 620 of 1069 Page 620 of 1069 ---PAGE BREAK--- Page 621 of 1069 Page 621 of 1069 Page 621 of 1069 Page 621 of 1069 ---PAGE BREAK--- Page 622 of 1069 Page 622 of 1069 Page 622 of 1069 Page 622 of 1069 ---PAGE BREAK--- Page 623 of 1069 Page 623 of 1069 Page 623 of 1069 Page 623 of 1069 ---PAGE BREAK--- Page 624 of 1069 Page 624 of 1069 Page 624 of 1069 Page 624 of 1069 ---PAGE BREAK--- Page 625 of 1069 Page 625 of 1069 Page 625 of 1069 Page 625 of 1069 ---PAGE BREAK--- Page 626 of 1069 Page 626 of 1069 Page 626 of 1069 Page 626 of 1069 ---PAGE BREAK--- Page 627 of 1069 Page 627 of 1069 Page 627 of 1069 Page 627 of 1069 ---PAGE BREAK--- Page 628 of 1069 Page 628 of 1069 Page 628 of 1069 Page 628 of 1069 ---PAGE BREAK--- Page 629 of 1069 Page 629 of 1069 Page 629 of 1069 Page 629 of 1069 ---PAGE BREAK--- Page 630 of 1069 Page 630 of 1069 Page 630 of 1069 Page 630 of 1069 ---PAGE BREAK--- Page 631 of 1069 Page 631 of 1069 Page 631 of 1069 Page 631 of 1069 ---PAGE BREAK--- Page 632 of 1069 Page 632 of 1069 Page 632 of 1069 Page 632 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Date Issued : Apr.1.2008 MSDS No. F-31667 25 1. PRODUCT AND COMPANY IDENTIFICATION Product Name : MX-C40NVM/MX-C38GVM/MX-C38FVM Magenta Developer Supplier Identification : Sharp Corporation 22-22 Nagaike-cho, Abeno-ku, Osaka, Japan Local suppliers are listed below. Please contact the nearest supplier for additional information. Area (Country) (Name and Telephone Number) U.S.A. Sharp Electronics Corporation Sharp Plaza, Mahwah, NJ Telephone number for information : 1-[PHONE REDACTED] Emergency telephone number : 1-[PHONE REDACTED] North America Canada Sharp Electronics of Canada Ltd. Telephone number for information : [PHONE REDACTED] Emergency telephone number : 1-[PHONE REDACTED] Oceania Australia Sharp Corporation of Australia PTY. Ltd. No1 Huntingwood Drive Huntingwood Blacktown N.S.W. Telephone number for information : 1300-13-50-22 Germany Sharp Electronics (Europe) GMBH Sonninstrasse 3, 20097 Hamburg Telephone number to access MSDS : 040-2376-2185 For more information : 040-2376-2613 United Kingdom Sharp Electronics Ltd. Telephone number for information : 08705-274-277 France Sharp Electronics France S.A. Telephone number for information : 01-49-90-34-00 Austria Sharp Electronics GMBH Telephone number for information : 01-727-19-0 Italy Sharp Electronics (Italy) S.P.A. Telephone number for information : 02895951 Spain Sharp Electronics (Espana) S.A. Telephone number for information : 93-581-97-00 Netherlands Sharp Electronics Benelux B.V. Telephone number for information : 30-6359500 Sweden Sharp Electronics Nordic AB Telephone number for information : 08-634-36-00 Europe Switzerland Sharp Electronics(Schweiz)AG Telephone number for information : 01-846-6111 Middle East U.A.E. Sharp Middle East FZE P.O.Box 17115 Jebel Ali, Dubai Telephone number for information : 04-815311 2. COMPOSITION/INFORMATION ON INGREDIENTS Substance[ ] Preparation[X] Ingredient CAS No. Proportion OSHA PEL ACGIH TLV DFG-MAK NOHSC- TWA Ferrite 65997-18-4 >90% Not listed Not listed Not listed Not listed Iron oxide Manganese oxide Magnesium oxide Strontium oxide Polyester resin Confidential < 5% Not listed Not listed Not listed Not listed Polyester resin Confidential < 5% Not listed Not listed Not listed Not listed Organic pigment Confidential < 1% Not listed Not listed Not listed Not listed Page:1/4 Page 633 of 1069 Page 633 of 1069 Page 633 of 1069 Page 633 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Date Issued : Apr.1.2008 MSDS No. F-31667 26 3. HAZARDS IDENTIFICATION Most Important Hazards and Effects of the Products Human Health Effects : There are no anticipated carcinogenic effects from exposure based on animal tests performed using toner. When used as intended according to instructions, studies do not indicate any of fibrosis will occur. Environmental Effects : Not toxic to aquatic organisms [Estimated from the other product containing similar material] Specific hazards : Dust explosion (like most finely divided organic powders) Directive 1999/45/EC(Europe) : Not classified as dangerous 4. FIRST-AID MEASURES Route(s) of Entry : Inhalation? Skin? Ingestion? No No Possible but very unusual. Inhalation : Remove to fresh air. If occur, consult medical personnel. Skin Contact : Wash with soap and water for 15 minutes or until particle is removed. If irritation does occur, consult medical personnel. Eye Contact : flush eyes immediately with water for 15 minutes. If irritation does occur, consult medical personnel. Ingestion : Rinse with water and drink several glasses of water . If irritation or discomfort does occur, consult medical personnel. 5. FIRE –FIGHTING MEASURES Extinguishing Media : Water , CO2, foam and dry chemicals Special Fire fighting Procedures : None Fire and Explosion Hazards : Toner material, like most finely divided organic powders, may form an explosive mixture. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions : None Environmental Precautions : None Methods for Cleaning Up : Wipe off with paper or cloth. Do not use vacuum cleaner when a large amount is released. It, like most finely divided organic powders, is capable of creating a dust explosion. 7. HANDLING AND STORAGE Handling Technical Measures : None Precautions : None Safe Handling Advice : Use of a dust mask is recommended when handling a large quantity of toner or during long term exposure, as with any non-toxic dust. Try not to disperse the particles. Storage Technical Measures : None Storage Conditions : Keep container closed and Store in a cool and dry place. Keep out of the reach of children. Incompatible Products : None Page:2/4 Page 634 of 1069 Page 634 of 1069 Page 634 of 1069 Page 634 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Date Issued : Apr.1.2008 MSDS No. F-31667 27 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Ventilation : Not required under intended use. Exposure limit values OSHA-PEL(USA) : 15mg/m3 (Total Dust) , 5mg/m3 (Respirable Dust) ACGIH-TLV(USA) : 10mg/m3 (Total Dust) , 3mg/m3 (Respirable Dust) Personal Protective Equipment Respiratory Protection : None required when used as intended in Sharp equipment. Hand Protection : None required when used as intended in Sharp equipment. Eye Protection : None required when used as intended in Sharp equipment. Skin Protection : None required when used as intended in Sharp equipment. Other Protective Equipment : Use of a dust mask and goggles are recommended when handling a large quantity of toner or during long term exposure, as with any non-toxic dust. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State : Solid Form: Powder Color: Red Odor: odorless Ph : Not applicable Boiling/Melting Point : Not applicable Flash Point(°C ) : Not applicable Explosion Properties : No data Density(g/cm³) : Approx. 5.0 (bulk density :Approx. 2.0) Solubility in water : Negligible 10. STABILITY AND REACTIVITY Stability : Stable Hazardous Reactions : Dust explosion, like most finely divided organic powders. Conditions to Avoid : Electric discharge, throwing into fire. Materials to Avoid : Oxidizing Materials Hazardous Decomposition Products : CO, CO2 and NOX Further Information : None 11. TOXICOLOGICAL INFORMATION Acute Toxicity Ingestion(oral) : LD50>2000mg/kg [Estimated from the other product containing similar material] Dermal : No data Inhalation : No data Eye irritation : Not an irritant [Estimated from the other product containing similar material] Skin irritation : Not an irritant [Estimated from the other product containing similar material] Skin sensitizer : Not sensitized [Estimated from the other product containing similar material] Mutagenicity : Negative(Ames Test) [Estimated from the other product containing similar material] Carcinogenicity : NTP? IARC Monographs? OHSA Regulated? No No No 12. ECOLOGICAL INFORMATION Ecotoxicity On available data, toner is not harmful to aquatic organisms [Estimated from the other product containing similar material] Page:3/4 Page 635 of 1069 Page 635 of 1069 Page 635 of 1069 Page 635 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Date Issued : Apr.1.2008 MSDS No. F-31667 28 13. DISPOSAL CONSIDERATIONS Waste from residues : Waste material may be dumped or incinerated under conditions which meet all federal, state and local environmental regulations. Contaminated Packaging : Waste may be disposed or incinerated under conditions which meet all federal, state and local environmental regulations. 14. TRANSPORT INFORMATION UN Classification : None Not classified as hazardous for transport. 15. REGULATORY INFORMATION US Information TSCA(Toxic Substances Control Act) : All chemical substances in this product comply with all applicable rules or order under TSCA. SARA(Superfund Amendments and Reauthorization Act) Title III 302 Extreme Hazardous Substance : None 311/312 Hazard Classification : None EU Information 1999/45/EC and 67/548/EEC Symbol & Indication : Not required R-Phrase : Not required 76/769/EEC : All chemical substances in this product comply with all applicable rules or order under 76/769/EEC. 16. OTHER INFORMATION NFPA Rating USA : Health=1 Flammability=1 Reactivity=0 WHMIS Legislation (Canada) : This product is not a controlled product. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. However, all materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we do not guarantee that these are the only hazards which exist. Page 636 of 1069 Page 636 of 1069 Page 636 of 1069 Page 636 of 1069 ---PAGE BREAK--- Page 637 of 1069 Page 637 of 1069 Page 637 of 1069 Page 637 of 1069 ---PAGE BREAK--- Page 638 of 1069 Page 638 of 1069 Page 638 of 1069 Page 638 of 1069 ---PAGE BREAK--- Page 639 of 1069 Page 639 of 1069 Page 639 of 1069 Page 639 of 1069 ---PAGE BREAK--- Page 640 of 1069 Page 640 of 1069 Page 640 of 1069 Page 640 of 1069 ---PAGE BREAK--- Page 641 of 1069 Page 641 of 1069 Page 641 of 1069 Page 641 of 1069 ---PAGE BREAK--- Safety Data Sheet Office Max Compressed Gas Duster Section 1. Identification Product Identifier Office Max Compressed Gas Duster Synonyms OM96090, OM96091, OM96092, OM04736, OM04737 Manufacturer Stock Numbers N/A Product Cas 75-37-6 Recommended use Dust Removal Uses advised against Use Only as Directed - Read label instructions carefully. Keep out of reach of children. Intentional misuse by deliberately concentrating and/or inhaling contents may be fatal. Manufacturer Contact Address Falcon Safety Products, Inc. 25 ImClone Drive Branchburg, NJ, 08876 USA Phone Emergency Phone Fax (908) 707-4900 (800) 498-7192 N/A Section 2. Hazards Identification Classification FLAMMABLE GASES - Category 2 GASES UNDER PRESSURE - Compressed gas Signal Word Warning Pictogram Hazard Statements Contains gas under pressure; may explode if heated Flammable gas Precautionary Statements Response Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Prevention Do not spray on an open flame or other ignition source. Keep away from heat. Pressurized container: Do not pierce or burn, even after use. Storage Protect from sunlight. Store in a well-ventilated place. Store at temperatures not exceeding 120 degrees F/49 degrees C Disposal N/A Page 1 of 8 Page 642 of 1069 Page 642 of 1069 Page 642 of 1069 Page 642 of 1069 ---PAGE BREAK--- Occupational exposure limits, if available, are listed in Section 8. General Keep out of reach of children Ingredients of unknown toxicity 0% Hazards not Otherwise Classified N/A No Data Available Section 3. Ingredients CAS Ingredient Name Weight % 75-37-6 Ethane, 1,1-difluoro- 100 % Section 4. First-Aid Measures General Advice Never give anything by mouth to an unconscious person. When persist or in all cases of doubt, seek medical advice. Inhalation Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Skin Take off all contaminated clothing immediately. Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician. Eye Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion Is not considered a potential route of exposure. Most important acute and delayed Anaesthetic effects: light-headedness, irregular heartbeat with a strange sensation in the chest, heart thumping, apprehension, feeling of fainting, dizziness or weakness. Protection of First-aiders If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to Physician Because of possible disturbances of cardiac catecholamine drugs, such as epinephrine, which may be used in situations of emergency life support, should be used with special caution. Page 2 of 8 Page 643 of 1069 Page 643 of 1069 Page 643 of 1069 Page 643 of 1069 ---PAGE BREAK--- Section 5. Fire Fighting Measures Suitable Extinguishing Media Water spray, water fog, dry chemical, alcohol resistant foam, carbon dioxide (CO2) Unsuitable Extinguishing Media No applicable data available. Specific Hazards Flammable. This substance's fire decomposition by-products will include hydrofluoric acid and possibly carbonyl flouride. Avoid contact with these materials, which are toxic and irritating. Evacuate personnel immediately in the event of a fire involving this substance. Vapors may form explosive mixtures with air. Vapors are heavier than air and may spread along floors. Vapors or gases may travel considerable distances to ignition source and flash back. Special protective equipment for firefighters Use personal protective equipment. Wear neoprene gloves during cleaning up work after a fire. Exposure to decompositon products may be a hazard to health. Further Information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers/tanks with water spray. Section 6. Accidental Release Measures NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) Evacuate personnel to safe areas. Ventilate the area. Refer to protective measures listed in sections 7 and 8. Spill Clean-up If this product is spilled and not recovered, or is recovered as a waste for treatment and disposal, the CERCLA Reportable Quantity is 100 lbs. (release of an Unlisted Hazardous Waste with the Characteristic of Ignitability). Evaporates. Ventilate area using forced ventilation, especially low or enclosed places where heavy vapors might collect. Accidental Release Measures Wear self-contained breathing apparatus (SCBA). Section 7. Handling and Storage Handling (Personnel) Avoid breathing vapors or mist. Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. Handle in accordance with good industrial hygiene and safety practice. Handling (Physical Aspects) Vapors are heavier than air and may spread along floors. Vapors may form flammable mixture with air. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropirate standard. No sparking tools should be used. Take measures to prevent the build up of electrostatic charge. Keep away from open flames, hot surfaces and sources of ignition. When using DO NOT SMOKE. Do not use in areas where vapors may accumulate such as paper shredders. Dust Explosion class Not applicable Storage Keep container closed and in a dry, well-ventilated location. Store in original container. The product has an indefinite shelf life when stored properly. Storage Period Recommended shelf life - 10 years provided product is stored in a dry location as directed. Storage Temperature Do not expose to temperatures above 120 degrees F (49 degrees C) as overheating could cause can to burst. DO NOT leave in direct sunlight or enclosed vehicle. Page 3 of 8 Page 644 of 1069 Page 644 of 1069 Page 644 of 1069 Page 644 of 1069 ---PAGE BREAK--- Section 8. Exposure Controls/Personal Protection Occupational Exposure Limits Ingredient Name ACGIH TLV OSHA PEL STEL Ethane, 1,1-difluoro- N/A N/A N/A Personal Protective Equipment N/A Engineering controls Ensure adequate ventilation, especially in confined areas. Use respiratory protection if needed. Eye/Face Protection Wear safety glasses with side shields. Direct contact with liquid may cause frostbite. Respiratory Protection For rescue use self-contained breathing apparatus. Vapors are heavier than air and can cause suffication by reducing oxygen available for breathing. Skin and body protection As required by employer code. If there is risk of skin contact, wear protective clothing, gloves, etc. Direct contact with liquid can cause frostbite. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practices. Page 4 of 8 Page 645 of 1069 Page 645 of 1069 Page 645 of 1069 Page 645 of 1069 ---PAGE BREAK--- Section 9. Physical and Chemical Properties Physical State Gas Color Clear Odor slight, ether- like Odor Threshold No applicable data available Solubility Water - Partition coefficient Water/n-octanol N/A VOC% N/A Viscosity No applicable data available Specific Gravity 0.91 Density lbs/Gal 0.9 Pounds per Cubic Foot N/A Flash Point <-58°F C) FP Method N/A Ph Neutral Melting Point No applicable data available Boiling Point -13 °F (-25 ° C) Boiling Range N/A LEL 3.9 UEL 16.9 Evaporation Rate No applicable data available Flammability Flammable Decomposition Temperature N/A Auto-ignition Temperature No applicable data available Vapor Pressure 5,960 KPa at 77F (25C) Vapor Density 2.4 at 77F (25C) (Air=1) Section 10. Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical Stability The product is chemically stable under recommended storage conditions. Conditions to Avoid Aerosol containers are unstable at temperatures above 120 degrees F/49 degrees C Incompatible Materials Incompatible products include Alkali metals, Alkaline earth metals, powdered metals, powdered metal salts. Hazardous Decomposition Products Decomposition products are hazardous. This material can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrofluoric acid and possibly carbonyl fluoride. Page 5 of 8 Page 646 of 1069 Page 646 of 1069 Page 646 of 1069 Page 646 of 1069 ---PAGE BREAK--- Section 11. Toxicological Information Component Analysis - LC50 1,1-Difluoroethane - > 64000 ppm rat Component analysis - Oral LD50 1,1-Difluoroethane - 1500 mg/kg rat Effects of Acute Exposure - Eye Contact with liquid may cause frostbite Effects of Acute Exposure - Skin Contact with liquid may cause frostbite Effects of Acute Exposure - Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effect (headaches, dizziness). Vapors may cause dizziness or suffocation. Effects of Acute Exposure - Ingestion Not a normal route of exposure Sensitization Non-hazardous by WHMIS/OSHA criteria. Carcinogenicity Not classifiable as a human carcinogen. Animal testing did not show carcinogenic effects. None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA as a carcinogen. Mutagenicity Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Tests on mammalian cell cultures showed mutagenic effects. Reproductive Toxicity No toxcicity to reproduction. Animal testing showed no reproductive toxicity. Teratogenicity Animal testing showed no developmental toxicity. Further Information Cardiac sensitization threshold limit: 405000 mg/m3 Section 12. Ecological Information Aquatic Toxicity 1,1-Difluoroethane 96 h LC50 : Fish 295.78 mg/l 96 h EC50 : Algae 47.76 mg/l 48 h EC50 : Daphnia (water flea) 146.7 mg/l Section 13. Disposal Waste Disposal Methods Comply with applicable Federal, State/Provincial and Local Regulations. May be a RCRA Hazardous waste due to the ignitability characteristic. Do not puncture or incinerate container. Contaminated Packaging Not Available Page 6 of 8 Page 647 of 1069 Page 647 of 1069 Page 647 of 1069 Page 647 of 1069 ---PAGE BREAK--- Section 14. Transport Information UN Number 1030 UN Proper Shipping Name 1,1-Difluoroethane DOT Classification 2.1 Packing Group N/A Packaging Exceptions Note: Falcon Safety Products has been granted a DOT special permit. A copy of DOT Special Permit SP-11516 can be obtained by calling Falcon Safety Products, Inc. at [PHONE REDACTED]. Transportation of Dangerous Goods (TDG - Canada) Proper Shipping name: 1,1-Difluoroethane Hazard Class: 2.1 UN number: 1030 Packaging Exceptions: Limited quantity (containers up to 125mL) IATA/ICAO (Air) Proper Shipping Name: 1,1-Difuoroethane. Hazard Class: 2.1. UN Number: 1030. Maximum Net Quantity Packaging: Cargo Aircraft only - 150 kg maximum (forbidden on passenger aircraft). Maximum Net Quantity packaging cargo only: 150 kg. IMDG (Marine Transport) Proper Shipping Name: 1,1-DIFLUOROETHANE. Hazard Class: 2.1. UN Number: 1030. Additional Information TDG Canada: Falcon Safety Products has been granted Equivalency Certificate SU 9211 (ren. 1) by the TCSS, TDGD to offer for transport by road, rail and marine. Section 15. Regulatory Information Canadian Federal Regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. WHMIS Status Controlled WHMIS Classification Class A - Compressed Gas, Class B - Division 1 - Flammable Gas TSCA On the inventory, or in compliance with the inventory. SARA 313 Regulated Chemical(s) This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. NJ Right to Know Regulated Chemical(s) Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): 1,1-Difluoroethane. California Prop. 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Canada Domestic Substances List (DSL) This product is listed on the DSL inventory list and complies with the inventory requirements administered by the governing country. Page 7 of 8 Page 648 of 1069 Page 648 of 1069 Page 648 of 1069 Page 648 of 1069 ---PAGE BREAK--- Section 16. Other Information Revision Date 4/28/2015 Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Prepared By Falcon Safety Products, Inc. [PHONE REDACTED] Page 8 of 8 Page 649 of 1069 Page 649 of 1069 Page 649 of 1069 Page 649 of 1069 ---PAGE BREAK--- Polishes, spray (furniture, shoes) SAFETY DATA SHEET Product name Distributed by Product use 1. Product and company identification Old English Aerosol - Lemon : : D8106245 : SDS # Formulation : #8099986 Old English Aerosol - Lemon : Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue, Unit #2 Mississauga, Ontario L4W 5S9 CANADA Telephone: +1 [PHONE REDACTED] 2. Hazards identification Classification of the substance or mixture FLAMMABLE AEROSOLS - Category 1 : Signal word : Danger Hazard statements : Extremely flammable aerosol. Hazard pictograms : GHS label elements 1/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 650 of 1069 Page 650 of 1069 Page 650 of 1069 Page 650 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Supplemental label elements : None known. Hazards not otherwise classified : None known. General Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Response : Not applicable. Storage : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Disposal : Not applicable. : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Precautionary statements 3. Composition/information on ingredients Mixture : Substance/mixture There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Potential acute health effects 2/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 651 of 1069 Page 651 of 1069 Page 651 of 1069 Page 651 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Over-exposure Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : 3/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 652 of 1069 Page 652 of 1069 Page 652 of 1069 Page 652 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 7. Handling and storage Conditions for safe storage, including any incompatibilities Do not store above the following temperature: 50°C (122°F). Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling 4/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 653 of 1069 Page 653 of 1069 Page 653 of 1069 Page 653 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM Not applicable. 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control Individual protection measures Occupational exposure limits Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and chemical properties Physical state Liquid. [Aerosol.] Lemon-like. Odor Not available. Color Not available. Odor threshold : : : : Appearance 5/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 654 of 1069 Page 654 of 1069 Page 654 of 1069 Page 654 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 9. Physical and chemical properties Melting point Vapor pressure Relative density Vapor density Solubility Not available. Not available. Not available. Not available. Not available. pH Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: <0°C (<32°F) Not available. Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : : : : : : : : : Boiling point : <34°C (<93.2°F) Flammability (solid, gas) : Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Type of aerosol : Spray Heat of combustion : 9.918 kJ/g Aerosol product 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 11. Toxicological information Acute toxicity Irritation/Corrosion Not available. Information on toxicological effects Carcinogenicity Not available. Mutagenicity Not available. Sensitization Not available. Not available. 6/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 655 of 1069 Page 655 of 1069 Page 655 of 1069 Page 655 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Not available. Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. 7/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 656 of 1069 Page 656 of 1069 Page 656 of 1069 Page 656 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Not available. Acute toxicity estimates 12. Ecological information Toxicity Not available. Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Not available. Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods 14. Transport information 8/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 657 of 1069 Page 657 of 1069 Page 657 of 1069 Page 657 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 14. Transport information 2.1 Limited quantity DOT Classification TDG Classification 2.1 Aerosols - UN1950 AEROSOLS - IMDG Class AEROSOLS 2.1 - Aerosols, flammable UN1950 IATA-DGR Class 2.1 Regulatory information UN number Proper shipping name Classes PG* Label Additional information - UN1950 Limited quantity See DG list UN1950 Limited quantity Mexico Classification UN1950 Aerosols, flammable 2.1 - Limited quantity PG* : Packing group 15. Regulatory information U.S. Federal regulations Clean Air Act (CAA) 112 regulated flammable substances: isobutane; propane : TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me; Cyclosiloxanes, di-Me; nonanal; octanal; decanal; citronellal; dodecanal; 2-methylundecanal; 7-hydroxycitronellal; α- hexylcinnamaldehyde TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Fire hazard 9/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 658 of 1069 Page 658 of 1069 Page 658 of 1069 Page 658 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information CAUTION AEROSOLS EXTREMELY FLAMMABLE. MAY CAUSE FLASH FIRE. FLAMMABLE AEROSOLS CONTENTS UNDER PRESSURE. Keep out of the reach of children. Keep away from heat, sparks and flame. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 120 Use only with adequate ventilation. Keep container closed and sealed until ready for use. Wash thoroughly after handling. Signal word : Hazard statements : Precautionary measures : Label elements The following components are listed: ISOBUTANE; PROPANE Massachusetts : New York : None of the components are listed. New Jersey : The following components are listed: Isobutane; PROPANE, 2-METHYL-; PROPANE : The following components are listed: PROPANE, 2-METHYL-; PROPANE State regulations No products were found. Composition/information on ingredients 16. Other information Hazardous Material Information System 2 2 0 0 2 2 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Personal protection Level 3 NFPA (30B) aerosol Flammability 10/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 659 of 1069 Page 659 of 1069 Page 659 of 1069 Page 659 of 1069 ---PAGE BREAK--- D8106245 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Date of previous issue Version : : : Indicates information that has changed from previously issued version. 20/07/2015. 20/07/2015. 2 Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Prepared by : Reckitt Benckiser Hull (UK) Dansom Lane Hull, HU8 7DS United Kingdom T +44 (0)1482 326151 F +44 (0)1482 582532 RB is a member of the CSPA Product Care Product Stewardship Program. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 11/11 20/07/2015. Date of issue : SDS # FF8099986 : Code # D8106245 : Page 660 of 1069 Page 660 of 1069 Page 660 of 1069 Page 660 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 1/9 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Use of the Substance/Mixture : Disinfectant Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : clear colourless / aerosol / pleasant Immediate Concerns : Warning FLAMMABLE: CAUSES EYE IRRITATION. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg as container may burst. Contents under pressure. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : Causes: Moderate eye irritation Skin : May cause skin reactions in rare cases. Prolonged or repeated contact may dry skin and cause irritation. Inhalation : Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. May cause nose, throat, and lung irritation. Page 661 of 1069 Page 661 of 1069 Page 661 of 1069 Page 661 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 2/9 Inhalation may cause central nervous system effects. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Causes headache, drowsiness or other effects to the central nervous system. Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, etc. may be more susceptible to irritating effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 30.00 - 60.00 Isobutane 75-28-5 10.00 - 30.00 Triethylene glycol 112-27-6 5.00 - 10.00 Propane 74-98-6 5.00 - 10.00 (C12- monium Saccharinate 68989-01-5 0.10 - 1.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Page 662 of 1069 Page 662 of 1069 Page 662 of 1069 Page 662 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 3/9 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Burns with colourless flame. Aerosol Product - Containers may rocket or explode in heat of fire. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Flash point : < -7 °C < 19.4 °F Note: Propellant Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available NFPA Classification : NFPA Level 2 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. Page 663 of 1069 Page 663 of 1069 Page 663 of 1069 Page 663 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 4/9 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid contact with skin, eyes and clothing. Do not puncture or incinerate. Avoid breathing vapors, mist or gas. For personal protection see section 8. Do not spray toward face. Do not use in areas without adequate ventilation. Note: Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. For more information visit www.inhalant.org. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge. Storage Requirements for storage areas and containers : Do not store at temperatures above 120 Deg. F (50 Deg as container may burst. Keep in a dry, cool and well-ventilated place. Page 664 of 1069 Page 664 of 1069 Page 664 of 1069 Page 664 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 5/9 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Ethyl alcohol 64-17-5 1,900 mg/m3 1,000 ppm - OSHA TWA Ethyl alcohol 64-17-5 - 1,000 ppm - ACGIH STEL Isobutane 75-28-5 - 1,000 ppm - ACGIH TWA Propane 74-98-6 1,800 mg/m3 1,000 ppm - OSHA TWA Propane 74-98-6 - 1,000 ppm - ACGIH TWA Personal protective equipment Respiratory protection Use only with adequate ventilation. Hand protection : No special requirements. Eye protection Safety glasses with side-shields Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : aerosol Color : clear colourless Odor : pleasant pH : 7 - 8 Page 665 of 1069 Page 665 of 1069 Page 665 of 1069 Page 665 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 6/9 Boiling point : no data available Freezing point : no data available Flash point : < -7 °C < 19.4 °F Propellant Evaporation rate : no data available Auto-ignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : no data available Water solubility : dispersible Volatile Organic Compounds Total VOC (wt. : 60.9 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 estimated > 5,000 mg/kg Page 666 of 1069 Page 666 of 1069 Page 666 of 1069 Page 666 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 7/9 Acute inhalation toxicity : LC50 > 6.27 mg/l Acute dermal toxicity : LD50 estimated > 5,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : None Anticipated Reproductive effects : no data available Teratogenicity : no data available Sensitisation : no data available 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Land transport ƒ U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2.1 UN number 1950 Packaging group: None. Page 667 of 1069 Page 667 of 1069 Page 667 of 1069 Page 667 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 8/9 Note: Limited quantities derogation may be applicable to this product, please check transport documents. Sea transport ƒ IMDG: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2 UN number: 1950 Packaging group: None. EmS: F-D, S-U Note: Limited quantities derogation may be applicable to this product, please check transport documents. Air transport ƒ ICAO/IATA: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2.1 UN/ID No.: UN 1950 Packaging group: None. Note: SC Johnson typically does not ship products via air. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Registration # / Agency 4822-548/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 4 Reactivity 0 Page 668 of 1069 Page 668 of 1069 Page 668 of 1069 Page 668 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OUST® SURFACE DISINFECTANT & AIR SANITIZER - CLEAN SCENT Version 2.0 Print Date 11/12/2012 Revision Date 08/22/2012 MSDS Number 350000003666 SITE_FORM Number 30000000000000008466.001 9/9 NFPA Ratings Health 2 Fire 4 Reactivity 0 Special - Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 669 of 1069 Page 669 of 1069 Page 669 of 1069 Page 669 of 1069 ---PAGE BREAK--- PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 Revision Date 09/21/2012 Print Date 10/03/2012 1 / 7 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH MSDS Number 200000011882 CAS-No. : Not applicable - product is a mixture General Use : Home care A formulated dishwashing liquid Company : Colgate-Palmolive Canada Inc. Two Morneau Shepell Centre, 6th Fl. 895 Don Mills Road Toronto, Ontario, M3C 1W3, Canada Telephone : Emergency telephone number : For emergencies involving spill, leak, fire, exposure or accident call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887. Medical Emergency (24HR): For MEDICAL EMERGENCIES involving this product call: (888) 489-3861 SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form : Viscous liquid Appearance : White Odour : Characteristic Potential Health Effects Eye contact : Causes eye irritation on direct contact. Skin contact : May cause skin irritation upon prolonged contact. Inhalation : Overexposure may cause respiratory tract irritation. Ingestion : Harmful if swallowed. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components OSHA-REGULATED COMPONENTS (present at a concentration of > or = Chemical Name CAS-No. Concentration * Page 670 of 1069 Page 670 of 1069 Page 670 of 1069 Page 670 of 1069 ---PAGE BREAK--- PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012 2 / 7 SODIUM CARBONATE 497-19-8 5.00 - 10.00 SODIUM SILICATE 1344-09-8 1.00 - 5.00 SODIUM BISULFITE TERMINATED SODIUM POLYACRYLATE 68479-09-4 1.00 - 5.00 SODIUM HYDROXIDE 1310-73-2 1.00 - 5.00 SODIUM HYPOCHLORITE 7681-52-9 1.00 - 5.00 NO. 2 SODIUM POLYACRYLATE 1.00 - 5.00 *All concentrations are present by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Carcinogenicity: Listed Carcinogens: The following components, present at a concentration of > or = 0.1%, are listed as carcinogens or potential carcinogens by either the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC), OSHA or ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 4. FIRST AID MEASURES First aid procedures Eye contact : Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists. Skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention. Inhalation : Remove victim to fresh air. Get medical attention, if persist. Ingestion : Drink 8 ounces of clear water. Get medical attention. SECTION 5. FIREFIGHTING MEASURES Flammable properties Flash point : Remarks: no data available Page 671 of 1069 Page 671 of 1069 Page 671 of 1069 Page 671 of 1069 ---PAGE BREAK--- PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012 3 / 7 Fire fighting Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Protective equipment and precautions for firefighters Special protective equipment for firefighters : Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use personal protection recommended in Section 8 of the MSDS. Methods for containment / Methods for cleaning up : Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of water. SECTION 7. HANDLING AND STORAGE Storage Requirements for storage areas and containers : Store at controlled room temperature at 20-25°C (68-77°F). SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Chemical Name CAS- No. Value Exposure Limits Source Notes SODIUM HYDROXIDE 1310-73- 2 Ceiling 2 mg/m3 ACGIH Ceil_Ti me 2 mg/m3 NIOSH/GUIDE PEL 2 mg/m3 OSHA_TRANS Ceiling 2 mg/m3 Z1A Page 672 of 1069 Page 672 of 1069 Page 672 of 1069 Page 672 of 1069 ---PAGE BREAK--- PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012 4 / 7 Engineering Controls : In an industrial work environment, no special precautions or control measures are required. Personal protective equipment Protective measures : In an industrial work environment, if a splash is likely, chemical goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary. General Hygiene Considerations : In an industrial work environment, avoid eye and prolonged skin contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Viscous liquid Appearance : White Odour : Characteristic Flash point : Note: no data available pH : Approximate 12.5 Density : Approximate1.16 g/cm3 Viscosity, dynamic : Approximate4,500 mPa.s SECTION 10. STABILITY AND REACTIVITY Materials to avoid : Remarks: Strong oxidizing agents Hazardous decomposition products : Note: None known. Hazardous reactions : Hazardous polymerisation does not occur. SECTION 11. TOXICOLOGICAL INFORMATION This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is Page 673 of 1069 Page 673 of 1069 Page 673 of 1069 Page 673 of 1069 ---PAGE BREAK--- PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012 5 / 7 a component of the hazard determination used to prepare the statements in Section 3 of the MSDS. SECTION 12. ECOLOGICAL INFORMATION No data available SECTION 13. DISPOSAL CONSIDERATIONS Further information : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state environment agency for specific rules). Do not dump in sewers, any body of water or on the ground. SECTION 14. TRANSPORT INFORMATION DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. IMDG : Not regulated. SECTION 15. REGULATORY INFORMATION US Regulations RCRA Information : Not listed SARA Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A) : Not listed Section 313 Toxic Release Inventory (40 CFR 372) : Not listed CERCLA Hazardous Substance List (40 CFR 302.4) - Reportable Quantity : 9761 lbs Page 674 of 1069 Page 674 of 1069 Page 674 of 1069 Page 674 of 1069 ---PAGE BREAK--- PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012 6 / 7 SODIUM HYPOCHLORITE 62406 lbs SODIUM HYDROXIDE 325154 lbs Benzene Clean Air Act Clean Air Act 111 Standards of Performance for New Stationary Sources : SODIUM HYPOCHLORITE PROPYLENE GLYCOL Benzene Clean Water Act Clean Water Act Section 307(a)(1) Toxic Pollutants : ZINC CHLORIDE Benzene Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) : SODIUM HYDROXIDE ZINC CHLORIDE Benzene State Regulations Massachusetts Right-To- Know List : SODIUM HYDROXIDE SODIUM HYPOCHLORITE Benzene New Jersey Right-To- Know List : WATER SODIUM CARBONATE SODIUM SILICATE SODIUM BISULFITE TERMINATED SODIUM POLYACRYLATE Page 675 of 1069 Page 675 of 1069 Page 675 of 1069 Page 675 of 1069 ---PAGE BREAK--- PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012 7 / 7 SODIUM HYDROXIDE SODIUM HYPOCHLORITE Right-To- Know List : WATER SODIUM CARBONATE SODIUM SILICATE SODIUM HYDROXIDE SODIUM HYPOCHLORITE Canada Canadian Workplace Hazardous Materials Information System (WHMIS) Listed Material : SODIUM CARBONATE SODIUM HYDROXIDE SODIUM HYPOCHLORITE Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. Other Information TSCA Section 8(b) Status : All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory. SECTION 16. OTHER INFORMATION Further information MSDS Number : 200000011882 Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate- Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss resulting from the use of the material. Page 676 of 1069 Page 676 of 1069 Page 676 of 1069 Page 676 of 1069 ---PAGE BREAK--- Page 677 of 1069 Page 677 of 1069 Page 677 of 1069 Page 677 of 1069 ---PAGE BREAK--- Page 678 of 1069 Page 678 of 1069 Page 678 of 1069 Page 678 of 1069 ---PAGE BREAK--- Page 679 of 1069 Page 679 of 1069 Page 679 of 1069 Page 679 of 1069 ---PAGE BREAK--- Page 680 of 1069 Page 680 of 1069 Page 680 of 1069 Page 680 of 1069 ---PAGE BREAK--- Page 681 of 1069 Page 681 of 1069 Page 681 of 1069 Page 681 of 1069 ---PAGE BREAK--- Page 682 of 1069 Page 682 of 1069 Page 682 of 1069 Page 682 of 1069 ---PAGE BREAK--- Page 683 of 1069 Page 683 of 1069 Page 683 of 1069 Page 683 of 1069 ---PAGE BREAK--- Page 684 of 1069 Page 684 of 1069 Page 684 of 1069 Page 684 of 1069 ---PAGE BREAK--- Page 685 of 1069 Page 685 of 1069 Page 685 of 1069 Page 685 of 1069 ---PAGE BREAK--- Page 686 of 1069 Page 686 of 1069 Page 686 of 1069 Page 686 of 1069 ---PAGE BREAK--- Page 687 of 1069 Page 687 of 1069 Page 687 of 1069 Page 687 of 1069 ---PAGE BREAK--- Page 688 of 1069 Page 688 of 1069 Page 688 of 1069 Page 688 of 1069 ---PAGE BREAK--- Safety Data Sheet 165903 / 500351 /MSD-001 Page 1 of 3 02/13/2015 1. Product And Company Identification Product Identifier: PIG Multi-Purpose Repair Putty (MSD-001) General Use: PIG Multi-Purpose Repair Putty epoxy sticks are used to make emergency patches and repairs of a wide variety of materials. Product Description: A hand kneadable, fast curing, epoxy adhesive in stick form. COMPANY PROFILE: EMERGENCY TELEPHONE: New Pig Corporation INFOTRAC One Pork Avenue 200 North Palmetto Street Tipton, PA 16684-0304 Leesburg, FL 34748 Information Number 24 hrs, 7 days/week 1-[PHONE REDACTED] 1-[PHONE REDACTED] Website: www.newpig.com, Email: [EMAIL REDACTED] 2. Hazards Identification Warning! Irritant: Product contains chemicals known to cause skin and eye irritation and may cause sensitization by skin contact. GHS Classification: Skin corrosion/irritation, Category 2 Serious eye damage/irritation, Category 2 Skin sensitisation, Category 1 Acute aquatic toxicity, Category 3 GHS Label Elements Signal Word: Warning H315 Causes skin irritation H319 Causes serious eye irritation H317 May cause an allergic skin reaction H412 Harmful to aquatic life with long lasting effects Precautionary Statements: P264 Wash hands (skin) thoroughly after handling P273 Avoid release to the environment P280 Wear protective gloves/protective clothing/eye protection/ face protection P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P303 + P361 IF ON SKIN: Take off contaminated clothing. Wash contaminated clothing before reuse. P332 + P313 IF SKIN irritation occurs: Get medical advice/attention P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 IF eye irritation persists: Get medical advice/attention P501 Dispose of contents and container in accordance with all local, regional, national and international regulations 3. Composition/Information on Ingredients CAS: 14807-96-6 Talc 30-40% EC: 238-877-9 CAS: 25068-38-6 epoxy resin OR CAS: 25036-25-3 Diglycidyl ether of bisphenol A 10-30% CAS: 90-72-2 2,4,6-Tri (dimethylaminomethyl) phenol EC: 202-013-9 1-5% CAS: 1314-98-3 Zinc Sulfide 1-5% EC : 215-251-3 CAS: 14808-60-7 Silica, quartz 0.1-1.0% EC: 238-878-4 Non-hazardous ingredients meeting the Massachusetts and New Jersey Right-To-Know requirements: Polyether polymercaptan Trade secret Sodium calcium magnesium silicate 65997-17-3 4. First Aid Measures Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Ingestion: Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin Contact: Flush contaminated skin with plenty of soap and water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing and shoes before reuse. 5. Fire Fighting Measures Extinguishing Media: Use an extinguishing agent suitable for the surrounding fire. Special Fire Fighting Procedures: Do not breathe fumes. Fire fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous Combustion Products: Carbon dioxide, carbon monoxide, nitrogen oxides, sulfur oxides, halogenated compounds, metal oxide/oxides. Unusual Hazards: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Page 689 of 1069 Page 689 of 1069 Page 689 of 1069 Page 689 of 1069 ---PAGE BREAK--- Safety Data Sheet 165903 / 500351 /MSD-001 Page 2 of 3 02/13/2015 6. Accidental Release Measures Spill or Leak Procedures: Wear appropriate personal protective equipment. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place into a designated, labeled waste container. Product should not be released into the environment. Prevent entry into sewers, water courses, basements or confined areas. Dispose of via a licensed waste disposal contractor. 7. Handling and Storage Handling Precautions: Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Wear impervious gloves when mixing or handling uncured product. Do not ingest. Avoid contact with eyes, skin and clothing. If sanding cured putty or substrates, wear eye protection and dust mask. For prolonged exposure to sanding dust, wear a half face respirator with dust filters. Wash thoroughly after handling, especially before eating, drinking, smoking and using restroom facilities. Wash contaminated goggles, faceshield and gloves. Professionally launder contaminated clothing before re-use. Storage Precautions: Store in original container protected from direct sunlight in a cool, dry, well ventilated area < 95°F (35°C). Shelf Life: ~2 years (in original tube with cap on) General: The container can be hazardous when empty. Follow label cautions even after the container is empty. Do not re-use empty containers for food, clothing or products for human or animal consumption, or where skin contact can occur. 8. Exposure Controls/Personal Protection Engineering Controls: Good general ventilation should be sufficient. Use local exhaust or other engineering controls to keep concentrations below PEL/TLV, or during prolonged sanding operations. PERSONAL PROTECTION Eyes: Safety glasses or goggles. Respirator: None required unless sanding or abrading. Gloves: Appropriate impervious gloves. Because a variety of protective gloves exist, consult glove manufacturer to determine the proper type for a specific operation. Other: Ensure that eyewash stations and safety showers are close to the workstation location. OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200): EXPOSURE LIMITS 8 hrs. TWA (ppm) OSHA PEL ACGIH TLV Talc 20 2 mg/m3* Silica, quartz 10 mg/m3 0.025 mg/m3 respirable dust %SiO2+2 * Respirable dust for talc containing no asbestos 9. Physical and Chemical Properties Appearance: Putty, gray color after cure Odor: Sulfurous Odor Threshold: Not applicable pH: Not applicable Melting Point/Freezing Point: Not available Initial Boiling Point and Range: Decomposition temperature: >302°F (>150°C) Flash Point: >200°F (>93°C) Method: Setaflash CC Evaporation Rate: Not available Flammability Limits: Not available Conditions of Flammability: Not available Explosive Properties: Not available Vapor Pressure: Not available Vapor Density: Not available Relative Density (H20 = 1.95 Solubility in Water: Insoluble in cold and hot water Auto-ignition Temperature: Not available Coefficient of Water/Oil Distribution: Not available 10. Stability and Reactivity General: This is a stable material. Conditions of Reactivity: Under normal conditions of storage and use, hazardous reactions will not occur. Incompatible Materials and Conditions to Avoid: Temperatures above 95°F (35°C). Oxidizing agents, acids and bases, amines. For compatibility guide, call 1-[PHONE REDACTED]. Hazardous Decomposition: Nitrogen oxides. Combustion produces oxides of carbon including highly poisonous carbon monoxide. Sulphur oxides. Hazardous Polymerization: Under normal conditions of storage and use, hazardous decomposition products should not be produced. 11. Toxicological Information ACGIH, A2 - silica is a suspected human carcinogen Target Organs: No specific data POTENTIAL HEALTH EFFECTS: Eye Contact: Causes serious eye irritation. may include pain or irritation, watering, redness. Ingestion: Irritating to mouth, throat and stomach. Inhalation: Dusts released from sanding hardened putty may cause irritation to the respiratory tract. Exposure to decomposition products may cause a health hazard. Serous effects may be delayed following exposure. Skin Contact: Causes skin irritation. may include irritation, redness LD50: Not available for mixture LC50: Not applicable for mixture Page 690 of 1069 Page 690 of 1069 Page 690 of 1069 Page 690 of 1069 ---PAGE BREAK--- Safety Data Sheet 165903 / 500351 /MSD-001 Page 3 of 3 02/13/2015 11. Toxicological Information (Cont’d) Carcinogenicity: Silica, quartz: IARC: Category 1 National Toxicology Program: Quartz 14808-60-7 OSHA: See Section 15 California Prop 65: Silica, (non-respirable). Talc, not containing asbestiform fibers. Reproduction Toxicity: Not available Teratogenicity: Not available Mutagenicity: Not available Synergistic Products: Not available Diglycidyl ether of bisphenol A: Ingestion: The oral LD50 for rats is 11.4 g/kg. Skin: Severe irritant, Rabbit: 24 hours 2 Milligrams 2,4,6-Tri (dimethylaminomethyl) phenol: Ingestion: The oral LD50 for rats is 1200 mg/kg. Skin: The dermal LD50 for rats is 1280 mg/kg. Skin: Severe irritant, Rat: 0.25 Milliliters 12. Ecological Information Mobility: Water contaminating. Persistence and degradability: Not inherently biodegradable Bioaccumulative potential: Taking into consideration the properties of several components, the product is estimated not to be readily biodegradable according to OECD classification. Ozone depletion potential: No ozone depleting chemicals are present or used in manufacture. Toxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. Disposal Considerations Waste Disposal Method: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contactor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 14. Transport Information DOT (Department of Transportation): Proper Shipping Name: Putty, NMFC 150110 Hazard Class: Not regulated Identification Number: Not applicable 15. Regulatory Information CERCLA (Comprehensive Environmental Response Compensation and Liability Act): No Reportable Quantity OSHA Hazard Communication Standard, 29 CFR 1910.1200: silica, talc (no asbestos fibers). SARA Title III (Superfund Amendments and Reauthorization Act): silica non-respirable, Bisphenol-A- epoxy resin, 2,4,6-Tri (dimethylaminomethyl) phenol. This product contains zinc compounds which are subject to the reporting requirements of section 313. They constitute approximately 1-5% of the putty. TSCA (Toxic Substances Control Act): Ingredients of this product are on the Inventory list. State regulations: Massachusetts: Mineral wool fiber; Soapstone New Jersey: Soapstone; Silica, quartz; Quartz (SiO2); Zinc compounds Soapstone dust; quartz (SiO2); Zinc compounds 16. Other Information NFPA Hazard Ratings: Health – 2 none  extreme Fire - 1 0  4 Reactivity – 0 PPE - B WHMIS Classification: D2B Reason for Issue: Reviewed, changes to Sections 2, 4, 6, 7 & 16. Prepared by: Dale Gatehouse, Entreprises Krenda Inc. Approved by: Lisa Baxter, New Pig Corporation Previous Date of Issue: 02/24/2014 Revised Date: 02/13/2015 SDS Number: MSD-001 The following is in lieu of all warranties, expressed or implied: All information provided is based on testing and data believed to be accurate. Page 691 of 1069 Page 691 of 1069 Page 691 of 1069 Page 691 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® CLEAN & DUST WIPES - CITRUS SCENT Version 1. Print Date 08/25/2008 Revision Date 08/22/2008 MSDS Number 350000003620 1/7 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : PLEDGE® CLEAN & DUST WIPES - CITRUS SCENT Use of the Substance/Preparation : Furniture Polish/Cleaner Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : white / Wipes / orange Immediate Concerns : No adverse effects expected when used as directed. Potential Health Effects Routes of exposure : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : None known. Inhalation : None known. Ingestion : None known. Aggravated Medical Condition : None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight % Deionized Water 7732-18-5 40.00 - 70.00 Non-woven fabric Mixture 15.00 - 40.00 Dimethicone 63148-62-9 3.00 - 7.00 Naphtha (petroleum), hydrotreated heavy 64742-48-9 3.00 - 7.00 4. FIRST AID MEASURES Page 692 of 1069 Page 692 of 1069 Page 692 of 1069 Page 692 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® CLEAN & DUST WIPES - CITRUS SCENT Version 1. Print Date 08/25/2008 Revision Date 08/22/2008 MSDS Number 350000003620 2/7 Eye contact : Rinse with plenty of water. Skin contact : Rinse with plenty of water. Inhalation : No special requirements Ingestion : No special requirements 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Alcohol foam, carbon dioxide, dry chemical, water fog Further information : Standard procedure for chemical fires. Fight fire with normal precautions from a reasonable distance. Flash point : Note: not applicable Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Handling Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Storage Requirements for storage areas and containers : Keep in a dry, cool and well-ventilated place. Page 693 of 1069 Page 693 of 1069 Page 693 of 1069 Page 693 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® CLEAN & DUST WIPES - CITRUS SCENT Version 1. Print Date 08/25/2008 Revision Date 08/22/2008 MSDS Number 350000003620 3/7 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection : not required under normal use Eye protection : No special requirements. Hygiene measures : Wash thoroughly after handling. Avoid contact with eyes. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Wipes Color : white Odor : orange pH : not applicable Melting point : no data available Boiling point : no data available Flash point : not applicable Evaporation rate : no data available Autoignition temperature : not applicable Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Water solubility : negligible Partition coefficient: n- octanol/water : no data available Page 694 of 1069 Page 694 of 1069 Page 694 of 1069 Page 694 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® CLEAN & DUST WIPES - CITRUS SCENT Version 1. Print Date 08/25/2008 Revision Date 08/22/2008 MSDS Number 350000003620 4/7 Viscosity, dynamic : not applicable Specific Gravity : not applicable Percent volatile : not determined 10. STABILITY AND REACTIVITY Conditions to avoid : None known. Materials to avoid : None. Hazardous decomposition products : When exposed to fire, produces normal products of combustion. Hazardous reactions : Stable 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : no data available 12. ECOLOGICAL INFORMATION Ecotoxicity effects : Not Available Page 695 of 1069 Page 695 of 1069 Page 695 of 1069 Page 695 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® CLEAN & DUST WIPES - CITRUS SCENT Version 1. Print Date 08/25/2008 Revision Date 08/22/2008 MSDS Number 350000003620 5/7 13. DISPOSAL CONSIDERATIONS Product : Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. 14. TRANSPORT INFORMATION Land transport ƒ U.S. DOT and Canadian TDG Surface Transportation UN-Number: None. Proper shipping name not regulated Class: None. Packaging group None. Sea transport ƒ IMDG: UN-Number: None. Packaging group: None. Proper shipping name not regulated Class: None. Air transport ƒ ICAO/IATA: Class: None. Packaging group: None. Proper shipping name not regulated UN/ID No.: None. 15. REGULATORY INFORMATION Global Chemical Inventories Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects. Page 696 of 1069 Page 696 of 1069 Page 696 of 1069 Page 696 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® CLEAN & DUST WIPES - CITRUS SCENT Version 1. Print Date 08/25/2008 Revision Date 08/22/2008 MSDS Number 350000003620 6/7 16. OTHER INFORMATION HMIS Ratings Health 1 Flammability 0 Reactivity 0 NFPA Ratings Health 1 Fire 0 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 697 of 1069 Page 697 of 1069 Page 697 of 1069 Page 697 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® CLEAN & DUST WIPES - CITRUS SCENT Version 1. Print Date 08/25/2008 Revision Date 08/22/2008 MSDS Number 350000003620 7/7 Page 698 of 1069 Page 698 of 1069 Page 698 of 1069 Page 698 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 1/11 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Recommended use : Hard Surface Cleaner Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Gases under pressure Compressed gas Contains gas under pressure; may explode if heated. Labelling Hazard symbols Gas cylinder Signal word Warning Hazard statements Contains gas under pressure; may explode if heated. Precautionary statements Protect from sunlight. Store in a well-ventilated place. Other hazards : None identified Page 699 of 1069 Page 699 of 1069 Page 699 of 1069 Page 699 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 2/11 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 1.00 - 5.00 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : No special requirements 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Aerosol Product - Containers may rocket or explode in heat of fire. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Page 700 of 1069 Page 700 of 1069 Page 700 of 1069 Page 700 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 3/11 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wash thoroughly after handling. Environmental precautions : Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : Sweep up and shovel into suitable containers for disposal. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Precautions for safe handling : Avoid contact with skin, eyes and clothing. For personal protection see section 8. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Normal measures for preventive fire protection. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Ethyl alcohol 64-17-5 1,900 mg/m3 1,000 ppm - OSHA TWA Ethyl alcohol 64-17-5 - 1,000 ppm - ACGIH STEL Personal protective equipment Respiratory protection : No special requirements. Hand protection : No special requirements. Page 701 of 1069 Page 701 of 1069 Page 701 of 1069 Page 701 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 4/11 Eye protection : No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : aerosol Compressed gas Color : clear Odor : Woody Odour Threshold : No data available pH : 6.0 - 7.0 at (20 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : does not flash Evaporation rate : No data available Flammability (solid, gas) : Does not sustain combustion. Upper/lower flammability or explosive limits : No data available Page 702 of 1069 Page 702 of 1069 Page 702 of 1069 Page 702 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 5/11 Vapour pressure : similar to water Vapour density : No data available Relative density : 0.99 g/cm3 at 20 °C Solubility(ies) : completely soluble Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, dynamic : similar to water Viscosity, kinematic : similar to water Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 1.9 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous : If accidental mixing occurs and toxic gas is formed, exit area Page 703 of 1069 Page 703 of 1069 Page 703 of 1069 Page 703 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 6/11 reactions immediately. Do not return until well ventilated. Conditions to avoid : Direct sources of heat. Incompatible materials : Do not mix with bleach or any other household cleaners. Strong bases Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Warning Acute oral toxicity : LD50 Calculated > 5,000 mg/kg Acute inhalation toxicity : No data available Acute dermal toxicity : LD50 Calculated > 2,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Page 704 of 1069 Page 704 of 1069 Page 704 of 1069 Page 704 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 7/11 Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard No classification proposed - Aggravated Medical Condition : None known. 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Ethyl alcohol flow- through test LC50 Pimephales promelas (fathead minnow) 14,200 mg/l 96 h Toxicity to aquatic invertebrates Ethyl alcohol static test EC50 Daphnia magna (Water flea) 48 h Components End point Species Value Exposure time Components End point Species Value Exposure time Page 705 of 1069 Page 705 of 1069 Page 705 of 1069 Page 705 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 8/11 2 mg/l NOEC Daphnia magna 9.6 mg/l 9 d Toxicity to aquatic plants Ethyl alcohol Static EC50 Chlorella vulgaris (Fresh water algae) 275 mg/l 72 h Persistence and degradability Component Biodegradation Exposure time Summary Ethyl alcohol 97 % 28 d Readily biodegradable Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Ethyl alcohol 3.2 estimated -0.35 Measured Mobility Component End point Value Ethyl alcohol No data available PBT and vPvB assessment Component Results Ethyl alcohol Not fulfilling PBT and vPvB criteria Components End point Species Value Exposure time Page 706 of 1069 Page 706 of 1069 Page 706 of 1069 Page 706 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 9/11 Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper shipping name UN 1950 AEROSOLS, non-flammable, 2.2 UN 1950 AEROSOLS, non- flammable, 2.2 UN 1950 AEROSOLS, non-flammable, 2.2 Transport hazard class(es) 2.2 2 2.2 Packing group - - - Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Page 707 of 1069 Page 707 of 1069 Page 707 of 1069 Page 707 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 10/11 Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. 16. OTHER INFORMATION HMIS Ratings Health 0 Flammability 0 Reactivity 0 NFPA Ratings Health 0 Fire 0 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information Page 708 of 1069 Page 708 of 1069 Page 708 of 1069 Page 708 of 1069 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000019958 11/11 This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 709 of 1069 Page 709 of 1069 Page 709 of 1069 Page 709 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 1/8 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Use of the Substance/Mixture : Furniture Polish/Cleaner Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : yellow / liquid / pleasant Immediate Concerns : Caution Avoid contact with skin, eyes and clothing. May be harmful if swallowed. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : Prolonged or repeated contact may dry skin and cause irritation. Inhalation : Excessive exposures may affect human health, as follows: Inhalation may cause central nervous system effects. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aspiration hazard if swallowed - can enter lungs and cause damage. Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. Page 710 of 1069 Page 710 of 1069 Page 710 of 1069 Page 710 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 2/8 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Hydrocarbons, C16-C20, n- alkanes, isoalkanes, cyclics, aromatics 64742-46-7 30.00 - 60.00 White Mineral Oil, (Petroleum) 8042-47-5 30.00 - 60.00 Citrus, Extract 94266-47-4 1.00 - 5.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Container may melt and leak in heat of fire. Further information : Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. Flash point : 102 °C Page 711 of 1069 Page 711 of 1069 Page 711 of 1069 Page 711 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 3/8 215.6 °F Method: Tag Closed Cup (TCC) Lower explosion limit : Note: not applicable Upper explosion limit : Note: not applicable 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Material can create slippery conditions. Personal precautions : No special precautions required. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Normal measures for preventive fire protection. Storage Requirements for storage areas and containers : Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis White Mineral Oil, (Petroleum) 8042-47-5 5 mg/m3 - - ACGIH TWA Personal protective equipment Page 712 of 1069 Page 712 of 1069 Page 712 of 1069 Page 712 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 4/8 Respiratory protection No personal respiratory protective equipment normally required. Hand protection : No special requirements. Eye protection No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : yellow Odor : pleasant pH : not applicable Boiling point : no data available Freezing point : no data available Flash point : 102 °C 215.6 °F Method: Tag Closed Cup (TCC) Evaporation rate : no data available Flammability (solid, gas) : Does not sustain combustion. Lower explosion limit : not applicable Upper explosion limit : not applicable Vapour pressure : no data available Density : 0.8424 g/cm3 at 40 °C Water solubility : negligible Viscosity, dynamic : 24 mPa.s at 40 °C Page 713 of 1069 Page 713 of 1069 Page 713 of 1069 Page 713 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 5/8 Viscosity, kinematic : 28.5 mm2/s at 40 °C Volatile Organic Compounds Total VOC (wt. : 1.1 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations 10. STABILITY AND REACTIVITY Conditions to avoid : Direct sources of heat. Materials to avoid : Strong oxidizing agents Materials to avoid : None known. Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 Calculated > 5,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Chronic effects Carcinogenicity : no data available Mutagenicity : None Anticipated Reproductive effects : no data available Teratogenicity : no data available Page 714 of 1069 Page 714 of 1069 Page 714 of 1069 Page 714 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 6/8 Sensitisation : Substance is not a sensitizer. 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport  U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport  IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport  ICAO/IATA: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Page 715 of 1069 Page 715 of 1069 Page 715 of 1069 Page 715 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 7/8 Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 1 Flammability 1 Reactivity 0 NFPA Ratings Health 1 Fire 1 Reactivity 0 Special - This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 716 of 1069 Page 716 of 1069 Page 716 of 1069 Page 716 of 1069 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL Version 2.0 Print Date 05/22/2014 Revision Date 05/21/2014 MSDS Number 350000017409 8/8 Page 717 of 1069 Page 717 of 1069 Page 717 of 1069 Page 717 of 1069 ---PAGE BREAK--- Version: 2.0 Effective Date: Apr-16-2015 Previous Date: Apr-10-2015 SAFETY DATA SHEET Potassium Hydrogen Phthalate Solutions 1. Identification Product identifier Potassium Hydrogen Phthalate Solutions Other means of identification None. Product application This SDS provides health and safety information for any (unacidified) KHP component of the following vials or kits. GE Analytical Instruments part number Product name STD 62025, STD 68110, STD 68210, STD 68225, STD 68250, STD 68310, STD 68350, STD68410, STD68450, STD68520, STD 77250, STD 90056 , 91200, STD 91300, STD 91400, STD 91500, STD 91600, STD 93100 - GE Analytical Instruments kit number STD 68020, 77000, 77014, 77200 , 90000, 90001, 90002, 90003, 90004, 90005, 90014, 90016, 90017, 90018, 90019, 90020, 90021, 90023, 90025, 90026, 90028, 90031, 90036, 96000, 99001 Recommended use Calibration Standard Recommended restrictions None known. GE Analytical Instruments Inc 6060 Spine Road Boulder, CO 80301 T [PHONE REDACTED] Emergency telephone 1-[PHONE REDACTED] INFOTRAC (North America) Outside of N.A., call collect: 1-[PHONE REDACTED] GE (800) 877-1940 Company/undertaking identification 2. Hazard(s) identification Not classified. Physical hazards Not classified. Health hazards Not classified. OSHA defined hazards Label elements None. Hazard symbol Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Page: 1 / 6 Page 718 of 1069 Page 718 of 1069 Page 718 of 1069 Page 718 of 1069 ---PAGE BREAK--- Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 7732-18-5 Water > 95.5 877-24-7 Potassium hydrogen phthalate < 4.5 Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our assessment of the potential hazards of this formulation. 4. First-aid measures Inhalation No treatment required. Skin contact Wash off with soap and water. Eye contact Flush eyes with water as a precaution. Ingestion Do not give anything to eat or drink. Most important acute and delayed None known. 5. Fire-fighting measures Suitable extinguishing media This product does not represent a fire hazard since it contains a high amount of water. Unsuitable extinguishing media None known. Specific hazards arising from the chemical None known. Special protective equipment and precautions for firefighters No special protective equipment required. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures See Section 8 of the SDS for Personal Protective Equipment. Methods and materials for containment and cleaning up Spills of the product are very slippery. Contain and recover by physical means. Remove small spills with plenty of water. Environmental precautions No special environmental precautions required. 7. Handling and storage Precautions for safe handling Handle in accordance with good industrial hygiene and safety procedures. Conditions for safe storage, including any incompatibilities Reasonable and safe chemical storage. 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Adequate ventilation. Individual protection measures, such as personal protective equipment Eye/face protection Safety goggles. Skin protection Hand protection None required. Other No special protective equipment required. Respiratory protection Not required. Thermal hazards Not applicable. Page: 2 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 719 of 1069 Page 719 of 1069 Page 719 of 1069 Page 719 of 1069 ---PAGE BREAK--- 9. Physical and chemical properties Appearance Color Colorless Physical state Liquid Odor None Odor threshold None pH (concentrated product) 6.5 Melting point/freezing point 32 °F (0 Initial boiling point and boiling range 212 °F (100 Flash point > 212 °F 100 Pensky Martens (CC) Evaporation rate 1 (Water = 1) Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 18 mm Hg at 21°C Vapor density 1 (Air = 1) Relative density 1 Solubility(ies) Solubility (water) 100 % Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 1 @ 4°C VOC (Weight None 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid None known. Incompatible materials None known. Hazardous decomposition products None known. 11. Toxicological information Information on likely routes of exposure Inhalation None known. Skin contact None known. Eye contact None known. Ingestion None known. related to the physical, chemical and toxicological characteristics Not available. Page: 3 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 720 of 1069 Page 720 of 1069 Page 720 of 1069 Page 720 of 1069 ---PAGE BREAK--- Information on toxicological effects Acute toxicity Not classified. Test Results Product Species Potassium Hydrogen Phthalate Solutions (CAS Mixture) LD50 Rat Oral Acute > 5000 mg/kg, (Calculated according to GHS additivity formula) Skin corrosion/irritation Not classified. Serious eye damage/eye irritation Not classified. Respiratory or skin sensitization Respiratory sensitization Not classified. Skin sensitization Not classified. Germ cell mutagenicity Not classified. Carcinogenicity Not classified. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Not classified. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not classified. 12. Ecological information Ecotoxicity No ecotoxicity data noted for the ingredient(s). Bioaccumulative potential Not available. Mobility in soil Not available. Other adverse effects Not available. Persistence and degradability No data available 13. Disposal considerations Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner. Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. 15. Regulatory information US federal regulations All components of this product are included on or are in compliance with the U.S. TSCA regulations. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. Page: 4 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 721 of 1069 Page 721 of 1069 Page 721 of 1069 Page 721 of 1069 ---PAGE BREAK--- CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Inventory status Country(s) or region Inventory name On inventory (yes/no)* Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). US state regulations US - Massachusetts RTK - Substance List Not regulated. US - RTK - Hazardous Substances Not regulated. US - Rhode Island RTK Not regulated. US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Worker and Community Right-to-Know Law Not listed. US. California Proposition 65 US - California Proposition 65 - CRT: Listed date/Carcinogenic substance No ingredient listed. US - California Proposition 65 - CRT: Listed date/Developmental toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin No ingredient listed. Page: 5 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 722 of 1069 Page 722 of 1069 Page 722 of 1069 Page 722 of 1069 ---PAGE BREAK--- 16. Other information, including date of preparation or last revision Issue date Mar-18-2015 Revision date Apr-16-2015 Version # 2.0 List of abbreviations CAS: Chemical Abstract Service Registration Number NFPA: National Fire Protection Association ACGIH: American Conference of Governmental Industrial Hygienists TWA: Time Weighted Average STEL: Short Term Exposure Limit LD50: Lethal Dose, 50% LC50: Lethal Concentration, 50% EC50: Effect Concentration, 50% NOEL: No Observed Effect Level COD: Chemical Oxygen Demand BOD: Biochemical Oxygen Demand TOC: Total Organic Carbon TLV: Threshold Limit Value IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by This SDS has been prepared by GE Water & Process Technologies Regulatory Department (1-[PHONE REDACTED]). Page: 6 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 723 of 1069 Page 723 of 1069 Page 723 of 1069 Page 723 of 1069 ---PAGE BREAK--- PRODUCT SAFETY DATA SHEET 28 Mar 2007 Print date: 1. PRODUCT AND COMPANY IDENTIFICATION Item Number / Product code: 0064131 PROFESSIONAL Product name: PROFESSIONAL LYSOL® BRAND FOOD SURFACE SANITIZER (TRIGGER) Validation / Revision Date: 28 March 2007 EPA Identifier: EPA Reg. Number: 6836-290-675 Formula Number: 1154-055 (0064131) UPC Number and Size: 36241-80028 40 oz. Trigger. Product Description: A food surface sanitizer spray in a trigger container. Manufacturer: Reckitt Benckiser North America, Inc. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 Emergency telephone number: 1-[PHONE REDACTED] Transportation Emergencies: 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside the U.S. and Canada (North America), call: [PHONE REDACTED] 2. COMPOSITION / INFORMATION ON INGREDIENTS Product name: PROFESSIONAL LYSOL® BRAND FOOD SURFACE SANITIZER (TRIGGER) Page 1 of 7 Product code: 0064131 PROFESSIONAL 23 Sep 2009 23 Sep 2009 Page 724 of 1069 Page 724 of 1069 Page 724 of 1069 Page 724 of 1069 ---PAGE BREAK--- Components: Wt % ACGIH: OSHA: DIALKYL DIMETH AMMO CHLOR 68424-95-3 0-0.01 None None BENZALKONIUM CHLORIDE 80% 68424-85-1 0-0.01 None None ETHANOL SDA 40-2 95% 64-17-5 0-0.01 TWA (TLV): 1000 ppm @10 TWA (PEL): 1000 ppm @10 TWA (PEL): 1900 mg/m³ @10 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION: Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling. KEEP OUT OF REACH OF CHILDREN 4. FIRST AID MEASURES Inhalation: Move to fresh air. Skin contact: Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Eye contact: If in eyes, hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses if present after the first 5 minutes then continue rinsing. Call a Poison Control Center or doctor for treatment advice Ingestion: Rinse mouth with water. Contact a physician or Poison Control Center if develop. Never give an unconscious person anything to ingest Notes to physician: Treat Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Flash point: CLOSED CUP: Higher than 93.3º C (>200º [Tagliabue]. Flammability Limits in Air: Lower: No information available. Upper: No information available. Autoignition temperature: No information available. Suitable extinguishing media: As suitable for surrounding fire. Extinguishing media which must not be used for safety reasons: No information available. Specific hazards: Not applicable. Unusual hazards: None known Product name: PROFESSIONAL LYSOL® BRAND FOOD SURFACE SANITIZER (TRIGGER) Page 2 of 7 Product code: 0064131 PROFESSIONAL Page 725 of 1069 Page 725 of 1069 Page 725 of 1069 Page 725 of 1069 ---PAGE BREAK--- Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus, pressure- demand, MSHA / NIOSH (approved or equivalent) and full protective gear. Specific methods: Standard procedure for chemical fires. Key: Personal Protection Index = A. (Also see Sections 3 & 8) 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid contact with eyes. Read and follow container directions. For clean-up of a large quantity spill, wear appropriate skin and eye protection. Environmental precautions: Do not allow material to contaminate ground water system. Methods for cleaning up: Small spills: Dilute with water and mop up, or absorb with an inert material and place in an appropriate waste disposal container. Large spills: Contain and collect for later disposal according to local, provincial, state or federal regulations. 7. HANDLING AND STORAGE Handling: None required for normal use according to the label instructions. For occupational exposures wear appropriate eye and skin protection where the potential for splashing exists. CAUTION: Causes moderate eye irritantion. Avoid contact with eyes, skin and clothing. Storage: Store containers in an upright position in a cool, dry area, inaccessable to small children and pets. Do not store on side. Avoid creasing or impacting of side walls. Do not reuse empty container. Discard in trash or recycle when empty. KEEP OUT OF REACH OF CHILDREN Incompatible products: None known. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: For occupational exposures, ensure adequate ventilation. Personal Protective Equipment Respiratory protection: None required under normal use conditions. Hand protection: None required for normal recommended use. Read product label instructions carefully. Emergency responders should wear impermeable gloves. Health: 2 Flammability: 0 Flammability: 0 Reactivity: 0 Instability: 0 NFPA: Health: 2 Product code: 0064131 PROFESSIONAL HMIS: Product name: PROFESSIONAL LYSOL® BRAND FOOD SURFACE SANITIZER (TRIGGER) Page 3 of 7 Page 726 of 1069 Page 726 of 1069 Page 726 of 1069 Page 726 of 1069 ---PAGE BREAK--- Skin and body protection: None required under normal recommended use conditions. Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the product that has been dissolved in liquid (such as a fire scene) is possible. Eye protection: Emergency responders should wear full eye and face protection. None required under recommended product use. Appropriate eye protection such as: Safety glasses with side shields, chemical goggles or full face shield for occupational exposures. Hygiene measures: Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid (Trigger spray container) Appearance: Clear liquid. Colour: Clear, water white Odour: Odorless. pH: 9.5 - 11.0 Flash point: Greater than 93º C (>200º F) Specific gravity: 1.19 (Water = 1.0) Vapour pressure: Not determined. Solubility: Completely soluble. Explosion limits: - upper: No data available. - lower: No data available. 10. STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. Polymerization: Hazardous polymerisation does not occur. Hazardous decomposition products: Oxides of carbon and unknown organic compounds. Materials to avoid: Do not mix with other household chemicals. Conditions to avoid: Store away from excessive heat and moisture. 11. TOXICOLOGICAL INFORMATION Acute toxicity Component Information: Product Information LC50/inhalation/4h/rat = No information available. LD50/dermal/rabbit = No information available. LD50/oral/rat = No information available. Local effects Skin irritation: None expected during normal conditions of use. Eye irritation: Moderate eye irritation Product name: PROFESSIONAL LYSOL® BRAND FOOD SURFACE SANITIZER (TRIGGER) Page 4 of 7 Product code: 0064131 PROFESSIONAL Page 727 of 1069 Page 727 of 1069 Page 727 of 1069 Page 727 of 1069 ---PAGE BREAK--- Inhalation None expected during normal conditions of use. Ingestion Health injuries are not known or expected under normal use. Sensitization Not expected to be a skin sensitiser. Chronic toxicity: No information available. Specific effects Carcinogenic effects: Not listed as carcinogenic by OSHA, NTP or IARC. Mutagenic effects: No information available. Reproductive toxicity: No information available. Target organ effects: No information available. Information is based on data on the components and the toxicology of similar products. 12. ECOLOGICAL INFORMATION Product Information Aquatic toxicity: No information available. Component Information: Other information: Ozone depletion potential; ODP; (R-11 = 1) = No information available. Global warming potential (GWP) = No information available. Additional ecological information: No information available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of in accordance with local regulations. Contaminated packaging: Empty container can be disposed of as household trash or rinsed and recycled where appropriate. 14. TRANSPORT INFORMATION UN / Id No: Not applicable DOT: Classification: Not a DOT regulated material. (United States) Proper shipping name: Not applicable. U.S. DOT - Hazard Class: Not applicable. Subsidiary risk: Not applicable. Packing Group: Not applicable. DOT RQ (lbs): Not applicable. = 11200 mg/L LC50 fingerling trout = 12900 mg/L LC50 rainbow trout (30 days old) flow-through = 14200 mg/L LC50 fathead minnow flow-through = 34634 mg/L EC50 Photobacterium phosphoreum = 35470 mg/L EC50 Photobacterium phosphoreum Product code: 0064131 PROFESSIONAL ETHANOL SDA 40-2 95% 64-17-5 (0-0.01) Product name: PROFESSIONAL LYSOL® BRAND FOOD SURFACE SANITIZER (TRIGGER) Page 5 of 7 Ecotoxicity: Page 728 of 1069 Page 728 of 1069 Page 728 of 1069 Page 728 of 1069 ---PAGE BREAK--- ERG No: Not applicable. TDG (Canada): Classification: Not regulated under TDG Proper shipping name: Not applicable. Status: Not applicable. Packing Group: Not applicable. WHMIS hazard class: Not a WHMIS controlled product. IMDG / IMO Classification: Not regulated under IMDG Proper shipping name: Not applicable. Class: Not applicable. Subsidiary Risk: Not applicable. Packing group: Not applicable. IMDG page: Not applicable. Marine pollutant: Not applicable. EMS: Not applicable. MFAG: See Guide. ADR / RID Classification: Not applicable. Proper shipping name: Not applicable. Class: Not applicable. Subsidiary risk: Not applicable. Packing Group: Not applicable. ADR/RID-labels: Not applicable Hazard Identification Number: Not applicable. CEFIC Tremcard No: Not applicable. ICAO / IATA: Classification: Not regulated under ICAO / IATA Proper shipping name: Not applicable. Class: Not applicable. Subsidiary Risk: Not applicable Packing Group: Not applicable. Maximum quantity Not applicable. 15. REGULATORY INFORMATION Components: PICCS: TSCA: DSL: NDSL: ENCS: CHINA: AICS: EINECS-No DIALKYL DIMETH AMMO CHLOR Present Present 270-331-5 BENZALKONIUM CHLORIDE 80% Present Present 270-325-2 ETHANOL SDA 40-2 95% Present Present 200-578-6 U.S. Regulations: California Proposition 65 - None. California Proposition 65 - None. CERCLA/SARA 313: None Components: Components: ETHANOL SDA 40-2 95% - 64-17-5 CERCLA/SARA 313: None Not Listed. California Proposition 65 - None. Not Listed. Components: BENZALKONIUM CHLORIDE 80% - 68424-85-1 DIALKYL DIMETH AMMO CHLOR - 68424-95-3 Product code: 0064131 PROFESSIONAL Product name: PROFESSIONAL LYSOL® BRAND FOOD SURFACE SANITIZER (TRIGGER) Page 6 of 7 Not Listed. Page 729 of 1069 Page 729 of 1069 Page 729 of 1069 Page 729 of 1069 ---PAGE BREAK--- Canada WHMIS hazard class: Not a WHMIS controlled product. 16. OTHER INFORMATION Reason for revision: This is a new product. Additional advice: This product should only be used as directed on the label and for the purpose intended. Prepared by: Reckitt Benckiser Inc. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. Phone: [PHONE REDACTED] FAX: [PHONE REDACTED]. Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. HMIS CERCLA/SARA 313: None Product code: 0064131 PROFESSIONAL National Fire Protection Association Product name: PROFESSIONAL LYSOL® BRAND FOOD SURFACE SANITIZER (TRIGGER) Page 7 of 7 Health Hazard Reactivity 0 2 Fire Hazard Personal Protection A 0 Regulatory Department Update product information. Page 730 of 1069 Page 730 of 1069 Page 730 of 1069 Page 730 of 1069 ---PAGE BREAK--- PRODUCT SAFETY DATA SHEET 08 Sep 2008 Print date: 1. PRODUCT AND COMPANY IDENTIFICATION Item Number / Product code: 0081285 Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Validation / Revision Date: 08 Sepetmber 2008 Formula Number: 0081285 (1095-050) Country; 0082445 (1095-056) Fresh; 0081288 (1095-058) Original; 0081283 (1095-048) Green Apple Breeze; 0081286 (1095-052) Garden Mist; 0081280 (1095-046) Spring Waterfall; 0081281 (1095-047) Crisp Linen. UPC Number and Size: Country Scent®, 36241-04625 (19 oz.); Fresh, 36241-04675 (19 oz.); Original Scent, 36241-04650 (19 oz.); Green Apple Breeze®, 36241-76768 (19 oz.); Garden Mist®, 36241-80571 (19 oz.); Spring Waterfall®, 36241-76075 (19 oz.); Crisp Linen®, 36241-74828 (19 oz.). Product Description: Disinfectant aerosol spray. Manufacturer: Reckitt Benckiser North America, Inc. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 Telephone: +1 [PHONE REDACTED] Emergency Telephone Number: 1-[PHONE REDACTED] (U.S) Transportation Emergencies: 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside the U.S. and Canada (North America), call: [PHONE REDACTED] Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Page 1 of 10 Product code: 0081285 0081285 (1095-050) Country; 0082445 (1095-056) Fresh; 0081288 (1095-058) Original; 0081286 (1095-052) Garden Mist; 0081280 (1095-046) Spring Waterfall; 0081281 (1095-047) Crisp Linen. Country Scent®, 36241-04625 (19 oz.); Fresh, 36241-04675 (19 oz.); Original Scent, 36241-04650 (19 oz.); Garden Mist®, 36241-80571 (19 oz.); Spring Waterfall®, 36241-76075 (19 oz.); Crisp Linen®, 36241-74828 (19 oz.). 24 June 2009 24 June 2009 Page 731 of 1069 Page 731 of 1069 Page 731 of 1069 Page 731 of 1069 ---PAGE BREAK--- 2. COMPOSITION / INFORMATION ON INGREDIENTS Components: Wt % ACGIH: OSHA: ETHANOL SDA 40-2 95% 64-17-5 55-60 TWA (TLV): 1000 ppm @10 TWA (PEL): 1000 ppm @10 TWA (PEL): 1900 mg/m³ @10 ISOBUTANE 75-28-5 3-4 TWA (TLV): 800 ppm par TWA (TLV): 1900 mg/m3 None PROPANE 74-98-6 3-4 TWA (TLV): 1000 ppm @10 TWA (TLV): 1000 ppm @10 TWA (PEL): 1000 ppm @10 TWA (PEL): 1800 mg/m³ @10 N-ALDIMETHBENZAMMSAC 33% 68989-01-5 0-1 None None 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: FLAMMABLE ! CAUTION: Contents under pressure. DO NOT puncture or incinerate container. DO NOT expose to heat or store above 55º C (130º as container may burst. Keep away from heat, sparks and open flame. Causes moderate eye irritation. Do not spray in eyes, on skin or on clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum or using tobacco. KEEP OUT OF REACH OF CHILDREN 4. FIRST AID MEASURES Inhalation: Move to fresh air. Skin contact: Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Eye contact: If in eyes, IMMEDIATELY hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses if present after the first 5 minutes then continue rinsing eye. Call a Poison Control Center or Doctor for treatment advice. Ingestion: Call a physician or Poison Control Center immediately. Rinse mouth with water and drink afterwards plenty of water. DO NOT INDUCE VOMITING! Notes to physician: Contains denatured ethanol; ingestion may result in ethanol poisoning Aggravated Medical Conditions: No information available. Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Page 2 of 10 Product code: 0081285 Page 732 of 1069 Page 732 of 1069 Page 732 of 1069 Page 732 of 1069 ---PAGE BREAK--- 5. FIRE-FIGHTING MEASURES Flash point: 65.5º F (18.6º Aerosol flame extension less than 18 inches (45 cm). FLAMMABLE AEROSOL. Flammability Limits in Air: Lower: 3.3% in Air. Upper: 19% in Air. Autoignition temperature: No information available. Suitable extinguishing media: Water spray mist or foam. As suitable for surrounding fire. Extinguishing media which must not be used for safety reasons: No information available. Specific hazards: Contents under pressure. Exposure to temperatures above 55º C (130º F) may cause bursting. Keep away from extreme heat, sparks or open flame. Unusual hazards: Move containers away from fire if possible and safe to do so. Use water spray to cool fire exposed containers. Provide shielding for personnel exposed to venting, rupturing or bursting containers Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus, pressure-demand, MSHA / NIOSH (approved or equivalent) and full protective gear. Specific methods: Standard procedure for chemical fires. NFPA Aerosol Level: Flammability Rating 1, per NFPA 30B. Key: Personal Protection Index = B. (Also see Sections 3 & 8) 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Ensure adequate ventilation. Environmental precautions: Do not allow material to contaminate ground water system. Methods for cleaning up: Small amounts: Wipe up with absorbent material (e.g. cloth, fleece, paper towel, etc.). Large spills: Eliminate all sources of ignition and ventilate the area with equipment rated for use in flammable environments. Collect any remaining liquid and store in metal container for later disposal according to local, state, provincial or federal regulations. Flammability: 3 Flammability: 1 Reactivity: 0 Instability: 0 NFPA: Health: 1 HMIS: Product code: 0081285 Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Page 3 of 10 Health: 1 Page 733 of 1069 Page 733 of 1069 Page 733 of 1069 Page 733 of 1069 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling: Use with adequate ventilation. Safe handling advice: CAUTION: Contents under pressure. DO NOT puncture or incinerate. DO NOT expose to heat or store above 55º C (130º as container may burst. Storage: KEEP OUT OF REACH OF CHILDREN Keep away from heat and sources of ignition. Store in original container in areas inaccessable to small children and pets. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: For occupational exposures, ensure adequate ventilation. Personal Protective Equipment Respiratory protection: No personal respiratory protective equipment normally required. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of vapours generated by this product during a spill or other clean-up operations. Hand protection: Avoid contact with the skin. For sensitive skin or prolonged use, wear rubber gloves. Emergency responders should wear impermeable gloves. Eye protection: Not required under normal conditions of use. Causes moderate eye irritation. Avoid contact with eyes. Emergency responders should wear full eye and face protection. Skin and body protection: Usual safety precautions while handling the product will provide adequate protection against injury or irritation. Follow product label instructions. Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands with soap and water after use. Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Page 4 of 10 Product code: 0081285 Page 734 of 1069 Page 734 of 1069 Page 734 of 1069 Page 734 of 1069 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid (Aerosol spray container) Appearance: Aerosol. Colour: Clear, water white Odour: Fragrances are scent specific. See container label for scent description. pH: 10.5 Flash point: 65.5º F (18.6º Aerosol flame extension less than 45 centimeters (18 inches). Flammable Aerosol. Specific gravity: Greater than 1.0. Vapour pressure: 95 - 105 psig. Solubility: Completely soluble. Explosion limits: - upper: 19% - lower: 3.3% 10. STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. DO NOT expose to heat or store above 55º C (130º F) as container may burst. Polymerization: Hazardous polymerisation does not occur. Hazardous decomposition products: Oxides of carbon and unknown organic compounds. Materials to avoid: Oxidising agents. Conditions to avoid: Keep away from open flames, hot surfaces and sources of ignition. Pressurised container. Protect from the sunlight and do not expose to temperatures exceeding 55º C (130º Extremes of temperature can occur in cars and near ovens and fireplaces. Do not place in contact with hot surfaces or near naked flames. Do not pierce or burn even after use. Do not spray on a naked flame, onto or near fire, or any incandescent material such as an electric fire. Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Page 5 of 10 Product code: 0081285 Page 735 of 1069 Page 735 of 1069 Page 735 of 1069 Page 735 of 1069 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Acute toxicity Component Information: Product Information LC50/inhalation/4h/rat = No information available. LD50/dermal/rabbit = No information available. LD50/oral/rat = No information available. Local effects Skin irritation: None expected during normal conditions of use. Eye irritation: Causes moderate eye irritation. Inhalation None expected during normal use. However intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. NOTE TO PARENTS: Intentional misuse by deliberately concentrating and inhaling aerosol products may be harmful or fatal. Ingestion Harmful if swallowed. Contains denatured ethyl alcohol. Sensitization Not expected to be a skin sensitiser. Chronic toxicity: No information available. Specific effects Carcinogenic effects: Not listed as carcinogenic by OSHA, NTP or IARC. Mutagenic effects: No information available. Reproductive toxicity: No information available. Target organ effects: No information available. Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Page 6 of 10 Product code: 0081285 Page 736 of 1069 Page 736 of 1069 Page 736 of 1069 Page 736 of 1069 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Product Information Aquatic toxicity: No information available. Component Information: Other information: Ozone depletion potential; ODP; (R-11 = 1) = No information available. Global warming potential (GWP) = No information available. Additional ecological information: Information given is based on data on the components and the ecotoxicology of similar products. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of in accordance with local regulations. Contaminated packaging: Empty container can be disposed of as household trash or rinsed and recycled where appropriate. Waste Disposal: Container disposal: Empty containers may be included with domestic refuse for disposal to a landfill. This container may also be recycled in communities where aerosol container recycling is available. Before offering for recycling, empty the can or use the product according to the label instructions. Product code: 0081285 Ecotoxicity: Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) = 11200 mg/L LC50 fingerling trout = 12900 mg/L LC50 rainbow trout (30 days old) flow-through = 14200 mg/L LC50 fathead minnow flow-through = 34634 mg/L EC50 Photobacterium phosphoreum = 35470 mg/L EC50 Photobacterium phosphoreum Page 7 of 10 ETHANOL SDA 40-2 95% 64-17-5 (55-60) Page 737 of 1069 Page 737 of 1069 Page 737 of 1069 Page 737 of 1069 ---PAGE BREAK--- 14. TRANSPORT INFORMATION UN / Id No: UN 1950 DOT: Classification: UN1950, Aerosols, Flammable, Class 2.1 Re-Classed as Consumer Commodity ORM-D. Proper shipping name: Consumer Commodity U.S. DOT - Hazard Class: Not applicable. Subsidiary risk: Not applicable. Packing Group: Not applicable. DOT RQ (lbs): Not applicable. ERG No: 126 / 171 TDG (Canada): Classification: UN 1950, Aerosols, Flammable, Class 2.1 Re-Classed as Consumer Commodity. Proper shipping name: Consumer Commodity / Limited Quantity / LTD. QTY. Status: Not applicable. Packing Group: Not applicable. WHMIS hazard class: B5 Flammable aerosol IMDG / IMO Classification: UN 1950 - Aerosols, Class 2.1, Limited Quantity. Proper shipping name: Aerosols. Class: 2 Subsidiary Risk: Not applicable. Packing group: Not applicable. IMDG page: See IMDG Code. Marine pollutant: Not applicable. EMS: Not applicable. F-D, S-U MFAG: Not applicable. Maximum quantity: See IMDG Code. ADR / RID Classification: Not applicable. Proper shipping name: Not applicable. Class: Not applicable. Subsidiary risk: Not applicable. ADR/RID-labels: Not applicable Hazard Identification Number: Not applicable. CEFIC Tremcard No: Not applicable. ICAO / IATA: Classification: UN 1950 - Aerosols, Flammable, Limited Quantity. or Consumer Commodity, ID 8000, if acceptable to airline (500 ml. / 17 fl.oz. or less). Proper shipping name: Aerosols, Flammable / Consumer Commodity. Class: 2.1 / (9 if shipped as a Consumer Commodity) Subsidiary Risk: Not applicable Packing Group: Not applicable. Maximum quantity See DG List. Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Page 8 of 10 Product code: 0081285 Page 738 of 1069 Page 738 of 1069 Page 738 of 1069 Page 738 of 1069 ---PAGE BREAK--- 15. REGULATORY INFORMATION Components: PICCS: TSCA: DSL: NDSL: ENCS: CHINA: AICS: EINECS-No ETHANOL SDA 40-2 95% Present Present Present Present 200-578-6 ISOBUTANE Present Present Present Present Present 200-857-2 PROPANE Present Present Present Present 200-827-9 N-ALDIMETHBENZAMMSAC 33% Present Present Present Present 273-545-7 U.S. Regulations: CERCLA/SARA 313: None Canada WHMIS hazard class: B5 Flammable aerosol N-ALDIMETHBENZAMMSAC 33% - 68989-01-5 ISOBUTANE - 75-28-5 Not Listed. Listed (Sn 0844) California Proposition 65 - None. Not Listed. ETHANOL SDA 40-2 95% - 64-17-5 California Proposition 65 - None. Components: PROPANE - 74-98-6 California Proposition 65 - None. Not Listed. Components: California Proposition 65 - None. Product code: 0081285 Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Components: Page 9 of 10 Components: Page 739 of 1069 Page 739 of 1069 Page 739 of 1069 Page 739 of 1069 ---PAGE BREAK--- 16. OTHER INFORMATION Reason for revision: Revision of data and / or an update of the PSDS. Additional advice: This product should only be used as directed on the label and for the purpose intended. Prepared by: Reckitt Benckiser Inc. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: [PHONE REDACTED]. Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. National Fire Protection Association HMIS Product code: 0081285 Product name: PROFESSIONAL LYSOL® BRAND III DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) Page 10 of 10 Health Hazard Note: NFPA Aerosol Level: Flammability rated as per NFPA 30B. Reactivity 0 1 Fire Hazard Personal Protection B 3 Regulatory Group Page 740 of 1069 Page 740 of 1069 Page 740 of 1069 Page 740 of 1069 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 2* Flammability 0 Reactivity 0 DATE OF PREPARATION Mar 5, 2010 MATERIAL SAFETY DATA SHEET B20W2251 19 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B20W2251 PRODUCT NAME PROMAR® 200 Interior Latex Eg-Shel Enamel, Extra White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 2 107-21-1 Ethylene Glycol ACGIH TLV 100 MG/M3 CEILING (aerosol) 0.12 mm OSHA PEL 50 PPM CEILING 0.1 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 15 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 13 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 741 of 1069 Page 741 of 1069 Page 741 of 1069 Page 741 of 1069 ---PAGE BREAK--- B20W2251 page 2 of 4 UEL N.A. LEL N.A. FLASH POINT Not Applicable SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Page 742 of 1069 Page 742 of 1069 Page 742 of 1069 Page 742 of 1069 ---PAGE BREAK--- B20W2251 page 3 of 4 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.85 lb/gal 1299 g/l SPECIFIC GRAVITY 1.31 BOILING POINT 212 - 388 °F 100 - 197 °C MELTING POINT Not Available VOLATILE VOLUME 58% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.2 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.78lb/gal 94g/l Less Water and Federally Exempt Solvents 0.35lb/gal 42g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans. TOXICOLOGY DATA CAS No. Ingredient Name 107-21-1 Ethylene Glycol LC50 RAT 4HR Not Available LD50 RAT 4700 mg/kg 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Page 743 of 1069 Page 743 of 1069 Page 743 of 1069 Page 743 of 1069 ---PAGE BREAK--- B20W2251 page 4 of 4 SECTION 14 — TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 107-21-1 Ethylene Glycol 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 744 of 1069 Page 744 of 1069 Page 744 of 1069 Page 744 of 1069 ---PAGE BREAK--- page 1 of 3 UEL N.A. LEL N.A. FLASH POINT Not Applicable HMIS Codes Health 1 Flammability 0 Reactivity 0 DATE OF PREPARATION Feb 25, 2011 MATERIAL SAFETY DATA SHEET B30T2654 06 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B30T2654 PRODUCT NAME PROMAR® 200 Zero VOC Interior Latex Flat, Ultradeep Base MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS No ingredients in this product are hazardous as defined by the Department of Labor. SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Page 745 of 1069 Page 745 of 1069 Page 745 of 1069 Page 745 of 1069 ---PAGE BREAK--- B30T2654 page 2 of 3 SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Required for long or repeated contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.98 lb/gal 1076 g/l SPECIFIC GRAVITY 1.08 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 65% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.00 lb/gal 0 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. Page 746 of 1069 Page 746 of 1069 Page 746 of 1069 Page 746 of 1069 ---PAGE BREAK--- B30T2654 page 3 of 3 HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. TOXICOLOGY DATA No LC50 or LD50 data available. SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 747 of 1069 Page 747 of 1069 Page 747 of 1069 Page 747 of 1069 ---PAGE BREAK--- ® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 12 SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: Propanol Issue Date: 03/31/2015 Print Date: 07/31/2015 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. IDENTIFICATION Product name: Propanol Recommended use of the chemical and restrictions on use Identified uses: Industrial solvent. Chemical intermediate. We recommend that you use this product in a manner consistent with the listed use. If your intended use is not consistent with the stated use, please contact your sales or technical service representative. COMPANY IDENTIFICATION THE DOW CHEMICAL COMPANY 2030 WILLARD H DOW CENTER MIDLAND MI 48674-0000 UNITED STATES Customer Information Number: [PHONE REDACTED] [EMAIL REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Hazard classification This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Flammable liquids - Category 3 Serious eye damage - Category 1 Specific target organ toxicity - single exposure - Category 3 Label elements Hazard pictograms Page 748 of 1069 Page 748 of 1069 Page 748 of 1069 Page 748 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 2 of 12 Signal word: DANGER! Hazards Flammable liquid and vapour. Causes serious eye damage. May cause drowsiness or dizziness. Precautionary statements Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Use only outdoors or in a well-ventilated area. Wear protective gloves/ eye protection/ face protection. Response IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage Store in a well-ventilated place. Keep container closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/ container to an approved waste disposal plant. Other hazards no data available 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: propan-1-ol This product is a substance. Page 749 of 1069 Page 749 of 1069 Page 749 of 1069 Page 749 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 3 of 12 Component CASRN Concentration Propanol 71-23-8 100.0% 4. FIRST AID MEASURES Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin contact: Wash off with plenty of water. Eye contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. Most important and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Maintain adequate ventilation and oxygenation of the patient. Chemical eye burns may require extended irrigation. Obtain prompt consultation, preferably from an ophthalmologist. The decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. No specific antidote. Treatment of exposure should be directed at the control of and the clinical condition of the patient. Skin contact may aggravate preexisting dermatitis. 5. FIREFIGHTING MEASURES Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Unsuitable extinguishing media: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Special hazards arising from the substance or mixture Page 750 of 1069 Page 750 of 1069 Page 750 of 1069 Page 750 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 4 of 12 Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Unusual Fire and Explosion Hazards: Container may vent and/or rupture due to fire. When product is stored in closed containers, a flammable atmosphere can develop. Electrically ground and bond all equipment. Flammable mixtures of this product are readily ignited even by static discharge. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Flammable mixtures may exist within the vapor space of containers at room temperature. Flammable concentrations of vapor can accumulate at temperatures above flash point; see Section 9. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Use caution and test if material is burning before entering area. Material burns with invisible flame. Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Evacuate area. Refer to section 7, Handling, for additional precautionary measures. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Contain spilled material if possible. Collect in suitable and properly labeled containers. Large spills: Pump with explosion-proof equipment. If available, use foam to smother or supress. Ground and bond all containers and handling equipment. See Section 13, Disposal Considerations, for additional information. 7. HANDLING AND STORAGE Precautions for safe handling: Keep away from heat, sparks and flame. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on Page 751 of 1069 Page 751 of 1069 Page 751 of 1069 Page 751 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 5 of 12 or near empty containers. Never use air pressure for transferring product. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Do not get in eyes. Avoid breathing vapor. Do not swallow. Avoid contact with skin and clothing. Wash thoroughly after handling. No smoking, open flames or sources of ignition in handling and storage area. Keep container closed. Use only with adequate ventilation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or flame. Keep container closed. Storage stability Storage Period: Steel drums. 24 Month Bulk 12 Month 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure limits are listed below, if they exist. Component Regulation Type of listing Value/Notation Propanol ACGIH TWA 100 ppm OSHA Z-1 TWA 500 mg/m3 200 ppm Exposure controls Engineering controls: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Individual protection measures Eye/face protection: Use chemical goggles. If exposure causes eye discomfort, use a full- face respirator. Skin protection Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Natural rubber (“latex”). Neoprene. Nitrile/butadiene rubber (“nitrile” or “NBR”). Polyethylene. Ethyl vinyl alcohol laminate (“EVAL”). Polyvinyl chloride (“PVC” or “vinyl”). Viton. Avoid gloves made of: Polyvinyl alcohol NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. Selection of air-purifying or positive- Page 752 of 1069 Page 752 of 1069 Page 752 of 1069 Page 752 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 6 of 12 pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. The following should be effective types of air-purifying respirators: Organic vapor cartridge. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Liquid. Color Colorless Odor Mild Odor Threshold No test data available pH No test data available Melting point/range -127 °C ( -197 Literature Freezing point -127 °C ( -197 Literature Boiling point (760 mmHg) 97 °C ( 207 at 100.32 kPa Literature Flash point closed cup 24 °C ( 75 DIN 51755 Evaporation Rate (Butyl Acetate = 1) 1.3 Literature Flammability (solid, gas) Not applicable to liquids Lower explosion limit 2.1 % vol Literature Upper explosion limit 13.7 % vol Literature Vapor Pressure 15 mmHg at 20 °C (68 Literature Relative Vapor Density (air = 1) 2.1 Literature Relative Density (water = 1) 0.805 at 20 °C (68 / 20 °C Literature Water solubility 100 % at 20 °C (68 Literature Partition coefficient: n- octanol/water log Pow: 0.25 Measured Auto-ignition temperature 400 °C (752 at 1,013 hPa Literature Decomposition temperature No test data available Kinematic Viscosity 2.3 mm2/s at 25 °C (77 Literature Explosive properties no data available Oxidizing properties no data available Molecular weight 60.10 g/mol Molecular formula C3H7OH Percent volatility No test data available Saturated vapour concentration No test data available Volatile Organic Compounds 805 g/L Literature NOTE: The physical data presented above are typical values and should not be construed as a specification. Page 753 of 1069 Page 753 of 1069 Page 753 of 1069 Page 753 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 7 of 12 10. STABILITY AND REACTIVITY Reactivity: no data available Chemical stability: Stable. Possibility of hazardous reactions: Polymerization will not occur. Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Avoid static discharge. Incompatible materials: Avoid contact with: Aldehydes. Halides. Halogenated organics. Halogens. Strong acids. Strong oxidizers. Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Carbon monoxide. Carbon dioxide. 11. TOXICOLOGICAL INFORMATION Toxicological information on this product or its components appear in this section when such data is available. Acute toxicity Acute oral toxicity Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. LD50, Rat, > 2,000 mg/kg Acute dermal toxicity Prolonged skin contact is unlikely to result in absorption of harmful amounts. LD50, Rabbit, male, 4,032 mg/kg OECD Test Guideline 402 Acute inhalation toxicity Prolonged excessive exposure may cause adverse effects. May cause respiratory irritation and central nervous system depression. may include headache, dizziness and drowsiness, progressing to incoordination and unconsciousness. LC50, Rat, male and female, 4 Hour, vapour, > 33.8 mg/l OECD Test Guideline 403 Skin corrosion/irritation Prolonged exposure not likely to cause significant skin irritation. May cause drying and flaking of the skin. May cause more severe response on covered skin (under clothing, gloves). Page 754 of 1069 Page 754 of 1069 Page 754 of 1069 Page 754 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 8 of 12 Serious eye damage/eye irritation May cause severe irritation with corneal injury which may result in permanent impairment of vision, even blindness. Chemical burns may occur. Vapor may cause eye irritation experienced as mild discomfort and redness. Sensitization Did not cause allergic skin reactions when tested in guinea pigs. Did not cause allergic skin reactions when tested in humans. For respiratory sensitization: No relevant data found. Specific Target Organ Systemic Toxicity (Single Exposure) May cause drowsiness or dizziness. Route of Exposure: Inhalation Specific Target Organ Systemic Toxicity (Repeated Exposure) In animals, effects have been reported on the following organs: Central nervous system. Liver. Carcinogenicity Available data are inadequate to evaluate carcinogenicity. Did not cause cancer in animal skin painting studies. Teratogenicity At extremely high concentrations, n-propanol has been reported to cause birth defects in rats. At progressively lower concentrations there were no birth defects. These concentrations exceed relevant human dose levels. Reproductive toxicity In animal studies, has been shown to interfere with fertility in males. Effects are reversible. These concentrations exceed relevant human dose levels. Mutagenicity In vitro genetic toxicity studies were negative in some cases and positive in other cases. Animal genetic toxicity studies were inconclusive Aspiration Hazard May be harmful if swallowed and enters airways. 12. ECOLOGICAL INFORMATION Ecotoxicological information on this product or its components appear in this section when such data is available. Toxicity Acute toxicity to fish Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Page 755 of 1069 Page 755 of 1069 Page 755 of 1069 Page 755 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 9 of 12 LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 4,555 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates LC50, scud Gammarus sp., static test, 48 Hour, 1,000 mg/l EC50, Daphnia magna (Water flea), static test, 48 Hour, 3,644 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants EC50, Pseudokirchneriella subcapitata (green algae), static test, 48 Hour, Growth rate inhibition, 9,170 mg/l Toxicity to bacteria IC50, activated sludge, static test, 3 Hour, > 1,000 mg/l, OECD 209 Test Chronic aquatic toxicity Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), 21 d, number of > 100 mg/l Persistence and degradability Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. 10-day Window: Pass Biodegradation: 83 % Exposure time: 5 d Method: OECD Test Guideline 301D or Equivalent 10-day Window: Pass Biodegradation: 83 - 92 % Exposure time: 28 d Method: OECD Test Guideline 301F or Equivalent Theoretical Oxygen Demand: 2.40 mg/mg Biological oxygen demand (BOD) Incubation Time BOD 5 d 58 - 64 % 10 d 76 % 20 d 75 - 94 % Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: Ozone. Atmospheric half-life: 23 Hour Method: Estimated. Bioaccumulative potential Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient: n-octanol/water(log Pow): 0.25 Measured Mobility in soil Potential for mobility in soil is very high (Koc between 0 and 50). Page 756 of 1069 Page 756 of 1069 Page 756 of 1069 Page 756 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 10 of 12 Partition coefficient(Koc): 3 Estimated. 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device. 14. TRANSPORT INFORMATION DOT Proper shipping name Propyl alcohol, normal UN number UN 1274 Class 3 Packing group III Classification for SEA transport (IMO-IMDG): Proper shipping name PROPYL ALCOHOL, NORMAL UN number UN 1274 Class 3 Packing group III Marine pollutant No Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code Consult IMO regulations before transporting ocean bulk Classification for AIR transport (IATA/ICAO): Proper shipping name Propyl alcohol, normal UN number UN 1274 Class 3 Packing group III This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. Page 757 of 1069 Page 757 of 1069 Page 757 of 1069 Page 757 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 11 of 12 15. REGULATORY INFORMATION OSHA Hazard Communication Standard This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Fire Hazard Acute Health Hazard Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) Section 103 This material does not contain any components with a CERCLA RQ. Worker and Community Right-To-Know Act: The following product components are cited in the Hazardous Substance List and/or the Environmental Substance List, and are present at levels which require reporting. Components CASRN Propanol 71-23-8 California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances knownto the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. United States TSCA Inventory (TSCA) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. : 16. OTHER INFORMATION Hazard Rating System NFPA Health Fire Reactivity 2 3 0 Revision Identification Number: 101234211 / A001 / Issue Date: 03/31/2015 / Version: 3.4 Page 758 of 1069 Page 758 of 1069 Page 758 of 1069 Page 758 of 1069 ---PAGE BREAK--- Product name: Propanol Issue Date: 03/31/2015 Page 12 of 12 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend ACGIH USA. ACGIH Threshold Limit Values (TLV) OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 8-hour, time-weighted average Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company. THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer- specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 759 of 1069 Page 759 of 1069 Page 759 of 1069 Page 759 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 1 / 15 SECTION 1. IDENTIFICATION Product name : PURELL® Hand Sanitizer Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-[PHONE REDACTED] CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal Word : Warning Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation. Page 760 of 1069 Page 760 of 1069 Page 760 of 1069 Page 760 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 2 / 15 Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration Ethanol 64-17-5 50 - < 70 Propan-2-ol 67-63-0 1 - < 5 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Page 761 of 1069 Page 761 of 1069 Page 761 of 1069 Page 761 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 3 / 15 Get medical attention. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Page 762 of 1069 Page 762 of 1069 Page 762 of 1069 Page 762 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 4 / 15 Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Page 763 of 1069 Page 763 of 1069 Page 763 of 1069 Page 763 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 5 / 15 Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 STEL 1,000 ppm ACGIH Propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm 980 mg/m3 NIOSH REL ST 500 ppm 1,225 mg/m3 NIOSH REL TWA 400 ppm 980 mg/m3 OSHA Z-1 Biological occupational exposure limits Ingredients CAS-No. Control parameters Biological specimen Sam- pling time Permissible concentratio n Basis Propan-2-ol 67-63-0 Acetone Urine End of shift at end of work- week 40 mg/l ACGIH BEI Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and Page 764 of 1069 Page 764 of 1069 Page 764 of 1069 Page 764 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 6 / 15 use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety goggles Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : clear, Colorless to pale yellow Odor : citrus Odor Threshold : No data available pH : 6.0 - 9.2 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Page 765 of 1069 Page 765 of 1069 Page 765 of 1069 Page 765 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 7 / 15 Flash point : 25 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 0.89 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 1,000 - 35,000 mm2/s (20 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. Page 766 of 1069 Page 766 of 1069 Page 766 of 1069 Page 766 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 8 / 15 SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Propan-2-ol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Propan-2-ol: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Ingredients: Page 767 of 1069 Page 767 of 1069 Page 767 of 1069 Page 767 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 9 / 15 Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Propan-2-ol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Propan-2-ol: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative Propan-2-ol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Mammalian micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative Page 768 of 1069 Page 768 of 1069 Page 768 of 1069 Page 768 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 10 / 15 Carcinogenicity Not classified based on available information. Ingredients: Propan-2-ol: Species: Rat Application Route: inhalation (vapor) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Propan-2-ol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative STOT-single exposure Not classified based on available information. Ingredients: Propan-2-ol: Assessment: May cause drowsiness or dizziness. Page 769 of 1069 Page 769 of 1069 Page 769 of 1069 Page 769 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 11 / 15 STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Propan-2-ol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapor) Exposure time: 104 w Method: OECD Test Guideline 413 Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Propan-2-ol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 24 h Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800 mg/l Page 770 of 1069 Page 770 of 1069 Page 770 of 1069 Page 770 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 12 / 15 Exposure time: 8 d Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Propan-2-ol: Biodegradability : Result: rapidly degradable Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: n- octanol/water : log Pow: -0.35 Propan-2-ol: Partition coefficient: n- octanol/water : log Pow: 0.05 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulation UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. Page 771 of 1069 Page 771 of 1069 Page 771 of 1069 Page 771 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 13 / 15 (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 IATA-DGR UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo aircraft) : 366 Packing instruction (passenger aircraft) : 355 IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. Class : 3 Packing group : III Labels : FLAMMABLE LIQUID ERG Code : 127 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Page 772 of 1069 Page 772 of 1069 Page 772 of 1069 Page 772 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 14 / 15 Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: Propan-2-ol 67-63-0 3.013 % US State Regulations Right To Know Ethanol 64-17-5 50 - 70 % Water 7732-18-5 30 - 50 % Propan-2-ol 67-63-0 1 - 5 % New Jersey Right To Know Ethanol 64-17-5 50 - 70 % Water 7732-18-5 30 - 50 % Propan-2-ol 67-63-0 1 - 5 % California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) Page 773 of 1069 Page 773 of 1069 Page 773 of 1069 Page 773 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizer Version 1.2 Revision Date: 03/19/2015 MSDS Number: 46955-00003 Date of last issue: 02/10/2015 Date of first issue: 01/13/2015 15 / 15 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 03/19/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro- vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8 Flammability Health Instability 2 3 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 3 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 774 of 1069 Page 774 of 1069 Page 774 of 1069 Page 774 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 1 / 15 SECTION 1. IDENTIFICATION Product name : PURELL® Hand Sanitizing Spray Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-[PHONE REDACTED] CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal Word : Warning Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation. Page 775 of 1069 Page 775 of 1069 Page 775 of 1069 Page 775 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 2 / 15 Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration Ethanol 64-17-5 70 - < 90 Propan-2-ol 67-63-0 1 - < 5 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Page 776 of 1069 Page 776 of 1069 Page 776 of 1069 Page 776 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 3 / 15 Get medical attention. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Page 777 of 1069 Page 777 of 1069 Page 777 of 1069 Page 777 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 4 / 15 Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Page 778 of 1069 Page 778 of 1069 Page 778 of 1069 Page 778 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 5 / 15 Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 STEL 1,000 ppm ACGIH Propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm 980 mg/m3 NIOSH REL ST 500 ppm 1,225 mg/m3 NIOSH REL TWA 400 ppm 980 mg/m3 OSHA Z-1 Biological occupational exposure limits Ingredients CAS-No. Control parameters Biological specimen Sam- pling time Permissible concentratio n Basis Propan-2-ol 67-63-0 Acetone Urine End of shift at end of work- week 40 mg/l ACGIH BEI Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and Page 779 of 1069 Page 779 of 1069 Page 779 of 1069 Page 779 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 6 / 15 use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety goggles Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : clear, Colorless to pale yellow Odor : citrus Odor Threshold : No data available pH : 5.5 - 9.0 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Page 780 of 1069 Page 780 of 1069 Page 780 of 1069 Page 780 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 7 / 15 Flash point : 25.50 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 0.8740 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 1,000 - 17,000 mm2/s (20 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. Page 781 of 1069 Page 781 of 1069 Page 781 of 1069 Page 781 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 8 / 15 SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Propan-2-ol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Propan-2-ol: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Ingredients: Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Page 782 of 1069 Page 782 of 1069 Page 782 of 1069 Page 782 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 9 / 15 Propan-2-ol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Propan-2-ol: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative Propan-2-ol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Mammalian micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative Carcinogenicity Not classified based on available information. Ingredients: Propan-2-ol: Page 783 of 1069 Page 783 of 1069 Page 783 of 1069 Page 783 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 10 / 15 Species: Rat Application Route: inhalation (vapor) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Propan-2-ol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative STOT-single exposure Not classified based on available information. Ingredients: Propan-2-ol: Assessment: May cause drowsiness or dizziness. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Ethanol: Page 784 of 1069 Page 784 of 1069 Page 784 of 1069 Page 784 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 11 / 15 Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Propan-2-ol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapor) Exposure time: 104 w Method: OECD Test Guideline 413 Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Propan-2-ol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 24 h Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800 mg/l Exposure time: 8 d Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h Page 785 of 1069 Page 785 of 1069 Page 785 of 1069 Page 785 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 12 / 15 Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Propan-2-ol: Biodegradability : Result: rapidly degradable Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: n- octanol/water : log Pow: -0.35 Propan-2-ol: Partition coefficient: n- octanol/water : log Pow: 0.05 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulation UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 IATA-DGR Page 786 of 1069 Page 786 of 1069 Page 786 of 1069 Page 786 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 13 / 15 UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo aircraft) : 366 Packing instruction (passenger aircraft) : 355 IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. Class : 3 Packing group : III Labels : FLAMMABLE LIQUID ERG Code : 127 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. Page 787 of 1069 Page 787 of 1069 Page 787 of 1069 Page 787 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 14 / 15 SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: Propan-2-ol 67-63-0 3.4086 % US State Regulations Right To Know Ethanol 64-17-5 70 - 90 % Water 7732-18-5 20 - 30 % Propan-2-ol 67-63-0 1 - 5 % New Jersey Right To Know Ethanol 64-17-5 70 - 90 % Water 7732-18-5 20 - 30 % Propan-2-ol 67-63-0 1 - 5 % California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: REACH : All ingredients (pre-)registered or exempt. TSCA : All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption. DSL : All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL). AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) Page 788 of 1069 Page 788 of 1069 Page 788 of 1069 Page 788 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Spray Version 1.0 Revision Date: 03/30/2015 MSDS Number: 81219-00001 Date of last issue: - Date of first issue: 03/30/2015 15 / 15 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 03/30/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro- vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8 Flammability Health Instability 2 3 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 3 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 789 of 1069 Page 789 of 1069 Page 789 of 1069 Page 789 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 1 / 14 SECTION 1. IDENTIFICATION Product name : PURELL® Hand Sanitizing Wipes Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-[PHONE REDACTED] CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal Word : Warning Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation. Page 790 of 1069 Page 790 of 1069 Page 790 of 1069 Page 790 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 2 / 14 Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration Ethanol 64-17-5 10 - < 20 Benzethonium chloride 121-54-0 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Page 791 of 1069 Page 791 of 1069 Page 791 of 1069 Page 791 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 3 / 14 Get medical attention. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Page 792 of 1069 Page 792 of 1069 Page 792 of 1069 Page 792 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 4 / 14 Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Page 793 of 1069 Page 793 of 1069 Page 793 of 1069 Page 793 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 5 / 14 Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 STEL 1,000 ppm ACGIH Hazardous components without workplace control parameters Ingredients CAS-No. Benzethonium chloride 121-54-0 Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Page 794 of 1069 Page 794 of 1069 Page 794 of 1069 Page 794 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 6 / 14 Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety goggles Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : impregnated cloth Color : colorless, clear, cloudy Odor : citrus Odor Threshold : No data available pH : 4.0 - 7.5 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 37.8 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Page 795 of 1069 Page 795 of 1069 Page 795 of 1069 Page 795 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 7 / 14 Density : 0.9780 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : No data available Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Page 796 of 1069 Page 796 of 1069 Page 796 of 1069 Page 796 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 8 / 14 Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Benzethonium chloride: Acute oral toxicity : LD50 (Rat): 295 mg/kg Method: OECD Test Guideline 401 Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Benzethonium chloride: Species: Rabbit Result: Corrosive after 1 to 4 hours of exposure Serious eye damage/eye irritation Causes serious eye irritation. Ingredients: Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Benzethonium chloride: Page 797 of 1069 Page 797 of 1069 Page 797 of 1069 Page 797 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 9 / 14 Test Type: Magnusson-Kligman-Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative Benzethonium chloride: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Carcinogenicity Not classified based on available information. Ingredients: Benzethonium chloride: Species: Rat Application Route: Skin contact Exposure time: 2 Years Result: negative IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Page 798 of 1069 Page 798 of 1069 Page 798 of 1069 Page 798 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 10 / 14 Method: OECD Test Guideline 416 Result: negative STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Benzethonium chloride: Toxicity to fish : LC50 mykiss (rainbow trout)): 1.15 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.22 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Page 799 of 1069 Page 799 of 1069 Page 799 of 1069 Page 799 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 11 / 14 Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 0.12 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 M-Factor (Acute aquatic tox- icity) : 1 Toxicity to bacteria : EC50: 35.70 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Benzethonium chloride: Biodegradability : Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 301B Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: n- octanol/water : log Pow: -0.35 Benzethonium chloride: Partition coefficient: n- octanol/water : log Pow: 1.08 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. Page 800 of 1069 Page 800 of 1069 Page 800 of 1069 Page 800 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 12 / 14 SECTION 14. TRANSPORT INFORMATION International Regulation Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Right To Know Water 7732-18-5 70 - 90 % Ethanol 64-17-5 10 - 20 % Propan-2-ol 67-63-0 0.1 - 1 % New Jersey Right To Know Water 7732-18-5 70 - 90 % Ethanol 64-17-5 10 - 20 % D-Glucitol, ethoxylated 53694-15-8 1 - 5 % Page 801 of 1069 Page 801 of 1069 Page 801 of 1069 Page 801 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 13 / 14 California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: REACH : All ingredients (pre-)registered or exempt. TSCA : All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption. DSL : All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL). AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek OSHA Z-1 / TWA : 8-hour time weighted average Flammability Health Instability 2 2 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 2 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 802 of 1069 Page 802 of 1069 Page 802 of 1069 Page 802 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Hand Sanitizing Wipes Version 1.0 Revision Date: 03/30/2015 MSDS Number: 80013-00001 Date of last issue: - Date of first issue: 03/30/2015 14 / 14 Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 03/30/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid- ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8 Page 803 of 1069 Page 803 of 1069 Page 803 of 1069 Page 803 of 1069 ---PAGE BREAK--- Safety Data Sheet Page 1 of 4 January 2015 1. Identification Name of the product: ReadRight PowerDuster Product Identification Number(s): RR3530 Recommended use: No-residue spray duster Use not recommended: Any use contacting skin or subject to inhaling large amount of fumes or exposure to flame. Company: Advantus Corporation Telephone: [PHONE REDACTED] 12276 San Jose Blvd., Ste. 618 Fax number: [PHONE REDACTED] Jacksonville, FL 32223 Emergency: 1-[PHONE REDACTED] CHEMTREC (Transportation): 1-[PHONE REDACTED] CPR STATEMENT: This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the SDS contains all the information required by the CPR. This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the U.S. Government's Occupational Safety and Health Administration (OSHA). It is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation. 2. Hazards identification Emergency Overview GHS Classification OSHA Hazards per 29 CFR 1910: OSHA HCS Flammable Gasses, Category 1 H220 Extremely flammable gas. Gases under pressure (Compressed gas), H280 Gas under pressure. May explode if heated. Other hazards which do not result in classification are: None GHS Label elements, including precautionary statements Pictogram: Signal word: Danger Hazard statements: H205 Extremely flammable gas. H280 Contains gas under pressure; may explode if heated. Inhalation of high concentrations of vapor is harmful and may cause heart irregularities, unconsciousness or death. Intentional misuse or deliberate inhalation may cause death without warning. Vapor reduces oxygen available for breathing and is heavier than air. Liquid contact can cause frostbite. H313 May be harmful in contact with skin. Precautionary statements: P211 Do not spray on an open flame or other ignition source. P251 Pressurized container. Do not pierce or burn even after use. P270 Do not eat, drink or smoke while using this product. P235+ P410 + P403 Keep cool. Protect from sunlight. Store in a well-ventilated place. Hazards not otherwise classified (HNOC) or not covered by GHS - 3. Composition / Information on ingredients Chemical identity: 1,1-Difluoroethane 100% Common name: HFC 152a Numbers of identity: CAS #75-37-6 Impurities: None known. Page 804 of 1069 Page 804 of 1069 Page 804 of 1069 Page 804 of 1069 ---PAGE BREAK--- Safety Data Sheet Page 2 of 4 4. First-aid measures P304+313 +341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Consult a physician. P302+352 IF ON SKIN: Wash with soap and water. Check for frost bite. P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Check for frostbite. Remove contact lenses if present and easy to do; continue rinsing. P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Most important and effects, both acute and delayed: Severe eye irritation. Skin irritation. Because of possible disturbances of cardiac catecholamine drugs, such as epinephrine, should be used with special caution only in situations of emergency life support. 5. Firefighting measures Suitable extinguishing equipment: Water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Emergency procedures: Fire and Explosion Hazards: Aerosol cans may erupt with force at temperatures above 49° C (120° F) Fire decomposition by-products will include hydrofluoric acid, and possibly carbonyl fluoride. Avoid contact with theses materials, which are toxic and irritating. Evacuate personnel immediately in the event of a fire involving this product. Extinguishing Media: Water Spray, Water fog, Dry Chemical, Carbon dioxide. “Alcohol” foam. Cool cans with water spray. If gas exiting can ignites, stop flow of gas. Do not put out fire unless leak can be stopped. Self-contained breathing apparatus (SCBA) is required if containers rupture and contents are released under fire conditions. 6. Accidental release measures Use personal protective equipment. Avoid breathing, mist or vapors. Ensure adequate ventilation. NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. The chances of a large spill or leak are unlikely in aerosol containers. If this product is spilled and not recovered, or is recovered as a waste for treatment or disposal, the CERCLA Reportable Quantity is 100 lbs. (Release of an unlisted Hazardous Waste characteristic of ignitability). 7. Handling and storage Precautions for safe handling: Avoid contact with skin and eyes. Avoid inhalation of vapors or mist. Contents under pressure. Conditions for safe storage: Avoid breathing vapors or mist. Keep containers closed. Use only with adequate ventilation. Avoid repeated or prolonged contact with eyes, skin or clothing. Wash thoroughly after handling. Do not store in direct sunlight. Store in cool dry place, away from heat, sparks or flames which may generate toxic decomposition products. Vapors are heavy and may concentrate in low poorly ventilated areas. Page 805 of 1069 Page 805 of 1069 Page 805 of 1069 Page 805 of 1069 ---PAGE BREAK--- Safety Data Sheet Page 3 of 4 8. Exposure controls / personal protection Information on the system design: Product is intended for external use only. Stay up wind, out of any spray developed. Exposure Limits: 1,1-Difluoroethane CAS #75-37-6 PEL (OSHA) None Established TLV (ACGIH) None Established AEL (DuPont) 1000 ppm, 8 Hr. TWA WEEL (AIHA) 1000 ppm, 8 Hr. TWA Personal protective equipment Product is a gas which is heavier than air. Avoid breathing vapors. Protect skin from cold discharge. Engineering Controls Ground all equipment and cylinders before use. Do not use near any spark producing electrical devices such as paper shredders. Respiratory Protection: Use only with adequate ventilation. Keep container closed. Use approved NIOSH self- contained or supplied air respirators for emergencies and in situations where air may be displaced by vapors. Eye Protection: Use chemical protective safety glasses. Hygiene measures Wash hands and face before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. Protective Clothing: Where there is potential for skin contact, use appropriate impervious gloves, apron, pants and jacket. 9. Physical and chemical properties Appearance: Liquefied Gas Odor: Slight Ethereal Odor threshold: no data available pH-value: no data available Melting/ freezing point: no data available Initial boiling point: -25°C (-13°F) Flash point: <-50°C Evaporation rate: no data available Flammability (solid, gas): Flammable Explosion limits: LEL/UEL: 3.9-16.9 by volume) Vapor pressure: 87 psia at 25°C (77°F) Vapor density: 2.4 (Air = 1.0) at 25°C (77°F) Relative density (water=1.00): no data available Auto-ignition temperature: 454°C (849°F) Solubility: 0.28 WT% @ 25°C (77°F) and 87 psia. Decomposition temperature: Not available Partition coefficient: Log Kow = no data available Viscosity: no data available Fire and Explosion Hazards: Aerosol cans may erupt forcefully at temperatures above 120°F (49°C) 10. Stability and reactivity Chemical stability: Stable under recommended storage conditions. Possibility of hazardous reactions: No data. Conditions to avoid: Open flames and high temperatures. Materials to avoid: No data. Hazardous decomposition products: See Section 5 for action by fire. 11. Toxicological information Routes of Entry: Inhalation. Oral ALD: >1500 mg/kg in rats Dermal Toxicity LD 50: No data available for gas. Inhalation ALC, 4 hr: 383,000 ppm in rats Eye Irritation (Rabbit) No data. Dermal Irritation (Rabbit) No data. Chronic Effects on Humans: No data This product does not contain a substance at a concentration exceeding OSHA thresholds that has been listed as a carcinogen or potential carcinogen published by NTP, IARC or OSHA. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard: no data available Page 806 of 1069 Page 806 of 1069 Page 806 of 1069 Page 806 of 1069 ---PAGE BREAK--- Safety Data Sheet Page 4 of 4 12. Ecological information Ecotoxicity: Aquatic Toxicity: no data available Other adverse effects no data available 13. Disposal considerations Offer surplus and non-recyclable solutions to a licensed disposal company. Reclaim by distillation, incinerate, or remove to a permitted waste facility. Dispose in accordance with local, state and federal regulations. This material may be a RCRA Hazardous waste upon disposal due to the ignitability characteristic. 14. Transport information DOT (US) UN number: 1030 Class: 2.1 Proper shipping name: 1,1-DIFLUOROETHANE Reportable Quantity (RQ): None Marine pollutant: No data Poison Inhalation Hazard: No data May also be classed as a Consumer Commodity ORM-D 15. Regulatory information SARA 302: None subject to the reporting requirements of SARA Title III, Section 302. SARA 313: None that exceed the threshold reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Acute : Yes Chronic : No Fire : Yes Reactivity : No Pressure : Yes Right To Know Components: No information California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. This product is a flammable gas as defined by OSHA in 29CFR 1910.1200(c). Use of this product may require compliance with 29CFR 1910.119, Process Safety Management of Highly Hazardous Chemicals. This information must be included in all MSDS that are copied and distributed for this material. California V.O.C. Data: This product contains 0 grams total VOC per liter. 16. Other information SDS Preparation date: November 24, 2014. SDS Code: AC RR 3530 Hazard Categories: Health Fire Pressure Reactivity Reference 49 CFR 171.8, Immediate Yes Yes Yes No OSHA 29 CFR 1910.1200 and Delayed No No XXX XXX SARA 302/311/312/313. HMIS Hazard ratings: Health 1 Fire 4 Instability 0 Other B (Goggles, gloves) Hazard Ratings: Least: 0 Slight: 1 Moderate: 2 High: 3 Extreme: 4 HMIS® is a registered trade and service mark of the NPCA. Note: The information in this SDS was obtained from current reputable and competent sources. However, the data is provided without warranty, expressed or implied, regarding its correctness or accuracy. It is the user's responsibility to determine safe conditions for the use of this product and to assume liability for loss, injury, damage or expense resulting from improper use of this product. WHIMIS - Canada Class A - Compressed Gas Class B-1 - Flammable Gas CEPA DSL: difluoroethane Page 807 of 1069 Page 807 of 1069 Page 807 of 1069 Page 807 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product Name Reagent Alcohol Cat No. : A962-4; A962-200; A962F-1GAL; A962P-4; A962RB-200; A962S-4; A9624-4LC; A995-4; A995RS-19; A995RS-50; A995RS-200; A995SS-28; A9954-LC; A995SS-50; A995SS-115; A995SS-200 Synonyms Denatured Alcohol; Denatured Ethanol (Histological/HPLC) Recommended Use Laboratory chemicals. Uses advised against No Information available Details of the supplier of the safety data sheet 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Danger Hazard Statements Highly flammable liquid and vapor Harmful if swallowed Harmful if inhaled Page 1 / 9 Aspiration Toxicity Category 1 Revision Date 27-Aug-2015 Acute oral toxicity Category 4 Emergency Telephone Number CHEMTRECÒ, Inside the USA: [PHONE REDACTED] CHEMTRECÒ, Outside the USA: 001-[PHONE REDACTED] Acute dermal toxicity Category 4 Revision Number 2 Acute Inhalation Toxicity - Vapors Category 4 Creation Date 24-Feb-2010 Specific target organ toxicity (single exposure) Category 1 Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Target Organs - Central nervous system (CNS), Optic nerve. Specific target organ toxicity - (repeated exposure) Category 1 Target Organs - Kidney, Liver, spleen, Blood. Flammable liquids Category 2 Page 808 of 1069 Page 808 of 1069 Page 808 of 1069 Page 808 of 1069 ---PAGE BREAK--- Harmful in contact with skin May cause drowsiness or dizziness May be harmful if swallowed and enters airways Causes damage to organs Causes damage to organs through prolonged or repeated exposure Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Keep cool Response IF exposed: Call a POISON CENTER or doctor/physician Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do NOT induce vomiting Fire In case of fire: Use CO2, dry chemical, or foam for extinction Storage Store locked up Store in a well-ventilated place. Keep container closed Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified Other hazards Poison, may be fatal or cause blindness if swallowed. Vapor harmful. Cannot be made non-poisonous. WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. 3. Composition / information on ingredients Component CAS-No Weight % Ethyl alcohol 64-17-5 90.0 Methyl alcohol 67-56-1 5.0 Isopropyl alcohol 67-63-0 5.0 Page 2 / 9 Reagent Alcohol Revision Date 27-Aug-2015 Page 809 of 1069 Page 809 of 1069 Page 809 of 1069 Page 809 of 1069 ---PAGE BREAK--- 4. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. Inhalation Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a respiratory medical device. Immediate medical attention is required. Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately. Most important Breathing difficulties. Inhalation of high vapor concentrations may cause like headache, dizziness, tiredness, nausea and vomiting Notes to Physician Treat 5. Fire-fighting measures Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam. Use water spray to cool unopened containers. Unsuitable Extinguishing Media Water may be ineffective Flash Point 12.8 - 14.4 °C / 55 - 57.9 °F Method - No information available Autoignition Temperature 362.8 °C / 685 °F Explosion Limits Upper 19 vol % Lower 3.3 vol % Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Hazardous Combustion Products Carbon monoxide (CO) Carbon dioxide (CO2) Thermal decomposition can lead to release of irritating gases and vapors Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. NFPA 6. Accidental release measures Personal Precautions Remove all sources of ignition. Use personal protective equipment. Take precautionary measures against static discharges. Do not get in eyes, on skin, or on clothing. Environmental Precautions Should not be released into the environment. See Section 12 for additional ecological information. Methods for Containment and Clean Up Remove all sources of ignition. Soak up with inert absorbent material. Take precautionary measures against static discharges. Keep in suitable, closed containers for disposal. Page 3 / 9 Flammability 3 Instability 0 Physical hazards N/A Reagent Alcohol Health 2 Revision Date 27-Aug-2015 Page 810 of 1069 Page 810 of 1069 Page 810 of 1069 Page 810 of 1069 ---PAGE BREAK--- 7. Handling and storage Handling Use only under a chemical fume hood. Wear personal protective equipment. Use explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Do not breathe vapors or spray mist. Do not get in eyes, on skin, or on clothing. Storage Keep containers closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Flammables area. 8. Exposure controls / personal protection Exposure Guidelines Page 4 / 9 OSHA PEL NIOSH IDLH ACGIH - American Conference of Governmental Industrial Hygienists Ethyl alcohol STEL: 1000 ppm OSHA - Occupational Safety and Health Administration (Vacated) TWA: 1000 ppm (Vacated) TWA: 1900 mg/m3 TWA: 1000 ppm TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health Methyl alcohol TWA: 200 ppm STEL: 250 ppm Skin (Vacated) TWA: 200 ppm (Vacated) TWA: 260 mg/m3 (Vacated) STEL: 250 ppm (Vacated) STEL: 325 mg/m3 Skin TWA: 200 ppm TWA: 260 mg/m3 IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 Isopropyl alcohol TWA: 200 ppm STEL: 400 ppm Engineering Measures Use only under a chemical fume hood. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. (Vacated) TWA: 400 ppm (Vacated) TWA: 980 mg/m3 (Vacated) STEL: 500 ppm (Vacated) STEL: 1225 mg/m3 TWA: 400 ppm TWA: 980 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 Reagent Alcohol Personal Protective Equipment Revision Date 27-Aug-2015 Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Component Quebec Mexico OEL (TWA) Ontario TWAEV Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. Ethyl alcohol TWA: 1000 ppm TWA: 1880 mg/m3 TWA: 1000 ppm TWA: 1900 mg/m3 STEL: 1000 ppm Methyl alcohol TWA: 200 ppm TWA: 262 mg/m3 STEL: 250 ppm STEL: 328 mg/m3 Skin TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 310 mg/m3 TWA: 200 ppm STEL: 250 ppm Skin Isopropyl alcohol TWA: 400 ppm TWA: 985 mg/m3 STEL: 500 ppm STEL: 1230 mg/m3 TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TWA: 200 ppm STEL: 400 ppm Component ACGIH TLV Legend Page 811 of 1069 Page 811 of 1069 Page 811 of 1069 Page 811 of 1069 ---PAGE BREAK--- 9. Physical and chemical properties Physical State Liquid Appearance Clear Odor aromatic Odor Threshold No information available pH No information available Melting Point/Range -114.1 °C / -173.4 °F Boiling Point/Range 78.5 °C / 173.3 °F Flash Point 12.8 - 14.4 °C / 55 - 57.9 °F Evaporation Rate No information available Flammability (solid,gas) No information available Flammability or explosive limits Upper 19 vol % Lower 3.3 vol % Vapor Pressure 44 mmHg Vapor Density 1.24 Specific Gravity 0.8 Solubility Soluble in water Partition coefficient; n-octanol/water No data available Autoignition Temperature 362.8 °C / 685 °F Decomposition Temperature No information available Viscosity No information available 10. Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. Conditions to Avoid Incompatible products. Heat, flames and sparks. Incompatible Materials Strong oxidizing agents, Strong acids, Strong bases, Metals, Acid Acid chlorides Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Thermal decomposition can lead to release of irritating gases and vapors Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. 11. Toxicological information Acute Toxicity Oral LD50 Category 4. ATE = 300 - 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Vapor LC50 Category 4. ATE = 10 - 20 mg/l. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Ethyl alcohol LD50 = 7060 mg/kg ( Rat ) Not listed 20000 ppm/10H ( Rat ) Methyl alcohol LD50 = 6200 mg/kg ( Rat ) LD50 = 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L ( Rat ) 4 h Page 5 / 9 Revision Date 27-Aug-2015 Reagent Alcohol Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other are experienced. Page 812 of 1069 Page 812 of 1069 Page 812 of 1069 Page 812 of 1069 ---PAGE BREAK--- Isopropyl alcohol 5840 mg/kg ( Rat ) 13900 mg/kg ( Rat ) 12870 mg/kg ( Rabbit ) 72.6 mg/L ( Rat ) 4 h Toxicologically Synergistic Products No information available Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Irritating to eyes and skin Sensitization No information available Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Ethyl alcohol 64-17-5 Group 1 Known A3 X Not listed Methyl alcohol 67-56-1 Not listed Not listed Not listed Not listed Not listed Isopropyl alcohol 67-63-0 Not listed Not listed Not listed Not listed Not listed IARC: (International Agency for Research on Cancer) IARC: (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2A - Probably Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Mutagenic Effects Mutagenic effects have occurred in humans. Reproductive Effects Adverse reproductive effects have occurred in humans. Developmental Effects Substances known to cause developmental toxicity in humans. Component substance is listed on California Proposition 65 as a developmental hazard. Teratogenicity Teratogenic effects have occurred in humans. STOT - single exposure Central nervous system (CNS) Optic nerve STOT - repeated exposure Kidney Liver spleen Blood Aspiration hazard No information available / effects,both acute and delayed Inhalation of high vapor concentrations may cause like headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor Information No information available Other Adverse Effects See actual entry in RTECS for complete information. 12. Ecological information Ecotoxicity . Component Freshwater Algae Freshwater Fish Microtox Water Flea Ethyl alcohol EC50 (72h) = 275 mg/l (Chlorella vulgaris) Fathead minnow (Pimephales promelas) LC50 = 14200 mg/l/96h Photobacterium phosphoreum:EC50 = 34634 mg/L/30 min Photobacterium phosphoreum:EC50 = 35470 mg/L/5 min EC50 = 9268 mg/L/48h EC50 = 10800 mg/L/24h Methyl alcohol Not listed Pimephales promelas: LC50 > 10000 mg/L 96h EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min EC50 > 10000 mg/L 24h Isopropyl alcohol EC50: > 1000 mg/L, 72h (Desmodesmus subspicatus) EC50: > 1000 mg/L, 96h (Desmodesmus subspicatus) LC50: > 1400000 µg/L, 96h (Lepomis macrochirus) LC50: = 11130 mg/L, 96h static (Pimephales promelas) LC50: = 9640 mg/L, 96h flow-through (Pimephales promelas) = 35390 mg/L EC50 Photobacterium phosphoreum 5 min 13299 mg/L EC50 = 48 h 9714 mg/L EC50 = 24 h Page 6 / 9 Reagent Alcohol Revision Date 27-Aug-2015 Page 813 of 1069 Page 813 of 1069 Page 813 of 1069 Page 813 of 1069 ---PAGE BREAK--- Persistence and Degradability No information available Bioaccumulation/ Accumulation No information available. Mobility . Component log Pow Ethyl alcohol -0.32 Methyl alcohol -0.74 Isopropyl alcohol 0.05 13. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. Component RCRA - U Series Wastes RCRA - P Series Wastes Methyl alcohol - 67-56-1 U154 - 14. Transport information DOT UN-No UN1987 Proper Shipping Name ALCOHOLS, N.O.S. Proper technical name (Ethanol, Methanol, Isopropanol) Hazard Class 3 Packing Group II TDG UN-No UN1987 Proper Shipping Name ALCOHOLS, N.O.S. Hazard Class 3 Packing Group II IATA UN-No UN1987 Proper Shipping Name ALCOHOLS, N.O.S. Hazard Class 3 Packing Group II IMDG/IMO UN-No UN1987 Proper Shipping Name ALCOHOLS, N.O.S. Hazard Class 3 Packing Group II 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Ethyl alcohol X X - 200-578-6 - X X X X X Methyl alcohol X X - 200-659-6 - X X X X X Isopropyl alcohol X X - 200-661-7 - X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Page 7 / 9 Revision Date 27-Aug-2015 Reagent Alcohol Page 814 of 1069 Page 814 of 1069 Page 814 of 1069 Page 814 of 1069 ---PAGE BREAK--- Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) Not applicable SARA 313 Component CAS-No Weight % SARA 313 - Threshold Values % Methyl alcohol 67-56-1 5.0 1.0 Isopropyl alcohol 67-63-0 5.0 1.0 SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act Not applicable Clean Air Act Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors Methyl alcohol X - OSHA Occupational Safety and Health Administration Not applicable CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Component Hazardous Substances RQs CERCLA EHS RQs Methyl alcohol 5000 lb - California Proposition 65 This product contains the following Proposition 65 chemicals: Ethyl alcohol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage Component CAS-No California Prop. 65 Prop 65 NSRL Category Ethyl alcohol 64-17-5 Development (alcoholic beverages only) - Developmental Carcinogen Methyl alcohol 67-56-1 Developmental - Developmental State Right-to-Know Component Massachusetts New Jersey Illinois Rhode Island Ethyl alcohol X X X X X Methyl alcohol X X X X X Isopropyl alcohol X X X - X U.S. Department of Transportation Reportable Quantity (RQ): Y DOT Marine Pollutant N DOT Severe Marine Pollutant N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Page 8 / 9 Reagent Alcohol Revision Date 27-Aug-2015 Page 815 of 1069 Page 815 of 1069 Page 815 of 1069 Page 815 of 1069 ---PAGE BREAK--- Other International Regulations Mexico - Grade Serious risk, Grade 3 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class B2 Flammable liquid D1B Toxic materials D2A Very toxic materials D2B Toxic materials 16. Other information Prepared By Regulatory Affairs Thermo Fisher Scientific Email: [EMAIL REDACTED] Creation Date 24-Feb-2010 Revision Date 27-Aug-2015 Print Date 27-Aug-2015 Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 9 / 9 Reagent Alcohol Revision Date 27-Aug-2015 Page 816 of 1069 Page 816 of 1069 Page 816 of 1069 Page 816 of 1069 ---PAGE BREAK--- Page 817 of 1069 Page 817 of 1069 Page 817 of 1069 Page 817 of 1069 ---PAGE BREAK--- Material Safety Data Sheet U.S. DEPARTMENT OF LABOR May be used to comply with Occupational Safety and Health OSHA=S Hazard Communication Standard (Non-Mandatory Form) 29 CFR 2910.1200. Standard must be Form Approved consulted for specific requirements. OMB No. 1218-0072 Identity (As Used on Label and List) Renown Blue Tint Flush Toilet Bowl Cleaner #REN03015 Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Section I Supplier=s Name AmSan LLC Emergency Telephone Number [PHONE REDACTED] Address (number, Street, City, State, and ZIP Code) Telephone Number for Information [PHONE REDACTED] 5727 South Lewis Ave. Tulsa, OK 74105 Date Prepared 03/01/2007 Signature of Preparer (optional) Section II - HMIS Rating Health 0 Flammability 0 Reactivity 0 Section III - Hazardous Ingredients/Identity Information Hazardous Components [Specific Chemical Identity: Common Name(s)] OSHA PEL ACGIH TLV Other Limits % (optional) Recommende Urea CAS #57-13-6 N/A N/A 50 Surfactants, Water & Fillers N/A N/A 50 Section IV - Physical/Chemical Characteristics Boiling Point N/A Specific Gravity (H2O = 1) >1.0 Vapor Pressure (mm Hg.) N/A Melting Point N/A Vapor Density (AIR = 1) N/A Evaporation Rate N/A Solubility in Water: Complete Appearance and Odor: Blue solid in plastic cup; faint ammonia odor Section V - Fire and Explosion Hazard Data Flash Point (Method Used) N/A Flammable Limits LEL N/A UEL N/A Extinguishing Media Water, Carbon Dioxide, dry chemical Special Fire Fighting Procedures Elevated temperatures may cause release of ammonia; use SCBA or activated charcoal respirator. Unusual Fire and Explosion Hazards None N/A = Not Applicable N/D = Not Determined Page 1 N/E = Not Established OSHA 174, Sept. 1985 Page 818 of 1069 Page 818 of 1069 Page 818 of 1069 Page 818 of 1069 ---PAGE BREAK--- #REN03015 Section VI - Reactivity Data Unstable Conditions to Avoid: High temperatures may cause release of ammonia vapors Stability Stable X Incompatibility (Materials to Avoid): Avoid contact with strong oxidizing agents such as nitric acid. Hazardous Decomposition or Byproducts: Carbon and sulfur oxides, ammonia, and unburned hydrocarbons May Occur Conditions to Avoid: None Hazardous Polymerization Will Not Occur X Section VII - Health Hazard Data Route(s) of Entry: Inhalation? No Skin? Yes Ingestion? Yes Health Hazards (Acute and Chronic): Acute - none known Chronic - prolonged skin contact may cause irritation Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Signs and of Exposure: None known Medical Conditions Generally Aggravated by Exposure: None known Emergency and First Aid Procedures: Eyes - flush with water; seek medical attention. Skin - wash with soap and water. Ingestion - seek immediate medical attention. Section VIII - Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spill: Scoop up material and discard. Wash unrecoverable material down the drain with water. Waste Disposal Method: Dispose of in accordance with local, state and federal regulations. Other precautions: Do not store at temperatures above 130oF. Section IX - Control Measures Respiratory Protection (Specify Type): None required Local Exhaust Adequate Special N/A Ventilation Mechanical (General) Adequate Other N/A Protective Gloves: None required Eye Protection: None required Other Protective Clothing or Equipment: Eye wash/shower facility nearby Work/Hygienic Practices: Good housekeeping practices. Avoid skin/eye contact. N/A = Not Applicable N/D = Not Determined Page 2 N/E = Not Established OSHA 174, Sept. 1985 Page 819 of 1069 Page 819 of 1069 Page 819 of 1069 Page 819 of 1069 ---PAGE BREAK--- RESOLVE High Traffic Area Foam Carpet Cleaner SAFETY DATA SHEET Product name Distributed by 1. Product and company identification : : D8040582_3 : SDS # Formulation : 8125757 RESOLVE® High Traffic Area Foam Carpet Cleaner Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] 2. Hazards identification Classification of the substance or mixture FLAMMABLE AEROSOLS - Category 1 : Signal word : Danger Hazard statements : Extremely flammable aerosol. Hazard pictograms : GHS label elements General Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Response : Not applicable. Storage : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Precautionary statements 1/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 820 of 1069 Page 820 of 1069 Page 820 of 1069 Page 820 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Supplemental label elements : None known. Hazards not otherwise classified : None known. Disposal : Not applicable. 3. Composition/information on ingredients Mixture : Substance/mixture butane 1 - 3 106-97-8 propane 1 - 3 74-98-6 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Potential acute health effects 2/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 821 of 1069 Page 821 of 1069 Page 821 of 1069 Page 821 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide For non-emergency personnel 3/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 822 of 1069 Page 822 of 1069 Page 822 of 1069 Page 822 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling 8. Exposure controls/personal protection Control Occupational exposure limits 4/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 823 of 1069 Page 823 of 1069 Page 823 of 1069 Page 823 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection butane OSHA PEL 1989 (United States, 3/1989). TWA: 800 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. isobutane NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. propane OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. Ingredient name Exposure limits Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection : : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection 5/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 824 of 1069 Page 824 of 1069 Page 824 of 1069 Page 824 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Aerosol.] Not available. Not available. Not available. Not available. Not available. Characteristic. Odor pH White. Opaque. Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Not determined. Not available. 10 to 11 Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Extremely flammable. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Type of aerosol : Foam Aerosol product 10. Stability and reactivity Conditions to avoid Avoid all possible sources of ignition (spark or flame). The product is stable. Chemical stability : : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 6/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 825 of 1069 Page 825 of 1069 Page 825 of 1069 Page 825 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 10. Stability and reactivity Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. No specific data. : Incompatible materials : 11. Toxicological information Acute toxicity Irritation/Corrosion Not available. Information on toxicological effects Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact related to the physical, chemical and toxicological characteristics Inhalation Adverse may include the following: respiratory tract irritation coughing : Eye contact : Adverse may include the following: irritation redness : Not available. Potential acute health effects Not available. 7/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 826 of 1069 Page 826 of 1069 Page 826 of 1069 Page 826 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Not available. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Skin contact Ingestion No specific data. No specific data. : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity ORAL (LD50) Calculated value for the mixture > 2000 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. 12. Ecological information Toxicity Not available. LogPow BCF Potential Bioaccumulative potential Product/ingredient name butane 2.89 - low isobutane 2.8 - low propane 1.09 - low Persistence and degradability Mobility in soil Not available. 8/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 827 of 1069 Page 827 of 1069 Page 827 of 1069 Page 827 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 12. Ecological information Other adverse effects : No known significant effects or critical hazards. Soil/water partition coefficient (KOC) : Not available. 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods 14. Transport information 2.1 - DOT Classification TDG Classification 2.1 AEROSOLS - UN1950 AEROSOLS - IMDG Class AEROSOLS 2.1 - Aerosols, flammable UN1950 IATA-DGR Class 2.1 Regulatory information UN number Proper shipping name Classes PG* Label Additional information - UN1950 - - UN1950 - Mexico Classification UN1950 AEROSOLS 2.1 - - PG* : Packing group 15. Regulatory information U.S. Federal regulations Clean Water Act (CWA) 311: ammonia Clean Air Act (CAA) 112 regulated flammable substances: butane; propane : TSCA 8(a) PAIR: 2-methylundecanal; α-hexylcinnamaldehyde; 2-(4-tert-butylbenzyl) propionaldehyde; dodecanal TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. 9/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 828 of 1069 Page 828 of 1069 Page 828 of 1069 Page 828 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information CAUTION MAY CAUSE EYE IRRITATION. CONTENTS UNDER PRESSURE. Keep out of the reach of children. Do not get in eyes. Avoid contact with eyes, skin and clothing. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 120 Use only with adequate ventilation. Do not swallow. Keep container closed and sealed until ready for use. Wash thoroughly after handling. Signal word : Hazard statements : Precautionary measures : Label elements Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed The following components are listed: BUTANE; PROPANE Massachusetts : New York : None of the components are listed. New Jersey : The following components are listed: BUTANE; PROPANE : The following components are listed: BUTANE; PROPANE State regulations SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Fire hazard No products were found. Composition/information on ingredients 16. Other information Hazardous Material Information System 1 1 0 Health Flammability Physical hazards : Personal protection B 10/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 829 of 1069 Page 829 of 1069 Page 829 of 1069 Page 829 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information 0 1 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Date of previous issue Version : : : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Indicates information that has changed from previously issued version. 29/05/2015. No previous validation. 3 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Prepared by : Reckitt Benckiser Italy Via Sant'Antonio, 5 30034 MIRA, VENICE ITALY ++39 [PHONE REDACTED] Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 11/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 830 of 1069 Page 830 of 1069 Page 830 of 1069 Page 830 of 1069 ---PAGE BREAK--- D8040582_3 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information RB is a member of the CSPA Product Care Product Stewardship Program. 