Document Butte_doc_3299d03d48

Butte, Montana PM2.5 Source Apportionment Research Study Summer 2013 Final Report January 4, 2014 by Tony J. Ward, Ph.D. University of Montana – Missoula Skaggs Building 176 Missoula, MT 59812 Office: (406) 243-4092 Fax: (406) 243-2807 ---PAGE BREAK--- 2 1.0. Executive Summary During the summer of 2013, ambient samples of PM2.5 (particulate matter less than or equal to 2.5 microns in diameter) were collected in Butte, Montana. These samples were then used to identify the major sources of PM2.5 to the Butte airhshed during the summer of 2013. As part of the program, air samples were collected every six days from June 3 through September 7, 2013. After the samples were collected, they were analyzed for chemical compounds of interest (elements, carbon, and ions), with these data then used in a Chemical Mass Balance (CMB) computer model to apportion the sources of the fine fraction. For the samples collected during the summer of 2013 and used for CMB modeling, PM2.5 mass concentrations were very low. The average PM2.5 24-hour concentration was 5.8 micrograms per cubic meter (µg/m3) on the scheduled sample days (n=10), with the highest concentration (11.5 µg/m3) measured on 7/3/13. The results of the CMB modeling revealed that wood smoke was the major source of ambient PM2.5 throughout the summer months in Butte, contributing nearly 72% of the measured PM2.5. This wood smoke component is likely from residential outdoor biomass burning, as well as local and regional controlled / wild forest fire events. The other sources of PM2.5 identified by the CMB model were street sand/road dust secondary sulfate ammonium nitrate and automobile exhaust Approximately 2.4% of the PM2.5 was unexplained by the CMB model. ---PAGE BREAK--- 3 2.0. Overview During the summer of 2013, PM2.5 sampling was conducted to identify the major sources of ambient PM2.5 in Butte, Montana. Within this report, the sampling, analytical, and computer modeling methodologies are described in Sections 3.0 through 5.0, respectively. Section 6.0 presents the results of the PM2.5 sampling and CMB modeling program. Sections 7.0 and 8.0 present a discussion of all of the CMB modeling findings, and results of the Quality Assurance/Quality Control (QA/QC) program, respectively. 3.0. PM2.5 Sampling Program 3.1. Sampling Program Experimental Method PM2.5 sampling was conducted every six days following the Environmental Protection Agency’s (EPA) fixed monitoring schedule at the Butte-Greeley school during the summer of 2013. The Butte sampling site is part of the Chemical Speciation Network (CSN) for EPA. Sampling was conducted using a MetOne (Grants Pass, OR) Spiral Ambient Speciation Sampler (SASS) and a URG 3000N Sequential Particulate Speciation System. During each 24-hour event, the SASS collected ambient air at a flow rate of 6.7 liters per minute (LPM) through Teflon and nylon filter media, respectively, while the URG collected air sample through a quartz filter at a flow rate of 22.0 LPM. 3.2. Sampling Program Quality Assurance / Quality Control (QA/QC) A stringent QA/QC program was employed throughout this study. Prior to sampling, clean filters (Teflon, nylon, and quartz) were provided by the Research Triangle Institute (RTI, Research Triangle Park, NC). Following the sampling events, exposed Teflon and nylon filters were sent back to RTI for laboratory analyses, while the exposed quartz filters were sent to Desert Research Institute (Reno, NV). During shipment of both clean and exposed filter media, all PM2.5 filters remained in their protective containers and were transported in a cooler containing cold packs. Throughout the sampling program, the air samplers were maintained by Montana Department of Environmental Quality (DEQ) staff. During each sampling event (24-hour period), the filters were subjected to temperatures that did not exceed the ambient temperature by more than five °C for more than 30 minutes continuously. A goal of DEQ and Butte-Silver Bow City-County Health Department personnel was to remove the exposed filters from the samplers within 48 hours following the conclusion of the sampling event, and also to refrigerate the exposed filters immediately upon collection. The air sampler was also audited with an independent transfer standard during the program to verify the accurate measurement of air flow rates, ambient/filter temperatures, and barometric pressures. In addition, PM2.5 quartz filter field blanks were collected periodically throughout the program in an effort to determine any artifact carbon contamination. 4.0. Analytical Program 4.1. PM2.5 Speciation Data The Met One Super SASS / URG 3000N collected ambient PM2.5 on Teflon, nylon, and quartz filter media, respectively. Exposed Teflon and nylon filter samples were analyzed by RTI. From the Teflon filter, a gravimetric analysis (RTI, 2008) was initially performed followed by an elemental analysis (RTI, 2009a) using energy-dispersive X-ray fluorescence (EDXRF) where 31 ---PAGE BREAK--- 4 elements were quantified. From the nylon filter, ions (including ammonium, potassium, sodium, nitrate, and sulfate) were measured by ion chromatography (IC) (RTI, 2009b; RTI, 2009c). From the quartz filter, elemental carbon and organic carbon (EC/OC) concentrations were measured by Desert Research Institute using the IMPROVE_A method (Chow et al., 2007). Following the respective analyses, sample results (including analyte concentrations and uncertainties) were provided to Tony Ward for use in the CMB source apportionment model. 4.2. Analytical Program QA/QC RTI (PM2.5 mass, elements and ions) and Desert Research Institute (OC/EC) were responsible for QA/QC activities within their respective laboratories. 5.0. Computer Modeling Program In this project, the most recent version of the Chemical Mass Balance (CMB) computer model (Version 8.2) was utilized to apportion the sources of PM2.5 in Butte. The CMB receptor model (Friedlander, 1973; Cooper and Watson, 1980; Gordon, 1980, 1988; Watson, 1984; Watson et al., 1984; 1990; Hidy and Venkataraman, 1996) is based on an effective-variance least squares method, and consists of a solution to linear equations that expresses each receptor chemical concentration as a linear sum of products of source fingerprint abundances and contributions. For each sample day, the CMB modeling process began by selecting from a combination of 75 sources (see Table 1) and 38 chemical species (31 elements, 5 ions, OC and EC, Table 3) in an effort to reconstruct the measured Butte ambient PM2.5 mass and chemical composition. As part of the CMB modeling procedure, multiple combinations would be tried for each sample run in an effort to select the best combination of sources and species, with an evaluation of the diagnostic performance measures conducted each time until an optimal fit could be obtained. The resulting output file contained the source contribution estimate (SCE) of each identified source, along with the associated standard errors (STD ERR). Unexplained concentrations were also calculated by taking the difference between the actual measured mass and the CMB predicted mass for each sample run. 5.1. CMB Model Source Profiles For the CMB modeling program, a list of sources that could potentially contribute PM2.5 to the Butte airshed was developed. For each identified source, an attempt was made to locate a source profile. Source profiles are the fractional mass abundances of measured chemical species relative to primary PM2.5 mass in source emissions, and are part of the input data loaded into the CMB model. Source profiles represent a general source category rather than any local, individual, PM2.5 emission source. Table 1 presents the source profiles used in the summer 2013 Butte CMB study. The profiles in this table are listed together as source groups, and can be broken down into profiles for street sand and road dust (Profiles 1- 10 and 75), pure secondary source emissions (Profiles 11-13), gasoline and diesel exhaust emissions (Profiles 14 – 40), tire and brake wear (Profiles 41 - 46), meat cooking (Profiles 47 - 50), deicer (Profile 51), and wood combustion (Profiles 52 – 71). Since this source list was also used for a previous western Montana CMB study funded by DEQ (study areas of Missoula, Butte, Belgrade, Hamilton, and Helena), local industrial sources are included in Table 1 (Profiles 72 – 74). ---PAGE BREAK--- 5 Table 1: PM2.5 source profiles used in the summer 2013 Butte CMB modeling program. Profile ID Description 1 ST_SANDF CITY STREET SANDING PILE, STREET SAND 2 ERN_RUSF INTERSECTION ERNEST AND RUSSEL ST, STREET SAND 3 RUS_STF2 RUSSEL ST, STREET SAND 4 DESP_LTF DESPERADO PARKING LOT, STREET SAND 5 SPECIATE 411042.5, PAVED ROAD DUST - BUTTE, MT 6 SPECIATE 411302.5, PAVED ROAD DUST – COMPOSITE 7 SPECIATE 411052.5, PAVED ROAD DUST - EAST HELENA, MT 8 SPECIATE 411012.5, PAVED ROAD DUST - MISSOULA, MT 9 UNDST_CP SPECIATE 412202.5, UNPAVED ROAD DUST – COMPOSITE 10 UNDST_HE SPECIATE 412042.5, UNPAVED ROAD DUST - EAST HELENA, MT 11 SO4_FZER SULFATE (SO4 IS ONLY SPECIE, THEREFORE IS ONLY NONZERO CONCENTRATION) 12 NH4SO4F2 AMMONIUM SULFATE (INCLUDES NH4) 13 NH4NO3F2 AMMONIUM NITRATE (INCLUDES NH4) 14 LDV_PBCF SPECIATE 311052.5 LIGHT DUTY VEHICLE-LEADED COMPOSITE 15 LDV_XPBF SPECIATE 312022.5 LIGHT DUTY VEHICLE-UNLEADED 16 LDV_DSLF SPECIATE 321022.5 LIGHT DUTY VEHICLE-DIESEL 17 LDV_DS2F SPECIATE 321032.5 LIGHT DUTY VEHICLE-DIESEL (2ND PROFILE OF THIS TYPE) 18 HDV_DSLF SPECIATE 322032.5, HEAVY DUTY VEHICLE-DIESEL 19 LDV_NCAT SPECIATE 311082.5, LIGHT DUTY VEHICLE - NON CATALYST 20 LDV_WCAT SPECIATE 311072.5, LIGHT DUTY VEHICLE - WITH CATALYST 21 HDV_TRK1 SPECIATE 322022.5, HEAVY DUTY DIESEL 22 HDV_TRK2 SPECIATE 322082.5, HEAVY DUTY DIESEL TRUCKS 23 LDV_UNL1 SPECIATE 312012.5, LIGHT DUTY VEHICLE – UNLEADED 24 LDV_UNL2 SPECIATE 312032.5, LIGHT DUTY VEHICLE – UNLEADED 25 GASEXST1 SPECIATE 3875, GASOLINE EXHAUST - WINTER, SMOKER 26 GASEXST2 SPECIATE 3884, GASOLINE EXHAUST - WINTER, LOW EMITTER PROFILE 1 27 GASEXST3 SPECIATE 3888, GASOLINE EXHAUST - WINTER, LOW EMITTER PROFILE 2 28 GASEXST4 SPECIATE 3892, GASOLINE EXHAUST - WINTER, HIGH EMITTER PROFILE 1 29 GASEXST5 SPECIATE 3896, GASOLINE EXHAUST - WINTER, HIGH EMITTER PROFILE 2 30 GASEXST6 SPECIATE 3900, GASOLINE EXHAUST - WINTER, NON-SMOKER 31 GASEXST7 SPECIATE 3904, GASOLINE EXHAUST - WINTER, SMOKER PROFILE 1 32 GASEXST8 SPECIATE 3908, GASOLINE EXHAUST - WINTER, SMOKER PROFILE 2 33 SPECIATE 3878, DIESEL EXHAUST PROFILE 1 34 SPECIATE 3879, DIESEL EXHAUST PROFILE 2 35 SPECIATE 3880, DIESEL EXHAUST PROFILE 3 36 SPECIATE 3912, DIESEL EXHAUST PROFILE 4 37 SPECIATE 3913, DIESEL EXHAUST PROFILE 5 38 SPECIATE 3914, DIESEL EXHAUST PROFILE 6 39 D_TRAINF DIESEL TRAIN (SENT FROM MISSOULA) 40 D_TRUCKF DIESEL TRUCK (SENT FROM MISSOULA) 41 TIRE_WR1 SPECIATE 340022.5, TIRE WEAR PROFILE 1 42 TIRE_WR2 SPECIATE 340032.5, TIRE WEAR PROFILE 2 43 TIRE_WR3 SPECIATE 340082.5, TIRE WEAR PROFILE 3 44 TIRE_WR4 SPECIATE 3156, TIRE WEAR PROFILE 4 45 BRAKEASB SPECIATE 340042.5, BRAKE LINING – ASBESTOS 46 BRAKEWER SPECIATE 3157, BRAKE WEAR ---PAGE BREAK--- 6 47 MTCOOKCH SPECIATE 160002.5, MEAT COOKING – CHARBROILING 48 MTCOOKFR SPECIATE 160012.5, MEAT COOKING – FRYING 49 COOKING1 SPECIATE 4383, COOKING 50 COOKCHAR SPECIATE 91005, COOKING - CHARBROILING COMPOSITE 51 DEICER_F MAGNESIUM CHLORIDE DEICER (CHEMICAL ANALYSIS SENT FROM MISSOULA) 52 RWC_MEDF SPECIATE 421042.5 RESIDENTIAL WOOD SMOKE FROM MEDFORD, OR 53 RWC_POCF SPECIATE 421052.5 RESIDENTIAL WOOD SMOKE FROM POCATELLO, ID 54 RWC_F222 RESIDENTIAL WOOD COMBUSTION (SUPPLIED BY MISSOULA) 55 RWC_ALON SPECIATE 423182.5, RESIDENTIAL WOOD COMBUSTION 56 RWC_COMP SPECIATE 423032.5, RESIDENTIAL WOOD COMBUSTION, COMPOSITE 57 RWB_COMP SPECIATE 423302.5, COMPOSITE OF RESIDENTIAL WOODBURNING SOURCES 58 SPECIATE 421022.5, WOOD STOVES - AVERAGE ALL FUELS 59 SPECIATE 421012.5, WOOD STOVES - PINE FUELS 60 SPECIATE 3235, RESIDENTIAL WOOD BURNING PROFILE 1 61 SPECIATE 3236, RESIDENTIAL WOOD BURNING PROFILE 2 62 SPECIATE 3238, RESIDENTIAL WOOD BURNING PROFILE 3 63 SPECIATE 3239, RESIDENTIAL WOOD BURNING PROFILE 4 64 SPECIATE 3240, RESIDENTIAL WOOD BURNING PROFILE 5 65 SPECIATE 3769, RESIDENTIAL WOOD BURNING PROFILE 6 66 SPECIATE 3770, RESIDENTIAL WOOD BURNING PROFILE 7 67 RWCCOMP1 SPECIATE 423192.5, RESIDENTIAL WOOD COMBUSTION COMPOSITE 68 RWCCOMP2 SPECIATE 423312.5, RESIDENTIAL WOODSTOVE COMPOSITE 69 SPECIATE 91031, RESIDENTIAL WOOD COMBUSTION: HARDSOFT - COMPOSITE 70 SPECIATE 91032, RESIDENTIAL WOOD COMBUSTION: HARDSOFTN/A - COMPOSITE 71 SPECIATE 91033, RESIDENTIAL WOOD COMBUSTION: SOFT – COMPOSITE 72 GRAINDST SPECIATE 214012.5, GRAIN HANDLING DUST 73 SPECIATE 272032.5, CEMENT KILN (COAL-FIRED) 74 SPECIATE 275012.5, GYPSUM CALCINER 75 SOILDUST SPECIATE 413062.5, SOIL DUST - EAST HELENA, MONTANA Source profiles were either taken directly from SPECIATE 4.0 (USEPA, 2006) or from previous Missoula Valley CMB applications (Carlson, 1990; Schmidt, 1996; Ward and Smith, 2005). SPECIATE 4.0 is EPA's repository of Total Organic Compound (TOC) and Particulate Matter (PM) speciated source profiles for use in source apportionment studies. For each source found in the database, both the compound fraction and uncertainty for the source-specific compounds are presented. Since Missoula and Butte have similar topographies and many of the same sources of PM2.5, several of the CMB source profiles developed in past Missoula CMB applications were included in the Butte PM2.5 source apportionment program. These include profiles for street sand (Profiles 1 - secondary sulfate (Profile 11), secondary ammonium sulfate (Profile 12), secondary ammonium nitrate (Profile 13), diesel train (Profile 39) and diesel truck exhaust (Profile 40), deicer (Profile 51), and residential wood combustion (Profile 54). All SPECIATE and Missoula CMB profiles used in the Butte CMB were reviewed before being loaded as input files into the CMB model. For those chemical species known to be absent from specific source types, default values of zero for the mass fraction and uncertainty of 0.0001 were used. Multiple source profiles for each source were used because source compositions can vary substantially among sources, even within a single source over an extended period of time. ---PAGE BREAK--- 7 One assumption of the CMB model is that compositions of source emissions are constant over the period of ambient and source sampling, and that chemical species do not react with each other. CMB is well suited for apportioning sources of primary aerosols (those emitted directly as particles). However, it is difficult to attribute secondary aerosols formed through gas-to-particle transformation in the atmosphere to specific sources. Sulfate, nitrate, and ammonium abundances in directly emitted particles are not sufficient to account for the concentrations of these species measured in the atmosphere. Therefore, to account for secondary aerosol contributions to PM2.5 mass, sulfate (Profile 11), ammonium sulfate (Profile 12), and ammonium nitrate (Profile 13) were expressed as “pure” secondary source profiles, and represented by their chemical form. 5.2. CMB Modeling Program QA/QC Following the CMB validation protocol (Watson et al., 2004), a comprehensive QA/QC plan was applied throughout the Butte CMB modeling program to ensure accurate results. The QA/QC protocol: 1) determines model applicability; 2) selects a variety of profiles to represent identified contributors; 3) evaluates model outputs and performance measures; 4) identifies and evaluates deviations from model assumptions; 5) identifies and corrects model input deficiencies; 6) verifies consistency and stability of source contribution estimates; and 7) evaluates CMB results with respect to other data analysis and source assessment methods. For each model run, evaluations of several different combinations of source profiles were used, with the number of chemical species always exceeding the number of source types. As described in Table 2, statistical parameters used to evaluate the validity of source contribution estimates included TSTAT, R2, Chi2, DF, and R/U ratios. The results of these fitting parameters (for each modeling run) have to be within the EPA target ranges for the modeling results to be considered valid. It should also be noted that concentrations of species found on quartz field blanks were not subtracted (or blank-corrected) from the ambient sample concentrations before the modeling was conducted. Table 2: Statistical criteria for the CMB model. Output / Statistic Abbreviation EPA Target Explanation Std. Error STD ERR SCE The standard error of the SCE. T-statistic TSTAT > 2.0 The ratio of the value of the SCE to the uncertainty in the SCE. A T- STAT greater than 2 means that the SCE has a relative uncertainty of less than 50%. R-square R-SQUARE (R2) 0.8 to 1.0 A measure of the variance of the ambient concentration explained by the calculated concentration. Chi-square CHI-SQUARE (Chi2) 0.0 to 4.0 A term that compares the difference between the calculated and measured ambient concentrations to the uncertainty of the difference. A perfect fit has a chi-square of 0.0, and a chi-square less than 2 usually indicates a good fit. Percent Mass % MASS 100% The ratio of the total calculated to measured mass. ---PAGE BREAK--- 8 Explained ± 20% Degrees of Freedom DF > 5 The difference between the number of fitting species and the number of fitting sources. Ratio of Calculated to Measured RATIO C/M 0.5 to 2.0 The ratio of the calculated to measured concentration of an ambient species. Ideally, this value should be 1.0. Ratio of Residual to Uncertainty RATIO R/U –2.0 to 2.0 The ratio of the residual (calculated minus measured) to the uncertainty of the residual (square root of the sum of squares of the uncertainties). 6.0. Sampling and CMB Modeling Results 6.1 PM2.5 Mass and Speciation Data Out of the 17, 24-hour integrated sample runs scheduled every six days from 6/3/13 through 9/7/13, only 10 sample runs met QA/QC criteria that allowed them to be useable for CMB modeling. Listed below are the sample runs that were excluded for CMB modeling along with the associated reasons for exclusion: 6/27/2013: Sample time out of limits (sample invalid). 7/27/2013: URG (carbon data) invalid due to flow problem. 8/2/2013: URG (carbon data) invalid due to flow problem. 8/8/2013: URG (carbon data) invalid due to flow problem. 8/14/2013: URG (carbon data) invalid due to flow problem. 8/20/2013: URG (carbon data) invalid due to flow problem. 