Document douglascountywi_gov_doc_23dd0a0c82

Safety Data Sheets Pattison Highway Shop Pattison Highway Shop 02/29/2016 ---PAGE BREAK--- Safety Data Sheet Index Binder: Pattison Highway Shop - Pattison Highway Shop 1WVL3 - Graphite Dry Film Lubricant 1 Gal Superior Graphite 02/10/2012 5 41770 OATLEY REGULAR CLEAR PVC SOLVENT CEMENT Oatey Company 03/10/1992 7 6MT43 – PAINT SPRAY SEYMOUR OF SYCAMORE 05/20/2003 11 763 Rust Transformer (Bulk) A.W. Chesterton Company 05/20/2015 13 ANTI SEIZE LUBRICANT Permatex, Inc. 03/01/2005 14 Armor All Detailer’s Advantage Protectant Spray The Armor All/STP Products Company 12/28/2012 21 ATHLETIC FIELD MARKER - WHITE Lawson Products, Inc. 01/08/2014 25 Black Flag Wasp, Hornet & Yellow Jacket Killer CHEMSICO DIV OF UNITED INDUSTRIES CORP 02/25/2015 28 BLASTOUT WINDSHIELD WASHER SOLVENT 67-56-1 BLASTOUT, LLC 06/11/1999 34 Castle Dry Lub Castle Products, Inc. 09/19/2013 36 Citra Clean Total Solutions 08/13/2014 39 DETAIL DEMON AUTO FINISH CLEANER/POLISH Nyco Products Company 01/06/2011 41 Diamond Iron Fighter Salt Blocks 7647-14-5 Cargill Incorporated 12/09/2014 46 Diesel Exhaust Fluid 57-13-6 CF Industries Sales, LLC 06/03/2015 52 Diesel Fuel 64742-80-9 Total Petrochemicals & Refining USA, Inc. 07/22/2015 58 DIESEL FUEL SUPPLEMENT +CETANE BOOST Power Service Products, Inc. 05/30/2015 59 ELECTRA SEAL PLUS AEROSOL Mantek - Division of NCH 09/14/2004 72 Febreze Set & Refresh (Air Freshener) Procter & Gamble 11/20/2014 77 GERMICIDAL CLEANER Claire Manufacturing Company 03/23/2015 83 GLEME GLASS CLEANER Claire Manufacturing Company 05/26/2015 92 Goo Gone Spray Gel Goo Gone 08/14/2014 102 GREAT STUFF Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP The Dow Chemical Company 04/13/2015 108 GREEN KLEEN MULTI-PURPOSE CLEANER Nyco Products Company 04/06/2012 127 Product Name CAS Number Manufacturer Version Date Page Page 2 of 377 Page 2 of 377 Page 2 of 377 Page 2 of 377 ---PAGE BREAK--- DEGREASER GS RESTROOM CLEANER Spartan Chemical Company, Inc. 05/04/2015 129 Health Gards Metered Aerosols -07932 Fresh Garden HOSPECO 05/20/2015 134 Insect Repellent CRC Industries, Inc. 05/21/2015 135 KILZ Color Change Ceiling Paint Masterchem Industries LLC 04/30/2015 145 Kimberly Clark Professional Hand Wipes; Kimberly Clark Professional Heavy Duty Hand Cleaning Wipes; Wypall Waterless Hand Wipes Kimberly-Clark Corporation 09/05/2003 150 KRYLON Industrial QUIK-MARK Solvent-Based Inverted Marking Chalk (APWA) Orange THE SHERWIN-WILLIAMS COMPANY- KRYLON Products Group 03/13/2015 155 KRYLON WEEKEND Spray Paint, All Purpose Grey Primer THE SHERWIN-WILLIAMS COMPANY - KRYLON INDUSTRIAL PRODUCTS GROUP 06/09/2015 170 Liquid Wrench Penetrating Oil RSC Chemical Solutions 05/06/2015 176 Lotion Hand Cleaner with Pumice Malco Products, Inc. 08/24/2012 185 Majestic Bleach 7681-52-9 CHAMPION PACKAGING 05/01/2007 193 Marvel Air Tool Oil Marvel Oil Company 03/10/2015 196 Microburst 3000 & 9000 Air Neutralizer - All Fragrances Rubbermaid Commercial Products 11/04/2013 204 MOBILGREASE XHP 462 Exxon Mobil Corporation 06/05/2015 207 MRO SAFETY YELLOW SEYMOUR OF SYCAMORE 11/07/2014 217 Multi-Purpose Automatic Transmission Fluid Beacon Lubricants, Inc. 06/19/2015 222 Oatey Purple Primer- NSF Listed for PVC and CPVC OATEY CO. 05/27/2015 237 PARTS MASTER PREMIUM POWER STEERING FLUID OMNI Specialty Packaging 01/31/2012 247 POLAR WINDSHIELD WASH & DEICER FLUID -30 Degree F Old World Industries, LLC 10/29/2014 253 POLAR WW SOLVENT 6/1GL Warren Distribution, Inc. 04/02/2015 263 Polymer-Modified MasterSeal (PMM) SealMaster Inc 01/13/2010 270 PROMAR 200 Zero VOC Interior Latex Flat, Ultradeep Base THE SHERWIN WILLIAMS COMPANY 02/25/2011 272 Propane 74-98-6 BERNZ-O-MATIC 06/11/2011 275 PX Super “99” Isopropyl Alcohol 67-63-0 SuperClean Brands, Inc. 12/12/2007 278 QUIK TIP MARKER HIGH GLOSS WHITE Mohawk Finishing Products Division of RPM Wood Finishes 07/04/2015 281 Product Name CAS Number Manufacturer Version Date Page Page 3 of 377 Page 3 of 377 Page 3 of 377 Page 3 of 377 ---PAGE BREAK--- Group, Inc. RAID WASP & HORNET KILLER 33 S.C. Johnson & Son, Inc. 02/23/2015 289 SHINE PLUS Spartan Chemical Company, Inc. 04/16/2015 303 SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M CERTIFIED LABS, DIV. OF NCH CORP. 06/19/2015 308 SUPER GEAR LUBE 150 Tower Oil & Technology 06/23/2015 312 T70Threadlocker SAF-T-LOK INTERNATIONAL CORP. 10/30/2014 316 TDL The Blaster Corporation 06/11/2015 320 TREMPRIME SILICONE POROUS PRIMER Tremco Canada Division 07/07/2012 327 TRI-TRACK CLEAR (AEROSOL) TRI-CHEM CORPORATION 12/19/2005 333 Triple Foam Blue Anti Freeze SIMONIZ USA, Inc. 06/08/2015 335 TWINKLE Stainless Steel Cleaner & Polish JohnsonDiversey, Inc. 06/24/2010 340 United 126 Vandalism Mark Remover United Laboratories Inc. 03/17/2003 344 United 177 Sunshine in a Can United Laboratories Inc. 12/29/2010 346 UNITED 195 SMELL JEL United Laboratories Inc. 12/22/2012 348 UNITED 77 BIATRON United Laboratories Inc. 02/08/2013 350 Unleaded Gasoline Total Petrochemicals & Refining USA, Inc. 07/24/2015 352 Upholstery & Carpet Cleaner STONER INCORPORATED 11/14/2013 364 Wire & Mag Wheel Cleaner Auto Industrial Marine Chemicals, Inc. 09/27/2013 365 Zymol Cleaner Wax ZYMOL ENTERPRISES INC 06/20/2008 373 Product Name CAS Number Manufacturer Version Date Page Page 4 of 377 Page 4 of 377 Page 4 of 377 Page 4 of 377 ---PAGE BREAK--- Page 5 of 377 Page 5 of 377 Page 5 of 377 Page 5 of 377 ---PAGE BREAK--- Page 6 of 377 Page 6 of 377 Page 6 of 377 Page 6 of 377 ---PAGE BREAK--- Page 7 of 377 Page 7 of 377 Page 7 of 377 Page 7 of 377 ---PAGE BREAK--- Page 8 of 377 Page 8 of 377 Page 8 of 377 Page 8 of 377 ---PAGE BREAK--- Page 9 of 377 Page 9 of 377 Page 9 of 377 Page 9 of 377 ---PAGE BREAK--- Page 10 of 377 Page 10 of 377 Page 10 of 377 Page 10 of 377 ---PAGE BREAK--- Page 11 of 377 Page 11 of 377 Page 11 of 377 Page 11 of 377 ---PAGE BREAK--- Page 12 of 377 Page 12 of 377 Page 12 of 377 Page 12 of 377 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: 763 Rust Transformer (Bulk) CAS Number: Manufacturer: A.W. Chesterton Company SDS Date: 5/20/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=tRLAZ%2f3M9MU%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 13 of 377 Page 13 of 377 Page 13 of 377 Page 13 of 377 ---PAGE BREAK--- Click here to go back to MSDS Barnes Distribution 1301 E. 9th Street, #700 Cleveland OH 44114 (800) 726-9626 Material Safety Data Sheet MSDS Form No. : KP150014 Item No. : KP150014, 150014 MATERIAL SAFETY DATA SHEET ANTI SEIZE LUBRICANT Part # KP150014 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS Name: ANTI SEIZE LUBRICANT Product CAS: (none) Product Code: 09175 Synonyms: 150014; ANTI SEIZE LUBRICANT; KP150014 Company Identification: Name: PERMATEX Address: 10 COLUMBUS BLVD Address: City: HARTFORD State: CT Zip: 06106 For information, call: [PHONE REDACTED] Emergency Number: [PHONE REDACTED] Emergency Agency: CHEM-TEL Number: [PHONE REDACTED] MSDS Creation Date: 3/1/2005 Supersedes Date: 6/17/2003 Miscellaneous: SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS Chemical Name CAS MIN MAX DISTILLATED (PET) HYDROTREATED HY NAPHTH 64742-52-5 20 30 CALCIUM OXIDE 1305-78-8 15 25 ALUMINUM POWDER (PYROPHIC) 7429-90-5 5 15 GRAPHIC 7782-42-5 1 10 MINERAL OIL 64741-44-2 1 10 MSDS - KP150014 http://apps.barnesdistribution.com/website/msds.nsf/webview/KP150014ENG?OpenDocument (1 of 7) [5/23/2006 4:05:44 PM] Page 14 of 377 Page 14 of 377 Page 14 of 377 Page 14 of 377 ---PAGE BREAK--- SILICA, QUARTZ 14808-60-7 .1 1 LITHIUM GREASE MIXT-UR-E 30 40 Miscellaneous: ITEM ACGIH 8 HR. TWA OSHA 8 HR. TWA 1 5 MG/M3 MIST 5 MG/M3 MIST 2 2 MG/M3 5 MG/M3 3 METAL DUST, AS AL: 10 MG/M3 TWA TOTAL DUST, AL: 15 MG/M3 TWA; RESPIRABLE FRACTION, AS AL: 5 MG/M3 TWA 4 3 MG/M3 TWA 3 MG/M3 TWA 5 5 MG/M3 TWA 10 MG/M3 TWA 6 0.1 MG/M3 TWA (RESPIRABLE DUST) 0.1 MG/M3 TWA (RESPIRABLE DUST) 7 5 MG/M3 (OIL/MIST) 5 MG/M3 (OIL/MIST) Lbs of VOC per Gallon Coating (minus water): 0 Coating Density (lbs/gal): 0 Solvent Density (lbs/gal): 0 Percent Solvent (volume): 0 Percent Solids (volume): 0 Percent Water (volume): 0 SECTION 3 - HAZARDS IDENTIFICATION NFPA: Health: 1 Fire: 1 Reactivity: 1 Other: HMIS: Health: 1 Fire: 1 Reactivity: 0 Special Protection: POTENTIAL HEALTH EFFECTS Target Organs: Eye: MAY CAUSE EYE IRRITATION. Skin: MAY CAUSE SKIN IRRITATION.REPEATED SKIN CONTACT MAY CAUSE ALLERGIC SKIN REACTIONS. Ingestion: MAY CAUSE GASTROINTESTINAL IRRITATION. Inhalation: MAY CAUSE NOSE, THROAT AND RESPIRATORY IRRITATION.EXCESSIVE ACCIDENTAL EXPOSURE MAY CAUSE HEADACHE, DIZZINESS, NAUSEA AND MILD RESPIRATORY IRRITATION. Miscellaneous: MAY CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MSDS - KP150014 http://apps.barnesdistribution.com/website/msds.nsf/webview/KP150014ENG?OpenDocument (2 of 7) [5/23/2006 4:05:44 PM] Page 15 of 377 Page 15 of 377 Page 15 of 377 Page 15 of 377 ---PAGE BREAK--- SECTION 4 - FIRST AID MEASURES Eye: FLUSH WITH COPIOUS AMOUNTS OF COLD WATER FOR AT LEAST 15 MINUTES AND CONTACT PHYSICIAN. Skin: WASH WITH SOAP AND WATER. Ingestion: CONTAINS ALIPHATIC HYDROCARBONS AND PETROLEUM OIL. DO NOT INDUCE VOMITING. CONTACT PHYSICIAN IMMEDIATELY. MINUTE AMOUNT ASPIRATED INTO LUNGS DURING INGESTION MAY CAUSE SEVERE PULMONARY IN URY. Inhalation: MOVE TO FRESH AIR AND CONTACT PHYSICIAN. IF NOT BREATHING GIVE ARTIFICAL RESPIRATION, PREFERABLY MOUTH TO MOUTH.IF BREATHING IS DIFFICULT GIVE OXYGEN. GET MEDICAL ATTENION. Notes to Physician: SECTION 5 - FIRE FIGHTING MEASURES Unusual Fire and Explosion Hazards: MAY IGNITE WHEN SUFFICIENT HEAT IS APPLIED. Special Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. WATER SPRAY MAY BE INEFFECTIVE ON FLAMES BUT SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL. Extinguishing Media: FOAM, DRY CHEMICAL OR CARBON DIOXIDE. Flash Point: >00 DEG F METHOD: TAG CLOSED CP Flammable Limits: Lower Limit: (LEL):30% ALUM METAL; 1% OIL Upper Limit: (UEL):7% OIL AutoIgnition Temperature: N/D General Information: MSDS - KP150014 http://apps.barnesdistribution.com/website/msds.nsf/webview/KP150014ENG?OpenDocument (3 of 7) [5/23/2006 4:05:44 PM] Page 16 of 377 Page 16 of 377 Page 16 of 377 Page 16 of 377 ---PAGE BREAK--- SECTION 6 - ACCIDENTAL RELEASE MEASURES Disposal: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS FOR PETROLEUM DISTILLATES. Spills/Leaks: VENTILATE AREA BY OPENING DOORS AND WINDOWS. REMOVE IGNITION SOURCES. REMOVE LEAKING CONTAINER AND TRANSFER REMAINING PRODUCT TO ANOTHER VESSEL. PREVENT PRODUCT FROM GOING INTO 0SEWERS AND WATER COURSES BY DIKING OR IMPOUNDING. USING APPROPRIATE SAFETY EQUIPMENT, MOP UP 1OR SOAK UP WITH ABSORBENT MATERIAL, SUCH AS SAND OR CLAY. SECTION 7 - HANDLING and STORAGE Handling: AVOID PROLONGED SKIN CONTACT. KEEP AWAY FROM EYES. DO NOT INHALE VAPORS DO NOT USE NEAR HEAT, SPARKS, OR OPEN FLAME. WASH HANDS AND FACE AFTER HANDLING THIS COMPOUND. Storage: STORE BULK BELOW 150 F AND ABOVE 32 F. STORE AWAY FROM IGNITION SOURCES AND AVOID BREATHING VAPORS. WASH HANDS WITH SOAP AND WATER AFTER USE OR BEFORE BREAKS AND LUNCH AND AT THE END OF 0WORK PERIODS. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: LOCAL EXHAUST: LOCAL EXHAUST IS USUALLY ADEQUATE. MECHANICAL (GENERAL): HOWEVER, MECHANICAL VENTILATION SHOULD BE USED WHEN SPRAYING IN ENCLOSED AREAS. VAPOR CONCENTRATION SHOULD BE MINIMIZED AS MUCH AS POSSIBLE. Eyes: USE FACE SHIELD OR GOGGLES WHEN SPRAYING OR SPLASHING. Skin: PROTECTIVE GLOVES: NEOPRENE OR NITRILE GLOVES RECOMMENDED. Clothing: NONE. MSDS - KP150014 http://apps.barnesdistribution.com/website/msds.nsf/webview/KP150014ENG?OpenDocument (4 of 7) [5/23/2006 4:05:44 PM] Page 17 of 377 Page 17 of 377 Page 17 of 377 Page 17 of 377 ---PAGE BREAK--- Respirators: NONE REQUIRED IF GOOD VENTILATION IS MAINTAINED. FOR ENCLOSED AREAS, USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance/Odor: APPEARANCE: SILVER PASTE ODOR: PETROLEUM pH: DOES NOT APPLY Vapor Pressure: <5 MM HG Vapor Density: N/D Evaporation Rate: N/D Viscosity: N/D Boiling Point: N/D Freezing/Melting Point: N/D Decomposition Temperature: N/D Solubility: IN WATER: NIL Specific Gravity: 1.17 Molecular Formula: N/A Molecular Weight: N/D Miscellaneous: % VOLATILE / VOLUME: 0 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: YES Conditions to Avoid: STABILITY: AVOID SPARKS OR OPEN FLAMES. (SEE HANDLING AND STORAGE PRECAUTIONS). Incompatibilities with Other Materials: STRONG OXIDIZERS, ALKALIES, MINERAL ACIDS, SELECTED AMINES. Hazardous Decomposition Products: METAL OXIDE FUMES, OXIDES OF CARBON, NITROGEN COMPOUNDS, BARIUM OXIDE, SULFUR DIOXIDE, HYDROGEN SULFIDE, ZINC. Hazardous Polymerization: WILL NOT OCCUR. SECTION 11 - TOXICOLOGICAL INFORMATION Toxicological Information: SEE SECTION 3 MSDS - KP150014 http://apps.barnesdistribution.com/website/msds.nsf/webview/KP150014ENG?OpenDocument (5 of 7) [5/23/2006 4:05:44 PM] Page 18 of 377 Page 18 of 377 Page 18 of 377 Page 18 of 377 ---PAGE BREAK--- SECTION 12 - ECOLOGICAL INFORMATION Ecological Information: NO DATA AVAILABLE. SECTION 13 - OTHER PRECAUTIONS Other Precautions: Work/Hygienic Practices: WASH HANDS AFTER USE. SECTION 14 - TRANSPORT INFORMATION Transportation Information: DOT (49CFR172) DOMESTIC GROUND TRANSPORT DOT SHIPPING NAME: UNRESTRICTED HAZARD CLASS: NONE U/ID NUMBER: NONE MARINE POLLUTANT: NONE IATA PROPER SHIPPING NAME: UNRESTRICTED CLASS OR DIVISOIN: NONE UN/NA NUMBER: NONE IMDG PROPER SHIPPING: UNRESTRICTED HAZARD CLASS: NONE UN NUMBER: NONE Label Information: SECTION 15 - REGULATORY INFORMATION Regulatory Information: TSCA INVENTORY: ALL OF THE INGREDIENTS ARE LISTED ON THE TSCA INVENTORY. MSDS - KP150014 http://apps.barnesdistribution.com/website/msds.nsf/webview/KP150014ENG?OpenDocument (6 of 7) [5/23/2006 4:05:44 PM] Page 19 of 377 Page 19 of 377 Page 19 of 377 Page 19 of 377 ---PAGE BREAK--- SARA: THIS PRODUCT CONTAINS AN INGREDIENT(S) REPORTABLE UNDER SARA TITLE III, SECTION 313 REPO TING. SECTION 16 - ADDITIONAL INFORMATION Additional Information: MSDS - KP150014 http://apps.barnesdistribution.com/website/msds.nsf/webview/KP150014ENG?OpenDocument (7 of 7) [5/23/2006 4:05:44 PM] Page 20 of 377 Page 20 of 377 Page 20 of 377 Page 20 of 377 ---PAGE BREAK--- Material Safety Data Sheet The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] Armor All Detailer’s Advantage® Protectant Spray Page 1 of 4 1. Product And Company Identification Product Name: Armor All Detailer’s Advantage® Protectant Spray Responsible Party: The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Information Phone Number: +1 [PHONE REDACTED] Emergency Phone Number: For Medical Emergencies, call 1-[PHONE REDACTED] / +1 [PHONE REDACTED] (Outside US and Canada) For Transportation Emergencies, call 1-[PHONE REDACTED] (Chemtrec) +1-[PHONE REDACTED] for Outside US and Canada (call collect) MSDS Date Of Preparation: 12/28/12 Product Use: Automotive maintenance product – For consumer and professional use 2. Hazards Identification EMERGENCY OVERVIEW CAUTION: Eye irritant. Prolonged skin contact may cause mild irritation. 3. Composition/Information On Ingredients Component CAS No. Amount Alkyl dimethyl benzyl ammonium chloride (C12- C16) 68424-85-1 < 0.3% Non-Hazardous Ingredients Mixture Balance 4. First Aid Measures Inhalation: Remove to fresh air. Seek medical attention if breathing problems develop, or persist. Skin Contact: Wash exposed skin with water. If skin irritation or redness develops, seek medical attention. Eye Contact: Flush eyes with large amounts of water for 15 minutes. If irritation or other persist, seek medical attention. Ingestion: If the victim is fully conscious, have them drink a glass of water. Get medical assistance by calling a doctor or poison center. Never give anything by mouth to a person who is unconscious or drowsy. 5. Firefighting Measures Extinguishing Media: Use any media that is suitable for the surrounding fire. Cool fire exposed containers with water. Special Fire Fighting Procedures: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Unusual Fire Hazards: None known. Page 21 of 377 Page 21 of 377 Page 21 of 377 Page 21 of 377 ---PAGE BREAK--- Material Safety Data Sheet The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] Armor All Detailer’s Advantage® Protectant Spray Page 2 of 4 Hazardous Combustion Products: None known. 6: Accidental Release Measures Personal Precautions: Wear appropriate protective equipment. Environmental Precautions: Prevent entry in storm sewers and waterways. Report spill as required by local and national regulations. Methods for Containment and Clean-Up: Absorb with an inert material. Collect into a suitable container for disposal. Rinse area with water. 7. Handling and Storage Avoid contact with eyes. Avoid prolonged contact with skin and clothing. Wash hands after use. Keep out of the reach of children. No special storage required. 8. Exposure Controls / Personal Protection CHEMICAL EXPOSURE LIMIT Alkyl dimethyl benzyl ammonium chloride (C12-C16) None Established Non-Hazardous Ingredients None Established Ventilation: General ventilation should be adequate for all normal use. Respiratory Protection: None required under normal use conditions. Gloves: None normally required. Avoid prolonged skin contact. Impervious gloves such as rubber, neoprene or nitrile can be used if needed to avoid prolonged or repeated skin contact. Eye Protection: Safety glasses or goggles are recommended if eye contact is possible. Other Protective Equipment/Clothing: None required under normal use conditions. 9. Physical and Chemical Properties Appearance And Odor: Clear liquid with fragrance. pH: ~ 11.5 Specific Gravity: ~1.0 Boiling Point: Not determined Vapor Pressure: Not determined Freezing Point: Not determined Vapor Density: Not determined Solubility In Water: Soluble Percent Volatile: >95% Viscosity: Not determined Evaporation Rate: Not determined Coefficient Of Water/Oil Distribution: Not determined Autoignition Temp: Not applicable Flash Point: Not applicable Flammability Limits: LEL: Not applicable LEL: Not applicable Page 22 of 377 Page 22 of 377 Page 22 of 377 Page 22 of 377 ---PAGE BREAK--- Material Safety Data Sheet The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] Armor All Detailer’s Advantage® Protectant Spray Page 3 of 4 10. Stability and Reactivity Stability: Stable Conditions To Avoid: None known. Incompatibility: None known. Hazardous Decomposition Products: None known. 11. Toxicological Information Acute Hazards: Inhalation: Inhalation of mists may cause mild upper respiratory tract irritation. Skin Contact: Prolonged or repeated contact may cause irritation. Eye Contact: Direct contact may cause eye irritation with redness, tearing and pain. Ingestion: Swallowing may cause gastrointestinal disturbances. Chronic Hazards: None currently known. Medical Conditions Aggravated By Exposure: None currently known. Carcinogen: None of the components is listed as a carcinogen or potential carcinogen by IARC, NTP, ACGIH or OSHA. Acute Toxicity Values: Alkyl dimethyl benzyl ammonium chloride (C12-C16): LD50 Oral Rat: 50-500 mg/kg 12. Ecological Information No ecotoxicity data is currently available. This product may be harmful to aquatic life if released directly to the environment. 13. Disposal Considerations Dispose of in accordance with all local, state/provincial and federal regulations. Offer empty containers for recycling. 14. Transport Information DOT Hazardous Materials Description: Not Regulated Canadian TDG Hazardous Materials Description: Not Regulated IMDG Dangerous Goods Description: Not Regulated Page 23 of 377 Page 23 of 377 Page 23 of 377 Page 23 of 377 ---PAGE BREAK--- Material Safety Data Sheet The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] Armor All Detailer’s Advantage® Protectant Spray Page 4 of 4 15. Regulatory Information United States: EPA TSCA INVENTORY: All of the components of this material are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory. CERCLA Section 103: This product has no RQ. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA Hazard Category (311/312): Acute Health SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None Canada: Canadian WHMIS Classification: Class D - Division 2 - Subdivision B - (Toxic material causing other toxic effects) Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian DSL or the NDSL. This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. 16. Other Information NFPA Rating (NFPA 704): Health: 1 Fire: 0 Instability: 0 HMIS Rating: Health: 1 Fire: 0 Reactivity: 0 REVISION SUMMARY: Change in Section 3, 5, 10 DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH Page 24 of 377 Page 24 of 377 Page 24 of 377 Page 24 of 377 ---PAGE BREAK--- Page 1/3 Safety Data Sheet acc. to OSHA HCS Printing date 01/08/2014 Revised On 01/08/2014 38.0 1 Identification of the substance and manufacturer Trade name: ATHLETIC FIELD MARKER - WHITE Product code: 28341 Product category PC9a Paints and coatings. Manufacturer/Supplier: Lawson Products, Inc. 8770 W. Bryn Mawr Avenue Chicago, IL 60631 USA phone: [PHONE REDACTED] Emergency telephone number: [PHONE REDACTED] 2 Hazard(s) identification GHS Hazard pictograms GHS02 GHS07 GHS08 Signal word Danger Hazard statements Extremely flammable aerosol. Causes skin irritation. May cause damage to organs through prolonged or repeated exposure. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapours/spray. Specific treatment (see on this label). Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 74-98-6 propane 12.6% 142-82-5 heptane 10.89% 13463-67-7 titanium dioxide 10.47% 64742-89-8 VM&P Naphtha 9.47% 106-97-8 n-butane 7.4% 1317-65-3 Calcium Carbonate 6.86% 64742-47-8 Mineral Spirits 3.95% 4 First-aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Contact physician or poison control center. 5 Fire-fighting measures Extinguishing agents: CO2, sand, extinguishing powder, or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards: Can form explosive gas-air mixtures. Protective equipment for firefighters: A respiratory protective device may be necessary. Additional information Cool endangered receptacles with water spray. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage systems or ground water. Methods and material for containment and cleaning up: Absorb liquid components with liquid-binding material. 7 Handling and storage Precautions for safe handling No special precautions are necessary if used correctly. Fire/explosion protection: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 i.e. electric lights. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not smoke. Protect from electrostatic discharges. (Contd. on page 2) US4 Page 25 of 377 Page 25 of 377 Page 25 of 377 Page 25 of 377 ---PAGE BREAK--- Page 2/3 Safety Data Sheet acc. to OSHA HCS Printing date 01/08/2014 Revised On 01/08/2014 Trade name: ATHLETIC FIELD MARKER - WHITE (Contd. of page 1) 38.0 Storage requirements: Observe pressurized container storage regulations. Consult with your local authorities. 8 Exposure controls/personal protection Components with limit values that require monitoring at the workplace: 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F: minimal oxygen content 142-82-5 heptane PEL (USA) Long-term value: 2000 mg/m³, 500 ppm REL (USA) Long-term value: 350 mg/m³, 85 ppm Ceiling limit value: 1800* mg/m³, 440* ppm *15-min TLV (USA) Short-term value: 2050 mg/m³, 500 ppm Long-term value: 1640 mg/m³, 400 ppm 106-97-8 n-butane REL (USA) Long-term value: 1900 mg/m³, 800 ppm TLV (USA) Short-term value: 2370 mg/m³, 1000 ppm Hygienic protection: Keep away from foodstuffs and animal feed. Wash hands after use. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you suspect overexposure conditions exist, please consult an authority on chemical hygeine. Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance. Eye protection: sealed goggles 9 Physical and chemical properties Appearance: Aerosol. Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Boiling point: -44 °C (-47 Flash point: -19 °C Flammability (solid, gaseous): Not applicable. Decomposition temperature: Not determined. Auto igniting: Product is not self-igniting. Danger of explosion: In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.1 Vol % Upper Explosion Limit: 10.9 Vol % Specific Gravity: Between 0.77 and 0.85 (Water equals 1.00) Vapour density Not determined. Evaporation rate Not applicable. Partition coefficient (n-octanol/water): Not determined. VOC content: 575.4 g/l / 4.80 lb/gl VOC content (less exempt solvents): 37.3 % Water: 31.3 % MIR Value: 0.52 Solids content: 31.4 % Other information No further relevant information available. 10 Stability and reactivity Conditions to avoid: Do not allow the can to exceed 120 degrees Fahrenheit. Stable at normal temperatures. Possibility of hazardous reactions: No dangerous reactions known. Hazardous decomposition: No dangerous decomposition products known. 11 Toxicological information Skin effects: No irritant effect. Eye effects: No irritating effect. Sensitization: No sensitizing effects known. Carcinogenic categories IARC (International Agency for Research on Cancer) 13463-67-7 titanium dioxide 2B (Contd. on page 3) US4 Page 26 of 377 Page 26 of 377 Page 26 of 377 Page 26 of 377 ---PAGE BREAK--- Page 3/3 Safety Data Sheet acc. to OSHA HCS Printing date 01/08/2014 Revised On 01/08/2014 Trade name: ATHLETIC FIELD MARKER - WHITE (Contd. of page 2) 38.0 NTP (National Toxicology Program) None of the ingredients is listed. 12 Ecological information Aquatic toxicity: Hazardous for water, do not empty into drains. Persistence and degradability: The product is degradable after prolonged exposure to natural weathering processes. Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available. Other adverse effects: No further relevant information available. 13 Disposal considerations Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Completely empty cans should be recycled. 14 Transport information DOT, ADR N/A UN proper shipping name: DOT Consumer Commodity ORM-D Aerosols, flammable ADR 1950 Aerosols, ENVIRONMENTALLY HAZARDOUS IATA AEROSOLS, flammable Transport hazard class(es): Class 2.1 Marine pollutant: Yes Symbol (fish and tree) Special marking (ADR): Symbol (fish and tree) Special precautions for user: Warning: Gases EMS Number: F-D,S-U Packaging Group: UN "Model Regulation": UN1950, Aerosols, ENVIRONMENTALLY HAZARDOUS, 2.1 15 Regulatory information SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): None of the ingredients is listed. CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. California Proposition 65 chemicals known to cause cancer: 100-41-4 ethyl benzene EPA: 142-82-5 heptane D ACGIH: 13463-67-7 titanium dioxide A4 NIOSH: 13463-67-7 titanium dioxide 16 Other information Contact: Regulatory Affairs US4 Page 27 of 377 Page 27 of 377 Page 27 of 377 Page 27 of 377 ---PAGE BREAK--- SAFETY DATA SHEET Chemsico Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Black Flag Wasp Hornet & Yellowjacket Killer 1-[PHONE REDACTED] HG-11036 21-1058, 21-0666, 01-1006 Page 1 SDS Date: 2/25/15 Product Name: Black Flag Wasp, Hornet & Yellow Jacket Killer EPA Reg. No. 9688-190 CAS Aerosol Product Use: Wasp & Hornet Killer Aerosol Manufacturer: Chemsico Div. of United Industries Corp. P.O. Box 142642 St. Louis, MO 63114 This product is classified according the Globally Harmonized System (GHS). ROUTES OF EXPOSURE Potential short term health effects: Skin contact, Ingestion Eyes: No reaction expected. Skin: May cause irritation. Inhalation: No expected reaction. Ingestion: May be harmful if swallowed. Target organs: Skin, Digestive system Chronic effects: Prolonged or repeated exposure can cause drying, defatting and dermatitis. Signs and may include redness, edema, drying, defatting and cracking of the skin. Composition comments: This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). NOTE: No reportable quantities of hazardous ingredients are present per OSHA 29 CFR 1910.1200. No toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are present. ACTIVE COMPONENT CAS# PERCENTAGE Lambda-cyhalothrin 91465-08-6 0.010% Prallethrin 23031-36-9 0.025% Petroleum Distillates 64742-47-8 3.500% Butyl Propasol 5131-66-8 3.000% Propane 74-98-6 3.500% OTHER COMPONENT CAS# PERCENTAGE Other N/A 89.965 Note: Ingredients not identified are not hazardous. SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION SECTION 2 - HAZARDS IDENTIFICATION SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS Page 28 of 377 Page 28 of 377 Page 28 of 377 Page 28 of 377 ---PAGE BREAK--- SAFETY DATA SHEET Chemsico Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Black Flag Wasp Hornet & Yellowjacket Killer 1-[PHONE REDACTED] HG-11036 21-1058, 21-0666, 01-1006 Page 2 FIRST AID PROCEDURES Eye contact: None required Skin contact: Flush with large amounts of cool water. Wash with soap and water. Remove contaminated clothing and wash before reuse. Obtain medical attention if irritation persists. Inhalation: None required Ingestion: Immediately call a Poison Control Center or doctor. Do not induce vomiting unless told to do so. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person. Note to Physician: may be delayed. General advice: If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children. Flammable properties: Pressurized Aerosol Container SUITABLE EXTINGUISHING MEDIA Extinguishing media: Water Fog, Foam, CO2, Dry Chemical Unsuitable extinguishing media: Not Available SPECIFIC HAZARDS ARISING FROM THE CHEMICAL Protection of firefighters: Not Available Protective equipment for firefighters: Firefighters should wear full protective clothing including self-contained breathing apparatus. Hazardous combustion products: None known SENSITIVITY TO MECHANICAL IMPACT Explosion data: Not Available Sensitivity to static discharge: Not Available Personal precautions: Keep unnecessary personnel away. Do not touch or walk through spilled material. HMIS Ratings Health Hazard 1 Fire Hazard 2 Reactivity 0 Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. SECTION 4 - FIRST AID MEASURES SECTION 5 - FIRE FIGHTING MEASURES SECTION 6 - ACCIDENTAL RELEASE MEASURES Page 29 of 377 Page 29 of 377 Page 29 of 377 Page 29 of 377 ---PAGE BREAK--- SAFETY DATA SHEET Chemsico Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Black Flag Wasp Hornet & Yellowjacket Killer 1-[PHONE REDACTED] HG-11036 21-1058, 21-0666, 01-1006 Page 3 Methods for cleaning up: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. Handling: Use good industrial hygiene practices in handling this material. Storage: Keep out of reach of children. Store in a closed container away from incompatible materials. Engineering controls: General ventilation normally adequate. EYE / FACE PROTECTION Personal protective equipment: None required Hand protection: None required Skin and body protection: None required Respiratory protection: None required General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product. Appearance: Clear Color: Light yellow to water-white Form: Aerosol Odor: Aromatic solvent (slight) Odor threshold: Not Available Physical state: Pressurized liquid pH: 5-6 Freezing point: 32°F Boiling point: 212°F Flash point: 1190F (liquid portion) Flame Extension 0” (level 1 aerosol) Flammability limits in air, lower, % by volume: Not Available SECTION 7 - HANDLING AND STORAGE SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES Page 30 of 377 Page 30 of 377 Page 30 of 377 Page 30 of 377 ---PAGE BREAK--- SAFETY DATA SHEET Chemsico Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Black Flag Wasp Hornet & Yellowjacket Killer 1-[PHONE REDACTED] HG-11036 21-1058, 21-0666, 01-1006 Page 4 Flammability limits in air, upper, % by volume: Not Available Vapor pressure: Not Available Vapor density: Not Available Specific gravity: 0.973 Octanol/water coefficient: Not Available Auto-ignition temperature: Not Available Chemical stability: Stable under recommended storage conditions. Conditions to avoid: Do not mix with other chemicals. Incompatible materials: Avoid strong oxidizers. Hazardous decomposition products: None known. Possibility of hazardous reactions: Hazardous polymerization does not occur. EFFECTS OF ACUTE EXPOSURE Eye: May cause irritation. Skin: May cause irritation. LD50 >5000 mg/kg Inhalation: LC50 > 2mg/L (EPA Tox category IV) Ingestion: LD50 > 3000 mg/kg Sensitization: Not a skin sensitizer. Chronic effects/ Carcinogenicity: Not Available Mutagenicity: Not Available Reproductive effects: Not Available Teratogenicity: Not Available Ecotoxicity: Not Available Environmental effects: Not Available Aquatic toxicity: Toxic to aquatic organisms Persistence / degradability: Not Available Bioaccumulation / accumulation: Not Available Partition coefficient: Not Available Mobility in environmental media: Not Available Chemical fate information: Not Available SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION SECTION 11 - TOXICOLOGICAL INFORMATION SECTION 12 - ECOLOGICAL INFORMATION Page 31 of 377 Page 31 of 377 Page 31 of 377 Page 31 of 377 ---PAGE BREAK--- SAFETY DATA SHEET Chemsico Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Black Flag Wasp Hornet & Yellowjacket Killer 1-[PHONE REDACTED] HG-11036 21-1058, 21-0666, 01-1006 Page 5 Waste codes: Not Available Disposal instructions: Dispose in accordance with all applicable regulations. Waste from residues / unused products: Not Available Contaminated packaging: Not Available U.S. Department of Transportation (DOT): Aerosols, Flammable, 2.1, UN-1950, Limited Quantity U.S. Federal regulations: This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. IATA: 1950, Aerosols, Flammable, 2.1 IMDG: 1950, Aerosols, 2.1 (lambda-cyhalothrin), Marine Pollutant, Limited Quantity 29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA): No CERCLA (Superfund) reportable quantity: Not Available HAZARD CATEGORIES Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate Hazard No Delayed Hazard No Fire Hazard No Pressure Hazard No Reactivity Hazard No Section 302 extremely hazardous Substance: No Section 311 hazardous chemical: No Clean Air Act (CAA): Not Available Clean Water Act (CWA): Not Available State regulations: INVENTORY STATUS Inventory Country(s) or region name on inventory (yes/no)*: N/A, Regulated by EPA SECTION 13 - DISPOSAL CONSIDERATIONS SECTION 14 - TRANSPORTATION INFORMATION SECTION 15 - REGULATORY INFORMATION Page 32 of 377 Page 32 of 377 Page 32 of 377 Page 32 of 377 ---PAGE BREAK--- SAFETY DATA SHEET Chemsico Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Black Flag Wasp Hornet & Yellowjacket Killer 1-[PHONE REDACTED] HG-11036 21-1058, 21-0666, 01-1006 Page 6 Disclaimer: Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date: 2/25/15 Prepared by: United Industries Corp. (800) 242-1166 SECTION 16 - OTHER INFORMATION Page 33 of 377 Page 33 of 377 Page 33 of 377 Page 33 of 377 ---PAGE BREAK--- Page 34 of 377 Page 34 of 377 Page 34 of 377 Page 34 of 377 ---PAGE BREAK--- Page 35 of 377 Page 35 of 377 Page 35 of 377 Page 35 of 377 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Dry Lub™ PRODUCT TYPE: Dry Lubricant Coating PRODUCT CODE: C2015 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Potential for aspiration if swallowed. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Acetone 67-64-1 1000ppm 750ppm 750ppm 15-40% Toluene 108-88-3 200ppm 20ppm 150ppm 15-40% Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Isopropyl Alcohol 67-63-0 400ppm NE 400ppm 5-10% Molybdenum Disulfide 1317-33-5 15 mg/m3(dust) 10 mg/m3 NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: No information available. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: ≥ -141°F LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 36 of 377 Page 36 of 377 Page 36 of 377 Page 36 of 377 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Product is extremely flammable. Do not store near ignition sources. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Eye protection not normally required but recommended. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 64.5% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Black Powder / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. Strong bases. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Sulfur Oxides. HAZARDOUS POLYMERIZATION: Does not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: Acetone: Oral LD50 (rat) 5800 mg/kg Toluene: Oral LD50 (rat) 636 mg/kg; Dermal LD50 (rabbit) 8390 mg/kg; Inhalation LC50 (rat) 12.5 mg/L (4h) ISopropanol: Oral LD50 (rat) 4396 mg/kg; Dermal LD50 (rabbit) 12870 mg/kg; Inhalation LC50 (rat) 72.6 mg/L (4h) Not classified to be a carcinogen to humans. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT Ground: Consumer Commodity ORM-D, or Limited Quantity. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Page 37 of 377 Page 37 of 377 Page 37 of 377 Page 37 of 377 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 3 of 3 Section 311/312 hazardous chemical: Acute Health Hazard: Yes; Chronic Health Hazard: Yes; Fire Hazard: Yes; Sudden Release of Pressure Hazard: No; Reactive Hazard: No.. Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 2 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 11/29/93 UPDATED: 9/19/2013 PRODUCT C2015 Page 38 of 377 Page 38 of 377 Page 38 of 377 Page 38 of 377 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 REVISION DATE: August 13, 2014 CHEMTREC: (800) 424-9300 DATE OF ISSUE: August 13, 2014 I - Product Identification Citra Clean PRODUCT CODE: 0440 CHEMICAL FORMULATION: Citrus based grit hand cleanser NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 0 FLAMMABILITY: 1 REACTIVITY: 0 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. SUBSTANCE APPROX % OSHA PEL ACGIH TLV EPA 40 CFR: CAS # 302 355 372 d-Limonene 1.0 - 10.0 N/E N/E N N N 5989-27-5 Linear Alcohol Ethoxylate 1.0 - 5.0 N/E N/E N N N 34398-01-1 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = 0.998 VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): < 1.0 VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = N/D SOLUBILITY IN WATER: Miscible pH: 6.5 – 7.5 APPEARANCE AND ODOR: Orange, opaque liquid; citrus fragrance. IV - Fire and Explosion Hazard Data FLASH POINT > 200 (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/E LOWER: N/E EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should be equipped with self-contained breathing apparatus and protective clothing. Use water spray to cool fire-exposed containers. UNUSUAL FIRE AND EXPLOSION HAZARD: None. Page 39 of 377 Page 39 of 377 Page 39 of 377 Page 39 of 377 ---PAGE BREAK--- PRODUCT NAME: Citra Clean PRODUCT CODE: 0440 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong acids and oxidizing agents. CONDITIONS TO AVOID: None HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbons. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Moderate irritation, redness, and tearing. IF ON SKIN: Irritation with repeated or prolonged contact. Contains a possible sensitizer. IF SWALLOWED: Gastrointestinal irritation, nausea, vomiting, and diarrhea. IF INHALED: No hazards under normal use. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Wash with water. IF SWALLOWED: Contact physician or poison control center immediately. Do not induce vomiting. Never give anything to an unconscious person. IF INHALED: Remove person to fresh air. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and extinguish all sources of ingestion. Soak up on inert absorbent and place in closed container for disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. VENTILATION LOCAL: Not required MECHANICAL: Not required PROTECTIVE GLOVES: None. EYE PROTECTION: None. OTHER PROTECTIVE EQUIPMENT: None. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place, away from heat or open flame. Wash hands thoroughly after handling. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT ID NUMBER: None DOT PROPER SHIPPING NAME: None DOT CLASS: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: August 13, 2014 Prepared by: Technical Dept. DATE OF ISSUE: August 13, 2014 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of this material. Page 40 of 377 Page 40 of 377 Page 40 of 377 Page 40 of 377 ---PAGE BREAK--- Common Name: DETAIL DEMON AUTO FINISH CLEANER/POLISH Manufacturer: NYCO PRODUCTS MSDS Revision Date: 1/6/2011 Grainger Item Number(s): 11U479 Manufacturer Model Number(s): MSDS Table of Contents Click the desired link below to jump directly to that section in the MSDS. SECTION I - PRODUCT IDENTITY SECTION II - HAZARDOUS INGREDIENTS SECTION III - CHEMICAL AND PHYSICAL SECTION IV - FIRE AND EXPLOSION HAZARDS SECTION V - REACTIVITY INFORMATION SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE SECTION VIII - REGULATORY INFORMATION MATERIAL SAFETY DATA SHEET MSDS NO.: N524 NYCO PRODUCTS CO. 5332 DANSHER ROAD ILLINOIS 60525 EMERGENCY PHONES: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) REVISION DATE: 1/6/2011 SUPERSEDES DATE: 8/8/2005 PLEASE NOTE: THIS MSDS IS BEING PROVIDED TO YOUR COMPANY FOR THE PURPOSE OF PROVIDING CURRENT HEALTH AND SAFETY INFORMATION TO YOUR MANAGEMENT AND FOR YOUR EMPLOYEES WHO WORK WITH THIS MATERIAL. PLEASE READ THE Page 41 of 377 Page 41 of 377 Page 41 of 377 Page 41 of 377 ---PAGE BREAK--- INFORMATION ON THESE SHEETS, AND THEN PROVIDE THIS INFORMATION TO THOSE PEOPLE AT YOUR COMPANY WHOSE RESPONSIBILITY IT IS TO COMPLY WITH FEDERAL AND STATE RIGHT-TO-KNOW REGULATIONS. ALSO MAKE THIS INFORMATION AVAILABLE TO ANY EMPLOYEE WHO REQUESTS IT. IT IS YOUR OBLIGATION TO COMPLY WITH THESE REGULATIONS. SECTION I - PRODUCT IDENTITY PRODUCT NAME: DETAIL DEMON AUTO FINISH CLEANER/POLISH FORMULA: MIXTURE, ADDITIVES AND ALCOHOL IN WATER. CHEMICAL TYPE: AS ABOVE HMIS RATINGS: HEALTH 1 (SLIGHT) FLAMMABILITY 2 (MODERATE) REACTIVITY 0 (MINIMAL) PROTECTION B (GOGGLES & GLOVES) SECTION II - HAZARDOUS INGREDIENTS INGREDIENT PERCENT TLV CARCINOGEN (OSHA, TP, IARC) ISOPROPANOL 400 PPM NO CAS NO.: 67-63-0 STEL: 500 PPM SECTION III - CHEMICAL AND PHYSICAL APPEARANCE: OPAQUE VIOLET LIQUID BOILING POINT: <212 DEG. F ODOR: TUITTI-FRUITTI MELTING POINT: N/A pH: 7.0 - 8.0 SPEC. GRAVITY (H2O = 1.00 WATER SOLUBILITY: COMPLETE VAPOR PRESSURE (MMHg): N/A Page 42 of 377 Page 42 of 377 Page 42 of 377 Page 42 of 377 ---PAGE BREAK--- VISCOSITY @ 25 DEG. C: WATER THIN (BROOKFIELD) VOC CONTENT: 3% SECTION IV - FIRE AND EXPLOSION HAZARDS FLASH POINT (METHOD): 161 DEG. F CL.CP. EXPLOSION LIMITS: UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: WATER FOG, FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL SPECIAL FIREFIGHTING PROCEDURES AND HAZARDS: TREAT AS A COMBUSTIBLE LIQUID. NOTE: THIS PRODUCT IS COMBUSTIBLE UNDER OSHA CRITERIA, BUT IS NOT REGULATED BY DOT SINCE IT CONTAINS LESS THAN 24% ALCOHOL AND OVER 50% WATER, AND THE OTHER INGREDIENTS DO NOT CONSTITUTE A DOT HAZARD: SEE (CFR 173.115(B)(2)(I) AND (II). SECTION V - REACTIVITY INFORMATION STABLE UNSTABLE ( ) PRECAUTIONS: INCOMPATIBILITY: NONE KNOWN HAZARDOUS DECOMPOSITION PRODUCTS: IF IN A FIRE: CO, CO2, HYDROCARBONS. HAZARDOUS POLYMERIZATION: OCCURS ( ) DOES NOT OCCUR SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID INHALATION: BREATHING OF VAPORS MAY CAUSE DIZZINESS AND SHORTNESS OF BREATH. WEAR Page 43 of 377 Page 43 of 377 Page 43 of 377 Page 43 of 377 ---PAGE BREAK--- APPROVED VAPOR RESPIRATOR IF NEEDED. REMOVE TO FRESH AIR. SKIN: EXTENDED CONTACT MAY CAUSE IRRITATION OR DEFATTING. PROLONGED CONTACT WITH 2-BUTOXYETHANOL MAY RESULT IN THE ABSORPTION OF POTENTIALLY HARMFUL AMOUNTS LEADING TO POSSIBLE LIVER AND KIDNEY DAMAGE. WEAR PROTECTIVE GLOVES IF NEEDED. REMOVE CONTAMINATED CLOTHING & WASH IF NECESSARY BEFORE REUSE. FLUSH SKIN THOROUGHLY WITH WATER FOR 15 MINUTES. EYES: CAN CAUSE IRRITATION. WEAR GOGGLES AS NEEDED. FLUSH IMMEDIATELY WITH WATER FOR 15 MINUTES. GET PROMPT MEDICAL ATTENTION IF NEEDED. INGESTION: MAY CAUSE A MILD GASTRIC DISTURBANCE. DRINK LOTS OF WATER. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IF EFFECTS PERSIST. MOST LIKELY ROUTES OF ENTRY: SKIN, EYES. OTHER IMPORTANT MEDICAL OR PRECAUTIONARY INFORMATION: NONE SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE SPILLS AND LEAKS: SMALL SPILLS CAN BE FLUSHED INTO NORMAL DRAINAGE OR INTO GROUND WITH COPIOUS AMOUNTS OF WATER, OR TAKEN UP WITH ABSORBENT MATERIAL. LARGER SPILLS SHOULD BE CONTAINED BY DIKING OR OTHER METHODS AND HELD FOR DISPOSAL OR REUSE. REMOVE ALL SOURCES OF IGNITION. PROVIDE STRONG VENTILATION. STORAGE AND HANDLING: CHECK DAILY FOR ANY LEAKS FROM CONTAINERS, VESSELS, PUMPS, AND PIPING. KEEP AWAY FROM SOURCES OF IGNITION. KEEP AT TEMPERATURES BELOW 95 DEG. F. WASTE DISPOSAL: COLLECT IN CLOSED CONTAINERS AND SEND TO A LICENSED TREATMENT OR DISPOSAL FACILITY. EMPTY CONTAINERS: RINSE WELL BEFORE HANDLING AND DISPOSAL. OBSERVE LABEL PRECAUTIONS. DO NOT Page 44 of 377 Page 44 of 377 Page 44 of 377 Page 44 of 377 ---PAGE BREAK--- CUT, WELD OR BURN. OTHER PRECAUTIONS: NONE SECTION VIII - REGULATORY INFORMATION REPORTABLE FOR SARA TITLE III, S.313 (FORM NONE. THE INFORMATION HEREIN HAS BEEN COMPILED FROM SOURCES BELIEVED TO BE RELIABLE AND IS ACCURATE TO THE BEST OF OUR KNOWLEDGE. HOWEVER, NYCO PRODUCTS COMPANY CANNOT GIVE ANY GUARANTEES REGARDING INFORMATION FROM OTHER SOURCES, AND EXPRESSLY DOES NOT MAKE ANY WARRANTIES, NOR ASSUMES ANY LIABILITY, FOR ITS USE. Page 45 of 377 Page 45 of 377 Page 45 of 377 Page 45 of 377 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product identifier Diamond Iron Fighter® Salt Blocks Other means of identification SDS number ND17 Synonyms Sodium Chloride (Salt) Treated with Citric Acid. Recommended use Salt may be intended for food or animal feed (agricultural) as well as several industrial applications including deicing and water conditioning. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Cargill Incorporated Address Minneapolis, MN 55440 Telephone 1-[PHONE REDACTED] Website www.cargillsalt.com Emergency telephone number CHEMTREC (800) 424-9300 2. Hazard(s) identification Not classified. Physical hazards Not classified. Health hazards Not classified. OSHA defined hazards Label elements None. Hazard symbol Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures 7647-14-5 99.65 Sodium Chloride CAS number % Chemical name 77-92-9 0.35 Citric acid 4. First-aid measures Inhalation If dust from the material is inhaled, remove the affected person immediately to fresh air. Call a physician if develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Give one or two glasses of water if patient is alert and able to swallow. Get medical attention if occur. Diamond Iron Fighter® Salt Blocks SDS US 922247 Version 01 Revision date: - Issue date: 09-December-2014 1 / 6 Page 46 of 377 Page 46 of 377 Page 46 of 377 Page 46 of 377 ---PAGE BREAK--- Most important acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Use water spray to cool unopened containers. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. This product is not flammable or combustible. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Avoid inhalation of dust from the spilled material. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Keep upwind. Methods and materials for containment and cleaning up If sweeping of a contaminated area is necessary use a dust suppressant agent which does not react with the product. Collect dust using a vacuum cleaner equipped with HEPA filter. Minimize dust generation and accumulation. Avoid release to the environment. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Keep away from strong acids. Provide appropriate exhaust ventilation at places where dust is formed. Minimize dust generation and accumulation. Avoid breathing dust. Avoid contact with eyes. Practice good housekeeping. Avoid contact with water and moisture. Conditions for safe storage, including any incompatibilities Store in original closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Becomes hygroscopic at 70-75% relative humidity. Avoid humid or wet conditions as product will cake and become hard. Store at ambient temperature and atmospheric pressure. 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumes that may be generated during handling or thermal processing. Individual protection measures, such as personal protective equipment Eye/face protection Unvented, tight fitting goggles should be worn in dusty areas. Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear suitable protective clothing. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Diamond Iron Fighter® Salt Blocks SDS US 922247 Version 01 Revision date: - Issue date: 09-December-2014 2 / 6 Page 47 of 377 Page 47 of 377 Page 47 of 377 Page 47 of 377 ---PAGE BREAK--- 9. Physical and chemical properties Appearance Compressed 50-pound white salt blocks. Physical state Solid. Form solid. Color White. Odor Slight. Odor threshold Not available. pH Not available. Melting point/freezing point 1473.8 °F (801 Initial boiling point and boiling range 2669 °F (1465 (760 mmHg) Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 2.4 mm Hg (1376.6 °F (747 Vapor density Not available. Relative density 2.16 (H2O = 1) Solubility(ies) Solubility (water) 26.4 % Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Molecular formula NaCl Molecular weight 58.44 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Contact with incompatible materials. Avoid dispersal of dust in the air clearing dust surfaces with compressed air). Incompatible materials Avoid contact with strong acids. Becomes corrosive to metals when wet. Hazardous decomposition products May evolve chlorine gas when in contact with strong acids. 11. Toxicological information Information on likely routes of exposure Inhalation Inhalation of dusts may cause respiratory irritation. Skin contact Prolonged or repeated skin contact may cause irritation. Eye contact Dust in the eyes will cause irritation. Ingestion Expected to be a low ingestion hazard. Diamond Iron Fighter® Salt Blocks SDS US 922247 Version 01 Revision date: - Issue date: 09-December-2014 3 / 6 Page 48 of 377 Page 48 of 377 Page 48 of 377 Page 48 of 377 ---PAGE BREAK--- related to the physical, chemical and toxicological characteristics Eye and skin contact: Exposure may cause temporary irritation, redness, or discomfort. Ingestion of large amounts (greater than 0.1 pound) can cause gastrointestinal upset and irritation of the stomach. Information on toxicological effects Acute toxicity In some cases of confirmed hypertension, ingestion may result in elevated blood pressure. Test Results Components Species Sodium Chloride (CAS 7647-14-5) LD50 Rat Oral Acute 3000 mg/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Dust in the eyes will cause irritation. Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Due to the physical form of the product it is not an aspiration hazard. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects None known. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Diamond Iron Fighter® Salt Blocks SDS US 922247 Version 01 Revision date: - Issue date: 09-December-2014 4 / 6 Page 49 of 377 Page 49 of 377 Page 49 of 377 Page 49 of 377 ---PAGE BREAK--- Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations All components are on the U.S. EPA TSCA Inventory List. This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) Yes Australia Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No Canada Inventory of Existing Chemical Substances in China (IECSC) Yes China European Inventory of Existing Commercial Chemical Substances (EINECS) Yes Europe European List of Notified Chemical Substances (ELINCS) No Europe Diamond Iron Fighter® Salt Blocks SDS US 922247 Version 01 Revision date: - Issue date: 09-December-2014 5 / 6 Page 50 of 377 Page 50 of 377 Page 50 of 377 Page 50 of 377 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Inventory of Existing and New Chemical Substances (ENCS) Yes Japan Existing Chemicals List (ECL) Yes Korea New Zealand Inventory Yes New Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes Philippines *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory Yes United States & Puerto Rico 16. Other information, including date of preparation or last revision Issue date 09-December-2014 Revision date - Version # 01 HMIS® ratings Health: 1 Flammability: 0 Physical hazard: 0 Personal protection: A Disclaimer All statements, technical information and recommendations contained herein are, the best of our knowledge, reliable and accurate; however no warranty, either expressed or implied is made with respect thereto, nor will any liability be assumed for damages resultant from the use of the material described. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations. It is also the responsibility of the user to maintain a safe workplace. The user should consider the health hazards and safety information provided herein as a guide and should take the necessary steps to instruct employees and to develop work practice procedures to ensure a safe work environment. This information is not intended as a license to operate under, or a recommendation to practice or infringe upon any patent of this Company or others covering any process, composition of matter or use. Diamond Iron Fighter® Salt Blocks SDS US 922247 Version 01 Revision date: - Issue date: 09-December-2014 6 / 6 Page 51 of 377 Page 51 of 377 Page 51 of 377 Page 51 of 377 ---PAGE BREAK--- Diesel Exhaust Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 03 June 2015 Date of issue: 15 May 2015 Supersedes Date: 09/06/2013 Version: 1.0 15 May 2015 EN (English US) 1/6 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: Diesel Exhaust Fluid 1.2. Intended Use of the Product Diesel Exhaust NOx Reducing Agent 1.3. Name, Address, and Telephone of the Responsible Party Company CF Industries Sales, LLC 4 Parkway North, Suite 400 Deerfield, Illinois 60015-2590 [PHONE REDACTED] www.cfindustries.com 1.4. Emergency Telephone Number Emergency Number : [PHONE REDACTED] For Chemical Emergency, Spill, Leak, Fire, Exposure, or Accident, call CHEMTREC – Day or Night SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Not classified 2.2. Label Elements GHS-US Labeling No labeling applicable 2.3. Other Hazards Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Not applicable 3.2. Mixture Name Product Identifier % (w/w) Classification (GHS-US) Water (CAS No) 7732-18-5 67.5 Not classified Urea (CAS No) 57-13-6 32.5 Not classified SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Inhalation: When occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists. Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical attention if irritation develops or persists. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness develops or persists. Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention. 4.2. Most Important and Effects Both Acute and Delayed General: Not expected to present a significant hazard under anticipated conditions of normal use. Inhalation: Prolonged exposure to liquid may cause a mild irritation. Skin Contact: May cause mild skin irritation. Eye Contact: Prolonged exposure to liquid may cause a mild irritation. Page 52 of 377 Page 52 of 377 Page 52 of 377 Page 52 of 377 ---PAGE BREAK--- Diesel Exhaust Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 15 May 2015 EN (English US) 2/6 Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Not available 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media 5.2. Special Hazards Arising From the Substance or Mixture 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Oxides of Carbon, Nitrogen. Ammonia. Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid breathing (vapor, mist, spray). Avoid prolonged contact with eyes, skin and clothing. 6.1.1. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Stop leak if safe to do so. Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Contact competent authorities after a spill 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Absorb and/or contain spill with inert material, then place in suitable container. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: When heated to decomposition, emits toxic fumes. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool, and well-ventilated place. Keep container closed when not in use. Keep/Store away from extremely high or low temperatures, incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Alkalis. 7.3. Specific End Use(s) Diesel Exhaust NOx Reducing Agent. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters No additional information available. Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Fire Hazard: Not considered flammable but may burn at high temperatures. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions will not occur under normal conditions. Page 53 of 377 Page 53 of 377 Page 53 of 377 Page 53 of 377 ---PAGE BREAK--- Diesel Exhaust Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 15 May 2015 EN (English US) 3/6 8.2. Exposure Controls Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Personal Protective Equipment: In case of splash hazard: safety glasses. Materials for Protective Clothing: Not applicable. Hand Protection: Wear chemically resistant protective gloves. Eye Protection: In case of splash hazard: chemical goggles or safety glasses. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. Other Information: When using, do not eat, drink, or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Colorless, clear Odor : Slight Ammonia Odor Threshold : Not available pH : 9.8 - 10 Evaporation Rate : Not available Melting Point : Not available Freezing Point : - 12 °C (11 Boiling Point : 104 °C (219 Flash Point : Not available Auto-ignition Temperature : Not available Decomposition Temperature : Not available Flammability (solid, gas) : Not available Lower Flammable Limit : Not available Upper Flammable Limit : Not available Vapor Pressure : Not available Relative Vapor Density at 20 °C : Not available Relative Density : Not available Specific gravity / density : 9.0909 lbs. / USG - 4.13 kg / 3.785L @20°C (68°F) Specific Gravity : 1.087-1.093 @20°C (68°F) Solubility : 100% Partition Coefficient: N-Octanol/Water : Not available Viscosity : Not available Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact. Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge. SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity: Hazardous reactions will not occur under normal conditions. 10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 10.4. Conditions to Avoid: Extremely high or low temperatures. Incompatible materials. 10.5. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Alkalis. 10.6. Hazardous Decomposition Products: Nitrogen oxides. Irritating fumes. Ammonia. Carbon oxides (CO, CO2). Page 54 of 377 Page 54 of 377 Page 54 of 377 Page 54 of 377 ---PAGE BREAK--- Diesel Exhaust Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 15 May 2015 EN (English US) 4/6 SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects - Product LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Not classified pH: 9.8 - 10 Serious Eye Damage/Irritation: Not classified pH: 9.8 - 10 Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not classified Carcinogenicity: Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: Not classified After Inhalation: Prolonged exposure to liquid may cause a mild irritation. After Skin Contact: May cause mild skin irritation. After Eye Contact: Prolonged exposure to liquid may cause a mild irritation. After Ingestion: Ingestion is likely to be harmful or have adverse effects. 11.2. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Water (7732-18-5) LD50 Oral Rat > 90000 mg/kg Urea (57-13-6) LD50 Oral Rat 8471 mg/kg SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No additional information available Urea (57-13-6) LC50 Fish 1 16200 - 18300 mg/l (Exposure time: 96 h - Species: Poecilia reticulata) EC50 Daphnia 1 3910 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) 12.2. Persistence and Degradability Diesel Exhaust Fluid Persistence and Degradability Not established. 12.3. Bioaccumulative Potential Diesel Exhaust Fluid Bioaccumulative Potential Not established. Urea (57-13-6) BCF Fish 1 < 10 Log Pow -1.59 (at 25 12.4. Mobility in Soil Not available 12.5. Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations. Acute Toxicity: Not classified Page 55 of 377 Page 55 of 377 Page 55 of 377 Page 55 of 377 ---PAGE BREAK--- Diesel Exhaust Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 15 May 2015 EN (English US) 5/6 SECTION 14: TRANSPORT INFORMATION 14.1. In Accordance with DOT Not regulated for transport 14.2. In Accordance with IMDG Not regulated for transport 14.3. In Accordance with IATA Not regulated for transport 14.4. In Accordance with TDG Not regulated for transport SECTION 15: REGULATORY INFORMATION 15.1. US Federal Regulations Water (7732-18-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Urea (57-13-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State Regulations Urea (57-13-6) U.S. - Minnesota - Hazardous Substance List U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term 15.3. Canadian Regulations Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria Urea (57-13-6) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date : 15 May 2015 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. NFPA Health Hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA Fire Hazard : 0 - Materials that will not burn. NFPA Reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 0 Minimal Hazard Physical : 0 Minimal Hazard Party Responsible for the Preparation of This Document CF Industries, Corporate EHS Department, [PHONE REDACTED] Diesel Exhaust Fluid WHMIS Classification Uncontrolled product according to WHMIS classification criteria Page 56 of 377 Page 56 of 377 Page 56 of 377 Page 56 of 377 ---PAGE BREAK--- Diesel Exhaust Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 15 May 2015 EN (English US) 6/6 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. CF believes the information contained herein is accurate; however, CF makes no guarantees or warranties with respect to such accuracy and assumes no liability in connection with the use of the information contained herein by any party. The provision of the information contained herein by CF is not intended to be and should not be construed as legal advice or as ensuring compliance by other parties. Judgments as to the suitability of the information contained herein for the party’s own use or purposes are solely the responsibility of that party. Any party handling, transferring, transporting, storing, applying or otherwise using this product should review thoroughly all applicable laws, rules, regulations, standards and good engineering practices. Such thorough review should occur before the party handles, transfers, transports, stores, applies or otherwise uses this product. North America GHS US 2012 & WHMIS 2 Page 57 of 377 Page 57 of 377 Page 57 of 377 Page 57 of 377 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Diesel Fuel CAS Number: 64742-80-9 Manufacturer: Total Petrochemicals & Refining USA, Inc. SDS Date: 7/22/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=P74coa%2fh0QI%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 58 of 377 Page 58 of 377 Page 58 of 377 Page 58 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 1 of 13 POWER SERVICE PRODUCTS, INC. SAFETY DATA SHEET SECTION 1 - IDENTIFICATION PRODUCT NAME: DIESEL FUEL SUPPLEMENT +CETANE BOOST Unless otherwise noted, all sections of this SDS apply to each of the following products and part numbers. PART NUMBERS: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11080-06 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 COMPANY IDENTIFICATION: Power Service Products, Inc. P.O. Box 1089 Weatherford, TX 76086 Email: [EMAIL REDACTED] Phone: [PHONE REDACTED] or [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone Number: Within USA 1-[PHONE REDACTED]. Outside USA 001-[PHONE REDACTED] (Call Collect). RECOMMENDED USES: Diesel fuel additive SECTION 2 – HAZARD(S) IDENTIFICATION CLASSIFICATION UNDER 29 CFR 1910.1200(d) (NC=product does not meet classification criteria) 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Acute Toxicity, Oral: NC NC NC Acute Toxicity, Dermal: NC NC NC Acute Toxicity, Inhalation, Vapors: 3 3 3 Page 59 of 377 Page 59 of 377 Page 59 of 377 Page 59 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 2 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Skin Corrosion/Irritation: 2 2 2 Serious Eye Damage/Eye Irritation: 2 2 2 Respiratory Sensitization: NC NC NC Skin Sensitization: NC NC NC Germ Cell Mutagenicity: NC NC NC Carcinogenicity: 2 2 2 Reproductive Toxicity: NC NC NC Specific Target Organ Toxicity, Single Exposure: 3 3 3 Specific Target Organ Toxicity, Repeated or Prolonged Exposure: NC NC NC Aspiration Hazard: 1 1 1 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Physical Properties Criteria Category Category Category Explosives: NC NC NC Flammable Gases: NC NC NC Flammable Aerosols: NC NC NC Oxidizing Gases: NC NC NC Gases Under Pressure: NC NC NC Flammable Liquids: 3 3 3 Flammable Solids: NC NC NC Self-Reactive Chemicals: NC NC NC Pyrophoric Liquids: NC NC NC Pyrophoric Solids: NC NC NC Self-Heating Chemicals: NC NC NC Chemicals Which, in Contact with Water, Emit Flammable Gases: NC NC NC Oxidizing Liquids: NC NC NC Oxidizing Solids: NC NC NC Organic Peroxides: NC NC NC Corrosive to Metals: NC NC NC LABEL SIGNAL WORD, HAZARD STATEMENTS, SYMBOLS AND PRECAUTIONARY STATEMENTS UNDER 29 CFR 1910.1200(f): Please see the Note regarding product labeling in Section 16. Page 60 of 377 Page 60 of 377 Page 60 of 377 Page 60 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 3 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Signal Word Danger Danger Danger Hazard Statement(s): Flammable liquid and vapor. Toxic if inhaled. May be fatal if swallowed and enters airways. Harmful if swallowed. Causes skin and serious eye irritation. May cause respiratory irritation and drowsiness or dizziness. Symbols: The following symbols are for all treatment ratios. Precautionary Statement(s): Keep away from sparks and open flames. No smoking. Keep container closed. Use only non-sparking tools. Ground/Bond container and receiving equipment. Use explosion-proof pumps when pumping. Take precautionary measures against static discharge. Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves and eye protection. Store locked up and in cool, well ventilated place. KEEP OUT OF REACH OF CHILDREN. Hazards Not Otherwise Classified: None SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS The specific chemical identity and exact concentration percentage has been withheld as a Trade Secret. Specific chemical information will be made available to health professionals in accordance with 29 CFR 1910.1200. INGREDIENTS CLASSIFIED AS HEALTH HAZARDS TREATMENT RATIO 1:400 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 50 - 90 Hydroxy alkoxylate Trade secret Trade secret 4 - 10 Alkyl Nitrates Trade secret Trade secret 2 - 6 Naphthalene Not available 91-20-3 0.05 – 0.2 Page 61 of 377 Page 61 of 377 Page 61 of 377 Page 61 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 4 of 13 TREATMENT RATIO 1:1000 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 40 - 90 Alkyl Nitrates Trade secret Trade secret 5 - 15 Aromatic Hydrocarbons Trade secret Trade secret 2 - 5 Hexan-1-ol, 2-ethyl Trade secret Trade secret 1 - 4 Naphthalene Not available 91-20-3 0.1 – 0.5 TREATMENT RATIO 1:1500 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 20 - 55 Alkyl Nitrates Trade secret Trade secret 10 – 20 Aromatic Hydrocarbons Trade secret Trade secret 3 - 8 Hexan-1-ol, 2-ethyl Trade secret Trade secret 2 – 5 Naphthalene Not available 91-20-3 0.2 – 0.9 SECTION 4 - FIRST AID MEASURES As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. EYE CONTACT: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice. SKIN CONTACT: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs get medical advice/attention. INHALATION: Remove person to fresh air and keep comfortable for breathing. Call a doctor. INGESTION: If swallowed, IMMEDIATELY call a doctor. Do NOT induce vomiting. SECTION 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPECIFIC HAZARDS: Vapors are heavier than air and may travel along the ground to a distant ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH Page 62 of 377 Page 62 of 377 Page 62 of 377 Page 62 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 5 of 13 EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY CONTAINER. PROTECTIVE EQUIPMENT AND PRECAUTIONS: Use standard protective equipment including self-contained breathing apparatus (SCBA). SECTION 6 - ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures. See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment. SPILL CONTAINMENT AND CLEAN-UP: Eliminate potential sources of ignition. Stop leak if it can be done without risk. Dike and contain spill. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. A vapor suppressing foam may be used to reduce vapors. Local, state and federal laws and/or regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up releases. The user/responder will need to determine which local, state and federal laws and/or regulations are applicable. The National Response Center can be reached at 1-[PHONE REDACTED]. SECTION 7 - HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Avoid contact with eyes and skin. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and flames. No smoking. CONDITIONS FOR SAFE STORAGE: DO NOT USE OR STORE near heat, sparks, or flame. USE AND STORE ONLY IN A WELL-VENTILATED AREA. Handle containers with care. Keep container closed when not in use. Store locked up. STORAGE TEMPERATURE: Treatment Ratio Part Numbers: Storage Temperature: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11041-04, 11080-06 -20F to 104F (-29C to 40C) 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 0F to 104F (-18C to 40C) Page 63 of 377 Page 63 of 377 Page 63 of 377 Page 63 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 6 of 13 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 10F to 104F (-12C to 40C) EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: CAS # OSHA ACGIH NIOSH PEL TLV STEL REL STEL IDLH Note 100-41-4 100 ppm 20 ppm not est. 100 ppm 125 ppm 800 ppm (LEL) n/a Naphthalene 91-20-3 10 ppm 10 ppm not est. 10 ppm 15 ppm 250 ppm skin Petroleum Distillates n/a 500 ppm not est. not est. not est. not est. not est. n/a Cumene 98-82-8 50 ppm 50 ppm not est. 50 ppm not est. 900 ppm (LEL) Skin Toluene 108-88-3 100 ppm 20 ppm not est. 100 ppm 150 ppm 500 ppm Skin Hydroxy Alkoxylate Proprietary 50 ppm 20 ppm not est. 5 ppm not est. not est. skin ENGINEERING CONTROLS: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Local exhaust ventilation is recommended to control exposure. PERSONAL PROTECTIVE EQUIPMENT (PPE): Eyes and Face: Eye protection such as safety glasses or chemical goggles is recommended if contact is likely. Skin: Protective chemical/oil resistant gloves are recommended. Wear additional protective clothing as appropriate. Respiratory: Wear a NIOSH/MSHA approved respirator as necessary. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Practice good housekeeping. NOTE: These precautions are for room temperature handling. Page 64 of 377 Page 64 of 377 Page 64 of 377 Page 64 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 7 of 13 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Appearance Liquid, brown Liquid, brown Liquid, brown Odor Aromatic solvent Aromatic solvent Aromatic solvent Odor Threshold Not available Not available Not available pH 7 – 8 basic) 7 – 8 basic) 7 – 8 basic) Melting point/Freezing point Not available Not available Not available Initial Boiling Point and Boiling Range 300F (149C) 300F (149C) 300F (149C) Flash Point 105F (40.5C) 116F (46.6C) 121F (49.4C) Evaporation Rate Not available Not available Not available Flammability Not available Not available Not available Upper / lower Flammability or Explosive Limits Not available Not available Not available Vapor Pressure 0.2 – 0.95 0.2 – 0.95 0.2 – 0.95 Vapor Density >5.0 >5.0 >5.0 Relative Density/Specific Gravity (at 60°F) 0.910 0.912 0.896 Solubility Not available Not available Not available Partition Coefficient; n-octanol / water Not available Not available Not available Auto-ignition Temperature Not available Not available Not available Decomposition temperature Not available Not available Not available Viscosity Not available Not available Not available Pour Point -55F (-13C) -30F (1.1C) -15F (9.4C) SECTION 10 - STABILITY AND REACTIVITY REACTIVITY: see Incompatible Materials below CHEMICAL STABILITY: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. POSSIBILITY OF HAZARDOUS REACTION: Hazardous polymerization will not occur. CONDITIONS TO AVOID: Flames, high energy ignition sources, and elevated temperatures. INCOMPATIBLE MATERIALS: May react with strong oxidizing agents, such as; chlorates, nitrates, peroxides, nitrogen oxides, sulfur oxides, etc.; alkalis; nitric acid; sulfuric acid; aluminum; brass; copper; reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, products of incomplete combustion. Page 65 of 377 Page 65 of 377 Page 65 of 377 Page 65 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 8 of 13 SECTION 11 - TOXICOLOGICAL INFORMATION LIKELY ROUTES OF EXPOSURE INGESTION INHALATION SKIN CONTACT EYE CONTACT SKIN ABSORPTION 1:400 Treatment Ratio X X X X 1:1000 Treatment Ratio X X X X 1:1500 Treatment Ratio X X X X RELATED TO PHYSICAL, CHEMICAL AND TOXICOLOGICAL CHARACTERISTICS: Breathing of high vapor concentrations may cause dizziness, light- headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors, or convulsions, loss of consciousness, coma or death. DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND LONG-TERM EXPOSURE: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in the presence of maternal toxicity in animals. NUMERICAL MEASURES OF TOXICITY Note: the information provided below are estimates; testing of the product is not available. Treatment Ratio Acute Oral Toxicity (ATEmix estimate) Acute Dermal Toxicity (ATEmix estimate) Acute Inhalation (ATEmix estimate) 1:400 Treatment Ratio Does not meet criteria Does not meet criteria 7.10 (vapors) 1:1,000 Treatment Ratio Does not meet criteria Does not meet criteria 8.56 (vapors) 1:1,500 Treatment Ratio Does not meet criteria Does not meet criteria 7.48 (vapors) SENSITIZATION: No information available. MUTAGENICITY: No information available. CARCINOGENICITY LISTINGS – the following chemicals are listed as indicated: Page 66 of 377 Page 66 of 377 Page 66 of 377 Page 66 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 9 of 13 Chemical List Cumene IARC, NTP IARC Naphthalene IARC, NTP REPODUCTIVE TOXICITY: No information available. TERATOGENICITY/EMBRYOTOXICITY: Hydroxy Alkoxylate has caused fetotoxicity with maternal toxicity. This product contains a component of a complex mixture (Xylenes (1330-20- that has been shown to cause teratogenicity and/or embryotoxicity. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Respiratory tract irritation, drowsiness/dizziness. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): No information available ASPIRATION HAZARD: Aspiration hazard identified. SECTION 12 - ECOLOGICAL INFORMATION ECOTOXICITY: This material is expected to be toxic to aquatic organisms. PERSISTENCE AND DEGRADABILITY: No information available. BIOACCUMULATIVE POTENTIAL: No information available. MOBILITY IN SOIL: No information available. OTHER ADVERSE EFFECTS: No information available. SECTION 13 - DISPOSAL CONSIDERATIONS RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste regulations (40 CFR Part 261). Disposal of the used product may also be regulated as hazardous waste due to resulting mixture characteristics, mixture components or product use. Such changes to the product may result in different and/or additional hazardous waste codes. Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY State or local laws may impose additional regulatory requirements regarding disposal. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION Page 67 of 377 Page 67 of 377 Page 67 of 377 Page 67 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 10 of 13 HAZARD DATA. Dispose or recycle empty containers appropriately per local, state and federal regulations. SECTION 14 - TRANSPORTATION INFORMATION The following part numbers are not regulated by DOT: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 1080-06 1:1,000 Treatment Ratio 1128-04 1:1,500 Treatment Ratio 1050-02, 1055-01 The following part numbers are regulated by DOT: 1:1,000 Treatment Ratio 1060-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes 1:1,000 Treatment Ratio 1000 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) RQ (Xylene, Naphthalene) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes PRODUCT RQ: 100 lbs. (45.45 kg) – Xylene, Naphthalene 1:1,500 Treatment Ratio 1260-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes Page 68 of 377 Page 68 of 377 Page 68 of 377 Page 68 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 11 of 13 SECTION 15 - REGULATORY INFORMATION §14(a) Consumer Product Safety Act General Certificate of Conformity Power Service Products, Inc. certifies that this product meets the statutory and regulatory requirements of the US Consumer Products Safety Act, the Federal Hazardous Substances Act, and the Poison Prevention Packaging Act of 1970, as applicable. The Power Service products are manufactured in the United States in Weatherford, Texas, unless otherwise indicated on the product label. The product manufacture lot code is stamped on the product container. This Certification is based upon a reasonable testing program conducted by Power Service Products, Inc. which includes a quality control program incorporating, as necessary, confirmation of compliance by component suppliers. Third-party testing is not required to certify compliance. Further details may be obtained by contacting the Power Service Products, Inc. EHS Manager at 1-[PHONE REDACTED]. Contents of this SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act inventory reporting requirements. EPA SARA TITLE III CHEMICAL LISTINGS: Section 302 Extremely Hazardous Substances: None Sections 311/ 312 Hazard Class: Acute Health Effects: Yes Sudden Release of Pressure Hazard: No Chronic Health Effects: Yes Reactivity Hazard: No Fire Hazard: Yes NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) RATING: HEALTH: 2 FIRE: 2 REACTIVITY: 0 Section 313: Specific chemical information is being withheld as a Trade Secret. The following chemicals subject to the reporting requirements of EPCRA Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (40 CFR Part 372) may be present in this product at a concentration that does not exceed the specified upper weight percentage. Treatment Ratio CAS Number Chemical Name Max % 1:400 Treatment Ratio 100-41-4 24.0 NA Glycol Ether Category 8.0 Page 69 of 377 Page 69 of 377 Page 69 of 377 Page 69 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 12 of 13 Treatment Ratio CAS Number Chemical Name Max % 91-20-3 Naphthalene 1.0 98-82-8 Cumene 4.0 108-88-3 Toluene 4.0 1:1000 Treatment Ratio 100-41-4 19.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 3.5 108-88-3 Toluene 3.5 1:1,500 Treatment Ratio 100-41-4 12.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 2.0 108-88-3 Toluene 2.0 State or local laws may impose additional regulatory requirements for components of this material. It is the responsibility solely of the Employer to maintain compliance with State and Local reporting. This product contains a chemical known to the state of California to cause cancer and/or birth defects or other reproductive harm: toluene, cumene, naphthalene. SECTION 16 – OTHER INFORMATION DATE OF PREPARATION / REVISION: May 30, 2015 NOTE regarding product labeling: The OSHA Hazard Communication Standard applies to hazardous chemicals known to be present in the workplace. However, the labeling and Safety Data Sheet requirements do not apply to consumer products when they are used in the workplace for the purposes intended by the manufacturer and the use results in a duration and frequency of exposure which is not greater than the range of exposures that could reasonably be experienced by consumers when used for the intended purpose. Power Service Products intends for product packaged in 1 gallon or smaller containers to be used by consumers and has labeled those containers as required under the Consumer Product Safety Commission regulations. Power Service Products intends for product packaged in containers larger than 1 gallon to be used in the workplace and has labeled those products as required by the OSHA Hazard Communication Standard. The Consumer Product Safety Commission and OSHA Hazard Communication Standard labeling requirements are different and variations between the consumer and industrial labels may occur. It is the employer’s responsibility to purchase the appropriate product for use in the workplace. The information contained herein is offered in good faith and is believed to be accurate based on the data available to us as of the date of SDS preparation. The information in this document applies to this specific product as supplied. It may not be appropriate for this product if the product is used in combination with other materials. The information in this document is not intended to constitute product performance information. Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product. No statement shall be construed as an endorsement of any product or process. The recommended Page 70 of 377 Page 70 of 377 Page 70 of 377 Page 70 of 377 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 13 of 13 industrial hygiene and safe handling procedures are believed to be valid in the context of the intended use as described in product labeling. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. You are urged to obtain material safety data sheets for all products you buy, process, use or distribute, and are encouraged to advise those who may come in contact with such products of the information contained therein. Regulatory requirements are subject to change and may differ between locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. No warranty or guarantee is expressed or implied with respect to this product, the accuracy and sufficiency of the data or recommendations herein, or the results to be obtained from the use of this product. IN NO EVENT SHALL POWER SERVICE PRODUCTS, INC. BE LIABLE FOR ANY LOSS, CLAIM, DAMAGE OR LIABILITY OF ANY KIND, WHICH MAY ARISE FROM OR IN CONNECTION WITH THE INFORMATION CONTAINED IN THIS DOCUMENT OR FROM THE USE, HANDLING OR STORAGE OF THE PRODUCT BY THE BUYER/USER, WHETHER DIRECT, INDIRECT, OR CONSEQUENTIAL, OR FOR ANY CLAIM BY ANY THIRD PARTY, BEYOND THE PURCHASE PRICE OR REPLACEMENT OF THE PRODUCT IN CONNECTION WITH WHICH SUCH LOSS, CLAIM, DAMAGE OR LIABILITY AROSE. THE FOREGOING LIMITATIONS APPLY REGARDLESS OF THE CAUSES OR CIRCUMSTANCES GIVING RISE TO SUCH LOSS, CLAIM, DAMAGE OR LIABILITY, EVEN IF SUCH LOSS, CLAIM, DAMAGE, OR LIABILITY IS BASED ON NEGLIGENCE OR OTHER TORTS OR BREACH OF CONTRACT. Page 71 of 377 Page 71 of 377 Page 71 of 377 Page 71 of 377 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET: ELECTRA SEAL PLUS AEROSO Section I - General Information (000000-000000- - 5625) Date of Issue: 9/14/2004 12:00:00 AM Supercedes: 1/1/1989 12:00:00 AM Chemical Name & Synonyms: N/A Trade Name & Synonyms: ELECTRA SEAL PLUS AEROS Chemical Family: SOLVENT MIXTURE Formula is a mixture: Manufacturer Name: MANTEK, DIVISION OF NCH CORP. Manufacturer Address: BOX 152170 IRVING, TEXAS 75015 Prepared By: M McDowell/Chemist Product Code Number: 5625 Emergency Phone Number: [PHONE REDACTED] Section II - Hazardous Ingredients THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS Chemical Name (Ingredients) Hazard TLV PEL STEL ALIPHATIC PETROLEUM DISTILLATES IRR/COMB 100 PPM $1 500 PPM $2 N/E MINERAL OIL IRRITANT 5 MG/M3$$1 5 MG/M3$$2 10MG/M3$ BARIUM SULFONATE IRRITANT 0.5MG/M3*1 0.5MG/M3*2 N/E SOLVENT REFINED LIGHT PARAFFINIC DISTILLATE IRRITANT 5 MG/M3$$1 5 MG/M3$$2 10MG/M3$ SOLVENT REFINED LIGHT NAPHTHENIC DISTILLATE IRRITANT 5 MG/M3$$1 5 MG/M3$$2 10MG/M3$ SEVERELY HYDROTREATED LIGHT PARAFFINIC DISTILLATE IRRITANT 5 MG/M3$$1 5 MG/M3$$2 10MG/M3$ SEVERELY HYDROTREATED LIGHT NAPHTHENIC DISTILLATE IRRITANT 5 MG/M3$$1 5 MG/M3$$2 10MG/M3$ PROPANE FLAM/ASPHY 1000PPM**1 1000 PPM 1 N/E N-BUTANE FLAM/ASPHY 1000PPM**1 N/E 2 N/E $ STODDARD SOLVENT VALUES OIL MIST VALUES * BARIUM VALUES ALIPHATIC HYDROCARBON GASES # 64742-47-8, 64742-88-7, 8052-41-3 Section IIa - Non-Hazardous Ingredients (NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NJ TRADE Secret Registry 409363 - 5098P Section III - Physical Data Boiling Point 300° Specific Gravity (H20=1): 0.73 Vapor Pressure (mm Hg): 2529 Color: AMBER Vapor Density (Air=1): 1.7 Odor: SOLVENT pH @ 100% : N/A Clarity: TRANSPA % Volatile by Volume: 92 Evaporation Rate (BuAc=1): 36.7 H20 Solubility: INSOLUBLE Viscosity: NON-VISC Strona 1 z 5 PIRS: Material Safety Data Sheet 2007-05-16 Page 72 of 377 Page 72 of 377 Page 72 of 377 Page 72 of 377 ---PAGE BREAK--- Even numbered pages not converted in the evaluation version To purchase go to our website at http://www.bclcomputers.com Page 73 of 377 Page 73 of 377 Page 73 of 377 Page 73 of 377 ---PAGE BREAK--- FOR SEVERAL MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS. Skin Contact: WASH AFFECTED AREAS WITH LARGE AMOUNTS OF SOAP AND WATER FOR 15 MINUTES. REMOVE CONTAMI CLOTHING AND SHOES. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. WASH CLOTHING AND CLEAN S BEFORE REUSE. Ingestion: GIVE 3 TO 4 GLASSES OF WATER, BUT DO NOT INDUCE VOMITING. IF VOMITING OCCURS, GIVE FLUIDS AGAIN IMMEDIATE MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIN Notes to Physician: INGESTION AND SUBSEQUENT VOMITING OF THIS PRODUCT CAN LEAD TO ASPIRATION OF THE PRODUCT IN LUNGS WHICH CAN CAUSE DAMAGE AND MAY BE FATAL. DEPENDING ON THE AMOUNT INGESTED AND RETA WELL AS THE TOXICITY OF THE PRODUCT, GASTRIC LAVAGE SHOULD BE CONSIDERED. KEEP PATIENT'S HE HIPS TO PREVENT PULMONARY ASPIRATION. IF COMATOSE, A CUFFED ENDOTRACHAEL TUBE WILL PREVEN ASPIRATION. Section VI - Toxicity Information Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By: [ ] IARC [ ] NTP [ ] OSHA [ ] ACGIH [ ] Other VOC CONTENT: 90% BY WEIGHT, 92.1% BY VOLUME, 656.9 G/L ALIPHATIC PETROLEUM DISTILLATES ORL-RAT LD50: >10 G/KG 4. IHL-RAT LC50: >290 PPM 4. SKN-RBT LD50: >3 G/KG 4. SKN SENSITIZER: NO 4. SKN IRRITATION: SLIGHT 4. EYE IRRITATION: SLIGHT 4. THIS HYDROCARBON WAS ADMINISTERED ORALLY 5 DAYS/WEEK TO MALE AND FEMALE RATS AT 100, 500, O MG/KG FOR 13 WEEKS. AN ADDITIONAL GROUP WAS DOSED WITH 100 MG/KG FOR 13 WEEKS FOLLOWED BY RECOVERY PERIOD. NO MORTALITIES OR CLINICAL EFFECTS WERE OBSERVED. LIVER AND KIDNEY WEIGHT 500 AND 1000 MG/KG EXPOSURE GROUPS WERE SIGNIFICANTLY INCREASED. AFTER THE 4-WEEK RECOVER THERE WERE NO DIFFERENCES IN ORGAN WEIGHTS. 4. HYDROCARBON MISTS, AND MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS, ARE REPORTED TO ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND SHORT-TERM REPEATED EXP HIGH CONCENTRATIONS WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAM REACTION, LIPOID GRANULOMA FORMATION, AND LIPOID PNEUMONIA. IN ACUTE AND SUB-ACUTE STUDIES EXPOSURES TO LOWER CONCENTRATIONS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODU SIGNIFICANT TOXICOLOGICAL EFFECTS. IN LONG TERM STUDIES (UP TO TWO YEARS) NO CARCINOGENIC EF HAVE BEEN REPORTED IN ANY ANIMAL SPECIES TESTED. THESE PETROLEUM DISTILLATES ARE SEVERELY HYDROTREATED, SEVERELY SOLVENT EXTRACTED, AND/OR PROCESSED BY MILD HYDROTREATMENT AND EXTRACTION. FOR THIS REASON, THEY ARE NOT CLASSIFIED AS CANCER HAZARDS. 3. MINERAL OIL IHL-RAT LC50: 2062 PPM/4H 4. ORL-RAT LD50: 5000 MG/KG 3. SKN-RBT SDT: 100 MG/24H MILD 3. EYE-RBT SDT: 250 MG/5D MODERATE 3. BARIUM SULFONATE NO TOXICITY DATA AVAILABLE SOLVENT REFINED LIGHT PARAFFINIC DISTILLATE ORL-RAT LD50: >15 G/KG 4. SKN-RBT LD50: >5 G/KG 4. SOLVENT REFINED LIGHT NAPHTHENIC DISTILLATE ORL-RAT LD: >5 G/KG 4. SKN-RBT LD: >5 G/KG 4. SEVERELY HYDROTREATED LIGHT PARAFFINIC DISTILLATE NO TOXICITY DATA AVAILABLE Strona 3 z 5 PIRS: Material Safety Data Sheet 2007-05-16 Page 74 of 377 Page 74 of 377 Page 74 of 377 Page 74 of 377 ---PAGE BREAK--- Even numbered pages not converted in the evaluation version To purchase go to our website at http://www.bclcomputers.com Page 75 of 377 Page 75 of 377 Page 75 of 377 Page 75 of 377 ---PAGE BREAK--- ©2006 NCH Corporation All rights reserved. ENSURE COMPLIANCE WITH OSHA'S PERSONAL PROTECTIVE EQUIPMENT (PPE) STANDARD FOR EYE AND FA PROTECTION, 29 CFR 1910.133. Other Protection: WEAR GENERAL-DUTY WORK CLOTHES AND SHOES. REMOVE OIL SOAKED CLOTHING AND SHOES. WASH CL AND CLEAN SHOES BEFORE REUSE. A SAFETY SHOWER AND AN EYEWASH STATION SHOULD BE AVAILABLE Section X - Storage and Handling Information Storage Temperature Max: 120°F. Min: 30°F. Storage Conditions Indoors [ ] Outdoors [ ] Heated [ ] Refrig Precautions to be Taken in Handling and Storing: USE WITH CAUTION AROUND HEAT, SPARKS, PILOT LIGHTS, STATIC ELECTRICITY, AND OPEN FLAME. SOME MATERIALS SUCH AS RAGS, PAPER, ETC. WHEN WETTED WITH THIS PRODUCT MAY UNDERGO SPONTANEO COMBUSTION. Other Precautions: KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL BEFORE USING THE PRODUCT. FOLLOW THE DIRECTIONS. Section XI - Regulatory Information Chemical Name CAS Number Upper % Limit BARIUM COMPOUNDS N/A 5 Those Ingredients listed above are subject to the reporting requirements of 313 of Title III of the Superfund Amendments Reauthorization Act of 1986 and 40 CFR part 372. Please call 1-[PHONE REDACTED] for additional information if you are a California customer. This MSDS is not intended for use of California. Section XII - References 1. THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS AND BIOLOGICAL EXPOS INDICES, ACGIH, 2004. 2. OSHA PEL. 3. VENDOR'S MSDS 4. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBS CCINFOWeb, 2004. ALL THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE TOXIC SUBSTA CONTROL ACT (TSCA) AND ARE EITHER LISTED ON THE TSCA INVENTORY OR OTHERWISE EXEMPTED FROM IRR:IRRITANT, FLAM/FLAMM:FLAMMABLE, COMB:COMBUSTIBLE, CORR:CORROSIVE CARC:CARCINOGENIC, TO N/A:NOT APPLICABLE, N/E:NOT ESTABLISHED, COC:CLEVELAND OPEN CUP, PMCC:PENSKY-MARTIN CLOSED TCC:TAGLIABUE CLOSED CUP, LEL:LOWER EXPLOSION LIMIT, UEL:UPPER EXPLOSION LIMIT, NFPA:NATIONAL PROTECTION ASSOCIATION, IARC:INTERNATIONAL AGENCY FOR THE RESEARCH ON CANCER, NTP:NATIONA TOXICOLOGY PROGRAM, OSHA:OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION, ACGIH:AMERICAN CON OF GOVERNMENTAL INDUSTRIAL HYGIENISTS, TLV:THRESHOLD LIMIT VALUE, PEL:PERMISSIBLE EXPOSURE STEL:SHORT-TERM EXPOSURE LIMIT, MLD:MILD, MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC, PNOS:PARTICLES (INSOLUBLE) NOT OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST, ORL:ORAL, IHL:IN HMN:HUMAN THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. MANTEK, DIVISION OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the us disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage, or disposal of the product. Strona 5 z 5 PIRS: Material Safety Data Sheet 2007-05-16 Page 76 of 377 Page 76 of 377 Page 76 of 377 Page 76 of 377 ---PAGE BREAK--- Febreze Set & Refresh (Air Freshener) – Rain / Ginger Verbena Page 1 of 6 The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS RQ1302020-1 Issue Date: 11-20-2014 Supersedes: RQ1302020 Issue Date: 03-11-2013 SECTION I - PRODUCT IDENTIFICATION Identity: Febreze Set & Refresh (Air Freshener) Finished Product Brands/Scent Version: Rain / Ginger Verbena P&G Telephone Number: 1-[PHONE REDACTED] or call the Local Poison Control Center or your physician. SECTION II - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: Contents harmful if swallowed. This is expected to be a highly unusual route of exposure for this product. Amounts that may be swallowed as a result of workplace handling are not likely to cause injury. Eye Contact: Contact causes mild eye irritation. Skin Contact: Moderately irritating to the skin. Prolonged / repeated direct contact with fragrance oils may result in skin sensitization. Inhalation: Prolonged high level exposures may cause slight drowsiness, headache and / or mild respiratory tract irritation. Signs and of Exposure: Ingestion: May cause minor gastrointestinal upset such as vomiting and nausea. Eye Contact: May cause redness or stinging of eyes. Skin: Prolonged contact may cause itching or dryness of skin. Inhalation: May cause mild of nose or throat irritation or congestion. Medical Conditions Generally Know to be Aggravated by Exposure: None Potential Environmental Effects: (See Section 12 for more information) SECTION III - COMPOSITION AND INGREDIENTS The fragrance contains one or more components at greater than 1% concentration (in the fragrance) which are considered hazardous per OSHA 29 CFR 1910.1200 (See Section VII for applicable exposure limits) and/or WHMIS under HPA: Chemical Name Common Name CAS No. Composition Range LD50/LC50 Benzyl acetate 140-11-4 5-10% 2.4 mg/kg Diphenyl ether 101-84-8 1-5% 3.37mg/kg Citral 5392-40-5 0.5 to 1.5% 4960 mg/kg Page 77 of 377 Page 77 of 377 Page 77 of 377 Page 77 of 377 ---PAGE BREAK--- Febreze Set & Refresh (Air Freshener) – Rain / Ginger Verbena Page 2 of 6 SECTION IV – FIRST AID INFORMATION First Aid Procedures: Ingestion: If ingested, do not induce vomiting. Call a physician or local Poison Control Center ASAP. Eye Contact: Immediately flush eyes with water for at least 15 minutes. Call a physician, if persist. Skin: Remove any contaminated clothing or shoes. Thoroughly wash affected areas with soap and water. Flush with large quantities of water. If irritation develops or persists, call a physician. Inhalation: If exposed to excessive levels, get fresh air. If persist, contact a physician Note to Physician: (if applicable) Other: The following caution statements are included in the product front and back panels: Front Panel Labeling: CAUTION: EYE IRRITANT. See caution on back. Back Panel Labeling: CAUTION: EYE IRRITANT. Avoid contact with eyes. Do not put fingers into product vent. Wash hands after handling perfume cartridge. KEEP OUT OF REACH OF CHILDREN AND PETS. FIRST AID TREATMENT: Contains fragrance oils. If eye contact occurs rinse with plenty of water for 20 minutes. If eye irritation persists, consult a physician. IF SWALLOWED; do not induce vomiting, call a physician or poison control center immediately. SECTION V - FIRE FIGHTING INFORMATION Flash Point and Method Used: For the neat fragrance: 190.40 °F (88 ºC) - Closed Cup Flammable Properties: Upper Flammable Limit: unknown Lower Flammable Limit: unknown Explosive Limits: UEL: unknown LEL: unknown Auto-ignition Temperature: Unknown Hazardous Combustion Products: Unknown Explosion Data (Sensitivity to Mechanical Impact): NA Explosion Data (Sensitivity to Static Discharge): NA Extinguishing Media: Suitable: Use dry chemical, carbon dioxide, water spray or regular foam. Unsuitable: None known. Protection of Firefighters: Specific Hazards Arising from the Material: No special hazards known. Protective Equipment and Precautions for Firefighters: Normal fire-fighting gear. Page 78 of 377 Page 78 of 377 Page 78 of 377 Page 78 of 377 ---PAGE BREAK--- Febreze Set & Refresh (Air Freshener) – Rain / Ginger Verbena Page 3 of 6 SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact of fragrance with skin and eyes. Wear rubber gloves. Provide maximum ventilation in the area of the spill to disperse vapors. Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE, PROVINCIAL AND LOCAL REGULATIONS. Contain all spills. Methods for Containment: For large spills: dike or contain spill. Absorb with inert material and dispose. Flush area with water. Prevent washings from entering waterways. Sorbents may be used. For small spills: Wipe up with paper towels or cloth. Methods for Cleanup: Sweep up and place in suitable, clean dry containers for reclamation or disposal. Other Information: N/A SECTION VII – HANDLING AND STORAGE Precautions To Be Taken in Handling: Do not use around open flame. Precautions To Be Taken in Storage: Store in a cool dry place with adequate ventilation. SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines: Ingredient Exposure Limit Type* Exposure Limit Regulatory Agency Benzyl acetate (140-11-4) TWA 10ppm ACGIH Diphenyl ether (101-84-8) TWA 1ppm ACGIH Diphenyl ether (101-84-8) STEL 2ppm ACGIH Citral (5392-40-5) TWA 5ppm ACGIH Engineering Controls: Workplace should have sufficient general ventilation to disperse vapors in the event of a spill of the contents of this product. Personal Protective Equipment (PPE): Eye/Face Protection: None required for normal consumer use. Avoid contact with eyes. Wash hands after handling refill cartridges. If eye contact occurs, rinse with plenty of water for 20 minutes. Industrial setting: If a splash of solution is likely, chemical goggles may be needed. Skin Protection: None required for normal consumer use. Industrial setting: Minimize skin contact with protective gloves (rubber or neoprene). Respiratory Protection: None required with normal consumer use. Industrial setting: Use ventilation to minimize exposure to fragrance vapors. Prolonged exposure to high vapor concentrations may require respiratory protection as approved by local regulatory agencies NIOSH) for organic vapors. Page 79 of 377 Page 79 of 377 Page 79 of 377 Page 79 of 377 ---PAGE BREAK--- Febreze Set & Refresh (Air Freshener) – Rain / Ginger Verbena Page 4 of 6 SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Colorless to amber liquid Flash Point (Method Used): For the neat fragrance: : 190.40 °F (88 ºC) - Closed Cup Odor: Perfume odor Reserve Alkalinity: N/A Odor Threshold: NK Solubility in Water: NK Physical State: Liquid. Decomposition Temperature: NK Vapor Pressure (mm Hg): 0.062 (calculated) Evaporation Rate (nBuOAc=1): NK Vapor Density (Air=1): NK Specific Gravity/Density: NK Boiling Point: NK Melting/Freezing Point: NK Partition Coefficient (n-octanol/water): NK pH (100% solution): N/A Volatile Organic Compound (VOC): Not applicable - Product not regulated for VOC Content at State or Federal level. SECTION X - STABILITY AND REACTIVITY Chemical Stability: Stable under ambient conditions. Does not undergo violent exothermic reactions at elevated temperatures or pressures. Conditions to Avoid: Avoid ignition sources and open flames Incompatible Materials: Avoid contact with strong oxidizers. Hazardous Decomposition Products: When exposed to fire, produces carbon monoxide and other products of combustion. Possibility of Hazardous Reactions: None known. SECTION XI - TOXICOLOGICAL INFORMATION The fragrance is a mixture of materials carefully formulated to comply with the International Fragrance Association (IFRA) and Procter & Gamble guidelines regarding their safe use in consumer products. The health hazards and precautions described herein are based on the toxicity of individual components, and testing of this or similar mixtures. This perfume is expected to be very low in oral and dermal toxicity. If exposed to high concentrations, transient eye, skin and respiratory irritation may occur. Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: This finished consumer product is not carcinogenic. NTP: No IARC: No SECTION XII - ECOLOGICAL INFORMATION This product is expected to be safe at relevant environmental concentrations. It is intended for dispersive use and should not be disposed of directly into the environment. The used product is compatible with municipal solid waste systems and will not pose a hazard to the environment when the waste is properly handled. Page 80 of 377 Page 80 of 377 Page 80 of 377 Page 80 of 377 ---PAGE BREAK--- Febreze Set & Refresh (Air Freshener) – Rain / Ginger Verbena Page 5 of 6 SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal is to be performed in compliance with federal, state/provincial and local regulations. Non-Household Setting (US Federal): Product covered by this MSDS, in its original form, when disposed as waste, is considered non hazardous waste according to the federal RCRA Regulation (40CFR261). Disposal should be in accordance with the local, state and federal regulations. Non-Household Setting (California): Hazardous, in accordance with 22 CCR 66261.20 through 22 CCR 66261.24 Household Use: Product used in the household may be disposed of in refuse. SECTION XIV - TRANSPORT INFORMATION Ground Transport (US DOT): Product covered by this MSDS, in its original form, is not regulated for transportation. Air Transport (IATA): UN3082, Environmentally Hazardous Substance, liquid, n.o.s (alcohols and aldehydes), 9, III LTD QTY Marine/Water Transport (IMDG): UN3082, Environmentally Hazardous Substance, liquid, n.o.s (alcohols and aldehydes), 9, III LTD QTY SECTION XV - REGULATORY INFORMATION United States All intentionally-added components of this product are listed on the US TSCA Inventory. EPA Registration Number: Not Applicable SARA 313/302/304/311/312 Chemicals: None California: This product has been evaluated and does not require warning labeling under California Proposition 65. California Registration Number: Not Applicable State Right-to-Know and CERCLA: The following ingredients present in the fragrance of this finished product are listed on state right-to- know lists or state worker exposure lists: Ingredient CAS # Conc. in fragrance CERCLA RQ State IL MA NJ PA RI Benzyl acetate 140-11-4 5-10% x Diphenyl ether 101-84-8 1-5% x x x x Canada: All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations. SECTION XVI - OTHER INFORMATION Page 81 of 377 Page 81 of 377 Page 81 of 377 Page 81 of 377 ---PAGE BREAK--- Febreze Set & Refresh (Air Freshener) – Rain / Ginger Verbena Page 6 of 6 Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance. P&G Hazard Rating: Health: 1 4=EXTREME Flammability: 2 3=HIGH Reactivity: 1 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/A. - Not Applicable *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication regulations. This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the product. Page 82 of 377 Page 82 of 377 Page 82 of 377 Page 82 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 1 / 9 SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier GERMICIDAL CLEANER Revision date 03-23-2015 Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 04 Supersedes date 03-05-2015 Recommended use Cleaner Recommended restrictions None known. 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Flammable aerosols Serious eye damage/eye irritation Not classified. Not classified. Category 1 Category 2 Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear eye/face protection. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Not available. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 2-Butoxyethanol Butane EDTA Tertrasodium Salt 111-76-2 106-97-8 64-02-8 2.5 - 10 1 - 2.5 1 - 2.5 Other components below reportable levels 90 - 100 Page 83 of 377 Page 83 of 377 Page 83 of 377 Page 83 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 2 / 9 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if occur. Most important acute and delayed Indication of immediate medical attention and special treatment needed Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Provide general supportive measures and treat Keep victim under observation. may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Page 84 of 377 Page 84 of 377 Page 84 of 377 Page 84 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 3 / 9 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2-Butoxyethanol (CAS 111-76-2) US. ACGIH Threshold Limit Values PEL 240 mg/m3 50 ppm Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) TWA 20 ppm STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Biological limit values ACGIH Biological Exposure Indices TWA 24 mg/m3 5 ppm TWA 1900 mg/m3 800 ppm Components Value Determinant Specimen Sampling Time 2-Butoxyethanol (CAS 111-76-2) 200 mg/g Butoxyacetic acid (BAA), Creatinine in urine * with hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Page 85 of 377 Page 85 of 377 Page 85 of 377 Page 85 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 4 / 9 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Flammability limit - upper Not available. Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 55 - 75 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.979 estimated 10. Stability and reactivity Reactivity Reacts violently with strong acids. This product may react with oxidizing agents. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals. Contact with incompatible materials. Incompatible materials Acids. Oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Causes serious eye irritation. Page 86 of 377 Page 86 of 377 Page 86 of 377 Page 86 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 5 / 9 related to the physical, chemical and toxicological characteristics Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Information on toxicological effects Acute toxicity Harmful if inhaled. Harmful if swallowed. Components Species 2-Butoxyethanol (CAS 111-76-2) Acute Dermal LD50 Guinea pig Test Results 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Inhalation Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit 400 ppm, 7 Hours Oral Rat 450 ppm, 4 Hours LD100 Rabbit 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l EDTA Tertrasodium Salt (CAS 64-02-8) Acute Oral LD50 Rat 1658 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin burns. Serious eye damage/eye irritation Respiratory or skin sensitization Causes eye burns. Risk of serious damage to eyes. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Page 87 of 377 Page 87 of 377 Page 87 of 377 Page 87 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 6 / 9 Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components 2-Butoxyethanol (CAS 111-76-2) Aquatic Species Test Results Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours EDTA Tertrasodium Salt (CAS 64-02-8) Aquatic Algae Fish IC50 LC50 Algae Bluegill (Lepomis macrochirus) 1.01 mg/L, 72 Hours 472 - 500 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN1950 Aerosols 2.2 - 2.2 Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging exceptions Packaging non bulk Packaging bulk 306 None None Page 88 of 377 Page 88 of 377 Page 88 of 377 Page 88 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 7 / 9 This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code UN1950 Aerosols, non-flammable 2.2 - 2.2 Not applicable. Yes 2L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo aircraft Cargo aircraft only Packaging Exceptions IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant EmS Allowed. Allowed. LTD QTY UN1950 AEROSOLS 2.2 - 2.2 Not applicable. Yes Not available. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG LTD QTY Not applicable. Page 89 of 377 Page 89 of 377 Page 89 of 377 Page 89 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 8 / 9 Marine pollutant 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable quantity Threshold planning quantity Threshold planning quantity, lower value Threshold planning quantity, upper value Ammonia 7664-41-7 100 500 lbs Hydrogen Peroxide 7722-84-1 1000 1000 lbs SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Safe Drinking Water Act (SDWA) US state regulations Not regulated. US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Rhode Island RTK Butane (CAS 106-97-8) Page 90 of 377 Page 90 of 377 Page 90 of 377 Page 90 of 377 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 9 / 9 US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) No Yes No Yes No No Yes No No No Yes A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 07-28-2014 Revision date 03-23-2015 Version # 04 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision Information Product and Company Identification: Alternate Trade Names Page 91 of 377 Page 91 of 377 Page 91 of 377 Page 91 of 377 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier GLEME GLASS CLEANER Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 01 Recommended use cleaner Recommended restrictions None known. 2. Hazard(s) identification Liquefied gas Gases under pressure Physical hazards Not classified. Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 111-76-2 2-Butoxyethanol 2.5 - 10 64-17-5 Ethyl Alcohol 2.5 - 10 106-97-8 Butane 1 - 2.5 74-98-6 Propane Other components below reportable levels 90 - 100 1 - 2.5 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Get medical attention if persist. 1 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 92 of 377 Page 92 of 377 Page 92 of 377 Page 92 of 377 ---PAGE BREAK--- Skin contact Get medical attention if irritation develops and persists. Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Most important acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. See Section 8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Keep containers closed in a dry, cool and well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 2 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 93 of 377 Page 93 of 377 Page 93 of 377 Page 93 of 377 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 240 mg/m3 2-Butoxyethanol (CAS 111-76-2) 50 ppm PEL 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm PEL 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values Value Components Type TWA 20 ppm 2-Butoxyethanol (CAS 111-76-2) STEL 1000 ppm Butane (CAS 106-97-8) STEL 1000 ppm Ethyl Alcohol (CAS 64-17-5) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 24 mg/m3 2-Butoxyethanol (CAS 111-76-2) 5 ppm TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm TWA 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine * 2-Butoxyethanol (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection If contact is likely, safety glasses with side shields are recommended. Hand protection For prolonged or repeated skin contact use suitable protective gloves. Skin protection Other Wear suitable protective clothing. 3 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 94 of 377 Page 94 of 377 Page 94 of 377 Page 94 of 377 ---PAGE BREAK--- Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Clear. Physical state Gas. Form Aerosol. Liquefied gas. Color Light yellow. Odor Characteristic. Odor threshold Not available. pH 9.1 - 10.1 estimated Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 80 - 100 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Aerosol spray enclosed space Deflagration density > 2.52 g/cm3 Tested Aerosol spray ignition distance < 15 cm Tested estimated Specific gravity 0.977 - 0.997 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 4 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 95 of 377 Page 95 of 377 Page 95 of 377 Page 95 of 377 ---PAGE BREAK--- Incompatible materials Strong oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Test Results Components Species 2-Butoxyethanol (CAS 111-76-2) LD50 Guinea pig Dermal Acute 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit Inhalation 400 ppm, 7 Hours Rat 450 ppm, 4 Hours LD100 Rabbit Oral 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l Ethyl Alcohol (CAS 64-17-5) LC50 Cat Inhalation Acute 85.41 mg/l, 4.5 Hours 43.68 mg/l, 6 Hours Mouse > 60000 ppm 79.43 mg/l, 134 Minutes Rat > 115.9 mg/l, 4 Hours 5 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 96 of 377 Page 96 of 377 Page 96 of 377 Page 96 of 377 ---PAGE BREAK--- Test Results Components Species 51.3 mg/l, 6 Hours LD50 Monkey Oral 6000 mg/kg Mouse 10500 ml/kg Rat 1187 - 2769 mg/kg 7800 ml/kg Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation May be irritating to the skin. Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. May be irritating to eyes. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity Harmful to aquatic life. Product Test Results Species GLEME GLASS CLEANER (CAS Mixture) Aquatic EC50 Crustacea 13838.1602 mg/l, 48 hours estimated Daphnia Components Test Results Species 2-Butoxyethanol (CAS 111-76-2) Aquatic LC50 Fish 1250 mg/l, 96 hours Inland silverside (Menidia beryllina) 6 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 97 of 377 Page 97 of 377 Page 97 of 377 Page 97 of 377 ---PAGE BREAK--- Components Test Results Species Ethyl Alcohol (CAS 64-17-5) Aquatic EC50 Crustacea 7700 - 11200 mg/l, 48 hours Water flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50 Fish > 100.1 mg/l, 96 hours Fathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Ethyl Alcohol -0.31 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950 UN number Aerosols UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 306 Packaging exceptions None Packaging non bulk None Packaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950 UN number Aerosols, non-flammable UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group No. Environmental hazards 2L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 7 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 98 of 377 Page 98 of 377 Page 98 of 377 Page 98 of 377 ---PAGE BREAK--- Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only LTD QTY Packaging Exceptions IMDG UN1950 UN number AEROSOLS UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTY Packaging Exceptions Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. 8 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 99 of 377 Page 99 of 377 Page 99 of 377 Page 99 of 377 ---PAGE BREAK--- Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) 9 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 100 of 377 Page 100 of 377 Page 100 of 377 Page 100 of 377 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 05-26-2015 Version # 01 References EPA: AQUIRE database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 10 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 101 of 377 Page 101 of 377 Page 101 of 377 Page 101 of 377 ---PAGE BREAK--- Page 102 of 377 Page 102 of 377 Page 102 of 377 Page 102 of 377 ---PAGE BREAK--- Page 103 of 377 Page 103 of 377 Page 103 of 377 Page 103 of 377 ---PAGE BREAK--- Page 104 of 377 Page 104 of 377 Page 104 of 377 Page 104 of 377 ---PAGE BREAK--- Page 105 of 377 Page 105 of 377 Page 105 of 377 Page 105 of 377 ---PAGE BREAK--- Page 106 of 377 Page 106 of 377 Page 106 of 377 Page 106 of 377 ---PAGE BREAK--- Page 107 of 377 Page 107 of 377 Page 107 of 377 Page 107 of 377 ---PAGE BREAK--- ® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 19 SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Print Date: 06/19/2015 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. IDENTIFICATION Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Recommended use of the chemical and restrictions on use Identified uses: Polyurethane foam. COMPANY IDENTIFICATION THE DOW CHEMICAL COMPANY 2030 WILLARD H DOW CENTER MIDLAND MI 48674-0000 UNITED STATES Customer Information Number: [PHONE REDACTED] [EMAIL REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Hazard classification This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Flammable aerosols - Category 2 Acute toxicity - Category 4 - Inhalation Skin irritation - Category 2 Eye irritation - Category 2B Respiratory sensitisation - Category 1 Skin sensitisation - Category 1 Carcinogenicity - Category 2 Effects on or via lactation Specific target organ toxicity - single exposure - Category 3 Specific target organ toxicity - repeated exposure - Category 2 - Inhalation Page 108 of 377 Page 108 of 377 Page 108 of 377 Page 108 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 2 of 19 Label elements Hazard pictograms Signal word: DANGER! Hazards Flammable aerosol. Causes skin and eye irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing cancer. May cause harm to breast-fed children. May cause damage to organs (Respiratory system) through prolonged or repeated exposure if inhaled. Precautionary statements Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Avoid contact during pregnancy/ while nursing. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. Response IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Page 109 of 377 Page 109 of 377 Page 109 of 377 Page 109 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 3 of 19 Storage Store in a well-ventilated place. Keep container closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 122 Disposal Dispose of contents/ container to an approved waste disposal plant. Other hazards no data available 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: Diphenylmethane Diisocyanate, isomers and homologues This product is a substance. Component CASRN Concentration Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 10.0 - 30.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 10.0 - 30.0 % Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer 57029-46-6 10.0 - 30.0 % Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer 53862-89-8 10.0 - 30.0 % Tris(1-chloro-2-propyl) phosphate 13674-84-5 5.0 - 10.0 % Paraffin waxes and Hydrocarbon waxes, chlorinated 63449-39-8 5.0 - 10.0 % Isobutane 75-28-5 7.0 - 13.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % Note Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. 4. FIRST AID MEASURES Description of first aid measures Page 110 of 377 Page 110 of 377 Page 110 of 377 Page 110 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 4 of 19 General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be available in work area. Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Most important and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Maintain adequate ventilation and oxygenation of the patient. May cause respiratory sensitization or asthma-like Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Treatment of exposure should be directed at the control of and the clinical condition of the patient. Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. bronchitis, reactive airways dysfunction 5. FIREFIGHTING MEASURES Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Unsuitable extinguishing media: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Special hazards arising from the substance or mixture Page 111 of 377 Page 111 of 377 Page 111 of 377 Page 111 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 5 of 19 Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. Hydrogen cyanide. Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire- exposed containers and fire-affected zone until fire is out. Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Confined space entry procedures must be followed before entering the area. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. See Section 10 for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Contain spilled material if possible. Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use non-sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Collect in suitable and properly labeled containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See Section 10 for more specific information. See Section 13, Disposal Considerations, for additional information. Page 112 of 377 Page 112 of 377 Page 112 of 377 Page 112 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 6 of 19 7. HANDLING AND STORAGE Precautions for safe handling: Keep away from heat, sparks and flame. No smoking, open flames or sources of ignition in handling and storage area. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Storage stability Storage temperature: Shelf life: Use within 49 °C (120 12 Month 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure limits are listed below, if they exist. Component Regulation Type of listing Value/Notation 4,4' -Methylenediphenyl diisocyanate ACGIH TWA 0.005 ppm OSHA Z-1 C 0.2 mg/m3 0.02 ppm Isobutane ACGIH STEL 1,000 ppm Methyl ether US WEEL TWA 1,000 ppm Propane ACGIH OSHA Z-1 TWA 1,800 mg/m3 1,000 ppm This material contains a simple which may displace oxygen. Insure adequate ventilation to prevent an oxygen deficient atmosphere., The minimum requirement of 19.5% oxygen at sea level (148 torr O2, dry air) provides an adequate amount of oxygen for most work assignments. Exposure controls Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilationto control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. Lethal concentrations may exist in areas with poor ventilation. Individual protection measures Eye/face protection: Use safety glasses (with side shields). Skin protection Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove Page 113 of 377 Page 113 of 377 Page 113 of 377 Page 113 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 7 of 19 barrier materials include: Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Respiratory protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air- purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive-pressure self-contained breathing apparatus or positive- pressure air line with auxiliary self-contained air supply. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Foam Color Yellow Odor Mild Odor Threshold No test data available pH Not applicable Melting point/range No test data available Freezing point No test data available Boiling point (760 mmHg) Not applicable Flash point closed cup -104 °C ( -155 Closed Cup Evaporation Rate (Butyl Acetate = 1) No test data available Flammability (solid, gas) Flammable gas. Lower explosion limit No test data available Upper explosion limit No test data available Vapor Pressure 1,151 hPa at 55 °C (131 Not reported Container is under pressure. Relative Vapor Density (air = 1) No test data available Relative Density (water = 1) 1.06 Estimated. Water solubility Insoluble Page 114 of 377 Page 114 of 377 Page 114 of 377 Page 114 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 8 of 19 Partition coefficient: n- octanol/water no data available Auto-ignition temperature No test data available Decomposition temperature No test data available Kinematic Viscosity Not applicable Explosive properties Not explosive Oxidizing properties No Molecular weight No test data available NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: no data available Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Possibility of hazardous reactions: Can occur. Exposure to elevated temperatures can cause product to decompose and generate gas. This can cause pressure build-up and/or rupturing of closed containers. Acids. Conditions to avoid: Avoid temperatures above 50 °C Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose. Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. TOXICOLOGICAL INFORMATION Toxicological information on this product or its components appear in this section when such data is available. Acute toxicity Acute oral toxicity Page 115 of 377 Page 115 of 377 Page 115 of 377 Page 115 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 9 of 19 Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. As product: Single dose oral LD50 has not been determined. LD50, Rat, > 2,000 mg/kg Estimated. Acute dermal toxicity Prolonged skin contact is unlikely to result in absorption of harmful amounts. As product: The dermal LD50 has not been determined. LD50, Rabbit, > 2,000 mg/kg Estimated. Acute inhalation toxicity In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. As product: The LC50 has not been determined. Skin corrosion/irritation Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Serious eye damage/eye irritation May cause moderate eye irritation. May cause slight temporary corneal injury. Sensitization Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. May cause allergic respiratory reaction. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Specific Target Organ Systemic Toxicity (Single Exposure) May cause respiratory irritation. Route of Exposure: Inhalation Specific Target Organ Systemic Toxicity (Repeated Exposure) Page 116 of 377 Page 116 of 377 Page 116 of 377 Page 116 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 10 of 19 Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Carcinogenicity Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Teratogenicity In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Reproductive toxicity Based on information for component(s): May cause harm to breastfed babies. Mutagenicity In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard. COMPONENTS INFLUENCING TOXICOLOGY: Diphenylmethane Diisocyanate, isomers and homologues Acute inhalation toxicity LC50, Rat, 4 Hour, dust/mist, 0.49 mg/l For similar material(s): 2,4'-Diphenylmethane diisocyanate (CAS 5873-54-1). LC50, Rat, 4 Hour, Aerosol, 0.31 mg/l For similar material(s): 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8). LC50, Rat, 1 Hour, Aerosol, 2.24 mg/l 4,4' -Methylenediphenyl diisocyanate Acute inhalation toxicity LC50, Rat, 1 Hour, dust/mist, 2.24 mg/l Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer Acute inhalation toxicity The LC50 has not been determined. Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer Acute inhalation toxicity The LC50 has not been determined. Tris(1-chloro-2-propyl) phosphate Acute inhalation toxicity LC50, Rat, 4 Hour, dust/mist, > 7 mg/l Paraffin waxes and Hydrocarbon waxes, chlorinated Page 117 of 377 Page 117 of 377 Page 117 of 377 Page 117 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 11 of 19 Acute inhalation toxicity As product: The LC50 has not been determined. Isobutane Acute inhalation toxicity LC50, Mouse, 1 Hour, 52 mg/l Methyl ether Acute inhalation toxicity LC50, Rat, 4 Hour, gas, 164000 ppm Propane Acute inhalation toxicity LC50, Rat, male and female, 4 Hour, vapour, > 425000 ppm 12. ECOLOGICAL INFORMATION Ecotoxicological information on this product or its components appear in this section when such data is available. Toxicity Diphenylmethane Diisocyanate, isomers and homologues Acute toxicity to fish The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Based on information for a similar material: LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg/l, OECD Test Guideline 201 or Equivalent Toxicity to bacteria Based on information for a similar material: EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l Toxicity to soil-dwelling organisms EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000 mg/kg Toxicity to terrestrial plants Page 118 of 377 Page 118 of 377 Page 118 of 377 Page 118 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 12 of 19 EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l 4,4' -Methylenediphenyl diisocyanate Acute toxicity to fish The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Based on information for a similar material: LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg/l, OECD Test Guideline 201 or Equivalent Toxicity to bacteria Based on information for a similar material: EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l Toxicity to soil-dwelling organisms EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000 mg/kg Toxicity to terrestrial plants EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer Acute toxicity to fish For this family of materials: Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer Acute toxicity to fish Not expected to be acutely toxic to aquatic organisms. Tris(1-chloro-2-propyl) phosphate Acute toxicity to fish Material is toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). LC50, Lepomis macrochirus (Bluegill sunfish), static test, 96 Hour, 84 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates Page 119 of 377 Page 119 of 377 Page 119 of 377 Page 119 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 13 of 19 EC50, Daphnia magna (Water flea), 48 Hour, 131 mg/l Acute toxicity to algae/aquatic plants ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate inhibition, 82 mg/l, OECD Test Guideline 201 or Equivalent Toxicity to bacteria EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of 32 mg/l LOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of > 32 mg/l Paraffin waxes and Hydrocarbon waxes, chlorinated Acute toxicity to fish Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1 mg/L in the most sensitive species tested). LC50, mykiss (rainbow trout), 96 Hour, > 0.1 mg/l Isobutane Acute toxicity to fish No relevant data found. Methyl ether Acute toxicity to fish Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). LC50, Poecilia reticulata (guppy), semi-static test, 96 Hour, > 4,000 mg/l Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, > 4,000 mg/l, OECD Test Guideline 202 or Equivalent Propane Acute toxicity to fish No relevant data found. Persistence and degradability Diphenylmethane Diisocyanate, isomers and homologues Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. 10-day Window: Not applicable Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 302C or Equivalent 4,4' -Methylenediphenyl diisocyanate Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric Page 120 of 377 Page 120 of 377 Page 120 of 377 Page 120 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 14 of 19 environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. 10-day Window: Not applicable Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 302C or Equivalent Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer Biodegradability: For this family of materials: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer Biodegradability: Expected to degrade slowly in the environment. Tris(1-chloro-2-propyl) phosphate Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 14 % Exposure time: 28 d Method: OECD Test Guideline 301E or Equivalent 10-day Window: Not applicable Biodegradation: 95 % Exposure time: 64 d Method: OECD Test Guideline 302A or Equivalent Theoretical Oxygen Demand: 1.17 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 0.24 d Method: Estimated. Paraffin waxes and Hydrocarbon waxes, chlorinated Biodegradability: Expected to degrade slowly in the environment. Theoretical Oxygen Demand: 2.89 mg/mg Isobutane Biodegradability: Biodegradation may occur under aerobic conditions (in the presence of oxygen). Theoretical Oxygen Demand: 3.58 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 4.4 d Method: Estimated. Methyl ether Page 121 of 377 Page 121 of 377 Page 121 of 377 Page 121 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 15 of 19 Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301A or Equivalent Theoretical Oxygen Demand: 2.08 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 6.4 d Method: Estimated. Propane Biodegradability: No relevant data found. Theoretical Oxygen Demand: 3.64 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 8.4 d Method: Estimated. Bioaccumulative potential Diphenylmethane Diisocyanate, isomers and homologues Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d 4,4' -Methylenediphenyl diisocyanate Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer Bioaccumulation: No relevant data found. Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer Bioaccumulation: In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Tris(1-chloro-2-propyl) phosphate Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient: n-octanol/water(log Pow): 2.59 Measured Bioconcentration factor (BCF): 0.8 - 4.6 Cyprinus carpio (Carp) 42 d Measured Paraffin waxes and Hydrocarbon waxes, chlorinated Page 122 of 377 Page 122 of 377 Page 122 of 377 Page 122 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 16 of 19 Bioaccumulation: Bioconcentration potential is low (BCF less than 100 or log Pow greater than Partition coefficient: n-octanol/water(log Pow): 7.4 Estimated. Isobutane Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient: n-octanol/water(log Pow): 2.76 Measured Methyl ether Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient: n-octanol/water(log Pow): 0.10 Measured Propane Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient: n-octanol/water(log Pow): 2.36 Measured Mobility in soil Diphenylmethane Diisocyanate, isomers and homologues In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. 4,4' -Methylenediphenyl diisocyanate In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer No relevant data found. Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Tris(1-chloro-2-propyl) phosphate Potential for mobility in soil is slight (Koc between 2000 and 5000). Partition coefficient(Koc): 1300 Estimated. Paraffin waxes and Hydrocarbon waxes, chlorinated Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Partition coefficient(Koc): > 5000 Estimated. Isobutane Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 35 Estimated. Methyl ether Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 1.29 - 14 Estimated. Propane Potential for mobility in soil is very high (Koc between 0 and 50). Page 123 of 377 Page 123 of 377 Page 123 of 377 Page 123 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 17 of 19 Partition coefficient(Koc): 24 - 460 Estimated. 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device. 14. TRANSPORT INFORMATION DOT Proper shipping name Aerosols UN number UN 1950 Class 2.1 Packing group Reportable Quantity MDI Classification for SEA transport (IMO-IMDG): Proper shipping name AEROSOLS UN number UN 1950 Class 2.1 Packing group Marine pollutant Paraffin waxes and Hydrocarbon waxes, chlorinated Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code Consult IMO regulations before transporting ocean bulk Classification for AIR transport (IATA/ICAO): Proper shipping name Aerosols, flammable UN number UN 1950 Class 2.1 Packing group This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service Page 124 of 377 Page 124 of 377 Page 124 of 377 Page 124 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 18 of 19 representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. REGULATORY INFORMATION OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Acute Health Hazard Chronic Health Hazard Fire Hazard Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Components CASRN Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 4,4' -Methylenediphenyl diisocyanate 101-68-8 Worker and Community Right-To-Know Act: The following chemicals are listed because of the additional requirements of law: Components CASRN Isobutane 75-28-5 Methyl ether 115-10-6 Propane 74-98-6 California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances knownto the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. United States TSCA Inventory (TSCA) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. : 16. OTHER INFORMATION Page 125 of 377 Page 125 of 377 Page 125 of 377 Page 125 of 377 ---PAGE BREAK--- Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC EF QP Issue Date: 04/13/2015 Page 19 of 19 Revision Identification Number: 101265380 / A001 / Issue Date: 04/13/2015 / Version: 5.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend ACGIH USA. ACGIH Threshold Limit Values (TLV) C Ceiling OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants STEL Short-term exposure limit TWA 8-hour, time-weighted average US WEEL USA. Workplace Environmental Exposure Levels (WEEL) Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company. THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer- specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 126 of 377 Page 126 of 377 Page 126 of 377 Page 126 of 377 ---PAGE BREAK--- N950 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 4/6/2012 MSDS No. N950 Supersedes Date: 10/4/2011 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: GREEN KLEEN MULTI-PURPOSE CLEANER DEGREASER Formula: Mixture of propylene glycol ethers and detergents in water. Chemical Type: Organic compounds in water HMIS RATINGS Health = 0 (Minimal) Flammability = 0 (Minimal) Reactivity = 0 (Minimal) Protection = B (Safety goggles & gloves) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Dipropylene glycol methyl ether CAS # 34590-94-8 1-5% TWA – 100 ppm STEL – 150 ppm No SECTION III - CHEMICAL AND PHYSICAL Appearance: Clear Green Liquid Boiling Point: 212OF Odor: Sassafras Melting Point: N/A pH: 10.0-11.5 Spec. Gravity (H20 = 1.01 Water Solubility: Complete Vapor Pressure (Mm Hg): N/A Viscosity @ 25°C.: < 25 cps (Brookfield) VOC Content: 3.5% SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): > 200oF. (TCC) Explosion Limits: Upper: N/A Lower: N/A Extinguishing Media: Water fog, CO2, halon system, foam Special Firefighting Procedures and Hazards: Minimize prolonged skin and eye contact. Wear eye protection if exposure to liquid is likely. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: None known Hazardous Decomposition Products: If in a fire: CO, CO2, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur: Page 127 of 377 Page 127 of 377 Page 127 of 377 Page 127 of 377 ---PAGE BREAK--- N950 Page 2 of 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of mists may cause irritation. Wear an approved mist respirator if exposure is likely. Remove to fresh air. Give artificial respiration or oxygen if needed. Skin: Extended contact may cause irritation and defatting. Wear protective gloves if needed. Wash skin with soap and plenty of water. Remove contaminated clothing and wash before wearing again. Eye: May cause irritation from misting. Wear splash proof goggles as needed. Flush with water for 15 minutes. If irritation persists consult a doctor. Ingestion: May cause mild gastric disturbances, nausea. Avoid swallowing. Drink lots of water or, preferably, milk. Do not induce vomiting. Get medical attention if effects persist. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Do not drain to sewer without dilution. Larger spills should be contained by diking or other methods and held for disposal or reuse. Storage and Handling: Check daily for any leaks from containers, vessels, pumps, and piping. Waste Disposal: May be disposable in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility. Rinse well before handling and disposal. Observe label precautions. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Other Precautions: N/A SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form None The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 128 of 377 Page 128 of 377 Page 128 of 377 Page 128 of 377 ---PAGE BREAK--- Revision Date: 04-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: GS RESTROOM CLEANER Product Number: 3503 , 3533 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Serious Eye Damage/Eye Irritation: Category 2A GHS Label Elements Signal Word: Warning Hazard Statements: Causes serious eye irritation Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Wear eye / face protection Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. Page 1 / 5 0.30298% of the mixture consists of ingredient(s) of unknown toxicity. Symbols: Page 129 of 377 Page 129 of 377 Page 129 of 377 Page 129 of 377 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 citric acid 77-92-9 5-10 alcohol ethoxylate 68439-46-3 1-5 xanthan gum 11138-66-2 0.1-1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Engineering Controls: Page 2 / 5 Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Page 130 of 377 Page 130 of 377 Page 130 of 377 Page 130 of 377 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Heat, flames and sparks. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 29382 mg/kg Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Clear Odor: Bland pH: 1.5-2.5 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.03 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 131 of 377 Page 131 of 377 Page 131 of 377 Page 131 of 377 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available citric acid 77-92-9 = 3000 mg/kg ( Rat ) Not Available Not Available alcohol ethoxylate 68439-46-3 = 1378 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea citric acid 77-92-9 Not Available 1516: 96 h Lepomis macrochirus mg/L LC50 static Not Available 120: 72 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 acetaldehyde - 75-07-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. Page 4 / 5 EPA Pesticide Registration Number: 5741-25 Page 132 of 377 Page 132 of 377 Page 132 of 377 Page 132 of 377 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Caution. Causes moderate eye irritation. May be harmful if swallowed. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. 16. OTHER INFORMATION Revision Date: 04-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 0 Physical Hazards: 0 Page 133 of 377 Page 133 of 377 Page 133 of 377 Page 133 of 377 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Health Gards Metered Aerosols -07932 Fresh Garden CAS Number: Manufacturer: HOSPECO SDS Date: 5/20/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=cx6ix0w2RLU%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 134 of 377 Page 134 of 377 Page 134 of 377 Page 134 of 377 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Insect Repellent Product identifier Other means of identification 14011 Product code EPA: 51147-13-55809 Registration number Insect repellent Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information [PHONE REDACTED] Technical Assistance [PHONE REDACTED] Customer Service [PHONE REDACTED] 24-Hour Emergency [PHONE REDACTED] (US) (CHEMTREC) [PHONE REDACTED] (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Liquefied gas Gases under pressure Category 4 Acute toxicity, oral Health hazards Category 4 Acute toxicity, dermal Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Sensitization, skin Category 3 narcotic effects Specific target organ toxicity, single exposure Category 2 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. 1 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 135 of 377 Page 135 of 377 Page 135 of 377 Page 135 of 377 ---PAGE BREAK--- Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing. Wear eye/face protection. Avoid release to the environment. Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information 32.11% of the mixture consists of component(s) of unknown acute oral toxicity. 32.11% of the mixture consists of component(s) of unknown acute dermal toxicity. 72.39% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures CAS number % Common name and synonyms Chemical name 67-63-0 Isopropyl alcohol 30 - 40 134-62-3 N,N-Diethyl-m-toluamide (DEET) 25.1 68476-86-8 Liquefied Petroleum Gas 20 - 30 113-48-4 Dicarboximide 5 - 10 136-45-8 Dipropyl isocinchomeronate 2.5 67-64-1 Acetone 1 - 3 57-55-6 Propylene glycol 1 - 3 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Most important acute and delayed Provide general supportive measures and treat Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. General information 2 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 136 of 377 Page 136 of 377 Page 136 of 377 Page 136 of 377 ---PAGE BREAK--- 5. Fire-fighting measures Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will spread on the water surface. Stop the flow of material, if this is without risk. Prevent product from entering drains. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. Environmental precautions 7. Handling and storage Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Wash contaminated clothing before reuse. For product usage instructions, please see the product label. Precautions for safe handling Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 3 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 137 of 377 Page 137 of 377 Page 137 of 377 Page 137 of 377 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 2400 mg/m3 Acetone (CAS 67-64-1) 1000 ppm PEL 980 mg/m3 Isopropyl alcohol (CAS 67-63-0) 400 ppm US. ACGIH Threshold Limit Values Value Components Type STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm STEL 400 ppm Isopropyl alcohol (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm STEL 1225 mg/m3 Isopropyl alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Value Components Form Type TWA 10 mg/m3 Aerosol. Propylene glycol (CAS 57-55-6) Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) 40 mg/l Acetone Urine * Isopropyl alcohol (CAS 67-63-0) * - For sampling details, please see the source document. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Viton®. Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. General hygiene considerations 4 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 138 of 377 Page 138 of 377 Page 138 of 377 Page 138 of 377 ---PAGE BREAK--- 9. Physical and chemical properties Appearance Liquid. Physical state Aerosol. Form Clear. Colorless. Color Mild. Alcoholic. Odor Odor threshold Not available. pH Not available. Melting point/freezing point -138.5 °F (-94.7 estimated Initial boiling point and boiling range 132.9 °F (56.1 estimated Flash point 75 °F (23.9 Tag Closed Cup Evaporation rate Moderate. Not available. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 2 % estimated Flammability limit - upper 12.8 % estimated Vapor pressure 1234.3 hPa estimated Vapor density > 1 (air = 1) Relative density 0.8 estimated Solubility (water) Immiscible. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 700 °F (371.1 estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 67.3 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Heat, flames and sparks. Contact with incompatible materials. Conditions to avoid Acids. Strong oxidizing agents. Isocyanates. Chlorine. Incompatible materials Carbon oxides. Nitrogen oxides (NOx). Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Skin contact Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion Harmful if swallowed. related to the physical, chemical and toxicological characteristics Headache. May cause drowsiness and dizziness. Nausea, vomiting. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Harmful in contact with skin. Harmful if swallowed. Narcotic effects. May cause an allergic skin reaction. 5 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 139 of 377 Page 139 of 377 Page 139 of 377 Page 139 of 377 ---PAGE BREAK--- Test Results Product Species Insect Repellent Dermal Acute LD50 Rabbit 1380 mg/kg estimated Inhalation LC50 Rat 40990 ppm, 4 hours estimated 12 mg/l, 4 Hours estimated Oral LD50 Rat 1737 mg/kg estimated * Estimates for product may be based on additional component data not shown. TDL0 Human 117 g/kg estimated Causes skin irritation. Skin corrosion/irritation Causes serious eye irritation. Serious eye damage/eye irritation Respiratory sensitization Not a respiratory sensitizer. May cause an allergic skin reaction. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. 12. Ecological information Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Ecotoxicity Product Test Results Species Insect Repellent Aquatic Acute EC50 Crustacea 171.4605 ppm, 48 hours estimated Daphnia LC50 Fish 218.1529 ppm, 96 hours estimated Fish Components Test Results Species Acetone (CAS 67-64-1) Aquatic EC50 Crustacea 10294 - 17704 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 4740 - 6330 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) Isopropyl alcohol (CAS 67-63-0) Aquatic Acute EC50 Crustacea 7550 - 13299 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 3200 mg/l, 96 hours Fathead minnow (Pimephales promelas) N,N-Diethyl-m-toluamide (DEET) (CAS 134-62-3) Aquatic LC50 Fish 106 - 114 mg/l, 96 hours Fathead minnow (Pimephales promelas) 6 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 140 of 377 Page 140 of 377 Page 140 of 377 Page 140 of 377 ---PAGE BREAK--- Components Test Results Species Propylene glycol (CAS 57-55-6) Aquatic LC50 Fish 710 mg/l, 96 hours Fathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Acute EC50 Crustacea 4850 - 34000 mg/l, 48 hours Water flea (Daphnia magna) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Isopropyl alcohol 0.05 N,N-Diethyl-m-toluamide (DEET) 2.02 Propylene glycol -0.92 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Disposal of waste from residues / unused products D001: Waste Flammable material with a flash point <140 F Hazardous waste code Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk IATA UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only 7 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 141 of 377 Page 141 of 377 Page 141 of 377 Page 141 of 377 ---PAGE BREAK--- IMDG UN1950 UN number AEROSOLS, LIMITED QUANTITY UN proper shipping name 2 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Dipropyl isocinchomeronate (CAS 136-45-8) CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. CERCLA Hazardous Substances: Reportable quantity Acetone (CAS 67-64-1) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Not regulated. Food and Drug Administration (FDA) US EPA Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Information Warning. Signal word Harmful if swallowed. Causes substantial but temporary eye injury. This product is registered in all 50 United States and Puerto Rico. This product is not registered outside of the United States and Puerto Rico. Hazard statement 8 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 142 of 377 Page 142 of 377 Page 142 of 377 Page 142 of 377 ---PAGE BREAK--- Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Section 311/312 Hazard categories No SARA 302 Extremely hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Acetone (CAS 67-64-1) Dipropyl isocinchomeronate (CAS 136-45-8) Isopropyl alcohol (CAS 67-63-0) Liquefied Petroleum Gas (CAS 68476-86-8) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Propylene glycol (CAS 57-55-6) Dipropyl isocinchomeronate (CAS 136-45-8) Isopropyl alcohol (CAS 67-63-0) US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Isopropyl alcohol (CAS 67-63-0) US. Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Isopropyl alcohol (CAS 67-63-0) Propylene glycol (CAS 57-55-6) US. Rhode Island RTK Acetone (CAS 67-64-1) Dipropyl isocinchomeronate (CAS 136-45-8) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Cumene (CAS 98-82-8) Listed: April 6, 2010 Dipropyl isocinchomeronate (CAS 136-45-8) Listed: May 1, 1996 Ethanal (CAS 75-07-0) Listed: April 1, 1988 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 64.9 % Not regulated Consumer products (40 CFR 59, Subpt. C) State This product is regulated as an Insect Repellent. This product is compliant for use in all 50 states. Consumer products VOC content (CA) 64.9 % VOC content (OTC) 64.9 % 9 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 143 of 377 Page 143 of 377 Page 143 of 377 Page 143 of 377 ---PAGE BREAK--- International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 05-21-2015 Issue date Allison Cho Prepared by Version # 01 CRC # 926 Further information Health: 1 Flammability: 3 Physical hazard: 0 Personal protection: B HMIS® ratings Health: 1 Flammability: 3 Instability: 0 NFPA ratings NFPA ratings 0 1 3 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. Disclaimer 10 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 144 of 377 Page 144 of 377 Page 144 of 377 Page 144 of 377 ---PAGE BREAK--- GHS Pictograms: SAFETY DATA SHEET SECTION 1 : IDENTIFICATION Product Name: KILZ® Color Change Ceiling Paint Product Code: 6800 SDS Manufacturer Number: 6800 Manufacturer Name: Masterchem Industries LLC Address: 3135 Old Highway M Imperial, MO 63052-2834 General Phone Number: (636) 942-2510 General Fax Number: (636) 942-3663 Customer Service Phone Number: (800) 325-3552 CHEMTREC: For emergencies in the US, call CHEMTREC: [PHONE REDACTED] Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect) SDS Creation Date: January 30, 2007 SDS Revision Date: April 30, 2015 (M)SDS Format: SECTION 2 : HAZARD(S) IDENTIFICATION Signal Word: Warning. GHS Class: Eye Irritant, Category 2. Skin Irritant, Category 2. Hazard Statements: Causes eye and skin irritation. Precautionary Statements: Wear protective clothing, gloves, eye, and face protection. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Take off contaminated clothing and wash it before reuse. Dispose of unused contents, container, and other contaminated wastes in accordance with local, state, federal, and provincial regulations. If in eyes: Rinse cautiously with water for several minutes and remove contacts if present and easy to do. Continue rinsing and get medical attention if eye irritation persists. If on skin: Wash with plenty of soap and water. If swallowed: Rinse mouth and get medical attention if you feel unwell. Emergency Overview: Irritant. Route of Exposure: Eyes. Skin. Inhalation. Ingestion. Potential Health Effects: Eye: Causes eye irritation. Skin: Causes skin irritation. Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation. Ingestion: May be harmful if swallowed. May cause vomiting. Chronic Health Effects: Prolonged or repeated contact may cause skin irritation. Overexposure may cause headaches and dizziness. Target Organs: Eyes. Skin. Respiratory system. Digestive system. Aggravation of Pre-Existing Conditions: None generally recognized. SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# Ingredient Percent EC Num. Titanium dioxide 13463-67-7 10 - 30 by weight Amorphous Silica 112926-00-8 1 - 5 by weight Ethylene glycol 107-21-1 1 - 5 by weight Flux Calcined Diatomaceous Earth (DE) 68855-54-9 1 - 5 by weight Limestone 1317-65-3 5 - 10 by weight Product: KILZ® Color Change Ceiling Paint I Manufacturer: Masterchem Industries LLC I Revison:4/30/2015, Version:0 Page 1 of 5 Page 145 of 377 Page 145 of 377 Page 145 of 377 Page 145 of 377 ---PAGE BREAK--- Nepheline Syenite 37244-96-5 5 - 10 by weight Silica, - cristobalite 14464-46-1 1 - 5 by weight SECTION 4 : FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Remove contacts if present and easy to do. Continue rinsing. Get medical attention, if irritation or of overexposure persists. Skin Contact: Immediately wash skin with soap and plenty of water. Get medical attention if irritation develops or persists. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. SECTION 5 : FIRE FIGHTING MEASURES Flash Point: None. Lower Flammable/Explosive Limit: Not applicable. Upper Flammable/Explosive Limit: Not applicable. Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry chemical, or water fog or spray when fighting fires involving this material. Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Ratings: NFPA Health: 1 NFPA Flammability: 1 NFPA Reactivity: 0 SECTION 6 : ACCIDENTAL RELEASE MEASURES Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Use proper personal protective equipment as listed in section 8. Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways. Methods for containment: Contain spills with an inert absorbent material such as soil or sand. Prevent from spreading by covering, diking or other means. Provide ventilation. Methods for cleanup: Clean up spills immediately observing precautions in the protective equipment section. Place into a suitable container for disposal. Provide ventilation. After removal, flush spill area with soap and water to remove trace residue. SECTION 7 : HANDLING and STORAGE Handling: Use with adequate ventilation. Avoid breathing vapor and contact with eyes, skin and clothing. Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, and incompatible substances. Keep container closed when not in use. Hygiene Practices: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhaling vapor or mist. SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166. Skin Protection Description: Chemical-resistant gloves and chemical goggles, face-shield and apron or coveralls should be used to prevent contact with eyes, skin or clothing. Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Product: KILZ® Color Change Ceiling Paint I Manufacturer: Masterchem Industries LLC I Revison:4/30/2015, Version:0 Page 2 of 5 Page 146 of 377 Page 146 of 377 Page 146 of 377 Page 146 of 377 ---PAGE BREAK--- PPE Pictograms: EXPOSURE GUIDELINES Titanium dioxide : Guideline ACGIH: TLV-TWA: 10 mg/m3 Amorphous Silica : Guideline OSHA: PEL-TWA: 20 Ethylene glycol : Guideline ACGIH: TLV-STEL: C 100 mg/m3 SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES Physical State: Liquid. Color: White Odor: Slight. Odor Threshold: Not applicable. Boiling Point: >99°F (>37°C) Melting Point: Not applicable. Density: 11.25 Solubility: Not applicable. Vapor Density: Not applicable. Vapor Pressure: Not applicable. Evaporation Rate: Not applicable. pH: 7 - 10 Viscosity: 50-140 Coefficient of Water/Oil Distribution: Not applicable. Flammability: Not applicable. Flash Point: None. VOC Content: Material VOC: 49 gm/L(Includes Water) Coating VOC.:22 gm/L(Excludes Water) SECTION 10 : STABILITY and REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Hazardous Polymerization: Not reported. Conditions to Avoid: Heat, flames, incompatible materials, and freezing or temperatures below 32 deg. F. Incompatible Materials: Oxidizing agents. Strong acids and alkalis. SECTION 11 : TOXICOLOGICAL INFORMATION Ethylene glycol : Eye: Administration into the eye - Rat Standard Draize test: 0.012 %/3D [Not reported.] Administration into the eye - Rabbit Standard Draize test: 500 mg/24H [Mild] Administration into the eye - Rabbit Standard Draize test: 100 mg/1H [Mild] Administration into the eye - Rabbit Standard Draize test: 0.012 ppm/3D [Not reported.] Administration into the eye - Rabbit Standard Draize test: 1440 mg/6H [Moderate] (RTECS) Skin: Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill: 9530 uL/kg [Details of toxic effects not reported other than lethal dose value] (RTECS) Ingestion: Oral - Rat LD50 - Lethal dose, 50 percent kill: 4700 mg/kg [Details of toxic effects not reported other than lethal dose value] (RTECS) SECTION 12 : ECOLOGICAL INFORMATION Ecotoxicity: No ecotoxicity data was found for the product. Environmental Fate: No environmental information found for this product. SECTION 13 : DISPOSAL CONSIDERATIONS Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, Product: KILZ® Color Change Ceiling Paint I Manufacturer: Masterchem Industries LLC I Revison:4/30/2015, Version:0 Page 3 of 5 Page 147 of 377 Page 147 of 377 Page 147 of 377 Page 147 of 377 ---PAGE BREAK--- if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. SECTION 14 : TRANSPORT INFORMATION DOT Shipping Name: Not restricted as a dangerous good. DOT UN Number: Not restricted as a dangerous good. IATA Shipping Name: Not restricted as a dangerous good. IATA UN Number: Not restricted as a dangerous good. Canadian Shipping Name: Not restricted as a dangerous good. Canadian UN Number: Not restricted as a dangerous good. IMDG UN NUmber : Not restricted as a dangerous good. IMDG Shipping Name : Not restricted as a dangerous good. ADR UN Number: Not restricted as a dangerous good. ADR Shipping Name : Not restricted as a dangerous good. SECTION 15 : REGULATORY INFORMATION Titanium dioxide : TSCA Inventory Status: Listed Canada DSL: Listed Amorphous Silica : Canada DSL: Listed Ethylene glycol : TSCA Inventory Status: Listed Section 313: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical. Canada DSL: Listed Flux Calcined Diatomaceous Earth (DE) : TSCA Inventory Status: Listed Canada DSL: Listed Limestone : TSCA Inventory Status: Listed Nepheline Syenite : Canada DSL: Listed Silica, - cristobalite : TSCA Inventory Status: Listed Canada DSL: Listed SECTION 16 : ADDITIONAL INFORMATION HMIS Ratings: HMIS Health Hazard: 1 HMIS Fire Hazard: 1 HMIS Reactivity: 0 HMIS Other: x SDS Creation Date: January 30, 2007 SDS Revision Date: April 30, 2015 MSDS Revision Notes: Quarterly formula update SDS Format: MSDS Author: Actio Corporation Disclaimer: This Health and Safety Information is correct to the best of our knowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or damage which may result from its use. We shall ensure, so far as is reasonably practicable, that any revision of this Data Sheet is sent to all customers to whom we have directly supplied this substance, but must point out that it is the responsibility of any intermediate supplier to ensure that such revision is passed to the ultimate user. The information given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chemicals should be handled only by competent personnel, within a controlled environment. Should further information be required, this can be obtained through the sales office whose address is at the top of this data sheet. Trademark: The trademarks, service marks, graphics and logos used on this MSDS are registered or unregistered trademarks of BEHR Process Corporation. All Rights Reserved. Product: KILZ® Color Change Ceiling Paint I Manufacturer: Masterchem Industries LLC I Revison:4/30/2015, Version:0 Page 4 of 5 Page 148 of 377 Page 148 of 377 Page 148 of 377 Page 148 of 377 ---PAGE BREAK--- Copyright© 1996-2015 Actio Corporation. All Rights Reserved. Product: KILZ® Color Change Ceiling Paint I Manufacturer: Masterchem Industries LLC I Revison:4/30/2015, Version:0 Page 5 of 5 Page 149 of 377 Page 149 of 377 Page 149 of 377 Page 149 of 377 ---PAGE BREAK--- Page 150 of 377 Page 150 of 377 Page 150 of 377 Page 150 of 377 ---PAGE BREAK--- Page 151 of 377 Page 151 of 377 Page 151 of 377 Page 151 of 377 ---PAGE BREAK--- Page 152 of 377 Page 152 of 377 Page 152 of 377 Page 152 of 377 ---PAGE BREAK--- Page 153 of 377 Page 153 of 377 Page 153 of 377 Page 153 of 377 ---PAGE BREAK--- Page 154 of 377 Page 154 of 377 Page 154 of 377 Page 154 of 377 ---PAGE BREAK--- KRYLON® Industrial QUIK-MARK™ Solvent-Based Inverted Marking Chalk (APWA) Orange Not available. Aerosol. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : THE SHERWIN-WILLIAMS COMPANY KRYLON PRODUCTS GROUP Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 03501 03501 Product code : Product Information Telephone Number : (800) 247-3266 Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 63% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 1/15 Page 155 of 377 Page 155 of 377 Page 155 of 377 Page 155 of 377 ---PAGE BREAK--- Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if inhaled. Causes serious eye irritation. Causes skin irritation. Suspected of damaging the unborn child. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. : Hazard statements Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release silica which has been shown to cause lung damage and cancer under long term exposure. DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 2/15 Page 156 of 377 Page 156 of 377 Page 156 of 377 Page 156 of 377 ---PAGE BREAK--- Section 3. Composition/information on ingredients Lt. Aliphatic Hydrocarbon Solvent 18.3 64742-89-8 Propane 11.2 74-98-6 Butane 10.8 106-97-8 Acetone 8.0 67-64-1 Toluene 7.3 108-88-3 n-Butyl Acetate 5.3 123-86-4 2-Butoxyethanol 2.7 111-76-2 Med. Aliphatic Hydrocarbon Solvent 2.3 64742-88-7 Ingredient name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Causes serious eye irritation. : Eye contact Potential acute health effects Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 3/15 Page 157 of 377 Page 157 of 377 Page 157 of 377 Page 157 of 377 ---PAGE BREAK--- Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. Over-exposure Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use an extinguishing agent suitable for the surrounding fire. Extinguishing media None known. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 4/15 Page 158 of 377 Page 158 of 377 Page 158 of 377 Page 158 of 377 ---PAGE BREAK--- Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 5/15 Page 159 of 377 Page 159 of 377 Page 159 of 377 Page 159 of 377 ---PAGE BREAK--- Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Propane NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. Butane NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. ACGIH TLV (United States, 4/2014). STEL: 1000 ppm 15 minutes. Acetone ACGIH TLV (United States, 4/2014). TWA: 500 ppm 8 hours. TWA: 1188 mg/m³ 8 hours. STEL: 750 ppm 15 minutes. STEL: 1782 mg/m³ 15 minutes. NIOSH REL (United States, 10/2013). TWA: 250 ppm 10 hours. TWA: 590 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 2400 mg/m³ 8 hours. Toluene OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 375 mg/m³ 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m³ 15 minutes. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 6/15 Page 160 of 377 Page 160 of 377 Page 160 of 377 Page 160 of 377 ---PAGE BREAK--- Section 8. Exposure controls/personal protection ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. n-Butyl Acetate ACGIH TLV (United States, 4/2014). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 2/2013). TWA: 150 ppm 8 hours. TWA: 710 mg/m³ 8 hours. 2-Butoxyethanol ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2013). Absorbed through skin. TWA: 5 ppm 10 hours. TWA: 24 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). Absorbed through skin. TWA: 50 ppm 8 hours. TWA: 240 mg/m³ 8 hours. Med. Aliphatic Hydrocarbon Solvent OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 400 mg/m³ 8 hours. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 7/15 Page 161 of 377 Page 161 of 377 Page 161 of 377 Page 161 of 377 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.9 1.55 [Air = 1] 13.5 kPa (101.325 mm Hg) [at 20°C] Not available. Not available. Odor pH Not available. Color Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] Not available. 7 Viscosity Kinematic (room temperature): <0.07 cm2/s cSt) Kinematic (40°C (104°F)): <0.07 cm2/s cSt) Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 0.9% Upper: 12.8% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 0.00002541 kJ/g Aerosol product Section 10. Stability and reactivity Conditions to avoid Avoid all possible sources of ignition (spark or flame). The product is stable. Chemical stability : : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 8/15 Page 162 of 377 Page 162 of 377 Page 162 of 377 Page 162 of 377 ---PAGE BREAK--- Section 10. Stability and reactivity Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. No specific data. : Incompatible materials : Section 11. Toxicological information Acute toxicity Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours Acetone LD50 Oral Rat 5800 mg/kg - Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours LD50 Oral Rat 636 mg/kg - n-Butyl Acetate LC50 Inhalation Gas. Rat 390 ppm 4 hours LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - 2-Butoxyethanol LCLo Inhalation Vapor Guinea pig >3.1 mg/l 1 hours LD50 Dermal Guinea pig >2000 mg/kg - LD50 Oral Rat 1300 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Acetone Eyes - Mild irritant Human - 186300 parts per million - Eyes - Mild irritant Rabbit - 10 microliters - Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams - Eyes - Severe irritant Rabbit - 20 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Mild irritant Rabbit - 395 milligrams - Toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 870 Micrograms - Eyes - Severe irritant Rabbit - 24 hours 2 milligrams - Skin - Mild irritant Pig - 24 hours 250 microliters - Skin - Mild irritant Rabbit - 435 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Skin - Moderate irritant Rabbit - 500 milligrams - n-Butyl Acetate Eyes - Moderate irritant Rabbit - 100 milligrams - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - 2-Butoxyethanol Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams - Eyes - Severe irritant Rabbit - 100 milligrams - Skin - Mild irritant Rabbit - 500 - Product/ingredient name Result Score Exposure Observation Species Information on toxicological effects Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 9/15 Page 163 of 377 Page 163 of 377 Page 163 of 377 Page 163 of 377 ---PAGE BREAK--- Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. milligrams Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Butane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Acetone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Toluene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects 2-Butoxyethanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Med. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Name Category Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined Propane Category 2 Not determined Not determined Butane Category 2 Not determined Not determined Acetone Category 2 Not determined Not determined Toluene Category 2 Not determined Not determined 2-Butoxyethanol Category 2 Not determined Not determined Med. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined Aspiration hazard Route of exposure Target organs Route of exposure Target organs Classification Toluene - 3 - 2-Butoxyethanol - 3 - Product/ingredient name NTP IARC OSHA Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 10/15 Page 164 of 377 Page 164 of 377 Page 164 of 377 Page 164 of 377 ---PAGE BREAK--- Section 11. Toxicological information Name Result Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Propane ASPIRATION HAZARD - Category 1 Butane ASPIRATION HAZARD - Category 1 Toluene ASPIRATION HAZARD - Category 1 Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Long term exposure Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 11/15 Page 165 of 377 Page 165 of 377 Page 165 of 377 Page 165 of 377 ---PAGE BREAK--- Not available. May cause damage to organs through prolonged or repeated exposure. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : Suspected of damaging the unborn child. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Oral 2743.1 mg/kg Inhalation (gases) 2737.7 ppm Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Potential delayed effects : Not available. Section 12. Ecological information Toxicity Lt. Aliphatic Hydrocarbon Solvent Acute LC50 >100000 ppm Fresh water Fish - mykiss 96 hours Acetone Acute EC50 20.565 mg/l Marine water Algae - Ulva pertusa 96 hours Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours Acute LC50 10000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Chronic NOEC 5 µg/l Marine water Fish - Gasterosteus aculeatus - Larvae 42 days Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 5500 µg/l Fresh water Fish - kisutch - Fry 96 hours Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days n-Butyl Acetate Acute LC50 32000 µg/l Marine water Crustaceans - Artemia salina - Nauplii 48 hours Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Butoxyethanol Acute EC50 >1000 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 800000 µg/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 1250000 µg/l Marine water Fish - Menidia beryllina 96 hours Product/ingredient name Species Result Exposure Persistence and degradability Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 12/15 Page 166 of 377 Page 166 of 377 Page 166 of 377 Page 166 of 377 ---PAGE BREAK--- Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Lt. Aliphatic Hydrocarbon Solvent - 10 to 2500 high Toluene - 90 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Acetone - - Readily Toluene - - Readily n-Butyl Acetate - - Readily 2-Butoxyethanol - - Readily Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 Special provisions LIMITED QUANTITY Emergency schedules (EmS) LIMITED QUANTITY, F-D, S-U DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. TDG Classification UN1950 AEROSOLS 2.1 - No. Special provisions LIMITED QUANTITY Mexico Classification UN1950 AEROSOLS 2.1 - No. Special provisions (ERG#126) IATA UN1950 AEROSOLS, flammable 2.1 - No. Special provisions LIMITED QUANTITY Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 13/15 Page 167 of 377 Page 167 of 377 Page 167 of 377 Page 167 of 377 ---PAGE BREAK--- Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not available. : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information U.S. Federal regulations : WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 State regulations Section 16. Other information Notice to reader Hazardous Material Information System 2 3 0 Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 14/15 Page 168 of 377 Page 168 of 377 Page 168 of 377 Page 168 of 377 ---PAGE BREAK--- Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 15/15 Page 169 of 377 Page 169 of 377 Page 169 of 377 Page 169 of 377 ---PAGE BREAK--- page 1 of 6 DATE OF PREPARATION Jun 9, 2015 MATERIAL SAFETY DATA SHEET 363 02 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 363 PRODUCT NAME KRYLON® WEEKEND® Spray Paint, All Purpose Grey Primer MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON INDUSTRIAL PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) Page 170 of 377 Page 170 of 377 Page 170 of 377 Page 170 of 377 ---PAGE BREAK--- 363 page 2 of 6 HMIS Codes Health 2* Flammability 3 Reactivity 0 SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 14 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 13 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 3 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 1 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 6 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 1 67-63-0 2-Propanol ACGIH TLV 200 PPM 33 mm ACGIH TLV 400 PPM STEL OSHA PEL 400 PPM 40 67-64-1 Acetone ACGIH TLV 500 PPM 180 mm ACGIH TLV 750 PPM STEL OSHA PEL 1000 PPM 5 110-19-0 Isobutyl Acetate ACGIH TLV 150 PPM 12.5 mm OSHA PEL 150 PPM 10 14807-96-6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust 1 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 171 of 377 Page 171 of 377 Page 171 of 377 Page 171 of 377 ---PAGE BREAK--- 363 page 3 of 6 UEL 12.8 LEL 1.0 FLASH POINT Propellant < 0 °F SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Page 172 of 377 Page 172 of 377 Page 172 of 377 Page 172 of 377 ---PAGE BREAK--- 363 page 4 of 6 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 6.46 lb/gal 774 g/l SPECIFIC GRAVITY 0.78 BOILING POINT <0 - 292 °F <-18 - 144 °C MELTING POINT Not Available VOLATILE VOLUME 93% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 43.59% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Page 173 of 377 Page 173 of 377 Page 173 of 377 Page 173 of 377 ---PAGE BREAK--- 363 page 5 of 6 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 67-63-0 2-Propanol LC50 RAT 4HR Not Available LD50 RAT 5045 mg/kg 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 110-19-0 Isobutyl Acetate LC50 RAT 4HR Not Available LD50 RAT 13400 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, 2.1, LIMITED QUANTITY Page 174 of 377 Page 174 of 377 Page 174 of 377 Page 174 of 377 ---PAGE BREAK--- 363 page 6 of 6 SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 3 100-41-4 1 1330-20-7 Xylene 6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 175 of 377 Page 175 of 377 Page 175 of 377 Page 175 of 377 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Liquid Wrench Penetrating Oil Product identifier Other means of identification L103 SDS number L103 Part No. 3403.19.5000 Tariff code Penetrant Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service: (704) 821-7643 Technical: (704) 684-1811 Emergency phone number Emergency Telephone: (303) 623-5716 Emergency Contact: ([PHONE REDACTED]) E-mail United States Not available. Indian Trail, NC 28079 2. Hazard(s) identification Category 2 Flammable aerosols Physical hazards Category 1B Germ cell mutagenicity Health hazards Category 1A Carcinogenicity Category 3 narcotic effects Specific target organ toxicity, single exposure Category 2 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement May cause drowsiness or dizziness. May cause genetic defects. May cause cancer. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Flammable aerosol. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist or vapor. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. Collect spillage. 1 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 176 of 377 Page 176 of 377 Page 176 of 377 Page 176 of 377 ---PAGE BREAK--- Storage Store in a well-ventilated place. Keep container closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Combustible. Supplemental information 31.72% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 31.72% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures CAS number % Common name and synonyms Chemical name 64742-47-8 Distillates (petroleum), Hydrotreated Light 60 - < 70 68476-86-8 Petroleum Gases, Liquefied, Sweetened; Petroleum Gas; 20 - < 30 Other components below reportable levels 10 - < 20 64741-88-4 Distillates (petroleum), Solvent-refined Heavy Paraffinic < 0.3 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists. Skin contact Rinse with water. Get medical attention if irritation develops and persists. Eye contact In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Most important acute and delayed Provide general supportive measures and treat Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. General information 5. Fire-fighting measures Powder. Alcohol resistant foam. Dry chemicals. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Specific methods Combustible. Flammable aerosol. General fire hazards 2 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 177 of 377 Page 177 of 377 Page 177 of 377 Page 177 of 377 ---PAGE BREAK--- 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Refer to attached safety data sheets and/or instructions for use. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Use water spray to reduce vapors or divert vapor cloud drift. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing mist or vapor. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). Level 3 Aerosol. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Form Type PEL 5 mg/m3 Mist. Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) 2000 mg/m3 500 ppm US. ACGIH Threshold Limit Values Value Components Form Type TWA 5 mg/m3 Inhalable fraction. Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Form Type TWA 100 mg/m3 Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Ceiling 1800 mg/m3 Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) STEL 10 mg/m3 Mist. 3 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 178 of 377 Page 178 of 377 Page 178 of 377 Page 178 of 377 ---PAGE BREAK--- No biological exposure limits noted for the ingredient(s). Biological limit values Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Chemical respirator with organic vapor cartridge and full facepiece. Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Use of an impervious apron is recommended. Other Chemical respirator with organic vapor cartridge and full facepiece. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Opaque Liquid. Appearance Liquid. Physical state Aerosol. Form Yellow Color Pleasant. Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 347 °F (175 estimated Flash point > 200.0 °F 93.3 Tag Closed Cup Evaporation rate Not available. Not applicable. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 0.7 % estimated Flammability limit - upper 5 % estimated Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 0.57 hPa estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 410 °F (210 estimated Decomposition temperature Not available. Viscosity Not available. Other information Density 7.42 lbs/gal Not explosive. Explosive properties Flame extension > 18 in 4 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 179 of 377 Page 179 of 377 Page 179 of 377 Page 179 of 377 ---PAGE BREAK--- Flammability (flash back) No Flammability class Combustible IIIB estimated Heat of combustion > 36 kJ/g Heat of combustion (NFPA 30B) 27.62 kJ/g estimated Not oxidizing. Oxidizing properties Percent volatile 0.21 % estimated Specific gravity 0.88 estimated VOC (Weight 21.4 % w/w 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong oxidizing agents. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Headache. May cause drowsiness and dizziness. Nausea, vomiting. Diarrhea. Information on toxicological effects Acute toxicity Narcotic effects. Prolonged skin contact may cause temporary irritation. Skin corrosion/irritation Direct contact with eyes may cause temporary irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Skin sensitization May cause genetic defects. Germ cell mutagenicity Carcinogenicity May cause cancer. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) Known To Be Human Carcinogen. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 5 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 180 of 377 Page 180 of 377 Page 180 of 377 Page 180 of 377 ---PAGE BREAK--- 12. Ecological information Toxic to aquatic life with long lasting effects. Ecotoxicity Components Test Results Species * Estimates for product may be based on additional component data not shown. Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Aquatic LC50 Fish 2.9 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT Not available. UN number Consumer commodity UN proper shipping name ORM-D Class Transport hazard class(es) - Subsidiary risk None Label(s) Not applicable. Packing group Yes Marine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 156, 306 Packaging exceptions 156, 306 Packaging non bulk None Packaging bulk IATA UN1950 UN number Aerosol, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk III Packing group Yes Environmental hazards 9L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information 6 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 181 of 377 Page 181 of 377 Page 181 of 377 Page 181 of 377 ---PAGE BREAK--- Allowed. Cargo aircraft only IMDG UN1950 UN number Aerosols UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk III Packing group Yes Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IATA; IMDG Marine pollutant 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. One or more components are not listed on TSCA. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. 7 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 182 of 377 Page 182 of 377 Page 182 of 377 Page 182 of 377 ---PAGE BREAK--- No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) Petroleum Gases, Liquefied, Sweetened; Petroleum Gas; (CAS 68476-86-8) US. Massachusetts RTK - Substance List Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) US. New Jersey Worker and Community Right-to-Know Act Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) US. Worker and Community Right-to-Know Law Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* No Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 05-06-2015 Issue date Version # 01 8 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 183 of 377 Page 183 of 377 Page 183 of 377 Page 183 of 377 ---PAGE BREAK--- The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer 9 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 184 of 377 Page 184 of 377 Page 184 of 377 Page 184 of 377 ---PAGE BREAK--- PRODUCT AND COMPANY IDENTIFICATION 1 Manufacturer Malco Products, Inc. 361 Fairview Ave Barberton, OH 44203 Contact: Telephone Number: FAX Number: E-Mail: Web Technical Department [PHONE REDACTED] [PHONE REDACTED] [EMAIL REDACTED] www.malcopro.com 24 hour Emergency Assistance: 1-[PHONE REDACTED] Lotion Hand Cleaner with Pumice 8/24/12 02 1062 Hand Cleaning Product Name: Revision Date: Version: MSDS Number: Product Use: HAZARDS IDENTIFICATION 2 See Below Route of Entry: English: No information Spanish: no hay nada información French:Aucun renseignement Target Organs: English: Not known to be an inhalation irritant. Spanish: No conocido ser un irritante de inhalación. French: Non su être un irritant d'inhalation. Inhalation: English: Not irritating to the skin. Spanish: No irritando a la piel. French: Pas en irritant à la peau. Skin Contact: English: Eye Irritant Spanish: Irritante de Ojo French: Irritant d'Oeil Eye Contact: English: Harmful if swallowed. Spanish: Dañoso si está tragado. French: Nocif si avalé. Classification According to Directive 1999/45/EC (DSD) Classification: Xi, Xn, R22, R36 GHS/CLP Signal Word(s): WARNING Hazard Phrase(s): H302, H320 Ingestion: Lotion Hand Cleaner with Pumice Material Safety Data Sheet Revision Date: 8/24/12 MSDS Number: 1062 Page of 1 8 MSDS Malco Products, Inc. Page 185 of 377 Page 185 of 377 Page 185 of 377 Page 185 of 377 ---PAGE BREAK--- Precautionary Phrase(s): P101, P102, P103, P264, P270, P301+P312, P305+P351+P338, P330, P337+P313, P501 Pictogram(s): Exclamation New Zealand Register of Hazardous Substances HSNO: HSR002617 N.O.S. (Combustible) Group Standard 2006 HMIS II-ratings (scale 0-4): Health = 1, Fire = 2, Reactivity = 0 HMIS® Rating H1/F2/PH0 NFPA-ratings (scale 0-4): Health = 1, Fire = 2, Reactivity = 0 COMPOSITION/INFORMATION ON INGREDIENTS 3 Ingredients: Cas#/EC# Perc. Chemical Name Haz* R* Class Phrases 8052-41-3/ I 1-9% I Mineral spirits I T,Xn I R45,R46 232-489-3 I I I I R65 14808-60-7/I 1-10% I Silica, I Xi I R20, R36 238-878-4 I I quartz I I 102-71-6/ I 1-5% I Triethanolamine I Xi I R36. R38 203-049-8 I I I I 64742-47-8/I 15-25%I Distillates, petroleum,I Xn I R65 265-149-8 I I hydrotreated light I I * Self Classification FIRST AID MEASURES 4 English: If breathing is difficult or irritating, move person to fresh air immediately. If persist, get medical attention. Spanish: Si respiración está difícil o irritante, se mueva la persona al aire fresco inmediatamente. Si los síntomas persisten, busque la atención médica. French: En cas de difficultés respiratoires ou d'irritation, transporter immédiatement la personne à l'air frais. Si les persistent, consulter un médecin. Inhalation: English: Rinse area with soap and water. Seek medical attention if any redness or irritation persists. Spanish: Enjuaga el área con jabon y agua. Busque la atención médica. French: La région de rinçage avec le savon et l'eau. Cherchez l'attention médicale si la rougeur ou l'irritation persistent. Skin Contact: English: Flush immediately with large amounts of clean water for a minimum of 15 minutes, lifting upper and lower lids occasionally. Remove contact lenses, if present and easy to do. Do not rub eyes. If any irritation persists, seek medical attention. Spanish: Vacie inmediatamente con mucho agua limpio por un mínimo de 15 minutos, levantándose los párpados superiores y inferiores de vez en cuando. Quite lentes de contacto, si presente y fácil para hacer. No se frote los ojos. Si la irritación persiste, busque la atención Eye Contact: Lotion Hand Cleaner with Pumice Material Safety Data Sheet Revision Date: 8/24/12 MSDS Number: 1062 Page of 2 8 MSDS Malco Products, Inc. Page 186 of 377 Page 186 of 377 Page 186 of 377 Page 186 of 377 ---PAGE BREAK--- médica inmediatamente. French: Rincer immédiatement à grande eau propres pendant au moins 15 minutes, en soulevant les paupières inférieures et supérieures de temps à autre. Enlevez des lentilles cornéennes, si présent et facile de faire. Ne pas se frotter les yeux. Si une irritation persiste, chercher l'attention médicale. English: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Spanish: De ser ingerido, no induzca vómitos: busque el consejo médico inmediatamente y muestre este contenedor o etiqueta. French: Si avalé, n'incitez pas de vomissement : cherchez le conseil médical tout de suite et montrez ce récipient ou étiquette. Ingestion: FIRE FIGHTING MEASURES 5 English: All types Spanish: Todos los tipos French: Tous les types Flash Point: Flash Point Method: Burning Rate: Autoignition Temperature: LEL: UEL: Flammability Classification: 145 F Closed Cup Not Available Not Available Not Available Not Available Combustible (Domestic U.S.) / Non-Flammable (EU International) ACCIDENTAL RELEASE MEASURES 6 English: Contain large spills with dikes to prevent entry to waterways and sanitary sewers and transfer the material to appropriate containers for reclamation or disposal. Absorb/trap remaining material or small spills with inert material (dirt, sand, industrial absorbent) and then place in a chemical waste containers. Flush residual spill area with large amounts of water. Dispose of all clean up materials in accordance with all applicable federal, state, and local heath and environmental regulations. Spanish: Contenga derramamientos grandes con diques para prevenir la entrada a los canales y alcantarillas sanitarias y transferir la materia a los contenedores para recuperación o disposición. Disponga de todos los materiales de la limpieza de acuerdo con todas las regulaciones aplicables federales y estados y las regulaciones locales del salud y ambientales. French: Contenir les déversements majeurs avec des digues afin d'éviter qu'ils ne pénètrent les voies d'eau et les égouts sanitaires. Transférer les matériaux dans des conteneurs appropriés aux fins de réclamation ou d'élimination. Absorber/cerner les matériaux restants ou les déversements mineurs avec des matériaux inertes (impuretés, sable, absorbant industriel) et les placer ensuite dans des conteneurs pour déchets chimiques. Rincer la zone de déversement résiduel à grande quantité d'eau Procéder à la mise au rebut des matériaux de nettoyage conformément à toutes les réglementations sanitaires et environnementales au niveau national, régional et local. HANDLING AND STORAGE 7 English: Wear proper Personal Protective Equipment when handling. Spanish: Lleve puesto el Equipo Protector Personal apropiado manejando. French: Portez l'Équipement Protecteur Personnel nécessaire en manipulant. Handling Precautions: English: Do not store below 32 degrees F. Do not store in direct sunlight. Keep away from heat, open flames or other sources of ignition. Keep away from children. Keep containers closed. Spanish: No almacene debajo de 32 F grados. No almacene en la luz directa del sol. Storage Requirements: Lotion Hand Cleaner with Pumice Material Safety Data Sheet Revision Date: 8/24/12 MSDS Number: 1062 Page of 3 8 MSDS Malco Products, Inc. Page 187 of 377 Page 187 of 377 Page 187 of 377 Page 187 of 377 ---PAGE BREAK--- Consérvese lejos de calor, llamas abiertas u otras fuentes de la ignición. Mantiene a distancia los niños. Mantiene que los contenedores están cerrados muy bien. French: Ne pas entreposer à des températures inférieures à 0 °C (32 Ne pas entreposer directement à la lumière du jour. Tenez éloigné de la chaleur, les flammes ouvertes ou d'autres sources d'ignition. Tenir à l'écart des enfants. Bien fermer les conteneurs. Les matériaux exposés à l'air peuvent absorber l'eau. EXPOSURE CONTROLS/PERSONAL PROTECTION 8 English: Local exhaust recommended. Spanish: Extractor local está recommendado French: Évacuation locale recommandée. Engineering Controls: HMIS PP, A I Goggles English: Safety glasses or goggles recommended. Spanish: Cristales inastillables o anteojos recomendados. French: Les verres de sécurité ou les lunettes de protection recommandées. Protective Equipment: English: There is no data available for this product. Spanish: No hay ningunos datos disponibles para este producto. French: Il n'y a aucune donnée disponible pour ce produit. Exposure Guidelines/Other: PHYSICAL AND CHEMICAL PROPERTIES 9 Light Green Appearance: Viscous Liquid Physical State: Herbal/Fresh Odor: ~8.0 pH: No available data Vapor Pressure: No available data Vapor Density: Not available Boiling Point: <32 F Freezing/Melting Pt.: Partial in in water Solubility: 8.2 lbs/gal Spec Grav./Density: 6.98% by weight VOC: STABILITY AND REACTIVITY 10 English: Yes Spanish: sí French: Oui Stability: English: Keep away from ignition sources, heat, sparks or flames. Spanish: Consérvese lejos de fuentes de ignición, calor, chispas o llamas. French: Tenez éloigné des sources d'ignition, la chaleur, les étincelles ou les flammes. Conditions to avoid: English: Strong acids. Oxidizers. Spanish: Ácidos fuertes. Oxidantes. French: Acides puissants. Oxydants. Materials to avoid (incompatability): English: Carbon Monoxide and other hazardous chemicals. Spanish: Monóxido de carbono y otros productos químicos arriesgados. French: Oxyde de carbone et d'autres produits chimiques les hasardeux. Hazardous Decomposition products: Lotion Hand Cleaner with Pumice Material Safety Data Sheet Revision Date: 8/24/12 MSDS Number: 1062 Page of 4 8 MSDS Malco Products, Inc. Page 188 of 377 Page 188 of 377 Page 188 of 377 Page 188 of 377 ---PAGE BREAK--- English: Will not occur Spanish: No occurirá French: Aucun risque Hazardous Polymerization: TOXICOLOGICAL INFORMATION 11 English: There is no data available for this product. Spanish: No hay ningunos datos disponibles para este producto. French: Il n'y a aucune donnée disponible pour ce produit. ECOLOGICAL INFORMATION 12 English: There is no data available for this product. Spanish: No hay ningunos datos disponibles para este producto. French: Il n'y a aucune donnée disponible pour ce produit. DISPOSAL CONSIDERATIONS 13 English: Dispose of in accordance with local, state, and federal regulations. Spanish: Disponga de acuerdo con las regulaciones locales, estadas y federales. French: Conformément à toutes les réglementations locales, régionales et gouvernementales. TRANSPORT INFORMATION 14 English: Because this is produced and shipped in several different container sizes as well as domestically and internationally, please consult your transportation specialist for the proper shipping name and class. French: Veuillez consulter votre spécialiste en transport pour le nom et la classe appropriés d'expédition. Spanish: Por favor, llame a su especialista de transporte para la clase transportiva. DOT Class: Cosumer Commodity ORM-D IMDG: Not Regulated REGULATORY INFORMATION 15 European CHIP Regulation: Xi ES: Irritante EN: Irritant FR: Irritant Xn ES: Nocivo Lotion Hand Cleaner with Pumice Material Safety Data Sheet Revision Date: 8/24/12 MSDS Number: 1062 Page of 5 8 MSDS Malco Products, Inc. Page 189 of 377 Page 189 of 377 Page 189 of 377 Page 189 of 377 ---PAGE BREAK--- EN: Harmful FR: Nocif R22 ES: Nocivo por ingestión. EN: Harmful if swallowed. FR: Nocif par ingestion. R36 ES: Irritante a ojos. EN: Irritating to eyes. FR: Agaçant aux yeux. S1/2 ES: Quédese cerrado y del alcance de niños.. EN: Keep locked up and out of the reach of children. FR: Gardez mis sous clé et de la portée d'enfants. S25 ES: Evite el contacto con ojos. EN: Avoid contact with eyes. FR: Évitez le contact avec les yeux. S26 ES: En caso del contacto con ojos, aclare inmediatamente con mucha agua y busque el consejo médico. EN: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. FR: En cas du contact avec les yeux, rincez immédiatement avec l'abondance d'eau et cherchez le conseil médical. S3/7 ES: Guarde el contenedor fuertemente cerrado en un lugar chulo. EN: Keep container closed in a cool place. FR: Gardez le récipient fermement fermé dans un endroit frais. S39 ES: Ojo de ropa y/o protección de cara. EN: Wear eye/face protection. FR: Oeil de vêtements et-ou protection de visage. S62 ES: De ser ingerido, no induzca vómitos: busque el consejo médico inmediatamente y muestre este contenedor o etiqueta. EN: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. FR: Si avalé, n'incitez pas de vomissement : cherchez le conseil médical tout de suite et montrez ce récipient ou étiquette. Lotion Hand Cleaner with Pumice Material Safety Data Sheet Revision Date: 8/24/12 MSDS Number: 1062 Page of 6 8 MSDS Malco Products, Inc. Page 190 of 377 Page 190 of 377 Page 190 of 377 Page 190 of 377 ---PAGE BREAK--- *Mineral spirits (8052413 1-9%) MASS, OSHAWAC, PA, TXAIR *Silica, quartz (14808607 1-10%) MASS, NRC, OSHAWAC, PA, TXAIR *Triethanolamine (102716 1-5%) HAP, MASS, PA, TXAIR This product contains chemicals known to the State of California to cause cancer and/or birth defects or other reproductive harm. Formaldehyde (CAS 50-00-0)* *However, typical end-use exposure will be lower than Safe Harbor Levels according to Prop 65 REGULATORY KEY DESCRIPTIONS MASS = MA Massachusetts Hazardous Substances List OSHAWAC = OSHA Workplace Air Contaminants PA = PA Right-To-Know List of Hazardous Substances TXAIR = TX Air Contaminants with Health Effects Screening Level NRC = Nationally Recognized Carcinogens HAP = Hazardous Air Pollutants CERCLA = Superfund clean up substance = Clean Water Act Hazardous substances EHS302 = Extremely Hazardous Substance EPCRAWPC = EPCRA Water Priority Chemicals NJEHS = NJ Extraordinarily Hazardous Substances NJHS = NJ Right-to-Know Hazardous Substances OSHAHTS = OSHA Hazardous and Toxic Substances OSHAPSM = OSHA Chemicals Requiring process safety management PROP65 = CA Prop 65 SARA313 = SARA 313 Title III Toxic Chemicals TOXICRCRA = RCRA Toxic Hazardous Wastes (U-List) = TX Hazardous Waste List OTHER INFORMATION 16 English: The information contained herein is based on data considered accurate to the best of our knowledge at the date of its publication. However, no warranty is expressed or implied regarding the accuracy, completeness, or adequacy of the information contained herein. The vendor shall not be held liable (regardless of fault) to the vendee or third persons, or anyone for any direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of such information. Spanish: La información en este documento está basada en data que está considerada ser exacta al mejor de nuestro conocimiento en la fecha de publicación. Sin embargo, no hay garantía expresado o implicado con respecto la exactitud, lo completo, o a la suficiencia de la información contenida en este documento. El Lotion Hand Cleaner with Pumice Material Safety Data Sheet Revision Date: 8/24/12 MSDS Number: 1062 Page of 7 8 MSDS Malco Products, Inc. Page 191 of 377 Page 191 of 377 Page 191 of 377 Page 191 of 377 ---PAGE BREAK--- vendedor no es obligado (sin importar culpa) al comprador o personas terceras, o alguien para unos daños directos, especiales o consecuentes como resulto de o conectado con la exactitud, lo completo, la suficiencia o el equipar de esta información. French: Les présentes informations sont basées sur des données jugées exactes. Toutefois, aucune garantie ne peut être formulée expressément ou implicitement quant à l'exactitude de ces données et aucun résultat ne peut être obtenu sur l'utilisation desdites données. Si les consignes de sécurité stipulées dans la fiche signalétique n'ont pas été respectées, le revendeur n'endosse aucune responsabilité quant aux blessures subies par l'acheteur ou une partie tierce infligées suite à l'utilisation des matériaux. En outre, le revendeur n'endosse aucune responsabilité quant aux blessures que l'acheteur ou une partie tierce pourrait subir suite à une utilisation anormale des matériaux et cela même si les consignes de sécurité ont été respectées. La responsabilité des risques inhérents à l'utilisation des matériaux incombe entièrement à l'acheteur. END OF MSDS DOCUMENT Lotion Hand Cleaner with Pumice Material Safety Data Sheet Revision Date: 8/24/12 MSDS Number: 1062 Page of 8 8 MSDS Malco Products, Inc. Page 192 of 377 Page 192 of 377 Page 192 of 377 Page 192 of 377 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MAJESTIC BLEACH 5.25 % WT SECTION I – PRODUCT IDENTIFICATION PRODUCT NAME: Majestic Bleach MANUFACTURER: Champion Packaging 1840 Internationale Parkway Woodridge, IL 60517 (630) 972-0100 DATE LAST REVISED: May 1, 2007 CAS NUMBER: 7681-52-9 CHEMICAL FORMULA: NaOCL (Solution) HAZARDOUS INGREDIENTS: Sodium Hypochlorite 5.25% WT EMERGENCY TELEPHONE NO.: INFOTRAC: 1-[PHONE REDACTED] SECTION II – PHYSICAL DATA APPEARANCE: Clear to Yellow Liquid ODOR: Pungent, irritating, that of household bleach. SOLUBILITY: Complete BOILING POINT: Decomposes prior to boiling SPECIFIC GRAVITY: 1.086 @ 60’ F pH: 12.75 VAPOR PRESSURE: Approximately that of air EVAPORATION RATE: Not Applicable SECTION III – FIRE AND EXPLOSION INFORMATION FIRE: Not considered to be a fire hazard. EXPLOSION: Not considered an explosion hazard. FIRE EXTINGUISHING MEDIA: Use any means suitable for extinguishing surrounding fire. SPECIAL INFORMATION: Wear fully encapsulated suits with self-contained breathing apparatus (Positive Pressure). Page 1 of 3 Page 193 of 377 Page 193 of 377 Page 193 of 377 Page 193 of 377 ---PAGE BREAK--- SECTION IV – REACTIVITY DATA STABILITY: Stable under ordinary conditions of use and storage. Unstable at elevated temperatures. HAZARDOUS DECOMPOSITION PRODUCTS: Decomposes under various mechanisms. May generate chlorine or oxygen, which can be toxic and explosive, respectively. HAZARDOUS POLYMERIZATION: This substance does not polymerize. INCOMPATIBILITIES (Material to Avoid): Reacts vigorously with Amine, Ammonium Acetate, Ammonium Oxalate, Acids and most organics. SECTION V – LEAK / SPILL DISPOSAL INFORMATION RELEASES/SPILLS: Move unprotected personnel upwind out of danger. REPORTABLE QUANTITY (RQ) (CWA/CERCLA): 100 lbs., 454 Kg DISPOSAL: Dilute with water and flush to local sewer system, if permitted. Solid waste must be disposed of in a permitted waste management facility. Ensure compliance with local, state, and federal regulations. SECTION VI – HEALTH HAZARD INFORMATION EXPOSURE/HEALTH EFFECTS: INHALATION: Respiratory tract irritant. INGESTION: Can cause corrosion of the mucous membranes. IF SWALLOWED: Call poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. SKIN CONTACT: Contact with liquid can cause chemical burns. Immediately flush with soap and water. EYE CONTACT: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. CHRONIC EXPOSURE: No data found. CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: NTP -NO; IARC -NO; OSHA -NO; ACGIH –NO. SECTION VII – OCCUPATIONAL CONTROL MEASURES OSHA PERMISSIBLE EXPOSURE LIMIT: Not established. VENTILATION SYSTEM: Local exhaust. PERSONAL RESPIRATORS: (NIOSH Approved) Recommended for all personnel working in or about an area of potential exposure. SKIN PROTECTION: Wear impervious protective clothing including boots, gloves, lab coat, apron, or coveralls to prevent skin contact. EYE PROTECTION: Use chemical safety goggles that are impervious to product. Contact lenses should not be worn when working with this material. Maintain eye wash fountain and quick-drench facilities in work area. Page 2 of 3 Page 194 of 377 Page 194 of 377 Page 194 of 377 Page 194 of 377 ---PAGE BREAK--- SECTION VIII – STORAGE AND SPECIAL INFORMATION Store in cool, dry, ventilated area. Protect against physical damage. Keep separate from incompatibles. SECTION IX – REGULATORY INFORMATION Regulated under the Federal Insecticide Fungicide and Rotenticide Act (FIFRA) if any sanitation or disinfection claims are made on label. NFPA/HMIS RATINGS: HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 HIGHER ALKALINITY R - 1. SARA TITLE III - SEC. 302, 304, 311, 312. REPORTABLE QUANTITY (RQ) (CWA/CERCLA): 100 lbs. THE INFORMATION CONTAINED HEREIN IS PROVIDED IN GOOD FAITH AND IS BELIEVED TO BE CORRECT AS OF THE DATE HEREOF; HOWEVER, CHAMPION PACKAGING, INC. MAKES NO REPRESENTATION AS TO THE COMPREHENSIVENESS OR ACCURACY OF THE INFORMATION. IT IS EXPECTED THAT INDIVIDUALS RECEIVING THE INFORMATION WILL EXERCISE THEIR INDEPENDENT JUDGMENT IN DETERMINING ITS APPROPRIATENESS FOR A PARTICULAR PURPOSE. ACCORDINGLY, CHAMPION PACKAGING, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES OF ANY KIND RESULTING FROM THE USE OF OR RELIANCE UPON SUCH INFORMATION. NO REPRESENTATIONS, OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR TO THE PRODUCT TO WHICH THE INFORMATION REFERS. Page 3 of 3 Page 195 of 377 Page 195 of 377 Page 195 of 377 Page 195 of 377 ---PAGE BREAK--- MARVEL OIL CO., INC. 625 WILLOWBROOK CTR PKWY WILLOWBROOK, IL 60527 SAFETY DATA SHEET 1. Product and Company Identification 1.1 Product Identifier Product Name: Marvel Air Tool Oil Product Code (SKU): MM85R1 (50100), MM080R (50093) - See Section 15 for discontinued SKU’s 1.2 Relevant Identified Uses Of The Substance Product Use: Engine Oil Additive – Fuel additive (EPA Registered) 1.3 Details of the Supplier of the SDS Company Name: Marvel Oil Company, Inc. Street Address: 625 Willowbrook Centre Parkway City, State, Zip Code: Willowbrook, Illinois 60527 1.4 Emergency Telephone Numbers Phone Number: 1(630)455-3700 Fax Number: 1(630)455-3868 Transportation: 1(800)424-9300 (CHEMTREC) Medical Assistance: Call your local Poison Control Center 2. Hazard Identification: 2.1 Classification of the Substance or Mixture Hazard Classification: Flammable liquid 3 Skin irritation 2 Reproductive Toxicity 2 Aspiration toxicity 1 2.2 Label Elements Pictogram: Signal Word: Danger Hazard Statement: Flammable liquid and vapor. Causes skin irritation. Suspected of damaging fertility of the un-born child. May be fatal if swallowed and enters airways. Precautionary Statement: Keep away from heat, sparks, open flames or hot surfaces. Do not smoke. Keep containers closed. Ground all containers and receiving equipment. Use explosion proof electrical, ventilation, and lighting equipment. Use only non- sparking tools. Take precautionary measures against static Page 196 of 377 Page 196 of 377 Page 196 of 377 Page 196 of 377 ---PAGE BREAK--- discharge. Wear protective gloves, clothing, eye glasses and face shield. Do not handle until all safety precautions have been read and understood. Wash hands thoroughly after handling. If exposed, get medical attention. If on skin or hair, remove immediately all contaminated clothing and launder before re-use. Wash skin with soap and water. If skin irritation occurs, get medical attention. If swallowed, immediately call a poison control center or doctor. Do NOT induce vomiting. Store in a well ventilated place. Dispose of contents and container in accordance with all local, state, national and international regulations. 2.3 Other Hazards Description of additional HNOC: None 3. Information on Ingredients: 3.1 Substance not applicable 3.2 Mixture Component CAS Number Concentration (wt%) Petroleum Distillates (Hydrotreated Heavy 64742-52-5 60-100% Naphthenic) Petroleum Distillates (Stoddard Solvent) 8052-41-3 10-30% Tricresyl Phosphate 1330-78-5 0.1-1.0% Ortho Dichlorobenzene 95-50-1 0.1-1.0% Para Dichlorobenzene 106-46-7 <0.1% 4. First Aid Measures: 4.1 Description of First Aid Measures Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects persist or you feel un-well. Skin: In case of skin contact, wash thoroughly with soap and water. Remove contaminated clothing and footwear. Launder clothing before re-use. Call a physician if irritation develops or persists. Eyes: In case of eye contact, immediately flush eyes with plenty of water. Remove contact lenses if worn. If irritation persists, get medical attention Ingestion: If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person. Immediately call a poison control center or physician. 4.2 Most important and effects – acute and chronic Inhalation: May cause respiratory tract irritation. Vapors may cause drowsiness or dizziness. Skin: Cause skin irritation. may include redness, edema, drying, defatting, and cracking of skin. Eyes: May cause temporary eye irritation. may include discomfort or pain, excess blinking and tearing, with redness and swelling. Ingestion: May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. Page 197 of 377 Page 197 of 377 Page 197 of 377 Page 197 of 377 ---PAGE BREAK--- 4.3 Indication of any immediate medical attention and special treatment may not appear immediately. Seek medical attention if effects develop or persist and you feel un-well. 5. Fire Fighting Measures: 5.1 Extinguishing media Carbon dioxide, dry chemical, and alcohol foam 5.2 Special hazards arising from the substance or mixture CO2, CO, and hydrocarbons 5.3 Advice for Fire Fighters Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory protection (SCBA). Cool closed containers exposed to fire with water. See Section 8 for personal protection. 6. Accidental Release Measures: 6.1 Personal precautions, protective equipment, and emergency procedures Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate all source of ignition. 6.2 Methods and materials for containment and clean up For containment: Contain and absorb spill with inert material. Place in suitable container for disposal. Do not flush to sewer or allow to enter waterways. See section 8 for PPE. For clean up: Take up material and place in a suitable container. Vapors may be heavier than air and may travel along the ground to a distant source of ignition. Provide adequate ventilation. 7. Handling and Storage 7.1 Precautions for safe handling Keep away from source of ignition. Do not smoke. Take precaution to eliminate static discharge. Avoid contact with skin and eyes. Avoid breathing vapor or mist. Do not swallow. Do not eat or drink while handling. Wash hands with soap and water after handling. Use only non-sparking tools. 7.2 Conditions for safe storage including incompatibilities Keep out of reach of children. Store in a well ventilated place. Do not store above 49°C (120°F). 7.3 Specific end uses Shelf Life: Shelf life is considered to be 7 – 10 years when properly stored. 8. Exposure Control/Personal Protection: 8.1 Control parameters Page 198 of 377 Page 198 of 377 Page 198 of 377 Page 198 of 377 ---PAGE BREAK--- Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA) Petroleum Distillates (Hydrotreated Heavy not applicable not applicable Naphthenic) Petroleum Distillates (Stoddard Solvent) 500 ppm 100 ppm Tricresyl Phosphate not applicable not applicable Ortho Dichlorobenzene 50 ppm 25 ppm Para Dichlorobenzene 75 ppm 10 ppm 8.2 Exposure controls Use adequate ventilation to keep exposure below recommended limits. Ensure that eye wash station and safety shower are close to work station. Hand Protection Equipment: Wear chemical resistant gloves to prevent skin contact. Eye Protection Equipment: Wear safety glasses or splash goggles to prevent eye contact. Skin and Body Protection: Wear suitable protective clothing. Respiration/Ventilation Protection Requirements: Provide good ventilation. Ingestion Protection Requirements: Do not eat, drink or smoke while handling. Wash hands with soap and water after handling. Launder all clothing and foot wear before re-use. 9. Physical And Chemical Properties: 9.1 Information of basic chemical and physical properties Physical Form: thin liquid Color: clear red Odor: typical oily Odor Threshold: not available pH: not applicable – oil based product Melting Point/Freeze Point: -51⁰C (-60⁰F) Initial Boiling Point: not available Flash Point (Seta Closed Cup): 53⁰C (128⁰F) Flammability Limits: Explosive Limits: Upper: not available Lower: not available Evaporation Rate: not available Flammability Solid/Gas: not applicable Vapor Pressure: not available Vapor Density: not available Specific Gravity: 0.876 Solubility in Water: insoluble Auto Ignition Temperature: not available Partition coefficient (n/octonol/water): not available Viscosity (Kinimatic @ 100⁰C): 2.0 – 3.0 cSt 9. 2 Other information % NVM by Weight: 75.0% % VOC Content (California): 24.92% 10. Stability and Reactivity: 10.1 Reactivity Does not react under normal conditions 10.2 Chemical stability Stable Page 199 of 377 Page 199 of 377 Page 199 of 377 Page 199 of 377 ---PAGE BREAK--- 10.3 Possibility of hazardous reactions Does not react under normal conditions 10.4 Conditions to avoid Heat and incompatible materials 10.5 Incompatible materials Strong oxidizers such as bleach and peroxides 10.6 Hazardous decomposition products CO2, CO and hydrocarbons 11. Toxicological Information: 11.1 Information on Toxicological effects Marvel Mystery Oil LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg LC50 – Inhalation Rat >20 mg/L (4 hr) Petroleum Distillates Hydrotreated Heavy Naphthenic (64742-52-5) LD50 – Oral Rat >5000 mg/Kg LD50 – Dermal Rabbit >5000 mg/Kg LC50 – Inhalation Rat >5 mg/L (4 hr) Tricresyl Phosphate (1330-78-5) LD50 – Oral Rat 3000 mg/Kg o-Dichlorobenzene (95-50-1) LD50 – Oral Rat 500 mg/Kg LD50 – Dermal Rabbit >10000 mg/Kg LC50 – Inhalation Rat 8.15 mg/L (4 hr) p-Dichlorobenzene (106-46-7) LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg Skin corrosion/irritation Causes skin irritation Serious eye damage/irritation Based on available data, classification data are not met Respiratory or skin sensitization Based on available data, classification data are not met Germ cell mutagenicity Based on available data, classification data are not met Carcinogenicity Based on available data, classification data are not met o-Dichlorobenzene (95-50-1) IARC Group 3 – Not Classified p-dichlorobenzene (106-46-7) IARC Group 2B – Possible carcinogen to humans. NTP 1-Evidence of Carcinogenicity 3, Reasonably anticipated to be a human Carcinogen Reproductive toxicity Suspected of damaging fertility of un-born child Specific target organs – single exposure Based on available data, classification data are not met Specific target organs – repeated exposure Based on available data, classification data are not met Page 200 of 377 Page 200 of 377 Page 200 of 377 Page 200 of 377 ---PAGE BREAK--- Aspiration hazard May be fatal if swallowed and enters air ways. after inhalation May cause respiratory tract irritation. Vapors may cause drowsiness and dizziness. after skin contact Cause skin irritation. may include redness, edema, drying, defatting, and cracking of skin. after eye contact May cause temporary eye irritation. may include discomfort or pain, excess blinking and tearing, with redness and swelling. after ingestion May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. 12. Ecological Information: 12.1 Toxicity Not recommended for release into aquatic systems without treatment 12.2 Persistence and degradability Not established 12.3 Bioaccumulative potential Not established 12.4 Mobility in soil Not established 12.5 Other adverse effects None known 13. Disposal Considerations: 13.1 Waste treatment methods RCRA Hazardous Waste: Regulated as a hazardous waste (D-001 Ignitable). Waste Disposal Method: Dispose of in accordance with local, state and federal regulations Waste Disposal Vessel: Metal drums are recommended. 14. Transportation Information: 14.1 UN number 1268 14.2 UN Proper shipping name Petroleum Distillate n.o.s. 14.3 Transport Hazard class 3 14.4 Packaging group III 14.5 Marine Pollutant No 14.6 Transportation in Bulk Not applicable Page 201 of 377 Page 201 of 377 Page 201 of 377 Page 201 of 377 ---PAGE BREAK--- 14.7 Special precautions Use limited quantities 15. Regulatory Information: 15.1 US Federal Regulations TSCA Status: All ingredients are commercially available and listed by the manufacturer under TSCA. 15.2 Foreign Regulations Canadian Status: All materials contained in this product are listed on the Canadian Domestic Substance List (DSL). Consult Turtle Wax, Inc. regarding status of ingredients. European Union: All materials contained in this product are listed on EINECS. AICS: All materials are registered for AICS (Australia) 15.3 State Regulations State Regulatory Information: The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements, contact the appropriate agency in your state. California Prop 65: CAS Number Concentration State Code p-Dichlorobenzene (106-46-7) <0.1% Cancer 15.4 HIMS & NFPA Classifications HIMS Classification: Health 2 Flammability 2 Reactivity 0 NFPA Classification: Health 2 Flammability 2 Reactivity 0 15.5 Discontinued SKU’s All discontinued SKU’s used this same formula. MM080, MM085, MM85R, MM086, MM088R, MM089 16. Other Information: Reason For Issue Conversion to OSHA GHS SDS Format Prepared By James Heidel Preparer’s Title Technical Director, R&D SDS Administrator Jean Mayszak - Technical Compliance Manager, R&D Page 202 of 377 Page 202 of 377 Page 202 of 377 Page 202 of 377 ---PAGE BREAK--- Approval Date March 10, 2015 Supersedes Date December 27, 2012 Revision Number #11 This information is, to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy oneself as to the suitableness and completeness of such information for their own particular use. Page 203 of 377 Page 203 of 377 Page 203 of 377 Page 203 of 377 ---PAGE BREAK--- Page 204 of 377 Page 204 of 377 Page 204 of 377 Page 204 of 377 ---PAGE BREAK--- Page 205 of 377 Page 205 of 377 Page 205 of 377 Page 205 of 377 ---PAGE BREAK--- Page 206 of 377 Page 206 of 377 Page 206 of 377 Page 206 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBILGREASE XHP 462 Product Description: Base Oil and Additives Product Code: 2015A0202527, 642538-00, 97AB14 Intended Use: Grease COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77253 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary Page 207 of 377 Page 207 of 377 Page 207 of 377 Page 207 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 2 of 10 from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes BENZENAMINE, N-PHENYL-, REACTION PRODUCTS WITH 68411-46-1 1 - < 5% H402, H412 ZINC DIALKYL DITHIOPHOSPHATE 68457-79-4 1 - < 2.5% H315, H318, H401, H411 ZINC DINONYLNAPHTHALENE SULFONATE 28016-00-4 0.1 - < 1% H315, H319(2A), H317 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Page 208 of 377 Page 208 of 377 Page 208 of 377 Page 208 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 3 of 10 Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Incomplete combustion products, Smoke, Fume, Oxides of carbon, Sulfur oxides, Aldehydes FLAMMABILITY PROPERTIES Flash Point [Method]: >294°C (561°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas. Page 209 of 377 Page 209 of 377 Page 209 of 377 Page 209 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 4 of 10 SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Page 210 of 377 Page 210 of 377 Page 210 of 377 Page 210 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 5 of 10 Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Solid Form: Semi-fluid Color: Blue Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.9 Flammability (Solid, Gas): N/D Flash Point [Method]: >294°C (561°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 460 cSt (460 mm2/sec) at 40 °C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material. Page 211 of 377 Page 211 of 377 Page 211 of 377 Page 211 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 6 of 10 SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Page 212 of 377 Page 212 of 377 Page 212 of 377 Page 212 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 7 of 10 Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Middle distillates: Carcinogenic in animal tests. Lifetime skin painting tests produced tumors, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations In Vitro. Inhalation of vapors did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. Page 213 of 377 Page 213 of 377 Page 213 of 377 Page 213 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 8 of 10 SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, KECI, PICCS, TSCA Special Cases: Page 214 of 377 Page 214 of 377 Page 214 of 377 Page 214 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 9 of 10 Inventory Status ENCS Restrictions Apply EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DIALKYL DITHIOPHOSPHATE 68457-79-4 1 - < 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations HYDROTREATED RESIDUAL OIL 64742-57-0 17, 18 ZINC DIALKYL DITHIOPHOSPHATE 68457-79-4 13, 15, 17, 19 ZINC DINONYLNAPHTHALENE SULFONATE 28016-00-4 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 Page 215 of 377 Page 215 of 377 Page 215 of 377 Page 215 of 377 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 Revision Date: 05 Jun 2015 Page 10 of 10 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 7049658XUS (1009426) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 216 of 377 Page 216 of 377 Page 216 of 377 Page 216 of 377 ---PAGE BREAK--- Page 217 of 377 Page 217 of 377 Page 217 of 377 Page 217 of 377 ---PAGE BREAK--- Page 218 of 377 Page 218 of 377 Page 218 of 377 Page 218 of 377 ---PAGE BREAK--- Page 219 of 377 Page 219 of 377 Page 219 of 377 Page 219 of 377 ---PAGE BREAK--- Page 220 of 377 Page 220 of 377 Page 220 of 377 Page 220 of 377 ---PAGE BREAK--- Page 221 of 377 Page 221 of 377 Page 221 of 377 Page 221 of 377 ---PAGE BREAK--- Safety Data Sheet: Multi-Purpose Automatic Transmission Fluid Revision Date: June 19, 2015 SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: Multi-Purpose Automatic Transmission Fluid Product Description: Base Oil and Additives Intended Use: Automatic transmission fluid COMPANY IDENTIFICATION Supplier: Beacon Lubricants P.O Box 754 Edinboro, PA 16412 Emergency Telephone: 1-[PHONE REDACTED] – Beacon Lubricants, Inc. Emergency Telephone: 1-[PHONE REDACTED] (24 hours) – Chemtrec approval SECTION 2 HAZARDS IDENTIFICATION This material is hazardous according to regulatory guidelines (M)SDS Section 15) CLASSIFICATION: Skin Sensitizer: Category 1 LABEL: Pictogram: Signal Word: Warning Hazard Statements: H317: May cause allergic skin reaction. Precautionary Statements: P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P103: Read label before use. P261: Avoid Page 222 of 377 Page 222 of 377 Page 222 of 377 Page 222 of 377 ---PAGE BREAK--- breathing mist/vapors. P272: Contaminated work clothing should not be allowed out of the work place. P273: Avoid release to the environment. P280: Wear protective gloves. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P333 + P313: If skin irritation or rash occurs: Get medical advice/attention. P501: Dispose of contents and container in accordance with local regulations. Contains: BIS(2-HYDROXTETHYL) TALLOW AMINE Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1900. 1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 2 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 2 Flammability: 1 Reactivity: 0 Note: This material should not be used for any other purpose than the indented use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Page 223 of 377 Page 223 of 377 Page 223 of 377 Page 223 of 377 ---PAGE BREAK--- SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS # Concentration* GHS Hazard Code 1H-IMIDAZOLE-1- ETHANOL, 2- (HEPTADECENYL)- 4,5,DIHYDRO- 27136-73-8 0.1 - < 1 % H302, H314(1B), H400(M factor H410(M factor 1) 2-PROPANOL, 1-(TERT- 67124-09-8 1 – 2.5 % H317, H400 (M factor H410(M factor 1) BENZENAMINE, AR- NONYL-N-(NONYL PHENYL)- 36878-20-3 1 - < 5% H413 BIS(2- HYDROXYETHYL)TALLOW AMINE 61791-44-4 0.1 - < 0.25% H302, H317, H330(2), H314(1B), H400(M factor 10) DIPHENLAMINE 122-39-4 0.1 - < 1 % H301, H311, H331, H373, H400(M factor H410(M factor 1) HYDROTREATED LIGHT PARAFFINIC DISTILLATES, PETROLEUM 64742-55-8 10 - < 20 % H304 SOLVENT DEWAXED LIGHT PARAFFINC DISTILLATE (PETROLEUM) 64742-56-9 70 - < 80 % H304 *All Concentrations are percent by weight unless material is a gas. Gas concentration are in the percent by volume. Page 224 of 377 Page 224 of 377 Page 224 of 377 Page 224 of 377 ---PAGE BREAK--- As per paragraph of 29 CFR 1910.1200, formulation is a considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial form high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extend of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self- contained breathing apparatus (SCBA). Use water supply to cool fire exposed Page 225 of 377 Page 225 of 377 Page 225 of 377 Page 225 of 377 ---PAGE BREAK--- surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, sulfur oxides, Oxides of carbon, Smoke, Fume, Incomplete combustion products. FLAMMABILITY PROPERTIES Flash Point [Method]: >177°C (351°F) [ASTEM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Auto ignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for firefighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Service. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respiration with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with Page 226 of 377 Page 226 of 377 Page 226 of 377 Page 226 of 377 ---PAGE BREAK--- suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and ground may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE: The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabeled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Page 227 of 377 Page 227 of 377 Page 227 of 377 Page 227 of 377 ---PAGE BREAK--- Exposure limits/standards (Note: Exposure limits are no additive) Substance Name Form Limit / Standard NOTE Source DIPHENYLAMINE TWA 10 mg/m3 N/A ACGIH HYDROTREATED LIGHT PARAFFINIC DISTILLAES, PETROLEUM Mist TWA 5 mg/m3 N/A OSHA Z1 HYDROTREATED LIGHT PARAFFINIC DISTILLAES, PETROLEUM Inhalable fraction. TWA 5 mg/m3 N/A ACGIH HYDROTREATED LIGHT PARAFFINIC DISTILLAES, PETROLEUM Mist TWA 5 mg/m3 N/A ACGIH SOLVENT DEWAXED LIGHT PARAFFINIC DISTILLATE (PETROLEUM) Mist TWA 5 mg/m3 N/A OSHA Z1 SOLVENT DEWAXED LIGHT PARAFFINIC DISTILLATE (PETROLEUM) Inhalable fraction TWA 5 mg/m3 N/A ACGIH SOLVENT DEWAXED LIGHT PARAFFINIC DISTILLATE (PETROLEUM) Mist TWA 5 mg/m3 N/A ACGIH Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5mg/m3 - ACGIH TLV (inhalable fraction), 5 mg/m3 - OHSA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. Page 228 of 377 Page 228 of 377 Page 228 of 377 Page 228 of 377 ---PAGE BREAK--- ENGINEERING CONTROLS The level of protection and toes of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information of the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a levee which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filters capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacture for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on Page 229 of 377 Page 229 of 377 Page 229 of 377 Page 229 of 377 ---PAGE BREAK--- published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Environmental Controls Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Red Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15°C): 0.863 Flammability (Solid, Gas): N/A Flash Point [Method]: >177°C (351°F) [ASTM D-02] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Auto ignition Temperature: N/D Boiling Point / Range: >316°C (600°F) Decomposition Temperature: N/D Vapor Density (Air = >2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): >3.5 Solubility in Water: Negligible Page 230 of 377 Page 230 of 377 Page 230 of 377 Page 230 of 377 ---PAGE BREAK--- Viscosity: 34 cSt (34 mm2/sec) at 40° I 7.2 cSt (7.2 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -34°C (-30°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on the assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point date for material Minimally Toxic. Based on assessment of components. Skin Page 231 of 377 Page 231 of 377 Page 231 of 377 Page 231 of 377 ---PAGE BREAK--- Acute Toxicity: No end point date for material Minimally Toxic. Based on assessment of components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material May cause mild, short-lasting discomfort to eyes. Based on assessment of components. Sensitization Respiratory Sensitization: No end point data for material Not expected to be a respiratory sensitizer Skin Sensitization: No end point date for material Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Date available Not expected to be an aspiration hazard. Based on phsico-chemical properties of the materials. Germ Cell Mutagenicity: No end point data for material Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material Not expected to be a reproductive toxicant. Based on the assessment of the components Lactation: No end point data for material Not expected to cause harm to breast-fed children Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material Not expected to cause organ damage from a single exposure Repeated Exposure: No end point data for material Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. TOXICITY FOR SUBSTANCES NAME ACUTE TOXICITY 2, 6-DI-TERT-BUTYL-P-CRESOL Oral Lethality: LD50 0.89 g/kg (Rat) Page 232 of 377 Page 232 of 377 Page 232 of 377 Page 232 of 377 ---PAGE BREAK--- OTHER INFORMATION Contains: Base oil severely refined. Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material — Not expected to be harmful to aquatic organisms. MOBILITY Base oil component— Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component— Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component — Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bio-concentration or limit bioavailability. OTHER ECOLOGICAL INFORMATION VOC: 1.1 G/L [ASTM E1868-10] SECTION 13 DISPOSAL CONSIDERATIONS Page 233 of 377 Page 233 of 377 Page 233 of 377 Page 233 of 377 ---PAGE BREAK--- Disposal recommendations based on material as supplied. Disposal must be in accordance current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning: Empty Container Warning (where applicable): Empty containers may contain reside and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJUST OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport Page 234 of 377 Page 234 of 377 Page 234 of 377 Page 234 of 377 ---PAGE BREAK--- SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is no considered hazardous in accordance with OHSA HazCom 2012, 29, CFR 1910. 1200. Listed or exempt form listing/notification on the following chemical inventories: AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazards substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of Sara 313 Toxic Release Program. The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations DIPHENYLAMINE 122-39-4 18 HYDROTREATED LIGHT PARAFFINIC DISILLATES, PETROLEUM 64742-55-8 1, 4, 17, 18 --REGULATORY LISTS SEARCHED— 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P6 CARC 15 = MI 293 SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H301: Toxic if swallowed; Acute Tox Oral, Cat 3 H302: Harmful if swallowed; Acute Tox Oral, Cat 4 Page 235 of 377 Page 235 of 377 Page 235 of 377 Page 235 of 377 ---PAGE BREAK--- H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 H311: Toxic in contact with skin; Acute Tox Dermal, Cat 3 H314(1B): Causes severe skin burns and eye damage; Skin Corr/Irriation, Cat 1B H317: May cause allergic skin reaction; Skin Sensitization, Cat 1 H330(2): Fatal if inhaled; Acute Tox Inh, Cat 2 H331: Toxic if inhaled; Acute Tox Inh, Cat 3 H373: May cause damage to organs through prolonged or repeated exposure; Target Organ, Repeated, Cat 2 H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 H413: May cause long lasting harmful effects to aquatic life; Chronic Env Tox, Cat 4 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementations of GHS requirements. The information and recommendations contained herein are, to the best of Beacon Lubricants knowledge and belief, accurate and reliable as of the date issued. You can contact Beacon Lubricants to insure that this document is the most current available from Beacon Lubricants. The information and recommendations are offered for the user’s consideration and examination. It is the user’s responsibility to satisfy itself that the product is suitable for intended use. If the buyer repackages this product, it is the user’s responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alternation of this document is strictly prohibited. Expect to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. Page 236 of 377 Page 236 of 377 Page 236 of 377 Page 236 of 377 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Oatey Purple Primer- NSF Listed for PVC and CPVC Product identifier Other means of identification 1402E Product code Part Numbers: 30755(TV), 30756(TV), 30757(TV), 30758, 30759, 30927 Synonyms Joining PVC Pipes Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH 44135 Telephone [PHONE REDACTED] E-mail [EMAIL REDACTED] Transport Emergency Chemtrec 1-[PHONE REDACTED] (Outside the US 1-[PHONE REDACTED]) Emergency First Aid 1-[PHONE REDACTED] Contact person MSDS Coordinator 2. Hazard(s) identification Category 2 Flammable liquids Physical hazards Category 4 Acute toxicity, oral Health hazards Category 2 Skin corrosion/irritation Category 2A Serious eye damage/eye irritation Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects Specific target organ toxicity, single exposure Category 1 Aspiration hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 1 / 10 Page 237 of 377 Page 237 of 377 Page 237 of 377 Page 237 of 377 ---PAGE BREAK--- Storage Store in a well-ventilated place. Keep container closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures 67-64-1 25-40 Acetone CAS number % Chemical name 108-94-1 25-40 Cyclohexanone 109-99-9 15-30 Furan, Tetrahydro- 78-93-3 15-30 Methyl ethyl ketone *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Eye contact Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Ingestion Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Most important acute and delayed Provide general supportive measures and treat Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Specific methods Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. General fire hazards Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 2 / 10 Page 238 of 377 Page 238 of 377 Page 238 of 377 Page 238 of 377 ---PAGE BREAK--- 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Components PEL 2400 mg/m3 Acetone (CAS 67-64-1) 1000 ppm PEL 200 mg/m3 Cyclohexanone (CAS 108-94-1) 50 ppm PEL 590 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) 200 ppm PEL 590 mg/m3 Methyl ethyl ketone (CAS 78-93-3) 200 ppm US. ACGIH Threshold Limit Values Value Type Components STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm STEL 50 ppm Cyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 100 ppm Furan, Tetrahydro- (CAS 109-99-9) Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 3 / 10 Page 239 of 377 Page 239 of 377 Page 239 of 377 Page 239 of 377 ---PAGE BREAK--- US. ACGIH Threshold Limit Values Value Type Components TWA 50 ppm STEL 300 ppm Methyl ethyl ketone (CAS 78-93-3) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Type Components TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm TWA 100 mg/m3 Cyclohexanone (CAS 108-94-1) 25 ppm STEL 735 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) 250 ppm TWA 590 mg/m3 200 ppm STEL 885 mg/m3 Methyl ethyl ketone (CAS 78-93-3) 300 ppm TWA 590 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices Value Sampling Time Determinant Specimen Components 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) 80 mg/l 1,2-Cyclohexan ediol, with hydrolysis Urine * Cyclohexanone (CAS 108-94-1) 8 mg/l Cyclohexanol, with hydrolysis Urine * 2 mg/l Tetrahydrofura n Urine * Furan, Tetrahydro- (CAS 109-99-9) 2 mg/l MEK Urine * Methyl ethyl ketone (CAS 78-93-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1) Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Face shield is recommended. Wear safety glasses with side shields (or goggles). Eye/face protection Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 4 / 10 Page 240 of 377 Page 240 of 377 Page 240 of 377 Page 240 of 377 ---PAGE BREAK--- Skin protection Wear appropriate chemical resistant gloves. Hand protection Wear appropriate chemical resistant clothing. Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid. Physical state Translucent liquid. Form Purple Color Solvent. Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 Flash point 14.0 - 23.0 °F (-10.0 - -5.0 Evaporation rate 5.5 - 8 Not available. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 1.8 Flammability limit - upper 11.8 Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.84 0.02 @20°C Solubility(ies) Solubility (water) Negligible Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Bulk density 7 lb/gal VOC (Weight 505 g/l SQACMD Method 24 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. Incompatible materials Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 5 / 10 Page 241 of 377 Page 241 of 377 Page 241 of 377 Page 241 of 377 ---PAGE BREAK--- No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Test Results Components Species Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute 20 ml/kg LC50 Rat Inhalation 50 mg/l, 8 Hours LD50 Rat Oral 5800 mg/kg Cyclohexanone (CAS 108-94-1) LD50 Rabbit Dermal Acute 948 mg/kg LC50 Rat Inhalation 8000 ppm, 4 hours LD50 Rat Oral 1540 mg/kg * Estimates for product may be based on additional component data not shown. Causes skin irritation. Skin corrosion/irritation Causes serious eye irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not available. This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. IARC Monographs. Overall Evaluation of Carcinogenicity Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 6 / 10 Page 242 of 377 Page 242 of 377 Page 242 of 377 Page 242 of 377 ---PAGE BREAK--- OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test Results Species Acetone (CAS 67-64-1) Aquatic LC50 Fish > 100 mg/l, 96 hours Fathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Cyclohexanone (CAS 108-94-1) Aquatic LC50 Fish 481 - 578 mg/l, 96 hours Fathead minnow (Pimephales promelas) No data is available on the degradability of this product. Persistence and degradability No data available. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1) -0.24 Cyclohexanone (CAS 108-94-1) 0.81 Furan, Tetrahydro- (CAS 109-99-9) 0.46 Methyl ethyl ketone (CAS 78-93-3) 0.29 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging 14. Transport information DOT UN1993 UN number Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 26274 LBS, Acetone RQ = 13130 LBS) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk 3 Label(s) II Packing group Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 7 / 10 Page 243 of 377 Page 243 of 377 Page 243 of 377 Page 243 of 377 ---PAGE BREAK--- Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IB2, T7, TP1, TP8, TP28 Special provisions 150 Packaging exceptions 202 Packaging non bulk 242 Packaging bulk IATA UN1993 UN number Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk II Packing group No. Environmental hazards 3H ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IMDG UN1993 UN number FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk II Packing group No. Marine pollutant Environmental hazards F-E, S-E EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not available. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) LISTED Cyclohexanone (CAS 108-94-1) LISTED Furan, Tetrahydro- (CAS 109-99-9) LISTED Methyl ethyl ketone (CAS 78-93-3) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 8 / 10 Page 244 of 377 Page 244 of 377 Page 244 of 377 Page 244 of 377 ---PAGE BREAK--- Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Methyl ethyl ketone (CAS 78-93-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 US state regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Domestic Substances List (DSL) Yes Canada *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory Yes United States & Puerto Rico 16. Other information, including date of preparation or last revision 27-May-2015 Issue date - Revision date Version # 01 Health: 2 Flammability: 3 Physical hazard: 0 HMIS® ratings Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 9 / 10 Page 245 of 377 Page 245 of 377 Page 245 of 377 Page 245 of 377 ---PAGE BREAK--- NFPA ratings 0 2 3 The information in the sheet was written based on the best knowledge and experience currently available. Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. Disclaimer Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 10 / 10 Page 246 of 377 Page 246 of 377 Page 246 of 377 Page 246 of 377 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 1 of 6 Material Safety Data Sheet NFPA HMIS Health Hazard 0 Fire Hazard 1 Reactivity 0 Issuing Date 19-July-2010 Revision Date 18-Jan-2012 Revision Number 2 1. PRODUCT AND COMPANY IDENTIFICATION Product Name PARTS MASTER PREMIUM POWER STEERING FLUID Product Code F-79 Recommended Use Manufactured by: Omni Specialty Packaging 10399 S. Hwy 1 Shreveport, LA 71115 Phone: 1 (318) 524-1100 Emergency Telephone Number CHEMTREC 1 (800) 424-9300 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Clear Liquid Physical State Liquid Odor Mild petroleum odor Potential Health Effects Principal Routes of Exposure Eye contact, Skin contact, Inhalation, Ingestion Acute Toxicity Eyes Eye contact may result in slight irritation and redness.. Skin Minimally irritating upon direct contact. Inhalation Inhalation of oil mist or fumes can cause irritation of the nose, throat and upper respiratory tract Ingestion Do not ingest. May cause nausea, vomiting/diarrhea. Chronic Effects Prolonged exposure may cause chronic effects. 1 0 0 Page 247 of 377 Page 247 of 377 Page 247 of 377 Page 247 of 377 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 2 of 6 Aggravated Medical Conditions Personnel with pre-existing skin disorders should avoid contact with this product. Environmental Hazard See Section 12 for additional Ecological Information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Mixture Chemical Name CAS-No Weight % Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 85-100 Viscosity Index Improver Lubricant Mixture 5-15 Additive Package N/A 0-10 4. FIRST AID MEASURES Eye Contact Flush with large amounts of water for 15 minutes. Get medical attention if eye irritation develops or persists. If material is hot, treat for thermal burns and take victim to the hospital immediately. Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removing all contaminated clothing and shoes. Get medical attention immediately if skin discoloration occurs. Inhalation If affected, remove individual to fresh air. If not breathing, give mouth-to-mouth resuscitation. Get medical attention if develop or persist. Ingestion CALL PHYSICIAN IMMEDIATELY. Never give anything by mouth to an unconscious person. Don’t induce vomiting except at the instructions of the physician. Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Flammable Properties Not flammable. Flash Point 380°F Suitable Extinguishing Media Water Fog. Carbon dioxide (CO2). Foam. Dry chemical. Unsuitable Extinguishing Media Water stream may spread fire. Hazardous Combustion Products Decomposition and combustion products may include smoke, carbon dioxide, carbon monoxide, and other low molecular weight hydrocarbons. Explosion Data Sensitivity to Mechanical Impact Not sensitive. Sensitivity to Static Discharge Not sensitive. Protective Equipment and Precautions for Firefighters Wear positive pressure self-contained breathing apparatus (SCBA). Use water to cool containers exposed to flames. Structural firefighters’ protective clothing will only provide limited protection. Mist or sprays may be flammable below the product normal flash point. NFPA Health Hazard 0 Flammability 1 Reactivity 0 Physical and Chemical Hazards - Page 248 of 377 Page 248 of 377 Page 248 of 377 Page 248 of 377 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 3 of 6 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Avoid contact with skin, eyes, and clothing. Ensure adequate ventilation. Methods for Containment Dike far ahead of liquid spill for later disposal. Methods for Cleaning Up Pick up free liquid for recycle and/or disposal. Residual liquid and/or solid can be absorbed on inert material. Evacuation Procedures Large Spill Consider initial downwind evacuate for at least 300 meters (1000 feet). Fire If tank, rail car or tank car is involved in a fire, isolate for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. Reporting Requirements Spills that enter a water body must be reported immediately to the USEPA’s National Response Center at (800)424-8802. Check with your local and state regulators regarding their reporting requirements. 7. HANDLING AND STORAGE Handling Do not pressure, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. See NFPA 30 and OSHA 1910.106 – flammable and combustible liquids. Storage Store away from heat, sparks, open flame, or strong oxidizing agents in closed and properly labeled containers. Empty containers retain product residue (liquid, and/or vapor) and can be dangerous 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 5 mg/m³ mist 5 mg/m³ mist None listed Viscosity Index improver Lubricant 5 mg/m³ mist 5 mg/m³ mist None listed Engineering Measures Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended limits. Personal Protective Equipment Eye/Face Protection Safety glasses or face shield where splashing is possible. Full face-shield to be worn during emergencies. Skin and Body Protection As needed to prevent repeated skin contact. Solvent resistant gloves should be used if needed. Respiratory Protection Not normally needed. During emergencies wear respirator. Hygiene Measures Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product. Page 249 of 377 Page 249 of 377 Page 249 of 377 Page 249 of 377 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 4 of 6 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Clear Liquid Odor Mild petroleum odor Physical State Liquid pH N/A Flash Point 380°F Autoignition Temperature 600°F Boiling Point/Range >500°F Freezing Point <-40°C Explosion Limits N/A Flammability Limits in Air N/A Specific Gravity 0.85 Solubility Negligible Evaporation Rate N/A Vapor Pressure N/A Vapor Density Not Determine Density N/A 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Incompatible Products Open Flame and strong oxidizing agents. Conditions to Avoid Heat, flames, and sparks. Hazardous Decomposition Products Decomposition and combustion products may include hydrogen sulfide, alkyl mercaptans, sulfides, oxides or sulfur, oxides of : phosphorous, calcium and zinc; aldehydes, carbon monoxide and carbon dioxide. Hazardous Polymerization None under normal processing. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information Test on similar materials show a low order of acute oral and dermal toxicity. Acute Oral Effects Test on similar materials indicates low order of acute toxicity. Acute Inhalation Effects Low acute toxicity expected on inhalation. Skin Effects Practically non-toxic if absorbed. Other similar highly refined products have not shown skin tumors in mouse skin painting studies. Eye Irritation Minimal irritation on contact. Eye irritation or practically non-irritating base on similar products. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 Rat >2000 mg/kg Rabbit >2000 mg/kg Rat > 2.18 mg/L 4 hours Chronic Toxicity Chronic Toxicity Prolonged exposure may cause chronic effects. Carcinogenicity Not considered a potential carcinogen base on IP346 DMSO of less than 3.0 wt% Target Organ Effects Respiratory system, Eyes, Skin, Genotoxicity This product is considered non-mutagenic and has negative potential for tumor development based on from Modified Ames Assay, with Mutagenic Index of less than 1.0. Page 250 of 377 Page 250 of 377 Page 250 of 377 Page 250 of 377 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 5 of 6 12. ECOLOGICAL INFORMATION Ecotoxicity This product is not toxic to fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. Product may be moderately toxic to amphibians by preventing dermal respiration. This product may cause gastrointestinal distress to birds and mammals through ingestion during pelage grooming. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with local regulations. Keep this product out of sewers and waterways. Contaminated Packaging Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT Not regulated IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION International Inventories TSCA DSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 Present X 265-169-7 X X X X X U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act If spilled into navigable waters it is reportable to National Response Center, [PHONE REDACTED]. Reportable Quantity = Oil Sheen present on navigable water surface. (40 CFR 116; 401.15) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. CERCLA Page 251 of 377 Page 251 of 377 Page 251 of 377 Page 251 of 377 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 6 of 6 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. Florida No listed ingredients are present Massachusetts RTK No listed ingredients are present Minnesota RTK No listed ingredients are present New Jersey RTK Lists petroleum oil, but this product does not contain hazardous ingredients. RTK Lists petroleum oil, but this product does not contain hazardous ingredients greater than Illinois DOL TSL No listed ingredients are present International Regulations Mexico – Grade No information available. Canada Not listed on the Canadian Controlled Product Ingredient Disclosure and is compliant with Controlled Products Regulation CONEG Metals Since cadmium, chromium, lead and mercury are not detectable and it does not exceed 100ppm total in this product, it is compliant with CONEG Metals regulation. EEC (Europe) This product is not known to be a dangerous good internationally. R-Phrases R45: May Cause Cancer S-Phrases S53: Avoid Exposure S45 Hazard Label None Danger Symbol None This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION Prepared By Juan Parker Issuing Date 28-June-2010 Revision Date 31-Jan-2012 Revision Note Not applicable Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 252 of 377 Page 252 of 377 Page 252 of 377 Page 252 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 1 Initial Preparation Date: 7/19/1999 Last Revision Date: 10/23/2014 Effective Date: 10/29/2014 MATERIAL SAFETY DATA SHEET PRODUCT IDENTITY: POLAR WINDSHIELD WASH & DEICER FLUID -30F 1. CHEMICAL PRODUCT & COMPANY INFORMATION OLD WORLD INDUSTRIES, LLC 4065 COMMERCIAL AVENUE ILLINOIS 60062 PHONE: [PHONE REDACTED] EMERGENCY PHONE: 1-[PHONE REDACTED] (CHEMTREC) 2. COMPOSITION / INFORMATION ON INGREDIENTS 8-Hour Time Weighted Vapor Pressure Material CAS# % by Wt. Avg. (TWA) mm Hg @ Temp Methanol 67-56-1 35 200 ppm (260 Mg/M3) 96.1 20 C Propylene Glycol 57-55-6 <5 Not established 0.8 20 C Additives N/A <1 N/A N/A 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Slight odor. May be fatal if swallowed. Vapors can cause eye irritation. LD50 Rat (Oral): 5,628 mg/kg (Methanol) LD50 Rabbit (Skin): 20 g/kg (Methanol) Carcinogency: No National Toxicology Program: No International Agency for Research on Cancer: No OSHA Regulated: Yes HAZARD RATING SYSTEM HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: A KEY: 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe A - Safety glasses POTENTIAL HEALTH EFFECTS Health Hazards (Acute and Chronic): Acute: Acute methanol intoxication is manifested initially by signs of narcosis. This is followed by a latent period Page 253 of 377 Page 253 of 377 Page 253 of 377 Page 253 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 2 in which formic acid accumulates in the body causing metabolic acidosis. Severe abdominal, leg, and back pain occur and visual degeneration can lead to blindness. 1. Humans – Ingestion of 80 to 150 mL of methanol is usually fatal to humans (HSDB 1994). One worker died from exposure to vapor ranging from 4,000 to 13,000 ppm over 12 hours (ACGIH 1991). The concentration of 4,000 ppm is roughly equivalent to a total of 1,140 mg/kg over the 12-hour period (see end note Poisoning by nonlethal doses can be described in three stages: narcotic stage similar to ethanol; latent period of 10-15 hours; visual disturbances and central nervous system lesions (Rowe and McCollister 1981). Visual disturbances can lead to blindness due to edema of the retina and atrophy of the optic nerve head (HSDB 1994). Third-stage CNS lesions include headache, dizziness, abdominal, back, and leg pain, delirium that can lead to coma, and nausea (HSDB 1994). Formic acid production causes severe metabolic acidosis (Rowe and McCollister 1981). 2. Animals – Oral LD50 values for methanol is animals are 0.4 g/kg in the mouse, 6.2 to 13 g/kg in the rat, 14.4 g/kg in the rabbit, and 2 to 7 g/kg in the monkey (Rowe and McCollister 1981). The LD50 for dermal application to rabbits is 20 mL/kg (approximately 16 g/kg) (Rowe and McCollister 1981). Dose-response data for inhalation vary with species, dose, and duration (8,800 ppm for 8 hours to 152,800 ppm for 94 minutes). of intoxication include incoordination, salivation, lethargy, narcosis, and death (Rowe and McCollister 1981). Sub-chronic/Chronic: Chronic exposure to methanol, either orally or by inhalation, causes headache, insomnia, gastrointestinal problems, and blindness in humans and hepatic and brain alterations in animals. EPA has derived an oral RfD (reference dose) (see end note 3) for methanol of 0.5 mg/kg/day, based on the absence of liver and brain effects in animals exposed by mouth to 500 mg/kg/day. 1. Humans – “Chronic” exposure to methanol vapors (no time or dose given) caused conjunctivitis, headache, giddiness, insomnia, gastric disturbances, and bilateral blindness (ACGIH 1991). Marked vision loss occurred in one worker exposed to 1,200 to 8,000 ppm vapor for 4 years (ACGIH 1991). 2. Animals – No effects were seen in rats given 1% (approximately 140 mg/kg/day) methanol in drinking water for 6 months (Rowe and McCollister 1981). Hepatic abnormalities (proteinic degeneration, altered RNA metabolism) occurred in rhesus monkeys given 3 to 6 g/kg for 3 to 20 weeks and in rats given 10, 100, or 500 mg/kg/day for one month (Rowe and McCollister 1981). Rabbits chronically fed methanol (no dose or time given) had increasing blood levels, brain and eye edema, and myelin thinning (HSDB 1994). Male and female rats were gavaged with 100, 500, or 2,500 mg/kg/day for 90 days (U.S. EPA 1994). Increased levels of SGPT and SAP as well as decreased brain weights were seen in both sexes at the highest dose; a no-observed-adverse effect level (NOAEL) for the study was 500 mg/kg/day. Based on these data, the U.S. EPA (1994) calculated a chronic RfD (see end note 4) for methanol of 0.5 mg/kg/day. No toxic effects were seen in dogs exposed by inhalation to either 10,000 ppm for 3 minutes, 3x/day, for 100 days or to 450 or 500 ppm, 8 hours/day for 379 days (Rowe and McCollister 1981). Ultrastructural changes were observed in the photoreceptor cells of rabbits exposed to 46.6 ppm for 6 months (Rowe and McCollister 1981). Rowe and McCollister (1981) concluded that the effects of combined oral and inhalation exposure appear to be additive. Rats exposed by inhalation to 16.8 ppm, 4 hours/day, for 6 months and administered 0.7 mg/kg/day orally had changes in blood morphology, oxidation-reduction processes, and liver function (Rowe and McCollister 1981). Carcinogenicity: No information was found on the carcinogenicity of methanol in the secondary sources searched. 1. Humans – No information was found in the secondary sources searched concerning the carcinogenicity of methanol to humans. 2. Animals – No information was found in the secondary sources searched concerning the carcinogenicity of methanol to animals. The NTP has assigned a project leader for methanol and the design of the study is in progress (NTP 1994). Page 254 of 377 Page 254 of 377 Page 254 of 377 Page 254 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 3 4. FIRST AID MEASURES Ensure physician has access to this MSDS. Routes of Entry: Inhalation, Skin, Ingestion Signs and of Exposure: Eye Contact: May cause eye irritation. Skin Contact: Frequent or prolonged contact may cause skin irritation experienced as burning, drying, cracking and redness. Inhalation: May cause nose and throat irritation. High concentrations may cause acute central nervous system depression characterized by headaches, dizziness, nausea and confusion. Skin Absorption Health Risks and of Exposure: Harmful quantities of Methyl Alcohol may affect eyes and central nervous system. Ingestion Health Risks and of Exposure: May cause nausea, abdominal pain, headache, shortness of breath, visual impairment and blindness. Severe poisoning can cause coma and death. Medical Conditions Generally Aggravated by Exposure: Ingestion of large amounts of Methyl Alcohol has been shown to damage organs including liver, kidney, pancreas, heart, lungs and brain. Although this rarely occurs, survivors of severe intoxication may suffer permanent neurological damage. Overexposure may aggravate pre-existing disorders of the eyes. People have died as a result of drinking large amounts of methanol. Drinking smaller, non-lethal amounts of methanol adversely affects the human nervous system. Effects range from headaches to incoordination similar to that associated with drunkenness. Delayed effects such as severe abdominal, leg, and back pain can follow the inebriation effects of methanol. Loss of vision and even blindness can also occur after exposure to amounts of methanol causing inebriation. These effects are not likely to occur at levels of methanol that are normally found in the environment. Human health effects associated with breathing or otherwise consuming smaller amounts of methanol over long periods of time are not known. Workers repeatedly exposed to methanol have experienced several adverse effects. Effects range from headaches to sleep disorders and gastrointestinal problems to optic nerve damage. Laboratory studies show that repeat exposure to large amounts of methanol in air or in drinking water cause similar adverse effects in animals. TREATMENT Eyes: Flush with large quantities of water for 15 minutes and seek medical attention. Skin: Remove contaminated clothing and wash contaminated skin with large amounts of soap and water. If irritation persists, get medical attention. Launder clothing before reuse. Inhalation: Remove to fresh air. If breathing has stopped, apply artificial respiration. If breathing is difficult, give oxygen provided a qualified operator is available. Get medical attention. Ingestion: If swallowed, Do Not induce vomiting. Drink a large amount of water, milk or sodium bicarbonate to dilute material in stomach. (Never give anything by mouth to an unconscious person.) Call Poison Control Center, hospital emergency room or physician immediately. Page 255 of 377 Page 255 of 377 Page 255 of 377 Page 255 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 4 Notes to Physician: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at blood hemodialysis. Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material: skin, lung (for example, asthma-like conditions), liver, kidney, central nervous system, pancreas, heart). Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. 5. FIRE FIGHTING MEASURES FIRE & EXPLOSION HAZARD DATA Flammable Properties: Flash Point: 86 F Method Used: ETA 1010 CC Flammability Limits: Percentage of vapor concentration at which methanol can ignite in presence of spark: LEL: 6.0% UEL: 36.0% Hazardous Combustion Products: Methanol Extinguishing Media: Foam, dry chemical, carbon dioxide or any Class B extinguishing agent. Water may be unsuitable as an extinguishing medium but helpful in keeping adjacent containers cool Fire Fighting Instructions: Use water spray to cool fire exposed containers. Water may be ineffective but may be used to cool exposed containers to prevent pressure buildup and possible auto-ignition or explosion when exposed to extreme heat. If water is used, fog nozzles are preferable. Unusual Fire and Explosion Hazards: Handle as flammable liquid. Vapors are heavier than air and may travel along the ground or may be moved by ventilation. Vapors form an explosive mixture in air between the upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Protective Equipment For Fire Fighters: Wear NIOSH approved self-contained breathing apparatus with full face piece and protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Small Spill: Absorb liquid on vermiculite, floor absorbent or other absorbent material. Large Spill: Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred. Page 256 of 377 Page 256 of 377 Page 256 of 377 Page 256 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 5 7. HANDLING AND STORAGE Do not swallow. Store in closed containers in a cool, dry, well-ventilated area. Keep away from sparks and open flame. Respiratory Protection: Use approved NIOSH respirator when TLV is exceeded. Ventilation: Provide sufficient ventilation to maintain exposure below TLV. Protective Gloves: Wear appropriate impermeable gloves. Eye Protection: Use chemical safety glasses, goggles and face shields for eye protection. Other Protective Clothing or Equipment: Long sleeves and apron are recommended. Work / Hygienic Practices: Avoid prolonged or repeated skin contact. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Eye Protection: Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative. Skin Protection: Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots. Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH/MSHA approved air supplied respiratory is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure. Engineering Controls: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s). Exposure Guidelines: Component: Methyl Alcohol (67-56-1) OSHA VPEL 200.000 ppm – TWA (skin) OSHA VPEL 250.000 ppm – STEL (skin) ACGIH TLV 200.000 ppm – TWA (skin) ACGIH TLV 250.000 ppm – STEL (skin) 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Range: 166 F - 194 F Specific Gravity (Water .94 @ 20 C Vapor Density (Air=1): Heavier than air Water Solubility: Soluble Appearance: Clear purple liquid Odor: Mild alcohol odor Evaporation Rate: Greater than n-butyl acetate Page 257 of 377 Page 257 of 377 Page 257 of 377 Page 257 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 6 10. STABILITY & REACTIVITY DATA Stability: Stable Conditions to Avoid: Ignition sources, such as heat, sparks and flames Incompatibility (Materials to Avoid): Strong acids and strong oxidizing agents Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide. Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations an act as an Hazardous Polymerization: Will not occur 11. TOXICOLOGICAL INFORMATION Mutagenicity (The Effects On Genetic Material): Genotoxicity: Methanol was negative for cell transformation in Syrian hamster embryo cells (clonal assay and viral enhanced), sister chromatid exchange in vitro, and for aneuploidy and chromosome aberrations in Neurospora crassa (GENETOX 1992). The micronucleus test and the assay for chromosome aberrations in mammalian were inconclusive (GENETOX 1992). Developmental/Reproductive Toxicity: No information was found on the developmental toxicity of methanol in humans. Methanol can cause adverse effects in the developing in rats at doses that cause overt maternal intoxication. 1. Humans – No information was found in the secondary sources searched regarding the developmental or reproductive toxicity of methanol to humans. However, one of the breakdown products of the artificial sweetener aspartame is methanol. Increased blood methanol levels did not lead to increased formic acid levels in women receiving up to 200 mg/kg aspartame (no other details reported) and no evidence of fetal risk was detected (HSDB 1994). 2. Animals – Rats were exposed by inhalation, 7 hours/day, to 5,000 or 10,000 ppm methanol on gestation days 1-19 or to 20,000 ppm on days 7-15. Maternal intoxication (unsteadiness) occurred at the highest dose and coincided with extra or rudimentary ribs and urinary or cardiovascular defects in the fetuses (ACGIH 1991). Male rats had significantly lowered testosterone levels after inhalation exposure to 200 ppm methanol for 6 weeks; at 10,000 ppm a change in luteinizing hormone was also observed (HSDB 1994). Neurotoxicity: Methanol causes central nervous system depression in humans and animals as well as degenerative changes in the brain and visual system. 1. Humans – Methanol causes narcosis similar to ethanol intoxication and nonlethal doses can lead to blindness. Autopsy of individuals after lethal doses revealed edema and hyperemia of the brain and degeneration of the ganglion cells of the retina (Rowe and McCollister 1981). 2. Animals – Acute methanol intoxication in animals causes CNS depression as observed by narcosis, incoordination, lethargy, drowsiness, and prostration (Rowe and McCollister 1981). Page 258 of 377 Page 258 of 377 Page 258 of 377 Page 258 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 7 Significant Data With Possible Relevance To Humans: Pharmacokinetics: 1. Absorption – Methanol is readily absorbed after oral, inhalation, or dermal exposure. Oral doses in humans of 71 to 84 mg/kg resulted in blood levels of 4.7 to 7.6 mg/100 mL of blood within 3 hours (Rowe and McCollister 1981). Inhalation of 500 to 1,000 ppm methanol for 3 to 4 hours gave urine concentrations of 1 to 3 mg methanol/100 mL of urine at the end of exposure (Rowe and McCollister 1981). Based on urinary methanol levels, the rate of absorption of the chemical appears to be proportional to the concentration of vapor inhaled (HSDB 1994). The rate of dermal absorption increased for 35 minutes then decreased over the next 25 minutes (no other details given) (HSDB 1994). 2. Distribution – Methanol distributes rapidly in dogs exposed to 4,000 to 15,000 ppm for 12 hours to 5 days; the highest concentrations of the chemical were found in blood, eye fluid, bile, and urine (HSDB 1994). 3. Metabolism – Methanol is oxidized in the human liver by the enzyme alcohol dehydrogenase (Rowe and McCollister 1981). Metabolic products include formaldehyde and formic acid (HSDB 1994). The rate of metabolism for methanol (25 mg/kg/hr) is much slower than for ethanol (175 mg/kg/hr) and is independent of concentrations in the blood (HSDB 1994). Formic acid is responsible for the toxic effects of methanol (ACGIH 1991). 4. Excretion – Methanol is excreted either as parent compound in the urine or expired air, or as the formic acid metabolite in urine (Rowe and McCollister 1981; HSDB 1994). The amount of formic acid excreted varies greatly with species from 1% in rabbits to 20% in dogs; humans are intermediate (HSDB 1994). In humans, the half-life of methanol elimination in expired air after oral or dermal exposure is 1.5 hours (HSDB 1994). 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE Methanol evaporates when exposed to air. It dissolves completely when mixed with water. Most direct releases of methanol to the environment are to air. Methanol also evaporates from water and soil exposed to air. Once in air, it breaks down to other chemicals. Microorganisms that live in water and in soil can also break down methanol. Because it is a liquid that does not bind well to soil, methanol that makes it way into the ground can move through the ground and enter groundwater. Plants and animals are not likely to store methanol. Methanol by itself is not likely to cause environmental harm at levels normally found in the environment. Methanol can contribute to the formation of photochemical smog when it reacts with other volatile organic carbon substances in air. Movement & Partitioning: The miscibility of methanol in water and a low KOC indicate that the chemical will be highly mobile in soil (HSDB 1994). Volatilization half-lives from a model river and an environmental pond were estimated at 4.8 days and 51.7 days, respectively (HSDB 1994). Methanol can be removed from the atmosphere in rain water (HSDB 1994). Degradation & Transformation: 1. Air – Once in the atmosphere, methanol exists in the vapor phase with a half life of 17.8 days (HSDB 1994). The chemical reacts with photochemically produced hydroxyl radicals to produce formaldehyde (HSDB 1994). Methanol can also react with nitrogen dioxide in polluted air to form methyl nitrite (HSDB 1994). 2. Soil – Biodegradation is the major route of removal of methanol from soils. Several species of Page 259 of 377 Page 259 of 377 Page 259 of 377 Page 259 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 8 Methylobacterium and Methylomonas isolated from soils are capable of utilizing methanol as a sole carbon source (CHEMFATE 1994). 3. Water – Most methanol is removed from water by biodegradation. The degradation products of methane and carbon dioxide were detected from aqueous cultures of mixed bacteria isolated from sewage sludge (CHEMFATE 1994). Aerobic, Gram-negative bacteria (65 strains) isolated from seawater, sand, mud, and weeks of marine origin utilized methanol as a sole carbon source (CHEMFATE 1994). Aquatic hydrolysis, oxidation, and photolysis are not significant fate processes for methanol (HSDB 1994). 4. Biota – Bioaccumulation of methanol in aquatic organisms is not expected to be significant based on an estimated bioconcentration factor of 0.2 (HSDB 1994). Ecotoxicology: 1. Toxicity to Aquatic Organisms – Methanol has low acute toxicity to aquatic organisms; lethal concentrations are much greater than 100 mg/L. Ninety-six hour LC50 values for fish are 28,100 mg/L for Pimephales promelas (fathead minnow), 20,100 mg/L for mykiss (rainbow trout), and >28,000 mg/L for Alburnus alburnus (bleak) (AQUIRE 1994). Forty-eight hour LC50 values for Cyprinus carpio (common carp) and Carassius auratus (goldfish) are 28,000 mg/L and 1,700 mg/L, respectively (AWQUIRE 1994). Growth inhibition occurred for 4 strains of Anabaena (blue-green algae) over a range of EC50s of 2.57%-3.13% for 10-14 days (AQUIRE 1994). The LC50 for Artemia salina (brine shrimp) is >10,000 mg/L in 24 hours and that for Culex restuans (mosquito) is 20,000 mg/L in 18 hours (AQUIRE 1994). 2. Toxicity to Terrestrial Organisms – No information was found in the secondary sources searched regarding the toxicity of methanol to terrestrial organisms. However, based on the range of oral LD50s, 0.4 to 14.2 g/kg, for monkeys, rats, mice, and rabbits (Rowe and McCollister 1981), it is unlikely that methanol would be toxic to terrestrial animals at environmental levels. 3. Abiotic Effects – Methanol reacts with nitrogen dioxide in polluted atmospheres to produce methyl nitrite (HSDB 1994). According to the definition provided in the Federal Register (1992), methanol is a volatile organic compound (VOC) substance. As a VOC, methanol can contribute to the formation of photochemical smog in the presence of other VOCs. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION U. S. Department of Transportation: In Inner Packaging No More Than 5.0 L: Proper Shipping Name: Consumer Commodity ORM-D Per 49 CFR Part 173.10 (PG III, inner packaging no more than 5.0L) In Packaging Over 5.0 L: Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III Page 260 of 377 Page 260 of 377 Page 260 of 377 Page 260 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 9 International Air Dangerous Good Regulations (IATA): Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III Ltd. Qty. Packaging Instruction: Y309 (Max qty. per package 10L) Special Provision: A3 International Maritime Dangerous Goods (IMDG): Proper Shipping Name: Limited Quantities of Class 3 (This must be notated on Shipper's Declaration). 15. REGULATORY INFORMATION THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS: CHEMICAL NAME CAS NUMBER Methanol 67-56-1 U.S. Federal Regulations TSCA (Toxic Substances Control Act) Status – TSCA (UNITED STATES) The intentional ingredients of this product are listed. CERCLA RQ – 40 CFR 302.4(a) Component RQ (lbs) Methyl Alcohol 5,000 SARA 302 Components – 40 CFR 355 Appendix A None Section 311/312 Hazard Class – 40 CFR 370.2 Immediate Delayed Fire Reactive ( ) Sudden Release of Pressure ( ) SARA 313 Components – 40 CFR 372.65 Section 313 Component(s) CAS Number % Methanol 67-56-1 35 International Regulations Inventory Status – DSL (CANADA) The intentional ingredients of this product are listed. WHMIS Information: B2, D1A ECL (SOUTH KOREA) The intentional ingredients of this product are listed. EINECS (EUROPE) The intentional ingredients of this product are listed. ENCS (JAPAN) The intentional ingredients of this product are listed. Page 261 of 377 Page 261 of 377 Page 261 of 377 Page 261 of 377 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 10 State and Local Regulations California Proposition 65: Methanol is on the California Proposition 65 list as a reproductive toxicant. New Jersey RTK (Right-to-Know) Label Information: Methyl Alcohol (67-56-1) RTK (Right-to-Know) Label Information: Methanol (67-56-1) Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant. 16. OTHER INFORMATION Contact: Tom Cholke Phone: (847) 559-2225 Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this MSDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Page 262 of 377 Page 262 of 377 Page 262 of 377 Page 262 of 377 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Name: POLAR WW SOLVENT 6/1GL Product Code: WW65006P 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Windshield Wash Recommended restrictions: AZ, CA, TX, Atlanta Area 1.3. Details of the supplier of the safety data sheet Manufacturer: Warren Distribution, Inc. 727 S. 13th Street Omaha, NE 68102 Information Phone: +01 (800) 825-1235 +01 (402) 341-9397 E-mail: [EMAIL REDACTED] 1.4. Emergency telephone number Emergency phone number: CHEMTREC: +1 (800) 424-9300 International: +01 (703) 527-3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Specific Target Organ Systemic Toxicity (STOT) - Single Exposure Category 1 Flammable Liquid Category 3 2.2. Label elements GHS Hazard Symbols Signal Word Danger Hazard Statements H226 - Flammable liquid and vapor. H370 - Causes damage to organs. Precautionary Statements Prevention P210 - Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P233 - Keep container closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/…/ equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P264 - Wash exposed areas thoroughly after handling. P270 - Do no eat, drink or smoke when using this product. P280 - Wear protective gloves/protective clothing/eye protection/face protection. Response P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P307+P311 - IF exposed: Call a POISON CENTER or doctor/physician. P321 - Specific treatment (see section P370+P378 - In case of fire: Use … to extinguish. Storage P233 - Keep container closed. P403+P235 - Store in a well-ventilated place. Keep cool. Page 263 of 377 Page 263 of 377 Page 263 of 377 Page 263 of 377 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 2 of 7 P405 - Store locked up. Disposal P501- Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3. Other hazards Hazards not otherwise classified: No data available. Unknown acute toxicity (GHS-US) Unknown Acute Toxicity (Gas): 61.197286 % of the mixture consists of ingredient(s) of unknown toxicity. SECTION 3: Composition/information on ingredients Chemical Name % CAS # GHS Classification Methanol 15 - 40 67-56-1 Acute Tox. 3; H311 Acute Tox. 3; H301 Acute Tox. 3; H331 Flam. Liq. 2; H225 STOT SE 1; H370 Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately. Eyes Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention. Skin Contact Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. Ingestion Seek medical attention immediately or call the Poison control center. Do not induce vomiting. If patient is fully conscious, give up to two glasses of water. Provide medical care provider with this SDS. 4.2. Most important and effects, both acute and delayed Vomiting, Nausea, Headache, Dizziness, Drowsiness, Coughing, Mental confusion, Systemic effects similar to those resulting from ingestion, Temporary or permanent blindness, Muscle pains, Impaired vision 4.3. Indication of any immediate medical attention and special treatment needed Note to Doctor No additional first aid information available. Page 264 of 377 Page 264 of 377 Page 264 of 377 Page 264 of 377 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 3 of 7 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable and Unsuitable Extinguishing Media: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water may be ineffective but water spray can be used to extinguish a fire if swept across the base of the flames. Water can absorb heat and keep exposed material from being damaged by fire. 5.2. Special hazards arising from the substance or mixture Fire and/or Explosion Hazards Vapors may be ignited by sparks, flames or other sources of ignition if material is above the flash point giving rise to a fire (Class Vapors are heavier than air and may travel to a source of ignition and flash back. 5.3. Advice for firefighters Fire Fighting Methods and Protection Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential for hazardous vapors and decomposition products.Flammable component(s) of this material may be lighter than water and burn while floating on the surface. Hazardous Combustion Products Carbon monoxide, Formaldehyde SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General Measures: Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Evaporation of volatile substances can lead to the displacement of air creating an environment that can cause 6.2. Environmental precautions Avoid runoff into storm sewers and ditches that lead to waterways. 6.3. Methods and material for containment and cleaning up Methods for cleaning up: Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Dispose of according to Federal, State, Local, or Provincial regulations. Used fluid should be disposed of at a recycling center. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. 6.4. Reference to other sections Follow all protective equipment recommendations provided in Section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Empty containers may retain product residues/ vapors. Use proper bonding and grounding during bulk product transfer.Use spark-proof tools and explosion-proof equipment 7.2. Conditions for safe storage, including any incompatibilities Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed. Do not expose to extreme temperatures or flames. Incompatible materials See Section 10. 7.3. Specific end use(s) Windshield Wash SECTION 8: Exposure controls/personal protection 8.1. Control parameters Chemical Name Occupational Exposure Limits Value Methyl alcohol OSHA PEL 200 ppm TWA; 260 mg/m3 TWA Methyl alcohol OSHA STEL 250 ppm STEL; 325 mg/m3 STEL Methanol ACGIH TLV-TWA 200 ppm TWA Page 265 of 377 Page 265 of 377 Page 265 of 377 Page 265 of 377 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 4 of 7 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Chemical Name Occupational Exposure Limits Value Methanol ACGIH STEL 250 ppm STEL Methyl alcohol IDLH 6000 ppm IDLH None. OSHA PEL-Skin Notation Methyl alcohol OSHA STEL-Skin Notation Potential for dermal absorption Methanol ACGIH TLV-Skin Designation Skin - potential significant contribution to overall exposure by the cutaneous route 8.2. Exposure controls Engineering Measures Use local exhaust ventilation or other engineering controls to minimize exposures and maintain operator comfort. Respiratory Protection Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to eliminate Respirator Type(s) None required where adequate ventilation is provided. If airborne concentrations are above the applicable exposure limits, use NIOSH/MSHA approved respiratory protection. Eye Protection Wear chemically resistant safety glasses with side shields when handling this product. Do not wear contact lenses. An eye wash station must be available where this product is used. Skin Protection Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Gloves Butyl rubber, Polyethylene, Polyvinylalcohol SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical State Liquid Color Blue Odor Moderate Odor threshold Not determined pH Not determined Freezing point Not determined Boiling Point Not determined Flash Point 36 Flash Point Method PMCC Evaporation Rate 2-10 (n-Butyl acetate = 1) Upper Flammable/Explosive Limit, % in air 36.5 (air = 1) Lower Flammable/Explosive Limit, % in air 6 (air = 1) Flammability (solid, gas) Not applicable Vapor pressure Not determined Vapor Density Not determined Relative Density 0.82 Solubility in Water Complete; 100% Octanol/Water Partition Coefficient Not determined Autoignition Temperature Not determined Decomposition Temperature Not determined 9.2. Other information Volatiles, % by weight 0.000000 SECTION 10: Stability and reactivity 10.1. Reactivity No data available. Page 266 of 377 Page 266 of 377 Page 266 of 377 Page 266 of 377 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 5 of 7 SECTION 10: Stability and reactivity 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks, open flame, other ignition sources, and elevated temperatures.Visible light 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Carbon monoxide, Formaldehyde SECTION 11: Toxicological information 11.1. Information on toxicological effects Ingestion Toxicity No hazard in normal industrial use.Estimated to be > 5.0 g/kg. Skin Contact This material is likely to be moderately irritating to skin based on animal data.Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Absorption Estimated to be > 5.0 g/kg; practically non-toxic Inhalation Toxicity No hazard in normal industrial use. Likely to be practically non-toxic based on animal data. Eye Contact The material is likely to be moderately irritating to eyes based on animal data. Can cause moderate irritation, tearing and reddening, but not likely to permanently injure eye tissue. Sensitization Non-hazardous under Respiratory Sensitization category.No data available to indicate product or components may be a skin sensitizer. Mutagenicity No data available to indicate product or any components present at greater than 0.1% is mutagenic or genotoxic. Carcinogenicity Not a carcinogen according to NTP, IARC, or OSHA. Reproductive and Developmental Toxicity No data available to indicate product or any components present at greater than 0.1% may cause birth defects. Specific target organ toxicity-Single exposure H370 - Causes damage to organs. Specific target organ toxicity-Repeated exposure Non-hazardous under Specific Target Organ Systemic Toxicity Repeated Exposure category. Long-Term (Chronic) Health Effects Drowsiness, Headache, Impaired vision, Circulatory failure, Abdominal pain, Skin rashes Aspiration toxicity Non-hazardous under Aspiration category. Other information No data available. Agents Classified by IARC Monographs Not applicable IARC Group 1 Not applicable IARC Group 2A Not applicable IARC Group 2B National Toxicity Program (NTP) Status Not applicable Known Human Carcinogen Not applicable Reasonably Anticipated To Be A Human Carcinogen SECTION 12: Ecological information 12.1. Toxicity Acute Aquatic ecotoxicity: Non-hazardous under Aquatic Acute Environment category. Chronic Aquatic ecotoxicity: Non-hazardous under Aquatic Chronic Environment category. 12.2. Persistence and degradability Biodegrades quickly. 12.3. Bioaccumulative potential Bioconcentration is not expected to occur. 12.4. Mobility in soil This material is expected to have very high mobility in soil. It does not absorb to most soil types. This material is expected to evaporate quickly from surface soils and/or waters. 12.5. Results of PBT and vPvB assessment Page 267 of 377 Page 267 of 377 Page 267 of 377 Page 267 of 377 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 6 of 7 SECTION 12: Ecological information No data available. 