12/12 29/05/2015. Date of issue : SDS # D8040582_2 : Code # D8040582_3 : Page 831 of 1069 Page 831 of 1069 Page 831 of 1069 Page 831 of 1069 ---PAGE BREAK--- [ANSI] Product Name : RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 MSDS Number : 841849 Date Prepared : 04/01/2013 Date Modified : 08/01/2014 Date : 08/22/2014 Material Safety Data Sheet (ANSI form) Section1 : Chemical Product and Company Identification Product Name : RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 (Black toner) General Use : The Image Formation of Printing Machine or Copier MSDS Number : 841849 Company Name : Ricoh Americas Corporation Department : Safety Engineering Center, Quality Assurance Center, Quality Management Division Address : 5 Dedrick Place, West Caldwell, NJ 07006 Telephone Number 1-[PHONE REDACTED] (For emergencies) : 1-[PHONE REDACTED] or 1-[PHONE REDACTED] (For product information) or Telefax Number : 1-[PHONE REDACTED] E-mail : [EMAIL REDACTED] Section2 : Composition, Information on Ingredients Ingredients Chemical Contents ACGIH (TLV) OSHA (PEL) CAS No./Common Name Formula TWA STEL C TWA C Confidential Confidential 60-90 N.A N.A N.A N.A N.A Polyester Resin Confidential Confidential 1-20 10mg/m3 N.A N.A N.A N.A Wax 1333-86-4 C 1-20 N.A N.A N.A Carbon Black 3.0mg/m3 3.5mg/m3 13463-67-7 TiO2 0.1-1 N.A N.A N.A Titan Oxide 10mg/m3 15mg/m3 7631-86-9 O2Si ＜10 N.A N.A N.A Silica 10mg/m3 15mg/m3 This product does not contain any of the following substances as ingredients. Cadmium, Hexavalent Chromium, Mercury, Lead, Polybrominated biphenyls (PBB), Polybrominated diphenyl ethers (PBDE), SVHC (substances of very high concern: published by ECHA). And if it contains any impurities, it does not exceed any of the thresholds of RoHS. Hazardous Ingredients Information Chemical Name : Carbon Black CAS Number : 1333-86-4 EEC Number : 215-609-9 OSHA Z-Tables (USA) : 3.5mg/m3 ACGIH-TLV : 3.0mg/m3 NTP (USA) : Not listed IARC Monographs : Group 2B Symbol (EU) : Not listed R-Phrase (EU) : Not listed DFG-MAK (GER) : III 3B OELs-TWA (Australia) : 3.0mg/m3 California Proposition 65 (USA) : Listed Chemical Name : Titan Oxide CAS Number : 13463-67-7 EEC Number : 236-675-5 OSHA Z-Tables (USA) : 15mg/m3 ACGIH-TLV : 10mg/m3 NTP (USA) : Not listed IARC Monographs : Group 2B Symbol (EU) : Not listed R-Phrase (EU) : Not listed DFG-MAK (GER) : Not listed OELs-TWA (Australia) : 10mg/m3 California Proposition 65 (USA) : Not listed Page 832 of 1069 Page 832 of 1069 Page 832 of 1069 Page 832 of 1069 ---PAGE BREAK--- [ANSI] Product Name : RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 MSDS Number : 841849 Date Prepared : Date Modified : 08/01/2014 Date : 08/22/2014 Section3 : Hazards Identification Emergency Overview HMIS Health : 1 Flammabilit y : 1 Reactivity : 0 PPE:See section 8 NFPA Health : 1 Flammabilit y : 1 Reactivity : 0 The Most Important Hazards Adverse Human Health Effects : There are no significant hazards expected with intended use. Potential Health Effects Primary Entry Routes : Inhalation ; Yes Skin ; Yes Ingestion ; Yes Environmental Effects : There are no significant hazards expected with intended use. Physical and Chemical Hazards : There are no significant hazards expected with intended use. Specific Hazards : Dust explosion (like most finely grained organic powders) Main : Acute Inhalation Toxicity Exposure to excessive amount of dust may cause physical irritation to respiratory tract. Acute Oral Toxicity Low acute toxicity in animal experiment. Acute Eye Irritation May cause slight transient irritation. Acute Skin Irritation May be non-irritant. Sensitization From test no apparent significant hazards are expected . (Only few cases reported on incidental allergy-related conjunctivitis or dermatitis.) Chronic Effect Slight pulmonary fibrosis has been reported in rats upon chronic inhalation exposure to a toner at 4mg/m3 every day for 2 years. No pulmonary change was found at 1mg/m3. These findings show that exposure to excessive amounts of powder may cause damage to lungs. However, normal use and handling of this product as intended, does not result in inhalation of excessive amounts of powder. Carcinogenicity Carbon black and titanium dioxide contained in this product are classified to Group 2B of IARC as the result of inhalation test in use of rat. But oral/skin test does not show carcinogenicity. The toner containing carbon black did not show carcinogenicity in chronic inhalation exposure test in use of rat. In the animal experiment with very high concentration of titanium dioxide (excessive burden of rat’s lungs clearance mechanism (overload phenomenon)), the rat alone showed lung tumor. Under a normal use practice, the concentration should be far lower than the above; and it is assumed that there is no such use. Also, relation between respiratory disease and work exposure of titanium dioxide is not observed with epidemiological survey. Medical Conditions Aggravated by Exposure Not applicable Classification of the Chemical Product This mixture is not classified as dangerous. Page 833 of 1069 Page 833 of 1069 Page 833 of 1069 Page 833 of 1069 ---PAGE BREAK--- [ANSI] Product Name : RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 MSDS Number : 841849 Date Prepared : 04/01/2013 Date Modified : 08/01/2014 Date : 08/22/2014 Section4 : First Aid Measures Inhalation : Remove from exposure to fresh air and rinse mouth with water. Seek medical advice. Skin Contact : Wash thoroughly with soapy water. Eye Contact : Flush with a large amount of water until particle is removed. Seek medical advice. Ingestion : Drink several glasses of water to dilute ingested toner. Seek medical advice. Immediate Medical Attention : Immediate medical attention is not required. Section5 : Fire Fighting Measures Flash Point (degrees centigrade) : Not applicable Burning Rate (mm/sec) : 0.223 or below Autoignition Temperature (degrees centigrade) : Not available Flammable Limits（%） : LEL Not available UEL Not available Extinguishing Media to Avoid : Not applicable Specific Hazards : Can form explosive dust-air mixtures when finely dispersed in air. Fire-Fighting Instructions / Specific Method : No special fire protecting method is required. Sprinkling or fire extinguishers can be used. Protection of Firefighters : Wear gloves, glasses, a mask if necessary. Section6 : Accidental Release Measures Personal Precautions : Do not breathe in dust. Environment Precautions : Do not flush into sewers or watercourses. Methods for Cleaning Up : Fine powder may form explosive dust-air mixture. Confirm there is no source of fire and if there is a source, remove it. Sweep up spilled powder slowly and clean remainder with wet cloth. If a vacuum cleaner is used, a dust explosion-proof type must be chosen. Section7 : Handling and Storage Handling : Technical Measures/Precautions Not applicable Safe Handling Advice Do not handle in areas where there is wind or draught, this may cause dust to get into eyes. Avoid breathing in dust. Storage : Technical Measures Not applicable Storage Conditions Keep out of reach of children. Store in dry, well-ventilated area, to maintain quality the temperature should not exceed 35 for a ℃ long time. Avoid direct sunlight. Packaging material Not applicable Specific Use(s) : Image formation in printing machines or copiers. Page 834 of 1069 Page 834 of 1069 Page 834 of 1069 Page 834 of 1069 ---PAGE BREAK--- [ANSI] Product Name : RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 MSDS Number : 841849 Date Prepared : 04/01/2013 Date Modified : 08/01/2014 Date : 08/22/2014 Section8 : Exposure Controls/Personal Protection Technical measures : Use adequate ventilation. None required with intended use. Control Parameters Exposure Limit Value ( I ) USA OSHA PEL (TWA) : 15mg/m3 (Total dust) 5.0mg/m3 (Respirable fraction) ACGIH TLV (TWA) : 10mg/m3 (Inhalable fraction) 3.0mg/m3 (Respirable fraction) DFG MAK : 4.0mg/m3 (Total dust) 1.5mg/m3 (Respirable fraction) Personal Protection Respiratory Protections (Specify Type) None required in normal use. If the limit of exposure concentration is exceeded, use authorised respirator. Eye Protection Put on goggles if necessary. Protective Gloves Use vinyl or rubber gloves if necessary. Protective Clothing or Equipment Wear chemical-resistant apron or other impervious clothing if necessary. Hygiene Measures Wash hands after handling Section9 : Physical and Chemical Properties Appearance Physical state : Solid Form : Powder Colour : Black Odor : plastic odor pH : Not applicable Boiling Point (degrees centigrade) : Not applicable Vapor Pressure (Pa) : Not applicable Vapor Density (AIR=1) : Not applicable Density : Approx.1.2 Measuring Temp (degrees centigrade) : 25 Formula Weight : Not applicable Melting Point (degrees centigrade) : (Softening point) Approx.90 Decomposition temperature (degrees centigrade) : Not available Viscosity (Pa･s) : Not applicable Volatile : 0.2 or below Evaporation Rate (Butyl Acetate = 1) : Not applicable Water Solubility (g/L) : Insoluble Chloroform Solubility (g/L) : soluble Section10 : Stability and Reactivity Stability : Stable Hazardous Reaction : Dust explosion, like most finely grained organic powders. Condition to Avoid : Not applicable in normal use. Materials to Avoid : Not applicable in normal use condition. Hazardous Polymerization : None Hazardous Decomposition or Byproducts : Decomposition products will not occur. Page 835 of 1069 Page 835 of 1069 Page 835 of 1069 Page 835 of 1069 ---PAGE BREAK--- [ANSI] Product Name : RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 MSDS Number : 841849 Date Prepared : 04/01/2013 Date Modified : 08/01/2014 Date : 08/22/2014 Section11 : Toxicological Information Acute Toxicity Acute Oral Toxicity (LD50) : 5000 or over [mg/kg] (Rat) Acute Dermal Toxicity : Not available Acute Inhalation Toxicity : Not applicable (Based on other Ricoh products test results of similar ingredients.) Local effects Acute Skin Irritation(PII) : 1.0 or below (Rabbit) (Based on other Ricoh products test results of similar ingredients.) Acute Eye Irritation : Non-irritant (Rabbit) (Based on other Ricoh products test results of similar ingredients.) Sensitization Acute Allergenic Effects : Non-skinsensitive (Mouse) (Based on other Ricoh products test results of similar ingredients.) Specific Effects Carcinogenicity : Carbon black and titanium dioxide contained in this product are classified to Group 2B of IARC as the result of inhalation test in use of rat. But oral/skin test does not show carcinogenicity. The toner containing carbon black did not show carcinogenicity in chronic inhalation exposure test in use of rat. In the animal experiment with very high concentration of titanium dioxide (excessive burden of rat’s lungs clearance mechanism (overload phenomenon)), the rat alone showed lung tumor. Under a normal use practice, the concentration should be far lower than the above; and it is assumed that there is no such use. Also, relation between respiratory disease and work exposure of titanium dioxide is not observed with epidemiological survey. Mutagenicity : Negative (Ames test) Reproduction Toxicity : Does not contain substances listed as hazardous to reproductive health. Teratogenic : Not available. Section12 : Ecological Information Mobility : No data are available on the adverse effect one environment. Persistence/Degradabilit y : Not available Bioaccumulation : Not available Ecotoxicity Acute Toxicity for Fish (LC50) : Not classified as toxic (EU Directive 1999/45/EC)mg/l/96hr Acute Toxicity for Daphnia (EC50) : Not classified as toxic (EU Directive 1999/45/EC)mg/l/48hr Algae Inhibition Test (IC50) : Not classified as toxic (EU Directive 1999/45/EC)mg/l/72hr Page 836 of 1069 Page 836 of 1069 Page 836 of 1069 Page 836 of 1069 ---PAGE BREAK--- [ANSI] Product Name : RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 MSDS Number : 841849 Date Prepared : 04/01/2013 Date Modified : 08/01/2014 Date : 08/22/2014 Section13 : Disposal Consideration General information: Dispose of waste and residues in accordance with local authority requirements Disposal methods: Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Confirm disposal procedures with local regulations. Precautions Do not throw the toner cartridge or toner into an open flame. The hot toner may scatter and cause burns or other damage. Section14 : Transport Information International Regulations Land Transport RID/ADR : Not applicable DOT 49 CFR : Not applicable ADNR : Not applicable Sea Transport IMDG Code : Not applicable Air Transport ICAO-TI/IATA-DGR : Not applicable UN Number : Not applicable Class : Not applicable Specific Precautionary Transport Measures and Conditions Avoid direct sunlight in quality. Section15 : Regulatory Information Regulations US Information Information on the label : Not required TSCA (Toxic Substances Control Act) : This product complies with all applicable rules and regulations under TSCA. SARA (Superfund Amendments and Reauthorization Act) Title III 313 Reportable Ingredients : Not regulated California Proposition 65 : Not regulated Canada Information WHMIS Controlled product : Not a controlled product EU Information Information on the label (1999/45/EC and 67/548/EEC) Symbol & Indication : Not required R-Phrase : Not required S-Phrase : Not required Special Precautions under 1999/45/EC Annex V : Not required 76/769/EEC This product complies with applicable rules and regulations under 76/769/EEC Page 837 of 1069 Page 837 of 1069 Page 837 of 1069 Page 837 of 1069 ---PAGE BREAK--- [ANSI] Product Name : RICOH/SAVIN/LANIER Print Cartridge Black MP C6003 MSDS Number : 841849 Date Prepared : 04/01/2013 Date Modified : 08/01/2014 Date : 08/22/2014 Section16 : Other Information Explanation of Hazardous Materials Identification System [HMIS]& National Fire Protection Association [NFPA] Hazard Rating Systems: Both the HMIS and NFPA systems use number from to to show the degree of hazard in an uncontrolled situation: 0=Minimum Hazard 1=Slight Hazard 2=Moderate Hazard 3=Serious Hazard 4=Severe Hazard Colors may also be used in both systems: Blue=Health Hazard Red=Fire Hazard Yellow=Reactivity Hazard White=Indicate a special hazard HMIS will specify any Personal Protective Equipment reqired [PPE], NFPA will specify OX(oxidizer), Acid(acid), ALK(Alkali), COR(Corrosive), W(use no water), xx(Radioactive). Literature References : ANSI Z400.1-1993 ISO 11014-1 Commission Directive 91/155/EEC IARC (1996) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol.65, Printing Process and Printing Inks, Carbon Black and Some Nitro Compounds", Lyon, pp149-261 H.Muhle, B.Bellman, O.Creutzenberg, C.Dasenbrock, H.Emst, R.Kilpper, J.C.MacKenzie, P.Morrow, U.Mohr, S.Takenaka and R.Mermelstein(1991) "Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats" Fundamental and Applied Toxicology 17,pp280-299 IARC (2008) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol.93" NIOSH CURRENT INTELLIGENCE BULLETIN "Evaluation of Health Hazard and Recommendation for Occupational Exposure to Titanium Dioxide DRAFT" ACGIH-TLV : Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices OSHA Z-Tables : US Department of Labor, 29CFR Part 1910 , Tables Z-1, Z-2, and Z-3 NTP (USA) : US Department of Health and Human Services National Toxicology Program Annual Report on Carcinogens DFG-MAK（GER）: DFG List of MAK and BAT Value Symbol (EC) : EU Directive 67/548/EEC 91/155/ EEC : EU Directive 91/155/ EEC 1999/45/EC Annex V : EU Directive 1999/45/EC 76/769/EEC : EU Directive 76/769/EEC EC 304/2003 : Regulation (EC) No 304/2003 of the European Parliament and of the Council of 28 January 2003 concerning the export and import of dangerous chemicals WHMIS Controlled product : Canada Workplace Hazardous Information System OELs-TWA (Australia) : Guidance Note on the Interpretation of Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC: 3008 (1995)] Abbreviations : OSHA PEL PEL (Permissible Exposure Limit) under Occupational Safety and Health Act ACGIH-TLV TLV (Threshold Limit Values) under American Conference of Governmental Industrial Hygienists REACH EC)No.1907/2006:Council Regulation concerning the Registration, Evaluation, Authorization and Restriction of Chemicals SVHC Substances of Very High Concern ECHA The European Chemicals Agency DFG-MAK MAK (Maximale Arbeitsplatz Konzentrationen) by Deutsche Forschungs Gemeinschaft RoHS Restriction of the use of certain Hazardous Substances in Electrical and Electronic Equipment TWA Time Weighted Average IARC International Agency for Research on Cancer NTP National Toxicology Program WHMIS Workplace Hazardous Information System NOHSC National Occupational Health and Safety Commission Act 1985 Disclaimer(S) : This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Ricoh Americas Corporation. It relates only to the specific material designated herein, and does not relate to use in combination with any other material or process. Ricoh Americas Corporation assumes no legal responsibility for use or reliance upon this information. Page 838 of 1069 Page 838 of 1069 Page 838 of 1069 Page 838 of 1069 ---PAGE BREAK--- MSDS PREPARED BY: Safetec of America, Inc., 887 Kensington Ave., Buffalo, NY 14215 (716) 895‐1822 Form Revised 1/2006 May be used to comply with OSHA's Hazard Communica 212.0 °F 100.0 Tag Closed Cup (Liquid) Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Flammability limit - upper Not available. Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Wipe is not soluble Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. 10. Stability and Reactivity Reactivity May react with incompatible materials. Possibility of hazardous reactions Hazardous polymerization does not occur. Chemical stability Stable under recommended storage conditions. Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals. Contact with incompatible materials. Incompatible materials Acids. Oxidizers. Caustics. Hazardous decomposition products May include and are not limited to: Oxides of carbon. Chloride compounds Ammonia. 11. Toxicological Information Information on likely routes of exposure Ingestion Not applicable under normal conditions of use. Inhalation Health injuries are not known or expected under normal use. Skin contact Prolonged skin contact may cause skin irritation. Eye contact Health injuries are not known or expected under normal use. related to the physical, chemical and toxicological characteristics may include stinging, tearing, redness, swelling of the eyes, and blurred vision. may include redness, drying, defatting and cracking of the skin. may include stomach distress, nausea or vomiting. Information on toxicological effects Acute toxicity Page 843 of 1069 Page 843 of 1069 Page 843 of 1069 Page 843 of 1069 ---PAGE BREAK--- #19617 Page: 4 of 6 Issue date 11-February-2015 Components Species ammonium chlorides (CAS 68391-01-5) Acute Dermal LD50 Rat Inhalation LC50 Not available Oral LD50 Mouse Test Results 2000 mg/kg 1420 mg/kg 150 mg/kg Rat 240 mg/kg Quaternary ammonium compounds, chlorides (CAS 85409-23-0) Acute Dermal LD50 Not available Inhalation LC50 Not available Oral LD50 Rat 300 - 2000 mg/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Exposure minutes Not available. Erythema value Not available. Oedema value Not available. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Corneal opacity value Not available. Iris lesion value Not available. Conjunctival reddening value Not available. Conjunctival oedema value Not available. Recover days Not available. Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity Non-hazardous by OSHA criteria. Carcinogenicity Non-hazardous by OSHA criteria. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Non-hazardous by OSHA criteria. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Not classified. Not classified. Aspiration hazard Not classified. Chronic effects Non-hazardous by OSHA criteria. Further information This product has no known adverse effect on human health. 12. Ecological Information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. See below Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Mobility in soil No data available. Mobility in general Not available. Page 844 of 1069 Page 844 of 1069 Page 844 of 1069 Page 844 of 1069 ---PAGE BREAK--- #19617 Page: 5 of 6 Issue date 11-February-2015 Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal Considerations Disposal instructions Dispose of used towelette in trash. Do not flush in toilet. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code This product is not a hazardous waste. Waste from residues / unused products Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty packaging may be disposed in trash. 14. Transport Information U.S. Department of Transportation (DOT) Not regulated as dangerous goods. 15. Regulatory Information US federal regulations This product is NOT known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. PRECAUTIONARY STATEMENTS: Hazard to humans and domestic animals. CAUTION: Causes moderate eye irritation. Harmful if absorbed through skin. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or tobacco. Remove contaminated clothing and wash before reuse. EPA Reg. # 61178-4-9480 EPA Est. # 9480-NY-1. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely No hazardous substance SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Food and Drug Administration (FDA) Not regulated. Not regulated. US state regulations This product is not subject to warning labeling under the California Proposition 65 regulation. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. Page 845 of 1069 Page 845 of 1069 Page 845 of 1069 Page 845 of 1069 ---PAGE BREAK--- #19617 Page: 6 of 6 Issue date 11-February-2015 US - Texas Effects Screening Levels: Listed substance ammonium chlorides (CAS 68391-01-5) US. Massachusetts RTK - Substance List Not regulated. US. RTK - Hazardous Substances Not regulated. US. Rhode Island RTK Not regulated. Listed. Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) 16. Other Information Yes LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 HEALTH / 1 0 FLAMMABILITY 0 1 0 PHYSICAL HAZARD 0 PERSONAL X PROTECTION Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date 11-February-2015 Further information For any questions surrounding this SDS, please contact the supplier/manufacturer listed on the first page of the document. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Not for use on skin. Not a baby wipe. For use on hard surfaces only. Revision 0. Bulk Liquid # 4BQ08401. Other information This Safety Data Sheet was prepared to comply with the current OSHA Hazard Communication Standard (HCS) adoption of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Prepared by Dell Tech Laboratories, Ltd. Phone: (519) 858-5021 Page 846 of 1069 Page 846 of 1069 Page 846 of 1069 Page 846 of 1069 ---PAGE BREAK--- Hazardous Material Identification System – (HMIS) HEALTH – 2 REACTIVITY – 0 Schultz Company P. O. Box 4406 Bridgeton, MO 63044-0406 Material Safety Data Sheet Complies with OSHA’s Hazard Communication Standard, 29 CFR 1910.1200 FLAMMABILITY – 0 PERSONAL – I Trade Name: Houseplant & Garden Insect Spray Product Type: Liquid Ready-to-Use Insecticide Product Item Number: 1042 Formula Code Number: 21-0522 EPA Registration Number Manufacturer Emergency Telephone Numbers 478-125-39609 Chemsico Division of United Industries Corporation 8494 Chapin Industrial Drive St. Louis, MO 63114 For Chemical Emergency: For Information: Prepared by: Date Prepared: 1-[PHONE REDACTED] 1-[PHONE REDACTED] C.A. Duckworth MARCH 5, 2008 II Hazards Ingredient/Identity Information III Physical and Chemical Characteristics Chemical % OSHA PEL ACGIH TLV Appearance & Odor: Clear liquid, mild odor Pyrethrins 0.02 NA 5 mg/m3 Boiling Point: 215F CAS #8003-34-7 Melting Point: NA Piperonyl Butoxide CAS #51-03-6 0.20 NA NA Vapor Pressure: NA Specific Gravity: 1.0 (H20=1) Vapor Density: greater than 1 (Air=1) % Volatile (by vol.): greater than 95% Solubility in Water: 100% Evaporation Rate: Less than 1 (Butyl Acetate=1) PH: 7.0 IV Fire and Explosive Hazards Data V Reactivity Data Flash Point: >200 F (TCC) Stability: Stable Flame Extension: NA Polymerization: Will not occur Flammable Limits: NA Conditions to Avoid: None Autoignition Temperature: NA Incompatible Materials: N/A Fire Extinguishing Media: Water fog, Carbon dioxide, Dry chemical Hazardous Decomposition Decomposition Temperature: NA or Byproducts: N/A Special Fire-Fighting Procedures: Use procedures for elimination of original source of fire. Unusual Fire & Explosion Hazards: Vapors are heavier than air. VI Health Hazard Data VII Precautions for Safe Handling and Use Ingestion (Swallowing): Harmful if swallowed. First Aid: Call a physician or Poison Control Center immediately. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so. Never give anything by mouth to an unconscious person. Skin Contact: Harmful if absorbed through skin. First Aid: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call for treatment advice. Eye Contact: Avoid contact with eyes. First Aid: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses after the first 5 minutes then continue rinsing eye. Call for treatment advice. Inhalation Toxicity: Avoid breathing vapors and spray mist. First Aid: Move person to fresh air. If person is not breathing call 911 or an ambulance, then give artificial respiration, preferably mouth-to- mouth. Call for further advice. Special Notes: Have product container with you when calling. Health conditions Aggravated by Exposure: Skin disorders Ingredients listed by NTP, OSHA, or IARC as Carcinogens or Potential Carcinogens: None Steps to be Taken in Case Material is Released or Spilled: Avoid breathing vapors. Avoid skin contact with liquid. Soak up with absorbent material. Waste Disposal: If empty: Do not reuse this container. Place in trash or offer for recycling if available. If partially filled: Call your local solid waste agency or 1-800-CLEANUP for disposal instructions. Never pour unused product down any indoor or outdoor drain. Handling & Storage Precautions: Do not contaminate water, food or feed by storage or disposal. Store in original container VIII Control Measures IX Transportation Data Read and follow label directions. They are your best guide to using this product effectively, and give necessary safety precautions to protect your health. DOT Shipping Name: Not Regulated by DOT DOT Hazard Class: None The information and statements herein are believed to be reliable but are not to be construed as warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Page 847 of 1069 Page 847 of 1069 Page 847 of 1069 Page 847 of 1069 ---PAGE BREAK--- Page 848 of 1069 Page 848 of 1069 Page 848 of 1069 Page 848 of 1069 ---PAGE BREAK--- Page 849 of 1069 Page 849 of 1069 Page 849 of 1069 Page 849 of 1069 ---PAGE BREAK--- Page 850 of 1069 Page 850 of 1069 Page 850 of 1069 Page 850 of 1069 ---PAGE BREAK--- Page 851 of 1069 Page 851 of 1069 Page 851 of 1069 Page 851 of 1069 ---PAGE BREAK--- There was a PDF conversion failure for Uploaded SDS - Product Name: SHARP TONER YELLOW CAS Number: Manufacturer: SHARP SDS Date: To complete your binder, please upload a different SDS for this product or remove the SDS from your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 852 of 1069 Page 852 of 1069 Page 852 of 1069 Page 852 of 1069 ---PAGE BREAK--- Material Safety Data Sheet: SHINE M UP AEROSOLSAMPLE, CAN CL Supercedes Date 02/23/2006 Issuing Date 11/18/2009 1. PRODUCT AND COMPANY IDENTIFICATION Product Name SHINE M UP AEROSOLSAMPLE, CAN CL Product Code 5056 Recommended Use Cleaning agent Chemical Nature Aerosol Information on Manufacturer Emergency Telephone Number CERTIFIED LABS, DIV. OF NCH CORP. CHEMTREC ® [PHONE REDACTED] BOX 152170 IRVING, TEXAS 75015 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION May be harmful if inhaled May cause skin irritation May cause eye irritation May be harmful if swallowed Contents under pressure Color Off-white Physical State Liquid Odor Ammoniacal Potential Health Effects Principle Route of Exposure Skin contact, Eye contact, Inhalation. Primary Routes of Entry Inhalation Acute Effects Eyes May cause eye irritation. Skin May cause skin irritation. Inhalation May cause irritation of respiratory tract. Inhalation may cause central nervous system effects. and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Chronic Toxicity Occupational health effects due to inhalation of mineral dusts incorporating silica (quartz, cristobalite, tridymite), silicates (kaolin, talc) graphite or coal, Kidney injury may occur, May cause cancer after repeated inhalation of spray or dust. Target Organ Effects Eyes, Skin, Respiratory system, Central nervous system, Heart, Liver, Kidney, Lungs. Aggravated Medical Conditions Respiratory disorders, Skin disorders, Liver disorders, Kidney disorders, Heart disease. Potential Environmental Effects See Section 12 for additional Ecological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No Silica (Quartz) 14808-60-7 Propane 74-98-6 Butane 106-97-8 Ammonium tallate 68132-50-3 4. FIRST AID MEASURES General Advice Avoid contact with skin, eyes, and clothing. Avoid breathing vapors, mist, or gas. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists. Skin Contact Wipe up with absorbent material (e.g. cloth, fleece). Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use. Inhalation If inhaled, remove to fresh air. Get medical attention if occur. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if occur. Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Flash Point >212°F/>100°C Method Seta closed cup Autoignition Temperature No information available. Flammability Limits in Air % Propellant. Upper 1.8 Lower 9.5 Suitable Extinguishing Media Foam. Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific Hazards Arising from the Chemical Solvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Material can create slippery conditions. Flame extension: 0 inches / 0 cm and Burnback: 0 inches / 0 cm. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Aerosol Level (NFPA 30B) - 1 NFPA Health 2 Flammability 1 Instability 0 HMIS Health 2 Flammability 1 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes, and clothing. Remove all sources of ignition. Environmental Precautions Prevent further leakage or spillage if safe to do so. Page 1 / 4 Page 853 of 1069 Page 853 of 1069 Page 853 of 1069 Page 853 of 1069 ---PAGE BREAK--- Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Pick up and transfer to properly labeled containers. Neutralizing Agent Not applicable. 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes, and clothing. Avoid breathing dust/fume/gas/mist/vapours/spray. Contents under pressure. Do not puncture. Storage Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Storage Temperature Minimum 35°F/2°C Maximum 120°F/49°C Storage Conditions Indoor X Outdoor Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH Silica (Quartz) TWA: 0.025 mg/m3 No data available IDLH: 50 mg/m3 TWA: 0.05 mg/m3 Propane TWA: 1000 ppm TWA: 1800 mg/m3 TWA: 1000 ppm IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Butane TWA: 1000 ppm No data available TWA: 1900 mg/m3 TWA: 800 ppm Ammonium tallate No data available No data available No data available Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection For prolonged or repeated contact, use protective gloves Respiratory Protection In case of inadequate ventilation wear respiratory protection. General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity Viscous Color Off-white Odor Ammoniacal Appearance Opaque pH @10% -10 Specific Gravity 1.180 Evaporation Rate 12.3 (Butyl acetate=1) Percent Volatile (Volume) 76.4 VOC Content 6.5 VOC Photoreactive (Y/N) Yes Vapor Pressure 136.9 mmHg @ 70 °F Vapor Density 1.3 (Air = 1.0) Solubility Completely soluble Boiling Point/Range 212°F/100°C 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Hazardous polymerization does not occur. Conditions to Avoid Heat, flames, and sparks. Incompatible Products Oxidizing agents, Acids, Highly halogenated compounds, Fluorinated hydrocarbons. Hazardous Decomposition Products Carbon oxides, Nitrogen oxides (NOx). Possibility of Hazardous Reactions Dangerous fumes form when mixed with other products. Chlorine. 11. TOXICOLOGICAL INFORMATION Product Information No information available. Component Information Acute toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other Silica (Quartz) 500 mg/kg ( Rat ) no data available no data available no data available no data available Propane no data available no data available 658 mg/L ( Rat ) 4 h no data available no data available Butane no data available no data available 658 mg/L ( Rat ) 4 h no data available no data available Ammonium tallate no data available no data available no data available no data available no data available Chronic Toxicity Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects Silica (Quartz) no data available no data available no data available no data available eyes, respiratory system (in animals: lung cancer) Propane no data available no data available no data available no data available CNS Butane no data available no data available no data available no data available CNS Ammonium tallate no data available no data available no data available no data available no data available Carcinogenicity Component ACGIH IARC NTP OSHA Other Silica (Quartz) A2 Group 1 Known X not applicable Propane not applicable not applicable not applicable not applicable not applicable Butane not applicable not applicable not applicable not applicable not applicable Ammonium tallate not applicable not applicable not applicable not applicable not applicable 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Page 2 / 4 Page 854 of 1069 Page 854 of 1069 Page 854 of 1069 Page 854 of 1069 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Product Information No information available. Component Information Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow Silica (Quartz) no data available no data available no data available no data available N/A Propane no data available no data available no data available no data available 2.3 Butane no data available no data available no data available no data available 2.89 Ammonium tallate no data available no data available no data available no data available N/A Persistence and Degradability No information available. Bioaccumulation No information available. Mobility No information available. 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations. Container Disposal Contents under pressure. Do not puncture. Empty remaining contents. Empty containers should be taken for local recycling, recovery or waste disposal. 14. TRANSPORT INFORMATION DOT DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity ,ORM-D TDG Proper shipping name Aerosols Hazard Class 2.1 UN-No UN1950 Description AEROSOLS,2.1,UN1950, LTD QTY ICAO UN-No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 Shipping Description Aerosols,UN1950, LTD QTY IATA UN-No UN1950 Proper Shipping Name Aerosols, flammable Hazard Class 2.1 ERG Code 10L Shipping Description UN1950,Aerosols, flammable,2.1, LTD QTY IMDG/IMO Proper Shipping Name Aerosols Hazard Class 2 UN-No UN1950 EmS No. F-D, S-U Shipping Description UN1950, Aerosols,2, LTD QTY 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard Yes Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs Silica (Quartz) Not applicable Not applicable Propane Not applicable Not applicable 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Page 3 / 4 Page 855 of 1069 Page 855 of 1069 Page 855 of 1069 Page 855 of 1069 ---PAGE BREAK--- Butane Not applicable Not applicable Ammonium tallate Not applicable Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class A Compressed gases, D2A Very toxic materials. 16. OTHER INFORMATION Prepared By Dan Hollas Supercedes Date 02/23/2006 Issuing Date 11/18/2009 Reason for Revision No information available. Glossary No information available. List of References. No information available. CERTIFIED LABS, DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL 5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Issuing Date 18-Nov-2009 Page 4 / 4 Page 856 of 1069 Page 856 of 1069 Page 856 of 1069 Page 856 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 08-Jul-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19902 Product name Silicone Lubricant Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Skin absorption. Potential health effects Eyes Contact with eyes may cause irritation. Skin May cause the following effects: . Skin Irritation. Dermatitis. Repeated or prolonged exposure may cause:. Redness. Frostbite. Possible burns to tissue. May be absorbed through the skin in harmful amounts. Inhalation May cause the following effects. Shortness of breath. Dizziness. Light headedness. Extreme overexposure may cause. Liver damage. Kidney damage. Possible Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. Gastrointestinal irritation. Aspiration hazard. May cause severe lung damage if aspirated into the lungs from ingestion or vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Petroleum distillates, hydrotreated light 64742-47-8 39-44 Propane 74-98-6 22-27 Butane 106-97-8 17-22 Hexane 110-54-3 15-20 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 20 minutes. Seek medical attention. Skin contact Wash area thoroughly with soap and water. Ingestion If a large quantity of liquid is swallowed, do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Seek medical attention. Inhalation Remove to fresh air. Provide oxygen if breathing is difficult. If not breathing, give artificial respiration. Keep warm and quiet. Seek medical attention. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5% Lower 1.2% Suitable extinguishing media Water fog. Carbon dioxide (CO2). Dry chemical powder. Foam. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Flammable. Irritant. Page 857 of 1069 Page 857 of 1069 Page 857 of 1069 Page 857 of 1069 ---PAGE BREAK--- Fire and Explosion Hazards Flammable . Evacuate area of unprotected and unnecessary personnel. Material is highly volatile and readily gives off vapors. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Shut off source of leak if safe to do so. Evacuate area of unprotected and unnecessary personnel. Ventilate area to maintain exposure below permissible exposure limits. Dike or dam large spills. Soak up excess with absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. 7. HANDLING AND STORAGE Handling Keep container closed when not in use. Storage Keep container closed. Keep away from direct sunlight. Keep away from open flames, hot surfaces and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Containers exposed to extreme heat may burst. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Petroleum distillates, hydrotreated light - - - - Hexane 500 ppm 1800 mg/m3 - 50 ppm N/D Butane 800 ppm - - 1000 ppm Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. If current ventilation practices are not adequate in maintaining airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Use with adequate explosion-proof ventilation to meet the limits in Section 8 . Hygiene measures Remove and wash contaminated clothing before re-use. Other precautions Use personal protective equipment. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand Protection Gloves are recommended to prevent prolonged or repeated contact. Protective gloves. Eye protection Safety glasses with side-shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Clear Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity No data available Vapor pressure No data available Vapor density No data available Evaporation Rate <1 (ether = 1) Water solubility No data available VOC Content 58% by weight Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Heat, flames and sparks. Incompatability Strong oxidizing agents. Page 2 / 4 Product code 19902 Product name Silicone Lubricant Page 858 of 1069 Page 858 of 1069 Page 858 of 1069 Page 858 of 1069 ---PAGE BREAK--- Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Petroleum distillates, hydrotreated light 64742-47-8 5000 mg/kg 2000 mg/kg 5.2 mg/L Hexane 110-54-3 - 3000 mg/kg 48000 ppm Butane 106-97-8 - - 658 g/m3 Propane 74-98-6 - - 658 mg/L Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Kidney. Liver. Central nervous system. Carcinogenic effects See Table Below. Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Petroleum distillates, hydrotreated light Not Listed Not Listed Not Listed Not Listed Not Listed Hexane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Full or partially full containers are considered hazardous waste. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Hexane Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Petroleum distillates, hydrotreated light Not Listed Not Listed Not Listed Hexane Listed Listed Not Listed Butane Listed Listed Not Listed Propane Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Petroleum distillates, hydrotreated light X X - X Hexane X X - X Butane X X - X Propane X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION NFPA Page 3 / 4 Water Flea Data Daphnia magna EC50>1000 mg/L (24 h) Product name Silicone Lubricant Water Flea Data Den-dronereides heteropoda LC50=4720 mg/L (96 h) Product code 19902 Hexane Petroleum distillates, hydrotreated light Page 859 of 1069 Page 859 of 1069 Page 859 of 1069 Page 859 of 1069 ---PAGE BREAK--- 16. OTHER INFORMATION Health - 2 Flammability - 4 Reactivity - 0 HMIS Health - 2 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 19902 Product name Silicone Lubricant Page 860 of 1069 Page 860 of 1069 Page 860 of 1069 Page 860 of 1069 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Degreaser Version No. 13443-15A Issue Date: June 1, 2015 Supersedes Date: January 14, 2013 OSHA HCS-2012 / GHS Page 1 of 5 Section 1: IDENTIFICATION Product Name: Simple Green® Degreaser Additional Names: Manufacturer’s Part Number: *Please refer to Section 16 Recommended Use: Cleaner and degreaser formulated to safely remove, oil, grease, and grime. Restrictions on Use: Do not use on non-rinsable or asphalt surfaces Company: Sunshine Makers, Inc. 15922 Pacific Coast Highway Huntington Beach, CA 92649 USA Telephone: [PHONE REDACTED] ● [PHONE REDACTED] Mon – Fri, 8am – 5pm PST Fax: [PHONE REDACTED] Email: [EMAIL REDACTED] Emergency Phone: Chem-Tel 24-Hour Emergency Service: [PHONE REDACTED] Section 2: HAZARDS IDENTIFICATION This product is considered hazardous (Eye Corrosive/Irritant – Category 2B) by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) OSHA HCS 2012 Label Elements Signal Word: Warning Hazard Symbol(s)/Pictogram(s): None required Hazard Statements: H320 – Causes Eye Irritation. Precautionary Statements: P264 – Wash hands thoroughly after handling. P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 – If eye irritation persists: Get medical advice. Hazards Not Otherwise Classified (HNOC): No hazards not otherwise classified were identified Other Information: None Known. Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Ingredient CAS Number Percent Range Water 7732-18-5 > 91%* Triethanolamine 102-71-6 ≤ Ethoxylated Alcohol 68439-46-3 ≤ Propylene Glycol Butyl Ether 5131-66-8 < Tetrapotassium Pyrophosphate 7320-34-5 < Potassium Silicate 1312-76-1 < *specific percentages of composition are being withheld as a trade secret Section 4: FIRST-AID MEASURES Inhalation: Not expected to cause respiratory irritation. If adverse effect occurs, move to fresh air. Skin Contact: Not expected to cause skin irritation. If adverse effect occurs, rinse skin with water. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice. Ingestion: May cause upset stomach. Drink plenty of water to dilute. See section 11. Most Important Acute and Delayed: None known. Indication of Immediate Medical Attention and Special Treatment Needed, if necessary: Treat Page 861 of 1069 Page 861 of 1069 Page 861 of 1069 Page 861 of 1069 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Degreaser Version No. 13443-15A Issue Date: June 1, 2015 Supersedes Date: January 14, 2013 OSHA HCS-2012 / GHS Page 2 of 5 Section 5: FIRE-FIGHTING MEASURES Suitable & Unsuitable Extinguishing Media: Use Dry chemical, CO2, water spray or “alcohol” foam. Avoid high volume jet water. Specific Hazards Arising from Chemical: In event of fire, fire created carbon oxides and oxides of phosphorus may be formed. Special Protective Actions for Fire-Fighters: Wear positive pressure self-contained breathing apparatus; Wear full protective clothing. This product is non-flammable. See Section 9 for Physical Properties. Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures: For non-emergency personnel: See section 8 – personal protection. For emergency responders: Avoid eye contact. Safety goggles suggested if splashing or misting is likely to occur. Environmental Precautions: Do not allow into open waterways and ground water systems. Methods and Materials for Containment and Clean Up: Dike or soak up with inert absorbent material. See section 13 for disposal considerations. Section 7: HANDLING AND STORAGE Precautions for Safe Handling: Ensure adequate ventilation. Keep out of reach of children. Keep away from heat, sparks, open flame and direct sunlight. Do not pierce any part of the container. Do not mix or contaminate with any other chemical. Do not eat, drink or smoke while using this product. Conditions for Safe Storage including Incompatibilities: Keep container closed. Keep in cool dry area. Avoid prolonged exposure to sunlight. Do not store at temperatures above 109oF (42.7oC). If separation occurs, mix the product for reconstitution. Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limit Values: Triethanolamine (102-71-6) 5 mg/m3 PEL California Diethanolamine (111-42-2) 3 ppm TWA; 15 mg/m3 TWA Connecticut, Michigan, Minnesota, OSHA, Tennessee, Vermont, Washington 0.46 ppm PEL; 2 mg/m3 PEL California 6 ppm STEL Washington Appropriate Engineering Controls: Showers, eyewash stations, ventilation systems Individual Protection Measures / Personal Protective Equipment (PPE) Eye Contact: Use protective glasses or safety goggles if splashing or spray-back is likely. Respiratory: Use in well ventilated areas or local exhaust ventilations when cleaning small spaces. Skin Contact: Use protective gloves (any material) when used for prolonged periods or dermally sensitive. General Hygiene Considerations: Wash thoroughly after handling and before eating or drinking. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear Liquid Partition Coefficient: n-octanol/water: Not determined Odor: No added odor Autoignition Temperature: Non-flammable Odor Threshold: Not determined Decomposition Temperature: 109oF pH: 9.0 – 10.5 Viscosity: Like water Freezing Point: 0oC (32oF) Specific Gravity : 1.01 – 1.04 Boiling Point & Range: 98oC (210oF) VOCs: **Water & fragrance exemption in calculation Flash Point: > 212oF SCAQMD 304-91 / EPA 24: Not tested Evaporation Rate: Not determined CARB Method 310**: 5 g/L 0.042 lb/gal 0.5% Flammability (solid, gas): Not applicable SCAQMD Method 313: 5.1 g/L 0.042 lb/gal 0.51% Upper/Lower Flammability or Explosive Limits: Not applicable VOC Composite Partial Pressure: Not determined Page 862 of 1069 Page 862 of 1069 Page 862 of 1069 Page 862 of 1069 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Degreaser Version No. 13443-15A Issue Date: June 1, 2015 Supersedes Date: January 14, 2013 OSHA HCS-2012 / GHS Page 3 of 5 Section 9: PHYSICAL AND CHEMICAL PROPERTIES - continued Vapor Pressure : Not determined Nutrient Content: Vapor Density: Not determined Nitrogen - <0.1% by formula) Relative Density: 8.34 – 8.67 lb/gal Phosphorous - < 0.25% (by formula) Solubility: 100% in water Sulfur - <0.1% by formula) Section 10: STABILITY AND REACTIVITY Reactivity: Non-reactive. Chemical Stability: Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg). Possibility of Hazardous Reactions: None known. Conditions to Avoid: Excessive heat or cold. Incompatible Materials: Do not mix with oxidizers, acids, bathroom cleaners, or disinfecting agents. Hazardous Decomposition Products: Normal products of combustion - CO, CO2, oxides of phosphorus. Section 11: TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Inhalation - Overexposure may cause headache. Skin Contact - Not expected to cause irritation. Eye Contact - Causes minimal/mild eye irritation. Ingestion - May cause upset stomach. related to the physical, chemical and toxicological characteristics: no expected under typical use conditions. Delayed and immediate effects and or chronic effects from short term exposure: no expected under typical use conditions. Delayed and immediate effects and or chronic effects from long term exposure: headache, dry skin, or skin irritation may occur. Interactive effects: Not known. Numerical Measures of Toxicity Acute Toxicity: Oral LD50 (rat) > 5 g/kg body weight Dermal LD50 (rabbit) > 5 g/kg body weight Calculated via OSHA HCS 2012 / Globally Harmonized System of Classification and Labelling of Chemicals Skin Corrosion/Irritation: Non-irritant per Dermal Irritection® assay modeling. No animal testing performed. Eye Damage/Irritation: Minimal/Mild irritant per Ocular Irritection® assay modeling. No animal testing performed. Germ Cell Mutagenicity: Mixture does not classify under this category. Carcinogenicity: Volume of ingredients does not trigger or classify under this category. This product contains trace amounts of Diethanolamine (IARC 2B and ACGIH A3) Reproductive Toxicity: Mixture does not classify under this category. STOT-Single Exposure: Mixture does not classify under this category. STOT-Repeated Exposure: Mixture does not classify under this category. Aspiration Hazard: Mixture does not classify under this category. Section 12: ECOLOGICAL INFORMATION Ecotoxicity: Volume of ingredients used does not trigger toxicity classifications under the Globally Harmonized System of Classification and Labelling of Chemicals. Aquatic: Not tested on finished formulation. Terrestrial: Not tested on finished formulation. Persistence and Degradability: Based on similar formulations, expected to be Readily BIodegradable Bioaccumulative Potential: No data available. Mobility in Soil: No data available. Other Adverse Effects: No data available. Page 863 of 1069 Page 863 of 1069 Page 863 of 1069 Page 863 of 1069 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Degreaser Version No. 13443-15A Issue Date: June 1, 2015 Supersedes Date: January 14, 2013 OSHA HCS-2012 / GHS Page 4 of 5 Section 13: DISPOSAL CONSIDERATIONS Unused or Used Liquid: May be considered hazardous in your area depending on usage and tonnage of disposal – check with local, regional, and or national regulations for appropriate methods of disposal. Empty Containers: May be offered for recycling. Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or storm drains. Section 14: TRANSPORT INFORMATION U.N. Number: Not applicable U.N. Proper Shipping Name: Cleaning Compound, Liquid NOI Transport Hazard Class(es): Not applicable NMFC Number: 48580-3 Packing Group: Not applicable Class: 55 Environmental Hazards: Marine Pollutant - NO Transport in Bulk (according to Annex II of MARPOL 73/78 and IBC Code): Unknown. Special precautions which user needs to be aware of/comply with, in connection with transport or conveyance either within or outside their premises: None known. U.S. (DOT) / Canadian TDG: Not Regulated for shipping. ICAO/ IATA: Not classified as Hazardous IMO / IDMG: Not classified as Hazardous ADR/RID: Not classified as Hazardous Section 15: REGULATORY INFORMATION All components are listed on: TSCA and DSL Inventory. SARA Title III: Sections 311/312 – Not applicable. Sections 313 Superfunds Amendments and Reauthorizations Act of 1986 – Diethanolamine (111-42-2) < 0.01% Sections 302 – Not applicable. Clean Air Act (CAA): Triethanolamine (102-71-6), Diethanolamine (111-42-2), Propylene Glycol Butyl Ether (5131-66-8) Clean Water Act (CWA): Not applicable CERCLA: Diethanolamine (111-42-2) 100 lb RQ State Right To Know Lists: Triethanolamine (102-71-6) Massachusetts, New Jersey, Diethanolamine (111-42-2) Massachusetts, New Jersey, CA Proposition 65: Diethanolamine (111-42-2) < 0.01% Texas ESL: Triethanolamine 102-71-6 5 µg/m3 long term 50 µg/m3 short term Ethoxylated Alcohol 68439-46-3 60 µg/m3 long term 600 µg/m3 short term Propylene Glycol Butyl Ether 5131-66-8 73 µg/m3 long term 730 µg/m3 short term Tetrapotassium Pyrophosphate 7320-34-5 5 µg/m3 long term 50 µg/m3 short term Potassium Silicate 1312-76-1 5 µg/m3 short term Diethanolamine 111-42-2 1 µg/m3 long term 10 µg/m3 short term Section 16: OTHER INFORMATION Size Item Number UPC 32 oz. 1900000113443 043318134432 32 oz., 12 per case 13443, 1910001213443 043318134432 1 gallon 1900000113447, 005692678 043318134470 1 gallon, 4 per case 13447 & 1910000413447, 005692678 043318134470 5 gallon 13445 & 1900000113445, 005692686 043318134456 55 gallon 13446 & 1900000113446, 005692694 043318134463 USA part numbers listed only. Not all part numbers listed. USA part numbers may not be valid for international sale. Page 864 of 1069 Page 864 of 1069 Page 864 of 1069 Page 864 of 1069 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Degreaser Version No. 13443-15A Issue Date: June 1, 2015 Supersedes Date: January 14, 2013 OSHA HCS-2012 / GHS Page 5 of 5 Section 16: OTHER INFORMATION - continued NFPA: Health – Eye Irritant Stability – Stable Flammability – Non-flammable Special - None Acronyms NTP National Toxicology Program IARC International Agency for Research on Cancer OSHA Occupational Safety and Health Administration CPSC Consumer Product Safety Commission TSCA Toxic Substances Control Act DSL Domestic Substances List Prepared / Revised By: Sunshine Makers, Inc., Regulatory Department. This SDS has been revised in the following sections: Revised MSDS to SDS format DISCLAIMER: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Page 865 of 1069 Page 865 of 1069 Page 865 of 1069 Page 865 of 1069 ---PAGE BREAK--- 1. IDENTIFICATION Product Name Sodium Bicarbonate Product Code 7941 CAS No. 144-55-8 Chemical Formula NaHCO3 Recommended Use For laboratory, scientific, R&D or manufacturing use. Emergency Telephone Call CHEMTREC 1-[PHONE REDACTED] (EKI CCN 7453) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Although this product does not normally require specific hazard precautions, chemical users should always take care to minimize personnel exposure and workplace contamination. Store closed at 15-30C. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Sodium bicarbonate 144-55-8 >97 4. FIRST AID MEASURES Description of first aid measures General advice This chemical is not expected to produce any significant adverse health effects. Eye contact Flush eyes with plenty of water, removing contact lenses if present. Get medical attention if irritation develops. Skin contact Wash thoroughly with soap and water while removing contaminated garments. Get medical attention if irritation develops. Inhalation Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion Rinse mouth and drink several glasses of water. Contact a physician or poison control center if develop. 5. FIRE-FIGHTING MEASURES Page 1 / 4 Version 1 SAFETY DATA SHEET Revision Date 04-Aug-2015 Company E K Industries, Inc. 1403 Herkimer St. Joliet, IL 60432 Tel. (800) 283-4244 Page 866 of 1069 Page 866 of 1069 Page 866 of 1069 Page 866 of 1069 ---PAGE BREAK--- Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Specific hazards arising from the chemical No information available. Hazardous combustion productsCarbon oxides. Sodium oxides. Protective equipment and precautions for firefighters Firefighters should wear self-contained breathing apparatus with full facepiece operated in pressure-demand or other positive pressure mode. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. For emergency responders Remove all sources of ignition. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Use personal protective equipment as required Handle in accordance with good industrial hygiene and safety practice. Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible materials Acids. Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering Controls Emergency showers, eyewash stations, ventilation systems. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Solid Appearance White powder Odor odorless Odor threshold No information available Page 2 / 4 No information available 7941 - Sodium Bicarbonate pH 8.3 Revision Date 04-Aug-2015 Melting point / freezing point Page 867 of 1069 Page 867 of 1069 Page 867 of 1069 Page 867 of 1069 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions No information available. Conditions to avoid Exposure to air or moisture over prolonged periods. Extremes of temperature and direct sunlight. Incompatible materials Acids. Strong oxidizing agents. Hazardous Decomposition Products Carbon oxides. Sodium oxide. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Component Oral LD50 Dermal LD50 Inhalation LC50 Sodium bicarbonate 144-55-8 ( >97 ) = 4220 mg/kg ( Rat ) - - No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation No information available. Serious eye damage/eye irritation No information available. Irritation May cause eye irritation. Inhalation of dust in high concentration may cause irritation of respiratory system. Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity This chemical does not contain any carcinogens or potential carcinogens as listed by ACGIH, OSHA, IARC or NTP . 12. ECOLOGICAL INFORMATION Ecotoxicity No information available Persistence and degradability Page 3 / 4 Evaporation rate No information available Vapor density No information available No information available Relative density No information available Revision Date 04-Aug-2015 Water solubility Soluble in water Flammability (solid, gas) No information available Solubility in other solvents No information available Partition coefficient No information available Flammability Limit in Air Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Flash point No information available Upper flammability limit: No information available 7941 - Sodium Bicarbonate Lower flammability limit: No information available Boiling point / boiling range Vapor pressure No information available Page 868 of 1069 Page 868 of 1069 Page 868 of 1069 Page 868 of 1069 ---PAGE BREAK--- No information available. Bioaccumulation No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note: Transportation information is provided as a general reference only and may not be applicable in all situations. This information applies to non-bulk shipments only. Per 49 CFR §173.22, it is the shipper’s responsibility to ensure that all materials are properly packaged, classified and labeled prior to shipment. DOT Not regulated IATA Not regulated 15. REGULATORY INFORMATION No information available. 16. OTHER INFORMATION Prepared By EKI Regulatory Affairs (Email: [EMAIL REDACTED]) Revision Date 04-Aug-2015 Disclaimer E K Industries, Inc. makes no representation as to the comprehensiveness or accuracy of this document. Individuals using this information, or the product to which it refers, must exercise their independent judgment in determining all appropriateness for a particular purpose. Accordingly, E K Industries, Inc. will not be responsible for damages of any kind or nature resulting from the use of this information or the corresponding product. No representations or warranties of any kind or nature, including but not limited to: express warranties, implied warranties or merchantability, or warranties of fitness for a particular purpose, are made hereunder with respect to the information set forth herein or to the product to which the information refers. End of Safety Data Sheet Page 4 / 4 7941 - Sodium Bicarbonate Revision Date 04-Aug-2015 Page 869 of 1069 Page 869 of 1069 Page 869 of 1069 Page 869 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 1/10 SAFETY DATA SHEET 1. Identification Product identifier: Sodium Hydroxide, Pellets Other means of identification Product No.: 3115, 3718, 3722, 3723, 3728, 5045, 5565, 7001, 7680, 7708, 7772 Recommended use and restriction on use Recommended use: Not available. Restrictions on use: Not known. Details of the supplier of the safety data sheet Manufacturer Company Name: Avantor Performance Materials, Inc. Address: 3477 Corporate Parkway, Suite 200 Center Valley, PA 18034 Telephone: Customer Service: [PHONE REDACTED] Fax: [PHONE REDACTED] Contact Person: Environmental Health & Safety E-mail: [EMAIL REDACTED] Emergency telephone number: 24 Hour Emergency: [PHONE REDACTED] Chemtrec: [PHONE REDACTED] 2. Hazard(s) identification Hazard Classification Physical Hazards Corrosive to metals Category 1 Health Hazards Skin Corrosion/Irritation Category 1 Serious Eye Damage/Eye Irritation Category 1 Unknown toxicity - Health Acute toxicity, inhalation, dust or mist 100 % Unknown toxicity - Environment Chronic hazards to the aquatic environment 100 % Hazard Symbol: Label Elements Page 870 of 1069 Page 870 of 1069 Page 870 of 1069 Page 870 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 2/10 Signal Word: Danger Hazard Statement: May be corrosive to metals. Causes severe skin burns and eye damage. Precautionary Statement Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves/protective clothing/eye protection/face protection. Keep only in original container. Wash hands thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Absorb spillage to prevent material damage. Storage: Store locked up. Store in corrosive resistant container with a resistant inner liner. Store in a well-ventilated place. Keep container closed. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not result in GHS classification: None. 3. Composition/information on ingredients Substances Chemical Identity Common name and synonyms CAS number Content in percent SODIUM HYDROXIDE 1310-73-2 90 - 100% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures General information: Get medical advice/attention if you feel unwell. Show this safety data sheet to the doctor in attendance. Ingestion: Call a physician or poison control center immediately. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Inhalation: Move to fresh air. Call a physician or poison control center immediately. Apply artificial respiration if victim is not breathing If breathing is difficult, give oxygen. Page 871 of 1069 Page 871 of 1069 Page 871 of 1069 Page 871 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 3/10 Skin Contact: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician or poison control center immediately. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately. Most important acute and delayed Corrosive to skin and eyes. Indication of immediate medical attention and special treatment needed Treatment: Treat may be delayed. 5. Fire-fighting measures General Fire Hazards: Move containers from fire area if you can do so without risk. Use water spray to keep fire-exposed containers cool. Cool containers exposed to flames with water until well after the fire is out. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media: The product reacts with water and will generate heat. Specific hazards arising from the chemical: Fire may produce irritating, corrosive and/or toxic gases. Special protective equipment and precautions for firefighters Special fire fighting procedures: No unusual fire or explosion hazards noted. Special protective equipment for fire-fighters: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Keep unauthorized personnel away. Ventilate closed spaces before entering them. Use personal protective equipment. See Section 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Methods and material for containment and cleaning up: Sweep up and place in a clearly labeled container for chemical waste. Clean surface thoroughly to remove residual contamination. Neutralize spill area and washings with dilute acetic acid. Notification Procedures: Prevent entry into waterways, sewer, basements or confined areas. Stop the flow of material, if this is without risk. Inform authorities if large amounts are involved. Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Page 872 of 1069 Page 872 of 1069 Page 872 of 1069 Page 872 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 4/10 7. Handling and storage Precautions for safe handling: Do not get in eyes, on skin, on clothing. Do not eat, drink or smoke when using the product. Do not taste or swallow. Avoid breathing dust or vapor. Use personal protective equipment as required. Wash hands thoroughly after handling. Conditions for safe storage, including any incompatibilities: Do not store in metal containers. Keep container closed. Store in a well-ventilated place. Store in a dry place. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity type Exposure Limit Values Source SODIUM HYDROXIDE Ceiling 2 mg/m3 US. ACGIH Threshold Limit Values (2011) Ceil_Time 2 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) PEL 2 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Ceiling 2 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Appropriate Engineering Controls No data available. Individual protection measures, such as personal protective equipment General information: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. An eye wash and safety shower must be available in the immediate work area. Eye/face protection: Wear safety glasses with side shields (or goggles) and a face shield. Skin Protection Hand Protection: Chemical resistant gloves Other: Wear suitable protective clothing. Respiratory Protection: In case of inadequate ventilation use suitable respirator. Air-purifying respirator with a high efficiency particulate filter. Hygiene measures: Provide eyewash station and safety shower. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing to remove contaminants. Discard contaminated footwear that cannot be cleaned. 9. Physical and chemical properties Appearance Physical state: solid Form: Pellets Color: White Odor: Odorless Page 873 of 1069 Page 873 of 1069 Page 873 of 1069 Page 873 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 5/10 Odor threshold: No data available. pH: 13 (0.5% aqueous solution) Melting point/freezing point: 323 °C Initial boiling point and boiling range: 1,388 °C Flash Point: not applicable Evaporation rate: No data available. Flammability (solid, gas): No data available. Upper/lower limit on flammability or explosive limits Flammability limit - upper No data available. Flammability limit - lower No data available. Explosive limit - upper No data available. Explosive limit - lower No data available. Vapor pressure: No data available. Vapor density: No data available. Relative density: 2.13 (25 Solubility(ies) Solubility in water: 1,110 g/l Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity: No data available. Other information Molecular weight: 40 g/mol (HNaO) 10. Stability and reactivity Reactivity: Reacts violently with strong acids. Chemical Stability: Material is stable under normal conditions. Possibility of Hazardous Reactions: Hazardous polymerization does not occur. The substance is hygroscopic and will absorb water by contact with the moisture in the air. Conditions to Avoid: Avoid dust formation. Heat. Moisture. Incompatible Materials: Oxidizing agents. Acids. Flammable liquid. Contact with metals may evolve flammable hydrogen gas. Hazardous Decomposition Products: Sodium oxides 11. Toxicological information Information on likely routes of exposure Ingestion: May cause burns of the gastrointestinal tract if swallowed. Inhalation: May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Skin Contact: Causes severe skin burns. Eye contact: Causes serious eye damage. Page 874 of 1069 Page 874 of 1069 Page 874 of 1069 Page 874 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 6/10 Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: LD 50 (Rat): 130 - 340 mg/kg Dermal Product: LD 50 (Rabbit): 1,350 mg/kg Inhalation Product: No data available. Repeated dose toxicity Product: No data available. Skin Corrosion/Irritation Product: Causes severe skin burns. Serious Eye Damage/Eye Irritation Product: Causes serious eye damage. Respiratory or Skin Sensitization Product: Not a skin sensitizer. Carcinogenicity Product: This substance has no evidence of carcinogenic properties. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): No carcinogenic components identified Germ Cell Mutagenicity In vitro Product: No mutagenic components identified In vivo Product: No data available. Reproductive toxicity Product: No components toxic to reproduction Specific Target Organ Toxicity - Single Exposure Product: None known. Specific Target Organ Toxicity - Repeated Exposure Product: None known. Aspiration Hazard Product: Not classified Other effects: None known. Page 875 of 1069 Page 875 of 1069 Page 875 of 1069 Page 875 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 7/10 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): SODIUM HYDROXIDE LC 50 (Western mosquitofish (Gambusia affinis), 96 125 mg/l Mortality Aquatic Invertebrates Product: No data available. Specified substance(s): SODIUM HYDROXIDE EC 50 (Water flea (Ceriodaphnia dubia), 48 34.59 - 47.13 mg/l Intoxication Chronic hazards to the aquatic environment: Fish Product: No data available. Aquatic Invertebrates Product: No data available. Toxicity to Aquatic Plants Product: No data available. Persistence and Degradability Biodegradation Product: Expected to be readily biodegradable. BOD/COD Ratio Product: No data available. Bioaccumulative Potential Bioconcentration Factor (BCF) Product: No data available on bioaccumulation. Partition Coefficient n-octanol / water (log Kow) Product: No data available. Mobility in Soil: The product is water soluble and may spread in water systems. Other Adverse Effects: Harmful to aquatic organisms. The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms. 13. Disposal considerations Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local laws. Contaminated Packaging: Since emptied containers retain product residue, follow label warnings even after container is emptied. Page 876 of 1069 Page 876 of 1069 Page 876 of 1069 Page 876 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 8/10 14. Transport information DOT UN Number: UN 1823 UN Proper Shipping Name: Sodium hydroxide, solid Transport Hazard Class(es) Class(es): 8 Label(s): 8 Packing Group: II Marine Pollutant: Not a Marine Pollutant Special precautions for user: – IMDG UN Number: UN 1823 UN Proper Shipping Name: SODIUM HYDROXIDE, SOLID Transport Hazard Class(es) Class(es): 8 Label(s): 8 EmS No.: F-A, S-B Packing Group: II Marine Pollutant: Not a Marine Pollutant Special precautions for user: – IATA UN Number: UN 1823 Proper Shipping Name: Sodium hydroxide, solid Transport Hazard Class(es): Class(es): 8 Label(s): 8 Marine Pollutant: Not a Marine Pollutant Packing Group: II Special precautions for user: – 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) None present or none present in regulated quantities. CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Reportable quantity SODIUM HYDROXIDE 1000 lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Acute (Immediate) SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity SODIUM HYDROXIDE 1000 lbs. Page 877 of 1069 Page 877 of 1069 Page 877 of 1069 Page 877 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 9/10 SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity SODIUM HYDROXIDE 10000 lbs SARA 313 (TRI Reporting) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) Chemical Identity Reportable quantity SODIUM HYDROXIDE Reportable quantity: 1000 lbs. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): None present or none present in regulated quantities. US State Regulations US. California Proposition 65 No ingredient regulated by CA Prop 65 present. US. New Jersey Worker and Community Right-to-Know Act Chemical Identity SODIUM HYDROXIDE US. Massachusetts RTK - Substance List Chemical Identity SODIUM HYDROXIDE US. RTK - Hazardous Substances Chemical Identity SODIUM HYDROXIDE US. Rhode Island RTK Chemical Identity SODIUM HYDROXIDE Inventory Status: Australia AICS: On or in compliance with the inventory Canada DSL Inventory List: On or in compliance with the inventory EINECS, ELINCS or NLP: On or in compliance with the inventory Japan (ENCS) List: On or in compliance with the inventory China Inv. Existing Chemical Substances: Not in compliance with the inventory. Korea Existing Chemicals Inv. (KECI): On or in compliance with the inventory Canada NDSL Inventory: Not in compliance with the inventory. Philippines PICCS: On or in compliance with the inventory US TSCA Inventory: On or in compliance with the inventory New Zealand Inventory of Chemicals: On or in compliance with the inventory Japan ISHL Listing: On or in compliance with the inventory Japan Pharmacopoeia Listing: Not in compliance with the inventory. 16.Other information, including date of preparation or last revision NFPA Hazard ID Flammability Health Reactivity Special hazard. 0 1 3 Page 878 of 1069 Page 878 of 1069 Page 878 of 1069 Page 878 of 1069 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 10/10 Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; RNP - Rating not possible Issue Date: 04-14-2015 Revision Date: No data available. Version 2.1 Further Information: No data available. Disclaimer: THE INFORMATION PRESENTED IN THIS MATERIAL SAFETY DATA SHEET (MSDS/SDS) WAS PREPARED BY TECHNICAL PERSONNEL BASED ON DATA THAT THEY BELIEVE IN THEIR GOOD FAITH JUDGMENT IS ACCURATE. HOWEVER, THE INFORMATION PROVIDED HEREIN IS PROVIDED “AS IS,” AND AVANTOR PERFORMANCE MATERIALS MAKES AND GIVES NO REPRESENTATIONS OR WARRANTIES WHATSOEVER, AND EXPRESSLY DISCLAIMS ALL WARRANTIES REGARDING SUCH INFORMATION AND THE PRODUCT TO WHICH IT RELATES, WHETHER EXPRESS, IMPLIED, OR STATUTORY, INCLUDING WITHOUT LIMITATION, WARRANTIES OF ACCURACY, COMPLETENESS, MERCHANTABILITY, NON- INFRINGEMENT, PERFORMANCE, SAFETY, SUITABILITY, STABILITY, AND FITNESS FOR A PARTICULAR PURPOSE, AND ANY WARRANTIES ARISING FROM COURSE OF DEALING, COURSE OF PERFORMANCE, OR USAGE OF TRADE. THIS MSDS/SDS IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PROPERLY TRAINED PERSON USING THIS PRODUCT, AND IS NOT INTENDED TO BE COMPREHENSIVE AS TO THE MANNER AND CONDITIONS OF USE, HANDLING, STORAGE, OR DISPOSAL OF THE PRODUCT. INDIVIDUALS RECEIVING THIS MSDS/SDS MUST ALWAYS EXERCISE THEIR OWN INDEPENDENT JUDGMENT IN DETERMINING THE APPROPRIATENESS OF SUCH ISSUES. ACCORDINGLY, AVANTOR PERFORMANCE MATERIALS ASSUMES NO LIABILITY WHATSOEVER FOR THE USE OF OR RELIANCE UPON THIS INFORMATION. NO SUGGESTIONS FOR USE ARE INTENDED AS, AND NOTHING HEREIN SHALL BE CONSTRUED AS, A RECOMMENDATION TO INFRINGE ANY EXISTING PATENTS OR TO VIOLATE ANY FEDERAL, STATE, LOCAL, OR FOREIGN LAWS. AVANTOR PERFORMANCE MATERIALS REMINDS YOU THAT IT IS YOUR LEGAL DUTY TO MAKE ALL INFORMATION IN THIS MSDS/SDS AVAILABLE TO YOUR EMPLOYEES. Page 879 of 1069 Page 879 of 1069 Page 879 of 1069 Page 879 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product Name Sodium Phosphate Monobasic Monohydrate (Certified ACS) Cat No. : S369-1; S369-3; S369-50; S369-250LB; S369-500 Synonyms Sodium dihydrogen phosphate monohydrate; Dihydrogen sodium phosphate monohydrate Recommended Use Laboratory chemicals. Uses advised against No Information available Details of the supplier of the safety data sheet 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Warning Hazard Statements Causes eye irritation May cause respiratory irritation Precautionary Statements Prevention Page 1 / 7 Emergency Telephone Number CHEMTRECÒ, Inside the USA: [PHONE REDACTED] CHEMTRECÒ, Outside the USA: 001-[PHONE REDACTED] Target Organs - Respiratory system. Revision Number 2 Creation Date 14-Oct-2009 Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Serious Eye Damage/Eye Irritation Category 2B Revision Date 25-Aug-2015 Specific target organ toxicity (single exposure) Category 3 Page 880 of 1069 Page 880 of 1069 Page 880 of 1069 Page 880 of 1069 ---PAGE BREAK--- Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Storage Store in a well-ventilated place. Keep container closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition / information on ingredients Component CAS-No Weight % Phosphoric acid, monosodium salt, monohydrate 10049-21-5 >95 Sodium phosphate, monobasic 7558-80-7 - 4. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if occur. Inhalation Move to fresh air. If breathing is difficult, give oxygen. Get medical attention if occur. Ingestion Do not induce vomiting. Obtain medical attention. Most important No information available. Notes to Physician Treat 5. Fire-fighting measures Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Unsuitable Extinguishing Media No information available Flash Point No information available Method - No information available Autoignition Temperature No information available Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Hazardous Combustion Products Sodium oxides Oxides of phosphorus Page 2 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 881 of 1069 Page 881 of 1069 Page 881 of 1069 Page 881 of 1069 ---PAGE BREAK--- Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. NFPA 6. Accidental release measures Personal Precautions Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation. Environmental Precautions Should not be released into the environment. See Section 12 for additional ecological information. Methods for Containment and Clean Up Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust formation. 7. Handling and storage Handling Wear personal protective equipment. Ensure adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Avoid dust formation. Storage Keep containers closed in a dry, cool and well-ventilated place. 8. Exposure controls / personal protection Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. 9. Physical and chemical properties Physical State Solid Appearance White Odor Odorless Odor Threshold No information available pH 4.1-4.5 @ 20°C 5% aq.solution Melting Point/Range 100 °C Boiling Point/Range No information available Flash Point No information available Evaporation Rate Not applicable Flammability (solid,gas) No information available Flammability or explosive limits Page 3 / 7 Flammability 0 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Personal Protective Equipment Instability 1 Physical hazards N/A Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Revision Date 25-Aug-2015 Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. Health 1 Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other are experienced. Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Page 882 of 1069 Page 882 of 1069 Page 882 of 1069 Page 882 of 1069 ---PAGE BREAK--- Upper No data available Lower No data available Vapor Pressure negligible Vapor Density Not applicable Specific Gravity No information available Solubility Soluble in water Partition coefficient; n-octanol/water No data available Autoignition Temperature No information available Decomposition Temperature > 100°C Viscosity Not applicable Molecular Formula H2 Na O4 P . H2 O Molecular Weight 137.99 10. Stability and reactivity Reactive Hazard None known, based on information available Stability Hygroscopic. Conditions to Avoid Incompatible products. Excess heat. Avoid dust formation. Exposure to moist air or water. Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Sodium oxides, Oxides of phosphorus Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. 11. Toxicological information Acute Toxicity Product Information Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Mist LC50 Based on ATE data, the classification criteria are not met. ATE > 5 mg/l. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Sodium phosphate, monobasic LD50 = 8290 mg/kg ( Rat ) LD50 > 7940 mg/kg ( Rabbit ) Not listed Toxicologically Synergistic Products No information available Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Moderately irritating to the eyes Sensitization No information available Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Phosphoric acid, monosodium salt, monohydrate 10049-21-5 Not listed Not listed Not listed Not listed Not listed Sodium phosphate, monobasic 7558-80-7 Not listed Not listed Not listed Not listed Not listed Mutagenic Effects No information available Reproductive Effects No information available. Page 4 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 883 of 1069 Page 883 of 1069 Page 883 of 1069 Page 883 of 1069 ---PAGE BREAK--- Developmental Effects No information available. Teratogenicity No information available. STOT - single exposure Respiratory system STOT - repeated exposure None known Aspiration hazard No information available / effects,both acute and delayed No information available Endocrine Disruptor Information No information available Other Adverse Effects The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. 12. Ecological information Ecotoxicity No information available. Persistence and Degradability Soluble in water Persistence is unlikely based on information available. Bioaccumulation/ Accumulation No information available. Mobility Will likely be mobile in the environment due to its water solubility. 13. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT Not regulated TDG Not regulated IATA Not regulated IMDG/IMO Not regulated 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Phosphoric acid, monosodium salt, monohydrate - - - - - X - X X - Sodium phosphate, monobasic X X - 231-449-2 - X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Page 5 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 884 of 1069 Page 884 of 1069 Page 884 of 1069 Page 884 of 1069 ---PAGE BREAK--- Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) Not applicable SARA 313 Not applicable SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act Not applicable Clean Air Act Not applicable OSHA Occupational Safety and Health Administration Not applicable CERCLA Not applicable California Proposition 65 This product does not contain any Proposition 65 chemicals State Right-to-Know Not applicable U.S. Department of Transportation Reportable Quantity (RQ): N DOT Marine Pollutant N DOT Severe Marine Pollutant N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Component DHS Chemical Facility Anti-Terrorism Standard Sodium phosphate, monobasic 2000 lb STQ Other International Regulations Mexico - Grade No information available Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class D2B Toxic materials Page 6 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 885 of 1069 Page 885 of 1069 Page 885 of 1069 Page 885 of 1069 ---PAGE BREAK--- 16. Other information Prepared By Regulatory Affairs Thermo Fisher Scientific Email: [EMAIL REDACTED] Creation Date 14-Oct-2009 Revision Date 25-Aug-2015 Print Date 25-Aug-2015 Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 7 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 886 of 1069 Page 886 of 1069 Page 886 of 1069 Page 886 of 1069 ---PAGE BREAK--- ISO 9001:2008 CERTIFIED 130 W. GRAND LAKE BLVD., WEST CHICAGO, IL. 50185 [PHONE REDACTED] OFFICE [PHONE REDACTED] FAX FOR CHEMICAL EMERGENCY. SPILL, LEAK, EXPOSURE, OR ACCIDENT, CALL CHEMTREC, 1-[PHONE REDACTED] Revised 8-21-14 SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SODIUM THISOULFATE 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL FORMULA: Na2S203 Cas# 7772-98-7 100% TLV: Not established by ACGIH: ACGIH (sulfur Dioxide) TWA 2 ppm (5.2 m (S)2(/m3; STEl 5 pppm (13 mg (S02)/m3) Toxicity values of the Hazardous ingredients Sodium Thiosulfate Intraperitoneal (ld50): Acute 5200 mg/kg (Mouse) 3. HAZARDS IDENTIFICATION POTENTIONAL HEALTH EFFECTS SIGNAL WORD: DANGER EYE CAN CAUSE SEVERE EYE IRRITATION. INCLUDE STINGING, TEARING, REDNESS AND SWELLIN OF THE EYES. CAN INJURE EYE TISSUE. SKIN CAN CAUSE SKIN IRRITATION. MAY INCLUDE REDNESS AND BURNING OF THE SKIN, AND OTHER SKIN DAMAGE. THE FEELING OF IRRITATION OR PAIN MAY NOT OCCUR UNTIL SEVERAL HOURS AFTER THE EXPOSURE. ADDITIONAL OF SKIN CONTACT MAY INCLUDE, HAIR LOSS, PASSAGE OF THIS MATERIAL INTO THE BODY THROUGH THE SKIN IS POSSIBLEM BUT IS UNLIKELY THAT THIS WOULD RESULT IN HARMFUL EFFECTS DURING SAFE HANDLING AND USE. SWALLOWING SWALLOWING THIS MATERIAL MAY BE HARMFUL OR FATAL. MAY INCLUDE SEERE STOMACH AND INESTINAL IRRITATION (NAUSEA, VOMITING, DIARRHEA), ABDOMINAL PAIN, AND VOMITING OF BLOOD. SWALLOWING THIS MATERIAL MAY CAYSE BURNS AND DESTROY TISSUE IN THE MOIUTH, THROAT AND DIGESTIVE TRACT. LOW BLOOD PRESSURE AND SHOCK MAY OCCUR AS A RESULT OF SEVERE TISSUE INJURY. INHALATION IT IS POSSIBLE TO BREATHE THIS MATERIAL UNDER DERTAIN CONDITIONS OF HANDLING AND USE FOR EXAMPLE (DURING HEATIN, SPRAYING OR STIRRING). BREATHING SMALL AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS NOT LIKELY TO CAUSE HARMFUL EFFECTS. BREATHING LARGE AMOUNTS MAY BE HARMFUL. USUALLY OCCUR AT AIR CONCENTRATIONS HIGHER THAN THE RECOMMENDED EXPOSURE LIMITS (SEE SECTION 8) OF EXPOSURE SIGNS AND OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING, SWALOWING, AND OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE STOMACH, OR INTENSTINAL UPSET (NAUSEA, VOMITING, DIARRHEA), IRRITATION (NOSE, THROAT, AIRWAYS) COUGH DIFFICULT BREATHING, LUNG EDEMA, (FLUID BUILD UP IN THE LUNG TISSUE) LUNG DAMAGE, DAMAGE TO THE MOUTH, THROAT AND OR AIRWAYS, SCHOCK. TARGET ORGANS N//A DEVELOPMENTAL INFORMATION THIS MATERIAL (OR A COMPONENT) HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN LAB ANIMAL STUDIES. HARM TO THE FETUS OCCURS ONLY AT EXPOSURE LEELS THAT HARM THE PREGNANT AMIMAL. THE RELEVENACE OF THESE FINDINGS TO HUMANS IS UNCERTAIN. Page 887 of 1069 Page 887 of 1069 Page 887 of 1069 Page 887 of 1069 ---PAGE BREAK--- CANCER INFORMATION THIS MATERIAL IS NOT LISTED AS A CARCINOGEN BY THE INTERNATIONAL AGENCY FOR RESEARCH FOR CANCER, THE NATIONAL TOXICOLOGY PROGRAM FOR THE OCCUPATIONAL SAFETY AND HEALTH ADMINSTRATION OTHER HEALTH EFFECTS: NO DATA PRIMARY ROUTE OF ENTRY INHALATION, SKIN ABSORPTION, SIN CONTACT, EYE CONTACT, INGESTION 4. FIRST AID MEASURES INHALATION IF DEVELOP, MOVE INDIVIDUAL AWSAY FROM EXPOSURE AND INTO RESH AIR. IF PERSIS, SEEK MEDICAL ATTENTION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. EEP PERSON WARM AND QUIET, SEEK IMMEDIATE MEDICAL ATTENTION. EYES IF DEVELOP, IMMEDIATELY MOVE INDIVIUAL AWAY FRM EXPOSURE AND INTO FRESH AIR. FLUSH EYS GENTLY WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS APART, SEEK IMMEDIATE MEDICAL ATTENTION. SKIN IMMEDIATELY FLUSH SKIN WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMVING CONTAMINATED CLOTHING AND SHOES. SEEK MEDICAL ATTENTION. LAUNDER CLOTHING BEFORE REUSE AND DISCARD CONTAMINATED SHOES. SWALLOWING SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR UNCONSCIOUS DO NOT GIVE ANYTHING MY MOUTH, PLACE INDIVIUAL ON THE LEFT SIDE WITH HEAD DOWN. CONTACT A PHYSICIAN, MEDICAL FACILITYOR POSION CONTROL CENTER FOR ADVICE ABOUT WHETHER TO INDUCE VOMITING. IF POSSIBLE, DO NOT LEAVE INDIVDUAL UNATTENDED. NOTE TO PHYSICIAN PRE EXISTING DISORDERS OF THE FOLLOWINF ORFANS (OR ORGAN SYSTEMS) MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. SKIN, LUNG (FOR I.E. ASTHMA LIKE CONDITIONS) 5. FIRE FIGHTING MEASURES FLASH LIMIT: N/A EXPLOSIVE LIMIT: N/A AUTOIGNITION TEMPERATURE; NO DATA HAZARDOUS PRODUCTS OF COMBUSTION: MAY FORM CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS. FIRE & EXPLOSION HAZARDS NO SPECIAL FIRE HAZARDS ARE KNOWN TO BE ASSOCIATED WITH THIS PRODUCT EXTINGUISHING MEDIA USE AN EXTUINGUISHING MEDIA APPOPRIATE FOR SURROUNDING FIRE FIRE FIGHTING INSTRUCTIONS USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND STRUCTURES UNTIL FIRE IS OUT IF IT CAN BE DONE WITH MINIMAL RISK. AVOID BRATHING BURNING LIQUID WITH WATER USED FOR COOLING PURPOSES. WEAR FULL FIRE FIGHTING TURN OUT EAR (FULL BUNKER GEAR) , AND RESPIRATORY PROTECTION (SCBA). NFPA RATING HEALTH = 3 FLAMMABILITY = 1 REACTIVITY=0 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. SCOOP OR SCRAPE UP. PUT IN CONTAINER FOR RECOVERY OR DISPOSAL. LARGE SPILL PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AEA OF SPILL UNTIL CEAN UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. 7. HANDLING AND STORAGE HANDLING CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONAINERS RETAIN PRODUCT RESIDUES, (VAPOR, LIQUID AND OR SOLID) ALL HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED. EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE Page 888 of 1069 Page 888 of 1069 Page 888 of 1069 Page 888 of 1069 ---PAGE BREAK--- IMMEDIATE VICINITY OF OF POTENTIAL EXPOSURE. USE GOOD PERSONAL HYGIENE PRACTIVES. WASH HANDS BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. REMOVE SOILED CLOTHING AND WASH BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP AND WATER. STORAGE PRODUCT SOLUTIONS ARE CORROSIVE TO MANY COMMONLY USED MATERIALS OF CONSTRUCTION SUCH AS STEEL, GALVANIZED IRON, ALUMINUM, IN AND ZINC. THESE SOLUTIONS CAN BE STORED AND HANDLED IN BAKED PHENOLIC-LINED STEEL, POLYETHYLENE, STAINLESS STEEL OR REINFORECED EPOXY PLASTIC EQUIPMENT. STORE IN CLOSED CONTAINERS IN A DRY WELL VENTILATED AREA, 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED, HOWEVER, OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. CONSULT YOUR SAFETY REPRESENTATIVE SKIN PROTECTION WEAR IMERVIOUS GLOVE (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER) TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS RESPIRATORY PROTECTION IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED 9SEE EXPOSURE GUIDELINES ) A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPERT ENVIRONMENTAL CONTRO OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR INDUSTRIAL HYGIENIEST). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUC EXPOSURE. ENGINEERING CONTROLS PROVIDE SUFFICIENT MECHANICAL (GENERAL AND OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW LEVEL OF OVER EXPOSURE (FROM KNOWN, SUSPECTED OR APARENT ADVERSE EFFECTS) EXPOSURE GUIDELINES ORGANIC SALT – NO EXPOSURE LIMITS ESTABLISHED. SODIUM HYDROXIDE (1310-73-2) OSHA PEL – 2.00 MG/M3 –TWA OSHA VPEL 2.00 MG/M3 – CEILING ACGIH TLV 2.00 MG/M3 - CEILING 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: (FOR PRODUCT) 219.0 F (103.8 C) @ 760 MMHG VAPOR PRESSURE: (FOR PRODUCT ) < 17.500 MM/HG @ 68.00 F SPECIFIC VAPOR DENSITY: .6000 @AIR = 1 SPECIFIC GRAVITY: 1.260 @ 77.00 F LIQUID DENSITY 10.480 LBS/GAL @ 77.00 F 1.260 KG/L @ 25.00 C PERCENT VOLATILES: >60. % EVAPORATION RATE: SLOWER THAN ETHYL ETHER APPEARANCE: CLEAR LIQUID STATE: LIQUID PHYSICAL FORM: HOMOGENEOUS SOLUTION COLOR: CLEAR PALE YELLOW ODOR: SLIGHT AMINE ODOR ph: 10.5 -12.0 @ 1% AQUEUS SOLUTION FREEZING POINT: <-8.0 F (-22.2 C) MOLECULAR WEIGHT : 380.0 10. STABILITY AND REACTIVITY HAZARDOUS POLYMERIXATION PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION Page 889 of 1069 Page 889 of 1069 Page 889 of 1069 Page 889 of 1069 ---PAGE BREAK--- HAZARDOUS DECOMPOSITION MAY FORM: CARBON OXIDES, NITROEN OXIDES, TOXIC FUME CHEMICAL STABILITY STABLE INCOMPATBILITY AVOID CONTACT WITH: REACTIVE METALS SUCH AS ALUMINUM AND MANESIUM, STEEL, STRONG MINERAL ACIDS, STRONG OXIDZING AGENTS. REACTS WITH ACTIVE METALS (POTASSIUM , SODIUM, ALUMINUM ETC) TO PRODUCT FLAMMABLE HYDROGEN GAS. 11. TOXICOLOGICAL INFORMATION LD 50 AND LC 50 DATA SODIUM HYDROXIDE (CAS# 1310-73-2) ORAL LDLO (RABBIT): 500 MG/KG DERMAL LD50 (RABBIT) 1350 MG/KG INHALATION LC50: N/A ETHYLENEDIAMINEERAACETATE, SODIUM SALT (CAS#64-02-8) ORAL LD50 (MALE RATE: 3030 MG/KG DERMAL LD50 (RABBIT):>5000 MG/KG INHALATION LC50: N/A 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION 96 HR LC50 RAINBOW TROUT (STATIC CONDITIONS: 884 MG/L* 96 HR LC50 FATHEAD MINNOW (STATIC CONDITIONS: 707 MG/L* 48 HR LC50 CERIODAPHNIA DUBIA (STATIC CONDITIONS: 536 MG/L* 48 HR LC50 CERIODAPHNIA DBIA (STATIC CONDITIONS: 574 MG/L* *BASED ON SIMILAR FORMULATION CHEMICAL FATE INFORMATION BOD5:<2000 MG/L* COD: 329,800 MG/L* *BASED ON SIMILAR PRODUCT 13. DISPOSAL CONSIDERATIONS WASTE MANAGEMENT INFORMATION DISPOSE OF IN ACCORDANCW WITH ALL APPLICABLE LOCA, SATE AND FEDERAL REGULATINS. FOR ASISTANCE WITH YOUR WASTE MANAGEMENT NEEDS – INCLUDING DISPOSAL, RECYCLING AND WASTE STREAM REDUCTIONS, CONTACT MINERAL MASTERS [PHONE REDACTED] 14. TRANSPORT INFORMATION DOT INFORMATION – 249 CFR 172.101 D.O.T. Description: UN3267, CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S., 8, PG III CONTAINER MODE: 55 GAL DRUM/TRUCK PACKAGE NOS COMPONENT: ETHYLENEDIAMINE TETRAACETIC ACID NA SALT RQ (REPORTABLE QUANTITY ) 49 CFR 172.101: N/A OTHER TRANSPORTATION THE TRANSPORTATION INFORMATON MAY VARY WITH THE CONTAINER AND MODE OF SHIPMENT Page 890 of 1069 Page 890 of 1069 Page 890 of 1069 Page 890 of 1069 ---PAGE BREAK--- 15. REGULATORY INFORMATION US FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCES CONTROL ACT ) STATUS TSCA (UNITED SATES) THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED. CERCLA RQ – 40 CFR 302.4 COMPONENT RQ (LBS) SODIUM HYDROXIDE 1000 CERCLA RQ – 40 CFR 355 APPENDIX NONE Sara 311/312 Hazard Class – 40 CFR 370.2 Immediate Delayed ( ) Fire Reactive Sudden Release of Pressure Sara 313 Components – 40 CFR 372.65 None OSHA Process Safety Mgmt. – 29 CFR 1910 None Listed EPA Accidental Release Prevention 40 CFR 68 None Listed International Regulations – Inventory Status AICS (Australia) The intentional ingredients of this product are listed. DSL (Canada) The Intentional ingredients of this product are listed ECL (South Korea) The Intentional ingredients of this product are listed EINECS (Europe) The Intentional ingredients of this product are listed ENC (Japan) The Intentional ingredients of this product are listed IECSC (China) The Intentional ingredients of this product are listed PICCS (Philippines) The Intentional ingredients of this product are listed State and Local Regulations California Prop. 65 None NEW JERSEY RTK LABEL INFORMATION SODIUM HYDROXIDE 1310-73-2 RTK LABEL INFORMATION SODIUM HYDROXIDE (NAOH) 1310-73-2 The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirtm in advance or need that the information is current applicable and suitable to their circumstances. SECTION 16. OTHER INFORMATION IMPORTANT: The information presented herein, while not guaranteed, was prepared by competent technical personnel and it is true and accurate to the best of our knowledge. NO WARRANTY OR MERCHANTABILITY OR FITNESS FOR PURPOSE, OR OF ANY OTHER KIND, EXPRESSED OR IMPLIED, IS MADE REGARDING PERFORMANCE, STABILITY OR OTHERWISE. This information is not intended to be all inclusive as to the manner and conditions of use, handling, and storage. Other factors may involve other or additional safety or performance considerations. While or technical personnel will be happy to respond to questions, safe handling and use remains the responsibility of the customer. No suggestions for use are intended as and nothing herein shall be construed as a recommendation to infringe any existing patents or violate any federal, state, local laws, rules regulations or ordinances. Page 891 of 1069 Page 891 of 1069 Page 891 of 1069 Page 891 of 1069 ---PAGE BREAK--- Safety Data Sheet D-124 Revision Number: 004.0 Issue date: 04/20/2015 RS number: 387271 Product name: Soft Scrub Spray Gel w/Bleach Page 1 of 6 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER Product identifier used on the label: Soft Scrub Spray Gel with Bleach Other means of identification: 1145834, 1550760 Recommended use of the chemical and restrictions on use: APC bleach, Do not mix with other products. Name, address and telephone number of the chemical manufacturer: The Dial Corporation, a Henkel Company 7201 E. Henkel Way Scottsdale AZ 85255 CHEMTREC: 1-[PHONE REDACTED] (24 hours daily) Internet: www.henkelna.com Emergency telephone number: Medical Emergencies: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION The hazards described in this OSHA Globally Harmonized System Safety Data Sheet (SDS) are not intended for consumers, and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Classification of the substance or mixture in accordance with paragraph of §1910.1200 HAZARD CLASS HAZARD CATEGORY SKIN CORROSION 1C SERIOUS EYE DAMAGE 2A Signal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with paragraph of §1910.1200 Signal word: DANGER Hazard Statement(s): Causes severe skin burns and eye damage. Symbol(s): Precautionary Statements: Prevention: Wash thoroughly after handling. Wear protective gloves, eye protection, and face protection. Use personal protective equipment as required. Response: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Wash contaminated clothing before reuse. Storage: Not prescribed. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Hazards not otherwise classified: Not available. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Page 892 of 1069 Page 892 of 1069 Page 892 of 1069 Page 892 of 1069 ---PAGE BREAK--- RS number: 387271 Product name: Soft Scrub Spray Gel w/Bleach Page 2 of 6 See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS The following chemicals are classified as health hazards in accordance with paragraph of § 1910.1200. Chemical Name* CAS Number (Unique Identifier) Concentration Sodiumhypochlorite 7681-52-9 1 - 5 % Sodium hydroxide 1310-73-2 1 - 5 % *The specific chemical identity and/or exact percentage (concentration) of composition has been withheld because a trade secret is claimed in accordance with paragraph of §1910.1200. 4. FIRST AID MEASURES Description of necessary measures Inhalation: Remove from exposure area to fresh air immediately Keep affected person warm and at rest. Treat and supportively. Contact physician or local poison control center. Skin contact: Take off contaminated clothing. Rinse affected area with large amounts of water until no evidence of product remains. Contact physician or local poison control center. Eye contact: Rinse eyes immediately with plenty of water, occasionally lifting upper and lower lids, until no evidence of product remains. Get medical attention if pain or irritation develops. Ingestion: Treat and supportively. Maintain airway and respiration. Do not induce vomiting. Dilution by rinsing the mouth and giving water or milk to drink is generally recommended. Contact physician or local poison control center. Most important and effects, both acute and delayed After eye contact: May cause mild to severe irritation with possibility of permanent eye damage. After skin contact: Moderate to strong irritation of the skin (redness, swelling, burning), severe burns also possible. After Ingestion: Ingestion may cause pain, burning, swelling and redness in the mouth and throat. Nausea and vomiting may occur. After inhalation: Irritation of the respiratory tract, coughing. Inhalation of larger amounts may cause laryngospasm with shortness of breath. Indication of any immediate medical attention and special treatment needed After eye contact: Rinse eyes immediately with plenty of water, occasionally lifting upper and lower lids, until no evidence of product remains. After skin contact: Rinse affected area with large amounts of water until no evidence of product remains. After ingestion: Do not induce vomiting. Dilution by rinsing the mouth and giving a glass of water to drink is generally recommended. After inhalation: Remove from exposure area to fresh air immediately 5. FIRE FIGHTING MEASURES Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Dry chemical, carbon dioxide, water spray or regular foam. Unsuitable extinguishing media: None known Specific hazards arising from the chemical Oxides of carbon and oxides of nitrogen. Special protective equipment and precautions for fire-fighters In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Move containers from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Avoid breathing hazardous vapors, keep upwind. Isolate area. Keep unnecessary personnel away. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear skin, eye and respiratory protection as recommended in Section 8. Stop leak if you can do it without risk. Spills present a slipping hazard. Keep unnecessary personnel away. Ventilate spill area if possible. Make sure area is slip-free before re-opening to traffic. Page 893 of 1069 Page 893 of 1069 Page 893 of 1069 Page 893 of 1069 ---PAGE BREAK--- RS number: 387271 Product name: Soft Scrub Spray Gel w/Bleach Page 3 of 6 Methods and materials for containment and cleaning up SMALL SPILLS: Contain and absorb with sand or other absorbent material and place into clean, dry containers for later disposal. Wash site of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable waste container. 7. HANDLING AND STORAGE Precautions for safe handling Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Conditions for safe storage, including any incompatibilities Store in a cool, dry, ventilated area out of reach of children and away from sources of heat, moisture, and incompatible substances. Storage areas for large quantities (warehouse) should be well ventilated. Keep the containers closed when not in use. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV), and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparing the safety data sheet, where available. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Sodiumhypochlorite None None 2 mg/m3 STEL None Sodium hydroxide 2 mg/m3 Ceiling 2 mg/m3 PEL None None Appropriate engineering controls Provide local exhaust or general dilution ventilation to keep exposure to airborne contaminants below the permissible exposure limits where mists or vapors may be generated. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Individual protection measures Respiratory: Air contamination monitoring should be carried out where mists or vapors are likely to be generated, to assure that the employees are not exposed to airborne contaminants above the permissible exposure limits. Eye: Splash-proof safety glasses are required to prevent eye contact where splashing of product may occur. Hand/Body: Protective gloves are required where repeated or prolonged skin contact may occur. Protective clothing is required where repeated or prolonged skin contact may occur. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: gel green Odor: citric, fruity Odor threshold: Not available. pH: 12.5 - 13.3 (25 Melting point/ range: Not available. Boiling point/range: Not available. Flash point: Not available. Evaporation rate: Not available. Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Vapor pressure: Not available. Vapor density: Not available. Solubility in water: Not available. Partition coefficient (n-octanol/water): Not available. Autoignition temperature: Not available. Decomposition temperature: Not available. Viscosity: 200 - 500 mPa.s VOC content: Not available. Page 894 of 1069 Page 894 of 1069 Page 894 of 1069 Page 894 of 1069 ---PAGE BREAK--- RS number: 387271 Product name: Soft Scrub Spray Gel w/Bleach Page 4 of 6 10. STABILITY AND REACTIVITY Reactivity: This product reacts with acids. Chemical stability: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm). Possibility of hazardous reactions: Hazardous polymerization has not been reported to occur under normal temperatures and pressures. Conditions to avoid: Avoid storing in direct sunlight and avoid extremes of temperature. Incompatible materials: Strong oxidizers, acids. Reacts with other household chemicals such as acid toilet bowl cleaners, rust removers, acids, vinegar, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Hazardous decomposition products: Thermal decomposition products may include oxides of carbon and chrorine. 11. TOXICOLOGICAL INFORMATION Likely routes of exposure including related to characteristics Inhalation: Direct contact with mucous membranes may result in corrosive damage. Skin contact: Corrosive to the skin. Contact with the skin or mucous membranes may cause severe irritation and burns. Eye contact: Causes serious eye damage. Ingestion: Ingestion of large quantities may be harmful. Ingestion may cause severe irritation or burns to esophagus, mouth, and stomach with nausea, vomiting and diarrhea. Physical/Chemical: The product is alkaline. The product is corrosive. Other relevant toxicity information: This product is a household product. The use of this product by consumers is safe under normal and reasonable foreseen use. Numerical measures of toxicity, including delayed and immediate effect Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Sodiumhypochlorite Oral LD50 (RAT) = 8,91 g/kg Irritant, Corrosive, Skin Sodium hydroxide None Irritant, Corrosive, Eyes Carcinogenicity information Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen Sodiumhypochlorite No No No Sodium hydroxide No No No Carcinogenicity None of the ingredients in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health Administration (OSHA). Mutagenicity This product contains an ingredient which has been associated with mutagenicity effects. Toxicity for reproduction This product contains an ingredient which has been associated with reproductive, fetal or developmental effects. 12. ECOLOGICAL INFORMATION Aquatic Toxicity: This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal use conditions. The following toxicity information is available for the hazardous ingredient(s) when used as technical grade and is provided as reference for the occupational settings. Toxicity to fish: The aquatic toxicity profile of this product has not been determined. Page 895 of 1069 Page 895 of 1069 Page 895 of 1069 Page 895 of 1069 ---PAGE BREAK--- RS number: 387271 Product name: Soft Scrub Spray Gel w/Bleach Page 5 of 6 Toxicity to aquatic invertebrates: The aquatic toxicity profile of this product has not been determined. Toxicity to algae: The aquatic toxicity profile of this product has not been determined. Persistence and degradability No data available. Bioaccumulative potential The bioaccumulation potential of this product has not been determined. Mobility in soil The mobility of this product (in soil and water) has not been determined. 13. DISPOSAL CONSIDERATIONS Description of waste residues: Hazardous waste number: D002 (Corrosivity) Safe handling and disposal methods: Recommended method of disposal: This product is a RCRA characteristic hazardous waste (corrosive) and must be disposed of in a RCRA Subtitle C landfill. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the hazardous waste representative at the nearest EPA Regional Office for guidance. Disposal of uncleaned packages: Do not reuse this container. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper shipping classification may vary by packaging, properties, and mode of transportation. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: None Hazard class or division: None Identification number: None Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: None Hazard class or division: None Identification number: None Packing group: None Marine pollutant: None Page 896 of 1069 Page 896 of 1069 Page 896 of 1069 Page 896 of 1069 ---PAGE BREAK--- RS number: 387271 Product name: Soft Scrub Spray Gel w/Bleach Page 6 of 6 15. REGULATORY INFORMATION Occupational safety and health act: Hazard Communication Standard, 29 CFR 1910.1200(g) Appendix D: The Occupational Safety and Health Administration (OSHA) require that the Safety Data Sheets (SDSs) are readily accessible to employees for all hazardous chemicals in the workplace. Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this SDS may contain health hazard information not relevant to consumer use. United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 Export Notification: None above reporting de minimis CERCLA/SARA Section 302 : None above reporting de minimis CERCLA/SARA Section 311/312: Not available. CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. 16. OTHER INFORMATION DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: R&D Support Services Issue date: 04/20/2015 Page 897 of 1069 Page 897 of 1069 Page 897 of 1069 Page 897 of 1069 ---PAGE BREAK--- Material Safety Data Sheet D-122 Revision 09.0 Revision Date: 04/14/2014 The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672 USA Hard Surface Cleaner 04/14/2014 Page 1 of 4 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name(s): Soft Scrub® with Lemon Soft Scrub® with Baking Soda Product Use: Hard Surface Cleaner Formula IDH Number(s): 1407931, 1563069 (SS Lemon); 1417184, 1563068, 1722708 (SS w/Baking Soda) Company Address: The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672 USA Contact Information: Medical Emergencies: 1-[PHONE REDACTED] CHEMTREC: 1-[PHONE REDACTED] (24 hours daily) SECTION 2: HAZARD IDENTIFICATION EMERGENCY OVERVIEW CAUTION: This product is a white cream with a lemon or lavender fragrance. Direct contact with eyes can cause irritation. Ingestion of large amounts may cause some gastrointestinal discomfort including nausea, vomiting and diarrhea. Repeated or prolonged excessive contact may cause irritation or dermatitis. Keep out of reach of children. No significant environmental effects. Not a fire hazard. Product is stable. This product is labeled in accordance with regulations administered by the Consumer Product Safety Commission. The use pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of the Occupational Safety and Health Administration applicable to this Material Safety Data Sheet differ from the requirements of the CPSC and as a result, this MSDS may contain additional health hazard information not pertinent to consumer use and not found on the product label. Regulatory Status: This material is considered to be hazardous under OSHA’s Hazard Communication Standard (29 CFR 1900.1200). This MSDS should be retained and available for employees and other users of this product. Potential Health Effects NOTE: The acute health effects described below are those which could potentially occur for the finished product. They are based on the toxicology information available for the finished product and/or each hazardous ingredient, and are consistent with the product type and the likelihood of a specific route of exposure. Known chronic health effects related to exposure to a specific ingredient are indicated. Eye Contact: This product may cause mild to moderate eye irritation. Skin Contact: Repeated or prolonged excessive exposure can cause mild skin irritation or dermatitis. Ingestion: Ingestion of large amounts may cause some gastrointestinal discomfort including nausea, vomiting, abdominal pain, diarrhea, and lethargy. Inhalation: Irritating, in high concentration, to the respiratory tract (nose, throat, and lungs). Subchronic/Chronic Health Effects: None known. Medical Conditions Generally Recognized As Being Aggravated By Exposure: Pre-existing chronic skin conditions. Potential Environmental Effects See Section 12: Ecological Information. SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS Based on our hazard evaluation, the following chemical substance(s) in this product have been identified as hazardous. Ingredient CAS Number Percent (w/w) Calcium Carbonate 471-34-1 30 - 60 % Sodium 68411-30-3 5 - 10 % Alcohol Ethoxylate 66455-15-0 1 – 5 % SECTION 4: FIRST AID MEASURES Eyes: Immediately rinse eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medical attention if pain or irritation persists. Skin: Rinse affected area with plenty of water until no evidence of product remains. Get medical attention if irritation persists. Page 898 of 1069 Page 898 of 1069 Page 898 of 1069 Page 898 of 1069 ---PAGE BREAK--- Hard Surface Cleaner MSDS D-122 (Rev. 9) The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672 USA Hard Surface Cleaner 04/14/2014 Page 2 of 4 Ingestion: Treat and supportively. Maintain airway and respiration. If vomiting occurs, keep head below hips to prevent aspiration. Dilution by rinsing the mouth and giving water or milk to drink is generally recommended. If unconscious, the victim should not be given anything to drink. Contact physician or local poison control center. Inhalation: Remove from exposure area to fresh air immediately. Keep affected person warm and at rest. Treat and supportively. Contact physician or local poison control center. If breathing has stopped, give artificial respiration, and get medical attention immediately. Note to Physician: The physician's judgment should be used to control and clinical condition based on the individual reactions of the patient. SECTION 5: FIRE FIGHTING MEASURES Flammable Properties OSHA Flammability Classification: Not applicable Flash Point: > 200°C (93.3°C) (TCC) Auto-Ignition Temperature: Not applicable Flame Projection: Not available Flammable/Explosive limits – lower: Not available Flammable/Explosive limits – upper: Not available Hazardous Combustion Products: Oxides of carbon and nitrogen. Fire and Explosion Hazard: Negligible fire hazard when exposed to heat or flame. Extinguishing Media Dry chemical, carbon dioxide, water spray or regular foam. Protection of Firefighters In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Use flooding amounts of water as a fog, solid streams may be ineffective. Avoid breathing vapors; keep upwind. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear skin, eye and respiratory protection as recommended in Section 8. Stop or reduce any leaks if it is safe to do so. Spills present a slipping hazard. Keep unnecessary personnel away. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Make sure area is slip-free before re- opening to traffic. Environmental Precautions: Small or household quantities may be disposed in sewer or other liquid waste system. For larger quantities check with your local water treatment plant. Methods for Containment and Clean-Up: SMALL SPILLS: Contain and absorb with sand or other absorbent material and place into containers for later disposal. Wash site of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable waste container. SECTION 7: HANDLING AND STORAGE Handling: Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Storage: Store in a cool, dry, ventilated area out of reach of children and away from sources of heat, moisture, and incompatible substances. Store in suitable labeled containers. Store the containers closed. SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION This product is a laundry care product. The use of this product by consumers is safe under normal and reasonable foreseen use. The information provided below refers to the occupational settings. Worker Exposure Limits Ingredient ACGIH TLV OSHA PEL AIHA WEEL NIOSH Calcium carbonate TWA: 10 mg/m 3 (total dust) TWA: 15 mg/m 3 (total dust), 5 mg/m 3 (respirable dust) N/A N/A Engineering Controls: Provide local exhaust or general dilution ventilation to keep exposure to airborne contaminants below the permissible exposure limits where mists or vapors may be generated. Respirator: Air contamination monitoring should be carried out where mists or vapors are likely to be generated, to assure that the employees are not exposed to airborne contaminants above the permissible exposure limits. If respiratory protection is required, it must be based on the contamination levels found in the workplace, must not exceed the working limits of the respirator and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). For Fire Fighting and Other Immediately Dangerous To Life or Health Conditions: Page 899 of 1069 Page 899 of 1069 Page 899 of 1069 Page 899 of 1069 ---PAGE BREAK--- Hard Surface Cleaner MSDS D-122 (Rev. 9) The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672 USA Hard Surface Cleaner 04/14/2014 Page 3 of 4 Any self-contained breathing apparatus that has a full-face piece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator that has a full-face piece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure demand or other positive-pressure mode. Clothing: Protective clothing is required where repeated or prolonged skin contact may occur. Gloves: Chemical-resistant gloves are required where repeated or prolonged skin contact may occur. Eye/Face Protection: Splash-proof safety glasses are required to prevent eye contact where splashing of product may occur. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: White Physical state: Cream Liquid Odor: Lemon or lavender Odor threshold: None Boiling point: Not available Evaporation rate: Not available Melting point: Not available Vapor density: Not available Density: 1.36 g/ml @ 25°C Vapor pressure: Not available pH: 10.5 – 12.0 (neat) Water solubility: Partial Partition coefficient (n-octanol/water): Not available Viscosity (Dynamic): 5,000 – 12,000 cps Flammable Properties: See Section 5 SECTION 10: STABILITY AND REACTIVITY Chemical Stability: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm). Conditions to Avoid: Avoid storing in direct sunlight and avoid extremes of temperature. Incompatible Materials: Strong oxidizers and reducing agents. Reacts with other household chemicals such as acid toilet bowl cleaners, rust removers, acids, vinegar, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Hazardous Decomposition Products: Thermal decomposition products may include oxides of carbon. Possibility of Hazardous Reactions: Polymerization does not occur under normal temperatures and pressures. SECTION 11: TOXICOLOGICAL INFORMATION Product Information Summary: This is a household product. The use of this product by consumers is safe under normal and reasonable foreseen use. Direct contact with eyes can cause irritation. Ingestion of large amounts may cause some gastrointestinal discomfort including nausea, vomiting and diarrhea. Repeated or prolonged excessive contact may cause irritation or dermatitis. Component Analysis: The following toxicity information is for the hazardous ingredient(s) when used as technical grade and is provided as reference for the occupational settings. Ingredient / Product LD50 / Draize Score Toxicity / Irritation Rating Acute Oral Toxicity Calcium carbonate 6,450 mg/kg (rat) Practically Non-hazardous Sensitization: This product is not considered a skin or respiratory sensitizer. Carcinogenicity: None of the ingredients in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health Administration (OSHA). Mutagenicity: None of the ingredients in this product are known to cause mutagenicity. Reproductive/Fetal/Developmental effects: None of the ingredients in this product are known to have reproductive, fetal, or developmental hazards. Target organ toxicity: None of the ingredients in this product are known to have target organ toxicity. Epidemiological information: None of the ingredients in this product are known to have health-related information in working populations. SECTION 12: ECOLOGICAL INFORMATION This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal use conditions. The environmental toxicity of this product has not been evaluated. Environmental Fate: No environmental fate data exists for the product. Persistence and Degradability: The persistence and degradability of this product has not been determined. Bioaccumulation Potential: The bioaccumulation potential of this product has not been determined. Mobility: The mobility of this product (in soil and water) has not been determined. SECTION 13: DISPOSAL CONSIDERATIONS Page 900 of 1069 Page 900 of 1069 Page 900 of 1069 Page 900 of 1069 ---PAGE BREAK--- Hard Surface Cleaner MSDS D-122 (Rev. 9) The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672 USA Hard Surface Cleaner 04/14/2014 Page 4 of 4 Waste Number and Description: Not applicable, not regulated. Disposal Considerations: Disposal of products: This product is not a RCRA hazardous waste and can be disposed of in accordance with federal, state and local regulations. Disposal of packages: Not applicable. Additional information: Observe all federal, state and local regulations when storing or disposing of this substance SECTION 14: TRANSPORT INFORMATION DOT Transportation of Dangerous Goods – Ground DOT Hazard Class: Not regulated Packing Group: Not applicable DOT Proper Shipping Name: Not applicable Shipping Label Information: Not applicable UN/NA Number: Not applicable International Air Transportation (ICAO/IATA) ICAO/IATA Hazard Class: Not regulated ICAO/IATA Proper Shipping Name: Not applicable Water Transportation (IMO/IMDG) IMO/IMDG Hazard Class: Not regulated IMO/IMDG Proper Shipping Name: Not applicable SECTION 15: REGULATORY INFORMATION Occupational Safety and Health Act: Hazard Communication Rule, 29 CFR 1910.1200: The Occupational Safety and Health Administration (OSHA) require Material Safety Data Sheets to provide information about any hazard that may be associated with the product and make this information available in the workplace. Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this MSDS may contain health hazard information not relevant to consumer use. United States Regulatory Information: Consumer Product Safety Commission (CPSC): This product is regulated as a consumer product under CPSC. TSCA: All components of this product are listed on U.S. Toxic Substances Control Act (TSCA) chemical substance inventory. EPA CERCLA/SARA TITLE III Superfund Amendment and Reauthorization Act: This product contains no CERCLA/SARA Title III materials CERCLA/SARA Section 302 EHS: Not available CERCLA/SARA 311/312: This product contains no hazardous chemicals reportable under Sections 311/312. This product contains no hazardous chemicals reportable under Section 304. CERCLA/SARA 313: Not applicable - Consumer product State Regulations California Proposition 65: This product does not contain substances listed under California Proposition 65. Canada Regulatory Information: Canadian Environmental Protection Act: Some components of this product are not listed on the Canadian Domestic Substances List (DSL) nor the NDSL. Health Canada: This product is not regulated by Health Canada. Worker Hazardous Materials Information System: WHMIS Classification: D2B (Irritating). SECTION 16: OTHER INFORMATION DISCLAIMER: The information contained herein is provided in good faith and is believed to be correct as of the date hereof. However, The Dial Corporation makes no representation as to the comprehensiveness or accuracy of the information. It is expected that individuals receiving the information will exercise their independent judgment in determining its appropriateness for a particular purpose. Accordingly, The Dial Corporation will not be responsible for damages of any kind resulting from the use of or reliance upon such information. No representations, or warranties, either expressed or implied of merchantability, fitness for a particular purpose or of any other nature is made hereunder with respect to the information set forth herein or to the product to which the information refers. NFPA RATINGS (Scale 0-4, where 4=high degree of hazard): HEALTH=1 FLAMMABILITY=1 REACTIVITY=0 HMIS RATINGS (Scale 0-4, where 4=high degree of hazard): HEALTH=2 FLAMMABILITY=1 REACTIVITY=0 Creation Date: 07/14/2006 Supercedes: Rev. 8, 05/15/2012 Revision: Updated Formula I.D. Numbers. Page 901 of 1069 Page 901 of 1069 Page 901 of 1069 Page 901 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 1 / 9 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN Product code : 200000033036 : B02947300001 Manufacturer or supplier's details Company : Colgate-Palmolive Co 300 Park Avenue New York, NY 10022 Telephone : US: Consumer Affairs - 1-[PHONE REDACTED] Emergency telephone number : For emergencies involving spill, leak, fire, exposure or acci- dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887. Medical Emergency (24HR): For MEDICAL EMERGENCIES involving this product call: (888) 489-3861 Recommended use of the chemical and restrictions on use Recommended use : A formulated liquid hand soap SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance liquid Colour orange GHS Classification Skin irritation : Category 2 Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal word : Warning Page 902 of 1069 Page 902 of 1069 Page 902 of 1069 Page 902 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 2 / 9 Hazard statements : H315 Causes skin irritation. H319 Causes serious eye irritation. Precautionary statements : Prevention: P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P362 Take off contaminated clothing and wash before reuse. Potential Health Effects Inhalation : No adverse effects due to inhalation are expected. Skin : Prolonged or repeated skin contact may cause irritation. Eyes : Causes eye irritation on direct contact. Ingestion : May be harmful if swallowed in large quantities. Aggravated Medical Condi- tion : None known. Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration Page 903 of 1069 Page 903 of 1069 Page 903 of 1069 Page 903 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 3 / 9 CETRIMONIUM CHLORIDE 112-02-7 1 - < 5 GLYCERIN 56-81-5 1 - < 5 SECTION 4. FIRST AID MEASURES If inhaled : Remove victim to fresh air. Get medical attention, if symp- toms persist. In case of skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention. In case of eye contact : Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. If swallowed : Drink 8 ounces of clear water. Get medical attention. Most important and effects, both acute and delayed : Causes skin irritation. Causes serious eye irritation. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car- bon dioxide. Hazardous combustion prod- ucts : No hazardous combustion products are known Special protective equipment for firefighters : Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protection recommended in Section 8 of the SDS. Methods and materials for containment and cleaning up : Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa- ter. SECTION 7. HANDLING AND STORAGE Conditions for safe storage : Store at controlled room temperature at 20-25°C (68-77°F). Page 904 of 1069 Page 904 of 1069 Page 904 of 1069 Page 904 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 4 / 9 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis GLYCERIN 56-81-5 TWA (mist, respirable fraction) 5 mg/m3 OSHA Z-1 TWA (mist, total dust) 15 mg/m3 OSHA Z-1 TWA (Mist - total dust) 10 mg/m3 OSHA P0 TWA (Mist - respirable fraction) 5 mg/m3 OSHA P0 Engineering measures : In an industrial work environment, no special precautions or control measures are required. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally re- quired. Protective measures : In an industrial work environment, if a splash is likely, chemi- cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary. Hygiene measures : In an industrial work environment, avoid eye and prolonged skin contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : orange Flash point : > 200 °F Density : 1.01 g/cm3 SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reac- tions : Hazardous polymerisation does not occur. Incompatible materials : Strong oxidizing agents Page 905 of 1069 Page 905 of 1069 Page 905 of 1069 Page 905 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 5 / 9 Hazardous decomposition products : None known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: CETRIMONIUM CHLORIDE: Acute oral toxicity : LD50 (Rat): 450 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : Remarks: No data available Acute dermal toxicity : LD50 (Rabbit): 429 mg/kg Method: OECD Test Guideline 402 GLYCERIN: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : Remarks: No data available Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Method: No information available. Skin corrosion/irritation Causes skin irritation. Components: CETRIMONIUM CHLORIDE: Result: Corrosive after 1 to 4 hours of exposure GLYCERIN: Result: No skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Components: CETRIMONIUM CHLORIDE: Result: Irreversible effects on the eye Page 906 of 1069 Page 906 of 1069 Page 906 of 1069 Page 906 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 6 / 9 GLYCERIN: Remarks: No data available Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: CETRIMONIUM CHLORIDE: Exposure routes: Inhalation Result: Does not cause respiratory sensitisation. Exposure routes: Dermal Result: Does not cause skin sensitisation. GLYCERIN: Exposure routes: Inhalation Remarks: No data available Exposure routes: Dermal Result: Does not cause skin sensitisation. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS. Page 907 of 1069 Page 907 of 1069 Page 907 of 1069 Page 907 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 7 / 9 SECTION 12. ECOLOGICAL INFORMATION The product has not been tested as a whole for environmental toxicity. However, environmental infor- mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua- tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients surfactants are biode- gradable) or testing conducted on the final product This product is biodegradable). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state envi- ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground. SECTION 14. TRANSPORT INFORMATION DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. IMDG : Not regulated. International Regulation Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) HYDROGEN PEROXIDE 7722-84-1 1000 * Page 908 of 1069 Page 908 of 1069 Page 908 of 1069 Page 908 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 8 / 9 Calculated RQ exceeds reasonably attainable upper limit. SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermedi- ate or Final VOC's (40 CFR 60.489): GLYCERIN 56-81-5 Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know GLYCERIN 56-81-5 HYDROGEN PEROXIDE 7722-84-1 Right To Know WATER Water GLYCERIN 56-81-5 New Jersey Right To Know WATER Water CETRIMONIUM CHLORIDE 112-02-7 GLYCERIN 56-81-5 LAURAMIDOPROPYLDIMETHYLAMINE OXIDE 61792-31-2 COCAMIDE MEA 68140-00-1 California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. Page 909 of 1069 Page 909 of 1069 Page 909 of 1069 Page 909 of 1069 ---PAGE BREAK--- NA SOFTSOAP ANTIBACTERIAL LIQUID HAND SOAP CRISP CLEAN This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 SDS Number: 660000000407 Revision Date: 05/22/2015 9 / 9 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im- plied, as to the accuracy, reliability or completeness of the information and assumes no re- sponsibility for injury, damage or loss resulting from the use of the material. Flammability Health Instability 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 910 of 1069 Page 910 of 1069 Page 910 of 1069 Page 910 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 1 / 60 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Commercial Product Name : Special Stains Trich.III Green Staining Mat.-No./ Genisys-No. : 05279372001 1.2 Relevant identified uses of the substance or mixture and uses advised against Recommended restrictions on use : For professional users only. 1.3 Details of the supplier of the safety data sheet Company : Ventana Medical Systems 1910 E. Innovation Park Drive 85755 Tucson AZ E-mail address : Telephone : 1-[PHONE REDACTED] or [PHONE REDACTED] Telefax : Responsible Department : In case of emergencies: : CHEMTREC 1-[PHONE REDACTED] (U.S. or Canada) 1-[PHONE REDACTED] (International) : 2. Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Corrosive to metals, Category 1 H290: May be corrosive to metals. Acute toxicity, Category 4 H302: Harmful if swallowed. Skin corrosion, Category 1A H314: Causes severe skin burns and eye damage. Skin sensitization, Category 1 H317: May cause an allergic skin reaction. Germ cell mutagenicity, Category 2 H341: Suspected of causing genetic defects. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Specific target organ toxicity - single exposure, Category 2 H371: May cause damage to organs. Classification (67/548/EEC, 1999/45/EC) Sensitising R43: May cause sensitization by skin contact. Mutagenic Category 3 R40: Limited evidence of a carcinogenic effect. Highly flammable R11: Highly flammable. Explosive R 1: Explosive when dry. Toxic R39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Page 911 of 1069 Page 911 of 1069 Page 911 of 1069 Page 911 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 2 / 60 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal word : Danger Hazard statements : H225 Highly flammable liquid and vapour. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H371 May cause damage to organs. Precautionary statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 Keep container closed. P234 Keep only in original container. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable Page 912 of 1069 Page 912 of 1069 Page 912 of 1069 Page 912 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 3 / 60 for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/ physician. P310 Immediately call a POISON CENTER or doctor/ physician. P321 Specific treatment (see supplemental first aid instructions on this label). P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P390 Absorb spillage to prevent material damage. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P406 Store in corrosive resistant stainless steel container with a resistant inner liner. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. 2.3 Other hazards No information available. 3. Composition/information on ingredients 3.2 Mixtures Bouin's Solution Classification (REGULATION (EC) No 1272/2008) Skin corrosion, Category 1A H314: Causes severe skin burns and eye damage. Skin sensitization, Category 1 H317: May cause an allergic skin reaction. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Classification (67/548/EEC, 1999/45/EC) Corrosive R35: Causes severe burns. Carcinogenic Category 3 R40: Limited evidence of a carcinogenic effect. Sensitising R43: May cause sensitization by skin contact. R 1: Explosive when dry. Hazardous components Chemical Name CAS-No. Classification Classification Concentration Page 913 of 1069 Page 913 of 1069 Page 913 of 1069 Page 913 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 4 / 60 EC-No. Registration number (67/548/EEC) (REGULATION (EC) No 1272/2008) acetic acid 64-19-7 200-580-7 R10 C; R35 Flam. Liq. 3; H226 Skin Corr. 1A; H314 5 - < 10 formaldehyde 50-00-0 200-001-8 Carc.Cat.3; R40 T; R23/24/25 C; R34 R43 Acute Tox. 3; H301 Acute Tox. 3; H331 Acute Tox. 3; H311 Skin Corr. 1B; H314 Skin Sens. 1; H317 Carc. 2; H351 3 - < 5 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. Hematoxylin A Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Acute toxicity, Category 4 H302: Harmful if swallowed. Specific target organ toxicity - single exposure, Category 2 H371: May cause damage to organs. Classification (67/548/EEC, 1999/45/EC) Highly flammable R11: Highly flammable. Harmful R20/21/22, R68/20/21/22: Harmful by inhalation, in contact with skin and if swallowed., Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification (67/548/EEC) Classification (REGULATION (EC) No 1272/2008) Concentration ethanol 64-17-5 200-578-6 F; R11 Flam. Liq. 2; H225 50 - 100 methanol 67-56-1 200-659-6 F; R11 T; R23/24/25- R39/23/24/25 Flam. Liq. 2; H225 Acute Tox. 3; H301 Acute Tox. 3; H331 Acute Tox. 3; H311 STOT SE 1; H370 3 - < 10 propan-2-ol 67-63-0 200-661-7 F; R11 Xi; R36 R67 Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336 < 10 Page 914 of 1069 Page 914 of 1069 Page 914 of 1069 Page 914 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 5 / 60 haematoxylin 517-28-2 208-237-3 Xn; Xn; R22- R36/37/38 Acute Tox. 4; H302 Skin Irrit. 2; H315 Eye Irrit. 2; H319 STOT SE 3; H335 < 10 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. Hematoxylin B Classification (REGULATION (EC) No 1272/2008) Skin corrosion, Category 1A H314: Causes severe skin burns and eye damage. Classification (67/548/EEC, 1999/45/EC) Corrosive R35: Causes severe burns. Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification (67/548/EEC) Classification (REGULATION (EC) No 1272/2008) Concentration Iron(III)-chloride hexahydrate 10025-77-1 231-729-4 Xn; Xn; R22 Xi; Xi; R38-R41 Acute Tox. 4; H302 Skin Irrit. 2; H315 Eye Dam. 1; H318 < 5 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. Enhancer Classification (REGULATION (EC) No 1272/2008) Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Classification (67/548/EEC, 1999/45/EC) Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. Remarks : No dangerous ingredients according to Regulation (EC) No. 1907/2006 Red Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 3 H226: Flammable liquid and vapour. Skin corrosion, Category 1A H314: Causes severe skin burns and eye damage. Page 915 of 1069 Page 915 of 1069 Page 915 of 1069 Page 915 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 6 / 60 Classification (67/548/EEC, 1999/45/EC) Corrosive R35: Causes severe burns. Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification (67/548/EEC) Classification (REGULATION (EC) No 1272/2008) Concentration ethanol 64-17-5 200-578-6 F; R11 Flam. Liq. 2; H225 < 10 acetic acid 64-19-7 200-580-7 R10 C; R35 Flam. Liq. 3; H226 Skin Corr. 1A; H314 1 - < 5 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. Red 2 Classification (REGULATION (EC) No 1272/2008) Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Classification (67/548/EEC, 1999/45/EC) Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification (67/548/EEC) Classification (REGULATION (EC) No 1272/2008) Concentration acetic acid 64-19-7 200-580-7 R10 C; R35 Flam. Liq. 3; H226 Skin Corr. 1A; H314 1 - < 3 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. Mordant Classification (REGULATION (EC) No 1272/2008) Skin corrosion, Category 1A H314: Causes severe skin burns and eye damage. Classification (67/548/EEC, 1999/45/EC) Corrosive R35: Causes severe burns. Hazardous components Page 916 of 1069 Page 916 of 1069 Page 916 of 1069 Page 916 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 7 / 60 Chemical Name CAS-No. EC-No. Registration number Classification (67/548/EEC) Classification (REGULATION (EC) No 1272/2008) Concentration Phosphormolybdänsäur e 51429-74-4 C; C; R34 Skin Corr. 1B; H314 1 - < 5 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. GREEN FOR TRICHROME Classification (REGULATION (EC) No 1272/2008) Corrosive to metals, Category 1 H290: May be corrosive to metals. Skin corrosion, Category 1A H314: Causes severe skin burns and eye damage. Classification (67/548/EEC, 1999/45/EC) Corrosive R35: Causes severe burns. Remarks : No dangerous ingredients according to Regulation (EC) No. 1907/2006 Green 2 Classification (REGULATION (EC) No 1272/2008) Germ cell mutagenicity, Category 2 H341: Suspected of causing genetic defects. Classification (67/548/EEC, 1999/45/EC) Harmful R68: Possible risk of irreversible effects. Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification (67/548/EEC) Classification (REGULATION (EC) No 1272/2008) Concentration hydrogen chloride 7647-01-0 231-595-7 C; R34 Xi; R37 Met. Corr. 1; H290 Skin Corr. 1B; H314 STOT SE 3; H335 < 5 dihydrogen (ethyl)[4-[4- [ethyl(3- sulphonatobenzyl)amin o](4-hydroxy-2- ene]cyclohexa-2,5- dien-1-ylidene](3- sulphonatobenzyl)amm onium, disodium salt 2353-45-9 219-091-5 Xn; Xn; R68 Muta. 2; H341 1 - < 10 For the full text of the R-phrases mentioned in this Section, see Section 16. Page 917 of 1069 Page 917 of 1069 Page 917 of 1069 Page 917 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 8 / 60 For the full text of the H-Statements mentioned in this Section, see Section 16. 4. First aid measures 4.1 Description of first aid measures General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : Move to fresh air. If unconscious place in recovery position and seek medical advice. If persist, call a physician. In case of skin contact : Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Clean mouth with water and drink afterwards plenty of water. Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If persist, call a physician. Take victim immediately to hospital. Rinse mouth with water. 4.2 Most important and effects, both acute and delayed : No information available. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine. Page 918 of 1069 Page 918 of 1069 Page 918 of 1069 Page 918 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 9 / 60 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. 5.3 Advice for firefighters Special protective equipment for firefighters : Wear self contained breathing apparatus for fire fighting if necessary. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Refer to protective measures listed in sections 7 and 8. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.2 Environmental precautions Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Page 919 of 1069 Page 919 of 1069 Page 919 of 1069 Page 919 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 10 / 60 6.4 Reference to other sections Treat recovered material as described in the section "Disposal considerations". 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Avoid formation of aerosol. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. To prevent leaks or spillages from spreading, provide a suitable liquid retention system. Advice on protection against fire and explosion : Do not spray on a naked flame or any incandescent material. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : No smoking. Keep container closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Further information on storage conditions : See label or package insert Other data : No decomposition if stored and applied as directed. 7.3 Specific end use(s) Specific use(s) : Laboratory chemicals Page 920 of 1069 Page 920 of 1069 Page 920 of 1069 Page 920 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 11 / 60 8. Exposure controls/personal protection Exposure Guidelines Bouin's Solution Components with workplace control parameters Components CAS-No. Value Control parameters Source acetic acid 64-19-7 TWA 10 ppm USA. ACGIH Threshold Limit Values (TLV) STEL 15 ppm USA. ACGIH Threshold Limit Values (TLV) TWA 10 ppm 25 mg/m3 USA. NIOSH Recommended Exposure Limits ST 15 ppm 37 mg/m3 USA. NIOSH Recommended Exposure Limits TWA 10 ppm 25 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 10 ppm 25 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 formaldehyde 50-00-0 C 0.3 ppm USA. ACGIH Threshold Limit Values (TLV) TWA 0.016 ppm USA. NIOSH Recommended Exposure Limits C 0.1 ppm USA. NIOSH Recommended Exposure Limits TWA 0.016 ppm USA. NIOSH Recommended Exposure Limits C 0.1 ppm USA. NIOSH Recommended Exposure Limits Hematoxylin A Components with workplace control parameters Components CAS-No. Value Control parameters Source ethanol 64-17-5 TWA 1,000 ppm USA. ACGIH Threshold Limit Values (TLV) Page 921 of 1069 Page 921 of 1069 Page 921 of 1069 Page 921 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 12 / 60 TWA 1,000 ppm 1,900 mg/m3 USA. NIOSH Recommended Exposure Limits TWA 1,000 ppm 1,900 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 1,000 ppm 1,900 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 methanol 67-56-1 TWA 200 ppm USA. ACGIH Threshold Limit Values (TLV) TWA 200 ppm USA. ACGIH Threshold Limit Values (TLV) STEL 250 ppm USA. ACGIH Threshold Limit Values (TLV) STEL 250 ppm USA. ACGIH Threshold Limit Values (TLV) TWA 200 ppm 260 mg/m3 USA. NIOSH Recommended Exposure Limits TWA 200 ppm 260 mg/m3 USA. NIOSH Recommended Exposure Limits ST 250 ppm 325 mg/m3 USA. NIOSH Recommended Exposure Limits ST 250 ppm 325 mg/m3 USA. NIOSH Recommended Exposure Limits TWA 200 ppm 260 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 200 ppm 260 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 200 ppm 260 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 TWA 200 ppm 260 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 STEL 250 ppm 325 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 STEL 250 ppm 325 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Page 922 of 1069 Page 922 of 1069 Page 922 of 1069 Page 922 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 13 / 60 Contaminants - 1910.1000 propan-2-ol 67-63-0 TWA 200 ppm USA. ACGIH Threshold Limit Values (TLV) STEL 400 ppm USA. ACGIH Threshold Limit Values (TLV) TWA 400 ppm 980 mg/m3 USA. NIOSH Recommended Exposure Limits ST 500 ppm 1,225 mg/m3 USA. NIOSH Recommended Exposure Limits TWA 400 ppm 980 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 400 ppm 980 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 STEL 500 ppm 1,225 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 Hematoxylin B Contains no substances with occupational exposure limit values. Enhancer Contains no substances with occupational exposure limit values. Red Components with workplace control parameters Components CAS-No. Value Control parameters Source ethanol 64-17-5 TWA 1,000 ppm USA. ACGIH Threshold Limit Values (TLV) TWA 1,000 ppm 1,900 mg/m3 USA. NIOSH Recommended Exposure Limits TWA 1,000 ppm 1,900 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 1,000 ppm 1,900 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 acetic acid 64-19-7 TWA 10 ppm USA. ACGIH Threshold Page 923 of 1069 Page 923 of 1069 Page 923 of 1069 Page 923 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 14 / 60 Limit Values (TLV) STEL 15 ppm USA. ACGIH Threshold Limit Values (TLV) TWA 10 ppm 25 mg/m3 USA. NIOSH Recommended Exposure Limits ST 15 ppm 37 mg/m3 USA. NIOSH Recommended Exposure Limits TWA 10 ppm 25 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 10 ppm 25 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 Red 2 Components with workplace control parameters Components CAS-No. Value Control parameters Source acetic acid 64-19-7 TWA 10 ppm USA. ACGIH Threshold Limit Values (TLV) STEL 15 ppm USA. ACGIH Threshold Limit Values (TLV) TWA 10 ppm 25 mg/m3 USA. NIOSH Recommended Exposure Limits ST 15 ppm 37 mg/m3 USA. NIOSH Recommended Exposure Limits TWA 10 ppm 25 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 10 ppm 25 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 Mordant Contains no substances with occupational exposure limit values. GREEN FOR TRICHROME Contains no substances with occupational exposure limit values. Green 2 Page 924 of 1069 Page 924 of 1069 Page 924 of 1069 Page 924 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 15 / 60 Components with workplace control parameters Components CAS-No. Value Control parameters Source hydrogen chloride 7647-01-0 C 2 ppm USA. ACGIH Threshold Limit Values (TLV) C 5 ppm 7 mg/m3 USA. NIOSH Recommended Exposure Limits C 5 ppm 7 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants C 5 ppm 7 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 Personal protective equipment Eye protection : Eye wash bottle with pure water fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Hand protection : Protective gloves Skin and body protection : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Respiratory protection : In the case of vapour formation use a respirator with an approved filter. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Bouin's Solution Appearance : liquid Colour : yellow Odour : formaldehyde-like Page 925 of 1069 Page 925 of 1069 Page 925 of 1069 Page 925 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 16 / 60 pH : 1.21 Melting point/range : no data available Boiling point/boiling range : no data available Flash point : not applicable Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 1.031 g/cm3 Water solubility : completely miscible Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : Hazardous decomposition products formed under fire conditions. Viscosity, dynamic : no data available Explosive properties : Explosive when dry. Oxidizing properties : The substance or mixture is not classified as oxidizing. Hematoxylin A Appearance : liquid Colour : yellow-orange Odour : alcohol-like pH : 5.36 Melting point/range : no data available Boiling point/boiling range : 78 °C Flash point : ca. 12.5 °C Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 0.793 g/cm3 Water solubility : completely miscible Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : Hazardous decomposition products formed under fire conditions. Viscosity, dynamic : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Hematoxylin B Page 926 of 1069 Page 926 of 1069 Page 926 of 1069 Page 926 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 17 / 60 Appearance : liquid Colour : yellow-orange Odour : very faint pH : 1.5 - 1.9 Melting point/range : no data available Boiling point/boiling range : no data available Flash point : not applicable Flammability (solid, gas) : The product is not flammable. Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Water solubility : completely miscible Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : no data available Viscosity, dynamic : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Enhancer Appearance : liquid Colour : colourless Odour : none pH : acidic Melting point/range : no data available Boiling point/boiling range : no data available Flash point : not applicable Flammability (solid, gas) : The product is not flammable. Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Water solubility : completely miscible Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : no data available Viscosity, dynamic : no data available Page 927 of 1069 Page 927 of 1069 Page 927 of 1069 Page 927 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 18 / 60 Oxidizing properties : The substance or mixture is not classified as oxidizing. Red Appearance : liquid Colour : red Odour : slightvinegar-like pH : 2 - 4 Melting point/range : no data available Boiling point/boiling range : no data available Flash point : ca. 57 °C Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Water solubility : completely miscible Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : no data available Viscosity, dynamic : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Red 2 Appearance : liquid Colour : red Odour : vinegar-like pH : 2.48 Melting point/range : no data available Boiling point/boiling range : no data available Flash point : not applicable Flammability (solid, gas) : The product is not flammable. Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 1.0048 g/cm3 Water solubility : completely miscible Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : Hazardous decomposition products formed under fire Page 928 of 1069 Page 928 of 1069 Page 928 of 1069 Page 928 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 19 / 60 conditions. Viscosity, dynamic : no data available Mordant Appearance : liquid Colour : colourless Odour : none pH : 1.86 Melting point/range : no data available Boiling point/boiling range : no data available Flash point : not applicable Flammability (solid, gas) : The product is not flammable. Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 1.001 g/cm3 Water solubility : completely miscible Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : Hazardous decomposition products formed under fire conditions. Viscosity, dynamic : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. GREEN FOR TRICHROME Appearance : liquid Colour : green Odour : slight pH : 1.4 Melting point/range : no data available Boiling point/boiling range : no data available Flash point : not applicable Flammability (solid, gas) : The product is not flammable. Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 0.9884 g/cm3 Water solubility : completely miscible Page 929 of 1069 Page 929 of 1069 Page 929 of 1069 Page 929 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 20 / 60 Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : Hazardous decomposition products formed under fire conditions. Viscosity, dynamic : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Green 2 Appearance : liquid Colour : green Odour : none pH : acidic Melting point/range : no data available Boiling point/boiling range : no data available Flash point : not applicable Flammability (solid, gas) : The product is not flammable. Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Water solubility : completely miscible Partition coefficient: n- octanol/water : no data available Ignition temperature : no data available Thermal decomposition : no data available Viscosity, dynamic : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. 9.2 Other information Bouin's Solution Conductivity : no data available Oxidising potential : no data available Surface tension : no data available Hematoxylin A Conductivity : no data available Oxidising potential : no data available Surface tension : no data available Hematoxylin B Conductivity : no data available Oxidising potential : no data available Page 930 of 1069 Page 930 of 1069 Page 930 of 1069 Page 930 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 21 / 60 Surface tension : no data available Enhancer Conductivity : no data available Oxidising potential : no data available Surface tension : no data available Red Conductivity : no data available Oxidising potential : no data available Surface tension : no data available Red 2 Conductivity : no data available Oxidising potential : no data available Surface tension : no data available Mordant Conductivity : no data available Oxidising potential : no data available Surface tension : no data available GREEN FOR TRICHROME Conductivity : no data available Oxidising potential : no data available Surface tension : no data available Green 2 Conductivity : no data available Oxidising potential : no data available Surface tension : no data available 10. Stability and reactivity 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : Do not allow to dry. Explosive when dry. Reacts with the following substances: Oxidizing agents Reducing agents Amines Alcohol Acids Bases Page 931 of 1069 Page 931 of 1069 Page 931 of 1069 Page 931 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 22 / 60 : Further information: No decomposition if stored and applied as directed. : Vapours may form explosive mixture with air. 10.4 Conditions to avoid Conditions to avoid : Do not allow evaporation to dryness. Heat, flames and sparks. 10.5 Incompatible materials Materials to avoid : Alcohol Acids Bases Oxidizing agents Amines Reducing agents 10.6 Hazardous decomposition products Hazardous decomposition products : nitrogen oxides (NOx) Sulphur oxides Carbon oxides Oxides of phosphorus Gaseous hydrogen chloride (HCl). 11. Toxicological information 11.1 Information on toxicological effects Bouin's Solution Components: acetic acid : Acute oral toxicity : LD50 Oral: 3,310 mg/kg, rat Acute dermal toxicity : LD50 Dermal: 1016 µl/kg, rabbit Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : Result: Causes severe burns., Extremely corrosive and destructive to tissue. Serious eye damage/eye irritation : May cause irreversible eye damage. Respiratory or skin sensitization : Result: no data available STOT - single exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. Aspiration toxicity : no data available Page 932 of 1069 Page 932 of 1069 Page 932 of 1069 Page 932 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 23 / 60 Further information : no data available formaldehyde : Acute oral toxicity : LD50: 100 mg/kg, rat : LD50: 42 mg/kg, mouse Acute inhalation toxicity : LC50: 203 mg/l, rat : LC50: 0.155 mg/l, 2 h, mouse, Acute dermal toxicity : LD50: 270 mg/kg, rabbit Acute toxicity (other routes of administration) : LD50: 87 mg/kg, rat : LD50: 300 mg/kg, mouse : LD50: 420 mg/kg, rat Skin corrosion/irritation : Result: Causes burns., Extremely corrosive and destructive to tissue. Serious eye damage/eye irritation : May cause irreversible eye damage. Respiratory or skin sensitization : Classification: May cause sensitization by skin contact., Causes sensitization. Aspiration toxicity : no data available Further information : no data available Hematoxylin A Components: ethanol : Acute oral toxicity : LD50: 7,000 mg/kg, rat : LD50: 3,450 mg/kg, mouse Acute inhalation toxicity : LC50: 20000 ppm, 10 h, rat, : LC50: 39 g/m3, 4 h, mouse, Acute dermal toxicity : no data available Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : This information is not available. Serious eye damage/eye irritation : This information is not available. Respiratory or skin sensitization : Result: no data available STOT - single exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. Page 933 of 1069 Page 933 of 1069 Page 933 of 1069 Page 933 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 24 / 60 Aspiration toxicity : no data available Further information : no data available methanol : Acute oral toxicity : Acute toxicity estimate: 100 mg/kg, Expert judgement : LD50 Oral: 7,300 mg/kg, mouse : LD50 Oral: 5,600 mg/kg, rat Acute inhalation toxicity : Acute toxicity estimate: 3 mg/l, vapour, Expert judgement : LC50: 85.26 mg/l, 4 h, rat, : LC50: 64000 ppm, 4 h, rat, Acute dermal toxicity : Acute toxicity estimate: 300 mg/kg, Expert judgement : LD50 Dermal: 15,800 mg/kg, rabbit Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : The product may be absorbed through the skin., May irritate skin. Serious eye damage/eye irritation : Contact with eyes may cause irritation. Respiratory or skin sensitization : guinea pig, Did not cause sensitization on laboratory animals. Germ cell mutagenicity Genotoxicity in vitro : Ames test, Result: negative Genotoxicity in vivo : Result: negative STOT - single exposure : Assessment: Causes damage to organs. STOT - repeated exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration toxicity : No aspiration toxicity classification Further information : Solvents may degrease the skin. propan-2-ol : Acute oral toxicity : LD50 Oral: 4,570 mg/kg, rat : LD50 Oral: 3,600 mg/kg, mouse : LD50 Oral: 6,410 mg/kg, rabbit Acute inhalation toxicity : LC50: 30 mg/l, 16000 ppm, 4 h, rat, : LC50: 53 mg/l, mouse Acute dermal toxicity : LD50 Dermal: 13,400 mg/kg, rabbit Page 934 of 1069 Page 934 of 1069 Page 934 of 1069 Page 934 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 25 / 60 Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : May cause skin irritation in susceptible persons. Serious eye damage/eye irritation : Result: Irritating to eyes., May cause irreversible eye damage. STOT - single exposure : Assessment: May cause drowsiness or dizziness. Aspiration toxicity : no data available Further information : no data available haematoxylin : Acute oral toxicity : LD50 Oral: 400 mg/kg, rat Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : Result: Irritating to skin., May cause skin irritation in susceptible persons. Serious eye damage/eye irritation : Result: Irritating to eyes., May cause irreversible eye damage. Respiratory or skin sensitization : Result: no data available STOT - single exposure : Exposure routes: Inhalation Assessment: May cause respiratory irritation. STOT - repeated exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration toxicity : no data available Further information : no data available Hematoxylin B Components: Iron(III)-chloride hexahydrate : Acute oral toxicity : LD50 Oral: 316 mg/kg, rat Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : rabbit, Result: Irritating to skin., May cause skin irritation in susceptible persons. Serious eye damage/eye irritation : rabbit, Result: Risk of serious damage to eyes., May cause irreversible eye damage. Page 935 of 1069 Page 935 of 1069 Page 935 of 1069 Page 935 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 26 / 60 Respiratory or skin sensitization : Result: no data available Germ cell mutagenicity Assessment : Not mutagenic in Ames Test. STOT - single exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. STOT - repeated exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration toxicity : no data available Further information : no data available Enhancer No ingredients are hazardous according to OHSA criteria. Red Components: ethanol : Acute oral toxicity : LD50: 7,000 mg/kg, rat : LD50: 3,450 mg/kg, mouse Acute inhalation toxicity : LC50: 20000 ppm, 10 h, rat, : LC50: 39 g/m3, 4 h, mouse, Acute dermal toxicity : no data available Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : This information is not available. Serious eye damage/eye irritation : This information is not available. Respiratory or skin sensitization : Result: no data available STOT - single exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. Aspiration toxicity : no data available Further information : no data available acetic acid : Acute oral toxicity : LD50 Oral: 3,310 mg/kg, rat Acute dermal toxicity : LD50 Dermal: 1016 µl/kg, rabbit Acute toxicity (other routes of : no data available Page 936 of 1069 Page 936 of 1069 Page 936 of 1069 Page 936 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 27 / 60 administration) Skin corrosion/irritation : Result: Causes severe burns., Extremely corrosive and destructive to tissue. Serious eye damage/eye irritation : May cause irreversible eye damage. Respiratory or skin sensitization : Result: no data available STOT - single exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. Aspiration toxicity : no data available Further information : no data available Red 2 Components: acetic acid : Acute oral toxicity : LD50 Oral: 3,310 mg/kg, rat Acute dermal toxicity : LD50 Dermal: 1016 µl/kg, rabbit Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : Result: Causes severe burns., Extremely corrosive and destructive to tissue. Serious eye damage/eye irritation : May cause irreversible eye damage. Respiratory or skin sensitization : Result: no data available STOT - single exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. Aspiration toxicity : no data available Further information : no data available Mordant Components: Phosphormolybdänsäure : Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : Result: Causes burns., Extremely corrosive and destructive to Page 937 of 1069 Page 937 of 1069 Page 937 of 1069 Page 937 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 28 / 60 tissue. Serious eye damage/eye irritation : May cause irreversible eye damage. Respiratory or skin sensitization : Result: no data available STOT - single exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. Aspiration toxicity : no data available Further information : no data available GREEN FOR TRICHROME No ingredients are hazardous according to OHSA criteria. Green 2 Components: hydrogen chloride : Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : Result: Causes burns., Extremely corrosive and destructive to tissue. Serious eye damage/eye irritation : Result: Risk of serious damage to eyes., May cause irreversible eye damage. STOT - single exposure : Assessment: May cause respiratory irritation. STOT - repeated exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration toxicity : no data available Further information : no data available dihydrogen (ethyl)[4-[4-[ethyl(3-sulphonatobenzyl)amino](4-hydroxy-2- : Acute oral toxicity : LD50 Oral: > 2,001 mg/kg, rat Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Acute toxicity (other routes of administration) : no data available Skin corrosion/irritation : This information is not available. Page 938 of 1069 Page 938 of 1069 Page 938 of 1069 Page 938 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 29 / 60 Serious eye damage/eye irritation : This information is not available. Respiratory or skin sensitization : Result: no data available Germ cell mutagenicity Assessment : In vitro tests showed mutagenic effects STOT - single exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. STOT - repeated exposure : Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration toxicity : no data available Further information : no data available 12. Ecological information 12.1 Toxicity Bouin's Solution Components: acetic acid : Toxicity to fish : LC50: 410 mg/l, 48 h, Leuciscus idus (Golden orfe) Toxicity to daphnia and other aquatic invertebrates : EC50: 95 mg/l, 24 h, Daphnia magna (Water flea) Toxicity to algae : no data available Toxicity to bacteria : no data available Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available formaldehyde : Toxicity to fish : LC50: 108 mg/l, Leuciscus idus (Golden orfe) : LC50: 50 mg/l, mykiss (rainbow trout) : LC50: 41 mg/l, 96 h, Danio rerio (zebra fish) : LC100: 70 mg/l, mykiss (rainbow trout) Toxicity to daphnia and other aquatic invertebrates : EC50: 42 mg/l, 24 h, Daphnia magna (Water flea), OECD Test Guideline 202 Toxicity to algae : 2.5 mg/l, 168 h, Scenedesmus quadricauda (Green algae) Toxicity to bacteria : EC0: 14 mg/l, 16 h, Pseudomonas putida Page 939 of 1069 Page 939 of 1069 Page 939 of 1069 Page 939 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 30 / 60 Ecotoxicology Assessment Acute aquatic toxicity : This product has no known eco-toxicological effects. Chronic aquatic toxicity : This product has no known eco-toxicological effects. Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available Hematoxylin A Components: ethanol : Toxicity to fish : LC50: 8,000 mg/l, 48 h, Leuciscus idus (Golden orfe) : LC50: 7,100 mg/l, mykiss (rainbow trout), OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50: 5,400 mg/l, 48 h, Daphnia magna (Water flea) Toxicity to algae : EC0: 5,000 mg/l, 7 d, Scenedesmus quadricauda (Green algae) Toxicity to bacteria : EC0: 6,500 mg/l, 16 h, Pseudomonas putida Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available methanol : Toxicity to fish : LC50: 15,400 mg/l, 96 h, Lepomis macrochirus (Bluegill sunfish) : LC50: 8,000 mg/l, 48 h, mykiss (rainbow trout) : LC50: > 10,000 mg/l, Leuciscus idus (Golden orfe) Toxicity to daphnia and other aquatic invertebrates : EC50: > 10,000 mg/l, 48 h, Daphnia magna (Water flea) Toxicity to algae : 8,000 mg/l, 8 d, Scenedesmus quadricauda (Green algae) Toxicity to bacteria : 6,600 mg/l, 16 h, Bacteria Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available propan-2-ol : Toxicity to fish : LC0: 10,000 mg/l, mykiss (rainbow trout), OECD Test Guideline 203 : LC50: 12,250 mg/l, mykiss (rainbow trout), OECD Test Guideline 203 : LC100: 15,000 mg/l, mykiss (rainbow trout), OECD Test Guideline 203 Page 940 of 1069 Page 940 of 1069 Page 940 of 1069 Page 940 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 31 / 60 Toxicity to daphnia and other aquatic invertebrates : EC50: 9,500 mg/l, 24 h, Daphnia magna (Water flea) Toxicity to algae : EC0: 1,800 mg/l, 168 h, Scenedesmus quadricauda (Green algae), OECD Test Guideline 201 Toxicity to bacteria : EC0: 1,050 mg/l, 16 h, Pseudomonas putida Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available haematoxylin : Toxicity to fish : no data available Toxicity to daphnia and other aquatic invertebrates : no data available Toxicity to algae : no data available Toxicity to bacteria : no data available Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available Hematoxylin B Components: Iron(III)-chloride hexahydrate : Toxicity to fish : LC50: 22 mg/l, 96 h, Pimephales promelas (fathead minnow) Toxicity to daphnia and other aquatic invertebrates : EC50: 9.6 mg/l, 48 h, Daphnia magna (Water flea) Toxicity to algae : no data available Toxicity to bacteria : no data available Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available Enhancer No ingredients are hazardous according to OHSA criteria. Red Components: ethanol : Toxicity to fish : LC50: 8,000 mg/l, 48 h, Leuciscus idus (Golden orfe) : LC50: 7,100 mg/l, mykiss (rainbow trout), OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50: 5,400 mg/l, 48 h, Daphnia magna (Water flea) Toxicity to algae : EC0: 5,000 mg/l, 7 d, Scenedesmus quadricauda (Green Page 941 of 1069 Page 941 of 1069 Page 941 of 1069 Page 941 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 32 / 60 algae) Toxicity to bacteria : EC0: 6,500 mg/l, 16 h, Pseudomonas putida Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available acetic acid : Toxicity to fish : LC50: 410 mg/l, 48 h, Leuciscus idus (Golden orfe) Toxicity to daphnia and other aquatic invertebrates : EC50: 95 mg/l, 24 h, Daphnia magna (Water flea) Toxicity to algae : no data available Toxicity to bacteria : no data available Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available Red 2 Components: acetic acid : Toxicity to fish : LC50: 410 mg/l, 48 h, Leuciscus idus (Golden orfe) Toxicity to daphnia and other aquatic invertebrates : EC50: 95 mg/l, 24 h, Daphnia magna (Water flea) Toxicity to algae : no data available Toxicity to bacteria : no data available Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available Mordant Components: Phosphormolybdänsäure : Toxicity to fish : LC100: 25 mg/l, Fish Toxicity to daphnia and other aquatic invertebrates : no data available Toxicity to algae : EC100: 54 mg/l, Scenedesmus quadricauda (Green algae) Toxicity to bacteria : no data available Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available Page 942 of 1069 Page 942 of 1069 Page 942 of 1069 Page 942 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 33 / 60 GREEN FOR TRICHROME No ingredients are hazardous according to OHSA criteria. Green 2 Components: hydrogen chloride : Toxicity to fish : no data available Toxicity to daphnia and other aquatic invertebrates : no data available Toxicity to algae : no data available Toxicity to bacteria : no data available Ecotoxicology Assessment Acute aquatic toxicity : This product has no known eco-toxicological effects. Chronic aquatic toxicity : This product has no known eco-toxicological effects. Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available dihydrogen (ethyl)[4-[4-[ethyl(3-sulphonatobenzyl)amino](4-hydroxy-2- : Toxicity to fish : no data available Toxicity to daphnia and other aquatic invertebrates : no data available Toxicity to algae : no data available Toxicity to bacteria : no data available Ecotoxicology Assessment Toxicity Data on Soil : Not expected to adsorb on soil. Other organisms relevant to the environment : no data available 12.2 Persistence and degradability Bouin's Solution Components: acetic acid : Biodegradability : 71 Exposure time: 5 d formaldehyde : Biodegradability : no data available Hematoxylin A Components: ethanol : Biodegradability : no data available methanol : Page 943 of 1069 Page 943 of 1069 Page 943 of 1069 Page 943 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 34 / 60 Biodegradability : 99 Result: Readily biodegradable., Exposure time: 30 d, OECD Test Guideline 301 propan-2-ol : Biodegradability : 99 Exposure time: 11 d, OECD Test Guideline 302 : 57 Exposure time: 5 d, OECD Test Guideline 302 haematoxylin : Biodegradability : no data available Hematoxylin B Components: Iron(III)-chloride hexahydrate : Biodegradability : no data available Enhancer No ingredients are hazardous according to OHSA criteria. Red Components: ethanol : Biodegradability : no data available acetic acid : Biodegradability : 71 Exposure time: 5 d Red 2 Components: acetic acid : Biodegradability : 71 Exposure time: 5 d Mordant Components: Phosphormolybdänsäure : Biodegradability : no data available GREEN FOR TRICHROME No ingredients are hazardous according to OHSA criteria. Green 2 Components: hydrogen chloride : Biodegradability : no data available dihydrogen (ethyl)[4-[4-[ethyl(3-sulphonatobenzyl)amino](4-hydroxy-2- : Biodegradability : no data available 12.3 Bioaccumulative potential Bouin's Solution Components: acetic acid : Bioaccumulation : no data available formaldehyde : Bioaccumulation : no data available Page 944 of 1069 Page 944 of 1069 Page 944 of 1069 Page 944 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 35 / 60 Hematoxylin A Components: ethanol : Bioaccumulation : no data available methanol : Bioaccumulation : Does not bioaccumulate. propan-2-ol : Bioaccumulation : no data available haematoxylin : Bioaccumulation : no data available Hematoxylin B Components: Iron(III)-chloride hexahydrate : Bioaccumulation : no data available Enhancer No ingredients are hazardous according to OHSA criteria. Red Components: ethanol : Bioaccumulation : no data available acetic acid : Bioaccumulation : no data available Red 2 Components: acetic acid : Bioaccumulation : no data available Mordant Components: Phosphormolybdänsäure : Bioaccumulation : no data available GREEN FOR TRICHROME No ingredients are hazardous according to OHSA criteria. Green 2 Components: hydrogen chloride : Bioaccumulation : no data available Page 945 of 1069 Page 945 of 1069 Page 945 of 1069 Page 945 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 36 / 60 dihydrogen (ethyl)[4-[4-[ethyl(3-sulphonatobenzyl)amino](4-hydroxy-2- : Bioaccumulation : no data available 12.4 Mobility in soil Bouin's Solution Components: acetic acid : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available formaldehyde : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available Hematoxylin A Components: ethanol : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available methanol : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available propan-2-ol : Mobility : no data available Page 946 of 1069 Page 946 of 1069 Page 946 of 1069 Page 946 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 37 / 60 Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available haematoxylin : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available Hematoxylin B Components: Iron(III)-chloride hexahydrate : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available Enhancer No ingredients are hazardous according to OHSA criteria. Red Components: ethanol : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available acetic acid : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available Page 947 of 1069 Page 947 of 1069 Page 947 of 1069 Page 947 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 38 / 60 Red 2 Components: acetic acid : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available Mordant Components: Phosphormolybdänsäure : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available GREEN FOR TRICHROME No ingredients are hazardous according to OHSA criteria. Green 2 Components: hydrogen chloride : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available dihydrogen (ethyl)[4-[4-[ethyl(3-sulphonatobenzyl)amino](4-hydroxy-2- : Mobility : no data available Distribution among environmental compartments : no data available Environmental fate and pathways : no data available Physico-chemical removability : no data available Page 948 of 1069 Page 948 of 1069 Page 948 of 1069 Page 948 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 39 / 60 12.5 Results of PBT and vPvB assessment Bouin's Solution Components: acetic acid : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). formaldehyde : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). Hematoxylin A Components: ethanol : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). methanol : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). propan-2-ol : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). haematoxylin : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). Hematoxylin B Components: Iron(III)-chloride hexahydrate : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). Page 949 of 1069 Page 949 of 1069 Page 949 of 1069 Page 949 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 40 / 60 Enhancer No ingredients are hazardous according to OHSA criteria. Red Components: ethanol : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). acetic acid : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). Red 2 Components: acetic acid : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). Mordant Components: Phosphormolybdänsäure : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). GREEN FOR TRICHROME No ingredients are hazardous according to OHSA criteria. Green 2 Components: hydrogen chloride : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). dihydrogen (ethyl)[4-[4-[ethyl(3-sulphonatobenzyl)amino](4-hydroxy-2- : Assessment : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB). 12.6 Other adverse effects Page 950 of 1069 Page 950 of 1069 Page 950 of 1069 Page 950 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 41 / 60 Bouin's Solution Components: acetic acid : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available formaldehyde : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available Hematoxylin A Components: ethanol : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available methanol : Biochemical Oxygen Demand (BOD) : 600 - 1,120 mg/g, Biochemical oxygen demand, 5 d Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : 1,420 mg/g Adsorbed organic bound halogens (AOX) : no data available propan-2-ol : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon : no data available Page 951 of 1069 Page 951 of 1069 Page 951 of 1069 Page 951 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 42 / 60 (DOC) Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available haematoxylin : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available Hematoxylin B Components: Iron(III)-chloride hexahydrate : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available Enhancer No ingredients are hazardous according to OHSA criteria. Red Components: ethanol : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available acetic acid : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Page 952 of 1069 Page 952 of 1069 Page 952 of 1069 Page 952 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 43 / 60 Adsorbed organic bound halogens (AOX) : no data available Red 2 Components: acetic acid : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available Mordant Components: Phosphormolybdänsäure : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available GREEN FOR TRICHROME No ingredients are hazardous according to OHSA criteria. Green 2 Components: hydrogen chloride : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon (DOC) : no data available Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available Additional ecological information : no data available dihydrogen (ethyl)[4-[4-[ethyl(3-sulphonatobenzyl)amino](4-hydroxy-2- : Biochemical Oxygen Demand (BOD) : no data available Dissolved organic carbon : no data available Page 953 of 1069 Page 953 of 1069 Page 953 of 1069 Page 953 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 44 / 60 (DOC) Chemical Oxygen Demand (COD) : no data available Adsorbed organic bound halogens (AOX) : no data available 13. Disposal considerations 13.1 Waste treatment methods Product : Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Can be disposed as waste water, when in compliance with local regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. 14. Transport information 14.1 UN number DOT : 3316 IMDG : 3316 IATA : 3316 14.2 Proper shipping name DOT : Chemical kits IMDG : Chemical kit IATA : Chemical kit 14.3 Transport hazard class DOT : 9 IMDG : 9 IATA : 9 14.4 Packing group DOT Packaging group : II Labels : 9 Tunnel restriction code : packed IMDG Packaging group : II Labels : 9 EmS Number : F-A, S-P IATA_C Page 954 of 1069 Page 954 of 1069 Page 954 of 1069 Page 954 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 45 / 60 Packing instruction (cargo aircraft) : 960 Packaging group : II Labels : 9 IATA_P Packing instruction (passenger aircraft) : 960 Packaging group : II Labels : 9 14.5 Environmental hazards DOT Environmentally hazardous : no IMDG Marine Pollutant : no IATA Environmentally hazardous : no 14.6 Special precautions for user no data available 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Remarks : not applicable 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Bouin's Solution REGULATORY INFORMATION OSHA Hazards : Highly toxic by inhalation Toxic by ingestion Toxic by skin absorption Skin sensitiser Corrosive to skin Carcinogen WHMIS Classification : D1A Very Toxic Material Causing Immediate and Serious Toxic Effects Highly toxic by inhalation D1B Toxic Material Causing Immediate and Serious Toxic Effects Toxic by ingestion D2A Very Toxic Material Causing Other Toxic Effects Toxic by skin absorption D2B Toxic Material Causing Other Toxic Effects Carcinogen E Corrosive Material Skin sensitiser Page 955 of 1069 Page 955 of 1069 Page 955 of 1069 Page 955 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 46 / 60 Corrosive to metals Corrosive to skin This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. CERCLA Reportable Quantity Components : formaldehyde 100 lbs SARA 302 Reportable Quantity Product : 2778lbs Components : formaldehyde SARA 311/312 Hazards : Acute Health Hazard Chronic Health Hazard EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : The following components are subject to reporting levels established by SARA Title III, Section 302: Components : formaldehyde SARA 304 : Components : formaldehyde Components : formaldehyde Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): formaldehyde 3.6 % The following chemical(s) are listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart formaldehyde 3.6 % The following chemical(s) are listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): acetic acid 5 % formaldehyde 3.6 % Page 956 of 1069 Page 956 of 1069 Page 956 of 1069 Page 956 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 47 / 60 Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know Components : acetic acid 5 - 10 % formaldehyde 1 - 5 % Right To Know Components : water 60 - 100 % acetic acid 5 - 10 % formaldehyde 1 - 5 % picric acid 0 - 0.1 % New Jersey Right To Know Components : water 60 - 100 % acetic acid 5 - 10 % formaldehyde 1 - 5 % California Prop 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Hematoxylin A REGULATORY INFORMATION TSCA list : Listed List of substances. The following chemical substances are subject to all the provisions of part 716. Manufacturers, importers, and processors of a listed substance are subject to the reporting requirements of subpart A for that substance. OSHA Hazards : Flammable liquid Toxic by ingestion Moderate skin irritant Moderate eye irritant Carcinogen WHMIS Classification : B2 Flammable liquid Flammable liquid D1B Toxic Material Causing Immediate and Serious Toxic Effects Toxic by ingestion D2B Toxic Material Causing Other Toxic Effects Moderate skin irritant Page 957 of 1069 Page 957 of 1069 Page 957 of 1069 Page 957 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 48 / 60 Moderate eye irritant This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. CERCLA Reportable Quantity Components : methanol 5000 lbs methanol 5000 lbs SARA 302 Reportable Quantity Product : This material does not contain any components with a SARA 302 RQ. Fire Hazard Acute Health Hazard Chronic Health Hazard EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 304 : This material does not contain any components with a section 304 EHS RQ. Components : methanol Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): methanol 4.75 % This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): ethanol 85.5 % methanol 4.75 % propan-2-ol 4.75 % Clean Water Act Page 958 of 1069 Page 958 of 1069 Page 958 of 1069 Page 958 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 49 / 60 This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know Components : ethanol 70 - 90 % methanol 1 - 5 % propan-2-ol 1 - 5 % Right To Know Components : ethanol 70 - 90 % methanol 1 - 5 % propan-2-ol 1 - 5 % water 1 - 5 % New Jersey Right To Know Components : ethanol 70 - 90 % methanol 1 - 5 % propan-2-ol 1 - 5 % water 1 - 5 % haematoxylin 1 - 5 % California Prop 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Hematoxylin B REGULATORY INFORMATION OSHA Hazards : Toxic by ingestion Moderate skin irritant Severe eye irritant WHMIS Classification : D1B Toxic Material Causing Immediate and Serious Toxic Effects Toxic by ingestion D2B Toxic Material Causing Other Toxic Effects Moderate skin irritant E Corrosive Material Severe eye irritant Corrosive to metals This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. Page 959 of 1069 Page 959 of 1069 Page 959 of 1069 Page 959 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 50 / 60 CERCLA Reportable Quantity Components : Iron(III)-chloride hexahydrate 1000 lbs SARA 302 Reportable Quantity Product : This material does not contain any components with a SARA 302 RQ. Acute Health Hazard EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 304 : This material does not contain any components with a section 304 EHS RQ. Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): hydrogen chloride 0.2 % This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know Components : Iron(III)-chloride hexahydrate 1 - 5 % hydrogen chloride 0.1 - 1 % Right To Know Components : water 60 - 100 % Iron(III)-chloride hexahydrate 1 - 5 % hydrogen chloride 0.1 - 1 % Page 960 of 1069 Page 960 of 1069 Page 960 of 1069 Page 960 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 51 / 60 New Jersey Right To Know Components : water 60 - 100 % Iron(III)-chloride hexahydrate 1 - 5 % California Prop 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Enhancer REGULATORY INFORMATION OSHA Hazards : No OSHA Hazards WHMIS Classification : Not Rated This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. CERCLA Reportable Quantity SARA 302 Reportable Quantity Product : This material does not contain any components with a SARA 302 RQ. No SARA Hazards EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 304 : This material does not contain any components with a section 304 EHS RQ. Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart Page 961 of 1069 Page 961 of 1069 Page 961 of 1069 Page 961 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 52 / 60 Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know No components are subject to the Massachusetts Right to Know Act. Right To Know Components : water 60 - 100 % New Jersey Right To Know Components : water 60 - 100 % lithium carbonate 0.1 - 1 % California Prop 65 Components : WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. lithium carbonate Red REGULATORY INFORMATION OSHA Hazards : Combustible Liquid Corrosive to skin Carcinogen WHMIS Classification : B3 Combustible Liquid Combustible Liquid E Corrosive Material Corrosive to metals Corrosive to skin This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. CERCLA Reportable Quantity Components : acetic acid 5000 lbs SARA 302 Reportable Quantity Product : This material does not contain any components with a SARA 302 RQ. Page 962 of 1069 Page 962 of 1069 Page 962 of 1069 Page 962 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 53 / 60 Fire Hazard Acute Health Hazard Chronic Health Hazard EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 304 : This material does not contain any components with a section 304 EHS RQ. Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): ethanol 7 % acetic acid 1.5 % Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know Components : ethanol 5 - 10 % acetic acid 1 - 5 % Right To Know Components : water 60 - 100 % ethanol 5 - 10 % acetic acid 1 - 5 % New Jersey Right To Know Components : water 60 - 100 % ethanol 5 - 10 % Page 963 of 1069 Page 963 of 1069 Page 963 of 1069 Page 963 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 54 / 60 acetic acid 1 - 5 % California Prop 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Red 2 REGULATORY INFORMATION OSHA Hazards : Corrosive to skin WHMIS Classification : E Corrosive Material Corrosive to skin This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. CERCLA Reportable Quantity Components : acetic acid 5000 lbs SARA 302 Reportable Quantity Product : This material does not contain any components with a SARA 302 RQ. Acute Health Hazard EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 304 : This material does not contain any components with a section 304 EHS RQ. Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): acetic acid 1.5 % Page 964 of 1069 Page 964 of 1069 Page 964 of 1069 Page 964 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 55 / 60 Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know Components : acetic acid 1 - 5 % Right To Know Components : water 60 - 100 % acetic acid 1 - 5 % New Jersey Right To Know Components : water 60 - 100 % acetic acid 1 - 5 % sodium 6-(2- azodibenzenesulphonate 1 - 5 % California Prop 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Mordant REGULATORY INFORMATION OSHA Hazards : Corrosive to skin WHMIS Classification : E Corrosive Material Corrosive to metals Corrosive to skin This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. CERCLA Reportable Quantity SARA 302 Reportable Quantity Product : This material does not contain any components with a SARA 302 RQ. Acute Health Hazard Page 965 of 1069 Page 965 of 1069 Page 965 of 1069 Page 965 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 56 / 60 EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 304 : This material does not contain any components with a section 304 EHS RQ. Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know No components are subject to the Massachusetts Right to Know Act. Right To Know Components : water 60 - 100 % Phosphormolybdänsäure 1 - 5 % New Jersey Right To Know Components : water 60 - 100 % Phosphormolybdänsäure 1 - 5 % California Prop 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. GREEN FOR TRICHROME REGULATORY INFORMATION OSHA Hazards : No OSHA Hazards WHMIS Classification : D2B Toxic Material Causing Other Toxic Effects Page 966 of 1069 Page 966 of 1069 Page 966 of 1069 Page 966 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 57 / 60 Mutagen E Corrosive Material Corrosive to metals This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. CERCLA Reportable Quantity Components : hydrogen chloride 5000 lbs SARA 302 Reportable Quantity Product : This material does not contain any components with a SARA 302 RQ. No SARA Hazards EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 304 : This material does not contain any components with a section 304 EHS RQ. Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): hydrogen chloride 0.75 % This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know Components : hydrogen chloride 0.1 - 1 % Right To Know Page 967 of 1069 Page 967 of 1069 Page 967 of 1069 Page 967 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 58 / 60 Components : water 60 - 100 % hydrogen chloride 0.1 - 1 % New Jersey Right To Know Components : water 60 - 100 % California Prop 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Green 2 REGULATORY INFORMATION OSHA Hazards : Corrosive to skin Severe eye irritant Mutagen WHMIS Classification : D2B Toxic Material Causing Other Toxic Effects Severe eye irritant E Corrosive Material Mutagen Corrosive to skin This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. CERCLA Reportable Quantity Components : hydrogen chloride 5000 lbs SARA 302 Reportable Quantity Product : This material does not contain any components with a SARA 302 RQ. Acute Health Hazard Chronic Health Hazard EPCRA - Emergency Planning and Community Right-to-Know Act SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 304 : This material does not contain any components with a section 304 EHS RQ. Clean Air Act Page 968 of 1069 Page 968 of 1069 Page 968 of 1069 Page 968 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 59 / 60 Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): hydrogen chloride 1.5 % This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. US State Regulations Massachusetts Right To Know Components : hydrogen chloride 1 - 5 % Right To Know Components : water 60 - 100 % hydrogen chloride 1 - 5 % New Jersey Right To Know Components : water 60 - 100 % hydrogen chloride 1 - 5 % dihydrogen (ethyl)[4-[4- [ethyl(3- sulphonatobenzyl)amino](4- hydroxy-2- cyclohexa-2,5-dien-1- ylidene](3- sulphonatobenzyl)ammoniu m, disodium salt 1 - 5 % California Prop 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. 15.2 Chemical Safety Assessment A Chemical Safety Assessment is not required for this substance when it is used in the specified applications. Page 969 of 1069 Page 969 of 1069 Page 969 of 1069 Page 969 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Special Stains Trich.III Green Staining Version 1 . 0 Revision Date 07-16-2012 Print Date 05-13-2013 60 / 60 16. Other information Full text of R-phrases referred to under sections 2 and 3 R 1 Explosive when dry. R10 Flammable. R11 Highly flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R22 Harmful if swallowed. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R34 Causes burns. Full text of H-Statements referred to under sections 2 and 3. Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Page 970 of 1069 Page 970 of 1069 Page 970 of 1069 Page 970 of 1069 ---PAGE BREAK--- 1. IDENTIFICATION Product Name Spic and SpanÒ All-Purpose Cleaner - Made from Concentrate Product Code(s) 4-50 Product ID: 15153796_DIL_PROF_NG Product Type: Finished Product - Professional Use Only Recommended Use Hard Surface Cleaner Restrictions on Use Use only as directed on label. Manufacturer Procter & Gamble Professional 2 P&G Plaza Cincinnati, Ohio 45202 Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5 1-[PHONE REDACTED] E-mail Address Emergency Telephone Transportation (24 HR) CHEMTREC - 1-[PHONE REDACTED] Canada) or 1-[PHONE REDACTED] Mexico toll free in country: [PHONE REDACTED] 2. HAZARD IDENTIFICATION This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Not Classified. Page 1 / 7 Precautionary Statements - Prevention None Issuing Date: 09-Jan-2015 Precautionary Statements - Response None Precautionary Statements - Storage None Revision Date: 07-Apr-2015 Hazard Statements None Precautionary Statements - Disposal None SAFETY DATA SHEET Version 2 Hazard pictograms None Page 971 of 1069 Page 971 of 1069 Page 971 of 1069 Page 971 of 1069 ---PAGE BREAK--- 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists. Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if occur. Inhalation Move to fresh air. If persist, call a physician. Most important acute and delayed None under normal use conditions. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Dry chemical. Alcohol-resistant foam. Unsuitable Extinguishing Media None. Special hazard None known. Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical None. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Advice for emergency responders Use personal protective equipment as required. Environmental precautions Keep out of waterways. Do not discharge product into natural waters without pre-treatment Page 2 / 7 None Revision Date: 07-Apr-2015 Hazardous ingredients None. 15153796_DIL_PROF_NG - Spic and SpanÒ All-Purpose Cleaner - Made from Concentrate Hazards not otherwise classified (HNOC) Page 972 of 1069 Page 972 of 1069 Page 972 of 1069 Page 972 of 1069 ---PAGE BREAK--- or adequate dilution. Methods and materials for containment and cleaning up Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines No exposure limits noted for ingredient(s). Exposure controls Engineering Measures Distribution, Workplace and Household Settings: Ensure adequate ventilation Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction Personal Protective Equipment Eye Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection Hand Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves Skin and Body Protection Distribution, Workplace and Household Settings: No special protective equipment required Page 3 / 7 15153796_DIL_PROF_NG - Spic and SpanÒ All-Purpose Cleaner - Made from Concentrate Revision Date: 07-Apr-2015 Page 973 of 1069 Page 973 of 1069 Page 973 of 1069 Page 973 of 1069 ---PAGE BREAK--- Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Wear suitable protective clothing Respiratory Protection Distribution, Workplace and Household Settings: No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20°C liquid Appearance light green Odor Scented Odor threshold No information available VOC Content Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity None under normal use conditions. Stability Stable under normal conditions. Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. Conditions to Avoid None under normal processing. Materials to avoid None in particular. Hazardous Decomposition Products None under normal use. 11. TOXICOLOGICAL INFORMATION Product Information Information on likely routes of exposure Inhalation No known effect. Page 4 / 7 Note Water solubility Flash point 100% Solubility in other solvents > 93.3 °C / > 200 °F No information available Revision Date: 07-Apr-2015 Partition coefficient: n-octanol/waterNo information available pH value Autoignition temperature Evaporation rate No information available . Decomposition temperature No information available No information available . Viscosity of Product No information available < 10 cps 10.53 Flammability (solid, gas) Property No information available Flammability Limits in Air Melting/freezing point Upper flammability limit No information available No information available Lower Flammability Limit No information available Values Vapor pressure No information available Boiling point/boiling range Vapor density 15153796_DIL_PROF_NG - Spic and SpanÒ All-Purpose Cleaner - Made from Concentrate No information available 100 °C / 212 °F Relative density 1.006 Page 974 of 1069 Page 974 of 1069 Page 974 of 1069 Page 974 of 1069 ---PAGE BREAK--- Skin contact No known effect. Ingestion No known effect. Eye contact No known effect. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation No known effect. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment Waste from Residues / Unused Products Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Codes (non-household setting) 331 14. TRANSPORT INFORMATION DOT Not applicable - diluted product is not intended to be shipped IMDG Not applicable - diluted product is not intended to be shipped IATA Not applicable - diluted product is not intended to be shipped 15. REGULATORY INFORMATION Page 5 / 7 15153796_DIL_PROF_NG - Spic and SpanÒ All-Purpose Cleaner - Made from Concentrate Revision Date: 07-Apr-2015 Page 975 of 1069 Page 975 of 1069 Page 975 of 1069 Page 975 of 1069 ---PAGE BREAK--- U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) Chemical Name CAS-No Sulfuric acid sodium salt (1:2) 7757-82-6 X International Inventories United States All intentionally-added components of this product(s) are listed on the US TSCA Inventory. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act 16. OTHER INFORMATION HMIS Ratings Health hazard 2 Flammability 1 Physical hazard 0 NFPA Ratings Health hazard 2 Flammability 1 Instability 0 Page 6 / 7 15153796_DIL_PROF_NG - Spic and SpanÒ All-Purpose Cleaner - Made from Concentrate Revision Date: 07-Apr-2015 Page 976 of 1069 Page 976 of 1069 Page 976 of 1069 Page 976 of 1069 ---PAGE BREAK--- Issuing Date: 09-Jan-2015 Revision Date: 07-Apr-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7 15153796_DIL_PROF_NG - Spic and SpanÒ All-Purpose Cleaner - Made from Concentrate Revision Date: 07-Apr-2015 Page 977 of 1069 Page 977 of 1069 Page 977 of 1069 Page 977 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Antistatic agents Liquid. Chemtrec - 1-[PHONE REDACTED] CANTUC (Canadian Transportation): (613) 996-6666 Emergency phone: (800) 858-4043 24/7 SAFETY DATA SHEET GHS product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Supplier's details : Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152 Tel. [PHONE REDACTED] or toll free [PHONE REDACTED] Static Free™ Hand Guard™ Relevant identified uses of the substance or mixture and uses advised against Not applicable. Section 2. Hazards identification Not classified. Classification of the substance or mixture : Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 82.5% OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Other means of identification : Antistatic agents CAS number : Not applicable. Substance/mixture Product code : C805 CAS number/other identifiers : Mixture Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 1/11 Page 978 of 1069 Page 978 of 1069 Page 978 of 1069 Page 978 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 3. Composition/information on ingredients stearic acid 1 - 5 57-11-4 glycerol 1 - 2 56-81-5 octadecan-1-ol 1 - 2 112-92-5 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Description of necessary first aid measures Specific treatments : No specific treatment. Most important acute and delayed Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Harmful if swallowed. : Ingestion Skin contact : No known significant effects or critical hazards. May cause eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. Adverse may include the following: nausea or vomiting diarrhea No specific data. : : : Eye contact : Adverse may include the following: irritation redness watering Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 2/11 Page 979 of 1069 Page 979 of 1069 Page 979 of 1069 Page 979 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 3/11 Page 980 of 1069 Page 980 of 1069 Page 980 of 1069 Page 980 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : glycerol OSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust OSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 10 mg/m³ 8 hours. Form: Total dust Section 8. Exposure controls/personal protection Ingredient name Exposure limits Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 4/11 Page 981 of 1069 Page 981 of 1069 Page 981 of 1069 Page 981 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Viscous liquid.] 0°C (32°F) 1 Not available. Not available. Not available. Pleasant. Odor pH White. Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Not available. Not available. 7.2 Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : 100°C (212°F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity stearic acid LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 4600 mg/kg - glycerol LD50 Oral Rat 12600 mg/kg - octadecan-1-ol LD50 Oral Rat >5000 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Information on toxicological effects Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 5/11 Page 982 of 1069 Page 982 of 1069 Page 982 of 1069 Page 982 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. stearic acid Skin - Mild irritant Human - 72 hours 75 milligrams Intermittent - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - glycerol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - octadecan-1-ol Eyes - Mild irritant Rabbit - 24 hours 100 milligrams - Skin - Mild irritant Man - 48 hours 30 Percent - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on the likely routes of exposure Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Harmful if swallowed. : Ingestion Skin contact : No known significant effects or critical hazards. May cause eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Inhalation No specific data. No specific data. : : Eye contact : Adverse may include the following: irritation redness watering Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. : Not available. Potential acute health effects Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 6/11 Page 983 of 1069 Page 983 of 1069 Page 983 of 1069 Page 983 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 11. Toxicological information Not available. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Ingestion Adverse may include the following: nausea or vomiting diarrhea : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 26833.3 mg/kg Dermal 58333.3 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name stearic acid 8.23 238 to 288 low glycerol -1.76 - low octadecan-1-ol 7.4 - high Toxicity Not available. Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 7/11 Page 984 of 1069 Page 984 of 1069 Page 984 of 1069 Page 984 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Section 14. Transport information - - - - - - - Not regulated. - - Not regulated. Not regulated. - - - DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : TDG Classification Not regulated. - - - No. - ADR/RID Not regulated. - - - No. - Mexico Classification Not regulated. - - - No. - Section 15. Regulatory information U.S. Federal regulations : Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed TSCA 8(a) CDR Exempt/Partial exemption: Not determined Commerce control list precursor: 2,2',2''-nitrilotriethanol Not determined. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 8/11 Page 985 of 1069 Page 985 of 1069 Page 985 of 1069 Page 985 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 15. Regulatory information The following components are listed: TRIETHANOLAMINE; GLYCERINE MIST WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. Massachusetts : retinyl palmitate Yes. No. No. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level California Prop. 65 DEA List II Chemicals (Essential Chemicals) : Not listed New York : None of the components are listed. New Jersey : The following components are listed: TRIETHANOLAMINE; ETHANOL, NITRILOTRIS-; GLYCERIN; 1,2,3-PROPANETRIOL; PROPYLENE GLYCOL; 1, 2-PROPANEDIOL : The following components are listed: ETHANOL, 2,2',2"-NITRILOTRIS-; 1,2, 3-PROPANETRIOL; 1,2-PROPANEDIOL State regulations SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Not applicable. stearic acid 1 - 5 Yes. No. No. Yes. No. glycerol 1 - 2 No. No. No. Yes. No. octadecan-1-ol 1 - 2 No. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. Triethanolamine Schedule III Listed Ingredient name List name Status UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. International lists National inventory Australia : All components are listed or exempted. Canada : All components are listed or exempted. China : All components are listed or exempted. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 9/11 Page 986 of 1069 Page 986 of 1069 Page 986 of 1069 Page 986 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 15. Regulatory information Europe : Not determined. Japan : Not determined. Republic of Korea : Not determined. Malaysia : Not determined. New Zealand : All components are listed or exempted. Philippines : All components are listed or exempted. Taiwan : Not determined. Section 16. Other information 5/18/2015. History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 5/18/2015. No previous validation. 1 Hazardous Material Information System 0 0 0 0 0 0 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 10/11 Page 987 of 1069 Page 987 of 1069 Page 987 of 1069 Page 987 of 1069 ---PAGE BREAK--- Static Free™ Hand Guard™ Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 11/11 Page 988 of 1069 Page 988 of 1069 Page 988 of 1069 Page 988 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 1 of 9 Rev. 15-Jul-15 Page 1 of 9 Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Section 1. CHEMICAL PRODUCT SECTION Identification: Product Name: STATICIDE® General Purpose Product Number: # 2001, 2003, 530, 2001-5, 2001-2 Product description: Anti-static topical for non-porous surfaces Product type: Water with surfactants Application: Industrial applications, professional applications Manufacturer: ACL Incorporated 840 W. 49th Place Chicago, IL 60609 PH: (01) [PHONE REDACTED] FAX: (01) [PHONE REDACTED] US/Canada Emergency TEL: INFOTRAC: (01) [PHONE REDACTED] (day or night) International Emergency TEL: INFOTRAC: [PHONE REDACTED] (day or night) Section 2. HAZARDOUS IDENTIFICATION 2.1 Classification of the substance or mixture Product definition: Mixture GHS-US classification Physical: Not Classified Health: Eye irritation / category 2B Environmental: Not Classified 2.2 Label Elements Hazard Pictograms: none Signal Word: Warning Hazard Statement: Causes eye irritation (H320) Precautionary Statements: General: If medical advice is needed, have container or label at hand (P101) Keep out of reach of children (P102) Read label before use (P103) Prevention: Wash hands thoroughly after handling (P264) Response: IF IN EYES, Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing (P305 +P351 + P338) If eye irritation persists, get medical attention or advice (P337 + P313) IF ON SKIN, wash with plenty of water. (P302 + P352) Unknown Acute Toxicity: No data available Page 989 of 1069 Page 989 of 1069 Page 989 of 1069 Page 989 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 2 of 9 Rev. 15-Jul-15 Page 2 of 9 Storage Not a hazardous substance or mixture. See section 7 for storage details. Disposal Dispose of contents in accordance with local and national regulations. See section 13 for disposal details. Hazardous ingredients: NA Supplemental label elements: NA Annex XVII: Not applicable Special packaging requirements Containers to be fitted with child-resistant fastenings: Not applicable Tactile warning of danger: Not applicable Section 3. COMPOSITION / INFORMATION ON INGREDIENTS Substance/Mixture : Mixture CHEMICAL CAS CLASSIFICATION WEIGHT Deionized Water 7732-18-5 Not classified 95 – 99 Quaternary ammonium compounds, coco (hydroxyethyl)methyl, nitrates 71487-00-8 Acute Tox. 4; H302 Skin Corr. 1B; H314 Eye Dam. 1; H318 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 M-Factor (Acute): 1 < .5 Isopropanol 67-63-0 Flam. Liq. 2; H225 Eye Irrit. 2A; H319 STOT SE 3; H336 < .5 Section 4. FIRST AID MEASURES 4.1 Description of first aid measures General Advice: If exposed or concerned: Get medical advice/attention Inhalation: If are experienced, remove the source of contamination or move victim to fresh air. If the affected person is not breathing, apply artificial respiration. If breathing is difficult give oxygen. Eye Contact: Immediately flush eyes with large amounts of cold water for 15 minutes while holding eyelids open. If irritation persists, get medical attention. Skin Contact: If irritated, Wash with soap and water. Take off contaminated clothing and wash it before reuse. Get medical attention if irritation persists. Ingestion: Clean mouth with water and drink afterwards plenty of water. If swallowed, seek medical attention. Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. Wear gloves 4.2 Most important and effects, both acute and delayed The most important known and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data Page 990 of 1069 Page 990 of 1069 Page 990 of 1069 Page 990 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 3 of 9 Rev. 15-Jul-15 Page 3 of 9 Section 5. FIRE FIGHTING MEASURES Protective equipment and precautions for firefighters: 5.1 Extinguishing media Suitable extinguishing media: Alcohol resistant foam, carbon dioxide (CO2). Dry chemical. Unsuitable extinguishing media: Not determined 5.2 Special hazards arising from the substance or mixture Not determined. 5.3 Advice for firefighters Wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 5.4 Further information: No data available Section 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment as required. For personal protection see section 8. 6.2 Environmental precautions No special environmental precautions required. 6.3 Methods and materials for containment and cleaning up Containment: Prevent further leakage or spillage if safe to do so. Halt spill at source and contain or dike spill with inert absorbent material. Clean up: Transfer liquid to containers for recovery or disposal. Shovel absorbent into drums for disposal in accordance with local, state and federal regulations. 6.4 Reference to other sections For disposal see section 13. Section 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid contact with eyes. For precautions see section 2.2 Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wash face, hands, and any exposed skin thoroughly after handling. Wear eye/face protection. 7.2 Conditions for safe storage, including any incompatibilities Keep container closed in a dry and well-ventilated place away from direct sunlight. Storage Conditions: Ambient (40° - 90° F) Incompatible Materials: None known based on information supplied. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 Designed for interior industrial manufacturing. May be used to decay static on carpets and upholstery. May be used on composite materials for static control but will not withstand weathering. Section 8. EXPOSURE CONTROL / PERSONAL PROTECTION 8.1 Control parameters Occupational exposure limits Component OSHA PEL ACGIH TLV NIOSH REL Isopropanol 400 ppm TWA ; 980 Mg/m3 500 ppm STEL ; 1225 Mg/m3 400 ppm TWA ; 983 Mg/m3 500 ppm STEL ; 1230 Mg/m3 400 ppm TWA 980 Mg/m3 500 ppm STEL 1225 Mg/m3 Page 991 of 1069 Page 991 of 1069 Page 991 of 1069 Page 991 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 4 of 9 Rev. 15-Jul-15 Page 4 of 9 Recommended monitoring procedures: Not established DNELs/DMELs: No DNELs/DMELs available. PNECs: No PNECs available 8.2 Exposure controls Appropriate engineering controls: Eyewash stations. Local Exhaust ventilation acceptable Individual protection measures Hygiene measures: Wash hands before eating, smoking and using the lavatory and at the end of the working period. When using, do not eat or drink. When using, do not smoke. Eye/face protection: Ensure that eyewash stations are proximal to the work-station location. Splash Goggles are recommended for large spills. Skin protection: Wear protective work clothing if necessary. Hand protection: Gloves Recommended. Body protection Wear lab coat. Other skin protection: Ensure the safety showers are proximal to the work-station location. Respiratory protection: None required in well ventilated areas. Environmental exposure controls: For normal conditions, protection is not necessary. In Case of Large Spill: Wear gloves, goggles, and protective work clothing. The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). Section 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Clear pale yellow liquid Odor Pleasant pH 7.1 Melting point/freezing point NE / Less than 0C Initial boiling point and boiling range 100C (212F) Flash point and method None Evaporation rate (H2O 1 estimate Flammability (solid, gas, liquid) NA Upper/lower flammability or explosive limits NA Vapor pressure NE Vapor density (air=1) 2 estimate Relative density .99 Solubility(ies). Miscible Partition coefficient: n-octanol/water NE Autoignition temperature NA Decomposition temperature NE Viscosity NE Volatile by weight >98.5% 9.2 Other safety information VOC (g/l) < 3.6 Section 10. STABILITY AND REACTIVITY Page 992 of 1069 Page 992 of 1069 Page 992 of 1069 Page 992 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 5 of 9 Rev. 15-Jul-15 Page 5 of 9 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions None under normal procession 10.4 Conditions to avoid: Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible materials None known based on information supplied 10.6 Hazardous decomposition products: Hazardous Polymerization will not occur. Other decomposition products In the event of fire: see section 5 Section 11. TOXICOLOGY INFORMATION 11.1 Acute toxicity Product/ingredient name Result Species Dose Exposure Isopropanol LD50 dermal LC50 inhalation LD50 oral Rabbit Rat Rabbit 12,800 mg/kg 72.6 mg/l 6410 mg/kg - 4 hours - quaternary ammonium compounds, coco methyl, nitrates LD50 oral Rat 300 – 2,000 mg/kg - Conclusion/Summary: Not available Irritation/Corrosion Product/ingredient name Result Species Exposure Isopropanol Eyes - Moderate irritant Eyes - Moderate irritant Eyes - Severe irritant Skin - Mild irritant Rabbit Rabbit Rabbit Rabbit 24 hours 100 milligrams 10 milligrams 100 milligrams 500 milligrams quaternary ammonium compounds, coco methyl, nitrates Burns skin Risk of serious eye damage Rabbit Rabbit Read across analogy Conclusion/Summary: Not available Sensitization Conclusion/Summary: Not available. Mutagenicity Conclusion/Summary: Not available. Product/ingredient name Result Species Test Isopropanol Does not cause skin sensitization Guinea Pig Bueler quaternary ammonium compounds, coco methyl, nitrates No data available Product/ingredient name Result Species Test Isopropanol Negative Bacteria Ames test Method: OECD Test Guideline 471 quaternary ammonium compounds, coco methyl, nitrates Likely to be negative Based on similar quaternary salts Page 993 of 1069 Page 993 of 1069 Page 993 of 1069 Page 993 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 6 of 9 Rev. 15-Jul-15 Page 6 of 9 Carcinogenicity Conclusion/Summary: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA Reproductive toxicity Conclusion/Summary: Not available. Teratogenicity Conclusion/Summary: Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure): Not available. Aspiration hazard: Not available. Information on the likely routes of exposure: Not available. 11.2 Primary route(s) of exposure/entry: Inhalation, Skin Contact. 11.3 related to the physical, chemical and toxicological characteristics Eye contact: Adverse may include the following: Pain, watering, redness Inhalation: Adverse may include the following: nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness Skin contact: Adverse may include the following: pain or irritation, redness, blistering may occur Ingestion: Adverse may include the following: stomach pains Section 12. ECOLOGICAL INFORMATION 12.1 Toxicity Product/ingredient name Result Species Exposure propan-2-ol Acute LC50 1400000 to 1950000 μg/l Marine water Acute LC50 4200000 μg/l Fresh water Crustaceans - Crangon crangon Fish - Rasbora heteromorpha 48 hours 96 hours Quaternary ammonium compounds, benzyl- chlorides Acute LC50 0.31 mg/l Fish 96 hours Conclusion/Summary : Not available. 12.2 Persistence and degradability Product/ingredient name Test Result Dose Inoculum Quaternary ammonium compounds, coco (hydroxyethyl)methyl, nitrates (salts) - 20 % - 42 days - - propan-2-ol 301E Ready Biodegradability - Modified OECD Screening Test 95 % - 21 days - - Conclusion/Summary : Not available. Product/ingredient name Category Route of exposure Target organs propan-2-ol Category 3 Not applicable. Narcotic effects Page 994 of 1069 Page 994 of 1069 Page 994 of 1069 Page 994 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 7 of 9 Rev. 15-Jul-15 Page 7 of 9 Product/ingredient name Aquatic half-life Photolysis Biodegradability propan-2-ol - - Readily 12.3 Bioaccumulative potential Product/ingredient name LogPow BCF Potential propan-2-ol 0.05 - low 12.4 Mobility in soil Soil/water partition coefficient (KOC): Not available. Mobility: Not available. 12.5 Results of PBT and vPvB assessment PBT: Not available. vPvB: Not available. 12.6 Other adverse effects: No known significant effects or critical hazards. Section 13. DISPOSAL CONSIDERATIONS The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Product Methods of disposal: Offer surplus and non-recyclable solutions to a licensed disposal company Hazardous waste: The classification of the product does not meet the criteria for a hazardous waste. Contaminated Packaging Methods of disposal: Dispose of as unused product. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. Special precautions: RCRA 40 CFR 261 Classifications: As packaged and after use, it does not meet the criteria of a hazardous waste as defied under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it has neither the characteristics of Subpart C nor is listed in Subpart D. Federal, State, and Local laws governing disposal of material can differ. Ensure proper disposal compliance with proper authorities before disposal. Section 14. TRANSPORTATION INFORMATION U.S. DOT Information Proper Shipping Name: Non Hazardous Material Hazard Class: NA IATA Proper Shipping Name: NON HAZARDOUS MATERIAL Hazard Class: NA IMDG Proper Shipping Name: NON HAZARDOUS MATERIAL Hazard Class: NA Section 15. REGULATORY INFORMATION US Federal Regulations: MSDS complies with the OSHA Hazard Communication Rule, 29 CFR 1910.1200. CERCLA/Superfund, 40 CFR 117, 302: None of the chemicals are Section 302 hazards SARA Superfund and Reauthorization Act of 1986 Title III sections 302, 311,312 and 313: Page 995 of 1069 Page 995 of 1069 Page 995 of 1069 Page 995 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 8 of 9 Rev. 15-Jul-15 Page 8 of 9 Section 302 – Extremely hazardous substances (40 CFR 355): None of the chemicals are Section 302 hazards Section 311/312 – MSDS Requirements (40 CFR 370): By our hazard evaluation, this product is non-hazardous. Section 313 – List of Toxic Chemicals (40CFC 372): This product does not contain chemicals on the 313 list of Toxic Chemicals. Toxic Substance Control Act (TSCA): All substances are TSCA listed. Resource Conservation and Recovery Act (RCRA 40 CFR 261) Subpart C & D: Refer to Section 13 Federal Water Pollution Control Act, Clean Water Act, 40 CFR 401.15 (formerly section 307) 40 CFR 116 (formerly section 311): No products listed STATE REGULATIONS: California Proposition 65: None of the chemicals are on the Proposition 65 list--- INTERNATIONAL REGULATIONS: Canada WHMIS: 904 (1050 FR) Isopropanol is listed on Ingredient Disclosure List (SOR/88-64) To the best of our ability, this MSDS is written in accordance to REACH Directive EC1907/2006 Annex II and GHS requirements. This product is not subject to REACH restrictions. It does not contain any candidates on the SvHC. Sections 16. OTHER INFORMATION NFPA Health: Can cause significant irritation NFPA Fire: Will not burn NFPA Instability: Stable NFPA Reactivity: None HMIS Health: Slight Hazard. Irritation or minor reversible injury possible. HMIS Flammability: Minimal Hazard. Will not burn unless heated. HMIS Reactivity: Minimal Hazard. Stable HMIS Personal Protection: B. Safety glasses and protective gloves should be worn when handling this material. REVISION DATES, SECTIONS, REVISED BY: 15-Mar-92, Original release date 02-APR-01, Reviewed 17-Feb-04, New Format, mkb 31-Jan-07Section 11 & 12, mkb 28-Aug-09 New address, mkb 06-Mar-12 REACH updates, mkb 10-DEC-14 Section 2, mkb 13-Mar-15 Reviewed all sections, mkb 15-Jul-15 Added GHS elements, mkb ABBREVIATIONS USED IN THIS DOCUMENT: NE – Not Established, NA – Not Applicable, NIF – No Information Found ABRIDGED LIST OF REFERENCES: Code of Federal Regulations (CFR) Chemical Guide and OSHA Hazardous Communication Standard The Environmental Protection Agency (www.epa.gov) ANSI Standard: ANSI Z400.1-1998 Merck Index Directive EC1907/2006 UN ST/SG/AC.10/30/ GHS Page 996 of 1069 Page 996 of 1069 Page 996 of 1069 Page 996 of 1069 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 9 of 9 Rev. 15-Jul-15 Page 9 of 9 To the best of our knowledge, the information contained herein is accurate. However, neither ACL STATICIDE nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Page 997 of 1069 Page 997 of 1069 Page 997 of 1069 Page 997 of 1069 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: STERIPHENE II BRAND DISINFECTANT DEODORANT Product Number: 6075; 6081 Janitorial Spartan Chemical Company, Inc. Product/Technical Information:1-(800)-537-8990 1110 Spartan Drive Medical Emergency:1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil Emergency:CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: ORM-D, Consumer commodity, deodorants, aerosol, n.o.s. NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: 1- Slight Fire: 4 - Extreme Fire: 4 - Extreme Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Chemical Name(s) % W CAS Registry No. Table Z- 1 - A NTP, IARC or OSHA Carcinogen TWA mg/m3 STEL mg/m 3 CELING mg/m3 Ethanol 60-70 64-17-5 1900 Not Established Not Established No Propane 5-10 74-98-6 1800 Not Established Not Established No Isobutane 5-10 75-28-5 1900 (NIOSH) Not Established Not Established No *Ortho phenyl phenol < 1.0 90-43-7 1 (Dow) Not Established Not Established No Ortho benzyl-para-chlorophenol < 1.0 120-32-1 Not Established Not Established Not Established No Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA Boiling Point: 165-175 °F Vapor Pressure: 35 mm Hg @ 75°C Vapor Density (AIR = Unknown Solubility in Water: Complete pH: 8.0-9.0 Specific Gravity (H2O=1): 0.84 Evaporation Rate (but.ace.=1): 1.5 (concentrate) Percent Solid by Weight: Trace Physical State: Liquid Appearance & Odor: Light yellow liquid, citrus, floral fragrance Page 998 of 1069 Page 998 of 1069 Page 998 of 1069 Page 998 of 1069 ---PAGE BREAK--- SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: Propellant: < 0°F Method Used: ASTM-D3065 Flammable Limits: N/A Flame Extension: 20" This product is a NFPA 30 B Storage Level II aerosol. Extinguishing Media: Foam or Carbon dioxide2 Special Fire Fighting Procedures: Use equipment or shielding required to protect personnel against bursting, rupturing or venting containers. Unusual Fire & Explosive Hazards: At elevated temperatures (54°C/130°F), containers may vent, rupture or burst. SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes Effects of Overexposure- Conditions to Avoid: Causes substantial but temporary eye injury. Harmful if absorbed through the skin. Inhalation of product mist may cause respiratory irritation. Ortho phenyl phenol has been shown to produce urinary bladder tumors in male rats and liver tumors in male mice fed exaggerated doses. Do not get in eyes, on skin or on clothing. Avoid inhalation of product mist. Do not spray on food or food utensils. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses; If present; after the first 5 minutes; then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Wash contaminated clothing before reuse. Inhalation: In case of respiratory irritation; move person to fresh air. Get medical attention if irritation persists. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: None known Hazardous Decomposition Products: CO2, CO Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Remove ignition sources. Avoid breathing vapors or contact with liquid. Soak up with absorbent material and transfer to containers for disposal. Rinse area with water and flush to sanitary sewer. Keep spill out of storm sewers and waterways. Waste Disposal Method: Do not incinerate or puncture aerosol container. Dispose of in accordance with federal, state and local regulations. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure Page 999 of 1069 Page 999 of 1069 Page 999 of 1069 Page 999 of 1069 ---PAGE BREAK--- limits (see Section II) are exceeded or if respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Impervious gloves are recommended for prolonged or repeated contact. Eye Protection(Specify Type): Splash goggles are recommended to prevent eye contact. Other Protective Equipment: See CFR 1910.132-138. Page 1000 of 1069 Page 1000 of 1069 Page 1000 of 1069 Page 1000 of 1069 ---PAGE BREAK--- SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Flammable! Contents under pressure. Do not use near fires, sparks or flame. Do not store where temperatures could exceed 120°F. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash before reuse. Do not contaminate water, food or feed by storage or disposal. Other Precautions: Keep out of reach of children. © SCC 09/22/2008 Name: Ronald T. Cook Title: Manager, Regulatory Affairs STERIPHENE II BRAND DISINFECTANT DEODORANT Effective Date: 09/22/2008 Supercedes: 06/30/2005 Ref: 29 CFR 1910.1200 (OSHA) Changes: Review This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 1001 of 1069 Page 1001 of 1069 Page 1001 of 1069 Page 1001 of 1069 ---PAGE BREAK--- Page 1002 of 1069 Page 1002 of 1069 Page 1002 of 1069 Page 1002 of 1069 ---PAGE BREAK--- Page 1003 of 1069 Page 1003 of 1069 Page 1003 of 1069 Page 1003 of 1069 ---PAGE BREAK--- Page 1 of 7 Super Lube, Multi-Purpose Lubricant part number TY25733 Material Safety Data Sheet Issue Date: October 27, 2008 Revised Date: March 10, 2010 Reason: Add HMIS codes. 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Common Name: Super Lube, Multi-Purpose Lubricant part number TY25733 Product use: t n a cir b u L Manufactured For: Contact Information: TIG Distributing Telephone: [PHONE REDACTED] P.O. Box 535 Marshalltown, IA 50158 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: l o s o r e A WHMIS hazard class: A, B.5 Color: Translucent HMIS codes: Fire - 3 Odor: 2 - h tla e H cita h pil A Reactance - 0 Other - 0 DANGER: F+ EXTREMELY FLAMMABLE CONTENTS UNDER PRESSURE VAPOR MAY CAUSE FLASH FIRE HARMFUL IF INHALED CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health E ects Inhalation: Vapors and mists will irritate the respiratory tracts and nasal passages. Overexposure may cause nervous ni tl u s er y a m er u s o p x er e v o e m ertx E . n oiss er p e d m ets y s unconsciousness and possibly death. Skin contact: Irritating to skin. Eye contact: Contact with eyes will cause irritation. Ingestion: Not expected under normal conditions of use. Existing conditions aggravated None generally recognized. by exposure: See Section 11 for additional toxicological information. Page 1004 of 1069 Page 1004 of 1069 Page 1004 of 1069 Page 1004 of 1069 ---PAGE BREAK--- Page 2 of 7 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components % ACGIH TLV OSHA PEL OTHER N-Heptane <80 400 ppm TWA 2000 mg/m³ TWA None 142-82-5 500 ppm STEL 500 ppm TWA Xn, Xi, N; R12-38-51/53-65-67 Additional information: For the wording of the listed risk phrases refer to section 16. Other components Polyalphaole n <13 5mg/m³ TWA (mist 5mg/m³ TW A (mist None 68037-01-4 10mg/m³ STEL (mist White mineral oil (petroleum) <7 5mg/m³ TWA (mist 5mg/m³ TWA (mist None 8042-47-5 10mg/m³ STEL (mist Antioxidant <0.5 Not established Not established None 41484-35-9 Fumed Silica <3 10mg/m³ TWA 6mg/m³ TWA None 68611-44-9 Polytetra uoroethylene <1 Not established Not established None 9002-84-0 <0.5 AIHA WEEL 025322-69-4 is 50 ppm Total 10mg/m³ aerosol only Proprietary Additives <0.5 Not established Not established None 4. FIRST AID MEASURES Inhalation: Remove to fresh air. Restore breathing. Skin contact: elp h ti w yletaid e m m i h s a w ,n ik s h ti w tc at n o c retf A nty of water. Immediately ush skin with plenty of water (using soap, if available). Get medical attention if develop and persist. Page 1005 of 1069 Page 1005 of 1069 Page 1005 of 1069 Page 1005 of 1069 ---PAGE BREAK--- Page 3 of 7 Eye contact: re d n u o sla ,reta w fo yt n elp h ti w yletaid e m m i e s n i R the eyelids, for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Get medical attention immediately. Notes to physician: Treatment: 5. FIRE-FIGHTING MEASURES Flash point: Not available Autoignition temperature: Not available Flammable/Explosive limits-lower 1.1 (vol Flammable/Explosive limits-upper 7.0 (vol Extinguishing media: Carbon dioxide (CO2). Dry chemical. Foam. Special fire fighting procedures: Water spray may be ineffective. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Hazardous combustion products: Oxides of carbon. Sensitivity to mechanical impact: Not available Sensitivity to static discharge: Not available 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: No information available Clean-up methods: Remove all ignition sources. Ventilate area. Soak up with inert absorbent. 7. HANDLING AND STORAGE Handling: tc at n o c d io v A .n o italit n e v eta u q e d a h ti w yln o e s U with eyes, skin and clothing. Do not breathe mist or vapors. Storage: ta re p m et o t e s o p x e r o ,eta re n ic n i ,e r u tc n u p t o n o D ures above 48.9° C (120° Heat from sunlight, radiators, Page 1006 of 1069 Page 1006 of 1069 Page 1006 of 1069 Page 1006 of 1069 ---PAGE BREAK--- Page 4 of 7 stoves, hot water, and other heat sources could cause containers to burst. Incompatible products: None reasonably foreseeable. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Respiratory protection: If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH. Skin protection: Chemical resistant, impermeable gloves. Eye/face protection: Safety glasses with side-shields. See Section 3 for exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Aerosol Color: Translucent Odor: Aliphatic Odor Threshold: Not available Vapor pressure: 5.0 – 5.5 BAR @ 20° C pH: Not applicable Boiling point/range: Not available Melting point/range: Not available Specific gravity: Not available Vapor density: Heavier than air Evaporation rate: Faster than ether Solubility in water: Not soluble Partition coefficient (n-octano/water): Not available VOC content: 77.0% 10. STABILITY AND REACTIVITY Stability: Stable Hazardous polymerization: Will not occur. Hazardous decomposition products: None under normal use. Incompatibility: None known. Page 1007 of 1069 Page 1007 of 1069 Page 1007 of 1069 Page 1007 of 1069 ---PAGE BREAK--- Page 5 of 7 Conditions to avoid: Heat, flames and sparks. 11. TOXICOLOGICAL INFORMATION Product toxicity data: Not available Toxicologically synergistic products: Not available Refer to the following for irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and Mutagenicity. Ingredient Toxicity Data & Carcinogen Status Hazardous components LD50s & LC50s Other LD50s and LC50s NTP Carcinogen IARC Carcinogen OSHA Carcinogen ACGIH- Carcinogen n-Heptane 142-82-5 Inhalation LC50 (Rat) = 103 g/m³ None No No No No Other components Polyalphaolefin Proprietary None None No No No No White mineral Oil (petroleum) 8042-47-5 Oral LD50 (Rat) >5000 mg/kg None No No No No Antioxidant 41484-35-6 Oral LD50 (Rat) >5000 mg/kg Dermal LD50(Rabbit) >3000 mg/kg Inhalation LC50 (Rat) >3.5 mg/m³ None No No No No Fumed Silica 68611-44-9 Oral LD50 (Rat) >5000 mg/kg None No No No No Polytetra- fluoroethylene 9002-84-0 Not determined None No No No No 025322-69-4 Oral LD50 (Rats) >10,000 mg/kg Dermal LD50 (Rabbit) >10,000 mg/kg None No No No No Literature Referenced Target Organ & Other Health Effects s n a g r O te g r a T/stc e ff E h tla e H st n e n o p m o c s u o d r a z a H n-Heptane 142-82-5 Central nervous system, irritant Other components Polyalphaolefin Proprietary No target organs White mineral oil (petroleum) Irritant Page 1008 of 1069 Page 1008 of 1069 Page 1008 of 1069 Page 1008 of 1069 ---PAGE BREAK--- Page 6 of 7 8042-47-5 Antioxidant 41484-35-6 No target organs Fumed Silica 68611-44-6 Nuisance dust, irritant to eyes and skin Polytetrafluoroethylene 9002-84-0 Irritant 025322-69-4 No target organs 12. ECOLOGICAL INFORMATION Ecological information: Not available 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of in accordance with federal and local regulations. 14. TRANSPORT INFORMATION Transportation of Dangerous Goods – Ground: Proper shipping name: Consumer Commodity, ORM-D Hazardous class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA): Proper shipping name: Aerosols, Flammable Hazardous class or division: 2.1 Identification number: UN 1950 Packing group: Y203 Exceptions: (Not more than 500 ml) May qualify as Consumer Commodity ID8000 Water Transportation (IMO/IMDG): Proper shipping name: Aerosols, LTD. QTY. Hazardous class or division: 2 Identification number: UN 1950 Packing group: None Marine pollutant: None 15. REGULATORY INFORMATION Labeling according to EU guidelines: The product has been classified and marked in accordance with EU Directives/Ordinance on Hazardous Materials. Page 1009 of 1069 Page 1009 of 1069 Page 1009 of 1069 Page 1009 of 1069 ---PAGE BREAK--- Page 7 of 7 Code letter and hazard designation of product: F+ Extremely flammable. Risk phrases: 12 Extremely flammable. 52/53 Harmful to aquatic organisms, may cause long- term adverse effects in the aquatic environment. 67 Vapors may cause drowsiness and dizziness. Safety phrases: 3/7 Keep container closed in a cool place. 16 Keep away from sources of ignition-No smoking. 23 Do not breathe fumes/aerosol. 51 Use only in well ventilated areas. Special labeling of certain preparations: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn even after use. Keep out of reach of children. Water hazard class: Water hazard class 1 (Self-assessment): hazardous for water. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List. United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. SECTION 16: OTHER INFORMATION This product contains a chemical known to the state of California to cause cancer/reproductive harm. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the informati on required by the Controlled Product Regulations. Relevant R-phrases: 11 Highly flammable 38 Irritating to skin. 51/53 Toxic to aquatic organisims, may cause long-term adverse effects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. 67 Vapors may cause drowsiness and dizziness. Data prepared by Environment protection department. Page 1010 of 1069 Page 1010 of 1069 Page 1010 of 1069 Page 1010 of 1069 ---PAGE BREAK--- Page 1011 of 1069 Page 1011 of 1069 Page 1011 of 1069 Page 1011 of 1069 ---PAGE BREAK--- Page 1012 of 1069 Page 1012 of 1069 Page 1012 of 1069 Page 1012 of 1069 ---PAGE BREAK--- Page 1013 of 1069 Page 1013 of 1069 Page 1013 of 1069 Page 1013 of 1069 ---PAGE BREAK--- SAFETY DATA SHEET. Issuing date 23-Mar-2015 Revision Date 23-Mar-2015 Version 2 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product name TEF-GEL Recommended use of the chemical and restrictions on use Product code 97673 Product Type Extremely flammable aerosol Synonyms Supplier's details Recommended Use Gel Lubricant. Uses advised against Emergency telephone number Chemical Emergency Phone Number [PHONE REDACTED] Page 1 / 9 Manufactured For: Lawson Products, Inc 8770 W. Bryn Mawr Avenue - Suite 900 Chicago, IL 60631-3515 [PHONE REDACTED] Page 1014 of 1069 Page 1014 of 1069 Page 1014 of 1069 Page 1014 of 1069 ---PAGE BREAK--- 97673 TEF­GEL Revision Date 23-Mar-2015 2. HAZARDS IDENTIFICATION Classification Skin corrosion/irritation Category 2 Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Aspiration toxicity Category 1 GHS Label elements, including precautionary statements Emergency Overview Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wear protective gloves/protective clothing/eye protection/face protection Wash face, hands and any exposed skin thoroughly after handling Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Precautionary Statements - Response If exposed or concerned: Get medical advice/attention Specific treatment (see first aid on this label) IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Flammable aerosols Category 1 Gases under pressure Compressed Gas DANGER Hazard Statements Causes skin irritation Suspected of damaging fertility or the unborn child May cause respiratory irritation. May cause drowsiness or dizziness May cause damage to organs (Central Nervous System, Eyes, Peripheral Nervous System, Respiratory System, and Skin) through prolonged or repeated exposure. May be fatal if swallowed and enters airways Extremely flammable aerosol Contains gas under pressure; may explode if heated Appearance Hazy Page 2 / 9 Physical state Aerosol Odor Light Vanilla Scent Page 1015 of 1069 Page 1015 of 1069 Page 1015 of 1069 Page 1015 of 1069 ---PAGE BREAK--- 97673 TEF­GEL Revision Date 23-Mar-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS # 64742-49-0, COMMERCIAL HEXANES, MAY BE SUBSTITUTED FOR CAS #110-54-3. Synonyms Chemical Name CAS-No Weight HEXANE 64742-49-0 60-70 POLYMERIC VISCOSITY MODIFIER MIXTURE 10-20 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 10-20 WHITE MINERAL OIL 8042-47-5 1-10 *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Keep eye wide open while rinsing. If persist, call a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Inhalation Move to fresh air. Artificial respiration and/or oxygen may be necessary. If not breathing, give artificial respiration. If breathing has stopped, contact emergency medical services immediately. Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately. Most important acute and delayed Main Irritating to skin. Causes serious eye damage. Causes drowsiness or dizziness. Harmful or fatal if swallowed and enters airways. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container closed Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None Other information 0% of the mixture consists of ingredient(s) of unknown toxicity Page 3 / 9 Page 1016 of 1069 Page 1016 of 1069 Page 1016 of 1069 Page 1016 of 1069 ---PAGE BREAK--- 97673 TEF­GEL Revision Date 23-Mar-2015 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. Specific hazards arising from the chemical No information available. Explosion Data Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with the skin and the eyes. Evacuate personnel to safe areas. Ensure adequate ventilation. Avoid dust formation. Take precautionary measures against static discharges. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Contents under pressure. Do not puncture or incinerate cans. Stop leak if you can do it without risk. Environmental precautions Environmental precautions No special environmental precautions required. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Methods and materials for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Conditions for safe storage, including any incompatibilities Technical measures/Storage conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known based on information supplied. Aerosol Level 3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page 4 / 9 Control parameters Page 1017 of 1069 Page 1017 of 1069 Page 1017 of 1069 Page 1017 of 1069 ---PAGE BREAK--- 97673 TEF­GEL Revision Date 23-Mar-2015 Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH HEXANE 64742-49-0 TWA: 50 ppm Skin - potential significant contribution to overall exposure by the cutaneous route TWA: 500 ppm TWA: 1800 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 180 mg/m3 IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 74-98-6: TWA: 1000 ppm 106-97-8: STEL: 1000 ppm 75-28-5: STEL: 1000 ppm 74-98-6:TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 106-97-8: (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 74-98-6:IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 106-97-8:TWA: 800 ppm TWA: 1900 mg/m3 75-28-5:TWA: 800 ppm TWA: 1900 mg/m3 ACGIH: (American Conference of Governmental Industrial Hygienists) OSHA: (Occupational Safety & Health Administration) NIOSH IDLH: Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Exposure controls Engineering Measures Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Safety glasses with side-shields. Skin and body protection Chemical resistant apron. Protective gloves. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and chemical properties Physical state Aerosol Appearance Hazy Odor Light Vanilla Scent Color amber Odor Threshold No information available Property Values Remarks • Methods pH No information available not applicable Melting/freezing point No information available Boiling point/boiling range No information available Flash Point -97 °C / -143 °F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air upper flammability limit No information available lower flammability limit No information available Vapor pressure No information available Vapor density Page 5 / 9 No information available Page 1018 of 1069 Page 1018 of 1069 Page 1018 of 1069 Page 1018 of 1069 ---PAGE BREAK--- 97673 TEF­GEL Revision Date 23-Mar-2015 Explosive properties No information available Other information VOC Content(%) 78.76 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Avoid breathing vapors or mists. Eye contact May cause slight irritation. Avoid contact with eyes. Skin contact Irritating to skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Avoid contact with skin. Ingestion Harmful if swallowed. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation HEXANE 64742-49-0 > 5000 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) = 73680 ppm ( Rat ) 4 h WHITE MINERAL OIL 8042-47-5 > 5000 mg/kg ( Rat ) - - Information on toxicological effects of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Specific Gravity 0.720 Water solubility Practically insoluble Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available Not applicable Decomposition temperature No information available Viscosity No information available Page 6 / 9 No data available Page 1019 of 1069 Page 1019 of 1069 Page 1019 of 1069 Page 1019 of 1069 ---PAGE BREAK--- 97673 TEF­GEL Revision Date 23-Mar-2015 Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Irritating to skin. Sensitization None known. Germ Cell Mutagenicity None known. Carcinogenicity There are no known carcinogenic chemicals in this product. Reproductive toxicity Product is or contains a chemical which is a known or suspected reproductive hazard. Specific target organ systemic toxicity (single exposure) May cause respiratory irritation. May cause drowsiness and dizziness. Specific target organ systemic toxicity (repeated exposure) May cause damage to organs through prolonged or repeated exposure. Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin. Neurological effects Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Aspiration hazard May be fatal if swallowed and enters airways. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 3401 mg/kg ATEmix (dermal) 7482 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates PROPANE/ISOBUTANE/N- BUTANE 68476-86-8 - - - - WHITE MINERAL OIL 8042-47-5 - 10000 mg/L LC50 Lepomis macrochirus 96h - - Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name log Pow PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 2.8 WHITE MINERAL OIL 8042-47-5 6 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment Waste Disposal Methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not re-use empty containers. Page 7 / 9 14. TRANSPORT INFORMATION Page 1020 of 1069 Page 1020 of 1069 Page 1020 of 1069 Page 1020 of 1069 ---PAGE BREAK--- 97673 TEF­GEL Revision Date 23-Mar-2015 DOT Ground CONSUMER COMMODITY ORM-D or LIMITED QUANTITY IATA UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD. QTY. IMDG UN1950, AEROSOLS, 2.1, LTD. QTY. 