9/1/2013: Sample scheduled but not collected. In presenting the final results, these sample days were excluded from both the averaged results of the speciated data (Table and the CMB modeling. Table 3 presents the average concentrations (in µg/m3) of elements, ions, and OC/EC, respectively measured throughout summer 2013. The minimum detection limits (MDL) in µg/m3 for each compound are also presented, with the bolded values (within the tables) indicating analyte concentrations measured at or above the MDL. All MDLs were provided by RTI. ---PAGE BREAK--- 9 Table 3: Average PM2.5 Elemental, Ion, and OC/EC Concentrations, Summer 2013. Concentration (µg/m3) n= 10 Minimum Detection Limit PM2.5 Mass 5.8 0.9 Magnesium 0.010 0.012 Aluminum 0.053 0.015 Silicon 0.172 0.011 Phosphorus 0.000 0.013 Sulfur 0.185 0.009 Chlorine 0.017 0.007 Potassium 0.191 0.006 Calcium 0.035 0.006 Titanium 0.003 0.005 Vanadium 0.000 0.003 Chromium 0.001 0.002 Manganese 0.001 0.002 Iron 0.054 0.002 Nickel 0.000 0.001 Copper 0.011 0.002 Zinc 0.003 0.002 Arsenic 0.000 0.001 Selenium 0.000 0.002 Bromine 0.001 0.002 Rubidium 0.000 0.002 Strontium 0.002 0.002 Zirconium 0.000 0.006 Silver 0.002 0.016 Cadmium 0.004 0.017 Indium 0.000 0.019 Tin 0.001 0.025 Antimony 0.000 0.040 Barium 0.006 0.010 Lead 0.000 0.003 Sodium 0.004 0.036 Cobalt 0.000 0.001 Sulfate 0.463 0.009 Nitrate 0.234 0.018 Ammonium 0.114 0.017 Potassium 0.152 0.017 Sodium (ion) 0.037 0.013 Total Carbon 1.9 0.14 Organic Carbon 1.7 0.14 Elemental Carbon 0.23 0.0 Bolded values indicate concentrations measured at or above the MDL. Out of the 31 elements quantified, only 10 had averages that measured at or above their reported MDL as noted by the bolded fonts in Table 3. Potassium (0.191 µg/m3) had the highest concentration of the measured elements, followed by sulfur (0.185 µg/m3) and silicon (0.172 µg/m3). The average concentrations of the ion species and the total carbon, organic carbon and elemental carbon were all measured above their MDLs. Sulfate (0.463 µg/m3) had the highest concentration of any of the measured ions, while total carbon levels (1.9 µg/m3) were ---PAGE BREAK--- 10 predominantly enriched with organic carbon (1.7 µg/m3). Results from the quartz field blanks for the organic species were minimal, therefore speciated data were not corrected prior to using in the CMB model. 6.2. Chemical Mass Balance Modeling Table 4 presents the PM2.5 sources identified by the CMB model, including source contribution estimates standard errors) and % contribution to total measured PM2.5. In addition, CMB results are summarized as a pie chart and presented in Figure 1. In total, five source profile types were identified by the CMB model as contributors to the ambient PM2.5 throughout the summer of 2013. Wood smoke (likely residential outdoor biomass waste combustion) was the major source of PM2.5 identified, contributing 71.9% of the measured PM2.5. The other sources of PM2.5 identified by the CMB model were street sand/road dust secondary sulfate ammonium nitrate and automobiles Approximately 2.4% of the PM2.5 was unexplained by the CMB model. Appendix A presents the identified sources with their corresponding standard errors (STD ERR) for each sample day. The standard error is a single standard deviation. When a standard error value is multiplied by two or three times, the result may be taken as a measure of the upper and lower limit of an individual source’s contribution. There is about a 66% probability that the true source contribution is within one standard error and about a 95% probability that the true contribution is within two standard errors of the source contribution estimate. Appendix B presents the raw input files for the Butte CMB model (including the ambient data and source profiles), while Appendix C presents the final outputs for the summer 2013 Butte CMB model. Table 4: Sources identified by the Butte summer 2013 CMB model (average µg/m3 ± std err) and percent contribution to overall PM2.5 measured mass. Sulfate Ammonium Nitrate Autos Wood Smoke Street Sand Unexplained PM2.5 Mass N Sampling Dates 0.4±0.1 0.3 ±0.1 0.1±0.03 4.1±0.2 (71.9%) 0.6±0.1 (11.1%) 0.1 5.8 10 6/3/12- 9/7/13 ---PAGE BREAK--- 11 Figure 1: PM2.5 sources identified in Butte, Montana during the summer of 2013. As noted earlier, source apportionment was not conducted on seven of the scheduled sample days (6/27/2013, 7/27/2013, 8/2/2013, 8/8/2013, 8/14/2013, 8/20/2013, and 9/1/2013) due to incomplete filter collection or sampler malfunction. 7.0. Discussion - CMB Modeling Overall, the ambient PM2.5 levels measured on the scheduled sample days were very low throughout the summer of 2013 (5.8 µg/m3). When conducting the source apportionment modeling on these sample days, the results of the CMB modeling revealed that wood smoke was the major source of PM2.5 throughout the summer months in Butte, contributing an average of 71.9% of the measured PM2.5. The other sources of PM2.5 identified by the CMB model were street sand secondary sulfate ammonium nitrate and automobiles Finally, 2.4% (0.1 µg/m3) was unexplained by the CMB model. Unexplained concentrations were calculated by taking the difference between the actual measured mass and the CMB predicted mass for each sample run. 7.1. Wood Smoke The wood smoke source identified by the CMB model should be viewed as a general source predominantly composed of outdoor residential open burning of biomass wastes emissions, as well as other biomass combustion emission sources such as smoke from prescribed fires (or controlled and/or wildfires), and small industrial sources. Several wood smoke source profiles taken from the EPA SPECIATE database provided good fits for this source. However, profiles 58 (SPECIATE 421022.5, wood stoves – average all fuels), 59 (SPECIATE 421012.5, wood stoves – pine fuels), 65 (SPECIATE 3769, residential wood burning profiles), and 68 (SPECIATE 423312.5, residential wood stove composite) provided the best statistically fitting wood smoke profiles for each of the sampling runs. Generally, both elemental potassium and the potassium ion gave good fits when modeling, with the elemental form usually providing the Street Sand 11.1% Sulfate 7.8% Ammonium Nitrate 5.5% Automobiles 1.3% Wood Smoke 71.9% Unexplained 2.4% Avg PM2.5: 5.8 µg/m3 ---PAGE BREAK--- 12 better statistical fit. Note that elemental potassium was also the element found in greatest abundance throughout the scheduled sample days during the summer of 2013 (0.191 µg/m3). Given that multiple wood smoke profiles provided strong statistical fits (i.e. gave the best results), this supports that wood smoke is the major source of PM2.5 in the Butte airshed throughout the summer months. 7.2. Secondary Pollutants Two secondary aerosols, ammonium nitrate (NH4NO3) and sulfate (SO4), were identified by the CMB model as contributing to PM2.5 concentrations in Butte during the summer of 2013. Each of these sources was identified in each sample run throughout the program. “Pure secondary” aerosols such as ammonium nitrate and sulfate are actually formed through gas- to-particle transformations in the atmosphere, and are represented by their chemical form in the model. As noted earlier, one assumption of the CMB model is that compositions of source emissions are constant over the period of ambient and source sampling, and that chemical species do not react with each other. CMB is well suited for apportioning sources of primary aerosols (those emitted directly as particles). However, it is difficult to attribute secondary aerosols formed through gas-to-particle transformation in the atmosphere to specific sources. Using the secondary sulfate and the ammonium nitrate profiles allows us to account for the secondary aerosol contributions to PM2.5 mass. Sulfate (SO4) is representative of particles directly emitted during combustion and secondary particles formed in the atmosphere. Ammonium nitrate (NH4NO3) is also a secondary particle. Ammonium nitrate is an extremely volatile species, and is not always detected in the particle form during the warmer months. Ammonia (NH3) and oxides of nitrogen (NOx) are the precursors for ammonium nitrate particles (Seinfeld and Pandis, 1998). PM2.5 has been found to correlate with gaseous emissions of NOx from vehicles, with heavy duty vehicles contributing significantly greater amounts of NOx and particulate matter on a per vehicle basis than light duty vehicles (Gillies et al., 2001). Between 40 and 45% of all NOx emissions in the United States are estimated to come from transportation, with about half of this coming from light-duty gasoline trucks and cars and approximately one-quarter from heavy-duty gasoline and diesel vehicles (Seinfeld and Pandis, 1998; Dreher and Harley, 1998). Other sources of NOx in Butte might include small industry and natural gas furnaces (Schmidt, 1996). Ammonia emissions to the atmosphere arise from many sources including the decay of livestock waste, use of chemical fertilizers, emissions from sewage treatment plants, biological processes in soils, and to a lesser extent, combustion processes (Fraser and Cass, 1998). The source of the secondary sulfate might include the transportation sector and/or “normal” background levels. 7.3. Mobile Sources Diesel exhaust was not identified by the CMB model as being a source of ambient PM2.5 during the summer months, though automobile exhaust was identified as a minor source PM2.5 emitted directly from gasoline-powered vehicles was identified in two of the 10 sampling days during the summer months. ---PAGE BREAK--- 13 7.4. Street Sand / Road Dust Street sand (11.1%) was detected in eight of the 10 sampling days. Each of the street sand/road dust source profiles loaded into the model provided statistically significant fits. However, the following source profiles gave the best fits and were used in CMB modeling: 06 (SPECIATE 411302.5, paved road dust - composite); 10 (SPECIATE 412042.5, unpaved road dust – East Helena, MT); and 01 (City Street sanding pile, Missoula). 8.0. Quality Assurance / Quality Control Results 8.1. Sampling Program QA/QC For the Butte sampling program, Montana DEQ personnel maintained and audited the PM2.5 samplers. As noted previously, there were several days throughout the summer 2013 sampling program where complete samples were not collected (and therefore CMB analyses were not conducted). Listed below are the sample runs that were excluded for CMB modeling along with the associated reasons for exclusion: 6/27/2013: Sample time out of limits (sample invalid). 7/27/2013: URG (carbon data) invalid due to flow problem. 8/2/2013: URG (carbon data) invalid due to flow problem. 8/8/2013: URG (carbon data) invalid due to flow problem. 8/14/2013: URG (carbon data) invalid due to flow problem. 8/20/2013: URG (carbon data) invalid due to flow problem. 9/1/2013: Sample scheduled but not collected. 8.2. Analytical Program QA/QC RTI (gravimetric, elemental, and ion analyses) and the Desert Research Institute (OC/EC analyses) were responsible for QA/QC activities within their respective laboratories. No Teflon and nylon blanks were collected during the summer 2013 final results. However, to monitor for artifact contamination in the field and in the laboratory, two quartz filter blanks were collected (6/15/13 and 8/14/13) during the sampling program and analyzed for OC, EC, and TC. RTI does not currently report uncertainties or MDL values for organic carbon analyses. After communicating with RTI’s Prakash Doraiswamy on 6/19/13, it was recommended that the average blank levels (included in the raw report) may be a more robust guide to system MDL values as they include both analytical instrument and background contributions to detection limits. Using this recommendation from RTI, we can conclude that blank concentrations were very low for OC (0.14 µg/m3), EC (0.0 µg/m3), and TC (0.14 µg/m3), and did not suggest any issues with artifact contamination of samples. 8.3. CMB Program QA/QC EPA‟s validation protocol (Watson et al., 2004) was followed throughout this CMB modeling program to ensure accurate results. For each model run, several different combinations of source profiles were evaluated, and the number of chemical species always exceeded the number of source types. The source contribution estimates and the statistics and diagnostic information were reviewed for each model run to determine the validity of the initial model results. The analysis was repeated by eliminating source profiles that gave negative source contribution estimates or standard errors that exceeded the source contribution estimates. When conducting ---PAGE BREAK--- 14 the CMB model runs, only sources with TSTATs >2 were reported. If a TSTAT was then the source was not considered a significant contributor for that sample day. The majority of the CMB fitting parameters used to evaluate the validity of source contribution estimates were well within EPA target ranges. Table 5 presents the program average key „goodness-of-fit‟ statistics commonly evaluated for CMB models, the results for the Butte CMB runs, and the EPA target ranges for each parameter. The values for R2, Chi2, DF, and % mass explained for each CMB model run were generally well within the EPA target ranges. For the most part, the R/U ratios were all less than 2, and source collinearity (similarities between identified sources) was not a problem throughout this modeling application. Table 5: Average goodness-of-fit parameters for the summer 2013 Butte CMB. Goodness-of-Fit Parameter Butte CMB EPA Target R2 0.98 0.8 - 1.00 Chi2 0.26 0.00 – 4.0 Degrees of Freedom 38 > 5 % Mass Explained 97.6 80 – 120% TSTAT >2 >2 It is believed that all of the PM2.5 emission sources (or at least the source types) were identified during the Butte CMB modeling program. Missing source types are identified by a low percent mass explained and/or a RATIO R/U for chemical species which are in the missing source. In addition, a “high negative” residual for one or more species and a large Chi2 can be indicative of missing sources. The good agreement between the calculated source contributions and the measured ambient concentrations indicate that all of the major source types are included in the calculations, and that ambient and source profile measurements are reasonably accurate. CMB is intended to complement rather than replace other data analysis and modeling methods. For this project, the sensitivity of the CMB model‟s results to the errors in the source profiles were evaluated by using different chemical abundances of a source type and by changing the fitting species used in the source type. The results of the sensitivity tests for each run showed that the CMB calculations carried out in this study were acceptable. Although there were a few cases where the fitting parameters were outside the EPA target range, none of these cases were considered invalid, and all of the fits were quite strong. Therefore, the source contribution estimates identified in this project can be considered valid. Finally, it should be noted that if the measured concentration is less than 5 μg/m3, the percent mass may be outside of the acceptable ranges because the uncertainty in the mass measurement is approximately 1 to 2 μg/m3. Four of the summer 2013 sampling days had PM2.5 concentrations that were below 5 μg/m3. However, goodness-of-fit parameters were met on these sampling days, and no problems were incurred during the CMB modeling. ---PAGE BREAK--- 15 9.0. References Carlson, 1990. PM10 Chemical Mass Balance study for Missoula, Montana. Missoula City- County Health Department Chow, J.C., Watson, J.G., Chen, Chang, M.C.O., Robinson, N.F., Trimble, D.L., and Kohl, S.D., 2007. The IMPROVE_A temperature protocol for thermal/optical carbon analysis: Maintaining consistency with a long-term database. J. Air Waste Manage. Assoc., 57(9): 1014-1023. Cooper, J.A., Watson, J.G., 1980. Receptor oriented methods of air particulate source apportionment. JAPCA, 30, 1116-25. Dreher D.B., Harley, R.A., 1998. A Fuel-Based Inventory for Heavy-Duty Diesel Truck Emissions, J. Air & Waste Manage. Assoc., 48, 352-358. Fraser, M.P., Cass, G.R., 1998. Detection of excess ammonia emissions from in-use vehicles and the implications for fine particle control. Environ. Sci. Technol., 32, 1053-1057. Friedlander, S.K., 1973. Chemical element balances and identification of air pollution sources. Environ. Sci. Technol., 7, 235-240. Gillies, J.A., Gertler, A.W., Sagebiel, J.C., Dippel, W.A., 2001. On-road particulate matter (PM2.5 and PM10) emissions in the Sepulveda tunnel, Los Angeles, California. Environ. Sci. Technol., 35, 1054-1063. Gordon, G.E., 1980. Receptor models. Environ. Sci. Technol., 14, 792-800. Gordon, G.E., 1988. Receptor models. Environ. Sci. Technol., 22, 1132-1142. Hidy, G.M., Venkataraman, 1996. The chemical mass balance method for estimating atmospheric particle sources in Southern California. Chem. Eng. Comm., 151, 187-209. RTI International, 2008. SOP for Particulate Matter (PM) Gravimetric Analysis, July 8, 2008, http://www.epa.gov/ttn/amtic/files/ambient/pm25/spec/RTIGravMassSOPFINAL.pdf (accessed 10/7/2011). RTI International, 2009a. SOP for the X-Ray Fluorescence Analysis of Particulate Matter Deposits on Teflon Filters, August 19, 2009, (accessed 10/7/2011). RTI International, 2009b. SOP for PM2.5 Cation Analysis, August 25, 2009, http://www.epa.gov/ttn/amtic/files/ambient/pm25/spec/pm25cationsop.pdf (accessed 10/7/2011). ---PAGE BREAK--- 16 RTI International, 2009c. SOP for PM2.5 Anion Analysis, August 26, 2009, http://www.epa.gov/ttn/amtic/files/ambient/pm25/spec/pm25anionsop.pdf (accessed 10/7/2011). Schmidt, 1996. Chemical Mass Balance source apportionment of Missoula, Montana 1995/1996 winter suspended particulate matter. Missoula City-County Health Department Seinfeld, J.H., Pandis, S.N., 1998. Atmospheric Chemistry and Physics. From Air Pollution to Climate Change, New York, John Wiley & Sons. USEPA, 2006. SPECIATE 4.0: EPA's repository of Total Organic Compound (TOC) and Particulate Matter (PM) speciated profiles for a variety of sources for use in source apportionment studies. U.S. Environmental Protection Agency OAQPS, Research Triangle Park, NC. http://www.epa.gov/ttn/chief/software/speciate/ index. Ward, T.J., and Smith, G.C., 2005. The 2000/2001 Missoula Valley PM2.5 Chemical Mass Balance study, including the 2000 wildfire season – seasonal source apportionment, Atmospheric Environment, 39, 709-717. Watson, J.G., 1984. Overview of receptor model principles. JAPCA, 34, 