12.6. Other adverse effects Not determined SECTION 13: Disposal considerations 13.1. Waste treatment methods Disposal Methods Dispose of by incineration following Federal, State, Local, or Provincial regulations. Waste Disposal Code(s) D001 Waste Description for Spent Product Spent or discarded material is a hazardous waste. Contaminated packaging: Containers of this material may be hazardous when emptied. SECTION 14: Transport information DOT Basic Description UN1993, FLAMMABLE LIQUID, N.O.S. (METHANOL), 3, III, LTD QTY IMDG Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S Technical Name: METHANOL UN Number: UN1993 Hazard Class: 3 Packing Group: III Exception: LTD QTY EMS# F-E,S-E IATA Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S Technical Name: METHANOL UN Number: UN1993 Hazard Class: 3 Packing Group: III Exception: LTD QTY SECTION 15: Regulatory information Chemical Inventories TSCA Status All components of this material are on the US TSCA Inventory or are exempt. U.S. State Restrictions: AZ, CA, TX, Atlanta Area WHMIS: B2, D1B, D2A, D2B Chemical Name Regulation CAS # % Methanol CERCLA 67-56-1 15 - 40 Methanol SARA 313 67-56-1 15 - 40 None. SARA EHS None. TSCA 12b U.S. State Regulations Chemical Name Regulation CAS # % None. California Prop 65- Cancer Methanol California Prop 65- Dev. Toxicity 67-56-1 15 - 40 None. California Prop 65- Reprod -fem None. California Prop 65- Reprod-male Page 268 of 377 Page 268 of 377 Page 268 of 377 Page 268 of 377 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 7 of 7 Chemical Name Regulation CAS # % Methanol Massachusetts RTK List 67-56-1 15 - 40 Methyl alcohol New Jersey RTK List 67-56-1 15 - 40 Methanol RTK List 67-56-1 15 - 40 None. Rhode Island RTK List Methyl alcohol Minnesota Hazardous Substance List 67-56-1 15 - 40 HMIS Ratings: NFPA Ratings: Health: 2 Health: 2 Fire: 3 Fire: 3 Reactivity: 0 Reactivity: 0 PPE: B KEY: 0 - Least 1 - Slight 2 - Moderate 3 - High 4 – Extreme SECTION 16: Other information Revision Date 4/2/2015 11:56:38 AM Supersedes: 4/2/2015 4:47:28 AM References ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association CFR: Code of Federal Regulations DOT: United States Department of Transportation GHS: Globally Harmonized System of Classification and Labeling of Chemicals HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transportation Association IDLH: Immediately Dangerous to Life or Health IMDG: International Maritime Dangerous Goods NFPA: National Fire Protection Association NIOSH: National Institute for Occupational Safety and Health NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit RTK: Right-to-Know SARA: Superfund Amendments and Reauthorization Act STEL: Short-term Exposure Limit TLV: Threshold limit value TSCA: Toxic Substances Control Act TWA: Time weighted average UN: United Nations WHMIS: Workplace Hazardous Materials Information System Disclaimer This safety data sheet and the information it contains is offered to you in good faith as accurate. We have reviewed any information contained in the data sheet which we have received from outside sources and we believe the information to be correct, but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user's obligation to evaluate and use this product in a safe manner and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as permission or recommendation for the use of any product in a manner that might infringe existing patents. No warranty is made, either expressed or implied. Page 269 of 377 Page 269 of 377 Page 269 of 377 Page 269 of 377 ---PAGE BREAK--- H.M.I.S. RATING Health 1 Flammability 0 Reactivity 0 Protective Equip. E Material Safety Data Sheet – OSHA 174 Material Safety Data Sheet May be used to comply with OSHA’s Hazard communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements. US Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved OMB No. 1218-0072 Polymer-Modified MasterSeal (PMM) Product No. S1097 SECTION I - Manufacturer / Product Information Manufacturer's Name: SealMaster Emergency Telephone No.: Chemtrec: 1-[PHONE REDACTED] Telephone Number for Information: 1-[PHONE REDACTED] Address: Locations Nationwide www.sealmaster.net Date Prepared: January 13, 2010 SECTION II - Chemical Identity Information Ingredient CAS # OSHA_PEL ACGIH_TLV Other Limits Percent Ball Clay 1332-58-7 10 mg/m3 N/A Asphalt 8052-42-4 N/A 5 mg/m3 Calcium Carbonate 1317-65-3 5 mg/m3 2mg/m3 SECTION III - Physical / Chemical Characteristics Boiling Point: 100° Celsius (212° Fahrenheit) Vapor Pressure (mm Hg): Nearly equal to water. Specific Gravity (H2O = 1.14 Melting Point: N/A Vapor Density (AIR = <1 Evaporation Rate (Butyl Acetate = Approximately 1.8 Solubility in Water: Easily dispersible in the liquid state. Appearance and Odor: Black liquid, asphaltic odor. SECTION IV - Fire and Explosion Hazard Data Flash Point (Method Used): N/A Flammable Limits: N/A LEL: N/A UEL: N/A Extinguishing Media: Foam, CO2, dry chemical, water fog, other. Special Fire Fighting Procedures: Full protective equipment, including self-contained breathing apparatus to be worn. Water cool sealed containers in area of fire to prevent rupture due to steam generation. Unusual Fire and Explosion Hazards: N/A SECTION V - Reactivity Data Stability: Unstable: Stable: X Conditions to Avoid: Keep from freezing and extreme heat. Incompatibility (Materials to Avoid): Strong oxidizers. Hazardous Decomposition or Byproducts: Combustion may yield fumes, smoke, carbon monoxide, carbon dioxide and other toxic pyrolysis products. Hazardous Polymerization: May Occur: Will Not Occur: X Conditions to Avoid: N/A Page 270 of 377 Page 270 of 377 Page 270 of 377 Page 270 of 377 ---PAGE BREAK--- SECTION VI - Health Hazard Data Route(s) of Entry: Inhalation? Yes Skin Contact? No Ingestion? Yes Eye Contact? Yes Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Inhalation Hazards: Vapors and Fumes can cause irritation to nasal and respiratory tract. Extended exposure can cause dizziness and nausea. Ingestion Hazards: Product has low order of acute toxicity. Skin Hazards: Hot emulsified asphalt can cause thermal burns. Frequent or prolonged contact can cause irritation and dermatitis. Product has low order of toxicity. Eye: Emulsified asphalt can cause eye irritation. Medical Conditions Generally Aggravated by Exposure: None known. Emergency and First Aid Procedures: Inhalation: Move person to fresh air immediately. If not breathing, give artificial resuscitation. Immediately call a physician. Ingestion: If ingested, call a physician immediately and follow directions. Skin Contact: Hot material- Gently flush with cool water. Call a physician. Cold material- Remove emulsified asphalt with waterless hand cleaner and wash with soap and water. If irritation occurs, call a physician. Eye Contact: Gently flush with large amounts of water. Call a physician immediately. SECTION VII - Precautions for Safe Handling and Use Steps to be taken in case material is released or spilled: Dike and contain spill with inert material (sand, sawdust, diamateous earth, etc.). Pump liquid into storage tanks. Remaining liquid may be taken up with inert materials. Place in closed container for proper disposal. Waste Disposal Method: Dispose of in accordance with Local, State, and Federal regulations. Precautions to Be Taken in Handling and Storage: Keep container closed and upright to prevent leakage. Avoid freezing or temperatures above 50° Celsius. Other Precautions: Do not take internally. Keep away from children. Avoid breathing vapors. For external use only. SECTION VIII - Control Measures Respiratory Protection (Specify Type): None required if good ventilation is maintained. Otherwise use NIOSH approved respirator designed to remove particles and vapor. Local Exhaust: Yes Special: N/A Ventilation: Mechanical (General): N/A Other: N/A Protective Gloves: Yes Eye Protection: Yes Other Protective Clothing or Equipment: A rubber apron is recommended to protect clothing from splash during application. Work/Hygienic Practices: Do not apply during or just before (within one hour) of rain to avoid contamination of runoff water. Wash hands before eating. SECTION IX - Disclaimer All information, recommendations, and suggestions concerning this product are based upon tests, literature references, and/or calculations, believed to be reliable. The manufacturer makes no guarantee, expressed or implied, as to the affect of use, or the safety and toxicity of the product. The information contained in this sheet cannot be taken as the sum total of all protective measures to be taken. Page 271 of 377 Page 271 of 377 Page 271 of 377 Page 271 of 377 ---PAGE BREAK--- page 1 of 3 UEL N.A. LEL N.A. FLASH POINT Not Applicable HMIS Codes Health 1 Flammability 0 Reactivity 0 DATE OF PREPARATION Feb 25, 2011 MATERIAL SAFETY DATA SHEET B30T2654 06 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B30T2654 PRODUCT NAME PROMAR® 200 Zero VOC Interior Latex Flat, Ultradeep Base MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS No ingredients in this product are hazardous as defined by the Department of Labor. SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Page 272 of 377 Page 272 of 377 Page 272 of 377 Page 272 of 377 ---PAGE BREAK--- B30T2654 page 2 of 3 SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Required for long or repeated contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.98 lb/gal 1076 g/l SPECIFIC GRAVITY 1.08 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 65% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.00 lb/gal 0 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. Page 273 of 377 Page 273 of 377 Page 273 of 377 Page 273 of 377 ---PAGE BREAK--- B30T2654 page 3 of 3 HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. TOXICOLOGY DATA No LC50 or LD50 data available. SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 274 of 377 Page 274 of 377 Page 274 of 377 Page 274 of 377 ---PAGE BREAK--- Material Safety Data Sheet U.S. Department of Labor May be used to comply with Occupational Safety and Health Administration OSHA's Hazard Communication Standard, (Non-Mandatory Form) 29 CFR 1910.1200. This Standard must be Form Approved consulted for specific requirements. OMB No. 1218-0072 IDENTITY (As Used on Label and List) PROPANE Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Section I Manufacturer's Name BernzOmatic Emergency Telephone Number [PHONE REDACTED] Address (Number, Street, City, State, and ZIP Code) Telephone Number for Information [PHONE REDACTED] 1 Bernzomatic Drive Date Prepared June 11, 2011 Medina, NY 14103 Signature of Preparer (optional) Section II - Hazard Ingredients/Identity Information Hazardous Components (Specific Chemical Identity; Common Name(s)) US OSHA PEL ACGIH TLV Other Limits Recommended % (optional) PROPANE (CAS No. 74-98-6) 1000PPM 1000PPM N/A 100 NFPA HAZARD RATINGS Health – 1 Flammability – 4 Reactivity - 0 HMIS RATINGS Health – 0 Flammability – 4 Reactivity - 0 Notes: When propane fuel is burned efficiently, the normal by-products of combustion are CO2 and H20. Inefficient burning may add CO to the by-products of combustion. Section III - Physical/Chemical Characteristics Boiling Point: -44° F Specific Gravity (H2O = Liquid @ 60° F .51 Vapor Pressure (mm Hg.): @ 100° F 197psig Melting Point: Not Applicable Vapor Density (AIR = @ 1 ATM @ 60° F 1.56 Evaporation Rate (Butyl Acetate = Not Applicable Solubility in Water: Insoluble Appearance and Odor (At Normal Conditions): Colorless – Rotten Egg Odor. Page 275 of 377 Page 275 of 377 Page 275 of 377 Page 275 of 377 ---PAGE BREAK--- 2 Section IV - Fire and Explosion Hazard Data Flash Point (Method Used): -156° F Closed Cup Flammable Limits: LEL 2.1 UEL 9.5 Extinguishing Media: Stop flow of gas or oxygen. Special Fire Fighting Procedures: Use water to cool tanks. Unusual Fire and Explosion Hazards: Auto ignition temp. 842° F. Heavier than air (vapor density 1.5). May travel a considerable distance to a source of ignition and flashback. Section V - Reactivity Data Stability: Unstable NO Conditions to Avoid: Stable X N/A Incompatibility (Materials to Avoid): N/A Hazardous Decomposition or Byproducts At temperatures above the melting point metal oxide fumes may be evolved. Hazardous Polymerization: May Occur NO Conditions to Avoid: Will Not Occur X N/A Section VI - Health Hazard Data Route(s) of Entry: Inhalation? YES Skin? YES Ingestion? NO Health Hazards (Acute and Chronic) Contact with liquid propane may cause frost burns. Carcinogenicity: NTP? Not listed as a carcinogen IARC Monographs? Not listed as a carcinogen OSHA Regulated? Not listed as a carcinogen Signs and of Exposure: High concentrations may cause headaches and drowsiness. Medical Conditions Generally Aggravated by Exposure: Not Applicable Emergency and First Aid Procedures: Remove exposed person from contaminated area. Warning: This fuel and by-products of combustion of this fuel, contain chemicals known to the State of California to cause cancer, birth defects, and other reproductive harm. Page 276 of 377 Page 276 of 377 Page 276 of 377 Page 276 of 377 ---PAGE BREAK--- 3 Section VII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Released or Spilled: Remove ignition sources and ventilate area. Waste Disposal Method: Vent gas to atmosphere in flame free, spark free area outdoors. Precautions to Be taken in Handling and Storing: Store at temperatures below 120° F in well ventilated, spark free, flame free area. Other Precautions: None Section VIII - Control Measures Respiratory Protection (Specify Type): Not required with normal use. Ventilation: Local Exhaust – N/A Mechanical (General) – N/A Special – N/A Other – N/A Protective Gloves: Not Required Eye Protection: Not Required Other Protective Clothing or Equipment: Not Required Work/Hygienic Practices: N/A Section IX – Transportation Information WHMIS Classification: A – Compressed Gas & B1 – Flammable Gas Class: 2.1 Proper Shipping Name: Petroleum Gas, Liquefied Hazard Classification: Flammable Gas UN Number: 1075 Section X – Additional Information DISCLAIMER: Judgments as to the suitability of information herein or the purchaser’s purposes are necessarily the purchaser’s responsibility. Reasonable care has been taken in the preparation of this material, but there are NO WARRANTIES, NO REPRESENTATIONS, AND NO RESPONSIBILITY AS TO THE ACCURACY OR THE SUITABILITY OF THIS INFORMATION FOR ANY PURCHASER’S USE OR FOR ANY CONSEQUENCE TO USE. This Material Safety Data Sheet is offered solely for your information, consideration and investigation. BernzOmatic provides no warranties; either express or implied, and assumes no responsibilities for the accuracy or completeness of the data contained in this document. The data in this Material Safety Data Sheet relates only to this product and does not relate to use in combination with any other material or in any process. Page 277 of 377 Page 277 of 377 Page 277 of 377 Page 277 of 377 ---PAGE BREAK--- Page 278 of 377 Page 278 of 377 Page 278 of 377 Page 278 of 377 ---PAGE BREAK--- Page 279 of 377 Page 279 of 377 Page 279 of 377 Page 279 of 377 ---PAGE BREAK--- Page 280 of 377 Page 280 of 377 Page 280 of 377 Page 280 of 377 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M290-0202 Safety Data Sheet 1. Identification Product Information: M290-0202 Product Name: QUIK TIP™ MARKER HIGH GLOSS WHITE Recommended Use: Surface Preparation or Protection Mohawk Finishing Products Division of RPM Wood Finishes Group, Inc. 22 South Center Street Hickory, NC 28602 USA Supplied by: Company Phone No: (800) 522-8266 Emergency Phone No. CHEMTREC: (800) 424-9300 (703) 527-3887 (Collect calls are accepted) International Emergency No. CHEMTREC: 2. Hazards Identification GHS Classification Carc. 1B, Eye Dam. 1, Flam. Liq. 2, Muta. 1B, STOT SE 3 NE Symbol(s) of Product Signal Word Danger GHS HAZARD STATEMENTS Flammable Liquid, category 2 H225 Highly flammable liquid and vapour. Serious Eye Damage, category 1 H318 Causes serious eye damage. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Carcinogenicity, category 1B H350 May cause cancer. GHS LABEL PRECAUTIONARY STATEMENTS P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. Page 1 / 8 Page 281 of 377 Page 281 of 377 Page 281 of 377 Page 281 of 377 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M290-0202 P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P403+P233 Store in a well-ventilated place. Keep container closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. GHS ADDITIONAL INFORMATION H362 May cause harm to breast-fed children GHS SDS PRECAUTIONARY STATEMENTS P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. 3. Composition/Information on ingredients Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements n-butyl acetate 123-86-4 10-25 GHS02-GHS07 H226-336 titanium dioxide 13463-67-7 10-25 No Information No Information methyl ethyl ketone 78-93-3 2.5-10 GHS02-GHS07 H225-319-332-336 acetone 67-64-1 2.5-10 GHS02-GHS07 H225-302-319-336 pm acetate 108-65-6 2.5-10 GHS02-GHS07 H226-332 cellulose nitrate, cellulose ester 9004-70-0 2.5-10 No Information No Information ethyl acetate 141-78-6 2.5-10 GHS02-GHS07 H225-319-332-336 butanol 71-36-3 2.5-10 GHS02-GHS05- GHS07 H226-302-315-318-332-335-336 isopropyl acetate 108-21-4 2.5-10 GHS02-GHS07 H225-319-336 isopropanol 67-63-0 2.5-10 GHS02-GHS07 H225-302-319-336 toluene 108-88-3 1.0-2.5 GHS02-GHS07- GHS08 H225-304-315-332-336-361-373 aluminum oxide 1344-28-1 1.0-2.5 No Information No Information petroleum distillate 64742-49-0 1.0-2.5 GHS08 H304-340-350 100-41-4 0.1-1.0 GHS02-GHS07- GHS08 H225-304-332-373 The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section. 4. First-aid Measures FIRST AID - EYE CONTACT: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. FIRST AID - SKIN CONTACT: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. FIRST AID - INGESTION: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. FIRST AID - INHALATION: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Page 2 / 8 Page 282 of 377 Page 282 of 377 Page 282 of 377 Page 282 of 377 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M290-0202 5. Fire-fighting Measures SPECIAL FIREFIGHTING PROCEDURES: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. FIREFIGHTING EQUIPMENT: This is a NFPA/OSHA Class 1B or less flammable liquid. Follow NFPA30, Chapter 16 for fire protection and fire suppression. Use a dry chemical, carbon dioxide, or similar ABC fire extinguisher for incipeint fires. Water may be used to cool and prevent rupture of containers that are exposed to heat from fire. 6. Accidental Release Measures ENVIRONMENTAL MEASURES: No Information STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage system or open waterways. 7. Handling and Storage HANDLING: Avoid inhalation and contact with eyes, skin, and clothing. Wash hands thoroughly after handling and before eating or drinking. In keeping with safe handling practices, avoid ignition sources (smoking, flames, pilot lights, electrical sparks); ground and bond containers when transferring the material to prevent static electricity sparks that could ignite vapor and use spark proof tools and explosion proof equipment. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can potentially cause an explosion that may lead to injury. STORAGE: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. 8. Exposure Controls/Personal Protection Ingredients with Occupational Exposure Limits Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING n-butyl acetate 150 ppm 200 ppm 150 ppm N.D. titanium dioxide 10 mg/m3 N.D. 15 mg/m3 N.D. methyl ethyl ketone 200 ppm 300 ppm 200 ppm N.D. acetone 250 ppm 500 ppm 1000 ppm N.D. pm acetate N.D. N.D. N.D. N.D. cellulose nitrate, cellulose ester N.D. N.D. N.D. N.D. ethyl acetate 400 ppm N.D. 400 ppm N.D. butanol 20 ppm N.D. 100 ppm N.D. isopropyl acetate 100 ppm 200 ppm 250 ppm N.D. isopropanol 200 ppm 400 ppm 400 ppm N.D. toluene 20 ppm N.D. 200 ppm 300 ppm aluminum oxide N.D. N.D. 15 mg/m3 N.D. petroleum distillate N.D. N.D. N.D. N.D. 20 ppm N.D. 100 ppm N.D. Page 3 / 8 Page 283 of 377 Page 283 of 377 Page 283 of 377 Page 283 of 377 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M290-0202 Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation Sk = Skin Sensitizer N.E. = Not Established N.D. = Not Determined Personal Protection RESPIRATORY PROTECTION: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. SKIN PROTECTION: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. EYE PROTECTION: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. OTHER PROTECTIVE EQUIPMENT: No Information HYGIENIC PRACTICES: It is good practice to avoid contact with the product and/or its vapors, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Page 4 / 8 Page 284 of 377 Page 284 of 377 Page 284 of 377 Page 284 of 377 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M290-0202 9. Physical and Chemical Properties Colored Liquid LIQUID Appearance: Physical State: Strong Solvent Not determined Odor: Odor Threshold: 1.129 Not determined Density, g/cm3: pH: Not determined Not determined Freeze Point, Viscosity: Not determined Partition Coefficient, n-octanol/ water: Not determined Solubility in Water: Not determined Not determined Decomposition temperature, Explosive Limits, > 100 °F -4 ° F Boiling Range, Flash Point, Supports Combustion Not determined Combustibility: Auto-Ignition Temperature, Faster than Diethyl Ether Not determined Evaporation Rate: Vapor Pressure, mmHg: Not determined Vapor Density: N.I. = No Information 10. Stability and reactivity STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Heat, flames and sparks. INCOMPATIBILITY: Acids, Bases, Oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: Not determined. 11. Toxicological information Practical Experiences EMERGENCY OVERVIEW: No Information EFFECT OF OVEREXPOSURE - EYE CONTACT: No Information EFFECT OF OVEREXPOSURE - INGESTION: No Information EFFECT OF OVEREXPOSURE - INHALATION: No Information EFFECT OF OVEREXPOSURE - SKIN CONTACT: No Information Page 5 / 8 Page 285 of 377 Page 285 of 377 Page 285 of 377 Page 285 of 377 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M290-0202 CARCINOGENICITY: May cause cancer. This product contains Titanium Dioxide, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This classification is relevant when exposed to titanium dioxide in dust or powder form only, including cured product that is subject to sanding, grinding, cutting, or other surface preparation activities. PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Skin Contact, Inhalation Acute Toxicity Values The acute effects of this product have not been tested. Data on individual components are tabulated below CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 123-86-4 n-butyl acetate 14130 mg/kg Rat >17600 mg/kg Rabbit 23.4 mg/l Rat 13463-67-7 titanium dioxide >10000 mg/kg Rat >10000 mg/kg Rabbit >20 mg/l 78-93-3 methyl ethyl ketone 2483 mg/kg Rat 5000 mg/kg Rabbit >20 mg/l 67-64-1 acetone 1800 mg/kg Rat 20000 mg/kg Rabbit 50.1 mg/L Rat 108-65-6 pm acetate 8532 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L 9004-70-0 cellulose nitrate, cellulose ester >5000 mg/kg Rat >5000 mg/kg >20 mg/l 141-78-6 ethyl acetate 5620 mg/kg Rat >18000 mg/kg Rabbit 200 mg/l Rat 71-36-3 butanol 700 mg/kg Rat 3402 mg/kg Rabbit 8000 mg/l Rat 108-21-4 isopropyl acetate 3000 mg/kg Rat >17440 mg/kg Rabbit 50.6 mg/L Rat 67-63-0 isopropanol 1870 mg/kg Rat 4059 mg/kg Rabbit 72.6 mg/L Rat 108-88-3 toluene 2600 mg/kg Rat 12000 mg/kg Rabbit 12.5 mg/L Rat 1344-28-1 aluminum oxide >5000 mg/kg Rat N.I. >20 mg/l 64742-49-0 petroleum distillate >5000 mg/kg Rat >3160 mg/kg Rabbit 54 mg/l Rat 100-41-4 3500 mg/kg Rat 15400 mg/kg Rabbit 17.2 mg/L Rat N.I. = No Information 12. Ecological information ECOLOGICAL INFORMATION: Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. 13. Disposal Information Product DISPOSAL METHOD: Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage system or open waterways. 14. Transport Information SPECIAL TRANSPORT PRECAUTIONS: No Information Page 6 / 8 Page 286 of 377 Page 286 of 377 Page 286 of 377 Page 286 of 377 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M290-0202 DOT: CONSUMER COMMODITY IATA: CONSUMER COMMODITY, ID 8000 IMDG: LIMITED QUANTITY UN1263 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Fire Hazard, Acute Health Hazard, Chronic Health Hazard SARA SECTION 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. butanol 71-36-3 isopropanol 67-63-0 toluene 108-88-3 TOXIC SUBSTANCES CONTROL ACT This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name CAS-No. Castor oil, sulphated, sodium salt 68187-76-8 U.S. State Regulations: CALIFORNIA PROPOSITION 65 CARCINOGENS WARNING: This product contains a chemical known to the State of California to cause cancer. CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Page 7 / 8 Page 287 of 377 Page 287 of 377 Page 287 of 377 Page 287 of 377 ---PAGE BREAK--- Date Printed: 7/4/2015 Product: M290-0202 16. Other Information 5/9/2015 Supersedes Date: Revision Date: 7/4/2015 Reason for revision: Product Composition Changed Datasheet produced by: Regulatory Department HMIS Ratings: Health: 2 Flammability: 3 Reactivity: 0 Personal Protection: X Volatile Organic Compounds, gr/ltr: 652 Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS02 GHS05 GHS07 GHS08 The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions and recommendations are not followed. Page 8 / 8 Page 288 of 377 Page 288 of 377 Page 288 of 377 Page 288 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 1/14 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : RAID® WASP & HORNET KILLER 33 Recommended use : Insecticide Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Aerosol Category 1 Extremely flammable aerosol. Aspiration hazard Category 1 May be fatal if swallowed and enters airways. Gases under pressure Compressed gas Contains gas under pressure; may explode if heated. Labelling Hazard symbols Flame Gas cylinder Health hazard Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Precautionary statements If medical advice is needed, have product container or label at hand. Page 289 of 377 Page 289 of 377 Page 289 of 377 Page 289 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 2/14 Keep out of reach of children. Read label before use. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 122 Protect from sunlight. Store in a well-ventilated place. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Distillates (petroleum), hydrotreated light 64742-47-8 60.00 - 100.00 Carbon dioxide 124-38-9 1.00 - 5.00 Isopropanol 67-63-0 1.00 - 5.00 Cypermethrin 52315-07-8 0.0001 - 0.10 Prallethrin 23031-36-9 0.0001 - 0.10 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Page 290 of 377 Page 290 of 377 Page 290 of 377 Page 290 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 3/14 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. NFPA Classification : NFPA Level 3 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Page 291 of 377 Page 291 of 377 Page 291 of 377 Page 291 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 4/14 Precautions for safe handling : Avoid contact with skin, eyes and clothing. Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Pressurized container. Do not pierce or burn, even after use. Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Do not spray on an open flame or other ignition source. Storage Requirements for storage areas and containers : Protect from sunlight. Do not expose to temperatures exceeding 50 122 Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. Store locked up. Page 292 of 377 Page 292 of 377 Page 292 of 377 Page 292 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 5/14 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Distillates (petroleum), hydrotreated light 64742-47-8 1,200 mg/m3 152 ppm - SUPPLIER Carbon dioxide 124-38-9 9,000 mg/m3 5,000 ppm - OSHA TWA Carbon dioxide 124-38-9 - 30,000 ppm - ACGIH STEL Carbon dioxide 124-38-9 - 5,000 ppm - ACGIH TWA Isopropanol 67-63-0 980 mg/m3 400 ppm - OSHA TWA Isopropanol 67-63-0 - 400 ppm - ACGIH STEL Isopropanol 67-63-0 - 200 ppm - ACGIH TWA Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Eye protection : No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 293 of 377 Page 293 of 377 Page 293 of 377 Page 293 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 6/14 Form : aerosol Color : clear Odor : characteristic Odour Threshold : No data available pH : Not applicable Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 22 °C 71.6 °F Evaporation rate : No data available Flammability (solid, gas) : Sustains combustion Upper/lower flammability or explosive limits : No data available Vapour pressure : Not applicable Vapour density : No data available Relative density : 0.81 g/cm3 at 21 °CGLP: yes Solubility(ies) : negligible Partition coefficient: n- : No data available Page 294 of 377 Page 294 of 377 Page 294 of 377 Page 294 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 7/14 octanol/water Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 3 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Stable under recommended storage conditions. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Danger Page 295 of 377 Page 295 of 377 Page 295 of 377 Page 295 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 8/14 Acute oral toxicity : NA GHS LD50 estimated > 5,000 mg/kg Acute inhalation toxicity : NA GHS LC50 (dust and mist) estimated > 5.47 mg/l Acute dermal toxicity : NA GHS LD50 estimated > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Acute toxicity No classification proposed - Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard Category 1 - Aggravated Medical : None known. Page 296 of 377 Page 296 of 377 Page 296 of 377 Page 296 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 9/14 Condition 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Distillates (petroleum), hydrotreated light static test LC50 Lepomis macrochirus 2.2 mg/l 96 h Carbon dioxide No data available Isopropanol LC50 Pimephales promelas (fathead minnow) 9,640 mg/l 96 h Cypermethrin LC50 mykiss (rainbow trout) 0.00283 mg/l 96 h NOEC Pimephales promelas (fathead minnow) 0.00001 mg/l 28 d Prallethrin LC50 mykiss (rainbow trout) 0.012 mg/l 96 h Toxicity to aquatic invertebrates Distillates (petroleum), hydrotreated light No data available Components End point Species Value Exposure time Components End point Species Value Exposure time Page 297 of 377 Page 297 of 377 Page 297 of 377 Page 297 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 10/14 Carbon dioxide No data available Isopropanol EC50 Daphnia magna (Water flea) 13,299 mg/l 48 h Cypermethrin EC50 Daphnia magna (Water flea) 0.00471 mg/l 48 h NOEC Daphnia magna (Water flea) 0.00004 mg/l 21 d Prallethrin EC50 Daphnia magna (Water flea) 0.0062 mg/l 48 h Toxicity to aquatic plants Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol EC50 Desmodesmus subspicatus (green algae) > 1,000 mg/l 72 h Cypermethrin ErC50 No data available > 0.0033 mg/l 72 h Prallethrin No data available Pseudokirchneriella subcapitata (green algae) 2 mg/l 96 h Persistence and degradability Component Biodegradation Exposure time Summary Components End point Species Value Exposure time Page 298 of 377 Page 298 of 377 Page 298 of 377 Page 298 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 11/14 Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol 53 % 5 d Readily biodegradable Cypermethrin 0.6 - 1.4 % 33 d Not readily biodegradable. Prallethrin No data available Not readily biodegradable. Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Distillates (petroleum), hydrotreated light 61 - 159 No data available Carbon dioxide No data available No data available Isopropanol 0.96 estimated 0.05 Cypermethrin 373.4 Measured 5.3 - 5.6 Prallethrin No data available 4.49 Mobility Component End point Value Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol No data available Cypermethrin Koc 80653 - 574360 Prallethrin No data available PBT and vPvB assessment Component Results Distillates (petroleum), hydrotreated light Not fulfilling PBT and vPvB criteria Isopropanol Not fulfilling PBT and vPvB criteria Page 299 of 377 Page 299 of 377 Page 299 of 377 Page 299 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 12/14 Cypermethrin Not fulfilling PBT and vPvB criteria Prallethrin Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper shipping name AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 Transport hazard class(es) 2.1 2 2.1 Packing group - - - Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION FIFRA Labeling This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to Page 300 of 377 Page 300 of 377 Page 300 of 377 Page 300 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 13/14 certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: CONTENTS UNDER PRESSURE. Exposure to temperatures above 130° F may cause bursting. Extremely flammable. This product is extremely toxic to fish and aquatic invertebrates. Drift and runoff may be hazardous to fish in water adjacent to treated areas. Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Registration # / Agency 4822-553/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 3 Reactivity 0 Page 301 of 377 Page 301 of 377 Page 301 of 377 Page 301 of 377 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 14/14 NFPA Ratings Health 2 Fire 3 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 302 of 377 Page 302 of 377 Page 302 of 377 Page 302 of 377 ---PAGE BREAK--- Revision Date: 16-Apr-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: SHINE PLUS Product Number: 3025 , 3027 Recommended Use: Cleaning agent Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Reproductive Toxicity: Category 2 GHS Label Elements Signal Word: Warning Hazard Statements: Suspected of damaging fertility or the unborn child Precautionary Statements: Prevention: Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wear eye / face protection Wear protective gloves Response: If exposed or concerned: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Store locked up. Disposal: Dispose of contents and container in accordance with local, state and federal regulations. Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • May cause eye irritation. • May cause skin irritation. • Keep out of reach of children. Page 1 / 5 Symbols: Page 303 of 377 Page 303 of 377 Page 303 of 377 Page 303 of 377 ---PAGE BREAK--- 3025 - SHINE PLUS Revision Date: 16-Apr-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 40-70 dimethyl siloxane, hydroxyl-terminated 70131-67-8 10-30 aminofunctional siloxane 68554-54-1 1-5 alcohol ethoxylate 84133-50-6 1-5 556-67-2 0.1-1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Page 2 / 5 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Page 304 of 377 Page 304 of 377 Page 304 of 377 Page 304 of 377 ---PAGE BREAK--- 3025 - SHINE PLUS Revision Date: 16-Apr-2015 Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 65909 mg/kg ATEmix (dermal): 11658 mg/kg 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: White Odor: Floral fragrance pH: 4.8-5.3 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.992 Solubility(ies): Miscible in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 305 of 377 Page 305 of 377 Page 305 of 377 Page 305 of 377 ---PAGE BREAK--- 3025 - SHINE PLUS Revision Date: 16-Apr-2015 Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available 556-67-2 = 1540 mg/kg ( Rat ) > 2400 mg/kg ( Rat ) > 4640 mg/kg ( Rabbit ) = 794 µL/kg ( Rabbit ) > 12.7 mg/kg ( Rat ) 4 h > 17.6 mg/L ( Rat ) 1 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea alcohol ethoxylate 84133-50-6 Not Available 3.2: 96 h Pimephales promelas mg/L LC50 Not Available 3.2: 48 h water flea mg/L EC50 556-67-2 Not Available 500: 96 h Brachydanio rerio mg/L LC50 1000: 96 h Lepomis macrochirus mg/L LC50 Not Available 25.2: 24 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: Yes Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 dioxane - 123-91-1 Carcinogen formaldehyde - 50-00-0 Page 4 / 5 Carcinogen acetaldehyde - 75-07-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. Page 306 of 377 Page 306 of 377 Page 306 of 377 Page 306 of 377 ---PAGE BREAK--- 3025 - SHINE PLUS Revision Date: 16-Apr-2015 16. OTHER INFORMATION Revision Date: 16-Apr-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1* Flammability: 0 Physical Hazards: 0 Page 307 of 377 Page 307 of 377 Page 307 of 377 Page 307 of 377 ---PAGE BREAK--- Safety Data Sheet Supercedes Date 10/25/2013 Issuing Date 06/19/2015 1. PRODUCT AND COMPANY IDENTIFICATION Product Name SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M Product Code J109 Recommended use Lubricant Chemical nature Hydrocarbons Mixture Information on Manufacturer Emergency Telephone Number CERTIFIED LABS, DIV. OF NCH CORP. CHEMTREC® [PHONE REDACTED] BOX 152170 IRVING, TEXAS 75015 Telephone inquiry [PHONE REDACTED] 2. HAZARD IDENTIFICATION Color Dark green Physical state liquid Odor Fish GHS Classification Physical Hazards None Health Hazard Serious Eye Damage/Eye Irritation Category 2B Other hazards None Labeling Signal Word WARNING Hazard statements H320 - Causes eye irritation Precautionary Statements P264 - Wash face, hands and any exposed skin thoroughly after handling P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists, get medical attention. 10 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS No. Weight % Petroleum distillates, hydrotreated heavy paraffinic DMSO extractable) 64742-54-7 60-100 Petroleum distillates, solvent dewaxed heavy paraffinic DMSO extractable) 64742-65-0 3-7 Ethylene-Propylene polymer 9010-79-1 1-5 Petroleum distillates, solvent-refined light paraffinic DMSO extractable) 64741-89-5 1-5 Magnesium long chain alkaryl sulphonate 252312-98-4 1-5 Long Chain Alkaryl Amine 36878-20-3 1-5 Polybutene 9003-29-6 1-5 Polyolefin amide alkeneamine borate 84605-20-9 1-5 Phosphorodithiotic acid, mixed O, O-bis(sec-Bu and isooctyl) esters, zinc salts 113706-15-3 1-5 4. FIRST AID MEASURES General advice Avoid contact with skin, eyes and clothing. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists. Skin Contact Wash off with soap and plenty of water. Get medical attention if irritation develops and persists. Page 1 / 4 Page 308 of 377 Page 308 of 377 Page 308 of 377 Page 308 of 377 ---PAGE BREAK--- Inhalation If inhaled, remove to fresh air. Get medical attention if occur. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if occur. Rinse mouth. Notes to physician Treat 5. FIRE-FIGHTING MEASURES Flash Point > 400 °F / > 204 °C Method ASTM D-92 Flammability Limits in Air Not applicable. Upper: No data available Lower: No data available Suitable Extinguishing Media Carbon dioxide (CO2). Dry chemical. Water spray. Foam. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards arising from the chemical Material can create slippery conditions. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, NOHSC (approved or equivalent) and full protective gear. NFPA Health 1 Flammability 1 Instability 0 HMIS Health 1 Flammability 1 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Prevent further leakage or spillage if safe to do so. Material can create slippery conditions. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Neutralizing Agent Not applicable. 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Storage Store in original container. Keep containers closed in a dry, cool and well-ventilated place. Storage Temperature Minimum 0 °F / -18 °C Maximum 120 °F / 49 °C Storage Conditions Indoor X Outdoor X Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH Petroleum distillates, hydrotreated heavy paraffinic DMSO extractable) TWA: 5 mg/m3 STEL: 10 mg/m3 TWA: 5 mg/m3 No data available Petroleum distillates, solvent dewaxed heavy paraffinic DMSO extractable) TWA: 5 mg/m3 STEL: 10 mg/m3 TWA: 5 mg/m3 No data available Petroleum distillates, solvent-refined light paraffinic DMSO extractable) TWA: 5 mg/m3 STES: 10 mg/m3 TWA: 5 mg/m3 No data available Polybutene 5 mg/m3 as oil mist 10 mg/m3 as oil mist No data available Engineering Measures Ensure adequate ventilation, especially in confined areas. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection For prolonged or repeated contact, use protective gloves with appropriate chemical resistance. Respiratory Protection In case of inadequate ventilation wear respiratory protection. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Viscosity Semi-viscous Color Dark green Odor Fish Odor Threshold Not applicable Appearance Transparent pH Not applicable Specific Gravity 0.859 Evaporation Rate No data available Percent Volatile (Volume) 0 J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M Issuing Date 06/19/2015 Issuing Date 06/19/2015 Issuing Date 06/19/2015 Issuing Date 06/19/2015 Page 2 / 4 Page 309 of 377 Page 309 of 377 Page 309 of 377 Page 309 of 377 ---PAGE BREAK--- VOC Content 0.9 VOC Content (g/L) 0 Vapor Pressure <0.1mmHg @ 70 F Vapor Density 4.7 (Air = 1.0) Solubility Negligible n-Octanol/Water Partition No data available Melting Point/Range No data available Decomposition Temperature No data available Boiling Point/Range No data available Flammability (solid, gas) No data available Flash Point > 400 °F / > 204 °C Method ASTM D-92 Autoignition Temperature No information available. Flammability Limits in Air Not applicable Upper: No data available Lower: No data available 10. STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous polymerization does not occur. Conditions to Avoid None known. Incompatible Products Strong oxidizing agents. Decomposition Temperature No data available Hazardous Decomposition Products Carbon oxides. Possibility of Hazardous Reactions None under normal processing. 11. TOXICOLOGICAL INFORMATION Product Information No information available. The following values are calculated based on chapter 3.1 of the GHS document Oral LD50 No information available Dermal LD50 No information available Inhalation LC50 Gas No information available Mist No information available Vapor No information available Principle Route of Exposure Skin contact, Eye contact. Primary Routes of Entry Eye contact. Acute Effects: Eyes May cause eye irritation. Skin May cause skin irritation. Inhalation Low hazard for usual industrial or commercial handling. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Toxicity Prolonged skin contact may defat the skin and produce dermatitis. Target Organ Effects Heart, Liver, Lungs, and Kidneys. Aggravated Medical Conditions Skin disorders, Liver disorders, Kidney disorders, Respiratory disorders. Component Information Acute Toxicity Component Oral LD50 Dermal LD50 Inhalation LC50 Draize Test Other Petroleum distillates, hydrotreated heavy paraffinic DMSO extractable) > 5000 mg/kg (Rat) > 5000 mg/kg (Rabbit) no data available no data available no data available Petroleum distillates, solvent dewaxed heavy paraffinic DMSO extractable) >5000 mg/kg (rat) >5000 mg/kg (rabbit) no data available no data available no data available Petroleum distillates, solvent- refined light paraffinic DMSO extractable) > 5000 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) = 2.18 mg/L ( Rat ) 4 h no data available no data available Long Chain Alkaryl Amine > 5000 mg/kg ( Rat ) no data available no data available no data available no data available Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects Polybutene no data available no data available no data available no data available Heart, liver, kidney, lung Carcinogenicity Contains no ingredient listed as a carcinogen. 12. ECOLOGICAL INFORMATION Product Information No information available. Component Information Component Toxicity to Algae Toxicity to Fish Microtox Crustacea log Pow Petroleum distillates, hydrotreated heavy paraffinic DMSO extractable) No information available. LC50 > 5000 mg/L mykiss 96 h No information available 1000: 48 h Daphnia magna mg/L EC50 N/A Petroleum distillates, solvent dewaxed heavy paraffinic No information available. LC50 > 5000 mg/L mykiss 96 h No information available 1000: 48 h Daphnia magna mg/L EC50 N/A J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M Issuing Date 06/19/2015 Issuing Date 06/19/2015 Issuing Date 06/19/2015 Issuing Date 06/19/2015 Page 3 / 4 Page 310 of 377 Page 310 of 377 Page 310 of 377 Page 310 of 377 ---PAGE BREAK--- DMSO extractable) Petroleum distillates, solvent- refined light paraffinic DMSO extractable) No information available. LC50 > 5000 mg/L mykiss 96 h No information available 1000: 48 h Daphnia magna mg/L EC50 N/A Long Chain Alkaryl Amine No information available. LC50 > 1000 mg/L Pimephales promelas 96 h No information available No information available. N/A Persistence and Degradability No information available. Bioaccumulation No information available. Mobility No information available. 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations. Container Disposal Empty containers should be taken for local recycling, recovery, or waste disposal. 14. TRANSPORT INFORMATION DOT Not regulated TDG Not regulated ICAO Not regulated IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Component CAS No. Weight % SARA 313 - Threshold Values Phosphorodithiotic acid, mixed O, O-bis(sec-Bu and isooctyl) esters, zinc salts 113706-15-3 1-5 1.0 SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CERCLA 16. OTHER INFORMATION Prepared By Muneerah Travis Supercedes Date 10/25/2013 Issuing Date 06/19/2015 Reason for Revision No information available. Glossary No information available. List of References. No information available. CERTIFIED LABS, DIV. OF NCH CORP.assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this document is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M J109 - SPECTRA XTREME 15W40 CJ-4, 1250 LT PWC TOTE, NAC M M Issuing Date 06/19/2015 Issuing Date 06/19/2015 Issuing Date 06/19/2015 Issuing Date 06/19/2015 Page 4 / 4 Page 311 of 377 Page 311 of 377 Page 311 of 377 Page 311 of 377 ---PAGE BREAK--- SAFETY DATA SHEET (SDS) 1 - IDENTIFICATION SUPER GEAR LUBE 150 Chemical family: Petroleum Hydrocarbon Recommended use: Gear Lubricant Tower Oil & Technology Co. 4300 South Tripp Ave. Chicago, IL 60632 Information telephone (773) 927-6161 (7:30 AM to 4 PM, CST, Monday to Friday) 24 Hr. emergency telephone CHEMTREC: (800) 424-9300 2 - HAZARDS IDENTIFICATION OSHA/HCS Status:This material is classified as non-hazardous under OSHA regulations (29 CFR 1910.1200) (Hazcom 2012) Classification of chemical/mixture: Not Classified Signal word: None required. Hazard Pictogram: None required. Hazard statement: None required. Precautionary statement: None required. 3 - COMPOSITION/ INFORMATION ON INGREDIENTS Chemical name CAS # Concentration Ingredients classified as non-hazardous under OSHA regulations (29CFR 1900-1200) (Hazcom 2012) Material Name: SUPER GEAR LUBE 150 Revision Date: June 23, 2015 Page 1 of 4 Page 312 of 377 Page 312 of 377 Page 312 of 377 Page 312 of 377 ---PAGE BREAK--- 4 - FIRST-AID MEASURES Description of first aid measures: Inhalation: If overcome by fumes from hot product, move to fresh air. Get medical attention. Ingestion: Do not induce vomiting. Get medical attention. Skin: Wash with warm water and mild soap. Remove contaminated clothing. Eye: Hold eyelids apart and flush with plenty of water for at least 15 minutes. Check for contact lenses, remove if present and easy to do, continue rinsing an additional 10 minutes or until irritation subsides . If irritation persists get medical attention. and effects, both acute and delayed: Acute: Possible skin and transient eye irritation. Chronic: Repeated or prolonged skin contact may remove natural oils, resulting in development of dermatitis. 5 - FIRE-FIGHTING MEASURES Extinguishing media: Suitable: Use water fog or spray, foam, dry chemicals, or carbon dioxide (CO2) to extinguish flames. Unsuitable: Do not use straight streams of water, as this will spread the fire. Specific hazards and combustion products: Products may include and are not limited to oxides of carbon, sulfur, and phosphorus upon combustion. Special protective equipment and precautions for fire-fighters: Use standard protective equipment and in enclosed spaces, recommend self-contained breathing apparatus (SCBA) with full face-piece operated in a pressure- demand or other positive mode and full body protective clothing. Use water spray to cool fire exposed surfaces and to protect personnel. If a spill has not ignited, use water spray to disperse vapors. Treat as oil fire. 6 - ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: All persons dealing with the spill should wear appropriate personal protective equipment. Keep others away from spill. Restrict access to area until the spill has been cleaned up. Extinguish all sources of ignition. Methods and materials for containment and cleaning up: Extinguish all sources of ignition. Contain spill, soak up in absorbent medium, earth, sand or other non-combustible material. Transfer to suitable containers. If spill enters sewer, notify proper authorities. 7 - HANDLING AND STORAGE Precautions for safe handling: Minimize breathing vapors. Avoid prolonged or repeated skin contact. Wash thoroughly before meals and at end of work periods. Launder or dry-clean soiled clothing before reuse. Personnel in close vicinity of oil mists above TLV limit should wear approved breathing devices. Conditions for safe storage: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants. Incompatible materials: Strong oxidizing agents. 8 - EXPOSURE CONTROLS/ PERSONAL PROTECTION Exposure limits: No exposure standards have been established for this material. Engineering controls: Good general ventilation should be used. Individual protection measures and personal protective equipment: Splash goggles, face shield, chemical and oil resistant gloves, impervious apron if needed to avoid prolonged skin contact. TLV (THRESHOLD LIMIT VALUE): 5mg/m3 as oil mist in air over an 8 hour daily exposure (ACGIH) Material Name: SUPER GEAR LUBE 150 Revision Date: June 23, 2015 Page 2 of 4 Page 313 of 377 Page 313 of 377 Page 313 of 377 Page 313 of 377 ---PAGE BREAK--- 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Amber liquid. Odor: Mineral Oil. Odor threshold: Data currently unavailable. Product pH: N/A Freezing point: N/A Boiling point: N/A Flash point: Typical 380°F COC Evaporation rate: <0.01 (nButyl Acetate=`1) Flammability: Data currently unavailable. Upper/lower flammability limits: LEL: 0.9% UEL: 7.0% Vapor pressure: <0.01 mm Hg Vapor density: >1 (AIR = 1) Relative density: 0.92 (Water=1) Solubility: Negligible Partition coefficient (n-octanol/water): Information not available. Auto-ignition temperature: Data currently unavailable. Decomposition temperature: Data currently unavailable. Viscosity: Typical 735 SUS @ 100°F 10 - STABILITY AND REACTIVITY Chemical stability: Material is stable under normal conditions. Possibility of hazardous reactions: Hazardous polymerization will not occur. Conditions to avoid: Avoid heating above flash point temperatures, sparks, open flames and other ignition sources. Incompatible materials: Strong oxidizing agents. Hazardous decomposition products: Material does not decompose at ambient temperatures. Oxides of carbon, sulfur, and phosphorus upon combustion. 11 - TOXICOLOGICAL INFORMATION Information on likely routes of exposure: Inhalation: Yes Ingestion: Yes Skin: Yes Eye: Yes Potential of exposure: Inhalation: May cause irritation of respiratory tract. Avoid breathing vapors or mist of this product. Ingestion: Do not ingest. Small amounts (a tablespoonful) swallowed during normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause injury. Get medical attention if appear. Skin: Minimally toxic under normal use. May be mildly irritating with prolonged and/or repeated skin contact. Eye: Contact with eyes may cause irritation. Toxicological data: No data available. NTP, IARC or OSHA carcinogen: None of the constituents of this product have been identified as possible or proven carcinogens by NTP, IARC, or OSHA. 12 - ECOLOGICAL INFORMATION Ecotoxicity: May cause long-term adverse effects in the aquatic environment. Persistence and degradability: Data not available. Bioaccumulative potential: Data not available. Mobility in soil: Data not available. Other adverse effects: None known. Material Name: SUPER GEAR LUBE 150 Revision Date: June 23, 2015 Page 3 of 4 Page 314 of 377 Page 314 of 377 Page 314 of 377 Page 314 of 377 ---PAGE BREAK--- 13 - DISPOSAL CONSIDERATIONS Waste disposal method: Dispose of in accordance with federal, state and local regulations. 14 - TRANSPORT INFORMATION DOT Shipping: Not regulated by the U.S. Department of Transportation as a hazardous material. 15 - REGULATORY INFORMATION Sara III (Superfund Amendment and Reauthorization Act of 1986) 40 CFR Part 372 and 40 CFR Part 355 Sections 302, 304 and 40 CFR Part 355 – Extremely Hazardous Substances: Component % RQ (lbs.) TPQ (lbs.) CAS# NONE – – – – Sections 311, 312 and 40 CFR Part 355 – Hazard Categories: ACCUTE(IMMEDIATE HEALTH HAZARD): YES FIRE HAZARD: YES CHRONIC (DELATED HEALTH HAZARD): NO REACTIVE HAZARD: NO SUDDEN PRESSURE RELEASE: NO Sections 313 and 40 CFR Part 372 – Toxic Chemicals: Component % CAS# NONE – – CERCLA (Comprehensive Environmental Response, Compensation and Liability Act) Section 102 and 40 CFR Part 302 – Hazardous Substances: Component % RQ (lbs.) CAS# NONE – – – CLEAN WATER ACT Under section 311 of this act, contamination of surface waters by petroleum products must be reported immediately to the National Response Center. SECTION 311 DOES APPLY TO SUPER GEAR LUBE 150 California Proposition 65: None of the ingredients are listed. TSCA (Toxic Substances Control Act): All components of this formula are listed in the TSCA inventory. 16 - OTHER INFORMATION Preparation Date: August 1, 2014 Revision Date: June 23, 2015 The information appearing in this document is based upon data obtained from raw material manufacturers and/or recognized technical sources. While this information is believed to be correct, TOWER OIL & TECHNOLOGY makes no representations as to its accuracy or sufficiency, usage, or the hazards connected with the use of this material. Since this product may be applied under conditions unfamiliar to us or beyond our control, we claim no responsibility for the results of its use, and users are responsible for the verification of this information under their own operation conditions to determine whether the product is suitable for their particular purposes, and these users assume all risks of their use, handling, and disposal of the product. This information relates only to the product designated above and does not relate to its use in combination with any other material in any other process. Material Name: SUPER GEAR LUBE 150 Revision Date: June 23, 2015 Page 4 of 4 Page 315 of 377 Page 315 of 377 Page 315 of 377 Page 315 of 377 ---PAGE BREAK--- SAF-T-LOK Material Safety Data Sheet International Corporation T70 Issue Date: 10/30/14 SECTION I - PRODUCT AND COMPANY INFORMATION Product Name: T70Threadlocker Product Type: Anaerobic Adhesive/ Sealant Part Numbers: 27002/ 27021/27031/27041/ 27043/155-0695/154-9731 Hazard Rating: Health: 1 Fire: 1 Reactivity: 0 Company Identification: SAF-T-LOK International Corporation 300 EISENHOWER LANE NORTH LOMBARD, IL 60148 Contact: Helen Champagne Telephone/ Fax: (630) 495-2001 Emergency Phone (24 Hour): (703) 527-3887 Chemtrec (24 Hour): (800) 424-9300 Preparer: Ind. Hygiene Department Internet: www.saftlok.com Product Class: Mixture DOT Hazard Class: N/A Shipping Name: Unrestricted SECTION II - INGREDIENT AND HAZARD INFORMATION Components CAS# Percent dimethacrylate 109-16-0 40-70 Bis-phenol A fumerate resin 39921-03-4 20-40 Saccharin 81-07-2 1-5 Cumene hydroperoxide 80-15-9 0.1-5 SECTION III - HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW EMERGENCY OVERVIEW Physical appearance: Liquid HMIS Physical color: Red Health: 1 Odor: Mild / Inoffensive Flammability: 1 Reactivity: 0 Personal Protection: B WARNING; MAY CAUSE: EYE IRRITATION SKIN IRRITATION RESPIRATORY TRACT IRRITATION MAY IRRITATE EXISTING ALLERGIC SKIN CONDITIONS Relative routes of entry: Skin, Inhalation, Eyes, Ingestion Skin Contact: Usually no effect, however, as with any chemical, prolonged, excessive, or repeated exposure may cause mild to moderate skin irritation, exhibited by redness, drying and cracking of unprotected skin. Page 1 of 4 Product: T70 Threadlocker Page 316 of 377 Page 316 of 377 Page 316 of 377 Page 316 of 377 ---PAGE BREAK--- Eye Contact: May irritate with slight pain and redness. Respiratory/ Inhalation: Usually none, however, as with any chemical product, some irritation may occur. Ingestion: Amounts transferred to mouth by fingers, etc, during normal operation should not cause injury. Medical conditions generally aggravated by exposure: None known, however any chemical product may enhance allergies already present in certain individuals. SECTION IV – FIRST AID INSTRUCTIONS Skin Contact: Remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Get medical attention if occur. Wash clothing before reuse. Eye Contact: Flush with water for at least 15 minutes holding eyelid open. Get medical attention if persist. Respiratory / Inhalation: Remove to fresh air, if develop get medical attention. Ingestion: Do not induce vomiting. Obtain medical attention if develop. SECTION V – FIRE FIGHTING INSTRUCTIONS Flash Point: 96°C Unusual Fire and Explosion Hazards: None Flammable Limits: LEL: N/A, UEL: N/A Extinguishing Media: Carbon Dioxide, Foam, Dry Chemicals Fire Fighting Procedures: Air mask and procedures for fighting chemical fires SECTION VI -ACCIDENTAL RELEASE MEASURES Special Precautions: None known. Follow general precautions shown below. Environmental precautions: Prevent material from entering floor drains, sewers, or any bodies of water. Clean up methods: Scoop up into waste container or soak up with absorbent material. Store in a closed container until disposal. SECTION VII - HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing vapors. Wash hands thoroughly at mealtime and end of shift. Storage: Store in a cool location (60-90°F) in a well ventilated area away from sources of heat. Keep container closed when not in use. Personal Protection: Wear personal protective equipment as outlined in Section VIII of this MSDS. SECTION VIII – EXPOSURE CONTROLS AND PERSONAL PROTECTION Respiratory Protection: No respiratory protection required, but normal good ventilation is recommended. Forced ventilation may be required if concentrations exceed normal use exposure. Page 2 of 4 Product: T70 Threadlocker Page 317 of 377 Page 317 of 377 Page 317 of 377 Page 317 of 377 ---PAGE BREAK--- Skin Protection: Use impermeable gloves (neoprene, butyl rubber, natural rubber), as necessary to avoid skin contact, as well as proper clothing or plastic apron. Wash hands before eating, drinking, or using restroom. Eye Protection: Safety goggles or glasses are recommended. Eye Washes: Eye wash stations should be located within 100 feet or 10 second walk of the work area. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Red Odor: Mild Boiling Point: > 149°C Specific Gravity: 1.1 Vapor Density (Air = N/A Vapor Pressure (mm Hg.): < 5 @30°F pH: N/A Melting Point: N/A Evaporation Rate: N/A Solubility in Water: Partial V.O.C. Content: < 0.1% SECTION X –STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Hazardous decomposition byproducts: Oxides of carbon, Oxides of nitrogen Incompatibility: Reducing agents. Strong Oxidizers SECTION XI – TOXICOLOGICAL INFORMATION Product Toxicity: Estimated oral LD50 greater than 10,000 mg/kg. Estimated dermal LD50 greater than 5000 mg/kg. Carcinogen Status Ingredients: Health Effect NTP IARC OSHA Dimethacrylate ALG IRR NO NO NO Saccharin N/A NO NO NO Cumene Hydroperoxide COR, ALG, IRR NO NO NO Abbreviations: ALG Allergen IRR Irritant COR Corrosive SECTION XII – ECOLOGICAL DATA Water Hazard: Do not allow entry into drains or surface water SECTION XIII – DISPOSAL CONSIDERATIONS Recommended method of disposal: Unused product: Dispose of according to Federal, State and local regulations. EPA Hazardous Waste Number; Not an RCRA hazardous waste. Page 3 of 4 Product: T70 Threadlocker Page 318 of 377 Page 318 of 377 Page 318 of 377 Page 318 of 377 ---PAGE BREAK--- SECTION XIV – SHIPPING AND TRANSPORTATION INFORMATION U.S. Department of Transportation Ground (49 CFR) Proper Shipping Name: Unrestricted Hazard Class or Division: None Identification Number: None Packing Group: None International Air Transportation (OCAO/IATA): Proper Shipping Name: Unrestricted Hazard Class or Division: None Identification Number: None Packing Group: None Water Transportation (IMO/IMDG): Proper Shipping Name: Unrestricted Hazard Class or Division: None Identification Number: None Packing Group: None Marine Pollutant: None SECTION XV – REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. CERCLA/SARA Section 311/312: This product contains the following toxic chemical subject to the reporting requirements of section 313 of the Emergency Planning and Community Right- To-Know Act of 1986 (40 CFR): Cumene hydroperoxide. California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List. WHMIS hazard class D.2.B SECTION XVI – OTHER INFORMATION Revision date: 10/30/14 By: Human Resource Department DISCLAIMER: The information on this material safety data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. SAF-T-LOK International Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of SAF-T-LOK International Corporation products. Page 4 of 4 Product: T70 Threadlocker Page 319 of 377 Page 319 of 377 Page 319 of 377 Page 319 of 377 ---PAGE BREAK--- Product Name TDL Print Date: 6/11/15 Product Code: 16-TDL Total pages: Page 1 of 7 1 SAFETY DATA SHEET 1. Product and Company Identification Product Name: TDL Product Code: 16-TDL Product Type: Aerosol Product Use: Dry Film lubricant Manufacturer: The Blaster Corp Revision Date: 06/11/2015 Address: 8500 Sweet Valley Dr. Phone: (216)-901-5800 Valley View, OH 44125 www.blastercorp.com 24 Hour Emergency telephone number: Chemtrec (800) 424-9300 NOTE: The information contained herein is accurate to the best of our knowledge. We do not suggest or guarantee that any hazards listed herein are the only ones which exist. We provide this information as guidance for providing personal protection to your employees. The user has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. The user must meet all applicable safety and health standards. We provide this information as guidance for providing personal protection to your employees. 2. Hazard Identification Classification of substance or mixture: Flammable Aerosols Category 1 Gas under pressure Compressed Gas Skin Irritation Category 2, Specific target organ toxicity, single exposure Category 3 Central nervous system, Aspiration hazard Category 1 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1 GHS Label elements: This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission regulations which take precedence over OSHA Hazard Communication labeling. The actual container label will not include the label elements below. The labeling below applies to industrial/professional products. Page 320 of 377 Page 320 of 377 Page 320 of 377 Page 320 of 377 ---PAGE BREAK--- Product Name TDL Print Date: 6/11/15 Product Code: 16-TDL Total pages: Page 2 of 7 2 Pictograms Signal Word: Danger Hazard Statement(s) H222 Extremely flammable aerosol H229 Pressurized container: may burst if heated H280 Contains gas under pressure, may explode if heated H304 May be fatal if swallowed and enters airways H315 Causes Skin irritation H400 Very toxic to aquatic life H410 Very toxic to aquatic life with lasting effects Precautionary Statements: P210 Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. P251 Pressurized container: Do not pierce or burn, even after use P261 Avoid breathing dust/fume/gas/mist vapors/spray P264 Wash…thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 If Swallowed: Immediately call a poison center or doctor P304+P340 If Inhaled: Remove person to fresh air and keep comfortable for breathing. P332+P352 If skin irritation occurs: wash with plenty of water and soap. P403+P233 Store in well ventilated place Keep container closed. P410+P412 Protect from sunlight. Don not expose to temperatures exceeding 50°C/122°F P501 Dispose of contents/container in accordance with local/regional regulations. 3. Composition Information on ingredients Ingredients CAS # Percent n-Heptane 142-82-5 85-99% Toluene 108-88-3 0-2% Polytetrafluoroethylene 9002-84-0 1-5% Carbon Dioxide 124-38-9 .1-10 % 4. First Aid Measures Eye Contact: Flush with warm water for 15 minutes. Seek medical attention. Skin Contact: Page 321 of 377 Page 321 of 377 Page 321 of 377 Page 321 of 377 ---PAGE BREAK--- Product Name TDL Print Date: 6/11/15 Product Code: 16-TDL Total pages: Page 3 of 7 3 Wash with soap and water. Remove any contaminated clothing and launder before reusing. If irritation persists, seek medical attention. Inhalation: Remove exposed individual to fresh air, protecting yourself. Restore breathing if necessary. Contact a physician. Ingestion: Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. 