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS HEXANE X X X X X X X X PROPANE/ISOBUTA NE/N-BUTANE X X X Not listed X X X X WHITE MINERAL OIL X X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances CHINA - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard Yes Reactive Hazard no Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations Page 8 / 9 Page 1021 of 1069 Page 1021 of 1069 Page 1021 of 1069 Page 1021 of 1069 ---PAGE BREAK--- 97673 TEF­GEL Revision Date 23-Mar-2015 California Proposition 65 This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations EPA Pesticide Registration Number Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Chronic Hazard Star Legend Chronic Health Hazard; Repeated or prolonged exposure may cause central nervous system damage Prepared By Regulatory Affairs Issuing date 23-Mar-2015 Revision Date 23-Mar-2015 Revision Note No information available Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazard 2 Flammability 4 Instability 0 Physical and chemical hazards - HMIS Health Hazard 2* Flammability 4 Page 9 / 9 Physical Hazard 1 Personal protection B Page 1022 of 1069 Page 1022 of 1069 Page 1022 of 1069 Page 1022 of 1069 ---PAGE BREAK--- Page 1023 of 1069 Page 1023 of 1069 Page 1023 of 1069 Page 1023 of 1069 ---PAGE BREAK--- Page 1024 of 1069 Page 1024 of 1069 Page 1024 of 1069 Page 1024 of 1069 ---PAGE BREAK--- Page 1025 of 1069 Page 1025 of 1069 Page 1025 of 1069 Page 1025 of 1069 ---PAGE BREAK--- Page 1026 of 1069 Page 1026 of 1069 Page 1026 of 1069 Page 1026 of 1069 ---PAGE BREAK--- Revision Date: 08-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: TNT FOAMING DISINFECTANT CLEANER Product Number: 6343 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Signal Word: No signal word Hazard Statements: No hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 5 Liquefied gas Symbols: Page 1027 of 1069 Page 1027 of 1069 Page 1027 of 1069 Page 1027 of 1069 ---PAGE BREAK--- 6343 - TNT FOAMING DISINFECTANT CLEANER Revision Date: 08-May-2015 Other Information: • May be harmful if swallowed. • May cause eye irritation. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 0.0249% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 diethylene glycol monobutyl ether 112-34-5 1-5 N-butane 106-97-8 1-5 tetrapotassium pyrophosphate 7320-34-5 1-5 alkyl dimethyl ammonium chloride 85409-23-0 <0.1 alkyl dimethyl benzyl ammonium chloride 68391-01-5 <0.1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Remove all sources of ignition. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 5 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 1028 of 1069 Page 1028 of 1069 Page 1028 of 1069 Page 1028 of 1069 ---PAGE BREAK--- 6343 - TNT FOAMING DISINFECTANT CLEANER Revision Date: 08-May-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: Colorless Odor: Mint fragrance pH: 10.5-11.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 99 °C / 210 °F Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.01 (Product without propellant) Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 1029 of 1069 Page 1029 of 1069 Page 1029 of 1069 Page 1029 of 1069 ---PAGE BREAK--- 6343 - TNT FOAMING DISINFECTANT CLEANER Revision Date: 08-May-2015 Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 75960 mg/kg ATEmix (dermal): 53016 mg/kg ATEmix (inhalation-gas): 6292528 mg/l ATEmix (inhalation-dust/mist): 491.2 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available diethylene glycol monobutyl ether 112-34-5 = 3384 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) Not Available N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h tetrapotassium pyrophosphate 7320-34-5 Not Available > 4640 mg/kg ( Rabbit ) Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea diethylene glycol monobutyl ether 112-34-5 100: 96 h Desmodesmus subspicatus mg/L EC50 1300: 96 h Lepomis macrochirus mg/L LC50 static Not Available 2850: 24 h Daphnia magna mg/L EC50 100: 48 h Daphnia magna mg/L EC50 tetrapotassium pyrophosphate 7320-34-5 Not Available 100: 96 h mykiss mg/L LC50 Not Available 100: 48 h water flea mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Page 4 / 5 Aerosols Hazard Class: 2.1 Page 1030 of 1069 Page 1030 of 1069 Page 1030 of 1069 Page 1030 of 1069 ---PAGE BREAK--- 6343 - TNT FOAMING DISINFECTANT CLEANER Revision Date: 08-May-2015 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product contains the following listed substances: diethylene glycol monobutyl ether CAS No 112-34-5 applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substituted phenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, Chemical Category N230 SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: Yes Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ethanol - 64-17-5 Carcinogen Developmental WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. EPA Pesticide Registration Number: 5741-14 EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Caution. Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling. 16. OTHER INFORMATION Revision Date: 08-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 2 Physical Hazards: 2 Page 1031 of 1069 Page 1031 of 1069 Page 1031 of 1069 Page 1031 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET TRIAD II DISINFECTANT CLEANER Version Number: 1 Preparation date: 2006-03-01 Personal protective equipment NFPA HMIS Reactivity 0 Health Fire Hazard 3 0 0 3 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: TRIAD II DISINFECTANT CLEANER MSDS 113961001 Product code: 113961001, 113961X, 54336, 53957, 53958 Recommended use: Disinfectant. This product is intended to be diluted prior to use. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: Corrosive. Causes permanent eye damage, including blindness. Skin contact: Corrosive. Causes permanent damage . Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Ingestion: Corrosive. Causes burns to mouth, throat and stomach. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % LD50 Oral LD50 Dermal LC50 Inhalation N-alkyl Dimethyl Benzyl Ammonium Chloride 68424-85-1 1 - 5% 426 mg/kg (rat) Not available Not available Octyl decyl dimethyl ammonium chloride 68424-95-5 1 - 5% Not available Not available Not available Ethyl alcohol 64-17-5 0.1 - 1.5% 7060 mg/kg (rat) Not available 20 g/kg/10H (rat) 4. FIRST AID MEASURES Eye contact: Immediately flush eyes with running water for at least 15-20 minutes, keeping eyelids open. Get medical attention immediately. Skin contact: Flush immediately with plenty of water for at least 15-20 minutes. Get medical attention immediately. Inhalation: If breathing is affected, remove to fresh air. Get medical attention immediately. Ingestion: If swallowed, give a cupful of water or milk. THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptable to irritating effects 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Not applicable Specific hazards: Not applicable Unusual hazards: None known Specific methods: No special methods required EMERGENCY OVERVIEW DANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS. HARMFUL OR FATAL IF SWALLOWED. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com TRIAD II DISINFECTANT CLEANER Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] 1 of 3 Page 1032 of 1069 Page 1032 of 1069 Page 1032 of 1069 Page 1032 of 1069 ---PAGE BREAK--- Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Use appropriate containment to avoid environmental contamination. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF THE REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained. Personal Protective Equipment Eye protection: Chemical splash goggles. Hand protection: Chemical resistant gloves Skin and body protection: Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear. Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice Ingredient(s) CAS # ACGIH OSHA Mexico Ethyl alcohol 64-17-5 1000 ppm (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Elemental Phosphorous: 0 10. STABILITY AND REACTIVITY Stability: The product is stable. Polymerization: Hazardous polymerization does not occur. Hazardous decomposition products: None reasonably foreseeable. 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 estimated to be greater than 5000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known pH: Solubility in other solvents: No information available Evaporation rate: No information available 12.6 Odor: Minty Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: 1.024 10 Melting point/range: Not determined Bulk density: Density: 1.024 Appearance: Decomposition temperature: Not determined Liquid VOC: 1.4 No information available Autoignition temperature: No information available Vapor density: Flash point: >200 >93.3 No information available Viscosity: No information available Liquid Solubility: Soluble Color: TRIAD II DISINFECTANT CLEANER Partition coefficient (n-octanol/water): No information available 2 of 3 Clear Green Page 1033 of 1069 Page 1033 of 1069 Page 1033 of 1069 Page 1033 of 1069 ---PAGE BREAK--- Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal ordinances regarding disposal of pesticide wastes. 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Ethyl alcohol 64-17-5 X X X X N-alkyl Dimethyl Benzyl Ammonium Chloride 68424-85-1 - - - - Water 7732-18-5 - - - - Tetrasodium salt of EDTA 64-02-8 - - - - polyethoxyethanol 26027-38-3 - - - - Octyl decyl dimethyl ammonium chloride 68424-95-5 - - - - CERCLA / SARA None Canada WHMIS hazard class: E Corrosive material . Ingredient(s) CAS # NPRI Ethyl alcohol 64-17-5 X polyethoxyethanol 26027-38-3 X DIN No. : 02164078 PCP No. : 24161 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 TRIAD II DISINFECTANT CLEANER Page 1034 of 1069 Page 1034 of 1069 Page 1034 of 1069 Page 1034 of 1069 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Soy Broth CAS Number: Manufacturer: BD DIAGNOSTIC SYSTEMS SDS Date: 3/24/2014 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=24aw3Js6NwA%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 1035 of 1069 Page 1035 of 1069 Page 1035 of 1069 Page 1035 of 1069 ---PAGE BREAK--- Material Safety Data Sheet Product and company identification 1 . EU31900017 Product code : U.V CHARCOL WISER R1 (800) 424-9300 (703) 527-3887 (International) Sun Chemical Corporation 631 Central Avenue Carlstadt, NJ 07072 Product name Material uses Manufacturer/ Distributor In case of emergency : : : : Regulatory information Canada: (905) 796-2222 US: (201) 933-4500 : Other information (513) 830-8500 : 8/14/2014. : Date of revision Printing. Colorant. Hazardous Material Information System 2 1 1 * Health Fire hazard Reactivity Personal protection Hazards identification 2 . Physical state Solid. : Color : Black. Emergency overview Warning! : Routes of entry Potential acute health effects Irritating to respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Irritating to eyes. Harmful if swallowed. Irritating to skin. May cause sensitization by skin contact. Eyes Skin Inhalation May be harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Avoid exposure - obtain special instructions before use. Do not ingest. Do not get on skin or clothing. Avoid contact with eyes. Contains material which may cause birth defects, based on animal data. Contains material which may cause developmental abnormalities, based on animal data. Avoid exposure during pregnancy. Contains material which may impair male fertility, based on animal data. Use only with adequate ventilation. Keep container closed and sealed until ready for use. Wash thoroughly after handling. : : : : Medical conditions aggravated by over-exposure Pre-existing skin disorders may be aggravated by over-exposure to this product. : Carcinogenic effects Mutagenic effects Teratogenicity / Reproductive toxicity Contains material which may cause birth defects, based on animal data. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Dermal contact. Inhalation. OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Ingestion Potential chronic health effects(Long term exposure) Target organs : Contains material which may cause damage to the following organs: lungs, cardiovascular system, upper respiratory tract, eyes. 18- March- 2015 Page: 1/7 en - US Page 1036 of 1069 Page 1036 of 1069 Page 1036 of 1069 Page 1036 of 1069 ---PAGE BREAK--- EU31900017 Hazards identification 2 . See toxicological information (Section 11) Composition/information on ingredients 3 . Epoxy Acrylate Oligomer GPI-TSRN 004 10 - 25 Proprietary Acrylate Oligomer Proprietary 5 - 10 Acrylate Oligomer 80100015-5078P 5 - 10 Acrylated Oligomer 5 - 10 Alkyl Acrylate Ester 5 - 10 Acrylate Oligomer Proprietary 5 - 10 Polyester Acrylate Oligomer 80100015-5043P 2.5 - 5 Multi-Functional Acrylate Ester 1 - 2.5 Propoxylated Glyceryl Triacrylate 52408-84-1 1 - 2.5 Substituted Hetrocyclic Propanone 71868-10-5 1 - 2.5 Modiified Phenyl Butanone Proprietary 1 - 2.5 Hazardous ingredients CAS number % First aid measures 4 . Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if irritation develops. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. In case of accidental skin contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of skin. In case of accidental eye contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of the eyes. Fire-fighting measures 5 . Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides sulfur oxides halogenated compounds metal oxide/oxides Use an extinguishing agent suitable for the surrounding fire. Flammability of the product Products of combustion Extinguishing media : : Suitable : No specific fire or explosion hazard. 18- March- 2015 Page: 2/7 en - US Page 1037 of 1069 Page 1037 of 1069 Page 1037 of 1069 Page 1037 of 1069 ---PAGE BREAK--- EU31900017 Fire-fighting measures 5 . isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : Special exposure hazards : None known. Not suitable : IIIB : Flammability (OSHA criteria) Flash point Lowest known value: >93.3°C (200°F) (Closed cup) : Accidental release measures 6 . No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : Methods for cleaning up : Handling and storage 7 . Put on appropriate personal protective equipment (see Section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used, without Personal Protective Equipment measures. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not get in eyes or on skin or clothing. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Handling : Storage : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Keep away from direct sunlight or strong incandescent light. Exposure controls/personal protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Personal protection Consult local authorities for acceptable exposure limits. : 8 . Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Eyes 18- March- 2015 Page: 3/7 en - US Page 1038 of 1069 Page 1038 of 1069 Page 1038 of 1069 Page 1038 of 1069 ---PAGE BREAK--- EU31900017 Exposure controls/personal protection 8 . In case of inadequate ventilation wear respiratory protection. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. : Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Skin Respiratory Hands Lowest known value: 132°C (273°F) Solid. 900 to 1000°C (1652 to 1832°F) This is based on data for the following ingredient: Talc , not containing asbestiform fibres. Weighted average: 395.45°C (743.8°F) 1.158 g/cm³ (9.661 lbs/gal) Highest known value: >1 (Air = 1) (Epoxy Acrylate Oligomer). Not available. Black. Boiling/condensation point Melting/freezing point <1 (Epoxy Acrylate Oligomer) compared with butyl acetate Physical and chemical properties Physical state Density Vapor density Evaporation rate Odor Color 0.09% VOC : : : : : : : : : Flash point : Lowest known value: >93.3°C (200°F) (Closed cup) Lowest known value: >113.2°C (>235.8°F) (2-benzyl-2-dimethylamino- 4-morpholinobutyrophenone). : Auto-ignition temperature 9 . 0% The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : : : 10 . Conditions of reactivity : May polymerize on exposure to light. Reactivity - Light : Toxicological information 11 . Acute toxicity Tripropylene Glycol Diacrylate LD50 Intraperitoneal Rat 345 mg/kg - LD50 Oral Rat 6200 mg/kg - Trimethylolpropane Ethoxy Triacrylate LD50 Dermal Rabbit >13 g/kg - LD50 Intraperitoneal Rat 450 mg/kg - 2-benzyl-2-dimethylamino- 4-morpholinobutyrophenone LD50 Oral Rat >5000 mg/kg - Product/ingredient name Result Species Dose Exposure 18- March- 2015 Page: 4/7 en - US Page 1039 of 1069 Page 1039 of 1069 Page 1039 of 1069 Page 1039 of 1069 ---PAGE BREAK--- EU31900017 Toxicological information 11 . Conclusion/Summary : No known significant effects or critical hazards. Chronic toxicity Conclusion/Summary : No known significant effects or critical hazards. Carcinogenicity Conclusion/Summary : No known significant effects or critical hazards. Mutagenicity Conclusion/Summary : No known significant effects or critical hazards. Teratogenicity 2-benzyl-2-dimethylamino- 4-morpholinobutyrophenone Equivocal - Unreported Mammal - species unspecified - - Substituted Hetrocyclic Propanone Positive - Oral Rat - Male, Female - - Product/ingredient name Result Species Dose Exposure Conclusion/Summary : No known significant effects or critical hazards. Reproductive toxicity Product/ingredient name Maternal toxicity Fertility Development toxin Species Conclusion/Summary : No known significant effects or critical hazards. Dose Exposure Substituted Hetrocyclic Propanone - Positive - Rat - Male, Female Oral - Ecological information Environmental effects : No known significant effects or critical hazards. 12 . Aquatic ecotoxicity Conclusion/Summary : Not available. Biodegradability Conclusion/Summary : Not available. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal Disposal considerations : 13 . Refer to protective measures listed in sections 7 and 8. Empty containers or liners may retain some product residues. Transport information 14 . Not regulated. 18- March- 2015 Page: 5/7 en - US Page 1040 of 1069 Page 1040 of 1069 Page 1040 of 1069 Page 1040 of 1069 ---PAGE BREAK--- EU31900017 Regulatory information 15 . Irritating material Sensitizing material Target organ effects HCS Classification U.S. Federal regulations : : TSCA 8(a) CDR Exempt/Partial exemption: Not determined TSCA 8(a) PAIR: Acrylated Oligomer; 4-Methoxyphenol; Adduct SARA 302/304: No products were found. SARA 311/312 Hazards identification: Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Water Act (CWA) 307: toluene; Pigment Blue 15:3 Clean Water Act (CWA) 311: toluene International lists SARA 313 Product name CAS number Concentration SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. None identified. Supplier notification : CONEG : In compliance. Canada inventory: At least one component is not listed. Australia inventory (AICS): At least one component is not listed. China inventory (IECSC): At least one component is not listed. Japan inventory: At least one component is not listed. Korea inventory: At least one component is not listed. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): At least one component is not listed. International lists : TSCA 8(b) inventory : Listed Not listed TSCA commerce control list: Europe Inventory: Please contact your supplier to get the information. Other information CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF SWALLOWED. POSSIBLE BIRTH DEFECT HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE BIRTH DEFECTS, BASED ON ANIMAL DATA. POSSIBLE DEVELOPMENTAL HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE ADVERSE DEVELOPMENTAL EFFECTS, BASED ON ANIMAL DATA. POSSIBLE REPRODUCTIVE HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS IN MALES, BASED ON ANIMAL DATA. Label requirements : Notice to reader Version 4 : 16 . Hazardous Material Information System 2 1 1 * Health Fire hazard Reactivity Personal protection : EU31900017 To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 18- March- 2015 Page: 6/7 en - US Page 1041 of 1069 Page 1041 of 1069 Page 1041 of 1069 Page 1041 of 1069 ---PAGE BREAK--- EU31900017 Other information 16 . 18- March- 2015 Page: 7/7 en - US Page 1042 of 1069 Page 1042 of 1069 Page 1042 of 1069 Page 1042 of 1069 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 Safety Data Sheet 1. Identification Product Information: M282-3928 Product Name: ULTRA® MARK ICELAND DAWN Recommended Use: Surface Preparation or Protection Mohawk Finishing Products Division of RPM Wood Finishes Group, Inc. 22 South Center Street Hickory, NC 28602 USA Supplied by: Company Phone No: (800) 522-8266 Emergency Phone No. CHEMTREC: (800) 424-9300 (703) 527-3887 (Collect calls are accepted) International Emergency No. CHEMTREC: 2. Hazards Identification GHS Classification Carc. 1B, Eye Dam. 1, Flam. Liq. 2, Muta. 1B, Skin Irrit. 2 Symbol(s) of Product Signal Word Danger GHS HAZARD STATEMENTS Flammable Liquid, category 2 H225 Highly flammable liquid and vapour. Skin Irritation, category 2 H315 Causes skin irritation. Serious Eye Damage, category 1 H318 Causes serious eye damage. Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Carcinogenicity, category 1B H350 May cause cancer. GHS LABEL PRECAUTIONARY STATEMENTS P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container closed. P264 Wash hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Page 1 / 7 Page 1043 of 1069 Page 1043 of 1069 Page 1043 of 1069 Page 1043 of 1069 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. GHS SDS PRECAUTIONARY STATEMENTS P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. 3. Composition/Information on ingredients Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements ethanol 64-17-5 40-55 GHS02 H225 butanol 71-36-3 10-25 GHS02-GHS05- GHS07 H226-302-315-318-332-335-336 pm acetate 108-65-6 10-25 GHS02-GHS07 H226-332 titanium dioxide 13463-67-7 2.5-10 No Information No Information isopropanol 67-63-0 1.0-2.5 GHS02-GHS07 H225-302-319-336 carbon black 1333-86-4 1.0-2.5 GHS02 H251 aliphatic hydrocarbons 8052-41-3 0.1-1.0 GHS08 H304-340-350-372 aliphatic petroleum distillates 64742-88-7 0.1-1.0 GHS06-GHS08 H304-331-372 100-41-4 0.1-1.0 GHS02-GHS07- GHS08 H225-304-332-373 The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section. 4. First-aid Measures FIRST AID - EYE CONTACT: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. FIRST AID - SKIN CONTACT: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. FIRST AID - INGESTION: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. FIRST AID - INHALATION: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. 5. Fire-fighting Measures SPECIAL FIREFIGHTING PROCEDURES: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly Page 2 / 7 Page 1044 of 1069 Page 1044 of 1069 Page 1044 of 1069 Page 1044 of 1069 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. FIREFIGHTING EQUIPMENT: This is a NFPA/OSHA Class 1B or less flammable liquid. Follow NFPA30, Chapter 16 for fire protection and fire suppression. Use a dry chemical, carbon dioxide, or similar ABC fire extinguisher for incipeint fires. Water may be used to cool and prevent rupture of containers that are exposed to heat from fire. 6. Accidental Release Measures ENVIRONMENTAL MEASURES: No Information STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage system or open waterways. 7. Handling and Storage HANDLING: Avoid inhalation and contact with eyes, skin, and clothing. Wash hands thoroughly after handling and before eating or drinking. In keeping with safe handling practices, avoid ignition sources (smoking, flames, pilot lights, electrical sparks); ground and bond containers when transferring the material to prevent static electricity sparks that could ignite vapor and use spark proof tools and explosion proof equipment. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can potentially cause an explosion that may lead to injury. STORAGE: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. 8. Exposure Controls/Personal Protection Ingredients with Occupational Exposure Limits Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING ethanol N.D. 1000 ppm 1000 ppm N.D. butanol 20 ppm N.D. 100 ppm N.D. pm acetate N.D. N.D. N.D. N.D. titanium dioxide 10 mg/m3 N.D. 15 mg/m3 N.D. isopropanol 200 ppm 400 ppm 400 ppm N.D. carbon black 3 mg/m3 N.D. 3.5 mg/m3 N.D. aliphatic hydrocarbons 100 ppm N.D. 500 ppm N.D. aliphatic petroleum distillates N.D. N.D. N.D. N.D. 20 ppm N.D. 100 ppm N.D. Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation Sk = Skin Sensitizer N.E. = Not Established N.D. = Not Determined Personal Protection RESPIRATORY PROTECTION: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying Page 3 / 7 Page 1045 of 1069 Page 1045 of 1069 Page 1045 of 1069 Page 1045 of 1069 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 respirators may not provide adequate protection. SKIN PROTECTION: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. EYE PROTECTION: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. OTHER PROTECTIVE EQUIPMENT: No Information HYGIENIC PRACTICES: It is good practice to avoid contact with the product and/or its vapors, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. 9. Physical and Chemical Properties Colored Liquid LIQUID Appearance: Physical State: Moderately Strong Alcohol Not determined Odor: Odor Threshold: 0.916 Not determined Density, g/cm3: pH: Not determined Not determined Freeze Point, Viscosity: Not determined Partition Coefficient, n-octanol/ water: Not determined Solubility in Water: Not determined Not determined Decomposition temperature, Explosive Limits, > 100 °F 55 ° F Boiling Range, Flash Point, Supports Combustion Not determined Combustibility: Auto-Ignition Temperature, Faster than Diethyl Ether Not determined Evaporation Rate: Vapor Pressure, mmHg: Not determined Vapor Density: N.I. = No Information 10. Stability and reactivity STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Heat, flames and sparks. INCOMPATIBILITY: Acids, Bases, Oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: Not determined. Page 4 / 7 Page 1046 of 1069 Page 1046 of 1069 Page 1046 of 1069 Page 1046 of 1069 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 11. Toxicological information Practical Experiences EMERGENCY OVERVIEW: No Information EFFECT OF OVEREXPOSURE - EYE CONTACT: No Information EFFECT OF OVEREXPOSURE - INGESTION: No Information EFFECT OF OVEREXPOSURE - INHALATION: No Information EFFECT OF OVEREXPOSURE - SKIN CONTACT: No Information CARCINOGENICITY: May cause cancer. This product contains Titanium Dioxide, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This classification is relevant when exposed to titanium dioxide in dust or powder form only, including cured product that is subject to sanding, grinding, cutting, or other surface preparation activities. PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Skin Contact Acute Toxicity Values The acute effects of this product have not been tested. Data on individual components are tabulated below CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 64-17-5 ethanol 7060 mg/kg Rat N.I. 124.7 mg/L Rat 71-36-3 butanol 700 mg/kg Rat 3402 mg/kg Rabbit 8000 mg/l Rat 108-65-6 pm acetate 8532 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L 13463-67-7 titanium dioxide >10000 mg/kg Rat >10000 mg/kg Rabbit >20 mg/l 67-63-0 isopropanol 1870 mg/kg Rat 4059 mg/kg Rabbit 72.6 mg/L Rat 1333-86-4 carbon black >5000 mg/kg Rat >3000 mg/kg Rabbit >20 mg/l 8052-41-3 aliphatic hydrocarbons >5000 mg/kg Rat >3160 mg/kg Rat 21 mg/L Rat 64742-88-7 aliphatic petroleum distillates >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat 100-41-4 3500 mg/kg Rat 15400 mg/kg Rabbit 17.2 mg/L Rat N.I. = No Information 12. Ecological information ECOLOGICAL INFORMATION: Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. 13. Disposal Information Product DISPOSAL METHOD: Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, Page 5 / 7 Page 1047 of 1069 Page 1047 of 1069 Page 1047 of 1069 Page 1047 of 1069 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage system or open waterways. 14. Transport Information SPECIAL TRANSPORT PRECAUTIONS: No Information DOT: CONSUMER COMMODITY IATA: ID8000, CONSUMER COMMODITY, 9 IMDG: LIMITED QUANTITY UN1263 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Fire Hazard, Acute Health Hazard, Chronic Health Hazard SARA SECTION 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. butanol 71-36-3 isopropanol 67-63-0 TOXIC SUBSTANCES CONTROL ACT This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA components exist in this product. U.S. State Regulations: CALIFORNIA PROPOSITION 65 CARCINOGENS WARNING: This product contains a chemical known to the State of California to cause cancer. CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Page 6 / 7 Page 1048 of 1069 Page 1048 of 1069 Page 1048 of 1069 Page 1048 of 1069 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M282-3928 16. Other Information 5/16/2015 Supersedes Date: Revision Date: 7/4/2015 Reason for revision: Product Composition Changed Datasheet produced by: Regulatory Department HMIS Ratings: Health: 2 Flammability: 3 Reactivity: 0 Personal Protection: X Volatile Organic Compounds, gr/ltr: 683 Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H251 Self-heating: may catch fire. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS02 GHS05 GHS06 GHS07 GHS08 The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions and recommendations are not followed. Page 7 / 7 Page 1049 of 1069 Page 1049 of 1069 Page 1049 of 1069 Page 1049 of 1069 ---PAGE BREAK--- Page 1050 of 1069 Page 1050 of 1069 Page 1050 of 1069 Page 1050 of 1069 ---PAGE BREAK--- Page 1051 of 1069 Page 1051 of 1069 Page 1051 of 1069 Page 1051 of 1069 ---PAGE BREAK--- Page 1052 of 1069 Page 1052 of 1069 Page 1052 of 1069 Page 1052 of 1069 ---PAGE BREAK--- Windex -40°C Windshield Washer Fluid Safety Data Sheet Product Identifier Windex -40°C Windshield Washer Fluid Other Means of Identification 35-207WD, 35-207WD-2P, 35-207WD-PRO, 35-207WD-PRO2 Recochem Inc., 850 Montee de Liesse, Montreal, QC, H4T 1P4, Compliance and Regulatory Department, [PHONE REDACTED], www.recochem.com Recommended Use SDS No. Emergency Phone No. SECTION 1. IDENTIFICATION Manufacturer / Supplier Please refer to Product label. 1470 CANUTEC, [PHONE REDACTED], 24 Hours Restrictions on Use None known. GHS Label Elements SECTION 2. HAZARDS IDENTIFICATION Signal Word: Danger Hazard Statement(s): H226 Flammable liquid and vapour. H301 Toxic if swallowed. H311 Toxic in contact with skin. H331 Toxic if inhaled. H370 Causes damage to organs (eyes) if swallowed. Precautionary Statement(s): Prevention: P210 Keep away from heat, sparks, open flames, and hot surfaces. – No smoking. P233 Keep container closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical, ventilating, lighting, and other equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe fume, mist, vapours, spray. P264 Wash hands and skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. GHS Classification Flammable liquid - Category 3; Acute toxicity (Oral) - Category 3; Acute toxicity (Dermal) - Category 3; Acute toxicity (Inhalation) - Category 3; Specific target organ toxicity (single exposure) - Category 1 SDS No.: Date of Preparation: 1470 Page of 08 01 July 14, 2015 Product Identifier: Windex -40°C Windshield Washer Fluid Page 1053 of 1069 Page 1053 of 1069 Page 1053 of 1069 Page 1053 of 1069 ---PAGE BREAK--- P280 Wear protective gloves/protective clothing. Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE/doctor. P330 Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P312 Call a POISON CENTRE/doctor if you feel unwell. P363 Wash contaminated clothing before reuse. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTRE/doctor if you feel unwell. P321 Specific treatment (see supplemental first aid instruction on this label). P370 + P378 In case of fire: Use appropriate foam, carbon dioxide, dry chemical powder, water spray or fog to extinguish. Storage: Store in a well ventilated place. Keep cool. Keep container closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable regional, national and local laws and regulations. Other Hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Other Identifiers % Mixture: Methanol 67-56-1 30-60 Notes The specific chemical identity and/or exact percentage of composition (concentration) has been withheld as a trade secret. Inhalation Take precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment). Remove source of exposure or move to fresh air. Keep at rest in a position comfortable for breathing. If breathing has stopped, trained personnel should begin rescue breathing. If the heart has stopped, trained personnel should start cardiopulmonary resuscitation (CPR) or automated external defibrillation (AED). Avoid mouth-to-mouth contact by using a barrier device. Get medical advice/attention if you feel unwell or are concerned. Skin Contact Avoid direct contact. Wear chemical protective clothing if necessary. Take off immediately contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. Get medical advice/attention if you feel unwell or are concerned. Thoroughly clean clothing, shoes and leather goods before reuse or dispose of safely. Eye Contact Avoid direct contact. Wear chemical protective gloves if necessary. Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for at least 30 minutes, while holding the eyelid(s) open. If eye irritation persists, get medical advice/attention. SECTION 4. FIRST-AID MEASURES First-aid Measures SDS No.: Date of Preparation: 1470 Page of 08 02 July 14, 2015 Product Identifier: Windex -40°C Windshield Washer Fluid Page 1054 of 1069 Page 1054 of 1069 Page 1054 of 1069 Page 1054 of 1069 ---PAGE BREAK--- Ingestion Rinse mouth with water. Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Do not induce vomiting. If vomiting occurs naturally, lie on your side in the recovery position. Rinse mouth with water again. If breathing has stopped, trained personnel should immediately begin rescue breathing. If the heart has stopped, trained personnel should start cardiopulmonary resuscitation (CPR) or automated external defibrillation (AED). Avoid mouth-to-mouth contact by using a barrier device. Immediately call a Poison Centre or doctor. Treatment is urgently required. Special Instructions Acute exposure to methanol, either through ingestion or breathing high airborne concentrations can result in appearing between 40 minutes and 72 hours after exposure. and signs are usually limited to CNS, eyes and gastrointestinal tract. Because of the initial CNS’s effects of headache, vertigo, lethargy and confusion, there may be an impression of ethanol intoxication. Blurred vision, decreased acuity and photophobia are common complaints. Treatment with ipecac or lavage is indicated in any patient presenting within two hours of ingestion. A profound metabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a more accurate measure of severity than serum methanol levels. Treatment protocols are available from most major hospitals and early collaboration with appropriate hospitals is recommended. Immediate Medical Attention and Special Treatment Medical Conditions Aggravated by Exposure Respiratory conditions. Target Organs Eyes, liver, nervous system. Most Important and Effects, Acute and Delayed No specific treatment. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Extinguishing Media Suitable Extinguishing Media Carbon dioxide, dry chemical powder or appropriate foam. Special "alcohol resistant fire-fighting foams". Unsuitable Extinguishing Media Water is not effective for extinguishing a fire. It may not cool product below its flash point. Specific Hazards Arising from the Chemical Highly flammable liquid and vapour. Can ignite at room temperature. Releases vapour that can form explosive mixture with air. Can be ignited by static discharge. Can accumulate static charge by flow, splashing or agitation. Even dilute solutions in water may be flammable. May travel a considerable distance to a source of ignition and flash back to a leak or open container. See Section 9 (Physical and Chemical Properties) for flash point and explosive limits. Burns with an invisible flame. May accumulate in hazardous amounts in low-lying areas especially inside confined spaces, resulting in a fire hazard. In a fire, the following hazardous materials may be generated: toxic chemicals; very toxic carbon monoxide, carbon dioxide; very toxic, flammable formaldehyde. Special Protective Equipment and Precautions for Fire-fighters Review Section 6 (Accidental Release Measures) for important information on responding to leaks/spills. See Skin Protection in Section 8 (Exposure Controls/Personal Protection) for advice on suitable chemical protective materials. SECTION 5. FIRE-FIGHTING MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Evacuate downwind locations. Use the personal protective equipment recommended in Section 8 of this safety data sheet. Increase ventilation to area or move leaking container to a well-ventilated and secure area. Eliminate all ignition SECTION 6. ACCIDENTAL RELEASE MEASURES SDS No.: Date of Preparation: 1470 Page of 08 03 July 14, 2015 Product Identifier: Windex -40°C Windshield Washer Fluid Page 1055 of 1069 Page 1055 of 1069 Page 1055 of 1069 Page 1055 of 1069 ---PAGE BREAK--- sources. Use grounded, explosion-proof equipment. May accumulate in hazardous amounts in low-lying areas especially inside confined spaces, if ventilation is not sufficient. Distant ignition and flashback are possible. Environmental Precautions Do not allow into any sewer, on the ground or into any waterway. Methods and Materials for Containment and Cleaning Up Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Precautions for Safe Handling Put on appropriate personal protective equipment (see section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. Conditions for Safe Storage Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. SECTION 7. HANDLING AND STORAGE SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ACGIH TLV® OSHA PEL Chemical Name TWA STEL TWA Ceiling Control Parameters AIHA WEEL 8-hr TWA TWA Methanol 200 ppm 250 ppm 200 ppm 250 ppm Appropriate Engineering Controls Individual Protection Measures Skin Protection Respiratory Protection Eye/Face Protection Wear chemical protective clothing e.g. gloves, aprons, boots. Nitrile rubber. Wear chemical safety goggles. General ventilation is usually adequate. For large scale use of this product: do not allow product to accumulate in the air in work or storage areas, or in confined spaces. Use local exhaust ventilation, if general ventilation is not adequate to control amount in the air. Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product is used and stored. Control static electricity discharges which includes bonding of equipment to ground. Use only non-combustible, compatible materials for walls, floors, ventilation system, air cleaning devices, pallets, shelving. Provide safety shower in work area, if contact or splash hazard exists. SDS No.: Date of Preparation: 1470 Page of 08 04 July 14, 2015 Product Identifier: Windex -40°C Windshield Washer Fluid Page 1056 of 1069 Page 1056 of 1069 Page 1056 of 1069 Page 1056 of 1069 ---PAGE BREAK--- Not normally required if product is used as directed. For non-routine or emergency situations: wear a NIOSH approved air-purifying respirator with an organic vapour cartridge. pH 8 - 11 (100% solution) Appearance Clear blue liquid. Partition Coefficient, n-Octanol/Water (Log Kow) Not available Odour Pungent Vapour Pressure Not available Odour Threshold Not available Vapour Density (air = 1) Not available Initial Boiling Point/Range Not available Evaporation Rate Not available Flash Point 27.7 ºC (81.9 ºF) (closed cup) Melting Point/Freezing Point Not available (melting); -40 ºC (-40 ºF) (freezing) Relative Density (water = 1) 0.9350 - 0.9360 at 20 ºC Upper/Lower Flammability or Explosive Limit Not available (upper); Not available (lower) Solubility Soluble in water; Soluble in all proportions in alcohols (e.g. ethanol). Auto-ignition Temperature Not available SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Molecular Weight Not available Not available Decomposition Temperature Viscosity Not available (kinematic); Not available (dynamic) Basic Physical and Chemical Properties Liquid Physical State Other Information Flammability (solid, gas) Not applicable Chemical Stability Normally stable. Conditions to Avoid Heat. Open flames, sparks, static discharge, heat and other ignition sources. Incompatible Materials reactive or incompatible with the following materials: oxidizing agents (e.g. peroxides), strong acids (e.g. hydrochloric acid), strong bases (e.g. sodium hydroxide). Not corrosive to metals. Hazardous Decomposition Products Very toxic carbon monoxide, carbon dioxide; very toxic, flammable formaldehyde. Possibility of Hazardous Reactions None known. SECTION 10. STABILITY AND REACTIVITY Reactivity None known. SDS No.: Date of Preparation: 1470 Page of 08 05 July 14, 2015 Product Identifier: Windex -40°C Windshield Washer Fluid Page 1057 of 1069 Page 1057 of 1069 Page 1057 of 1069 Page 1057 of 1069 ---PAGE BREAK--- LC50: Not applicable. LD50 (oral): Not applicable. Skin Corrosion/Irritation Human experience shows very mild irritation. Serious Eye Damage/Irritation Animal tests show serious eye irritation. SECTION 11. TOXICOLOGICAL INFORMATION STOT (Specific Target Organ Toxicity) - Single Exposure Inhalation At high concentrations severe nose and throat irritation. Skin Absorption May be harmful based on animal tests. Ingestion Toxic, can cause death depression of the central nervous system, impaired vision and blindness. In some cases, there may be delayed effects on the nervous system. may include headache, nausea, vomiting, dizziness, drowsiness and confusion. A severe exposure may cause stomach pain, muscle pain, difficult breathing and coma. Vision can be impaired and permanent blindness can result. There may be other permanent effects on the nervous system e.g. tremor, seizures. If swallowed: liver function tests may show abnormal results. STOT (Specific Target Organ Toxicity) - Repeated Exposure Respiratory and/or Skin Sensitization Not known to be a respiratory sensitizer. Not known to be a skin sensitizer. Carcinogenicity May cause cancer based on animal studies. Development of Animal studies show effects on the If inhaled: known to cause: decreased weight, birth defects. Teratogenic(external, soft tissue and skeletal defects) embryotoxic (late resorptions). Reproductive Toxicity Not known to cause effects on sexual function or fertility. Germ Cell Mutagenicity Conclusions cannot be drawn from the limited studies available. LD50 (dermal): Not applicable. Acute Toxicity Sexual Function and Fertility Effects on or via Lactation No information was located. Not known to be an aspiration hazard. Aspiration Hazard Ingestion; eye contact; skin contact; inhalation. Likely Routes of Exposure Chemical Name LC50 LD50 (oral) LD50 (dermal) Methanol 83867.5 mg/m3 (rat) (4-hour exposure) 5628 mg/kg (rat) 15800 mg/kg (rabbit) Chemical Name IARC ACGIH® NTP OSHA Methanol Not Listed Not designated Not Listed Not Listed SDS No.: Date of Preparation: 1470 Page of 08 06 July 14, 2015 Product Identifier: Windex -40°C Windshield Washer Fluid Page 1058 of 1069 Page 1058 of 1069 Page 1058 of 1069 Page 1058 of 1069 ---PAGE BREAK--- Interactive Effects No information was located. This product and its degradation products are not expected to bioaccumulate. No information was located. There is no information available. SECTION 12. ECOLOGICAL INFORMATION Degrades rapidly based on quantitative tests. Toxicity Persistence and Degradability Mobility in Soil Other Adverse Effects Bioaccumulative Potential Chronic Aquatic Toxicity Acute Aquatic Toxicity Chemical Name LC50 Fish EC50 Crustacea ErC50 Aquatic Plants ErC50 Algae Methanol 15400 mg/L (Lepomis macrochirus (bluegill); 96-hour) 10000 mg/L (Daphnia magna (water flea); 48-hour) Chemical Name NOEC Fish EC50 Fish NOEC Crustacea EC50 Crustacea Methanol 7900 mg/L (Lepomis macrochirus (bluegill); 200-hrs) SECTION 13. DISPOSAL CONSIDERATIONS The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal Methods SECTION 14. TRANSPORT INFORMATION UN No. Proper Shipping Name Packing Group Transport Hazard Class(es) Regulation 1230 METHANOL 3 (6.1) II Canadian TDG 1230 METHANOL 3 (6.1) II US DOT Special Precautions for User Please note: In containers of 5 L (5Kg) capacity or less this product is classified as a "Consumer Commodity" under DOT regulations. In containers of 450L or less, this product meets the requirements for exemption under TDG regulation special provisions, part 1, section 1.36b: Class 3, Flammable liquids: Alcohol Exemption. Environmental Hazards Not applicable T t i B lk A di t A II f MARPOL 73/78 d th IBC C d SDS No.: Date of Preparation: 1470 Page of 08 07 July 14, 2015 Product Identifier: Windex -40°C Windshield Washer Fluid Page 1059 of 1069 Page 1059 of 1069 Page 1059 of 1069 Page 1059 of 1069 ---PAGE BREAK--- Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code SECTION 15. REGULATORY INFORMATION Canada Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL) All ingredients are listed on the DSL/NDSL. USA Toxic Substances Control Act (TSCA) Section 8(b) All ingredients are listed on the TSCA Inventory. Additional USA Regulatory Lists California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause birth defects. Safety, Health and Environmental Regulations Additional Information We are committed to uphold the Industry Consumer Ingredient Communication Voluntary Initiative. Please send us your request by visiting our website at www.recochem.com. Ingredients present (intentionally added ingredients) at a concentration of greater than one percent shall be listed in descending order of predominance. Ingredients present at a concentration of not more than one percent shall be listed but may be disclosed without respect to order of predominance. Disclaimer Notice to reader: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. SECTION 16. OTHER INFORMATION SDS Prepared By Compliance and Regulatory Department Phone No. [PHONE REDACTED] Date of Preparation July 14, 2015 SDS No.: Date of Preparation: 1470 Page of 08 08 July 14, 2015 Product Identifier: Windex -40°C Windshield Washer Fluid Page 1060 of 1069 Page 1060 of 1069 Page 1060 of 1069 Page 1060 of 1069 ---PAGE BREAK--- Windex Glass Cleaner with Ammonia-D® SAFETY DATA SHEET Version Number: 2 Preparation date: 2015-05-06 1. IDENTIFICATION Product name: Windex Glass Cleaner with Ammonia-D® Product Code: 3481049, 4601541 SDS MS0800380 Recommended use: • Industrial/Institutional • Glass Cleaner • This product is intended to be diluted prior to use Uses advised against: Uses other than those identified are not recommended Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Classification for the undiluted product This product is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and current Canadian Controlled Products Regulations (CPR). Precautionary Statements May be mildly irritating to eyes and skin. In case of contact, immediately flush with plenty of water. If irritation occurs and persists, get medical attention. Health hazards not otherwise classified (HHNOC) - Not applicable Physical hazards not otherwise classified (PHNOC) - Not applicable 3. COMPOSITION/INFORMATION ON INGREDIENTS Classified Ingredients Ingredient(s) CAS # Weight % Manufacturer, importer, supplier: US Headquarters Diversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.diversey.com Canadian Headquarters Diversey, Inc. - Canada 3755 Laird Road Mississauga, Ontario L5L 0B3 Phone: 1-[PHONE REDACTED] Classification for the diluted product @ 1:8 This product, when diluted as stated on the label, is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and current Canadian Controlled Products Regulations (CPR). Windex Glass Cleaner with Ammonia-D® 1 of 5 Precautionary Statements None required. Page 1061 of 1069 Page 1061 of 1069 Page 1061 of 1069 Page 1061 of 1069 ---PAGE BREAK--- 1,2-Benzisothiazol-3(2H)-one 2634-33-5 < 0.1% *Exact percentages are being withheld as trade secret information 4. FIRST AID MEASURES Undiluted Product: Eyes: In case of contact, immediately flush with plenty of water. If irritation occurs and persists, get medical attention. Skin: In case of contact, immediately flush with plenty of water. If irritation occurs and persists, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: Rinse mouth with water. Most Important No information available. Immediate medical attention and special treatment needed Not applicable. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Specific methods: No special methods required Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Not applicable. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Not relevant to the product itself. Environmental precautions and clean-up methods: Clean-up methods - large spillage. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. Aerosol Level (if applicable) : Not applicable 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines: This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Undiluted Product: Engineering measures to reduce exposure: No special ventilation requirements General room ventilation is adequate Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions. Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Diluted Product: Windex Glass Cleaner with Ammonia-D® 2 of 5 Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention. Skin: Rinse with plenty of water If irritation occurs and persists, get medical attention. Inhalation: No specific first aid measures are required Ingestion: Rinse mouth with water. Page 1062 of 1069 Page 1062 of 1069 Page 1062 of 1069 Page 1062 of 1069 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES: Explosion limits: - upper: Not determined - lower: Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Reactivity: Not Applicable Stability: Stable Hazardous decomposition products: Ammoniacal vapors. Materials to avoid: Do not mix with chlorinated products (such as bleach). Conditions to avoid: Do not mix with any other product or chemical. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure: Skin contact, Inhalation, Eye contact Delayed, immediate, or chronic effects and from short and long-term exposure Skin contact: May be mildly irritating to skin. may include redness and/or transient discomfort. Eye contact: May be mildly irritating to eyes. may include redness, watering and/or transient discomfort. Ingestion: No information available. Inhalation: No information available. Sensitization: No known effects. Target Organs (SE): None known Target Organs (RE): None known Ingredient(s) CAS # NTP IARC OSHA Ethyl alcohol 64-17-5 - Numerical measures of toxicity 12. ECOLOGICAL INFORMATION Ecotoxicity: No information available. Diluted Product: Personal Protective Equipment Eye protection: No personal protective equipment required under normal use conditions. Hand protection: No personal protective equipment required under normal use conditions. Skin and body protection: No personal protective equipment required under normal use conditions. Respiratory protection: No personal protective equipment required under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Physical State: Liquid Color: Clear, Turquoise Evaporation Rate: No information available Odor: Ammonia Odor threshold: No information available. Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Solubility: Completely Soluble Solubility in other solvents: No information available Relative Density (relative to water): 0.999 Density: 8.33 lbs/gal 0.999 Kg/L Vapor density: No information available Bulk density: No information available Vapor pressure: No information available. Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available Dilution Flash Point: > 200 °F > 93.3 °C Viscosity: No information available Elemental Phosphorus: 0 % by wt. VOC: 0.16 % * pH: 11 VOC % by wt. at use dilution 0.02 % * Windex Glass Cleaner with Ammonia-D® 3 of 5 Dilution pH: 10.2 @ 1:8 Flammability (Solid or Gas): Not applicable Metal Corrosion: Not determined Page 1063 of 1069 Page 1063 of 1069 Page 1063 of 1069 Page 1063 of 1069 ---PAGE BREAK--- Persistence and Degradability: No information available. Bioaccumulation: No information available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: This product, as sold, if discarded or disposed, is not a hazardous waste according to Federal regulations (40 CFR 261.4 Dispose in compliance with all Federal, state, provincial, and local laws and regulations. This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations. Contaminated Packaging: Do not re-use empty containers. RCRA Hazard Class (undiluted product): Not Regulated RCRA Hazard Class (diluted product): Not Regulated 14. TRANSPORT INFORMATION DOT/TDG/IMDG: Proper shipping descriptions can vary by pack size. Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information. DOT (Ground) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID IMDG (Ocean) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID 15. REGULATORY INFORMATION International Inventories at CAS# Level All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65. RIGHT TO KNOW (RTK) Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Alcohol ethoxylates 68439-46-3 - - - - Ammonium hydroxide 1336-21-6 X X X X Sodium lauryl sulfate 151-21-3 - - - - Sodium lauryl ether sulfate 9004-82-4 - - - - Ethyl alcohol 64-17-5 X X X - 1,2-Benzisothiazol-3(2H)-one 2634-33-5 - - - - CERCLA/ SARA Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Ammonium hydroxide 1336-21-6 > 0.1% - < 1% 1000 X SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canadian Regulations WHMIS hazard class: Non-controlled. Windex Glass Cleaner with Ammonia-D® 4 of 5 Page 1064 of 1069 Page 1064 of 1069 Page 1064 of 1069 Page 1064 of 1069 ---PAGE BREAK--- 16. OTHER INFORMATION NFPA (National Fire Protection Association) Rating Scale: (Low Hazard) 0 - 4 (Extreme Hazard) Version Number: 2 Preparation date: 2015-05-06 Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: Windex Glass Cleaner with Ammonia-D® 5 of 5 • Does not contain an added fragrance • This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 1065 of 1069 Page 1065 of 1069 Page 1065 of 1069 Page 1065 of 1069 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET WINDEX Super Concentrate Glass Cleaner with Ammonia-D HMIS NFPA Personal protective equipment Health 2 Flammability 0 Physical Hazard / Instability 0 1 0 0 Version Number: 5 Preparation date: 2014-09-18 1. PRODUCT AND COMPANY IDENTIFICATION Product name: WINDEX Super Concentrate Glass Cleaner with Ammonia-D MSDS MS0500051 Product Code: 3481049, 4513567, 4601541 Recommended use: • Industrial/Institutional • Glass Cleaner • This product is intended to be diluted prior to use Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Principal routes of exposure: Skin contact. Inhalation. Eye contact. Eye contact: Moderately irritating to the eyes. Skin contact: May be mildly irritating to skin. Inhalation: None known. Ingestion: May cause irritation to mouth, throat and stomach. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat Alcohol ethoxylates 68439-46-3 0.1 - 1.5% 1400 Not available Not available Ammonium hydroxide 1336-21-6 0.1 - 1.5% 350 Not available Not available Ethyl alcohol 64-17-5 0.1 - 1.5% 7060 Not available =124.7 mg/L (4 h) 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. If irritation persists, get medical attention. Skin contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: If swallowed, give a cupful of water or milk. Manufacturer, importer, supplier: US Headquarters Diversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.diversey.com WINDEX Super Concentrate Glass Cleaner with Ammonia-D 1 of 4 Canadian Headquarters Diversey, Inc. - Canada 3755 Laird Road Mississauga, Ontario L5L 0B3 Phone: 1-[PHONE REDACTED] EMERGENCY OVERVIEW CAUTION. CAUSES EYE IRRITATION. MAY BE MILDLY IRRITATING TO SKIN. Page 1066 of 1069 Page 1066 of 1069 Page 1066 of 1069 Page 1066 of 1069 ---PAGE BREAK--- Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Extinguishing media which must not be used for safety reasons: No information available. Specific hazards: Not applicable. Unusual hazards: None known. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Not relevant to the product itself. Environmental precautions and clean-up methods: Clean-up methods - large spillage. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements General room ventilation is adequate Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Ethyl alcohol 64-17-5 1000 ppm (STEL) 1000 ppm (TWA) 1900 mg/m3 (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Explosion limits: - upper: Not determined - lower: Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: Stable Polymerization: Hazardous polymerization does not occur. Hazardous decomposition products: Ammoniacal vapors. Materials to avoid: Do not mix with chlorinated products (such as bleach). Conditions to avoid: Do not mix with any other product or chemical. 11. TOXICOLOGICAL INFORMATION Physical State: Liquid Bulk density: No information available Appearance: Aqueous solution Evaporation Rate: No information available Specific gravity: 0.999 Color: Clear, Turquoise Vapor density: No information available Odor: Ammonia Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Solubility: Completely Soluble Density: 8.33 lbs/gal 0.999 Kg/L Solubility in other solvents: No information available Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available Viscosity: No information available WINDEX Super Concentrate Glass Cleaner with Ammonia-D 2 of 4 Elemental Phosphorus: 0 % by wt. VOC: 0.15 % * pH: 11 Dilution pH: 10.2 @ 1:8 Page 1067 of 1069 Page 1067 of 1069 Page 1067 of 1069 Page 1067 of 1069 ---PAGE BREAK--- Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg. Component Information: See Section 3. Chronic toxicity: None known Specific effects Carcinogenic effects: • None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known Ingredient(s) CAS # NTP IARC OSHA Ethyl alcohol 64-17-5 - 12. ECOLOGICAL INFORMATION Environmental Information: No data available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: This product, as sold, if discarded or disposed, is not a hazardous waste according to Federal regulations (40 CFR 261.4 Dispose in compliance with all Federal, state, provincial, and local laws and regulations. This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations. RCRA Hazard Class (undiluted product): Not Regulated 15. REGULATORY INFORMATION International Inventories at CAS# Level All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65. RIGHT TO KNOW (RTK) Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Alcohol ethoxylates 68439-46-3 - - - - Ammonium hydroxide 1336-21-6 X X X X Sodium lauryl sulfate 151-21-3 - - - - Sodium lauryl ether sulfate 9004-82-4 - - - - Ethyl alcohol 64-17-5 X X X - CERCLA/ SARA Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Ammonium hydroxide 1336-21-6 0.1 - 1.5% 1000 X SARA 311/312 Hazard Categories Immediate: X Delayed: - Fire: - Reactivity: - 14. TRANSPORT INFORMATION DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information. DOT (Ground) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID WINDEX Super Concentrate Glass Cleaner with Ammonia-D 3 of 4 IMDG (Ocean) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID Page 1068 of 1069 Page 1068 of 1069 Page 1068 of 1069 Page 1068 of 1069 ---PAGE BREAK--- Sudden Release of Pressure: - Canada WHMIS hazard class: D2B Toxic materials. Ingredient(s) CAS # NPRI Ethyl alcohol 64-17-5 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: • This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations • Contains an added fragrance, see "Odor" heading in section 9 for specific description WINDEX Super Concentrate Glass Cleaner with Ammonia-D 4 of 4 Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 1069 of 1069 Page 1069 of 1069 Page 1069 of 1069 Page 1069 of 1069