619-623. Watson, J.G., Cooper, J.A., Huntzicker, J.J., 1984. The effective variance weighting for least squares calculations applied to the mass balance receptor model. Atmos. Environ., 18, 7, 1347-1355. Watson, J.G., Robinson, N.F., Chow, J.C., Henry, R.C., Kim, B.M., Pace, T.G., Meyer, E.L., Nguyen, 1990. The USEPA/DRI chemical mass balance receptor model, CMB 7.0. Environ. Software, 5, 38-49. Watson, J.G., et al., 2004. Protocol for Applying and Validating the CMB Model for PM2.5 and VOC. Report No. EPA-451/R-04-001, USEPA QAQPS. ---PAGE BREAK--- 17 Appendix A: Source Contribution Estimates and Associated Standard Errors (µg/m3) for Each Sample Day. Date PM2.5 Mass Street Sand Street Sand STD ERR Sulfate Sulfate STD ERR Ammonium Nitrate Ammonium Nitrate STD ERR Autos Autos STD ERR Wood Smoke Wood Smoke STD ERR 6/3/13 2.1 0.00 0.00 0.22 0.03 0.16 0.03 0.00 0.00 1.60 0.22 6/9/13 4.4 0.82 0.18 0.32 0.05 0.37 0.05 0.00 0.00 2.60 0.10 6/15/13 4.1 0.21 0.04 0.11 0.03 0.35 0.04 0.00 0.00 3.53 0.03 6/21/13 3.3 0.30 0.06 0.20 0.03 0.28 0.04 0.27 0.12 2.33 0.17 6/27/13* 7/3/13 11.5 0.00 0.00 1.17 0.17 0.38 0.15 0.00 0.00 8.73 0.32 7/9/13 5.4 0.48 0.18 0.42 0.05 0.26 0.06 0.00 0.00 3.89 0.11 7/15/13 5.9 1.30 0.29 0.56 0.07 0.33 0.08 0.00 0.00 3.75 0.52 7/21/13 6.6 0.40 0.09 0.29 0.05 0.33 0.07 0.46 0.14 5.26 0.24 7/27/13* 8/2/13* 8/8/13* 8/14/13* 8/20/13* 8/26/13 8.3 2.07 0.38 0.66 0.08 0.37 0.09 0.00 0.00 4.65 0.19 9/1/13* 9/7/13 6.6 0.80 0.25 0.53 0.07 0.32 0.07 0.00 0.00 5.03 0.27 Average 5.8 0.6 0.1 0.4 0.1 0.3 0.1 0.1 0.03 4.1 0.2 *No CMB modeling run conducted. ---PAGE BREAK--- 18 Appendix B: Butte CMB Input Files (Ambient and Source Profiles). TMAC TOT Mass by gravimetry (ug/m3) C42 MO Molybdenum by XRF (ug/m3) C12 MG Magnesium by XRF (ug/m3) C46 PD Palladium by XRF (ug/m3) C13 AL Aluminum by XRF (ug/m3) C47 AG Silver by XRF (ug/m3) C14 SI Silicon by XRF (ug/m3) C48 CD Cadmium by XRF (ug/m3) C15 P Phosphorus by XRF (ug/m3) C49 IN Indium by XRF (ug/m3) C16 S Sulfur by XRF (ug/m3) C50 SN Tin by XRF (ug/m3) C17 CL Chlorine by XRF (ug/m3) C51 SB Antimony by XRF (ug/m3) C19 K Potassium by XRF (ug/m3) C56 BA Barium by XRF (ug/m3) C20 CA Calcium by XRF (ug/m3) C57 LA Lanthanum by XRF (ug/m3) C22 TI Titanium by XRF (ug/m3) C80 HG Mercury by XRF (ug/m3) C23 V Vanadium by XRF (ug/m3) C82 PB Lead by XRF (ug/m3) C24 CR Chromium by XRF (ug/m3) C200 TC Total Carbon by TOT (ug/m3) C25 MN Manganese by XRF (ug/m3) C201 OC Organic Carbon by TOT (ug/m3) C26 FE Iron by XRF (ug/m3) C202 EC Elemental Carbon by TOT (ug/m3) C28 NI Nickel by XRF (ug/m3) C203 SO4 Sulfate by IC (ug/m3) C29 CU Copper by XRF (ug/m3) C204 NO3 Nitrate by IC (ug/m3) C30 ZN Zinc by XRF (ug/m3) C205 NH4 Ammonia by IC (ug/m3) C31 GA Gallium by XRF (ug/m3) C217 CL2 Chloride by IC (ug/m3) C32 GE Germanium by XRF (ug/m3) C219 K2 Potassium by IC (ug/m3) C33 AS Arsenic by XRF (ug/m3) C300 F2 Fluoride by IC (ug/m3) C34 SE Selenium by XRF (ug/m3) C301 NA2 Sodium by IC (ug/m3) C35 BR Bromine by XRF (ug/m3) C302 CA2 Calcium by IC (ug/m3) C37 RB Rubidium by XRF (ug/m3) C303 MG2 Magnesium by IC (ug/m3) C38 SR Strontium by XRF (ug/m3) C304 NA Sodium by XRF (ug/m3) C39 Y Yttrium by XRF (ug/m3) C305 CO Cobalt by XRF (ug/m3) C40 ZR Zirconium by XRF (ug/m3) ---PAGE BREAK--- 19 Butte Ambient PM2.5 Speciation Data ID Date Dur STHOUR Size TMAC TMAU C12 MG C13 AL BUTTE2 6/3/13 24 0 FINE 2.1 0.41 0 0.0038 0.012 0.01 BUTTE2 6/9/13 24 0 FINE 4.4 0.41 0 0.0039 0.0533 0.0098 BUTTE2 6/15/13 24 0 FINE 4.1 0.41 0 0.0038 0.049 0.013 BUTTE2 6/21/13 24 0 FINE 3.3 0.42 0 0.0039 0.0172 0.0082 BUTTE2 6/27/13 24 0 FINE BUTTE2 7/3/13 24 0 FINE 11.5 0.63 0.0873 0.0086 0.06 0.016 BUTTE2 7/9/13 24 0 FINE 5.4 0.47 0 0.0039 0.0264 0.0084 BUTTE2 7/15/13 24 0 FINE 5.9 0.41 0.00481 0.006 0.0853 0.012 BUTTE2 7/21/13 24 0 FINE 6.6 0.5 0 0.0039 0.037 0.0088 BUTTE2 7/27/13 24 0 FINE BUTTE2 8/2/13 24 0 FINE BUTTE2 8/8/13 24 0 FINE BUTTE2 8/14/13 24 0 FINE BUTTE2 8/20/13 24 0 FINE BUTTE2 8/26/13 24 0 FINE 8.3 0.56 0 0.0039 0.146 0.016 BUTTE2 9/1/13 24 0 FINE BUTTE2 9/7/13 24 0 FINE 6.6 0.5 0.00458 0.0045 0.0397 0.01 Date C14 SI C15 P C16 S C17 CL C19 K 6/3/13 0.0382 0.0061 0 0.0045 0.075 0.0064 0 0.0021 0.00933 0.0019 6/9/13 0.176 0.016 0 0.0053 0.159 0.012 0.00012 0.0026 0.0364 0.003 6/15/13 0.0702 0.0088 0 0.0062 0.1 0.0083 0.00128 0.0027 0.0191 0.0027 6/21/13 0.124 0.011 0 0.0053 0.0708 0.0057 0.00315 0.0026 0.0238 0.0024 6/27/13 7/3/13 0.154 0.016 0 0.0076 0.546 0.04 0.132 0.01 1.53 0.11 7/9/13 0.117 0.011 0 0.0053 0.145 0.011 0.00315 0.0026 0.039 0.0032 7/15/13 0.271 0.023 0 0.0035 0.198 0.015 0.0224 0.0027 0.0498 0.0039 7/21/13 0.167 0.015 0 0.0053 0.119 0.0089 0.00082 0.0026 0.0649 0.0049 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0.425 0.036 0 0.0053 0.235 0.017 0.00479 0.0026 0.0973 0.0072 9/1/13 9/7/13 0.179 0.016 0 0.0036 0.199 0.015 0.00047 0.0017 0.0446 0.0035 ---PAGE BREAK--- 20 Butte Ambient PM2.5 Speciation Data, cont. Date C20 CA C22 TI C23 V C24 CR C25 MN 6/3/13 0 0.0021 0 0.0014 0 0.001 0 0.00072 0 0.00059 6/9/13 0.0258 0.0025 0.00372 0.0022 0 0.0013 0.0015 0.00089 0.00042 0.00087 6/15/13 0.0134 0.0028 0 0.0015 0 0.0012 0.00173 0.00089 0 0.0007 6/21/13 0.0119 0.0025 0.00117 0.0021 0 0.0013 0.00204 0.00097 0.00196 0.0007 6/27/13 7/3/13 0.0312 0.0039 0.00525 0.0024 0.0007 0.0015 0 0.00072 0.00237 0.00075 7/9/13 0.0191 0.0025 0.00151 0.002 0.00082 0.0013 0 0.00085 0.00172 0.00088 7/15/13 0.0589 0.0046 0.00535 0.0021 0 0.0011 0.00099 0.00085 0 0.00054 7/21/13 0.0422 0.0034 0.00163 0.002 0 0.0013 0.0023 0.00094 0.00122 0.00088 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0.102 0.0075 0.00606 0.0023 0.00128 0.0014 0.0019 0.00092 0.00382 0.0008 9/1/13 9/7/13 0.0468 0.0037 0.00047 0.0019 0.0015 0.0011 0.00141 0.00081 0.00167 0.00064 Date C26 FE C28 NI C29 CU C30 ZN C31 GA 6/3/13 0.00821 0.00095 0 0.00038 0 0.00045 0 0.0012 0 0.0001 6/9/13 0.0529 0.004 0 0.0004 0.00411 0.00069 0.00363 0.00071 0 0.0001 6/15/13 0.0129 0.0013 0 0.00038 0.00264 0.00068 0 0.0012 0 0.0001 6/21/13 0.0463 0.0035 0 0.0004 0.00671 0.00079 0.002 0.00065 0 0.0001 6/27/13 7/3/13 0.0514 0.0038 0 0.00038 0.0275 0.0021 0.00768 0.0012 0 0.0001 7/9/13 0.0409 0.0031 0.00001 0.0004 0.00459 0.00068 0.00177 0.00062 0 0.0001 7/15/13 0.0902 0.0066 0 0.00056 0.0241 0.002 0.00243 0.00086 0 0.0001 7/21/13 0.0605 0.0045 0 0.0004 0.00974 0.00093 0.00241 0.00061 0 0.0001 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0.127 0.0092 0 0.0004 0.0231 0.0018 0.00635 0.00082 0 0.0001 9/1/13 9/7/13 0.0472 0.0035 0 0.00041 0.00268 0.00069 0.00342 0.00074 0 0.0001 ---PAGE BREAK--- 21 Butte Ambient PM2.5 Speciation Data, cont. Date C32 GE C33 AS C34 SE C35 BR C37 RB 6/3/13 0 0.0001 0 0.00062 0 0.00066 0.00058 0.00084 0 0.00059 6/9/13 0 0.0001 0 0.0006 0 0.00063 0.00044 0.00091 0 0.00065 6/15/13 0 0.0001 0.00016 0.00095 0 0.00066 0.00021 0.0011 0 0.00058 6/21/13 0 0.0001 0 0.00061 0 0.00063 0.00056 0.0009 0 0.00065 6/27/13 7/3/13 0 0.0001 0.00082 0.0015 0 0.00066 0.00163 0.0011 0.00029 0.0011 7/9/13 0 0.0001 0 0.00061 0.00064 0.00085 0.00089 0.00098 0 0.00065 7/15/13 0 0.0001 0.00105 0.0013 0 0.00087 0.00195 0.00092 0 0.00047 7/21/13 0 0.0001 0.00049 0.00077 0 0.00063 0.00082 0.00091 0 0.00066 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0 0.0001 0 0.00061 0 0.00063 0.00266 0.001 0 0.00065 9/1/13 9/7/13 0 0.0001 0.0007 0.0013 0 0.00082 0.00227 0.001 0 0.00086 Date C38 SR C39 Y C40 ZR C42 MO C46 PD 6/3/13 0 0.00076 0 0.0001 0 0.0066 0 0.0001 0 0.0001 6/9/13 0 0.0084 0 0.0001 0 0.0087 0 0.0001 0 0.0001 6/15/13 0.0007 0.0013 0 0.0001 0.00349 0.01 0 0.0001 0 0.0001 6/21/13 0 0.0084 0 0.0001 0 0.0088 0 0.0001 0 0.0001 6/27/13 7/3/13 0.0211 0.0025 0 0.0001 0 0.0066 0 0.0001 0 0.0001 7/9/13 0 0.0084 0 0.0001 0 0.0088 0 0.0001 0 0.0001 7/15/13 0.00175 0.0013 0 0.0001 0 0.0097 0 0.0001 0 0.0001 7/21/13 0 0.0084 0 0.0001 0 0.0088 0 0.0001 0 0.0001 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0 0.0084 0 0.0001 0 0.0088 0 0.0001 0 0.0001 9/1/13 9/7/13 0 0.0012 0 0.0001 0 0.0076 0 0.0001 0 0.0001 ---PAGE BREAK--- 22 Butte Ambient PM2.5 Speciation Data, cont. Date C47 AG C48 CD C49 IN C50 SN C51 SB 6/3/13 0 0.005 0 0.0062 0 0.0073 0 0.011 0 0.014 6/9/13 0 0.0047 0.00233 0.019 0 0.0053 0 0.0089 0 0.013 6/15/13 0 0.005 0 0.0062 0 0.0073 0 0.011 0 0.014 6/21/13 0.0175 0.015 0.0128 0.018 0 0.0053 0 0.0089 0 0.013 6/27/13 7/3/13 0.00116 0.015 0 0.0062 0 0.0073 0 0.011 0 0.014 7/9/13 0 0.0047 0.0105 0.019 0 0.0053 0 0.0089 0 0.013 7/15/13 0 0.0068 0.0116 0.02 0 0.0075 0 0.0096 0 0.013 7/21/13 0 0.0047 0 0.0057 0 0.0053 0 0.0089 0 0.013 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0 0.0047 0 0.0057 0 0.0053 0.00816 0.033 0 0.013 9/1/13 9/7/13 0 0.012 0 0.0074 0 0.011 0 0.012 0 0.017 Date C56 BA C57 LA C80 HG C82 PB C200 TC 6/3/13 0 0.0034 0 0.0001 0 0.0001 0 0.0016 0.895 0.0001 6/9/13 0 0.0036 0 0.0001 0 0.0001 0 0.0013 1.17 0.0001 6/15/13 0 0.0037 0 0.0001 0 0.0001 0 0.0016 1.49 0.0001 6/21/13 0 0.0036 0 0.0001 0 0.0001 0 0.0013 1.21 0.0001 6/27/13 7/3/13 0.0565 0.0059 0 0.0001 0 0.0001 0 0.0016 3.48 0.0001 7/9/13 0 0.0036 0 0.0001 0 0.0001 0 0.0013 1.68 0.0001 7/15/13 0 0.0034 0 0.0001 0 0.0001 0.0007 0.0024 2.1 0.0001 7/21/13 0 0.0036 0 0.0001 0 0.0001 0 0.0013 2.67 0.0001 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0 0.0036 0 0.0001 0 0.0001 0 0.0013 2.17 0.0001 9/1/13 9/7/13 0 0.0033 0 0.0001 0 0.0001 0.00023 0.0023 2.49 0.0001 ---PAGE BREAK--- 23 Butte Ambient PM2.5 Speciation Data, cont. Date C201 OC C202 EC C203 SO4 C204 NO3 C205 NH4 6/3/13 0.782 0.0001 0.113 0.0001 0.167 0.016 0.145 0.013 0.00715 0.0014 6/9/13 0.948 0.0001 0.225 0.0001 0.388 0.032 0.248 0.02 0.184 0.014 6/15/13 1.27 0.0001 0.223 0.0001 0.247 0.018 0.275 0.025 0.0754 0.013 6/21/13 1.04 0.0001 0.166 0.0001 0.122 0.0095 0.245 0.023 0.0199 0.0094 6/27/13 7/3/13 3.18 0.0001 0.301 0.0001 1.53 0.11 0.273 0.025 0.157 0.018 7/9/13 1.51 0.0001 0.169 0.0001 0.342 0.025 0.176 0.018 0.154 0.018 7/15/13 1.9 0.0001 0.199 0.0001 0.374 0.031 0.226 0.019 0.191 0.013 7/21/13 2.26 0.0001 0.412 0.0001 0.322 0.024 0.229 0.022 0.149 0.011 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 1.85 0.0001 0.322 0.0001 0.573 0.045 0.278 0.022 0.1 0.0078 9/1/13 9/7/13 2.27 0.0001 0.213 0.0001 0.566 0.041 0.248 0.023 0.101 0.014 Date C217 CL2 C219 K2 C300 F2 C301 NA2 C302 CA2 6/3/13 0 0.0001 0 0.0023 0 0.0001 0.0149 0.003 0 0.0001 6/9/13 0 0.0001 0.0118 0.0029 0 0.0001 0.0224 0.0035 0 0.0001 6/15/13 0 0.0001 0 0.0079 0 0.0001 0.0273 0.0053 0 0.0001 6/21/13 0 0.0001 0 0.0078 0 0.0001 0.015 0.0045 0 0.0001 6/27/13 7/3/13 0 0.0001 1.44 0.11 0 0.0001 0.0527 0.0069 0 0.0001 7/9/13 0 0.0001 0 0.0078 0 0.0001 0.0345 0.0057 0 0.0001 7/15/13 0 0.0001 0 0.001 0 0.0001 0.0804 0.066 0 0.0001 7/21/13 0 0.0001 0.0303 0.003 0 0.0001 0.0283 0.063 0 0.0001 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0 0.0001 0.0342 0.0043 0 0.0001 0.064 0.0062 0 0.0001 9/1/13 9/7/13 0 0.0001 0 0.0078 0 0.0001 0.0266 0.0052 0 0.0001 ---PAGE BREAK--- 24 Butte Ambient PM2.5 Speciation Data, cont. Date C303 MG2 C304 NA C305 CO 6/3/13 0 0.0001 0 0.013 0 0.00038 6/9/13 0 0.0001 0 0.01 0 0.00045 6/15/13 0 0.0001 0.00117 0.013 0 0.00048 6/21/13 0 0.0001 0 0.01 0 0.00045 6/27/13 7/3/13 0 0.0001 0.0367 0.013 0 0.00048 7/9/13 0 0.0001 0 0.01 0.00014 0.00051 7/15/13 0 0.0001 0 0.018 0.00035 0.00063 7/21/13 0 0.0001 0 0.01 0 0.00045 7/27/13 8/2/13 8/8/13 8/14/13 8/20/13 8/26/13 0 0.0001 0 0.011 0 0.00059 9/1/13 9/7/13 0 0.0001 0.00425 0.0097 0.00082 0.00053 ---PAGE BREAK--- 25 Butte PM2.5 Source Profiles PNO SID SIZE C12 MG C13 AL C14 SI C15 P HAML01 ST_SANDF FINE 0.001711 0.000172 0.086563 0.012623 0.215927 0.031127 0 0.000399 HAML02 ERN_RUSF FINE 0.003032 0.000307 0.07822 0.011493 0.213167 0.030867 0 0.0004 HAML03 RUS_STF2 FINE 0.002852 0.000301 0.077316 0.011654 0.213645 0.031554 0 0.000463 HAML04 DESP_LTF FINE 0.00099 0.0001 0.089841 0.01315 0.224711 0.032514 0 0.000404 HAML05 FINE 0 0.0001 0.1349 0.0135 0.3485 0.0349 0.0041 0.0004 HAML06 FINE 0.0084 0.0021 0.0792 0.0145 0.2148 0.0278 0.0011 0.0004 HAML07 FINE 0 0.0001 0.0882 0.0088 0.2633 0.0263 0.0029 0.0004 HAML08 FINE 0.01 0.0013 0.081 0.01 0.238 0.03 0 0.0001 HAML09 UNDST_CP FINE 0 0.0001 0.1524 0.0154 0.3351 0.0337 0.0031 0.0003 HAML10 UNDST_HE FINE 0 0.0001 0.1334 0.0133 0.3742 0.0374 0.0022 0.0003 HAML11 S04_FZER FINE 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 FINE 0 0.00001 0 0.000001 0 0.00001 0 0.000001 HAML13 NH4NO3F2 FINE 0 0.00001 0 0.00001 0 0.00001 0 0.000001 HAML14 LDV_PBCF FINE 0 0.1 0.00656 0.001312 0.01187 0.002374 0.00301 0.000602 HAML15 LDV_XPBF FINE 0 0.1 0.00699 0.00281 0.03427 0.01755 0.00441 0.00164 HAML16 LDV_DSLF FINE 0 0.1 0.00007 0.00004 0.00202 0.00177 0.00026 0.00015 HAML17 LDV_DS2F FINE 0 0.1 0.00009 0.00007 0.00053 0.00028 0.00026 0.00008 HAML18 HDV_DSLF FINE 0 0.1 0.00003 0.00026 0.00018 0.00018 0.00042 0.00009 HAML19 LDV_NCAT FINE 0 0.0001 0.0073 0.0001 0.0039 0.0001 0.0048 0.0001 HAML20 LDV_WCAT FINE 0 0.0001 0.0007 0.0001 0.0004 0.0001 0.0017 0.0001 HAML21 HDV_TRK1 FINE 0.009 0.0015 0.01 0.002 0.016 0.002 0.0015 0.0002 HAML22 HDV_TRK2 FINE 0 0.0001 0.0005 0.0001 0.0059 0.0001 0.0003 0.0001 HAML23 LDV_UNL1 FINE 0 0.0001 0.0012 0.0001 0.0051 0.0001 0 0.0001 HAML24 LDV_UNL2 FINE 0 0.0001 0.0015 0.0013 0.0624 0.0397 0.0004 0.0004 HAML25 GASEXST1 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML26 GASEXST2 FINE 0.002309 0.001365 0.002104 0.000937 0.007517 0.003151 0.004076 0.001365 HAML27 GASEXST3 FINE 0.002754 0.002177 0.001611 0.001473 0.005431 0.000742 0.002105 0.000254 HAML28 GASEXST4 FINE 0.000588 0.000477 0.00065 0.000417 0.003066 0.000703 0.001395 0.001362 HAML29 GASEXST5 FINE 0.000115 0.000151 0.000221 0.00006 0.003874 0.000058 0.000403 0.000032 HAML30 GASEXST6 FINE 0.001571 0.001008 0.001481 0.001049 0.005609 0.003284 0.002927 0.001898 HAML31 GASEXST7 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML32 GASEXST8 FINE 0 0.0001 0 0.0001 0 0.000487 0.000634 0.0001 HAML33 FINE 0.000881 0.000891 0.0004 0.000957 0.005101 0.001284 0.000344 0.000349 HAML34 FINE 0.000982 0.001039 0.000467 0.001159 0.005527 0.00143 0.000379 0.000392 HAML35 FINE 0.000802 0.000782 0.000352 0.000815 0.004754 0.001208 0.000316 0.000315 HAML36 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML37 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML38 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML39 D_TRAINF FINE 0 0.00001 0 0.000156 0.002987 0.000127 0.00062 0.000327 HAML40 D_TRUCKF FINE 0 0.00001 0.000189 0.000042 0.0006 0.00003 0.000038 0.000075 HAML41 TIRE_WR1 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 FINE 0.0004 0.0001 0.0007 0.0001 0.0005 0.0001 0.0025 0.0001 HAML43 TIRE_WR3 FINE 0.0004 0.0001 0.0005 0.0001 0.0018 0.0001 0 0.0001 HAML44 TIRE_WR4 FINE 0.0004 -99 0.0006 -99 0.0012 -99 0.0013 -99 HAML45 BRAKEASB FINE 0.138 0.0001 0.0022 0.0001 0.108 0.0001 0 0.0001 HAML46 BRAKEWER FINE 0.083 -99 0.0003 -99 0.0679 -99 0 -99 HAML47 MTCOOKCH FINE 0.0091 0.0001 0.0008 0.0001 0.0011 0.0001 0.001 0.0001 HAML48 MTCOOKFR FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML49 COOKING1 FINE 0.001905 0.002633 0.000651 0.000825 0.004782 0.00446 0.000048 0.000285 HAML50 COOKCHAR FINE 0.000956 0.0001 0.000521 0.0001 0.00096 0.0001 0.000479 0.0001 HAML51 DEICER_F FINE 0.404 0.04 0 0.1 0 0.1 0.00004 0.00003 HAML52 RWC_MEDF FINE 0 0.00041 0 0.00085 0.00059 0.00056 0 0.0002 HAML53 RWC_POCF FINE 0.00002 0.00001 0.00005 0.00004 0.00003 0.00003 0 0.00002 HAML54 RWC_F222 FINE 0 0.00001 0.000051 0.000044 0.000493 0.00003 0.000074 0.000072 HAML55 RWC_ALON FINE 0.0007 0.0002 0.0002 0.0001 0 0.0001 0 0.0001 HAML56 RWC_COMP FINE 0.0007 0.0002 0.0002 0.0001 0 0.0001 0 0.0001 HAML57 RWB_COMP FINE 0.0002 0.0001 0.0001 0.0001 0 0.0001 0 0.0001 HAML58 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML59 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML60 FINE 0 0.0001 0 0.000078 0.000261 0.000222 0 0.000052 HAML61 FINE 0 0.0001 0 0.000062 0.000169 0.000198 0 0.000053 HAML62 FINE 0 0.0001 0 0.000056 0.00002 0.000023 0 0.000025 HAML63 FINE 0 0.0001 0.000037 0.000061 0.000139 0.000015 0 0.000027 HAML64 FINE 0 0.0001 0 0.000051 0.000457 0.000019 0 0.000027 ---PAGE BREAK--- 26 Butte PM2.5 Source Profiles, cont. PNO SID C16 S C17 CL C19 K C20 CA C22 TI HAML01 ST_SANDF 0.000091 0.000147 0.051379 0.005776 0.04006 0.005156 0.016497 0.001883 0.004813 0.000254 HAML02 ERN_RUSF 0.005031 0.000695 0.002797 0.000339 0.03506 0.004541 0.010587 0.00123 0.004134 0.000233 HAML03 RUS_STF2 0.002367 0.000406 0.001001 0.000204 0.035728 0.004756 0.012546 0.001507 0.004267 0.000282 HAML04 DESP_LTF 0.002299 0.000338 0.000167 0.00009 0.040212 0.005202 0.013537 0.001563 0.003949 0.000221 HAML05 0.0103 0.001 0.0017 0.0002 0.0237 0.0024 0.0394 0.0039 0.0034 0.0004 HAML06 0.0057 0.0017 0.0013 0.0006 0.0114 0.002 0.0228 0.0056 0.0038 0.0007 HAML07 0.0208 0.0025 0.0037 0.0006 0.0156 0.0016 0.0586 0.0059 0.0035 0.0004 HAML08 0 0.0001 0.0003 0.0002 0.023 0.005 0.017 0.001 0.0026 0.0002 HAML09 UNDST_CP 0.0159 0.0019 0.0037 0.0005 0.0281 0.0029 0.0358 0.0041 0.005 0.0005 HAML10 UNDST_HE 0.0042 0.0006 0.0018 0.0003 0.0173 0.0017 0.0619 0.0062 0.0074 0.0007 HAML11 S04_FZER 0.333 0.033 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 0 0.000001 0 0.000001 0 0.000001 0 0.000001 0 0.000001 HAML13 NH4NO3F2 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML14 LDV_PBCF 0.00011 0.000022 0.00157 0.000314 0.00092 0.000184 0.00097 0.000194 0.00004 0.000008 HAML15 LDV_XPBF 0.03255 0.02025 0.00066 0.00034 0.00011 0.00008 0.00526 0.00141 0.00004 0.00002 HAML16 LDV_DSLF 0.00589 0.00168 0.00025 0.00014 0.00005 0.00002 0.00021 0.00014 0 0.1 HAML17 LDV_DS2F 0.0062 0.00239 0.00035 0.00012 0.00013 0.00008 0.00023 0.00014 0 0.00001 HAML18 HDV_DSLF 0.00343 0.00055 0.00016 0.00022 0 0.0001 0.00048 0.00008 0.00002 0.00004 HAML19 LDV_NCAT 0 0.0001 0.0085 0.0001 0.0009 0.0001 0.0045 0.0001 0.0004 0.0001 HAML20 LDV_WCAT 0 0.0001 0.0245 0.0001 0 0.0001 0 0.0001 0.0001 0.0001 HAML21 HDV_TRK1 0.027 0.0001 0 0.0001 0.0017 0.0003 0.007 0.002 0.0001 0.0001 HAML22 HDV_TRK2 0 0.0001 0.0028 0.0001 0.0006 0.0001 0.0016 0.0001 0.0003 0.0001 HAML23 LDV_UNL1 0 0.0001 0 0.0001 0.0004 0.0001 0.0017 0.0001 0 0.0001 HAML24 LDV_UNL2 0.0539 0.0273 0.0005 0.0011 0.0002 0.0005 0.0035 0.0023 0.0001 0.0002 HAML25 GASEXST1 0.0025 0.00064 0.000447 0.000765 0.00023 0.00158 0.001573 0.000895 0 0.003473 HAML26 GASEXST2 0.010985 0.004374 0.002262 0.002036 0.000627 0.000484 0.005821 0.001918 0.000129 0.002842 HAML27 GASEXST3 0.006712 0.000533 0.00531 0.001877 0.000891 0.000792 0.00358 0.000963 0.000186 0.004603 HAML28 GASEXST4 0.005437 0.002624 0.001104 0.000625 0.000202 0.000215 0.002289 