5. Fire Fighting Measures Flash Point: Flash point of liquid portion < 30°F Flammable limits in air, % by volume: Upper: No Information Lower: No Information Extinguishing Media: Dry chemical, carbon dioxide, halon, or foam is recommended. Water spray may be used to cool containers or structures. Halon may decompose into toxic materials and carbon dioxide will displace oxygen, take proper precautions when using these materials. Unusual Fire & Explosion Hazards: This material may be ignited by extreme heat, sparks, flames or other ignition sources (static electricity). Vapors are heavier than air and will collect in low areas (sewers) or travel considerable distances. If containers are not cooled in a fire, they may rupture and ignite. Special Fire Fighting Procedures: At elevated temperatures (over 130F) aerosol container may burst, vent or rupture; use equipment or shielding to protect personnel. Cooling exposed containers with streams of water may be helpful. Emergency responders should wear self-contained breathing apparatus. Wear other protective gear as conditions warrant. Keep unauthorized people out and try to contain spills or leaks if it can be done safely. Material will float on water, avoid spreading the fire. 6. Accidental Release Measures Spill or Leak Instructions Contain spill with dikes of soil or nonflammable absorbent to minimize contaminated area. Avoid run-off into storm sewers and ditches leading to waterways. If required, notify state and local authorities. Place leaking containers in well-ventilated area. Clean up small spills by using a nonflammable absorbent or flushing sparingly with water. Contain larger spills with nonflammable diking or absorbent. Clean up by vacuuming or sweeping. Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Assess the spill situation, as the spill may not evolve large amounts of hazardous airborne contaminants in many outdoor spill situations. It may be advisable in some cases to simply monitor the situation until spilled product is removed. 7. Handling and Storage Page 322 of 377 Page 322 of 377 Page 322 of 377 Page 322 of 377 ---PAGE BREAK--- Product Name TDL Print Date: 6/11/15 Product Code: 16-TDL Total pages: Page 4 of 7 4 Handling: Store below 120°F in cool, dry area, out of direct sunlight and away from strong oxidizers. Do not puncture or burst. Use in accordance with good work place practices. Use with adequate ventilation. Keep containers closed when not in use. Always open containers slowly to allow any excess pressure to vent. Avoid breathing vapor. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling. Decontaminate soiled clothing thoroughly before re-use. Destroy contaminated leather clothing. Empty containers may contain residues from the product. Treat empty containers with the same precautions as the material last contained. Do not cut, weld or apply heat to empty containers Do not incinerate Storage: Store in a cool, dry area, away form heat or direct sunlight. Keep containers closed when not in use. Do not store with incompatible materials 8. Exposure Controls / Personal Protection Protective Equipment: Use gloves if necessary to prevent excessive skin contact. Do not wear contacts and always use ANSI approved safety glasses or splash shield. Engineering Controls: General or dilution ventilation is frequently sufficient as the sole means of controlling employee exposure. Local ventilation is usually preferred. Use a NIOSH approved respirator if ventilation is not adequate to maintain exposures below TLV levels. Respiratory Protection: Use adequate ventilation to maintain exposure limits. If the exposure limits of the products or any of its components is exceeded, an approved organic vapor mask should be used (consult your safety equipment supplier). Above exposure levels an approved self-contained breathing apparatus or airline respirator with full face-piece is required Other Suggested Equipment: Eye wash station and emergency showers should be available. Spill containment equipment should be available. Discretion Advised: We. take no responsibility for determining what measures are required for personal protection in any specific application. The general information should be used with discretion. xposure guidelines: Ingredients CAS # Percent Exposure Limits n-Heptane 142-82-5 85-99% OSHA (TWA 4 00 ppm ACGIH (TWA) 400 ppm Toluene 108‐88‐3 1-2% OSHA (TWA) 200 ppm ACGIH (TLV) 20 ppm Polytetrafluoroethylene 9002-84-0 1-5% ACGIH (TLV) 10 mg/m3 Inhalable particles Carbon Dioxide 124-38-9 .1-10 % OSHA (PEL) 5000 ppm Page 323 of 377 Page 323 of 377 Page 323 of 377 Page 323 of 377 ---PAGE BREAK--- Product Name TDL Print Date: 6/11/15 Product Code: 16-TDL Total pages: Page 5 of 7 5 ACGIH (TLV_TWA) 5000 ppm 9. Physical and Chemical Properties Boiling Point: NA Specific Gravity: <1 Vapor Density: >1(Air=1) Water Solubility: Negligible Odor/Appearance: Clear mist as dispensed from aerosol can. Evaporation Rate: Ether = 1 Slower 10. Stability and Reactivity Stability: Stable Conditions to Avoid: Heat, spark, and open flame Incompatibility: Strong-Oxidizing Agents Hazardous Decomposition: Combustion will produce Carbon Monoxide, Carbon Dioxide and hydrocarbons.. Hazardous Polymerization: Will not occur 11. Toxicological Information Component Toxicological Information: Acute oral toxicity n-HEPTANE LD 50 Rat: 17g/kg toluene LD 50 Rat 2.6 7.5 g/kg Polytetrafluoroethylene LD50 >5,000 mg/kg Acute inhalation toxicity n-HEPTANE LC 50 Rat: 65-103 g/m3 , 4 h Toluene LC 50 Rat: 8,000 ppm 49 g/m3 4h Acute dermal toxicity n-HEPTANE LD 50 Rabbit: 3400 mg/kg Toluene LD 50 Rabbit 14 g/kg Information on Toxicological Effects of Components n-Heptane Reproductive Toxicity: No evidence of developmental toxicity was found in pregnant laboratory animals (rats and mice) exposed to high vapor concentrations of unleaded gasoline and petroleum naphthas via inhalation. A two- generation reproductive toxicity study of vapor recovery gasoline did not adversely affect reproductive function or survival and development. Toluene Carcinogenicity: Exposure of rats and mice to toluene at concentrations ranging from 120-1200 ppm for two years did not demonstrate evidence of carcinogenicity. Toluene has not been listed as a carcinogen by IARC. Target Organs: Epidemiology studies suggest that chronic occupational overexposure to toluene may damage color vision. Subchronic and chronic inhalation studies with toluene produced kidney and liver damage, hearing loss and central nervous system (brain) damage in laboratory animals. Intentional misuse by deliberate inhalation of high concentrations of toluene has been shown to cause liver, kidney, and central nervous system damage, including hearing loss and visual disturbances. Reproductive Toxicity: Exposure to toluene during pregnancy has demonstrated limited evidence of developmental toxicity in laboratory animals. Decreased fetal body weight and increased skeletal variations in both inhalation and oral studies, but only at doses that were maternally toxic. No fetal toxicity was seen at doses that were not maternally toxic. Decreased sperm counts have been observed in male rats in the absence of a reduction in fertility. Toluene has been reported to cause mental or growth retardation in the children of solvent abusers who directly inhale toluene during pregnancy. Page 324 of 377 Page 324 of 377 Page 324 of 377 Page 324 of 377 ---PAGE BREAK--- Product Name TDL Print Date: 6/11/15 Product Code: 16-TDL Total pages: Page 6 of 7 6 12. Ecological Information Toxicity: The acute toxicity in aquatic organisms is expected to be between 10 and 100 mg/L, based on component data. This material should be regarded as harmful to aquatic organisms, with the potential to cause long term adverse effects in the aquatic environment. Persistence and Degradability: Heptane is expected to biodegrade in soil based on 100% degradation after 4 and 25 days in screening tests using gasoline contaminated soil and activated sewage sludge, respectively. Based on 100% degradation within 25 days during aerobic biodegradation screening tests, heptane is expected to biodegrade in natural water. 13. Disposal Considerations Do not puncture or burn containers. Give empty, leaking, or full containers to disposal service equipped to handle and dispose of aerosol (pressurized) containers. Dispose of spilled material in accordance with state and local regulations for waste that is non-hazardous by Federal definition. Note that this information applies to the material as manufactured; processing, use, or contamination may make this information inappropriate, inaccurate, or incomplete. Note that this handling and disposal information may also apply to empty containers, liners and rinsate. State or local regulations or restrictions are complex and may differ from federal regulations. This information is intended as an aid to proper handling and disposal; the final responsibility for handling and disposal is with the owner of the waste. See Section 9 - Physical and Chemical Properties. 14. Transport Information Aerosols (limited quantity), Class 2.1, ERG 126 AIR (IATA) Aerosols (limited quantity), Class 2.1, ERG 126, UN No. 1950 Vessel Aerosol (Limited Quantity), Class 2.1, UN No 1950 15. Regulatory Information Environmental Regulations SARA 302/304: None SARA 311/312: Immediate ( x ) Delayed ( ) Fire ( x ) Reactive ( ) Sudden Release of Pressure ( x ) Section 313 This product contains: Toluene 1-4% California Prop 65 WARNING! This product contains a chemical known in the State of California to cause Page 325 of 377 Page 325 of 377 Page 325 of 377 Page 325 of 377 ---PAGE BREAK--- Product Name TDL Print Date: 6/11/15 Product Code: 16-TDL Total pages: Page 7 of 7 7 cancer. BENZENE WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. BENZENE TOLUENE All the chemicals used in this product are TSCA listed. Check with your local regulators to be sure all local regulations are met. 16. Other Information Hazard ratings This information is intended solely for the use of individuals trained in the NFPA and/or HMIS systems. NFPA: Level 3 Aerosol HMIS: Health: 2 Flammability: 4 Reactivity: 0 RATING: 4-EXTREME 3-HIGH 2-MODERATE 1-SLIGHT 0-INSIGNIFICANT Note: The information contained herein is accurate to the best of our knowledge. We do not suggest or guarantee that any hazards listed herein are the only ones which exist. We make no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances. Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of other materials. This material may be released from gas, liquid, or solid materials made directly or indirectly from it. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. User must meet all applicable safety and health standards. Possession of an SDS does not indicate that the possessor of the SDS was a purchaser or user of the subject product. Page 326 of 377 Page 326 of 377 Page 326 of 377 Page 326 of 377 ---PAGE BREAK--- Material Safety Data Sheet TREMPRIME SILICONE POROUS PRIMER Version 4.0 Print Date 07/08/2012 REVISION DATE: 07/07/2012 1/6 943303 506 SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION Product Information Trade name : TREMPRIME SILICONE POROUS PRIMER Product code : 943303 506 Supplier : Tremco Canada division 220 Wicksteed Avenue Toronto, ON M4H 1G7 Telephone : (416) 421-3300 Emergency Phone: : (613) 996-6666 Product use : Coating Preparation Information Prepared by: : Sewnauth Raghunandan Date: : 07/07/2012 Telephone : (416) 421-3300 SECTION 2 - HAZARDS IDENTIFICATION Emergency Overview Clear. Liquid. May cause moderate irritation to the respiratory system. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue. Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel. Leave area to breathe fresh air. Avoid further overexposure. If persist, get medical attention. Acute Potential Health Effects/ Routes of Entry Inhalation : May cause moderate irritation to the respiratory system. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue. Eyes : Vapor and/or mist may cause eye irritation. Direct contact may cause temporary redness and discomfort. Ingestion : May cause irritation to the mouth, throat and stomach. May cause gastrointestinal irritation, nausea, and vomiting. Skin : May cause moderate irritation. Aggravated Medical Conditions Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure. Chronic Health Effects Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Prolonged or repeated overexposure to acetone may cause liver damage, Central Nervous System depression and narcosis. Repeated overexposure to ethyl silicate vapor may cause kidney, liver and lung damage based on animal experiments. Prolonged or repeated exposure may cause defatting, drying, and irritation of the skin, dermatitis, central nervous system (CNS) effects, heart muscle sensitization and hearing loss, and brain, liver, kidney, and testes damage. Toluene overexposure may cause burns of the skin, respiratory tract damage. May be harmful to the human fetus based on animal tests and limited epidemiology data. Fillers are encapsulated and not expected to be released from product under normal conditions of use. Target Organs: Skin, Eye, Lung, Liver, Kidney, Nerve, Reproductive Page 327 of 377 Page 327 of 377 Page 327 of 377 Page 327 of 377 ---PAGE BREAK--- Material Safety Data Sheet TREMPRIME SILICONE POROUS PRIMER Version 4.0 Print Date 07/08/2012 REVISION DATE: 07/07/2012 2/6 943303 506 SECTION 3 : HAZARDOUS INGREDIENTS Chemical Name CAS-No. Weight % Range Acetone 67-64-1 40.0 - 70.0 Toluene 108-88-3 10.0 - 30.0 2031-67-6 7.0 - 13.0 Tetraethoxysilane 78-10-4 1.0 - 5.0 Ethyl alcohol 64-17-5 0.1 - 1.0 The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR). SECTION 4 - FIRST AID MEASURES Get immediate medical attention for any significant overexposure. Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel.Leave area to breathe fresh air. Avoid further overexposure. If persist, get medical attention. Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical attention immediately. Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If irritation, rash or other disorders develop, get medical attention immediately. Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately. SECTION 5: FIRE / EXPLOSION HAZARDS Flash point : 0 -18 °C Method : Pensky-Martens Closed Cup Lower explosion limit : 2.3 Solvent Upper explosion limit : 13 Solvent Autoignition temperature : Not available. Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam. Hazardous combustion products : Smoke, fumes.Carbon monoxide and carbon dioxide can form.Nitrogen oxides can form. Protective equipment for firefighters : Use accepted fire fighting techniques. Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA).Water may be used to cool containers to minimize pressure build-up. Fire and explosion conditions : Vapor concentrations in enclosed areas may ignite explosively.Product may ignite if heated in excess of its flash point.Vapors may travel to sources of ignition and flashback.Closed container, may burst when exposed to extreme heat.Empty containers may contain ignitable vapors. SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately. Page 328 of 377 Page 328 of 377 Page 328 of 377 Page 328 of 377 ---PAGE BREAK--- Material Safety Data Sheet TREMPRIME SILICONE POROUS PRIMER Version 4.0 Print Date 07/08/2012 REVISION DATE: 07/07/2012 3/6 943303 506 Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area. SECTION 7 - HANDLING AND STORAGE Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when not in use. Precautions also apply to emptied containers. To prevent generation of static discharges, use bonding/grounding connection when pouring liquid. Extinguish all ignition sources including pilot lights, non- explosion proof motors and electrical equipment until vapors dissipate. Personal protective equipment must be worn during maintenance or repair of contaminated mixer, reactor, or other equipment. Keep container closed when not in use. Vapor may migrate to sources of ignition. Do not smoke, weld, generate sparks, or use flame near container. Store in sealed containers in a cool, dry, ventilated warehouse location. SECTION 8 - PREVENTIVE MEASURES/EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protection equipment Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or supplied air respirator when airborne contaminant level(s) are expected to exceed exposure limits indicated on the MSDS. Follow manufacturer's directions for respirator use. Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to reduce exposure. Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes with contaminated body parts or materials. Have eye washing facilities readily available. Protective measures : Use professional judgment in the selection, care, and use.Inspect and replace equipment at regular intervals. Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed areas.Use local exhaust when the general ventilation is inadequate. Exposure Limits Chemical Name CAS Number Regulation Limit Form Acetone 67-64-1 Ontario TWAEV: 500 ppm Ontario STEV: 750 ppm ACGIH TWA: 500 ppm ACGIH STEL: 750 ppm Toluene 108-88-3 ACGIH TWA: 20 ppm Ontario TWAEV: 20 ppm Tetraethoxysilane 78-10-4 Ontario TWAEV: 85 mg/m3 ACGIH TWA: 10 ppm Ethyl alcohol 64-17-5 Ontario TWAEV: 1,900 mg/m3 ACGIH STEL: 1,000 ppm SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State : Liquid Page 329 of 377 Page 329 of 377 Page 329 of 377 Page 329 of 377 ---PAGE BREAK--- Material Safety Data Sheet TREMPRIME SILICONE POROUS PRIMER Version 4.0 Print Date 07/08/2012 REVISION DATE: 07/07/2012 4/6 943303 506 Form : Liquid Color : Clear Odor : Aromatic Solvent pH : Not available. Vapour pressure : Not available. Vapor density : Heavier than air Melting point/range : Not available. Freezing point : Not available. Boiling point/range : 133 56 °C Water solubility : Negligible Evaporation Rate: : Not available. Specific Gravity : 0.9 % Volatile Weight : 63 % SECTION 10 - REACTIVITY / STABILITY Substances to avoid : Oxidizing agents.Strong acids.Strong bases. Stability : Stable under normal conditions. Avoid welding arcs, flames or other high temperature sources. Hazardous polymerization : Will not occur. SECTION 11 - TOXICOLOGICAL INFORMATION Acetone, CAS-No.: 67-64-1 Acute oral toxicity (LD-50 oral) 9,800 mg/kg ( Rat ) 3,000 mg/kg ( Mouse ) 5,340 mg/kg ( Rabbit ) 5.2 g/kg ( Mouse ) 5,800 mg/kg ( Rat ) Acute inhalation toxicity (LC-50) 50.1 mg/l for 8 h ( Rat ) 76 mg/l for 4 h ( Rat ) Acute dermal toxicity (LD-50 dermal) 20,000 mg/kg ( Rabbit ) 20 mg/kg ( Rabbit ) Toluene, CAS-No.: 108-88-3 Acute oral toxicity (LD-50 oral) 2,600 - 7,500 mg/kg ( Rat ) 5,000 mg/kg ( Rat ) Acute inhalation toxicity (LC-50) 26,700 mg/l for 1 h ( Rat ) 400 mg/l for 24 h ( Mouse ) 5,320 mg/l for 8 h ( Mouse ) Acute dermal toxicity (LD-50 dermal) 12,124 mg/kg ( Rabbit ) SECTION 12 - ECOLOGICAL INFORMATION No Data Available SECTION 13 - WASTE DISPOSAL CONSIDERATIONS RCRA Class : D001: Reportable Quantity = 100 lbs. (Characteristic of ignitability) This classification applies only to the material as it was originally produced. Disposal Method : Dispose according to all applicable regulations (hazardous household waste depot, or Page 330 of 377 Page 330 of 377 Page 330 of 377 Page 330 of 377 ---PAGE BREAK--- Material Safety Data Sheet TREMPRIME SILICONE POROUS PRIMER Version 4.0 Print Date 07/08/2012 REVISION DATE: 07/07/2012 5/6 943303 506 as liquid industrial waste for industrial product). SECTION 14 - TRANSPORTATION / SHIPPING DATA TDG: UN1139, COATING SOLUTION, 3, PG II CFR / DOT: UN1139, Coating solution, 3, PG II IMDG: UN1139, COATING SOLUTION, 3, PG II Further Information: The above shipping description may not be accurate for all container sizes and all modes of transportation. Please refer to Bill of Lading. SECTION 15 - REGULATORY INFORMATION North American Inventories: All components are listed or exempt from the TSCA inventory. This product or its components are listed on, or exempt from the Canadian Domestic Substances List. Canadian Regulations: WHMIS Classification : B2, D2A This is a "controlled product" under the Canadian Workplace Hazardous Materials Information System (WHMIS). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. Other Regulations: Regulatory VOC (less water and exempt solvent) : 252 g/l SECTION 16 - OTHER INFORMATION HMIS Rating : Health 2 0 = Minimum 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Flammability 3 Reactivity 1 PPE Page 331 of 377 Page 331 of 377 Page 331 of 377 Page 331 of 377 ---PAGE BREAK--- Material Safety Data Sheet TREMPRIME SILICONE POROUS PRIMER Version 4.0 Print Date 07/08/2012 REVISION DATE: 07/07/2012 6/6 943303 506 Further information: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. Prepared by: Sewnauth Raghunandan Legend ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration DOT - Department of Transportation PEL - Permissible Exposure Limit DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act EPA - Environmental Protection Agency STEL - Short Term Exposure Limit HMIS - Hazardous Materials Information System TLV - Threshold Limit Value IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act MSHA - Mine Safety Health Administration TWA - Time Weighted Average NDSL - Non-Domestic Substance List V - Volume NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System Page 332 of 377 Page 332 of 377 Page 332 of 377 Page 332 of 377 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # AERTKC SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550 MADISON HEIGHTS, MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS TRI-TRACK CLEAR (AEROSOL) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Toluene (CAS# 108-88-3) >1 100 ppm Xylene (CAS# 1330-20-7) >1 100 ppm Acetone (CAS# 67-64-1) >1 750 ppm Hydrocarbon Propellant (CAS# 68476-85-7) >1 1000 ppm Amorphorus Silica (CAS# 7631-86-9) >1 6 mg/m3 This product contains 2 ounce of Toluene, 2 ounces of Xylene and 4 ounces of Acetone per can of product. Toluene, Xylene, and Acetone are regulated chemicals under the Emergency Planning and Right- To-Know Act. You are required to file E.P.A. SARA reports once threshold of 10,000 pounds of any of these chemicals has been purchased for one location in each calendar year. All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT (ºF) RANGE -13 to 232 SPECIFIC GRAVITY (H2O = 1) 0.80 VAPOR PRESSURE (in can PSIG) 65 PERCENT VOLATILE BY VOLUME 77 VAPOR DENSITY (AIR = 1) N/A EVAPORATION RATE ( Butyl Acetate faster SOLUBILITY IN WATER insoluble PH N/A APPEARANCE AND ODOR Clear liquid with paint odor. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) 45ºF T.O.C. FLAMMABLE LIMITS USA Flame Projection Test: Extremely Flammable Spray EXTINGUISHING MEDIA Dry Chemical, Foam, Carbon Dioxide SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120ºF. (Continued on reverse side) Page 333 of 377 Page 333 of 377 Page 333 of 377 Page 333 of 377 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA (AEROSPY) THRESHOLD LIMIT VALUE 100 ppm PRIMARY ROUTES OF ENTRY Inhalation x Skin Contact x Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- irritation. Skin- prolonged or repeated contact may cause irritation. Inhalation- headache, dizziness, nausea, unconsciousness and even death. Ingestion- nausea, vomiting. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- flush with water and then wash with soap and water, launder contaminated clothing before reuse- get medical attention if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- Do Not Induce Vomiting- aspiration of material into lungs may be harmful or fatal- get medical attention. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None Known Carcinogen: NTP IARC OTHER No SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE x CONDITIONS TO AVOID Sources of ignition and temperatures in excess of 120ºF. INCOMPATABILITY (Conditions to avoid) Strong Oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR x CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Eliminate all sources of ignition and ventilate area. Dike area to contain spill. Use absorbent material to soak up spill. Shovel or sweep into container for disposal. WASTE DISPOSAL METHOD Aerosol cans when emptied and depressurized through normal use pose no disposal hazard and should be recycled. Absorbent materials should be disposed of in accordance with all Local, State, and Federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Use NIOSH approved respirators in areas where TLV has been exceeded LOCAL EXHAUST To control TLV SPECIAL N/A VENTILATION MECHANICAL (General) To control TLV OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical Goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower. SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- use only with adequate ventilation. Do not take internally. Avoid use near sources of ignition. Avoid storage in areas where temperatures may exceed OTHER PRECAUTIONS 120ºF. Read and follow label directions before using. Keep Out of Reach of Children.. HMIS SYMBOL HMIS NFPA NFPA SYMBOL SEVERE 4 EXTREME FIRE REACTIVITY SERIOUS 3 HIGH 4 MODERATE 2 MODERATE 2 0 SLIGHT 1 SLIGHT TOXICITY MINIMAL 0 INSIGNIFICANT SPECIAL NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE December 19, 2005 PHONE NUMBER CHEMTREC [PHONE REDACTED] HEALTH 2 FLAMMABILITY 4 REACTIVITY 0 Page 334 of 377 Page 334 of 377 Page 334 of 377 Page 334 of 377 ---PAGE BREAK--- Safety Data Sheet PAGE 1 of 5 1 – PRODUCT IDENTIFICATION PRODUCT NAME: Triple Foam Blue Anti Freeze PRODUCT TYPE: Solvent Based Cleaning Compound PRODUCT NUMBER: A0061XXX (Last 3 characters vary with the packaging) CONTROL NUMBER: A0061XXX COMPANY: Simoniz USA, Inc. 201 Boston Turnpike Bolton, CT 06043 1-[PHONE REDACTED] www.simoniz.com EMERGENCY (800) 255-3924 (CHEM-TEL) 2 – HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE/MIXTURE: Flammable Liquids Eye Irritation (2A) Reproductive Toxicity (1B) SYMBOLS: SIGNAL WORD: DANGER! HAZARD STATEMENT: Highly flammable liquid and vapour. Causes serious eye irritation May damage fertility or the unborn child PRECAUTIONARY STATEMENTS: PREVENTION: Keep away from heat/sparks/open flames / hot surfaces – No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical / ventilating / light equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves / protective clothing / eye protection / face protection. Wash hands thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. RESPONSE: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use dry sand, dry chemical or alcohol-resitant foam for extinction. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. If eye irritation persists get medical advice/attention. IF exposed or concerned: Get medical advice/attention. STORAGE: Store in a well ventilated place. Keep cool. Store locked up. DISPOSAL: Dispose of container and contents in accordance with local regulations. Page 335 of 377 Page 335 of 377 Page 335 of 377 Page 335 of 377 ---PAGE BREAK--- Safety Data Sheet PAGE 2 of 5 3 – COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENT C.A.S. NUMBER Methanol 67-56-1 Sodium Lauryl Ether Sulfate 68585-34-2 Percentages of ingredients are being withheld as trade secret information. This information will be disclosed as necessary to authorized individuals 4 – FIRST-AID MEASURES BREATHING (INHALATION): If victim shows signs of discomfort or irritation, remove to fresh air. If persist, get immediate medical attention. SWALLOWING (INGESTION): . DO NOT INDUCE VOMITING! Drink a large quantity of water or milk. Do not attempt to give liquids to an unconscious person. Get immediate medical attention! EYES: Inhalation, skin absorption, or ingestion. SKIN (DERMAL): Flush from skin and clothing with large amounts of fresh water. If irritation persists, consult physician. Wash contaminated clothing before wearing. 5 – FIRE-FIGHTING MEASURES FLASHPOINT: 52 degrees F. EXTINGUISHING MEDIA: Water fog or fine spray. Carbon dioxide, Dry chemical or Alcohol resistant foam. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters working in areas where this product is present should be equipped with an approved, fully enclosed SCBA. UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. 6 – ACCIDENTAL RELEASE MEASURES SPILL PROCEDURES: Dike to prevent spillage into streams or sewer systems. Consult local, state and federal authorities. WASTE DISPOSAL: As recommended by local, state and federal authorities. 7 – HANDLING and STORAGE STORAGE: Store in a cool, well ventilated area. Avoid overheating or freezing. Page 336 of 377 Page 336 of 377 Page 336 of 377 Page 336 of 377 ---PAGE BREAK--- Safety Data Sheet PAGE 3 of 5 HANDLING: Flammable! Ground and bond all containers when handling. Use non-sparking tools. Do not place this product in an unmarked container! Keep away from children! Spilled material is slippery. ATTENTION: Empty containers retain vapor and product residue and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat, flame, sparks, static electricity or other sources of ignition. Do not reuse empty container. 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: Not usually needed in well-ventilated areas. If needed, use a NIOSH approved respirator. PROTECTIVE CLOTHING: Nitrile or PVC gloves, and chemical splash goggles. ADDITIONAL MEASURES: Flammable! Ground and bond all containers when handling. Use non-sparking tools. Do not place this product in an unmarked container! Keep away from children! Spilled material is slippery. ATTENTION: Empty containers retain vapor and product residue and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat, flame, sparks, static electricity or other sources of ignition. Do not reuse empty container. INGREDIENT C.A.S. NUMBER PEL Methanol 67-56-1 200 ppm PEL, 250 ppm STEL Sodium Lauryl Ether Sulfate 68585-34-2 No limits established 9 – PHYSICAL / CHEMICAL PROPERITES APPEARANCE & ODOR: Blue transparent liquid, with an alcoholic odor. ODOR THRESHOLD: N/A pH: N/A MELTING POINT: 148 degrees F. FREEZING POINT: N/A BOILING 148 degrees F. BOILING POINT RANGE: N/A FLASHPOINT: 52 degrees F. EVAPORATION RATE: N/A FLAMMABILITY (solid/gas):.... N/A EXPLOSION LIMITS: N/A VAPOR PRESSURE: 97 mm Hg SPECIFIC GRAVITY: 0.79 SOLUBILITY IN WATER: Completely soluble. PARTITION COEFFICIENT: N/A AUTO-IGNITION TEMPERATURE: N/A DECOMPOSITION TEMPERATURE: N/A VISCOSITY: Water thin Page 337 of 377 Page 337 of 377 Page 337 of 377 Page 337 of 377 ---PAGE BREAK--- Safety Data Sheet PAGE 4 of 5 10 – STABILITY and REACTIVITY STABILITY: Stable under normal conditions. HAZARDOUS DECOMP.: This product not known to polymerize. INCOMPATIBILITY: Avoid strong oxidizers. Avoid heat, sparks or open flames. 11 – TOXICOLOGICAL INFORMATION ROUTE(S) OF ENTRY: Inhalation, skin absorption, or ingestion. LISTED CARCINOGEN: None over 0.1%. MEDICAL CONDITION AGGRAVATED: May aggravate pre-existing dermatitis. INHALATION: Inhalation of significant amounts of this product can cause headaches, dizziness, confusion or nausea. Can also cause loss of consciousness or death. Use only in well ventilated areas. INGESTION: Swallowing even small amounts may cause blindness or death. Other effects may be nausea, headache, vomiting and visual disturbances. EYES: Undiluted product will cause burns or eye irritation, or possibly permanent damage. SKIN (DERMAL): This product may cause irritation or redness of the skin. ACUTE TOXICITY* (ORAL):…… >2000 mg/kg ACUTE TOXICITY* (DERMAL):.. >2000 mg/kg ACUTE TOXCITY* (INHALATION): >20,000 ppm V (Gas), >20 mg/l (Vapor), >5 mg/l (Dust) *Determined using the additivity formula for mixtures (GHS Purple Book, 3.1.3.6) 12 – ECOLOGICAL INFORMATION ENVIRONMENTAL FATE AND DISTRIBUTION: N/A 13 –DISPOSAL CONSIDERATIONS WASTE DISPOSAL: As recommended by local, state and federal authorities. 14 – TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Methanol HAZARD CLASS: 3 Flammable UN/NA NUMBER: UN 1230 PACKAGING GROUP : II 15 - REGULATIONS Contents of this MSDS comply with the OSHA Hazard Communication Standard 29CFR 1910.1200 Page 338 of 377 Page 338 of 377 Page 338 of 377 Page 338 of 377 ---PAGE BREAK--- Safety Data Sheet PAGE 5 of 5 16 – OTHER INFORMATION NFPA HEALTH: 1 NFPA FLAMMABILITY: 3 NFPA REACTIVITY: 0 NFPA OTHER: None ADDITIONAL: The information contained in this SDS is based on the data available to us from sources we believe to be reliable. No warranty or guaranty expressed or implied is made regarding the accuracy of this data or the results obtained from the reliance on this data. The manufacturer assumes no responsibility for injury from the use of this product. Be safe- read this product safety information and pass it on to all persons who may be exposed to this product. Federal law requires it. This product and/or all of its components are either included on or exempt from the TSCA Inventory of Chemical Substances. REVISION DATE: 06/08/15 Page 339 of 377 Page 339 of 377 Page 339 of 377 Page 339 of 377 ---PAGE BREAK--- 1. PRODUCT AND COMPANY IDENTIFICATION Product name: TWINKLE Stainless Steel Cleaner & Polish MSDS 126155001 Product Code: 91224 Recommended use: Industrial/Institutional. Cleaning product. Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Principal routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat Butane 106-97-8 5 - 10% Not available Not available =658 mg/L (4 h) Propane 74-98-6 5 - 10% Not available Not available =658 mg/L (4 h) 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Skin contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Dry chemical, water spray, foam, carbon dioxide. Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. NFPA 30B Level 1 Aerosol . Canadian Headquarters JohnsonDiversey, Inc. - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] EMERGENCY OVERVIEW CAUTION. CONTENTS UNDER PRESSURE. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com TWINKLE Stainless Steel Cleaner & Polish 1 of 4 MATERIAL SAFETY DATA SHEET HMIS TWINKLE Stainless Steel Cleaner & Polish NFPA Personal protective equipment None / Aucune / Ninguno Health 1 Version Number: 2 Reactivity 0 4 Preparation date:2010-06-24 1 0 Fire Hazard 4 Page 340 of 377 Page 340 of 377 Page 340 of 377 Page 340 of 377 ---PAGE BREAK--- Unusual hazards: None known Specific methods: No special methods required Special protective equipment for firefighters:As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons:No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Put on appropriate personal protective equipment (see Section Remove all sources of ignition. Environmental precautions and clean-up methods: Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. CONTENTS UNDER PRESSURE. Do not puncture or incinerate. Keep away from open flames, hot surfaces and sources of ignition. Do not use or spray on floors. Do not let product overspray on to the floor as the product's ingredients could make the floor slippery.FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. NFPA 30B Level 1 Aerosol . Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Do not pierce or burn, even after use. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements General room ventilation is adequate Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Butane 106-97-8 1000 ppm (TWA) 800 ppm (TWA) 1900 mg/m3 (TWA) Propane 74-98-6 1000 ppm (TWA) 1000 ppm (TWA) 1800 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Explosion limits:- upper:Not determined- lower:Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Viscosity:No information available Physical State:Aerosol Elemental Phosphorus:0% by wt. Odor:Lemon VOC:15% * pH:10.8 Boiling point/range:Not determined Dilution pH:10.8@RTU Evaporation RateNo information available Melting point/range:Not determined Bulk density:No information available Decomposition temperature:Not determined Specific gravity:0.85 Autoignition temperature:No information available Solubility:Dispersible Density:7.09lbs/gal0.85Kg/L Color:White Solubility in other solvents:No information available Appearance:Aerosol Flash point:<20°F<-7°C Vapor density:No information available TWINKLE Stainless Steel Cleaner & Polish Partition coefficient (n-octanol/water):No information available 2 of 4 Page 341 of 377 Page 341 of 377 Page 341 of 377 Page 341 of 377 ---PAGE BREAK--- Hazardous decomposition products: None reasonably foreseeable. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg; Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories:U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65:This product is not subject to the reporting requirements under California's Proposition 65 RIGHT TO KNOW (RTK) Ingredient(s) CAS # MARTK: PARTK: RIRTK: Silicones 63148-62-9 - - - - Butane 106-97-8 X X X X Propane 74-98-6 X X X X Water 7732-18-5 - - - - White mineral oil 8042-47-5 X - - - CERCLA/ SARA SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: X Reactivity: - Sudden Release of Pressure: X Canada WHMIS hazard class:A Compressed gases Ingredient(s) CAS # NPRI Propane 74-98-6 X DOT/TDG:Please refer to the Bill of Lading/receiving documents for up to date shipping information 14. TRANSPORT INFORMATION TWINKLE Stainless Steel Cleaner & Polish 3 of 4 Page 342 of 377 Page 342 of 377 Page 342 of 377 Page 342 of 377 ---PAGE BREAK--- White mineral oil 8042-47-5 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 4 of 4 TWINKLE Stainless Steel Cleaner & Polish Page 343 of 377 Page 343 of 377 Page 343 of 377 Page 343 of 377 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 320 37th Avenue • St. Charles, Illinois 60174 • To Reorder, Call [PHONE REDACTED] PRODUCT IDENTIFICATION USE / DESCRIPTION REVISION DATE FOR MEDICAL AND UNITED 126 VANDALISM March 17, 2003 TRANSPORTATION EMERGENCIES: MARK REMOVER INFOTRAC: [PHONE REDACTED] HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety) Always follow Label Directions and Cautions. Susceptible to Release of Energy. 4 Extreme. 3 High. 2 Moderate. 1 Slight. 0 Minimal. See Health Hazard Data Section of this M.S.D.S. for more detailed information. FLAMMABILITY (0 = Maximum Safety) Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated to burn. 3 Ignites at normal temperature. 0 Will not burn. 2 Ignites when moderately heated. HAZARDOUS CAS ACGIH ACGIH OSHA OTHER S.A.R.A. TITLE III COMPONENTS NUMBER TWA STEL PEL TWA RECOMMENDED LIMITS QUANTITIES n-Butyl acetate 123-86-4 150 ppm 200 ppm 150 ppm NIOSH TWA None 713 mg/m3 950 mg/m3 710 mg/m3 150 ppm 710 mg/m3 Toluene 108-88-3 SKIN: 50 ppm Not 200 ppm NIOSH TWA 0.25* 188 mg/m3 established 100 ppm 375 mg/m3 Ethanol 64-17-5 1000 ppm Not 1000 ppm NIOSH TWA None 1880 mg/m3 established 1900 mg/m3 1000 ppm 1900 mg/m3 Ethylene glycol 111-76-2 Skin: 20 ppm Not Skin: 50 ppm NIOSH TWA 0.10* monobutyl ether 97 mg/m3 established 240 mg/m3 Skin: 5 ppm 24 mg/m3 Diethylene glycol 111-90-0 Not Not Not None 0.20* monoethyl ether established established established Propane 74-98-6 2500 ppm Not 1000 ppm NIOSH TWA None 4508 mg/m3 established 1800 mg/m3 1000 ppm 1800 mg/m3 Isobutane 75-28-5 Not Not Not NIOSH TWA None established established established 800 ppm 1900 mg/m3 n-Methyl-2-pyrrolidone 872-50-4 Not Not Not None 0.05* established established established * Pounds of reportable material per can of UNITED 126. BOILING POINT SPECIFIC GRAVITY (H20 = 1) Not determined At 25°C. = 0.88 Concentrate VAPOR PRESSURE (psig) MELTING POINT (At 77° 55 psig Not determined VAPOR DENSITY (Air = 1) EVAPORATION RATE Greater than 1 (Butyl Acetate = 1) Greater than 1 SOLUBILITY IN WATER VOLATILE ORGANIC COMPOUNDS Emulsifiable (Pounds Per Can Of Product) 0.75 APPEARANCE AND ODOR pH: Water white gel with sweet ethereal odor Not applicable FLASH POINT (Method Used) FLAMMABLE LIMITS LEL UEL Extremely flammable by Flame Extension Test–Greater than 18 inches Not determined Not determined Not determined EXTINGUISHING MEDIA Foam, carbon dioxide, dry chemical, and Halon SPECIAL FIRE FIGHTING PROCEDURES Use water spray or mist to keep containers cool. Use equipment or shielding as necessary to protect personnel from bursting, rupturing or venting containers. Wear self-contained breathing apparatus to avoid inhaling toxic components in the product. Use dikes as necessary to prevent runoff from entering sewers or public water courses. UNUSUAL FIRE AND EXPLOSION HAZARDS Do not expose the container to temperatures over 120°F. as it may burst or rupture due to pressure build-up, greatly increasing the fire hazard. 4 May detonate-vacate area if 2 Violent chemical change Materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. PERSONAL PROTECTION UNITED 126 HAZARDOUS COMPONENTS IDENTITY, EXPOSURE LIMITS AND S.A.R.A. TITLE III INFORMATION PHYSICAL / CHEMICAL CHARACTERISTICS FIRE AND EXPLOSION HAZARD DATA 0 3 3 PAGE (CONTINUED ON REVERSE SIDE) L A B O R A T O R I E S Page 344 of 377 Page 344 of 377 Page 344 of 377 Page 344 of 377 ---PAGE BREAK--- STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE X None known INCOMPATIBILITY (Materials To Avoid) Oxidizing materials HAZARDOUS DECOMPOSITION OR BYPRODUCTS When strongly heated, as in a fire, this product may produce hydrogen chloride, phosgene, chlorine, and carbon monoxide HAZARDOUS POLYMERIZATION:WILL NOT OCCUR X CONDITIONS TO AVOID MAY OCCUR X None known HEALTH HAZARDS EYES: May cause moderate to severe irritation. SKIN: May cause dryness, irritation and defatting of tissue. May be absorbed through skin resulting in central nervous system depression. Prolonged contact may cause liver, kidney and lung damage. INHALATION: May cause headache, dizziness, nausea, and upper respiratory irritation. Prolonged exposure may cause liver, kidney, and lung damage. IF SWALLOWED: May cause nausea, upset stomach, vomiting, and headache. Prolonged exposure may cause liver, kidney, and lung damage. Aspiration into lungs during vomiting may cause chemical pneumonitis. CARCINOGENICITY: NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No This product contains a chemical known to the state of California to cause cancer or reproductive toxicity? Yes (Toluene) SIGNS AND OF OVEREXPOSURE EYES: Moderate to severe irritation SKIN: Dryness, irritation, CNS depression INHALATION: Headache, dizziness, nausea, upper respiratory irritation IF SWALLOWED: Nausea, upset stomach, vomiting TARGET ORGANS: Eyes, skin, liver, central nervous system, heart, kidneys, respiratory system MEDICAL CONDITIONS GENERALLY AGGRAVATED BY OVEREXPOSURE Skin sensitivity, chemical allergies, heart condition EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with plenty of cool water for at least 15 minutes while holding eyelids open. Call a physician or poison control center immediately. SKIN: Remove contaminated clothing, wash with soap and water. If irritation persists, call a physician or poison control center. INHALATION: Remove to fresh air immediately. Apply CPR as needed. Call a physician or poison control center immediately. IF SWALLOWED: Do not induce vomiting. Call a physician or poison control center immediately. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Small spills: Mop up or soak up immediately. Remove to out of doors. Large spills: Evacuate area. Contain liquid; transfer to closed metal containers. Keep out of water supply. WASTE DISPOSAL METHOD Do not puncture or incinerate containers. Consult local, state and federal authorities for proper disposal guidelines. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Do not expose to temperatures exceeding 120°F. Store in a cool, well-ventilated area, away from sources of ignition. Keep out of reach of children. Store as NFPA Code 30B: Level 2 Aerosol. RESPIRATORY PROTECTION (Specify Type) If TLV is exceeded, use a NIOSH / MSHA-approved respirator. VENTILATION: MECHANICAL (General) LOCAL EXHAUST Provide adequate ventilation Generally adequate PROTECTIVE GLOVES EYE PROTECTION Chemical-resistant gloves Safety glasses OTHER PROTECTIVE CLOTHING OR EQUIPMENT Chemical-resistant apron and long-sleeved shirts and gloves are recommended. WORK HYGENIC PRACTICES Wash hands and face with soap and water after using this product. Remove contaminated clothing and launder before reusing. REACTIVITY DATA HEALTH HAZARD DATA PRECAUTIONS FOR SAFE HANDLING AND USE CONTROL MEASURES FOR USE WHERE SIGNIFICANT EYE, SKIN OR INHALATION EXPOSURE IS LIKELY PAGE UNITED 126 VANDALISM MARK REMOVER Page 345 of 377 Page 345 of 377 Page 345 of 377 Page 345 of 377 ---PAGE BREAK--- - 1 - UNITED 177 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 177 SUNSHINE IN A CAN Spray and Wipe Degreaser-Cleaner December 29, 2010 HMIS III HEALTH (0 = Maximum Safety) 1 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 2 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) 1,1,1,2-Tetrafluoroethane 811-97-2 1-5 NE NE NE NE 3. HAZARDS IDENTIFICATION Eyes: May cause irritation. Skin: Prolonged or repeated contact may cause irritation. Inhalation: Mists of this product may irritate nasal passages. Intentional misuse by concentrating and inhaling the product can be harmful or fatal. Ingestion: Exposure by ingestion of an aerosol is unlikely. Swallowing large amounts may cause nausea, upset stomach and vomiting. 4. FIRST AID MEASURES Eyes: Flush with plenty of water for 15 minutes and call a physician. Skin: Wash off with soap and water. If irritation persists, call a physician. Inhalation: Remove to fresh air. Apply artificial respiration if needed and call a physician. Ingestion: Induce vomiting under the direction of a physician. Never give anything by mouth to an unconscious person. Call a physician immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): -156F/-104.4C Propellant Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): Non-Flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of carbon and nitrogen. Fire and Explosion Hazards: At elevated temperatures (over 49°C/120°F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening of container structure. Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may cause fire or explosion hazard. Extinguishing Media: Water, Water fog, Foam, Dry chemical powder, Carbon dioxide. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers.. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. After removal flush contaminated area thoroughly with water. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 • 214 Dolomite Drive, Downsview, Ontario M3J 2N2 To Reorder Call: www.unitedlabsinc.com [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: B Page 346 of 377 Page 346 of 377 Page 346 of 377 Page 346 of 377 ---PAGE BREAK--- - 2 - Large Spills: Eliminate all ignition sources. Stop leak if you can do so without risk or move to a safe and open area if the leak is irreparable. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. After removal flush contaminated area thoroughly with water. 7. HANDLING AND STORAGE Avoid breathing vapor. Pressurized container: Keep away from heat and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 120°F (49C). Store as Level 1 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses are recommended. Skin: Chemical resistant gloves recommended only for prolonged or repeated exposure. Respiratory: None required if good ventilation is maintained. If exposure exceeds occupational exposure limits, use a NIOSH approved respirator to prevent overexposure. Engineering Controls: General ventilation is adequate under normal conditions, mechanical ventilation is optional. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: ~185F/85C Specific Gravity: ~0.9979 (H2O=1) Vapor Pressure: 91-101 psig@ 70F/21C Melting Point: ND Vapor Density: ND Evaporation Rate: ND Solubility in Water: Partially pH: 9.1 – 10.1 Appearance and Odor: Aerosol, clear semi-stable foam with a clean light botanical scent. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: No hazardous decomposition products are known. Chemical Stability: Stable Incompatibility: Strong oxidizing agents. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: ND SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 177 SUNSHINE IN A CAN PREPARED BY: Sandy Kopacz Page 347 of 377 Page 347 of 377 Page 347 of 377 Page 347 of 377 ---PAGE BREAK--- - 1 - UNITED 195 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 195 SMELL JEL Jellied Deodorant Spray December 22, 2012 HMIS III HEALTH (0 = Maximum Safety) 0 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Isopropyl alcohol 67-63-0 5-10 200 ppm 400 ppm 980 mg/m3 >5045 mg/kg (Rat/oral) 16000 ppm 8 hr (Rat) 1.2-propanediol 57-55-6 5-10 N/A N/A 22000-31000 Mg/kg(Rat/oral) N/A Propane/N-Butane 68476-85-7 10-30 1000 ppm 1800 mg/m3 1000 ppm 1800 mg/m3 N/A N/A 3. HAZARDS IDENTIFICATION Emergency Overview: Aerosol under pressure do not expose to high temperatures 120°F/49°C or store in direct sunlight. Routes of Entry: Eyes, Skin, Ingestion, Inhalation Eyes: May cause irritation. Skin: May cause slight irritation, possible dryness with prolonged contact. Inhalation: Intentional overexposure to mist or vapors may result in dizziness and headache. Ingestion: May cause nausea or gastric discomfort. Chronic Health Hazards: None known. Medical Conditions Generally Aggravated by Exposure: None known. Carcinogenicity (NTP/IARC/OSHA): None 4. FIRST AID MEASURES Eyes: Flush with plenty of water for 15 minutes and call a physician immediately. Skin: Wash with soap and water. If irritation persists, call a physician. If Inhaled: Remove patient to fresh air immediately. Apply artificial respiration if needed and call a physician. If Swallowed: Drink several glasses of water. Call a physician immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): 180°F/82.2°C Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): Nonflammable per 16 CFR 1500.45 Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Fire and Explosion Hazards: Do not expose aerosols to temperatures above 120°F/49°C or the container may burst, rupture or vent. Extinguishing Media: Water, foam, Carbon dioxide, Dry chemical, Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. Prevent runoff from entering sewers and public waterways. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Pick up small spills with rag or towel. Clean surface thoroughly to remove residual contamination. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Prevent material from entering sewers or drains. Wash area thoroughly to remove residual contamination. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: A Page 348 of 377 Page 348 of 377 Page 348 of 377 Page 348 of 377 ---PAGE BREAK--- - 2 - 7. HANDLING AND STORAGE Keep this product properly labeled and store in a cool, well-ventilated area, away from heat or other sources of ignition. Do not expose to direct sunlight or store at temperatures above 120°F/49°C. may cause bursting. Wash hands and face with soap and water after using this product. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses recommended if direct contact is possible. Skin: Chemical resistant gloves recommended only for prolonged or repeated exposure. Respiratory: Not normally needed. If TLV is exceeded, an organic vapor cartridge respirator or SCBA may be needed. Engineering Controls: Ventilation not normally required and local exhaust generally adequate. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212°F/100°C (Initial-Concentrate) Specific Gravity: 0.99 (Concentrate@77°F) Vapor Pressure: 17.5 77°F Melting Point: ND Vapor Density: >1 Evaporation Rate: <1 Solubility in Water: Soluble pH: 7.6—7.7 VOC (Volatile Organic Compounds): 24.9% Appearance and Odor: White aerosol foam in orange or mulberry scent 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Chemical Stability: Stable Conditions to Avoid (Polymerization): None Incompatibility: Avoid contact with strong oxidizers, alkalies, and acids. 11. TOXICOLOGICAL INFORMATION See section 2 12. ECOLOGICAL INFORMATION N/A 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Wrap container and place in trash collection. Disposal regulations may be different for each state and/or locality. Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. RCRA Hazard Class: Considered non-hazardous under RCA, however product should be fully characterized prior to disposal (40 CFR 261) 14. TRANSPORT INFORMATION US DOT: Consumer Commodity, ORM-D IMDG-Water/Ocean: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2, PG None IATA-Air: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2 PG None 15. REGULATORY INFORMATION U.S. Federal Regulations: TSCA (Toxic Substances Control Act): All Chemicals are listed or exempt CERCLA (Comprehensive Response Compensation, and Liability Act): None SARA Title III Section 302 EHS: None SARA Title III Section 311/312: None SARA Title III Section 313 Toxic Chemicals: Isopropyl Alcohol – CAS#67-63-0 State Regulations: California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No Right-to-know acts for Rhode Island, Florida, Minnesota, Massachusetts, New Jersey, Tennessee, Connecticut hazardous material survey. Illinois toxic substances disclosure to employee act. 195WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 195 SMELL JEL PREPARED BY: Sandy Kopacz Page 349 of 377 Page 349 of 377 Page 349 of 377 Page 349 of 377 ---PAGE BREAK--- - 1 - UNITED 77 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 77 BIATRON® Organic Digester and Liquid Drain Cleaner February 8, 2013 HMIS III HEALTH (0 = Maximum Safety) 3 PHYSICAL HAZARD (0 = Maximum Safety) 2 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 0 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Sulfuric acid 7664-93-9 60-100 1 mg/m3 1 mg/m3 2140 mg/kg (rat/oral) 347 ppm 1 hr/rat 3. HAZARDS IDENTIFICATION Eyes: Very corrosive. Causes severe burns and blindness. Do not wear contact lenses. Skin: Very corrosive. Causes severe and painful burns. Inhalation: May cause headache, drowsiness, and central nervous system depression. Mist causes severe irritation of nose, throat and lungs. Ingestion: Very corrosive. Causes severe burns to mouth, throat, and stomach. Harmful or fatal. 4. FIRST AID MEASURES Eyes: Flood with cool water for at least 15 minutes and get medical attention immediately. DO NOT wear contact lenses. Skin: Flood with cool water for several minutes until all the product is washed away. Then cover area with moistened sodium bicarbonate. Seek medical attention immediately. Inhalation: Remove patient to fresh air immediately. If patient is not breathing, apply artificial respiration. Seek medical attention immediately. Ingestion: DO NOT induce vomiting. If conscious, immediately drink large amounts of water to reduce the concentration. Give milk of magnesia or whites of eggs beaten into water. Avoid carbonates or sulfates. Get medical attention immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): None Explosive Limits: Lower (LEL): NA Upper (UEL): NA Flame Projection (Aerosol): NA Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of sulfur and carbon. Fire and Explosion Hazards: This product reacts violently with generation of great heat, when water is added. Temperatures may exceed 240F and may boil and splatter the mixture. May react with metals to release hydrogen gas. Extinguishing Media: Use media appropriate for surrounding material. Use water spray to cool containers exposed to fire. Do not get water inside containers. Fire Fighting Instructions: Avoid spraying water onto leaking containers. Water applied directly to sulfuric acid causes evolution of heat and splattering. Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. Stay upwind if product is involved in a fire. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: p, n, o Page 350 of 377 Page 350 of 377 Page 350 of 377 Page 350 of 377 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wear protective equipment and clothing before entering area. Ventilate area. Avoid contact with skin and eyes. Neutralize spill with soda ash. Flush area with water using care. Unneutralized acid will generate heat when mixed with water. Large Spills: Same as above. 7. HANDLING AND STORAGE Store in a secure area out of reach of children and unauthorized persons. Keep containers closed when not in use. Do not store near incompatible materials, such as strong alkalis or flammables. Store product in a well-ventilated area. Do not add water to concentrate. Wear appropriate personal protective equipment. Do not breathe sprays or mists. Do not get in eyes, on skin or on clothing. Do not ingest. Deactivating chemicals: Lime, limestone, sodium carbonate, sodium bicarbonate, diluted sodium hydroxide, dilute aqua ammonia. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety goggles and Face Shield are recommended. Skin: Chemical resistant gloves are recommended. Respiratory: To avoid breathing fumes, use NIOSH-approved respirator. Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces. Other Protective Equipment: Coveralls, boots and or other acid resistant protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 535F/279C Specific Gravity: 1.835 (H2O=1) Vapor Pressure: 1.7 mmHg Melting Point: -31F/35C Vapor Density: >1 (air=1) Evaporation Rate: <1 (BA=1) Solubility in Water: Complete pH: 1 Appearance and Odor: viscous, clear, tan colored liquid with no scent 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce toxic gases and vapors (sulfur dioxide, sulfuric acid vapors and sulfur trioxide) may be released when sulfuric acid decomposes. Chemical Stability: Stable under normal conditions, but reacts violently with water and organic materials with evolution of heat. Under fire conditions, decomposes to form sulfur oxides. Incompatibility: Do not mix this product with other cleaning chemicals, especially bases or oxidizers such as bleach. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT- Land: UN 1830, Sulfuric Acid, 8, PG II TDG - Land: UN 1830, Sulphuric Acid, 8, PG II UN: Available upon request. 