0.001675 0.00004 0.000862 HAML29 GASEXST5 0.004536 0.000169 0.001068 0.000226 0.000139 0.000313 0.001174 0.000254 0.000033 0.000971 HAML30 GASEXST6 0.008608 0.004545 0.001766 0.001608 0.000445 0.000371 0.004307 0.002517 0.000091 0.002065 HAML31 GASEXST7 0.003831 0.002576 0.000488 0.000545 0.000159 0.001193 0.001122 0.001157 0 0.002629 HAML32 GASEXST8 0.002362 0.000565 0 0.0001 0.000239 0.00141 0.001652 0.000995 0 0.003109 HAML33 0.002967 0.001861 0.000682 0.001639 0.00006 0.000294 0.000598 0.000466 0.000005 0.00115 HAML34 0.003262 0.002123 0.000735 0.00175 0.000065 0.000347 0.000662 0.000529 0.000006 0.00133 HAML35 0.002732 0.00167 0.000638 0.001542 0.000055 0.000256 0.000547 0.000417 0.000004 0.001018 HAML36 0.0061 0.00142 0.000891 0.000515 0 0.001174 0.000266 0.000851 0 0.002592 HAML37 0.00329 0.001908 0.001753 0.000483 0.000081 0.000214 0.000621 0.000479 0 0.001128 HAML38 0.002522 0.001455 0.000205 0.000297 0.000038 0.000156 0.000583 0.000531 0.000004 0.000753 HAML39 D_TRAINF 0.038635 0.000242 0.000556 0.000115 0.00021 0.000088 0.002701 0.000118 0 0.00031 HAML40 D_TRUCKF 0.006849 0.000051 0.000273 0.000035 0.000061 0.000023 0.000076 0.000018 0.000017 0.000081 HAML41 TIRE_WR1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 0.0199 0.0001 0.015 0.0001 0 0.0001 0.0002 0.0001 0.0002 0.0001 HAML43 TIRE_WR3 0 0.0001 0.0006 0.0001 0.0004 0.0001 0.002 0.0001 0.0006 0.0001 HAML44 TIRE_WR4 0.0199 -99 0 0.0001 0.0004 -99 0.0011 -99 0.0004 -99 HAML45 BRAKEASB 0 0.0001 0.0015 0.0001 0 0.0001 0.019 0.0001 0 0.0001 HAML46 BRAKEWER 0.0128 -99 0 0.0001 0.0002 -99 0.0011 -99 0.0036 -99 HAML47 MTCOOKCH 0 0.0001 0.0037 0.0001 0.0016 0.0001 0.0006 0.0001 0.0001 0.0001 HAML48 MTCOOKFR 0 0.0001 0.0352 0.0001 0.0036 0.0001 0.0015 0.0001 0 0.0001 HAML49 COOKING1 0.002455 0.001843 0.00718 0.011944 0.003036 0.003243 0.001726 0.002115 0.000066 0.001528 HAML50 COOKCHAR 0.0019 0.0001 0.004029 0.0001 0.002468 0.0001 0.000335 0.0001 3.35E-05 0.0001 HAML51 DEICER_F 0.024 0.003 0.487 0.05 0.0022 0.0005 0.0006 0.0001 0 0.1 HAML52 RWC_MEDF 0.00159 0.0005 0.00129 0.00043 0.00497 0.00208 0.00018 0.00022 0.00002 0.00094 HAML53 RWC_POCF 0.00055 0.00004 0.00087 0.00012 0.00118 0.00023 0.00009 0.00002 0 0.00004 HAML54 RWC_F222 0.001425 0.000026 0.001856 0.000065 0.003546 0.000065 0.001265 0.000038 0.000047 0.00008 HAML55 RWC_ALON 0.0018 0.0002 0.0051 0.0003 0.0086 0.001 0.0007 0.0001 0 0.0001 HAML56 RWC_COMP 0.0018 0.0002 0.0051 0.0003 0.0086 0.0001 0.0007 0.0001 0 0.0001 HAML57 RWB_COMP 0.005 0.0001 0.0033 0.0002 0.0262 0.0001 0.0002 0.0001 0 0.0001 HAML58 0.018 0.0001 0.008 0.0001 0.08 0.0001 0 0.0001 0 0.0001 HAML59 0.001 0.0001 0.001 0.0001 0.01 0.0001 0 0.0001 0 0.0001 HAML60 0.000978 0.000446 0.001756 0.00089 0.00298 0.002665 0.000549 0.000644 0 0.000133 HAML61 0.000701 0.000114 0.001197 0.000125 0.001298 0.000422 0.000491 0.000818 0 0.000139 HAML62 0.000608 0.000021 0.001292 0.000046 0.00121 0.00004 0.000075 0.00001 0 0.000065 HAML63 0.000596 0.000022 0.001315 0.000049 0.001044 0.000037 0.000134 0.000013 0 0.000078 HAML64 0.000791 0.000025 0.001064 0.000036 0.001918 0.000058 0.000037 0.000015 0 0.000058 ---PAGE BREAK--- 27 Butte PM2.5 Source Profiles, cont. PNO SID C23 V C24 CR C25 MN C26 FE C28 NI HAML01 ST_SANDF 0 0.000058 0.000132 0.000023 0.000885 0.000054 0.050261 0.002582 0.000076 0.000015 HAML02 ERN_RUSF 0.000148 0.000056 0.00029 0.000035 0.000566 0.000047 0.047608 0.002535 0.000161 0.000022 HAML03 RUS_STF2 0 0.000073 0.000299 0.000054 0.000403 0.000066 0.045997 0.002807 0.000188 0.000038 HAML04 DESP_LTF 0.000055 0.000052 0.000119 0.000026 0.00074 0.000052 0.045618 0.002418 0.000083 0.000019 HAML05 0.0003 0.0001 0.0003 0.0001 0.0013 0.0001 0.0435 0.0044 0.0001 0.0001 HAML06 0.0002 0.0001 0.0004 0.0001 0.001 0.0002 0.0365 0.0048 0.0001 0.0001 HAML07 0.0002 0.0001 0 0.0001 0.0014 0.0002 0.0389 0.0039 0 0.0001 HAML08 0 0.0001 0 0.0001 0.0003 0.0001 0.032 0.004 0 0.0001 HAML09 UNDST_CP 0.0004 0.0001 0.0002 0.0001 0.0017 0.0002 0.0369 0.0038 0 0.0001 HAML10 UNDST_HE 0.0004 0.0001 0.0002 0.0001 0.0005 0.0001 0.0234 0.0023 0 0.0001 HAML11 S04_FZER 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 0 0.000001 0 0.000001 0 0.000001 0 0.000001 0 0.000001 HAML13 NH4NO3F2 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML14 LDV_PBCF 0.00003 0.000006 0.00001 0.000002 0.01166 0.002332 0.00066 0.000132 0.00013 0.000026 HAML15 LDV_XPBF 0.00022 0.00011 0.00005 0.00004 0.00004 0.00003 0.00421 0.00124 0 0.1 HAML16 LDV_DSLF 0 0.1 0 0.1 0 0.1 0.00016 0.00006 0 0.1 HAML17 LDV_DS2F 0 0.00001 0 0.00001 0 0.00001 0.00002 0.00002 0 0.00001 HAML18 HDV_DSLF 0.00002 0.00003 0 0.00003 0 0.00003 0 0.00008 0.00002 0.00003 HAML19 LDV_NCAT 0 0.0001 0.0001 0.0001 0.009 0.0001 0.0075 0.0001 0 0.0001 HAML20 LDV_WCAT 0 0.0001 0 0.0001 0 0.0001 0.0015 0.0001 0.0004 0.0001 HAML21 HDV_TRK1 0 0.0001 0 0.0001 0.0004 0.0001 0.006 0.001 0 0.0001 HAML22 HDV_TRK2 0.0001 0.0001 0.0002 0.0001 0.0001 0.0001 0.0013 0.0001 0.0003 0.0001 HAML23 LDV_UNL1 0 0.0001 0 0.0001 0.0002 0.0001 0.0011 0.0001 0.0002 0.0001 HAML24 LDV_UNL2 0 0.0001 0 0.0001 0 0.0002 0 0.0004 0 0.0001 HAML25 GASEXST1 0 0.001585 0.000004 0.00028 0 0.0002 0.000852 0.000244 0 0.00007 HAML26 GASEXST2 0.000104 0.001194 0.000523 0.00031 0.000195 0.00032 0.01799 0.011531 0.000146 0.000204 HAML27 GASEXST3 0.000231 0.001927 0.00082 0.000497 0.000113 0.000529 0.009088 0.000367 0.000098 0.000333 HAML28 GASEXST4 0.00002 0.000379 0.000172 0.000086 0.000066 0.00008 0.007668 0.000483 0.000064 0.000047 HAML29 GASEXST5 0.000005 0.000447 0.000152 0.000094 0.000083 0.000062 0.007111 0.000075 0.000089 0.000029 HAML30 GASEXST6 0.000068 0.00087 0.000373 0.000234 0.00014 0.00023 0.013566 0.009848 0.000111 0.000147 HAML31 GASEXST7 0 0.001202 0.000006 0.000214 0.000005 0.000148 0.003298 0.004224 0.00001 0.000053 HAML32 GASEXST8 0 0.001419 0.000004 0.000251 0 0.000175 0.00086 0.000199 0.000002 0.000063 HAML33 0.000011 0.00046 0 0.000121 0.000003 0.00009 0.000201 0.000226 0.000002 0.000057 HAML34 0.000013 0.000531 0 0.000139 0.000004 0.000104 0.000217 0.000241 0.000002 0.000067 HAML35 0.00001 0.000408 0 0.000107 0.000003 0.000079 0.000187 0.000213 0.000002 0.000051 HAML36 0 0.001183 0 0.000211 0 0.000144 0.001296 0.0007 0.000037 0.000049 HAML37 0.000009 0.000442 0 0.000115 0.000001 0.000088 0.000246 0.000125 0.000006 0.000058 HAML38 0.000006 0.000326 0 0.000092 0 0.00006 0.000262 0.000291 0.000002 0.000038 HAML39 D_TRAINF 0.000056 0.000113 0.00008 0.000032 0.000042 0.000025 0.000373 0.00003 0.000016 0.000012 HAML40 D_TRUCKF 0.000004 0.00003 0.00001 0.000008 0.000008 0.000007 0.000048 0.000007 0.000003 0.000003 HAML41 TIRE_WR1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML43 TIRE_WR3 0 0.0001 0 0.0001 0.0001 0.0001 0.0046 0.0001 0.0001 0.0001 HAML44 TIRE_WR4 0 -99 0 -99 0.0001 -99 0.0046 -99 0.0001 -99 HAML45 BRAKEASB 0 0.0001 0.001 0.0001 0.0004 0.0001 0.04 0.0001 0 0.0001 HAML46 BRAKEWER 0.0007 -99 0.0012 -99 0.0017 -99 0.287 -99 0.0007 -99 HAML47 MTCOOKCH 0 0.0001 0 0.0001 0 0.0001 0.0007 0.0001 0.0001 0.0001 HAML48 MTCOOKFR 0 0.0001 0.0015 0.0001 0.0004 0.0001 0.0024 0.0001 0.0005 0.0001 HAML49 COOKING1 0.000003 0.00065 0.000034 0.000106 0.000256 0.000355 0.003152 0.003914 0.000055 0.000052 HAML50 COOKCHAR 0.000002 0.0001 0 0.0001 5E-07 0.0001 0.000457 0.0001 6.25E-05 0.0001 HAML51 DEICER_F 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML52 RWC_MEDF 0.00001 0.00038 0.00001 0.0001 0.00003 0.00007 0.00042 0.00052 0 0.00004 HAML53 RWC_POCF 0 0.00002 0 0.001 0.00001 0.001 0 0.001 0 0.001 HAML54 RWC_F222 0.000006 0.000029 0.000005 0.000008 0.000058 0.000008 0.000111 0.000008 0.000001 0.000003 HAML55 RWC_ALON 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML56 RWC_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML57 RWB_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML58 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML59 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML60 0 0.000054 0 0.000012 0.00002 0.000024 0.000036 0.000038 0 0.000005 HAML61 0 0.000057 0 0.000006 0.000015 0.000029 0.000036 0.000048 0 0.000005 HAML62 0 0.000026 0 0.000006 0 0.000005 0.000007 0.000002 0 0.000002 HAML63 0.000002 0.000032 0 0.000008 0.000002 0.000006 0.000014 0.000003 0 0.000003 HAML64 0 0.000024 0 0.000006 0 0.000005 0.000014 0.000002 0 0.000002 ---PAGE BREAK--- 28 Butte PM2.5 Source Profiles, cont. PNO SID C29 CU C30 ZN C31 GA C32 GE C33 AS HAML01 ST_SANDF 0.000133 0.000015 0.00012 0.000014 0.000003 0.000007 0 0.000006 0.000038 0.00002 HAML02 ERN_RUSF 0.000115 0.000018 0.0007 0.000047 0.000015 0.000011 0.000013 0.00001 0.000007 0.000042 HAML03 RUS_STF2 0.00008 0.000027 0.000733 0.00006 0.000047 0.000015 0.00004 0.000015 0 0.000064 HAML04 DESP_LTF 0.0001 0.000017 0.00036 0.000029 0.000014 0.000009 0 0.000008 0.000018 0.000027 HAML05 0.0033 0.0003 0.0025 0.0003 0 0.0001 0 0.0001 0.0002 0.0001 HAML06 0.001 0.0002 0.002 0.0005 0 0.0001 0 0.0001 0.0004 0.0002 HAML07 0.0038 0.0004 0.0129 0.0013 0 0.0001 0 0.0001 0.0034 0.0005 HAML08 0.0011 0.0003 0.0004 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML09 UNDST_CP 0.0095 0.0012 0.0038 0.0005 0 0.0001 0 0.0001 0.0003 0.0001 HAML10 UNDST_HE 0.0001 0.0001 0.0003 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML11 S04_FZER 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 0 0.000001 0 0.000001 0 0.000001 0 0.000001 0 0.000001 HAML13 NH4NO3F2 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML14 LDV_PBCF 0.00029 0.000058 0.00129 0.000258 0.00035 0.00007 0 0.1 0.00096 0.000192 HAML15 LDV_XPBF 0.00031 0.00024 0.00592 0.00263 0.00001 0.00001 0 0.1 0 0.1 HAML16 LDV_DSLF 0.00001 0.000002 0.00047 0.00027 0 0.1 0 0.1 0.00002 0.00001 HAML17 LDV_DS2F 0.00002 0.00001 0.00037 0.00011 0 0.00001 0 0.1 0.00002 0.00002 HAML18 HDV_DSLF 0.00001 0.00003 0.00053 0.00017 0 0.00002 0 0.1 0 0.00008 HAML19 LDV_NCAT 0 0.0001 0.0061 0.0001 0 0.0001 0 0.0001 0.0004 0.0001 HAML20 LDV_WCAT 0.0112 0.0001 0.0106 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML21 HDV_TRK1 0.0003 0.0001 0.0016 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML22 HDV_TRK2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.0002 0.0001 HAML23 LDV_UNL1 0.0002 0.0001 0.0008 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML24 LDV_UNL2 0.0001 0.0002 0.0012 0.0005 0.0001 0.0001 0 0.0001 0 0.0001 HAML25 GASEXST1 0.000098 0.00008 0.00056 0.001118 0.000011 0.000165 0 0.0001 0.000015 0.000111 HAML26 GASEXST2 0.000392 0.000212 0.006534 0.002866 0.000007 0.000237 0 0.0001 0.000003 0.000454 HAML27 GASEXST3 0.000222 0.000352 0.003033 0.000308 0.000019 0.000379 0 0.0001 0.000009 0.000412 HAML28 GASEXST4 0.000192 0.000181 0.002571 0.002408 0 0.000069 0 0.0001 0.000001 0.000243 HAML29 GASEXST5 0.000094 0.000033 0.00117 0.000215 0 0.000069 0 0.0001 0 0.000362 HAML30 GASEXST6 0.000306 0.000209 0.004835 0.003245 0.000004 0.000173 0 0.0001 0.000002 0.000403 HAML31 GASEXST7 0.000111 0.000059 0.000327 0.000847 0.000005 0.00013 0 0.0001 0.000012 0.000132 HAML32 GASEXST8 0.00009 0.000071 0.000491 0.001001 0.000008 0.000148 0 0.0001 0.000015 0.000099 HAML33 0 0.000062 0.000593 0.000806 0.000003 0.000095 0 0.0001 0.000003 0.000106 HAML34 0.000001 0.000072 0.000657 0.000907 0.000004 0.000109 0 0.0001 0.000004 0.000123 HAML35 0 0.000055 0.000542 0.000726 0.000003 0.000084 0 0.0001 0.000003 0.000094 HAML36 0.000057 0.000057 0 0.000823 0 0.00013 0 0.0001 0.000009 0.000126 HAML37 0.000003 0.000063 0.000587 0.000305 0.000013 0.000091 0 0.0001 0.000008 0.000101 HAML38 0 0.00004 0.000682 0.001172 0 0.000062 0 0.0001 0.000003 0.00007 HAML39 D_TRAINF 0.000053 0.000017 0.000048 0.00002 0 0.00001 0 0.00001 0.000023 0.000066 HAML40 D_TRUCKF 0.000003 0.000004 0.000025 0.000005 0 0.00001 0 0.00001 0 0.000017 HAML41 TIRE_WR1 0 0.0001 0.01 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 0 0.0001 0.0102 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML43 TIRE_WR3 0.0005 0.0001 0.0004 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML44 TIRE_WR4 0.0005 -99 0.0053 -99 0 0.0001 0 0.0001 0 -99 HAML45 BRAKEASB 0 0.0001 0.0031 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML46 BRAKEWER 0.0115 -99 0.0003 -99 0 0.0001 0 0.0001 0 -99 HAML47 MTCOOKCH 0.0034 0.0001 0.0022 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML48 MTCOOKFR 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML49 COOKING1 0.000278 0.000476 0.000363 0.000428 0.000001 0.000201 0 0.0001 0.000007 0.000111 HAML50 COOKCHAR 0.000143 0.0001 0.000309 0.0001 0 0.0001 0 0.0001 3.5E-06 0.0001 HAML51 DEICER_F 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML52 RWC_MEDF 0.00009 0.00012 0.00053 0.00058 0 0.00015 0 0.001 0.00001 0.00011 HAML53 RWC_POCF 0 0.001 0.00021 0.00008 0 0.00001 0 0.0001 0 0.00001 HAML54 RWC_F222 0 0.000005 0.000289 0.000009 0 0.00001 0 0.00001 0 0.000019 HAML55 RWC_ALON 0 0.0001 0.0004 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML56 RWC_COMP 0 0.0001 0.0004 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML57 RWB_COMP 0 0.0001 0.0001 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML58 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML59 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML60 0 0.000005 0.000317 0.000347 0 0.000018 0 0.0001 0 0.00002 HAML61 0 0.000004 0.000095 0.000038 0 0.000018 0 0.0001 0 0.000021 HAML62 0 0.000004 0.000092 0.000003 0 0.000009 0 0.0001 0 0.000008 HAML63 0 0.000004 0.000105 0.000004 0 0.000011 0 0.0001 0.000002 0.00001 HAML64 0 0.000003 0.000137 0.000004 0 0.000008 0 0.0001 0 0.000007 ---PAGE BREAK--- 29 Butte PM2.5 Source Profiles, cont. PNO SID C34 SE C35 BR C37 RB C38 SR C39 Y HAML01 ST_SANDF 0.000003 0.000007 0.00002 0.000009 0.000173 0.000017 0.000091 0.000016 0 0.000017 HAML02 ERN_RUSF 0 0.000011 0.000054 0.000017 0.000156 0.000022 0.000129 0.000023 0 0.000027 HAML03 RUS_STF2 0 0.000022 0.000042 0.000029 0.000177 0.00004 0.000073 0.000042 0 0.000051 HAML04 DESP_LTF 0.000006 0.000009 0.000008 0.000012 0.000126 0.00002 0.000031 0.000018 0 0.000022 HAML05 0 0.0001 0 0.0001 0 0.0001 0.0003 0.0001 0 0.0001 HAML06 0 0.0001 0.0002 0.0001 0 0.0001 0.0001 0.0001 0 0.0001 HAML07 0.0001 0.0001 0.0011 0.0001 0 0.0001 0.0002 0.0001 0 0.0001 HAML08 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML09 UNDST_CP 0 0.0001 0.0001 0.0001 0 0.0001 0.0003 0.0001 0 0.0001 HAML10 UNDST_HE 0 0.0001 0 0.0001 0 0.0001 0.0003 0.0001 0 0.0001 HAML11 S04_FZER 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 0 0.000001 0 0.000001 0 0.000001 0 0.000001 0 0.000001 HAML13 NH4NO3F2 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML14 LDV_PBCF 0 0.1 0.08274 0.016548 0.00003 0.000006 0 0.1 0.00001 0.000009 HAML15 LDV_XPBF 0 0.1 0.00249 0.00114 0 0.1 0 0.1 0 0.1 HAML16 LDV_DSLF 0 0.1 0.00005 0.00001 0 0.1 0 0.1 0 0.1 HAML17 LDV_DS2F 0 0.00001 0.00002 0.00001 0 0.00001 0 0.00001 0 0.00002 HAML18 HDV_DSLF 0 0.00003 0 0.00003 0 0.00004 0 0.00005 0 0.00007 HAML19 LDV_NCAT 0 0.0001 0.0338 0.0001 0.0001 0.0001 0.0001 0.0001 0 0.0001 HAML20 LDV_WCAT 0 0.0001 0.0004 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML21 HDV_TRK1 0 0.0001 0 0.0001 0 0.0001 0.0001 0 0 0.0001 HAML22 HDV_TRK2 0 0.0001 0.0001 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML23 LDV_UNL1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML24 LDV_UNL2 0 0.0001 0.0041 0.0031 0 0.0001 0 0.0001 0 0.0001 HAML25 GASEXST1 0 0.00005 0.000008 0.000049 0 0.000076 0 0.000136 0 0.000078 HAML26 GASEXST2 0.000008 0.000138 0.000389 0.000372 0.000005 0.00011 0.000016 0.000118 0 0.000147 HAML27 GASEXST3 0.000029 0.000222 0.000015 0.000191 0.000015 0.000171 0.000018 0.000191 0 0.000233 HAML28 GASEXST4 0 0.000035 0.000303 0.000414 0 0.000036 0.000004 0.000034 0 0.000042 HAML29 GASEXST5 0 0.000026 0.000781 0.000021 0 0.000046 0.000001 0.000034 0 0.00004 HAML30 GASEXST6 0.000004 0.000099 0.000352 0.000358 0.000003 0.00008 0.00001 0.000085 0 0.000108 HAML31 GASEXST7 0.000002 0.000037 0.000059 0.000091 0 0.000058 0 0.000103 0 0.00006 HAML32 GASEXST8 0.000003 0.000043 0.000006 0.000044 0 0.000068 0 0.000122 0 0.00007 HAML33 0.000002 0.000056 0.000012 0.000051 0.000008 0.000048 0.000001 0.000052 0.000005 0.000064 HAML34 0.000003 0.000065 0.000013 0.000059 0.000009 0.000055 0.000001 0.00006 0.000005 0.000075 HAML35 0.000002 0.00005 0.000011 0.000045 0.000008 0.000042 0.000001 0.000046 0.000004 0.000057 HAML36 0 0.000036 0.000006 0.000037 0 0.000056 0 0.000101 0 0.000058 HAML37 0.000002 0.000054 0.000009 0.000049 0.000008 0.000045 0 0.000049 0 0.000061 HAML38 0 0.000037 0.000015 0.000033 0.000001 0.000031 0.000001 0.000034 0.000002 0.000042 HAML39 D_TRAINF 0.000021 0.000029 0.000014 0.000025 0 0.00004 0.000045 0.000057 0 0.00001 HAML40 D_TRUCKF 0.000007 0.000008 0.000013 0.000007 0.000008 0.000011 0.000007 0.000016 0 0.00001 HAML41 TIRE_WR1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 0 0.0001 0 0.0001 0 0.0001 0.0001 0.0001 0 0.0001 HAML43 TIRE_WR3 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML44 TIRE_WR4 0 -99 0 -99 0 -99 0.0001 -99 0 0.0001 HAML45 BRAKEASB 0 0.0001 0 0.0001 0 0.0001 0.0004 0.0001 0 0.0001 HAML46 BRAKEWER 0 -99 0 -99 0.0001 -99 0.0007 -99 0 0.0001 HAML47 MTCOOKCH 0 0.0001 0.0001 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML48 MTCOOKFR 0.0001 0.0001 0.0008 0.0001 0.0009 0.0001 0.0001 0.0001 0 0.0001 HAML49 COOKING1 0.000001 0.000046 0.00007 0.000139 0.000004 0.00005 0.000011 0.000064 0 0.000078 HAML50 COOKCHAR 5E-07 0.0001 3.85E-05 0.0001 1.5E-06 0.0001 5.5E-06 0.0001 0 0.0001 HAML51 DEICER_F 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML52 RWC_MEDF 0 0.00006 0.00003 0.00005 0.00001 0.00005 0 0.00006 0 0.00008 HAML53 RWC_POCF 0 0.001 0.00001 0.00001 0 0.001 0 0.001 0 0.001 HAML54 RWC_F222 0.000006 0.000008 0.000019 0.000007 0.000017 0.000012 0.000042 0.000016 0 0.00001 HAML55 RWC_ALON 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML56 RWC_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML57 RWB_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML58 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML59 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML60 0 0.000008 0.000017 0.000011 0 0.000008 0 0.000008 0 0.000012 HAML61 0 0.000009 0.000011 0.000004 0 0.000009 0 0.000007 0 0.000012 HAML62 0 0.000004 0.000009 0.000003 0 0.000004 0 0.000005 0 0.000006 HAML63 0.000001 0.000005 0.000011 0.000002 0 0.000005 0.000001 0.000006 0 0.000007 HAML64 0 0.000004 0.000007 0.000001 0.000003 0.000004 0 0.000004 0 0.000005 ---PAGE BREAK--- 30 Butte PM2.5 Source Profiles, cont. PNO SID C40 ZR C42 MO C46 PD C47 AG C48 CD HAML01 ST_SANDF 0.000009 0.000042 0 0.000056 0 0.000064 0 0.000082 0 0.0001 HAML02 ERN_RUSF 0.000143 0.000066 0 0.000092 0.000084 0.000092 0.000147 0.000116 0.000118 0.000137 HAML03 RUS_STF2 0.000082 0.000128 0.000071 0.000182 0 0.000173 0.000481 0.00022 0.000447 0.000275 HAML04 DESP_LTF 0.000136 0.000059 0.000023 0.000082 0 0.000076 0 0.000098 0 0.000124 HAML05 0 0.0001 0 0.0001 0.0002 0.0001 0 0.0001 0 0.0001 HAML06 0 0.0001 0 0.0001 0 0.0001 0 0.0002 0.0003 0.0003 HAML07 0 0.0001 0 0.0001 0 0.0001 0.0002 0.0004 0.0023 0.0007 HAML08 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML09 UNDST_CP 0 0.0001 0 0.0001 0.0002 0.0002 0 0.0001 0.0001 0.0003 HAML10 UNDST_HE 0 0.0001 0 0.0001 0.0005 0.0002 0 0.0001 0 0.0001 HAML11 S04_FZER 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 0 0.000001 0 0.000001 0 0.000001 0 0.000001 0 0.000001 HAML13 NH4NO3F2 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML14 LDV_PBCF 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML15 LDV_XPBF 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML16 LDV_DSLF 0 0.00002 0 0.00001 0 0.00001 0 0.00002 0 0.00002 HAML17 LDV_DS2F 0 0.00008 0 0.00005 0 0.00005 0 0.00006 0 0.00008 HAML18 HDV_DSLF 0 0.0003 0 0.00018 0 0.00018 0.00009 0.00025 0 0.00032 HAML19 LDV_NCAT 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML20 LDV_WCAT 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML21 HDV_TRK1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML22 HDV_TRK2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML23 LDV_UNL1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML24 LDV_UNL2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML25 GASEXST1 0.00001 0.00011 0.00001 0.00012 0.00003 0.00033 0.00007 0.00035 0.000026 0.00041 HAML26 GASEXST2 0.000012 0.000166 0.000018 0.000307 0.000089 0.001009 0.000182 0.001093 0.000127 0.001193 HAML27 GASEXST3 0.00002 0.000268 0.000034 0.000497 0.000162 0.001634 0.000317 0.001768 0.000143 0.00193 HAML28 GASEXST4 0.000006 0.000042 0.000023 0.000071 0.000008 0.000246 0.000043 0.000268 0.000039 0.000294 HAML29 GASEXST5 0.000002 0.000034 0.00001 0.000045 0.000011 0.000146 0.000029 0.000158 0.000019 0.000177 HAML30 GASEXST6 0.000009 0.000119 0.00002 0.000219 0.000054 0.000724 0.000122 0.000784 0.000089 0.000856 HAML31 GASEXST7 0.000002 0.000084 0.000005 0.000093 0.000027 0.000247 0.000058 0.000268 0.000017 0.000311 HAML32 GASEXST8 0.000004 0.000099 0.000007 0.00011 0.000023 0.000293 0.000068 0.000317 0.000022 0.000367 HAML33 0 0.000076 0.000007 0.00014 0.00002 0.000386 0.000147 0.000433 0.000049 0.000462 HAML34 0 0.000088 0.000008 0.000162 0.000022 0.000447 0.000164 0.000502 0.000053 0.000535 HAML35 0 0.000067 0.000007 0.000124 0.000019 0.000342 0.000133 0.000382 0.000045 0.000409 HAML36 0 0.000083 0 0.000091 0.00002 0.000237 0.000055 0.000257 0.000014 0.000299 HAML37 0 0.000072 0.000002 0.000132 0 0.000379 0.000111 0.000433 0.000079 0.000452 HAML38 0 0.00005 0.000002 0.000092 0.000026 0.000249 0.000061 0.000281 0.000044 0.000298 HAML39 D_TRAINF 0 0.000159 0 0.00001 0 0.00001 0 0.00001 0.000181 0.000289 HAML40 D_TRUCKF 0 0.000043 0 0.00001 0 0.00001 0 0.00001 0 0.000074 HAML41 TIRE_WR1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML43 TIRE_WR3 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML44 TIRE_WR4 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML45 BRAKEASB 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML46 BRAKEWER 0 0.0001 0.0037 -99 0 0.0001 0 0.0001 0 0.0001 HAML47 MTCOOKCH 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML48 MTCOOKFR 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML49 COOKING1 0.000067 0.001602 0 0.000165 0.000012 0.000316 0.000044 0.00039 0.000007 0.000398 HAML50 COOKCHAR 0 0.0001 0 0.0001 0 0.0001 0.000044 0.0001 0.000002 0.0001 HAML51 DEICER_F 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML52 RWC_MEDF 0 0.0001 0.00002 0.00018 0 0.00036 0 0.00041 0 0.00046 HAML53 RWC_POCF 0 0.00001 0 0.00001 0 0.00002 0 0.00002 0.00001 0.00002 HAML54 RWC_F222 0.00005 0.000046 0 0.00001 0 0.00001 0 0.00001 0 0.000071 HAML55 RWC_ALON 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML56 RWC_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML57 RWB_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML58 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML59 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML60 0 0.000015 0 0.000027 0 0.000051 0 0.000059 0 0.000064 HAML61 0 0.000016 0 0.000028 0 0.000053 0 0.000061 0 0.000068 HAML62 0 0.000008 0 0.000014 0 0.000024 0 0.000029 0 0.000031 HAML63 0 0.000009 0 0.000016 0 0.000029 0.000005 0.000034 0.000013 0.000038 HAML64 0 0.000007 0 0.000012 0 0.000023 0.000006 0.000026 0 0.000028 ---PAGE BREAK--- 31 Butte PM2.5 Source Profiles, cont. PNO SID C49 IN C50 SN C51 SB C56 BA C57 LA HAML01 ST_SANDF 0 0.00012 0 0.000154 0 0.000185 0.002177 0.000787 0 0.001048 HAML02 ERN_RUSF 0.00034 0.00019 0 0.00023 0 0.000287 0 0.001177 0.002004 0.001598 HAML03 RUS_STF2 0.000193 0.00035 0.000523 0.000461 0.000264 0.000558 0.004926 0.002333 0.00476 0.003205 HAML04 DESP_LTF 0 0.000153 0 0.000189 0.000184 0.000233 0 0.001028 0.004419 0.001385 HAML05 0 0.0001 0 0.0001 0.0009 0.0006 0 0.0001 0 0.0001 HAML06 0 0.0002 0.0001 0.0003 0.0002 0.0005 0.0001 0.0013 0 0.0001 HAML07 0 0.0007 0.0005 0.0008 0.0012 0.0015 0.001 0.0038 0 0.0001 HAML08 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML09 UNDST_CP 0.0002 0.0003 0 0.0001 0.0001 0.0007 0.002 0.0019 0 0.0001 HAML10 UNDST_HE 0 0.0001 0 0.0001 0.0003 0.0009 0.0032 0.0025 0 0.0001 HAML11 S04_FZER 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 0 0.000001 0 0.000001 0 0.000001 0 0.000001 0 0.000001 HAML13 NH4NO3F2 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML14 LDV_PBCF 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML15 LDV_XPBF 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML16 LDV_DSLF 0 0.00003 0 0.00003 0 0.00007 0 0.00013 0 0.00025 HAML17 LDV_DS2F 0 0.0001 0 0.00012 0 0.00027 0 0.00051 0 0.00094 HAML18 HDV_DSLF 0 0.0004 0 0.00048 0 0.00109 0 0.00202 0 0.00368 HAML19 LDV_NCAT 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML20 LDV_WCAT 0 0.0001 0 0.0001 0 0.0001 0.0012 0.0001 0 0.0001 HAML21 HDV_TRK1 0 0.0001 0 0.0001 0 0.0001 0.0008 0.0001 0 0.0001 HAML22 HDV_TRK2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML23 LDV_UNL1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML24 LDV_UNL2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML25 GASEXST1 0.00005 0.000406 0.00002 0.00054 0.000085 0.000577 0.002484 0.008619 0.00001 0.002427 HAML26 GASEXST2 0.000017 0.00139 0.000132 0.001761 0.000096 0.002111 0.000308 0.007779 0.000088 0.010564 HAML27 GASEXST3 0.000024 0.002251 0.000282 0.002851 0.000197 0.003419 0.000681 0.012603 0.000077 0.01712 HAML28 GASEXST4 0.000021 0.000338 0.000106 0.00042 0.000055 0.000512 0.000163 0.002234 0.000137 0.002547 HAML29 GASEXST5 0.000034 0.000191 0.00018 0.000234 0.000077 0.000285 0.00007 0.002312 0.000197 0.001349 HAML30 GASEXST6 0.000019 0.000996 0.000121 0.001262 0.000079 0.001514 0.000246 0.005633 0.000109 0.00757 HAML31 GASEXST7 0.000036 0.000308 0.000018 0.000406 0.000078 0.000438 0.00168 0.006558 0.000035 0.001846 HAML32 GASEXST8 0.00005 0.000364 0.000019 0.00048 0.000114 0.000518 0.00252 0.007722 0.000007 0.00218 HAML33 0.000072 0.000554 0.000075 0.000716 0.000019 0.000854 0.000532 0.003168 0.000217 0.00421 HAML34 0.000083 0.000641 0.000084 0.000827 0.000021 0.000988 0.000597 0.003664 0.000238 0.004868 HAML35 0.000063 0.00049 0.000069 0.000634 0.000018 0.000756 0.000481 0.002806 0.0002 0.003729 HAML36 0.000035 0.000296 0.000019 0.000391 0.00009 0.000422 0.001046 0.006589 0.000054 0.001784 HAML37 0.000078 0.000548 0.000195 0.000717 0.000026 0.000838 0.00083 0.003118 0 0.004095 HAML38 0.000018 0.000357 0.000025 0.000471 0.000019 0.000559 0.00035 0.002051 0.000272 0.002757 HAML39 D_TRAINF 0 0.00001 0 0.00001 0.000645 0.000348 0.001324 0.001005 0 0.00001 HAML40 D_TRUCKF 0 0.00001 0 0.00001 0.000065 0.000089 0.000083 0.000262 0 0.00001 HAML41 TIRE_WR1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML43 TIRE_WR3 0 0.0001 0 0.0001 0 0.0001 0.0004 0.0001 0 0.0001 HAML44 TIRE_WR4 0 0.0001 0 0.0001 0 0.0001 0.0002 -99 0 0.0001 HAML45 BRAKEASB 0 0.0001 0 0.0001 0 0.0001 0.0092 0.0001 0 0.0001 HAML46 BRAKEWER 0 0.0001 0.0066 -99 0 0.0001 0.0545 -99 0 0.0001 HAML47 MTCOOKCH 0 0.0001 0 0.0001 0 0.0001 0.002 0.0001 0 0.0001 HAML48 MTCOOKFR 0 0.0001 0 0.0001 0 0.0001 0.0046 0.0001 0 0.0001 HAML49 COOKING1 0.000012 0.000475 0.000026 0.000704 0.000216 0.000797 0.00022 0.003728 0.000112 0.004968 HAML50 COOKCHAR 0.000002 0.0001 0.000014 0.0001 0.000027 0.0001 0.00021 0.0001 0.0001 0.0001 HAML51 DEICER_F 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML52 RWC_MEDF 0 0.00055 0 0.00074 0 0.00081 0.00021 0.00297 0.00001 0.00334 HAML53 RWC_POCF 0 0.00002 0 0.00003 0 0.00004 0.00002 0.00013 0.00011 0.00015 HAML54 RWC_F222 0 0.00001 0 0.00001 0.00007 0.000087 0.000258 0.000256 0 0.00001 HAML55 RWC_ALON 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML56 RWC_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML57 RWB_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML58 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML59 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML60 0 0.000076 0 0.000102 0 0.000119 0 0.000408 0 0.000476 HAML61 0 0.000079 0 0.000106 0 0.000124 0 0.000426 0 0.000497 HAML62 0.000002 0.000037 0.000015 0.00005 0 0.000058 0.000126 0.000196 0.000072 0.000228 HAML63 0 0.000044 0 0.000059 0.000011 0.00007 0.000077 0.000241 0.000079 0.000282 HAML64 0.000008 0.000033 0.00002 0.000045 0.000002 0.000053 0.000055 0.000177 0.000057 0.000207 ---PAGE BREAK--- 32 Butte PM2.5 Source Profiles, cont. PNO SID C80 HG C82 PB C200 TC C201 OC C202 EC HAML01 ST_SANDF 0 0.000012 0.000005 0.000032 0.005788 0.001656 0.005788 0.000402 0 0.001608 HAML02 ERN_RUSF 0 0.000017 0.000367 0.000059 0.088622 0.027722 0.088622 0.025997 0 0.009637 HAML03 RUS_STF2 0.000104 0.000029 0.00027 0.000098 0.092446 0.014278 0.088996 0.013065 0.003449 0.004625 HAML04 DESP_LTF 0 0.000015 0.000105 0.000042 0.035653 0.003477 0.035653 0.002815 0 0.002038 HAML05 0 0.0001 0.0018 0.0002 0 0.0001 0 0.0001 0 0.0001 HAML06 0 0.0001 0.0039 0.001 0 0.0001 0.0318 0.015 0.0047 0.0033 HAML07 0.0002 0.0001 0.0247 0.0025 0 0.0001 0 0.0001 0 0.0001 HAML08 0 0.0001 0.0013 0.0002 0 0.0001 0.1 0.0001 0.014 0.0001 HAML09 UNDST_CP 0 0.0001 0.0011 0.0002 0 0.0001 0 0.0001 0 0.0001 HAML10 UNDST_HE 0 0.0001 0.0004 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML11 S04_FZER 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 0 0.000001 0 0.000001 0 0.000001 0 0.000001 0 0.000001 HAML13 NH4NO3F2 0 0.00001 0 0.00001 0 0.000014 0 0.00001 0 0.00001 HAML14 LDV_PBCF 0.00002 0.000018 0.19821 0.039642 0.49799 0.084818 0.41611 0.083222 0.08188 0.016376 HAML15 LDV_XPBF 0.00001 0.00001 0.00364 0.00138 0.87832 0.127898 0.49202 0.09893 0.3863 0.08106 HAML16 LDV_DSLF 0 0.1 0.00016 0.00013 0.89497 0.14085 0.23635 0.0549 0.65862 0.12971 HAML17 LDV_DS2F 0 0.00001 0.00025 0.00017 1.06104 0.073579 0.43358 0.02103 0.62746 0.07051 HAML18 HDV_DSLF 0 0.00003 0 0.00011 0.88104 0.057591 0.36046 0.03406 0.52058 0.04644 HAML19 LDV_NCAT 0 0.0001 0.0866 0.0001 0 0.0001 0.655 0.0001 0.0801 0.0001 HAML20 LDV_WCAT 0 0.0001 0.0019 0.0001 0 0.0001 0.501 0.0001 0.226 0.0001 HAML21 HDV_TRK1 0 0.0001 0.013 0.003 0 0.0001 0.209 0.0001 0.548 0.0001 HAML22 HDV_TRK2 0 0.0001 0 0.0001 0 0.0001 0.326 0.0001 0.405 0.0001 HAML23 LDV_UNL1 0 0.0001 0 0.0001 0 0.0001 0.211 0.0001 0.178 0.0001 HAML24 LDV_UNL2 0 0.0002 0 0.0006 0 0.0001 0.9291 0.5174 0.0483 0.068 HAML25 GASEXST1 0.00001 0.00014 0.000225 0.000223 0.833024 0.033825 0.7718 0.033578 0.061223 0.030365 HAML26 GASEXST2 0.000002 0.000315 0.002252 0.001329 0.808111 0.049022 0.433517 0.091606 0.374594 0.084459 HAML27 GASEXST3 0.000009 0.000506 0.000356 0.000543 0.816766 0.070421 0.538563 0.048488 0.278203 0.051069 HAML28 GASEXST4 0 0.000085 0.001149 0.000846 0.859487 0.035144 0.519218 0.169008 0.340269 0.203396 HAML29 GASEXST5 0.000001 0.000071 0.002126 0.000058 0.89993 0.032912 0.333416 0.015305 0.566513 0.029137 HAML30 GASEXST6 0.000001 0.000228 0.001779 0.001212 0.83445 0.041542 0.475375 0.119002 0.359075 0.128379 HAML31 GASEXST7 0.000006 0.000121 0.000463 0.000504 0.844731 0.032374 0.695579 0.139336 0.149152 0.162283 HAML32 GASEXST8 0.000008 0.000129 0.000185 0.000214 0.831421 0.034028 0.775962 0.033862 0.055459 0.00335 HAML33 0 0.000127 0.000003 0.000154 0.939271 0.037229 0.189289 0.07886 0.749982 0.102669 HAML34 0 0.000147 0.000003 0.000177 0.946986 0.03916 0.13948 0.055758 0.807506 0.077093 HAML35 0 0.000113 0.000003 0.000136 0.93284 0.036272 0.230403 0.095497 0.702437 0.120941 HAML36 0 0.000133 0.000383 0.000447 0.921953 0.034867 0.307311 0.136645 0.614641 0.161304 HAML37 0 0.000121 0.00001 0.000147 0.933226 0.033793 0.198087 0.077406 0.735138 0.101438 HAML38 0 0.000084 0.000001 0.000101 0.946829 0.03364 0.175588 0.075777 0.771241 0.096654 HAML39 D_TRAINF 0.000294 0.000114 0.000135 0.000104 0.888 0.080483 0.8 0.08 0.088 0.0088 HAML40 D_TRUCKF 0 0.000028 0.000043 0.000029 0.959 0.088083 0.877 0.0877 0.082 0.0082 HAML41 TIRE_WR1 0 0.0001 0 0.0001 0 0.0001 0.2175 0.0001 0.609 0.0001 HAML42 TIRE_WR2 0 0.0001 0 0.0001 0 0.0001 0.583 0.0001 0.287 0.0001 HAML43 TIRE_WR3 0 0.0001 0.0002 0.0001 0 0.0001 0.36 0.0001 0.153 0.0001 HAML44 TIRE_WR4 0 0.0001 0.0002 -99 0 0.0001 0.4715 -99 0.22 -99 HAML45 BRAKEASB 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML46 BRAKEWER 0 0.0001 0.0001 -99 0 0.0001 0.107 -99 0.0261 -99 HAML47 MTCOOKCH 0 0.0001 0.0003 0.0001 0 0.0001 0.588 0.0001 0 0.0001 HAML48 MTCOOKFR 0 0.0001 0.002 0.0001 0 0.0001 0.574 0.0001 0 0.0001 HAML49 COOKING1 0.000001 0.000091 0.000131 0.000357 0.96804 0.174052 0.866333 0.16309 0.101707 0.062895 HAML50 COOKCHAR 0.000001 0.0001 0.000066 0.0001 0 0.0001 0.809977 0.0001 0.040563 0.0001 HAML51 DEICER_F 0 0.1 0 0.1 0.0028 0.0004 0.0028 0.0004 0 0.1 HAML52 RWC_MEDF 0.00004 0.0002 0.00007 0.00018 0.63213 0.099039 0.48868 0.06759 0.14345 0.07239 HAML53 RWC_POCF 0 0.00001 0 0.00001 0.53248 0.091316 0.45356 0.08871 0.07892 0.02166 HAML54 RWC_F222 0.000009 0.00003 0.000099 0.00003 0.843 0.081067 0.81 0.081 0.033 0.0033 HAML55 RWC_ALON 0 0.0001 0 0.0001 0 0.0001 0.475 0.138 0.128 0.084 HAML56 RWC_COMP 0 0.0001 0 0.0001 0 0.0001 0.475 0.138 0.128 0.084 HAML57 RWB_COMP 0 0.0001 0 0.0001 0 0.0001 0.4185 0.083 0.1505 0.0849 HAML58 0 0.0001 0 0.0001 0 0.0001 0.359 0.0001 0.064 0.0001 HAML59 0 0.0001 0 0.0001 0 0.0001 0.387 0.0001 0.045 0.0001 HAML60 0 0.00003 0 0.000016 0.706333 0.171481 0.551734 0.158401 0.154599 0.065689 HAML61 0 0.000031 0 0.000014 0.706292 0.188745 0.58012 0.183841 0.126172 0.042749 HAML62 0 0.000015 0 0.000013 0.619308 0.041502 0.545075 0.041294 0.074233 0.00415 HAML63 0 0.000018 0.000001 0.000015 0.814796 0.05215 0.660123 0.051312 0.154673 0.009316 HAML64 0 0.000013 0 0.000011 0.936987 0.054448 0.752901 0.053285 0.184086 0.011194 ---PAGE BREAK--- 33 Butte PM2.5 Source Profiles, cont. PNO SID C203 SO4 C204 NO3 C205 NH4 C217 CL2 C219 K2 HAML01 ST_SANDF 0.003289 0.000365 0 0.001218 0 0.001218 0.049944 0.005545 0.004385 0.000487 HAML02 ERN_RUSF 0.015327 0.004688 0 0.007299 0.027736 0.008484 0.018979 0.005805 0.025549 0.007814 HAML03 RUS_STF2 0.004528 0.000772 0 0.003484 0 0.003484 0.005924 0.001009 0.012195 0.002078 HAML04 DESP_LTF 0 0.001543 0 0.001543 0 0.001543 0 0.001543 0.005401 0.000633 HAML05 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML06 0.0007 0.0011 0.0001 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML07 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML08 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML09 UNDST_CP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML10 UNDST_HE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML11 S04_FZER 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML12 NH4SO4F2 0.7273 0.036365 0 0.00001 0.2727 0.0136 0 0.00001 0 0.00001 HAML13 NH4NO3F2 0 0.00001 0.775 0.0388 0.225 0.02251 0 0.00001 0 0.00001 HAML14 LDV_PBCF 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML15 LDV_XPBF 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML16 LDV_DSLF 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML17 LDV_DS2F 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML18 HDV_DSLF 0 0.1 0 0.1 0 0.1 0 0.1 0 0.1 HAML19 LDV_NCAT 0.0045 0.0001 0.0063 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML20 LDV_WCAT 0.0359 0.0001 0.0181 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML21 HDV_TRK1 0.049 0.009 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML22 HDV_TRK2 0.0022 0.0001 0.0033 0.0001 0.0008 0.0001 0 0.0001 0 0.0001 HAML23 LDV_UNL1 0.5 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML24 LDV_UNL2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML25 GASEXST1 0.00238 0.00109 0.00282 0.00246 0 0.0001 0.000271 0.000463 0 0.0001 HAML26 GASEXST2 0.017285 0.00556 0.002004 0.001557 0 0.0001 0.001371 0.001234 0 0.0001 HAML27 GASEXST3 0.017474 0.003354 0.003534 0.002521 0 0.0001 0.003218 0.001138 0 0.0001 HAML28 GASEXST4 0.004475 0.002085 0.001015 0.000376 0 0.0001 0.000669 0.000378 0 0.0001 HAML29 GASEXST5 0.00408 0.000313 0.001178 0.000173 0 0.0001 0.000647 0.000137 0 0.0001 HAML30 GASEXST6 0.011795 0.007987 0.00158 0.001115 0 0.0001 0.00107 0.000975 0 0.0001 HAML31 GASEXST7 0.003519 0.002166 0.002404 0.001772 0 0.0001 0.000295 0.00033 0 0.0001 HAML32 GASEXST8 0.002306 0.000742 0.00283 0.002279 0 0.0001 0.000295 0.000384 0 0.0001 HAML33 0.004167 0.004468 0.001657 0.001437 0 0.0001 0.000413 0.000993 0 0.0001 HAML34 0.004626 0.00497 0.001859 0.001729 0 0.0001 0.000445 0.00106 0 0.0001 HAML35 0.003805 0.004084 0.001502 0.001232 0 0.0001 0.000387 0.000934 0 0.0001 HAML36 0.007191 0.002191 0.00386 0.001276 0 0.0001 0.00054 0.000312 0 0.0001 HAML37 0.004629 0.004823 0.002016 0.001409 0 0.0001 0.001062 0.000293 0 0.0001 HAML38 0.00295 0.00356 0.001141 0.000824 0 0.0001 0.000124 0.00018 0 0.0001 HAML39 D_TRAINF 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML40 D_TRUCKF 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML41 TIRE_WR1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML43 TIRE_WR3 0.0025 0.0001 0.0015 0.0001 0.0002 0.0001 0 0.0001 0 0.0001 HAML44 TIRE_WR4 0 0.0001 0.0015 -99 0.0002 -99 0.0078 -99 0 0.0001 HAML45 BRAKEASB 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML46 BRAKEWER 0 0.0001 0.0016 -99 0 -99 0.0015 -99 0 0.0001 HAML47 MTCOOKCH 0.0021 0.0001 0.0002 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML48 MTCOOKFR 0.0091 0.0001 0.0208 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML49 COOKING1 0.003816 0.013882 0.002691 0.005956 0.000482 0.005991 0.007589 