15. REGULATORY INFORMATION VOC Volatile Organic Compounds): None TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: Extremely hazardous substance. SARA Title III Section 311/312: Immediate health, delayed health and physical hazard. SARA Title III Section 313 Toxic Chemicals: Sulfuric acid CAS# 7664-93-9 WHMIS Classification: E, D1A This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 77 BIATRON® PREPARED BY: Sandy Kopacz Page 351 of 377 Page 351 of 377 Page 351 of 377 Page 351 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Date of issue: 07/24/2015 EN (English US) Page 1 Section 1: Identification 1.1. Product identifier Product form : Mixture Product Identifier(s) : Unleaded Gasoline Grade Gasoline Regular Gasoline, Regular Unleaded Gasoline Mid-Grade Gasoline, Mid-Grade Unleaded Gasoline Premium Gasoline, Premium Unleaded Gasoline CAS No : 86290-81-5 1.2. Recommended use of the chemical and restrictions on use Use of the substance/mixture : Fuel 1.3. Details of the supplier of the safety data sheet Total Petrochemicals & Refining USA, Inc. P O Box 674411 Houston, TX 77267-4411 For non-emergency product information: Phone: [PHONE REDACTED] Email: [EMAIL REDACTED] 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-[PHONE REDACTED] (Toll Free USA & Canada) / [PHONE REDACTED] (Multiple languages) Total Petrochemicals & Refining USA, Inc.: 1-[PHONE REDACTED] (Language: English only) Section 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids Category 1 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Germ cell mutagenicity Category 1B Carcinogenicity Category 1B Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 1 Specific target organ toxicity (single exposure) Category 3 - Respiratory irritation Specific target organ toxicity (single exposure) Category 3 - Narcotic effects Specific target organ toxicity (repeated exposure) Category 1 Aspiration hazard Category 1 Hazardous to the aquatic environment - Chronic Hazard Category 2 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Causes serious eye irritation May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects Page 352 of 377 Page 352 of 377 Page 352 of 377 Page 352 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 2/12 May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs (lung) Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Precautionary statements (GHS-US) : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sparks, open flames, heat, hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray, mist, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear flame retardant protective clothing, impermeable protective gloves, eye protection, face protection. If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Section 4.1 of SDS or information on this label). If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. In case of fire: Use Water spray, foam, carbon dioxide (CO2), dry chemical to extinguish. Collect spillage. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Hazards not otherwise classified Other hazards not contributing to the classification : Product can accumulate electrostatic charges that may cause fire by electrical discharges. 2.4. Unknown acute toxicity (GHS-US) 19 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) 2.5. Additional information No additional information available Section 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Where concentrations in this product are displayed as ranges, it is due to batch-to-batch variability. Name CAS No % Other hydrocarbons ( C4- C14 ) - 5 - 40 Xylene 1330-20-7 1 - 20 Toluene 108-88-3 1 - 20 n-Heptane and Heptane Isomers - 0 - 20 Hexane isomers, excluding n-hexane - 0 - 20 n-Octane and Octane Isomers - 0 - 20 100-41-4 1 - 10 95-63-6 1 - 10 Page 353 of 377 Page 353 of 377 Page 353 of 377 Page 353 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 3/12 n-pentane 109-66-0 0 - 10 Isopentane 78-78-4 0 - 10 n-Nonane and Nonane Isomers - 0 - 10 n-Hexane 110-54-3 0 - 5 Benzene 71-43-2 0.1 - 2 Cyclohexane 110-82-7 0 - 2 Naphthalene 91-20-3 0.1 - 1 Cumene 98-82-8 0.1 - 1 Section 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if irritation persists. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important and effects, both acute and delayed : May cause genetic defects. after inhalation : May cause respiratory irritation. May cause drowsiness or dizziness. after skin contact : Causes skin irritation. after ingestion : May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available Section 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the chemical Fire hazard : Extremely flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Emergency procedures for non-emergency personnel : Evacuate unnecessary personnel. Emergency procedures for emergency responders : Ventilate area. Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. 6.2. Methods and material for containment and cleaning up For containment : Do not contaminate ground and surface water. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.3. Reference to other sections See section 8. Exposure controls/personal protection. Section 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Page 354 of 377 Page 354 of 377 Page 354 of 377 Page 354 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 4/12 Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No bare lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Use only outdoors or in a well-ventilated area. Do not breathe vapors, mist, spray. Never siphon by mouth. DO NOT fill container while container is in vehicle. Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : flames, heat sources, sparks. Keep in fireproof place. Keep container closed. Incompatible products : Strong bases. Strong acids. Strong oxidizing agents. Strong reducing agents. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. Section 8: Exposure controls/personal protection 8.1. Occupational Exposure Limits Unleaded Gasoline (86290-81-5) USA ACGIH ACGIH TWA (ppm) 300 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm n-Octane and Octane Isomers USA ACGIH ACGIH TWA (ppm) 300 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2350 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm n-Heptane and Heptane Isomers USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2000 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Hexane isomers, excluding n-hexane USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm USA OSHA Remark (OSHA) See OSHA Table Z-2. Xylenes p- isomers) (1330-20-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm n-Nonane and Nonane Isomers USA ACGIH ACGIH TWA (ppm) 200 ppm Isopentane (78-78-4) USA ACGIH ACGIH TWA (ppm) 1000 ppm (Pentane, all isomers) USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm (Pentane, all isomers) n-pentane (109-66-0) USA ACGIH ACGIH TWA (ppm) 600 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2950 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm (100-41-4) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Page 355 of 377 Page 355 of 377 Page 355 of 377 Page 355 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 5/12 n-Hexane (110-54-3) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Cyclohexane (110-82-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 1050 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 300 ppm Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 0.5 ppm USA ACGIH ACGIH STEL (ppm) 2.5 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm USA OSHA Remark (OSHA) (see 29 CFR 1910.1028) Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 50 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Cumene (98-82-8) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 245 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 50 ppm 8.2. Exposure controls Appropriate engineering controls : Ensure adequate ventilation. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Impermeable protective gloves. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Gloves should be discarded and replaced if there is any indication of degredation or chemical breakthrough. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear fire/flame resistant/retardant clothing. Respiratory protection : An approved organic vapor respirator/supplied air or self-contained breathing apparatus must be used when vapor concentration exceeds applicable exposure limits. Other information : Do not eat, drink or smoke during use. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Colorless. Amber or red, if dyed. Odor : Characteristic. Odor threshold : 83 ppm Weighted average pH : Not applicable Relative evaporation rate (butyl acetate=1) : No data available Relative evaporation rate (ether=1) : < 30 Slower than ethyl ether Melting point : < -60 °C Freezing point : No data available Boiling point : 27 (27 - 225) °C Flash point : < -35 °C (closed cup) Auto-ignition temperature : 280 - 470 °C (at 1013 hPa) Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 500 - 700 mm Hg at 21°C Relative vapor density at 20 °C : 3 - 4 Air = 1 Relative density : 0.75 Page 356 of 377 Page 356 of 377 Page 356 of 377 Page 356 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 6/12 Solubility : Water: 30 - 100 mg/l (at 20 Log Kow : No data available Viscosity, kinematic : < 1 cSt at 40°C Viscosity, dynamic : No data available Explosive limits : 1.4 - 7.6 vol % 9.2. Other information VOC content : 100 % Section 10: Stability and reactivity 10.1. Reactivity Flammable liquid and vapor. 10.2. Chemical stability The product is stable at normal handling and storage conditions. 10.3. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous polymerization will not occur. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Sparks. Heat. Overheating. Open flame. 10.5. Incompatible materials Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents. 10.6. Hazardous decomposition products Hazardous decomposition products formed under fire conditions: carbon monoxide, carbon dioxide, toxic fumes. Section 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure : Inhalation. Ingestion. Skin contact. Eye contact. Acute toxicity : Not classified Based on available data, the classification criteria are not met Combustion of hydrocarbon substances, like this product, produces potentially toxic gases which include carbon monoxide, carbon dioxide, oxides of nitrogen and/or sulfur. Exposure to carbon monoxide gas decreases the ability of the blood to carry oxygen to the body and may be potentially fatal. NIOSH lists the Immediately Dangerous to Life or Health Concentration (IDLH) for carbon monoxide gas as1200 ppm. Unleaded Gasoline (86290-81-5) LD50 oral rat > 5000 (5000 - 14000) mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.2 mg/l/4h Other hydrocarbons ( C4- C14 ) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5 mg/l/4h n-Octane and Octane Isomers LD50 oral rat > 5000 mg/kg Based on Isooctane LD50 dermal rabbit > 2000 mg/kg Based on Isooctane LC50 inhalation rat > 24 mg/l/4h Based on n-Octane n-Heptane and Heptane Isomers LD50 oral rat > 5000 mg/kg Based on iso-octane LD50 dermal rabbit 3000 mg/kg Based on n-heptane LC50 inhalation rat 103 g/m³ Based on n-heptane Hexane isomers, excluding n-hexane LD50 oral rat 15840 mg/kg based on n-hexane LD50 dermal rabbit 3000 mg/kg based on n-hexane LC50 inhalation rat 259 mg/l/4h based on n-hexane LC50 inhalation rat (ppm) 48000 ppm/4h Toluene (108-88-3) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat 28.1 (28.1 - 49) mg/l/4h LC50 inhalation rat (ppm) > 26700 ppm/1h Page 357 of 377 Page 357 of 377 Page 357 of 377 Page 357 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 7/12 Xylenes p- isomers) (1330-20-7) LD50 oral rat 4300 mg/kg LD50 dermal rabbit > 4200 mg/kg LC50 inhalation rat 21.7 mg/l/4h n-Nonane and Nonane Isomers LD50 oral rat > 5000 mg/kg Based on Iso-Octane LD50 dermal rabbit > 2000 mg/kg Based on Iso-Octane LC50 inhalation rat 17 mg/l/4h Based on nonane LC50 inhalation rat (ppm) 3200 ppm/4h Isopentane (78-78-4) LD50 oral rat > 2000 mg/kg Based on n-pentane LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 280 mg/l/4h LC50 inhalation rat (ppm) > 4094 ppmV/4h n-pentane (109-66-0) LD50 oral rat > 2000 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 364 mg/l/4h (95-63-6) LD50 oral rat 5000 mg/kg LD50 dermal rabbit > 3160 mg/kg LC50 inhalation rat 18 mg/l/4h (100-41-4) LD50 oral rat 3500 mg/kg LD50 dermal rabbit 15354 mg/kg LC50 inhalation rat 17.2 mg/l/4h n-Hexane (110-54-3) LD50 oral rat 15840 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 259 mg/l/4h Cyclohexane (110-82-7) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat 13.9 mg/l/4h Benzene (71-43-2) LD50 oral rat 930 (930 - 6400) mg/kg LD50 dermal rabbit > 8272 mg/kg LC50 inhalation rat 34.4 mg/l/4h Naphthalene (91-20-3) LD50 oral rat 490 mg/kg LD50 dermal rabbit > 20 g/kg LC50 inhalation rat > 340 mg/m³ (Exposure time: 1 h) Cumene (98-82-8) LD50 oral rat 1400 mg/kg LD50 dermal rat 10600 mg/kg LC50 inhalation rat 39 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : May cause genetic defects. Carcinogenicity : May cause cancer. Unleaded Gasoline (86290-81-5) IARC group 2B - Possibly carcinogenic to humans Toluene (108-88-3) IARC group 3 - Not classifiable Xylenes p- isomers) (1330-20-7) IARC group 3 - Not classifiable (100-41-4) IARC group 2B - Possibly carcinogenic to humans Benzene (71-43-2) IARC group 1 - Carcinogenic to humans National Toxicology Program (NTP) Status 1 - Known Human Carcinogens OSHA Carcinogen Status In OSHA Specifically Regulated Carcinogen list Additional information Benzene is a known human carcinogen and is known to cause acute myeloid leukemia & (disease that affects the bone marrow and blood) in Page 358 of 377 Page 358 of 377 Page 358 of 377 Page 358 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 8/12 humans who have been repeatedly exposed to benzene. Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 2 - Reasonably anticipated to be Human Carcinogen Cumene (98-82-8) IARC group 2B - Possibly carcinogenic to humans Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Causes damage to organs (lung). May cause respiratory irritation. May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. Section 12: Ecological information 12.1. Toxicity Ecology - general : Toxic to aquatic life with long lasting effects. 12.2. Persistence and degradability Unleaded Gasoline (86290-81-5) Persistence and degradability Not established. 12.3. Bioaccumulative potential Unleaded Gasoline (86290-81-5) Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. Section 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents and container in accordance with all local, regional, national and international regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. Section 14: Transport information US Transport (DOT) for Bulk Shipments (Non-Bulk Shipments May Differ) Transport document description : UN1203, Gasoline, 3, PGII UN or NA Number : UN1203 Proper Shipping Name : Gasoline Primary Hazard Class : 3 - Flammable liquid Packing Group : PGII Reportable Quantities (RQ)* *It is the shipper's responsibility to determine whether an RQ must be reported for each individual shipment. : Benzene 10 lbs (4.54 kg), Cumene 5000 lbs (2270 kg), 1000 lbs (454 kg), Hexane 5000 lbs (2270 kg), Toluene 1000 lbs (454 kg), Mixed Xylenes 100 lbs (45.4 kg), Naphthalene 100 lbs (45.4 kg), Cyclohexane 1000 lbs (454 kg) Hazard labels : Emergency Response Guide (ERG) Number : 128 In accordance with the definition in 49 CFR § 171.8, a hazardous substance does not include petroleum, including crude oil or any fraction thereof which is not other specifically listed or designated as such in Appendix A to 49 CFR § 172.101. Therefore, this product does not require a RQ designation. Transport by sea (IMDG) Transport document description : UN1203, GASOLINE, 3, PGII UN Number : UN1203 Page 359 of 377 Page 359 of 377 Page 359 of 377 Page 359 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 9/12 Proper Shipping Name : GASOLINE Primary Hazard Class : 3 - Flammable liquids Packing Group : PGII Hazard labels (IMDG) : Cargo name listed in 46 CFR 30.25, Table 30.25-1 : Gasolines: Automotive Air transport (IATA) Transport document description : UN1203, Gasoline, 3, PGII UN Number : UN1203 Proper Shipping Name : Gasoline Primary Hazard Class : 3 - Flammable Liquids Packing Group : PGII Hazard labels (IATA) : Section 15: Regulatory information 15.1. US Federal regulations EPA TSCA Status Under TSCA gasoline is a mixture. All components of this mixture are listed on TSCA. SARA Section 313 Supplier Notification This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372: CAS number Chemical name Concentration 108-88-3 Toluene 1 - 20% 1330-20-7 Xylenes p- isomers) 1 - 20% 95-63-6 1 - 10% 100-41-4 1 - 10% 110-54-3 n-Hexane 0 - 5% 110-82-7 Cyclohexane 0 - 2% 71-43-2 Benzene 0.1 - 2% 91-20-3 Naphthalene 0.1 - 1% 98-82-8 Cumene 0.1 - 1% This information must be included in all Safety Data Sheets that are copied and distributed for this product. For additional information, see 40 CFR §372.45 Notification About Toxic Chemicals. SARA Section 311/312 Hazard Classes Fire hazard Chronic health hazard Acute health hazard 15.2. International regulations CANADA Unleaded Gasoline (86290-81-5) WHMIS Classification Class B Division 2 - Flammable Liquid Page 360 of 377 Page 360 of 377 Page 360 of 377 Page 360 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 10/12 National inventories (86290-81-5) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Sustances List) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS) 15.3. US State regulations California Proposition 65 - This product contains a substance or substances known to the state of California to cause cancer and/or reproductive toxicity, not limited to any that may be listed below. Toluene (108-88-3) U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Male No (100-41-4) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Non-significant risk level (NSRL) 54 µg/day (inhalation) Benzene (71-43-2) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male Yes Non-significant risk level (NSRL) 6.4 µg/day (oral) Naphthalene (91-20-3) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Non-significant risk level (NSRL) 5.8 µg/day Cumene (98-82-8) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Section 16: Other information Other information : None. NFPA (National Fire Protection Association) NFPA health hazard : 1 NFPA fire hazard : 3 NFPA reactivity : 0 Page 361 of 377 Page 361 of 377 Page 361 of 377 Page 361 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 11/12 HMIS III Rating Health : 1* Flammability : 3 Physical Hazard : 0 Personal Protection : See section 8 of SDS US OSHA LABEL as specified under 29 CFR §1910.1200 Unleaded Gasoline Total Petrochemicals & Refining USA, Inc. PO Box 674411 Houston, TX 77267-4411 USA Tel. [PHONE REDACTED] or 1-[PHONE REDACTED] Danger Extremely flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Causes serious eye irritation May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs (lung) Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sparks, open flames, heat, hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray, mist, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear flame retardant protective clothing, impermeable protective gloves, eye protection, face protection. If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Section 4.1 of SDS or information on this label). If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. In case of fire: Use Water spray, foam, carbon dioxide (CO2), dry chemical to extinguish. Collect spillage. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. Unknown acute toxicity 19 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) Supplemental Information Product can accumulate electrostatic charges that may cause fire by electrical discharges. Version : 2.2 Date of issue : July 24, 2015 Page 362 of 377 Page 362 of 377 Page 362 of 377 Page 362 of 377 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 12/12 MSDS ID: UL_GASOLINE SDS REFERENCE NUMBER: RF0029 SDS Template - TOTAL SDS US (GHS HazCom 2012) TPRI Version 4.01 The information contained in this Safety Data Sheet (SDS) is believed by Total Petrochemicals & Refining USA, Inc. (TPRI) to be accurate on the date issued. However, materials may present unknown hazards and should be used with caution. Final determination of suitability and use of any material is the sole responsibility of the user. Neither TPRI nor any of its subsidiaries or affiliated companies assumes any liability whatsoever for the accuracy or completeness of the information contained herein or reliance thereto. If the material is repackaged, the user is responsible and must ensure that proper health, safety and other necessary information is included with the material and/or on the container. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING THE MATERIALS OR THE INFORMATION CONTAINED IN THIS SDS. ALTERATION OF THIS DOCUMENT IS STRICTLY PROHIBITED. Page 363 of 377 Page 363 of 377 Page 363 of 377 Page 363 of 377 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Upholstery & Carpet Cleaner CAS Number: Manufacturer: STONER INCORPORATED SDS Date: 11/14/2013 To complete your binder, please link a different SDS for this product or print the SDS manually from and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 364 of 377 Page 364 of 377 Page 364 of 377 Page 364 of 377 ---PAGE BREAK--- Product Name: Wire & Mag Wheel Cleaner General Use: SECTION 2 - HAZARDS IDENTIFICATION Page 1 of 8 Metal wheel cleaner Synonyms: Aqueous Hydrofluoric Acid containing mixture Product Codes(s): AC-WM Wire & Mag Wheel Cleaner 2.2 Label Elements Hazard Symbol(s): Signal Word: Hazard Statement(s): [Prevention] [Response] P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do not induce vomiting. P280 - Wear protective gloves, protective clothing, eye protection and face protection. 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.1 Product identifier 2.1 Classification of substance or mixture Classification (Regulation (EC) No 1272/2008) Labeling (Regulation (EC) No 1272/2008) Precautionary Statements: H330 - Fatal if inhaled P260 - Do not breathe mist, vapors or spray. P262 - Do not get in eyes, on skin or on clothing. P284 - Wear respiratory protection. P264 - Wash hands and other skin areas exposed to material thoroughly after handling. H310 - Fatal in contact with skin Acute toxicity - Category 2 [H330] P271 - Use only outdoors or in a well-ventilated area, Uses advised against: Use only for intended application as a metal wheel cleaner P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. REACH Registration Number: Some materials in this product have been registered according to Regulation (EC) 1907/2006. The remaining substances in this product have been pre-registered according to Article 2 REACH Regulation (EC) No 1907/2006. H300 - Fatal if swallowed P270 - Do not eat, drink or smoke when using this product. Acute toxicity - Category 1 [H310] Acute toxicity - Category 2 [H300] Skin corrosive - Category 1B [H314] Danger H314 - Causes severe skin burns and eye damage P304 + 340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P263 - Wash contaminated clothing before reuse. P320 + P321 + P322 - Specific treatment: Contact POISON CENTER or doctor Immediately. Refer to Section 4 P303 + P361 + P353 - IF ON SKIN: Remove immediately all contaminated clothing. Rinse skin with water or P302 + P350 - IF ON SKIN: Gently wash with plenty of soap and water. shower. of this SDS. [Disposal] [Storage] P501 - Dispose of contents/container in accordance with national/local regulations. P405 - Store locked up. P403 + P233 - Store in a well-ventilated place. Keep container closed. +1-[PHONE REDACTED]; +1-[PHONE REDACTED] (toll free) Auto Industrial Marine Chemicals, Inc. Manufacturer/Distributor P.O. Box 876 Buford, GA 30515 USA 1.3 Details of the supplier and of the safety data sheet 1.4 Emergency telephone number: +1-[PHONE REDACTED] CHEMTREC SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION SAFETY DATA SHEET Wire & Mag Wheel Cleaner AUTO INDUSTRIAL MARINE CHEMICALS, INC. " The Professional' s Choice" Product definition: Mixture P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Page 365 of 377 Page 365 of 377 Page 365 of 377 Page 365 of 377 ---PAGE BREAK--- SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Not applicable There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to the health or the environment and hence require reporting in this section. % by Weight CAS Number EC Number EC Classification Ingredient Index Number 3.2 Mixtures <8 Hydrofluoric Acid 7664-39-3 231-634-8 009-003-00-1 R26/27/28; C, R35 Eyes: Immediately flush eyes with large amounts of water for 15 minutes, keeping eyelids apart and away from the eyeball. Remove contact lenses, if present and easy to do, and continue rinsing. Immediately contact a doctor, preferably an ophthalmologist. If a physician is not Skin: Flush skin with large amounts of water while removing contaminated clothing using PVC gloves, and continue rinsing for at least 15 minutes Ingestion: is conscious and alert. Give four Calcium Gluconate (500 mg) tablets every two hours; if not available, give the victim milk or milk of magnesia. Rinse mouth with water. Remove dentures if any. DO NOT induce vomiting. If swallowed, give 3 - 4 glasses of water to drink if victim 4.2 Most important and effects, both acute and delayed Eyes: Ingestion: Very toxic by skin contact. Causes deep and excruciatingly painful burns to the skin. include redness, blistering, localized pain Skin: Potential health and effects Corrosive. Causes severe burns to the eyes. include pain, tearing, corneal opacity and blindness. Can cause permanent If suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. Move respiration by trained personnel. Do not use mouth-to-mouth method if victim inhaled the substance; give artificial respiration with the aid of a SECTION 4 - FIRST AID MEASURES Inhalation: 4.1 Description of first aid measures Apply and continually massage Calcium Gluconate Gel into the burn area with gloved fingers until the pain is relieved. For larger burns Very toxic if inhaled. Causes severe irritation to the nose, throat and respiratory tract. include dizziness, headache, Inhalation: pocket mask equipped with a one-way valve or other proper respiratory medical device. If unconscious, maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Calcium Gluconate 2.5% in normal saline may be given by nebulizer with oxygen. If unavailable, four Calcium Gluconate (500 mg) tablets should be given by mouth every two hours until the patient is admitted to the hospital. Get immediate Never give anything by mouth to an unconscious person. Immediately seek medical assistance. To prevent aspiration of swallowed material immediately available, apply one or two drops of 0.5% tetracaine hydrochloride solution or other topical ophthalmic anesthetic and continue or burns treated with Calcium Gluconate Gel (in which pain is present longer than 30 minutes), a physician should inject 5% aqueous Calcium Gluconate beneath, around and in the burned area. Use of local anesthetics is not recommended, as reduction in pain is an indicator of the exposed person to fresh air immediately. If breathing is difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial effectiveness of treatment. For large or severe burns four Calcium Gluconate (500 mg) tablets should be given by mouth every two hours, until patient receives medical care. Seek immediate medical attention. lay victim on side with head lower than waist. damage to the cornea. Direct contact with liquid may cause blindness and/or permanent eye damage. dermatitis and deep burns. Large or multiple burns over large body surface area may also cause hypocalcaemia and other toxic effects which Additional information: Inhalation of hydrofluoric acid mist may cause severe irritation of the mucous membranes and respiratory tract. Acute may include burning of the nose, throat and upper respiratory tract, nasal congestion, coughing, choking, chills, chest tightness and bronchitis. High concentrations in air may cause rapid inflammation and congestion of the lungs as well as severe breathing difficulties that may be delayed in onset (after exposure has ceased). incoordination, chest pains, coughing respiratory paralysis and/or failure. Very toxic if swallowed. Causes severe burns to the mouth, mucous membranes, throat, esophagus and stomach. include Additional information: Ingestion of hydrofluoric acid will result in severe burns of the mouth, throat and stomach. may include spontaneous vomiting with diarrhea and possibly bloody stools. Page 2 of 8 may be fatal. medical attention. irrigation. Do not use skin treatment preparations for burns for the eyes. Use no oils or greases unless instructed to do so by a doctor. Irrigate with 1% Calcium Gluconate in normal saline for one to two hours to prevent or lessen corneal damage. swelling of the oral mucosa, nausea, vomiting, pain, diarrhea, bleeding and ulceration. May be fatal. Ingestion may also result in the fluoride ion binding with calcium to produce abnormally low levels of serum calcium (hypocalcaemia), which will impair many necessary physiological functions physiological functions in the body (e.g. muscle contractions). Systemic toxicity is likely to occur unless medical treatment is immediate. The effects of contact with dilute solutions of hydrofluoric acid or its vapors may be delayed. The potential delay in clinical signs Delayed effects: or for dilute solutions of 0 - 20% is up to 24 hours. Exposure can also cause bone and joint changes in humans (Fluorosis). Wire & Mag Wheel Cleaner <3 2-Butoxyethanol 111-76-2 203-905-0 <3 Ethoxylate 265-200-4 9016-45-9 603-014-00-0 Xn, R22 Chemical characterization (preparation) Prolonged or repeated exposure to Hydrofluoric Acid may lead to irreversible damage to health. Prolonged or repeated skin contact will Chronic: lead to necrosis of the skin. 4.3 Indication of any immediate medical attention and special treatment needed Advice to Doctor/Physician and Hospital Personnel: tissue calcium. Failure to start or provide correct medical treatment may be fatal. treatment must be specific for Hydrofluoric Acid Solutions. Hydrofluoric Acid penetrates deeply and rapidly below fat layers, binding and depleting The damage caused by this product is far more extensive than that caused by solutions of Hydrochloric or other acids. First aid and medical Page 366 of 377 Page 366 of 377 Page 366 of 377 Page 366 of 377 ---PAGE BREAK--- SECTION 5 - FIRE FIGHTING MEASURES Suitable methods of extinction: Non-combustible. Use media extinguishing media suitable for surrounding material. 5.2 Special hazards arising from the substance or mixture 5.1 Extinguishable media Unsuitable methods of extinction: unidentifiable organic compounds. may not be immediately apparent. Obtain medical attention immediately. Page 3 of 8 None known 6.2 Environmental precautions Avoid dispersal of spilled material or run-off and prevent contact with soil and entry into drains, sewers or waterways. SECTION 6 - ACCIDENTAL RELEASE MEASURES Wear appropriate protective clothing designated in Section 8. Evacuate unnecessary personnel. Remove all sources of ignition. Good ventilation 6.1 Personal precautions, protective equipment and emergency procedures Eyes: Following contact with the eyes ensure that first aid treatment has been carried out. Irrigate eyes with 1% Calcium Gluconate solution every two to three hours for as long as considered necessary. Topical anesthetic and corticosteroid drops may be useful. An ophthalmologist should Skin: Skin burns may become necrotic or gangrenous and may spread. Infiltration of Calcium Gluconate into the surrounding tissue may be Ingestion: Nasogastric suction with Calcium Gluconate solution may reduce systemic fluoride toxicity. The possibility of chemical burns to the gastrointestinal tract needs to be kept in mind. Acute systemic fluoride poisoning may cause hypocalcaemia (hypomagnesaemia) requiring required for severe burns. This can be performed by the injection of 5% Calcium Gluconate solution. Injection should be made with care on the requiring intravenous calcium (magnesium) therapy. Electrocardiogram results and blood calcium/magnesium need to be monitored in acute be consulted as severe corneal damage is possible. Long term monitoring may be necessary. hands, feet and face. For fingers, toes and less severe burns, continue application of 2.5% Calcium Gluconate gel four to six times a day for up to three or four days. Wear gloves while applying the gel. If Calcium Gluconate solution is injected into the fingers or toes great care should be There is a major risk of systemic toxicity following inhalation, ingestion or skin burns. Calcium depletion and electrolytic disorders may be fatal. A skin burn of more than 5% of body area may be associated with systemic effects. Treatment with intravenous Calcium Gluconate should be started immediately. Patient may require treatment in an intensive care unit. Serum calcium and magnesium analyses should be performed frequently and the patient's electrolytic balance may need correction. Electrocardiograms should be monitored routinely for prolonged Q-T interval or bradycardia. Hepatic and renal function should be monitored. Intravenous corticosteroids may be necessary. Inhalation: Inhalation may lead to chemical pneumonitis, hemorrhagic pulmonary edema and may be fatal. Acute respiratory failure may develop requiring airway support, 100% oxygen and positive end expiratory pressure treatment for pulmonary edema. Be prepared to intubate or perform taken and not more than 0.5 ml should be injected. Pain not relieved by use of the gel is best managed by inter-arterial infusion of Calcium Gluconate solution by medical personnel experienced in this technique. Surgical debridement of the affected area may be necessary in larger burns to control hypocalcaemia. Delayed pulmonary edema may occur with burns to the face and/or neck. systemic fluoride poisoning. a tracheotomy. The use of nebulized Calcium Gluconate in a 2% solution should be considered. May react with some metals to form potential flammable and toxic gases. During a fire the water contained in this product may evaporate, leaving a residue that may combust, producing corrosive fumes of fluorides as well as carbon monoxide and other exposed to extreme heat. Unusual fire and explosion hazards: Hazardous decomposition products: CORROSIVE. Product may liberate hydrogen gas on contact with metals, creating a fire and explosion hazard. Potential sources of ignition should be removed from the area. Closed containers may explode due to the build-up of pressure when 5.3 Advice for firefighters Wear full protective equipment including self-contained breathing apparatus, a full acid resistant suit, PVC gloves and enclosed footwear. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Water contaminated by this material must be contained from being discharged to any waterway, sewer or drain to prevent environmental contamination. Cover drains. Approach the release from upwind. Contain spill and avoid drainage to areas that cannot be treated. Carefully neutralize material with lime slurry, soda ash, limestone, caustic soda or other alkaline material. Cover with a large quantity of non-combustible, inert absorbent 6.3 Methods and materials for containment and cleaning up (e.g. sand, vermiculite, diatomaceous earth). DO NOT use combustible absorbent such as sawdust. Collect using non-sparking tools and place disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. is necessary. Discharged material may produce hydrogen fluoride fumes. into an approved container for proper disposal. Observe possible material restrictions (Sections 7.2, 10.5 and 13). Dispose of via a licensed waste Spills and releases may have to be reported to Federal and/or local authorized. See Section 15 regarding reporting requirements. 6.4 Reference to other sections See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. Wire & Mag Wheel Cleaner SECTION 7 - HANDLING AND STORAGE 7.1 Precautions for safe handling Wear all appropriate personal protective equipment specified in Section 8. Do not get in eyes or on skin or clothing. Do not breathe mist or vapor. Do not ingest. If normal use of material presents a respiratory hazard, use only adequate ventilation or wear an appropriate respirator. Keep in original container or in an approved alternative made form a compatible material, kept closed when not in use. Keep away from alkalis. Empty containers retain product residue and can be hazardous. Do not reuse container. Spillage should be cleaned up to avoid damage to surrounding materials. Page 367 of 377 Page 367 of 377 Page 367 of 377 Page 367 of 377 ---PAGE BREAK--- Advice on protection against fire and explosion Keep away from heat and incompatible materials. 7.2 Conditions for safe storage, including any incompatibilities (see Section 10.5) and food and drink. Transfer only to approved containers having correct labeling. Separate from alkalis. Keep container Store in accordance with local regulations. Store in original container in a dry, cool and well ventilated area, away from incompatible materials closed. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Use appropriate containment to avoid environmental contamination. Ventilate enclosed areas. Do not take internally. Keep locked up and out of reach of children. Individual protection measures: Respiratory Protection: Wear acid resistant, protective clothing to prevent repeated or prolonged contact with product. Wear enclosed Always use an approved respirator when vapor/aerosols are generated. Where risk assessment shows air-purifying respirators are appropriate use a full-faced respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a Other protective equipment: Environmental exposure controls: concentrations and quantities of the product handled. shoes or protective boots if the situation requires. Protective clothing needs to be selected specifically for the workplace, depending on Facilities storing or using this material should be equipped with an eyewash station and safety shower. First Aid Kits should include Calcium Gluconate (500 mg) tablets, Calcium Gluconate gel and Calcium Gluconate solution Change contaminated clothing Wear fitting chemical safety goggles (plastic lenses). A face shield is recommended for applications where product is sprayed. Refer to 29 CFR 1910.133, ANSI Z87.1 or European Standard EN 166. Eye/face protection: Hygiene measures: Hand Protection: Wear Neoprene, nitrile, chlorinated polyethylene or PVC gloves. Gloves should be inspected before use. Use proper glove backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Follow OSHA respirator removal technique (without touching glove's surface) to avoid skin contact with this product. Change gloves as needed to prevent skin contact. Protective clothing. Protective boots, if the situation requires. Do not empty into drains. Engineering Measures: Technical measures and appropriate working operations should be given priority over the use of personal protective 8.2 Exposure controls equipment. Use adequate ventilation. Local exhaust is preferable. Refer to Section 7.1 for additional data. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Control parameters OCCUPATIONAL EXPOSURE LIMITS 3 ppm TWA OSHA CAS Number Ingredient Hydrofluoric Acid 7664-39-3 ACGIH 0.5 ppm TWA; 2 ppm Ceiling NIOSH SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Clear, colorless liquid Odor Characteristic Odor Threshold 0.04 - 0.13 ppm (for Hydrofluoric acid) regulations found in 29 CFR 1910.134 or European Standard EN 149. Molecular Weight Not applicable Chemical Formula Not applicable pH 1.8 - 2.2 Freezing/Melting Point, Range Boiling Point, Range <0 °C (<32 100 °C (212 Evaporation Rate Not available Flammability (solid, gas) Not applicable Flash Point Not applicable Apart from the uses mentioned in Section 1.2, no other specific uses are stipulated. 7.3 Specific end uses Immediately. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking or using the lavatory. 3 ppm; 2.5 mg/m3 TWA; 6 ppm; 5 mg/m3 Ceiling; 30 ppm IDLH Page 4 of 8 Autoignition Temperature Not applicable Decomposition Temperature Not determined Lower Explosive Limit (LEL) Not applicable Upper Explosive Limit (UEL) Not applicable Wire & Mag Wheel Cleaner 111-76-2 2-Butoxyethanol 50 ppm; 240 mg/m3 700 ppm 50 ppm TWA; 100 mg/m3 ceiling (aerosol only) Vapor Pressure Vapor Density <1 (Air = 1) Specific Gravity Viscosity No data available Solubility in Water Complete Partition Coefficient: n-octanol/water <1 (estimated) Volatiles by Volume @ 70 ºF 1.005 95.73% 17 mm Hg @ 20 °C 9.2 Other data No data available VOC Content 0.09% Page 368 of 377 Page 368 of 377 Page 368 of 377 Page 368 of 377 ---PAGE BREAK--- SECTION 11 - TOXICOLOGICAL INFORMATION Acute Oral Toxicity Hydrofluoric Acid solutions can be fatal if swallowed. 11.1 Information on toxicological effects Thermal decomposition products include hydrogen fluoride gas and oxides of carbon. 10.5 Incompatible materials 10.6 Hazardous decomposition products Extreme temperatures. Contact with incompatible materials. 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid Hydrofluoric Acid: LC50, rat - 1.34 mg/L, 1 h; LCLo, human - 0.04 mg/L, 30 min Acute inhalation toxicity Hydrofluoric Acid solutions of 7% can be fatal by absorption. Acute dermal toxicity No data available Sensitization A 2% Hydrofluoric Acid solution was corrosive to rabbit skin with 1 hour exposure, but not with 1 minute exposure. Solutions of 7% HF Eye irritation/corrosion Skin irritation/corrosion Genotoxicity in vitro No data available Aspiration hazard No data available No data available Specific organ toxicity - repeated exposure Handle in accordance with good industrial hygiene and safety practice. Product should be handled with care. 11.2 Further information No data available Mutagenicity No data available Specific organ toxicity - single exposure Page 5 of 8 Stable under recommended storage conditions, handling and use. 10.2 Chemical stability Metals and metal powders, strong oxidizing agents, strong bases, strong reducing agents, acetic alcohols, amines, glass, concrete silicone bearing materials, carbonates, cyanides, acrylonitrile, chlorates, nitrates, perchlorates, permanganates, epichlorohydrin, aniline, carbides, organic materials. Hydrofluoric Acid reacts with glass, concrete and other silicon bearing materials to form silicon tetrafluoride gas. Reacts with carbonates, sulfides, and cyanides to yield toxic gases (carbon dioxide, hydrogen sulfide, hydrogen cyanide). Product reacts with alkalis and some oxides in a violent violent, exothermic reaction. Reaction with metals yields hydrogen gas, a fire and explosive reactive hazard. Corrosive to many materials including leather, natural rubber and many organics. SECTION 10 - STABILITY AND REACTIVITY 10.1 Reactivity No special reactivity has been reported. Hazardous polymerization does not occur. cause severe burns. Chronic Effects: Wire & Mag Wheel Cleaner Ethoxylate - LD50, Rat: 3,310 mg/kg 2-Butoxyethanol - LD50, Rat: 1,746 mg/kg 2-Butoxyethanol - LC50, Rat: 700 ppm, 7 h Ethoxylate - LD50, Rabbit: >2,000 mg/kg 2-Butoxyethanol - LD50, Rat: >2,000 mg/kg ACGIH, A3 Carcinogen - Confirmed animal carcinogen with unknown relevance to humans. Not listed as a carcinogen by NTP or OSHA. 2-Butoxyethanol (CAS #111-76-2): IARC, Group 3 carcinogen - Not classifiable as to its carcinogenicity to humans. The remaining components in this product are not listed as carcinogens by ACGIH, IARC, NTP or OSHA. No data is available regarding the fertility effects. mutagenicity and/or teratogenicity of this product, nor is there any available data that indicates that it causes adverse developmental and/or 12.2 Persistence and degradability Expected to be biodegradable. SECTION 12 - ECOLOGICAL INFORMATION 12.1 Toxicity Acute and prolonged toxicity to fish (HF): Fish (fresh water), lethal concentration: 60 ppm (time period not specified) 2-Butoxyethanol is harmful to algae or higher aquatic plants. Hydrofluoric acid solutions of 7% can cause severe eye burns. Risk of serious damage to eyes. Page 369 of 377 Page 369 of 377 Page 369 of 377 Page 369 of 377 ---PAGE BREAK--- SECTION 13 - DISPOSAL CONSIDERATIONS Ethoxylate is a marine pollutant. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Page 6 of 8 The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff 13.1 Waste treatment methods product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a The classification of this product may meet the criteria for a hazardous waste. Product Methods of disposal: and contact with soil, waterways, drains and sewers. Hazardous waste: SECTION 14 - TRANSPORT INFORMATION Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping. This product contains a marine pollutant. Marine Pollutant: 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available. 12.6 Other adverse effects Additional ecological information 12.4 Mobility in soil, water 12.3 Bioaccumulation potential Harmful to the aquatic environment. May cause adverse effects in the aquatic environment due to changes in pH. Hydrofluoric Acid (CAS #7664-39-3); waste number U134 (Corrosive waste, Toxic waste) RCRA U-Series: Wire & Mag Wheel Cleaner Ethoxylate has the potential to bioaccumulate. n-Octanol/water partition coefficient (log Pow) is ~4.48. Ethoxylate absorbs to soil and has low mobility. The remaining components are water soluble and highly mobile in soil. U. S. Federal Regulations OSHA Hazard Communication Standard: This material contains "Hazardous Chemicals" as defined by the OSHA Hazard Communication Standard (28 CFR 1910.1200). Target Organ Effect, Toxic by inhalation, Highly toxic by ingestion, Highly toxic by skin absorption, Corrosive SECTION 15 - REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for substance or mixture OSHA Process Safety Management Standard: Hydrofluoric Acid (CAS # 7664-39-3) is regulated under OSHA PSM Standard 29 CFR 1910.119. EPA Risk Management Planning Standard: Hydrofluoric Acid (CAS #7664-39-3) is regulated under EPA RMP Standard (RMP) 40 CFR Part 68. TSCA Status: All components of this product are listed on the Toxic Substance Control Act (TSCA) Inventory. This product is subject to EPA Federal Insecticide, Fungicide and Rodenticide Act: This product is not a registered Pesticide under the FIFRA, 40 CFR Part 150. TSCA 12(b) Export Notification. Product contains Ethoxylate, which is a known marine pollutant. Proper Shipping Name: Corrosive liquids, n.o.s. (contains hydrofluoric acid) Hazard Class: 8 Packing Group: II NAERG: UN1760 UN/NA: IMO/IMDG (Water Transportation) EMS Number: F-A, S-B Proper Shipping Name: Hazard Class: 8 Packing Group: UN1760 II UN/NA: Guide #154 Marine Pollutant: No Corrosive liquids, n.o.s. (contains hydrofluoric acid) Packaging Authorization: Non-Bulk: 49 CFR 173.202; Bulk: 173.242 Packaging Exceptions: 49 CFR 173.154 US DOT (Domestic Ground Transportation) RID/ADR (Rail Transportation) Proper Shipping Name: Hazard Class: 8 Packing Group: II UN1760 UN/NA: Corrosive liquids, n.o.s. (contains hydrofluoric acid) ICAO/IATA (Air Transportation) Proper Shipping Name: Hazard Class: 8 Packing Group: UN1760 II UN/NA: Corrosive liquids, n.o.s. (contains hydrofluoric acid) Quantity Limitations: 49 CFR 175.27 and 175.75 - Cargo Aircraft Only: 30 L; Passenger Aircraft: 1 L Page 370 of 377 Page 370 of 377 Page 370 of 377 Page 370 of 377 ---PAGE BREAK--- Canadian Ingredient Disclosure List (IDL): Hydrofluoric Acid and 2-Butoxyehtanol are listed on the IDL. European Economic Community Canadian National Pollutant Release Inventory (NPRI): 1 WGK, Germany (Water danger/protection): Canadian Controlled Products Regulations (CPR): Products Regulations, and the MSDS contains all the information required by the Controlled Products Regulations. This product has been classified in accordance with the hazard criteria of the Controlled Canada WHMIS Hazard Symbol and Classification: Other U.S. State Inventories: Hydrofluoric Acid (CAS #7664-39-3) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/ Clean Water Act (CWA) Hydrofluoric Acid is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. U.S. State Regulations California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986: Air Pollutants List(s): CA, DE, ID, IL, ME, MA, MN, NC, NJ, NY, PA, WA, WI. Page 7 of 8 Hydrofluoric Acid, 2-Butoxyethanol and ethoxylate are listed. C - Corrosive to skin D-2B - Materials causing other D-1A - Materials causing immediate and serious toxic effects toxic effects SARA 313 Information: The following components are subject to reporting requirements of Section 313 of the Emergency Planning and Community Right-to Know Act of 1986: Hydrofluoric Acid (CAS #7664-39-3) and 2-Butoxyethanol (CAS #111-76-2). Superfund Amendments and Reauthorization Act (SARA) SARA 302/304 Extremely Hazardous Substance: SARA Section 311/312 Hazard Categories: Acute Health Hazard, Chronic Health Hazard SARA 302/304 Emergency Planning & Notification: Comprehensive Response Compensation and Liability Act (CERCLA): This product contains the following CERCLA reportable substances: Hydrofluoric Acid (CAS #7664-39-3), RQ - 45.36 kg (100 lbs) Hydrofluoric Acid is subject to reporting requirements of these sections of Title III of SARA. Hydrofluoric Acid (CAS #7664-39-3), as 100% HF, is listed as a Hazardous Air Pollutant (HAP) as designated in CAA Section 112 Clean Air Act (CAA) This product does not contain any Class 1 Ozone depletors. This product does not contain any Class 2 Ozone depletors. Hydrofluoric Acid Is subject to reporting requirements of these sections of Title III of SARA. Hydrofluoric Acid (CAS #7664-39-3), as 100% HF, is found on the CAA Section 112 list of Accidental Release Prevention Substances. Wire & Mag Wheel Cleaner 2-Butoxyethanol (CAS #111-76-2) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/ Air Pollutants lists: CA, ID, MA, MN, NJ, PA, WA, WI. Contains no chemicals listed by California Prop 65. Labeling (67/548/EEC to 1999/45/EC) C - Corrosive T+ - Very toxic Risk Phrases: R26/27/28 - Toxic by inhalation, in contact with skin and if swallowed. S9 - Keep container in a well-ventilated place. Safety Phrases: S1/2 - Keep locked up and out of the reach of children. S7 - Keep container closed. R35 - Causes severe burns. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible). Europe: Inventory of New and Existing Chemicals (EINECS) United States: Toxic Substance Control Act (TSCA) Australia: Australian Inventory of Chemical Substances (AICS) China: Inventory of Existing Chemical Substances in China (IECSC) Canada: Domestic Substance List (DSL). Japan: Inventory of Existing and New Chemical Substances (ENCS) Korea: Existing Chemicals List (ECL) Philippines: Philippines Inventory of Chemicals and Chemical Substances (PICCS) Chemical inventory Lists New Zealand: New Zealand Inventory of Chemicals (NZIoC) Yes Yes Yes Yes Yes No Yes Yes Yes *"Yes" indicates that all components of this product are in compliance with the inventory requirements administered by the governing country. *"No" indicates that one or more components of this product are not on the inventory and are not exempt from listing. Country Inventory Name Inventory Listing* Canada: Non-Domestic Substance List (NDSL). No 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out. Page 371 of 377 Page 371 of 377 Page 371 of 377 Page 371 of 377 ---PAGE BREAK--- SECTION 16 - OTHER INFORMATION HMIS and NFPA Hazard Rating Legend 4 = EXTREME * = Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH Hazardous Material Information System (HMIS) Health Flammability Physical Hazard Personal Protection 1 0 H 3 Full Text of Risk – Phrases Referenced in Section 3. R36/38 - Irritating to eyes and skin. Health Flammability Instability Special 1 3 0 National Fire Protection Association (NFPA) Page 8 of 8 the responsibility of the user to comply with all Federal, State and local laws and regulations regarding use of this product. Vendees or users assume all risks associated with the The information herein is given in good faith and is believed to be accurate and correct; however, no warranty, expressed or implied, is made. Auto Industrial Marine Chemicals, Inc. assumes no responsibility for personal injury or property damage that may arise from the use of this material since the conditions of handling and use are beyond our control. It is use of this material. Preparation Date: 27 September 2013 Wire & Mag Wheel Cleaner * Page 372 of 377 Page 372 of 377 Page 372 of 377 Page 372 of 377 ---PAGE BREAK--- zymöl enterprises, inc. P.O. Box 469 North Branford, CT 06471 Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Zymöl Cleaner Wax PRODUCT CODE CSZ503 CHEMICAL FAMILY Mixture: Water, Waxes, Emulsifiers, Additives CHEMICAL NAME Automotive polish and wax FORMULA Mixture MANUFACTURER EMERGENCY TELEPHONE NUMBERS Zymöl Enterprises Inc. Transportation: P. O. Box 469 CHEMTREC: [PHONE REDACTED] North Branford, CT 06471 Medical: Phone: 1-[PHONE REDACTED] Contact your local Poison Control Center 2. POSITION/INFORMATION ON INGREDIENTS COMPONENT CAS NUMBER CONCENTRATION (wt EXPOSURE LIMITS 8 hrs. TWA(ppm) CARCINOGEN OSHA PEL ACGIH TLV (OSHAS, NPT, IARC) n/av n/av n/av 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS INHALATION: Mist or Spray may cause irritation. No Chronic effects known. INGESTION: May cause digestive system upsets and/or Nausea. No chronic effects known. SKIN CONTACT: Can cause irritation with excessive or repeated contact. No chronic effects known. EYE CONTACT: Can cause irritation. No chronic effects known. Page 373 of 377 Page 373 of 377 Page 373 of 377 Page 373 of 377 ---PAGE BREAK--- - 2 - 4. FIRST AID MEASURES EYE: Flush with water for 15 minutes. SKIN: Remove contaminated clothing. Rinse affected areas thoroughly with water. INHALATION: Remove to fresh air. Use artificial respiration and oxygen if needed. INGESTION: Rinse mouth immediately. Drink large amounts of water. Do not induce vomiting. Get prompt medical attention. 5. FIRE FIGHTING MEASURES FLASH POINT: (Open Cup): 200oF Explosive Limits: Lower: n/av Upper: n/av EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, foam SPECIAL FIRE FIGHTING PROCEDURES: None 6. ACCIDENTIAL RELEASE MEASURES SPILL OR LEAK PROCEDURES: Small spills can be flushed to sanitary sewer if permitted by local regulations. Take up large spills using absorbing media and place in waste container. Floors may be slippery. Care should be taken not to slip. 7. HANDLING AND STORAGE: Keep away from strong oxidizers such as peroxides. Keep containers closed. Keep from freezing. STORAGE TEMPERATURE (MIN./MAX.): 32 degrees F / 120 degrees F SHELF LIFE: 5-7- years’ minimum when the original container is kept closed and properly stored. SPECIAL SENSITIVITY: None HANDLING AND STORAGE PRECAUTIONS: Rinse thoroughly before handling, re-use, or disposable. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION REQUIREMENTS: Wear splash proof goggles. Have convenient eye wash stations. SKIN PROTECTION REQUIREMENTS: Wear water resistant gloves as needed to reduce exposure. RESPIRATOR/VENTILATION PROTECTION REQUIREMENTS: None with normal use INGESTION PROTECTION REQUIREMENTS: Avoid swallowing. Wear face shield if face contact is likely. EXPOSURE LIMITS: In all cases get prompt medical attention if effects persist. Page 374 of 377 Page 374 of 377 Page 374 of 377 Page 374 of 377 ---PAGE BREAK--- - 3 - 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM: Liquid COLOR: Light Blue ODOR: Fruity Coconut BOILING POINT: 212 degrees Fahrenheit MELT / FREEZE POINT: 32 degrees F PH: 7.5 SOLUBILITY IN WATER: dispersible SPECIFIC GRAVITY: 1.082 @ 77 degrees F % NON-VOLATILE BY WEIGHT: 76% VAPOR PRESSURE @ 20 degrees Celsius: N/A VAPOR DENSITY: N/A 10. REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBILITIES: strong oxidizing agents. DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide and hydrocarbons when burned. 11. TOXICOLOGICAL INFORMATION ACUTE INHALATION: Aspiration into lungs can cause vomiting and/or diarrhea CHRONIC INHALATION: Not Determined ACUTE SKIN CONTACT: Prolonged or repeated contact can cause moderate irritation, de-fatting or dermatitis. CHRONIC SKIN CONTACT: Not Determined ACUTE EYE CONTACT: Can cause irritation, redness, tearing or blurred vision. 12. ECOLOGICAL INFORMATION There is no information available at this time. 13. DISPOSAL CONSIDERATIONS RCRA HAZARDOUS WASTE: Not classified as a hazardous waste. WASTE DISPOSAL METHOD: Waste disposal must be in accordance with appropriate Federal, State, and local regulations. Page 375 of 377 Page 375 of 377 Page 375 of 377 Page 375 of 377 ---PAGE BREAK--- - 4 - 14. TRANSPORT INFORMATION DOT INFORMATION: Not regulated as a hazardous material PROPER SHIPPING NAME: Non Bulk Not regulated Bulk Not Regulated TECHNICAL SHIPPING NAME: Consumer commodity HAZARD CLASS: Non Bulk None Bulk None UN NUMBER: None PRODUCT RQ (lbs): None LABEL: Non Bulk Not Required Bulk Not Required PLACARD: Non Bulk None Bulk None FREIGHT CLASS BULK: None FREIGHT CLASS PACKAGE: None PRODUCT LABEL None 15. REGULATORY INFORMATION TSCA STATUS: All ingredients listed CERCLA REPORTABLE QUANTITY: None SARA TITLE III: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES None SECTION 311/312 HAZARD CATEGORIES Acute Health No Chronic Health No Fire No Reactive No Sudden Release of Pressure No SECTION 313 CHEMICAL NAME CAS NUMBER CONCENTRATION RCRA STATUS: Not a RCRA hazardous waste CANADIAN STATUS: All materials contained in this product are listed on the Canadian Domestic Substances List (DSL). Page 376 of 377 Page 376 of 377 Page 376 of 377 Page 376 of 377 ---PAGE BREAK--- - 5 - EUROPEAN UNION: All materials contained in this product are listed on EINECS STATE REGULATORY INFORMATION The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. COMPONENT/ CAS NUMBER CONCENTRATION STATE CODE None n/ap none 16. OTHER INFORMATION HMIS CLASSIFICATION Health 1 Flammability 1 Reactivity 0 PPI B NFPA RATING Health 1 Fire 1 Reactivity 0 Special None REASON FOR ISSUE Revised for ANSI format PREPARED BY James P. Heidel TITLE Technical Manager APPROVAL DATE June 20, 2008 SUPERCEDES DATE January 18, 2000 REVISION NUMBER 1.3 This information is to the best of Zymöl Enterprises Inc.’s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitableness and completeness of such information for his own particular use. Page 377 of 377 Page 377 of 377 Page 377 of 377 Page 377 of 377