0.008405 0.002155 0.002298 HAML50 COOKCHAR 0.001349 0.0001 0.001446 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML51 DEICER_F 0.073 0.01 0 0.1 0 0.1 0.487 0.05 0.0022 0.0005 HAML52 RWC_MEDF 0.01125 0.0133 0.00568 0.00701 0.00384 0.0055 0.00478 0.00546 0.00497 0.00208 HAML53 RWC_POCF 0.00141 0.00033 0.00066 0.00027 0.00075 0.00033 0.00076 0.0001 0.00146 0.00054 HAML54 RWC_F222 0 0.00001 0 0.00001 0 0.00001 0 0.00001 0 0.00001 HAML55 RWC_ALON 0.0029 0.0002 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML56 RWC_COMP 0.0029 0.0002 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML57 RWB_COMP 0.0007 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML58 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML59 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML60 0.002223 0.001864 0.00146 0.001168 0.000715 0.000441 0.000017 0.000008 0.00246 0.002181 HAML61 0.001058 0.000564 0.001178 0.001396 0.000506 0.000379 0.000011 0.000001 0.001086 0.000404 HAML62 0.001082 0.000157 0.003121 0.000117 0.000571 0.000036 0.000012 0.0001 0.001045 0.000045 HAML63 0.001404 0.000213 0.000353 0.000094 0.000998 0.000053 0.000013 0.0001 0.000774 0.00005 HAML64 0.001493 0.000154 0.001237 0.000075 0.000351 0.000032 0.00001 0.0001 0.001668 0.000057 ---PAGE BREAK--- 34 Butte PM2.5 Source Profiles, cont. PNO SID C300 F2 C301 NA2 C302 CA2 C303 MG2 C304 NA HAML01 ST_SANDF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML02 ERN_RUSF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML03 RUS_STF2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML04 DESP_LTF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML05 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML06 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML07 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML08 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML09 UNDST_CP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML10 UNDST_HE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML11 S04_FZER 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML12 NH4SO4F2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML13 NH4NO3F2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML14 LDV_PBCF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML15 LDV_XPBF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML16 LDV_DSLF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML17 LDV_DS2F 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML18 HDV_DSLF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML19 LDV_NCAT 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML20 LDV_WCAT 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML21 HDV_TRK1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML22 HDV_TRK2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML23 LDV_UNL1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML24 LDV_UNL2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML25 GASEXST1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML26 GASEXST2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.00166 0.004102 HAML27 GASEXST3 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.005516 0.005516 HAML28 GASEXST4 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.000494 0.001361 HAML29 GASEXST5 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.000403 0.000304 HAML30 GASEXST6 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.00116 0.003148 HAML31 GASEXST7 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML32 GASEXST8 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML33 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.001403 0.002203 HAML34 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.001592 0.00265 HAML35 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.00126 0.001889 HAML36 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML37 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML38 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML39 D_TRAINF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML40 D_TRUCKF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML41 TIRE_WR1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML42 TIRE_WR2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML43 TIRE_WR3 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML44 TIRE_WR4 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.0006 -99 HAML45 BRAKEASB 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML46 BRAKEWER 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 -99 HAML47 MTCOOKCH 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML48 MTCOOKFR 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML49 COOKING1 0 0.0001 0.002373 0.001957 0 0.0001 0 0.0001 0.011632 0.018156 HAML50 COOKCHAR 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.003 0.0001 HAML51 DEICER_F 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML52 RWC_MEDF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML53 RWC_POCF 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML54 RWC_F222 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML55 RWC_ALON 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML56 RWC_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML57 RWB_COMP 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML58 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML59 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML60 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML61 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML62 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML63 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML64 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 ---PAGE BREAK--- 35 Butte PM2.5 Source Profiles, cont. PNO SID C305 CO HAML01 ST_SANDF 0 0.0001 HAML02 ERN_RUSF 0 0.0001 HAML03 RUS_STF2 0 0.0001 HAML04 DESP_LTF 0 0.0001 HAML05 0 0.0001 HAML06 0 0.0001 HAML07 0 0.0001 HAML08 0 0.0001 HAML09 UNDST_CP 0 0.0001 HAML10 UNDST_HE 0 0.0001 HAML11 S04_FZER 0 0.0001 HAML12 NH4SO4F2 0 0.0001 HAML13 NH4NO3F2 0 0.0001 HAML14 LDV_PBCF 0 0.0001 HAML15 LDV_XPBF 0 0.0001 HAML16 LDV_DSLF 0 0.0001 HAML17 LDV_DS2F 0 0.0001 HAML18 HDV_DSLF 0 0.0001 HAML19 LDV_NCAT 0 0.0001 HAML20 LDV_WCAT 0 0.0001 HAML21 HDV_TRK1 0 0.0001 HAML22 HDV_TRK2 0 0.0001 HAML23 LDV_UNL1 0 0.0001 HAML24 LDV_UNL2 0 0.0001 HAML25 GASEXST1 0 0.000076 HAML26 GASEXST2 0.000039 0.000437 HAML27 GASEXST3 0.000112 0.000393 HAML28 GASEXST4 0.000005 0.000149 HAML29 GASEXST5 0.000002 0.000132 HAML30 GASEXST6 0.000024 0.000312 HAML31 GASEXST7 0.000001 0.000097 HAML32 GASEXST8 0 0.000069 HAML33 0.000001 0.000057 HAML34 0.000001 0.000066 HAML35 0.000001 0.00005 HAML36 0 0.000063 HAML37 0.000001 0.000057 HAML38 0.000002 0.000038 HAML39 D_TRAINF 0 0.0001 HAML40 D_TRUCKF 0 0.0001 HAML41 TIRE_WR1 0 0.0001 HAML42 TIRE_WR2 0 0.0001 HAML43 TIRE_WR3 0 0.0001 HAML44 TIRE_WR4 0 0.0001 HAML45 BRAKEASB 0 0.0001 HAML46 BRAKEWER 0 0.0001 HAML47 MTCOOKCH 0 0.0001 HAML48 MTCOOKFR 0 0.0001 HAML49 COOKING1 0.000014 0.000092 HAML50 COOKCHAR 0.000008 0.0001 HAML51 DEICER_F 0 0.0001 HAML52 RWC_MEDF 0 0.0001 HAML53 RWC_POCF 0 0.0001 HAML54 RWC_F222 0 0.0001 HAML55 RWC_ALON 0 0.0001 HAML56 RWC_COMP 0 0.0001 HAML57 RWB_COMP 0 0.0001 HAML58 0 0.0001 HAML59 0 0.0001 HAML60 0 0.000006 HAML61 0 0.000007 HAML62 0.000001 0.000003 HAML63 0.000002 0.000003 HAML64 0.000001 0.000002 ---PAGE BREAK--- 36 Butte PM2.5 Source Profiles, cont. PNO SID SIZE C12 MG C13 AL C14 SI C15 P HAML65 FINE 0 0.000213 0.000345 0.000043 0.000492 0.000035 0.000032 0.000077 HAML66 FINE 0.00002 0.000035 0.000124 0.000192 0.000246 0.000218 0.000013 0.000017 HAML67 RWCCOMP1 FINE 0 0.0001 0.00161 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 FINE 0.00002 0.00024 0.00002 0.00049 0.00021 0.00032 0 0.0001 HAML69 FINE 0.000113 0.0001 0.00011 0.0001 0.00034 0.0001 0.00004 0.0001 HAML70 FINE 0.000113 0.0001 0.000088 0.0001 0.000228 0.0001 0.000013 0.0001 HAML71 FINE 0.000182 0.0001 0.000124 0.0001 0.00034 0.0001 0.000025 0.0001 HAML72 GRAINDST FINE 0 0.0001 0 0.0001 0.15 0.0001 0 0.0001 HAML73 FINE 0.0024 0.00024 0.0428 0.0043 0.0844 0.00844 0.00017 0.00075 HAML74 FINE 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML75 SOILDUST FINE 0.02 0.007 0.18 0.01 0.48 0.02 0 0.0001 PNO SID C16 S C17 CL C19 K C20 CA C22 TI HAML65 0.003315 0.000041 0.002263 0.000092 0.02228 0.000127 0.000678 0.000105 0 0.000192 HAML66 0.001796 0.00132 0.001284 0.000889 0.009341 0.0113 0.000309 0.000325 0 0.0001 HAML67 RWCCOMP1 0.00596 0.0001 0.0038 0.0001 0.00865 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0.00098 0.00029 0.001 0.00029 0.00289 0.00127 0.00012 0.00013 0.00001 0.00054 HAML69 0.001815 0.0001 0.001973 0.0001 0.009671 0.0001 0.0001 0.0001 0 0.0001 HAML70 0.001808 0.0001 0.001973 0.0001 0.00865 0.0001 0.00017 0.0001 0 0.0001 HAML71 0.001398 0.0001 0.001284 0.0001 0.007021 0.0001 0.00017 0.0001 0 0.0001 HAML72 GRAINDST 0 0.0001 0 0.0001 0.0055 0.0001 0.0055 0.0001 0 0.0001 HAML73 0.068 0.014 0 0.0001 0.054 0.015 0.1 0.013 0.00298 0.00036 HAML74 0.1366 0.0001 0 0.0001 0.0055 0.0001 0.13 0.0001 0 0.0001 HAML75 SOILDUST 0.0024 0.0015 0 0.0001 0.02 0.001 0.018 0.001 0.0076 0.0006 PNO SID C23 V C24 CR C25 MN C26 FE C28 NI HAML65 0 0.000121 0 0.00004 0.000041 0.000006 0.000465 0.000009 0 0.000008 HAML66 0 0.0001 0 0.0001 0.000017 0.000021 0.000167 0.000259 0 0.0001 HAML67 RWCCOMP1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0 0.0001 0 0.0001 0.00001 0.00004 0.00015 0.0003 0 0.0001 HAML69 0 0.0001 0 0.0001 0 0.0001 0.00009 0.0001 0 0.0001 HAML70 0 0.0001 0 0.0001 0 0.0001 0.000057 0.0001 0 0.0001 HAML71 0 0.0001 0 0.0001 0 0.0001 0.00009 0.0001 0 0.0001 HAML72 GRAINDST 0 0.0001 0 0.0001 0 0.0001 0.0005 0.0001 0 0.0001 HAML73 0.0001 0.00002 0.00027 0.00024 0.00034 0.00019 0.0093 0.0014 0.00093 0.00096 HAML74 0 0.0001 0.0055 0.0001 0.0005 0.0001 0.0055 0.0001 0.0055 0.0001 HAML75 SOILDUST 0.0003 0.0002 0.0002 0.0002 0.0028 0.0003 0.085 0.005 0 0.0001 PNO SID C29 CU C30 ZN C31 GA C32 GE C33 AS HAML65 0.000013 0.000003 0.000397 0.000006 0 0.000021 0 0.0001 0 0.000021 HAML66 0.000004 0.000007 0.000301 0.000159 0 0.0001 0 0.0001 0 0.0001 HAML67 RWCCOMP1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0.00003 0.00007 0.00027 0.00034 0 0.0001 0 0.0001 0.00001 0.00006 HAML69 0 0.0001 0.00022 0.0001 0 0.0001 0 0.0001 0.000002 0.0001 HAML70 0 0.0001 0.000299 0.0001 0 0.0001 0 0.0001 5E-07 0.0001 HAML71 0.000004 0.0001 0.000299 0.0001 0 0.0001 0 0.0001 0.000001 0.0001 HAML72 GRAINDST 0.0005 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML73 0.00023 0.00004 0.00217 0.00022 0 0.0001 0 0.0001 0.00004 0.0001 HAML74 0.0005 0.0001 0.0005 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML75 SOILDUST 0.0005 0.0003 0 0.0001 0 0.0001 0 0.0001 0 0.0001 ---PAGE BREAK--- 37 Butte PM2.5 Source Profiles, cont. PNO SID C34 SE C35 BR C37 RB C38 SR C39 Y HAML65 0 0.00001 0.000006 0.000009 0.000012 0.000003 0.000006 0.000009 0 0.000011 HAML66 0 0.0001 0.000007 0.000004 0.000006 0.000005 0.000002 0.000003 0 0.0001 HAML67 RWCCOMP1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0 0.0001 0.00001 0.00003 0 0.0001 0 0.0001 0 0.0001 HAML69 0 0.0001 0.000024 0.0001 0.000006 0.0001 0 0.0001 0 0.0001 HAML70 0 0.0001 0.000017 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML71 0 0.0001 0.000024 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML72 GRAINDST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML73 0.0001 0.00003 0 0.0001 0.00075 0.00019 0.00032 0.00003 0 0.0001 HAML74 0.0005 0.0001 0 0.0001 0 0.0001 0.0005 0.0001 0 0.0001 HAML75 SOILDUST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 PNO SID C40 ZR C42 MO C46 PD C47 AG C48 CD HAML65 0 0.000013 0 0.000024 0 0.000064 0 0.000076 0.000004 0.000077 HAML66 0 0.0001 0 0.0001 0.000003 0.000006 0.000007 0.000012 0.000006 0.000007 HAML67 RWCCOMP1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0 0.0001 0.00001 0.00011 0 0.0001 0 0.0001 0 0.0001 HAML69 0 0.0001 0 0.0001 0.000001 0.0001 0.000007 0.0001 0.000007 0.0001 HAML70 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML71 0 0.0001 0 0.0001 0.000002 0.0001 7.5E-06 0.0001 1.35E-05 0.0001 HAML72 GRAINDST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML73 0 0.0001 0.00016 0.00015 0.00005 0.00009 0.00006 0.00004 0.00016 0.00015 HAML74 0 0.0001 0.0005 0.0001 0 0.0001 0 0.0001 0.0005 0.0001 HAML75 SOILDUST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 PNO SID C49 IN C50 SN C51 SB C56 BA C57 LA HAML65 0 0.000093 0.000021 0.00012 0 0.000141 0.000119 0.00051 0.000475 0.000676 HAML66 0 0.0001 0.000013 0.000011 0 0.0001 0.000063 0.00006 0.000235 0.000237 HAML67 RWCCOMP1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0 0.0001 0 0.0001 0 0.0001 0.00009 0.00171 0.00006 0.00192 HAML69 0 0.0001 0.00001 0.0001 0 0.0001 0 0.0001 0.00001 0.0001 HAML70 0 0.0001 0 0.0001 0 0.0001 1.35E-05 0.0001 0.000035 0.0001 HAML71 4.5E-06 0.0001 1.15E-05 0.0001 5.5E- 06 0.0001 0 0.0001 4.45E-05 0.0001 HAML72 GRAINDST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML73 0.00006 0.00008 0.00004 0.00004 0 0.0001 0.00034 0.00007 0.00024 0.00024 HAML74 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML75 SOILDUST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 PNO SID C80 HG C82 PB C200 TC C201 OC C202 EC HAML65 0 0.000021 0 0.000031 0.568513 0.031458 0.403634 0.020245 0.164879 0.024079 HAML66 0 0.0001 0 0.0001 0.637606 0.124509 0.513711 0.117216 0.123895 0.041988 HAML67 RWCCOMP1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0.00001 0.00012 0.00002 0.00011 0 0.0001 0.47132 0.06719 0.10772 0.04482 HAML69 0 0.0001 0.000006 0.0001 0 0.0001 0.528184 0.0001 0.055791 0.0001 HAML70 0 0.0001 0.000002 0.0001 0 0.0001 0.519406 0.0001 0.089044 0.0001 HAML71 0 0.0001 0.000006 0.0001 0 0.0001 0.528184 0.0001 0.064794 0.0001 HAML72 GRAINDST 0 0.0001 0 0.0001 0.3 0.0001 0 0.0001 0 0.0001 HAML73 0.00001 0.00001 0.0182 0.0028 0 0.0001 0.054 0.006 0.002 0.004 HAML74 0 0.0001 0.0005 0.0001 0.01 0.0001 0 0.0001 0 0.0001 HAML75 SOILDUST 0 0.0001 0.0008 0.0006 0 0.0001 0 0.0001 0 0.0001 ---PAGE BREAK--- 38 Butte PM2.5 Source Profiles, cont. PNO SID C203 SO4 C204 NO3 C205 NH4 C217 CL2 C219 K2 HAML65 0.011983 0.000371 0.00081 0.00018 0.001124 0.000188 0.003638 0.00018 0.026861 0.000214 HAML66 0.009139 0.003809 0.000735 0.000188 0.001271 0.0002 0.002577 0.001142 0.01397 0.011577 HAML67 RWCCOMP1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0.00487 0.00765 0.00244 0.00403 0.00186 0.00317 0.00214 0.00315 0.00773 0.0127 HAML69 0.0041 0.0001 0.0019 0.0001 0.0015 0.0001 0 0.0001 0 0.0001 HAML70 0.0041 0.0001 0.0018 0.0001 0.001136 0.0001 0 0.0001 0 0.0001 HAML71 0.001846 0.0001 0.0013 0.0001 0.001586 0.0001 0 0.0001 0 0.0001 HAML72 GRAINDST 0.0055 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML73 0.183 0.064 0.002 0.0004 0 0.0001 0 0.0001 0 0.0001 HAML74 0.41 0.0001 0.0005 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML75 SOILDUST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 PNO SID C300 F2 C301 NA2 C302 CA2 C303 MG2 C304 NA HAML65 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.000481 HAML66 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.000054 0.000093 HAML67 RWCCOMP1 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML68 RWCCOMP2 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.00042 0.00079 HAML69 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.00094 0.0001 HAML70 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.0009 0.0001 HAML71 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.0009 0.0001 HAML72 GRAINDST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML73 0.002 0.00028 0 0.0001 0 0.0001 0 0.0001 0.0229 0.0046 HAML74 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0 0.0001 HAML75 SOILDUST 0 0.0001 0 0.0001 0 0.0001 0 0.0001 0.01 0.002 PNO SID C305 CO HAML65 0 0.000012 HAML66 0 0.0001 HAML67 RWCCOMP1 0 0.0001 HAML68 RWCCOMP2 0.00001 0.00002 HAML69 0 0.0001 HAML70 0 0.0001 HAML71 0 0.0001 HAML72 GRAINDST 0 0.0001 HAML73 0.001 0.001 HAML74 0 0.0001 HAML75 SOILDUST 0 0.0001 ---PAGE BREAK--- 39 Appendix C: Butte CMB Final Outputs. ---PAGE BREAK--- 40 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 6/3/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 0.96 % MASS 96.2 CHI SQUARE 0.16 DEGREES FREEDOM 39 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML11 S04_FZER 0.22053 0.02914 7.56700 YES HAML13 NH4NO3F2 0.16484 0.03316 4.97096 YES HAML68 RWCCOMP2 1.59627 0.22018 7.24992 1.98163 MEASURED CONCENTRATION FOR SIZE: FINE 2.1+- 0.4 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 3 FOR MAX. UNC. = 0.41200 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.02914 0.03315 0.22018 NUMBER ESTIMABLE SOURCES = 3 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML11 1.0000 HAML13 1.0000 HAML68 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY ---PAGE BREAK--- 41 TMAC TMAU 2.06000+- 0.41000 1.98163+- 0.22313 0.96+- 0.22 -0.2 C12 MG * 0.00000< 0.00380 0.00003< 0.02206 0.00< 0.00 0.0 C13 AL * 0.01200+- 0.01000 0.00003+- 0.02207 0.00+- 1.84 -0.5 C14 SI * 0.03820+- 0.00610 0.00034+- 0.02206 0.01+- 0.58 -1.7 C15 P * 0.00000< 0.00450 0.00000< 0.02205 0.00< 0.00 0.0 C16 S * 0.07500+- 0.00640 0.07500+- 0.00729 1.00+- 0.13 0.0 C17 CL * 0.00000< 0.00210 0.00160< 0.02206 0.00< 0.00 0.1 C19 K * 0.00933+- 0.00190 0.00461+- 0.02215 0.49+- 2.38 -0.2 C20 CA * 0.00000< 0.00210 0.00019< 0.02205 0.00< 0.00 0.0 C22 TI * 0.00000< 0.00140 0.00002< 0.02207 0.00< 0.00 0.0 C23 V * 0.00000< 0.00100 0.00000< 0.02205 0.00< 0.00 0.0 C24 CR * 0.00000< 0.00072 0.00000< 0.02205 0.00< 0.00 0.0 C25 MN * 0.00000< 0.00059 0.00002< 0.02205 0.00< 0.00 0.0 C26 FE * 0.00821+- 0.00095 0.00024+- 0.02206 0.03+- 2.69 -0.4 C28 NI * 0.00000< 0.00038 0.00000< 0.02205 0.00< 0.00 0.0 C29 CU * 0.00000< 0.00045 0.00005< 0.02205 0.00< 0.00 0.0 C30 ZN * 0.00000< 0.00120 0.00043< 0.02206 0.00< 0.00 0.0 C31 GA * 0.00000< 0.00010 0.00000< 0.02205 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.02205 0.00< 0.00 0.0 C33 AS * 0.00000< 0.00062 0.00002< 0.02205 0.00< 0.00 0.0 C34 SE * 0.00000< 0.00066 0.00000< 0.02205 0.00< 0.00 0.0 C35 BR * 0.00058< 0.00084 0.00002< 0.02205 0.03< 38.02 0.0 C37 RB * 0.00000< 0.00059 0.00000< 0.02205 0.00< 0.00 0.0 C38 SR * 0.00000< 0.00076 0.00000< 0.02205 0.00< 0.00 0.0 C39 Y * 0.00000< 0.00010 0.00000< 0.02205 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00660 0.00000< 0.02205 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00002< 0.02205 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00000< 0.02205 0.00< 0.00 0.0 C47 AG * 0.00000< 0.00500 0.00000< 0.02205 0.00< 0.00 0.0 C48 CD * 0.00000< 0.00620 0.00000< 0.02205 0.00< 0.00 0.0 C49 IN * 0.00000< 0.00730 0.00000< 0.02205 0.00< 0.00 0.0 C50 SN * 0.00000< 0.01100 0.00000< 0.02205 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01400 0.00000< 0.02205 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00340 0.00014< 0.02222 0.00< 0.00 0.0 C57 LA * 0.00000< 0.00010 0.00010< 0.02226 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00002< 0.02205 0.00< 0.00 0.0 C82 PB * 0.00000< 0.00160 0.00003< 0.02205 0.00< 0.00 0.0 C200 TC 0.89500+- 0.00010 0.00000+- 0.02205 0.00+- 0.02 -40.6 C201 OC * 0.78200+- 0.00010 0.75235+- 0.10950 0.96+- 0.14 -0.3 C202 EC * 0.11300+- 0.00010 0.17195+- 0.07487 1.52+- 0.66 0.8 C203 SO4 0.16700+- 0.01600 0.00777+- 0.02521 0.05+- 0.15 -5.3 C204 NO3 * 0.14500+- 0.01300 0.13164+- 0.02385 0.91+- 0.18 -0.5 C205 NH4 * 0.00715+- 0.00140 0.04006+- 0.02293 5.60+- 3.39 1.4 C217 CL2 0.00000< 0.00010 0.00342< 0.02262 0.00< 0.00 0.2 C219 K2 0.00000< 0.00230 0.01234< 0.02996 0.00< 0.00 0.4 C300 F2 0.00000< 0.00010 0.00000< 0.00016 0.00< 0.00 0.0 C301 NA2 0.01490+- 0.00300 0.00000+- 0.00016 0.00+- 0.01 -5.0 C302 CA2 0.00000< 0.00010 0.00000< 0.00016 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00016 0.00< 0.00 0.0 C304 NA * 0.00000< 0.01300 0.00067< 0.00126 0.00< 0.00 0.1 C305 CO * 0.00000< 0.00038 0.00002< 0.00004 0.00< 0.00 0.0 ---PAGE BREAK--- 42 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 6/9/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 0.99 % MASS 92.8 CHI SQUARE 0.34 DEGREES FREEDOM 38 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML06 0.82227 0.17667 4.65416 YES HAML11 S04_FZER 0.32301 0.04870 6.63221 YES HAML13 NH4NO3F2 0.36767 0.04979 7.38506 YES HAML58 2.59733 0.09586 27.09500 4.11028 MEASURED CONCENTRATION FOR SIZE: FINE 4.4+- 0.4 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 4 FOR MAX. UNC. = 0.88600 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.04828 0.04979 0.09428 0.17764 NUMBER ESTIMABLE SOURCES = 4 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML06 1.0000 HAML11 1.0000 HAML13 1.0000 HAML58 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY ---PAGE BREAK--- 43 TMAC TMAU 4.43000+- 0.41000 4.11028+- 0.19513 0.93+- 0.10 -0.7 C12 MG * 0.00000< 0.00390 0.00691< 0.03235 0.00< 0.00 0.2 C13 AL * 0.05330+- 0.00980 0.06512+- 0.03443 1.22+- 0.68 0.3 C14 SI * 0.17600+- 0.01600 0.17662+- 0.03957 1.00+- 0.24 0.0 C15 P * 0.00000< 0.00530 0.00090< 0.03230 0.00< 0.00 0.0 C16 S * 0.15900+- 0.01200 0.15900+- 0.01075 1.00+- 0.10 0.0 C17 CL * 0.00012< 0.00260 0.02185< 0.03231 0.7 C19 K 0.03640+- 0.00300 0.21716+- 0.03234 5.97+- 1.02 5.6 C20 CA * 0.02580+- 0.00250 0.01875+- 0.03263 0.73+- 1.27 -0.2 C22 TI * 0.00372+- 0.00220 0.00312+- 0.03231 0.84+- 8.70 0.0 C23 V * 0.00000< 0.00130 0.00016< 0.03230 0.00< 0.00 0.0 C24 CR * 0.00150+- 0.00089 0.00033+- 0.03230 0.22+-21.53 0.0 C25 MN * 0.00042< 0.00087 0.00082< 0.03230 1.96< 77.02 0.0 C26 FE * 0.05290+- 0.00400 0.03001+- 0.03254 0.57+- 0.62 -0.7 C28 NI * 0.00000< 0.00040 0.00008< 0.03230 0.00< 0.00 0.0 C29 CU * 0.00411+- 0.00069 0.00082+- 0.03230 0.20+- 7.86 -0.1 C30 ZN * 0.00363+- 0.00071 0.00164+- 0.03230 0.45+- 8.90 -0.1 C31 GA * 0.00000< 0.00010 0.00000< 0.03230 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.03230 0.00< 0.00 0.0 C33 AS * 0.00000< 0.00060 0.00033< 0.03230 0.00< 0.00 0.0 C34 SE * 0.00000< 0.00063 0.00000< 0.03230 0.00< 0.00 0.0 C35 BR * 0.00044< 0.00091 0.00016< 0.03230 0.37< 73.42 0.0 C37 RB * 0.00000< 0.00065 0.00000< 0.03230 0.00< 0.00 0.0 C38 SR * 0.00000< 0.00840 0.00008< 0.03230 0.00< 0.00 0.0 C39 Y * 0.00000< 0.00010 0.00000< 0.03230 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00870 0.00000< 0.03230 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00000< 0.03230 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00000< 0.03230 0.00< 0.00 0.0 C47 AG * 0.00000< 0.00470 0.00000< 0.03230 0.00< 0.00 0.0 C48 CD * 0.00233< 0.01900 0.00025< 0.03230 0.11< 13.89 -0.1 C49 IN * 0.00000< 0.00530 0.00000< 0.03230 0.00< 0.00 0.0 C50 SN * 0.00000< 0.00890 0.00008< 0.03230 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01300 0.00016< 0.03230 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00360 0.00008< 0.03232 0.00< 0.00 0.0 C57 LA * 0.00000< 0.00010 0.00000< 0.03230 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00000< 0.03230 0.00< 0.00 0.0 C82 PB * 0.00000< 0.00130 0.00321< 0.03231 0.00< 0.00 0.1 C200 TC 1.17000+- 0.00010 0.00000+- 0.03230 0.00+- 0.03 -36.2 C201 OC * 0.94800+- 0.00010 0.95859+- 0.03458 1.01+- 0.04 0.3 C202 EC * 0.22500+- 0.00010 0.17009+- 0.03242 0.76+- 0.14 -1.7 C203 SO4 0.38800+- 0.03200 0.00058+- 0.03231 0.00+- 0.08 -8.5 C204 NO3 * 0.24800+- 0.02000 0.28503+- 0.03531 1.15+- 0.17 0.9 C205 NH4 * 0.18400+- 0.01400 0.08273+- 0.03335 0.45+- 0.18 -2.8 C217 CL2 0.00000< 0.00010 0.00000< 0.03230 0.00< 0.00 0.0 C219 K2 * 0.01180+- 0.00290 0.00000+- 0.03230 0.00+- 2.74 -0.4 C300 F2 0.00000< 0.00010 0.00000< 0.00028 0.00< 0.00 0.0 C301 NA2 0.02240+- 0.00350 0.00000+- 0.00028 0.00+- 0.01 -6.4 C302 CA2 0.00000< 0.00010 0.00000< 0.00028 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00028 0.00< 0.00 0.0 C304 NA * 0.00000< 0.01000 0.00000< 0.00028 0.00< 0.00 0.0 C305 CO * 0.00000< 0.00045 0.00000< 0.00028 0.00< 0.00 0.0 ---PAGE BREAK--- 44 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 6/15/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 1.00 % MASS 101.9 CHI SQUARE 0.23 DEGREES FREEDOM 38 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML10 UNDST_HE 0.20769 0.03913 5.30700 YES HAML11 S04_FZER 0.10663 0.02715 3.92808 YES HAML13 NH4NO3F2 0.35121 0.03544 9.91062 YES HAML58 3.53442 0.02925 120.84122 4.19994 MEASURED CONCENTRATION FOR SIZE: FINE 4.1+- 0.4 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 4 FOR MAX. UNC. = 0.82400 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.02684 0.02952 0.03544 0.03914 NUMBER ESTIMABLE SOURCES = 4 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML10 1.0000 HAML11 1.0000 HAML13 1.0000 HAML58 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY ---PAGE BREAK--- 45 TMAC TMAU 4.12000+- 0.41000 4.19994+- 0.06518 1.02+- 0.10 0.2 C12 MG * 0.00000< 0.00380 0.00000< 0.01067 0.00< 0.00 0.0 C13 AL * 0.04900+- 0.01300 0.02771+- 0.01102 0.57+- 0.27 -1.2 C14 SI * 0.07020+- 0.00880 0.07772+- 0.01320 1.11+- 0.23 0.5 C15 P * 0.00000< 0.00620 0.00046< 0.01067 0.00< 0.00 0.0 C16 S * 0.10000+- 0.00830 0.10000+- 0.00354 1.00+- 0.09 0.0 C17 CL * 0.00128< 0.00270 0.02865< 0.01067 22.38< 47.94 2.5 C19 K 0.01910+- 0.00270 0.28635+- 0.01067 14.99+- 2.19 24.3 C20 CA * 0.01340+- 0.00280 0.01286+- 0.01075 0.96+- 0.83 0.0 C22 TI * 0.00000< 0.00150 0.00154< 0.01067 0.00< 0.00 0.1 C23 V * 0.00000< 0.00120 0.00008< 0.01067 0.00< 0.00 0.0 C24 CR * 0.00173+- 0.00089 0.00004+- 0.01067 0.02+- 6.17 -0.2 C25 MN * 0.00000< 0.00070 0.00010< 0.01067 0.00< 0.00 0.0 C26 FE * 0.01290+- 0.00130 0.00486+- 0.01068 0.38+- 0.83 -0.7 C28 NI * 0.00000< 0.00038 0.00000< 0.01067 0.00< 0.00 0.0 C29 CU * 0.00264+- 0.00068 0.00002+- 0.01067 0.01+- 4.04 -0.2 C30 ZN * 0.00000< 0.00120 0.00006< 0.01067 0.00< 0.00 0.0 C31 GA * 0.00000< 0.00010 0.00000< 0.01067 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.01067 0.00< 0.00 0.0 C33 AS * 0.00016< 0.00095 0.00000< 0.01067 0.00< 66.68 0.0 C34 SE * 0.00000< 0.00066 0.00000< 0.01067 0.00< 0.00 0.0 C35 BR * 0.00021< 0.00110 0.00000< 0.01067 0.00< 50.80 0.0 C37 RB * 0.00000< 0.00058 0.00000< 0.01067 0.00< 0.00 0.0 C38 SR * 0.00070< 0.00130 0.00006< 0.01067 0.09< 15.24 -0.1 C39 Y * 0.00000< 0.00010 0.00000< 0.01067 0.00< 0.00 0.0 C40 ZR * 0.00349< 0.01000 0.00000< 0.01067 0.00< 3.06 -0.2 C42 MO * 0.00000< 0.00010 0.00000< 0.01067 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00010< 0.01067 0.00< 0.00 0.0 C47 AG * 0.00000< 0.00500 0.00000< 0.01067 0.00< 0.00 0.0 C48 CD * 0.00000< 0.00620 0.00000< 0.01067 0.00< 0.00 0.0 C49 IN * 0.00000< 0.00730 0.00000< 0.01067 0.00< 0.00 0.0 C50 SN * 0.00000< 0.01100 0.00000< 0.01067 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01400 0.00006< 0.01067 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00370 0.00066< 0.01068 0.00< 0.00 0.1 C57 LA * 0.00000< 0.00010 0.00000< 0.01067 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00000< 0.01067 0.00< 0.00 0.0 C82 PB * 0.00000< 0.00160 0.00008< 0.01067 0.00< 0.00 0.0 C200 TC 1.49000+- 0.00010 0.00000+- 0.01067 0.00+- 0.01 -139.7 C201 OC * 1.27000+- 0.00010 1.26886+- 0.01067 1.00+- 0.01 -0.1 C202 EC * 0.22300+- 0.00010 0.22620+- 0.01067 1.01+- 0.05 0.3 C203 SO4 0.24700+- 0.01800 0.00000+- 0.01067 0.00+- 0.04 -11.8 C204 NO3 * 0.27500+- 0.02500 0.27219+- 0.01731 0.99+- 0.11 -0.1 C205 NH4 * 0.07540+- 0.01300 0.07902+- 0.01328 1.05+- 0.25 0.2 C217 CL2 0.00000< 0.00010 0.00000< 0.01067 0.00< 0.00 0.0 C219 K2 * 0.00000< 0.00790 0.00000< 0.01067 0.00< 0.00 0.0 C300 F2 0.00000< 0.00010 0.00000< 0.00036 0.00< 0.00 0.0 C301 NA2 0.02730+- 0.00530 0.00000+- 0.00036 0.00+- 0.01 -5.1 C302 CA2 0.00000< 0.00010 0.00000< 0.00036 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00036 0.00< 0.00 0.0 C304 NA * 0.00117< 0.01300 0.00000< 0.00036 0.00< 0.30 -0.1 C305 CO * 0.00000< 0.00048 0.00000< 0.00036 0.00< 0.00 0.0 ---PAGE BREAK--- 46 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 6/21/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 1.00 % MASS 102.8 CHI SQUARE 0.27 DEGREES FREEDOM 37 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML10 UNDST_HE 0.30489 0.06198 4.91909 YES HAML11 S04_FZER 0.20177 0.02635 7.65651 YES HAML13 NH4NO3F2 0.27823 0.03885 7.16180 YES HAML20 LDV_WCAT 0.27436 0.11903 2.30488 YES HAML59 2.33153 0.16810 13.86962 3.39077 MEASURED CONCENTRATION FOR SIZE: FINE 3.3+- 0.4 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 5 FOR MAX. UNC. = 0.66000 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.02633 0.03024 0.03878 0.06199 0.20376 NUMBER ESTIMABLE SOURCES = 5 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML10 1.0000 HAML11 1.0000 HAML13 1.0000 HAML20 1.0000 HAML59 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL ---PAGE BREAK--- 47 SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY TMAC TMAU 3.30000+- 0.42000 3.39077+- 0.10214 1.03+- 0.13 0.2 C12 MG * 0.00000< 0.00390 0.00000< 0.02018 0.00< 0.00 0.0 C13 AL * 0.01720+- 0.00820 0.04086+- 0.02058 2.38+- 1.65 1.1 C14 SI * 0.12400+- 0.01100 0.11420+- 0.02318 0.92+- 0.20 -0.4 C15 P * 0.00000< 0.00530 0.00114< 0.02018 0.00< 0.00 0.1 C16 S * 0.07080+- 0.00570 0.07080+- 0.00666 1.00+- 0.12 0.0 C17 CL * 0.00315+- 0.00260 0.00960+- 0.02018 3.05+- 6.88 0.3 C19 K * 0.02380+- 0.00240 0.02859+- 0.02018 1.20+- 0.86 0.2 C20 CA * 0.01190+- 0.00250 0.01887+- 0.02027 1.59+- 1.74 0.3 C22 TI * 0.00117< 0.00210 0.00228< 0.02018 1.95< 17.60 0.1 C23 V * 0.00000< 0.00130 0.00012< 0.02018 0.00< 0.00 0.0 C24 CR * 0.00204+- 0.00097 0.00006+- 0.02018 0.03+- 9.89 -0.1 C25 MN * 0.00196+- 0.00070 0.00015+- 0.02018 0.08+-10.29 -0.1 C26 FE * 0.04630+- 0.00350 0.00755+- 0.02019 0.16+- 0.44 -1.9 C28 NI * 0.00000< 0.00040 0.00011< 0.02018 0.00< 0.00 0.0 C29 CU * 0.00671+- 0.00079 0.00310+- 0.02018 0.46+- 3.01 -0.2 C30 ZN * 0.00200+- 0.00065 0.00300+- 0.02018 1.50+-10.10 0.0 C31 GA * 0.00000< 0.00010 0.00000< 0.02018 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.02018 0.00< 0.00 0.0 C33 AS * 0.00000< 0.00061 0.00000< 0.02018 0.00< 0.00 0.0 C34 SE * 0.00000< 0.00063 0.00000< 0.02018 0.00< 0.00 0.0 C35 BR * 0.00056< 0.00090 0.00011< 0.02018 0.20< 36.03 0.0 C37 RB * 0.00000< 0.00065 0.00000< 0.02018 0.00< 0.00 0.0 C38 SR * 0.00000< 0.00840 0.00009< 0.02018 0.00< 0.00 0.0 C39 Y * 0.00000< 0.00010 0.00000< 0.02018 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00880 0.00000< 0.02018 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00000< 0.02018 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00015< 0.02018 0.00< 0.00 0.0 C47 AG * 0.01750+- 0.01500 0.00000+- 0.02018 0.00+- 1.15 -0.7 C48 CD * 0.01280< 0.01800 0.00000< 0.02018 0.00< 1.58 -0.5 C49 IN * 0.00000< 0.00530 0.00000< 0.02018 0.00< 0.00 0.0 C50 SN * 0.00000< 0.00890 0.00000< 0.02018 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01300 0.00009< 0.02018 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00360 0.00130< 0.02019 0.00< 0.00 0.1 C57 LA * 0.00000< 0.00010 0.00000< 0.02018 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00000< 0.02018 0.00< 0.00 0.0 C82 PB * 0.00000< 0.00130 0.00064< 0.02018 0.00< 0.00 0.0 C200 TC 1.21000+- 0.00010 0.00000+- 0.02018 0.00+- 0.02 -60.0 C201 OC * 1.04000+- 0.00010 1.03976+- 0.02018 1.00+- 0.02 0.0 C202 EC * 0.16600+- 0.00010 0.16692+- 0.02018 1.01+- 0.12 0.0 C203 SO4 0.12200+- 0.00950 0.00985+- 0.02018 0.08+- 0.17 -5.0 C204 NO3 * 0.24500+- 0.02300 0.22059+- 0.02288 0.90+- 0.13 -0.8 C205 NH4 * 0.01990+- 0.00940 0.06260+- 0.02113 3.15+- 1.83 1.8 C217 CL2 0.00000< 0.00010 0.00000< 0.02018 0.00< 0.00 0.0 C219 K2 0.00000< 0.00780 0.00000< 0.02018 0.00< 0.00 0.0 C300 F2 0.00000< 0.00010 0.00000< 0.00024 0.00< 0.00 0.0 C301 NA2 0.01500+- 0.00450 0.00000+- 0.00024 0.00+- 0.02 -3.3 C302 CA2 0.00000< 0.00010 0.00000< 0.00024 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00024 0.00< 0.00 0.0 C304 NA * 0.00000< 0.01000 0.00000< 0.00024 0.00< 0.00 0.0 C305 CO * 0.00000< 0.00045 0.00000< 0.00024 0.00< 0.00 0.0 ---PAGE BREAK--- 48 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 7/3/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 0.99 % MASS 89.4 CHI SQUARE 0.24 DEGREES FREEDOM 37 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML11 S04_FZER 1.16755 0.16770 6.96225 YES HAML13 NH4NO3F2 0.37990 0.14890 2.55137 YES HAML58 8.73367 0.32011 27.28357 10.28112 MEASURED CONCENTRATION FOR SIZE: FINE 11.5+- 0.6 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 3 FOR MAX. UNC. = 2.30000 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.14890 0.16647 0.32075 NUMBER ESTIMABLE SOURCES = 3 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML11 1.0000 HAML13 1.0000 HAML58 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY ---PAGE BREAK--- 49 TMAC TMAU 11.50000+- 0.63000 10.28112+- 0.37641 0.89+- 0.06 -1.7 C12 MG * 0.08730+- 0.00860 0.00000+- 0.11676 0.00+- 1.34 -0.7 C13 AL * 0.06000+- 0.01600 0.00000+- 0.11676 0.00+- 1.95 -0.5 C14 SI * 0.15400+- 0.01600 0.00000+- 0.11676 0.00+- 0.76 -1.3 C15 P * 0.00000< 0.00760 0.00000< 0.11676 0.00< 0.00 0.0 C16 S * 0.54600+- 0.04000 0.54600+- 0.03854 1.00+- 0.10 0.0 C17 CL * 0.13200+- 0.01000 0.06987+- 0.11676 0.53+- 0.89 -0.5 C19 K 1.53000+- 0.11000 0.69869+- 0.11676 0.46+- 0.08 -5.2 C20 CA * 0.03120+- 0.00390 0.00000+- 0.11676 0.00+- 3.74 -0.3 C22 TI * 0.00525+- 0.00240 0.00000+- 0.11676 0.00+-22.24 0.0 C23 V * 0.00070< 0.00150 0.00000< 0.11676 0.00< 0.0 C24 CR * 0.00000< 0.00072 0.00000< 0.11676 0.00< 0.00 0.0 C25 MN * 0.00237+- 0.00075 0.00000+- 0.11676 0.00+-49.27 0.0 C26 FE * 0.05140+- 0.00380 0.00000+- 0.11676 0.00+- 2.27 -0.4 C28 NI * 0.00000< 0.00038 0.00000< 0.11676 0.00< 0.00 0.0 C29 CU * 0.02750+- 0.00210 0.00000+- 0.11676 0.00+- 4.25 -0.2 C30 ZN * 0.00768+- 0.00120 0.00000+- 0.11676 0.00+-15.20 -0.1 C31 GA * 0.00000< 0.00010 0.00000< 0.11676 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.11676 0.00< 0.00 0.0 C33 AS * 0.00082< 0.00150 0.00000< 0.11676 0.00< 0.0 C34 SE * 0.00000< 0.00066 0.00000< 0.11676 0.00< 0.00 0.0 C35 BR * 0.00163+- 0.00110 0.00000+- 0.11676 0.00+-71.63 0.0 C37 RB * 0.00029< 0.00110 0.00000< 0.11676 0.00< 0.0 C38 SR * 0.02110+- 0.00250 0.00000+- 0.11676 0.00+- 5.53 -0.2 C39 Y * 0.00000< 0.00010 0.00000< 0.11676 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00660 0.00000< 0.11676 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00000< 0.11676 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00000< 0.11676 0.00< 0.00 0.0 C47 AG * 0.00116< 0.01500 0.00000< 0.11676 0.00< 0.0 C48 CD * 0.00000< 0.00620 0.00000< 0.11676 0.00< 0.00 0.0 C49 IN * 0.00000< 0.00730 0.00000< 0.11676 0.00< 0.00 0.0 C50 SN * 0.00000< 0.01100 0.00000< 0.11676 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01400 0.00000< 0.11676 0.00< 0.00 0.0 C56 BA * 0.05650+- 0.00590 0.00000+- 0.11676 0.00+- 2.07 -0.5 C57 LA * 0.00000< 0.00010 0.00000< 0.11676 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00000< 0.11676 0.00< 0.00 0.0 C82 PB * 0.00000< 0.00160 0.00000< 0.11676 0.00< 0.00 0.0 C200 TC 3.48000+- 0.00010 0.00000+- 0.11676 0.00+- 0.03 -29.8 C201 OC * 3.18000+- 0.00010 3.13539+- 0.11676 0.99+- 0.04 -0.4 C202 EC * 0.30100+- 0.00010 0.55896+- 0.11676 1.86+- 0.39 2.2 C203 SO4 1.53000+- 0.11000 0.00000+- 0.11676 0.00+- 0.08 -9.5 C204 NO3 * 0.27300+- 0.02500 0.29442+- 0.11768 1.08+- 0.44 0.2 C205 NH4 * 0.15700+- 0.01800 0.08548+- 0.11707 0.54+- 0.75 -0.6 C217 CL2 0.00000< 0.00010 0.00000< 0.11676 0.00< 0.00 0.0 C219 K2 1.44000+- 0.11000 0.00000+- 0.11676 0.00+- 0.08 -9.0 C300 F2 0.00000< 0.00010 0.00000< 0.00088 0.00< 0.00 0.0 C301 NA2 0.05270+- 0.00690 0.00000+- 0.00088 0.00+- 0.02 -7.6 C302 CA2 0.00000< 0.00010 0.00000< 0.00088 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00088 0.00< 0.00 0.0 C304 NA 0.03670+- 0.01300 0.00000+- 0.00088 0.00+- 0.02 -2.8 C305 CO * 0.00000< 0.00048 0.00000< 0.00088 0.00< 0.00 0.0 ---PAGE BREAK--- 50 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 7/9/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 1.00 % MASS 94.4 CHI SQUARE 0.15 DEGREES FREEDOM 38 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML01 ST_SANDF 0.48285 0.18364 2.62928 YES HAML11 S04_FZER 0.42362 0.05343 7.92808 YES HAML13 NH4NO3F2 0.26370 0.05836 4.51850 YES HAML59 3.89131 0.10875 35.78263 5.06148 MEASURED CONCENTRATION FOR SIZE: FINE 5.4+- 0.5 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 4 FOR MAX. UNC. = 1.07200 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.05343 0.05836 0.10867 0.18369 NUMBER ESTIMABLE SOURCES = 4 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML01 1.0000 HAML11 1.0000 HAML13 1.0000 HAML59 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY ---PAGE BREAK--- 51 TMAC TMAU 5.36000+- 0.47000 5.06148+- 0.22480 0.94+- 0.09 -0.6 C12 MG * 0.00000< 0.00390 0.00083< 0.04236 0.00< 0.00 0.0 C13 AL * 0.02640+- 0.00840 0.04180+- 0.04280 1.58+- 1.70 0.4 C14 SI * 0.11700+- 0.01100 0.10426+- 0.04495 0.89+- 0.39 -0.3 C15 P * 0.00000< 0.00530 0.00000< 0.04236 0.00< 0.00 0.0 C16 S * 0.14500+- 0.01100 0.14500+- 0.01398 1.00+- 0.12 0.0 C17 CL * 0.00315+- 0.00260 0.02870+- 0.04246 9.11+-15.43 0.6 C19 K * 0.03900+- 0.00320 0.05826+- 0.04244 1.49+- 1.10 0.5 C20 CA * 0.01910+- 0.00250 0.00797+- 0.04237 0.42+- 2.22 -0.3 C22 TI * 0.00151< 0.00200 0.00232< 0.04236 1.54< 28.13 0.0 C23 V * 0.00082< 0.00130 0.00000< 0.04236 0.00< 51.66 0.0 C24 CR * 0.00000< 0.00085 0.00006< 0.04236 0.00< 0.00 0.0 C25 MN * 0.00172+- 0.00088 0.00043+- 0.04236 0.25+-24.63 0.0 C26 FE * 0.04090+- 0.00310 0.02427+- 0.04238 0.59+- 1.04 -0.4 C28 NI * 0.00001< 0.00040 0.00004< 0.04236 3.67< 0.0 C29 CU * 0.00459+- 0.00068 0.00006+- 0.04236 0.01+- 9.23 -0.1 C30 ZN * 0.00177+- 0.00062 0.00006+- 0.04236 0.03+-23.93 0.0 C31 GA * 0.00000< 0.00010 0.00000< 0.04236 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.04236 0.00< 0.00 0.0 C33 AS * 0.00000< 0.00061 0.00002< 0.04236 0.00< 0.00 0.0 C34 SE * 0.00064< 0.00085 0.00000< 0.04236 0.00< 66.19 0.0 C35 BR * 0.00089< 0.00098 0.00001< 0.04236 0.01< 47.60 0.0 C37 RB * 0.00000< 0.00065 0.00008< 0.04236 0.00< 0.00 0.0 C38 SR * 0.00000< 0.00840 0.00004< 0.04236 0.00< 0.00 0.0 C39 Y * 0.00000< 0.00010 0.00000< 0.04236 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00880 0.00000< 0.04236 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00000< 0.04236 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00000< 0.04236 0.00< 0.00 0.0 C47 AG * 0.00000< 0.00470 0.00000< 0.04236 0.00< 0.00 0.0 C48 CD * 0.01050< 0.01900 0.00000< 0.04236 0.00< 4.03 -0.2 C49 IN * 0.00000< 0.00530 0.00000< 0.04236 0.00< 0.00 0.0 C50 SN * 0.00000< 0.00890 0.00000< 0.04236 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01300 0.00000< 0.04236 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00360 0.00105< 0.04237 0.00< 0.00 0.0 C57 LA * 0.00000< 0.00010 0.00000< 0.04237 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00000< 0.04236 0.00< 0.00 0.0 C82 PB * 0.00000< 0.00130 0.00000< 0.04236 0.00< 0.00 0.0 C200 TC 1.68000+- 0.00010 0.00279+- 0.04237 0.00+- 0.03 -39.6 C201 OC * 1.51000+- 0.00010 1.50873+- 0.04236 1.00+- 0.03 0.0 C202 EC * 0.16900+- 0.00010 0.17511+- 0.04237 1.04+- 0.25 0.1 C203 SO4 0.34200+- 0.02500 0.00159+- 0.04236 0.00+- 0.12 -6.9 C204 NO3 * 0.17600+- 0.01800 0.20437+- 0.04359 1.16+- 0.27 0.6 C205 NH4 * 0.15400+- 0.01800 0.05933+- 0.04278 0.39+- 0.28 -2.0 C217 CL2 0.00000< 0.00010 0.02412< 0.04245 0.00< 0.00 0.6 C219 K2 0.00000< 0.00780 0.00212< 0.04236 0.00< 0.00 0.0 C300 F2 0.00000< 0.00010 0.00000< 0.00040 0.00< 0.00 0.0 C301 NA2 0.03450+- 0.00570 0.00000+- 0.00040 0.00+- 0.01 -6.0 C302 CA2 0.00000< 0.00010 0.00000< 0.00040 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00040 0.00< 0.00 0.0 C304 NA * 0.00000< 0.01000 0.00000< 0.00040 0.00< 0.00 0.0 C305 CO * 0.00014< 0.00051 0.00000< 0.00040 0.00< 2.82 -0.2 ---PAGE BREAK--- 52 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 7/15/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 0.96 % MASS 101.1 CHI SQUARE 0.18 DEGREES FREEDOM 38 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML06 1.29970 0.29344 4.42918 YES HAML11 S04_FZER 0.56132 0.07215 7.78042 YES HAML13 NH4NO3F2 0.32568 0.07708 4.22548 YES HAML68 RWCCOMP2 3.74711 0.52074 7.19573 5.93381 MEASURED CONCENTRATION FOR SIZE: FINE 5.9+- 0.4 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 4 FOR MAX. UNC. = 1.17400 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.07195 0.07705 0.29314 0.52094 NUMBER ESTIMABLE SOURCES = 4 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML06 1.0000 HAML11 1.0000 HAML13 1.0000 HAML68 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY ---PAGE BREAK--- 53 TMAC TMAU 5.87000+- 0.41000 5.93381+- 0.59156 1.01+- 0.12 0.1 C12 MG * 0.00481< 0.00600 0.01099< 0.05621 2.29< 12.03 0.1 C13 AL * 0.08530+- 0.01200 0.10301+- 0.05924 1.21+- 0.71 0.3 C14 SI * 0.27100+- 0.02300 0.27996+- 0.06677 1.03+- 0.26 0.1 C15 P * 0.00000< 0.00350 0.00143< 0.05614 0.00< 0.00 0.0 C16 S * 0.19800+- 0.01500 0.19800+- 0.01869 1.00+- 0.12 0.0 C17 CL * 0.02240+- 0.00270 0.00544+- 0.05615 0.24+- 2.51 -0.3 C19 K * 0.04980+- 0.00390 0.02565+- 0.05639 0.51+- 1.13 -0.4 C20 CA * 0.05890+- 0.00460 0.03008+- 0.05660 0.51+- 0.96 -0.5 C22 TI * 0.00535+- 0.00210 0.00498+- 0.05618 0.93+-10.51 0.0 C23 V * 0.00000< 0.00110 0.00026< 0.05613 0.00< 0.00 0.0 C24 CR * 0.00099+- 0.00085 0.00052+- 0.05613 0.53+-56.70 0.0 C25 MN * 0.00000< 0.00054 0.00134< 0.05613 0.00< 0.00 0.0 C26 FE * 0.09020+- 0.00660 0.04800+- 0.05649 0.53+- 0.63 -0.7 C28 NI * 0.00000< 0.00056 0.00013< 0.05613 0.00< 0.00 0.0 C29 CU * 0.02410+- 0.00200 0.00141+- 0.05613 0.06+- 2.33 -0.4 C30 ZN * 0.00243+- 0.00086 0.00361+- 0.05615 1.49+-23.11 0.0 C31 GA * 0.00000< 0.00010 0.00000< 0.05613 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.05613 0.00< 0.00 0.0 C33 AS * 0.00105< 0.00130 0.00056< 0.05613 0.53< 53.46 0.0 C34 SE * 0.00000< 0.00087 0.00000< 0.05613 0.00< 0.00 0.0 C35 BR * 0.00195+- 0.00092 0.00030+- 0.05613 0.15+-28.79 0.0 C37 RB * 0.00000< 0.00047 0.00000< 0.05613 0.00< 0.00 0.0 C38 SR * 0.00175+- 0.00130 0.00013+- 0.05613 0.07+-32.08 0.0 C39 Y * 0.00000< 0.00010 0.00000< 0.05613 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00970 0.00000< 0.05613 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00004< 0.05613 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00000< 0.05613 0.00< 0.00 0.0 C47 AG * 0.00000< 0.00680 0.00000< 0.05613 0.00< 0.00 0.0 C48 CD * 0.01160< 0.02000 0.00039< 0.05613 0.03< 4.84 -0.2 C49 IN * 0.00000< 0.00750 0.00000< 0.05613 0.00< 0.00 0.0 C50 SN * 0.00000< 0.00960 0.00013< 0.05613 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01300 0.00026< 0.05614 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00340 0.00047< 0.05652 0.00< 0.00 0.0 C57 LA * 0.00000< 0.00010 0.00022< 0.05659 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00004< 0.05613 0.00< 0.00 0.0 C82 PB * 0.00070< 0.00240 0.00514< 0.05615 7.35< 84.08 0.1 C200 TC 2.10000+- 0.00010 0.00000+- 0.05613 0.00+- 0.03 -37.4 C201 OC * 1.90000+- 0.00010 1.80742+- 0.25869 0.95+- 0.14 -0.4 C202 EC * 0.19900+- 0.00010 0.40975+- 0.17713 2.06+- 0.89 1.2 C203 SO4 0.37400+- 0.03100 0.01916+- 0.06304 0.05+- 0.17 -5.1 C204 NO3 * 0.22600+- 0.01900 0.26167+- 0.05949 1.16+- 0.28 0.6 C205 NH4 * 0.19100+- 0.01300 0.08025+- 0.05784 0.42+- 0.30 -1.9 C217 CL2 0.00000< 0.00010 0.00802< 0.05736 0.00< 0.00 0.1 C219 K2 0.00000< 0.00100 0.02897< 0.07359 0.00< 0.00 0.4 C300 F2 0.00000< 0.00010 0.00000< 0.00040 0.00< 0.00 0.0 C301 NA2 0.08040+- 0.06600 0.00000+- 0.00040 0.00+- 0.00 -1.2 C302 CA2 0.00000< 0.00010 0.00000< 0.00040 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00040 0.00< 0.00 0.0 C304 NA * 0.00000< 0.01800 0.00157< 0.00296 0.00< 0.00 0.1 C305 CO * 0.00035< 0.00063 0.00004< 0.00016 0.11< 0.51 -0.5 ---PAGE BREAK--- 54 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 7/21/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 1.00 % MASS 102.1 CHI SQUARE 0.15 DEGREES FREEDOM 37 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML10 UNDST_HE 0.40168 0.08976 4.47492 YES HAML11 S04_FZER 0.29195 0.05000 5.83858 YES HAML13 NH4NO3F2 0.32793 0.07366 4.45214 YES HAML15 LDV_XPBF 0.45567 0.14375 3.16983 YES HAML59 5.26120 0.24304 21.64721 6.73844 MEASURED CONCENTRATION FOR SIZE: FINE 6.6+- 0.5 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 5 FOR MAX. UNC. = 1.32000 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.04781 0.07248 0.07366 0.08938 0.27343 NUMBER ESTIMABLE SOURCES = 5 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML10 1.0000 HAML11 1.0000 HAML13 1.0000 HAML15 1.0000 HAML59 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL ---PAGE BREAK--- 55 SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY TMAC TMAU 6.60000+- 0.50000 6.73844+- 0.20225 1.02+- 0.08 0.3 C12 MG * 0.00000< 0.00390 0.00000< 0.05412 0.00< 0.00 0.0 C13 AL * 0.03700+- 0.00880 0.05677+- 0.02971 1.53+- 0.88 0.6 C14 SI * 0.16700+- 0.01500 0.16592+- 0.03380 0.99+- 0.22 0.0 C15 P * 0.00000< 0.00530 0.00289< 0.02921 0.00< 0.00 0.1 C16 S * 0.11900+- 0.00890 0.11900+- 0.01335 1.00+- 0.13 0.0 C17 CL * 0.00082< 0.00260 0.00628< 0.02920 7.66< 43.11 0.2 C19 K * 0.06490+- 0.00490 0.05961+- 0.02921 0.92+- 0.46 -0.2 C20 CA * 0.04220+- 0.00340 0.02726+- 0.02931 0.65+- 0.70 -0.5 C22 TI * 0.00163< 0.00200 0.00299< 0.02920 1.83< 18.06 0.0 C23 V * 0.00000< 0.00130 0.00026< 0.02920 0.00< 0.00 0.0 C24 CR * 0.00230+- 0.00094 0.00010+- 0.02920 0.04+-12.70 -0.1 C25 MN * 0.00122+- 0.00088 0.00022+- 0.02920 0.18+-23.93 0.0 C26 FE * 0.06050+- 0.00450 0.01132+- 0.02922 0.19+- 0.48 -1.7 C28 NI * 0.00000< 0.00040 0.00000< 0.05412 0.00< 0.00 0.0 C29 CU * 0.00974+- 0.00093 0.00018+- 0.02920 0.02+- 3.00 -0.3 C30 ZN * 0.00241+- 0.00061 0.00282+- 0.02922 1.17+-12.13 0.0 C31 GA * 0.00000< 0.00010 0.00000< 0.02920 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.05412 0.00< 0.00 0.0 C33 AS * 0.00049< 0.00077 0.00000< 0.05412 0.00< 0.0 C34 SE * 0.00000< 0.00063 0.00000< 0.05412 0.00< 0.00 0.0 C35 BR * 0.00082< 0.00091 0.00113< 0.02920 1.38< 35.65 0.0 C37 RB * 0.00000< 0.00066 0.00000< 0.05412 0.00< 0.00 0.0 C38 SR * 0.00000< 0.00840 0.00012< 0.05412 0.00< 0.00 0.0 C39 Y * 0.00000< 0.00010 0.00000< 0.05412 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00880 0.00000< 0.05412 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00000< 0.05412 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00020< 0.05412 0.00< 0.00 0.0 C47 AG * 0.00000< 0.00470 0.00000< 0.05412 0.00< 0.00 0.0 C48 CD * 0.00000< 0.00570 0.00000< 0.05412 0.00< 0.00 0.0 C49 IN * 0.00000< 0.00530 0.00000< 0.05412 0.00< 0.00 0.0 C50 SN * 0.00000< 0.00890 0.00000< 0.05412 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01300 0.00012< 0.05412 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00360 0.00129< 0.05413 0.00< 0.00 0.0 C57 LA * 0.00000< 0.00010 0.00000< 0.05412 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00000< 0.02920 0.00< 0.00 0.0 C82 PB * 0.00000< 0.00130 0.00182< 0.02921 0.00< 0.00 0.1 C200 TC 2.67000+- 0.00010 0.40022+- 0.06518 0.15+- 0.02 -34.8 C201 OC * 2.26000+- 0.00010 2.26028+- 0.05371 1.00+- 0.02 0.0 C202 EC * 0.41200+- 0.00010 0.41278+- 0.04708 1.00+- 0.11 0.0 C203 SO4 0.32200+- 0.02400 0.00000+- 0.05412 0.00+- 0.17 -5.4 C204 NO3 * 0.22900+- 0.02200 0.25415+- 0.05560 1.11+- 0.27 0.4 C205 NH4 * 0.14900+- 0.01100 0.07378+- 0.05462 0.50+- 0.37 -1.3 C217 CL2 0.00000< 0.00010 0.00000< 0.05412 0.00< 0.00 0.0 C219 K2 0.03030+- 0.00300 0.00000+- 0.05412 0.00+- 1.79 -0.6 C300 F2 0.00000< 0.00010 0.00000< 0.00053 0.00< 0.00 0.0 C301 NA2 0.02830< 0.06300 0.00000< 0.00053 0.00< 0.02 -0.4 C302 CA2 0.00000< 0.00010 0.00000< 0.00053 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00053 0.00< 0.00 0.0 C304 NA * 0.00000< 0.01000 0.00000< 0.00053 0.00< 0.00 0.0 C305 CO * 0.00000< 0.00045 0.00000< 0.00053 0.00< 0.00 0.0 ---PAGE BREAK--- 56 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 8/26/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 0.99 % MASS 93.9 CHI SQUARE 0.11 DEGREES FREEDOM 38 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML06 2.07228 0.38404 5.39604 YES HAML11 S04_FZER 0.65627 0.08362 7.84849 YES HAML13 NH4NO3F2 0.36589 0.08713 4.19933 YES HAML59 4.64975 0.18880 24.62806 7.74419 MEASURED CONCENTRATION FOR SIZE: FINE 8.2+- 0.6 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 4 FOR MAX. UNC. = 1.65000 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.08335 0.08713 0.18523 0.38583 NUMBER ESTIMABLE SOURCES = 4 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML06 1.0000 HAML11 1.0000 HAML13 1.0000 HAML59 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY ---PAGE BREAK--- 57 TMAC TMAU 8.25000+- 0.56000 7.74419+- 0.41027 0.94+- 0.08 -0.7 C12 MG * 0.00000< 0.00390 0.01741< 0.06577 0.00< 0.00 0.3 C13 AL * 0.14600+- 0.01600 0.16412+- 0.07218 1.12+- 0.51 0.2 C14 SI * 0.42500+- 0.03600 0.44513+- 0.08733 1.05+- 0.22 0.2 C15 P * 0.00000< 0.00530 0.00228< 0.06563 0.00< 0.00 0.0 C16 S * 0.23500+- 0.01700 0.23500+- 0.02195 1.00+- 0.12 0.0 C17 CL * 0.00479+- 0.00260 0.00734+- 0.06564 1.53+-13.73 0.0 C19 K * 0.09730+- 0.00720 0.07012+- 0.06576 0.72+- 0.68 -0.4 C20 CA * 0.10200+- 0.00750 0.04725+- 0.06665 0.46+- 0.65 -0.8 C22 TI * 0.00606+- 0.00230 0.00787+- 0.06564 1.30+-10.84 0.0 C23 V * 0.00128< 0.00140 0.00041< 0.06563 0.32< 51.27 0.0 C24 CR * 0.00190+- 0.00092 0.00083+- 0.06563 0.44+-34.54 0.0 C25 MN * 0.00382+- 0.00080 0.00207+- 0.06563 0.54+-17.18 0.0 C26 FE * 0.12700+- 0.00920 0.07564+- 0.06638 0.60+- 0.52 -0.8 C28 NI * 0.00000< 0.00040 0.00021< 0.06563 0.00< 0.00 0.0 C29 CU * 0.02310+- 0.00180 0.00207+- 0.06563 0.09+- 2.84 -0.3 C30 ZN * 0.00635+- 0.00082 0.00414+- 0.06564 0.65+-10.34 0.0 C31 GA * 0.00000< 0.00010 0.00000< 0.06563 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.06563 0.00< 0.00 0.0 C33 AS * 0.00000< 0.00061 0.00083< 0.06563 0.00< 0.00 0.0 C34 SE * 0.00000< 0.00063 0.00000< 0.06563 0.00< 0.00 0.0 C35 BR * 0.00266+- 0.00100 0.00041+- 0.06563 0.16+-24.67 0.0 C37 RB * 0.00000< 0.00065 0.00000< 0.06563 0.00< 0.00 0.0 C38 SR * 0.00000< 0.00840 0.00021< 0.06563 0.00< 0.00 0.0 C39 Y * 0.00000< 0.00010 0.00000< 0.06563 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00880 0.00000< 0.06563 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00000< 0.06563 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00000< 0.06563 0.00< 0.00 0.0 C47 AG * 0.00000< 0.00470 0.00000< 0.06563 0.00< 0.00 0.0 C48 CD * 0.00000< 0.00570 0.00062< 0.06563 0.00< 0.00 0.0 C49 IN * 0.00000< 0.00530 0.00000< 0.06563 0.00< 0.00 0.0 C50 SN * 0.00816< 0.03300 0.00021< 0.06563 0.03< 8.04 -0.1 C51 SB * 0.00000< 0.01300 0.00041< 0.06564 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00360 0.00021< 0.06568 0.00< 0.00 0.0 C57 LA * 0.00000< 0.00010 0.00000< 0.06563 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00000< 0.06563 0.00< 0.00 0.0 C82 PB * 0.00000< 0.00130 0.00808< 0.06566 0.00< 0.00 0.1 C200 TC 2.17000+- 0.00010 0.00000+- 0.06563 0.00+- 0.03 -33.1 C201 OC * 1.85000+- 0.00010 1.86535+- 0.07262 1.01+- 0.04 0.2 C202 EC * 0.32200+- 0.00010 0.21898+- 0.06598 0.68+- 0.20 -1.6 C203 SO4 0.57300+- 0.04500 0.00145+- 0.06567 0.00+- 0.11 -7.2 C204 NO3 * 0.27800+- 0.02200 0.28378+- 0.06715 1.02+- 0.25 0.1 C205 NH4 * 0.10000+- 0.00780 0.08233+- 0.06614 0.82+- 0.66 -0.3 C217 CL2 0.00000< 0.00010 0.00000< 0.06563 0.00< 0.00 0.0 C219 K2 0.03420+- 0.00430 0.00000+- 0.06563 0.00+- 1.92 -0.5 C300 F2 0.00000< 0.00010 0.00000< 0.00051 0.00< 0.00 0.0 C301 NA2 0.06400+- 0.00620 0.00000+- 0.00051 0.00+- 0.01 -10.3 C302 CA2 0.00000< 0.00010 0.00000< 0.00051 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00051 0.00< 0.00 0.0 C304 NA * 0.00000< 0.01100 0.00000< 0.00051 0.00< 0.00 0.0 C305 CO * 0.00000< 0.00059 0.00000< 0.00051 0.00< 0.00 0.0 ---PAGE BREAK--- 58 Chemical Mass Balance Version EPA-CMB8.2 Report Date: 12/16/2013 SAMPLE: OPTIONS: INPUT FILES: SITE: BUTTE BRITT & LUECKE: No INBUTTE5.IN8 SAMPLE DATE: 9/7/13 SOURCE ELIMINATION: No SOBUTTE5.SEL DURATION: 24 BEST FIT: No POBUTTE5.SEL START HOUR: 0 DSBUTTE5.SEL SIZE: FINE ADBUTTE5.txt PRBUTTE5.csv Species Array: 1 Sources Array: 1 FITTING STATISTICS: R SQUARE 0.94 % MASS 101.4 CHI SQUARE 0.81 DEGREES FREEDOM 38 SOURCE CONTRIBUTION ESTIMATES: SOURCE EST CODE NAME SCE(µg/m³) Std Err Tstat YES HAML06 0.80264 0.25360 3.16495 YES HAML11 S04_FZER 0.53376 0.06977 7.64987 YES HAML13 NH4NO3F2 0.32421 0.07330 4.42334 YES HAML65 5.03301 0.26896 18.71276 6.69362 MEASURED CONCENTRATION FOR SIZE: FINE 6.6+- 0.5 Eligible Space Collinearity Display ELIGIBLE SPACE DIM. = 4 FOR MAX. UNC. = 1.32000 (20.% OF TOTAL MEAS. MASS) 1 / Singular Value 0.06958 0.07329 0.24843 0.27380 NUMBER ESTIMABLE SOURCES = 4 FOR MIN. PROJ. = 0.95 PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE PROJ. SOURCE 1.0000 HAML06 1.0000 HAML11 1.0000 HAML13 1.0000 HAML65 ESTIMABLE LINEAR COMBINATIONS OF INESTIMABLE SOURCES COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE COEFF. SOURCE SCE Std Err SPECIES CONCENTRATIONS: CALCULATED RESIDUAL SPECIES FIT MEASURED CALCULATED MEASURED UNCERTAINTY ---PAGE BREAK--- 59 TMAC TMAU 6.60000+- 0.50000 6.69362+- 0.36437 1.01+- 0.09 0.2 C12 MG * 0.00458+- 0.00450 0.00674+- 0.05341 1.47+-11.75 0.0 C13 AL * 0.03970+- 0.01000 0.06531+- 0.05463 1.64+- 1.44 0.5 C14 SI * 0.17900+- 0.01600 0.17488+- 0.05785 0.98+- 0.33 -0.1 C15 P * 0.00000< 0.00360 0.00104< 0.05338 0.00< 0.00 0.0 C16 S * 0.19900+- 0.01500 0.19900+- 0.01767 1.00+- 0.12 0.0 C17 CL * 0.00047< 0.00170 0.01243< 0.05338 26.45< 0.2 C19 K * 0.04460+- 0.00350 0.12129+- 0.05340 2.72+- 1.22 1.4 C20 CA * 0.04680+- 0.00370 0.02171+- 0.05357 0.46+- 1.15 -0.5 C22 TI * 0.00047< 0.00190 0.00305< 0.05339 6.49< 0.0 C23 V * 0.00150+- 0.00110 0.00016+- 0.05338 0.11+-35.59 0.0 C24 CR * 0.00141+- 0.00081 0.00032+- 0.05338 0.23+-37.86 0.0 C25 MN * 0.00167+- 0.00064 0.00101+- 0.05338 0.60+-31.96 0.0 C26 FE * 0.04720+- 0.00350 0.03164+- 0.05351 0.67+- 1.13 -0.3 C28 NI * 0.00000< 0.00041 0.00008< 0.05338 0.00< 0.00 0.0 C29 CU * 0.00268+- 0.00069 0.00087+- 0.05338 0.32+-19.92 0.0 C30 ZN * 0.00342+- 0.00074 0.00360+- 0.05338 1.05+-15.61 0.0 C31 GA * 0.00000< 0.00010 0.00000< 0.05338 0.00< 0.00 0.0 C32 GE * 0.00000< 0.00010 0.00000< 0.05338 0.00< 0.00 0.0 C33 AS * 0.00070< 0.00130 0.00032< 0.05338 0.46< 76.26 0.0 C34 SE * 0.00000< 0.00082 0.00000< 0.05338 0.00< 0.00 0.0 C35 BR * 0.00227+- 0.00100 0.00019+- 0.05338 0.08+-23.51 0.0 C37 RB * 0.00000< 0.00086 0.00006< 0.05338 0.00< 0.00 0.0 C38 SR * 0.00000< 0.00120 0.00011< 0.05338 0.00< 0.00 0.0 C39 Y * 0.00000< 0.00010 0.00000< 0.05338 0.00< 0.00 0.0 C40 ZR * 0.00000< 0.00760 0.00000< 0.05338 0.00< 0.00 0.0 C42 MO * 0.00000< 0.00010 0.00000< 0.05338 0.00< 0.00 0.0 C46 PD * 0.00000< 0.00010 0.00000< 0.05338 0.00< 0.00 0.0 C47 AG * 0.00000< 0.01200 0.00000< 0.05338 0.00< 0.00 0.0 C48 CD * 0.00000< 0.00740 0.00026< 0.05338 0.00< 0.00 0.0 C49 IN * 0.00000< 0.01100 0.00000< 0.05338 0.00< 0.00 0.0 C50 SN * 0.00000< 0.01200 0.00019< 0.05338 0.00< 0.00 0.0 C51 SB * 0.00000< 0.01700 0.00016< 0.05338 0.00< 0.00 0.0 C56 BA * 0.00000< 0.00330 0.00068< 0.05345 0.00< 0.00 0.0 C57 LA * 0.00000< 0.00010 0.00239< 0.05348 0.00< 0.00 0.0 C80 HG * 0.00000< 0.00010 0.00000< 0.05338 0.00< 0.00 0.0 C82 PB * 0.00023< 0.00230 0.00313< 0.05338 13.61< 0.1 C200 TC 2.49000+- 0.00010 2.86133+- 0.16708 1.15+- 0.07 2.2 C201 OC * 2.27000+- 0.00010 2.05702+- 0.11566 0.91+- 0.05 -1.8 C202 EC * 0.21300+- 0.00010 0.83361+- 0.13245 3.91+- 0.62 4.7 C203 SO4 0.56600+- 0.04100 0.06087+- 0.05342 0.11+- 0.09 -7.5 C204 NO3 * 0.24800+- 0.02300 0.25542+- 0.05485 1.03+- 0.24 0.1 C205 NH4 * 0.10100+- 0.01400 0.07860+- 0.05388 0.78+- 0.54 -0.4 C217 CL2 0.00000< 0.00010 0.01831< 0.05338 0.00< 0.00 0.3 C219 K2 0.00000< 0.00780 0.13519< 0.05339 0.00< 0.00 2.5 C300 F2 0.00000< 0.00010 0.00000< 0.00051 0.00< 0.00 0.0 C301 NA2 0.02660+- 0.00520 0.00000+- 0.00051 0.00+- 0.02 -5.1 C302 CA2 0.00000< 0.00010 0.00000< 0.00051 0.00< 0.00 0.0 C303 MG2 0.00000< 0.00010 0.00000< 0.00051 0.00< 0.00 0.0 C304 NA * 0.00425< 0.00970 0.00000< 0.00242 0.00< 0.57 -0.4 C305 CO * 0.00082+- 0.00053 0.00000+- 0.00012 0.00+- 0.14 -1.5